Celstran® CFR-TP

Transcription

Celstran® CFR-TP

Celstran® CFR-TP
Continuous Fiber Reinforced Thermoplastics
The Material for Great Inventions™
© 2014 Celanese CFRTP-005R1 AM 03/14
Celstran® CFR-TP
Reputation built throughout major industries
“Best fiber
Impregnation”
“Outstanding
mechanical/
thermal
Performance”
“Very broad
resin/fiber
combinations”
“Large project
Experience”
“Help customers
develop their
new products”
Celstran® CFR-TP Overview
“Ability for
customized
Products”
2
Melt Impregnation Leadership
1980s
Present
Industry-leading
research in
melt impregnation
of fiber in tape form
with thermoplastics
Global leadership in
long fiber TP (LFRT)
11-25mm fibers
Fully impregnated
continuous fiber
CFR-TP
thermoplastic tapes
Fully impregnated
continuous fiber
thermoplastic
rods/shapes
CFR-TPR
Decades of Experience in Delivering the Most Performance
from the Fiber and Resin Matrix
3
Celstran® CFR-TP – Our Strengths
► Celanese is a world leader in
thermoplastic fiber impregnation
technology
► Celanese is a world leader in
thermoplastic resin technology
► Our strengths are our resin fiber
range, our size and experience in
engineering thermoplastics and our
impregnation quality
Celstran®
C
F
R
T
P
= Continuous
= Fiber
= Reinforced
= Thermo= plastic
4
Why Celstran® CFR-TP?
► CFR-TPs can extend the range of physical properties attainable
with reinforced thermoplastic materials by up
to an order of magnitude
► Extends the range of CFR-TPs commercially available to include
most significant resins, fibers and additives
► Improved range of useful, economical fabrication methods
‒ Winding, compression molding, automated tape placement, localized
reinforcement of injection
and blow molding
► Combines easy processing of TPs with performance
of composite materials
► Recyclability and shelf stability lend to better material yields
5
Celstran® CFR-TP Composites
Broad Portfolio
Polymer Matrix
mp (⁰C)
ABS
TPU
HDPE
POM
PP
PVDF
PA12
PA6
PES
PBT
PET
PA66
PPS
PPA
PEEK
110
117
127
166
173
173
177
220
225
249
254
255
282
300
343
GF-60 GF-60 GF-70 GF-60 GF-60 GF-50 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60 GF-60
GF-70
Reinforcing Fiber
(Type - Weight %)
E-Glass
GF-70 GF-70
GF-72
SGF-67
S-Glass
CF-60
CF-60
CF-65
CF-50
CF-60
CF-50
CF-60
CF-60
HT
Carbon
Fiber
CF-60
CF-60
CF-60
CF-60
CF-50
CF-60
CF-55
CF-60
CF-67
Standard Material
R&D Grade, Special type
Available on request
* Materials available in Black or Natural; Special colors available on request
** Other reinforcing fibers (e.g. Aramid, IM-7, heavy tow) available on request
Recognized by the Industry for the Ability to Customize Unique
Combinations of Fiber, TP Resin Matrix and Additives
6
Celstran® Composites
Broad Possibilities
Pellets – Long Fiber
Reinforced Thermoplastics
(LFRT)
Continuous Fiber Reinforced Continuous Fiber Reinforced
Thermoplastic (CFR-TP)
Thermoplastic (CFR-TP)
Tapes
Shapes
► ½ ” (≈ 11–12 mm)
► Full width rolls between
► 1” (≈ 25 mm)
254-330 mm
► Standard slit widths of
6, 12, 25, 75 mm
► Custom slit widths
available
► Custom
► Custom Shapes
(Customer Specific):
‒ Round
‒ Oval
‒ Rectangular
‒ Profiles
7
Celstran® Composites
Fiber Impregnation
Transfer From Pellet Knowledge Into CFR-TPs
Impregnation
of each
filament
Fully
impregnated
long fiber
granule
Celstran®
Composites
Impregnation
Process
Fully
impregnated
continuous
fiberreinforced tape
Excellent Properties for
New Applications
8
Celstran® CFR-TP Composites Benefits
► Take advantage of the full strength of the reinforcing fibers
► Extend LFRT mechanical specific properties by up to an
►
►
►
►
order of magnitude
Safe, efficient, environmentally friendly
For a wide range of applications
Facilitates complex designs
All the well-known benefits of thermoplastics
‒ Post processable
‒ High toughness
‒ Light weight
‒ Recyclable
‒ Environmental resistance
‒ Rapid processing
‒ Indefinite shelf life
‒ Wide range of fibers and matrices
9
140
20.3
120
17.4
100
14.5
80
11.6
60
8.7
40
5.8
20
2.9
0
Tensile Modulus (Mpsi)
Tensile Modulus (GPa)
Celstran® CFR-TP
Tensile Modulus – Carbon Fiber Products
0
High Performance Products
10
140
20.3
120
17.4
100
14.5
80
11.6
60
8.7
40
5.8
20
2.9
Tensile Modulus (Mpsi)
Tensile Modulus (GPa)
Celstran® CFR-TP
Tensile Modulus – Glass Fiber Products
0
0
General Performance Products
11
2500
363
2000
290
1500
218
1000
145
500
73
Tensile Strength (ksi)
Tensile Strength (MPa)
Celstran® CFR-TP
Tensile Strength – Carbon Fiber Products
0
0
12
2500
363
2000
290
1500
218
1000
145
500
73
Celstran® CFR-TP
Tensile Strength – Glass Fiber Products
0
0
13
140
20.3
120
17.4
100
14.5
80
11.6
60
8.7
40
5.8
20
2.9
0
Flexural Modulus (Mpsi)
Flexural Modulus (GPa)
Celstran® CFR-TP
Flexural Modulus – Carbon Fiber Products
0
14
140
20.3
120
17.4
100
14.5
80
11.6
60
8.7
40
5.8
20
2.9
Flexural Modulus (Mpsi)
Flexural Modulus (GPa)
Celstran® CFR-TP
Flexural Modulus – Glass Fiber Products
0
0
15
1400
203
1200
174
1000
145
800
116
600
87
400
58
200
29
0
Flexural Strength (ksi)
Flexural Strength (MPa)
Celstran® CFR-TP
Flexural Strength – Carbon Fiber Products
0
16
1400
203
1200
174
1000
145
800
116
600
87
400
58
200
29
Flexural Strength (ksi)
Flexural Strength (MPa)
Celstran® CFR-TP
Flexural Strength – Glass Fiber Products
0
0
17
Celstran® CFR-TP
Tg of Different Polymers
250
200
Tg [°C]
150
100
50
0
-50
-100
POM
TPU
PE
PP
PA6
PBT PA66
Polymers
PPS
PPA
PEI
PEEK
18
Celstran® CFR-TP
Thermal Key Points of Different Polymers
350
Tg
Tm
Ts
300
250
Tg [°C]
200
150
100
50
0
-50
-100
POM
HDPE
PP
PA6
PBT
PA66
PPS
PEI
PEEK
Polymers
19
9.0
0.32
8.0
0.29
7.0
0.25
6.0
0.22
5.0
0.18
4.0
0.14
3.0
0.11
2.0
0.07
1.0
0.04
0.0
0.00
Density (lb/in3)
Density (g/cc)
Celstran® CFR-TP
Comparison of Density
Polymers
20
9.0
0.32
8.0
0.29
7.0
0.25
6.0
0.22
5.0
0.18
4.0
0.14
3.0
0.11
2.0
0.07
1.0
0.04
0.0
0.00
Density (lb/in3)
Density (g/cc)
Celstran® CFR-TP
Comparison of Density
Polymers
21
Celstran® CFR-TP
Specific Property Comparison for Tension
Specific Tensile Strength - σ/ρ (MPa/(g/cc))
1600
1400
PEEK-CF55 PET-CF60
PA66-CF60
PES-CF60
PPS-CF50
PA12-CF60
1200
1000
HDPE-AF60
Glass Fiber
800
PP-GF60
PA12-GF68
POM-GF60
PA66-GF60
400
Brass
0
0
10000
HDPE-CF65
PPA-CF60
PP-CF50
PVDF-CF50
PP-GF70
PPS-GF70
HDPE-GF70
PPS-GF60
PPA-GF70
200
20000
Al 2024-T3
Al 6061-T6
Steel A36
PA6-CF60
PPS-CF60
POM-CF50
PA12-SGF67
600
PPS-CF67
PBT-CF60
Carbon Fiber
Metals
30000
40000
50000
60000
70000
Specific Tensile Modulus - E/ρ (MPa/(g/cc))
80000
90000
The Composite Advantages Over Metals
22
Specific Flexural Strength - σ/ρ (MPa/(g/cc))
Celstran® CFR-TP
Specific Property Comparison for Flexure
900
PEEK-CF55
800
PPA-CF60
PES-CF60
PPS-CF50
PET-CF60
700
PA66-CF60
PA6-CF60
Glass Fiber
600
PPS-GF70
500
PA66-GF60
PBT-GF60
POM-GF60
ABS-GF60
PP-GF70
400
300
POM-CF50
PA12-CF60
PP-CF50
PVDF-CF50
200
100
Brass
Steel A36
PBT-CF60
PA12-SGF67
PPA-GF70
PPS-GF60
PP-GF60
PA12-GF68
HDPE-GF70
Al 2024-T3
Al 6061-T6
PPS-CF67
PPS-CF60
HDPE-CF65
PP-CF60
HDPE-AF60
Carbon Fiber
Metals
0
0
10000
20000
30000
40000
50000
60000
Specific Flexural Modulus - E/ρ (MPa/(g/cc))
70000
80000
The Composite Advantages Over Metals
23
Celstran® CFR-TP – High Performance
Tensile Strength vs Volume Fraction
2400
348
PPS-CF67
2200
319
2000
PEEK-CF55
PA6-CF60
PA66-CF60
1800
PPS-CF50
POM-CF50
PPA-CF60
1600
290
PPS-CF60
PES-CF60
261
PA12-CF60
232
HDPE-CF65
PVDF-CF50
1400
PET-CF60
203
PBT-CF60
1200
174
PP-CF50
1000
145
30
35
40
45
50
Volume Fraction (%)
55
60
65
24
Celstran® CFR-TP – General Performance
Tensile Strength vs Volume Fraction
1300
189
PA12-SGF67
1200
174
160
PPS-GF70
1000
PP-GF70
PET-GF60
PPS-GF60
900
800
PBT-GF60
PP-GF60
700
145
131
HDPE-GF70
POM-GF60
PA12-GF68
116
102
ABS-GF60
PPA-GF70
PA66-GF60
TPU-GF60
600
1100
87
500
73
30
35
40
45
Volume Fraction (%)
50
55
25
Celstran® CFR-TP
Target Applications
Aircraft
Energy
Oil and Gas
Sport / Leisure
Celstran®
Composites
Building / Construction
Transportation
26
Celstran® CFR-TP for Oil & Gas Pipes
Airborne Onshore / Offshore
Reinforced Thermoplastic Pipe
► Significant reduction in life cycle cost
‒ Excellent resistance to corrosion, aging and permeation
► Spoolability allows for installation
speeds of up to 500 or more meters per hour
► Pipe system can be tailored to
avoid permeation issues
► Designed to handle pressure
fluctuations over its lifetime
► Burst pressure up to 520 bar
with 5mm wall thickness
Breadth of Portfolio Allows Tailored Materials and Pipes to Meet
Geographic and Application Requirements
27
Celstran® CFR-TP for Water Transfer Pipes
Composite Fluid Transfer LLC
Reinforced Thermoplastic Pipe
► 11” ID, 30 ft sectioned water transfer pipe.
► Lightweight
‒ Two persons can carry, eliminates need for
heavy equipment
► 250 psi working / 500 psi burst pressure
► Quick coupling
‒ butt fusion and electro fusion joints
► Flexibility enables 90 degree bend in
60 ft pipe span.
► Reduces number of fittings
► Low pressure drop
Broad Product Portfolio to Expand to High-temperature Applications
28
Multiple Composite
Processing Methods Available
► Automated tape lay-up/consolidation
‒ Winding
‒ Tape placement
► Press consolidation
‒ Double belt press
‒ Press consolidation
‒ Continuous press consolidation
► Fluid heat transfer under vacuum
(Quickstep Process*)
► Partial reinforcement
‒ Injection molding incorporation
‒ Compression molding incorporation
‒ Extrusion incorporation
► Sandwich structures
* Patented process of Quickstep Technologies Pty Ltd
Advanced Processes NOW Take Full Advantage
29
Disclaimer
Contact Information
© 2014 Celanese or its affiliates. All rights reserved.
Americas
This publication was printed based on Celanese’s
present state of knowledge, and Celanese
undertakes no obligation to update it. Because
conditions of product use are outside Celanese’s
control, Celanese makes no warranties, express or
implied, and assumes no liability in connection with
any use of this information. Nothing herein is
intended as a license to operate under or a
recommendation to infringe any patents.
Celanese®, registered C-ball design and all other
trademarks herein with ®, TM, SM, unless otherwise
noted, are trademarks of Celanese or its affiliates.
Fortron is a registered trademark of Fortron
Industries LLC.
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30
Thank you.
For more information:
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[email protected]
celanese.com/engineered-materials

Celstran® CFR-TP

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