EXACT ANALYSIS OF UNSTEADY CONVECTIVE DIFFUSION FOR
Transcription
EXACT ANALYSIS OF UNSTEADY CONVECTIVE DIFFUSION FOR
Bangmod Int. J. Math. & Comp. Sci. Vol. 1, No. 1, 2015: Pages 63 – 81 http://bangmod-jmcs.kmutt.ac.th/ ISSN : 2408-154X EXACT ANALYSIS OF UNSTEADY CONVECTIVE DIFFUSION FOR BLOOD FLOW WITH INTERPHASE MASS TRANSFER IN MAGNETIC FIELD Nirmala P. Ratchagar1 and R.Vijaya Kumar2,∗ 1 Department of Mathematics, Annamalai University, Annamalainagar, Tamilnadu - 608 002, INDIA E-mail : [email protected] 2 Department of Mathematics, Mathematics Section, Faculty of Engineering and Technology, Annamalai University, Annamalainagar,Tamilnadu - 608 002, INDIA E-mail : rathirath [email protected] *Corresponding author. Abstract This paper deals with a mathematical model for exact analysis of miscible dispersion of solute with interphase mass transfer in a blood(couple stress fluid) flow bounded by porous beds under the influence of magnetic field. The three coefficients, namely, exchange coefficient, convection coefficient, and dispersion coefficient are evaluated asymptotically at large-time using generalized dispersion model. The dispersion equation is used to calculate the mean concentration distribution of a solute, bounded by the porous layer, and is expressed as a function of dimensionless axial distance and time. It is computed for different values of Hartmann number (M ), Couple Stress Parameter(a), reaction rate Parameter(β) and Porous Parameter (σ). MSC: 76S05, 76W05,76D05 Keywords: magnetic field, couple stress fluid, porous medium, generalized dispersion model. Submission date: 11 February 2015 / Acceptance date: 12 May 2015 /Available online: 14 May 2015 c Theoretical and Computational Science and KMUTT-PRESS 2015. Copyright 2015 1. Introduction In many biomedical problems, the interphase mass transfer plays an important role because many physiological situation involve interphase mass transfer. Therefore, it is necessary to develop a technique for handling such problems, which involve interphase mass transport. Several authors have studied various characteristics of dispersion were mainly concerned with Taylors dispersion [23], which is valid for large time. Physiological fluid flow problems have been mainly concerned with transient phenomena where Taylors model is not valid. However, Sankarasubramanian and Gill[18] have developed an analytical method to analyze transient dispersion of non-uniform initial distribution called c 2015 By TaCS Center, All rights reserve. Published by Theoretical and Computational Science Center (TaCS), King Mongkut’s University of Technology Thonburi (KMUTT) Bangmod-JMCS Available online @ http://bangmod-jmcs.kmutt.ac.th/ Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 64 generalized dispersion in laminar flow in a tube with a first order chemical reaction at the tube wall. This method can be applied to physiological problems, where a first order chemical reaction occurs at the tube wall. One such situation is transport of oxygen and nutrients to tissue cells and removal of metabolic waste products from tissue cells. Interphase mass transfer also takes places in pulmonary capillaries, where the carbon dioxide is removed from the blood and oxygen is taken up by the blood. Rudraiah et al.[17] studied the dispersion in a stokes couple-stress fluid flow by using the generalized model of Gill and Sankarasubramanian [8]. Considering solute reaction at the channel walls in their all time analysis of dispersion, reaction at the walls is of practical interest and in the simplest case, a first order chemical reaction at the walls is considered by them, in carrying out an exact analysis of unsteady convection in couple stress fluid flows. Gill [7] developed a local theory of Taylor diffusion in fully developed laminar tube flow with a periodic condition at the inlet of the tube. Gill [8] obtained an exact solution to the unsteady convective diffusion equation for miscible displacement in fully developed laminar flow in tubes by defining dispersion coefficient to be functions of time. Shivakumar et al. [20] have obtained a closed-form solution for unsteady convective diffusion in a fluidsaturated sparsely packed porous medium using the generalized dispersion model of [8]. In all these investigations, it is assumed that, the solute does not chemically react in the liquid in which it is dispersed. Gupta [9], following Taylor [23], studied the effects of homogeneous and heterogeneous reaction on the dispersion of a solute in the laminar flow of Newtonian fluid between two parallel plates. Shukla et al.[19], Soundalgekar [21], Meena Priya[10], Dulal Pal [3] and Dutta et al. [4] studied dispersion in non-Newtonian fluids by considering only homogeneous firstorder chemical reaction in the bulk of the fluid. Chandra and Agarwal [2] considered dispersion in simple microfluid flows taking only homogeneous reaction into consideration. Suvadip Paul [22] examine a the influence of angularity on the transport process under the combined effects of reversible and irreversible wall reactions, when the flow is driven by a pressure gradient comprising of steady and periodic components. Francesco Gentile [5] studied the transport formulation proposed in [6] was further developed to account for the time dependency of the problem. Prathap Kumar et al.[11] also investigated the effect of homogeneous and heterogeneous reactions on the solute dispersion in composite porous medium. Recently,Ramana Rao[13], Ramana[14,15] and Ramana et al [16] studied combined the effect of non-Newtonian rheology and irreversible boundary reaction on dispersion in a Herschel-Bulkley fluid through a conduit, (pipe/channel) by using the generalized dispersion model proposed by [8]. Pauling [12] first reported that the erythrocytes orient with their disk plane parallel to the magnetic field. This paper deals with the effect of couple stress and magnetic field on the unsteady convective diffusion, with interphase mass transfer by using the generalized dispersion model of Sankarasubramanian and Gill [18]. Convection coefficient K1 and Dispersion coefficient K2 are influenced by the couple stress parameter arising due to suspension in the fluid, magnetic field and porous parameter. The exchange coefficient K0 arises mainly due to the interphase mass transfer, and it is independent of the solvent fluid velocity. The interphase mass transfer also influence the convection and dispersion coefficients. Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 65 2. Mathematical Formulation We have considered a steady laminar and fully developed flow (unidirectional) in a channel bounded by porous layers and separated by a distance 2h. A schematic diagram of the physical configuration and the description of the initial slug input of concentration are shown in figure 1. A uniform magnetic field Bo is applied in the y-direction to the flow of blood. We make the following assumption for electromagnetic interactions, i) the induce magnetic field and the electric field produced by the motion of blood are negligible (since blood has low magnetic Reynolds number). ii) no external electric field is applied. Flow region is divided into two sub-region such as Fluid film region and Porous tissue region. The governing equation of the motion for flow in vector form is given by y B0 Region 2 y=h Region 1 y=0 -Xs/2 x Xs/2 Region 2 y=-h B0 Figure 1. Physical Configuration Region 1:Fluid Film Region Conservation of mass for an incompressible flow ∇ · ~q = 0 (2.1) Conservation of momentum ∂~q ρ + (~q · ∇)~q = −∇p + µ∇2 ~q − λ∇4 ~q + J × B ∂t (2.2) Region 2:Porous Tissue Region Conservation of mass for an incompressible flow ∇ · ~q = 0 (2.3) Conservation of momentum ∂~q µ ρ + (~q · ∇)~q = −∇p + µ∇2 ~q − (1 + β1 )~q ∂t k (2.4) Maxwell’s equations are ∇ · B = 0, ∇ × ·B = µ0 J ∇×E =− ∂B0 ∂t Ohm’s law J = σ0 (E + ~q × B0 ) Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 66 Conservation of species ~ ∂C + (~q · ∇)C = D∇2 C ∂t In cartesian form, using the above equation (2.1)-(2.4) becomes Region 1:Fluid Film Region (2.5) ∂4u ∂p ∂2u (2.6) + µ 2 − λ 4 − B02 σ0 u, ∂x ∂y ∂y ∂p (2.7) 0=− ∂y Region 2:Porous Tissue Region ∂p µ 0=− − (1 + β1 )up , (2.8) ∂x k ∂p 0=− (2.9) ∂y where, ~q = ~iu + ~jv, u is the x components of velocity, p is the pressure, ρ is the density of the fluid, µ is the viscosity of the fluid, λ is the couple stress parameter, k is the permeability of the porous medium, E the electric field,σ0 is the electrical conductivity, J the current density and up is the darcy velocity. It may be noted that, (2.8) is the modified darcy equation. where, β1 is the couple stress parameter. We consider the dispersion of reactive solute in the fully developed flow through a parallel plate channel bounded by porous beds. Introduced a slug of concentration C = C0 ψ1 (x)Y1 (y). The mass balance equation (2.5) concerning the solute concentration C undergoes heterogeneous chemical reaction such as 2 ∂C ∂C ∂ C ∂2C +u =D + (2.10) ∂t ∂x ∂x2 ∂y 2 0=− where, D is the molecular diffusivity. The boundary conditions on velocity are −α ∂u = √ (u − up ) at y = h, (2.11) ∂y k α ∂u = √ (u − up ) at y = −h, (2.12) ∂y k ∂2u = 0 at y = ±h. (2.13) ∂y 2 where, α is the slip parameter. Eqs. (2.11) and (2.12) is Beavers and Joseph [1] slip condition at the lower and upper permeable surfaces and equation (2.13) specifies the vanishing of the couple stress. Initial and Boundary conditions on concentration The initial distribution assumed to be in a variable separable form is given by C(0, x, y) = C0 ψ1 (x)Y1 (y), (2.14) The heterogeneous reaction conditions are: −D ∂C ∂y D ∂C ∂y = = Ks C Ks C at y = h and at y = −h ) Bangmod-JMCS−[email protected] (2.15) c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 67 where, Ks is the reaction rate constant catalysed by the walls and C0 is a reference concentration. As the amount of solute in the system is finite, C(t, ∞, y) = ∂C (t, ∞, y) = 0 ∂x (2.16) where, C0 is reference concentration. Now, we introduce the non-dimensional quantities, U= y C Dx Dxs Dt h¯ u u ; η= ; θ= ; X = 2 ; Xs = 2 ; τ = 2 ; P e = ; u ¯ h C0 h u ¯ h u ¯ h D Equation (2.6) and (2.10) in non-dimensional form as ∂4U ∂2U − a2 2 + a2 M 2 U = P a2 4 ∂η ∂η (2.17) and ∂θ ∂θ ∂2θ 1 ∂2θ + U∗ + = 2 ∂τ ∂X1 P e2 ∂X1 ∂η 2 q 2 ∂p λ h 2 where, P = −h , l = µ ∂x µ and a = l is the couple stress parameter, M = ∗ u ¯h D (2.18) B02 σ0 h2 µ is the ¯ U −U ¯ U is the peclet number, U = is normalized square of the Hartmann number, P e = axial component of velocity as x1 = x − u ¯t which is dimensionless form is X1 = X − τ where X1 = xh12D a The initial and boundary conditions of (2.11) to (2.16) in dimensionless form ∂U = −ασ(U − Up ) at η = 1 ∂η (2.19) ∂U = ασ(U − Up ) at η = −1 ∂η (2.20) ∂2U = 0 at y = ±1 ∂η 2 (2.21) where, σ = √h k is the porous parameter. θ(0, X, η) ∂θ ∂η ∂θ ∂η = = = ψ(X)Y (η), −βθ βθ θ(τ, ∞, η) at η = 1, at η = −1 = (2.22) ) ∂θ (τ, ∞, η) = 0 ∂X Bangmod-JMCS−[email protected] (2.23) (2.24) c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 68 3. Method of solution Velocity distribution The solution of Equation (2.17) can be written as: P (3.1) M2 where, C1 ,C2 ,C3 and C4 are constants. Applying the boundary conditions (2.19)-(2.21) in (3.1), we obtain the the velocity of blood as P U (η) = 2C1 Coshm1 η + 2C3 Coshm3 η + 2 (3.2) M The normalized axial components of velocity obtained from(3.1) is ¯ U −U 2 C1 Sinhm1 C3 Sinhm3 = + C Coshm η + C Coshm η − U∗ = 1 1 3 3 ¯ A1 m1 m3 U (3.3) U (η) = C1 em1 η + C2 e−m1 η + C3 em3 η + C4 e−m3 η + where, ¯=1 U 2 Z1 U (η)dη = −1 2C1 Sinhm1 2C3 Sinhm3 P + + 2 m1 m3 M (3.4) Generalized Dispersion model The solution of (2.18) subject to the conditions (2.22)-(2.24), following Gill and Sankarasubramanian [18] is θ(τ, X, η) = ∞ X fk (τ, η) k=0 ∂ k θm , ∂X k (3.5) where, θm is the dimensionless cross sectional average concentration and is given by θm 1 = 2 Z1 θ(τ, X, η)dη (3.6) −1 Equation (2.18) is multiplied throughout by the limits -1 to 1 and using (3.6) we get, 1 2 and integrated with respect to y between 1 Z1 ∂θm 1 ∂ 2 θm 1 ∂θ 1 ∂ = 2 + − U ∗ θdη ∂τ Pe ∂X 2 2 ∂η −1 2 ∂X (3.7) −1 Using Eq. (3.5) in (3.7), we get the dispersion model for θm as 1 ∂θm 1 ∂ 2 θm 1 ∂ ∂θm = + (f0 (τ, η)θm (τ, X) + f1 (τ, η) (τ, X) + . . .) ∂τ Pe2 ∂X 2 2 ∂η ∂X −1 1 ∂ − 2 ∂X Z1 U ∗ (f0 (τ, η)θm (τ, X) −1 +f1 (τ, η) ∂ 2 θm ∂θm (τ, X) + f2 (τ, η) (τ, X) + . . .)dη ∂X ∂X 2 Bangmod-JMCS−[email protected] (3.8) c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 69 The generalized dispersion model of [7] is defined as ∞ X ∂θm ∂ i θm = Ki (τ ) ∂τ ∂X i i=0 (3.9) substituting (3.9) in (3.8) we get, ∂θm ∂ 2 θm K0 θm + K1 + K2 ∂X ∂X 2 = 1 1 ∂ 2 θm 1 ∂ ∂θm + (f0 θm + f1 + . . .) Pe2 ∂X 2 2 ∂η ∂X −1 1 Z ∂θm 1 ∂ U ∗ f0 (τ, ξ)θm (τ, X) + f1 (τ, ξ) (τ, X) − 2 ∂X ∂X −1 ∂ 2 θm +f2 (τ, ξ) (τ, X) + . . . dη ∂X 2 2 m ∂ θm Equating like coefficient of θm , ∂θ ∂X , ∂X 2 . . . we get Ki ’s are, δi2 1 ∂fi 1 Ki (τ ) = 2 + (τ, 1) − Pe 2 ∂η 2 Z1 fi−1 (τ, η)U ∗ (τ, η)dη (3.10) −1 (i = 1, 2, 3, . . .) where, f−1 = 0 and δi2 is the Kroneckar delta defined by δi2 = 1, 0, i=j i 6= j The exchange coefficient K0 (τ ) accounts for the non-zero solute flux at the channel wall, and negative sign indicates the depletion of solute in the system with time caused by the irreversible reaction, which occurs at the channel wall. The presence of non-zero solute flux at the walls of the channel, also affects the higher order Ki due to the explicit i appearance of ∂f ∂η (τ, 1) in equation (3.10). Equation (3.9) can be truncated after the term involving K2 without causing serious error, because K3 , K4 , etc. become negligibly small compared to K2 . The resulting model for the mean concentration is ∂θm ∂θm ∂ 2 θm = K0 (τ )θm + K1 (τ ) + K2 (τ ) ∂τ ∂X ∂X 2 (3.11) To solve the equation (3.11), we need the coefficients Ki (τ ) in addition to the appropriate initial and boundary conditions. For this, the corresponding function fk must be determined. So, substituting (3.5) into (2.18), the following set of differential equations for fk are generated. k X ∂fk ∂ 2 fk 1 ∗ = − U f + f − Ki fk−i , k−1 k−2 ∂τ ∂η 2 Pe2 i=0 (k = 0, 1, 2, . . .) (3.12) where, f−1 = f−2 = 0. Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 70 To evaluate Ki0 s, we need to know the fk ’s which are obtained by solving (3.12) for fk ’s subject to the boundary conditions, fk (τ, 0) = ∂fk (τ, 1) = ∂η ∂fk (τ, 0) = ∂η 1 2 f inite, (3.13) −βfk (τ, 1), (3.14) 0, (3.15) δk0 , (k = 0, 1, 2) (3.16) Z1 fk (τ, η)dη = −1 The function f0 and the exchange coefficient K0 are independent of the velocity and can be solved easily. It should be pointed out here, that, a simultaneous solution has to be obtained from these two quantities since K0 , which can be obtained from (3.10) as 1 1 ∂f0 (3.17) K0 (τ ) = 2 ∂η −1 Substituting k = 0 in equation (3.12) we get the differential equation for f0 as ∂f0 ∂ 2 f0 = − f0 K 0 (3.18) ∂τ ∂η 2 We derive an initial condition for f0 using (3.6) by taking τ = 0 in that equation to get 1 θm (0, X) = 2 Z1 θ(0, X, η)dη (3.19) −1 Substituting τ = 0 in (3.5) and setting fk (η) = 0(k = 1, 2, 3) gives us the initial condition for f0 as θ(0, X, η) f0 (0, η) = (3.20) θm (0, X) We note that the left hand side of (3.20) is a function of η only and the right hand side is a function of both X and η. Thus, clearly the initial concentration distribution must be a separable function of X and η. Substituting equation (2.14) and (3.19) into equation (3.20), we get f0 (0, η) = 1 2 ψ(η) R1 ψ(η)dη (3.21) −1 The solution of the reaction diffusion equation (3.18) with these conditions may be formulated as τ Z f0 (τ, η) = g0 (τ, η) exp − K0 (η)dη (3.22) 0 from which it follows that g0 (τ, η) has to satisfy ∂g0 ∂ 2 g0 = ∂τ ∂η 2 (3.23) Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 71 with conditions f0 (0, η) = g0 (0, η) = 1 2 ψ(η) , R1 ψ(η)dη (3.24) −1 g0 (τ, 0) = f inite, ∂g0 (τ, 1) = −βg0 (τ, 1). ∂η (3.25) (3.26) The solution of (3.23) subject to conditions (3.24)-(3.26) is g0 (τ, η) = ∞ X An Cos(µn η)exp[−µ2n τ ] (3.27) n=0 where, µn ’s are the roots of µn tanµn = β, n = 0, 1, 2, . . . (3.28) and An ’s are given by 2 An = R1 ψ(η)Cosµn ηdη −1 1+ Sin2µn 2µn R1 (3.29) ψ(η)dη −1 from (3.22), it follows that 9 P f0 (τ, η) = 2g0 (τ, η) R1 g0 (τ, η)dη = n=0 9 P An exp[−µ2n τ ]Cosµn η n=0 −1 (3.30) An 2 µn exp[−µn τ ]Sinµn The first ten roots of the transcendental equation (3.28) are obtained using MATHEMATICA 8.0 and are given in Table 1. We find that these ten roots ensured convergence of the series seen in the expansions for f0 and K0 . Having obtained f0 , we get K0 from (3.17) in the form 9 P K0 (τ ) = An µn exp[−µ2n τ ]Sinµn − n=09 P n=0 (3.31) An 2 µn exp[−µn τ ]Sinµn K0 (τ ) is independent of velocity distribution. As τ → ∞, we get the asymptotic solution for K0 from (3.31) as K0 (∞) = −µ20 (3.32) where, µ0 is the first root of the equation (3.28). Physically, this represents first order chemical reaction coefficient having obtained K0 (∞). We can now get K1 (∞), from (3.10) (with i = 1) knowing f0 (∞, η) and f1 (∞, η). Likewise, K2 (∞), K3 (∞), . . . require the knowledge of K0 , K1 , f0 , f1 and f2 . Equation (3.30) in the limit τ → ∞ reduces to µ0 f0 (∞, η) = Cos(µ0 η) (3.33) Sinµ0 Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 72 Then we find f1 , K1 , f2 , and K2 . For asymptotically long times, i.e., τ → ∞, equation (3.10) and (3.12) give us Ki ’s and fk ’s as Z1 δi2 − βfi (∞, 1) − U ∗ fi−1 (∞, η)dη, (i = 1, 2, 3) Ki (∞) = Pe2 −1 2 d fk 1 2 ∗ + µ f = (U + K )f − − K 1 k−1 2 fk−2 , (k = 1, 2) 0 k dη 2 Pe2 (3.34) (3.35) The fk ’s must satisfy the conditions (3.6) and this permits the eigen function expansion in the form of 9 X Bj,k Cos(µj η), k = 1, 2, 3, . . . (3.36) fk (∞, η) = j=0 Substituting (3.36) in (3.35) and multiplying the resulting equation by Cos(µj η) and integrating with respect " to η from -1 to 1, ∞ P 1 1 Bj,k Cosµj η = µ2 −µ Bj,k−2 Cosµj η 2 2 Pe 0 j j=0 # ∞ ∞ P P −U ∗ Bj,k−1 Cosµj η − Ki Bj,k−i Cosµj η j=0 j=0 multiplying by Cosµl η and integrating with respect to η, we get −1 X k 9 X 1 1 Sin2µ j Bj,k−2 − Bj,k = Ki Bj,k−i − 1 + Bj,k−1 I(j, l) (µ2j − µ20 ) Pe2 2µj i=1 j=0 k = (1, 2) (3.37) where, Z1 I(j, l) = U ∗ Cosµj ηCosµl ηdη = I(l, j) (3.38) −1 Bj,−1 = 0, Bj,0 = 0 f or j = 1 to 9 (3.39) The first expansion coefficient B0,k in equation (3.36) using conditions (3.13)-(3.16) can be expressed in terms of Bj,k (j = 1 to 9) as, fk = B0,k Cosµ0 η + ∞ X Bj,k Cosµj η (from equation 3.36) j=1 By integrating this equation, we get ∞ Sinµ0 η X Sinµj η 0 = B0,k + Bj,k µ0 µj j=1 (Using the boundary condition R1 fk (τ, η)dη = δk0 = 0) −1 B0,k = − µ0 Sinµ0 X 9 j=1 Bj,k Sinµj , (k = 1, 2, 3, . . .) µj Bangmod-JMCS−[email protected] (3.40) c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 73 Further, from (3.36) and (3.33) we find that µ0 (3.41) Sinµ0 Substituting i = 1 in (3.34) and using (3.38), (3.39) and (3.41) in the resulting equation, we get I(0, 0) i (3.42) K1 (∞) = − h 0 1 + Sin2µ 2µ0 B0,0 = Substituting i = 2 in (3.34) and using (3.36), (3.38) and (3.41) in the resulting equation, we get 9 X 1 Sinµ0 Bj,1 Ij,0 − 2 Pe 0 µ0 1 + Sin2µ j=0 2µ0 −1 µ0 0 = −(µ2j − µ20 )−1 1 + Sin2µ 2µ0 Sinµ0 I(j, 0) K2 = where, Bj,1 (3.43) Using the asymptotic coefficients K0 (∞), K1 (∞), and K2 (∞), in (3.9), one can determine the mean concentration distribution as a function of X, τ and the parameters a and β. The initial condition for solving (3.9) can be obtained from (2.22) by taking the crosssectional average. Since we are making long time evaluations of the coefficients, we note that the side effect is independent of θm on the initial concentration distribution. The solution of (3.9) with asymptotic coefficients can be written as: " # 2 1 [X + K1 (∞)τ ] p θm (τ, X) = exp K0 (∞)τ − (3.44) 4K2 (∞)τ 2Pe πK2 (∞)τ where, θm (τ, ∞) = 0, ∂θm (τ, ∞) = 0 ∂X 4. Results and Discussions We have modeled the solvent as a couple stress fluid(blood) and studied dispersion of solute in a blood flow bounded by porous beds in the presence of magnetic field considering heterogeneous chemical reaction, on the interphase. The walls of the channel act as catalysts to the reaction. The problem brings into focus three important dispersion coefficients namely, the exchange coefficient −K0 which arises essentially due to the wall reaction, the convective coefficient −K1 and diffusive coefficient K2 . The asymptotic values of these three coefficient are plotted in figures 2 to 16 for different value of Hartmann number (M < 1, M = 1, M > 1), Couple Stress Parameter(a = 5, 10, 20), reaction rate Parameter(β = 10−2 , 1, 102 ) and Porous Parameter (σ = 100, 200, 500). This paper gives the solutions in MATHEMATICA 8.0. From figure 2, it is cleat that −K0 increases with an increase in the wall reaction parameter(β) but it is unaffected by the couple stress parameter(a), Hartmann number (M ) and porous parameter (σ). The classical convective coefficient(−K1 ) is plotted in figures 3 to 5 versus wall reaction parameter (β) for different values of couple stress parameter(a), Hartmann number (M ) and porous parameter (σ) respectively for a fixed value of slip parameter α = 0.1, β1 = 0.1, P e = 100 and h = 2. From figure 3 and 4, Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 74 we conclude that −K1 decrease, with increasing values of couple stress parameter and Hartmann number. Figure 5 shows that increase in (−K1 ), increase the value of (σ). This is advantageous is maintaining the laminar flow. The scaled dispersion coefficient K2 − Pe−2 is plotted versus β in figures 6 to 8 for different values of a, M and σ. Figure 6 and 7, show that the increase in a and M, the effective dispersion coefficient decreases. From figure 8, we conclude that, increase in σ is to increase the effective dispersion coefficient K2 . These are useful in the control of dispersion of a solute. The cross sectional average concentration θm is plotted versus X in figures 9 to 12 respectively for different values of a, M, σ and β and for fixed values of other parameters given in these figures. It is shows that increase in β and σ decreases θm , while an increase in (a) and (M ) increases θm as expected on the physical ground. This may be attributed to increase in σ and β is to reduce the velocity and hence to decrease θm . The cross sectional average concentration θm is also plotted against the time τ in Figures 13 to 16 respectively for different values of a, M, σ and β and for fixed values of other parameters given in these figures. We conclude that the peak of θm decreases with an increase in β occurring at the lower interval of time τ . We also note that, although the peak decreases with an increase in σ and increases with an increase in a and M, but occurs at almost at the same interval of time τ.These results are useful to understand the transport of solute at different times. 5. Conclusion The present investigation brings out some interesting results on the dispersion process in flows of blood modeled as couple stress fluid in the presence of magnetic field. The convective dispersion process is analyzed employing the dispersion model of Gill and Sankarasubramanian [8]. It is observed that the effect of magnetic field on dispersion coefficient is found to decrease with increase in β and cross sectional average concentration is to increase the time to reach its peak value. References [1] G.S. Beavers and D. D. Joseph,Boundary conditions at a naturally permeable wall, J. Fluid Mech. 30(1967),197–207. [2] P. Chandra and R. P. Agarwal,Dispersion in simple micro fluid flows, International Journal of Engineering Science 21(1983), 431–442. [3] Dulal Pal, Effect of chemical reaction on the dispersion of a solute in a porous medium, Applied Mathematical Modeling 23,(1999), 557–566. [4] B. K. N. Dutta , C. Roy and A. S. Gupta, Dispersion of a solute in a nonNewtonian fluid with simultaneous chemical reaction, Mathematica-Mechanical fasc., 2(1974),78–82. [5] Francesco Gentile and Paolo Decuzzi, Time dependent dispersion of nanoparticles in blood vessels, J. Biomedical Science and Engineering 3(2010),517–524. [6] F. Gentile, M. Ferrari and P. Decuzzi,The transport of nanoparticles in blood vessels: The effect of vessel permeability and blood rheology, Annals of Biomedical Engineering2(36),(2008) , 254–261. [7] W. N. Gill,A note on the solution of transient dispersion problems, Proc. Roy. Soc. Lond. A 298(1967) ,335–339. Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 75 [8] W. N. Gill and R. Sankarasubramanian, Exact analysis of unsteady convective diffusion, Proc. Roy. Soc. Lond. A 316(1970) , 341–350. [9] P. S. Gupta and A. S. Gupta,Effect of homogeneous and heterogeneous reactions on the dispersion of a solute in the laminar flow between two plates, Proc. Roy. Soc. Lond. A 330(1972),59–63. [10] P. Meena Priya and Nirmala P. Ratchagar,Generalized dispersion of atmospheric aerosols on unsteady convective diffusion in couple stress fluid bounded by electrodes, Int. Journal of Applied Mathematics and Engineering Sciences 5(1)(2011),59–72. [11] J. Prathap Kumar, J. C. Umavathi and Shivakumar Madhavarao, Effect of homogeneous and heterogeneous reactions on the solute dispersion in composite porous medium, International Journal of Engineering, Science and Technology, Vol. 4, No. 2(2012), 58–76. [12] L. Pauling, C D. Coryell, The magnetic Properties and Structure of Hemoglobin, Oxyhemoglobin and Carbonmonoxy Hemoglobin, In: Proceedings of the National Academy of Science, USA 22 (1936), 210-216. [13] V. V. Ramana Rao, and D. Padma, Homogeneous and heterogeneous reaction on the dispersion of a solute in MHD Couette flow II, Curr. Sci., 46(1977), 42–43. [14] B. Ramana and G. Sarojamma, Unsteady Convective Diffusion in a Herschel-Bulkley Fluid in a Conduit with Interphase Mass Transfer, International Journal of Mathematical Modelling and Computations, Vol. 02, No. 03 (2012), 159 –179. [15] B. Ramana and G. Sarojamma, Effect of Wall Absorption on dispersion of a solute in a Herschel-Bulkley Fluid through an annulus, Pelagia Research Library ,Advances in Applied Science Research, 3 (6) (2012), 3878–3889. [16] B. Ramana, G. Sarojamma, B. Vishali and P. Nagarani,Dispersion of a solute in a Herschel-Bulkley fluid flowing in a conduit, Journal of Experimental Sciences , 3(2),(2012), 14–23. [17] N. Rudraiah, Dulal Pal and P. G. Siddheswar, Effect of couple stress on the unsteady convective diffusion in fluid flow through a channel, BioRheology, Vol.23(1986), 349– 358. [18] R. Sankarasubramanian and W. N. Gill,Unsteady convective diffusion with interphase mass transfer, Proc. Roy. Soc. London, A 333 (1973), 115–132. [19] J. B. Shukla, R. S. Parihar and B. R. P. Rao, Dispersion in non-Newtonian fluids: Effects of chemical reaction, Rheologica Acta,18(1979),740–748. [20] P. N. Shivakumar, N. Rudraiah, D. Pal and P. G. Siddheshwar,Closed form solution for unsteady diffusion in a fluid saturated sparsely packed porous medium, Int. Comm. Heat Mass Transfer, 14 (1987), 137–145. [21] V. M. Soundalgekar and P. Chaturani, Effects of couple-stresses on the dispersion of a soluble matter in a pipe flow of blood, Rheologica Acta, 19(1980),710–715. [22] Suvadip Paul and B. S. Mazumder, Transport of reactive solutes in unsteady annular flow subject to wall reactions, European Journal of Mechanics B/Fluids, 28(2009), 411–419. [23] G. I. Taylor, Dispersion of soluble matter in solvent flowing slowly through a tube, Proc. Roy. Soc. Lond. A., 219 (1953),186–203. Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 76 Table 1. Roots of the equation µn tanµn = β β 10−2 0.05 10−1 0.5 1.0 5.0 10.0 100.0 µ0 0.099834 0.22176 0.311053 0.653271 0.860334 1.31384 1.42887 1.55525 µ1 3.14477 3.15743 3.1731 3.29231 3.42562 4.03357 4.3058 4.66577 µ2 6.28478 6.29113 6.29906 6.36162 6.4373 6.9096 7.22811 7.77637 µ3 9.42584 9.43008 9.43538 9.47749 9.52933 9.89275 10.2003 10.8871 µ4 12.5672 12.5703 12.5743 12.606 12.6453 12.9352 13.2142 13.9981 µ5 15.7086 15.7111 15.7143 15.7397 15.7713 16.0107 16.2594 17.1093 µ6 18.8501 18.8522 18.8549 18.876 18.9024 19.1055 19.327 20.2208 µ7 21.9916 21.9934 21.9957 22.0139 22.2126 22.2126 22.4108 23.3327 µ8 25.1331 25.1347 25.1367 25.1526 25.1724 25.3276 25.5064 26.445 µ9 28.2747 28.2761 28.2779 28.292 28.3096 28.4483 28.6106 29.5577 -K0 2.0 1.5 1.0 0.5 Β 2 4 6 8 10 Figure 2. Plots of exchange coefficient versus reaction rate parameter β -K1 1.10 1.08 a=5 1.06 1.04 a=20 1.02 Β 20 40 60 80 100 Figure 3. Plots of convective coefficient −K1 versus β for different values of a when M = 1 and σ = 100 -K1 1.10 M=1 1.08 M=1.5 1.06 1.04 M=2 1.02 Β 20 40 60 80 100 Figure 4. Plots of convective coefficient −K1 versus β for different values of M when σ = 100 and a = 5 Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 77 -K1 1.12 Σ=100 1.10 1.08 Σ=200 1.06 1.04 Σ=500 1.02 Β 20 40 60 80 100 Figure 5. Plots of convective coefficient −K1 versus β for different values of σ when M = 1 and a = 5 1 K2 - Pe2 a=5 0.00135 a=10 0.00130 a=20 0.00125 Β 0.2 0.4 0.6 0.8 1.0 Figure 6. Plots of scale dispersion coefficient K2 − P e−2 versus β for different values of a when M = 1 and σ = 100 1 K2 - Pe2 0.0020 M=0.5 0.0015 M=1.0 0.0010 M=1.5 Β 0.2 0.4 0.6 0.8 1.0 Figure 7. Plots of scale dispersion coefficient K2 − P e−2 versus β for different values of M when σ = 100 and a = 5 Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 78 1 K2 - Pe2 0.0017 Σ=100 0.0016 Σ=200 0.0015 Σ=500 0.0014 0.0013 Β 0.2 0.4 0.6 0.8 1.0 Figure 8. Plots of scale dispersion coefficient K2 − P e−2 versus β for different values of σ when M = 1 and a = 5 HPeLΘm 8 a=5 6 a=10 a=20 4 2 X 0.2 0.4 0.6 0.8 1.0 Figure 9. Plots of mean concentration θm versus X for different values of a when M = 1, σ = 100, β = 10−2 and τ = 0.6 HPeLΘm 14 12 10 M=0.5 8 M=1.0 6 M=1.5 4 2 X 0.2 0.4 0.6 0.8 Figure 10.Plots of mean concentration θm versus X for different values of M when a = 5, σ = 100, β = 10−2 and τ = 0.6 Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 79 HPeLΘm 8 Σ=100 6 Σ=200 4 Σ=500 2 X 0.2 0.4 0.6 0.8 1.0 Figure 11. Plots of mean concentration θm versus X for different values of σ when M = 1, a = 5, β = 10−2 and τ = 0.6 HPeLΘm 8 Β=10-2 6 Β=1 4 Β=102 2 X 0.2 0.4 0.6 0.8 Figure 12. Plots of mean concentration θm versus X for different values of β when M = 1, a = 5, σ = 100 and τ = 0.6 HPeLΘm 8 6 a=5 a=10 4 a=20 2 Τ 0.2 0.4 0.6 0.8 1.0 Figure 13.Plots of mean concentration θm versus τ for different values of a when M = 1, σ = 100, β = 10−2 and X = 0.8 Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 80 HPeLΘm 12 10 M=0.5 8 M=1.0 6 M=1.5 4 2 Τ 0.2 0.4 0.6 0.8 1.0 Figure 14.Plots of mean concentration θm versus τ for different values of M when a = 5, σ = 100, β = 10−2 and X = 0.8 HPeLΘm 8 6 Σ=100 Σ=200 4 Σ=500 2 Τ 0.2 0.4 0.6 0.8 1.0 Figure 15.Plots of mean concentration θm versus τ for different values of σ when M = 1, a = 5, β = 10−2 and X = 0.8 HPeLΘm 8 6 Β=10-2 Β=1 4 Β=102 2 Τ 0.2 0.4 0.6 0.8 1.0 Figure 16. Plots of mean concentration θm versus τ for different values of β when M = 1, a = 5, σ = 100 and X = 0.8 APPENDIX A Bangmod-JMCS−[email protected] c 2015 By TaCS Center. Bangmod Int. J. Math. & Comp. Sci., 2015 ISSN: 2408-154X 81 p √ a2 − a4 − 4a2 M 2 √ , 2 p √ a2 + a4 − 4a2 M 2 √ m3 = , 2 m1 a3 = (m1 +ασ)e , a4 = (m1 −ασ)e−m1 , a5 = (m3 +ασ)em3 , a6 = (m3 −ασ)e−m3 , P k ∂p a7 = − ασ, 2 M µ (1 + β1 ) ∂x 2 m1 2 −m1 a8 = m1 e , a9 = m1 e a10 = m23 em3 , a11 = m23 e−m3 , Eq.(A.1) m1 = Eq.(A.2) Eq.(A.3) Eq.(A.4) Eq.(A.5) Eq.(A.6) Eq.(A.7) Eq.(A.8) Eq.(A.9) −a7 a10 − a7 a11 , a5 a8 − a6 a8 + a5 a9 − a6 a9 − a3 a10 + a4 a10 − a3 a11 + a4 a11 a7 a8 + a7 a9 = C4 = , a5 a8 − a6 a8 + a5 a9 − a6 a9 − a3 a10 + a4 a10 − a3 a11 + a4 a11 P 2C1 sinh m1 2C3 sinh m3 = + + 2, m1 m3 M C1 sinh m1 C3 sinh m3 = + , m1 m3 C1 sinh m1 C3 sinh m3 = + . m31 m33 C1 = C2 = Eq.(A.10) C3 Eq.(A.11) A1 A2 A3 Eq.(A.12) Eq.(A.13) Eq.(A.14) Bangmod International Journal of Mathematical Computational Science ISSN: 2408-154X Bangmod-JMCS Online @ http://bangmod-jmcs.kmutt.ac.th/ c Copyright 2015 By TaCS Center, All rights reserve. 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