Material Safety Data Sheet - Mohawk Wood Finishing Products
Transcription
Material Safety Data Sheet - Mohawk Wood Finishing Products
Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 11/28/2012 Product Name: Product Code: ULTRA® CLASSIC TONER NATURAL PINE M100-0002, M105-3164 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER NATURAL PINE Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex water benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER NATURAL PINE Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER NATURAL PINE Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary water 7732-18-5 benzene 71-43-2 EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER NATURAL PINE Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER NATURAL PINE Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 663.16 Coating VOC lbs/gal: 5.52 Material VOC g/l: 497.4 Material VOC lbs/gal: 4.14 Solids VOL%: 5.2 Solids WT %: 8.76 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER NATURAL PINE Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 11/28/2012 IM100-0002_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER NATURAL PINE Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. EINECS * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 5000 LBS ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS DSL Proposition 65 TSCA SARA 313 EPCRA TPQ * acetone * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary water 7732-18-5 * * * benzene 71-43-2 * * * * 1000 LBS * 10 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER NATURAL PINE Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:11/28/2012 File: IM100-0002_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) 04/25/2013 EHS Review/Issue Date: Hickory, NC 28603 Product Name: Product Code: ULTRA™ CLASSIC TONER MAISON BROWN M100-0004 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Odor: Strong Solvent Principal Hazards: DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. May be harmful if absorbed through the skin. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 04/25/2013 IM100-0004_MSDS_ENGUSA_009.pdf File: Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC TONER MAISON BROWN Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate ethylbenzene benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 100-41-4 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC TONER MAISON BROWN Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC TONER MAISON BROWN Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 ethylbenzene 100-41-4 benzene 71-43-2 435 MGM3 (100 PPM) EHS Review/Issue Date: 04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf 100 PPM 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC TONER MAISON BROWN Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Flash Point ( F): Not determined. -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf Page 5 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC TONER MAISON BROWN Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.34 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.33 Material VOC lbs/gal: 4.13 Solids VOL%: 5.41 Solids WT %: 9.14 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC TONER MAISON BROWN Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 ethylbenzene 100-41-4 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 04/25/2013 IM100-0004_MSDS_ENGUSA_009.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC TONER MAISON BROWN Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * ethylbenzene 100-41-4 * 1000 LBS * * * * * * benzene 71-43-2 * 10 LBS * * * * * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 04/25/2013 File: IM100-0004_MSDS_ENGUSA_009.pdf Page 8 of 9 * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC TONER MAISON BROWN Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:04/25/2013 IM100-0004_MSDS_ENGUSA_009.pdf File: Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA CLASSIC AEROSOL AMBER M100-0007 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL AMBER Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene organic-chrome complex wax solids water solvent red 130 benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 71839-77-5 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL AMBER Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL AMBER Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary wax solids proprietary water 7732-18-5 solvent red 130 71839-77-5 benzene 71-43-2 EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf 0.5 MGM3 0.5 MGM3 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL AMBER Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL AMBER Specific Gravity: 0.77 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 663.6 Coating VOC lbs/gal: 5.53 Material VOC g/l: 496.47 Material VOC lbs/gal: 4.13 Solids VOL%: 5.28 Solids WT %: 8.87 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL AMBER Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 organic-chrome complex proprietary wax solids proprietary water 7732-18-5 solvent red 130 71839-77-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0007_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL AMBER Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * organic-chrome complex proprietary wax solids proprietary water 7732-18-5 * * * solvent red 130 71839-77-5 * * * * * benzene 71-43-2 * * * * * * * * 1000 LBS 10 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * * * * Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL AMBER Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0007_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA CLASSIC MED BROWN WALNUT 1404952, M100-0207 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC MED BROWN WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex solvent red 130 water chromium complex benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 71839-77-5 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC MED BROWN WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC MED BROWN WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary solvent red 130 71839-77-5 water 7732-18-5 chromium complex proprietary benzene 71-43-2 EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf 0.5 MGM3 0.5 MGM3 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC MED BROWN WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC MED BROWN WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.92 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.76 Material VOC lbs/gal: 4.14 Solids VOL%: 5.22 Solids WT %: 8.82 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC MED BROWN WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary solvent red 130 71839-77-5 water 7732-18-5 chromium complex proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0207_MSDS_ENGUSA_015.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC MED BROWN WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * * wax solids proprietary organic-chrome complex proprietary solvent red 130 71839-77-5 * * * * * water 7732-18-5 * * * chromium complex proprietary benzene 71-43-2 * * * * * * 1000 LBS * * 10 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 8 of 9 * * * * * * Material Safety Data Sheet Product Name: ULTRA CLASSIC MED BROWN WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0207_MSDS_ENGUSA_015.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 11/28/2012 Product Name: Product Code: ULTRA™ CLASSIC EXTRA DARK WALNUT ACPC, M100-0209 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC EXTRA DARK WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids chromium complex water chromium complex organic cobalt complex chromium complex CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 proprietary proprietary proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC EXTRA DARK WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC EXTRA DARK WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary chromium complex proprietary water 7732-18-5 chromium complex proprietary organic cobalt complex proprietary chromium complex proprietary EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC EXTRA DARK WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC EXTRA DARK WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 662.48 Coating VOC lbs/gal: 5.52 Material VOC g/l: 497.04 Material VOC lbs/gal: 4.14 Solids VOL%: 5.27 Solids WT %: 8.89 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC EXTRA DARK WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary chromium complex proprietary water 7732-18-5 chromium complex proprietary organic cobalt complex proprietary chromium complex proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 11/28/2012 IM100-0209_MSDS_ENGUSA_018.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC EXTRA DARK WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary chromium complex proprietary water 7732-18-5 * * * chromium complex proprietary organic cobalt complex proprietary chromium complex proprietary * 1000 LBS WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC EXTRA DARK WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:11/28/2012 File: IM100-0209_MSDS_ENGUSA_018.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA CLASSIC AEROSOL DARK GOLDEN OAK M100-0220 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex water solvent orange 99 benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary water 7732-18-5 solvent orange 99 proprietary benzene 71-43-2 EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.1 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.61 Material VOC lbs/gal: 4.14 Solids VOL%: 5.21 Solids WT %: 8.79 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 solvent orange 99 proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0220_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary water 7732-18-5 * * * solvent orange 99 proprietary benzene 71-43-2 * * * * 1000 LBS * 10 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA CLASSIC AEROSOL DARK GOLDEN OAK Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0220_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA™ CLASSIC DK RED MAHOGANY M100-0227 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DK RED MAHOGANY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene cromate (1-) bis 2-(3-chlorophenyl) wax solids chromate (1-) bis methyl water solvent red 125 benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 51147-75-2 proprietary 71839-85-5 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DK RED MAHOGANY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DK RED MAHOGANY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary benzene 71-43-2 EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DK RED MAHOGANY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DK RED MAHOGANY Specific Gravity: 0.77 Weight per Gallon (lbs): Solubility (water): 6.4 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 668.01 Coating VOC lbs/gal: 5.56 Material VOC g/l: 500.29 Material VOC lbs/gal: 4.17 Solids VOL%: 5.28 Solids WT %: 8.86 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DK RED MAHOGANY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0227_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DK RED MAHOGANY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * wax solids proprietary chromate (1-) bis methyl 71839-85-5 * * * water 7732-18-5 * * * solvent red 125 proprietary benzene 71-43-2 * * * * * * 1000 LBS * 10 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DK RED MAHOGANY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0227_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 11/28/2012 Product Name: Product Code: ULTRA™ CLASSIC BROWN MAHOGANY M100-0229, M105-3168 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN MAHOGANY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids solvent brown 44 organic-chrome complex water solvent red 125 benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN MAHOGANY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN MAHOGANY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 solvent red 125 proprietary benzene 71-43-2 EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN MAHOGANY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN MAHOGANY Specific Gravity: 0.77 Weight per Gallon (lbs): Solubility (water): 6.38 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 663.8 Coating VOC lbs/gal: 5.53 Material VOC g/l: 497.02 Material VOC lbs/gal: 4.14 Solids VOL%: 5.28 Solids WT %: 8.88 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN MAHOGANY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 solvent red 125 proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 11/28/2012 IM100-0229_MSDS_ENGUSA_015.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN MAHOGANY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 * * * solvent red 125 proprietary benzene 71-43-2 * * * * 1000 LBS * 10 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN MAHOGANY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:11/28/2012 File: IM100-0229_MSDS_ENGUSA_015.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC PERFECT BROWN 1404949, M100-0249 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC PERFECT BROWN Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids water organic cobalt complex organic cobalt complex chromium complex benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary 7732-18-5 proprietary proprietary proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC PERFECT BROWN Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC PERFECT BROWN Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary water 7732-18-5 organic cobalt complex proprietary organic cobalt complex proprietary chromium complex proprietary benzene 71-43-2 EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC PERFECT BROWN Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC PERFECT BROWN Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.34 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.5 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.78 Material VOC lbs/gal: 4.14 Solids VOL%: 5.18 Solids WT %: 8.76 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC PERFECT BROWN Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary water 7732-18-5 organic cobalt complex proprietary organic cobalt complex proprietary chromium complex proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0249_MSDS_ENGUSA_019.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC PERFECT BROWN Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary water 7732-18-5 * * * organic cobalt complex proprietary organic cobalt complex proprietary chromium complex proprietary benzene 71-43-2 * * * * 1000 LBS * 10 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC PERFECT BROWN Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0249_MSDS_ENGUSA_019.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC MODERN MAHOGANY M100-0273 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC MODERN MAHOGANY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids solvent red 125 water chromium 2+ or 3+ compounds benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 117527-94-3 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC MODERN MAHOGANY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC MODERN MAHOGANY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary solvent red 125 proprietary water 7732-18-5 chromium 2+ or 3+ compounds 117527-94-3 benzene 71-43-2 EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC MODERN MAHOGANY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC MODERN MAHOGANY Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.67 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.93 Material VOC lbs/gal: 4.14 Solids VOL%: 5.19 Solids WT %: 8.8 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC MODERN MAHOGANY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary solvent red 125 proprietary water 7732-18-5 chromium 2+ or 3+ compounds 117527-94-3 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-0273_MSDS_ENGUSA_011.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC MODERN MAHOGANY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary solvent red 125 proprietary water 7732-18-5 * * * chromium 2+ or 3+ compounds 117527-94-3 * * benzene 71-43-2 * * * * * 1000 LBS * 10 LBS * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC MODERN MAHOGANY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-0273_MSDS_ENGUSA_011.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA™ CLASSIC LT OAK/NATURAL M100-0321, M105-3166 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT OAK/NATURAL Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex water benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT OAK/NATURAL Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT OAK/NATURAL Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary water 7732-18-5 benzene 71-43-2 EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT OAK/NATURAL Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT OAK/NATURAL Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.55 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.67 Material VOC lbs/gal: 4.14 Solids VOL%: 5.2 Solids WT %: 8.77 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT OAK/NATURAL Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0321_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT OAK/NATURAL Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. EINECS * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 5000 LBS WHMIS DSL Proposition 65 TSCA SARA 313 EPCRA TPQ * acetone * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary water 7732-18-5 * * * benzene 71-43-2 * * * * * * 1000 LBS * 10 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT OAK/NATURAL Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0321_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC LT PECAN M100-0322 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT PECAN Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene organic-chrome complex wax solids water benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT PECAN Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 3 of 9 Product Name: ULTRA™ CLASSIC LT PECAN Material Safety Data Sheet Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary wax solids proprietary water 7732-18-5 benzene 71-43-2 EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT PECAN Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT PECAN Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 662.66 Coating VOC lbs/gal: 5.52 Material VOC g/l: 496.62 Material VOC lbs/gal: 4.14 Solids VOL%: 5.25 Solids WT %: 8.83 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT PECAN Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 organic-chrome complex proprietary wax solids proprietary water 7732-18-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-0322_MSDS_ENGUSA_011.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT PECAN Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. EINECS * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 5000 LBS WHMIS DSL Proposition 65 TSCA SARA 313 EPCRA TPQ * acetone * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * organic-chrome complex proprietary wax solids proprietary water 7732-18-5 * * * benzene 71-43-2 * * * * * * 1000 LBS * 10 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 8 of 9 * * * * * * * Product Name: ULTRA™ CLASSIC LT PECAN Material Safety Data Sheet Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-0322_MSDS_ENGUSA_011.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC DARK WALNUT/OAK M100-0351 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT/OAK Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene organic-chrome complex solvent brown 44 wax solids chromium 2+ or 3+ compounds water benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 117527-94-3 7732-18-5 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT/OAK Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT/OAK Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary solvent brown 44 proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 benzene 71-43-2 EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT/OAK Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT/OAK Specific Gravity: 0.77 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.86 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.18 Material VOC lbs/gal: 4.13 Solids VOL%: 5.32 Solids WT %: 9 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT/OAK Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 organic-chrome complex proprietary solvent brown 44 proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0351_MSDS_ENGUSA_013.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT/OAK Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * organic-chrome complex proprietary solvent brown 44 proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 * * water 7732-18-5 benzene 71-43-2 * 1000 LBS * 10 LBS * * * * * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT/OAK Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0351_MSDS_ENGUSA_013.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE M100-0352 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene organic-chrome complex wax solids chromium 2+ or 3+ compounds water organic cobalt complex benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 117527-94-3 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 organic cobalt complex proprietary benzene 71-43-2 EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.26 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.67 Material VOC lbs/gal: 4.14 Solids VOL%: 5.23 Solids WT %: 8.85 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 organic-chrome complex proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 organic cobalt complex proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0352_MSDS_ENGUSA_006.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * organic-chrome complex proprietary wax solids proprietary chromium 2+ or 3+ compounds 117527-94-3 * * water 7732-18-5 * * * organic cobalt complex proprietary benzene 71-43-2 * * * * * * 1000 LBS * 10 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT WALNUT/COLONIAL MAPLE Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0352_MSDS_ENGUSA_006.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC VAN DYKE WALNUT M100-0353 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC VAN DYKE WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex chromium complex water chromium complex chromium complex CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 7732-18-5 proprietary proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC VAN DYKE WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC VAN DYKE WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary chromium complex proprietary water 7732-18-5 chromium complex proprietary chromium complex proprietary EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC VAN DYKE WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC VAN DYKE WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 662.51 Coating VOC lbs/gal: 5.52 Material VOC g/l: 496.52 Material VOC lbs/gal: 4.13 Solids VOL%: 5.27 Solids WT %: 8.87 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC VAN DYKE WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary chromium complex proprietary water 7732-18-5 chromium complex proprietary chromium complex proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-0353_MSDS_ENGUSA_012.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC VAN DYKE WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary chromium complex proprietary water 7732-18-5 * * * chromium complex proprietary chromium complex proprietary * * * 1000 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC VAN DYKE WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-0353_MSDS_ENGUSA_012.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC BROWN FRUITWOOD M100-0354 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN FRUITWOOD Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone isobutyl acetate propane ethyl acetate n-butyl acetate ethanol toluene isobutane cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene organic-chrome complex wax solids solvent red 125 chromium 2+ or 3+ compounds water benzene CAS 67-64-1 110-19-0 74-98-6 141-78-6 123-86-4 64-17-5 108-88-3 75-28-5 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 117527-94-3 7732-18-5 71-43-2 Percent Composition 20 - 30 10 - 20 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN FRUITWOOD Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN FRUITWOOD Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) 500 PPM isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM propane 74-98-6 1800 MGM3 (1000 PPM) ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM ethanol 64-17-5 1900 MGM3 (1000 PPM) toluene 108-88-3 isobutane 75-28-5 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 1000 PPM 200 PPM 20 PPM 1000 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary wax solids proprietary solvent red 125 proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 benzene 71-43-2 EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN FRUITWOOD Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN FRUITWOOD Specific Gravity: 0.79 Weight per Gallon (lbs): Solubility (water): 6.61 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 685.9 Coating VOC lbs/gal: 5.71 Material VOC g/l: 492.82 Material VOC lbs/gal: 4.1 Solids VOL%: 5.96 Solids WT %: 9.69 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN FRUITWOOD Section 11: Toxicology Information CAS Chemical acetone 67-64-1 isobutyl acetate 110-19-0 propane 74-98-6 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 ethanol 64-17-5 toluene 108-88-3 isobutane 75-28-5 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 organic-chrome complex proprietary wax solids proprietary solvent red 125 proprietary chromium 2+ or 3+ compounds 117527-94-3 water 7732-18-5 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0354_MSDS_ENGUSA_012.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC BROWN FRUITWOOD Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. EINECS acetone 67-64-1 * 5000 LBS * * * * isobutyl acetate 110-19-0 * 5000 LBS * * * * propane 74-98-6 * * * ethyl acetate 141-78-6 * 5000 LBS * * * * n-butyl acetate 123-86-4 * 5000 LBS * * * * ethanol 64-17-5 * 100 LBS * * * * * toluene 108-88-3 * 1000 LBS * * * * * isobutane 75-28-5 * * * cellulose nitrate, cellulose ester 9004-70-0 * * * * * Chemical Name CAS * * 100 LBS WHMIS DSL Proposition 65 TSCA SARA 313 EPCRA TPQ EPCRA EHS CERCLA CERCLA RQ Section 15: Regulatory Information alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * organic-chrome complex proprietary wax solids proprietary solvent red 125 proprietary chromium 2+ or 3+ compounds 117527-94-3 * * water 7732-18-5 benzene 71-43-2 * 1000 LBS * 10 LBS * * * * * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 8 of 9 * * * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC BROWN FRUITWOOD Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0354_MSDS_ENGUSA_012.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN M100-0355 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene cromate (1-) bis 2-(3-chlorophenyl) wax solids organic-chrome complex water chromium complex chromate (1-) bis methyl CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 51147-75-2 proprietary proprietary 7732-18-5 proprietary 71839-85-5 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 chromium complex proprietary chromate (1-) bis methyl 71839-85-5 EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.8 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.45 Material VOC lbs/gal: 4.13 Solids VOL%: 5.27 Solids WT %: 8.93 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 chromium complex proprietary chromate (1-) bis methyl 71839-85-5 IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-0355_MSDS_ENGUSA_018.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * wax solids proprietary organic-chrome complex proprietary water 7732-18-5 * * * chromium complex proprietary chromate (1-) bis methyl 71839-85-5 * * * * * * 1000 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC OAK/PINE-MEDIUM/TAVERN Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-0355_MSDS_ENGUSA_018.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC RED MAHOGANY/CHERRY 1404947, M100-0381 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC RED MAHOGANY/CHERRY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids solvent brown 44 organic-chrome complex water solvent red 125 chromium complex CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 7732-18-5 proprietary proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC RED MAHOGANY/CHERRY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC RED MAHOGANY/CHERRY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 solvent red 125 proprietary chromium complex proprietary EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC RED MAHOGANY/CHERRY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC RED MAHOGANY/CHERRY Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 662.45 Coating VOC lbs/gal: 5.52 Material VOC g/l: 496.49 Material VOC lbs/gal: 4.13 Solids VOL%: 5.27 Solids WT %: 8.89 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC RED MAHOGANY/CHERRY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 solvent red 125 proprietary chromium complex proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0381_MSDS_ENGUSA_013.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC RED MAHOGANY/CHERRY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary solvent brown 44 proprietary organic-chrome complex proprietary water 7732-18-5 * * * solvent red 125 proprietary chromium complex proprietary * 1000 LBS WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC RED MAHOGANY/CHERRY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0381_MSDS_ENGUSA_013.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC NATURAL CHERRY M100-0382 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC NATURAL CHERRY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene cromate (1-) bis 2-(3-chlorophenyl) p-xylene organic-chrome complex wax solids chromate (1-) bis methyl water solvent red 125 CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 51147-75-2 106-42-3 proprietary proprietary 71839-85-5 7732-18-5 proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC NATURAL CHERRY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Aspiration hazard. If vomiting occurs position head to prevent aspiration of liquid into lungs. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC NATURAL CHERRY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM organic-chrome complex proprietary wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC NATURAL CHERRY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC NATURAL CHERRY Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.41 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.34 Material VOC lbs/gal: 4.13 Solids VOL%: 5.3 Solids WT %: 9 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC NATURAL CHERRY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 p-xylene 106-42-3 organic-chrome complex proprietary wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-0382_MSDS_ENGUSA_009.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC NATURAL CHERRY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * p-xylene 106-42-3 * * * organic-chrome complex proprietary wax solids proprietary chromate (1-) bis methyl 71839-85-5 * * * water 7732-18-5 * * * solvent red 125 proprietary * * * 1000 LBS * 100 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC NATURAL CHERRY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-0382_MSDS_ENGUSA_009.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC DARK RED WALNUT M100-0383 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK RED WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene cromate (1-) bis 2-(3-chlorophenyl) wax solids water chromate (1-) bis methyl chromium complex chromium complex CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 51147-75-2 proprietary 7732-18-5 71839-85-5 proprietary proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK RED WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK RED WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary water 7732-18-5 chromate (1-) bis methyl 71839-85-5 chromium complex proprietary chromium complex proprietary EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK RED WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK RED WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.94 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.41 Material VOC lbs/gal: 4.13 Solids VOL%: 5.25 Solids WT %: 8.87 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK RED WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 wax solids proprietary water 7732-18-5 chromate (1-) bis methyl 71839-85-5 chromium complex proprietary chromium complex proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-0383_MSDS_ENGUSA_012.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK RED WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * wax solids proprietary water 7732-18-5 * * * chromate (1-) bis methyl 71839-85-5 * * * chromium complex proprietary chromium complex proprietary * * * 1000 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK RED WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-0383_MSDS_ENGUSA_012.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC DEEP RED MAHOGANY M100-0384 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DEEP RED MAHOGANY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene cromate (1-) bis 2-(3-chlorophenyl) p-xylene chromium 2+ or 3+ compounds wax solids chromate (1-) bis methyl water solvent red 125 CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 51147-75-2 106-42-3 117527-94-3 proprietary 71839-85-5 7732-18-5 proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DEEP RED MAHOGANY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Aspiration hazard. If vomiting occurs position head to prevent aspiration of liquid into lungs. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DEEP RED MAHOGANY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM chromium 2+ or 3+ compounds 117527-94-3 wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DEEP RED MAHOGANY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DEEP RED MAHOGANY Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 660.27 Coating VOC lbs/gal: 5.5 Material VOC g/l: 496.28 Material VOC lbs/gal: 4.13 Solids VOL%: 5.3 Solids WT %: 9.02 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DEEP RED MAHOGANY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 p-xylene 106-42-3 chromium 2+ or 3+ compounds 117527-94-3 wax solids proprietary chromate (1-) bis methyl 71839-85-5 water 7732-18-5 solvent red 125 proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0384_MSDS_ENGUSA_013.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DEEP RED MAHOGANY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * p-xylene 106-42-3 * * * chromium 2+ or 3+ compounds 117527-94-3 * * wax solids proprietary chromate (1-) bis methyl 71839-85-5 * * * water 7732-18-5 * * * solvent red 125 proprietary * 1000 LBS * 100 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DEEP RED MAHOGANY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0384_MSDS_ENGUSA_013.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) 08/15/2013 EHS Review/Issue Date: Hickory, NC 28603 Product Name: Product Code: ULTRA® CLASSIC TONER CHERRY M100-0408 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Odor: Strong Solvent Principal Hazards: DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. May be harmful if absorbed through the skin. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 08/15/2013 IM100-0408_MSDS_ENGUSA_016.pdf File: Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER CHERRY Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate ethanol isobutane toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate ethylbenzene benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 64-17-5 75-28-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 100-41-4 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER CHERRY Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipient fires. Water may be used to cool and prevent rupture of containers that are exposed to heat from fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER CHERRY Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM ethanol 64-17-5 1900 MGM3 (1000 PPM) 1000 PPM isobutane 75-28-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 ethylbenzene 100-41-4 benzene 71-43-2 435 MGM3 (100 PPM) EHS Review/Issue Date: 08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf 100 PPM 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER CHERRY Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Flash Point ( F): Not determined. -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf Page 5 of 9 Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER CHERRY Specific Gravity: 0.77 Weight per Gallon (lbs): Solubility (water): 6.38 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 663.09 Coating VOC lbs/gal: 5.52 Material VOC g/l: 495.68 Material VOC lbs/gal: 4.13 Solids VOL%: 5.38 Solids WT %: 9.06 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER CHERRY Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 ethanol 64-17-5 isobutane 75-28-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 ethylbenzene 100-41-4 benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 08/15/2013 IM100-0408_MSDS_ENGUSA_016.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA® CLASSIC TONER CHERRY Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. EINECS * * * * * * 5000 LBS * * * * 5000 LBS * * * * 5000 LBS * * * * * 100 LBS * * * * * * * * * * * * * * acetone 67-64-1 * propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * ethanol 64-17-5 5000 LBS isobutane 75-28-5 toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS DSL Proposition 65 TSCA SARA 313 EPCRA TPQ EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * * * * * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * ethylbenzene 100-41-4 * 1000 LBS * * * * * * benzene 71-43-2 * 10 LBS * * * * * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 08/15/2013 File: IM100-0408_MSDS_ENGUSA_016.pdf Page 8 of 9 * Material Safety Data Sheet Product Name: ULTRA® CLASSIC TONER CHERRY Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:08/15/2013 IM100-0408_MSDS_ENGUSA_016.pdf File: Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/01/2012 Product Name: Product Code: ULTRA™ CLASSIC LT GOLDEN OAK 1404951, M100-0415 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT GOLDEN OAK Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol pm acetate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic cobalt complex organic cobalt complex water organic-chrome complex cromate (1-) bis 2-(3-chlorophenyl) CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 108-65-6 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary proprietary 7732-18-5 proprietary 51147-75-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT GOLDEN OAK Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT GOLDEN OAK Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic cobalt complex proprietary organic cobalt complex proprietary water 7732-18-5 organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT GOLDEN OAK Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT GOLDEN OAK Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.36 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 662.75 Coating VOC lbs/gal: 5.52 Material VOC g/l: 496.67 Material VOC lbs/gal: 4.14 Solids VOL%: 5.23 Solids WT %: 8.85 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT GOLDEN OAK Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic cobalt complex proprietary organic cobalt complex proprietary water 7732-18-5 organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/01/2012 IM100-0415_MSDS_ENGUSA_012.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC LT GOLDEN OAK Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS * WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * alkyd resin proprietary NCP isopropanol 67-63-0 pm acetate 108-65-6 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * * * m-xylene 108-38-3 * * * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic cobalt complex proprietary organic cobalt complex proprietary water 7732-18-5 * * * organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * * 1000 LBS WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC LT GOLDEN OAK Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/01/2012 File: IM100-0415_MSDS_ENGUSA_012.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC YELLOW TONE UP M100-1488 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC YELLOW TONE UP Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene amorphous silica wax solids water organic-chrome complex benzene CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 112926-00-8 proprietary 7732-18-5 proprietary 71-43-2 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC YELLOW TONE UP Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC YELLOW TONE UP Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 20 PPM 200 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM amorphous silica 112926-00-8 wax solids proprietary water 7732-18-5 organic-chrome complex proprietary benzene 71-43-2 EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf * 10 PPM 29 CFR 1910.1028 0.5 PPM Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC YELLOW TONE UP Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC YELLOW TONE UP Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.37 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 663.03 Coating VOC lbs/gal: 5.52 Material VOC g/l: 496.76 Material VOC lbs/gal: 4.14 Solids VOL%: 5.21 Solids WT %: 8.84 Contains Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC YELLOW TONE UP Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 amorphous silica 112926-00-8 wax solids proprietary water 7732-18-5 organic-chrome complex proprietary benzene 71-43-2 IARC NTP * * * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-1488_MSDS_ENGUSA_009.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC YELLOW TONE UP Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * amorphous silica 112926-00-8 wax solids proprietary water 7732-18-5 organic-chrome complex proprietary benzene 71-43-2 * * * 1000 LBS * * * * * * * 10 LBS * * * * * * * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf * Page 8 of 9 * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC YELLOW TONE UP Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-1488_MSDS_ENGUSA_009.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 01/25/2012 Product Name: Product Code: ULTRA™ CLASSIC DARK WALNUT M100-7020, M105-3170 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex cromate (1-) bis 2-(3-chlorophenyl) water chromium 2+ or 3+ compounds chromate (1-) bis methyl CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 51147-75-2 7732-18-5 117527-94-3 71839-85-5 Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Aspiration hazard. If vomiting occurs position head to prevent aspiration of liquid into lungs. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 water 7732-18-5 chromium 2+ or 3+ compounds 117527-94-3 chromate (1-) bis methyl 71839-85-5 EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.3 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.71 Material VOC lbs/gal: 4.14 Solids VOL%: 5.23 Solids WT %: 8.83 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 water 7732-18-5 chromium 2+ or 3+ compounds 117527-94-3 chromate (1-) bis methyl 71839-85-5 IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 01/25/2012 IM100-7020_MSDS_ENGUSA_014.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC DARK WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * water 7732-18-5 * * * chromium 2+ or 3+ compounds 117527-94-3 * * chromate (1-) bis methyl 71839-85-5 * * * * * 1000 LBS * * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC DARK WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:01/25/2012 File: IM100-7020_MSDS_ENGUSA_014.pdf Page 9 of 9 Material Safety Data Sheet Section 1: Product and Company Identification RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266 P.O. Box 22000 CHEMTREC: (800) 424-9300 International: 703-527-3887 (collect) Hickory, NC 28603 EHS Review/Issue Date: 10/15/2011 Product Name: Product Code: ULTRA™ CLASSIC UNIVERSAL WALNUT M100-7021 Section 2: Hazards Identification EMERGENCY OVERVIEW Appearance: Colored Liquid Principal Hazards: Odor: Strong Solvent DANGER! Extremely Flammable. Causes eye, skin, nose and throat irritation. Harmful or fatal if swallowed. Harmful if inhaled. Vapor harmful. Potential Health Effects: See Section 11 for more information. Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption. Eye Contact: Product may cause eye damage; signs and symptoms may include burns, vision impairment, permanent corneal damage and/or soft tissue damage. Ingestion: Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions and/or bleeding. Post-ingestion vomitous in the lungs may cause chemical pneumonia. Skin Contact: Product may cause skin damage; signs and symptoms may include blistering, burns and/or possible scarring. Inhalation: Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness, swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation, ulceration, heart damage, blindness, bleeding and/or death. Serious risk of suffocation when in confined area. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 1 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC UNIVERSAL WALNUT Target Organs: Not Determined Carcinogenicity: This product contains carcinogens or potential carcinogens as listed by IARC or NTP. Hazardous Listing: Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition/Information on Ingredients Chemical acetone propane isobutyl acetate ethyl acetate n-butyl acetate isobutane ethanol toluene cellulose nitrate, cellulose ester alkyd resin isopropanol isobutyl isobutyrate 2,2,4-trimethyl-1,3-pentanediol diisobutyrate butyl cellosolve m-xylene castor oil o-xylene ethylbenzene p-xylene wax solids organic-chrome complex water chromium complex cromate (1-) bis 2-(3-chlorophenyl) chromium complex CAS 67-64-1 74-98-6 110-19-0 141-78-6 123-86-4 75-28-5 64-17-5 108-88-3 9004-70-0 proprietary NCP 67-63-0 97-85-8 6846-50-0 111-76-2 108-38-3 8001-79-4 95-47-6 100-41-4 106-42-3 proprietary proprietary 7732-18-5 proprietary 51147-75-2 proprietary Percent Composition 20 - 30 10 - 20 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 1 - 10 <1 <1 <1 <1 <1 <1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Section 4: First Aid Measures Eye Contact: If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention immediately after flushing. EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 2 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC UNIVERSAL WALNUT Ingestion: Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center immediately. Aspiration hazard. If vomiting occurs position head to prevent aspiration of liquid into lungs. Skin Contact: If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes. Seek medical attention immediately. Inhalation: Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is difficult, give oxygen. Seek medical attention immediately. Section 5: Fire Fighting Measures Extinguishing Media: Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire. Products of Combustion: Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases. Protection of Firefighters / Explosion Hazards: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Section 6: Accidental Release Measures Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways. EHS Review/Issue Date:10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 3 of 9 Material Safety Data Sheet Product Name: ULTRA™ CLASSIC UNIVERSAL WALNUT Section 7: Handling and Storage Handling: Contents under pressure. Do not puncture, incinerate, or discard in a compactor. Do not store above 120°F, or in direct sunlight. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Storage: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. Section 8: Exposure / Personal Protection Chemical CAS Z-1 PEL (units as noted) Z-2 PEL (PPM) Z-3 Status OSHA 29 CFR 1910.1000 Air Contaminants – Tables: Specifically Regulated see: ACGIH TLV (units as noted) acetone 67-64-1 2400 MGM3 (1000 PPM) propane 74-98-6 1800 MGM3 (1000 PPM) isobutyl acetate 110-19-0 700 MGM3 (150 PPM) 150 PPM ethyl acetate 141-78-6 1400 MGM3 (400 PPM) 400 PPM n-butyl acetate 123-86-4 710 MGM3 (150 PPM) 150 PPM isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 500 PPM 1000 PPM 1900 MGM3 (1000 PPM) 1000 PPM 200 PPM 20 PPM 980 MGM3 (400 PPM) 200 PPM 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 240 MGM3 (50 PPM) 20 PPM m-xylene 108-38-3 435 MGM3 (100 PPM) 100 PPM castor oil 8001-79-4 o-xylene 95-47-6 435 MGM3 (100 PPM) 100 PPM ethylbenzene 100-41-4 435 MGM3 (100 PPM) 100 PPM p-xylene 106-42-3 435 MGM3 (100 PPM) 100 PPM wax solids proprietary organic-chrome complex proprietary water 7732-18-5 chromium complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 chromium complex proprietary EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 4 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC UNIVERSAL WALNUT Engineering Controls: Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure limits. Eye / Face Protection: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. Skin Protection: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Respiratory Protection: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. General Hygiene Considerations: It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. Section 9: Physical and Chemical Properties Physical State: Colored Liquid Odor: Strong Solvent Odor Threshold: Not determined. pH: Not determined. Freezing Point: Not determined. Boiling Point: Not determined. Flash Point ( F): -144 (CALC.) Evaporation Rate: Not determined. Flammability (solid, gas): Not determined. Upper Flammability Limit: Not determined. Lower Flammability Limit: Not determined. Vapor Pressure: Not determined. Vapor Density: Not determined. o EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 5 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC UNIVERSAL WALNUT Specific Gravity: 0.76 Weight per Gallon (lbs): Solubility (water): 6.35 Not determined. Partition Coefficient (n-octanol/water): Not determined. Auto-ignition Temperature: Not determined. Coating VOC g/l: 661.76 Coating VOC lbs/gal: 5.51 Material VOC g/l: 496.87 Material VOC lbs/gal: 4.14 Solids VOL%: 5.2 Solids WT %: 8.81 Contains Non-Photochemically Reactive Solvent. VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations. Aerosol coating product category codes and applicable reactivity limits are displayed on product labels per 40 CFR 59.507. Section 10: Stability and Reactivity Stability: Stable under normal conditions. Conditions to Avoid/Incompatible Materials: Keep away from heat, sparks and flames. Hazardous Decomposition Products: Not determined. EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 6 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC UNIVERSAL WALNUT Section 11: Toxicology Information CAS Chemical acetone 67-64-1 propane 74-98-6 isobutyl acetate 110-19-0 ethyl acetate 141-78-6 n-butyl acetate 123-86-4 isobutane 75-28-5 ethanol 64-17-5 toluene 108-88-3 cellulose nitrate, cellulose ester 9004-70-0 alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 butyl cellosolve 111-76-2 m-xylene 108-38-3 castor oil 8001-79-4 o-xylene 95-47-6 ethylbenzene 100-41-4 p-xylene 106-42-3 wax solids proprietary organic-chrome complex proprietary water 7732-18-5 chromium complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 chromium complex proprietary IARC NTP * * Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known carcinogens are listed above. Section 12: Ecological Information Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. EHS Review/Issue Date: 10/15/2011 IM100-7021_MSDS_ENGUSA_008.pdf File: Page 7 of 9 Product Name: Material Safety Data Sheet ULTRA™ CLASSIC UNIVERSAL WALNUT Section 13: Disposal Considerations Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. Section 14: Transportation Information DOT Basic description: UN1950, AEROSOLS, FLAMMABLE, 2.1 See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations. * * * * * * 5000 LBS * * * * 5000 LBS * * * * * * * * * * * * * * * * * * * * * * * * * * acetone 67-64-1 5000 LBS propane 74-98-6 isobutyl acetate 110-19-0 * ethyl acetate 141-78-6 * n-butyl acetate 123-86-4 * 5000 LBS isobutane 75-28-5 WHMIS EINECS Proposition 65 DSL SARA 313 EPCRA TPQ TSCA * EPCRA EHS CAS CERCLA Chemical Name CERCLA RQ Section 15: Regulatory Information * ethanol 64-17-5 * 100 LBS toluene 108-88-3 * 1000 LBS cellulose nitrate, cellulose ester 9004-70-0 * 100 LBS alkyd resin proprietary NCP isopropanol 67-63-0 isobutyl isobutyrate 97-85-8 * * * 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 * * * butyl cellosolve 111-76-2 * * * * m-xylene 108-38-3 * * * * castor oil 8001-79-4 * * * * o-xylene 95-47-6 * 1000 LBS * * * * ethylbenzene 100-41-4 * 1000 LBS * * * * p-xylene 106-42-3 * 100 LBS * * * * wax solids proprietary organic-chrome complex proprietary water 7732-18-5 * * * chromium complex proprietary cromate (1-) bis 2-(3-chlorophenyl) 51147-75-2 * * * chromium complex proprietary * * * 1000 LBS * WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. EHS Review/Issue Date: 10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 8 of 9 * * * * * Material Safety Data Sheet Product Name: ULTRA™ CLASSIC UNIVERSAL WALNUT Section 16: Other Information IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. HMIS Codes Health 2 Flammability 4 Reactivity 0 Key to Abbreviations: * ACGIH CAS CERCLA CERCLA RQ CFR CPR DSL EINECS EPCRA EPCRA EHS EPCRA TPQ o F g/l gal IARC lbs or LBS MGM3 MIR MSDS NCP NIOSH NTP OSHA PEL PPM Proposition 65 SARA TLV TSCA USEPA VOC VOL WT WHMIS UN Item appears on indicated list (or inventory) American Conference of Governmental Industrial Hygienists Chemical Abstract Service Registry Number Comprehensive Environmental Response, Compensation, and Liability Act CERCLA Reportable Quantity Code of Federal Regulations Cardiopulmonary resuscitation Domestic Substances List of Canada European Inventory of Existing Chemical Substances Emergency Planning and Community Right-to-know Act EPCRA Extremely Hazardous Substance EPCRA Threshold Planning Quantity Fahrenheit degrees Grams per liter Gallons International Agency for Research on Cancer Pounds Milligrams per cubic meter Maximum Incremental Reactivity Material Safety Data Sheet WHMIS Non-Controlled Product National Institute of Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million California's Safe Drinking Water and Toxic Enforcement Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act United States Environmental Protection Agency Volatile Organic Compound Volume Weight Canadian Workplace Hazardous Materials Information System United Nations EHS Review/Issue Date:10/15/2011 File: IM100-7021_MSDS_ENGUSA_008.pdf Page 9 of 9