Celstran® CFR-TPR Composites
Transcription
Celstran® CFR-TPR Composites
Celstran® CFR-TPR Composites The Material for Great Inventions™ Continuous Fiber Reinforced Thermoplastic Rod Innovative Reinforcement Technology © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TP Reputation built throughout major industries “Best fiber Impregnation” “Outstanding mechanical/ thermal Performance” “Very broad resin/fiber combinations” “Large project Experience” “Help customers develop their new products” © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites “Ability for customized Products” 2 Melt Impregnation Leadership 1980s Present Industry-leading research in melt impregnation of fiber in tape form with thermoplastics Global leadership in long fiber TP (LFRT) 11-25mm fibers Fully impregnated continuous fiber CFR-TP thermoplastic tapes Fully impregnated continuous fiber thermoplastic rods/shapes CFR-TPR Decades of Experience in Delivering the Most Performance from the Fiber and Resin Matrix © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 3 Celstran® CFR-TPR A unidirectional reinforced composite rod product developed from fiber reinforced thermoplastics, available in both semi-continuous and custom lengths. Features and Benefits Industry Segments ► Broad portfolio of thermoplastic polymers ► Civil and fiber reinforcements ► A high strength-to-weight ratio ► Excellent toughness and fatigue ► Excellent chemical resistance ► ► ► ► © 2014 Celanese CFRTP-016R1 AM 03/14 ‒ Concrete reinforcement Oil and Gas ‒ Umbilicals – strength members, armoring ‒ Moorings and cables ‒ Slickline Marine ‒ Moorings and cables Energy infrastructure ‒ HV cable core Mining ‒ Conveyor belt reinforcement ‒ Cabling Celstran® CFR-TPR Composites 4 Celstran® CFR-TPR Capping A capping polymer is optional and can be customized to provide additional: Capped Rod ► Corrosion resistance ► Abrasion and wear resistance ► Galvanic corrosion resistance ► Flame resistance (FR) ‒ Reduced flame, smoke, toxicity (FST) ► Ultraviolet light stabilization (UV) ► Anti-oxidation protection (AO) ► Identification laser markable ► Color identification Uncapped Rod ► Electrical insulation © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 5 Celstran® CFR-TPR Minimum Radius ► The minimum bend diameter is derived from the dimensions of the composite rod diameter d d ► Recommended safe D minimum bend diameter is 150d 150d © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 6 Celstran® CFR-TPR Design Flexibility ► Celstran CFR-TPR can be used as individual rods, or multiple rods can be used to create macro-structures for high strength and stiffness composite cores or armoring reinforcement. © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 7 Celstran® CFR-TPR Property Comparison Specific Tensile Properties Specific Flexural Properties 1400 1800 1600 1400 PPA-CF60 PPS-CF5001 PPS-CF45 1200 PPS-CF5002 1000 800 600 400 GA5-UHS Inconel 718 200 Al 2024-T6 Brass Steel A36 0 0 20000 40000 60000 80000 100000 Specific Tensile Modulus - E/δ ‐ (MPa/(g/cc)) Specific Flexural Strength - σ/δ - (MPa/(g/cc)) Specific Tensile Strength - σ/δ - (MPa/(g/cc)) 2000 PPA-CF60 1200 PPS-CF5001 PPS-CF45 1000 PPS-CF5002 800 600 400 GA5-UHS 200 Inconel 718 Brass 0 0 Al 2024-T6 Steel A36 20000 40000 60000 80000 Specific Flexural Modulus - E/δ ‐ (MPa/(g/cc)) The Composite Advantages Over Metals © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 8 Celstran® CFR-TPR Property Comparison PPS-CF50 PPS-CF45 PPS-CF60 PPS-CF51 Capping Thickness (mm) 0.0 0.15 0.0 0.15 Diameter (mm) 3.18 3.48 3.18 3.48 CF Volume % 43% 37% 51% 43% Tensile Strength 329 ksi 2269 MPa 290 ksi 2000 MPa 372 ksi 2566 MPa 329 ksi 2269 MPa Tensile Break Load 4105 lb 18670 N 4210 lb 18700 N 4490 lb 19970 N 4850 lb 21570 N 15.7 Mpsi 108 GPa 17.1 Mpsi 118 GPa 14.4 Mpsi 99 Gpa Tensile Modulus Tensile Strain to Fail Density Lineal Weight 2.07% 0.055 lb/in3 1.53 g/cc 123 ft/lb 82 m/kg 13.3 Mpsi 91.7 GPa 2.08% 2.07% 2.19% 0.0536 lb/in3 1.48 g/cc 0.0569 lb/in3 1.58 g/cc 0.054 lb/in3 1.50 g/cc 108 ft/lb 72 m/kg 119 ft/lb 80 m/kg 101 ft/lb 68 m/kg ** Please note that the above values are preliminary and can be customized with changes in fiber loading and rod diameter © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 9 Celstran® CFR-TPR Thermal Key Points of Different Polymers Tg Tm Ts PA6 PBT PA66 Polymers 350 300 250 Tg (°C) 200 150 100 50 0 -50 -100 POM HDPE © 2014 Celanese CFRTP-016R1 AM 03/14 PP Celstran® CFR-TPR Composites PPS PEI PEEK 10 Celstran® CFR-TPR Elevated Temperature Tensile Properties 2,414 300.0 2,069 250.0 1,724 Tensile Strength (ksi) 350.0 1,379 200.0 PEI-CF50 150.0 1,034 PPS-CF50 100.0 PEEK-CF50 50.0 0.0 690 PAA-CF50 100 160 70 212 320 © 2014 Celanese CFRTP-016R1 AM 03/14 345 Temperature (˚C) 25 220 428 Temperature (˚F) Celstran® CFR-TPR Composites Tensile Strength (MPa) Unidirectional Carbon Fiber Reinforced Rod Tensile Strength 240 0 464 11 Celstran® CFR-TPR Preconditioned Tension Strength Retention ► Uncapped samples were preconditioned at elevated temperatures for a set period of time and tensile tested to failure ► PPS displays secondary crystallization below Tg and good property retention above Tg PPS-CF50 120.0 120.0 100.0 100.0 455°F / 235°C 80.0 473°F / 245°C 455˚F / 235˚C 80.0 473˚F / 245˚C 491˚F / 255˚C 60.0 509˚F / 265˚C 40.0 20.0 0.0 0 1000 2000 3000 Hours Aging © 2014 Celanese CFRTP-016R1 AM 03/14 4000 5000 Residual Tensile Strength (%) Residual Tensile Strength (%) PEEK-CF50 509˚F / 265˚C 60.0 491°F / 255°C 40.0 20.0 0.0 Celstran® CFR-TPR Composites 0 2000 4000 Hours Aging 12 Celstran® CFR-TPR Diameter Comparison Tensile Load Equivalent Rod Diameter Comparison 3000 435 PPA-CF60 PPS-CF50-01 PPS-CF45 2000 Tensile Strength (MPa) 363 PPS-CF50-02 290 GA5-UHS 1500 218 Inconel 718 1000 145 Al 6061-T6 Brass SS 302 500 73 Tesnile Strength (ksi) 2500 A36 Steel 0 0 10 9 8 7 6 5 4 Diameter (mm) 3 2 1 0 This graph indicates the required diameters for various materials to support 18.2 kN of tensile load. © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 13 Celstran® CFR-TPR Diameter Comparison Equivalent Rod Diameter Comparison 3000 435 GA5-UHS 3.43 mm 2000 Tensile Strength (MPa) PPS-CF50-01 3.17 mm 218 SS 302 A36 Steel 6.29 mm 6.49 mm Brass 7.26 mm Al 6061-T6 8.65 mm 30 1000 500 0 0 290 PPS-CF45 3.45 mm Inconel 718 4.07 mm 1500 363 20 © 2014 Celanese CFRTP-016R1 AM 03/14 145 Tesnile Strength (ksi) 2500 PPA-CF60 2.97 mm PPS-CF50-02 3.14 mm 73 60 40 Lineal Weight (ft/lb) 89 60 Lineal Weight (m/kg) Celstran® CFR-TPR Composites 119 149 80 100 0 120 14 Celstran® CFR-TPR for Overhead Conductor Southwire Company C7™ Overhead Conductor - New Transmission Line Innovation ► Minimal thermal expansion ► Stranded core – no single point of failure ► Unprecedented heat resistance ► Service life expectancy > 40 years Stranded continuous carbon fiber thermoplastic composite core (Celstran CFR-TPR) ► Flexible – robust, installs like conventional conductor ► Less sag – for lines with clearance or structure limitations Heat resistant Fortron ® PPS polymer matrix C7 is a registered trademark of Southwire Company Fortron is a registered trademark of Fortron Industries LLC High-performance PEEK capping layer Lightweight — High Strength-to-Weight Ratio 15 Celstran® CFR-TPR Additional Information ► Manufactured from a thermoplastic resin via a melt flow impregnation process and is safe for human handling ► Wet saw abrasion is a preferred method of machining ► Cutting with shears or saws can create significant localized damage ► Can be customized to withstand the vulcanizing process with adequate adhesion © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 16 Disclaimer Contact Information © 2014 Celanese or its affiliates. All rights reserved. Americas This publication was printed based on Celanese’s present state of knowledge, and Celanese undertakes no obligation to update it. Because conditions of product use are outside Celanese’s control, Celanese makes no warranties, express or implied, and assumes no liability in connection with any use of this information. Nothing herein is intended as a license to operate under or a recommendation to infringe any patents. Celanese®, registered C-ball design and all other trademarks herein with ®, TM, SM, unless otherwise noted, are trademarks of Celanese or its affiliates. Fortron is a registered trademark of Fortron Industries LLC. 8040 Dixie Highway, Florence, KY 41042 USA Product Information Service t: +1-800-833-4882 t: +1-859-372-3244 Customer Service t: +1-800-526-4960 t: +1-859-372-3214 e: [email protected] Europe Am Unisys-Park 1, 65843 Sulzbach, Germany Product Information Service t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011 e: [email protected] Asia 4560 Jinke Road, Zhang Jiang Hi Tech Park Shanghai 201203 PRC Customer Service t: +86 21 3861 9266 f: +86 21 3861 9599 e: [email protected] © 2014 Celanese CFRTP-016R1 AM 03/14 Celstran® CFR-TPR Composites 17 Thank you. For more information: 1-800-833-4882 [email protected] celanese.com/engineered-materials © 2014 Celanese CFRTP-016R1 AM 03/14
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