Research project - Colorado school of mines petroleum engineering
Transcription
Research project - Colorado school of mines petroleum engineering
Petroleum Engineering Department Research Fall 2013 PETROLEUM ENGINEERING Petroleum Engineering @ CSM • CSM Facts – Located in Golden, Colorado – foothills of the Rockies – 4000+ undergraduates, 1300+ graduates • Petroleum engineering – 18 tenured / tenure track / research / teaching faculty – $5.9 MM new research funding in FY 12 – Active research projects in • • • • • • • • Carbonate reservoir characterization Enhanced oil recovery Unconventional oil and gas Hydraulic fracturing Pore-scale physics and flow CO2 sequestration Geothermal Drilling PETROLEUM ENGINEERING PE Research / Teaching Faculty • • • • • • Linda Battalora ([email protected]) Alfred (Bill) Eustes ([email protected]) William Fleckenstein ([email protected]) Ramona Graves ([email protected]) Todd Hoffman ([email protected]) Hossein Kazemi ([email protected]) PETROLEUM ENGINEERING • • • • • • Carrie McClelland ([email protected]) Mark Miller ([email protected] Jennifer Miskimins ([email protected]) Erdal Ozkan ([email protected]) Ronny Pini ([email protected]) Manika Prasad ([email protected]) • • • • • • Azra Tutuncu ([email protected]) Wendy Wempe ([email protected]) Philip Winterfeld ([email protected]) Yu-Shu Wu ([email protected]) Xiaolong Yin ([email protected]) Luis Zerpa ([email protected]) PE Research Centers and Institution • CEMMC – Center for Earth, Materials, Mechanics, and Characterization (Graves / Miskimins) • MCERS – Marathon Center of Excellence for Reservoir Studies (Kazemi / Ozkan) • UNGI – Unconventional Natural Gas and Oil Institute (Tutuncu) PETROLEUM ENGINEERING PE Faculty and Research Areas • • • • • • • Alfred Eustes – Drilling for petroleum & non-petroleum Will Fleckenstein – Drilling and hydraulic fracturing Ramona Graves – Reservoir Characterization and CEMMC Todd Hoffman – EOR for unconventional reservoirs Hossein Kazemi – IOR/EOR, reservoir studies at MCERS Jennifer Miskimins – Stimulation and FAST consortium Erdal Ozkan – Well testing / MCERS / Unconventional reservoir engineering PETROLEUM ENGINEERING • • • • • • • Ronny Pinni – Phase behavior and multiphase flow in porous media Manika Prasad – Petrophysics of Organics, Clay, Sand, and Shale Azra Tutuncu – Geomechanics and unconventional gas and oil institute Wendy Wempe – Petrophysical modeling of mineral-fluid systems Yu-Shu Wu – CO2-EOR, CO2 sequestration, geothermal, hydrology Xiaolong Yin – Pore-scale physics and flow, suspension, phase behavior Luis Zerpa – EOR, reservoir, flow assurance, gas hydrate in nature Alfred William (Bill) Eustes III • Raised in southeastern US – – • Education – – – • Born in Florida Graduated Ben Eielson High School (Alaska) BS ME, Louisiana Tech University, 1978 MS ME, University of Colorado, Boulder, 1989 Ph.D. PE, Colorado School of Mines, 1996 Employment – ARCO Oil and Gas Company (June 1978 - April 1987) • • – Colorado School of Mines (April 1996) • – Senior Drilling Engineer Senior Production/Facilities Engineer Associate Professor Consultant • • • • Ponderosa Associates BP Alaska Sklar Exploration Fleckenstein, Eustes, and Associates PETROLEUM ENGINEERING Other Things About Me • ASME IPTI - Petroleum Division – Executive Committee member – seven years – Chair of the Division • NSF – Technical Advisory • • • Ice Coring and Drilling Rapid Access Ice Drill NASA – Martian drilling operations – Astrobiology project reviewer • • • Society of Petroleum Engineers American Association of Drilling Engineers – Student chapter faculty advisor • • • • International Association of Drilling Contractors PET Sigma Xi CSM – Undergraduate Coordinator Chapter co-author – Drilling in Extreme Environments – SPE Petroleum Engineering Handbook • General Engineering – SPE Drilling Engineering Textbook • • PETROLEUM ENGINEERING Drilling fluids Drilling problems 7 Courses Undergraduate – PEGN 311 – Drilling Engineering – PEGN 361 – Completion Engineering • Other classes – PEGN 315 – Field Session I – CSM 101 – Freshman Success Seminar – HNRS 312 – Foreign Area Study – HNRS 402 – McBride Practicum: Foreign Area Study Field Trip PETROLEUM ENGINEERING Graduate • • • • • • • • • PEGN 502 – Advanced Drilling Fluids (and Cement) PEGN 517 – Drilling Engineering Principles PEGN 594 – Directional and Horizontal Drilling PEGN 595 – Drilling Operations PEGN 596 – Advanced Well Control PEGN 597 – Tubular Design PEGN 598 – Underbalanced Drilling PEGN 598 – Well Planning Principles PEGN 603 – Drilling Models DRILLING Research Projects Since 1992 • Yucca Mountain Project – – – – – • Vibratory Core Rod Simulator Deviation Control Simulator PDC Bit Frequency Analysis Air Coring and Drilling Simulator Fuzzy Logic Controller Hanford Project – Resonant Sonic Drilling Simulator • Cougar Tool Project – Wave Propagation (Jarring) • Other Projects – Buckling in Curved Hole Project • DOE/BLM/USFS – Directional Drilling in the Rocky Mountains – Geothermal Drilling Risk Analysis • OMV – Benchmarking Drilling Operations PETROLEUM ENGINEERING DRILLING Research Projects Since 1992 • Ice Coring Project (NSF) – – – – – – • Jet Propulsion Laboratory Project – – – – • Review of US Ice Coring Operations Next Generation Ice Core Rig ICECUBE (South Pole Station) Rapid Access Ice Drill Lake Vostok Penetration Replicate Ice Coring Drilling State of the Art Review Prototype Bit Testing Minimum Mass Flowrate Autonomous Drilling Operations NASA – In-situ Resource Acquisition – Asteroid/Lunar Drill Systems PETROLEUM ENGINEERING Current and New Drilling Research • Unconventional Natural Gas and Oil Institute – High-Resolution Wellbore Gyro and Caliper Surveys for Torque and Drag – Analysis of Real-Time Operational Drilling – Applications of Distributed Temperature Sensing (DTS) in Unconventional Well Construction, Stimulation, and Production • National Science Foundation Sustainable Research Network – Routes to Sustainability for Natural Gas Development and Water and Air Resources in the Rocky Mountain Region • University of Colorado Boulder – lead institution • Geothermal drilling improvements – Sandia National Laboratory • Vaca Muerta Consortium - Argentina PETROLEUM ENGINEERING PERFORM Research Dr. Will Fleckenstein Interim Petroleum Engineering Department Head PETROLEUM ENGINEERING Resume Education 1986 – BS Petroleum Engineering, Colorado School of Mines 1988 – ME Petroleum Engineering, Colorado School of Mines 2000 – Ph.D. Petroleum Engineering, Colorado School of Mines Industry Experience Roughneck and Roustabout Operator’s Representative – Drilling, Completion and Workovers Engineer – Drilling, Completion, and Workover Design Area and Development Engineer Founder – FracOptimal, LLC Chairperson of Board - $1 Billion in Asset Credit Union PETROLEUM ENGINEERING Teaching Experience at CSM Completion Engineering (Junior level) Completions and Stimulations (Senior level) Advanced Completions and Stimulations (Graduate level) Drilling Engineering (Undergraduate and Graduate level) Drilling Fluids and Cementing (Graduate level) Redevelopment Special Topics (Graduate level) Artificial Lift Special Topics (Graduate level) Tubular Design (Graduate level) Integrated Field Development (Graduate level) Advanced Completions Engineering (Graduate level) Workover Design and Practice (Graduate level) Directional Drilling (Graduate level) Integrated Exploration & Development – Shales (Graduate Level) Integrated Exploration & Development – CBM (Graduate Level) Integrated Exploration & Development – Incised Valley Systems (Graduate Level) PETROLEUM ENGINEERING 14 Research Philosophy My research is devoted to research that solves critical human problems. My research aims at developing technology that can be directly applied, and may have significant commercial value. PETROLEUM ENGINEERING 15 NSF CRN Award – $1.4 Million to CSM 1. CU – CSM Partnership • CU and CSM, with other institutions, submitted a proposal to the NSF to study “Routes to Sustainability for Natural Gas Development and Water and Air Resources in the Rocky Mountain Region”, which was recommended for full funding, out of over 200 other preproposals 4 Goals for the CSM Petroleum Engineering Team 1. Assessment of the isolation of aquifers from gas- and oil-producing formations 2. Estimate the probabilities of casing and cement sheath failure 3. Examine the possibility of fracturing into aquifers using fracture modeling software 4. Evaluate procedures for “green” versus “non-green” well completions. PETROLEUM ENGINEERING 16 Shallow Aquifer Protection in General Cemented surface casing To protect surface water 1000’s of feet of rock formations between producing shale and surface waters Production casing PETROLEUM ENGINEERING 17 FracOptimal LLC – (CSM Equity Interest) FracOptimal LLC. was established to commercialize a patent pending, multi-stage fracturing technology invented by Dr. Fleckenstein at CSM. The second generation of the technology has now been developed and is ready to be prototyped. FracOptimal and CSM has received substantial fees for commercialization fees to date PETROLEUM ENGINEERING 18 Example of Possible Commercialization Verify Seal? PETROLEUM ENGINEERING A patent application titled “METHOD AND APPARATUS FOR TESTING A TUBULAR ANNULAR SEAL” has been filed to protect the intellectual property rights for the commercialization of this technology. 19 “Pig Prop” • Dr. Jennifer Miskimins reviewed and christened the technology “Pig Prop” • Fundamental change in how proppant is placed and used • Removes many of the chemicals in slickwater frac fluids • Much lighter proppant densities possible for same load bearing capability • Very high conductivities possible • Need to reduce to practice PETROLEUM ENGINEERING Dr. Ramona M. Graves Dean College of Earth Resource Sciences and Engineering & Petroleum Engineering Professor Colorado School of Mines Petroleum Engineering Department Golden, Colorado 80401 USA PETROLEUM ENGINEERING College of Earth Resource Sciences and Engineering CERSE is a unique College that combines earth science, engineering, economics, business, and social science. • • • • • • • Economic and Business Geology and Geological Engineering Geophysics Liberal Arts and International Studies Mining Engineering Petroleum Engineering The Colorado Geology Survey PETROLEUM ENGINEERING My Philosophy In order for use to stay a top quality programs …we must keep faculty - they are committed to both research and teaching. … we have to have quality graduate students. … we must create an integrated graduate environment of scholarship, professionalism, and become a graduate “community”. PETROLEUM ENGINEERING RESEARCH INTEREST RESERVOIR CHARACTERIZTION Cores Illite ROCKS Kaolinite PETROLEUM ENGINEERING Example (1) Research Projects SENSITIVITY STUDY OF FLOW UNIT DEFINITION BY USE OF RESERVOIR SIMULATION by Anne-Kristine Stolz SPE 84277 PETROLEUM ENGINEERING Example Flow Units Model 1homogeneous Model 2- GR Model 3-FZI Model 4-r35 Model 5-Pc Model 6-kh/fh Model 7-SMLP PETROLEUM ENGINEERING Results 70 60 RF (%) 50 40 BaseCase Model 1-homogeneous Model 2-GR Model 3-FZI Model 4-r35 Model 5-Pc Model 6-kh/phih Model 7-SMLP 30 20 10 0 0 0.5 1 1.5 Injected PV 2 2.5 3 Recovery Factor versus Injected Pore Volume PETROLEUM ENGINEERING Conclusions • Numerical simulation is important to confirm the flow unit assignment of a reservoir, in order to avoid inaccurate prediction of flow performance. • Results of the numerical simulation are a strong function of geologic model flow unit definition method. • Best correlation for a reservoir has to be established individually, based on data available PETROLEUM ENGINEERING Example (2) Research Projects DETERMINING THE BENEFITS OF APPLYING “STARWARS “ LASER TECHNOLOGY FOR DRILLING AND COMPLETING OIL AND GAS WELLS Special thanks to former students Darien O’Brien, Samih Batarsh, Bailo Suliman, Zane Gordon, Kristina Loop PETROLEUM ENGINEERING Quote "Drill for oil? You mean drill into the ground to try and find oil? You're crazy.” -- said to Col. Drake when he tried to enlist support for his project to drill for oil in 1859. PETROLEUM ENGINEERING Berea Sandstone CT Scan Sample ID: OBG3 Duration: 5.2 seconds Power: 6.2 kilowatts Continuous Beam Orientation: Horizontal Penetration: 1.6 inches COIL Laser PETROLEUM ENGINEERING Example (3) Research Projects Porosity and Permeability Changes in Lased Rocks Calculated Using Fractal Fragmentation Theory by Bailo Suliman CIPC 2004 Calgary, Canada PETROLEUM ENGINEERING What is a Fractal? • Originates from the Latin word factus which means to break • Collection of examples linked by a common point of view • Method for describing the inherent irregularity of natural objects • Fractal Theory applies to artificially fragmented rock • Fractal dimension is a relative measure of complexity (the greater the number, the more complex structure) PETROLEUM ENGINEERING Fractal Permeability Model (Flow Equations) Hagen-Poiseuille equation for flow rate though one straight capillary of diameter D: * D 4 * P q 128 * Lt * Darcy’s equation for flow rate though a tortuous path: k * A * P q Lt * PETROLEUM ENGINEERING Fractal Permeability Model (Combined Equation) Permeability equation in porous medium: L0Q * L10 D * DP 3 D k * Dmax PA 128 * A * (3 DT DP ) T T Where: PETROLEUM ENGINEERING Dp = Pore size fractal dimension Dmax = Maximum capillary diameter LT = tortuous length Lo = straight length D = diameter of average capillary DT = tortuosity fractal dimension Research Overview • Multidisciplinary Reservoir Characterization • Laser/Rock Interaction • Energy and Energy Engineering In general, any topic which helps us better understand reservoirs! PETROLEUM ENGINEERING Todd Hoffman Assistant Professor Background & Research PETROLEUM ENGINEERING Resume • Education – PhD, Petroleum Engineering, Stanford University, 2005 – MS, Petroleum Engineering, Stanford University, 2002 – BS, Petroleum Engineering, Montana Tech, 1999 • Employment – – – – Assistant Professor, Colorado School Of Mines, 2011-present Senior Reservoir Engineer, Golder Associates, 2009-2011 Reservoir Engineering Consultant, DRC Consulting, 2006-2009 Assistant Professor, Montana Tech, 2005-2008 PETROLEUM ENGINEERING Teaching Classes taught: • • • • • • PEGN 506 Enhanced Oil Recovery (Fall 11, 12 13) PEGN 438 Geostatistics (Spring 12, 13) PEGN 424 Reservoir Engineering II (Spring 13) PEGN 316 Massadona Geology Field Camp (Summer 13) PEGN 315 Summer Session I (Summer 12) PEGN 310 Fluid Properties (Fall 11, 12) PETROLEUM ENGINEERING Primary Research Interests and Experience • My main focus is on implementing Enhanced Oil Recovery techniques on Unconventional Oil Reservoirs • Additionally, I perform research on – IOR/EOR – Unconventional Reservoirs – Reservoir Modeling – Fractured Reservoirs • Interim Director of FAST Consortium PETROLEUM ENGINEERING Recent Projects at CSM EOR in Unconventional Oil Reservoirs • Modeling Gas Injection into the Sanish Field, ND • Are Longitudinal or Transverse Fractures Better for EOR in Unconventional Oil Reservoirs • MMP determination for Bakken Oil Reservoirs • EOS Model for Compositional Simulation of the Bakken • Theoretical and Experimental Evaluation of Injected Fluid Behavior in Unconventional Oil Reservoirs PETROLEUM ENGINEERING Recent Projects at CSM Unconventional Reservoir Engineering • Assessing the Upper and Lower Shale’s Contribution to Production from the Middle-Bakken • Effects of Natural & Hydraulic Fracture Characteristics on Current Analytical Models for Unconventional Reservoirs • Dynamic Reservoir Characterization for Optimization of Well & Completion Strategy in Fractured Shale Reservoirs • Reservoir Engineering Study to Determine Recovery, Refrac & EOR potential of Elm Coulee Field, MT • Modeling Complex Hydraulic Fractures in Shale Systems PETROLEUM ENGINEERING Recent Projects at CSM EOR Projects • Modeling Low Salinity Waterflood in Carbonates • Integration of Flow Simulation and Time-Lapse Seismic in a Continuous CO2 Injection Project in Delhi Field, LA • Modeling Lean Gas/Nitrogen Injection to Improve Liquid Recovery from Gas Condensate Fields Conventional Reservoir Engineering • Evaluating Water Influx with a Discrete Fracture Network Model for a Large Carbonate Reservoir • Incorporating Into Reservoir Models How Nonreservoir Effects Impact Production Data PETROLEUM ENGINEERING Modeling Gas Injection into Bakken Study Location Gridded Model Wells ND Hydraulic Fractures Sanish Model Sector Oil saturation profile for 4 new CO2 injectors case • CO2 increases production and is promising to increase RF from single digits of primary recovery PETROLEUM ENGINEERING Longitudinal or Transverse Fractures for EOR Fracture Orientation Cumulative Oil Production LF TF LTF • Production Rate of Injected Gas Long Transverse Production is similar, but much more gas cycling for transverse case Transverse Longitudinal PETROLEUM ENGINEERING Rising Bubble Apparatus (RBA) Rising Bubble Apparatus (RBA) Schematic RBA showing monitor and computer connection PETROLEUM ENGINEERING RBA - Test Sample MMP Conditions: 2215 psig 145 0F PETROLEUM ENGINEERING Bakken - EOS Model Lumping Scheme • Peng-Robinson Model • Matching Fluids data with EOS • Use EOS Model for Compositional Flow Simulation Model PETROLEUM ENGINEERING Bakken Reservoir Model Blue Blocks: Perm = 0.05 md Green Blocks: Perm = 0.107 md Red Blocks: Perm = 107md PETROLEUM ENGINEERING Core flooding • Incremental Recovery • Fracture to Matrix Penetration • Effects of WAG PETROLEUM ENGINEERING Upper and Lower Bakken Shale Production Contribution • Kerogen rich U&L Bakken shale (10-40%): Desorption significant • Theoretical scheme for desorption taking place in the liquid (oil) bulk Triple porosity break up • Simulation scheme for Bakken-type liquid rich shale U&L Shale matrix (Desorption and Diffusive matrix to fracture fluid transfer) PETROLEUM ENGINEERING U&L Shale and Middle Bakken fracture Middle Bakken matrix (Darcy matrix to fracture fluid transfer) 4D Seismic Assisted Reservoir Modeling • Time-lapse seismic data not only provide information for geological and geophysical characterization purposes • Moreover, it can be utilized in seismic integrated history matching process where synthetic seismic attributes (converted from flow simulation results) and actual seismic attributes (obtained from seismic interpretation) are matched to validate the reservoir model PETROLEUM ENGINEERING Acoustic impedance mismatch before 4D seismic integrated history matching Acoustic impedance mismatch after 4D seismic integrated history matching Modeling Complex Hydraulic Fractures in Shale Systems Significance Evaluate conformance issues Improve production predictions Reservoir development (well and hydraulic fracture spacing) PETROLEUM ENGINEERING The FAST Consortium • Fracturing, Acidizing Stimulation Technology (FAST) Consortium • Sponsored by industry, i.e. companies pay a flat fee and vote on projects to pursue • In existence since January 1, 2004 • Have meetings twice a year, November and April • 27 member companies • 16+ various projects on improved stimulation PETROLEUM ENGINEERING FAST’s Mission • Perform practical research in the area of oil and gas well stimulation with an emphasis on: – Direct application – Timely application – Production improvement • Provide an opportunity for graduate students to work on industry-sponsored projects PETROLEUM ENGINEERING Multiphase Flow Pressure Calculation Multiphase Flow Pattern Recognition Bubble Flow Slug Flow Annular-Mist Flow Stratified Flow Support Vector Machine model outputs flow pattern prediction for inclination angle from 0° to 90° Bottom-hole Pressure Prediction • • Incorporate BP neural network models into piecewise bottom-hole pressure calculation procedure Yield a least average absolute percent error of 3.1% Combine multiphase correlations and artificial neural network models to broaden prediction range and improve prediction accuracy PETROLEUM ENGINEERING Matrix Imbibition of Shale Gas Reservoirs and Potential Formation Damage Impacts • Up to 80% of injected fracturing fluid remains in the shale reservoirs after hydraulic fracture work. • Where is the fracturing fluid in shale gas formations? • How does the remaining fluid impact gas production? Face damage evaluation machine Shale rocks Measuring and evaluating the damage from the remaining hydraulic fracturing fluid in shale gas reservoirs PETROLEUM ENGINEERING Modeling clean-up and long term production from hydraulic fracturing wells • Modeling well flowback and long term production from hydraulically fractured wells in Woodford Shale, Oklahoma • Numerically investigating hydraulic fracturing processes, clean-up and relevant physics Develop a working model for Cana Woodford Shale development PETROLEUM ENGINEERING Single and Multiphase Non-Darcy Flow in Fracturing Sand • Single phase non-Darcy (ND) gas flow can reduces Fcd by 95%. • Additional 35% reduction is expected if multiphase non-Darcy flow is considered. • The usage of Frac sand (resin-coated and uncoated) has been increasing • Impact of ND flow on Frac Sand is greater than ceramic proppant. Assess the importance and range of applicability of: angularity, sphericity, grain size distribution, and resin coating on Barree & Conway ND flow model parameters. PETROLEUM ENGINEERING Fracture Proppant Conductivity Correlations Under Different Proppant Types, Sizes and Temperatures Taking Into Account The Effect of Time, Stress and Proppant Strength • Conductivity is one of the most important design criterions of any hydraulic fracture • Conductivity: is the volumetric capacity to flow Kf Wf reservoir fluids through porous proppant media • Mathematically: Fracture Conductivity (md-ft) = kf X wf Proppant permeability and width Project Objective: Evaluate more than 2,500 proppant conductivity tests done by Stimlab and develop correlations that can estimate the proppant fracture conductivity under varies conductions PETROLEUM ENGINEERING Shale Damage Mechanism: Proppant Embedment Proppant Embedment Fluid-Proppant Selection • Proppant embedment is an inevitable issue, dictated by Young’s modulus of the formation and damages conductivity • Embedment poses bigger threat under the influence fracturing fluids Develop a fluid-proppant selection to minimize embedment in Niobrara Shale PETROLEUM ENGINEERING Optimizing well and fracture placement Variation in fracture geometry and conductivity along horizontal well • Incorporating fracture to fracture interference PETROLEUM ENGINEERING Incorporate hydraulic fracture properties into a flow simulator • Contribution from each fracture is different • Drainage volumes used to optimize well spacing Hossein Kazemi Professor, Chesebro’ Distinguished Chair in Petroleum Engineering Pore-Scale Physics, Mathematical Modeling and Enhanced Oil Recovery in Conventional and Unconventional Reservoirs PETROLEUM ENGINEERING Bio • • • • B.S. and Ph.D., University of Texas, Austin Member of National Academy of Engineering SPE Honorary and Distinguished Member Co-director of Marathon Center of Excellence in Reservoir Studies (MCERS) PETROLEUM ENGINEERING The arrow shows a droplet just about to drop off of the channel wall and to migrate as a spherical droplet (From: O’Brien, Thyne and Slatt, AAPG Bull, Nov. 1996) PETROLEUM ENGINEERING Berea Sandstone, 119 md, Brine PETROLEUM ENGINEERING PETROLEUM ENGINEERING An outcrop of a Tensleep sandstone and Madison dolomite in Wyoming’s Alcova Reservoir PETROLEUM ENGINEERING Multistage Hydraulic Fracture Stimulation (Illustration: Courtesy of TAM International, Inc.) PETROLEUM ENGINEERING Idealized Mathematical Model Of Multi-stage Hydraulic Fracturing PETROLEUM ENGINEERING 3-D Numerical Model Pressure Solutions: Hybrid Unsteady-State (USS) and Pseudo-Steady State (PSS), (No WBS) PETROLEUM ENGINEERING 3-D Numerical Model Pressure Derivatives: Hybrid Unsteady-State (USS) and Pseudo-Steady State (PSS), (No WBS) PETROLEUM ENGINEERING Mini-DST Tool and Configuration Is a dual-packer module with a downhole pump Isolates a 3-foot open-hole interval of the wellbore Measures pressure using strain and quartz crystal gauges in the lower part of the tool SPE 159597 • Mini-DST to Characterize Formation Deliverability in the Bakken • Basak Kurtoglu, et al PETROLEUM ENGINEERING Core analysis 1” dia. x 1” length Kurtoglu , et al, SPE 159597 < 1 cc pore space 0.0001 md 6000 Mini- DST 5500 Pressure [psia] Pressure [psia] 5000 4500 4000 - Lower Three Forks (1) - Lower Three Forks (2) - Upper Three Forks (3) - Upper Three Forks (4) - Middle Bakken (5) - Middle Bakken (6) - Scallion (7) - Scallion (8) (act & ref) 3500 3000 0.4 0.6 0.8 1 1.2 1.4 Time [hr] 1.6 1.8 2 2.2 2.4 ~ 2500 cc formation fluid production rinv 5 - 50 ft 0.01 md - 0.1 md Pressure [psia] vs Time [hr] P-Pi (ref) (FL^2).d(P-Pi)/d(FL^2) (ref) Start linear flow End linear flow Start radial flow Mini-frac falloff after formation closure ~ 43 bbls injection followed by 7 days of falloff rinv 70 - 150 ft 0.01 md - 0.1 md 100 Start linear flow End linear flow Start radial flow Reservoir initial pressure Radial flow slope Far field mobility 10 1E-4 1E-3 0.01 0.1 45.8649 hr 118.438 hr 195.114 hr 6916.08 psia 7202.22 psia 0.0870848 md/cp 1 6000 5000 4000 Liquid Rate 400 200 Pressure (PSI) Pressure Derivative (PSI) Pressure 7000 Pressure [psi] Liquid rate [STB/D] Pressure [psia] ACA plot Pressure buildup 1000 10 days of shut-in rinv 130 ft 0.03 md 100 10 0 0.01 11/15/2009 12/18/2009 1/20/2010 2/22/2010 3/27/2010 History plot (Pressure [psia], Liquid rate [STB/D] vs Time [hr]) 0.1 1 10 100 Time(hr) [hr] Time Log-Log plot: p-p@dt=0 and derivative [psi] vs dt [hr] 30 Model - Production Data Analysis µ 0.4 cp 1.33 RB/STB B 24 ft h 8828 ft W 0.056 φm Model Normalized Pressure , ∆p/q (PSI/STB/D) 25 20 φf y= 1.637x-2.058 15 ct,m 5 ct,f m b kf, eff 0 Shf 10 kf 0 1 2 3 4 5 6 7 8 9 10 Square Root Time, t1/2 (DAY1/2) PETROLEUM ENGINEERING 11 12 13 14 15 Well history 1.2 years of production 0.0058 1.E-06 1/psi 1.E-05 1/psi 1.637 -2.058 (psi/stb)/d 1/2 psi/bbl 0.016 md 2.841 md 120, 000 BBLS ~ 0.01 md -0.011 Phase Envelope for Large Pores Phase Envelope for Unconfined Fluid System 1 Oil API 51.4 , OGR 30 STB/MMSCF, & GOR 33,333 SCF/STB 5000 2-Phase Boundary Pres = 4500 psi 99 Vol % 4500 98 Vol % 4000 97 Vol % 96 Vol % Pressure (psi) 3500 95 Vol % Critical Point 3000 2500 2000 1500 1000 500 Tres = 250 F 0 -200 -100 0 100 200 300 400 Temperature (F) PETROLEUM ENGINEERING 500 Undersaturated Gas-Oil Contact versus Saturated GOC (Danesh, 1998), P 196 PETROLEUM ENGINEERING Unconventional Reservoirs modified from Bohacs et al., 2013 PETROLEUM ENGINEERING 78 A Bakken Core Surrounded by Low-Salinity Brine From: Kurtoglu, PhD thesis, CSM, 2013 PETROLEUM ENGINEERING 78 Multiphase Rate Transient Analysis of Eagle Ford Ilkay Eker and Basak Kurtoglu, Graduate Research, CSM PETROLEUM ENGINEERING Multiphase Rate Transient Analysis of Bakken in Bailey Field Basak Kurtoglu, PhD Thesis, CSM, 2013 300 Rate Normalized Pressure ∆p/q (psi/STB/D) 250 200 150 100 50 0 0 10 20 30 Square Root of Time (day1/2) PETROLEUM ENGINEERING 40 Flow in organic-rich shale SEM image of a fine-grained sandstone sample (Passey et al., 2010) PETROLEUM ENGINEERING Ion-milled SEM of a Barnett sample (Passey et al., 2010) Schematic of pore and fluid distribution in shale Water-induced Stress Model PETROLEUM ENGINEERING Temperature and stress change PETROLEUM ENGINEERING Induced Micro-Seismicity by Cold-Water Injection Shear stress Fakcharoenphol, et al., CSM, 2012 Increase P Decrease T σ‘3a Combined effect PETROLEUM ENGINEERING σ'1a σ'3 ' p 3 T T0 σ'1 Core Flooding and Relative Permeability PETROLEUM ENGINEERING 86 Core Flooding Apparatus (Formation Response Tester, FRT 6100) PETROLEUM ENGINEERING USA CO2-EOR Production History (Oil & Gas Journal) PETROLEUM ENGINEERING Delhi Field Continuous CO2 EOR Tingting Chen, PhD candidate in Civil and Environmental Engineering, Collaborative Research, Reservoir Characterization Project (RCP), Geophysics OOWC: 3286 TVDSS Initial field fluid saturations PETROLEUM ENGINEERING Current CO2 saturation Seismic-Driven Reservoir Simulation and Monitoring of Waterflood Processes in Carbonate Reservoirs Project objectives: Funded by: Develop a reservoir fluid flow and geomechanics model to quantify stress changes and microseismic events Shear stress Use microseismic response to identify reservoir channels Increase pressure Decrease temperature Effective normal stress, Stress change during water injection PETROLEUM ENGINEERING Principal Investigators: Dr. Hossein Kazemi Dr. Thomas Davis Dr. Luis Zerpa WATERFLOOD MODEL-- Observations 800 200,000 History Oil Rate (STB/D) 600 150,000 Base Case Model 400 100,000 200 50,000 0 Cumulative Production (STB) Model with Water Injectors 0 0 100 200 300 400 500 600 Time (DAYS) The incremental production observed in the waterflood case shows that oil is pushed only from microfractures which are also concluded as a key driver mechanism for primary production The simulation response from the waterflood case also compared with the waterflood field data from the Crescent Point Energy, applied in Bakken Saskatchewan. PETROLEUM ENGINEERING Fracture Fluid Cleanup Field Example 3 years of fluid clean up Gas Rate (Mscf/d) Incremental reserves Before stimulation After stimulation 1 yr Time PETROLEUM ENGINEERING Courtesy of Gasfrac (2011) Damage Mechanisms Gel Filtrate Gel Filter Cake Microfractures • • • • Water blockage Gel filter cake formation Unbroken gel residue Polymer adsorption PETROLEUM ENGINEERING Proppant Unbroken Gel • • • • Proppant compaction Reservoir compaction Clay swelling Fines migration Model Development Geomechanics-Flow Model (Reservoir Module) PETROLEUM ENGINEERING Fracture Propagation Model (Fracture Module) Water-Oil Displacement Model for USS Transfer Function Numerical Modeling Results: Matching Oil Recovery T21: Fractured with open ends 1 1 0.9 0.9 0.8 0.8 0.7 0.7 0.6 Oil recovery Oil recovery T4: Fractured with only fracture open 0.5 0.4 0.3 0.5 0.4 0.3 0.2 0.2 0.1 0 0.6 0.1 0 10 20 30 40 50 60 70 Time (hr) Oil recovery by water Oil recovery by surfactant Numerical match 80 90 100 0 0 10 20 30 40 50 60 Oil recovery by water Oil recovery by surfactant Numerical match Centrifuge core results from Baharak Alamdari, 2011, CSM PETROLEUM ENGINEERING 70 Time (hr) 80 90 100 Slide 95 ENHANCED RECOVERY BY WATER INJECTION IN BAKKEN Fractures Macrofractures Matrix Water flow through fractures Microfractures (1) Cooled formation (3) PETROLEUM ENGINEERING (2) Temperature-induced microfractures (4) ES-SAGD Process Solvent dissolved in bitumen Solvent Vapor Steam Chamber Injection Well Oil Drainage Production Well PETROLEUM ENGINEERING PE-CSM Centrifuge Picture • Drainage and imbibition • 16500 rpm-15500 rpm • Automatically records recovery 15500 rpm= above 44000 times of earth gravity acceleration PETROLEUM ENGINEERING Centrifuge Experiments PETROLEUM ENGINEERING Comparison of Surfactants 0.5cc Emulsion A complex anionic surfactant system PETROLEUM ENGINEERING A simple non-anionic ethoxylated alcohol surfactant system 99 Stimulation and Unconventional Reservoirs Jennifer L. Miskimins, Ph.D., P.E. Associate Professor Fall 2013 PETROLEUM ENGINEERING Jennifer L. Miskimins, Ph.D., P.E. • Education – B.S. Petroleum Engineering, Montana Tech, 1990 – M.S. Petroleum Engineering, Colorado School of Mines, 2000 – Ph.D. Petroleum Engineering, Colorado School of Mines, 2002 • Experience – – – – PETROLEUM ENGINEERING Marathon Oil Company, 1990-1998 Colorado School of Mines, 2002-Present Barree & Associates, 2012-Present Registered Professional Engineer Jennifer L. Miskimins, Ph.D., P.E. • Other – SPE Distinguished Lecturer 2010-2011 and 2013-2014 – SPE Production & Operations Journal Executive Editor, 20082011 – Technical Committees • • • • SPE Hydraulic Fracturing Technical Conference, February 2014 SPE Liquids Rich Conference, September 2012 SPE Books Committee 2012-2015 SPE Production & Operations Technical Advisory Board – CSM, Diversity Committee Past Chair • Classes currently teaching – PEGN 522, Advanced Well Stimulation PETROLEUM ENGINEERING Main Research Interests and Current Projects • Hydraulic fracturing • Stimulation and completions • Unconventional reservoirs • RPSEA – Cryogenic fracturing fluids • Proppant transport in complex fractures PETROLEUM ENGINEERING Erdal Ozkan Professor Co-Director, MCERS Research Interests & Research Work PETROLEUM ENGINEERING 104 Personal BACKGROUND PhD, Petroleum Engineering, University of Tulsa (1988) MS, Petroleum Engineering, Istanbul Technical University (1982) BS, Petroleum Engineering, Istanbul Technical University (1980) Faculty at CSM (since 1998) Co-Director of Marathon Center of Excellence for Reservoir Studies (since 2005) PROFESSIONAL INTERESTS Reservoir Engineering, Modeling Unsteady Flow in Porous Media, Pressure-Transient Analysis, Horizontal Well Technology, Shale-Gas and Shale-Oil Reservoirs MISCELLENEOUS AWARDS SPE Formation Evaluation Award (2007) SPE Distinguished Member (2009) SPE 25 Year Club member (2010) Distinguished Alumnus, PE Department, The University of Tulsa (2007) SPE Editorial Review Committee Awards (1998, 2005, 2006, 2007) PETROLEUM ENGINEERING 105 Personal ACADEMIC EXPERIENCE Faculty at CSM: Prof. (since 2002), Assoc. Prof. (1998 – 2002) Co-Director: Marathon Center of Excellence for Res. Studies, CSM (since 2003) Faculty at Istanbul Tech. U.: Assoc. Prof. (1992 – 1998), Assist. Prof. (1989 – 1992) Visiting Professor: Petroleum Institute, Abu Dhabi (2011), U. of North Fluminense, Brazil (2010) Research Assoc. (on sabbatical leave from ITU): University of Tulsa (1997 – 1998) CONSULTING OMV, 2010 Marathon Oil Co., 2009 Baker Hughes, 2004 – 2006 Rosneft, 2007, 2010 EOG, 2007 Schlumberger, 1996 – 1997. PETROLEUM ENGINEERING 106 Personal MISCELLANEOUS PROFESSIONAL SERVICES AND ACTIVITIES: Member: SPE Reservoir Description and Dynamics Advisory Committee (since 2003) Technical Director: SPE Research and Development Technical Section (2007 – 2010) Chief Editor: JPSE (2006 – 2008) Executive Editor: SPEREE (2003 – 2005). Review Chairman: SPEREE (1999 – 2003) Assoc. Editor: ASME JERT (2001 – 2003), JNGST (since 2009), JPEP (since 2010) Technical Editor: SPEFE (1997 – 1999), SPEREE (since 2005) Editorial Board Member: SPEJ (1997 – 1999) Conference Chair/Co-Chair: SPE Unconventional Gas (2010), SPE Shale Gas Production (2008), SPE Unconventional Reservoirs (2008), SPE ATW Analysis of Well Performance – Future View (2007), SPE ATW on Unconventional Gas (2006) Committee Member: SPE North American Unconventional Gas Conference (2011), SPE ATW on Advances in Performance Diagnostics for Fractured and Horizontal Wells, (2007), 2nd International Oil Congress in Mexico (2007), SPE Middle-East Colloq. on Pet. Eng. Education (2006), ASME Energy Sources Technology Conference (2001), TCE/OMAE2000 Joint Conference on Energy for the New Millennium (2000), SPE Forum on Res. Eng. Aspects of Multilateral and Advanced Wells (1999), 9th Turkish Petroleum Congress (1992) PETROLEUM ENGINEERING 107 Research Interests Reservoir Engineering Modeling Unsteady Flow in Porous Media Block 1 Block 2 qe13 ze1 q~e12 q~w11 qe14 q~w1 2 ze2 q~e11 ye1 qe13 q~e22 q~w21 q~e21 q~w11 ye2 1 e5 q q~w22 q~w1 2 qe15 xe1 q~e12 q~w11 q~w1 2 L1h1 L2h1 q~e11 2yf Pressure profile in a horizontal well fracture qe14 xe2 q~ 2 e2 2zf2 q~e21 q~w21 q~w22 L2h1 L2h 2 Semi-analytical simulation 2zf1 2yf Horizontal well in a heterogeneous reservoir 200 ft 200 ft 80 ft 200 ft Lh=400 ft 950 ft 1600 ft PETROLEUM ENGINEERING 150 ft 200 ft 200 ft 108 Research Interests Unconventional Gas and Oil ye = dF/2 Fractured horizontal wells HYDRAULIC FRACTURE kF, wF, fF, ctf OUTER RESERVOIR ko, fo, cto xe Unconventional flow regimes in shale matrix xF Slip flow Microfractures Coupling flow at the matrix-fracture interface HORIZONTAL WELL PRODUCTIVITY INDEX, J/nF, Mscf/D-psi2 1E - 3 Reservoir Fracture Permeability = 2000 md Matrix Permeability = 10-6 md Trilinear flow model for fractured horizontal wells in shale Increasing number of fractures 1E - 4 Number of Fractures per foot 1E - 5 Multiple hydraulic fractures Stimulated reservoir volume ------------------------------------- 1.2E 8.0E 4.0E 2.0E 1.2E 1E - 6 1E --3 1E --2 1E --1 -0 -1 -1 -1 -1 1E+0 1E+1 1E+2 1E+3 1E+4 1E+5 TIME, t, hr Gas storage in shale PETROLEUM ENGINEERING INNER RESERVOIR NATURALLY FRACTURED kf, ff, ctf, km, fm, ctm Productivity of fracture horizontal wells in shale Research Interests Horizontal, Multilateral, and Fractured Wells Well and Reservoir Performance Prediction Multilateral wells Horizontal-well fractures Horizontal wells in anticlines Perforated horizontal wells PETROLEUM ENGINEERING Horizontal-well completion optimization Research Interests Pressure-Transient Analysis Fractured horizontal well PTA 1.E+02 1E+2 1E+1 Horizontal-well PTA CD = 0 1E+0 PRESSURE CD = 0.01 pwD and dpwD/dlntDxf PRESSURE DROP, pi - pwf , psi 1E+3 1.E+01 1.E-01 1.E-02 1.E-03 1.E-04 1.E-11 1E-2 1E-1 1E+0 1E+1 1E+2 1E+3 1E+4 1E+5 Non square-Shape Square Shape 1.E+00 DERIVATIVE 1E-1 FCD = 100 Radial linear Formation linear Pseudoradial 1.E-09 1.E-07 o o 200 ft 1.E-05 1.E-03 1.E-01 1.E+01 tDxf FLOWING TIME, t, hr Horizontal-well skin effect z ~r x k s k sy k sz kr kry krz Skin Zone h rw y z Lh PETROLEUM ENGINEERING ~r s w 200 ft 70 ft Multilateral-well PTA Books and Book Contributions Raghavan, R. and Ozkan, E.: A Method for Computing Unsteady Flows in Porous Media, Pitman Research Notes in Mathematics Series, Longman Scientific & Technical, Essex (1994). Petroleum Engineering Handbook, Vol. 1, General Engineering, Chapter 3, Mathematics of Transient Analysis, Society of Petroleum Engineers, Richardson, Texas (2006) Transient Well Testing, SPE Monograph 23, Chapter 13, Slanted Wells, Society of Petroleum Engineers, Richardson, Texas (2009). Transient Well Testing, SPE Monograph 23, Chapter 14, Horizontal Wells, Society of Petroleum Engineers, Richardson, Texas (2009). PETROLEUM ENGINEERING Selected Recent Papers/Publications Medeiros, F., Ozkan, E., and Kazemi, H.: “A Semi-Analytical Approach to Model Pressure-Transients in Heterogeneous Reservoirs,” SPEREE (2010) Medeiros, F., Kurtoglu, B., Ozkan, E., and Kazemi, H.: “Analysis of Production Data From Hydraulically Fractured Horizontal Wells in Shale Reservoirs,” SPEREE (2010) Raghavan, R., and Ozkan, E.: “Flow in Composite Slabs,” SPE Journal (2010). Ozkan, E., Brown, M., Raghavan, R., and Kazemi, H.: “Comparison of Fractured Horizontal-Well Performance in Conventional and Unconventional Reservoirs,” SPEREE (2011) Medeiros, F., Ozkan, E., and Kazemi, H.: “Productivity and Drainage Area of Fractured Horizontal Wells in Tight Gas Reservoirs,” SPEREE (2008) Ozkan, E., Raghavan, R., and Apaydin, O. G.: “Modeling of Fluid Transfer from Shale Matrix to Fracture Network,” SPE 134830, SPE Annual Technical Conference and Exhibition, Florence, Italy (2010) Davletbaev, A., Baikov, V., Ozkan, E., Garipov, T., Usmanov, T., Asmandiyarov, R., Slabetskiy, A., and Nazargalin, E.: “Multi-Layer Steady-State Injection Test with Higher Bottomhole Pressure than the Formation Fracturing Pressure,” SPE 136199, SPE Russian Oil & Gas Technical Conference and Exhibition, Moscow, Russia (2010) Brown, M., Ozkan, E., Raghavan, R., and Kazemi, H.: “Practical Solutions for Pressure Transient Responses of Fractured Horizontal Wells in Unconventional Reservoirs,” paper SPE 125043, presented at the 2009 SPE Annual Technical Conference and Exhibition held in New Orleans, Louisiana, Oct. 4–7, 2009. Wu, J., Georgi, D., and Ozkan, E.: “Deconvolution of Wireline Formation Test Data,” paper SPE 124220, presented at the 2009 SPE Annual Technical Conference and Exhibition held in New Orleans, Louisiana, Oct. 4–7, 2009. PETROLEUM ENGINEERING Selected Research Projects Investigation of the Coalbed Methane Potential of Turkey, funded by the State Planning Agency of Turkey Performance of Multiple Horizontal Wells in a Common Reservoir, funded by the Scientific and Technical Research Council of Turkey Optimization of Horizontal Well Completions, JIP funded by the US Department of Energy, US Department of the Interior, Minerals Management Service, Associated Western Universities, and private industry Optimization of Plunger Lift Performance in Stripper Wells: Funded by the Stripper Well Consortium, Pennsylvania State University Analysis and Evaluation of Horizontal Well Performance in the Bakken Shale of North Dakota and Montana, funded by Marathon Oil Co.; with H. Kazemi Analysis of Enhanced Oil Recovery Processes in the Akal, Nohoch, Ku, Maloob and Zaap Fields, funded by IMP/PEMEX; with H. Kazemi Streamline Simulation of Tracer and CDG Injection to Chihuido De La Sierra Negra Field, funded by Repsol, YPF, Argentina; with H. Kazemi Reservoir Study of Margarita Gas-Condensate Field, funded by Repsol, YPF, Argentina; with H. Kazemi Infill Drilling in a Fluvial Reservoir Under Waterflooding, funded by Repsol, YPF, Argentina; with H. Kazemi Wasatch–Mesaverde Reservoir Characterization: Funded by Kerr McGee; with H. Kazemi An Efficient Production-Data Analysis Algorithm for Layered Tight-Gas Reservoirs, Funded by Shell Canada PETROLEUM ENGINEERING Phase equilibria and multiphase flow in porous media Research Summary Ronny Pini Assistant Professor PETROLEUM ENGINEERING Resume • Education – 2009: PhD, Mechanical and Process Engineering, ETH Zurich Thesis: Enhanced Coal Bed Methane recovery finalized to carbon dioxide storage (Advisor, Prof. Marco Mazzotti) – 2004: MS, Chemical Engineering, ETH Zurich • Experience – 2013-current: Assistant Professor, Petroleum Engineering, Colorado School of Mines – 2010-2013: Postdoc, Energy Resources Engineering, Stanford University (Prof. Sally Benson) – 2009-2010: Postdoc, Mechanical and Process Engineering, ETH Zurich PETROLEUM ENGINEERING Teaching • Courses currently teaching – PEGN 413, Gas Measurement and Formation Evaluation Lab (PVT Lab) • Courses taught in the past – Labs in process engineering (ETH Zurich, 2006-2009) – Energy 201, Laboratory measurement of reservoir rock properties (Stanford University, 2010-2013) PETROLEUM ENGINEERING Research Experience Dissolution Adsorption • Working fluids: CO2, CH4, N2, H2… • Materials: - Commercial: act. carbon, zeolites, … - Natural: coals • Adsorption studies - Pure fluids and mixtures - Low- and High Pressure - Modeling (Lattice DFT) • Working fluids: N2, CH4, CO2… • Working fluids: CO2, N2, brine • Materials: coal cores • Materials: sandstones cores • Permeability studies - High pressure experiments - 1D core model (PDEs) • Core-flooding studies - High pressure experiments - Capillary pressure and rel. perm - Capillary heterogeneity! - Visualization technique (x-ray CT) • Applications: - Tissue engineering • Applications: - ECBM recovery - CO2 sequestration • Applications: - CO2 sequestration in saline aquifers - Enhanced Oil Recovery (EOR) • Publications: Pini et al., Macromol Sy 2007, 259, 197 Pini et al., J Polym Sci B 2008, 46, 483 • Publications: • Publications: Pini et al., JGR-Earth 2009, 114, B04203 Pini et al., Adv Water Res 2012, 38, 48 Pini et al., Water Resour Res, 2013 Pini et al., Adsorption 2011, 17, 889 • Working fluids: CO2 • Materials: - PGA and PLA copolymers • Dissolution and swelling studies - Visualization (experiment) - Modeling (Sanchez-Lacombe EOS) 2007, 259, 197–202 Macromol. Symp.Macromol. 2007, 259,S1ymp. 97–202 199 199 hp can bearead, a brass holder, whose hp can be read, using brassusing holder, whose dimensions areaknown, as aThe reference. The dimensions are known, as reference. initial volume ofinthe sample initial volume of the sample the beakerinisthe beaker is calculated initial sample calculated from initial from sample mass and mass and density as measured with a H elium pycnodensity as measured with a H elium pycnometer A ccuPyc1330 (M icromeritics, Belmeter A ccuPyc1330 (M icromeritics, Belgium).height The initial of the non-swollen gium). The initial of theheight non-swollen p p as h 2p ¼ V p =ðpr 2 Þ, polymer is then obtained polymer is then obtained as h 0 0 ¼ V 0 =ðpr 0Þ, where r is the internal of the beaker. where r is the internal radius of theradius beaker. p values, r p , are reported The initial density The initial density values, r 0 , are reported 0 1 a set of images in Table 1. inI nTable Figure1. 1I na Figure set of images of the PDLLatA sample at of the swelling of swelling the PDLLofA the sample COpressures pressures is shown. different COdifferent is shown. 2 exposure 2 exposure The actual of the polymer sample The actual value of thevalue polymer sample V p at each specific condition is thus volume V p atvolume each specific condition is thus Figure 2. Figure 2. Equation and the correinserted in inserted Equationin(1) and the(1)correEffect of the swelling correction on the CO2 sorption Effect of the swelling correction on the CO2 sorption sponding q¼ ms=mp0 is evaluated. sponding sorption q ¼sorption ms=mp0 is evaluated. of . PSDorption Sorption correction with swelling correction of PDLLA at 358C with. swelling LLA at 358C When the pressure in the(~balance When the pressure value in thevalue balance (~ correction ) and without ) and without (~ ).correction (~ ). does not match does not match exactly the exactly pressuretheat pressure at which view cell experiments carried andpressure andaitvalue reaches a value of about which the view cellthe experiments are carried are pressure it reaches of about out, value of the swelling at the80% required out, the value of the swelling at the required at 200 80% bar. at 200 bar. by interpolating the pressure is pressure obtained is byobtained interpolating the swelling through a fit. polynomial fit. swelling data throughdata a polynomial t is worth that the correction I t is worth Inoting, that noting, the correction Results Results broughtinto by account taking into brought by taking the account volume the volume change of the polymer sampletoisessential to The equilibrium swelling and sorption change of the polymer sample isessential The equilibrium swelling and sorption reliable of CO 2 solubility, behavior of investigated the systems investigated in this get reliablegetvalues of values CO 2 solubility, behavior of the systems in this at highI npressures. I n fact, accordwork is with modeled with the Sanchezespecially atespecially high pressures. fact, accordwork is modeled the Sanchezing to(1), Equation (1), thecorrecbuoyancy correc- (SL L acombe (SLof) equation state.[18] I n this ing to Equation the buoyancy L acombe ) equation state.[18] Iof n this b met term ðVincreases þ V p Þwith increases with pressure, equation,density pressure, and temperation term tion r b ðV met þ Vrp Þ equation, and density temperaincreasing fluid bulk Thisture effect tureby are related by the following expression: increasing fluid bulk density. Thisdensity. effect is areis related the following expression: shown 2, in where Figure the 2, where shown in Figure sorptionthe sorption 1 1 of LCO PDLL A plotted as of CO 2 in PDL A is plotted asis a function ofa function ~ 01 r~ þ P~r~þÞþ T~ r~lnð1 ¼0 r~ þ P~ þofT~ lnð1 1 r~0Þþ r¼ 2 in r0 r for twocases, different cases, i.e. by pressure forpressure two different i.e. by (3) (3) of V p in(1)Equation (1) keeping thekeeping value ofthe V pvalue in Equation p /g ] Activated Carbon CO2 7 Zeolites Dissolution, q [g [mmol/g] ex Multiphase flow 0.6 8 Excess adsorption, n Single phase flow 6 0.5 0.4 p to symbols) V 0 (empty where symbols) constant andconstant equal toand V 0p equal (empty where r 0 is of thesites number of sites r 0 is the number occupied by occupied by ~ T~ are ~ T~and or itcorrecting for the(filled swelling (filled a or correcting for the it swelling the r~lattice a molecule in molecule the latticein and , P, are r~, P, symbols). The error made the neglecting the respectively symbols). The error made neglecting reduced density, pressure respectively the reduced the density, pressure swelling effect on sorptionwith increases with and temperature. swelling effect on sorption increases These are reduced by the and temperature. These are reduced by the 5 4 3 Silica gel 0.3 0.2 0.1 2 Figure 1. Figure 1. Visualization ofVisualization the swellingof behavior of thebehavior PDLLAsample 358Cand different pressures. (a) nopressures. CO2 (b) 50(a)bar the swelling of theatPD at 358Cand different no CO2 (b) 50 bar LLAsample (c) 100 bar (d) (c) 150100 bar.bar (d) 150 bar. 0 0 1 50 100 150 200 250 Pressure, P [bar] www.ms-journal.de www.ms-journal.de Copyright ß 2007 WILEY-VC Verlag GYmbH Co. KG Copyright ß H 2007 WILE -VCH&Verlag GaA, mbHWeinheim & Co. KGaA, Weinheim 0 0 5 10 15 3 Bulk density, r [mmol/cm ] 20 • Applications: - Ads. Separation processes - ECBM recovery • Publications: Pini et al., Adsorption 2006, 12, 393 Pini et al., Adsorption 2008, 14, 133 Pini et al., IJGGC 2010, 4, 90 Phase Equilibrium PETROLEUM ENGINEERING Flow Processes Vision For a better understanding of complex hydrogeological flows in the subsurface… natural gas recovery Geothermal energy Nuclear waste disposal coal, shales, tight-rocks, ... Ad-/Absorbed phase surfactants steam, nuclides tracers,… Solid phase sandstones, carbonates, … oil recovery Fluid phase EOR Multiphase system Composition Ads. isotherm CO2 sequestration CH4,CO2, brine NAPL polymers,… Groundwater remediation …my approach integrates experimental observations with model predictions. PETROLEUM ENGINEERING Research project - Adsorption controls on fluid transport and storage • Our understanding of the adsorbed phase is still limited! • The quantification of adsorption at high-pressure is a technical challenge. • There is an increasing number of applications of adsorption at high-pressures. CO2 sequestration, (enhanced) coal-bed methane recovery, shale gas development, CH4 storage, H2 storage… • Experiments and Simulations – Static and dynamic, broad range of conditions (HPHT) – Hysteretic behavior – Development of an appropriate theoretical framework PETROLEUM ENGINEERING [mmol/g] Fluid behavior in confined systems (micro-/nanopores)? Flow in the presence of an adsorbed phase? Appropriate measures of adsorption? Behavior of complex microporous systems (shales and coals)? ex – – – – Excess adsorption, n • Foundamental questions: 8 Activated Carbon 7 Zeolites 6 5 4 3 Silica gel 2 1 0 0 CO2, 50C 5 10 15 3 Bulk density, r [mmol/cm ] Pini R. unpublished work 2013 20 Research project - Multiphase flow properties for reservoir rocks • Pc(S) and kr(S) functions are key to describe mulitphase flow in porous systems • Literature reports a distinct behavior for scCO2/Brine system: – Apparent end-point rel. perm to CO2 is low (< 0.2) – Significant IFT effects Pini et al. WRR 2013, 49(6) Is there a substantial difference between scCO2/brine and any other gas-liquid fluid pair? PETROLEUM ENGINEERING Relative Permeability • Novel exp. techniques developed and refined! • Berea sandstone: all systems have similar wetting behavior! • True end-point is reached! • Need to be proven with different (more complex) rocks. • Need to be proven for both drainage and imbibition. 1 0.8 gN2/water gCO2/water scCO2/brine 0.6 0.4 IFT 0.2 65 mN/m 57 mN/m 45 mN/m 0 0 0.5 Water Saturation 1 Research project - Capillary heterogeneities in sandstones • Reservoir rocks are heterogeneous – Pc(S) function is “non-unique” • In the subsurface: 5 cm – Larger accumulation of fluids than residual trapping alone – Trapping by capillary-barriers • Direct measurement of capillary pressure curves at various spatial scales Multiphase and rock properties are evaluated within a unique and consistent framework Core-Flooding experiment: Fluid saturations PETROLEUM ENGINEERING Scaling factors Permeability Validity and applicability: - fluid pairs - rocks Research project - Moving across scales Synchrotron imaging Medical CT scanner imaging 6 mm plugs, 1.8 um resolution 2 1 5 cm core, 2 mm resolution 1 1 6 0.8 0.6 0.4 2 6 mm plugs 4 4 5 5 3 0.2 0 Phase saturation map showing peculiar spots… …independent estimation of permeability, porosity and capillary pressure curves. • Relation between multiphase and rock properties • Build the critical link across different scales • Understand and predict the behavior of more complex systems PETROLEUM ENGINEERING Manika Prasad O-CLASSH Colorado School of Mines PETROLEUM ENGINEERING 125 Resume • Education – PhD, Geophysics, Kiel University, Germany – MS (Diplom), Geology, Kiel University, Germany – BS, Geology, University of Bombay, India • Employment – – – – Indian Institute of Geomagnetism and Indian Institute of Technology, Bombay University of Hawai’i Stanford University Colorado School of Mines • Director OCLASSH (Petrophysics of Organics, Clay, Sand, Shale) • Co-Director of Center for Rock-Abuse PETROLEUM ENGINEERING 126 Teaching at CSM GRADUATE • PEGN 519 Advanced Well Logging • PEGN 598Z Rock Mechanics • PEGN/GPGN 598W Environmental Impacts • GEGN/PEGN 598B Carbonate Reservoirs • PEGN 598B Introduction to Rock Physics • PEGN 598C Rock Physics Seminar UNDERGRADUATE • PEGN/GPGN 419 Well Logging • PEGN 315 Field Session I • PEGN 316 Field Session II • PEGN 438 Geostatistics PETROLEUM ENGINEERING 127 Research Focus and Projects Research Focus Rock physics of Clays, Shales, carbonates, and other reservoir sediments Acoustic Imaging of rocks and other materials Nanoscale determination of elastic and electrical properties Research Projects Industry Consortium: OCLASSH: Rockphysics and Petrophysics of Organic-Rich Rocks Industry Consortium: Geophysical Properties of Fluids, Phase IV: Fluids in Rocks PETROLEUM ENGINEERING 128 OCLASSH Main Research Topics • • • • • • • • • • Anisotropy of Elastic and Anelastic properties Formation resistivity factor of nano-darcy porous rocks Effective stress coefficient, anisotropy, natural fracture and stress systems Pore size distribution (NMR, MICP, Gas adsorption) Adsorption, desorption, wettability elastic, anelastic, electrical properties Pore system classification (macro, micro, nano, meso) and gas molecule size Effects of mineralogy and composition on elastic properties Reactions between free radicals on sediments; clay mineral intercalation Tortuosity of nano-darcy porous rocks; its relationship to formation factor Water saturation in low-porosity rock; effect on gas adsorption / desorption Cross-fertilization with other academic groups gives new impetus and expands focus to clay mineralogy (University Poland) and chalks (TU Denmark) PETROLEUM ENGINEERING 129 Benefits 1. 2. 3. 4. Scientific Advisory Board Address “unanswered” questions Address non-routine and fundamental issues Nano to macro scale investigations of elastic, anelastic, electrical, flow, & textural properties 5. Yearly meetings and reports; data; papers; report moratorium possible PETROLEUM ENGINEERING Awards in 2012-2013 • Fall 2012: Prasad was SEG/AAPG Distinguished Lecturer on Shales and Imposters • Summer 2013: Saidian won Second place in the SPWLA Conference student paper contest PETROLEUM ENGINEERING Publications in 2012-2013 • • • • • Zargari,* S.; Mba*, K.; Mattson, E.; Prasad, M.; 2013, Organic Maturity, Elastic Properties and Textural Characteristics of Self Resourcing Reservoirs; Geophysics, 78, # 4, D223–D235, doi: 10.1190/GEO2012-0431.1. Revil, A., Eppenhimer J.D., Skold, M., Karaoulis, M. , Godinez, L., Prasad, M., 2013, Low-frequency Complex Conductivity of Sandy and Clayey Materials, In Press with Journal of Colloid and Interface Science. doi: dx.doi.org/10.1016/j.jcis.2013.01.015 Revil, A., Woodruff, W., Torres-Verdín, C., Prasad, M., 2013, Complex conductivity tensor of hydrocarbon-bearing shales; Geophysics, 78, # 4, D223–D235, doi: 10.1190/GEO2012-0431.1. Kuila*, U., Prasad, M., 2013, Surface area and pore-size distribution in clays and shales; Geophysical Prospecting, 61, 341–362. Sharma*,R., Prasad, M., Batzle, M.L., Vega, S., 2013, Sensitivity of Flow and Elastic Properties to Fabric Heterogeneity in Carbonates; Geophysical Prospecting, 61, 270–286. PETROLEUM ENGINEERING Presentations in 2012-2013 • • • • • • Kuila*, U., Prasad, M., Kazemi, H., 2013, Assessing Knudsen flow in gas-flow models of shale reservoirs: in print CSEG Recorder. Wempe, W., Prasad, M., 2012, Bounding electrical-elastic data: Example application in calcareous claystone: SEG Technical Program Expanded Abstracts 2012: 1-5. Kuila*, U., Prasad, M., Derkowski, A., McCarty, D.K., 2012, Compositional Controls on Mudrock Pore-Size Distribution: An Example from Niobrara Formation: SPE Annual Technical Conference and Exhibition, 8-10 October 2012, San Antonio, Texas, USA Wu*, W. Saidian, M., Gaur, S., Prasad, M., 2012, Errors and Repeatability in VSARA Analysis of Heavy Oils: SPE Heavy Oil Conference Canada, 12-14 June 2012, Calgary, Alberta, Canada Castillo*, P., Prasad, M., Ou*, L., 2012, Petrophysical Description of Tight Gas Sands: 2012 SEG Annual Meeting in Las Vegas Kuila*, U., Prasad, M., Kazemi, H., 2012, Importance of Knudsen flow for gas transport in shales: 2012 Biennial Society for Petroleum Geophysicists in Hyderabad, India PETROLEUM ENGINEERING 133 Prasad: Modulus–Porosity–Kerogen Content Density - Porosity plus modified kerogen content correlate better: accounts for kerogen density. Reduce scatter in porosity – elastic modulus relation by accounting for pore-filling kerogen 3 40 BAKKEN NIOBRARA All Others 2.5 C66 (MPa) RHOB (g/cc) 30 2 1.5 1 BAKKEN NIOBRARA All Others 0.5 0 0.0 0.1 0.2 0.3 0.4 Porosity-modified Kerogen Content 20 y = 30.436e-4.94x R² = 0.881 10 BAZHENOV WOODFORD 0.5 BAZHENOV WOODFORD 0 0.0 0.1 0.2 0.3 Porosity + Kerogen Content 0.4 KC_Φ = Φ + 0.4 KC PETROLEUM ENGINEERING 0.5 134 Mba: Predict TR from E 0.200.2 TR TR = 0.0083*Young’s Modulus - 0.0793 0.18 Transformation Ratio, dec Transformation Ratio 0.16 0.16 Mba (2010): The nanoindentation modulus of “softer components” (kerogen and clay) increases with transformation ratio (TR). 0.14 0.12 0.12 0.1 0.08 0.08 0.06 RR²2==0.8246 0.8 0.04 0.04 0.02 00 0 PETROLEUM ENGINEERING 0 5 10 15 20 25 35 10 3030 20 4040 Median Young's Modulus, GPa Kerogen + Kerogen+Clay Clay Median Young’s Modulus, GPa 45 50 50 Zargari: Modulus of Compliant Parts of Shales Kerogen+Clays+ Minerals TOC Kerogen+Clays+ Bitumen+Minerals Zargari et al., 2013 Modulus of Softer Portion PETROLEUM 4/9/2014 ENGINEERING 135 Zargari: Maturity and Textural Alterations Bitumen globule with clay Feeder channels PETROLEUM ENGINEERING • Micro-fractures form with hydrocarbon generation. • Bitumen-filled fractures transport bitumen to surface. • Flow of bitumen mobilizes fines and clay particles Zargari et al., 2013 Kuila: PSD: Various Shales PETROLEUM ENGINEERING 137 Kuila, 2013 Godinez: Water Front Dielectric Scans Dry Sample 4.5mm Thick, 1” Diameter 0 PETROLEUM ENGINEERING Brine Saturated Brine/Air Saturated (24hrs) Godinez, 2013 Wilkinson: Elastic Modulus of Kerogen b) Gradient Image d) Storage Modulus (GPa) a) SEM Image 1 µm c) Topographic Image 1 µm 2 µm 1 µm Materials in Scan Reported Young’s Modulus Values from Modulus Mapping Quarz 129.5 GPa 88 ± 31 GPa 8 - 13 GPa 11 ± 3 GPa PETROLEUM Kerogen ENGINEERING Wilkinson, 2013 Saidian: NMR and Clay Characterization Slurry PETROLEUM ENGINEERING Saidian, 2013 140 Theme 1/Milad 141 Current Capabilities at CSM SEISMIC & ELECTRICAL PROPERTIES a) b) c) d) Multi-frequency acoustic and electrical property measurements under pressure Multi-frequency acoustic measurements (max. 150,000 psi, 1000 °C) Resistivity measurements under pressure Uniaxial load frames FLOW PROPERTIES a) b) c) d) e) 2-MHz NMR (soon with pressure capabilities) Nano-Darcy permeability measurements Conntional poro-perm measurements Centrifuge to measure capillary pressures Mercury injection porosimeter NANO- & MICRO-SCALE MEASUREMENTS a) Scanning acoustic microscope up to 250 MHz (up to 10 µm resolution) b) Micro-CT scanner (up to 10 µm resolution) c) SEM; ESEM; FE-SEM, Nano-indentation system (Material Science) QUANTITATIVE ANALYSES (including those with other departments) a) QEMSCAN, SEM, XRD, Rock-Eval, and optical microscopy, (Geology) b) Open Column Liquid Chromatography (Petroleum Engineering) c) NMR, FTIR, GCMS; MBMS (Chemistry and Chemical Engineering) PETROLEUM ENGINEERING 142 Equipment Wish List Under Construction or ordered • Pressure tests under SAM and micro-CT • Geo-centrifuge cell to measure compaction dependent properties (collaboration with INL) • Atomic Force Microscope to measure nano-scale acoustic and electrical properties under stress and heat Needed Equipment • Dedicated electrical resistivity system (routine measurements) • Poly-axial test system (currently under numerical stress tests) • Tensiometer • Chemisorption • GHz-frequency Acoustic Microscope PETROLEUM ENGINEERING Integrated Real Time Reservoir Characterization Conventional and Unconventional Research Outlook Fall 2013 Prof. Dr. Azra N. Tutuncu PETROLEUM ENGINEERING Resume • Education – PhD, Petroleum Engineering, University of Texas – MS, Petroleum Engineering, University of Texas – MS, Geophysics, Stanford University – BS, Geophysical Engineering, Istanbul Technical University • Employment – Academia : University of Texas and Stanford University as Research Faculty – Oil Industry: Technical and Leadership Assignments Shell Exploration and Production, Shell International EP, Shell Unconventional Resources – Academia: Colorado School of Mines • Director of Unconventional Gas Institute (UNGI) • Harry D. Campbell Chair, Professor of Petroleum Engineering PETROLEUM ENGINEERING Additional Professional Information • • • • • • • • • • • • • • EPA Scientific Board Member on Hydraulic Fracturing Research Former President of American Rock Mechanics Association (ARMA) Faculty Advisor, CSM ARMA Student Chapter CSM Graduate Council Member and Graduate Admission Committee Member Author of more than 100 Shell proprietary reports Author/co-author of over 100 journal and conference proceedings Holds five U.S. patents and three international patents on exploration, drilling and stimulation techniques and associated best practices AGI Environmental Geoscience Advisory Committee Member SEG, SPE, ARMA Editorial Review Committee Member SEG Research Committee Member Licensed Professional Engineer in the State of Texas Licensed Professional Geoscientist in the State of Texas 25 Year Club Member SEG, 25 Year Club Member SPE, Life Member ARMA Members of Pi Epsilon Tau and Sigma Xi PETROLEUM ENGINEERING Teaching at CSM • PEGN 590 Reservoir Geomechanics (Fall 2011, Fall 2012, Fall 2013) • PEGN 593 Advanced Well Integrity (Fall 2011, Fall 2012, Fall 2013) • PEGN 498 Reservoir Geomechanics (Fall 2011) • PEGN 490 Reservoir Geomechanics (Fall 2012, Fall 2013) • PEGN 498 Introduction to Geomechanics (Spring 2011) • PEGN 598 Geomechanics for Unconventional Reservoirs (Spring 2011, 2012, 2013) • PEGN 592 Shale Reservoir Engineering (Spring 2011, Spring 2012, Spring 2013) • PEGN 598 Introduction to Geomechanics (Fall 2010, Spring 2011) • PEGN 315 –Field Session I (Summer 2011, Summer 2012) • Super School (Summer 2012, Summer 2013) • UNGI TOPCORP Training (Summer 2013) PETROLEUM ENGINEERING Research Focus • Coupled Geomechanics and Rock Physics Modeling and Measurements – – – • Static, dynamic, petrophysical and transport characteristics of shale reservoirs and seal shales, tight gas sands, turbidite and fractured carbonates at in situ stress, elevated pore pressure and temperature measurements, case studies using field data and uncertainty analysis CO2 sequestration impact on geomechanical and flow characteristics of formations and seal integrity risk assessment Monitoring the lifecycle geomechanical and flow properties of unconventional resources, deepwater formations, HPHT and geothermal reservoirs and their seal integrity for environmentally friendly, economically viable production from challenging reservoirs Integrated Real Time Reservoir Characterization – Deformation, well Integrity, formation evaluation and monitoring in Inclined and horizontal wells, compaction, subsidence, sanding PETROLEUM ENGINEERING 3rd Generation Coupled-Geomechanics-Flow Characteristics UNGI Geomechanics Laboratory PETROLEUM ENGINEERING UNGI Stress Path Dependent Rock Properties and Fracture Effect Terzaghi’s Law eff = v - Ppore Mokhtari and Tutuncu (2013) Mese and Tutuncu (2000) 12000 CL=3.916E-6 psi-1 Stress (psi) 9000 6000 3000 Axial Strain Radial Strain 0 -4.E-03 0.E+00 4.E-03 8.E-03 1.E-02 Strain CL=1.393E-6 psi-1 10000 6.E-03 8980 psi PHyd 5.E-03 PPore Peff Strain 5000 3.E-03 2500 2.E-03 Effective Stress = 300 psi 0 0 500 1000 1500 Time (Min) PETROLEUM ENGINEERING 2000 0.E+00 2500 Strain Stress (psi) 7500 Integrated Reservoir Characterization Rock Properties and Strength PETROLEUM ENGINEERING Wellbore Stability/Wellpath OptimizationUNGI (with Mogi-Coulomb vs. Mohr-Coulomb Failure Criteria) Kadyrov and Tutuncu, 2012, ARMA 12-445 Compressive Failure Mogi-Coulomb PETROLEUM ENGINEERING MW (gr/cc) Compressive Failure Mohr-Coulomb MW (gr/cc) Effect of Eccentricity on Herschel-Bulkley Fluids Mokhtari and Tutuncu, 2012, ARMA 12-235 PETROLEUM ENGINEERING Creep Recovery Measurements and Modeling for Rheological Characterization of Drilling and Fracturing Fluids Fracture Fluid Proppant Carrying Capacity and Barite Settling URTeC 1571583 – Bui and Tutuncu (2013) PETROLEUM ENGINEERING Mechanical, Transport Property and Strength Measurements and Modeling Mokhtari et al. (2013) 18000 Pc=3390 psi, E=2.01 Mpsi Deviatoric Stress (psi) 16000 EF-1-1V 14000 12000 EF-1-1V Pc=2260 psi, EF-1-1V --> E=1.30 10000 EF-1-2V 8000 6000 4000 Pc=1130 psi, EF-1-1V --> E=0.7 2000 EF-1-2V 0 0 0.02 0.04 Axial Strain PETROLEUM ENGINEERING 0.06 Reservoir Characterization and Upscaling Coupled Core Measurements and Reservoir Modeling under In Situ Stress, Elevated PP and Temperature • Reservoir Scale: Seismic, Sonic, Density Resistivity, Imaging log, NMR data and analysis • Core Scale: Direction dependent acoustic and mechanical properties, strength, porosity, permeability measurements under realistic in situ stress conditions using elevated pore pressure and elevated temperature, fractured (natural and induced) reservoir characterization, fluid-rock interaction effect on mechanical, acoustic, flow characteristics and strength • MicroScale: CT-Scan, AFM, SEM, NMR, Surface Area, XRD, gas adsorption and dielectric coefficient measurements for micro-scale characterization PETROLEUM ENGINEERING Coupled Geomechanics and Fluid Flow Experiments and Modeling Projects • UNGI Geomechanics laboratory equipped with directional deformation, acoustic and permeability measurements and custom designed elastomers enabling seismic 0-200 Hz, 100 KHz and 1 MHz ultrasonic frequency measurements using single core plug at in situ stress and elevated pore pressure and temperature conditions • Simultaneous measurements of acoustic, mechanical, permeability and strength anisotropy under elevated pore pressure conditions using fracturing and drilling fluids • Unconventional shale database for building up correlations between static and dynamic moduli at true in situ stress, elevated pore pressure state and enhanced models incorporating coupled fluid flow and geomechanics PETROLEUM ENGINEERING Use of Shale-Fluid Interaction for Maximizing SRV and Optimum Fluid Design 4500 Confining Pressure 4000 3500 Circulating Pressure Pp = 3140psi 3000 PRESSURE (psi) Pore Pressure 2500 dPp = 1604psi 2000 1500 Circulation of 8% w/w NaCl solution 1000 Pp = 1536 psi Circulation of Sodium Silicate Fluid with 20%w/w Nacl Saturation with 8% w/w NaCl solution 500 0 0 2000 4000 6000 8000 Mese (2000) 10000 12000 14000 16000 Time (min) • • • • PETROLEUM ENGINEERING Uncertainty in SRV estimation Evidences in support of microseismic Fluid Composition effect on fracturing Discrete Fracture Network Modeling with integrated field and lab data Mechanical Property Change at Various Effective Stresses – CO2 Injection and Production Effect Guan and Tutuncu, 2012 – ARMA 12-234 Pe=10MPa PETROLEUM ENGINEERING Pe=6MPa Cement Sheath Integrity Modeling Bui and Tutuncu, 2013, ARMA 13-341 PETROLEUM ENGINEERING Operation Safety and Environment (SAGD Crater, Total-Canada) PETROLEUM ENGINEERING Anchor-handling tugboats battle the blazing remnants of the off shore oil rig Deepwater Horizon (US Coast Guard, photo 100421-G-XXXXL- Deepwater Horizon fire) http://ungi.mines.edu UNGI The Unconventional Natural Gas and Oil Institute (UNGI) UNGI Dr. Azra N. Tutuncu, P.E., P.G. Director of UNGI Harry D. Campbell Chair in Petroleum Engineering PETROLEUM ENGINEERING UNGI Faculty & Staff UNGI (50+ Faculty) • • • • • • • • • • • • • • • • • • • • • • • • Brian Asbury Jennifer Aschoff Linda Battalora Michael Batzle Jerry Boak Mary Carr Tzahi Cath John Curtis Kadri Dagdelen Tom Davis Rod Eggert Alfred W. Eustes William Fleckenstein Ramona Graves Marte Gutierrez Todd Hoffman John Humphrey Tissa Illangasekare Hossein Kazemi Carolyn Koh Ning Lu John McCray Carrie McClelland Mark Miller PETROLEUM ENGINEERING Joe Chen, Al Sami, Denise Winn-Bower, Daisuke Katsuki • • • • • • • • • • • • • • • • • • • • • • Jennifer Miskimins Mike Mooney Dag Nummedal Erdal Ozkan Piret Plink-Bjorklund John Poate David Pyles Andre Revil Rick Sarg Paul Sava Dendy Sloan Kathleen Smits Steve Sonnenberg Amadeu Sum Azra Nur Tutuncu Ilya Tsvankin Craig van Kirk Yu-Shu Wu David Wu Yuan Yang Xiaolong Yin Terry Young UNGI Research Consortia Strategy Coupled and Integrated Multiscale Measurements and Modeling (CIMMM) UNGI • Multidisciplinary integrated collaborative effort between CSM UNGI, major and independent oil companies, global service companies, DOE Laboratories, NETL Strategic Shale Center, other federal and state government organizations and academic institutions for fundamental shale research • Conduct integrated R&D projects using consortia sponsor data to enhance our fundamental understanding of nano to reservoir scale dependent shale reservoir characterization, drilling, hydraulic fracturing and production related alterations • Establishing an IN SITU SHALE LABORATORY, a mid-size pilot site containing underground facilities to Collect multidiscipline operation data Monitor in situ stress from exploration to field abandonment Study environmental impact of operations on land, surface, groundwater, air Calibrate the multiscale integrated models prior to delivery to the industry and government sponsors PETROLEUM ENGINEERING CSM UNGI Gas Leaders Training Effort for Domestic and International Regulators UNGI • The Department of State UGTEP award to accelerate international engagements and learning of technical and regulatory effort • GE and ExxonMobil foundation awards $1 million each to provide regulators and policymakers access to the latest technological and operational expertise in assisting their oversight of shale development. This is a CSM-UNGI effort in partnership with Penn State University and The University of Texas at Austin with the first training has been offered at CSM in August 20-24, 2013 (TOPCORP Pilot). PETROLEUM ENGINEERING UNGI Consortia Strategy Coupled and Integrated Multiscale Measurements and Modeling 25,000 psi 10,000 psi 10,000 psi Pore Pressure ~ 10,000 psi UNGI (2012) • Numerical multiscale model for gas flow in unconventional, low-permeability reservoirs incorporating Klinkenberg effect, non-Darcy flow, and adsorption terms and coupling these functions with geomechanical models for integrated model PETROLEUM ENGINEERING True triaxial measurements using single core to measure vertical and azimuthal Vp, Vs (ultrasonic, 100 KHz and seismic), perm anisotropy, resistivity and deformation simultaneously at elevated pore pressure and temperature Vaca Muerta PETROLEUM ENGINEERING UNGI CONSORTIA Eagle Ford (CIMMM) UNGI CIMMM Project Subcategories UNGI • Subgroup A - Coupled Nano/Micro and Core Scale Measurements and Modeling • Subgroup B -Solutions for Drilling Challenges in Low Permeability Unconventional Reservoirs • Subgroup C - Nano to Reservoir Scale Fluid Flow Measurements and Modeling in Gas and Oil Shale Reservoir • Subgroup D - Stimulation Experiments and Modeling in Gas Shale Reservoirs • Subgroup E - Hydrates as Unconventional Gas Reservoirs: Coupled Experimental and Modeling • Subgroup F – Environmental Challenges and Regulatory and Safety Aspects PETROLEUM ENGINEERING Stress-Dependent Permeability UNGI Katsuki et al., 2013, URTeC 1619487 PETROLEUM ENGINEERING UNGI High Field NMR Measurements and Modeling 200 smectite - T1 180 2.5 Kaolinite1 -T1 Alzahrani et al., 2013 160 2 140 120 1.5 T2, ms T1, ms 100 80 1 60 40 0.9 Clay Swelling 0.8 0.5 0.7 0 0.6 0 -0.5 0.5 1.5 2.5 3.5 S/V, 1/nm 20 0.5 Ionic Concentration, Molarity 500 45 450 40 400 35 350 0.4 Calculated Total S/V vs. Porosity Relaxation S/V DI water 0.3 Relaxation S/V 8% KCL 30 300 25 T2, ms T1, ms 250 20 200 15 150 10 100 50 5 Shale-T1 0 0 -0.5 0.5 1.5 2.5 Ionic Concentration, Molarity PETROLEUM ENGINEERING 3.5 0.2 0.72 0.74 0.76 0.78 0.8 Calculated Porosity, ratio 0.82 Vaca Muerta Anisotropic Geomechanical Properties Core and Log Data Coupling and Upscaling LOG(Static Elastic Coefficient) Willis et al., 2013 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 R² = 0.9191 0.0 0.5 1.0 LOG(Dynamic Elastic Coefficient * Density) PETROLEUM ENGINEERING 1.5 Multiscale Measurements and Modeling Stress Anisotropy from Seismic and Logs CORE SCALE RESERVOIR SCALE NANO SCALE PETROLEUM ENGINEERING Wendy Wempe • Education – BS, UC Santa Cruz, Earth Science, 1994 – Ph.D., Stanford University, Geophysics, 2000 • Employment – CU Boulder, Cooperative Institute for Research in Environmental Sciences (CIRES), Research Associate – Schlumberger Water Services, Petrophysicist – Colorado School of Mines, Research Assistant Professor PETROLEUM ENGINEERING Wempe’s Research Foci Developing practical mathematical conceptual/heuristic models to explain phenomena related to: 1. Modeling the electrical and elastic responses to changes in bound fluid content, wetted states, and relative permeability 2. Electrical-elastic rock physics modeling and petrophysical evaluation PETROLEUM ENGINEERING Wempe, CSM 173 Wempe et al. 2013 Research Projects 1. Electrical - Elastic modeling in tight gas sands and the influence of pore shape (including micro-fractures) on measurement. 2. Resistivity - velocity petrophysical charting 3. NMR T2 wettability index estimation, using conventional USBM and Amott WI as ground truth in tight oil sand. 4. NMR T2 pyrite correction model 5. Pore scale characterization (micro-XCT & QEMSCAN) and applications to rock physics modeling and transport properties PETROLEUM ENGINEERING Wempe, CSM 174 Wempe Research Projects Since 2000 PETROLEUM ENGINEERING Domain I Domain II New Upper Resistivity Bound Domain III Total Porosity(V:V) New Resistivity – Sonic Petrophysical Charting Formation Factor, (unitless) Free Fluid (V:V) (Bourbie and Zinszner, 1985) Formation Factor • Bound fluid – free fluid model development • Empirical resistivity upper bound development • Effects of fluids, mineral surfaces and bacterium on wetting hysteresis • Resistivity – sonic petrophysical charting technique development • Electrical – elastic pore shape theoretical modeling New free fluid – bound fluid model Total Porosity, Ø New Porosity Domain Theory Wempe and Mavko (2001) Ø = Øie Ø = Øe Ø = Øe + Øie Domain I Isolated Pores Domain II Connected Grains & Pores 0Øp 100% mineral PETROLEUM ENGINEERING Domain III Suspended Grains 1 Øc Total Porosity 100% fluid 176 Free Fluid tolune (V:V) New Free Fluid – Total Porosity Model Wempe (2000) FFwetting A(f f p ) m Domain I Domain II 0 0.2 0.4 Domain III 0.6 0.8 fc A (f c f p ) m 1 Total Porosity, Ø (V:V) Data: Bourbie and Zinszner, 1985 PETROLEUM ENGINEERING Wempe, CSM 177 Changes in Wetting Hysteresis Due to Microbial Activity Wempe et al (2003) Wilhelmy plate results: Clean Glass Plate Diesel Aged Glass Plate 80 Water Broth Diesel Bacterium Contact Angle, q 40 0 80 40 0 PETROLEUM ENGINEERING 0 2 4 6 0 Dipping Depth (mm) 2 4 6 New Empirical Resistivity Upper Bound Wempe (2000) Formation Factor, R/Rw R Total Porosity, Ø PETROLEUM ENGINEERING Total Porosity, Ø Resistivity – Velocity Bounds and Reservoir Characterization Wempe (2000) PETROLEUM ENGINEERING New Resistivity – Velocity Petrophysical Charting Technique Wempe (2000) F - Vp Bounds R/Rw - f Bounds R1-max/Rw R1-min /Rw R1-max/Rw f1ex-min f1ex Vp - f Bounds R1-min /Rw Vp1-max/Vw Vp1-min /Vw Vp1-max/Vw Example Porosity, f1ex Minimum Porosity, f1ex-min Maximum Porosity, f1ex-max PETROLEUM ENGINEERING Vp1-min /Vw f1ex f1ex-max 181 Dual Pore Shape Modeling in Tight Sandstones: Theoretical electrical and elastic modeling approach Ou & Wempe (in progress) Modeling disk-shaped micro-cracks closing with increased effective stress (Ou, 2013) Formation Factor P-wave Velocity (km/s) (Ou, 2013) Total Porosity, Ø PETROLEUM ENGINEERING Total Porosity, Ø Tight Sand Pore & Mineral Characterization and Associations Wempe (in progress) Tight Sand μCT Image Tight Sand QEMSCAN Mineral Map High-density pyrite ~5 μm ~5 μm Low-density pore Pore PETROLEUM ENGINEERING Quantitative approaches and studies of flow and transport in reservoirs An introduction of research projects – Fall 2013 Yu-Shu Wu, PhD PETROLEUM ENGINEERING Resume • Education – – – – PhD, Reservoir Engineering, U. of California at Berkeley, 1990 MS, Reservoir Engineering, U. of California at Berkeley, 1988 MS, Petroleum Engineering, Southwest Petroleum U., 1981 BS (Eqv.), Petroleum Engineering, Northeast Petroleum U., 1976 • Employment – Petroleum Engineer, Research Inst. of Petroleum Exploration and Development Beijing, China, 1982-1985 – Hydrogeologist, HydroGeoLogic, Inc., Herndon, VA,1990-1995 – Staff geological scientist, Lawrence Berkeley National Laboratory, Berkeley, CA, 1995-2008 – Professor, Petroleum Engineering, Colorado School of Mines (2008-current) PETROLEUM ENGINEERING Teaching • • • • PEGN 424: Reservoir Engineering II (Spring) PEGN 414: Well Test Analysis and Design (Fall, 2009; 2010; 2011) PEGN 315: Field Session I (Summer, 2009 and 2010) PEGN 598A: Introduction of Geothermal Science and Engineering (Spring, 2010) • PEGN 608: Multiphase Flow in Porous Media (Fall, 2009) • PEGN 515: Reservoir Engineering Principles (Fall) PETROLEUM ENGINEERING Research focus • Reservoir dynamics and simulation • Coupled processes of multiphase flow, chemical transport, and heat transfer in EOR operations • Fractured and unconventional reservoirs • CO2 EOR, storage and utilization • Enhanced geothermal systems (EGS) • Unconventional reservoir simulation • Simulation of hydraulic fracturing PETROLEUM ENGINEERING EMG Research group • The Energy Modeling Group (EMG) is a research organization in the PE Dept. consisting of faculty, graduate students, visiting scholars, and post doctoral fellows. • EMG's mission is to develop state-of-the-art reservoir modeling technology and advanced simulation tools for research, teaching, and field applications in the areas of subsurface energy and natural resources, and environmental science and engineering. PETROLEUM ENGINEERING Research project #1 • Title: “Simulation of Coupled Processes of Flow, Transport and Storage of CO2 in Saline Aquifers, ” the research project funded by US DOE and sponsored by CMG, Oct. 2009-Sept. 2014 • Research Team – CSM: Yu-Shu Wu, Hossein Kazemi, Xiaolong Yin, Jeffery Chen, and Phil Winterfeld – Lawrence Berkeley National Laboratory: Karsten Pruess/Curt Oldenburg PETROLEUM ENGINEERING Research project #2 • Title: “Development of Advanced Thermal-HydrologicalMechanical-Chemical (THMC) Modeling Capabilities for Enhanced Geothermal Systems (EGS),” the research project funded by DOE and sponsored by CMG, Jan. 2010-Dec. 2013 • Research Team – CSM: Yu-Shu Wu and Hossein Kazemi – Lawrence Berkeley National Laboratory (LBNL): Tianfu Xu and Keni Zhang PETROLEUM ENGINEERING Research project #3 • Title: ““Development of Non-Contaminating Cryogenic Fracturing Technology for Shale and Tight Gas Reservoirs,” funded by DOE’s RPSEA program, August 2012-August 2015 • Research Team – CSM: Yu-Shu Wu, Jennifer L. Miskimins and Xiaolong Yin; Timothy J. Kneafsey (Lawrence Berkeley National Laboratory); and Bryant Morris and Shannon Osterhout, Pioneer Natural Resources PETROLEUM ENGINEERING Research project #4 • Title: “Water Handling and Enhanced Productivity from Gas Shales,” funded by DOE’s RPSEA program, 2013- 2015 • Research Team – CSM: Yu-Shu Wu – USC: Kristian Jessen et al. PETROLEUM ENGINEERING Research project #5 • Title: “Development of a Tight Sand Gas Reservoir Simulator for Optimizing Single Horizontal Well Hydraulic Fracturing Design and Production,” funded by CNPC-USA, 2013- 2015 • Research Team – CSM: Yu-Shu Wu, Phil Winterfeld, and Xiaolong Yin PETROLEUM ENGINEERING Current projects and students • EGS modeling – Yi Xiong (PhD) • Modeling of CO2 sequestration – Shihao Wang (MS) • Unconventional reservoir simulation – Cong Wang (PhD) – Long Cai (MS) • Cryogenic fracturing – Bowen Yao (MS) PETROLEUM ENGINEERING Research/thesis topics • Unconventional reservoir simulation • Next generation reservoir simulation technology-Integrated modeling approaches • Coupled processes in multiphase flow, rock deformation/geomechanics, chemical reaction, and heat transfer for EOR • Flow and phase behavior in CO2-EOR • Hybrid modeling approach for fractured reservoirs • Simulation of rock fracturing PETROLEUM ENGINEERING Fluid Dynamics, Porous Media, and Suspensions A Summary of Research Projects Fall 2013 Xiaolong Yin PETROLEUM ENGINEERING Resume • Education – PhD, Chemical Engineering, Cornell University, 2006 – MS, Mechanical Engineering, Lehigh University, 2001 – BS, Theoretical and Applied Mechanics, Peking University, 1999 • Experience – Assistant Professor, Petroleum Engineering, Colorado School of Mines (2009-current) – Postdoc, Chemical Engineering, Princeton University, 2006-2008 • Activities – Members: SPE, AGU, APS, AIChE – Associated Editor – SPE Journal (2012-current) PETROLEUM ENGINEERING Teaching and Research • Classes taught – – – – PEGN 310 Reservoir Fluid Properties PEGN 315 Summer Field Session PEGN 511 Advanced Phase Behavior PEGN 601 Applied Mathematics • Research interests – – – – Porous media flow and transport Particle- and bubble-laden multiphase flows Lattice Boltzmann method Enhanced oil recovery and reservoir fluid phase behavior PETROLEUM ENGINEERING Current Projects / Students • Instability in gas-solid flows in fluidization and risers, National Science Foundation, CBET, 2012-2015, PI. • Slip flow of gases through nanopores and Klinkenberg effect, American Chemical Society Petroleum Research Fund, DNI, 2012-2014, PI. • Hydraulic fracturing fluid invasion and flowback in tight gas sand and shale, RPSEA Unconventional, 2011-2014, PI with Neeves (Co-PI). • Cryogenic fracturing for unconventionals, RPSEA Unconventional, 20122014, Co-PI with Wu (PI) and Miskimins (Co-PI). • Modeling of combined phase equilibrium and geochemical reactions for CO2 sequestration in saline aquifers, DOE NETL, 2009-2013, Co-PI with Wu (PI), Kazemi (Co-PI), and Chen (Co-PI). • Collaborative Projects with UNGI, MCERS, UREP, EMG • 4 PhD (1 co-advise), 4 MS (1 co-advise) PETROLEUM ENGINEERING Process and Objectives of Pore-Scale Simulation Pore geometry from measurement or stochastic construction Pore-scale direct numerical & physical simulations Single-phase flow: - Non-Darcy flow - Slip flow - Transport Multiphase flow: Geometry constructed directly from micro- or nano-scale imaging -Capillary pressure -Trapping -Relative permeability “Particulate” systems: Stochastically constructed geometries PETROLEUM ENGINEERING -Microemulsions -Nanoparticles -Macromolecules Process and Objectives of Pore-Scale Simulation Pore geometry from measurement or stochastic construction Pore-scale direct numerical & physical simulations Single-phase flow: - Non-Darcy flow - Slip flow - Transport Numerical Simulation • Lattice Boltzmann for single- and multiphase flows in the continuum regime • Direct Simulation Monte Carlo (DSMC) for flows with non-continuum effects Multiphase flow: Physical Simulation • Micro- and nanofluidic porous media analogs -Microemulsions -Nanoparticles -Macromolecules PETROLEUM ENGINEERING -Capillary pressure -Trapping -Relative permeability “Particulate” systems: Research Topics – Non-Darcy Flow • 2D/3D high-speed non-Darcy flows – Direct numerical simulations show that Darcy’s law begins to fail as Rek ~ O(0.1) – Forchheimer’s law becomes valid at Rek ~ O(1) Single-phase flow: - Non-Darcy flow - Slip flow - Transport Multiphase flow: -Capillary pressure -Trapping -Relative permeability “Particulate” systems: Re k U k Permeability reduction with increasing Re PETROLEUM ENGINEERING -Microemulsions -Nanoparticles -Macromolecules Newman and Yin, SPE J, 2013, 18:12-26. Research Topics – Slip Flow • Direct simulation of slip flow in nanopores – Slip is a non-continuum flow effect that increases the permeability of gas in nano pores – Microscopic slip gives rise to Klinkenberg effect Single-phase flow: - Non-Darcy flow - Slip flow - Transport Multiphase flow: -Capillary pressure -Trapping -Relative permeability “Particulate” systems: Us 2 Wall slip PETROLEUM ENGINEERING U n averaging b k app k 1 P Klinkenberg law -Microemulsions -Nanoparticles -Macromolecules Research Topics – Multiphase Flow in Porous Media • Simulation of water and surfactant flooding in microfluidic physical porous media models Stitiched photos of water (top) and surfactant (bottom) flooding at breakthrough. The model porosity is 20% and permeability is 150md. Capillary number = 10-5 (water flooding) and 10-4 (surfactant flooding) PDMS Microfluidic Porous Media Micromodel Single-phase flow: - Non-Darcy flow - Slip flow - Transport Multiphase flow: -Capillary pressure -Trapping -Relative permeability “Particulate” systems: -Microemulsions -Nanoparticles -Macromolecules Xu, Ok, Xiao, Yin, Neeves. Submitted to Phys. Fluids, 2013. PETROLEUM ENGINEERING Research Topics – Pore-Scale Transport • Simulation of dispersion of solute or nanoparticles in porous media Single-phase flow: - Non-Darcy flow - Slip flow - Transport Multiphase flow: -Capillary pressure -Trapping -Relative permeability UP Flow field in a porous medium made up by 40-m spherical beads. BOTTOM Two Brownian tracer species are advected by the flow and mix in the porous medium. RIGHT After the tracers leave the porous medium, the mixing level is assessed based on the concentration profiles. PETROLEUM ENGINEERING “Particulate” systems: -Microemulsions -Nanoparticles -Macromolecules Research Topics – Suspension Dynamics • Instability in particle lifting using gas/liquid Yin, Zenk, Mitrano, Hrenya, J. Fluid Mech. 2013, R2, 727 PETROLEUM ENGINEERING • Taylor dispersion of heat / mass in sheared particle suspensions Metzger, Yin, Ouamar, J. Fluid Mech. 2013, 724:527-552 Peer-Reviewed Publications (2012-2013) • Wu QH, Ok JT, Sun YP, Retterer ST, Neeves KB, Yin XL, Bai BJ, Ma YF, Optic imaging of single and two-phase pressure-driven flows in nanoscale channels, Lab Chip 13:1165-1171, 2013. • Newman MS, Yin XL, Lattice Boltzmann simulation of non-Darcy flow in stochastically generated 2D porous media geometries, SPE J. 18:12-26, 2013. • Metzger B, Yin XL, Ouamar R, Heat transfer across sheared suspensions: Role of the shear-induced diffusion, J. Fluid Mech. 724:527-552, 2013. • Yin XL, Zenk J, Mitrano PP, Hrenya CM, Impact of collisional vs. viscous dissipation on flow instabilities in gas-solid systems, J. Fluid Mech. 727, R2, 2013. • Wu MJ, Xiao F, Johnson-Paben, RM, Retterer ST, Yin XL, Neeves KB, Single- and two-phase flow in microfluidic porous media analogs based on Voronoi tessellation, Lab Chip 12:253-261, 2012. PETROLEUM ENGINEERING Conference Papers (2012-2013) • • • • • • • Petunin VV, Labra C, Xiao F, Tutuncu AN, Sun J, Yin XL, Porosity and permeability change under stress and correlation to rock texture, 5th Biot Conference on Poromechanics, 2013. Mokhtari M, Alqahtani AA, Tutuncu AN, Yin XL, Stress-dependent permeability anisotropy and wettability of shale resources, URTeC 1555068, 2013. Wu QH, Bai BJ, Ma YF, Ok JT, Neeves KB, Yin XL, Optic imaging of two-phase flow behavior in nano-scale fractures, SPE 164549, 2013. Teklu TW, Alharthy N, Kazemi H, Yin XL, Graves RM, Minimum miscibility pressure in conventional and unconventional reservoirs, URTeC 1589572, 2013. Teklu TW, Ghedan S, Graves RM, Yin XL, Minimum miscibility pressure determination: modified multiple mixing cell method, SPE 155454, SPE EOR OGWA, 2012. Zhang RL, Yin XL, Wu YS, Winterfeld PH, A fully coupled model of nonisothermal multiphase flow, solute transport, and reactive chemistry in porous media, SPE 159380, SPE ATCE, 2012. Zhang RL, Yin XL, Winterfeld PH, Wu YS, A fully coupled model of nonisothermal multiphase flow, geomechanics, and chemistry during CO2 sequestration in brine aquifers, TOUGH Symposium, 2012. PETROLEUM ENGINEERING Dr. Luis E. Zerpa • Assistant Professor, Petroleum Engineering Department, Colorado School of Mines • Previous to CSM, Assistant Professor at the University of Zulia, Venezuela • Consulting experience in reservoir simulation studies of an industrial offshore chemical EOR pilot project; Venezuelan National Oil Company (PDVSA) • B.S. (2001) and M.S. (2004) in Mechanical Engineering from the University of Zulia • Ph.D. in Petroleum Engineering from the Colorado School of Mines (2013) PETROLEUM ENGINEERING Teaching and Research CSM Courses: • PEGN 423 Petroleum Reservoir Engineering I Research Areas: • Reservoir simulation and characterization Courses taught in the past (U. of Zulia): • Numerical Analysis • Surrogate Models and Optimal Design of Complex Systems • Optimization for Engineers • Data Mining for Oil Industry • Exploration and Production Fundamentals • Integrated Optimization of Oil Production Systems • Reservoir Simulation and Applications PETROLEUM ENGINEERING • Enhanced oil recovery • Flow assurance and multiphase flow • Gas hydrates in nature as potential energy resource Current Research Projects • Integration of microseismic data and reservoir modeling for waterflood monitoring – Funded by Saudi Aramco, in collaboration with Dr. Hossein Kazemi (MCERS-CSM) and Dr. Thomas Davis (RCP-CSM) • Modeling gas hydrate formation in oil and gas flowlines – In collaboration with Dr. Carolyn Koh, Dr. Amadeu Sum and Dr. Dendy Sloan, Directors of the Center for Hydrate Research at CSM PETROLEUM ENGINEERING Seismic-Driven Reservoir Simulation and Monitoring of Waterflood Processes in Carbonate Reservoirs Project objectives: Funded by, • Develop a reservoir fluid flow and geomechanics model to quantify stress changes that promote microseismic events Shear stress • Use microseismic data to improve reservoir characterization Increase pressure Decrease temperature Effective normal stress, Stress change during water injection PETROLEUM ENGINEERING Principal Investigators: Dr. Hossein Kazemi Dr. Thomas Davis Dr. Luis Zerpa A Model for Gas Hydrate Formation in Oil and Gas Flowlines (CSMHyK) Water Entrainment Hydrate Growth Agglomeration Plugging Intrinsic kinetics or transport resistances Particle aggregation via capillary attraction Plugging from viscosity increase Gas Oil Water Surface area between water/hydrocarbon phases Empirical correlation PETROLEUM ENGINEERING dmgas dt uKB As T (Pressure drop increase) Model Allows Estimation of Hydrate Plugging Risk Fluid distribution Low hydrate plugging risk High hydrate plugging risk • Liquid loading = 90 vol. % • Water cut = 30 % • GOR = 570 scf/STB • Liquid loading = 79 vol. % • Water cut = 32 % • GOR = 894 scf/STB Zerpa, L.E., Sloan, E.D., Koh, C.A. and Sum, A.K., 2012. SPE 160578-PA, Oil and Gas Facilities, 1(5): 49-56. PETROLEUM ENGINEERING Quantifying Hydrate Plugging Risk in Oil Systems (PhD Student: P. Chaudhari) Risk Quantifying Parameter • Proposed model for hydrate plugging risk Risk Quantifying Parameter = Low Risk PETROLEUM ENGINEERING = f (mixture velocity, liquid loading, emulsification properties, water cut, hydrate amount, pipeline diameter, fluid properties) f (Inertia, Collision) f (Agglomeration, Accumulation, Bedding, Adhesion, Drag) Medium Risk High Risk/Plugging CSMHyK Application on Field Case Study (PhD Student: P. Chaudhari) • BP field case study • Can CSMHyK help to understand the system response upon shut-in/restart? Day 2 – Day 8 Water ingress Oil & Gas Water Hydrate Water Ingress PETROLEUM ENGINEERING Future Research Plans Global flow assurance perspective • Formation of solid deposits (hydrate, wax, asphaltene, and mineral scale) • Main goal: develop predictive tools for design and optimization of flow assurance techniques PETROLEUM ENGINEERING Future research plans Production from unconventional energy resources • • • Gas hydrate bearing sediments Application of surface chemistry concepts Gas production from hydrate bearing formations Production from gas shale Conventional Small volumes easy to develop Heavy Oil Extra-Heavy Oil Unconventional KG Basin, India (2008) Conventional Reservoirs Large volumes difficult to develop Increased break-even price required Tight Gas Basin-centered Gas Increased technology requirements Coal Bed Methane Bitumen Shale Gas Oil Shale Gas Hydrates Oil PETROLEUM ENGINEERING Gas Gas Shale Acknowledgements • Supporting Staff – – – – – Ms. Denise Winn-Bower Ms. Patricia Hassen Ms. Theresa Snyder Mr. Al Sami Mr. Joe Chen • Mr. Tim Marquez (1980) and donors to the new Petroleum Engineering Building - Marquez Hall PETROLEUM ENGINEERING