Celstran® CFR-TP
Transcription
Celstran® CFR-TP
Celstran® CFR-TP Continuous Fiber Reinforced Thermoplastics The Material for Great Inventions™ © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Reputation built throughout major industries “Best fiber Impregnation” “Outstanding mechanical/ thermal Performance” “Very broad resin/fiber combinations” “Large project Experience” “Help customers develop their new products” © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview “Ability for customized Products” 2 Melt Impregnation Leadership 1980s Present Industry-leading research in melt impregnation of fiber in tape form with thermoplastics Global leadership in long fiber TP (LFRT) 11-25mm fibers Fully impregnated continuous fiber CFR-TP thermoplastic tapes Fully impregnated continuous fiber thermoplastic rods/shapes CFR-TPR Decades of Experience in Delivering the Most Performance from the Fiber and Resin Matrix © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 3 Celstran® CFR-TP – Our Strengths ► Celanese is a world leader in thermoplastic fiber impregnation technology ► Celanese is a world leader in thermoplastic resin technology ► Our strengths are our resin fiber range, our size and experience in engineering thermoplastics and our impregnation quality © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview Celstran® C F R T P = Continuous = Fiber = Reinforced = Thermo= plastic 4 Why Celstran® CFR-TP? ► CFR-TPs can extend the range of physical properties attainable with reinforced thermoplastic materials by up to an order of magnitude ► Extends the range of CFR-TPs commercially available to include most significant resins, fibers and additives ► Improved range of useful, economical fabrication methods ‒ Winding, compression molding, automated tape placement, localized reinforcement of injection and blow molding ► Combines easy processing of TPs with performance of composite materials ► Recyclability and shelf stability lend to better material yields © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 5 Celstran® CFR-TP Composites Broad Portfolio Polymer Matrix mp (⁰C) ABS TPU HDPE POM PP PVDF PA12 PA6 PES PBT PET PA66 PPS PPA PEEK 110 117 127 166 173 173 177 220 225 249 254 255 282 300 343 GF-60 GF-60 GF-70 GF-60 GF-60 GF-50 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-70 Reinforcing Fiber (Type - Weight %) E-Glass GF-70 GF-70 GF-72 SGF-67 S-Glass CF-60 CF-60 CF-65 CF-50 CF-60 CF-50 CF-60 CF-60 HT Carbon Fiber CF-60 CF-60 CF-60 CF-60 CF-50 CF-60 CF-55 CF-60 CF-67 Standard Material R&D Grade, Special type Available on request * Materials available in Black or Natural; Special colors available on request ** Other reinforcing fibers (e.g. Aramid, IM-7, heavy tow) available on request Recognized by the Industry for the Ability to Customize Unique Combinations of Fiber, TP Resin Matrix and Additives © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 6 Celstran® Composites Broad Possibilities Pellets – Long Fiber Reinforced Thermoplastics (LFRT) Continuous Fiber Reinforced Continuous Fiber Reinforced Thermoplastic (CFR-TP) Thermoplastic (CFR-TP) Tapes Shapes ► ½ ” (≈ 11–12 mm) ► Full width rolls between ► 1” (≈ 25 mm) 254-330 mm ► Standard slit widths of 6, 12, 25, 75 mm ► Custom slit widths available ► Custom © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview ► Custom Shapes (Customer Specific): ‒ Round ‒ Oval ‒ Rectangular ‒ Profiles 7 Celstran® Composites Fiber Impregnation Transfer From Pellet Knowledge Into CFR-TPs Impregnation of each filament Fully impregnated long fiber granule Celstran® Composites Impregnation Process Fully impregnated continuous fiberreinforced tape Excellent Properties for New Applications © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 8 Celstran® CFR-TP Composites Benefits ► Take advantage of the full strength of the reinforcing fibers ► Extend LFRT mechanical specific properties by up to an ► ► ► ► order of magnitude Safe, efficient, environmentally friendly For a wide range of applications Facilitates complex designs All the well-known benefits of thermoplastics ‒ Post processable ‒ High toughness ‒ Light weight ‒ Recyclable ‒ Environmental resistance ‒ Rapid processing ‒ Indefinite shelf life ‒ Wide range of fibers and matrices © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 9 140 20.3 120 17.4 100 14.5 80 11.6 60 8.7 40 5.8 20 2.9 0 Tensile Modulus (Mpsi) Tensile Modulus (GPa) Celstran® CFR-TP Tensile Modulus – Carbon Fiber Products 0 High Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 10 140 20.3 120 17.4 100 14.5 80 11.6 60 8.7 40 5.8 20 2.9 Tensile Modulus (Mpsi) Tensile Modulus (GPa) Celstran® CFR-TP Tensile Modulus – Glass Fiber Products 0 0 General Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 11 2500 363 2000 290 1500 218 1000 145 500 73 Tensile Strength (ksi) Tensile Strength (MPa) Celstran® CFR-TP Tensile Strength – Carbon Fiber Products 0 0 High Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 12 2500 363 2000 290 1500 218 1000 145 500 73 Tensile Strength (ksi) Tensile Strength (MPa) Celstran® CFR-TP Tensile Strength – Glass Fiber Products 0 0 General Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 13 140 20.3 120 17.4 100 14.5 80 11.6 60 8.7 40 5.8 20 2.9 0 Flexural Modulus (Mpsi) Flexural Modulus (GPa) Celstran® CFR-TP Flexural Modulus – Carbon Fiber Products 0 High Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 14 140 20.3 120 17.4 100 14.5 80 11.6 60 8.7 40 5.8 20 2.9 Flexural Modulus (Mpsi) Flexural Modulus (GPa) Celstran® CFR-TP Flexural Modulus – Glass Fiber Products 0 0 General Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 15 1400 203 1200 174 1000 145 800 116 600 87 400 58 200 29 0 Flexural Strength (ksi) Flexural Strength (MPa) Celstran® CFR-TP Flexural Strength – Carbon Fiber Products 0 High Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 16 1400 203 1200 174 1000 145 800 116 600 87 400 58 200 29 Flexural Strength (ksi) Flexural Strength (MPa) Celstran® CFR-TP Flexural Strength – Glass Fiber Products 0 0 General Performance Products © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 17 Celstran® CFR-TP Tg of Different Polymers 250 200 Tg [°C] 150 100 50 0 -50 -100 POM TPU PE © 2014 Celanese CFRTP-005R1 AM 03/14 PP PA6 PBT PA66 Polymers Celstran® CFR-TP Overview PPS PPA PEI PEEK 18 Celstran® CFR-TP Thermal Key Points of Different Polymers 350 Tg Tm Ts 300 250 Tg [°C] 200 150 100 50 0 -50 -100 POM HDPE PP PA6 PBT PA66 PPS PEI PEEK Polymers © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 19 9.0 0.32 8.0 0.29 7.0 0.25 6.0 0.22 5.0 0.18 4.0 0.14 3.0 0.11 2.0 0.07 1.0 0.04 0.0 0.00 Density (lb/in3) Density (g/cc) Celstran® CFR-TP Comparison of Density Polymers © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 20 9.0 0.32 8.0 0.29 7.0 0.25 6.0 0.22 5.0 0.18 4.0 0.14 3.0 0.11 2.0 0.07 1.0 0.04 0.0 0.00 Density (lb/in3) Density (g/cc) Celstran® CFR-TP Comparison of Density Polymers © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 21 Celstran® CFR-TP Specific Property Comparison for Tension Specific Tensile Strength - σ/ρ (MPa/(g/cc)) 1600 1400 PEEK-CF55 PET-CF60 PA66-CF60 PES-CF60 PPS-CF50 PA12-CF60 1200 1000 HDPE-AF60 Glass Fiber 800 PP-GF60 PA12-GF68 POM-GF60 PA66-GF60 400 Brass 0 0 10000 HDPE-CF65 PPA-CF60 PP-CF50 PVDF-CF50 PP-GF70 PPS-GF70 HDPE-GF70 PPS-GF60 PPA-GF70 200 20000 Al 2024-T3 Al 6061-T6 Steel A36 PA6-CF60 PPS-CF60 POM-CF50 PA12-SGF67 600 PPS-CF67 PBT-CF60 Carbon Fiber Metals 30000 40000 50000 60000 70000 Specific Tensile Modulus - E/ρ (MPa/(g/cc)) 80000 90000 The Composite Advantages Over Metals © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 22 Specific Flexural Strength - σ/ρ (MPa/(g/cc)) Celstran® CFR-TP Specific Property Comparison for Flexure 900 PEEK-CF55 800 PPA-CF60 PES-CF60 PPS-CF50 PET-CF60 700 PA66-CF60 PA6-CF60 Glass Fiber 600 PPS-GF70 500 PA66-GF60 PBT-GF60 POM-GF60 ABS-GF60 PP-GF70 400 300 POM-CF50 PA12-CF60 PP-CF50 PVDF-CF50 200 100 Brass Steel A36 PBT-CF60 PA12-SGF67 PPA-GF70 PPS-GF60 PP-GF60 PA12-GF68 HDPE-GF70 Al 2024-T3 Al 6061-T6 PPS-CF67 PPS-CF60 HDPE-CF65 PP-CF60 HDPE-AF60 Carbon Fiber Metals 0 0 10000 20000 30000 40000 50000 60000 Specific Flexural Modulus - E/ρ (MPa/(g/cc)) 70000 80000 The Composite Advantages Over Metals © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 23 Celstran® CFR-TP – High Performance Tensile Strength vs Volume Fraction 2400 348 PPS-CF67 2200 319 2000 PEEK-CF55 PA6-CF60 PA66-CF60 1800 PPS-CF50 POM-CF50 PPA-CF60 1600 290 PPS-CF60 PES-CF60 261 PA12-CF60 232 HDPE-CF65 PVDF-CF50 1400 Tensile Strength (ksi) Tensile Strength (MPa) PET-CF60 203 PBT-CF60 1200 174 PP-CF50 1000 145 30 35 © 2014 Celanese CFRTP-005R1 AM 03/14 40 45 50 Volume Fraction (%) Celstran® CFR-TP Overview 55 60 65 24 Celstran® CFR-TP – General Performance Tensile Strength vs Volume Fraction 1300 189 PA12-SGF67 1200 174 160 PPS-GF70 1000 PP-GF70 PET-GF60 PPS-GF60 900 800 PBT-GF60 PP-GF60 700 145 131 HDPE-GF70 POM-GF60 PA12-GF68 116 102 ABS-GF60 PPA-GF70 PA66-GF60 TPU-GF60 600 Tensile Strength (ksi) Tensile Strength (MPa) 1100 87 500 73 30 35 © 2014 Celanese CFRTP-005R1 AM 03/14 40 45 Volume Fraction (%) Celstran® CFR-TP Overview 50 55 25 Celstran® CFR-TP Target Applications Aircraft Energy Oil and Gas Sport / Leisure Celstran® Composites Building / Construction © 2014 Celanese CFRTP-005R1 AM 03/14 Transportation Celstran® CFR-TP Overview 26 Celstran® CFR-TP for Oil & Gas Pipes Airborne Onshore / Offshore Reinforced Thermoplastic Pipe ► Significant reduction in life cycle cost ‒ Excellent resistance to corrosion, aging and permeation ► Spoolability allows for installation speeds of up to 500 or more meters per hour ► Pipe system can be tailored to avoid permeation issues ► Designed to handle pressure fluctuations over its lifetime ► Burst pressure up to 520 bar with 5mm wall thickness Breadth of Portfolio Allows Tailored Materials and Pipes to Meet Geographic and Application Requirements © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 27 Celstran® CFR-TP for Water Transfer Pipes Composite Fluid Transfer LLC Reinforced Thermoplastic Pipe ► 11” ID, 30 ft sectioned water transfer pipe. ► Lightweight ‒ Two persons can carry, eliminates need for heavy equipment ► 250 psi working / 500 psi burst pressure ► Quick coupling ‒ butt fusion and electro fusion joints ► Flexibility enables 90 degree bend in 60 ft pipe span. ► Reduces number of fittings ► Low pressure drop Broad Product Portfolio to Expand to High-temperature Applications © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 28 Multiple Composite Processing Methods Available ► Automated tape lay-up/consolidation ‒ Winding ‒ Tape placement ► Press consolidation ‒ Double belt press ‒ Press consolidation ‒ Continuous press consolidation ► Fluid heat transfer under vacuum (Quickstep Process*) ► Partial reinforcement ‒ Injection molding incorporation ‒ Compression molding incorporation ‒ Extrusion incorporation ► Sandwich structures * Patented process of Quickstep Technologies Pty Ltd Advanced Processes NOW Take Full Advantage © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 29 Disclaimer Contact Information © 2014 Celanese or its affiliates. All rights reserved. Americas This publication was printed based on Celanese’s present state of knowledge, and Celanese undertakes no obligation to update it. Because conditions of product use are outside Celanese’s control, Celanese makes no warranties, express or implied, and assumes no liability in connection with any use of this information. Nothing herein is intended as a license to operate under or a recommendation to infringe any patents. Celanese®, registered C-ball design and all other trademarks herein with ®, TM, SM, unless otherwise noted, are trademarks of Celanese or its affiliates. Fortron is a registered trademark of Fortron Industries LLC. 8040 Dixie Highway, Florence, KY 41042 USA Product Information Service t: +1-800-833-4882 t: +1-859-372-3244 Customer Service t: +1-800-526-4960 t: +1-859-372-3214 e: [email protected] Europe Am Unisys-Park 1, 65843 Sulzbach, Germany Product Information Service t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011 e: [email protected] Asia 4560 Jinke Road, Zhang Jiang Hi Tech Park Shanghai 201203 PRC Customer Service t: +86 21 3861 9266 f: +86 21 3861 9599 e: [email protected] © 2014 Celanese CFRTP-005R1 AM 03/14 Celstran® CFR-TP Overview 30 Thank you. For more information: 1-800-833-4882 [email protected] celanese.com/engineered-materials © 2014 Celanese CFRTP-005R1 AM 03/14
Similar documents
Celstran® CFR-TPR Composites
The Material for Great Inventions™
Continuous Fiber Reinforced Thermoplastic Rod
Innovative Reinforcement Technology
© 2014 Celanese CFRTP-016R1 AM 03/14