MSDS - Hill Brothers Chemical Co.

Transcription

Bill Of Lading//: 0340778
Product: AMMONIUM BIFLUORIDE CRY (GPD)
BREMNTAG,
August 5, 2014
SAFETY CONTACT
HILL BROTHERS CHEMICAL CO
4450 NORTH 42ND AVE
PHOENIX, AZ 85019
To Whom It May Concern,
Enclosed please find the Material Safety Data Sheet (MSDS) for the
material listed below. Either you recently purchased this product from us,
and/or we are furnishing this MSDS as required by the notification procedures
under Section 313 of SARA Title III.
The law requires that you distribute
these to those people in your company who are involved in the use and/or
handling of these chemicals.
Product Name: AMMONIUM BIFLUORIDE CRY (GPD)
We thank you for your order and hope we may continue to merit
serving your future requirements.
Product #: 872691
Name: AMMONIUM BIFLUORIDE CRY (GPD) Desc:
From: BRENNTAG mCIFIC INC.
To: HILL BROTHERS CHEMICAL CO
Material Safety Data Sheet
Tuesday, August 05, 2014
BRENNTAGJBB
MSDS Revision Date: D5/ID/2DD7
Page I of 3
1. Product Identification
Product Identity: Ammonium Bifluoride
Synonyms: Ammonium hydrogen fluoride; ammonium
difluoride; acid ammonium fluoride
Molecular Weight: 57.D4
Chemical Formula: NH4F HF
Technical Information: Z7D-830-12DD
Emergency Number: 800-424-9300 (CHEMTREC)
Distributed By Brenntag
Brsnntag Great Lakes LLC.
4420 N. Harley Davidson Avenue
Wauwatosa.WI 53225
Brenntag Mid-South Inc.
14D5 Hwy I36 W
Henderson. KY 42420
Brenntag Northeast. Inc.
SI West Huller Lane
Reading. PA 19B05
Brenntag Southeast. Inc.
ZDDD East Pettigrew Street
Durham. NC 27703
Brenntag Southwest. Inc.
BIO Fisher Road
LongviEw. TX 75BD4
Brenntag Pacific. Inc.
10747 Patterson Place
Santa Fe Springs. CA 9DB7D
2. Hazards Identification
Emergency Overview
DANGER!
Can be Fatal if Swallowed. Inhaled or Absorbed Through the Skin
Causes Severe Burns to Eyes, Skin, Digestive System, and Respiratory Tract
Irritation and Burn Effects May BE Delayed
Affects Respiratory System, Heart, Skeleton, Circulatory System, Central Nervous System, and Kidneys.
Potential Health Effects
Inhalation:
Causes severe irritation and burns to the respiratory system. Irritation and burning effects may be delayed.
digestion:
Severe irritation, burns, perforation of the gastrointestinal tract accompanied by shock. May cause kidney and
brain damage. Affects heart and circulatory system.
IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, expre $
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer asumesa H E ponsibiK ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi slVBDS 4iaH not in
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ons of sale.
Product #: 872691
Name: AMMONIUM BIFLUORIDE CRY (GPD)
From: BRENNTAG B\CIFIC INC.
To: HUL BROTHERS CHEMICAL CO
Desc:
BRENNTAG^K
MSDS Revision DatE: D5/ID/ZDD7
Page 2 of 3
Risk of throat Edema and suffocation. Nausea, vomiting (bloody), abdominal cramps and diarrhea (bloody). Cough
and difficulty breathing. Risk of chemical pneumonitis from product inhalation. Risk of hypocalcemia with nervous
disorders (tetany) and cardiac rhythm disorders. Risk of convulsions, loss of consciousness, deep coma and
cardiopulmonary arrest. Risk of general symptoms having a severe prognosis.
Skin Contact:
Painful irritation, redness and swelling of the skin. Severe burns; slow healing. Effects may be delayed. If touched
using the fingernails, severe pain after several hours. Risk of hypocalcemia following the extend of the lesions.
Intoxication hazards by inhalation of the product simultaneously.
Eye Contact:
Severe eye irritation, watering, redness and swelling of the eyelids. Burns. Risk nf serious or permanent eye
lesions. Risk of blindness.
3. Composition/Information on Ingredients
CAS#
1341-43-7
Chemical Name
Ammonium BifluoridE
Percent by Weight
IDD%
4. First Aid Measures
Inhalation:
Remove the subject from the contaminated area as soon as possible; transport him/her lying down, with the head
higher than the body, to a quiet, uncontaminated and well-ventilated location. Oxygen or cardiopulmonary
resuscitation if necessary. Keep warm (blanket). Consult with a physician in all cases. Take to hospital.
digestion:
Consult with a physician immediately in all cases. Take to hospital immediately. If the subject is completely
conscious administer milk, chewable calcium carbonate tablets or milk of magnesia. Do not induce vomiting. If
the subject presents nervous, respiratory or cardiovascular disorders: administer oxygen.
If the subject is unconscious: Use classical resuscitation measures.
IMPORTANT: While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty, expre s
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer asumesa 11 E ponsibift ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS fta fl not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ens of sale.
Product #: 872691
From: BRENNTAG PACIFIC INC.
To: HILL BROTHERS CHEMCAL CO
Desc:
BRENNTAG
Page 3 of 9
Skin Contact:
Consult with a physician immediately in all cases. Wipe off any excess material from skin and then immediately
flush skin with large amounts of soapy water. Remove contaminated clothing and shoes. Wash clothing before reuse. Apply bandages soaked in magnesium sulfate.
Eye Contact:
Consult with an ophthalmologist and physician immediately in all cases. Take to hospital immediately. Flush
eyes as soon as possible with running water for 15 minutes, while keeping the eyelids wide open.
5. Fire Fighting Measures
Go to Section S for Flammable Properties.
Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed
containers cool.
6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective eq uipment as specified in Section 8. Pick up
and place in a suitable container for reclamation or disposal, using a method that does not generate dust.
US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable
quantities. The toll free number for the US Coast Guard National Response Center is (8DD) 424-88D2.
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer asumesafl leyonsibility
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. ThisM>DS Siall not in
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and condit ens of sale.
Product #: 872691
From: BRENNTAG PACIFIC INC.
Desc:
BRENNTAG
MSDS Revision DatE: D5/ID/20D7
Page 4 of 3
7. Handling and Storage
Hygroscopic! Store in a Dry Place! Do Not Expose to Moisture!
Keep in a tightly closed container. Store in a cool. dry. ventilated area. Protect against physical damage.
Separate from acids and alkalis. Do not store in metal containers, as contact with moisture and metal at the same
time may release flammable hydrogen gas. Containers of this material may be hazardous when empty since they
retain product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
DSHA Permissible Exposure Limit (PEL): 2.5 mg(F)/m3 (TWA)
ACGIH Threshold Limit Value (TLV): 2.5 mg(F)/m3 (TWA)
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee Exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document. Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal
Respirators (NIDSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half
facepiece particulate respirator (NIDSH type N95 or better filters) may be worn for up to ten times the exposure
limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest.. A full-face piece particulate respirator (NIDSH type NIDO filters) may be worn up to 5D times
the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or
respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present,
use a NIDSH type R or P filter. For emergencies or instances where the exposure levels are not known. USE a fullfacepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers
in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer asumesa fl IE ponsibit ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS Sia D not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ms of sale.
Product #: 872691
Name: AMMONIUM BIFLUORIDE CRY (GPD) Desc:
From: BRENNTAG MCIFIC INC.
BRENNTAG^l
MSDS Revision DatE: D5/ID/2D07
Page 5 of 9
9. Physical and Chemical Properties
Appearance:
White Crystals
Odor:
Odorless
Physical State:
Solid
pH of water solutions;
3.5 (5% solution)
Melting Point:
I24.6C(257F)
Boiling Point:
24DC (4B4F)
Flash Point:
N/A
Upper Explosive Limit:
N/A
Lower Explosive Limit:
N/A
Vapor Pressure:
No Information Found
Vapor Density:
No Information Found
Specific Gravity:
1.51
Solubility in Water:
4l.5g/IDDg Water @25C(G8F)
Auto-ignition temperature: No Information Found
10. Stability and Reactivity
Chemical Stability: Stable under normal temperature and pressure.
Conditions to Avoid: Negligible
Incompatible Materials: Metals. Glass, Strong Gases, Alkaline:;
Hazardous Decomposition Products: Emits toxic fumes of hydrogen fluoride, nitric oxides, and ammonia when
heated to decomposition. Upon contact with moisture and metal, this material may release hydrogen gas.
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The Buyer asumesal re ponsibility
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS 3ia fl not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ens of sale.
Product #: 872691
From: BRENNTAG l&CIFIC INC.
Desc:
BRENNTAG
MSDS Revision Date: D5/ID/2D07
Page 6 of 9
11. Toxicological Information
LD5D/LC5D DATA NOT FOUND.
Acute Fluoride Exposure:
The mechanism far acute lethality at high fluoride dose levels is nut fully defined. It is believed that certain
essential enzymatic reactions may be blocked and there may be interference with the origin and transmission of
nerve impulses. The metabolic roles of calcium and physical damage to the kidney and the mucosa of the stomach
and intestine are also believed to be associated with the acute lethality mechanism. Fluoride interacts with bones
and teeth by replacing hydroxyl or bicarbonate ions in hydroxyapatite tn form fluorohydroxyapatite. Fluoride may
function as an essential key to bring about precipitation or nucleation of the apatite lattice in an oriented fashion
on collagen fibers. Accretion of new mineral continues, and fluoride, brought to the surfaces of newly formed
crystals by the extracellular fluid, replaces the hydroxyl ion. As crystal growth continues, fluoride is incorporated
into inner layers of the crystals as well as on the surface. Remodeling of the bone structure takes place by an
interplay of osteoclastic resorption of old bone and osteoblastic deposition of new bone. The presence of
fluornhydroxyapstite increases the crystalline structure of the bone and reduces its solubility. Available evidence
suggests that dental fluorosis results from toxic effects of fluoride on the epithelial enamel organ. Specifically,
several investigators have shown that ameloblasts are susceptible to fluoride. Dental staining often accompanies
fluornsis but does not itself determine the degree of fluorosis. The staining is believed to be due to the oxidation
of organic material in defective enamel or the penetration of hypoplastic sections of enamel by food pigments.
/Fluoride/ [USEPA, Office of Drinking Water; Criteria Document (Draft): Fluoride p.viii-3 (I985) ]
Human Exposure Excerpts:
Most available toxicity information on fluoride relates to acute toxicity of hydrofluoric acid ("HF"). However, other
water soluble fluoride-containing compounds can cause fluoride poisoning. The fluoride ion is systemically
absorbed almost immediately. It is highly penetrating and reactive and can cause both systemic poisoning and
tissue destruction. Fluoride ions, once separated from either HF or fluoride salts, penetrate deep into tissues,
causing burning at sites deeper than the original exposure site. The process of tissue destruction can continue
for days. Fluoride absorption can produce hyperkalemia (elevated serum potassium), hypocalcemia (lowered
serurn calcium), hypomagnesemia (lowered serum magnesium), and metabolic and respiratory acidosis. These
disturbances can then bring on cardiac arrhythmia, respiratory stimulation followed by respiratory depression,
muscle spasms, convulsions, central nervous system ("CNS") depression, possible respiratory paralysis or
cardiac failure, and death. Fluoride may also inhibit cellular respiration and glycolysis, alter membrane
permeability and excitability, and cause neurotaxic and adverse Gl effects. When exposure is through inhalation,
fluorides can cause severe chemical burns to the respiratory system. Inhalation can result in difficulty breathing
(dyspnea), bronchospasms, chemical pneumonitis, pulmonary edema, airway obstruction, and tracheobronchitis.
The severity of burns from dermal absorption can vary depending on the concentration of fluoride available,
duration of the exposure, the surface area exposed, and the penetrability of the exposed tissue. Ocular exposure
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer asumesa H re ponsibit ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS &a fl not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ois of sale.
Product #: 872691
From: BRENNTAG MCIFIC INC.
Desc:
BRENNTAG
Page 7 of 9
can result in serious eye injury. Ingestion of fluoride can result in mild to severe Gl symptoms. Reports suggest
that ingesting 3 to 5 milligrams of fluoride per kilogram of body weight (mg/kg) causes vomiting, diarrhea, and
abdominal pain. Ingestion of more than 5 mg/kg may produce systemic toxicity. A retrospective poison control
center study of fluoride ingestions reported that symptoms, primarily safely tolerated Gl symptoms that tended to
resolve within 24 hours, developed following ingestions of 4 to 8.4 mg/kg of fluoride. [G3 FR 29943 (June 2,
I9BB)]
Human fatalities have resulted from bath oral exposure to sodium fluoride and dermal exposure to hydrofluoric
acid. Dermal exposure to hydrofluoric acid is often accompanied by inhalation of hydrofluoric acid fumes. Human
studies and case reports have investigated the effects of nonlethal oral doses of sodium fluoride, although only
after acute exposure. These exposures have resulted in mostly gastrointestinal effects and consequences of
hypocalcemia (e.g., nervous system and cardiovascular effects). /Sodium fluoride and hydrofluoric acid/
[DHHS/ATSDR; Toxicological Profile for Fluorides, Hydrogen Fluoride.and Fluorine p.lG9 PB2DD4-IDDDD2 (2DD3).
Available from http://www.atsdr.cdc.gov/toxprofiles/tpll.html as of July 12.2QDG.]
Human Case Reports
Since 1995, there were six reports / to the American Association of Poison Control Centers/ of fluoride
poisoning in children under 5 years of age from a wheel cleaning product. The product contains ammonium
bifluoride and ammonium fluoride salts, reportedly containing at least 15 percent fluoride. Before December, 1996,
it was marketed for household use in non-CR packaging. Since that date it has been packaged in CR packaging,
and in September 1997 it was recalled by the manufacturer. Three deaths from fluoride-containing products were
documented in 1997 after the /CSPC/ staff had completed the briefing package for the proposed rule. Two
involved children under 5 years old. In one case, a 3-year-old female died from cardiac arrest after ingesting the
recalled wheel cleaner described above. The second death involved a 19-month-old female who ingested a rust
remover with hydrofluoric acid and ammonium bifluoride. Finally, a SB-year-old male died from cardiac arrest
after unintentional ingestion of a rust remover with ammonium bifluoride. [63 FR 2994B (June 2,1898) ]
In two separate cases, pediatric patients exposed la Armor-All Quicksilver Wheel Cleaner /containing ammonium
bifluoride/ exhibited systemic toxicity including mental status changes, marked hypocalcemia, and ventricular
fibrillation. One child also demonstrated profound hypomagnesemia. These are the first pediatric reports of
near-fatal outcomes after ingestion or inhalation of a hydrofluoric acid-like product, namely, ammonium
bifluoride. [Klasaer AE et al; Ann Emerg Med 28 (B): 713-8 (I99G) ]
12. Ecological Information
The visible effects of toxic concentrations of fluoride on plants are well documented. They may include chlorosis,
peripheral necrosis, leaf distortion, and malformation or abnormal fruit development. None of these symptoms
are specific to fluoride, and the effects of many other stresses may appear very similar. The diagnosis of fluoride
or implied, regarding, and assumes no liability for, the accuracy or completeness of the infonnation. The Buyer asumesafl re ponsibiEty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS dial noti n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's tenns and conditiois of sale.
Product#: 872691
From: BRENNTAG B\CIFIC INC.
To: HUL BROTHERS CHEMICAL CO
Desc:
Material Safety Data Sheet '
BRENNTAG
MSDS Revision Date: 05/ID/20D7
Page S of 3
injury normally involves both visual and chemical evidence, and comparison of a number of species of known
tolerance growing around the source. Factors relating to the frequency of exposure have also to be taken into
account. /Fluoride/ [WHO; Environ Health Criteria: Fluorine and Fluorides p.4G-7 (1384)]
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste
disposal facility. Processing, use or contamination of this product may change the waste management options.
State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused
contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT (ground)
Proper Shipping Name: RD. AMMONIUM HYDROGEN DIFLUDRIDE, SOLID
Hazard Class: 8
UN/NA: UNI727
Packing Group: II
Marine Pollutant: No
RQ Amount. IDO Pounds
IMDG (water)
Proper Shipping Name: RQ. AMMONIUM HYDROGEN DIFLUORIDE, SOLID
Hazard Class: 8
UN/NA: UNI727
Packing Group: II
15. Regulatory Information
SARA 3DZ
Not Listed
SARA 304
Not Listed
SARA 3I3
Not Listed
CERCLA
IDOIb.
TSCA Inventory
Yes
California Proposition G5
Not Listed
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer aseumesa fl E ponsibiR ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS Sia fl not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's terns and conditi ms of sale.
Product #: 872691
From: BRENNTAG B^CIFIC INC.
Desc:
BRENNTAG JW
Page 9 of 9
16. Other Information
This MSDS is provided as an information resource only. It should not be taken as a warranty or representation
for which Brenntag assumes legal liability. While Brenntag believes the information contained herein is accurate
and compiled from sources believed to be reliable, it is the responsibility of the user to investigate and verify its
identity. The buyer assumes all responsibility for using and handling the product in accordance with applicable
federal, state, and local regulations.
Distributed By Brenntag:
Brenntag Great Lakes LLC.
4420 N. Harley Davidson Avenue
Wauwatosa. Wl 53225
Brenntag Mid-South Inc.
l4D5Hwyl3BW
Henderson. KY4242D
Brenntag Northeast Inc.
81 West Hiiller Lane
Reading. PA I9ED5
Brenntag Southeast. Inc.
20DD East Pettigrew Street
Durham, NC 277D3
Brenntag Southwest. Inc.
BIO Fisher Road
Longview.TX 75BD4
Brenntag Pacific. Inc.
10747 Patterson Place
Santa Fe Springs. CA SOB7Q
or implied, regarding, and assumes no liability for, the accuracy or completeness of the information. The B uyer asumesa H ic ponsibiH ty
for handling, using and/or reselling the Product in accordance with the applicable federal, state, and local law. Thi s MSDS 3ia I not i n
any way limit or preclude the operation and effect of any of the provisions of Brenntag's tenns and conditi ms of sale.

MSDS - Hill Brothers Chemical Co.

Transcription

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