docAccessories Catalog - Bio
download 
Report Transcription
Accessories Catalog - Bio
EC-lab products Electrochemistry accessories Analytical cell Corrosion cell Glassware Electrodes Rotating electrodes Spectroelectrochemistry Quartz crystal analyzer Battery accessories Fuel cell Connection accessories Bio-Logic Bio-Logic SAS (founded in 1983) is located near Grenoble in the French Alps. We design and manufacture high performance, research laboratory instruments for electrochemistry, battery testing and fuel cell testing. Bio-Logic’s product range is based on a modular and flexible design. We offer potentiostat workstations from single channel up to 16 channel systems, integrating EIS capability and high current boosters. Analytical Small volume cells Large volume cells Flow cells InterDigitated Array (IDA) electrodes Ring disk type electrodes Screen Printed Electrodes (SPE) Corrosion Standard corrosion cells Avesta cell Flat cells Galvanic cells Plate material evaluating cell Coating cell 10 11 12 13 13 13 Glassware Small & big volume cell vials Bridge & purge tubes for corrosion cells Small size bridge tubes Bridge & purge tubes for analytical cells Bridge tubes with ceramic junction 14 16 16 17 18 Electrodes Working electrodes Small size reference electrodes King size reference electrodes Counter electrodes Metallic electrodes 18 20 22 23 23 Rotating Rotating Ring Disk Electrode (RRDE) Working electrode tips Rotating Disk Electrode (RDE) 24 25 26 Spectro- Spectrometer Static experiment Flow experiment Thin layer spectroelectrochemical cell 28 30 31 32 Quartz EQCM Quartz resonators Biosensor QCM 34 35 36 Battery Test cells Dilatometers Rack Battery (BH-1) & Coin Cell Holder (CCH) Current Collector (CC5) Sense Adapter Module (SAM-50) 38 39 40 40 41 41 Fuel Membrane Electrode Assemblies (MEA) Educational kit 42 43 Connection Multi-electrode investigation cables Specific cables External device connection Test Boxes & Dummy cells Faraday cages Connectors Transport cases 44 45 45 46 46 47 47 crystal analyzer accessories ELECTROCHEMISTRY accessories cell Analytical cell Corrosion Glassware Electrodes Rotating electrodes electrochemistry Spectro- accessories accessories Connection cell Fuel cell crystal analyzer electrochemistry Quartz electrodes accessories cell Battery cell 4 6 7 8 8 9 2/3 Analytical cell SVC-2 Small volume cells Each voltammetry cell is designed for a specific application (specific working electrode, volume of solution, oxygen free condition...). SVC-3 For example, for voltammetry investigations using standard working electrode with an outer diameter (OD) of 6 mm the fixed configuration of SVC-3 kit is recommended. For application requiring other working electrode shape, SVC-2 is more suitable. If only a small amount of the electroactive compound is available, SVC-2 in the microvolume mode is recommended. - SVC-2, modular - SVC-3, for a volume of 5 to 20 mL, only for working electrode with OD of 6 mm. - VC-4, for a volume of 1 to 3 mL, only for working electrode with OD of 6 mm. - Bulk electrolysis cell, for a volume of 100 mL. SVC-2 modularity: microvolume mode oxygen free mode Small amount of solution (200 μL in the sample holder) For electrode with OD of 10 mm For electrode with OD of 6 mm For microelectrode with OD of 4 mm Note that a complete analytical special kit SK-2 (A-012763) is also proposed, but the reference electrode has to be purchased separately. This kit includes: - SVC-3 kit (A-012669), - PK-3 polishing kit (A-011975) (see page 18), - one glassy carbon electrode, OD 6.0 mm, ID 3.0 mm (A-002012) (see page 18), - one platinum electrode, OD 6.0 mm, ID 1.6 mm (A-002013) (see page 18). 30 20 10 I/nA 0 -10 -20 -30 -40 -50 -0.5 0 Ewe/V 0.5 cell Analytical Glassware cell Corrosion Cell holder Purge tube (ETFE) Working electrodes Reference electrodes VC-4 A-011224 Bulk electrolysis cell A-001197 20 mL (7 pieces) 57 mm A-001056 20 mL (7 pieces) 50 mm A-001056 5 mL (7 pieces) 57 mm A-011504 100 mL (1 piece) 230 mm A-012632 adapter 10 to 6 - cell holder A-011227 porous carbon electrode lid for CE chamber for CE O-ring port plug stirrer bar A-010530 A-001198 A-001196 A-001236 A-009131 A-000178 9.0 mm (2 pieces) for 20 mL 1m A-012177 1m see page 18 see page 20 A-010537 1m A-010537 PTFE cap A-001209 A-010537 6.0 mm (2 pieces) for 20 mL 1m see page 18 see page 20 A-002222 A-011226 - A-002234 A-0 12551 - Rotating A-002222 A-012671 - electrodes A-002222 A-012670 - Electrodes Catalog n° A-012669 electrochemistry Options Sample holder Catalog n° SVC-3 A-012176 A-001209 A-010537 see page 20 10.2 mm 6.2 mm 1.65 mm 1.6 mm 1.6 mm 6.3 mm 6.2 mm crystal analyzer Counter electrode (CE) PTFE cap Purge tube (ETFE), 100 mm Additional items Catalog n° A-012668 Quartz Content Sample vial Catalog n° SVC-2 1.6 mm accessories Products Battery Small volume cells Bulk electrolysis cell Spectro- VC-4 Cell geometry The geometry of the cell should be optimized to reduce the ohmic drop. Working and reference electrodes have to be close to each other. accessories Connection cell Fuel The counter should not be the limiting factor for the electron transfer, so the surface area of the counter electrode should be larger than the surface area of the working electrode. ELECTROCHEMISTRY accessories 4/5 Analytical cell Large volume cells This analytical cell with volumes from 50-250 mL is well adapted for macro electrochemistry applications. Two types of packages are offered: - the standard analytical cell kit, - the complete analytical cell kit (which allows temperature control and gas purging). Standard analytical cell kit (80 mL) EL-ELECTRO-1 Complete analytical cell kit (80 mL) EL-ELECTRO-2 Complete analytical cell kit (150 mL) EL-ELECTRO-3 Glass cell 80 mL Double jacketed glass cell 80 mL Double jacketed glass cell 150 mL PTFE cap 5 holes PTFE ring, silicon encapsulated, OD 102 mm Cell collar with clamp Double purge tube Bridge tube for reference electrode, OD 6 mm Platinum counter electrode Purge tube Reference electrode Double nut 25 mm and 12 mm diameter Telescopic cell stand Options Electrode bridge extension for electroanalytical cell Bridge tube for reference electrode of OD 8 mm PT100 probe, indicate connector type Magnetic stirrer & heater, 220 V without PT100 probe 110 V Aluminum base holder for magnetic stirrer Set of 10 porous 4 mm glass frit (CoralPor™) with PTFE heat shrink (200 mm) 250 mL cells are also available: g lass cell EL-A-018 or double jacketed glass cell EL-A-021 EL-A-012 EL-A-002 EL-A-003 EL-A-004 EL-A-005 Catalog n° EL-A-001 EL-A-002 EL-A-020 EL-A-003 EL-A-004 EL-A-005 EL-A-006 EL-A-008 EL-A-009 EL-A-016 A-002056 EL-A-011 EL-A-012 EL-A-022 EL-A-017 EL-C-014 EL-C-015A EL-C-015B EL-C-018 092-VYC4 EL-A-008 EL-A-009 EL-A-022 cell Analytical Catalog n° A-012798 Radial flow cell OUTLET flow channel OUTLET INLET INLET OUTLET detector Catalog n° A-012799 Radial flow cell* Schematic diagram gasket Glassware cell Corrosion Cross flow cell* gasket Rotating Cross flow cell Product electrodes Flow cells Electrodes Radial flow cell Cross flow cell detector * Gasket, working, reference electrodes and connectors are sold separately ELECTROCHEMISTRY accessories electrochemistry Spectro- crystal analyzer Quartz accessories Battery cell Dual, parallel/cross flow A-001000 A-001002 A-001012 A-001008 A-001004 A-001009 A-001006 A-012583 A-001046 A-001047 A-001048 A-001049 A-001092 A-001093 A-001032 A-001016 A-012124 A-009908 A-011155 A-000999 A-010251 A-001146 A-001147 A-001148 A-012802 A-001192 A-001193 A-001031 A-012169 A-012173 A-012170 A-012174 A-012912 A-013273 A-001531 A-004130 Fuel Dual, series/cross flow glassy carbon Ø 3 mm x 2 (dual type), size 25 x 25 mm gold Ø 3 mm x 2 (dual type), size 25 x 25 mm platinum Ø 3 mm x 2 (dual type), size 25 x 25 mm silver Ø 3 mm x 2 (dual type), size 25 x 25 mm carbon paste Ø 3 mm x 2 (dual type), size 25 x 25 mm nickel Ø 3 mm x 2 (dual type), size 25 x 25 mm glassy carbon/gold Ø 3 mm x 2 (dual type), size 25 x 25 mm glassy carbon/platinum Ø 3 mm x 2 (dual type), size 25 x 25 mm gasket TG-2M PTFE (4 pieces) film thickness 12 µm TG-5M PTFE (4 pieces) film thickness 25 µm TG-6M PTFE (4 pieces) film thickness 50 µm TG-8M PTFE (4 pieces) film thickness 100 µm TG-11M silicon (4 pieces) film thickness 500 µm TG-12M silicon (4 pieces) film thickness 1,000 µm cross flow cell block material PEEK Radial flow electrode glassy carbon Ø 6 mm (single type), size 25 x 25 mm glassy carbon Ø 3 mm (single type), size 25 x 25 mm platinum Ø 3 mm (single type), size 25 x 25 mm gold Ø 3 mm (single type), size 25 x 25 mm PFCE carbon Ø 3 mm (single type), size 25 x 25 mm carbon paste Ø 3 mm (single type), size 25 x 25 mm gasket TG-2MR PTFE (4 pieces) film thickness 12 µm TG-5MR PTFE (4 pieces) film thickness 25 µm TG-6MR PTFE (4 pieces) film thickness 50 µm TG-8MR PTFE (4 pieces) film thickness 100 µm TG-11MR PTFE (4 pieces) film thickness 500 µm TG-12MR PTFE (4 pieces) film thickness 1,000 µm radial flow cell block material PEEK Cross/radial RE-3V Ag/AgCl reference electrode screw type size Ø 10 x 48 mm RE-7V non aqueous reference electrode (Ag/Ag+) screw type, poly acetal resin RE-3VP Ag/AgCl screw type electrode, PEEK resin RE-7VP non aqueous reference electrode (Ag/Ag+) screw type, PEEK resin 0.04" single leal connector (2 pieces) 0.04" MM connector (10 pieces) 1/16" PEEK tube ID 0.25 mm, length 3.0 m dynaseal PEEK fingertight (10 pieces) screw for pipe connecting integrated 1/16" accessories Single/radial flow electrode Connection Options Cross flow 6/7 Analytical cell 3 µm InterDigitated Array (IDA) electrodes 2 Counter electrode Passivation membrane 20 Reference electrode Working electrode #1 Working electrode #2 Quartz plate, thickness = 0.5 mm 12 The passivation membrane is a Novolac resin + naphtoquinorediazido compounds. 10 µm IDA electrode Width Interval Length N° of feet Film thickness Catalog n° Gold Platinum Gold without passivation membrane Platinum without passivation membrane Gold Platinum Gold without passivation membrane Platinum without passivation membrane Gold Platinum ITO Carbon Gold without passivation membrane Platinum without passivation membrane ITO without passivation membrane Carbon without passivation membrane 2 µm 2 µm 2 µm 2 µm 3 µm 3 µm 3 µm 3 µm 10 µm 10 µm 10 µm 10 µm 10 µm 10 µm 10 µm 10 µm 2 µm 2 µm 2 µm 2 µm 3 µm 3 µm 3 µm 3 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 5 µm 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 65 pairs 90 nm 90 nm 90 nm 90 nm 90 nm 90 nm 90 nm 90 nm 90 nm 90 nm 100 ±20 nm 1200 ±100 nm 90 nm 90 nm 100 ±200 nm 1200 ±100 nm A-012257 A-012258 A-012261 A-012264 A-012129 A-012130 A-012260 A-012263 A-012125 A-012126 A-012128 A-012127 A-012259 A-012262 A-012265 A-012266 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm 2 mm Options Cable kit for IDA electrode Ag/AgCl ink for reference electrode (2.0 mL) A-011066 A-011464 Ring disk type electrodes Ring disk type electrodes Ring OD Ring ID Disk Catalog n° Gold ring disk electrode (3 pieces) Platinum ring disk electrode (3 pieces) Carbon ring disk electrode (3 pieces) 6 mm 6 mm 6 mm 4 mm 4 mm 4 mm 3 mm 3 mm 3 mm A-002081 A-002082 A-002083 cell Analytical cell Corrosion Screen Printed Electrodes (SPE) are low cost and disposable. They include one reference electrode, one counter electrode and one or several working electrodes according to the design needed. The working electrode can be made of glassy carbon, platinum, gold. The SPE allows users to work with a small amount of solution (25-100 μL). Glassware Screen Printed Electrodes (SPE) Electrodes U-GEM, connector for 3-electrode SPE Counter electrode Reference electrode Rotating Working electrode Packaging Catalog n° alumina alumina valox FR1 valox FR1 alumina alumina valox FR1 valox FR1 alumina alumina valox FR1 valox FR1 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces G-GGA/1 G-GGA/2 G-GGP/1 G-GGP/2 G-PTGA/1 G-PTGA/2 G-PTGP/1 G-PTGP/2 G-AUGA/1 G-AUGA/2 G-AUGP/1 G-AUGP/2 Option Connector for 3-electrode Screen Printed Electrodes (2 mm banana plug) Ø of WE: size of pseudo-RE: overall dimension: 0.8 mm 20 x 1 mm 45 x 19 mm ELECTROCHEMISTRY accessories Working electrode Counter electrode & ref. electrode Substrat Packaging Catalog n° graphite graphite graphite graphite platinum platinum platinum platinum gold gold gold gold Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl alumina alumina valox FR1 valox FR1 alumina alumina valox FR1 valox FR1 alumina alumina valox FR1 valox FR1 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces 100 pieces 500 pieces G-A-GA/1 G-A-GA/2 G-A-GP/1 G-A-GP/2 G-A-PTA/1 G-A-PTA/2 G-A-PTP/1 G-A-PTP/2 G-A-AUA/1 G-A-AUA/2 G-A-AUP/1 G-A-AUP/2 cell Array of 16 WE U-GEM Fuel Ø of WE: 2 mm size of RE: 0.5 x 1 mm ratio CE/WE surface area:4/1 overall dimension: 50 x 10 mm electrochemistry Substrat Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl crystal analyzer Ref. electrode graphite graphite graphite graphite graphite graphite graphite graphite graphite graphite graphite graphite Quartz Counter electrode graphite graphite graphite graphite platinum platinum platinum platinum gold gold gold gold accessories Working electrode 3-electrode Battery Screen Printed Electrodes Spectro- Array of 16 working electrodes accessories Three-electrode sensor Connection Note with Bio-Logic’s multichannel potentiostats, it is possible to run simultaneous investigations on each working electrode of the array (up to 16). electrodes A two–electrode set-up is used for multi working electrode SPE with one shared reference electrode and one shared counter electrode. 8/9 Corrosion cell Standard corrosion cells For corrosion applications, two packages for large volume i.e. ~1 L are available: - basic corrosion cell kit, - complete corrosion cell kit (allows temperature control and includes sample holder and cell stand). Basic corrosion cell kit EL-CORR-1 Complete corrosion cell kit EL-CORR-2 Options Bridge tube for 6 mm diameter reference electrode PT100 probe (indicate connector type) Magnetic stirrer & heater, without PT100 probe Catalog n° EL-C-001 EL-C-002 EL-C-003 EL-C-004 EL-C-005 EL-C-006 EL-C-009 EL-C-011 EL-C-012 092-C-013 EL-C-016 EL-C-017 R-XR110 R-A94L111 R-X31M012 Glass cell 1 L Double jacketed glass cell 1 L PTFE cap PTFE ring, silicon encapsulated, OD 102 mm Cell collar with clamp Double purge tube Graphite counter electrode rod (2 pieces) Double nut 25 mm and 12 mm diameter Telescopic cell stand Sample holder 1 cm2 Purge tube Bridge tube for 8 mm diameter reference electrode Calomel reference electrode length 80 mm, OD 8 mm screw cap Cable connection for screw cap 100 mm, 2 mm banana plug 12 mm OD conical rings for reference electrode of 8 mm (4 pieces) EL-C-008 EL-C-014 EL-C-015A EL-C-015B EL-C-018 092-VYC4 220 V 110 V Aluminum base holder for magnetic stirrer Set of 10 porous frit (4 mm CoralPor™) with PTFE heat shrink (200 mm) 500 mL or 2 L double jacketed glass cell are also available (EL-C-020 and EL-C-021, respectively). 092-C-013 8 log (|I/nA|) 7 6 EL-C-002 5 4 3 -0.6 -0.4 0 -0.2 Ewe/V 0.2 EL-C-003 EL-C-004 EL-C-005 EL-C-017 EL-C-009 cell Analytical cell Corrosion Glassware Electrodes Avesta cell Avesta cell is an electrochemical cell developed for pitting corrosion testing (ASTM G150). It is designed to avoid microcrevice corrosion formed between the working electrode and the gasket at the bottom aperture of the cell. electrodes Rotating A filter paper ring placed between the sample and the gasket is flooded by distilled water in order to eliminate crevice corrosion. Options Peristaltic pump for low flow Bridge tube for reference electrode with OD of 8 mm Single purge tube Temperature probe PT100 Set of 10 porous frit (4 mm CoralPor™) with PTFE heat shrink (200 mm) Spectro- EL-AV-002 EL-AV-003 EL-AV-004 EL-A-005 EL-AV-006 EL-AV-007 EL-C-009 EL-AV-010 EL-C-011 EL-AV-012 EL-AV-015 crystal analyzer Content Double jacketed cell glass 250 mL PTFE cap 5 holes O-ring PTFE silcone encapsulated Cell collar with clamp Double purge tube Filter paper ring (100 pieces) Graphite counter electrode rods (2 pieces) Bridge tube for RE 6 mm Double nut Telescopic cell stand Skeleton Quartz EL-AV-001 accessories Catalog n° Avesta cell kit Battery Avesta cell electrochemistry The water flow is controlled by a peristaltic pump (EL-AV-008) which delivers 0.5 to 5 mL/h. EL-AV-008 EL-AV-013 EL-AV-014 EL-C-014 092-VYC4 Fuel Principle of Avesta cell Connection cell External gasket Filter paper ring Internal gasket INLET ELECTROCHEMISTRY accessories accessories Sample Copper connector 10/11 Corrosion cell Flat cells, 1 to 10 cm² sample area This cell with a volume of 250 mL is adapted to perform AC or DC experiments on flat specimen of 1 cm² or 10 cm² area. This cell has a double jacket for temperature control and three holes for reference electrode, purge tube and temperature probe with inner diameter of 17.6 mm and the 2 others of 8.3 mm. Thanks to its design, any sample with a thickness inferior to 10 mm fits in the holder. Flat cell 1 cm² Catalog n° Flat cell 10 cm² Catalog n° Flat cell kit 1 cm² EL-FLAT Flat cell kit 10 cm² EL-FLAT-2 Content RE-2B calomel reference electrode (length: 90 mm, OD: 6 mm) Platinum mesh counter electrode (54 mm wire/ 80 mesh), 25 x 35 mm Reference electrode bridge tube (6 mm diameter) Corrosion flat cell 1cm² EL-FLAT-3 includes: - glass part for flat cell (250 mL) - mechanical part for corrosion flat cell 1 cm² A-002056 A-702439 EL-F-004 EL-FLAT-3 EL-F-002 EL-FLAT-3H Content RE-2B calomel reference electrode (length: 90 mm, OD: 6 mm) Platinum mesh counter electrode (54 mm wire/ 80 mesh), 25 x 35 mm Reference electrode bridge tube (6 mm diameter) Corrosion flat cell 10 cm² EL-FLAT-4 includes: - glass part for flat cell (250 mL) - mechanical part for corrosion flat cell 10 cm² A-002056 A-702439 EL-F-004 EL-FLAT-4 EL-F-002 EL-FLAT-4H Investigation in agressive media If the experiment is performed in more agressive media such as fluorhydric acid media, it is possible to get a body of the flat cell in PVDF* instead of glass. Temperature PTFE PVDF* Borosilicated glass Fluorhydric acid 48% Sulfuric acid 98% Phosphoric acid 85% Hydrochloric acid 35% Nitric acid 70% Perchlorique acid 20° C 20° C 20° C 20° C 20° C 20° C 50° C 50° C 50° C 50° C Catalog n° Options PVDF* body (non double jacketed) EL-F-PVDF EPDM O-rings for 1 cm² with PEEK ferrule for CE** EL-SEAL-1B EPDM O-rings for 10 cm² with PEEK ferrule for CE** EL-SEAL-10B PTFE O-rings for 1 cm² with PEEK ferrule for CE** EL-SEAL-T1B PTFE O-rings for 10 cm² with PEEK ferrule for CE** EL-SEAL-T10B EPDM O-rings for 1 cm²** EL-SEAL-1 EPDM O-rings for 10 cm²** EL-SEAL-10 PTFE O-rings for 1 cm²** EL-SEAL-T1 PTFE O-rings for 10 cm²** EL-SEAL-T10 Set of 10 porous frit (4 mm CoralPor™) with PTFE heat shrink (200 mm) 092-VYC4 * Polyvinylidenefluoride ** The O-ring kits include 4 O-rings for the glassware side and 10 O-rings for the sample side 50° C 50° C Sodium Potassium hydroxide 50% hydroxide concentred 20° C 50° C * 20° C 50° C excellent good not recommended not compatible Polyvinylidenefluoride cell Analytical cell Corrosion Glassware Galvanic cell 1 cm² Catalog n° Galvanic cell 10 cm² Catalog n° Galvanic cell kit 1 cm² EL-GAL-1 Galvanic flat cell kit 10 cm² EL-GAL-10 EL-FLAT 092-FLAT/1 Content Flat cell kit 10 cm² Galvanic kit 10 cm² EL-FLAT-2 092-FLAT/10 Content Flat cell kit 1 cm² Galvanic kit 1 cm² Rotating Thanks to the modular design of the flat cell, it is possible to place two different materials at each end of the cell. Electrodes Galvanic cells, 1 to 10 cm² sample area Spectro- electrochemistry electrodes The surface area may be 1 or 10 cm². Plate material evaluating cell Catalog n° A-011951 Content PTFE cell [body & base] (1 piece) O-ring (1 piece) Screw 20 mm (1 piece) Purging tube, 100 mm Platinum counter electrode (1 piece) A-002222 Options O-ring (10 pieces) A-012022 ELECTROCHEMISTRY accessories Options Ag/AgCl reference electrode (OD: 6mm) Bridge tube for 6 mm reference electrode Mask for 1 cm² (20 pieces) Mask for 5 cm² (20 pieces) Mask for 10 cm² (20 pieces) crystal analyzer Quartz EL-P-002 EL-P-003 EL-P-004 EL-P-005 EL-P-006 EL-P-009 accessories Battery Content Glass for coating cell Nylon base with three feets Rubber cup with two holes Metallic clamp O-ring for coating cell Graphite rod counter electrode (L: 145 mm, OD: 6 mm) Catalog n° EL-COAT A-012167 EL-P-008 EL-P-011 EL-P-012 EL-P-013 cell Plate material evaluating cell Coating cell kit Fuel The required volume of solution is about 1 mL. Coating cell accessories This cell was developed to evaluate a plate material such as a metal, semi-conducting plate... The sample plate is sandwiched between the two cell blocks. Coating cell Connection Plate material evaluating cell, up to 1 cm² sample area 12/13 Glassware Small volume cell vials, 1 to 100 mL To complete a kit, the cell vials are also offered separately. 50 Note that other volumes are available on request. 28 72 18 50 30 ID 15.6 A-011504 ID 25.6 A-001056 A-001209 ID 46.4 A-012632 cell holder for A-011506 70 45 55 25.6 40 15,6 80 50 40 A-012672 A-001051 A-012652 Small & big volume cell vials Volume OD ID Height Quantity Purpose Catalog n° Small volume sample vial cell vials 5 mL 20 mL 100 mL 5 mL 20 mL 100 mL 18 mm 28 mm 50 mm 40 mm 55 mm 70 mm 15.6 mm 25.6 mm 46.4 mm 15.6 mm 25.6 mm 46.4 mm 30 mm 50 mm 72 mm 40 mm 50 mm 80 mm 90 mm 120 mm 90 mm 120 mm 62 mm 90 mm 62 mm 90 mm 80 mm 175 mm 85 mm 200 mm 10 10 1 1 1 1 1 1 1 1 1 1 A-011504 A-001056 A-012632 A-012672 A-001051 A-012652 A-001209 EL-A-001 EL-C-001 EL-A-002 EL-C-002 EL-C-019 water jacketed-glass vial Big volume cell vials cell holder for 20 mL vial sample vial 80 mL 1,000 mL water jacketed-glass vial 80 mL 1,000 mL cell holder for king size vial (1 L) VC-4 SVC-2, SVC-3 RRDE-3A, bulk electrolysis VC-4 SVC-2, SVC-3 RRDE-3A, bulk electrolysis SVC-2, SVC-3 EL-ELECTRO-1 EL-CORR-1 EL-ELECTRO-2 EL-CORR-2 EL-CORR-1 cell Analytical Corrosion Big volume cell vials, 100 to 2,000 mL 90 cell 62 90 Glassware 62 85 Electrodes 80 Rotating EL-A-002 EL-A-001 electrodes 120 90 120 Quartz crystal analyzer Spectro- electrochemistry 90 200 cell Fuel accessories Battery 175 accessories Connection EL-C-001 EL-C-002 EL-C-019, cell holder for EL-C-001 Dimensions in mm ELECTROCHEMISTRY accessories 14/15 Glassware Purge tubes Bridge tubes for corrosion cells The tolerance of each dimension is approximately ±0.5 mm. EL-C-008 EL-C-017 for corrosion cells EL-F-004B EL-F-004 EL-C-006 100 120 220 140 10 250 60 10 200 60 EL-C-016 10 10 10 A-012176 Small size bridge tubes A-012177 65 6 65 9 10 cell Analytical EL-A-006 R-AL100 100 R-AL110 cell with ceramic junction for analytical cells EL-A-008 Corrosion for analytical cells EL-A-017 Bridge tubes Purge tubes R-AL120 Glassware Bridge tubes Electrodes 70 138 165 electrodes 165 Rotating 200 Spectro- electrochemistry 250 10 10 crystal analyzer EL-A-016 Quartz 10 Vycor type compatibility Catalog n° 2 22 2 22 1 1 1 1 1 1 1 1 1 1 1 1 1 092-VYC3(1) A-012176 A-012306 A-012177 A-012307 EL-C-008 EL-C-017 EL-F-004 EL-F-004B EL-A-017 EL-A-008 EL-A-016 EL-A-006 EL-C-016 EL-C-006 R-AL100 R-AL110 R-AL210 Bridge tube for corrosion cells Bridge tube for analytical cells Purge tube for analytical cells Purge tube for corrosion cells Bridge tube with ceramic junction Ø 8 mm Ø 6 mm single double single double short standard with reverse sleeve (non aqueous) standard SVC-2, SVC-3 SVC-2, SVC-3 SVC-2 SVC-2 EL-CORR EL-CORR EL-FLAT EL-FLAT EL-ELECTRO EL-ELECTRO EL-ELECTRO EL-ELECTRO EL-CORR EL-CORR 8 mm 138 mm 1 Options (1) Set of 10 porous 2.8 mm glass frit (CoralPor™) with PTFE heat shrink (200 mm) (2) Set of 10 porous 4 mm glass frit (CoralPor™) with PTFE heat shrink (200 mm) ELECTROCHEMISTRY accessories 092-VYC4(2) accessories Quantity Purpose 68 mm 68 mm 68 mm 68 mm 250 mm 250 mm 120 mm 140 mm 165 mm 155 mm 165 mm 200 mm 200 mm 220 mm 70 mm 250 mm 138 mm 10 cell Height 6 mm 6 mm 9 mm 9 mm 10 mm 10 mm 10 mm 10 mm 10 mm 10 mm 10 mm 10 mm 10 mm 10 mm 12 mm 8 mm 8 mm Fuel OD Ø 6 mm Ø 6 mm Ø 9 mm Ø 9 mm Ø 6 mm Ø 8 mm accessories Ref. electrode Small size bridge tube Connection Glassware Battery 10 R-AL120 092-VYC3 092-VYC4 Dimensions in mm 16/17 Electrodes Working electrodes To address every application, a wide range of working electrodes (WE) is offered with diameters ranging from 7 µm up to 6 mm and built with different materials. Small type Standard type 15 15 Long type Micro type Gauze type 15 23 70 55 10 55 25 110 3 6 4 35 6 Working electrode maintenance To refresh the surface of the electrode we recommend polishing the electrode after each measurement. Working electrodes maintenance Catalog n° PK-3 electrode polishing kit A-011975 Content 0.05 µm polishing alumina (20 mL) 1 µm polishing diamond (10 mL) Glass plate (1 piece) Alumina polishing pad (10 pieces) Diamond polishing pad (10 pieces) A-001050 A-002054 A-002249 - Spare parts Alumina polishing pad (20 pieces) Diamond polishing pad (20 pieces) Emery paper UF800 (20 pieces) Coarse polishing pad (20 pieces) 6 µm polishing diamond (10 mL) A-001040 A-001041 A-012611 A-001042 A-002053 Dimensions in mm Analytical pH =0 pH = 7 cell Platinum 1 M HCIO4 0.1 m kci standard PFCE carbon electrode Platinum small PFCE carbon electrode platinum gauze electrode long platinum electrode standard platinum electrode small platinum electrode micro platinum electrode Gold gold gauze electrode long gold electrode standard gold electrode small gold electrode micro gold electrode Silver standard silver electrode Copper small silver electrode standard palladium electrode small palladium electrode standard nickel electrode micro nickel electrode standard copper electrode Iron micro copper electrode standard iron electrode Palladium Nickel Carbon paste standard carbon paste electrode hole depth 4 mm small carbon paste electrode hole depth 4 mm CPO carbon paste oil base 1 g ELECTROCHEMISTRY accessories Electrodes Rotating basal plane edge plane electrodes standard pyrolytic graphite electrode electrochemistry micro carbon fiber electrode Spectro- small glassy carbon electrode crystal analyzer A-012744 A-002417 A-002012 A-012297 A-002411 A-012298 A-002412 A-002002 A-002007 A-002252 A-002253 A-002408 A-002409 A-011854 A-002250 A-012745 A-002420 A-002422 A-002013 A-002313 A-002009 A-002003 A-002015 A-002005 A-002251 A-012746 A-002418 A-002421 A-002014 A-002314 A-002010 A-002004 A-002006 A-002416 A-002419 A-002011 A-002315 A-002019 A-002319 A-002016 A-002273 A-002017 A-012584 A-002271 A-002018 A-012585 A-002210 A-002223 A-001010 Quartz Catalog n° 3 mm 5 mm 3 mm 1.6 mm 1 mm 1.6 mm 1 mm 33 µm 7 µm 3 mm 3 mm 3 mm 1 mm 1 mm 25 x 35 mm 3 mm 5 mm 3 mm 1.6 mm 1.6 mm 100 µm 25 µm 15 µm 10 µm 25 x 35 mm 3 mm 5 mm 3 mm 1.6 mm 1.6 mm 100 µm 25 µm 10 µm 5 mm 3 mm 1.6 mm 1.6 mm 1.6 mm 1.6 mm 1.5 mm 100 µm 1.6 mm 3 mm 25 µm 1.5 mm 3 mm 3 mm 1.6 mm accessories Electrode size ±4% 6 mm 10 mm 6 mm 6 mm 6 mm 3 mm 3 mm 4 mm 4 mm 6 mm 6 mm 6 mm 6 mm 3 mm 80 mesh 6 mm 10 mm 6 mm 6 mm 3 mm 4 mm 4 mm 4 mm 4 mm 100 mesh 6 mm 10 mm 6 mm 6 mm 3 mm 4 mm 4 mm 4 mm 10 mm 6 mm 6 mm 3 mm 6 mm 3 mm 6 mm 4 mm 6 mm 6 mm 4 mm 6 mm 6 mm 6 mm 3 mm Battery OD PEEK PEEK PEEK PEEK PEEK PEEK PEEK glass glass PEEK PEEK PEEK PEEK PEEK PEEK PEEK PEEK PEEK PEEK PEEK glass glass glass glass PEEK PEEK PEEK PEEK PEEK PEEK glass glass glass PEEK PEEK PEEK PEEK PEEK PEEK PEEK glass PEEK PEEK glass PEEK PEEK PEEK PEEK long glassy carbon electrode standard glassy carbon electrode cell Isolation Carbon Fuel Working electrodes Glassware 3 accessories -3 -2 -1 0 1 2 Electroactivity window of the working electrodes in different media cell V vs SCE Connection Carbon Corrosion pH = 14 TBAP/ACN TBAP/DMF 18/19 Electrodes Small size reference electrodes for aqueous media (Ag/AgCl, Hg) Reference electrodes are divided into two groups according to the media in which the electrode is immersed (aqueous or organic media). RE-1B RE-1S RE-1C RE-2B RE-2C 50 RE-3V RE-6A 40.5 45 40 80 11 2.8 45 50 2.8 6 Ag/AgCl ink Small size reference electrode for aqueous media (Ag/AgCl, Hg) Junction Electrolyte Purpose Catalog n° RE-1B silver, silver chloride reference electrode(1) vycor glass 3 M NaCl A-012167 RE-1S silver, silver chloride reference electrode RE-1C silver, silver chloride reference electrode vycor glass ceramic 3 M NaCl saturated KCl RE-3V silver, silver chloride reference electrode screw type, poly acetal resin RE-3VP Ag/AgCl screw type electrode, PEEK resin Ag/AgCl ink, 2 mL vycor glass 3 M NaCl vycor glass 3 M NaCl SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell SECM SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell for flow cell spectroelectrochemcial cell SEC-3F for flow cell spectro electrochemcial cell SEC-3F for micro CV cell, IDA measurment SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell A-002056 (1) RE-2B calomel reference electrode RE-2C Hg2SO4 reference electrode, free from chloride RE-6A Hg/HgO reference electrode main body in polyacetal resin RHE Reversible Hydrogen Electrode kit Maintenance of Vycor-based reference electrode - surface resistance: 0.2 Ω/sq/25.4 µm - viscosity: 50,000 ±10,000 CP @21.1 °C - flash point: 82 °C ceramic saturated KCl A-012168 A-002058 A-012169 A-012170 A-011464 A-002057 ceramic saturated K2SO4 ceramic 1M NaOH for alkaline media A-012974 vycor glass HCl or H2SO4 for acidic media (pH < 2) A-013373 Spare parts (1) Set of 10 porous 2.8 mm glass frit (CoralPor™) with PTFE heat shrink (200 mm) 092-VYC3 Options RE-PV preservative vial for reference electrode, 10 mL Bridge tube Ø 9.0 mm (2 pieces) Bridge tube Ø 9.0 mm (22 pieces) Double junction chamber kit for RHE A- 012108 A-012177 A-012307 A-013375 Store your reference electrode immersed in the electrolyte When it is not in use, the recommended way to maintain the reference electrode capability and lifetime is to keep it in a sealed preservative vial with solution. This storage solution should be identical to the filling solution of the reference electrode. Prevent contamination To prevent contamination of the reference electrode, a sample holder can be used. Replace the vycor when needed Yellowish discoloration indicates contamination. This is caused by the adsorption of organic compounds into the pores. cell Analytical Corrosion Small size reference electrodes RE-7S 10 10 20 RE-7V RE-7VP 5.5 5.5 Glassware RE-7 cell for non aqueous media (Ag/Ag+) 20 35 30 35 30 23 11 11 Electrodes 44 Electrolyte solution Electrolyte solution Electrolyte solution Rotating Electrolyte solution electrodes 68 Catalog n° CV SECM flow cell flow cell A-012171 A-012172 A-012173 A-012174 Spare parts Electrolyte solution (10 mL) PTFE cap with Ag wire (for RE-7) PTFE cap with Ag wire (for RE-7S) Sample holder 6 mm diameter (for RE-7) (2 pieces) (1) Set of 10 porous 2.8 mm glass frit (CoralPor) with PTFE heat shrink (200 mm) A-012549 A-012057 A-012058 A-012176 092-VYC3 Options RE-PV preservative vial for reference electrode, 10 mL Bridge tube Ø 9.0 mm (2 pieces) Bridge tube Ø 9.0 mm (22 pieces) A- 012108 A-012177 A-012307 * Acetonitrile ** Tetra Butyl Ammonium Perchlorate accessories Hg/HgO/ NaOH (0.1 M) Hg/Hg2SO4 / K2SO4 (sat) Fc/Fc+ TBAP (0.1M) ACN Ag/Ag+ TBAP (0.1M) ACN Hg/Hg2Cl2 KCl (sat) Hg/Hg2Cl2 NaCl (sat) Ag/AgCl/ KCl (3.5 M) Ag/AgCl/ KCl (sat) Ag/AgCl/ NaCl( sat) NHE Normal Hydrogen Electrode cell 0.930 V 0.650 V 0.624 V 0.542 V 0.241 V 0.236 V 0.205 V 0.197 V 0.194 V 0.000 V Fuel 65 accessories A-012108 Battery To avoid electrolyte leakage or concentration due to evaporation during storage or transport, the electrolyte is separated from the body. This gives the possibility to fill it regularly. A-012177 Spectro- Purpose Ag/Ag+/ACN*/TBAP** Ag/Ag+/ACN*/TBAP** Ag/Ag+/ACN*/TBAP** Ag/Ag+/ACN*/TBAP** crystal analyzer Electrolyte vycor glass vycor glass vycor glass vycor glass Quartz Junction Connection RE-7 non aqueous reference electrode (Ag/Ag+)(1) RE-7S non aqueous reference electrode (Ag/Ag+)(1) RE-7V non aqueous reference electrode (Ag/Ag+) screw type, poly acetal resin RE-7VP non aqueous reference electrode (Ag/Ag+) screw type, PEEK resin electrochemistry Small size reference electrode for non aqueous media (Ag/Ag+) E/V vs NHE at 25 °C 9 Dimensions in mm ELECTROCHEMISTRY accessories 20/21 Electrodes King size reference electrodes R-REF621 R-XR110 R-XR200 R-XR300 R-XR400 R-XR820 m eas 120 Connection type Junction Length OD Catalog n° banana cable banana cable screw cap(1) banana cable screw cap(1) screw cap(1) ceramic ceramic ceramic ceramic ceramic ceramic 103 mm 103 mm 103 mm 103 mm 103 mm 103 mm 7.5 mm 12 mm 8 mm 7.5 mm 8 mm 8 mm R-REF201 R-REF251 R-REF421 R-REF601 R-REF621 R-REF921 screw cap(1) screw cap(1) screw cap(1) screw cap(1) screw cap(1) screw cap(1) screw cap(1) ceramic ceramic ceramic ceramic ceramic ceramic ceramic 120 mm 120 mm 120 mm 120 mm 120 mm 120 mm 160 mm 8 mm 8 mm 8 mm 8 mm 8 mm 8 mm 8 mm R-XR110 R-XR150 R-XR200 R-XR300 R-XR400 R-XR440 R-XR820 banana plug of 2 mm banana plug of 2 mm banana plug of 4 mm ceramic ceramic ceramic 1m 100 mm 1m 70 mm 138 mm 250 mm 138 mm Options (1) Cable connection for screw cap electrode, recommended to connect these references electrodes to the Bio-Logic instruments Salt bridge -Im(Z)/Ohm 3,000 Salt bridge with reverse sleeve, non aqueous Conical rings for 8 mm OD 12 mm electrodes (4 pieces) 0 0 2,000 Re(Z)/Ohm 4,000 160 Red rod reference electrode Calomel reference electrode non aqueous (LiCl) for general purpose Calomel reference electrode in KCl sat for CV, straight Calomel reference electrode in KCl sat for CV, curved Hg/HgSO4 reference electrode in sat K2SO4 for CV Ag/AgCl reference electrode Sat KCl for CV Hg/HgO reference electrode in 0.1 M KOH for CV Hg/HgO reference electrode in 1 M KOH with fiber rod Ag/AgCl reference electrode for EIS 1,000 u re m King size reference electrodes Hg/HgSO4 reference electrode in sat. K2SO4, chloride free 2,000 en t EIS 12 mm 8 mm 8 mm 8 mm R-CRI9439 R-A94L111 R-CL111 R-AL100 R-AL120 R-AL110 R-AL210 R-X31M012 cell Analytical A-002233 A-002234 A-002250 R-XM110 R-XM120 R-XM140 R-XM150 cell A-002222 Metallic electrodes Corrosion Counter electrodes Glassware 23 10 25 50 Electrodes 35 120 A-012198 A-002254 Wire Ø Surf. area Purpose Catalog n° 57 mm 0.5 mm ~ 0.7 cm2 A-002222 0.5 mm 0.5 mm 0.5 mm 0.5 mm 1.5 mm 0.08 mm 0.08 mm 0.07 mm 0.12 mm ~ 0.7 cm2 ~ 3.6 cm2 ~ 3.6 cm2 ~ 3.6 cm2 ~ 2.35 cm2 ~ 1 cm2 ~ 1 cm2 ~ 1 cm2 ~ 5.1 cm2 SVC-2, VC-4, plate material evaluating cell SVC-3 RRDE-3A, bulk electrolysis, SVC-3 RRDE-3A, bulk electrolysis, SVC-3 RRDE-3A, bulk electrolysis, SVC-3 flow cell Wire dimension Catalog n° 8 mm 8 mm 8 mm 12 mm 8 mm Ø 1 mm plate 5 x 5 mm plate 8 x 8 mm disk of 10 mm rod Ø of 3 mm R-XM110 R-XM120 R-XM140 R-XM150 R-M291C Glassy carbon(1) Options (1) Cable connection for screw cap electrode, recommended to connect these references electrodes to the Bio-Logic instruments Quartz R-CRI9439 R-A94L111 R-CL111 R-X31M012 accessories Conical rings for 8 mm OD 12 mm electrodes (4 pieces) 1 m, banana plug of 2 mm 100 mm, banana plug of 2 mm 1 m, banana plug of 4 mm accessories OD 80 mm 120 mm 120 mm 120 mm 103 mm Battery Length Platinum(1) cell Metallic electrodes Fuel flat cell A-002233 A-002234 A-012638 A-012639 A-012198 A-002250 A-702439 A-002251 A-002254 Connection 50 mm 230 mm Gold 230 mm Nickel 230 mm Stainless steel 50 mm Platinum gauze electrode, PEEK 80 mesh 25 x 35 mm Platinum gauze electrode, platinum wire of 51 mm 25 x 35 mm Gold gauze electrode, PEEK 100 mesh 25 x 35 mm 55 mesh 40 x 50 mm Spectro- Length Platinum crystal analyzer Counter electrodes electrochemistry electrodes Rotating 100 Dimensions in mm ELECTROCHEMISTRY accessories 22/23 Rotating electrodes Rotating Ring Disk Electrode (RRDE) RRDE-3A is a system that can be used to perform hydrodynamic (RDE or RRDE) measurement. Its design (short stainless steel shaft) allows the users to control accurately the electrode rotation and the modulation. RRDE-3A is electronically controlled by a closed loop circuit driving a DC servo-motor. Electrodes are small and rapidly interchangeable. The unit also provides an adjustable valve system for inert gas purging inside the cell vial. Additionally, the access to glass cell is easy for rinsing, cleaning, and replacing the electrodes. It is easy to remove and replace the cell vial. RRDE-3A is able to be operated as a stand-alone unit or directly controlled by Bio-Logic electrochemical workstation. Features - Remote- and manual-controlled rotation - Small sample volume (up to 10 - 15 mL), gas line connector is available, remote and manual controlled purge lines - Open architecture for easy access to cell Specifications Rotational range Setting resolution Accuracy Rotation control type Bandwidth 100 - 8,000 rpm 1 rpm < 0.1% PLL (phase-locked loop) 60 Hz at 3,500 rpm base and 1,000 rpm peak-to-peak modulation Inlet gas pressure 5 PSI Temperature 10-50 °C Power 100-240 VAC, 50/60 Hz Dimensions (W x D x H) 185 x (base: 230, body: 120) x 400 mm Weight 6 kg Rotating Ring Disk Electrode Catalog n° RRDE-3A apparatus A-012180 Working electrodes (page 25), reference electrodes (page 20) and counter electrodes (page 23) have to be purchased separately. Content RRDE-3A glass cell vial 100 mL Spin coating adapter Nipple for purge valve Tygon tubing, OD 6.4 mm x ID 3.2 mm (1.3 m) PTFE cap for RRDE-3A Instruction manual Power cable Options Water-jacketed glass cell (100 mL, OD 70 mm, ID 46.4 mm, H 80 mm) DB9 cable to control RRDE-3A Bipotentiostat cable for two standard channels Bearing assembly A-012632 A-012064 A-012065 A-010058 A-012631 A-012652 092-22/11 092-22/12 A-012625 cell Analytical cell Corrosion A-011162 A-011163 A-011164 A-011170 A-011171 Glassware A-011172 A-011169 Option PK-3 polishing kit Rotating electrodes electrochemistry crystal analyzer Quartz accessories A-013336 A-013337 A-013338 A-013339 A-013362 A-013338 A-013339 A-013361 A-013364 A-013366 A-013339 A-013361 A-013365 A-013367 A-013339 A-013361 Tool kit Disk electrode polishing and exchanging tool kit A-011172 A-011162 A-011163 A-011164 A-012617 A-012618 A-011169 A-011170 A-011171 A-011966 A-011967 A-011968 A-011969 A-011970 A-011971 A-011972 A-011973 Battery Catalog n° RRDE RDE Catalog n° 4.0 mm 4.0 mm 4.0 mm 4.0 mm 4.0 mm 4.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 3.0 mm 5.0 mm 5.0 mm 5.0 mm 5.0 mm 5.0 mm 5.0 mm - A-011975 Disk Replaceable Electrode tips platinum ring/GC disk replaceable electrode kit content platinum ring assembly glassy carbon disk PTFE spacer (3 pieces) glassy carbon disk replaceable electrode kit content glassy carbon disk PTFE spacer (3 pieces) disk assembly gold disk replaceable electrode kit content gold disk PTFE spacer (3 pieces) disk assembly platinum disk replaceable electrode kit content platinum disk PTFE spacer (3 pieces) disk assembly Disk Ø 7.0 mm 7.0 mm 7.0 mm 7.0 mm 7.0 mm 7.0 mm - 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm RRDE platinum ring/GC disk replaceable electrode kit cell Disk electrode Ø 3 mm RDE Ø 12 mm Ring OD 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm 25 mm Fuel RDE Tips length Tips OD Ring ID A-013340 accessories Disk electrode Ø 4 mm Ring electrode Ø 7 mm RRDE Ø 12 mm platinum ring/platinum disk platinum ring/glassy carbon disk gold ring/glassy carbon disk platinum ring/gold disk gold ring/platinum disk glassy carbon ring/glassy carbon disk glassy carbon disk platinum disk gold disk aluminum disk silver disk copper disk nickel disk tantalum disk titanium disk tungsten disk carbon paste disk, hole depth 4 mm Connection RRDE Spectro- Standard tips Electrodes Working electrode Disk electrode polishing and exchanging tool kit ELECTROCHEMISTRY accessories 24/25 Rotating electrodes Rotating Disk Electrode (RDE) Rotating Disk Electrode Catalog n° Rotating Disk Electrode system including control unit and electrode rotator R-RDE/EDI Content CTV101, controlling unit for EDI101 EDI101 RDE without tip (10-5,000 tr/min) R-R21V035 R-A35T040 The CTV101 speed control unit controls the EDI101 rotation speed. It offers accuracy better than ±0.1% for precise and fully reproducible experimental conditions. The measured rotation speed is clearly displayed on a four-digit LCD. The speed control unit can be directly driven from a Bio-Logic potentiostat/galvanostat. You can program the variation of the rotation speed from one method to another method and achieve a “Levich” type experiment all in one go. Options BEC/EDI electrochemical cell with glassware and electrodes glassy carbon Ø 3 mm EDI tip glassy carbon Ø 5 mm platinum Ø 2 mm platinum Ø 5 mm gold Ø 2 mm gold Ø 5 mm copper Ø 5 mm graphite Ø 4 mm silver Ø 5 mm nickel Ø 5 mm without any material stainless steel Ø 5 mm sample holder Ø 11 mm platinum, L 40 mm Ø 5 mm gold, L 40 mm Ø 4 mm Adapter EDI (banana 4 mm female, banana 2 mm male) R-XR51V001 R-A35T090 R-A35T095 R-A35T100 R-A35T105 R-A35T110 R-A35T120 R-A35T130 R-A35T140 R-A35T150 R-A35T160 R-A35T402 R-A35T420 R-A35T450 R-A35T452 R-A35T456 R-X41V001 This RDE can be used with the EL-ELECTRO-1, EL-ELECTRO-2 or EL-ELECTRO-3 kit. Specifications Rotational range Accuracy Eccentricity Setting resolution Material of EDI101 Gas inlet for brush contact purging Temperature Power Consommation Dimensions Weight 100 - 5,000 rpm < 0.1% < ±0.1 mm 1 rpm KeI-F Ø 2 mm 5 - 40 °C 230 Vac, 47.5 - 63 Hz 12 VA CTV101: 80 x 240 x 230 mm (W x D x H), EDI101: 255 mm (length) CTV101: 1.5 kg EDI101: 0.3 kg I/µA The EDI101 is a versatile and rugged rotating disk electrode ideal for use with any Bio-Logic potentiostat/galvanostat. It is available with a wide choice of quick-fit exchangeable tips in standard or custom materials: platinum, glassy carbon, gold... Thanks to its conic shaft holder, the EDI101 can be used with a wide range of cells. 700 600 500 400 300 200 100 0 0 0,2 0,4 Ewe/V 0,6 0,8 1 Analytical Rotating electrodes For RRDE measurement, a bipotentiostat is needed. A bipotentiostat controls the two working electrodes i.e. one channel to control the disk electrode and the other to control the ring. An SP-300 equipped with two channels would be an appropriate instrument for RRDE applications. ) 3/2 An example of the Levich analysis is performed on a 5.5 mM Potassium Hexacyanoferrate (III), in KCl (0.1 M) solution. The working electrode is a glassy carbon disk electrode. The sequence comprised of 13 rotational velocities from 10 rpm to 2000 rpm, and 13 twin-cycle cyclic voltammograms. The resulting CVs are overlaid and presented in the image below. The Levich analysis leads to the diffusion coefficient (D) determination which is D = 6.36 x 10-6 cm²/s. Current/mA 0.88 0.68 0.48 0.28 Rotating C electrodes -1/6 Of these two options, the latter is preferred because the leakage current is less. All of the Bio-Logic multichannel potentiostats (except cyclers) offer such electrode connection type. electrochemistry ( 0.62 n FmA v Spectro- D= Because of the presence of two working electrodes in the same setup, a specific connection mode (to avoid any ground loop trouble) is needed. This can be achieved in two different ways: - isolating the two channels (at least one potentiostat in floating mode), - grounding the counter electrode. The “CE-to-ground” mode of the Bio-Logic instruments provides this unique capability. At the disk electrode, the electro-active species are oxidized or reduced according to the applied potential. This new species is detected by reduction or oxidation at the ring, respectively. In a typical experiment, a CV is performed on the disk electrode and a constant voltage is applied on the ring electrode. It is the CV-CA technique that is available in EC-Lab® in the “bipotentiostat” techniques folder. crystal analyzer Where: - ω is the rotational velocity (radian per second), - n electrons involved within the reaction (dimensionless), - F is the Faraday constant (F = 96,485 C/mol), - A is the disk area (cm²), - D is the diffusion coefficient (cm²/s), - v is the kinematic viscosity (cm²/s), - C is the electroactive species concentration (mol/cm3). Quartz IL = ±0.62 n F A D2/3 ω1/2 v-1/6 C cell A 20th century electro-chemist, Dr. Levich proposed the relationship between the voltammetry limiting current (IL, A) of a rotating disk electrode and the physical parameters as follows: Glassware RRDE Electrodes RDE Corrosion cell applications accessories 7.57 ω⁄s-1/2 14.1 accessories Connection cell Fuel 1 Battery 0.08 ELECTROCHEMISTRY accessories 26/27 Spectroelectrochemistry Spectrometer Utilization modes Spectroelectrochemistry (SEC) can be useful to elucidate electrochemical reaction mechanisms. The spectroelectrochemical kit is composed of three parts (spectrometer, light source and cuvette holder). Transmittance The spectrometer is equipped with a trigger to synchronize electrochemical and spectroscopic measurements. Reflectance Absorbance/ - Concentration of chemicals (solution) transmittance - Polymer extrusion processes - DNA quantification - Freshness testing - Film thickness/composition (quality control) - Activation energy of photocatalytic species - Textile quality control Fluorescence Fluorescence - Marine organisms - Biology (DNA, protein, cell proliferation assay, histamine-analysis, alga monitoring) - Environmental fields (waste water analysis, ground water trace studies, hydrocarbon detection, dissolved oxygen) - Plant efficiency (plant physiology, plant breeding, horticulture, agronomy, agrochemicals, pollution studies, forestry, ecology) - Tissue diagnosis Scattering - Oil concentrations of oil/water system - Raman spectroscopy - Physical transition phenomena (e.g, melting point, glasstransition crystallize temperature) Irradiance Emission Spectrometer combo kit type Content Spectrometer Light source Cuvette holder 30 sec 60 sec 90 sec 120 sec 150 sec 180 sec 210 sec 240 sec 270 sec Absorbance 0,2 0 -0,2 300 400 Wavelenght 500 - Astronomy (e.g, spectra of Hale-Bopp, plasma monitoring) - In situmetal monitoring - Luminescence (PL,EL), LED & laser wavelength SEC2000-UV/VIS Catalog n° SEC2000-VIS/NIR Catalog n° SEC2000-UV/VIS A-012838 SEC2000-VIS/NIR A-012973 SEC2000-UV/VIS SEC2000-DH UV SEC2000-CUV A-012856 A-012193 A-012195 SEC2000-VIS/NIR SEC2000-TH visible SEC2000-CUV with diffusion plate A-012971 A-012194 A-012244 Option Connecting cable to synchronize the spectrometer and the Bio-Logic potentiostat 092-22/11 cell Analytical X-ray Ultraviolet ray Infrared Ultraviolet ray (UV) 100 (UV-C) 200 nm UV-B 280 nm Millimeter Meter Microwaves Radio waves Visible light Infrared (IR) UV-A 315 nm Kilometer Near IR 400 nm 700 nm 1,400 nm IR cell Gamma ray Micrometer Corrosion Nanometer Far IR 3,000 nm Glassware Picometer 10,000 nm Electromagnetic spectrum 2,048 pixels CCD array 500 - 1,000 nm blazed at 750 nm 1.8 ±0.2 nm: slit 50 µm x 1,000 µm (standard) (1) < 1% at a Abs < 2 mAbs 14 bit SMA905 USB 2.0 WindowsTM XP 98 x 118 x 35 mm A-012971 Rotating SEC2000-VIS/NIR combo kit electrodes SEC2000-UV/VIS combo kit 2,048 pixels CCD array 220 - 800 nm blazed at 400 nm 1.8 ±0.2 nm: slit 50 µm x 1,000 µm (standard) (1) < 1% at a Abs < 2 mAbs 14 bit SMA905 USB 2.0 WindowsTM XP 98 x 118 x 35 mm A-012856 electrochemistry Detector Wave length range Grating Resolution Accuracy Dark noise A/D resolution Optical entrance Interface Operating system Dimensions (W x D x H) Catalog n° Electrodes Spectrometer Spectro- (1). Slit could be selected from: 10, 25, 100, 200 μm. Spare parts Bulb 200 - 1,100 nm 200 - 400 nm < 5 x 10-8 W/nmsr 1 x 10-3 AU < 0.25%/h > 1,000 h > 2,000 h 360 - 2,000 nm - SMA905 included 98 x 118 x 35 mm A-012193 SMA905 not included 98 x 118 x 35 mm A-012194 A-012221 (UV bulb) A-012222 (TV bulb) Quartz SEC2000-TH Light source (tungsten halogen) 1,500 h accessories Battery Spectral range (Halogen + D2) D2 lamp spectral range power consumption (240 nm) stability drift bulb life(2) Halogen bulb life lamp Connector Dimensions (W x D x H) Catalog n° light source SEC2000-DH Light source (deuterium & tungsten halogen) crystal analyzer Light source cell Fuel (2). Value for less than 50% power consumption of 240 nm. ELECTROCHEMISTRY accessories SEC2000-UV/VIS combo kit SEC2000-VIS/NIR combo kit A-012195 A-012244 accessories Catalog n° Connection Cuvette holder 28/29 Spectroelectrochemistry Static experiment 45 40 39 100 13 6 A-012904 A-012907 Platinum Quartz glass spectroelectrochemical cell kit 0.5 mm Content platinum counter electrode thin layer quartz glass cell PTFE cap purging tube (ETFE, 100 mm) gauze working electrode 80 mesh, height 5 mm 1 mm Content platinum counter electrode thin layer quartz glass cell PTFE cap purging tube (ETFE, 100 mm) gauze working electrode 80 mesh, height 6 mm Options RE-1B Ag/AgCl reference electrode RE-7 non aqueous reference electrode Purging tube (ETFE), 1 m UA 0.5 0.1 0 .1 0 0 0 0 70 60 0 4 0 (nm) 65 ngth 55 50 40 0 30 8 45 35 0 0 -0 6 Catalog n° A-012906 Gold A-011501 A-012814 A-012609 A-012815 A-011501 A-012606 A-012609 A-012815 A-011501 A-012607 A-012904 A-012906 A-012907 A-011501 A-011498 100 mesh, height 5 mm 100 mesh, height 6 mm 10 12 14 16 Purging tube Catalog n° A-012813 5.5 mm 0.5 mm 5 mm A-012905 A-012906 A-012907 A-011501 A-012017 A-012167 A-012171 A-010537 0.4 0.3 0.2 Wave le A-011498 6.5 mm 1 mm 6 mm cell Analytical Glassware cell Corrosion Options Reference Ø 10 x 55 mm electrode screw type A-012169 A-012170 A-012173 A-012174 A-012655 A-012656 A-012657 A-012658 A-011465 A-010887 A-011233 A-011827 A-012661 A-012664 A-012665 A-012666 A-012667 A-011522 A-012234 electrodes Rotating Outlet Inlet Gold grid electrode A-012656 Solution volumes Gasket of 100 µm 250 µm 500 µm Volume 4.6 µl 11.5 µl 230 µl accessories Connection cell Fuel RE-3V aqueous RE-3VP aqueous (PEEK) RE-7V non aqueous RE-7VP non aqueous (PEEK) Working 8 x 27 x 1 mm platinum (1 piece) grid gold (1 piece) electrode carbon grid electrode (1 piece) for flow ITO electrode (4 pieces) cell 8 x 27 x 0.5 mm ITO electrode (12 pieces) 10 x 20 x 0.5 mm ITO electrode (10 pieces) 10 x 10 x 0.5 mm ITO electrode (30 pieces) Ø 4 inch x 0.5 mm ITO electrode (1 piece) Gasket silicone S500, 500 µm thick (4 pieces) PTFE T500, 500 µm thick (4 pieces) T250, 250 µm thick (4 pieces) T100, 100 µm thick (4 pieces) Fibre and lens 400 m optical fibre SR, 250 mm 400 µm optical fibre SR, 2 m UV/VIS collimating lens, 200-2,000 nm A-012661 A-012198 - electrochemistry SEC-2F S500 silicone gasket Stainless tube OD 1.59 mm (length of 50 mm) Needle adaptor Dynaseal PEEK fingertight Silicon tube (300 mm) PTFE tube (1 m) 1 1 1 1 2 1 1 2 1 1 Spectro- base cover block A block B Working electrode Silicone gasket 500 µm Counter electrode Collimating Lens Reference electrode crystal analyzer A-012660 Quartz Content SEC-2F flow cell Catalog n° accessories Quantity SEC-2F spectroelectrochemical flow cell Battery Flow experiment Electrodes Flow experiment ELECTROCHEMISTRY accessories 30/31 Spectroelectrochemistry Thin layer spectroelectrochemical cell UF-Full The UFS set is conceived to perform thin-layer spectroelectrochemistry. Spacer Thin layer spectroelectrochemical cell kit Catalog n° Full kit UF-Full Pseudo-reference electrode Content 1 PTFE windows aligner + 1 spacer (platinum or gold working electrode/platinum auxiliary electrode/ Ag pseudo-reference electrode) Stainless steel body cell XY holder (with magnets) to universally fit the cell in a spectrophotometer Plug PTFE mask Working electrode Auxiliary electrode Full kit + PTFE adapter for optical fibres + optical fibre Options PTFE adapter for optical fibres with UV/VIS/NIR collimating lenses (200-2500 nm), adjustable focus, SMA-905 connection Base stand for optical fibres measurements PTFE cuvette holder to be used with UF-OFA and UF-BS 1 spacer (platinum working electrode/platinum auxiliary electrode/Ag pseudo-reference electrode) 1 spacer (gold working electrode/platinum auxiliary electrode/Ag pseudo-reference electrode) Optical fibre: SMA-SMA connector length 1 m UF-SEC UF-XY UF-P UF-M UF-OFA UF-BS UF-C UF-SPP UF-SPA 092-101 Analytical Spectroelectrochemistry cell applications Ferrocene in CH2Cl2/NBu4PF4 (0.2 M) Scan rate: 5 mV/s cell Glassware Electrodes Due to the high Infra-Red absorbance of more common solvents and electrolytes, a very carefully measured background should be obtained before each Infra-Red spectroelectrochemical experiment. 400 electrodes Rotating For the same reason, it is also important to avoid changing the tightness of the cell screws during the experiment itself to avoid changes of the optical path. Starting potential : 150 mV Step of 50 mV electrochemistry A cyclic voltammetry should be registered in your SEC cell to better localize the redox process of interest: in fact, the UF spacer has an silver pseudo-reference electrode, which is sensitive to the solution medium (but is expected to remain constant in time in each given experimental condition). Potential drifts can be observed in the presence of irreversible redox reactions, which may alter the solution/analyte composition. A milli-molar concentration appears to be the most optimized concentration, but in some cases, the concentration can be adapted. Spectro- Small potential sweep rates (2-10 mV/s) are necessary both to ensure homogeneity of the reactant/product concentrations in the cell and to control the resistive effects. To maintain the ohmic drop as low as possible, the current should also be kept low which means low scan rates and low sample concentrations may be preferred. However, in some cases, due to the narrowness of the optical path, the use of a relatively high concentration of the sample may be required to study the changes of bands with a low molar extinction coefficient. 300 ε/cm-1.M-1 In such finite diffusion conditions, a thin solution layer (≤ 0.2 mm) adjacent to the electrode is confined by the cell walls, so that the cell thickness is smaller than the diffusion layer and the mass transfer can be ignored. The most significant virtue of thin-layer cells is the absence of the effect of the diffusion process and the rapidity with which the electro-active species can be exhaustively electrolyzed. The dropping to near zero of the current flow following the peak in the current potential plot is a characteristic behavior of thin-layer cells, indicating exhaustive electrolysis of the cell reactant and minimal diffusion effects in thin-layer electrochemical cells(1) (2). Corrosion Finite diffusion conditions 200 Quartz crystal analyzer 100 80 0 400 0 800 λ/nm 1,200 (1): M. Krejčik, M. Danĕk and F. Hartl, J. Electroanal. Chem., 1991, 317, 179. (2): P. Leoni, F. Marchetti, C. Bonaccorsi, F. Fabrizi de Biani, L. Marchetti, P. Zanello, Chem. Eur. J.,2008, 14, 847 accessories -40 Battery I/mA 40 -80 0 0.2 0.4 0.6 accessories Connection cell Fuel Ewe/V ELECTROCHEMISTRY accessories 32/33 Quartz crystal analyzer 092-QCA-FC EQCM The instrument monitors both the resonant frequency and the resonant resistance which are also reflected on the two analog outputs. It is possible to connect the Quartz Crystal Analyzer (QCA922) to a Bio-Logic potentiostat using a DB9-8BNC cable (catalog n°: 092-22/1). SE-CL3 EQCM Catalog n° Quartz crystal microbalance 9 MHz kit SE-QCA922B Content EQCM 9 MHz (or 5 MHz) main unit Adapter cable Male BNC/BNC cable (2 pieces, length 1 m) SE-QCA922-00 SE-QCA922-10 COR28100 Options Holder is needed to get a full QCM or EQCM set-up static and flow QCA cell dip cell well cell (PTFE) well cell (PEEK) transparent well cell flow cell (90 µL) (PTFE) flow cell (90 µL) transparent (PTFE) flow cell (90 µL) (PEEK) Connector from QCA to potentiostat Low flow peristaltic pump EQCM specifications Frequency range Resonant resistance range ∆F output Resistance output Gate time Display Interface Dimensions (W x D x H) Weight Temperature Power consumption 0.8 0.6 <I>/mA 0.4 0.2 0 -0.2 0 0.5 Ewe/V 1 1 MHz-10 MHz, resolution 0.1 Hz 10-16 Ω, resolution 0.1 Ω full scale: ±10 V (12 bit) ±200 Hz / ±2 kHz / ±20 kHz / ±200 kHz full scale: 0-10 V (11 bit) 1 / 2 / 4 / 8 / 16 kΩ variable (0.1, 1.0, 10.0 s) 40 digits x 2 rows IEEE-488, RS-232C 260 x 230 x 88 mm 3.3 kg 0 - 40 °C 100-120 V AC, 230-240 V AC, 50-60 Hz, (15 W) 092-QCA-FC SE-CL3 SE-CL4 SE-CL4PK SE-CL5 SE-CL6 SE-CL7 SE-CL6PK 092-22/1 EL-AV-008 mirror finish resonator and lead wire separated lead wire Others Resonators lead wire no sputter (50 pieces) Resonators 9 MHz, no sputter no lead wire (50 pieces) mirror finish no lead wire (50 pieces) cell cell Corrosion Glassware separated lead wire Platinum electrode Electrodes resonator and lead wire Stainless steel electrode Rotating standard finish Gold electrode SE-LEAD/2 SE-9Q/2 SE-9Q-M/2 crystal analyzer polish finish electrodes SE-5AU SE-9AU-E/1 SE-9AU-E/3 SE-9AU-P/1 SE-9AU-P/3 SE-9SI SE-9AL SE-9AU SE-9C SE-9CU SE-9MO SE-9NI SE-9PT SE-9SS SE-9SU SE-9SOS SE-9AU-S SE-9PT-S SE-9SOS-S SE-9SU-M SE-9AL-M SE-9AU-M SE-9AU-M2 SE-9C-M SE-9CU-M SE-9IT-M SE-9SOS-M SE-9NI-M SE-9PT-M SE-9SI-M SE-9SS-M SE-9TI-M SE-9AU-MS SE-9IT-MS SE-9PT-MS SE-9SOS-MS etching finish gold electrode (25 pieces) gold electrode (30 pieces) gold electrode (100 pieces) gold electrode (30 pieces) gold electrode (100 pieces) silicon electrode (25 pieces) aluminum electrode (25 pieces) gold electrode (25 pieces) graphite electrode (25 pieces) cupper electrode (25 pieces) molybdenum electrode (25 pieces) nickel electrode (25 pieces) platinum electrode (25 pieces) stainless steel (SUS304) electrode (25 pieces) stainless steel (SUS316L) electrode (25 pieces) SiO2 for solution measurement (25 pieces) gold electrode (25 pieces) platinum electrode (25 pieces) SiO2 for solution measurement (25 pieces) stainless steel (SUS316L) electrode (25 pieces) aluminum electrode (25 pieces) gold electrode (25 pieces) gold electrode (500 pieces) graphite electrode (25 pieces) copper electrode (25 pieces) ITO electrode (25 pieces) SiO2 for solution measurement (25 pieces) nickel electrode (25 pieces) platinum electrode (25 pieces) silicon electrode (25 pieces) stainless steel (SUS304) electrode (25 pieces) titanium electrode (25 pieces) gold electrode (25 pieces) ITO electrode (25 pieces) platinum electrode (25 pieces) SiO2 for solution measurement (25 pieces) electrochemistry Catalog n° 5 MHz 9 MHz Spectro- Quartz resonator (calibration at 5 MHz at factory with no charge when purchased) Analytical Quartz resonators accessories Electrode materials deposition sputtered vacuum deposition sputtered vacuum deposition Battery Roughness 0.6 µm 0.6 µm 0.06 µm 0.06 µm accessories Connection cell Fuel Standard finish Etching finish Mirror finish Polish finish Quartz Surface finishing ELECTROCHEMISTRY accessories 34/35 Quartz crystal analyzer Biosensor QCM The specification (27 MHz) of the Quartz Crystal Microbalance (QCM934) allows users to measure a small mass change. QCM934 is especially suitable in the bio-sensing field. - Excellent sensitivity and resolution. - Specially designed oscillation circuit for added stability. - Simultaneous measurement of resonant frequency, resonant resistance and temperature. - Expandable up to 4 channels. - Works with flows cell, well cell, dip cell. - Computer control and data collection via USB interface. Flow mode Catalog n° Flow cell kit SE-QCM934-F Content Main unit WinQCM software Oscillator & temperature control module Cable for oscillator & temperature control module Measurement chamber Flow cell (90 µL) Options Additional channel Low flow peristaltic pump Resonators of 9 MHz are compatible with QCM934 and the cell (see page 35). Specifications Frequency range 25 MHz-27 MHz, resolution 0.01 Hz Resonant resistance range 2 Ω, resolution 0.1 Ω Max channel 4 Gate time variable (0.1, 1.0, 10.0 s) Display 20 digits x 2 rows Interface USB 2.0 Dimensions (W x D x H) 320 x 280 x 133 mm Weight 5.5 kg Temperature 10 - 40 °C Power consumption 100-120 V AC, 230-240 V AC, 50-60 Hz, (60 W) SE-QCM934-000 SE-WQCM SE-QCM934-200 SE-QCM934-200A SE-QCM934-500 SE-QCM934-510 SE-QCM934-1CHF EL-AV-008 Oscillator & Temperature Control Module Osc.Status Temp.Status Power QCM934 Quartz Crystal Microbalance “Flow cell-based system of QCM934”, “perista pump” and “notebook computer” Batch mode Catalog n° Batch cell kit SE-QCM934-B Content Main unit WinQCM software Oscillator & temperature control module Cable for oscillator & temperature control module Cable for OSC module connection SE-QCM934-000 SE-WQCM SE-QCM934-200 SE-QCM934-200A Options Additional channel SE-QCM934-300 SE-QCM934-1CHB Dip cell QA - CL3 Oscillator & Temperature Control Module Osc.Status Temp.Status Power QCM934 Quartz Crystal Microbalance Transparent well cell QA -CL5 “Batch cell-based system of QCM934”, “transparent well/dip cell” and “notebook computer” Analytical Quartz crystal analyzer cell applications N R R N N + (2n+2)H+ + (2n+2+np)e- R The quartz electrode was immersed in an acetonitrile solution (Bu4NPF6 0.2 mol.L) containing a solution of 1 methylpyrrol monomer (0.01 mol.L). Polypyrrol film growth on the quartz working electrode Corrosion cell Glassware Electrodes ∆ƒ/kHz electrodes -0.2 300 -1 200 The mass calculation is done automatically in the process data tool of EC-Lab®. More details can be found in the application note(3). -1.4 150 100 -1.8 50 -2.2 0 -2.6 -50 electrochemistry -0.6 250 90 95 100 Time/s 105 Spectro- Fig. 2: graphic zoom on one cycle showing the resonant frequency and the current density versus elapsed time(3). Rotating The interesting point is to follow the frequency evolution versus potential on one cycle. The figure below shows the time evolution on one cycle. 110 -40 120 -60 100 -80 80 -100 60 -120 40 1,000 2,000 Time/s (1): G . Sauerbrey, Phys. Verh., 1957, 8, 113-114. (2): G . Sauerbrey, Z. Phys., 1959, 155, 206-222. (3): A pplication note #13. Section “Apps & literature of EC-Lab division”. accessories Connection Fig. 1 presents the polypyrrol film growth on the quartz electrode during the successive cycles of cyclic voltammetry. The reversibility of the charge transfer in such a polymer film is often dependent on the deposition mode (quasi-reversible in this example). The growth is very regular but tends to slow down in the last cycles. That can be due to an interfacial depletion of the solution in methyl pyrrol species in the layer close to the electrode surface and to a saturation of the working electrode surface area. 0.5 1 Ewe/V vs. Ag/AgCl / KCl (sat’d) crystal analyzer N -12 Quartz (n+2) -200 0 np+ R -10 accessories The polypyrrol film was coated on an Au quartz (used as the working electrode) using cyclic voltammetry (20 cycles). -8 -100 Battery Electropolymerization of pyrrol -6 0 cell ƒ0: resonant frequency (Hz) ∆ƒ: frequency change (Hz) ∆m:mass change (g) A:piezoelectrically active crystal area (area between electrodes, cm²) ρq: density of quartz (ρq = 2.648 g/cm³) µq:shear modulus of quartz for AT-cut crystal (µq = 2.947x1011 g/(cm.s²)) -4 100 Fuel A ρqµq ∆m -2 200 ∆ƒ/kHz 2ƒ02 0 300 ∆ƒ/kHz ∆ƒ = Fig. 1: overlaid frequency and current vs. Ewe of the polymer film growth. Scanning at 100 mV/s between 0 and 1.018 V. ∆m/µg The Sauerbrey equation is defined as: Fig. 1 shows the resonant frequency decrease and the resonant resistance increase while the polymer film is growing. Moreover the variation is dependent on the potential sweep resulting in a pseudo oscillation of frequency and resistance related to the successive cycles. This plot can also be made versus potential (see fig. 1). <I>/mA A mass increase results in a frequency decrease. Sauerbrey was the first who provided a description and experimental verification of the mass/frequency relationship between foreign layers firmly attached to the quartz crystal resonator(1)(2). QCM measurements during the film growth <I>/mA The Quartz crystal microbalance is a mass-sensitive detector based on frequency changes of an oscillating quartz crystal. The oscillation frequency of the crystal is proportional to the mass of the crystal, as well as solution properties near the surface (including viscosity, density, temperature, and compression waves). ELECTROCHEMISTRY accessories 36/37 Battery accessories Test cells 3-electrode test cell These cells allow users to characterize the electrode (positive and negative electrode). With the ECC-Ref test cell (E-ECC-REF) a reference electrode (Lithium wire) can be used to follow the behavior of the negative and positive electrode simultaneously. ECC-AIR Test cells Catalog n° For lithium Ion battery and 2-electrode test cell other aprotic electrochemical 3-electrode test cell system 2/3-electrode test cell 2/3-electrode test cell for gas analysis 5-electrode test cell (0.10 mm) E-ECC-STD E-ECC-REF E-ECCCOM E-ECCDEM E-ECCMREF Options ECC-Std-kit, to upgrade E-ECC-STD to E-ECC-REF ECC-Ref-kit, to upgrade E-ECC-REF to E-ECC-STD For both aqueous and aprotic 2/3-electrode test cell electrochemical systems with Options ref electrode adjustment tool For measuring ECC-press-DL gas evolution and ECC-press-Aqu for drawing gas samples ECC-press-Air (pressure test cell) ECC-press This can be done with a VSP, VMP3 or MPG2 that offer a 5-lead type connection. Other cells for specifics utilization are also available. For gas diffusion electrodes For optical characterization Option cable to connect Bio-Logic instrument (DB9 connector) to ECC-press ECC-AIR electrochemical test cell (in aprotic media) ECC-AIR electrochemical test cell E-ECCSTD-K E-ECCREF-K E-ECCAQU E-ECCAQU-1 E-ECCP-DL E-ECCP-AQ E-ECCP-A E-ECCP E-C-Press E-ECCAIR E-ECCAIR-N Options ECC-AIR-kit ECC-Opto Std face to face ECC SBS side by side, complete E-ECCAIR-K E-ECCOPT-S E-ECC-SBS Options ECC-Opto Aqu-kit lid (ECC-Opto) XRD, 6 mm lid (ECC-Opto) XRD lid (ECC-Opto) 10 mm E-ECCOPT-4 E-ECCOPT-3 E-ECCOPT-2 E-ECCOPT-1 Tools Electrode alignment and assembly tool Catalog n° Catalog n° ECC CellLoad E-ECCLOAD E-ECCLI16 E-ECCLI17 E-ECCLI18 E-ECCLI19 E-ECCLI20 Options REF - cleaning tool set REF- load Removing tool E-ECC-104 E-ECC-103 E-ECC-102 Load the metal lithium Catalog n° REF-load for test cells (allow us to load lithium metal inot REF bore of the E-ECC-REF) E-ECCLOADR Punching tool for lithium foil Catalog n° 6 mm 7 mm 8 mm 9 mm 10 mm E-ECCLI6 E-ECCLI7 E-ECCLI8 E-ECCLI9 E-ECCLI10 Catalog n° 11 mm 12 mm 13 mm 14 mm 15 mm E-ECCLI11 E-ECCLI12 E-ECCLI13 E-ECCLI14 E-ECCLI15 16 mm 17 mm 18 mm 19 mm 20 mm cell Analytical cell Corrosion Glassware The dilatometer is a research grade instrument dedicated to the measurement of chargeinduced strain (expansion and shrinkage) of electrodes down to the sub-micrometer range. The dilatometers have been developed for the investigation of Li-ion battery and other insertion-type electrodes. It may be used in organic as well as aqueous electrolyte solutions. Dilatometer Catalog n° Electro chemical dilatometer ECD-nano-DL (complete) Electro chemical dilatometer ECD-2-DL (complete) E-ECD-N E-ECD-2DL Options Cable to connect Bio-Logic instrument (DB9 connector) to ECD-nano-DL Cable to connect Bio-Logic instrument (DB9 connector) to ECD-2-DL E-C-N E-C-2DL Specifications 2.5 2.5 3.5 0 50 Time/h 100 150 Rotating accessories Battery Quartz 2 3 electrochemistry Ewe/V 2 3 Spectro- 1.5 capacitive LVDT 250 µm 500 µm < 0.1% of full range < 0.15% of full range ≤5 nm ≤50 nm ≥10 Hz ≥10 Hz ≤20 nm/h ≤100 nm/h 1.0 N (fixed) 0.3 N or 1.0 N (variable) aprotic organic electrolytes, optional aqueous electrolytes ≤3 mL (ca. 2 ml electrolyte required) -20 to 70 °C 2-electrode, 3-electrode (reference), auxiliary -10 to 10 V 230 x 100 x 110 mm 2.5 kg crystal analyzer 1 3.5 Displacement/µm 0.5 4 ECD-2-DL electrodes ECD-nano-DL Displacement sensor Dilatation range linearity Resolution Bandwidth Drift (sample-free) Load on test specimen Chemical compatibility Cell electrolyte volume Temperature range Electrode configurations DC output voltage Dimensions (H x W x D) Weight 0 4.5 Electrodes Dilatometers Cutting pliers Catalog n° 16.5 mm 17 mm 17.5 mm 18 mm 19 mm 19.8 mm Option Cross hair to reduce cutting scrap, stop rail, assy ELECTROCHEMISTRY accessories E-ECS16B E-ECS17 E-ECS17B E-ECS18 E-ECS19 E-ECS19B Catalog n° 20 mm 21 mm 22 mm 23 mm 24 mm E-ECS20 E-ECS21 E-ECS22 E-ECS23 E-ECS24 cell E-ECS11 E-ECS12 E-ECS13 E-ECS14 E-ECS15 E-ECS16 Fuel Catalog n° 11 mm 12 mm 13 mm 14 mm 15 mm 16 mm Docking station for 5 test cells Catalog n° ECC-Stand for 5 test cells (ECC series) (complete) E-ECCSTAND accessories E-ECS6 E-ECS7 E-ECS8 E-ECS9 E-ECS9B E-ECS10 Connection Catalog n° 6 mm 7 mm 8 mm 9 mm 9.5 mm 10 mm E-ECS-R 38/39 Battery accessories Battery Holder - 4-point measurement, - 4 A maximum current, - adaptable to a wide variety of battery sizes (coin cells, 18 650 or 26 650 cells), - ability to link together many battery holders. Battery Holder Catalog n° BH-1, dimensions (W x D x H) 134 x 79 x 185 mm 092-22/10 Coin Cell Holder The coin cell holder is directly plugged to the potentiostat connectors. No cable is required. 4 coin cells can be investigated simultaneously. Rack To get a compact setup, it is possible to put five units in a rack with a lateral tablet for a computer. It is possible to use this rack for VMP3, booster chassis, HCP and CLB only if the sliding option is not purchased. Rack for MPG-2xx series up to 5 units Catalog n° Including ethernet switch, power plugs, computer tablet With sliding tablet including ethernet switch, power plugs, computer tablet 092-85/1 092-85/2 Specifications Maximum units 5 units Dimensions rack 600 x 710 x 1850 mm (W x D x H) shelf with the sliding tablet 495 x 450 x 257 mm shelf without the sliding tablet 495 x 450 x 295 mm Temperature range 10 - 40° C Coin Cell Holder Catalog n° CCH, dimensions (W x D x H) 82 x 83 x 65 mm 092-22/14 cell Analytical cell Corrosion Glassware Current Collector (CC5) Electrodes Up to five current boosters can be connected in parallel, increasing the maximum current that can be passed through the cell. In order to simplify the connections, a current collector was designed. 094-201/1 electrodes electrochemistry Catalog n° CC5 Current Collector (5 channels) for VSP-300/VMP300 Spectro- Current Collector for 5 boosters Rotating A maximum current of 60 A can flow through the CC5 (Current Collector for 5 boosters). This simple device collects the current coming from each booster in parallel and delivers it through two 600 mm power cables terminated by two sturdy crocodile copper clips, similar to automobile battery clips. All the boosters need to be connected to each other using the DB 15 connectors. Quartz crystal analyzer Sense Adapter Module (SAM-50) 092-26 accessories Catalog n° SAM-50 accessories Connection cell Fuel Sense Adapter Module Battery To be added to a multichannel system to perform stack measurements up to 50 V for 5 channel boards and a 10-element measurement. ELECTROCHEMISTRY accessories 40/41 Fuel cell Membrane Electrode Assemblies (MEA) These MEAs are based on a 50 µm-thick perfluoronated membrane, and a platinum loading of 0.5 mg/cm² (±0.05), obtained with the standard catalyst concentration, 70% Pt/C. - 3 layers MEA corresponds to a Catalyst Covered Membrane (CCM): the proton exchanged membrane is covered with an ink containing the catalyst on the electroactive area. Platinum and platinum-Ruthenium alloys are available for hydrogen and reformate operations respectively. - 5 layers MEA corresponds to a CCM with Gas Diffusion Layers (GDL) completing the electrodes on the electroactive area on both sides of the membrane. - 7 layers MEA corresponds to a 5-layer MEA with a flat gasket (fiberglass reinforced silicon) around both electrodes. A subgasket, protecting the membrane and the edges of the active layer can be added to 5 and 7-layer MEAs. Membrane Electrode Assemblies (MEA) Catalog n° Single cell fixture (without MEA's) 095-08/1 095-08/2 095-07 095-08 095-08/3 095-09/13 095-09/14 095-09/15 095-09/16 095-09/17 095-09/18 095-09/1 095-09/2 095-09/3 095-09/4 095-09/5 095-09/6 095-09/7 095-09/8 095-09/9 095-09/10 095-09/11 095-09/12 Membrane Electrode Assemblies 5 cm² 16 cm² 25 cm² 50 cm² 100 cm² 5 cm² 16 cm² 25 cm² 50 cm² 100 cm² 225 cm² 3 layers 5 layers 7 layers 3 layers 5 layers 7 layers 3 layers 5 layers 7 layers 3 layers 5 layers 7 layers 3 layers 5 layers 7 layers 3 layers 5 layers 7 layers MEA selection Only the 7-layer MEAs is fully active. The other 3-layer and 5-layer MEAs need to be modified. 50 I/A 40 30 20 10 0 0.4 0.6 Ewe/V 0.8 cell Analytical cell Corrosion Glassware Electrodes electrodes Catalog n° 095-20/2 095-20/3 095-20/4 095-20/5 095-20/7 095-20/9 095-20/10 095-20/6 095-20/8 accessories Connection cell Fuel Options 25 cm² air-breathing cell (no MEA) Power supply by two photovoltaic cells 095-20/1 electrochemistry PEM#1: 25 cm² air-breathing cells (MEA S25-7L N50-Pt/C 70%), no possibility to dismantle the cell PEM#2: 25 cm² air-breathing cells (MEA S25-7L N125-Pt/C 70%), no possibility to dismantle the cell PEM#3: 25 cm² air-breathing cells (MEA S25-7L N212-Pt/C 40%), no possibility to dismantle the cell Electrolyzer kit (including gas line) Variable resistance Data acquisition (including connection, data logger, software) Power supply 220 V 110 V/220 V adapter for 110 V configuration Spectro- Content PEM kit 095-20/A 095-20/B crystal analyzer 110 V electrical grid 220 V electrical grid Quartz Educational kit (fuel cell /electrolyzer) accessories A porous material is placed inside the kit for the homogeneous diffusion of hydrogen over the whole surface area of the membrane electrode assembly. Educational kit Battery The educational fuel cell kit is very simple and easy to use: just plug the hydrogen tank into the cell and let the fuel cell use the oxygen in the surrounding air to produce electricity. - 1 plastic electrolyser cell (25 cm²) containing a 7-layer membrane electrode assembly. At the anode side of the electrolyser cell there is a water reservoir, the hydrogen gas produced comes out of the cell via one of the gas exits on the top and bottom side of the cell. A plastic screw is included for closing the unused gas exit. - 1 plastic air-breathing fuel cell (25 cm²). The cell has one hydrogen gas input and one exit. Rotating Educational kit ELECTROCHEMISTRY accessories 42/43 Connection accessories Specific cables By default, the potentiostat and the booster are provided with a cell cable of 1.5 m long. The cable connected from the booster to the potentiostat is 800 mm long for VMP3 based instruments. For some applications, the user may need cables with different length. That’s why, longer cable are offered. Moreover for applications performed in glove box, hermetic cell cables are also offered. Set-up connection Bad connection could induce some effects on the measurement (effect on the stability of the potentiostat, artifact...). We recommend the user to optimize the set-up by using the accessories offered in this section. Hermetic cell cable for glove box Catalog n° SP-50, SP-150, BiStat, VSP, VMP3, MPG2 A Jaeger connector 12 pins ensures the hermetic junction (hole diameter to make in the glove box wall: 27 mm): - cable with 2 mm connectors in one side and 12 pins Jaeger connector in the other side (length 1 m), - cable with DB-25 connector in one side and 12 pins Jaeger connector in the other side (length 1.5 m), - one feedthrough seal SP-200, SP-240, SP-300, VSP-300, VMP-300 A Jaeger connector 25 pins ensures the hermetic junction (hole diameter to make in the glove box wall: 45 mm): - cable with electrometer in one side and 25 pins connector in the other side (length: 1 m) - cable with DB-25 connector in one side and 25 pins connector in the other side (length: 1.5 m) - two feedthrough seals one installed in the glove box wall the other dedicated to the channel board calibration outside the box 092-23/5 094-101/6 Connection cable from booster to potentiostat Available length Catalog n° All boosters 3m 5m 092-33/5 092-33/6 Longer cable Available length Catalog n° SP-50, SP-150, VSP, VMP3, MPG2 2.5 m 3m 5m 10 m 2.5 m 3m 5m 2.5 m 3m 5m 092-23/2 092-23/7 092-23/3 092-23/4 092-33/11 092-33/12 092-33/13 092-33/21 092-33/22 092-33/23 Booster 2 A, 4 A, 5 A Booster 8 A, 10 A, 20 A cell Analytical cell Corrosion Glassware Nstat box (8 channels) Bipot cable: dedicated to RRDE applications Electrodes Multi-electrode investigation cables Nb of channels Length Catalog n° 4 8 8 2 2 2 1.5 m 1.5 m 1.5 m 1.5 m 3m 4m 092-16 092-22/3 092-22/4 092-22/12 092-22/12A 092-22/12B low current standard 092-16/1 Spectro- Option External power supply for the Nstat box (this option is needed if more than one Nstat box is connected to VMP3 or if the user uses VSP) electrodes Bipot cable (for VSP, BiStat, VMP3) Channel standard electrochemistry Nstat box (for VSP, VMP3) Rotating Multi-electrode investigation cables Quartz crystal analyzer External device connection DB9-8 BNC connector for auxiliary I/O PT100 temperature probe, to be connected to the auxiliary I/O, temperature range: -50 °C to 250 °C, dimensions: 3 x 20 mm, length of cable: 2.5 m IS1 isolation module for auxiliary I/O for SP300 based instruments 092-22/1 092-22/13 accessories External device connection Battery DB9-8 BNC connector Catalog n° ELECTROCHEMISTRY accessories PT100 temperature probe accessories IS1 Connection cell Fuel 094-081/5 44/45 Connection accessories Test Box 2 Test Box 3 Test Boxes DC2 Dummy cell for booster Dummy cells Test Boxes Catalog n° Test Box 2 several circuits with high precision resistors. For calibration and validation Test Box 3 3 circuits: linear, exponential, non-linear. For teaching and demonstration 092-22/6 092-22/7 The dummy cell for booster is especially dedicated to check periodically a booster. It is provided whith each booster chassis. The dummy cell for booster and DC2 can be bound together as well. Dummy cell DC2 Dummy cell for booster Catalog n° 1 R/C circuit. For standard check 1 power resistor, 5 mOhm. For standard check Dummy cell for booster specifications Resistance/mΩ 5 Standard tolerance Temperature coefficient 1% ±50 ppm/°C Standard Faraday cage Advanced Faraday cage Faraday cages To avoid any external perturbations, specially for low current application, we recommend using the Faraday cage. Please note that to activate this protection, Faraday cage has to be connected to the ground of the instrument (green plug on the rear panel of the instrument). Faraday cages Catalog n° Standard Faraday cage, for standard channel 400 x 200 x 600 mm for low current channel Advanced Faraday cage, 286 x 230 x 320 mm N-FAR600 NS-FAR600 A-012033 Advanced Faraday cage specifications Temperature Power supply Fuse Gas pressure Interface Weight 0 - 50 °C 100 VAC-240 VAC, 50/60 Hz 1A < 34 kPa max. IEEE-488, RS-232C 3.8 kg 094-111/3 092-32/1 cell Analytical Corrosion cell Connectors Catalog n° Red colour 092-1001/2 Blue colour 092-1001/26 Alligator clip 4 mm (pack of 5) 092-1001/13 092-1001/14 092-1001/23 Socket 2 mm female (pack of 10) 092-1001/5 092-1001/6 092-1001/7 Socket 4 mm female (pack of 10) 092-1001/25 092-1001/4 092-1001/3 Banana plug 2 mm (pack of 10) 092-1001/9 092-1001/10 092-1001/11 092-1001/12 092-1001/16 092-1001/15 092-1001/24 092-1001/19 092-1001/20 092-1001/21 092-1001/18 Banana adapter 2 mm female socket to 4 mm male plug (pack of 5) Adapter for banana 2 mm female socket to 4 mm male plug (pack of 5) Banana adapter 4 mm female socket to 2 mm male plug (pack of 5) Yellow colour Electrodes 092-1001/8 092-1001/17 Rotating Banana plug 4 mm (pack of 5) White colour 092-1001/22 Glassware Black colour 092-1001/1 Alligator clip with 2 mm connector (pack of 10) electrodes Connectors electrochemistry 092-1001/27 For booster board blue, white, red, black, blue, white, red blue, white, red red, black blue, white, red blue, white 092-1001/30 092-1001/31 crystal analyzer - 4 alligator clips of 2 mm: - 3 sockets of 2 mm: - 3 alligator clips of 2 mm: - 2 alligator clips of 4 mm: - 3 sockets of 2 mm: - 2 sockets of 4 mm: Quartz Connection kit For standard board Spectro- 092-1001/28 094-082 094-091 accessories Catalog n° SP-200 SP-240/SP-300 accessories Connection cell Fuel Transport cases Battery Transport cases ELECTROCHEMISTRY accessories 46/47
