ALEC TIRANTI LIMITED
Transcription
ALEC TIRANTI LIMITED
ALEC TIRANTI LIMITED TOOLS, MATERIALS & EQUIPMENT FOR MODELLING, CARVING, SCULPTURE 3 Pipers Court, Berkshire Drive, Thatcham, Berks RG19 4ER Tel: 0845 123 2100 Fax: 0845 123 210 London Shop: 27 Warren Street London W1T 5NB Tel & Fax: 020 7380 0808 Material Safety Data Sheet RTV T30 Catalyst Revision 6 Revision date 2014-08-20 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Catalyst C15 1.2. Relevant identified uses of the substance or mixture and uses advised against Description Restricted to professional users. RTV silicone for mould making. 1.3. Details of the supplier of the safety data sheet Company Alchemie Ltd Address Warwick Road Kineton Warwick CV35 0HU United Kingdom Web www.alchemie.com Telephone +44 (0) 1926 641600 Fax +44 (0) 1926 641698 Email [email protected] Email address of the competent person [email protected] 1.4. Emergency telephone number Emergency telephone number +44 (0) 1926 641600 08:30-17:00 Mon-Fri SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.1.1. Classification - 1999/45/ЕC T+; R26 T; R60-61 Xn; R22-68 Xi; R36/38 Symbols: T+: Very toxic. Main hazards Harmful if swallowed. Very toxic by inhalation. Irritating to eyes and skin. May impair fertility. May cause harm to the unborn child. Possible risk of irreversible effects. 2.2. Label elements Symbols T+: Very toxic. Risk phrases R22 - Harmful if swallowed. R26 - Very toxic by inhalation. R36/38 - Irritating to eyes and skin. R60 - May impair fertility. R61 - May cause harm to the unborn child. R68 - Possible risk of irreversible effects. Safety phrases S28 - After contact with skin, wash immediately with plenty of water. S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use. S63 - In case of accident by inhalation: remove casualty to fresh air and keep at rest. 2.3. Other hazards Other hazards Not applicable. SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/548/EEC / 1999/45/EC Chemical Name Index No. Tetraethyl silicate (Tetraethylacetate) Dibutyltin dilaurate 014-00500-0 CAS No. EC No. 78-10-4 201-0838 77-58-7 201-0398 REACH Registration Number 01211949619528 Conc.(%w/w) Classification 50 - 100% R10 Xn; R20 Xi; R36/37 T+; R26 T; R60-61 Xn; R22-68 Xi; R36/38 N; R50/53 4.1. Description of first aid measures Inhalation Toxic by inhalation. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Inhalation of vapour may cause shortness of breath. Move the exposed person to fresh air. Seek medical attention. Eye contact May cause irritation to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Skin contact May cause sensitisation by skin contact. Wash off immediately with plenty of soap and water. Seek medical attention. Ingestion May cause irritation to mucous membranes. DO NOT INDUCE VOMITING. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 4.2. Most important symptoms and effects, both acute and delayed Inhalation Prolonged or repeated exposure may cause: Sensitization. Toxic if inhaled. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Inhalation of vapour may cause shortness of breath. Sensitizer, Lungs. Eye contact May cause irritation to eyes. Skin contact May cause sensitisation by skin contact. Ingestion May cause irritation to mucous membranes. 4.3. Indication of any immediate medical attention and special treatment needed If you feel unwell, seek medical advice (show the label where possible). Remove the affected person from the source of contamination immediately. SECTION 5: Firefighting measures 5.1. Extinguishing media Use as appropriate: Foam, Carbon dioxide (CO2). For large fires:. Water spray. Do NOT use water jet. 5.2. Special hazards arising from the substance or mixture Carbon oxides may be formed in fire conditions. Burning produces irritating, toxic and obnoxious fumes. Move containers away from fire if it can be done without risk. 5.3. Advice for firefighters Wear self contained breathing apparatus and protective clothing. Do not allow product to enter drains. Do not allow runoff water to enter sewers or drains. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation of the working area. Wear suitable protective equipment. 6.2. Environmental precautions Do not allow product to enter drains. Prevent further spillage if safe. 6.3. Methods and material for containment and cleaning up Remove mechanically; cover the remainder with wet, absorbent material (e.g. sawdust, chemical binder based on calcium silicate hydrate, sand). After approximately one hour transfer to waste container and do not seal (evolution of CO2!). Transfer to suitable, labelled containers for disposal. Clean area thoroughly with detergent. 6.4. Reference to other sections See section 1 for further information. See section 8 for further information. See section 13 for further information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Avoid contact with eyes and skin. Wear suitable protective equipment. Wear suitable respiratory equipment when necessary. Do not eat, drink or smoke in areas where this product is used or stored. 7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed and in a well-ventilated place. Keep containers tightly closed. 7.3. Specific end use(s) Wear suitable protective equipment. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1. Exposure Limit Values Dibutyltin dilaurate WEL 8-hr limit ppm WEL 15 min limit ppm Tetraethyl silicate (Tetraethylacetate) DIR: - WEL 8-hr limit mg/m3: 0.1 (as Sn) WEL 15 min limit mg/m3: 0.2 (as Sn) 8hTWA ppm: 50 8hTWA mg/m3: 120 STEL mg/m3: 300 STEL ppm: 100 NOT: Skin 8.2. Exposure controls 8.2.1. Appropriate engineering controls Ensure adequate ventilation of the working area. 8.2.2. Individual protection measures Wear suitable protective equipment. Wear suitable gloves and eye/face protection. Eye / face protection Approved safety goggles. Avoid contact with eyes. Skin protection Handprotection Wear:. Latex rubber gloves. Nitrile rubber gloves. Wash hands after handling the product. Respiratory protection Do not breathe gas/fumes/vapour/spray. Wear suitable respiratory equipment when necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State Liquid Colour Yellow Odour Aromatic Relative density 1.1 - 1.15 (Water = 1 @ 20 °C) Viscosity 10 mPa.s (25°C) SECTION 10: Stability and reactivity 10.1. Reactivity Reacts with water. Avoid contact with:. Water. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Will not decompose if stored and used as recommended. 10.4. Conditions to avoid Avoid contact with: Water. Eliminate all sources of ignition. 10.5. Incompatible materials Avoid contact with: Water. 10.6. Hazardous decomposition products Will not decompose if stored and used as recommended. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Toxic by inhalation. Skin corrosion/irritation Irritating to skin. Respiratory or skin sensitisation May cause sensitisation by inhalation and skin contact. Germ cell mutagenicity No data is available on this product. Carcinogenicity No data is available on this product. Reproductive toxicity No data is available on this product. 11.1.4. Toxicological Information Dibutyltin dilaurate Tetraethyl silicate Dermal Rat LD50: > 2000 mg/kg Inhalation Mouse LC50/120min: 0.15 mg/l Inhalation Rat LC50/4 h: 10 - 16 mg/kg Oral Rat LD50: > 2500 mg/kg Dermal Rabbit LD50: 5878 mg/kg SECTION 12: Ecological information 12.1. Toxicity Tetraethyl silicate Fish LC50/96h: 245.000000 mg/l Algae EC50/72h: > 100 mg/l Brachydanio Rerio LC50/96h: > 245 mg/l 12.2. Persistence and degradability No data is available on this product. 12.3. Bioaccumulative potential No data is available on this product. 12.4. Mobility in soil No data is available on this product. 12.5. Results of PBT and vPvB assessment Not classified as PBT or VPvB. 12.6. Other adverse effects No known significant effects or critical hazards. SECTION 13: Disposal considerations General information Dispose of in compliance with all local and national regulations. Disposal methods Incinerate in suitable incineration plant, observing local authority regulations. Disposal of packaging Containers must be recycled in compliance with national legislation and environmental regulations. Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. SECTION 14: Transport information Hazard pictograms 14.1. UN number UN2788 14.2. UN proper shipping name ORGANOTIN COMPOUND, LIQUID, N.O.S. (Contains: Dibutyltin dilaurate; tetraethyl silicate) 14.3. Transport hazard class(es) ADR/RID 6.1 Subsidiary risk IMDG 6.1 Subsidiary risk IATA 6.1 Subsidiary risk 14.4. Packing group Packing group II 14.5. Environmental hazards Environmental hazards Yes Marine pollutant Yes ADR/RID Hazard ID 60 Tunnel Category (D/E) IMDG EmS Code F-A S-A IATA Packing Instruction (Cargo) 661 Maximum quantity 60 L Packing Instruction (Passenger) 654 Maximum quantity 5L SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations No specific regulations apply to this product. 15.2. Chemical safety assessment Very toxic by inhalation. SECTION 16: Other information Revision This document differs from the previous version in the following areas:. 15 - 15.2. Chemical safety assessment. Text of risk phrases in Section 3 R10 - Flammable R20 - Harmful by inhalation. R22 - Harmful if swallowed. R26 - Very toxic by inhalation. R36/37 - Irritating to eyes and respiratory system. R36/38 - Irritating to eyes and skin. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R60 - May impair fertility. R61 - May cause harm to the unborn child. R68 - Possible risk of irreversible effects. Further information The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.