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HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY DIJATOMITI U HRVATSKOJ: NJIHOV POTENCIJAL KAO PRIRODNI INSEKTICID DIATOMITE IN CROATIA: THEIR POTENTIAL AS NATURAL INSECTICIDE Ines Galović1, Josip Halamić1, Vlatka Rozman2, Zlatko Korunić3, Anita Liška2, Renata Baličević2, Pavo Lucić2 1Hrvatski 2Poljoprivredni geološki institut, Sachsova 2, 10000 Zagreb, Republika Hrvatska fakultet u Osijeku, Sveučilište Josipa Jurja Strossmayera u Osijeku, Kralja Petra Svačića 1d, 31000 Osijek, RH 3Diatom Research and Consulting Inc., 14 Tidefal Dr. Toronto, ON, MW 1J2, Canada www.diacromixpest.eu HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY Croatian Science Foundation (HRZZ) - call: IP-11-2013 (three-year research project) Project title: Development of new natural insecticide formulations based on inert dusts and botanicals to replace synthetic, conventional insecticides •Project acronym: DIACROMIXPEST •Project No. IP-11-2013-5570 •Period: from 1 July 2014 to 30 June 2017 •Project leader: Prof. Ph. D. Vlatka Rozman (FoA Osijek) HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY PROJECT TEAM Professor Vlatka Rozman Project leader Institution: Faculty of Agriculture, University of Osijek Assistant Professor Anita Liška Professor Josip Halamić Ph. D. Zlatko Korunić Associate Professor Renata Baličević Pavo Lucić, MSc. Ing. Agr. Research Associate Ines Galović HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY What is diatomite (diatomaceous earth)? Porous, fine-grained siliceous sedimentary rock mainly composed of fossilized (amorphous opaline silica: SiO2·nH2O) remains of diatoms formed in marine to freshwater environments of mid-high latitudes. When diatomite is crushed into a powder, it is usually called “diatomaceous earth,” or D.E. http://diatomaceous. org/food-gradediatomaceous-earth/ https://www.flickr.com/photos/rockbandit/169 058743/ http://earthcore.weebly.com/diatomace ous-earth.html HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY Marine sediments HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY - first diatomites are known from Dolje outcrops, Medvednica Mt., based on diatom analyses of diatomaceous tripolite (PANTOCSEK, 1903, JURILJ, 1957, KOCHANSKY-DEVIDE & BAJRAKTAREVIĆ, 1981 i GALOVIĆ & BAJRAKTATRVIĆ, 2006), and Lopatice i Gornja Šemnica, Hrvatsko Zagorje (BAJRAKTAREVIĆ, 1984) - First applied terminology of diatomites were used by GORJANOVIĆKRAMBERGER (1908) and Jurilj. - during the investigations for OGK RH 1:50000 from 2000 to 2004. few more outcrops of tripolite (diatomite) was discovered: at Medvednice (Markuševec section), Hrvatsko Zagorje (Crkovec), Plešivice (Jurjevčani) and Požega. - The investigations on HRZZ project induced few more potential diatomite outcrops in Banovina and Slavonija. Localities of potential diatomites in North Croatia. HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY The typical chemical composition of oven-dried diatomaceous earth is 70 to 90% silica, with 2 to 4% alumina (attributed mostly to clay minerals) and 0.5 to 2% iron oxide. Preliminary results on diatom analyses indicate dominance of Coscinodiscus spp., Thalassionema nitzschoides (GRUNOW) MERESCHKOWSKY and resting spores, which dimensions are less than 50 microns. HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY Usage of Diatomaceous Earth DE is used as a filtration aid, mild abrasive in products including metal polishes and toothpaste, mechanical insecticide, absorbent for liquids, matting agent for coatings, reinforcing filler in plastics and rubber, anti-block in plastic films, porous support for chemical catalysts, cat litter, activator in blood clotting studies, a stabilizing component of dynamite, and a thermal insulator. HRVATSKI GEOLOŠKI INSTITUT CROATIAN GEOLOGICAL SURVEY Acknowledgement Financial support was provided by the Croatian Science Foundation (HRZZ): Scientific research project IP-11-2013-5570: “Development of new natural insecticide formulations based on inert dusts and botanicals to replace synthetic, conventional insecticides“ www.diacromixpest.eu Thank you for your attention!