TechLiner TechLiner - Gloucester Engineering
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TechLiner TechLiner - Gloucester Engineering
www.bge.battenfeld.com A publication on trends and applications from Battenfeld Gloucester Engineering TechLiner December 2001 HEAVY DUTY SACKS by German Laverde, Director of Marketing Characteristics & Applications Welcome to the TechLiner...a publication from Battenfeld Gloucester Engineering that shares trends and applications in the plastics industry. This newsletter is published 3 times per year. We’d love to hear your comments and input! Please contact Loretta Cobb, Technical Writer at (978)282-9396 or [email protected]. Plastic shipping sacks, part of the industrial packaging sector of the polyolefin film market, are used to transport bulky materials from one place to another. Based on the final applications and the market demands, it is common to classify them according to the volume or weight they are able to hold, which determines the film thickness. Abstract Heavy duty sacks had an estimated polyethylene consumption of 670 million pounds in 2001. Very important in the growth of the market are the price changes for the resins involved, and the development of new technologies and structures. This article will review the typical applications, product requirements, and production techniques for the preferred process to produce heavy duty sacks. The types of materials used and typical structures for monolayer and coextrusion films will also be examined. The two main categories are: Consumer sacks, designed to carry products weighing less than or equal to 20 pounds, with thicknesses between 0.5 and 3.5 mils (12.7 and 89 microns). Heavy duty sacks, designed to carry products weighing more than 20 pounds, with thickness between 3.6 and 8 mils (91.4 and 203 microns) In this article, we will discuss only heavy duty sacks, which have an estimated polyethylene consumption of 670 million pounds for the year 2001. Applications Typical Applications As mentioned previously, very often the products packaged in heavy duty sacks are bulky and heavy. A typical application is to package raw materials including: • Plastic resins in pellet or powder form - polyethylene, polypropylene, polystyrene • Chemical products - sulfur, caprolactams, anhydride phtalic • Food - salt, sugar Advantages Advantages of heavy duty sacks made of film vs. those made from polypropylene raffia or multi-wall paper: • Protection from short term exposure to outside weather conditions • Better and more reliable sealability • Product visibility where desirable • Better accessibility to products • Better environmental stress cracking resistance (ESCR) In these applications, a very common weight for the filled sack is 25 kg or 55 lb. Applications Applications Product requirements Product requirements can be divided into film mechanical properties, physical properties, behavior expected once the sack is stored, and dimensional requirements. Film mechanical properties: The tensile properties of the film must resist the forces and loads during the filling operation, plus the loads resulting from handling and storage. Other applications for heavy duty sacks include: • • • • • • • Carbon black De-icing salt Explosives Garden compost Sand Pet food Fertilizers • • • • • • Potting soil Wood pellets Seeds Hazardous waste Asbestos debris Insulation Different things can affect the sack design and the properties needed: Typical Structures for Monolayer Film • Product weight and temperature at time of filling Composition Comments • Type of filling system 70% LDPE + 30% LLDPE butene LDPE improves clarity with acceptable tear and sealing properties. 60% LDPE + 40% LLDPE butene Better tear resistance and sealing behavior with good transparency. 60% LDPE + 20% LLDPE octene + 20% LLDPE butene Very good sealing properties tear resistance with equilibrium in price. Hexene can be a good option to replace the octene, which has a better raw materials price. 60% LLDPE butene + 40% LDPE Excellent tear and sealing properties with good processability. 40% LLDPE butene + 20% LLDPE octene or hexene + 40% LDPE Much better sealing properties, especially in contaminated environments (dust, grease, etc.). 50% LDPE butene + 30% LLDPE + 20% MDPE Improved stiffness allowing thickness reduction. Heterophasic Copolymer PP + Copolymer PP flexible + LLDPE Very good creep resistance. Allows thickness reduction. 60% LLDPE butene + 20% HDPE + 20% LDPE Increase in the tensile properties and film stiffness. However, adding HDPE reduces tear resistance. • Handling and storage conditions • Seal type at the bottom and top of the sack The first design consideration for the plastic sack is the weight of the product being packaged. Normal thickness for weights around 20 - 30 lb. (approx. 10 15 kg) is 3.8 or 4.0 mils (96.5 or 100 microns). If the contents’ weight is around 50 lb. (25 kg), which is the case of resin sacks, the thickness goes from 5.5 to 7 mils (140 to 180 microns). New materials and technologies are allowing thicknesses to be reduced to around 4 mils. The second consideration is the sack’s resistance to the load occurring in storage. Due to the methods used to store or palletize the sacks, sometimes they must resist 10 or even 20 times the weight of the product packaged. See photo below. As a consequence of the higher load, the sack must be rigid enough to avoid deformation in the transversal direction. This problem becomes more critical when the temperatures in the storage place are higher than 87°F (30°C). The resin selection for the film structure must consider this problem. The sack stiffness is also important if it is filled using an automatic machine and includes a valve in the top of the sack. The air used to transport and feed the material tends to inflate the sack. As a result, the film must be rigid enough to avoid deformations and thickness reduction. Sometimes small perforations in the film are made to help in the air evacuation. 9 feet (2.7 mts.) or more at the storage place. Tear resistance of the film is very important because of increased risk of puncture and damage to the sack in the storage place and during transport. The tear propagation characteristics should be reduced to avoid spillage. Physical properties of the film: The most important physical property in this application is the slipping characteristics of the film. The sack should have a high coefficient of friction (COF) on the outside to prevent sack slippage once they are palletized. At the same time, depending on the filling procedure or the product packaged, a low coefficient of friction on the inside could be required. It is helpful during the packaging process. Sealing properties are extremely important to guarantee the quality and performance not only of the seal, but the whole sack under critical conditions such as pressure, impact and mishandling. The possibility of impact occurs during transport and handling. Most important is the resistance to the impact generated when the sack falls from heights around Some modifications to the film surface can be done to increase the COF by embossing or by introducing additives into the resin. The first method must be performed without reduction to the mechanical properties or film thickness. Another important consideration is the ability to print the product description and manufacturer information on the sack surface. Normally this is done using flexography, and the sack requires a surface treatment to permit a good ink adhesion. The ink types are important because they must have abrasion resistance. However, inks containing excessive additives such as waxes, can negatively affect the COF on the film. Dimensional requirements: When the sack is being designed, dimensional requirements must be considered including method of transportation, common dimensions of the pallets and number of units per pallet. This will ensure good pallet stability and reduction of the slippage risk. Some market standards exist depending on the type of product and weight packaged. Characteristics Materials used, typical structures and reasons The traditional material used for the production of heavy-duty sacks has been polyethylene, including LDPE, LLDPE, ULDPE, HDPE and sometimes EVA. Depending on the final application and the mechanical properties required, LDPE is used alone or in blends with the other materials. Butene, hexene and octene LLDPE are included in the recipes. Butene is most widely used due to the balance between price and properties obtained. LLDPE provides very good tear resistance, sealing properties and puncture resistance. When it is blended with LDPE, a typical blending ratio is 60-75% LLDPE, plus 40-25% LDPE. It is important to select the appropriate LLDPE grade, because too much flexibility will be detrimental to the dimensional stability of the sack under load and temperatures. Alternatively, LDPE can be the major component. Fractional melt resins help with bubble stability and have better melt strength. These factors are important when thick films are being produced. Additionally, these resins provide a better impact resistance to the film. During the last few years, polypropylene (PP) has been participating in applications that were exclusive for PE. Heavy duty sacks are not an exception. Some resin companies such as Borealis, Basell and Dow have developed PP grades to be used in coextrusion or even mono-layer structures. PP will improve stiffness and tensile properties and increase the creep resistance, allowing, in some cases, thickness reduction. One of the most important properties achieved using PP is higher temperature resistance of the sacks, permitting their use in hot-filling operations. Cement and other industrial products require hot filling because of the characteristics of the production process. A packaging material that is able to resist higher temperatures helps reduce costs, increases plant throughputs and efficiency, and decreases the risk of pallet instability after filling and during storage. When ULDPE is used it can produce excessive flexibility, which can cause deformation under high loads. HDPE in the core layer or thinner layers of ULDPE can be used to diminish these problems. Typical densities for these resins are 0.918 to 0.925 gr/cc in the case of LDPE and LLDPE; 0.895 to 0.915 gr/cc for ULDPE. Melt index values for LDPE are Typical Structures for Coextrusion Layer A: % Final Thickness 25 Composition Comments 100% LDPE LDPE provides processability and clarity while LLDPE provides puncture and tear resistance properties with a good balance in raw materials cost. B: 50 100% LLDPE C: 25 100% LDPE A: 25 B: 50 C: 25 70% LDPE + 30% LLDPE HDPE is included to increase + slip additive the tensile properties without 70% LLDPE + 30% HDPE big change in the tear strength. Additionally, a 70% LDPE + 30% LLDPE different effect is achieved in + anti-slip additive the outer layers, helping in the packaging process and reducing the COF. A: 10 100% coPP B: 80 100% LLDPE C: 10 80% coPP + 20% LLDPE A: 20 B: 65 100% LLDPE with or without additives 100% LDPE + color C: 15 100% LLDPE + additives to increase COF, or 100% ULDPE Good sealing, very good puncture and temperature resistance. Can be used for hot-fill applications. Good creep resistance. Allows thickness reduction. Thin outside layers minimize the effect of expensive materials with a good combination of special effects. ULDPE can be used in the inner layer also, to improve the sealing properties especially in presence of grease. At the same time it gives very good tear resistance, and its tacky nature helps to increase the COF. Photo #2 Photo #4 Photo #3 Photo #1 better around 0.25 to 0.8 gr/10 min; lower values are preferred because of better impact resistance properties. Melt index values for LLDPE generally are around 0.8 to 1.5 gr/10 min. Extruded Product: Generally the film is produced as flat non-gusseted tubing. Printed, bottom sealed, stacked, gusseted, and non-gusseted bags are also produced in-line with a blown film process. Single wound sheet is produced specifically for form/fill/seal (FFS) machines or for sacks with a back seam. This type of film is more popular in Europe where there is a trend toward using automatic filling machines. Good sealability, toughness and stiffness are important properties for good film performance in FFS machines with speeds up to 1500 sacks/hr (25 sacks/min). Occasionally tubing is produced with gussets to get a better sack shape once it is filled. Some problems can arise due to excessive pressure on the edges of the gussets by the haul-off nip rolls. Modifications are implemented to this part of the process to override these problems, For HDPE, densities of 0.945 to 0.96 gr/cc are used, corresponding to medium or high molecular weight materials. Production Techniques Film Production Process: Blown film extrusion is the preferred process to produce heavy duty sacks. Tear strength and the impact resistance of this type of film is far superior than cast extruded film. The estimated market share for monolayer films is around 55% versus 45% for coextruded structures. Coextrusion allows more material combinations, special effects on the outside surface, and downgauging. Hot-fill Heavy Duty Bags - 2 BIG Differences 1% Secant Modulus Tear Strength 100 1200 80 1000 grams kpsi 60 40 800 400 200 0 0 MD TD MD TD Machine Direction Traversal Direction Machine Direction Traversal Direction Coex Blend BUR: The best mechanical properties are achieved in the range of values from 2.0:1 to 2.6:1. Very high blow up ratios (BUR) values can cause retraction problems in the seals, while very low values can affect the tear properties. Thickness: Typical values are in the range of 3.6 to 8 mils (91.4 to 203 microns) with gauges of 4 to 6 mils (100 to 150 microns) being the most common. Width: This depends on the type of product and the final use of the sack. A typical example is resin sacks with widths of 16 to 22 inches (40 to 55 cm). Converting Once the tubing or the single sheet is produced, it needs to be converted into the final sack. Single wound sheet is used in a form/fill/seal machine in a single operation to produce sacks filled with the product. One disadvantage is the sharp corners on the top and bottom ends of the sack which can make the palletizing process difficult. Another disadvantage is the COF needed for the forming operation, which can cause bag slippage in shipping and storage. In the case of tubing, there are several different forming and filling techniques. Some examples are: 600 20 including s-wrap rolls or even cooling rolls before the nip. Coex Blend source: Basell Polyolefins Open mouth layflat sack: the tubing is sealed at one end and cut; the customer fills and seals the sack at the top. Tapered sides and ends are obtained making the storage difficult. Open mouth side gusseted sack: the tubing is gusseted when extruded or postgusseted when sealed in the factory. The gusseted tubing is sealed only at one end and then cut. The customer fills and seals the sack at the top. The final shape is square at the sides when filled, for easier stacking. See photo #1. Hot-fill Hot-fillHeavy HeavyDuty DutyBags Bags- 2 BIG Differences 2 potential solutions for hot-fill heavy duty bags 2 potential solutions for hot-fill heavy duty bags Std Coex 20% Blend of Terpolymers Std Coex 60% LLDPE Squared bottom open mouth: special shape for the bottom seal. Uses flat tubing. The customer fills and seals the sack at the top. See photo #2. Valve sack with simple seal at bottom: includes a valve in the top to make the filling process easier. The customer fills the sack without post-sealing operations. Stacking is difficult. See photo #4. Valve sack with flat bottom: squared seal in the bottom or gusseted tubing includes a valve in the mouth. Perfect shape, easy to stack. The valve avoids spillage and permits faster filling. The customer fills the sack without post-sealing operations. 20% Blend of Terpolymers Hot-fill Coex 10% Copolymer PP 80% LLDPE 10% Copolymer PP Hot-fill Blend 20% Copolymer PP 20% LLDPE Thickness, mil 4.2 4.2 4.0 656 590 590 Tear Strength MD 1600 1280 170 g TD 1520 1280 330 Yield Strength MD 1876 2025 3250 psi TD 1911 2000 2900 Break Strengh MD 6253 5015 6750 psi TD 5764 4800 6100 1% Secant MD 35 46.5 86.5 (kpsi) TD 36 46.25 81.5 240 310 300 Heat Resistance source: Basell Polyolefins of filled palletized bags once stored. The process embosses from inside the tubing, burls to the exterior of the film and produces an obstacle to sliding. This tremendously increases the friction between one sack and another. See photo left. The embossing pattern can be modified and chosen according to the specific requirements and final results. Market size Embossed film offers advantages. Me lt index (gr/10 min) Density (gr/cc) Type Do w 123 0.25 0.921 LDP E Do w 133 0.22 0.921 LDP E Do w 2045A 1.0 0.920 LLDPE Do w 4001 1.0 Marlex D252/D257 0.3 0.923 LDP E P et rot hene NA 35 7 0.25 0.928 LDP E P et rot hene NA 98 5 0.25 0.920 LDP E Exxo nMobil LD 140 0.75 0.919 LDP E Exxo nMobil LD 052/051 0.25 0.918 LDP E Borstar FB223 0 0.9 (MFR5) 0.923 Bimodal LDPE Mopl en EP310D 0.8 (MFR 2.1) 0.900 PP 0.5 0.905 VLDPE UC Flexomer E TSE- NT7 (F) 60% Impact Copolymer PP Examples of resins used to produce heavy duty sacks: Producer/R eference Hot-fill Blend Dart Impact, g Other processes performed on the film are flexographic printing, embossing and handle sealing. See photo #3. Embossing: Secondary process used to modify the film surface to increase the COF and prevent the slipping, sliding and falling Hot-fill Coex ULDPE The market size was estimated to be 524.8 million pounds (262,400 Tons) for 1998 and 670 million pounds (335,000 Tons) for 2001 with an average annual growth rate of 8.4% into the year 2003. Very important in the growth of the market are the price changes for the resins, and the development of new technologies and structures. Depending on these advancements and price fluctuations, the consumers will be changing from multi-wall paper sacks to heavy duty plastic sacks. For more information, please contact Battenfeld Gloucester Engineering at 978-281-1800. German Laverde Director of Marketing The Story of Bakelite The first completely synthetic man-made substance was History of Plastics discovered in 1907, when New York chemist, Leo Baekeland, created a liquid resin that he named Bakelite. Baekeland had developed an apparatus, which he called a Bakelizer, enabling In today’s world, life without plastics is incomprehensible. We all know the many ways that plastics contribute to our health, safety and peace of mind. But how did the material plastic come about? Who were the key individuals in its development and use? In each TechLiner issue we will feature one element of plastic’s amazing history. him to vary heat and pressure precisely controlling the reaction of volatile chemicals. Using this apparatus, Baekeland developed a new liquid (bakelite resin), which rapidly hardened and took the shape of its container. This new material would not burn, boil, melt, or dissolve in any commonly available acid or solvent. Once it was firmly set, it would never change. This one benefit made it stand out from previous "plastics” produced. Previously, celluloid-based substances could be melted down innumerable times and reformed. Bakelite was the first thermoset plastic, which would retain its shape and form under any circumstances. Bakelite could be added to almost any material instantly making it more durable and effective. The US government saw Bakelite as opening the door to production of new weaponry and lightweight war machinery. In fact, Bakelite was a key ingredient in most of the weapons used in the Second World War. FREE TechLiner Binder Want a place to store your future issues of TechLiner? Contact Loretta Cobb to order your free binder today at (978) 282-9396 or e-mail [email protected] Battenfeld Gloucester Engineering Co., Inc. Blackburn Industrial Park/Post Office Box 900 Gloucester, Massachusetts 01931-0900 USA Tel 978-281-1800 Fax 978-282-9111 SMS Folientechnik Laxemburger Strasse 246 A-1239 Vienna, Austria Tel +43 1 615 1420-0 Fax +43 1 615 1420 7980 email: [email protected] www.bge.battenfeld.com PRSRT STD U.S. POSTAGE PAID PERMIT NO. 1 E. Hampstead, NH