Celstran® CFR-TPR Composites

Transcription

The Material for Great Inventions™
Continuous Fiber Reinforced Thermoplastic Rod
Innovative Reinforcement Technology
© 2014 Celanese CFRTP-016R1 AM 03/14
Celstran® CFR-TP
Reputation built throughout major industries
“Best fiber
Impregnation”
“Outstanding
mechanical/
thermal
Performance”
“Very broad
resin/fiber
combinations”
“Large project
Experience”
“Help customers
develop their
new products”
“Ability for
customized
Products”
2
Melt Impregnation Leadership
1980s
Present
Industry-leading
research in
melt impregnation
of fiber in tape form
with thermoplastics
Global leadership in
long fiber TP (LFRT)
11-25mm fibers
Fully impregnated
continuous fiber
CFR-TP
thermoplastic tapes
Fully impregnated
continuous fiber
thermoplastic
rods/shapes
CFR-TPR
Decades of Experience in Delivering the Most Performance
from the Fiber and Resin Matrix
3
Celstran® CFR-TPR
A unidirectional reinforced composite rod product developed from fiber reinforced
thermoplastics, available in both semi-continuous and custom lengths.
Features and Benefits
Industry Segments
► Broad portfolio of thermoplastic polymers
► Civil
and fiber
reinforcements
► A high strength-to-weight ratio
► Excellent toughness and fatigue
► Excellent chemical resistance
►
►
►
►
‒ Concrete reinforcement
Oil and Gas
‒ Umbilicals – strength members, armoring
‒ Moorings and cables
‒ Slickline
Marine
‒ Moorings and cables
Energy infrastructure
‒ HV cable core
Mining
‒ Conveyor belt reinforcement
‒ Cabling
4
Celstran® CFR-TPR
Capping
A capping polymer is optional and can be customized to provide
additional:
Capped Rod
► Corrosion resistance
► Abrasion and wear resistance
► Galvanic corrosion resistance
► Flame resistance (FR)
‒ Reduced flame, smoke, toxicity (FST)
► Ultraviolet light stabilization (UV)
► Anti-oxidation protection (AO)
► Identification laser markable
► Color identification
Uncapped Rod
► Electrical insulation
5
Celstran® CFR-TPR
Minimum Radius
► The minimum bend
diameter is derived from the
dimensions of the composite
rod diameter d
d
► Recommended safe
D
minimum bend diameter
is 150d
150d
6
Celstran® CFR-TPR
Design Flexibility
► Celstran CFR-TPR can be
used as individual rods, or
multiple rods can be used to
create macro-structures for
high strength and stiffness
composite cores or armoring
reinforcement.
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Celstran® CFR-TPR
Property Comparison
Specific Tensile Properties
Specific Flexural Properties
1400
1800
1600
1400
PPA-CF60
PPS-CF5001
PPS-CF45
1200
PPS-CF5002
1000
800
600
400
GA5-UHS
Inconel
718
200
Al 2024-T6
Brass
Steel A36
0
0
20000
40000
60000
80000
100000
Specific Tensile Modulus - E/δ ‐ (MPa/(g/cc))
Specific Flexural Strength - σ/δ - (MPa/(g/cc))
Specific Tensile Strength - σ/δ - (MPa/(g/cc))
2000
PPA-CF60
1200
PPS-CF5001
PPS-CF45
1000
PPS-CF5002
800
600
400
GA5-UHS
200
Inconel 718
Brass
0
0
Al 2024-T6
Steel A36
20000
40000
60000
80000
Specific Flexural Modulus - E/δ ‐ (MPa/(g/cc))
The Composite Advantages Over Metals
8
Celstran® CFR-TPR
Property Comparison
PPS-CF50
PPS-CF45
PPS-CF60
PPS-CF51
Capping Thickness
(mm)
0.0
0.15
0.0
0.15
Diameter
(mm)
3.18
3.48
3.18
3.48
CF Volume
%
43%
37%
51%
43%
Tensile Strength
329 ksi
2269 MPa
290 ksi
2000 MPa
372 ksi
2566 MPa
329 ksi
2269 MPa
Tensile Break Load
4105 lb
18670 N
4210 lb
18700 N
4490 lb
19970 N
4850 lb
21570 N
15.7 Mpsi
108 GPa
17.1 Mpsi
118 GPa
14.4 Mpsi
99 Gpa
Tensile Modulus
Tensile Strain to Fail
Density
Lineal Weight
2.07%
0.055 lb/in3 1.53 g/cc
123 ft/lb
82 m/kg
13.3 Mpsi 91.7 GPa
2.08%
2.07%
2.19%
0.0536
lb/in3
1.48 g/cc 0.0569 lb/in3 1.58 g/cc 0.054 lb/in3 1.50 g/cc
108 ft/lb
72 m/kg
119 ft/lb
80 m/kg
101 ft/lb
68 m/kg
** Please note that the above values are preliminary and can be customized with changes in fiber loading and rod diameter
9
Celstran® CFR-TPR
Thermal Key Points of Different Polymers
Tg
Tm
Ts
PA6
PBT
PA66
Polymers
350
300
250
Tg (°C)
200
150
100
50
0
-50
-100
POM
HDPE
PP
PPS
PEI
PEEK
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Celstran® CFR-TPR
Elevated Temperature Tensile Properties
2,414
300.0
2,069
250.0
1,724
Tensile Strength (ksi)
350.0
1,379
200.0
PEI-CF50
150.0
1,034
PPS-CF50
100.0
PEEK-CF50
50.0
0.0
690
PAA-CF50
100
160
70
212
320
345
Temperature (˚C)
25
220
428
Temperature (˚F)
Tensile Strength (MPa)
Unidirectional Carbon Fiber Reinforced Rod Tensile Strength
240
0
464
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Celstran® CFR-TPR
Preconditioned Tension Strength Retention
► Uncapped samples were preconditioned at elevated temperatures for a
set period of time and tensile tested to failure
► PPS displays secondary crystallization below Tg and good property
retention above Tg
PPS-CF50
120.0
120.0
100.0
100.0
455°F / 235°C
80.0
473°F / 245°C
455˚F / 235˚C
80.0
473˚F / 245˚C
491˚F / 255˚C
60.0
509˚F / 265˚C
40.0
20.0
0.0
0
1000
2000 3000
Hours Aging
4000
5000
Residual Tensile Strength (%)
Residual Tensile Strength (%)
PEEK-CF50
509˚F / 265˚C
60.0
491°F / 255°C
40.0
20.0
0.0
0
2000
4000
Hours Aging
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Celstran® CFR-TPR
Diameter Comparison
Tensile Load Equivalent Rod Diameter Comparison
3000
435
PPA-CF60
PPS-CF50-01
PPS-CF45
2000
363
PPS-CF50-02
290
GA5-UHS
1500
218
Inconel 718
1000
145
Al 6061-T6
Brass
SS 302
500
73
Tesnile Strength (ksi)
2500
A36 Steel
0
0
10
9
8
7
6
5
4
Diameter (mm)
3
2
1
0
This graph indicates the required diameters for various materials to support 18.2 kN of tensile load.
13
Celstran® CFR-TPR
Diameter Comparison
Equivalent Rod Diameter Comparison
3000
435
GA5-UHS
3.43 mm
2000
PPS-CF50-01
3.17 mm
218
SS 302 A36 Steel
6.29 mm 6.49 mm
Brass
7.26 mm
Al 6061-T6
8.65 mm
30
1000
500
0
0
290
PPS-CF45
3.45 mm
Inconel 718
4.07 mm
1500
363
20
145
Tesnile Strength (ksi)
2500
PPA-CF60
2.97 mm
PPS-CF50-02
3.14 mm
73
60
40
Lineal Weight (ft/lb)
89
60
Lineal Weight (m/kg)
119
149
80
100
0
120
14
Celstran® CFR-TPR for Overhead Conductor
Southwire Company
C7™ Overhead Conductor - New Transmission
Line Innovation
► Minimal thermal expansion
► Stranded core – no single point of failure
► Unprecedented heat resistance
► Service life expectancy > 40 years
Stranded continuous carbon fiber
thermoplastic composite core
(Celstran CFR-TPR)
► Flexible – robust, installs like
conventional conductor
► Less sag – for lines with clearance or
structure limitations
Heat resistant Fortron
® PPS
polymer matrix
C7 is a registered trademark of Southwire Company
Fortron is a registered trademark of Fortron Industries LLC
High-performance
PEEK capping layer
Lightweight — High Strength-to-Weight Ratio
15
Celstran® CFR-TPR
Additional Information
► Manufactured from a thermoplastic resin via a melt flow
impregnation process and is safe for human handling
► Wet saw abrasion is a preferred method of machining
► Cutting with shears or saws can create significant
localized damage
► Can be customized to withstand the vulcanizing process with
adequate adhesion
16
Disclaimer
Contact Information
© 2014 Celanese or its affiliates. All rights reserved.
Americas
This publication was printed based on Celanese’s
present state of knowledge, and Celanese
undertakes no obligation to update it. Because
conditions of product use are outside Celanese’s
control, Celanese makes no warranties, express or
implied, and assumes no liability in connection with
any use of this information. Nothing herein is
intended as a license to operate under or a
recommendation to infringe any patents.
Celanese®, registered C-ball design and all other
trademarks herein with ®, TM, SM, unless otherwise
noted, are trademarks of Celanese or its affiliates.
Fortron is a registered trademark of Fortron
Industries LLC.
8040 Dixie Highway, Florence, KY 41042 USA
Product Information Service
t: +1-800-833-4882 t: +1-859-372-3244
Customer Service
t: +1-800-526-4960 t: +1-859-372-3214
e: [email protected]
Europe
Am Unisys-Park 1, 65843 Sulzbach, Germany
Product Information Service
t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011
Asia
4560 Jinke Road, Zhang Jiang Hi Tech Park
Shanghai 201203 PRC
Customer Service
t: +86 21 3861 9266 f: +86 21 3861 9599
17
Thank you.
For more information:
1-800-833-4882
[email protected]
celanese.com/engineered-materials

Celstran® CFR-TPR Composites

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