material safety data sheet
Transcription
material safety data sheet
MATERIAL SAFETY DATA SHEET PAUL MITCHELL ACID WAVE. Page 1 Revised: 05-26-09 SECTION 1 – PRODUCT & COMPANY IDENTIFICATION Product : PAUL MITCHELL ACID WAVE. Company Name : VERNICO PRODUCTS Address : 680 AVE. LEPINE DORVAL, QUEBEC, H9P 2S5 Emergency Phone :514-636-4444 SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS CAS# HYDROGEN PEROXIDE 7722-84-1 %WEIGHT 2-3 SECTION 3 – HAZARD IDENTIFICATION Inhalation: May cause irritation of the respiratory tract. Skin and Eye Contact: Can cause irritation. Avoid prolong contact with skin and eyes. Rinse with water. Ingestion: Harmful if swallowed. In case of accidental ingestion, call physician. SECTION 4 – FIRST AID MEASURES Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Call a physician or poison control centre immediately. Skin Contact: Wash off with soap and water. If irritation persist, call a physician. Eye Contact: Rinse immediately with plenty of water and seek medical attention. SECTION 5 – FIRE FIGHTING MEASURES Extinguishing Media: Sprayed water stream, chemical fire extinguisher. Exposure Hazards: May release nitrogen, sulphur or carbon oxides. Precautions for Firefighting: Wear full firefighting gear and respiratory protection. SECTION 6 – ACCIDENTAL RELEASE MEASURES Wear gloves. Floor may be slippery. Contain spills immediately with an inert material. Clean residue with water. SECTION 7 – HANDLING AND STORAGE Handling: Avoid breathing vapours. Do not ingest. Provide sufficient air exchange in work rooms. Avoid contact with eyes and clothing. Avoid prolonged contact with skin. Follow the instructions. Storage: Keep in a dry cool place. Keep out of reach of children. Keep at temperatures above 0oC and under 40oC. PAUL MITCHELL ACID WAVE. SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Gloves/Type: PVC-Coated. Respiratory/Type: None required under normal operating conditions. Eye/Type: Chemical goggles. Clothing/Type: Wear impervious protective clothing. Other/Type: Eye bath and safety shower. SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Boiling Range: 100.0oC Specific Gravity: NA pH: 5.5–9.0 Vapour Pressure: NA Physical State: Liquid Odor: Mild SECTION 10 – STABILITY & REACTIVITY Stability: Stable under ordinary conditions. Hazardous Decomposition: May occur (oxygen). Conditions to Avoid: Heat, Flames, Ignition Sources. SECTION 11 – TOXICOLOGICAL INFORMATION Acute Toxicity: Harmful if swallowed. Irritancy: Can irritate eyes and skin. Sensitising Effects: May cause an allergic reaction. SECTION 12 – ECOLOGICAL INFORMATION Environmental Toxicity: NA SECTION 13 – DISPOSAL CONSIDERATION Disposal: In accordance with local and national regulations. SECTION 14 – TRANSPORT INFORMATION Proper Shipping Name: NA Hazard Class: NA UN/NA: NA Packing Group: NA SECTION 15 – REGULATORY INFORMATION Canadian Regulations. SECTION 16 – OTHER INFORMATION NA: Not Available. N.AP: Not Applicable Page 2 MATERIAL SAFETY DATA SHEET PAUL MITCHELL ALKALINE WAVE. Page 1 Revised: 05-26-09 SECTION 1 – PRODUCT & COMPANY IDENTIFICATION Product : PAUL MITCHELL ALKALINE WAVE. Company Name : VERNICO PRODUCTS Address : 680 AVE. LEPINE DORVAL, QUEBEC, H9P 2S5 Emergency Phone :514-636-4444 SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS CAS# HYDROGEN PEROXIDE 7722-84-1 %WEIGHT 2-3 SECTION 3 – HAZARD IDENTIFICATION Inhalation: May cause irritation of the respiratory tract. Skin and Eye Contact: Can cause irritation. Avoid prolong contact with skin and eyes. Rinse with water. Ingestion: Harmful if swallowed. In case of accidental ingestion, call physician. SECTION 4 – FIRST AID MEASURES Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Call a physician or poison control centre immediately. Skin Contact: Wash off with soap and water. If irritation persist, call a physician. Eye Contact: Rinse immediately with plenty of water and seek medical attention. SECTION 5 – FIRE FIGHTING MEASURES Extinguishing Media: Sprayed water stream, chemical fire extinguisher. Exposure Hazards: May release nitrogen, sulphur or carbon oxides. Precautions for Firefighting: Wear full firefighting gear and respiratory protection. SECTION 6 – ACCIDENTAL RELEASE MEASURES Wear gloves. Floor may be slippery. Contain spills immediately with an inert material. Clean residue with water. SECTION 7 – HANDLING AND STORAGE Handling: Avoid breathing vapours. Do not ingest. Provide sufficient air exchange in work rooms. Avoid contact with eyes and clothing. Avoid prolonged contact with skin. Follow the instructions. Storage: Keep in a dry cool place. Keep out of reach of children. Keep at temperatures above 0oC and under 40oC. PAUL MITCHELL ALKALINE WAVE. SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Gloves/Type: PVC-Coated. Respiratory/Type: None required under normal operating conditions. Eye/Type: Chemical goggles. Clothing/Type: Wear impervious protective clothing. Other/Type: Eye bath and safety shower. SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Boiling Range: 100.0oC Specific Gravity: NA pH: 6.0-7.5 Vapour Pressure: NA Physical State: Liquid Odor: Mild SECTION 10 – STABILITY & REACTIVITY Stability: Stable under ordinary conditions. Hazardous Decomposition: May occur (oxygen). Conditions to Avoid: Heat, Flames, Ignition Sources. SECTION 11 – TOXICOLOGICAL INFORMATION Acute Toxicity: Harmful if swallowed. Irritancy: Can irritate eyes and skin. Sensitising Effects: May cause an allergic reaction. SECTION 12 – ECOLOGICAL INFORMATION Environmental Toxicity: NA SECTION 13 – DISPOSAL CONSIDERATION Disposal: In accordance with local and national regulations. SECTION 14 – TRANSPORT INFORMATION Proper Shipping Name: NA Hazard Class: NA UN/NA: NA Packing Group: NA SECTION 15 – REGULATORY INFORMATION Canadian Regulations. SECTION 16 – OTHER INFORMATION NA: Not Available. N.AP: Not Applicable Page 2 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: DRY WAX PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: 1/2008 7/2007 JPMS-03-022 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Waxy solid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: 54 – 60°C Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: NA Solubility in/Miscibility with water: NA pH value at 20°C: NA 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY DATA SHEET PAUL MITCHELL EXOTHERMIC WAVE. Page 1 Revised: 05-26-09 SECTION 1 – PRODUCT & COMPANY IDENTIFICATION Product : PAUL MITCHELL EXOTHERMIC WAVE. Company Name : VERNICO PRODUCTS Address : 680 AVE. LEPINE DORVAL, QUEBEC, H9P 2S5 Emergency Phone : 514-636-4444 SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS CAS# HYDROGEN PEROXIDE 7722-84-1 %WEIGHT 2-3 SECTION 3 – HAZARD IDENTIFICATION Inhalation: May cause irritation of the respiratory tract. Skin and Eye Contact: Can cause irritation. Avoid prolong contact with skin and eyes. Rinse with water. Ingestion: Harmful if swallowed. In case of accidental ingestion, call physician. SECTION 4 – FIRST AID MEASURES Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Call a physician or poison control centre immediately. Skin Contact: Wash off with soap and water. If irritation persist, call a physician. Eye Contact: Rinse immediately with plenty of water and seek medical attention. SECTION 5 – FIRE FIGHTING MEASURES Extinguishing Media: Sprayed water stream, chemical fire extinguisher. Exposure Hazards: May release nitrogen, sulphur or carbon oxides. Precautions for Firefighting: Wear full firefighting gear and respiratory protection. SECTION 6 – ACCIDENTAL RELEASE MEASURES Wear gloves. Floor may be slippery. Contain spills immediately with an inert material. Clean residue with water. SECTION 7 – HANDLING AND STORAGE Handling: Avoid breathing vapours. Do not ingest. Provide sufficient air exchange in work rooms. Avoid contact with eyes and clothing. Avoid prolonged contact with skin. Follow the instructions. Storage: Keep in a dry cool place. Keep out of reach of children. Keep at temperatures above 0oC and under 40oC. PAUL MITCHELL EXOTHERMIC WAVE. SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Gloves/Type: PVC-Coated. Respiratory/Type: None required under normal operating conditions. Eye/Type: Chemical goggles. Clothing/Type: Wear impervious protective clothing. Other/Type: Eye bath and safety shower. SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Boiling Range: 100.0oC Specific Gravity: NA pH: 6.5-7.5 Vapour Pressure: NA Physical State: Liquid Odour: Mild SECTION 10 – STABILITY & REACTIVITY Stability: Stable under ordinary conditions. Hazardous Decomposition: May occur (oxygen). Conditions to Avoid: Heat, Flames, Ignition Sources. SECTION 11 – TOXICOLOGICAL INFORMATION Acute Toxicity: Harmful if swallowed. Irritancy: Can irritate eyes and skin. Sensitising Effects: May cause an allergic reaction. SECTION 12 – ECOLOGICAL INFORMATION Environmental Toxicity: NA SECTION 13 – DISPOSAL CONSIDERATION Disposal: In accordance with local and national regulations. SECTION 14 – TRANSPORT INFORMATION Proper Shipping Name: NA Hazard Class: NA UN/NA: NA Packing Group: NA SECTION 15 – REGULATORY INFORMATION Canadian Regulations. SECTION 16 – OTHER INFORMATION NA: Not Available. N.AP: Not Applicable Page 2 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: EXTRA BODY DAILY BOOST PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 1/2008 N/A JPMS-03-008 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, EXTRA-BODY FINISHING HAIR SPRAY (INT) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: January 9, 2008 REVISION DATE: SUPERSEDES: FORMULA: TPM2P11 L33799B PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI2M SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Ethanol Isobutane Propane CAS No ----------64-17-5 75-28-5 74-98-6 Percent ---------61.4% 26.9% 5.1% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid, Light Straw Yellow STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: ND SPECIFIC GRAVITY: 0.811-0.831 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: ND BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Isobutane, Propane); Acute and Fire Hazard (Isobutane, Propane, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, EXTRA-BODY FIRM FINISHING SPRAY (55%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: April 12, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPMK101 L35845A1A PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIK1,K2,K3,K4,K5 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Ethane, 1,1-Difluoro- Ethanol Aminomethyl Propanol CAS No ----------75-37-6 64-17-5 124-68-5 Percent ---------37.0% 55.0% 1.0% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Very Light Straw Yellow Liquid STATE: Aerosol ODOR: Peachy Mango PERCENT VOLATILE: 55 % SPECIFIC GRAVITY: 0.810 – 0.830 VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 25°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: Unknown VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Ethane,1,1-Difuoro-); Acute and Fire Hazard (Ethane,1,1-Difuoro-, Ethanol,) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 1 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, EXTRA-BODY SCULPTING FOAM (6% VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM3D01 L31841 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Mousse PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIF2 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Isobutane Propane Butane CAS No ----------75-28-5 74-98-6 106-97-8 Percent ---------2.7% 2.0% 1.3% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Light Straw Translucent Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 6 % SPECIFIC GRAVITY: 0.998-1.014 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Propane, Butane, Isobutane); Acute and Fire Hazard (Propane, Butane, Isobutane) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: EXTRA-BODY SCULPTING GEL PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL N/A JPMS-03-007 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, EXTRA-BODY FINISHING SPRAY (55%) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM2M01 L33720 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI2M SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------1,1-Difluoro-Ethane Ethanol CAS No ----------75-37-6 64-17-5 Percent ---------40.0% 54.1% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 55.0 % SPECIFIC GRAVITY: 0.800-0.820 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane); Acute and Fire Hazard (1,1-Difuoro-Ethane, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: FAST DRYING SCULPTING SPRAY 55%VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 12/2007 JPMS-04-009 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 55% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <76° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <76° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 Liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: FAST DRYING SCULPTING SPRAY 80%VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 12/2007 JPMS-04-004 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 80% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <54° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change In Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <54° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed, and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: FAST FORM (CREAM GEL) PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (3/2009) N/A JPMS-03-040 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Opaque lotion Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, FOAMING POMMADE Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: December 04, 2007 REVISION DATE: SUPERSEDES: FORMULA: TIR0111 L34499 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Smoothing Polish PRODUCT TYPE/CHEMICAL FAMILY: PRODUCT CODE: IMARE01,02,03 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Pentane CAS No ----------109-66-0 Percent ---------10.0% Hazardous ------------Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.2%; UEL=11.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Opaque Emulsion, White STATE: Liquid ODOR: Characteristic PERCENT VOLATILE: ND SPECIFIC GRAVITY: 0.920-0.964 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: ND BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Pentene); Acute and Fire Hazard (Pentene). SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: FREEZE AND SHINE SUPER SPRAY 55%VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 12/2007 JPMS-04-008 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 55% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <76° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <76° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: NA Reportable Quantity (40 CFR 302.4): NA California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components have been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: FREEZE AND SHINE SUPER SPRAY 80%VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 12/2007 JPMS-04-003 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 80% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <54° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <54° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed, and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 14. TRANSPORTATION INFORMATION 3 4 Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: NA Reportable Quantity (40 CFR 302.4): NA California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 1 MATERIAL SAFETY DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: GLOSS DROPS PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-04-006 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Phenyl Trimethicone 2116-84-9,1875891-3, 18876-34-1, 70131-69-0, 73559-47-4, 195868-36-1 541-02-6 64-17-5 218-320-6 7% Yes 208-764-9 200-578-6 4% 2% Yes Yes Cyclopentasiloxane Ethyl Alcohol 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES 1 2 EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <65° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <65° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor Pressure: N/A Density at 20°C: 0.95 – 0.97 Solubility in/Miscibility with water: Not miscible. pH value at 20°C: NA 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 14. TRANSPORTATION INFORMATION 3 4 Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1993 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Flammable liquid, N.O.S. Hazard class: 3 UN-Number: UN1993 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Phenyl Trimethicone Cyclopentasiloxane & Ethyl Alcohol ) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1993 Label: 3 Packaging group: II EMS Number: F-E-S-E Marine pollutant: NA Proper Shipping Name: Flammable (Contains Phenyl Trimethicon , Cyclopentasiloxane & Ethyl Alcohol ) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1993 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Phenyl Trimethicone, Cyclopentasiloxane & Ethyl Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: HAIR SCULPTING LOTION PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: 1/2008 7/2007 JPMS-03-006 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 20465 E. Walnut Dr. Walnut CA 91789 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): 1-800-255-3924 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-909-598-1951 PRODUCT CLASS: HAIR STYLING PRODUCT NAMES: Extra-Body Daily Boost, Re-Works, Lab ESP (Elastic Shaping Paste), Tea Tree Grooming Pomade, Lab XTG (Extreme Thickening Glue), Color Block, Volumizing Spray, Hair Sculpting Lotion, Extra-Body Sculpting Gel, Super Clean Sculpting Gel, Super Sculpt, Straight Works, Slick Works, Wax Works, Tea Tree Styling Gel, Tea Tree Styling Wax, Modern Elixir Styling Creme, Modern Elixirs Frizz Calmplex, Modern Elixirs Texturizing Balm, Modern Elixirs Styling Serum, Modern Elixirs Defining Pomade, Dry Wax, Tea Tree Shaping Cream, Quick Slip, Round Trip I. PRODUCT IDENTIFICATION REVISION DATE: SUPERCEDES: 06/2005 05/2004 MSDS NO: DESCRIPTION / USE: JPMS-06-001 Formulations designed to provide texture, definition and conditioning to the hair. II. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME (>1.0% Concentration) DEIONIZED WATER (AQUA) POLYQUATERNIUM-11 PROPYLENE GLYCOL MINERAL OIL (PARAFFINIUM LIQUIDUM) OLETH-5 DEA-OLETH-10 PHOSPHATE DEA OLETH-3 PHOSPHATE VP/VA COPOLYMER METHYLPROPANEDIOL SORBITOL BUTYLENE GLYCOL GLYCERIN STEARETH-20 OCTYLACRYAMIDE / ACRYLATES / BUTYLAMINOETHYL METHACRYLATE COPOLYMER CYCLOMETHICONE, PHENYLTRIMETHICONE, DIMETHICONE AND METHICONOL HEXYLENE GLYCOL POLYACRYLAMIDE / C13-14 ISOPARAFFIN / LAURETH-7 POLYACRYLAMIDOMETHYLPROPANE SULFONIC ACID TRIETHANOLAMINE CARBOMER PHENYL TRIMETHICONE METHACRYLOYL ETHYL BETAINE/ACRYLATES COPOLYMER CAS # EXPOSURE LIMITS 7732-18-5 53633-54-8 57-55-6 8012-95-1 9004-98-2 58855-63-3 58855-63-3 25086-89-9 2163-42-0 50-70-4 107-88-0 56-81-5 9005-00-9 70801-07-9 None Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established MIXTURE Not Established 107-41-5 MIXTURE 27119-07-9 102-71-6 9003-01-4 MIXTURE MIXTURE Not Established Not Established Not Established Not Established Not Established Not Established Not Established 1 2 CYCLOMETHICONE / DIMETHICONOL FRAGRANCE (PARFUM) PPG-5-CETEH-20 CETEARYL ALCOHOL PVP GLYCERYL STEARATE BEESWAX OZOKERITE STEARETH-21 STEARETH-2 DIETHYLHEXYL MELEATE VINYL CAPROLACTAM/VP/DIMETHYLAMINOETHYL METHACRYLATE COPOLYMER PHENOXYETHANOL, METHYLPARABEN, ETHYLPARABEN, PROPYLPARABEN, BUTYLPARABEN. OLETH-10 PEG-25 HYDROGENATED CASTOR OIL BIS-DIGLYCERYL POLYACYLADIPATE-2 STEARYL ALCOHOL CETYL ALCOHOL PETROLATUM SORBITAN ISOSTEARATE STEARALKONIUM CHLORIDE CETRIMONIUM CHLORIDE DIMETHICONE COPOLYOL PANTHENATE ISOSTEARYL ALCOHOL OCTYLDODECYL MYRISTATE POLYISOBUTENE GLYCERYL STEARATE (AND) PEG-100 STEARATE EUPHORBIA CERIFERA (CANDELILLA) WAX BEEWAX WHITE PASTILLES SP422P CETEARYL ALCOHOL (AND) CETEARETH-20 CYCLOPENTASILOXANE (AND) DIMETHICONE (AND) PHENYL TRIMETHICONE 1, 3 BUTYLENE GLYCOL VP/VA COPOLYMER CAPRYLIC/CAPRIC TRIGLYCERIDES (AND) SODIUM ACRYLATES COPOLYMER BEHENTRIMONIUM DIMETHICONE COPOLYOL PHTHALATE VINYL CAPROLACTAM/PVP/DIMETHYLAMINOMETHYL METHACRYLATE PEG-40 HYDROGENATED CASTOR OIL C12-15 ALKYL BENZOATE PEG-10 SOYA STEROL COPERNICA CERIFERA (CARNAUBA) WAX POLYQUATERNIUM-55 QUATERNIUM-91 (AND) CETRIMONIUM METHOSULFATE 69430—24-6 31692-79-2 MIXTURE MIXTURE 8005-44-5 9003-39-8 123-94-4 8006-40-4 8021-55-4 9005-00-9 9005-00-9 MIXTURE MIXTURE Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established MIXTURE Not Established 9004-98-2 MIXTURE MIXTURE 112-92-5 36653-82-4 MIXTURE 71902-01-7 122-19-0 112-02-7 MIXTURE 27458-93-1 22766-83-2 9003-27-4 123-94-4 9004-99-3 MIXTURE 8006-40-4 8005-44-5 68439-49-6 541-02-6 9006-65-9 2116-84-9 107-88-0 MIXTURE 65381-09-1 Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established MIXTURE MIXTURE Not Established Not Established 61788-85-0 68411-27-8 MIXTURE 8015-86-9 306769-73-3 65060-02-8 Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established Not Established 2 3 ISOHEXADECANE CYCLOMETHICONE POLYQUATERNIUM-37 (AND) PROPYLENE GLYCOL DICAPRYLATE/DICAPRATE (AND) PPG-1 TRIDECETH-6 4390-04-9 69430-24-6 26161-33-1 58748-27-9 Not Established Not Established Not Established DIMETHICONOL 31692-79-2 Not Established III. HAZARDS IDENTIFICATION This product is not considered to be hazardous under OSHA 29 CFR 1910.1200. ROUTES OF ENTRY Inhalation NO Skin/Eye Contact YES HEALTH EFFECTS Acute YES Chronic NO PHYSICAL EFFECTS Flammable NO Reactive NO Medical Conditions Aggravated: Effects of Accidental Exposure None known or reported. May irritate eyes May irritate pre-existing dermatitis condition. May cause vomiting and diarrhea if ingested. None known or reported. Medical Conditions Aggravated: Ingestion YES Hazardous Materials Identification System / National Fire Protection Association Classifications Health Flammability Reactivity Hazard Ratings: HMIS 0 1 0 NFPA 0 1 0 Immediate (Acute) Health Effects Inhalation Toxicity: Because of its low volatility, exposure to vapors is unlikely and no significant adverse effects to health will occur from inhalation. Inhalation Irritation: May cause transient irritation if inhaled as an aerosol. Skin Contact: Contact would be expected to cause transient redness if not washed off and left on the skin for an extended period of time. Skin Absorption: Not expected to be absorbed through the skin. Eye Contact Contact would be expected to cause transient redness if not washed out and left in the eye for an extended period of time. No visual impairment is expected. Ingestion Irritation: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting, lethargy or diarrhea. Ingestion Toxicity: Not expected to be toxic by ingestion unless large amounts are swallowed. Prolonged (Chronic) Health Effects Carcinogenicity: This product is not known or reported to be carcinogenic. Reproductive and Developmental Toxicity: No reproductive or developmental risk to humans is expected from exposure to this product. 3 4 IV. FIRST AID Inhalation: Skin / Eye Contact: Ingestion: Remove individual to fresh air. Remove contact lenses, if used. Flush with copious amount of water for 15 minutes. Call a physician if irritation develops. Immediately drink water to dilute. Never give anything by mouth to an unconscious person. Call a physician if symptoms develop. V. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide, Carbon Monoxide VI. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations: No extra protection normally needed due to low volatility and toxicity. Spill Mitigation Procedures Contain spill as soon as possible. Promptly clean up by flushing with water to drain. Caution: floor can be slippery when wet. VII. HANDLING AND STORAGE Handling: Storage: Disposal Do not take internally. Avoid prolonged contact with skin or eyes, Avoid breathing mist. Store in a cool, dry and well ventilated place Product classified as non-hazardous waste according to RCRA VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: No exposure limits established for this product. No engineering controls are likely to be required under normal conditions. Use general exhaust ventilation if mists or aerosols are generated. Personal Protective Equipment (PPE) for Routine Use of Product None required. 4 5 IX. PHYSICAL DATA Physical State: Odor pH Specific Gravity: Vapor Density Evaporation Rate: Clear to Cloudy White Liquid to Solid-Cream, No foreign matter, Floral, Peach, Citrus, Mint or Herbal Fragrance. 4-6.2 0.950-1.040 Heavier than air. Slower than ether. X. STABILITY AND REACTIVITY Stability and Reactivity Summary: Chemical Incompatibility: Hazardous Polymerization Stable under normal conditions. Not sensitive to mechanical shock. Strong oxidizing agents Will not occur XI. TOXICOLOGICAL INFORMATION Toxicity Data: No toxic risk to humans is expected. Not known or reported to be carcinogenic. XII. TRANSPORTATION INFORMATION THIS MATERIAL IS NOT REGULATED AS A DOT HAZARDOUS MATERIAL. Land (DOT): Not Regulated Air (IATA/ICAO): Not Regulated Water (IMO): Not Regulated XIII. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE XIV. ADDITIONAL INFORMATION THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200 BOCCHI LABORATORIES INC. BELIEVES INFORMATION ON THIS MSDS IS RELIABLE AND UP TO DATE. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSYTEMS, HEAT SEAL Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM0A51 L35622A PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Heat Seal PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI8D SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------- Ethanol CAS No ----------64-17-5 Percent ---------4.0% Hazardous ------------Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Almost Transparent to Hazy Liquid STATE: Liquid ODOR: Characteristic PERCENT VOLATILE: ND SPECIFIC GRAVITY: 0.946-1.046 @ 25°C VISCOSITY:ambient EVAPORATION RATE, >1 VAPOR PRESSURE: ND BOILING POINT: 163°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Not Regulated Not Regulated None None None IATA PROPER SHIPPING NAME: Not Regulated (Domestic) Not Regulated (Export) IATA HAZARD CLASS: None IATA LABELS REQUIRED: Not Regulated (Domestic) Not Regulated (Export) BILL OF LADING DESCRIPTION: Not Regulated (Domestic) Not Regulated (Export) UN/NA CODE: NA (Domestic) Not Regulated (Export) PACKING INSTRUCTIONS: None EMERGENCY RESPONSE GUIDE NUMBER: None EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Not Regulated None Not Regulated Not Regulated None Not Regulated No None None None CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: None Noted SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, HOLD ME TIGHT HAIR SPRAY Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: June 7, 2006 REVISION DATE: January 09, 2008 SUPERSEDES: June 7, 2006 FORMULA: TPM9301 L35844 PREPARED: Jay Hensel REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIC1,C2,C3,C4,C5 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Dimethyl Ether 1,1-Difluoro-Ethane Ethanol CAS No ----------115-10-6 75-37-6 64-17-5 Percent ---------4.0% 35.0% 49.3% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 53.3 % SPECIFIC GRAVITY: 0.813-0.833 @ 20°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane, Dimethyl Ether); Acute and Fire Hazard (1,1-Difuoro-Ethane, Dimethyl Ether, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS HOT OFF THE PRESS (55%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: March 23, 2009 REVISION DATE: SUPERSEDES: FORMULA: TPMM611 L37089A PREPARED: Stephanie Demyan REVISED BY: GENERIC/CHEMICAL NAME: Spray (Thermal Protection) PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMII1 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------1,1-Difluoro- Ethane Ethanol Dimethyl Ether CAS No ----------75-37-6 64-17-5 115-10-6 Percent ---------33.6% 50.0% 4.0% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid, Slightly Yellow STATE: Aerosol ODOR: To Match Standard PERCENT VOLATILE: 55 % SPECIFIC GRAVITY: 0.820 – 0.870 VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 25°°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: Unknown VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 International: 00-1-813979-0626 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane, Dimethyl Ether); Acute and Fire Hazard (1,1-Difuoro-Ethane, Dimethyl Ether, Ethanol,) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY NA 2=Moderate/Moderate 1 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: QUICK SLIP PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 12/2007 N/A JPMS-03-024 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Opaque, viscous cream Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: RE-WORKS PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-03-010 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: ROUND TRIP PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 12/2007 N/A JPMS-03-025 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Semi-viscous liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SCULPTING FOAM (6% VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM0241 L35964 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Mousse PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIE2 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Isobutane Propane CAS No ----------75-28-5 74-98-6 Percent ---------4.2% 1.0% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Slightly Hazy Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 6 % SPECIFIC GRAVITY: 0.990-1.010 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Propane, Isobutane); Acute and Fire Hazard (Propane, Isobutane) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS HEALTH 1 FLAMMABILITY 4 REACTIVITY 0 NFPA 704 NA NA NA KEY:NPCA-HMIS/NFPA 704 4=Severe/Extreme 3=Serious/High 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratoires, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SEAL AND SHINE PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: 1/2008 7/2007 JPMS-04-001 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 6% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: 132° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: 132° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed, and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Flammable liquid, N.O.S. Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SLICK WORKS PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-03-005 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly, hazy gel Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SOFT SCULPTING SPRAY GEL PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (7/2007) N/A JPMS-04-007 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 6% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: 106° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: 106° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed, and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Flammable liquid, N.O.S. Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI – International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SOFT SPRAY 55% VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 12/2007 JPMS-04-010 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 55% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <76° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <76° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR SPRAY PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SOFT SPRAY 80% VOC PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA 91350 REVISION DATE: SUPERCEDES: MSDS NO: 8/2009 1/2008 JPMS-04-005 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Ethyl Alcohol 64-17-5 200-578-6 80% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, begin artificial respiration immediately Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <54° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <54° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.98 – 1.0 Solubility in/Miscibility with water: Fully miscible. pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1170 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Ethanol Solutions Hazard class: 3 UN-Number: UN1170 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Alcohol). Maritime transport IMDG: IMDG Class: 3 UN Number: UN1170 Label: 3 Packaging group: II EMS Number: F-E-S-D Marine pollutant: NA Proper Shipping Name: Flammable (Contains Alcohol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1170 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: NA Reportable Quantity (40 CFR 302.4): NA California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SPRAY WAX Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: January 31, 2007 REVISION DATE: January 9, 2008 SUPERSEDES: January 31, 2007 FORMULA: TPM5Z01 L34328 PREPARED: Konrad Krauss REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Spray Wax PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMID1,D2 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, Inc., 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section III - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Isobutane 1,1-Difluoro-Ethane Acetone Heptane, 2,2,4,6,6pentamethyl CAS No ----------75-28-5 75-37-6 67-64-1 13475-82-6 Percent ---------38.0% 17.0% 12.0% 18.0% Hazardous ------------Yes Yes Yes Yes Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eyecups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only) Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Viscous, Creamy, Waxy Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 55% SPECIFIC GRAVITY: 0.79-0.81 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: ND BOILING POINT: Not Applicable VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Isobutane; 1,1-Difluoro-Ethane); Acute and Fire Hazard (Isobutane, 1,1 Difluoro-Ethane,Heptane, 2,2,4,6,6- pentamethyl, Acetone) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS HEALTH 1 FLAMMABILITY 4 REACTIVITY 0 NFPA 704 NA NA NA KEY:NPCA-HMIS/NFPA 704 4=Severe/Extreme 3=Serious/High 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: STRAIGHT WORKS PRODUCT DESCRIPTION: FORMULATION DESIGNED TO SMOOTH AND STRAIGHTEN HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL(6/2008) N/A JPMS-03-016 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy, viscous gel Color: As per customer Odor: As per customer Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 25°C: 0.990 – 1.019 Solubility in/Miscibility with water: Miscible pH value at 25°C: 6.70 – 7.30 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN EXTRA HAIR SPRAY (55%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM6S01 L33289 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI6Y SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------1,1-Difluoro-Ethane Ethanol CAS No ----------75-37-6 64-17-5 Percent ---------50.6% 40.0% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid. FFM STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 55.0 % SPECIFIC GRAVITY: 0.805-0.825 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane); Acute and Fire Hazard (1,1-Difuoro-Ethane, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN EXTRA HAIR SPRAY (80%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPMA601 L35930B2 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIA3 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Dimethyl Ether Ethanol CAS No ----------115-10-6 64-17-5 Percent ---------35.0% 44.3% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid, Straw Liquid, FFM STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 80 % SPECIFIC GRAVITY: 0.865-0.885 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Dimethyl Ether); Acute and Fire Hazard (Dimethyl Ether, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 1 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN LIGHT HAIR SPRAY (55%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM6T01 L33323 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI6U SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------1,1-Difluoro-Ethane Ethanol CAS No ----------75-37-6 64-17-5 Percent ---------41.5% 51.8% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid, FFM STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 55.0 % SPECIFIC GRAVITY: 0.806-0.826 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane); Acute and Fire Hazard (1,1-Difuoro-Ethane, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS HEALTH 1 FLAMMABILITY 4 REACTIVITY 0 NFPA 704 NA NA NA KEY:NPCA-HMIS/NFPA 704 4=Severe/Extreme 3=Serious/High 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN LIGHT HAIR SPRAY (80%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPMJ101 L35710A PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIJ3 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Dimethyl Ether Ethanol CAS No ----------115-10-6 64-17-5 Percent ---------35.0% 41.2% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 80.0 % SPECIFIC GRAVITY: 0.870-0.880 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Dimethyl Ether); Acute and Fire Hazard (Dimethyl Ether, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 1 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SUPER CLEAN SCULPTING GEL PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-03-002 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN HAIR SPRAY (55%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPM6R01 L33324 PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMI6V SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------1,1-Difluoro-Ethane Ethanol CAS No ----------75-37-6 64-17-5 Percent ---------51.0% 41.0% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid, FFM STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 55.0 % SPECIFIC GRAVITY: 0.813-0.833 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane); Acute and Fire Hazard (1,1-Difuoro-Ethane, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, SUPER CLEAN HAIR SPRAY (80%VOC) Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: November 16, 2007 REVISION DATE: SUPERSEDES: FORMULA: TPMH101 L36175A PREPARED AND REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIH2 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Dimethyl Ether Ethanol CAS No ----------115-10-6 64-17-5 Percent ---------35.0% 44.8% Hazardous ------------Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 80% SPECIFIC GRAVITY: 0.865-0.885 @ 25°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (Dimethyl Ether); Acute and Fire Hazard ( Dimethyl Ether, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 1 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SUPER SCULPT GLAZE PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 7/2007 N/A JPMS-03-003 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAMES: JOHN PAUL MITCHELL SYSTEMS: SUPER SKINNY RELAXING BALM MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERSEDES: MSDS NO: ORIGINAL (10/2007) N/A JPMS-03-037 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Description: Formulations designed to provide texture, definition and conditioning to the hair. Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide, Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in condition Melting point/Melting range: Not Applicable Boiling point/Boiling range: Not Applicable Flash point: Not Applicable Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor Pressure: Not Applicable Density at 20°C: 0.996 – 1.036 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 3.70 – 4.30 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number Not Applicable Label Not Applicable Packaging group: Not Applicable EMS Number: Not Applicable Marine pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label Not Applicable Packaging group: Not Applicable Proper shipping name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI – International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 1 MATERIAL SAFETY DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: SUPER SKINNY SERUM PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: 12/2007 7/2007 JPMS-04-011 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Cyclopentasiloxane & Cyclotetrasiloxane & Dimethiconol 541-02-6 293-51-6,556-67-2 31692-79-2 208-764-9 209-136-7 70131-67-8 60% Yes Cyclotetrasiloxane & Cyclopentasiloxane 293-51-6,556-67-2 541-02-6 209-136-7 208-764-9 39.5% Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES 1 2 EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Flammable Properties Flash Point: Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Product is flammable. <118° Fahrenheit Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in condition Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <118° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.95 – 0.97 Solubility in/Miscibility with water: Not miscible. pH value at 20°C: NA 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1993 Packaging group: III Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Flammable liquid, N.O.S. Hazard class: 3 UN-Number: UN1993 Packaging group: III Description of goods: Flammable in containers greater than 1 liter (Contains Cyclopentasiloxane, and Cyclotetrasiloxane, and Dimethiconol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1993 Label: 3 Packaging group: III EMS Number: F-E-S-E Marine pollutant: Yes Proper Shipping Name: Flammable (Contains Cyclopentasiloxane, and Cyclotetrasiloxane, and Dimethiconol) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1993 Label: 3 Packaging group: III Proper shipping name: Flammable (Contains Cyclopentasiloxane, and Cyclotetrasiloxane, and Dimethiconol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI- International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 1 MATERIAL SAFETY DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue, Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTERNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: THE SHINE PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-04-002 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Ingredient CAS No. EINECS No. Percent Hazardous Phenyl Trimethicone 2116-849,18758-91-3, 18876-34-1, 70131-69-0, 73559-47-4, 195868-36-1 218-320-6 2% Yes Ethyl Alcohol Cyclopentasiloxane 64-17-5 541-02-6 200-578-6 208-764-9 15% 70% Yes Yes 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 1 2 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. Call a physician if irritation develops. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing, immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is flammable. Flammable Properties Flash Point: <65° Fahrenheit Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, and dry chemical or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear To Slightly Hazy Color: As per customer Odor: Floral/Balsamic/Aldehydic/Alcoholic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: <65° Fahrenheit Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: NA Density at 20°C: 0.95 – 0.97 Solubility in/Miscibility with water: Not miscible. pH value at 20°C: NA 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (Containers less than 1 Liter) Proper Shipping Name: Consumer Commodity Hazard class: ORM-D UN-Number: UN1993 Packaging group: II Description of goods: Considered to be Consumer Commodity in container less than 1 liter. Land transport U.S. DOT (Containers greater than 1 Liter) Proper Shipping Name: Flammable liquid, N.O.S. Hazard class: 3 UN-Number: UN1993 Packaging group: II Description of goods: Flammable in containers greater than 1 liter (Contains Phenyl Trimethicone, Cyclopentasiloxane, and Ethyl Alcohol) Maritime transport IMDG: IMDG Class: 3 UN Number: UN1993 Label: 3 Packaging group: II EMS Number: F-E-S-E Marine pollutant: NA Proper Shipping Name: Flammable (Contains Phenyl Trimethicone , Cyclopentasiloxane, and Ethyl Alcohol ) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: UN1993 Label: 3 Packaging group: II Proper shipping name: Flammable (Contains Phenyl Trimethicone, Cyclopentasiloxane, and Ethyl Alcohol) 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 3 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS- Environmental Management System ICAO-TI – International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: THICKEN UP PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 1/2008 N/A JPMS-03-026 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: VOLUMIZING SPRAY PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL 12/2007 N/A JPMS-03-012 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required. VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Clear to slightly hazy liquid Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Fully miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 MATERIAL SAFETY1DATA SHEET Bocchi Laboratories, Inc. 26421 Ruether Avenue Santa Clarita, CA 91350 FOR ALL EMERGENCIES, CALL CHEM TEL (24 Hours/7 Days): UNITED STATES & CANADA ONLY: INTRNATIONAL: 1-813-979-0626 1-800-255-3924 00-1-813979-0626 FOR ALL MSDS QUESTIONS OR REQUESTS, CALL: 1-661-252-3807 1. PRODUCT IDENTIFICATION PRODUCT CLASS: HAIR STYLING (NON FLAMMABLE) PRODUCT NAME: JOHN PAUL MITCHELL SYSTEMS: WAX WORKS PRODUCT DESCRIPTION: FORMULATION DESIGNED TO PROVIDE HOLD, TEXTURE AND DEFINITION TO THE HAIR. MANUFACTURER: BOCCHI LABORATORIES, INC. 26421 RUETHER AVENUE, SANTA CLARITA, CA-91350 REVISION DATE: SUPERCEDES: MSDS NO: ORIGINAL (1/2008) N/A JPMS-03-004 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Hazardous Components: Components Not Applicable CAS No. EINECS No. Percent Hazardous 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: May cause nausea and vomiting if ingested. 4. FIRST AID MEASURES EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Call a physician if irritation develops. 1 2 INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing begin artificial respiration immediately. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if victim is unconscious or having convulsions. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or explosive. Flammable Properties Flash Point: Not established. Fire/Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Material may be ignited only if preheated to high temperatures, for example in a fire. Relative hazard is anticipated to be the same as typical combustible materials. Use foam, carbon dioxide, dry chemical, or water spray when fighting fires. In case of fire, use normal fire fighting equipment including a NIOSH approved self-contained breathing apparatus (SCBA). Use water to cool containers. Carbon Dioxide and Carbon Monoxide 6. ACCIDENTAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors and skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible materials. 2 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary, except as a good industrial practice. EYE PROTECTION: Not necessary, except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information: Form: Hazy, translucent gel Color: As per customer Odor: Floral/Balsamic/Aldehydic Change in Condition: Melting point/Melting range: NA Boiling point/Boiling range: NA Flash point: NA Self-igniting: Product is not self-igniting Danger of explosion: Product does not present an explosion hazard Vapor pressure: NA Density at 20°C: 0.960 – 1.030 Solubility in/Miscibility with water: Miscible pH value at 20°C: 4.0 – 9.0 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions of storage and handling HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known 11. TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section 3 for available information on potential health effects. 12. ECOLOGICAL INFORMATION: No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information 13. DISPOSAL CONSIDERATIONS: All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. 3 4 14. TRANSPORTATION INFORMATION Land transport U.S. DOT (All sizes) Proper Shipping Name: Not Regulated Hazard Class: Not Regulated UN Number: Not Applicable Packaging Group: Not Applicable Description of goods: Not Applicable Maritime transport IMDG: Not Applicable IMDG Class: Not Applicable UN Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable EMS Number: Not Applicable Marine Pollutant: Not Applicable Proper Shipping Name: Not Applicable Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not Applicable UN/ID Number: Not Applicable Label: Not Applicable Packaging Group: Not Applicable Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA) Inventory of Existing Chemical Substances: NONE Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311/312 (40 CFR 370.2): Health: Physical: NONE NONE Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: N.A. Reportable Quantity (40 CFR 302.4): N.A. California Right-to-Know Regulations (Prop. 65) NONE 4 5 16. ADDITIONAL INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA), Hazardous Materials Identification System (HMIS), and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY: NPCA-HMIS/NFPA 704 HEALTH 0 NA 4=Severe/Extreme FLAMMABILITY 1 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources and considered to be dependable and accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: CAS# - Chemical Abstract System No. EINECS# - European Inventory of Existing Chemical Substance DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods NA - Not Applicable HMIS-Hazardous Material Identification System NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration EMS-Environmental Management System ICAO-TI - International Civil Aviation Organization Technical Instructions IATA - DGR - International Air Transport Association Dangerous Goods Regulations SARA - Superfund Amendments and Reauthorization Act Title I, II, III This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993 Prepared by: Dr. George Andrassy, Bocchi Laboratories, Inc. 5 425 S. 9th Street City of Industry, CA. 91746 (626) 363-6200 JOHN PAUL MITCHELL SYSTEMS, WORKED UP HAIR SPRAY Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS FIRST PREPARATION DATE: June 7, 2006 REVISION DATE: January 09, 2008 SUPERSEDES: June 07, 2006 FORMULA: TPM9101 L35843A PREPARED: Jay R, Hensel REVISED BY: Urbano Marquez GENERIC/CHEMICAL NAME: Hair Spray PRODUCT TYPE/CHEMICAL FAMILY: NA PRODUCT CODE: PAUMIB1,B2,B3,B4,B5 SYNONYMS: None CONTACT ADDRESS: KIK Custom Products Los Angeles, 425 S. 9th Street, City of Industry, CA. 91746 EMERGENCY PHONE NUMBERS: KIK Aerosol Socal LLC: (626) 363-6200 Monday - Friday, 8:00 am – 5:00 pm PST Chem-tel: (800) 255-3924 – 24-Hours Section II - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient ------------Dimethyl Ether 1,1-Difluoro-Ethane Ethanol CAS No ----------115-10-6 75-37-6 64-17-5 Percent ---------4.0% 35.0% 50.0% Hazardous ------------Yes Yes Yes Section III - HAZARDS INDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Direct contact of product with eyes may cause irritation, and may result in irreversible damage. SKIN CONTACT: Not Known INHALATION: Not Known INGESTION: If ingested, may cause nausea and vomiting. If in aerosol form, ingestion is not likely. Section IV - FIRST AID EYE CONTACT: If irritation or redness due to vapors develops, move victim away from exposure and into fresh air. If material gets into the eyes, flush eyes immediately with clean water for at least 15 minutes. If available, use eye-cups or eye wash fountain. If symptoms persist, get medical attention. SKIN CONTACT: Clean affected areas with mild soap and water. Remove contaminated clothing, including shoes, and launder before reuse or discard. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, get medical attention. If victim is not breathing immediately begin artificial respiration. Get medical attention. INGESTION: Product is not likely to be ingested. If this occurs, treat systematically. Never give fluids or induce vomiting if the victim is unconscious or having convulsions Section V - FIRE FIGHTING MEASURES FLASH POINT: -30°F TCC (Propellant Only); Concentrate 36°F (EPA Method 1010) AUTOIGNITION TEMPERATURE: NA FLAMMABILITY LIMITS IN AIR (% V): LEL=1.8%; UEL=9.5% EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool by spraying them with water until the fire has been extinguished. UNUSUAL FIRE & EXPLOSION HAZARDS: Containers may rupture and release flammable liquids and /or gasses if exposed to the heat of fire. Section VI - ACCIDENTIAL RELEASE MEASURES SPILL ON LAND (LARGE SPILL): Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without risk. Minimize breathing of vapors. Minimize skin contact. Ventilate confined spaces. For small spills implement the following cleanup procedures: Prevent material from entering sewers, watercourses, or low areas. Contain spilled material with sand or earth. Do not use combustible materials such as sawdust. Observe precautions for volatile, combustible vapors from absorbed material. For large spills implement the preceding cleanup procedures and, if in public area, keep public away and advise authorities. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SPILL ON WATER (LARGE SPILL): Eliminate sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or scooping up floating material. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SMALL SPILLS: Leaking containers should be placed in open containers, outdoors, away from any source of ignition, until all pressure has been released. Section VII - STORAGE AND HANDLING STORAGE TEMPERATURE: Ambient STORAGE/TRANSPORT PRESSURE: 180 psig @ 131°F Max LOADING/UNLOADING TEMPERATURE: Ambient STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. DO NOT handle or store near an open flame, heat, or other source of ignition. DO NOT pressurize, cut, heat, or weld empty containers. DO NOT reuse containers. Section VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: None Required VENTILATION: Normal Ventilation adequate for recommended uses. PROTECTIVE CLOTHING: Not necessary except as a good industrial practice. EYE PROTECTION: Not necessary except as a good industrial practice. OTHER PRECAUTIONS: Avoid excessive inhalation. Read and follow all label directions and cautions. Use only as directed Section IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid STATE: Aerosol ODOR: Characteristic PERCENT VOLATILE: 54 % SPECIFIC GRAVITY: 0.813-0.833 @ 20°C VISCOSITY: Aerosol @ ambient EVAPORATION RATE, >1 VAPOR PRESSURE mm Hg @ 20°C: Can pressure not to exceed 180 psig @ 131°F BOILING POINT: 173°F VAPOR DENSITY (Air=1): >1 SOLUBILITY IN WATER: Soluble Section X - REACTIVITY STABILITY: Stable under normal conditions of storage and handling CONDITIONS TO AVOID INSTABILITY: Do not store containers in direct sunlight or where conditions will heat them above 120°F. HAZARDOUS POLYMERIZATON: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: None Known Section XI - TOXICOLOGICAL INFORMATION No specific toxicological data is available for this product. Please refer to Section III for available information on potential health effects. Section XII - ECOLOGICAL INFORMATION No specific ecological data are available for this product. Please refer to Section VI for information regarding accidental releases and Section XV for regulatory reporting information Section XIII - DISPOSAL CONSIDERATIONS All recovered material should be packaged, labeled, transported, disposed and reclaimed in conformance with local, county, state, and federal regulations. May be disposed of by controlled incineration. Do not contaminate any lakes, streams, ponds, or underground water supplies. Empty containers may be disposed of as normal refuse. Please recycle whenever possible. Section XIV - TRANSPORT INFORMATION U. S. DOT PROPER SHIPPING NAME: U. S. DOT HAZARD CLASS: U. S. DOT LABELS REQUIRED: U. S. DOT PLACARDS REQUIRED: EMERGENCY RESPONSE GUIDE NUMBER: Consumer Commodity ORM-D None None NAERG# 171 IATA PROPER SHIPPING NAME: Consumer Commodity ORM-D (Domestic) Aerosols, Flammable, N.O.S., UN1950 (Export) IATA HAZARD CLASS: 2.1 IATA LABELS REQUIRED: Consumer Commodity ORM-D-AIR (Domestic) Flammable Gas (Export) BILL OF LADING DESCRIPTION: Consumer Commodity ORM-D-AIR, 9, ID8000 (Domestic) Aerosols, Flammable, N.O.S., 2.1, UN1950 (Export) UN/NA CODE: NA (Domestic) UN1950 (Export) PACKING INSTRUCTIONS: 910 (Domestic) 203/Y203 (Export) Authorization: Limited Quantity EMERGENCY RESPONSE GUIDE NUMBER: 126 EMERGENCY RESPONSE NUMBERS: CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PROPER SHIPPING NAME: IMDG HAZARD CLASS: IMDG LABELS REQUIRED: IMDG SECONDARY LABELS REQUIRED: IMDG PLACARDS REQUIRED: BILL OF LADING DESCRIPTION: MARINE POLLUTANT: EMERGENCY RESPONSE GUIDE NUMBER: EMS NUMBER: MFAG NUMBER: EMERGENCY RESPONSE NUMBERS: Aerosols 2.1 CARTON MUST BE MARKED “AEROSOLS” Hollow Diamond with UN1950 Marked in Center None Aerosol, 2, UN1950 No 126 2-13 620 CHEM-TEL: 1-813-979-0626 US & Canada Only: 1-800-255-3924 International: 00-1-813979-0626 IMDG PAGE NUMBER: UN/NA CODE: 2102 UN1950 Section XV - REGULATORY INFORMATION TSCA: Components of this product are listed on the Toxic Substances Control Act (TSCA) Inventory SARA TITLE III, Section 311-312: Acute, Fire, Sudden Release (1,1-Difuoro-Ethane, Dimethyl Ether); Acute and Fire Hazard (1,1-Difuoro-Ethane, Dimethyl Ether, Ethanol) SARA TITLE III, Section 313: None noted CALIFORNIA PROPOSITION 65: Not Regulated Section XVI - OTHER INFORMATION HAZARD RATING SYSTEMS: This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) and/or National Fire Protection Association (NFPA 704) Identification of the Fire Hazards of Materials. NPCA-HMIS NFPA 704 KEY:NPCA-HMIS/NFPA 704 HEALTH 1 NA 4=Severe/Extreme FLAMMABILITY 4 NA 3=Serious/High REACTIVITY 0 NA 2=Moderate/Moderate 1=Slight/Slight 0=Minimal/Insignificant NOTE: The information presented herein for this product or its components has been compiled from different supplier sources considered to be dependable and is accurate to the best of our knowledge as to the proper use and handling of this product under normal conditions. However, no representation, warranty, or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Any use of this product which is not in conformance with this MSDS or which involves using the product in combination with any other product or any process is the responsibility of the user. EXPLANATION OF ABBREVIATIONS: ACGIH - American Conference of Governmental Industrial Hygienists CAS# - Chemical Abstract System No. DOT -Department Of Transportation IMDG - International Maritime Dangerous Goods code NA - Not Applicable ND - Not Determined NFPA - National Fire Protection Association OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limits ppm - Parts Per Million PMCC - Pensky-Martin Closed Cup (flash point) SARA - Superfund Amendments and Reauthorization Act Title I, II, III TLV - Threshold Limit Value This MSDS has been formatted to be consistent with ANSI Standard Z400.1-1993