File - Eisenhower High School Chemistry

Eisenhower Airlines Flight 1023 You and your CSI team are called to the scene of a plane crash. The plane shows evidence of a pre‐crash explosion. The site of the explosion has a compound with the following analysis: 37.01% carbon, 2.22% hydrogen, 18.5% nitrogen, and 42.27% oxygen. The victims are found in and around the crash and must be identified by the substance or substances found in their belongings or in their bodies since dental records are not available. Further evidence reveals that one person was murdered before the plane went down with the time of death established as one hour before the crash. Your job is to: 1. Use the percent composition data to determine the empirical formulas and identities for the compounds found at the crash site. (You must show all work on separate paper and turn it in with your final answers). 2. Use personal data to make a probable identification of each victim. 3. Determine who was murdered and who the most probable murderer is. VICTIM # 1. 2. ANALYSIS OF COMPOUND
% H
% N
6.98
4.62
5.30
% C 67.31 63.15 WHERE FOUND
% O
21.10
31.55
46.66 4.48 31.1 17.76 3. 4. 5. 72.15 15.87 75.42 7.08
2.22
6.63
4.68
18.51
8.38
16.03
63.41
9.57
6. 7. 37.01 57.14 80.48 2.22 6.16
7.45
18.5 9.52
9.39
42.27 27.18
2.68
8.90 4.48
9.52 8. 81.58 60.00 63.56 6.00 9.27 21.17 blood & luggage
briefcase (a)
stomach (b) pockets blood & pockets
blood (a) luggage (b) stomach briefcase (a)
35.53
luggage (b) pocket & briefcase(a)
pocket & briefcase(b) Use the table below to identify each of the compounds described above. The Flight List of Passengers and Crew: POSSIBLE COMPOUNDS NAME FORMULA NOTES
codeine C18H21NO3 painkiller, prescription, controlled
cocaine C17H21NO4 narcotic, illegal
aspirin C9H8O4 pain killer
vanilla C8H8O3 flavoring
trinitrotoluene C7H5N3O6 explosive
nitroglycerine C3H5N3O9 explosive, heart medication
curare C40H44N4O poison
thiobromine C7H8N4O2 chocolate (flavoring)
strychnine C21H22N2O2 rat poison
dimetacrine C10H13N antidepressant, prescription
acetaminophen C8H9NO2 pain killer (Tylenol)
aspartame C14H18N2O5 artificial sweetener (NutraSweet)
Kirchivald Swanson ‐ the pilot, yoga enthusiast, had a heart valve replacement surgery one year ago Melvin Minton – former quarterback for the Alpena Wildcats of the AFL, suspended for drug use Jasper Soloman‐ worked as an exterminator but was always conflicted due to an innate love of nature, clinically depressed Mertle DeCardenas – owned a small bakery in a run‐down part of Detroit Mortimer Pearson – pharmacist and part‐time mortician Jerome Logsdon – high school literature teacher addicted to sugar free drinks & poetry Joseph Siemianowski ‐ suspected leader of a terrorist organization called Nauka Nauczyciel Leonard Craun ‐ suspected drug dealing drop out of his high school’s Key Club Eisenhower Airlines Flight 1023 – CRASH REPORT Name of investigators ____________________________________________________ Remember ‐ you must show all work on separate paper and staple it to this page when you turn it in. VICTIM NAME OF SUBSTANCE VICTIM NAME
JUSTIFICATION # FOUND 1. 2. a. b. 3. 4. 5. a. b. 6. 7. a. b. 8. a. b. 1. What chemical was found at the crash site? 2. Who was the murderer? What evidence supports this? 3. Who was murdered? What evidence supports this? 4. Who had the explosives? What evidence supports this? 5. Use all of the evidence to describe the events leading up the plane crash.