Scientific Program - 20th International Symposium on

ORAL PROGRAM
July 11 (Mon)
TERRSA Hall
9:00-9:30
Opening Remarks
KL01
Tandem Catalytic Strategies for Processing Biofeedstocks
9:30-10:05
Tobin J. MARKS (Northwestern University)
KL02
New Reactivities of Gold Complexes: It Is All a Question of Ligand
Design!
10:05-10:40
Didier BOURISSOU (Université Paul Sabatier, LHFA-CNRS)
SL01
Adventures in Catalysis: from Mechanisms to Applications
11:00-11:20
Franziska SCHOENEBECK (RWTH Aachen University)
KL03
Transition Metal-Catalyzed Reduction of Molecular Dinitrogen into
Ammonia under Ambient Conditions
11:20-11:55
Yoshiaki NISHIBAYASHI (The University of Tokyo)
SL02
Bringing Ziegler-Natta Catalysts from Lab-Scale to World-Class
Size Polyethylene Plants
11:55-12:15
Matthias KRUCK (SABIC)
SL03
Selective Catalytic Aerobic Oxidation of Polyols and
Carbohydrates: Scope and Mechanism
12:15-12:35
Robert M. WAYMOUTH (Stanford University)
KL04
Advances in Atom Economic, Early Transition Metal Catalyzed
Amine Synthesis. Intermolecular Reactions of Alkenes by
Hydroamination and Hydroaminoalkylation
14:05-14:40
Laurel L. SCHAFER (The University of British Columbia)
SL04
Dinuclear Iron(III) Catalyzed
O
-Seletive Acylation of Aliphatic and
Aromatic Amino Alcohols and Transesterification of
tert
-Alcohols
14:40-15:00
Takashi OHSHIMA (Kyusyu University)
SL05
Towards Adaptive Catalytic Systems for Continuous-Flow
Asymmetric Catalysis
15:00-15:20
Walter LEITNER (RWTH Aachen University)
SL06
Ir-Catalyzed Selective Borylation of Carboranes via B–H Bond
Activation
15:20-15:40
Zaozao QIU (Shanghai Institute of Organic Chemistry)
SL07
Macrocyclic Iron(II)/(NH) P
2 2
Catalysts for the Highly Enantioselecti-
ve Transfer Hydrogenation of Polar Double Bonds on a Large Scale
15:40-16:00
Antonio MEZZETTI (ETH Zürich)
KL05
Palladium-Catalyzed Aerobic Cross-Dehydrogenative Coupling of
Unactivated Arenes
16:20-16:55
Paul L. ALSTERS (DSM)
SL08
Amide Hydrogenation: for Every Demand, a Catalyst!
16:55-17:15
Elisabetta ALBERICO (Istituto di Chimica Biomolecolare, CNR)
KL06
Ligand-Accelerated C–H Activation Reactions: Distance and
Geometry
17:15-17:50
Jin-Quan YU (The Scripps Research Institute)
SL09
Sustainable Synthesis of Amines—Direct Amination of
(Bio)Alcohols with NH
3
17:50-18:10
Dieter VOGT (University of Edinburgh)
SL10
Hydrofunctionalization of Alkynes Promoted by Rhodium–
18:10-18:30
N
-Heterocyclic Carbene Catalysts
Luis A. ORO (University of Zaragoza)
July 12 (Tue)
TERRSA Hall
KL07
Transition Metal-Catalyzed Asymmetric Allylic Dearomatization
Reactions
9:00-9:35
Shuli YOU (Shanghai Institute of Organic Chemistry)
KL08
Enantioselective and Light-Induced Catalysis with Redox-Active
Halides
9:35-10:10
Kilian MUÑIZ (Institute of Chemical Research of Catalonia)
SL11
Supramolecular Photocatalyst for the Reduction of Au(III) to Au(I)
and High Turnover Generation of Gold Nanocrystals
10:10-10:30
Brigitte BIBAL (Université de Bordeaux)
KL09
The Active Site in the Spotlight!
10:50-11:25
Moniek TROMP (University of Amsterdam)
SL12
Computational Approaches to Develop Phosphoramidite Ligands
Applied to Asymmetry Cycloisomerization and Conjugate Addition
11:25-11:45
Qian PENG (University of Oxford)
SL13
Chiral Triazole H-Donors in Anion-Binding: Novel Catalysts for the
Enantioselective Dearomatization of
N
-Heteroarenes
11:45-12:05
Olga GARCĺA MANCHEÑO (University of Regensburg)
SL14
Development of Catalytic System for Functional Materials
Synthesis
12:05-12:25
Mitsuru OHNO (Daicel)
KL10
Bringing Modern Data Analysis Tools to Prediction in Catalyst
Discovery
15:25-16:00
Matthew SIGMAN (University of Utah)
SL15
Catalytic Enantioselective Amination of Alcohols via Borrowing
Hydrogen
16:00-16:20
Yu ZHAO (National University of Sigapore)
SL16
A Chiral Electrophilic Selenium Catalyst for Highly
Enantioselective Oxidative Cyclization
16:20-16:40
Takuya HASHIMOTO (Kyoto University)
KL11
Asymmetric Hydroformylation and Transfer Hydroformylation:
Expanding Synthetic Utility and Mechanistic Understanding
17:00-17:35
Matt L. CLARKE (University of St Andrews)
KL12
Transition State Models in Asymmetric Catalysis: A Tool for
Rational Catalyst Design
17:35-18:10
Raghavan B. SUNOJ (Indian Institute of Technology Bombay)
SL17
Use of Homogeneous Catalysis Concepts to Prepare Well-Defined
Single-site Heterogeneous Catalysts
18:10-18:30
Jean-Marie BASSET (King Abdullah University of Science &
Technology)
July 13 (Wed)
TERRSA Hall
KL13
From Reactivity to NMR Physical Properties: The Example of
d0
Olefin Metathesis Catalysts
9:00-9:35
Odile EISENSTEIN (CNRS and Université de Montpellier)
KL14
Synthesis, Structure, and Catalysis of New Transition Metal
Complexes Having a Heavier Group 13 Element as a Supporting
Ligand
9:35-10:10
Jun TAKAYA (Tokyo Institute of Technology)
SL18
Catalytic Hydrogen Transfer Reactions Enabled by Ligand Design
10:10-10:30
Nathaniel SZYMCZAK (University of Michigan)
KL15
Commercial Applications of the Pd-Catalyzed Telomerization of
Butadiene with Methanol in the Synthesis of 1-Octene
10:50-11:25
Jessica L. KLINKENBERG (Dow Chemical)
SL19
Regioselective Carbonylations of Alkenes Using Recyclable CO
Surrogates
11:25-11:45
Ivana FLEISCHER (University of Regensburg)
SL20
Carboxyzincation Employing Carbon Dioxide and Zinc Powder:
Cobalt-Catalyzed Multicomponent Coupling Reactions with
Alkynes
11:45-12:05
Tetsuaki FUJIHARA (Kyoto University)
July 14 (Thu)
TERRSA Hall
KL16
Asymmetric Catalysis Activated by Visible Light
9:00-9:35
Eric MEGGERS (University of Marburg)
KL17
Using Computer Models to Understand and Predict Oxidative
Addition Reactions
9:35-10:10
Mu-Hyun BAIK (Korea Advanced Institute of Science & Technology)
SL21
New Catalytic Pathways for Radical Chemistry and Dual Catalysis
10:10-10:30
Louis FENSTERBANK (Sorbonne Universités)
KL18
Isomerization and Tandem Isomerization/Electrophilic
Halogenation of Allyic Alcohols. Transition Metal versus Organic
Catalysts
10:50-11:25
Belén MARTÍN-MATUTE (Stockholm University)
SL22
Water in Alkane Functionalization and Other Oxidation Catalyses
with Metal Coordination Compounds
11:25-11:45
Armando POMBEIRO (Instituto Superior Tecnico)
SL23
Rh(I)-Catalyzed Selective Hydroformylation Using Formaldehyde
11:45-12:05
Tsumoru MORIMOTO (Nara Institute of Scince and Technology)
SL24
Homogeneous C–N Coupling Catalysts Derived from Earth
Abundant Ni and Co Complexes of Donor Functionalised
N
-Heterocyclic Carbene Ligands
12:05-12:25
Muhammad D. BALA (University of KwaZulu-Natal)
KL19
Design of Visible-Light-Active Photocatalysts for Molecular
Transformation of Organic Compounds
15:25-16:00
Akiko INAGAKI (Tokyo Metropolitan University)
SL25
On the Invention of Atom Economic Reactions: RhodiumCatalyzed Addition of Pronucleophiles to Alkynes and Allenes
16:00-16:20
Bernhard BREIT (Albert-Ludwigs-Universität Freiburg)
SL26
Redox Switches for Catalysis Using Ferrocene-Based Ligands
16:20-16:40
Paula L. DIACONESCU (University of California, Los Angeles)
KL20
Rare-Earth Metal-Promoted 1,3-Diene Polymerization: SingleComponent Catalysts and Deactivation Reactions
16:40-17:15
Reiner ANWANDER (University of Tübingen)
July 15 (Fri)
TERRSA Hall
3
KL21
A New Class of PN -Pincer Ligands for Metal-Ligand Cooperation
9:00-9:35
Kuo-Wei HUANG (King Abdullah University of Science & Technology)
SL27
Dearomative Silylation of
N
-Heteroarenes Leading to Structually
Diverse Azacyclic Compounds
9:35-9:55
Sehoon PARK (Korea Advanced Institute of Science & Technology)
SL28
Synthesis of Stereoblock Polyisoprene with Neodymium Catalyst
9:55-10:15
Ryo TANAKA (Hiroshima University)
KL22
Unifying Heterogeneous and Homogeneous OER and ORR
Catalysis
10:15-10:50
Daniel G. NOCERA (Harvard University)
SL29
Direct Synthesis of Primary Amines via Ruthenium-Catalysed
Amination of Ketones with Ammonia and Hydrogen
11:10-11:30
Juan GALLARDO-DONAIRE (CaRLa)
SL30
‘Ru’ Complex Catalyzed Ester Metathesis Reaction and Its
Application to Transfer Hydrogenation of Esters with Primary
Alcohols
11:30-11:50
Eugene KHASKIN (Okinawa Institute of Science and Technology)
SL31
Synthetic Metalloproteins for Olefin Metathesis
11:50-12:10
Jun OKUDA (RWTH Aachen University)
SL32
Catalysis of Extreme Local Concentrations in Self Assembled
Nano-Spheres
12:10-12:30
Joost N. H. REEK (University of Amsterdam)
12:30-
Poster Award Ceremony & Closing Remarks
POSTER PROGRAM
July 12 (Tue)
1P-001
A Convenient Protocol for Catalytic Aromatic Pentafluoroethylation Using
Potassium (Pentafluoroethyl)trimethoxyborate
Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, and Hideki Amii
Gunma University, Japan
1P-002
First Complementary Asymmetric Reduction Catalyzed by Chiral Vanadyl(V)
Methoxide Complexes Using Pinacolborane and Catecholborane
Rachit Agarwal, Zhen-Xing Yang, and Dai-Jen Lin
National Tsing Hua University, Taiwan
1P-003
Carrier-Free Thiol-Protected Gold Nanoclusters Catalyzed Synthesis of N-Containing
Compounds
Yurina Adachi, Hideya Kawasaki, and Yasushi Obora
Kansai University, Japan
1P-004
C-4 Selective Borylation of Pyridines by Cooperative Iridium/Aluminum Catalysis
Lichen Yang, Teruhiko Saito, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan
1P-005
Straightforward Biomass Oxidation to Formic Acid Using Polyoxometalate Catalysts
(OxFA process) in an Integrated Biphasic Liquid-Liquid Reaction Media
Jakob Albert, Peter Wasserscheid, and Jenny Reichert
FAU Erlangen-Nuremberg, Germany
1P-006
Non-Metathesis Heterocycle Formation by Ruthenium-Catalyzed Intramolecular
[2+2] Cycloaddition of Allenamide-enes to Azabicyclo[3.1.1]heptanes
Mitsuhiro Arisawa,1,2 Yusuke Yoneshige,1 Tomomi Nada,2 Yasuhiro Ii,1 Satoshi Shuto,2
and Hiromichi Fujioka1
1
Osaka University, Japan, 2Hokkaido University, Japan
1P-007
Dynamic Kinetic Asymmetric Transformations with Hard Nucleophiles:
Cyclopentenes for Anti Tuberculosis and Antibiotics
Hadia Anwar Almahli
University of Oxford, UK
1P-008
Enanatioselective Nitro-Aldol Reaction of Isatins Using New AminoalcoholSquaramide Type Organocatalyst
Madhu Chennapuram,1 Ummareddy Venkata Subba Reddy,1 Chigusa Seki,1 Koji
Uwai,1 Yuko Okuyama,2 Michio Tokiwa,3 Mitsuhiro Takeshita,3 and Hiroto Nakano1
1
Muroran Institute of Technology, Japan, 2Tohoku Medical and Pharmaceutical University,
Japan, 3Tokiwakai Group, Japan
1P-009
Synthesis of CPZEN-45: Construction of the 1,4-Diazepin-2-one Core by
Cu-Catalyzed Intramolecular Amidation of a Vinyl Iodide
Takuma Yoshida, Hugh Nakamura, Chihiro Tsukano, and Yoshiji Takemoto
Kyoto University, Japan
1P-010
Rapid Access of the Taxol Core
Thomas Philippe Andre and Stephen P. Fletcher
University of Oxford, UK
1P-011
Multiple Functionalization of Dimethylpolysiloxanes Based on Iridium-Catalyzed
3
C(sp )–H Borylation
Toshimichi Ohmura, Kazuki Emura, Takeru Torigoe, and Michinori Suginome
Kyoto University, Japan
1P-012
Non-Covalent Interactions in Substrate Directable Enantioselective Heck Reactions
Ricardo Almir Angnes,1 Juliana Manso de Oliveira,1 Vitor H. Menezes da Silva,2
Bruno M. Servilha,2 Ataualpa A. C. Braga,2 and Carlos Roque Duarte Correia1
1
University of Campinas, Brazil, 2University of São Paulo, Brazil
1P-013
Hydrogen Production from a Methanol-Water Solution Catalyzed by an Iridium
Complex Bearing a Functional Ligand under Mild Conditions
Ken-ichi Fujita, Ryoko Kawahara, Takuya Aikawa, and Ryohei Yamaguchi
Kyoto University, Japan
1P-014
Development of Phosphoramidite Ligands for Copper Catalysed Conjugate Addition
onto 3-Methyl-cyclopent-2-enone with the Aid of Calculations
Ruchuta Ardkhean, Stephen F. Fletcher, and Robert S. Paton
University of Oxford, UK
1P-015
In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene
Oxide and CO2
Masahiro Hatazawa,1 Koji Nakabayashi,2 Shin-ichi Ohkoshi,2 and Kyoko Nozaki1
1
Graduate School of Engineering, The University of Tokyo, Japan, 2Graduate School of Science,
The University of Tokyo, Japan
1P-016
Modular Approach to 1,8-Naphthalimide Fluorophores and Theranostic Agents
Using the Buchwald-Hartwig Cross-Coupling
Trent D. Ashton,1 Cassandra L. Fleming,2 Tim D. Nalder, 1 Kyle N. Hearn, 1 and
Frederick M. Pfeffer1
1
Deakin University, Australia, 2Chalmers University of Technology, Sweden
1P-017
Chloride-Bridged Dinuclear Rhodium(III) Complexes Bearing Chiral Diphosphine
Ligands as New Rhodium(III) Catalyst Precursors for Asymmetric Hydrogenation of
Simple Olefins
Kenya Higashihara, Shoji Hida, Himanshu Sekhar Jena, Kosuke Higashida, Yusuke
Kita, and Kazushi Mashima
Osaka University, Japan
1P-018
Reduction of Ketones and Aldehydes with Moisture Tolerant Frustrated Lewis Pair
Catalyst
Mária Bakos, Ádám Gyömöre, Tamás Földes, Imre Pápai, Attila Domján, and Tibor
Soós
Hungarian Academy of Sciences, Hungary
1P-019
Zinc Catalyzed Alcoholysis and Formation of Tertiary N-β -Hydroxyethylamides via
Acyl Rearrangement
Takahiro Hirai, Yuji Nishii, Teruhiko Saito, and Kazushi Mashima
Osaka University, Japan
1P-020
Performance and Phase Behavior of Polymer Particles as Phase Transfer Agents in
Multiphasic Reactions
Bachir Bibouche,1 Daniel Peral,1 Hongxing Yu,1 Pablo Botero,1 Joe Mardoukh,1
Dmitrij Stehl,1 Reinhard Schomäcker,1 and Dieter Vogt2
1
Technische Universität Berlin, Germany, 2University of Edinburgh, UK
1P-021
Stoichiometric Acyclic Coupling Reactions of Conjugated Diene with Cumulenes
Masafumi Hirano, Takuya Okamoto, Nobuyuki Komine, and Sanshiro Komiya
Tokyo University of Agriculture and Technology, Japan
1P-022
Direct Observation of Physical Autocatalysis by Interferometric Scattering
Microscopy
Andrew J. Bissette, Jaime Ortega-Arroyo, Philipp Kukura, and Stephen P. Fletcher
University of Oxford, UK
1P-023
High-Pressure Hydrogen Gas Generation from Aqueous Formic Acid Using Iridium
Complex Catalyst Having Hydroxyl Ligand
Masayuki Iguchi, Yuichiro Himeda, and Hajime Kawanami
National Institute of Advanced Industrial Science and Technology, Japan
1P-024
Balancing Productive Reactivity and Competitive Deactivation with Cooperative
Ligands
Johanna M. Blacquiere
University of Western Ontario, Canada
1P-025
C-3 Selective Alkenylation of N-Acylindoles by Cooperative Nickel/Aluminum
Catalysis
Fumiyoshi Inoue, Teruhiko Saito, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan
1P-026
Ruthenium(II) and Iridium(III) Complexes Featuring NHC-alkylsulfonate Chelating
Ligand and Applications in Hydrogen Transfer Reactions
Christian Bruneau, Aruna Rajaraman, Apurba R. Sahoo, Frederic Hild, Cedric
Fischmeister, and Mathieu Achard
University of Rennes 1, France
1P-027
Synthesis of Substituted Nitrogen-Containing Heterocyclic Compounds Using Gold
Catalyzed Cascade Reaction
Shiori Nonaka, Minami Yamaguchi, Hiroshi Kameya, Daichi Itagaki, Kenji Sugimoto,
Hirofumi Ueda, and Hidetoshi Tokuyama
Tohoku University, Japan
1P-028
Exclusive Csp3–Csp3 vs Csp2–Csp3 Reductive Elimination from PtIV Governed by
Ligand Constraints
Shrinwantu Pal,1,2 Eric G. Bowes,2 and Jennifer A. Love2
1
The University of Tokyo, Japan, 2The University of British Columbia, Canada
1P-029
Volcano Plots and Linear Scaling Relationships in Homogeneous Catalysis
Michael Busch, Matthew D. Wodrich, and Clémence Corminboeuf
Ecole Polytechnique Fédéral de Lausanne, Switzerland
1P-030
AZADO-CuCl/bpy/DMAP/Air Enables Highly Efficient Oxidation of Amino Alcohols to
Amino Carbonyl Compounds
Yoshiharu Iwabuchi, Yusuke Sasano, Shota Nagasawa, Naoki Kogure, and Masatoshi
Shibuya
Tohoku University, Japan
1P-031
Selective Ruthenium-catalyzed Reductive Alkoxylation and Amination of Cyclic
Imides
Jose Ramón Cabrero Antonino, Iván Sorribes, Kathrin Junge, and Matthias Beller
Leibniz-Institut für Katalyse e.V., Germany
1P-032
Palladium-Catalyzed Enantioselective Arylation of Fluoro-ketones
Yushu Jin,1,2 Jason Joseph Beiger,2 Shaozhong Ge,2 John F Hartwig2
1
Kyushu University, Japan, 2Unversity of California, Berkeley, USA
1P-033
Dehydrogenative Oxidation of Alcohols in Water Catalyzed by an Iridium Complex
Bearing a Functional N-Heterocyclic Carbene Ligand
Masato Yoshida, Ryuichi Tamura, Yuhi Tanaka, Ken-ichi Fujita
Kyoto University, Japan
1P-034
Hyperbranched Ethylene Oligomers by κ2-(N,O)-salicylaldiminato Ni(II) complexes:
DFT and Experimental Investigation of The Role of Remote Substituents
Lucia Caporaso,1 Laura Falivene,2 Luigi Cavallo,2 Thomas Wiedemann,3 Inigo
Göttker-Schnetmann,3 and Stefan Mecking3
1
University of Salerno, Italy, 2King Abdullah University of Science and Technology,
Saudi Arabia, 3University of Konstanz, Germany
1P-035
Reductive Cross-Coupling of Alkynes and Aryl Iodides with Hydrogen by
Cooperative Palladium/Copper Catalysis
Ryohei Kameyama, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan
1P-036
Selective Catalytic Deuteration of Phosphorus Ligands using Ruthenium and
Rhodium Nanoparticles
Sergio Castillon,1 Emma Breso,1 Francisco Martinez,1 Cyril Godard,1 Carmen Claver,1
and Bruno Chaudret,2
1
University Rovira i Virgili, Spain, 2Institut National des Sciences Appliquées, France
1P-037
Stereoselective Mannich-type Reaction of Oxindoles under the Catalysis of Chiral
Ammonium Betaines
Kohsuke Kato,1,2 Masahiro Torii,1,2 Daisuke Uraguchi,1,2 and Takashi Ooi,1,2
1
Nagoya University, Japan, 2CREST, JST, Japan
1P-038
Supramolecular Helical Polymers as a Platform for Asymmetric Catalysis: Inducing,
Amplifying and Switching Chirality
Xavier Caumes,1 Alaric Desmarcheliers,1 Malcolm Zimbron,2 Matthieu Raynal,1
Christophe Thomas,2 and Laurent Bouteiller1
1
Sorbonne Universités, UPMC Université Paris 6, France, 2Chimie Paris Tech, France
1P-039
Organosilicon Reagents as Reductants of Early Transition Metal Complexes in a
Salt-free Manner for Generating Catalytically Active Species
Kento Kawakita, Teruhiko Saito, Haruka Nishiyama, Hayato Tsurugi, and Kazushi
Mashima
Osaka University, Japan
1P-041
An Yttrium-Containing Polyoxovanadate for Cyanosilylation of Carbonyl
Compounds
Yuji Kikukawa and Yoshihito Hayashi
Kanazawa University, Japan
1P-042
Synthesis and Electrochemical Performance of Polypyrrole/Manganese
Oxide/Graphene Oxide Ternary Hybrid by in situ Polymerization
Dong Hwang Chen and Pin Ru Wu
National Cheng Kung University, Taiwan
1P-043
Metal-free C(3)–H Arylation of Coumarins Promoted by Catalytic Amounts of
5,10,15,20-Tetrakis(4-diethylaminophenyl)porphyrin
Masahiro Kojima,1 Kounosuke Oisaki,1 and Motomu Kanai1,2
1
The University of Tokyo, Japan, 2JST-ERATO, Japan
1P-044
Synthesis of Phenanthridinone Derivatives from Benzyne
Yali Chen
Shanghai University, China
1P-045
Ruthenium-Catalyzed Selective Monofunctionalization via Cleavage of Inert
Aromatic Carbon–Heteroatom Bonds
Hikaru Kondo, Nana Akiba, Takuya Kochi, and Fumitoshi Kakiuchi
Keio University, Japan
1P-046
Tayloring Flavins for Visible-Light Photocatalysis: Flavin Mediated [2+2]
Photocycloadditions and Cycloreversions
Radek Cibulka, Michael Jirásek, Karolína Straková, Tomáš Hartman, Viktor Mojr, and
Eva Svobodová
University of Chemistry and Technology, Czech
1P-047
Nickel-Catalyzed Redox-Economical Coupling
Toshifumi Takahashi,1 Takuya Kurahashi,1,2 and Seijiro Matsubara1
1
Kyoto University, Japan, 2JST, ACT-C, Japan
1P-048
Catalytic Properties of Nitrogen Schiff Base Complexes to Valorize CO2 as Cyclic
Carbonates
Lorraine Christ
Institut de Recherches sur le Catalyse et Environnement de Lyon, France
1P-049
Catalytic Asymmetric Hydrogenation of Isoxazoles
Ryoichi Kuwano and Ryuhei Ikeda
Kyushu University, Japan
1P-050
Base-Promoted, Selective Alkyl Carbon–Oxygen Bond Cleavage of Aryl Alkyl Ethers
by Iridium(III) Porphyrin Complexes
Chen Chen and Kin Shing Chan
The Chinese University of Hong Kong, China
1P-051
Nickel-catalyzed Cross-coupling of Anisole Derivatives with Trimethylaluminum
through the Cleavage of Carbon–Oxygen Bonds
Mamoru Tobisu, Toshifumi Morioka, and Naoto Chatani
Osaka University, Japan
1P-052
Immobilized Pd-NHC Catalysts for Internal and Terminal Alkynes
Semihydrogenation
Carmen Claver,1 Alberto Martinez,1 Cyril Godard,1 Francio Giancarlo,2 Walter
Leitner2
1
University Rovira i Virgili, Italy, 2RWTH Aachen University, Germany
1P-053
Formation of 2,3-Bismethylenechromanes by Palladium-catalyzed Reaction of Aryl
Ethynyl Ethers with Allyl Pivalates through Double C–H Bond Cleavage
Yasunori Minami, Megumi Sakai, Tomohiro Anami, and Tamejiro Hiyama
Chuo University, Japan
1P-055
Rhodium-Catalyzed Reactions Using N-Sulfonyl-1,2,3-triazoles as Precursors of
Carbenoid Species
Tomoya Miura, Takayuki Nakamuro, Yuuta Funakoshi, Qiang Zhao, and Masahiro
Murakami
Kyoto University, Japan
1P-056
Non-covalent Interactions Enabled Diastereo- and Enantioselectivity to Build S- and
P-stereogenic Heterocyles
Francisco de Azambuja, Rafaela C. Carmona, Gabriel Heerdt, Tomaz H. D. Chorro,
and Carlos R. D. Correia
Universidade Estadual de Campinas, Brazil
1P-057
Designed Organotellurium Monomers for Living Control Polymerization of
Hyperbranched Polyacrylate
Yangtian Lu and Shigeru Yamago
Kyoto University, Japan
1P-058
Asymmetric Hydrogenation of 3-Substituted Pyridinium Salts
Johannes Gerardus de Vries,1 Laurent Lefort,2 Marc Renom-Carrasco,2,3 Piotr
Gajewski,2,3 Luca Pignataro,3 Umberto Piarulli,4 and Cesare Gennari3
1
Leibniz-Institut für Katalyse, Germany, 2DSM Ahead R&D B.V., The Netherlands, 3Università
degli Studi di Milano, Italy, 4Università degli Studi dell'Insubria, Italy
1P-059
Sulfoximine: A Reusable Directing Group for C–O, C–N and C–C Bond Formation via
C–H Bond Activation of Arenes
Ramu Yadav Muntha, Raja K. Rit, Majji Shankar, E. Ramesh, Koushik Ghosh, and
Akhila K. Sahoo
University of Hyderabad, India
1P-060
Electrophilic Cyanation of Boron Enolates: Efficient Access to β -Ketonitriles
Takaya Nagata, Kensuke Kiyokawa, and Satoshi Minakata
Osaka University, Japan
1P-061
Cu and Ni-based Catalysts for Carboxylation with CO2
Miriam Díaz de los Bernardo,1 yril Godard,2 Sergio Castillón,2 and Carmen Claver1
1
Centre Tecnològic de la Química a Catalunya, Spain, 2Universitat Rovira i Virgili, Spain
1P-062
Polyquinoxaline-based Helically Chiral Homogenous Nucleophilic Catalyst for
Asymmetric Steglich Rearrangement
Michinori Suginome, Ryo Murakami, and Takeshi Yamamoto
Kyoto University, Japan
1P-063
Isotopic Labelling of a Phosphine-Catalyzed [3+2] Cyclization Reaction: A Combined
in-situ FTIR, BTEM, and DFT Study
Tung Nguyen Dinh,1 Maxime Gicquel,2 Arnaud Voituriez,2 Angela Marinetti,2 James
David Nobbs,1 Cechao Foo,1 Angie Cheong,1 Qisong Xu,1 Liangfeng Guo,1 Shuying
Cheng,1 and Mark Vincent Garland1
1
Institute of Chemical and Engineering Sciences, Singapore, 2Institut de Chimie des Substances
Naturelles, France
1P-064
Iridium-Catalyzed Alkylation of 2-(Alkylamino)pyridines via Secondary sp3 C–H
Bond Activation
Masaki Nagai, Midori Nagamoto, Takahiro Nishimura, and Hideki Yorimitsu
Kyoto University, Japan
1P-065
Polyhydroacenes Made Easy by Gold(I) Catalysis
Ruth Dorel, Paul R. McGonigal, and Antonio M. Echavarren
Institute of Chemical Research of Catalonia, Spain
1P-066
Multiple Absolute Stereocontrol in Pd-Catalyzed [3+2] Cycloaddition of
Oxazolidinones and Trisubstituted Alkenes Using Chiral Ammonium-Phosphine
Hybrid Ligands
Yuya Nagato, Kohsuke Ohmatsu, Takashi Ooi
Nagoya University, Japan
1P-067
Catalytic Reductive Amination of Carbonyl Compounds with Frustrated Lewis Pairs
Éva Dorkó, Attila Domján, Márk Szabó and Tibor Soós
Hungarian Academy of Sciences, Hungary
1P-068
Ru-Catalyzed Anti-Markovnikov Hydroamination and Hydroalkoxylation of Allylic
Alcohols on the Basis of “Borrowing Hydrogen” Methodology
Yushi Nakamura, Tetsuo Ohta, and Yohei Oe
Doshisha University, Japan
1P-069
Iron-Catalysed Cross-Coupling Reactions of Arylmagnesiums with Aryl Chlorides
and Tosylates
Hung A. Duong and Yi-Yuan Chua
Institute of Chemical and Engineering Sciences (ICES), A*STAR, Singapore
1P-070
Cationic Mononuclear Ruthenium Carboxylates as Catalyst Prototypes for
Self-Induced Hydrogenation of Carboxylic Acids
Masayuki Naruto1 and Susumu Saito1,2
1
Graduate School of Science, Nagoya University, Japan, 2RCMS, Nagoya University, Japan
1P-071
Trihalomethylthiolation of Electron-Rich Heterocycles
Johannes Bruno Ernst, Roman Honeker, Lena Rakers, Andreas Rühling, and Frank
Glorius
Westfälische Wilhelms-Universität Münster, Germany
1P-072
Asymmetric Induction of Quaternary Centers at γ-Position of Cyclohexadienones
by Rh-phebox Catalyzed Conjugate Hydrosilylation
Hisao Nishiyama, Yuki Naganawa, Mayu Kawagishi, and Jun-ichi Ito
Nagoya University, Japan
1P-073
Guidelines to Select the N-Heterocyclic Carbene as Catalyst/Initiator for the Organopolymerization of Polar Monomers
Laura Falivene and Luigi Cavallo
King Abdullah University of Science and Technology, Saudi Arabia
1P-074
Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed
Enantioselective C–H Allylic Alkylation of Azoles with a Naphthol-NHC Chiral Ligand
Hirohisa Ohmiya, Heng Zhang, Saori Shibata, and Masaya Sawamura
Hokkaido University, Japan
1P-075
Fe-aturing Hydroboration with NacNac Iron Complexes
Maialen Espinal-Viguri, Callum R. Woof, and Ruth L. Webster
University of Bath, UK
1P-076
Ruthenium-Catalyzed 1,6-Enyne Cycloisomerization of Phenyl Enol Ether: Synthesis
of 2,3-Disubstituted Benzo[b]furans
Shohei Ohno, Kohei Takamoto, Hiromichi Fujioka, and Mitsuhiro Arisawa
Osaka University, Japan
1P-077
Ruthenium Nanoparticles in Olefin Metathesis: Their Formation and Non-Innocence
Deryn E. Fogg, Carolyn S. Higman, and Emma Davy
University of Ottawa, Canada
1P-078
Arylboration of Alkenes by Cooperative Nickel/Copper Catalysis
Yasuhiro Ohtagaki, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan
1P-079
Carbon–Carbon Bond Activation of Cyclopropanes by Rhodium Porphyrin
Complexes
Shiyu Feng and Kin Shing Chan
The Chinese University of Hong Kong, Hong Kong Special Administrative Region of China
1P-080
Rhodium-Catalyzed Enantioselective Formation of 2H-Azirines from Isoxazoles
Kazuhiro Okamoto, Atsushi Nanya, Takuya Shimbayashi, Akira Eguchi, and Kouichi
Ohe
Kyoto University, Japan
1P-081
Visible Light-Mediated Reductive Umpolung of Carbonyl Derivatives: A Straightforward Access to Vicinal Diamines and Amino Alcohols via α-Amino Radicals
Eleonora Fava,1,2 Anthony Millet,2 Masaki Nakajima,2 Sebastian Loescher,2 and
Magnus Rueping1,2
1
King Abdullah University of Science and Technology, Saudi Arabia, 2RWTH Aachen University,
Germany
1P-082
Development of a Robust Ir Catalyst for the Dehydrogenation of Formic Acid in
Large Scale
Naoya Onishi and Yuichiro Himeda
National Institute of Advanced Industrial Science and Technology, Japan
1P-083
Highly Regio- and Stereoselective Arylation of Trisubstituted Olefins via HeckMatsuda Reactions
Carlise Frota and Carlos Roque Duarte Correia
State University of Campinas, Brazil
1P-084
Synthesis of Fatty Acids Containing Cyclopropane Ring through Ni-Catalyzed CrossCoupling Reaction
Shohei Terahigashi, Takanori Iwasaki, Hitoshi Kuniyasu, and Nobuaki Kambe
Osaka University, Japan
1P-085
Development of DNA Metalloenzymes Using a Rational Design Approach for
Asymmetric Synthesis
Soyoung Park and Hiroshi Sugiyama
Kyoto University, Japan
1P-086
Design of an Indolylphosphine Ligand for Reductive Elimination-Demanding
Pd-catalyzed Mono-α-Arylation of Acetone with Aryl Chlorides
Wai Chung Fu, Chau Ming So, Wing Kin Chow, On Ying Yuen, and Fuk Yee Kwong
The Hong Kong Polytechnic University, Hong Kong Special Administrative Region of China
1P-087
Pd/NHC-Catalyzed Regioselective Suzuki-Miyaura Arylation of
2-Alkoxycarbonylaziridines
Tetsuya Matsuno, Youhei Takeda, and Satoshi Minakata
Osaka University, Japan
1P-088
Iron: A New Player in the Z-Selective (Cross) Dimerization of Terminal Alkynes
Catalysed by Transition Metal Complexes
Orestes Rivada-Wheelaghan,1 Subrata Chakraborty,2 Linda J. W. Shimon,2 Yehoshoa
Ben-David,2 and David Milstein2
1
Okinawa Institute of Science and Technology Graduate University, Japan, 2Weizmann Institute
of Science, Israel
1P-089
Acyclic Quaternary Centres from Asymmetric Conjugate Addition of Alkylzirconium
Reagents
Zhenbo Gao and Stephen P. Fletcher
University of Oxford, UK
1P-090
Nickel-Catalyzed Boron Insertion into the C2–O Bond of Benzofurans: Skeletal
Transformations of Furan Ring via Oxaborinine
Hayate Saito, Shinya Otsuka, and Hideki Yorimitsu
Kyoto University, Japan
1P-091
The Important Role of Molecular Dynamics to Reconcile Complex Catalytic
Mechanisms
Marc Vincent Garland, Marco Klähn, and Tung Nguyen Dinh
Institute of Chemical and Engineering Sciences, Singapore
1P-092
Theoretical Studies of Homogeneous Catalysis
W. M. C. Sameera and Keiji Morokuma
Kyoto University, Japan
1P-093
Roles Played by the Fluorine in Living Ethylene Polymerization Induced by
Fluorinated Bis(phenoxy-imine) Ti Catalysts
Takashi Nakano and Terunori Fujita
Mitsui Chemicals, Inc., Japan
1P-094
Cobalt-Catalyzed Dehydrogenative Thiolation of Indoles
Tobias Gensch, Felix Klauck, and Frank Glorius
Westfälische Wilhelms-Universität Münster, Germany
1P-095
Fluorine-Enriched Functional Phosphine Ligands Directed to Catalyst Recycling
Yuki Sato,1 Shin-ichi Kawaguchi,2 Akihiro Nomoto,1 and Akiya Ogawa1
1
Osaka Prefecture University, Japan, 2Saga University, Japan
1P-096
Robust Zinc Complexes that Contain Pyrrolidine-Based Ligands as Recyclable
Catalysts for the Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides
Cyril Godard,1 Elisabet Mercadé,1 Carmen Claver,1 and Ennio Zangrando2
1
Universitat Rovira i Virgili, Spain, 2Università di Trieste, Italy
1P-097
A Tridentate Phosphine Ligand Enabling Iron-Catalyzed Carbonyl Directed C(sp2)–H
Functionalization with Trimethylaluminum
Rui Shang, Laurean Ilies, and Eiichi Nakamura
The University of Tokyo, Japan
1P-098
Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides
and Aryl Grignard Reagents
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, and Nobuaki Kambe
Osaka University, Japan
1P-099
Hydride-Enhanced Ligand Nucleophilicity for Unprecedented Metalloorganic
Catalytic Reactivities - An In Silico Study
Theo Piechota Goncalves, Huaifeng Li, and Kuo-Wei Huang
King Abdullah University of Science and Technology, Saudi Arabia
1P-100
Enantioselective Synthesis of Chiral Tribenzoheteropins by the Catalytic
Intermolecular Cycloaddition
Takanori Shibata, Akihito Mitake, Tatsuki Sato, Riku Matsubara, and Kyalo Stephen
Kanyiva
Waseda University, Japan
1P-102
Aerobic Oxidation of Arylmethanols to Arylaldehydes Catalyzed by Cerium
Complexes with TEMPO
Satoru Shirase, Mitali Paul, Laurent Mathey, Murugesapandian Balasubramanian,
Shinji Tanaka, Hayato Tsurugi, and Kazushi Mashima
Osaka University, Japan
1P-103
Oxidative Cycloreversion Reactions of Cyclobutanes Using Flavinium Salts and
Visible Light
Tomas Hartman and Radek Cibulka
UCT Prague, Czech Republic
1P-104
Precise One-Pot Synthesis of End-Functionalized Poly(arylene vinylene)s by ADMET
Polymerization and Chain Transfer/Wittig-Type Coupling
Tomonari Miyashita, Akiko Inagaki, Shunsuke Sueki, and Kotohiro Nomura
Tokyo Metropolitan University, Japan
1P-105
Copper Complexes with Arylhydrazone Ligands as Catalysts in Alcohols Oxidation
Maria de Fatima C Guedes da Silva
Instituto Superior Técnico, Universidade de Lisboa, Portugal
1P-106
Rhodium-Catalyzed Stitching Reaction Leading to Unsymmetric
Dibenzo[a,e]pentalene Derivatives
Keisuke Takahashi, Shingo Ito, Ryo Shintani, and Kyoko Nozaki
The University of Tokyo, Japan
1P-107
Studies on Acid-Free Palladium and Platinum Catalyzed Hydroarylation of
Acetylene: From Stoichiometric to Catalytic Reaction
Christine Elisabeth Hahn
Texas A&M University-Kingsville, USA
1P-108
Intermediacy and Chemistry of Vinylidene and Aminocarbene Complexes in AntiMarkovnikov Hydroamination of Terminal Alkynes Catalyzed by
Phosphine-Quinolinolato Rhodium Complexes
Shotaro Takano, Takuya Kochi, and Fumitoshi Kakiuchi
Keio University, Japan
1P-110
Synthesis of Ir(I) and Rh(I) Complexes Bearing a Noninnocent PNP-Pincer Type
Phosphaalkene Ligand (Eind-PPEP) and Their Application for Catalytic
Hydrosilylation of CO2
Hiro-omi Taguchi,1 Katsuhiko Takeuchi,1 Daichi Sasaki,1 Shota Tsujimoto,2 Tsukasa
Matsuo,2 and Fumiyuki Ozawa1
1
Kyoto University, Japan, 2Kinki University, Japan
1P-111
Rh-Complexes in Homogeneous Catalysis - Catalyst Activation and Deactivation
Phenomena
Detlef Erich Wolfgang Heller, Antje Meißner, Hans-Joachim Drexler, Elisabetta
Alberico, and Anja König
Leibniz Institut für Catalyse, Germany
1P-112
Mixed-Picolinate and -Quinaldinate Iron(III) Complexes for Catalytic Oxidation of
Alcohols with Hydrogen Peroxide
Shinji Tanaka, Yoshihiro Kon, Masanori Tamura, and Kazuhiko Sato
AIST, Japan
1P-113
Sequential Functionalisation of Alkynes and Alkenes Catalysed by Au(I)- and
Pd(II)-NHC Complexes
Alberto Gómez Herrera, Fady Nahra, Marcel Brill, Steven Patrick Nolan,
and Catherine Suzanne Julienne Cazin
University of St Andrews, UK
1P-114
Copolymerization of Ethylene and Acrylates Catalyzed by Post-Metallocene Nickel
Complexes
Akio Tanna,1 Bruce S. Xin,1 Naomasa Sato,1 Koso Hirokane,1 Yasuo Oishi,1 Yohei
Konishi,1 Hiroyuki Shimizu,1 Hideshi Uchino,1 Hisashi Ohtaki,1 Hiromasa Tanahashi,1
Takao Tayano,1 and Fumihiko Shimizu2
1
Japan Polychem Corporation, Japan, 2Mitsubishi Chemical Group Science and Technology
Research Center, Inc., Japan
1P-115
Size Effects in the Alkali Metal Ion-Templated Formation of Oligo(ethylene
glycol)-Containing [2]Catenanes
Yong-Jay Lee,1 Tsung-Hsien Ho,1 Chien-Chen Lai,2 and Sheng-Hsien Chiu1
1
National Taiwan University, Taiwan, 2National Chung Hsing University and, China Medical
University Hospital, Taiwan
1P-116
The Retro-Hydroformylation Reaction
Toshiumi Tatsuki, Shuhei Kusumoto, and Kyoko Nozaki
The University of Tokyo, Japan
1P-117
Rhodium-Catalyzed Selective C–H Functionalization of NNN Tridentate Chelating
Compounds via a Rollover Pathway
Seugyoun Hong, Jaesung Kwak, and Sukbok Chang
Korea Advanced Institute of Science and Technology, Republic of Korea
1P-118
Asymmetric [4 + 2] Cycloaddition of Imines with Dienes Catalyzed by Cationic
Iron(III) Complex
Rei Tomifuji,1 Takuya Kurahashi,1,2 and Seijiro Matsubara1
1
Kyoto University, Japan, 2JST, ACT-C, Japan
1P-119
Effective Transfer Hydrogenation of Arylaldehydes in Water or Biphasic Medium
Felix A. Jalón,1 Margarita Ruiz de Castañeda,1 M. Carmen Carrión,2 Gustavo Espino,3
and Blanca R. Manzano1
1
University of Castilla-La Mancha, Spain, 2Fundación PCYTA, Paseo de la Innovación, Spain,
3
University of Burgos, Spain
1P-120
Synthesis and Application of Tetrahydro-2H-Fluorenes via a Pd(0)-Catalyzed
Benzylic C(sp3)–H Functionalization
Chihiro Tsukano, Satoshi Suetsugu, Nubusuke Muto, Misa Horinouchi, and Yoshiji
Takemoto
Kyoto University, Japan
1P-121
A Cross Metathesis Route to Aminoacids and Aminoesters – But Watch the Amine!
William Roy Jackson, Szabolcs Solyom, Nicolas D. Spiccia, and Andrea J. Robinson
Monash University, Australia
1P-122
Effective Protocol to Generate Amorphous Ni Nanoparticles for Catalytic Ullmann
Coupling Reactions
Yohei Ueda,1 Taiga Yurino,1 Yoshiki Shimizu,2 Shinji Tanaka,3 Haruka Nishiyama,1
Hayato Tsurugi,1 Kazuhiko Sato,3 and Kazushi Mashima1
1
Osaka University, Japan, 2NMRI, National Institute of Advanced Industrial Science and
Technology, Japan, 3IRC3, National Institute of Advanced Industrial Science and Technology,
Japan
1P-123
Organocatalytic C–F Bond Activation with Alanes
Alma D. Jaeger and Dieter Lentz
Freie Universität Berlin, Germany
1P-124
Maleimides-Assisted Anti-Markovnikov Wacker-Type Oxidation of Vinylarenes
Using Molecular Oxygen as a Terminal Oxidant
Sonoe Nakaoka, Yuka Murakami, Yasutaka Kataoka, and Yasuyuki Ura
Nara Women’s University, Japan
1P-125
Aluminum Compounds Bearing Ethylene Linked Pyrrole- and Keto-aminemorpholine Ligands: Synthesis, Characterization, Reaction Study and Ring Opening
Polymerization of
ε-caprolactone
1
Jui-Hsien Huang, Tzung-Han Lin,1 You-Ru Cai,1 Ching-Han Hu,1, Weilun Chang,2
and Ting-Yu Lee2
1
National Changhua University of Education, Taiwan, 2National Kaohsiung University, Taiwan
1P-126
Synthesis of 1,4-Dicarbonyl Compounds via Organic Dye Catalyzed Coupling
Reaction between Silyl Enolates and Bromocarbonyls under Visible Light
Naoto Esumi,1 Kensuke Suzuki,1 Yoshihiro Nishimoto,2 and Makoto Yasuda1
1
Graduate School of Engineering, Osaka University, Japan, 2COiRE, Graduate School of
Engineering, Osaka University, Japan
1P-127
Synthesis of “Olefin Metathesis Active” Niobium(V)-Alkylidene Complex
Kritdikul Wised and Kotohiro Nomura
Tokyo Metropolitan University, Japan
1P-128
Novel Rare Earth Metal-Catalyzed Synthesis of Benzimidazoles
Shun-Ichi Naito,1 Tsutomu Yoshimura,1 Yuanjun Di,1 Aoi Son,1 Yu Kimura,1,2 and
Teruyuki Kondo1
1
Graduate School of Engineering, Kyoto University, Japan, 2C-PIER, Kyoto University, Japan
1P-129
NHC-Catalyzed Enantioselective Hydroacylation of Unactivated Olefins
Daniel Janssen-Müller and Frank Glorius
University of Münster, Germany
1P-130
New Fluorous Organotellurium Compounds as Recyclable Controlling Agents for
Living Radical Polymerization
Shigeru Yamago, Mengmeng Yu, Toyomitsu Seki, Takehiro Fujita, Vijay Kumar Patel,
and Yasuyuki Nakamura
Kyoto University, Japan
1P-131
Iridium-Catalyzed Selective 1,2-Hydrosilylation of N-Heterocycles
Jinseong Jeong,1,2 Sehoon Park,1,2 and Sukbok Chang1,2
1
Korea Advanced Institute of Science and Technology, Korea, 2Institute of Basic Science, Korea
1P-132
Ni-Catalyzed Cross-Coupling Reaction of Aryl Sulfoxides with Arylzinc Reagents
Keita Yamamoto, Shinya Otsuka, Daishi Fujino, Hideki Yorimitsu, and Atsuhiro Osuka
Kyoto University, Japan
1P-133
Non-Classical Hydrogen Bonding and its Role in Asymmetric Organocatalysis
Ajitha Manjaly John and Kuo-Wei Huang
King Abdullah University of Science and Technology, Saudi Arabia.
1P-134
Multifunctional Chiral Bisamidine Ligand: Applications in Asymmetric Catalysis
Masahiro Yamanaka, Shotaro Doki, and Nobutaka Kishi
Rikkyo University, Japan
1P-135
Encapsulated Rhodium Catalysts for Asymmetric Hydroformylation
Lukas J. Jongkind and Joost N. H. Reek
Universiteit van Amsterdam, The Netherlands
July 14 (Thu)
2P-001
Scandium-Catalyzed Direct Transformation of Alcohols Using Silylated Reagents
Yuanjun Di,1 Yu Kimura,1,2 and Teruyuki Kondo1
1
Graduate School of Engineering, Kyoto University, Japan, 2LIMS, Kyoto University, Japan
2P-002
Electrocatalytic Functionalization of Biologically Important Substrates of Different
Classes of Arenes
Mikhail N. Khrizanforov, Sofia O. Strekalova, Vera V. Khrizanforova, Valeriya V.
Grinenko, Tatyana V. Gryaznova, and Yulia H. Budnikova
Russian Academy of Sciences, Russian Federation
2P-003
Remarkable Norbornene Incorporation in Ethylene/Norbornene Copolymerization
by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Qing Yan, Weizhen Zhao, Ken Tsutsumi, and Kotohiro Nomura
Tokyo Metropolitan University, Japan
2P-004
A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of
N-Pivaloylindoles with Organic Azides
Youyoung Kim and Sukbok Chang
Korea Advanced Institute of Science and Technology, Institute of Basic Science, Republic of
Korea
2P-005
NHC-Coordinated Palladacycle Catalyzed Synthesis of γ-Aryl- γ-lactones via
1,2-Addition to γ-Oxoesters
Ryo Akiyama,1 Tetsuya Yamamoto,2 and Hiraku Shinozaki2
1
Department of Materials Science and Engineering, Graduate School of Engineering, Tokyo
Denki University, Japan, 2Department of Green and Sustainable Chemistry, School of
Engineering, Tokyo Denki University, Japan
2P-006
Ruthenium Catalyzed Nitriles Hydrogenation under Mild Conditions
Rosa Adam Ortiz,1 Elisabetta Alberico,1,2 Charles Beromeo Bheeter,1 Ralf Jackstell,1
Henrik Junge,1 Matthias Beller1
1
Leibniz-Institut für Katalyse e. V., Germany, 2Istituto di Chimica Biomolecolare, CNR, Italy
2P-007
Manual Control of Catalytic Reactions: Reactions by Apoenzyme- and Cofactor-Gels
Hiroyasu Yamaguchi, Yuichiro Kobayashi, Yoshinori Takashima, Akihito Hashidzume,
and Akira Harada
Osaka University, Japan
2P-008
Kinetic Investigations on the Influence of the Co-substrates Hydrogen and Carbon
Monoxide in Monophosphite-Modified Hydroformylation
Christoph Kubis,1 Detlef Selent,1 Mathias Sawall,2 Wolfgang Baumann,1 Klaus
Neymeyr,2 Ralf Ludwig,3 Dieter Hess,4 Robert Franke,4 and Armin Börner1
1
Leibniz Institute for Catalysis, Germany, 2Institute for Mathematics, University of Rostock,
Germany, 2Institute for Chemistry, University of Rostock, Germany, 4Evonik Performance
Materials GmbH, Germany
2P-009
Palladium-Catalyzed Direct Coupling of Pyridine and Benzoxazole: OxidantControlled Regiodivergency
Shuya Yamada,1 Kei Murakami,1 and Kenichiro Itami1,2,3
1
2P-010
Nagoya University, Japan, 2WPI-ITbM, Japan, 3JST ERATO, Japan
Homogeneous Catalytic Carbon Dioxide Hydrogenation in Acidic Aqueous
Solutions: on the Sustainable Way of CO2 Utilization
Gabor Laurenczy
EPFL, Switzerland
2P-011
Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization:
Effective Prevention of Structural Defects
Masayuki Wakioka, Eisuke Iizuka, Rina Takahashi, and Fumiyuki Ozawa
Kyoto University, Japan
2P-012
Catalytic Transfer Hydrogenation of Ketones with Arene Ruthenium Compounds
and Selective Deuterium Labeling of Alcohols
Blanca R. Manzano,1 Félix A. Jalón,1 Ana M. Rodríguez,1 Miguel Ochoa,1 Maria
Carmen Carrión,1 Gustavo Espino,2 and Jesús Valladolid2
1
University of Castilla-La Mancha, Spain, 2University of Burgos, Spain
2P-013
Amino Alcohol Catalysed Enantioselective Aldol Reaction of Isatins with
Acetaldehyde: Application to Synthesis of Biological Active Natural Products
U. V. Subba Reddy,1 Chigusa Seki,1 Koji Uwai,1 Yuko Okuyama,2 Michio Tokiwa,3
Mitsuhiro Takeshita,3 and Hiroto Nakano1
1
Muroran Institute of Technology, Japan, 2Tohoku Medical and Pharmaceutical University,
Japan, 3Tokiwakai Group, Japan
2P-014
A General Catalytic Methylation and Formylation of Amines Using Carbon Dioxide
Huaifeng Li, Théo P Gonçalves, and Kuo-Wei Huang
King Abdullah University of Science and Technology, Saudi Arabia
2P-015
Electrophilic Activation of Aromatic Guest Molecules Utilizing a Macrocyclic Boronic
Ester Containing Difluorobenzothiadiazole Moiety
Tatsuhiro Uchikura,1 Kosuke Ono,2 Kohei Takahashi,1 Nobuharu Iwasawa1
1
Tokyo Institute of Technology, Japan, 2Tokyo University of Science, Japan
2P-016
Phosphoramidite Ligands Based on Simple 1,2-Diols
Nisha Mistry and Stephen P. Fletcher
University of Oxford, UK
2P-017
Photoredox-Catalyzed Carbonyloxy-Trifluoromethylation of Allenes Leading to
2-CF3-Allyl Alcohol Derivatives
Ren Tomita, Takashi Koike, and Munetaka Akita
Tokyo Institute of Technology, Japan
2P-018
Insight into the Metal-Mediated Cleavage Reaction of Carbon-Carbon Triple Bond
Yih-Hsing Lo
University of Taipei, Republic of China
2P-019
Synthesis of α-Amino Acid by Catalytic and Chemoselective α-Amination
Keisuke Tokumasu, Ryo Yazaki, and Takashi Ohshima
Kyushu University, Japan
2P-020
Functionalised Carbon Nanotubes with New Pyrene Tagged Chiral Diphosphite
Ligands for Rhodium Asymmetric Hydroformylation. Catalytic Testing under Batch
and Flow Conditions
Anton C. Martin, Cyril Godard, and Aurora R. Manrique
Universitat Rovira i Virgili, Spain
2P-021
Copolymerization of Ethylene and Polar Monomers Using Ni/IzQO Catalysts
Wenjie Tao, Ryo Nakano, Shingo Ito, and Kyoko Nozaki
The University of Tokyo, Japan
2P-022
Formation of Monomeric or Dimeric Palladium and Nickel Complexes with Various
Schiff Base Tridentate Ligands
Ji Min Lee, Ji Yeon Ryu, Young Min Byun, Seul Gi Lee, Hyoung-Ryun Park, and
Junseong Lee
Chonnam National University, Republic of Korea
2P-023
Synthesis and Reactivity of Group 9 Transition Metal Complexes Bearing
sp3-Hybridized Boron-Containing PBP Pincer Ligands
Yuuki Tanaka, Teruhiko Saito, and Yoshiaki Nakao
Kyoto University, Japan
2P-024
The Role of C-Scorpionate Complexes in Sustainable Oxidation of Alkanes
Luisa M. D. R. S. Martins and Armando J. L. Pombeiro
Universidade de Lisboa, Portugal
2P-025
Direct Catalytic Asymmetric C–C Bond-Forming Reactions via Direct Enolization of
Amide
Toshifumi Takeuchi, Karin Weidner, Liang Yin, Lennart Brewitz, Zhongdong Sun,
Fernando A. Arteaga, Ziijan Liu, Chen Jianyang, Bo Sun, Naoya Kumagai, and
Masakatsu Shibasaki
Institute of Microbial Chemistry, Japan
2P-026
Flavin-Mediated Oxidation of Hydrazines, New Approach towards Catalytic
Mitsunobu Reaction
Michal März and Radek Cibulka
UCT Prague, Czech Republic
2P-027
Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silicon-Bridged
Arylpyridinones
Ryo Takano, Ryo Shintani, and Kyoko Nozaki
The University of Tokyo, Japan
2P-028
Employing Pd-Catalyzed C–H Arylation in Multicomponent-Multicatalyst Reactions
(MC)2R: Domino Synthesis of Dihydrobenzoquinolines
Fabian Lied,1 Helena Brodnik,2 Frank Glorius,1 and Mark Lautens2
1
Westfälische Wilhelms-Universität Münster, Germany, 2University of Toronto, Canada
2P-029
Copper-Mediated Decarboxylative Coupling of Benzamides with Benzoic Acids via
Directed C–H Cleavage
Kazutaka Takamatsu, Koji Hirano, and Masahiro Miura
Osaka University, Japan
2P-030
Decarboxylative Coupling of Cinnamic Acids for Synthesis of Allyl Amines
Kyungho Park and Sunwoo Lee
Chonnam National University, Republic of Korea
2P-031
Cobalt-Salophen Complex Catalyzed Preparation of Alkyl Iodides from Aldehydes
via Oxidative Deformylation
Keiichi Sumiyama,1 Atsushi Kaiho,1 Hideaki Sogo,1 Hiroyuki Kusama,2 and Nobuharu
Iwasawa1
1
2P-032
Tokyo Institute of Technology, Japan, 2Gakushuin University, Japan
Computational Modelling of Post-Metallocene Catalyzed Propylene Polymerization:
A Benchmarking Study
Abigail R. E. Mountain,1 Betty Coussens,2 Alexandra Berthoud,3 Philip Mountford,4
and Nikolas Kaltsoyannis5
1
University College London, UK, 2DSM Chemical Technology R&D B.V., The Netherlands,
3
ARLANXEO Elastomers B.V., The Netherlands, 4 University of Oxford, UK, 5The University of
Manchester, UK
2P-033
Ni-Catalyzed Direct Asymmetric Allylic Alkylation of β -Ketoesters Using Allylic
Alcohols
Koya Shoji, Hiroaki Oda, Rahul D. Kavthe, Yusuke Kita, and Kazushi Mashima
Osaka University, Japan
2P-034
Enhanced Reactivity of a Pincer Ligand Towards O2 – Metal-Enhanced Ligand
Activity in a PN3P Rhodium Pincer Complex
Kristin Munkerup,1 Jinsong Hu,1 Yuan Wang,1 Craig Schwartz,2 Tsu-Chien Weng,2
Dennis Nordlund,2 Dimosthenis Sokaras,2 and Kuo-Wei Huang1
1
King Abdullah University of Science and Technology, Saudi Arabia, 2SLAC National
Accelerator Laboratory, USA
2P-035
Rhodium-Catalyzed Reaction of C–H Bonds in Benzamides with
α,β -Unsaturated
Lactones or Dihydrofurans
Kaname Shibata and Naoto Chatani
Osaka University, Japan
2P-036
Towards the Design of New Iron Catalysts for Unsaturated Substrates
Transformations
Hélène S. Olivier-Bourbigou,1 Pierre-Alain Breuil,1 Benjamin Burcher,1 Pierre
Braunstein,2 and Andreas Danopoulos2
1
IFP Energies nouvelles, France, 2Université de Strasbourg, France,
2P-037
π-Accepting NHC Ligands Derived form Imidazo[1,5-a]pyridines: Application to
Transition Metal Catalyses
Fumitoshi Shibahara, Yuma Koto, and Toshiaki Murai
Gifu University, Japan
2P-038
Studies on Rh Sulfide Catalysts for Use in Hydrosilylation
Matthew T. Olsen
Dow Corning Corporation
2P-039
Nickel-Catalyzed Multicomponent Reaction of Perfluoroarenes, Aryl Grignard
Reagents, and 1,3-Butadiene through Dimerization of 1,3-Butadiene
Wataru Yokoyama, Asuka Fukuoka, Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu,
and Nobuaki Kambe
Osaka University, Japan
2P-040
Experimental and Comptutational Investigations on the Enantioselective
Alkynylation of α-Ketosesters via Copper Catalysis
Martin C. Schwarzer,1 Takaoki Ishii,2 Hirohisa Ohmiya,2 Masaya Sawamura,2 and
Seiji Mori1
1
Ibaraki University, Japan, 2Hokkaido University, Japan
2P-041
Chirality and Physical Autocatalysis
Sarah M. Morrow, Andrew J. Bissette, and Stephen P. Fletcher
University of Oxford, UK
2P-042
Strong Brønsted Base-Catalyzed Asymmetric 1,4-Addition Reactions of Weekly
Acidic Compounds
Io Sato, Hirotsugu Suzuki, Yasuhiro Yamashita, and Shū Kobayashi
The University of Tokyo, Japan
2P-043
Comparative Catalytic Activity of Group 9 [Cp*M(III)] Complexes: Cobalt-Catalyzed
C–H Amidation of Arenes with Dioxazolones as Amidating Reagents
Juhyeon Park1 and Sukbok Chang2
1
Korea Advanced Institute of Science and Technology, Republic of Korea, 2Institute of Basic
Science, Republic of Korea
2P-044
Oxovanadium(V)-Catalyzed Synthesis of Urea Derivatives from Amines and Carbon
Dioxide
Takashi Sakuramoto, Toshiyuki Moriuchi, Ryota Kawai, and Toshikazu Hirao
Osaka University, Japan
2P-045
Multiphasic Hydroformylation with Polymer Particles as Phase Transfer Agents and
Catalyst Carriers
Daniel Peral,1 Bachir Bibouche,1 Reinhard Schomäcker,1 and Dieter Vogt2
1
Technische Universität Berlin, Germany, 2University of Edinburgh, UK
2P-046
Ternary Hybrid Catalysis Enabling Room-Temperature Hydrogen Gas Release from
Tetrahydronaphthalenes
Yutaka Saga,1,2 Shota Kato,1 Masahiro Kojima,1 Hiromu Fuse,1 Shigeki Matsunaga,3
Arisa Fukatsu,4 Mio Kondo,4 Shigeyuki Masaoka,4 and Motomu Kanai1,2
1
The University of Tokyo, Japan, 2ERATO, JST, Japan, 3Hokkaido University, Japan,
4
Institute for Molecular Science, Japan
2P-048
Trapping of Azidocarbeniumion: A Unique Strategy for the Synthesis of Azides
Suman Pramanik1,2 and Prasanta Ghorai1
1
Osaka University, Japan, 2Indian Institute of Science Education and Research Bhopal, India
2P-049
Mechanistic Study on Ru-Catalyzed Asymmetric Hydrogenation of Aromatic
Ketones Using a Linear Tetradentate N4 Ligand
Masahiro Yoshimura,1 Shinji Tanaka,2 and Masato Kitamura3
1
Aichi Gakuin University, 2RCMS, Nagoya University, 3Graduate School of Pharmaceutical
Sciences, Nagoya University
2P-050
Using Enantioselective Branched Hydroformylation for the Synthesis of Natural
Products and Pharmaceutical Intermediates
Rachael Pittaway and Matt L. Clarke
University of St Andrews, UK
2P-051
Hydration of Nitriles Catalyzed by Homogeneous Iridium(I) Catalysts Having
(O,O)-Chelate Ligands
Toshiyuki Oshiki
Okayama University, Japan
2P-052
On the Mechanism of the Dual Metal Catalysis
Albert Poater
Universitat de Girona, Spain
2P-053
para-Selective Alkylation of Aromatic Carbonyl and Sulfonyl Compounds by
Cooperative Nickel/Aluminum Catalysis
Shogo Okumura,1 Shuwei Tang,2 Teruhiko Saito,1 Kazuhiko Semba,1 Shigeyoshi
Sakaki,2 and Yoshiaki Nakao1
1
Graduate School of Engineering, Kyoto University, Japan, 2FIFC, Kyoto University, Japan
2P-054
Microemulsion Systems as Smart Solvents for Homogeneous Catalysis:
Rhodium-Catalyzed Hydroformylation of Long-Chain Alkenes
Tobias P. Pogrzeba, Marcel Schmidt, Markus Illner, and Reinhard Schomäcker
Technische Universität Berlin, Germany
2P-055
Ruthenium-Catalyzed C1- and C7-Selective Acetoxylation of Carbazole and Indole
Derivatives via C–H Bond Cleavage
Takeshi Okada,1 Tetsuya Satoh,2 and Masahiro Miura1
1
Osaka University, Japan, 2Osaka City University, Japan
2P-056
Catalyzed Ketone Hydrogenation: Why Is a Strong Base Needed?
Rinaldo Poli,1 S. M. Wahidur Rahaman,1 Eric Deydier,1 Agustí Lledós,2 and Eric
Manoury1
1
Laboratoire de Chimie de Coordination, France, 2Universitat Autònoma de Barcelona, Spain
2P-057
Allylarylation, Allylalkenylation and Allylmethylation of Alkenes by Cooperative
Palladium/Copper Catalysis
Naoki Ohta, Yuko Yano, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan
2P-058
Metathesis and Peptidomimetics – Insulin, A Case Study
A. Belgi, W. R. Jackson, and A. J. Robinson
Monash University, Australia
2P-059
4,4’-Bipyridine-Catalyzed Diboration of Pyrazines: B–B Bond Activation through
Radical Pathway
Toshimichi Ohmura,1 Yohei Morimasa,1 Michinori Suginome,1 Yasujiro Murata,2
Tomoya Ichino,3 Tetsuya Taketsugu,3 and Satoshi Maeda3
1
Graduate School of Engineering, Kyoto University, Japan, 2ICR, Kyoto University, Japan,
Hokkaido University, Japan
3
2P-061
Hydrogenolysis of Arenols with Hydrosilanes by Nickel Catalysis
Akito Ohgi and Yoshiaki Nakao
Kyoto University, Japan
2P-062
Ruthenium Catalyzed C–H Silylation of Unprotected Gramines, Tryptamines and
Their Congeners
Carina Sollert,1 Karthik Devaraj,1 Carmen Juds,1 Paul J. Gates,2 Lukasz T. Pilarski1
1
Uppsala University, Sweden, 2University of Bristol, UK
2P-063
Copper-Catalyzed Selective tertiary-Alkylative Fluoriations
Takashi Nishikata, Syo Ishida, and Ryo Fujimoto
Yamaguchi University, Japan
2P-064
A New Twist in the Chemistry of Allenes: Platinum-Catalysed Reactions of Allenes
with Nucleophiles
Teresa Quiros and Maria Paz Muñoz
University of East Anglia, UK
2P-065
Synthesis of PNP-Ir Complexes and Their Application as Catalyst for
Dehydrogenation of Alkanes
Shin Nakayama and Makoto Yamashita
Chuo University, Japan
2P-067
Gold-Catalyzed Cyclization/Intermolecular Methylene Transfer Sequence of
O-Propargylic Formaldoximes
Itaru Nakamura, Shinya Gima, Yu Kudo, and Masahiro Terada
Tohoku University, Japan
2P-068
Titanium Aryloxides for Catalytic Hydrofunctionalization: Insights into
Hydroalkoxylation, Hydroamination, and Hydroaminoalkylation
Scott Aaron Ryken and Laurel L. Schafer
The University of British Columbia, Canada
2P-069
Mechanistic Study on Iron-Catalyzed Cross-Coupling Reaction Based on X-ray
Absorption Spectroscopy
Sho Nakajima,1,2 Katsuhiro Isozaki,1,2,3 Naohisa Nakagawa,1,2,3 Ryuji Imayoshi,1,2 Toru
Hashimoto,4 Nicholas J. Gower,1 Laksmikanta Adak,1 Tetsuo Honma,5 Masafumi
Takagaki,5 Yusuke Sunada,4 Hideo Nagashima,3,4 Daisuke Hashizume,6 Takahiro
Iwamoto,1,2,3 Takuji Hatakeyama,1,7 Hikaru Takaya,1,2 and Masaharu Nakamura1,2
1
ICR, Kyoto University, Japan, 2Graduate School of Engineering, Kyoto University, Japan,
3
CREST, JST, Japan, 4Kyushu University, Japan, 5JASRI, SPring-8, Japan, 6RIKEN CEMS,
Japan, 7ESICB, Kyoto University, Japan
2P-070
A Unique Self-Assembled Ru-Co Heterometallic Cages Based on Length of Arene
Ruthenium
Ji Yeon Ryu, Ji Min Lee, Eun Hye Wi, Saem Hwang, and Junseong Lee
Chonnam National University, Republic of Korea
2P-071
Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear
Complex of Ruthenium and Cobalt
Masahiro Nagaoka, Toshiro Takao, and Hiroharu Suzuki
Tokyo Institute of Technology, Japan
2P-073
One-Step Catalytic Asymmetric Construction of Deoxypropionate Motif by
Propylene Oligomerization
Toshiki Murayama, Yusuke Ota, and Kyoko Nozaki
The University of Tokyo, Japan
2P-074
Asymmetric Addition of Heteroaryl Boronic Acids to Racemic Halides
Philipp Schäfer and Stephen P. Fletcher
University of Oxford, UK
2P-075
Mechanistic Insights into the Construction of Chiral Spiro-9-silabifluorenes via the
Rhodium-Catalyzed Dehydrogenative Silylation
Masahito Murai, Yutaro Takeuchi, and Kazuhiko Takai
Okayama University, Japan
2P-076
Carboxylic Acids – Emerged by Carbon Dioxide (C1-Block), Molecular Hydrogen and
Non-Activated Olefins
Marc Schmitz, Thomas G. Ostapowicz, Jürgen Klankermayer, and Walter Leitner
RWTH Aachen University, Germany
2P-077
Direct C–H Alkenylation of Thienothiophene and Realated Fused Heteroarenes
under Palladium Catalysis
Tomohiro Morita, Tetsuya Satoh, and Masahiro Miura
Osaka University, Japan
2P-078
From Molecular Bridges to Nanoparticle Stabilizers: Thiolate-Capped Highly
Selective Rh Nanocatalysts
Erika Martin and Alejandro Serrano-Maldonado
Universidad Nacional Autónoma de México, Mexico
2P-079
Diversity-Oriented Synthesis of Tetrathia[8]circulenes by C–H Borylation and
Annulation
Yoshihiro Miyake,1 Shohei Kato,1 Yuma Serizawa,1 Daisuke Sakamaki,2 Shu Seki,2 and
Hiroshi Shinokubo1
1
Nagoya University, Japan, 2Kyoto University, Japan
2P-081
Ligand-Controlled Insertion Regioselectivity Accelerates Copolymerization of
Ethylene with Methyl Acrylate by Cationic Bisphosphine Monoxide-Palladium
Catalysts
Yusuke Mitsushige,1 Brad P. Carrow,2 Shingo Ito,1 and Kyoko Nozaki, 1
1
The University of Tokyo, Japan, 2Princeton University, USA
2P-082
Nickel-Catalyzed Asymmetric Hydrogenation
Michael Shevlin
Merck and Co., Inc., USA
2P-083
Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Tertiary Alkyl
Grignard Reagents
Koji Yamashita, Takanori Iwasaki, Hitoshi Kuniyasu, and Nobuaki Kambe
Osaka University, Japan
2P-084
Nickel Based Hydroalkoxylation of 1,3-Butadiene: Scope of the Reaction and
Mechanism
Alexis Mifleur,1,2 Isabelle Suisse,2 André Mortreux,2 and Mathieu Sauthier2
1
Osaka University, Japan, 2Unité de Catalyse et Chimie du Solide, France
2P-085
Dynamic Kinetic Asymmetric Allylic Alkylation Using Non-Stabilized Nucleophiles
Mireia Sidera and Stephen P. Fletcher
University of Oxford, UK
2P-086
Dehydrogenation of Alkanes Catalyzed by New Long-Tethered PBP-Pincer Iridium
Complexes: Ligand Design and Catalytic Performance
Enrique Huang Kwan, Yasushi Jack Kawai, Sei Kamakura, Hayato Ogawa, and
Makoto Yamashita
Chuo University, Japan
2P-087
Syntheses, Structures and Optical Properties of Phenanthrene Derivatives
Akihito Konishi,1,2 Atsushi Morinaga,1 and Makoto Yasuda1
1
Graduate School of Engineering, Osaka University, Japan, 2CAMP, Osaka University, Japan
2P-088
Mild and Low-Temperature Decarbonylation of Aldehydes
Pim Puylaert, Sandra Hübner, and Johannes G. de Vries
Leibniz Institute for Catalysis, Germany
2P-089
Mechanistic Study and Application to Catalyst Recycle Process for the
Copolymerization of Ethylene and Allyl Acetate Catalyzed by Phosphine-Sulfonate
Palladium Complex
Jun-ichi Kuroda,1 Masafumi Koyano,1 Daisuke Yagyu,1 Shingo Ito,2 Kyoko Nozaki,2
and Yoshikuni Okumura1
1
Showa Denko K.K., Japan, 2The University of Tokyo, Japan
2P-091
Proline-Mediated, Asymmetric, Three-Component Mannich Reaction Using
p-Fluoroaniline: Formal Synthesis of Ezetimibe
Seitaro Koshino,1 Yujiro Hayashi,1 and Yasuharu Shimasaki2
1
Tohoku University, Japan, 2Sumitomo Chemical Co., Ltd., Japan
2P-092
Cobalt Porphyrin Catalyzed Carbon–Carbon Bond Transfer Hydrogenation with DMF
Chun Meng Tam, Ching Tat To, and Kin Shing Chan
The Chinese University of Hong Kong, China
2P-093
Ni-Catalyzed Selective Stannylation of Allyl Acetates
Kimihiro Komeyama, Yuuhei Itai, and Ken Takaki
Hiroshima University, Japan
2P-095
Asymmetric Synthesis of Highly π-Allyl Donative Lactones Using CpRu/Brønsted
Acid Combined Catalyst
Masato Kitamura,1 Shinji Tanaka,2 and Yusuke Suzuki1
1
Graduate School of Pharmaceutical Sciences, Nagoya University, Japan, 2RCMS, Nagoya
University, Japan
2P-096
A Facile Synthesis of Coronene and Its Derivatives
Huaida Xia, Dandan Zhou, Bingxin Liu, Qitao Tan, and Bin Xu
Shanghai University, China
2P-097
Ligands Containing Proton-Shuttle Groups for CO2 Hydrogenation
Julia R. Khusnutdinova, Abhishek Dubey, and Luca Nencini
Okinawa Institute of Science and Technology, Japan
2P-098
Copper-Catalyzed Stannylation Reactions of Alkynes
Hiroto Yoshida
Hiroshima University, Japan
2P-099
Cyclic [2]Catenane Dimers, Trimers, and Tetramers
Shun-Te Tung and Yi-Wei Wu
National Taiwan University, Taiwan
2P-100
Iron-Catalyzed Homo- and Copolymerization of Propylene
Takafumi Kawakami, Shingo Ito, and Kyoko Nozaki
The University of Tokyo, Japan
2P-101
High Catalytic Potential of Palladium Complexes with Imidazole Ligands
Anna M. Trzeciak, Wojciech Zawartka, Przemyslaw Wojcik, and Mehmet Mart
University of Wroclaw, Poland
2P-102
APEX Polymerization for Structurally Well-Defined Graphene Nanoribbons
Yuuta Yano,1 Nobuhiko Mitoma,2 Hideto Ito,1 and Kenichiro Itami1,2,3
1
Graduate School of Science, Nagoya University, Japan, 2ERATO, JST, Japan, 3ITbM, Nagoya
University, Japan
2P-103
Modeling CO2 Capture by Alcoholamines: A Theoretical Perspective from Electronic
Structure Methods to Molecular Mechanics
Ming-Kang Brad Tsai
National Taiwan Normal University, Taiwan
2P-104
Nickel-Catalyzed Hydroalkenylation of Alkynes via C–F Bond Activation:
2-Fluoro-1,3-diene Synthesis
Kohei Kanazawa, Yota Watabe, Takeshi Fujita, and Junji Ichikawa
University of Tsukuba, Japan
2P-105
N-Substituent Effects of Chiral Pentane-2,4-diyl Based P,N Ligands on the
Coordination Chemistry and Enantioselectivity in Palladium-Catalyzed Asymmetric
Allylic Alkylations
Imre Tóth,1 Gergely Farkas,1 Zsófia Császár,1 Kristóf Stágel,1 Attila Bényei,2 György
Lendvay,3 and József Bakos1
1
University of Pannonia, Hungary, 2University of Debrecen, Hungary, 3Institute of Materials
and Environmental Chemistry, Hungarian Academy of Sciences, Hungary
2P-106
Synthesis of Fused Furan Compounds via Palladium(II)-Catalyzed Intramolecular
Dehydrocyclization
Hiroyuki Kaida,1 Koji Hirano,1 Tetsuya Satoh,2 and Masahiro Miura1
1
Osaka University, Japan, 1Osaka City University, Japan
2P-107
Conversion of Bio-derived Pentenoic Acids to Nylon Monomers Using Carbonylation
and Olefin Metathesis
Martin van Meurs, James David Nobbs, Ludger Paul Stubbs, Eite Drent, and
Chuanzhao Li
Institute of Chemical & Engineering Sciences, Singapore
2P-108
Oxidative Aromatization of 9-([1,1'-Biphenyl]-2-ylmethylene)-9H-fluorenes via
Spirocyclization and 1,2-Aryl Migration Cascade for Synthesis of Polyaromatic
Hydrocarbons
Tienan Jin, Xuan Zhang, Zhanqiang Xu, and Yoshinori Yamamoto
Tohoku University, Japan
2P-109
Indium Trihalide Mediated Oxymetalation of Carbon–Carbon Multiple Bonds
Yuji Kita,1 Yoshihiro Nishimoto,2 and Makoto Yasuda1
1
Graduate School of Engineering, Osaka University, Japan, 2Center for Open Innovation
Research and Education, Graduate School of Engineering, Osaka University, Japan
2P-110
Copper Nitrate Participated Regio- and Stereoselective Difunctionalization of
Alkynes: A Direct Approach to
α-Chloro-β -nitroolefins
Mingchun Gao, Qitao Tan, and Bin Xu
Shanghai University, China
2P-111
Enantioselective Alkynylation of Activated Ketones Catalyzed by CCN Pincer Rh
Complexes
Jun-ichi Ito, Shino Ubukata, Shun Muraoka, and Hisao Nishiyama
Nagoya University, Japan
2P-112
High TON’s Desired. The Asymmetric Hydrogenation towards the Vitamin E Side
Chain. An Industrial Application
Gerard K. M. Verzijl,1 Jonathan Medlock,2 Werner Bonrath,2 Thomas Netscher,2 René
Stemmler,2 and André de Vries1
1
DSM Ahead R&D Innovative Synthesis B.V., Netherland, 2DSM Nutritional Products,
Netherland
2P-113
A Light/Ketone/Copper System for Carboxylation of Allylic C–H Bonds of Alkenes
with CO2
Naoki Ishida, Yusuke Masuda, Sho Uemoto, and Masahiro Murakami
Kyoto University, Japan
2P-115
Application of Bis(trimethylsilyl)cyclohexadiene and Its Derivatives for Reducing
Tungsten(VI) Imido Chlorides: A Simple Procedure for Generating Ring-opening
Polymerization Catalysts
Hideaki Ikeda, Hiromasa Tanahashi, Hayato Tsurugi, and Kazushi Mashima
Osaka University, Japan
2P-116
Versatile Palladium Catalysts for Carbonylation Reactions Under Atmospheric
Pressure
Marta Vico Solano, Vlad Pascanu, and Belén Martín-Matute
Stockholm University, Sweden
2P-117
Development of Dinuclear Cobalt–Salen Complexes for Copolymerization of
Epoxides with Carbon Dioxide
Yo Hiranoi and Koji Nakano
Tokyo University of Agriculture and Technology, Japan
2P-119
Transition-Metal-Catalyzed Highly Selective Thiolative Lactonization of Acetylenic
Alcohols with Carbon Monoxide and Organic Disulfides
Shinya Higashimae, Akihiro Nomoto, and Akiya Ogawa
Osaka Prefecture University, Japan
2P-120
Vanadyl Species-Catalyzed, Complementary beta-Oxidative Carbonylation of
Styrene Derivatives with Aldehydes
Wen Chieh Yang
National Tsing Hua University, Taiwan
2P-121
Palladium Catalyzed Cross-Coupling of Catalyst-Poisoning ortho-Sulfur
Functionalized Aryl Halides: An Application into Thia-PAH Synthesis
Tomoyuki Yanagi, Hayate Saito, Dhananjayan Vasu, Jan Niklas Hausmann, Hideki
Yorimitsu, and Atsuhiro Osuka
Kyoto University, Japan
2P-122
Versatile Bis-N-heterocyclic Carbene Ruthenium Pincer Catalyst Platform:
Metal-Ligand Cooperative Behavior and Catalytic Activity towards Ester
Hydrogenation
Robbert van Putten,1 Georgy A. Filonenko,1 Laurent Lefort,2 Emiel J. M. Hensen,1
and Evgeny A. Pidko1
1
2P-123
2
Eindhoven University of Technology, The Netherlands, DSM, The Netherlands
Stereocontrolled Synthesis of Vinyl Boronates and Vinyl Silanes via
Atom-Economical Ruthenium-Catalyzed Alkene–Alkyne Coupling
Barry M. Trost, Dennis C. Koester, and Alastair Neale Herron
Stanford University, USA
2P-124
Synthesis and Reactivity of Group 10 Transition Metal Complexes Bearing
Aluminum Containing Diphosphine Ligands
Naofumi Hara, Teruhiko Saito, and Yoshiaki Nakao
Kyoto University, Japan
2P-125
Sustainable Methodology for the Synthesis of Molecular Hybrid Silicates with
Tunable Catalytically Competent Silanol Protons for Metal-Free CO2 Conversion
Miriam de Jesús Velásquez Hernández, Aaron Torres Huerta, Uvaldo Hernández
Balderas, Diego Martinez Otero, Alejandra Nuñez Pineda, and Vojtech Jancik
Universidad Nacional Autónoma de México, Mexico
2P-126
An Introverted Bis-Au Cavitand-Catalyzed Cross-Dimerization of Terminal Alkynes
Tetsuo Iwasawa, Naoki Endo, Mao Kanaura, and Michael Peter Schramm
Ryukoku University, Japan
2P-127
Catalytic Hydrodebromination of Allylic Bromides with Water Catalyzed by
Rhodium Porphyrin Complexes
Wu Yang, Haojie Zhang, and Kin Shing Chan
The Chinese University of Hong Kong, China
2P-128
Synthesis of Tetraalkoxysilane from Silica and Alcohol
Seong Jib Choi, Norihisa Fukaya, Toshio Horikoshi, Hiroshi Kumai, Minoru Hasegawa,
Hiroyuki Yasuda, Kazuhiko Sato, and Jun-Chui Choi
National Institute of Advanced Industrial Science and Technology, Japan
2P-129
Boosting the Activity in Supported Ionic Liquid Phase (SILP) Catalyzed
Hydroformylation via Surface Functionalization of the Carbon Support
Alexander M. Weiß, Macarena Munoz, Marco Haumann, and Peter Wasserscheid
Friedrich-Alexander Universität Erlangen-Nürnberg, Germany
2P-130
Cp*Co(III)-Catalyzed Dehydrative C–H Allylation of 6-Arylpurines and Aromatic
Amides Using Allyl Alcohols in Fluorinated Alcohols
Youka Bunno,1 Manami Murakami,1 Yudai Suzuki,2 Motomu Kanai,2 Tatsuhiko
Yoshio,1,3 and Shigeki Matsunaga1,3
1
Hokkaido University, Japan, 2The University of Tokyo, Japan, 3ACT-C, JST, Japan
2P-131
Metal-Organic and Organocatalytic Methods for Stereocontrolled Activated
Monomer Catalysis
Insun Yu, Natália Vieira, and Philip Mountford
University of Oxford, UK
2P-132
Rate Acceleration of Solid-Liquid Phase-Transfer Catalysis by Rotor-Stator
Homogenizer
Yusuke Aota, Taichi Kano, and Keiji Maruoka
Kyoto University, Japan
2P-133
A User-Friendly Alkylation Method of Iridium Porphyrins with Alkyl Halides
Huiping Zuo and Kin Shing Chan
The Chinese University of Hong Kong, China
2P-134
Iron Fluoride/NHC-Catalyzed Cross-Coupling Reaction of Aryl Chlorides with
Grignard Reagents and Its Mechanistic Study by XAFS Analysis
Ryosuke Agata,1,2 Takahiro Iwamoto,1,2,3 Hikaru Takaya,1,2 and Masamaru Nakamura1,2
1
ICR, Kyoto University, Japan, 2Graduate School of Engineering, Kyoto University,
Japan, 3CREST, JST, Japan
2P-135
Rhodium-Catalyzed Allylarylation of Enones
Kouhei Iitsuka, Naoki Ohta, Kazuhiko Semba, and Yoshiaki Nakao
Kyoto University, Japan