Production of Elemental Sulphur from SO

Transcription

Production of Elemental Sulphur from SO
For further information contact:
Steve Pollitt
Mahin Rameshni
+44 20 8326 5217
Parkview, Great West Road
Brentford, Middlesex TW8 9AZ
London, UK
[email protected]
Director of Sulphur Technology
+1 626 803 9058
181 West Huntington Drive
Monrovia, California 91016
[email protected]
RSR®
(Rameshni SO2 Reduction)
Production of Elemental Sulphur from SO2
Advanced Technology
Production of Elemental Sulphur from SO2
WorleyParsons has over 50 years of global experience
that includes 534 sulphur recovery units, accounting for
over 60% of the world’s production of recovered sulphur
and including the world’s largest single-train sulphur
plant.
Sulphur emissions for ore roasters, smelters, and coal-fired power plants need
to be reduced considering:
•
•
•
•
•
•
f Combination of two well proven processes
500+
Claus-type plants
Less demand for sulphuric acid production
Lower fuel consumption
Reduced emissions
Better product sulphur quality
Better operational stability
Lower cost
Lower Cost
f Lower operation cost
WorleyParsons Innovative
SO2 – Reduction Process ®
100+
f Lower capital cost
Tail gas treaters
f Less number of equipment
CS2 REACTION
HEATER
NO. 1 CS2
REACTOR
f Mostly carbon steel material of construction
f Higher sulphur quality
SO2
SO2
BLOWER
NO. 3 CS2
REACTOR
NATURAL GAS
SO2
PREHEATER
f No soot formation
CS2 WASTE
HEAT BOILER
f Ability to control the temperature
NO. 1
SULPHUR
CONDENSER
CS2 + H2S
650˚C
4-7 bar
CH4 + 2S2
NO. 2
REHEATER
RECYCLE
BLOWER
steam
SO2
NO. 3
SULPHUR
CONDENSER
650C
f Light Metals
water
sulphur
NO. 3
SULPHUR
REACTOR
methane
(natural gas)
f Base Metals
NATURAL
GAS
SULPHUR
NO. 4
SULPHUR
CONDENSER
SULPHUR
f Ferrous Metals
TAIL GAS
reactor
tubes
INCINERATOR
SULPHUR
fuel gas
SULPHUR
SULPHUR
PIT
Sulphur from Mining and Minerals
furnace
NO. 3
REHEATER
NO. 2
SULPHUR
CONDENSER
CS2 + 2H2S
SULPHUR
NO.2
SULPHUR
REACTOR
NO. 1
SULPHUR
REACTOR
f Fewer side reactions
REACTION
RECYCLE
GAS
REHEATER
SULPHUR
RECYCLE
PUMP
f Less plot space
f Higher sulphur recovery up to 98%
NO. 2 CS2
REACTOR
SRU WASTE
HEAT BOILER
f Superior fuel efficiency
Superior Performance
NATURAL GAS
NO. 1
REHEATER
– CS2 Section, reaction of natural gas and recycled sulphur vapor
to produce CS2
– Claus Section –catalytic hydrolysis of CS2 to H2S and reaction of
H2S and SO2 to produce elemental sulphur in a conventional
Claus unit
f Safe, reliable, simple operation
f Commercial experience in large scale in both processes
f Apply for any SO2 stream, with or without SO2 concentration process
SULPHUR
PRODUCT
PUMP
sulphur
methane
H2O
mix. S, H2S, CS2
CS2
H2S
S
f Coal
f Chemicals
Advanced Technology
Production of Elemental Sulphur from SO2
WorleyParsons has over 50 years of global experience
that includes 534 sulphur recovery units, accounting for
over 60% of the world’s production of recovered sulphur
and including the world’s largest single-train sulphur
plant.
Sulphur emissions for ore roasters, smelters, and coal-fired power plants need
to be reduced considering:
•
•
•
•
•
•
f Combination of two well proven processes
500+
Claus-type plants
Less demand for sulphuric acid production
Lower fuel consumption
Reduced emissions
Better product sulphur quality
Better operational stability
Lower cost
Lower Cost
f Lower operation cost
WorleyParsons Innovative
SO2 – Reduction Process ®
100+
f Lower capital cost
Tail gas treaters
f Less number of equipment
CS2 REACTION
HEATER
NO. 1 CS2
REACTOR
f Mostly carbon steel material of construction
f Higher sulphur quality
SO2
SO2
BLOWER
NO. 3 CS2
REACTOR
NATURAL GAS
SO2
PREHEATER
f No soot formation
CS2 WASTE
HEAT BOILER
f Ability to control the temperature
NO. 1
SULPHUR
CONDENSER
CS2 + H2S
650˚C
4-7 bar
CH4 + 2S2
NO. 2
REHEATER
RECYCLE
BLOWER
steam
SO2
NO. 3
SULPHUR
CONDENSER
650C
f Light Metals
water
sulphur
NO. 3
SULPHUR
REACTOR
methane
(natural gas)
f Base Metals
NATURAL
GAS
SULPHUR
NO. 4
SULPHUR
CONDENSER
SULPHUR
f Ferrous Metals
TAIL GAS
reactor
tubes
INCINERATOR
SULPHUR
fuel gas
SULPHUR
SULPHUR
PIT
Sulphur from Mining and Minerals
furnace
NO. 3
REHEATER
NO. 2
SULPHUR
CONDENSER
CS2 + 2H2S
SULPHUR
NO.2
SULPHUR
REACTOR
NO. 1
SULPHUR
REACTOR
f Fewer side reactions
REACTION
RECYCLE
GAS
REHEATER
SULPHUR
RECYCLE
PUMP
f Less plot space
f Higher sulphur recovery up to 98%
NO. 2 CS2
REACTOR
SRU WASTE
HEAT BOILER
f Superior fuel efficiency
Superior Performance
NATURAL GAS
NO. 1
REHEATER
– CS2 Section, reaction of natural gas and recycled sulphur vapor
to produce CS2
– Claus Section –catalytic hydrolysis of CS2 to H2S and reaction of
H2S and SO2 to produce elemental sulphur in a conventional
Claus unit
f Safe, reliable, simple operation
f Commercial experience in large scale in both processes
f Apply for any SO2 stream, with or without SO2 concentration process
SULPHUR
PRODUCT
PUMP
sulphur
methane
H2O
mix. S, H2S, CS2
CS2
H2S
S
f Coal
f Chemicals
For further information contact:
Steve Pollitt
Mahin Rameshni
+44 20 8326 5217
Parkview, Great West Road
Brentford, Middlesex TW8 9AZ
London, UK
[email protected]
Director of Sulphur Technology
+1 626 803 9058
181 West Huntington Drive
Monrovia, California 91016
[email protected]
RSR®
(Rameshni SO2 Reduction)
Production of Elemental Sulphur from SO2