orchem 2016 - Gesellschaft Deutscher Chemiker
Transcription
orchem 2016 - Gesellschaft Deutscher Chemiker
M A R G Liebig-Vereinigung für Organische Chemie 20. Lecture Conference O ORCHEM 2016 P R September 5 – 7, 2016 Weimar www.gdch.de/orchem2016 © Neue Weimarhalle INVITATION WELCOME SPONSORS AND SUPPORTERS SPONSORS AND SUPPORTERS The 20th ORCHEM conference aims at encompassing all aspects of organic chemistry and therefore constitutes one of the most important organic chemistry conferences in Germany for academics, industrial chemists, and students. It takes place in Weimar for the fifth time in 2016. Bayer Pharma Aktiengesellschaft Leverkusen As scientific progress thrives on personal discussions and interactions, ORCHEM is the ideal conference for young researchers to mingle with internationally renowned scientists from Germany and abroad. Consequently, an important feature of the ORCHEM program are two poster sessions where young researchers can present their latest results. DFG – Deutsche Forschungsgemeinschaft Bonn Additionally, the best poster abstracts will be presented as flash talks in the main auditorium. NOVALED GMBH Dresden The ORCHEM 2016 lectures will cover the following areas: • Synthesis • Catalysis Sanofi-Aventis Deutschland GmbH Frankfurt am Main • Methodology • Reactivity Symrise AG Holzminden There will also be an evening lecture on September 5, 2016, entitled “Chemistry meets Piano – Musical Stories with a Twist“. Thieme Chemistry Stuttgart SCIENTIFIC COORDINATOR Peter R. Schreiner Professor at Justus-Liebig University Giessen EurJOC European Journal of Organic Chemistry EurJOC/Wiley-VCH Weinheim The conference is also generously supported by FCI Fonds der chemischen Industrie EXHIBITORS Advion Ltd Biotage GB Ltd Georg Thieme Verlag KG Magritek GmbH NOVALED GMBH Springer Fachmedien Wiesbaden GmbH 2 3 PROGRAM PROGRAM Monday, September 5, 2016 Tuesday, September 6, 2016 Großer Saal 14:00 OPENING P. R. Schreiner, Giessen/DE Großer Saal Chair: T. J. J. Müller, Düsseldorf/DE 09:00 Carbopalladation Cascades – Not only syn, but also anti D. Werz, Braunschweig/DE Chair: H. Gröger, Bielefeld/DE 14:05 Selectivity Control in Catalyzed C–H Activation L. Ackermann, Göttingen/DE 09:45 Adventures in Catalysis: from Mechanisms to Applications F. Schoenebeck, Aachen/DE 14:50 Low-cost electronic structure methods for large chemical systems S. Grimme, Bonn/DE 10:30 COFFEE BREAK 15:35 AWARD of the Gmelin-Beilstein-Denkmünze to Joe P. Richmond, Heidelberg/DE Laudatio by Guido Herrmann, Heidelberg/DE 16:00 COFFEE BREAK Chair: S. Haak, Stuttgart/DE 11:00 SYNLETT BEST PAPER AWARD LECTURE On discovery in catalysis F. Glorius, Münster/DE 11:45 Bringing Modern Data Analysis Tools to Prediction in Catalyst Discovery M. Sigman, Salt Lake City/US Chair: M. Oestreich, Berlin/DE 16:30 Poster Flash Talks 12:30 LUNCH BREAK Chair: A. Nijs, Weinheim/DE Chair: T. K. Lindhorst, Kiel/DE 17:10 EURJOC LECTURE Small Ring Chemistry en route to Acyclic Quaternary Carbon Stereocenters I. Marek, Haifa/IL 14:30 AWARD of the Emil-Fischer-Medaille (GDCh Prize) Laudatio by Prof. Dr. Herbert Waldmann, Dortmund/DE Award Lecture by D. Trauner, Munich/DE 17:55 POSTER SESSION (with beer and prezels) 15:20 AWARD of the ORCHEM PRIZES 2016 Award Lectures Chair: P. R. Schreiner, Giessen/DE 16:10 COFFEE BREAK 19:00 PUBLIC EVENING LECTURE Chemistry meets Piano - Musical Stories with a Twist N. Maulide, Vienna/AT 16:10 Liebig-Vereinigung für Organische Chemie GENERAL MEETING/MITGLIEDERVERSAMMLUNG Chair: M. Urmann, Frankfurt am Main/DE 17:00 Contribution of natural products to the management of the antibiotic crisis P. Hammann, Frankfurt am Main/DE 17:45 New Approaches for Multicatalytic Transformations K. Zeitler, Leipzig/DE 18:30 POSTER SESSION 4 5 PROGRAM FLASH TALKS & POSTER / POSTER LIST FLASH TALKS & POSTER Wednesday, September 7, 2016 Großer Saal Chair: H. G. Schmalz, Cologne/DE 09:00 Applying Physical Organic Principles in Selective Reaction Design R. Gilmour, Münster/DE 09:45 Structure Determination of Organic and Organometallic Compounds Using (Anisotropic) NMR Parameters C. M. Thiele, Darmstadt/DE 10:30 COFFEE BREAK Chair: K. Rück-Braun, Berlin/DE 11:00 Investigations of reaction intermediates with mass spectroscopy J. Roithová, Prague/CZ 11:45 Carbene Catalysis and the Breslow Intermediate A. Berkessel, Cologne/DE, M. Paul, Cologne/DE, D. Kootz, Cologne/DE, W. Harnying, Cologne/DE, V. R. Yatham, Cologne/DE, S. Elfert, Cologne/DE, M. Breugst, Cologne/DE Chair: P. R. Schreiner, Giessen/DE 12:30 POSTER PRIZES AND CONCLUDING REMARKS M001/ Pd(II)-Catalyzed, Enantioselective 3-Component-Synthesis of α-Substituted Amino Acid Derivatives from Sulfonamides, Glyoxalates and Boronic Acids SL01 A. M. Diehl, Frankfurt am Main/DE, G. Manolikakes, Frankfurt am Main/DE, T. Beisel, Frankfurt am Main/DE M002/ Ruthenium-NHC-Catalyzed Enantioselective Hydrogenation of Aromatic Compounds SL02 M. P. Wiesenfeldt, Münster/DE, D. Paul, Münster/DE, F. Glorius, Münster/DE M003/ Allylic Substitution with Hydrides – Copper(I)-catalyzed Allylic Reductions T. N. T. Nguyen, Berlin/DE, J. F. Teichert, Berlin/DE, F. Pape, Berlin/DE, N. O. Thiel, SL03 Berlin/DE M004/ Autoinduced Catalysis in FLP Hydrogenations: From Mechanistic Investigation towards a Structure-Reactivity Relationship SL04 S. Tussing, Paderborn/DE M005/ Mechanisms of Iodine-Catalyzed Reactions D. von der Heiden, Cologne/DE, E. Detmar, Cologne/DE, M. Breugst, Cologne/DE SL05 M006/ Organic Synthesis in Water under High Pressure and High Temperature Conditions in a Flow System SL06 M. Oltmanns, Hannover/DE, J. Hartwig, Hannover/DE, A. Kirschning, Hannover/DE M007/ Triarylmethyl Radicals as Spin Labels for Biomolecules J. J. Jassoy, Bonn/DE, A. Berndhäuser, Bonn/DE, F. Duthie, Bonn/DE, SL07 O. Schiemann, Bonn/DE M008/ Asymmetric visible-light photoredox cross-dehydrogenative coupling of aldehydes with diarylmethanes SL08 E. Larionov, Tarragona/ES, M. Pericas, Tarragona/ES M009/ Iodine(III)-mediated oxidative intramolecular arene-alkene coupling C. Depken, Göttingen/DE, F. Krätzschmar, Göttingen/DE SL09 INFORMATION FOR LECTURES AND POSTERS / FLASH TALKS For your presentation a PC or a Mac as well as a projector will be provided. M010/ Total synthesis of Rubrolide R and S M. Schacht, Hamburg/DE, G. J. Boehlich, Hamburg/DE, J. de Vries, Hamburg/DE, SL10 N. Schützenmeister, Hamburg/DE The poster sessions take place in the foyer: POSTER LIST 1st session on September 5, 2016, starting at 17:55 2nd session on September 6, 2016, starting at 18:30 Poster size: Portrait A0 (approx. 85 cm x 120 cm) Selected posters will be presented in flash talks on September 5, 2016 from 16:30 – 17:10 6 M011 Stereoselective Synthesis of 1,3-Diamines J. Halli, Frankfurt am Main/DE, G. Manolikakes, Frankfurt am Main/DE M012 Nickel-Catalyzed Synthesis of Enamides and Enecarbamates via Isomerization of Allylamides and Allylcarbamates P. Kramer, Frankfurt am Main/DE, J. Halli, Frankfurt am Main/DE, M. Bechthold, Frankfurt am Main/DE, G. Manolikakes, Frankfurt am Main/DE 7 POSTER LIST POSTER LIST M025 Selective Chemoenzymatic One-pot Sequences for the Synthesis of Triazoles B. Remberg, Düsseldorf/DE, M. Krajnc, Düsseldorf/DE, T. J. J. Müller, Düsseldorf/DE M026 Synthesis of β-hydroxysulfones from sulfonyl chlorides and alkenes utilizing visible light photocatalytic sequences S. Pagire, Regensburg/DE Synthesis of nitro-fatty acids J. Grimmer, Frankfurt am Main/DE M027 Stereo- and Chemoselective Cu(I)-catalyzed Alkyne Semihydrogenation F. Pape, Berlin/DE, J. F. Teichert, Berlin/DE M016 Discrimination of Methylated Lysines by a Simple Monocharged Calixarene T. Hanauer, Freiberg/DE, Y. Li, Auckland/NZ, D. Correddu, Auckland/NZ, I. K. H. Leung, Auckland/NZ, T. Gruber, Freiberg/DE M028 Copper(I)-Hydride Chemistry with Ammonia Borane E. Korytiaková, Berlin/DE, J. F. Teichert, Berlin/DE M017 Synthesis of an unsaturated, chiral macrolide from an African reed frog – a potential pheromone M. Menke, Braunschweig/DE, P. S. Peram, Braunschweig/DE, I. Starnberg, Vienna/AT, W. Hödl, Vienna/AT, S. Schulz, Braunschweig/DE M029 Asymmetric Synthesis of Allylic Amines via Hydroamination of Allenes with Benzophenone Imine Y. Wang, Freiburg/DE M030 Synthesis of Novel Pentacene Derivatives and Cyclooctynes for the Study of Internal Interfaces F. Wagner, Marburg/DE, P. Hofmann, Marburg/DE, P. Nikodemiak, Marburg/DE M031 Regio- and Stereoselective Addition of C-Nucleophiles to Vicinal Diketoesters and Diketoamides L. J. Selter, Marburg/DE, L. Zygalski, Marburg/DE, J. Roßbach, Marburg/DE M032 Studies towards the total synthesis of 18-HEPE M. Jübermann, Wuppertal/DE, S. F. Kirsch, Wuppertal/DE M033 Total synthesis of C-4-branched carbohydrates C. Schultze, Potsdam/DE M034 Synthesis of Novobiocin analogues via Pd-catalysed coupling reactions F. Otte, Potsdam/DE M035 Palladium-Catalyzed Oxyarylation of Indoles and Benzofurans V. Ramella, Münster/DE, Z. He, Münster/DE, A. Studer, Münster/DE M036 Regioselective rhodium catalyzed addition of 1,3 dicarbonyl compounds to terminal alkynes T. M. Beck, Freiburg/DE M037 The Asymmetric Piers Hydrosilylation L. Süsse, Berlin/DE, J. Hermeke, Berlin/DE M038 Friedel–Crafts-type Intermolecular C–H Silylation of Electron-Rich Arenes Initiated by Base Metal Salts Q. Yin, Berlin/DE, H. F. T. Klare, Berlin/DE M039 Synthesis of Chiral Piperazinones Using Chiral Isocyanides and AziridineAldehyde Dimers N. Heine, Münster/DE, S. Kaldas, Toronto/CA, V. Nenajdenko, Moscow/RU, A. Studer, Münster/DE, A. Yudin, Toronto/CA M013 Ligand- and Oxidant-free C-H Alkylation and Benzylation Using Pyrrole as a Directing Group J. M. Wiest, Garching/DE M014 Nickel-catalyzed cross-coupling reactions of sulfinic acid salts with aryl halides N. Liu, Frankfurt am Main/DE, G. Manolikakes, Frankfurt am Main/DE M015 M018 M019 In vitro studies of the post-PKS pathway in jerangolid biosynthesis Totalsynthesis of the precursor projerangolid F. C. Lindner, Bayreuth/DE, F. Hahn, Bayreuth/DE Application of N-heterocyclic carbenes as versatile ligands for nanoparticle stabilization and catalysis L. Rakers, Münster/DE, C. Richter, Münster/DE, A. Rühling, Münster/DE, A. Ferry, Münster/DE, K. M. Chepiga, Münster/DE, K. Schaepe, Münster/DE, P. Tegeder, Münster/DE, B. Vonhören, Münster/DE, B. J. Ravoo, Münster/DE, F. Glorius, Münster/DE M020 Chiral Triazoles in Anion-Binding Catalysis J. Bamberger, Regensburg/DE, M. Zurro, Regensburg/DE, S. Asmus, Regensburg/DE, S. Beckendorf, Münster/DE, O. García Mancheño, Regensburg/DE M021 Asymmetric dearomatization of diazarenes by anion-binding catalysis T. Fischer, Regensburg/DE, J. Bamberger, Regensburg/DE, O. García Mancheño, Regensburg/DE M022 Design, Syntheses, Applications, and Mechanistic Understanding of (Thio)-Urea Containing Chiral Ammonium Salt Catalysts M. Waser, Linz/AT M023 Ruthenium catalyzed oxidative coupling reaction of 2-phenylpyridine in ionic liquid with iron(III) chloride M. Muntzeck, Paderborn/DE, R. Wilhelm, Paderborn/DE M024 Synthesis of 3-Benzazepines by a Metal-Free Oxidative C-H Bond Functionalization-Ring Expansion Tandem Reaction A. Gini, Straubing/DE, J. Bamberg, Regensburg/DE, J. Luis, Madrid/ES, R. Mas-Ballesté, Madrid/ES, J. Alemán, Madrid/ES, O. García Mancheño, Regensburg/DE 8 9 POSTER LIST POSTER LIST M040 First Enantioselective Macrolactonization via Intramolecular RhodiumCatalyzed Coupling of Allenes with Carboxylic Acids S. Ganss, Freiburg/DE M053 Selective Synthesis of Pyrrolo[1,2-a]quinolines and Ullazines by Visible Light mediated one- and twofold Annulation of N-Arylpyrroles with Arylalkynes A. Das, Regensburg/DE M041 Organocatalyzed synthesis of cyclic carbonates from bio-based epoxides and CO2 C. Wulf, Rostock/DE, H. Büttner, Rostock/DE, T. Werner, Rostock/DE M054 Derivatives of 9-hydroxyphenalenone – A new group of fluorophores L. Bensch, Düsseldorf/DE M042 Base-free catalytic Wittig reaction T. Werner, Rostock/DE, M.-L. Schirmer, Rostock/DE M055 Synthesis of new electron rich dimers and oligomers based in 4H-dithienothiazines J. Nau, Düsseldorf/DE M043 Fatty Acid Uptake Inhibition in Caco-2 Cells by Homovanillic Esters F. Hentschel, Holzminden/DE, J. Hans, Holzminden/DE, B. Lieder, Vienna/AT, K. Geißler, Holzminden/DE, V. Somoza, Vienna/AT, J. Ley, Holzminden/DE M056 Synthesis of 2-Pyrones via Alkynones in a One-Pot Fashion N. Breuer, Düsseldorf/DE M044 Monomers for Substitution of HEMA in Dental Materials J. Angermann, Schaan/LI, Y. Catel, Schaan/LI, U.K. Fischer, Schaan/LI, N. Moszner, Schaan/LI M057 Decarboxylative γ-Arylation of Carboxylic Acids I. Scheipers, Münster/DE M058 Hydrothioesterification of alkenes P. Gehrtz, Regensburg/DE, V. Hirschbeck, Regensburg/DE, I. Fleischer, Regensburg/DE M059 Chemoenzymatic Synthesis of Natural Products and Derivatives Based on a Biaryl Skeleton A. Ullrich, Jülich/DE, J. Pietruszka, Jülich/DE M060 Overcoming the lack of Stereocomplementarity within Ene-reductases: The Chemoenzymatic Synthesis of all four Stereoisomers of 2-Methylbutane1,3-diol M. R. Mantel, Jülich/DE, E. Rüthlein, Jülich/DE, J. Pietruszka, Jülich/DE M061 Merging Conventional Transition-Metal-Catalyzed Hydrosilylation with Unconventional Si–H Bond Surrogates P. Smirnov, Berlin/DE M062 Formation of gold-acetonyl complexes M. Anania, Prague/CZ, T. Terencio, Prague/CZ, J. Roithová, Prague/CZ M063 Synthesis of thienoacenes utilizing palladium-catalyzed C-S coupling reactions P. Oechsle, Paderborn/DE, J. Paradies, Paderborn/DE M064 Frustrated Lewis Pair-catalyzed cycloisomerization of 1,5-enynes via 5-endo-dig cyclization/protodeborylation sequence N. A. Sitte, Paderborn/DE, J. Paradies, Paderborn/DE M065 Acid-free generation of cyanoform and its ketenimine tautomer M. Chityala, Chemnitz/DE, K. Banert, Chemnitz/DE M066 Catalytic Synthesis of Siloles by Sila-Friedel–Crafts Reactions L. Omann, Berlin/DE M067 A Systematic Study of Fully or Partially Fluorinated Triarylboranes as Catalysts in Direct and Transfer Hydrosilylation Reactions S. Keess, Berlin/DE, A. Simonneau, Berlin/DE M045 Synthesis of modified Hyaluronic Acid Oligomers M. Mende, Karlsruhe/DE, S. Bräse, Karlsruhe/DE M046 Synthesis of Fluorescently-Labeled Glycostructures as Tools for Imaging Techniques M. Wawryszyn, Karlsruhe/DE, A. Braun, Karlsruhe/DE, I. Wehl, Karlsruhe/DE, U. Schepers, Karlsruhe/DE, S. Bräse, Karlsruhe/DE M047 M048 Metal-Free Ammonia–Borane Dehydrogenation Catalyzed bya Bis(borane) Lewis Acid Z. Lu, Giessen/DE, L. Schweighauser, Giessen/DE, H. Hausmann, Giessen/DE, H. A. Wegner, Giessen/DE Solvent effects influencing intramolecular London dispersion forces stabilizing the (Z)-isomers of azobenzene switches M. A. Strauss, Giessen/DE, L. Schweighauser, Giessen/DE, S. Bellotto, Giessen/DE, H. A. Wegner, Giessen/DE M049 Imidazopyridines – a new synthesis J. M. Herr, Giessen/DE, M. Steinbach, Giessen/DE, R. Göttlich, Giessen/DE M050 Alkali- and earth alkali metal salts as catalysts for the cycloaddition of CO2 to epoxides W. Li, Rostock/DE, J. Steinbauer, Rostock/DE, T. Werner, Rostock/DE M051 Accelerated Discovery in Photocatalysis using a Mechanism-based Screening Method M. Teders, Münster/DE, M. N. Hopkinson, Münster/DE, A. Gómez-Suárez, Münster/DE, B. Sahoo, Münster/DE, F. Glorius, Münster/DE M052 Stereoselective Semihydrogenation of Propiolates N. O. Thiel, Berlin/DE, J. F. Teichert, Berlin/DE 10 11 POSTER LIST M068 Breaking the Aromaticity for Formal SEAr of Pyridines with Catalytically Generated Silicon Electrophiles S. Wübbolt, Berlin/DE M069 B(C6F5)3-Catalyzed Transfer Hydrogenation Using Cyclohexa-1,4-dienes as Dihydrogen Surrogate I. Chatterjee, Berlin/DE POSTER LIST M082 Photocatalytic addition of nucleophiles to styrene derivatives S. Hermann, Karlsruhe/DE, H.-A. Wagenknecht, Karlsruhe/DE M083 Applications of Pnicogen Bonding in Organocatalysis J. Schmauck, Cologne/DE, M. Breugst, Cologne/DE M084 Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids L. Pitzer, Münster/DE, L. Candish, Münster/DE, A. Gómez-Suárez, Münster/DE, F. Glorius, Münster/DE M085 Tailoring the Surface of Zeolite L Towards Controlled (Self-)Assembly T. Buscher, Münster/DE, Á. Barroso, Münster/DE, C. Denz, Münster/DE, A. Studer, Münster/DE M070 Oxidative Coupling Reactions Using Molybdenum(V) Reagents S. B. Beil, Mainz/DE, S. R. Waldvogel, Mainz/DE, M. Schubert, Mainz/DE M071 Phenothiazinyl-Merocyanine-Functionalized Silica Hybrids H. Khelwati, Düsseldorf/DE M072 First Investigations towards the Synthesis of Oxaspirodion I. Netz, Mainz/DE, A. Leuthner, Mainz/DE, U. Nubbemeyer, Mainz/DE M086 Photooxidations by a modular photo-flow reactor with singlet oxygen P. Bayer, Regensburg/DE, A. J. von Wangelin, Regensburg/DE Towards the Total Synthesis of the Cystobactamids T. Planke, Hannover/DE, A. Kanakis, Hannover/DE, A. Kirschning, Hannover/DE M087 Consecutive One-Pot Synthesis of 3,4,5-Triarylated Isoxazoles Employing Pd-catalyzed C-H-activation T. Deden, Düsseldorf/DE, T. J. J. Müller, Düsseldorf/DE Nucleic Acid-based Hybrid Catalysts in Asymmetric Diels-Alder Reactions J. J. Marek, Münster/DE, U. Hennecke, Münster/DE M088 Investigating Auxiliary-controlled Zwitterionic Aza-Claisen-Rearrangements as the Key-Step in a Stereoselective Route towards Cripowellins M. Sperner, Mainz/DE, U. Nubbemeyer, Mainz/DE Post-synthetic Copperfree Labeling of Nucleic Acids by the Use of Inverse Electron Demand Diels-Alder Cycloaddition D. Ploschik, Karlsruhe/DE, H.-A. Wagenknecht, Karlsruhe/DE M089 Applications and mechanistic details of TiIII-catalyzed reductive umpolung reactions M. Bau, Freiburg/DE, M. Feurer, Freiburg/DE, G. Frey, Freiburg/DE, H.-T. Luu, Freiburg/DE, A. Steffani, Freiburg/DE, J. Streuff, Freiburg/DE M090 Synthesis of bioactive and photoswitchable jaspamide derivatives F. Küllmer, Jena/DE, G. M. Borowiak, Munich/DE, S. Peil, Jena/DE, V. Nasufovic, Jena/DE, D. Trauner, Munich/DE, H.-D. Arndt, Jena/DE M091 Asymmetric Catalysis of Diels-Alder Reaction Towards Altersolanol Derivatives B. Mechsner, Jülich/DE M073 M074 M075 M076 M077 Modular Synthesis of Teraryl-based alpha-Helix-Mimetics R. Breinbauer, Graz/AT, M. Trobe, Graz/AT, M. Peters, Graz/AT, S. Grimm, Graz/AT, B. Wölfl, Graz/AT Exploring thiopeptide topology with synthesis: toward geometric isomers of nosiheptide I. Raztsou, Jena/DE, K. P. Wojtas, Jena/DE, T. Winkler, Jena/DE, S. Walter, Jena/DE, H.-D. Arndt, Jena/DE M078 NHAcT+BF4--mediated Asymmetric Oxidative CH Functionalization via IonPairing Catalysis S. Stockerl, Regensburg/DE, O. García Mancheño, Regensburg/DE M092 Selenium dioxide-mediated activation of phenols B. Dahms, Mainz/DE, S. R. Waldvogel, Mainz/DE, N. Beiser, Mainz/DE, R. Franke, Marl/DE, K. M. Dyballa, Marl/DE, T. Quell, Mainz/DE M079 Hydrogenation of alkenes and alkynes catalysed by Fe[N(SiMe3)2]2 -aluminium organyls T. N. Gieshoff, Regensburg/DE M093 Intramolecular Trapping Reactions of Triazafulvenes K. Weigand, Chemmitz/DE, K. Banert, Chemnitz/DE M080 Total synthesis of sphingolipids and sphingosine-type signaling molecules of microbial origin D. Leichnitz, Jena/DE, A. Cantley, Boston/US, A. Woznica, Berkeley/US, N. King, Berkeley/US, J. Clardy, Boston/US, C. Beemelmanns, Jena/DE M094 Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A A. Haydl, Freiburg/DE, B. Breit, Freiburg/DE M095 Electron catalysis and perfluoroalkylation D. Leifert, Münster/DE, A. Studer, Münster/DE M096 Recent Discoveries in the Aromatic Nucleophilic Substitution (SNAr) Chemistry of Highly Substituted Porphyrins M. Kielmann, Dublin/IE, M. O. Senge, Dublin/IE M081 Synthesis and characterization of Bis(imino)acenaphthene-Iron(II) complexes M. Villa, Regensburg/DE, D. Schaarschmidt, London/GB 12 13 POSTER LIST POSTER LIST M097 Dimerization of Bio-Isoprene D. Kellner, Straubing/DE M113 Studies Towards the Total Synthesis of (−)-Lytophilippine A A. Klüppel, Dortmund/DE M098 Tripodal and hexapodal pyrazole-based receptors: Complexes with ammonium ions and solvent molecules in the solid state M. Schulze, Freiberg/DE, N. Koch, Freiberg/DE M114 Total Synthesis and Structural Elucidation of (–)-Fusaequisin A and (–)-Curvicollide C V. von Kiedrowski, Dortmund/DE M099 N-Alkylation of Sterically Hindered N-Chloroamines M. Heck, Chemnitz/DE, K. Banert, Chemnitz/DE M115 Towards the total synthesis of raputindole A M. Kock, Braunschweig/DE, T. Lindel, Braunschweig/DE M100 Biomedical application of nanodiamond via orthoester hydrolysis S. Schweeberg, Wuerzburg/DE, A. Krueger, Wuerzburg/DE M116 Studies Towards the Total Synthesis of Marine Diterpenoid (+)-Gagunin E A. Schäfer, Dortmund/DE M101 Nucleophilic Attack on Allenyl Isothiocyanates J. Seifert, Chemnitz/DE, F. Richter, Chemnitz/DE, K. Banert, Chemnitz/DE M117 Metallosupramolecular helicates as model compounds for EPR-measurements C. Klein, Bonn/DE, O. Schiemann, Bonn/DE, A. Lützen, Bonn/DE M102 Phenanthrene functionalised tribenzotriquinacenes as precursors for distorted nanographenes R. Buschmann, Wuerzburg/DE, A. Krueger, Wuerzburg/DE M118 Synthesis and optical resolution of tribenzotriquinacenes S. Götz, Bonn/DE M103 1,3-Dipolar cycloaddition of acetylenedicarboxylates at cyclooctynes S. Bochmann, Chemnitz/DE, K. Banert, Chemnitz/DE M119 Synthesis of ligands and metallosupramolecular aggregates from Pd(II) ions L. Volbach, Bonn/DE M104 Functionalised Diamond Particles: A new Carrier for Organocatalysis B. Kiendl, Wuerzburg/DE, T. Brueckner, Wuerzburg/DE, F. Pinzner, Wuerzburg/DE, P. Buschmann, Wuerzburg/DE, A. Krueger, Wuerzburg/DE M120 Lewis Base catalyzed Nucleophilic Substitutions P. H. Huy, Saarbrücken/DE, S. Morsch, Saarbrücken/DE, S. M. Kappler, Saarbrücken/DE M105 FLP-catalyzed Oxidation of Indolines by B(C6F5)3 A. F. G. Maier, Paderborn/DE, J. Paradies, Paderborn/DE T120 A plausible scenatrio for the prebiotic formation of purine nucleosides S. Becker, Munich/DE, I. Thoma, Munich/DE, A. Deutsch, Munich/DE, T. Gehrke, Munich/DE, P. Mayer, Munich/DE, H. Zipse, Munich/DE, T. Carell, Munich/DE M106 Mechanistic Investigations of Radical Intermediates in NHC-Catalysed Cyclisation Reactions J. Phan, Hamburg/DE, J. Rehbein, Hamburg/DE T121 Metallosupramolecular aggregates of dissymmetric 4,15-disubstituted [2.2] paracyclophanes J. Anhäuser, Bonn/DE, A. Lützen, Bonn/DE M107 Syntheses of natural HDAC-inhibitors and derivatives thereof P. Servatius, Saarbrücken/DE T122 One-pot hydroformylation /Michael addition reactions of acrylates S. Quintero-Duque, Regensburg/DE, I. Fleischer, Regensburg/DE M108 Synthesis of Tryptophan containing Natural Products and Derivatives thereof L. Junk, Saarbrücken/DE T123 Development of new biocatalytic tools for heterocycle synthesis T. Hollmann, Bayreuth/DE, G. Berkhan, Hannover/DE, F. Hahn, Bayreuth/DE M109 Carbohydrate Receptors Combining both a Macrocyclic Building Block and Flexible Side-Arms as Recognition Units: Structure-Activity Relationship Studies F. Amrhein, Freiberg/DE, B. Ebersbach, Freiberg/DE, M. Mazik, Freiberg/DE T124 Metal Free Carboamination of Internal Alkynes – An Easy Access to Polysubstituted Quinolines T. Stopka, Aachen/DE M110 Cyclopentanoids by Uncatalyzed Intramolecular Carbonyl Ene (ICE) Reaction of α-Keto Esters D. Tymann, Dortmund/DE, D. C. Dragon, Dortmund/DE T125 N-substituted porphyrins M. Roucan, Dublin/IE, M. O. Senge, Dublin/IE M111 Aza-Wittig enabled stereoselective total synthesis of urukthapelstatin A A. Oberheide, Jena/DE, H.-D. Arndt, Jena/DE T126 Structural Chemistry of Dodecasubstituted Porphyrins K. J. Flanagan, Dublin/IE, M. O. Senge, Dublin/IE M112 Advances in the Functionalization of Cubane, for Use as a Scaffold in the Synthesis of Multiporphyrin Arrays G. Locke, Dublin/IE, S. S. R. Bernhard, Dublin/IE, S. Plunkett, Dublin/IE, M. O. Senge, Dublin/IE T127 A conformational Study of Porphyrins with ´few´ Substituents K. J. Flanagan, Dublin/IE, M. O. Senge, Dublin/IE T128 Dynamics in N-Heterocyclic Carbene-Stabilized Carbon-Centred Radicals S. Malcherek, Hamburg/DE, J. Rehbein, Hamburg/DE 14 15 POSTER LIST POSTER LIST T129 Total synthesis and biological evaluation of Cyclomarin analogues A. Kiefer, Saarbrücken/DE T145 Catalytic Synthesis of Difluoromethyl Cyclopropanes K. J. Hock, Aachen/DE, L. Mertens, Aachen/DE, R.M. Koenigs, Aachen/DE T130 Quantifying London dispersion with Gomberg-type model systems S. Rösel, Giessen/DE, P. R. Schreiner, Giessen/DE T146 T131 Cooperative Catalysis: Calcium and Camphorsulfonic Acid Catalyzed Cycloisomerization of Diynols M. Rauser, Aachen/DE, S. Schroeder, Aachen/DE, M. Niggemann, Aachen/DE Fluoroalkyl-substituted Diazoalkanes – Powerful Reagents for the Synthesis of Fluorinated Heterocycles L. Mertens, Aachen/DE, K. J. Hock, Aachen/DE, R. M. Koenigs, Aachen/DE T147 T132 Enantioselective Synthesis of Guaianolides of the Osmitopsin family by Domino Metathesis A. Barthel, Dresden/DE, F. Kaden, Dresden/DE, P. Metz, Dresden/DE Intra- versus Intermolecular Electron Transfer in Radical Nucleophilic Aromatic Substitution of Diiodo(hetero)arenes – a Tool for Estimating Electron Mobility in p-Systems B. Janhsen, Münster/DE, A. Studer, Münster/DE T148 Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Internal Alkynes with Alcohols Leading to Branched Allylic Ethers Z. Liu, Freiburg/DE T149 Tetrasubstituted Enol Ethers via an anti-Carbopalladation/Alkoxylation Cascade T. Schitter, Braunschweig/DE, D. B. Werz, Braunschweig/DE T150 Metal-Free C-S Coupling Reactions Mediated by Weak Bases D. Koziakov, Regensburg/DE, M. Majek, Regensburg/DE, A. Jacobi von Wangelin, Regensburg/DE T151 Rigidity-controlled Supramolecular Affinity Materials and their Application for Gravimetric Detection of Hazardous and Illicit Compounds D. Ryvlin, Mainz/DE, I. Pyka, Mainz/DE, S. R. Waldvogel, Mainz/DE T152 Synthesis of Fluorescently Labeled Glycosphingolipids for Biophysical Investigations K. Kettelhoit, Braunschweig/DE, D. B. Werz, Braunschweig/DE T153 C−H Activation of Diamondoids by Pd(OAc)2 M. Larrosa Ferreiro, Giessen/DE, R. Hrdina, Giessen/DE T154 Synthesis of New Perfluorinated Pyridinium Based Ionic Liquids T. Alpers, Oldenburg/DE, J. Christoffers, Oldenburg/DE T155 Bifunctional Diaminoterephthalic Acid Derivatives as New Tools for Life Sciences L. Buschbeck, Oldenburg/DE, J. Christoffers, Oldenburg/DE T156 The Postfunctionalization of Rhodium(II) Complexes J.-P. Berndt, Giessen/DE, P. R. Schreiner, Giessen/DE, R. Hrdina, Giessen/DE T157 Intramolecular C–H Amination Reactions Provide Access to Disubstituted Diamondoids R. Hrdina, Giessen/DE T158 Air Stable Diamondoid Phosphines O. Moncea, Giessen/DE, A. A. Fokin, Kiev/UA, P. R. Schreiner, Giessen/DE, J. C. Hierso, Dijon/FR T159 London dispersion interactions in [121]tetramantane dimers M. Sekutor, Giessen/DE, P. R. Schreiner, Giessen/DE T133 Stereoelectronic effects in sulfide, sulfoxide, and sulfone α-carbanions J. Podlech, Karlsruhe/DE, B. D. Süveges, Karlsruhe/DE, S. Hönig, Karlsruhe/DE T134 Iron-Catalyzed Cross-Coupling Reactions of Allylic Acetates J. Bernauer, Regensburg/DE T135 Synthesis of small molecules for optical and whole body imaging of CCR6 R. Vidyadharan, Münster/DE, G. Haufe, Münster/DE, L. Li, Münster/DE, L. Sorokin, Münster/DE T136 New modular concept for the synthesis and structural assignment of Asitrilobin A, an Annonaceae acetogenin, potent anti-cancer agent J. van Kempen, Münster/DE, J. Kerschbaumer, Münster/DE, H. Schimanski, Münster/DE, G. Haufe, Münster/DE T137 C3-Symmetric tricyclo[2.2.1.0 ]heptane-3,5,7-triol V. Kozel, Münster/DE, P. Kirsch, Darmstadt/DE, G. Haufe, Münster/DE T138 Catalytic Hydrogen Autotransfer Alkylation of Pyrroles with Alcohols S. Koller, Garching/DE, L. Hintermann, Garching/DE T139 Comparative Study of anti-Markovnikov Alkyne Hydration Catalysts: Is there Evidence for a Ru(II)/Ru(IV) Mechanism? M. Schreyer, Garching/DE, L. Hintermann, Garching/DE 2,6 T140 Towards the Total Synthesis of Chondrochloren J. Geldsetzer, Braunschweig/DE, M. Kalesse, Hannover/DE T141 New Ligand Concepts for Cerium-Catalyzed Asymmetric α-Hydroxylation B. Schäfer, Oldenburg/DE, J. Christoffers, Oldenburg/DE T142 Formation of 1,4-Diketones and δ-Lactones by Cerium-Catalyzed Coupling of β-Oxoesters, Enol Acetates and Dioxygen I. Geibel, Oldenburg/DE, J. Christoffers, Oldenburg/DE T143 Deoxygenation of benzylic alcohols via transfer hydrogenation B. Ciszek, Regensburg/DE, I. Fleischer, Regensburg/DE T144 Iron-Phosphine Catalysts for Dealkoxylative Cross-Coupling Reactions S. Sandl, Regensburg/DE, D. Gärtner, Regensburg/DE 16 17 POSTER LIST T160 Immobilization of Polymers on Self-assembled Structures via Nitroxide Photoclick Trapping L. Hesping, Münster/DE, F. Schibilla, Münster/DE, U. Keller, Münster/DE, J. Klingauf, Münster/DE, B. J. Ravoo, Münster/DE, A. Studer, Münster/DE T161 Diaminoterephthalic Acid Derivatives – Fluorescent Dyes for Life Sciences M. Wallisch, Oldenburg/DE, J. Christoffers, Oldenburg/DE T162 Visible-light photoredox catalysis with [Ru(bpy)3]Cl2 M. Neumeier, Regensburg/DE, M. Májek, Regensburg/DE T163 Mechanochemical Cycloreversion of Cyclobutane Observed at the Single Molecule Level U. Lüning, Kiel/DE, K. Holz, Kiel/DE, M. F. Pill, Munich/DE, N. Preußke, Kiel/DE, F. Berger, Innsbruck/AT, H. Clausen-Schaumann, Munich/DE, M. K. Beyer, Innsbruck/AT T164 Development of organocatalytic pericyclic reactions for the synthesis of complex organic molecules C. Apel, Berlin/DE, M. Christmann, Berlin/DE T165 Synthesis of Functionalized Propellanes L. M. Schneider, Berlin/DE, V. M. Schmiedel, Berlin/DE, T. Pecchioli, Berlin/DE, M. Christmann, Berlin/DE T166 Studies toward the synthesis of caylobolide A L. Grothues, Berlin/DE, M. Christmann, Berlin/DE T167 Studies towards the Total synthesis of Actinoranone M. Menger, Berlin/DE T168 Peptide-catalyzed Baeyer-Villiger Oxidation D. Niedek, Giessen/DE, S. M. M. Schuler, Giessen/DE, P. R. Schreiner, Giessen/DE T169 Lewis acids as activators in CBS-catalyzed Diels-Alder reactions – Distortion induced Lewis acidity enhancement of SnCl4 R. Möckel, Marburg/DE, A. R. Nödling, Marburg/DE, R. Tonner, Marburg/DE, G. Hilt, Marburg/DE T170 Highly Reactive Nickel Catalyst for Olefin Isomerization F. Weber, Marburg/DE T171 Design, Synthesis and Pharmacological Evaluation of ABCG2 Modulators S. Stark, Regensburg/DE T172 Photocatalytically activated reduction systems for enzymatic reactions M. Hacker, Regensburg/DE T173 Synthesis of Pyrroloquinoline Alkaloids Isolated from Fruiting Bodies of Mycena Species B. Reck, Bremen/DE, P. Spiteller, Bremen/DE T174 Separation and Identification of Muscarin Isomeres A. Treu, Bremen/DE, P. Spiteller, Bremen/DE, T. Dülcks, Bremen/DE 18 POSTER LIST T175 Polyarylacetylenes as Chiral Alignment Media:Improved Properties by Vinylrhodium Initiated Polymerization A. Proskurjakov, Darmstadt/DE, M. Reggelin, Darmstadt/DE T176 Photocatalytic α-Cyanation of Tertiary Amines using Rose Bengal and Non-toxic Cyanide Sources A. M. Nauth, Mainz/DE, J. C. Orejarena Pacheco, Mainz/DE, A. Lipp, Mainz/DE, Ž. Papadopulu, Mainz/DE, N. Vierengel, Mainz/DE, T. Opatz, Mainz/DE T177 Highly Enantioselective Titanium-Salalen Catalyzed Epoxidation of NonConjugated Terminal Olefins Using Hydrogen Peroxide As Oxidant T. Leuther, Cologne/DE, M. Lansing, Cologne/DE, H. Engler, Cologne/DE, A. Berkessel, Cologne/DE T178 New Syntheses of Pterocarpenes and Aza-Analogues L. Biondo, Saarbrücken/DE T179 Synthesis of Aurachins: 4-prenylated quinolines via Suzuki-coupling L. Stief, Saarbrücken/DE T180 To what degree is London dispersion solvent dependent? Re-vitalizing an old molecular balance J. M. Schümann, Giessen/DE, P. R. Schreiner, Giessen/DE T181 Synthesis of novel asymmetric, clickable diphosphate tweezers for regioselective protein surface recognition A. Sowislok, Essen/DE T182 Synthesis of fluorinated analogs of a leishmanial LPG capping structure for vaccine development A. Baumann, Munich/DE, S. Marchner, Munich/DE, M. Daum, Munich/DE, A. Hoffmann-Röder, Munich/DE T183 Synthesis of fluorinated capsular polysaccharide antigens of Streptococcus pneumoniae D. Gast, Munich/DE, M. Reindl, Munich/DE, A. Hoffmann-Röder, Munich/DE T184 Selective Tryptophan Isotope Labeling by Using E. coli Overexpression Media J. Schörghuber, Vienna/AT, R. Lichtenecker, Vienna/AT, M. Bisaccia, Vienna/AT, W. Schmid, Vienna/AT, R. Konrat, Vienna/AT T185 Studies towards the Total Synthesis of Bilobalide using Photochemical Key Steps J. Emsermann, Mainz/DE T186 Novel Syntheses Towards 5,7-Diamino-3,5,7,9-tetradeoxy-nonulosonic Acids M. Gintner, Vienna/AT, Y. Yoneda, Shizuoka/JP, C. Schmölzer, Linz/AT, W. Schmid, Vienna/AT T187 Iron-Catalyzed Cross-Coupling of Secondary Alkyl Chlorides E. Reyes-Rodriguez, Regensburg/DE, S. Grupe, Regensburg/DE, E. B. Bauer, Missouri/US, D. R. Kempe, Bayreuth/DE, A. Jacobi von Wangelin, Regensburg/DE 19 POSTER LIST POSTER LIST T188 Mass Spectrometric Challenges: Investigation of a HAuCl4 catalysed reaction M. T. S. Schmidt, Bonn/DE T203 Hydroxycarbenes in Synthesis M. M. Linden, Giessen/DE, P. R. Schreiner, Giessen/DE T189 Reactions of Donor-Acceptor Cyclopropanes with Carbonyl Ylides M. Petzold, Braunschweig/DE, D. B. Werz, Braunschweig/DE T204 T190 Synthesis of trifluoromethylated compounds as potential scaffolds in medicinal chemistry using N-aryl hemiaminal ethers S. Wunder, Munich/DE, A. Deutsch, Munich/DE, A. Hoffmann-Röder, Munich/DE Using mass spectrometry for mechanistic studies on organic reactions J. A. Willms, Bonn/DE, R. Beel, Bonn/DE, M. L. Schmidt, Bonn/DE, C. Mundt, Bonn/DE, M. Engeser, Bonn/DE T205 BOIMPYs – New Members Approaching the BODIPY Family L. J. Patalag, Braunschweig/DE T206 Ruthenium(II)-Catalyzed C–H Functionalizations of Benzoic Acids A. Bechtoldt, Göttingen/DE, C. Kornhaaß, Göttingen/DE, L. Ackermann, Göttingen/DE T207 Synthesis of Tetrahydrothiopene Derivatives via Lewis-Acid Catalyzed Cyclopropane/Thioketone Cycloadditions A. U. Augustin, Braunschweig/DE, M. Sensse, Braunschweig/DE, D. B. Werz, Braunschweig/DE T208 Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Fundamental Studies Revealing the Active Catalytic Species and the Key Roles of Ligand and Additive I. Kalvet, Aachen/DE, F. Schoenebeck, Aachen/DE T209 A Co-Catalyzed Desymmetrization of Quaternary Centers by Hydroacylation to form Cyclobutanones Selectively J. Riedel, Irvine/US, D. Kim, Irvine/US, V. Dong, Irvine/US T210 Studies toward the Asymmetric Synthesis of the Norhasubanan Alkaloid (+)-Stephadiamine N. Vrielink, Munich/DE, B. M. Stoltz, Pasadena/US, D. Trauner, Munich/DE T211 A mild base-mediated Conia-Ene type cyclization for the total synthesis of lycoposerramine-R F. W. W. Hartrampf, Munich/DE, T. Furukawa, Osaka/JP, D. Trauner, Munich/DE T212 Total Synthesis of Nosiheptide and first SAR studies K. P. Wojtas, Jena/DE, T. Winkler, Jena/DE, S. Walter, Jena/DE, H.-D. Arndt, Jena/DE T191 Oxidative Allylic Esterification of Alkenes by Cooperative Selenium Catalysis using Air as the Sole Oxidant S. Ortgies, Göttingen/DE, C. Depken, Göttingen/DE T192 One-pot transformation of styrene into enantiopure 1phenylethylamin: formal asymmetric hydroamination of unactivated alkenes F. Uthoff, Bielefeld/DE, H. Sato, Osaka/JP, H. Gröger, Bielefeld/DE T193 Studies toward the synthesis of fluorinated N. meningitidis W135 antigens M. Reindl, Munich/DE, M. Daum, Munich/DE T194 Cyanide-free, enantioselective nitrile synthesis with aldoxime dehydratases – Synthetic potential of an unusual enzyme class T. Betke, Bielefeld/DE, P. Rommelmann, Bielefeld/DE, K. Oike, Bielefeld/DE, H. Gröger, Bielefeld/DE, Y. Asano, Toyama/JP T195 The Enantioselective Dakin-West Reaction R. C. Wende, Giessen/DE, A. Seitz, Giessen/DE, D. Niedek, Giessen/DE, S. M. M. Schuler, Giessen/DE, C. Hofmann, Giessen/DE, J. Becker, Giessen/DE, P. R. Schreiner, Giessen/DE T196 Evaluation of quorum sensing mechanism in host organisms and bacteria. S. Schwarz, Hamburg/DE, W. Maison, Hamburg/DE T197 One-Pot Synthesis of 5-Hydroxy-4H-1,3-thiazin-4-ones: Structure Revision of Thiasporine A T. Seitz, Berlin/DE, M. Christmann, Berlin/DE T198 Total Synthesis of a new Fusaricidin-Type Cyclodepsipeptide M. Reimann, Mainz/DE, T. Opatz, Mainz/DE T213 Trifluoromethylhydroxycarbene: Conformer-Specific Hydrogen Atom Tunneling H. Quanz, Giessen/DE, A. Mardyukov, Giessen/DE, P. R. Schreiner, Giessen/DE T199 C-SeCF3 Bond Formation via Dinuclear Pd(I) Catalysis T. Sperger, Aachen/DE, F. Schoenebeck, Aachen/DE T214 T200 Organocatalytic alkene syn-dihydroxylation utilizing a chiral cyclic peroxide A. Pilehvarlangroodi, Giessen/DE Synthesis and application of Diazocine-Photoswitches in the backbone of peptides M. T. Gailer, Munich/DE, T. Podewin, Munich/DE, A. Hoffmann-Röder, Munich/DE T215 T201 Fluoride-activated calcium carbide in the synthesis of terminal alkynes A. Hosseini Pichikola, Giessen/DE Synthetic studies towards Xenicane-diterpenes V. M. Schmiedel, Berlin/DE T216 T202 Crinine-Type Alkaloid Syntheses: Generation of Key Intermediates via Stereoselective Introduction of the Quaternary Carbon Center N. Kümmerer, Mainz/DE, S. Bernhard, Mainz/DE Understanding the reactivity of ene yne reactive platforms. Formation of allenes,isochromanes and furanones through different activation modes C. Ascheberg, Aachen/DE T217 Oxidative Methoxy Carbonylation of Vinyl Stannanes: Application to Formal Synthesis of Tubelactomicin A H. Sommer, Mülheim/DE, A. Fürstner, Mülheim/DE 20 21 POSTER LIST T218 Bacterial Alkaloids Prevent Amoebal Predation M. Klapper, Jena/DE, S. Götze, Jena/DE, R. Barnett, Jena/DE, K. Willing, Jena/DE, P. Stallforth, Jena/DE T219 Design of a Chemical Probe of a Eukaryotic Signal Involved in Multicellular Development R. Barnett, Jena/DE, R. Barnett, Jena/DE, P. Stallforth, Jena/DE T220 Calcium-catalyzed dynamic multicomponent reaction S. Gao, Aachen/DE T221 Synthesis of Guaiane Sesquiterpenes and New (–)-Englerin A Analogs T. Siemon, Berlin/DE T222 Zwitterionic “stealth” reagents for PET and SPECT imaging of cancer. F. Rueping, Hamburg/DE, W. Maison, Hamburg/DE T223 Nickel-catalyzed Trifluoromethylthiolation of Csp2–O Bonds: A Case of Computational Assistance of Method Development A. B. Dürr, Aachen/DE, G. Yin, Aachen/DE T224 Electron-Catalysed Fluoroalkylation of Vinyl Azides E. G. Mackay, Münster/DE T225 Biarylic Base Pair Ligands For Sequence-Selective DNA Recognition M. S. Peters, Essen/DE, S. Gadre, Essen/DE, T. Schrader, Essen/DE T226 Studies towards the Total Synthesis of Integramycin J. Trenner, Braunschweig/DE, E. Prusov, Braunschweig/DE T227 Visible-light Photocatalysis with Organic Dyes M. Májek, Regensburg/DE, A. Jacobi von Wangelin, Regensburg/DE T228 Chalcogenation at Dinuclear Pd(I) sites T. Scattolin, Aachen/DE, F. Schoenebeck, Aachen/DE T229 Ortho-Trialkylstannyl Arylphosphanes via C-P and C-Sn Bond Formation in Arynes Y. Li, Münster/DE, A. Studer, Münster/DE, C. Mück-Lichtenfeld, Münster/DE, S. Chakrabarty, Münster/DE T230 Merging Calcium- and Copper- Catalysis: Synthesis of Substituted Heterocycles S. Schroeder, Aachen/DE, M. Rauser, Aachen/DE, M. Niggemann, Aachen/DE T231 Regio- and Stereoselective Cyanotriflation of Alkynes Using Aryl(cyano)iodonium Triflates X. Wang, Münster/DE T232 Synthesis and Application of new DOTA-derivatives M. Holzapfel, Hamburg/DE, E. Kriemen, Hamburg/DE, W. Maison, Hamburg/DE T233 Intragel Photoreduction of Aryl Halides by Green-to-Blue Upconversion under Aerobic Conditions M. Häring, Regensburg/DE, A. J. von Wangelin, Regensburg/DE, R. Pérez-Ruiz, Regensburg/DE 22 POSTER LIST T234 Brønsted Acid-Catalyzed Addition of Enamides to ortho-Quinone Methide Imines – Efficient and Highly Enantioselective Synthesis of Chiral Tetrahydroacridines M. Kretzschmar, Leipzig/DE, C. Schneider, Leipzig/DE, T. Hodík, Leipzig/DE T235 New Approaches to Symmetric and Non-symmetric Molecular Tweezers for Protein Surface Recognition C. Heid, Essen/DE, T. Schrader, Essen/DE T236 Brønsted Acid Catalyzed [3+2]-Cycloaddition of 2-Vinylindoles with In Situ Generated 2-Methide-2H-indoles – Highly Enantioselective Synthesis of Pyrrolo[1,2-a]indoles K. Bera, Leipzig/DE T237 Brønsted Acid-Catalyzed, Conjugate Addition of β-Dicarbonyls toward in situ Generated Ortho-Quinomethides – Enantioselective Synthesis of 4-Aryl-4HChromenes S. Haseloff, Leipzig/DE T238 Synergistic Rhodium/Phosphoric Acid Catalysis for the Enantioselective Addition of Oxonium Ylides to ortho-Quinone Methides M. Spanka, Leipzig/DE, C. Schneider, Leipzig/DE, S. Kumar Allamsetti, Leipzig/DE T239 Efficient Acrylation of Organosolv Lignin using their Subunits 4-Hydroxy-3methoxybenzylalcohol,Syringol and Guajacol as a model to establish the conversion process M. Tretbar, Leuna/DE, C. Rossberg, Leuna/DE 23 GENERAL INFORMATION CONFERENCE VENUE GENERAL INFORMATION ACCOMMODATION The conference will take place in the Rooms are reserved for the participants in various hotels throughout the city. Congress Centrum Neue Weimarhalle UNESCO-Platz 1 99423 Weimar, Germany Internet: www.weimarhalle.de Reservations can be made on the HRS Online Booking Portal, see www.gdch.de/orchem2016, “Accommodation” Alternatively, please contact HRS – HOTEL RESERVATION SERVICE Phone: +49 221 2077 7320 E-mail:[email protected] TRAVEL INFORMATION Arrival by Plane Erfurt Airport is located 45 km from Weimar. Trains to Weimar (travel time around 1 hour) are leaving every 30 minutes. Arrival by car The Congress Centrum Neue Weimarhalle is located in the city centre of Weimar near Goetheplatz. There are signs to the Congress Centrum Neue Weimarhalle at all main roads in Weimar. A4 from Frankfurt/Dresden Take exit „Weimar“ (exit 49) and follow the B85 to Weimar (4 km). In Weimar, follow the signs to center of Weimar (Goetheplatz) and to Congress Centrum Neue Weimarhalle. B7 from Erfurt or Jena Follow the signs to the center of Weimar (Goetheplatz) and to Congress Centrum Neue Weimarhalle. Parking near Congress Centrum Neue Weimarhalle • underground car park Congress Centrum Neue Weimarhalle • car park opposite the entrance to the underground car park • underground car park Weimar Atrium • large car park Stadionvorplatz (Herbststraße) for cars and coaches, 5 min. walk Public Transport After arrival at Weimar main station, take bus line 1 direction Ehrendorf, line 5 direction Klinikum, line 7 direction Weimar West or line 8 direction Klinikum/Merketal. Exit at bus stop Goetheplatz (around 6 minutes busride). The Congress Centrum Neue Weimarhalle is located in 2 minutes walking distance from the bus stop. Walk towards the main post office and turn left into Schwanenseestraße. Go through an entrance gate on the right side of the street to UNESCO-Platz – you will see the Congress Centrum Neue Weimarhalle in front of you. Arrival by Train The „Deutsche Bahn“ offers attractive conditions for travelling to GDCh events. Further information can be found at www.gdch.de/bahn 24 Bookings should be made not later than July 5, 2016 under the keyword „ORCHEM 2016”. The customers will be held accountable for non-occupancy of reserved rooms. REGISTRATION Please register online via internet no later than July 24, 2016 www.gdch.de/orchem2016 GESELLSCHAFT DEUTSCHER CHEMIKER e.V. Silvia Kirrwald – Congress Team Postfach 90 04 40 60444 Frankfurt am Main GERMANY Phone: +49 69 7917-358 E-mail:[email protected] Internet:www.gdch.de All tickets and congress papers will be handed to the participants upon check-in at the registration desk. Participants are requested to wear their congress badge at all times for identification and admittance to the conference rooms. By online registration, payment by credit card or direct debit is preferred. If you wish to pay by bank transfer (free of bank commission) please do not forget to print the invoice at the end of your online-registration. GESELLSCHAFT DEUTSCHER CHEMIKER e.V. IBAN DE85 5008 0000 0490 0200 00 SWIFT-BIC DRES DE FF Commerzbank AG, Frankfurt am Main Code: 5200 37 / ORCHEM 2016 25 GENERAL INFORMATION GENERAL INFORMATION REGISTRATION FEES* DEADLINES GDCh-member and member of EuCheMS-member societies e 250,- Member, unemployed or retired e 130,- Non-member e 300,- Student – GDCh-member** e 100,- Student – Non-member** e 110,- Gold member (with over 50 years of GDCh membership) free of charge *) The registration fees are not liable to value added tax (tax exemption addditional § 4 Nr. 22a UStG.) **)Valid student card required If fees are paid in advance, but after August 21, 2016, we kindly ask participants to show proof of payment when claiming their tickets and conference papers at the conference office. Onsite payment only by electronic cash or credit card (Amex, Mastercard, VISA). July 5, 2016 July 24, 2016 July 24, 2016 Room reservation Personal registration Cancellation of participation INFORMATION CONCERNING THE SCIENTIFIC PROGRAM Prof. Dr. Peter R. Schreiner Justus Liebig University Giessen Institute of Organic Chemistry Heinrich-Buff-Ring 17 35392 Giessen Germany Phone: +49 641 99 34301 E-mail: [email protected] INFORMATION DURING THE CONFERENCE The conference office will be located in the foyer in front of the lecture hall. CANCELLATION Written cancellations received on or before July 24, 2016 will be refunded less a e 25,- administration fee. After that date the full amount of the invoice has to be paid. Requests for refund will not be accepted; however, registration may be transferred to another member of your organization. In this case please send a note to GDCh, Congress Team to [email protected]. If the conference is cancelled for whatever reason, fees paid will be refunded. Further recourse is excluded. COFFEE BREAKS The participant fee includes free refreshments at coffee breaks. LUNCH There are several restaurants within walking distance from the Weimarhalle. COPYRIGHT PERMISSION Photos made on GDCh conferences are used exclusively by GDCh for documentation, news coverage and advertisement. Opening hours: Monday, September 5, 2016 Tuesday, September 6, 2016 Wednesday, September 7, 2016 12.00 – 17.30 hrs 08.00 – 17.00 hrs 08.30 – 11.00 hrs INFORMATION BEFORE AND AFTER THE CONFERENCE GESELLSCHAFT DEUTSCHER CHEMIKER e.V. (German Chemical Society) Silvia Kirrwald – Congress Team P.O. Box 90 04 40 60444 Frankfurt am Main GERMANY Varrentrappstr. 40-42 60486 Frankfurt am Main GERMANY Phone: +49 69 7917-358 E-mail: [email protected] Internet:www.gdch.de/tagungen Executive Director: Professor Dr. Wolfram Koch, Registernummer beim Vereinsregister: VR 4453, Registergericht Frankfurt am Main Date: August 2016 26 27