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Home Search Collections Journals About Contact us My IOPscience Spectral irradiance measurement and actinic radiometer calibration for UV water disinfection This content has been downloaded from IOPscience. Please scroll down to see the full text. 2014 Metrologia 51 S282 (http://iopscience.iop.org/0026-1394/51/6/S282) View the table of contents for this issue, or go to the journal homepage for more Download details: IP Address: 176.9.124.142 This content was downloaded on 03/12/2014 at 14:56 Please note that terms and conditions apply. Bureau International des Poids et Mesures Metrologia Metrologia 51 (2014) S282–S288 doi:10.1088/0026-1394/51/6/S282 Spectral irradiance measurement and actinic radiometer calibration for UV water disinfection Peter Sperfeld1, Bettina Barton1, Sven Pape1, Anna-Lena Towara1, Jutta Eggers2 and Gabriel Hopfenmüller3 1 Physikalisch-Technische Bundesanstalt, Braunschweig & Berlin, Germany DVGW-Technologiezentrum Wasser, Karlsruhe, Germany 3 sglux SolGel Technologies GmbH, Berlin, Germany 2 E-mail: [email protected] Received 6 June 2014, revised 29 July 2014 Accepted for publication 10 September 2014 Published 20 November 2014 Abstract In a joint project, sglux and PTB investigated and developed methods and equipment to measure the spectral and weighted irradiance of high-efficiency UV-C emitters used in water disinfection plants. A calibration facility was set up to calibrate the microbicidal irradiance responsivity of actinic radiometers with respect to the weighted spectral irradiance of specially selected lowpressure mercury and medium-pressure mercury UV lamps. To verify the calibration method and to perform on-site tests, spectral measurements were carried out directly at water disinfection plants in operation. The weighted microbicidal irradiance of the plants was calculated and compared to the measurements of various actinic radiometers. Keywords: radiometery, UV water disinfection, microbicidal irradiance, actinic radiometer, UV lamps, UV-C (Some figures may appear in colour only in the online journal) 1. Introduction More and more water disinfection systems are equipped with high-efficiency UV emitters, which have to fulfil specific requirements for their spectral irradiance. A high irradiance should be achieved in the spectral range covering the microbicidal action spectrum between 240 nm and 290 nm, whereas below 240 nm, the irradiance should be low, in order to avoid any possible photochemical processes leading to by-product formation. When disinfecting water, a prescribed reduction equivalent dose (RED) has to be applied to guarantee a sufficient microbicidal effect [1]. Depending on the water flowrate and transmittance, defined irradiances in the UV-C spectral range thus have to be achieved and continuously measured. The irradiance is often measured by means of specially adapted actinic radiometers. The radiometer response has to represent the weighted microbicidal irradiance of the UV 0026-1394/14/06S282+7$33.00 emitters. However, the spectral responsivity does not exactly match the microbicidal action spectrum and the readout of the radiometer has to be corrected by its spectral mismatch. The direct spectral responsivity calibration of such actinic radiometers is very limited due to the high spectral power needed for such measurements. Thus, a calibration facility has been constructed, where actinic radiometers are calibrated with respect to the spectral irradiance of typical highpower UV sources. Actinic radiometers that monitor UV lamps cannot provide any information on the spectral distribution of the lamps in the plants. Especially when characterizing new UV devices, or after replacing a lamp, spectral measurements are, however, of great importance. This is the only way to rule out, for example, radiation in the spectral range below 240 nm where undesirable chemical byproducts are generated. Spectral measurements at high UV irradiances, however, place high S282 © 2014 BIPM & IOP Publishing Ltd Printed in the UK P Sperfeld et al Metrologia 51 (2014) S282 requirements on the spectroradiometers used—and the corresponding entrance optics. With specially adapted measuring instruments, and in combination with actinic radiometers, a reliable traceability of the weighted irradiance measurements is possible. In this article the theoretical background for a source-based calibration method is presented. This method requires traceable spectral irradiance measurements and reliable standard sources of a calibration facility to calibrate sensors for high UV irradiances. In addition, spectral measurements at disinfection plants and the comparison to detector measurements were carried out to verify the feasibility and practicability of on-site measurements. In most cases, however, it is not possible to obtain an optimum adaptation of the relative spectral responsivity of a radiometer to the microbicidal action spectrum. Often, SiC photodiodes are used, whose spectral responsivity for longer wavelengths is cut off by means of a suitable interference filter. This, however, often reproduces the curve of the microbicidal action spectrum to a limited extent only. The deviations of the spectral slopes from the spectral responsivity and from the actinic action spectrum have different effects depending on the radiation sources used. This can be expressed by means of the spectral mismatch factor mS: 2. Calibration methods mS = ∫ smic,rel (λ) ⋅ Eλ,S,rel (λ) dλ . ∫ Amic (λ) ⋅ Eλ,S,rel (λ) dλ (4) (1) Here, ES,rel(λ) is the relative spectral irradiance of the radiation source S and Eλ,S(λ) = ES,0·Eλ,S,rel(λ). Hence, if the spectral mismatch factor mS of a radiometer for a defined radiation source S and the actinic irradiance of the source are known, the corrected responsivity of the radiometer can be determined: smic,S = s0 ⋅ mS . (5) An actinic radiometer has a specially adapted spectral responsivity smic(λ) whose relative spectral curve smic,rel(λ) is, ideally, identical to the microbicidal function Amic(λ). When irradiated with the radiation source S, the following photocurrent is obtained for the radiometer: If the radiation source S is a low-pressure mercury lamp, then mS = 1, since the spectrum of the source S basically only exists at the wavelength λ0. For all other sources, mS or at least smic,S has to be determined separately. The microbicidal effect of UV radiation is defined by a corresponding action spectrum Amic(λ) which corresponds to the inactivation of the spores of bacillus subtilis [1]. In the case of a radiation source S of known spectral irradiance Eλ,S(λ), the microbicidal irradiance is defined as Emic,S = ∫ Amic (λ) ⋅ Eλ,S (λ) dλ . ∫ imic , S = s0 ⋅ smic ,rel (λ ) ⋅ Eλ, S (λ ) dλ (2) where s0 is the absolute value of the irradiance responsivity of the radiometer, measured in (A W−1 m−2). When calibrating and using the radiometer, the responsivity smic,abs is interesting with regard to the microbicidal irradiance Emic which is defined as smic,abs,S = imic,S = s0 ⋅ Emic , S ∫ smic ,rel (λ) ⋅ Eλ,S (λ) dλ . ∫ Amic (λ) ⋅ Eλ,S (λ) dλ (3) In the case of an ideal actinic radiometer, the following applies: smic,rel(λ) = Amic(λ), and thus smic,abs,S = s0. This means that the absolute value of the radiometer responsivity only needs to be calibrated against a single wavelength in order to determine the responsivity with regard to the microbicidal irradiance for any random radiation emitter. This type of calibration is often carried out with low-pressure mercury lamps which, in the UV-C spectral range, mostly exhibit only one defined spectral line at λ0 = 253.6 nm. If only low-pressure mercury lamps are used for water disinfection, then this conventional calibration is fully sufficient. For this purpose, low-pressure lamps of known irradiance can be used for source-based calibration. Or in the case of detector-based calibration, a radiometer of known responsivity is used and compared under irradiation with a low-pressure lamp by directly substituting it for the radiometer to be calibrated. 3. Spectroradiometric measurements Often, the spectral responsivity smic(λ) of a radiometer cannot be determined directly since the sensors are relatively insensitive to irradiation in order to be able to measure high irradiances at all. In the case of a spectral calibration, however, the spectral irradiances involved are often comparatively low, which generate a signal with a low signal-to-noise ratio in radiometers. In many cases, actinic radiometers are therefore calibrated directly with a radiation source of known microbicidal irradiance. For this type of source-based calibration, it is necessary to know the exact spectral irradiance Eλ,S(λ). Then, the radiometer’s responsivity to microbicidal irradiance for the radiation source S can be determined by measurement: smic,abs, S = imic, S ∫ Amic (λ) ⋅ Eλ,S (λ) dλ . (6) Hereby, imic,S is the radiometer’s signal or indication at the microbicidal irradiance according to equation (1) which is formed by the integral in the denominator. Traceable spectral measurements of high-power UV sources are rather challenging. The spectral irradiance of such lamps is higher by several orders of magnitude than the spectral irradiance of typical transfer standard lamps. Typical spectral irradiances of UV emitters used in water disinfection S283 P Sperfeld et al Metrologia 51 (2014) S282 Lam p: 10 : H a lo g e n la m p sp e c tra l irra d ia n ce / W /(m ²· n m ) : D e u te riu m la m p : H g m e d iu m p re s s u re 1 : H g lo w p re s s u re 0 ,1 0 ,0 1 1 0 -3 1 0 -4 1 0 -5 1 0 -6 1 0 -7 300 400 500 w a v e le n g th / n m 600 700 800 Figure 1. Spectral irradiance of standard lamps compared to high-power UV lamps measured using the array spectroradiometer described in this paper. plants are shown in figure 1 compared to the spectral irradiance distribution of standard lamps used in spectroradiometry. For spectral measurements on such different radiation sources, high requirements must be placed on the spectroradiometers used and on their entrance optics: •The instruments must exhibit high dynamics and linearity up to four orders of magnitude of the signal. •They should exhibit sufficient repeatability and reproducibility and should be largely insensitive to variations of the ambient conditions (temperature, humidity). •The entrance optics and the sensors must have a high endurance up to the very high UV irradiances. •Sufficient stray light suppression with regard to longwave radiation is indispensable. •The entrance optics must have a defined reference plane, and the field of view should correspond to that of the respective actinic radiometers. In order to perform measurements directly on site at water disinfection plants, the spectrometer must be easily transportable and mobile calibration possibilities should be available. For this type of utilization, two spectroradiometers have been modified and characterized at PTB. The first instrument is a fast-scanning double monochromator system with fibrecoupled entrance optics. This device has a high stray light suppression and, by combining a photomultiplier with neutral density filters, it exhibits a high dynamic range. To determine the microbicidal irradiance, the lamp spectrum is measured in the wavelength range from 200 nm to 360 nm. For these measurements, the spectrometer is adjusted to a spectral bandwidth of 1 nm. Recording a spectrum in wavelength steps of 0.5 nm takes approximately 90 s, regardless of the irradiance level. The second spectrometer used is a charge-coupled device (CCD) array spectroradiometer with a spectral range from 200 nm to 800 nm and a spectral bandwidth of 2.4 nm. This device is also equipped with fibre-coupled entrance optics. The integration time of the measurements varies between 15 ms and 10 s, depending on how high the maximum irradiance is. The device turns out to be very linear with regard to the integration time variation. As for most array spectroradiometers, however, this device has a rather low stray light suppression, with effects especially seen in the UV spectral range. E.g. when incandescent lamps are used as calibration standards, a stray light level clearly higher than 20% may occur below 300 nm. The stray light behaviour of the array spectroradiometer used was therefore thoroughly characterized and considerably reduced with the aid of a stray light correction matrix and an out-of-range correction [2]. An integration time variation is insufficient to bridge the high difference in dynamics between the calibration sources and the UV lamps to be characterized. Hence, neutral density filters have been integrated into both spectrometers. These allow an attenuation of the induced radiation by up to 3 orders of magnitude. Neutral density filters, however, are optimized mainly for the spectral range above 300 nm where they really exhibit a largely spectrally independent transmission curve. In the UV-C spectral range, these filters show a strongly decreasing transmission by up to −2% nm−1. The spectral transmission of the neutral density filters used was therefore measured several times in the spectral range from 200 nm to 360 nm before and after operation under high UV irradiation. Figure 2 shows the transmission of the three density filters used in the array spectroradiometer with the optical densities OD1–OD3. It was also demonstrated that the transmission of the filters remains constant over time, in spite of intermittently high UV irradiances. The two spectroradiometers have identical entrance optics for the spectral measurements. A flat quartz glass diffuser is mounted into a housing for an actinic radiometer (figure 3), as used in water disinfection plants [3]. This allows the entrance optics of the spectroradiometers to be inserted S284 P Sperfeld et al Metrologia 51 (2014) S282 : OD1 : OD2 : OD3 0,1 transmission 0,05 0,01 0,005 10-3 5·10-4 200 300 400 500 600 wavelength / nm 700 800 Figure 2. Transmission of several neutral density filter types incorporated into the two spectroradiometers used. Figure 3. Schematical drawing of the adapted spectrometer entrance optics. (1) housing, (2) diffuser plate, (3) optical fibre. directly on site. Hereby, the 160° field of view of the diffusers corresponds to that of the radiometers. The diffusers were thoroughly characterized and tested, especially as to their UV resistance [4]. Quartz glass-fibre bundles, which are located directly behind the diffusers, lead the incident radiation onto the entrance slit of the spectroradiometers. The radiation incident at the entrance slit has already been attenuated by the diffusers to such an extent that it is proven that it has no harmful effect on the optical elements of the spectroradiometers. Thus, two clearly different spectroradiometers are available to carry out spectral measurements. After application of all corrections and transmission adaptations within the scope of their measurement capabilities, these spectroradiometers should provide measurement results that are in good agreement with each other for different lamps. 4. Calibration facility It has turned out that due to the spectral mismatch in commercially available actinic radiometers, the calibration factors must be determined separately, at least for each type of lamp used [5]. Therefore, commercially available UV lamps designed specifically for UV disinfection have been characterized and their suitability as a calibration standard has been investigated [6]. To calibrate sensors for UV water disinfection plants based on medium-pressure mercury emitters as well as on low-pressure mercury sources, a 1000 W mediumpressure lamp and a 40 W low-pressure lamp were selected. Figure 4. The transfer standard for high-power UV irradiance. A medium pressure lamp (1) is mounted at the top, the low pressure mercury lamp (2) in the middle can be removed. The sensor mount with baffle tube (3) is located at the bottom of the chamber. The medium-pressure mercury lamp is mounted on top of a ventilated cabinet and the low-pressure source can be mounted underneath (figure 4). The measurement chamber is double-walled and has reflecting internal walls. A fan blows air through the gap between the double wall to cool the internal chamber without causing a draught inside. After the working temperature has been reached, this uniform background ventilation provides stable temperature conditions inside the chamber. When using the 1000 W lamp, temperatures between 58 °C at the bottom and 105 °C at the top of the internal chamber are reached. Both lamps were characterized with regard to their stability and reproducibility, and their temperature curve was measured S285 P Sperfeld et al Metrologia 51 (2014) S282 The spectral irradiance Eλ,S(λ) of the two types of lamps used, as presented in figure 1, was measured repeatedly with the two adapted spectroradiometers, and the microbicidal irradiance Emik,S was calculated. The low-pressure mercury lamp achieves approximately Emik,Hg-LP = (3.3 ± 0.1) W m−2, whereas the medium-pressure lamp reaches Emik,Hg-MP = (45 ± 2) W m−2. Hereby, the microbicidal irradiances, which were calculated independently of each other with the two spectroradiometers, deviate from each other by less than 1%. Thus at this measuring facility, irradiances are attained which allow UV radiometers for water disinfection to be calibrated directly. In industrial water disinfection plants, however, much higher irradiances may occur. 5. On-site spectral measurements Figure 5. Schematic drawing of the sensor mount (1) and the baffle tube (2). Monitor photodiodes are located right and left of the centre (3). At the top of the baffle tube, a long-pass filter can be placed (4). A mechanical shutter (5) can be rotated to completely block the UV radiation. at different locations inside the chamber. The electrical power of the 1000 W medium-pressure lamp is regulated by its mains supply. UV monitor sensors register a stable signal after temperature balance has been reached inside the chamber. This process takes approximately 90 min. Upon restart, the reproducibility of the irradiance is, after another pre-warming period, better than 0.5%. After this, a stability of the irradiance of better than 0.2% is attained during the operation of the lamp. The low-pressure mercury lamp, which is operated with DC voltage, reaches stable operating conditions after approximately 120 min. Only then has the temperature balance inside the measuring chamber been reached at which a temperature of approximately 45 °C at the lamp is attained. The reproducibility of the microbicidal irradiance is then also better than 0.5% here, and the stability lies at around 0.2%. A holder is located at the bottom of the chamber. This holder can accommodate both UV sensors and the entrance optics of the spectroradiometers (figure 5). Towards the top, it is closed by means of a baffle tube which limits the sensors’ field of view. On the upper side of the baffle tube, there is a fixture for a filter and a mechanical shutter for dark measurements. Two UV monitor sensors monitor the incident radiation. One of the sensors is permanently exposed to the radiation; the other one is located behind the shutter and carries out measurements at the same time as the measurements with the UV radiometers or spectrometers. The baffle tube limits the field of view in such a way that only the direct irradiation of the lamps is incident on the UV radiometers and reflections from the walls or other components are ruled out. Thus, identical optical conditions are provided for all sensors and entrance optics, although the total field of view of the sensors is not used at calibration. A long-pass filter with 235 nm cut-on wavelength is inserted into the filter holder at the top end of the baffle tube. This fused silica filter with a steep transmission change between 230 nm and 250 nm blocks most of the radiation below 240 nm. In Germany, water disinfection plants undergo thorough tests before they are granted approval. TZW, the Water Technology Centre (Technologiezentrum Wasser) of DVGW, the German Technical and Scientific Association for Gas and Water (Deutscher Verein des Gas- und Wasserfaches e.V.) carries out the inspection of new plants. For this purpose, TZW operates a testing laboratory for UV devices at the water works of St.-Augustin-Meindorf, where large-scale UV plants can be tested at flowrates of up to 3500 m3 h−1. By means of microbiological test procedures, the microbicidal effectiveness of the devices can be tested under various operating conditions. Hereby, the German Drinking Water Ordinance (TrinkwV 2001, Deutsche Trinkwasserverordnung) requires that water flowing through such UV plants is subjected to a RED of 400 J m−2. For this reason, numerous correspondingly strong UV lamps must be available at devices operated at a high flowrate. The irradiance of each lamp must be monitored by means of UV radiometers. The lamps’ power can be adjusted as a function of the flowrate. TZW checks the adjusting mechanisms of new devices and the irradiances of the UV lamps. The measurements are performed with calibrated UV radiometers. Direct spectral measurements were previously not feasible at large-scale UV plants. With the adapted spectroradiometers, it was possible to test directly at TZW’s test rig whether spectral measurements are feasible at all [7]. For this purpose, a mobile measuring assembly of PTB (consisting of the spectroradiometers, several UV radiometers and calibration sources) was set up at the water works. There, with temperatures around 12 °C, the ambient conditions were clearly different from those at PTB’s laboratory. In addition, the geometric conditions at a UV plant and, for instance, the effect of flowing water cannot be simulated at the radiometry lab. Direct comparison with reference radiometers of TZW is therefore an important indicator of the reliability of the field measurements. Microbicidal irradiances were determined at several devices and compared with each other. First measurements at a small UV reactor with low-pressure mercury lamps, a flowrate of 6 m3 h−1 and a microbicidal irradiance of 63 W m−2 ± 2 W m−2 showed a good agreement between the spectroradiometers, the UV radiometers S286 P Sperfeld et al Metrologia 51 (2014) S282 Table 1. Measurement results of the microbicidal irradiance at a UV reactor with 48 kW medium-pressure mercury lamps, at different power settings. Relative electrical power TZW sensor PTB Spectrorad. 1 PTB Spectrorad. 2 PTB Sensor 2 PTB Sensor 3 PTB Sensor 4 30% 50% 100% 181 W m−2 350 W m−2 827 W m−2 206 W m−2 401 W m−2 969 W m−2 193 W m−2 378 W m−2 906 W m−2 200 W m−2 386 W m−2 910 W m−2 196 W m−2 379 W m−2 898 W m−2 203 W m−2 389 W m−2 920 W m−2 rel. electrical pow er : 30 % 0,1 : 50 % : 100 % E ( λ ) / E m ik 0,01 10 -3 10 -4 10 -5 200 300 400 500 W avelength / nm 600 700 800 Figure 6. Normalized spectral irradiance of a UV reactor with 48 kW medium-pressure mercury lamps at different power settings. and TZW’s reference radiometers. The standard deviation of all measurement results was below 2.5%. The result at this reactor was verified also at 50% of the irradiance power and a flowrate of 0.6 m3 h−1. Larger water disinfection plants are increasingly being equipped with medium-pressure mercury lamps. Their compact design allow a considerably higher energy density in minimum space. During the joint measurements at TZW’s test rig, we had the opportunity to use a UV reactor with 48 kW mediumpressure lamps in total. The device’s electrical power was set between 30% and 100%, so that microbicidal irradiances from approximately 200 W m−2 to 900 W m−2 were reached at the measurement points. These irradiances lie much higher than the values attained at the calibration facility in the lab. Table 1 shows that mainly consistent agreement was achieved between all the measuring instruments. The standard deviation of all PTB measurement results amounts to less than 3%. TZW’s sensor shows an indication of the microbicidal irradiance which is lower by approximately 10%. This is due to the fact that the sensor was calibrated by the manufacturer with respect to a low-pressure mercury lamp and the mismatch to the spectrum of a medium-pressure mercury lamp was not taken into account in these measurements. For this type of sensor, this deviation amount is expected and usually leads to an indication of the microbicidal irradiance which is too low. The fast-scanning spectroradiometer (PTB Spectrorad. 1) shows higher values than the mean value of the PTB measurements. The deviation increases slightly with rising irradiance. Both the clearly different ambient conditions and a possible non-linearity of the photomultiplier at these high irradiances can be responsible for this behaviour. In addition to the measured microbicidal irradiances, the spectral curves of the irradiance provide important information concerning the tested UV plants. Figure 6 shows the spectral slope of the measurements at different power settings of the device, normalized to the resulting microbicidal irradiance. Here, it can be seen clearly that the variation of the electrical power has nearly no influence on the relative spectral slope. This allows us to rule out a change in the microbicidal effectiveness due to a shift of the lamp spectrum. This observation justifies the use of UV radiometers to check the UV plants, as far as the correction factors are correspondingly adapted to medium-pressure lamps. A change in the electrical power of the lamps does not cause a shift of this adjustment factor. In addition, figure 6 shows clearly that the required absorption of the UV radiation is reached below 240 nm. It has thus been shown that traceable spectral measurements can be carried out, even at high UV irradiances at these reactors. This allows, for instance, new types of radiation sources to be characterized or the change in the spectral irradiance as a function of the water properties to be investigated. Hereby, these results have confirmed that S287 P Sperfeld et al Metrologia 51 (2014) S282 different sources require different adapted adjustment factors for the UV radiometers. The commercially available calibration station can hereby be used by testing laboratories as well as by sensor manufacturers to calibrate the UV radiometers. Acknowledgments 6. Conclusion References For the first time, PTB has carried out traceable spectral measurements directly on UV disinfection plants in operation. Water disinfection systems using two types of mercurybased UV emitters were measured at the TZW test centre in St. Augustin, Germany. The resulting calculated microbicidal irradiances agreed with the measurement results of the reference radiometers used at the test centre. Additional measurements using reference radiometers calibrated at a newly designed calibration facility confirmed the introduced source-based calibration method. Hereby, these results have confirmed that different radiation sources require different adapted adjustment factors for the UV radiometers. The commercially available calibration station can hereby be used by testing laboratories as well as by sensor manufacturers to calibrate the UV radiometers. In addition, the direct spectral measurements allow new water disinfection UV plants and new types of lamps to be investigated and developed. Combined with newly developed UV transfer standard lamps, it will be possible to calibrate broadband actinic UV radiometers in terms of microbicidal irradiance responsivity for these new types of radiation sources. [1] Arbeitsblatt W 2006 294-3: UV-Geräte zur Desinfektion in der Wasserversorgung; Teil 3: Messfenster und Sensoren zur radiometrischen Überwachung von UV-Desinfektionsgeräten— Anforderungen, Prüfung und Kalibrierung, Technische Regel der DVGW, Ausgabe 2006-06, Wirtschafts- und Verlagsgesellschaft Gas und Wasser mbH, Bonn, June 2006 [2] Sperfeld P, Nevas S and Pape S 2014 Application of a compact array spectroradiometer for the UV spectral range Poster presented at NEWRAD 2014 (Helsinki, Finland, 24–27 June 2014) pp 263–4 [3] Hopfenmüller G et al 2013 PTB traceable calibrated reference UV radiometer for measurements at high irradiance medium pressure mercury discharge lamps Proc. 2013 EMEA Regional Conf. (Karlsruhe, Germany, 4–5 June 2013) [4] Barton B et al 2011 Characterization of new optical diffusers used in high irradiance UV radiometers Poster Presented at NEWRAD 2011 Maui, Hawaii, 19–23 September 2011) [5] Larason T and Ohno Y 2006 Calibration and characterization of UV sensors for water disinfection Metrologia 43 S151–6 [6] Barton B et al 2013 Developing and setting up a calibration facility for UV sensors at high irradiance rates Proc. 2013 EMEA Regional Conf. (Karlsruhe, Germany, 4–5 June 2013) [7] Sperfeld P, Barton B, Pape S, Eggers J and Hopfenmüller G 2013 Traceable measurements of the spectral irradiance of UV water disinfection plants Proc. 2013 EMEA Regional Conf. (Karlsruhe, Germany, 4–5 June 2013) pp 122–3 This work was supported in part by the Federal Ministry for Economic Affairs and Energy based on a decision of the German Parliament under grant no. KF2303704RR9. S288