Sinergia e Incompatibilidad entre Filtros Solares

Sinergia e Incompatibilidad entre
Filtros Solares
Vanessa Arruda
Gerente de Marketing Técnico Latam
Marzo 2012
Agenda
•
Sol y piel – porque necesitamos la protección UV?
•
Cambios Regulatórios y Retos
•
Eligiendo filtros UV y sinérgia entre ellos
•
Fotoestabilidad y desempeño de PARSOL® 1789
•
Tendencias de Mercado Europa
Page 1
Agenda
•Sol y piel – porque necesitamos la protección UV?
•
Cambios Regulatórios y Retos
•
Eligiendo filtros UV y sinérgia entre ellos
•
Fotoestabilidad y desempeño de PARSOL® 1789
•
Tendencias de Mercado Europa
Page 2
Radiación UVB y UVA
UVA-1 (longo): 340-400
UVA-2 (curto): 320-340
ULTRAVIOLETA
UVC
100
UVB
280
VISÍVEL
INFRAVERMELHO
UVA
320
400
800
1700
Efeitos
Efeitos
Efeitos
Bioquímicos
Luminosos
Bioquímicos*
Page Res 1982;272:229-38; Photodermatol Photoimmunol Photomed 1992/1993;9:275-8
*Arch Dermatol
Radiación UVB y UVA: daños en la piel
• Rayos UVB
•
•
•
•
•
Alta energía pero no penetra en la piel muy
profundo – principalmente afecta la
epidermis
Primera causa de quemaduras solares
Causa daños en el DNA y contribuye al
cancer de piel en un 65%
Actua como inmunosupresor
Contribuye al fotoenvejecimiento
• Rayos UVA
•
•
•
•
Penetra mais profundamente en la dermis,
dañando el colágeno y afectando la
producción de elastina que lleva a las
arrugas
El daño en la piel es cumulativo y la mayor
causa de fotoenvejecimiento
Estimula la producción de melanina y
puede causar la pigmentación
Causa danõ en el DNA y contribuye al
cancer de piel en un 35%
Page 4
Rayos UV son los
responsables por unos
90% del
fotoenvejecimiento
prematuro!
Radiación UVB y UVA: daños en la piel
Page
Cual es la edad de la piel?
Factores intrínsicos de la edad
vs.
Factores externos
(ej. fotoenvejecimiento)
Page 6
La radiación UVB depende de vários factores
•
•
•
•
Las estaciones – más alta en verano y menor en invierno.
Hora del día – más alta al medio día
Latitud – más alta en Ecuador
Altitud – alta radiación UVB
100
90
80
70
60
50
40
30
20
10
Radiación UVA es mas constante durante el año y horas del día
Page 7
Y porque la protección UVA?
•
Prevención del cancer de piel: UVA
contribuye en un 35% de todos los canceres
de piel
•
Prevención de daños en la piel, daños al
DNA, mutaciones p53
•
Prevención de la actividad inmunosupresora
•
Prevención de manchas de edad y otras
pigmentaciones
•
Prevención del fotoenvejecimiento y
arrugas
•
Prevención del 90% de todos los sintomas
del envejecimiento prematuro!
Page 8
*Sources: The Skin Cancer Foundation, Mayoclinic.com, AAD.org
Agenda
•
Sol y piel – porque necesitamos la protección UV?
• Cambios
Regulatórios
y Retos
•Cambios
Regulatórios
y Retos
•
Eligiendo filtros UV y sinérgia entre ellos
•
Fotoestabilidad y desempeño de PARSOL® 1789
•
Tendencias de Mercado Europa
Page 9
Recomendación Europea 2006
Very High Protection
High Protection
Medium Protection
Low Protection
Measured Sun
Protection
Factor
50+
> 60
50
50 - 59.9
30
30 - 49.9
25
25 - 29.9
20
20 - 24.9
15
15 - 19.9
10
10 - 14.9
6
6 - 9.9
Recommended
minimum UVA
Protection
Factor
Recommended
minimum
critical
wavelength
1/3 of labeled SPF
Category
Labeled Sun
Protection
Factor
370nm
Threshold: go / no go criteria
Page 10
UVA
Agenda
•
Sol y piel – porque necesitamos la protección UV?
•
Cambios Regulatórios y Retos
•
Eligiendo filtros
filtros UV
UV yy sinérgia
sinérgia entre
entre ellos
ellos
Eligiendo
•
Fotoestabilidad y desempeño de PARSOL® 1789
•
Tendencias de Mercado Europa
Page 13
Alto desempeño en SPF
UV1,210,000
A contribution to SPF
1,2
0,04
1
0,03
1 1,000
0,03
W/qm*nm
W/qm*nm
relative Energy
0,8
0,8
0,100
0,02
0,6
0,6
0,010
0,4
90 %
0,4
0,001
Erythema Action Spectrum
Erythema Action
Spectrum
Erythema
Action Spectrum
95 %
Erythemal
Energy
0,2
0,2
0,02
UV-SSR Source
Spectrum
UV-SSR
Source Spectrum
98 %
0,01
Effective Erythemal Radiation during SPF test
0,01
0 0,000
290 290 300 300 310310
0
290
300
310
320
320
320
330
330
330
340
340
340
350
nm
nm
nm
Page 14
350
350
360
360
360
370
370
370
380380 390 390 400 400
380
390
0,00
400
Como elegir el filtro UVA?
Comparación del desempeño de filtros UVA
E 1/1
l, nm
Page 15
Alto desempeño en SPF
SPF in vivo
UVA Contribution - Experimental Data
Avobenzone concentration
Absorptance
- 2.9 %
-3.5 %
-2.9 %
-1.9 %
Una buena protección UVA entrega 2 – 4 % Absorbancia:
también colabora para un alto SPF!
Page 16
Alto desempeño en SPF
La estabilización de la Avobenzona es
necesaria
100%
Productos de mercado con niveles
de estabilización 100% contienen:
95%
• Octocrileno
90%
y/o
85%
% HPLC Recovery Avobenzone
after Radiation
80%
75%
70%
3.0% 4.0% 5.0% 6.0% 7.0% 8.0% 9.0%
Octocrylene use level
Page 17
Dose-Response for a O/W system
• Uso de estabilizantes
adicionales, como
Methilbenzelideno canfora
(MBC)
Overview de los Filtros Solares DSM
Buthyl Methoxydibenzoylmethane (BMDBM)
UVA filter
Ethylhexyl Methoxycinnamate (OMC)
UVB filter
Octocrylene
UVB filter
4-Methylbenzylidene Camphor
approved UVB filter outside US
Ethylhexyl Salicylate
UVB filter
Homosalate
UVB filter
Phenylbenzimidazole Sulfonic Acid
UVB filter (water soluble)
Titanium Dioxide
UVB filter (inorganic)
Titanium Dioxide TX50 AB
Polysilicone-15
UVB filter (inorganic)
approved UVB filter outside
US (polymeric) (permitted in
hair care applications and as a
foto stabilizer in US)
Page 20
PARSOL 1789
INCI name:
USAN:
Buthyl Methoxydibenzoylmethane (BMDBM)
Avobenzone
E11 = 1100 - 1180 (Ethanol)
max: 357 nm (UVA absorber)
• Uso de solventes para mantener el producto en
solución
• Calentar hasta 80 - 85 °C : solución clara
• Uso de agentes quelantes para evitar complejos
con metales de transición
• Seleccionar con cuidado sistema de preservación
(no formaldehyde y sus donantes)
• Impurezas de hierro pueden llevar a cambio de
color
Avobenzona (PARSOL® 1789) es 100% fotoestable cuando es
formulada junto con Octocrileno (PARSOL® 340) y/o 4- methylbenzilideno
canfora (PARSOL® 5000)
Page 21
PARSOL 340
INCI name:
USAN:
E11 = 340 - 370 (Ethanol)
max: 303 nm (UVB absorber)
Octocrylene
Octocrylene
•PARSOL® 340 es fácil de manejar. Puede ser facilmente disuelto en la fase
grasosa de la formulación.
•PARSOL® 340 es compatible con la gran mayoría de los ingredientes
cosméticos
•PARSOL® 340 es un excelente fotoestabilizador de la Avobenzona
•PARSOL® 340 es un óptimo solvente de la Avobenzone (25%)
Benefícios 3 en 1:
- Filtro UVB
- Estabilizante para Avobenzone
- Solvente para otros filtros UV
Page 22
Nuevas oportunidades para el Octocrileno
Lista de filtros UV permitidos y su concentración máxima de uso
Calculado como Esther 14%:
Page 23
PARSOL 5000
E11 = 930 - 990 (Ethanol)
max: 299 nm (UVB absorber)
INCI name: 4-Methylbenzylidene Camphor
• Se recomienda usar solventes para mantener el producto en
solución
• Calentar hasta 80 - 85 °C para obtención de una solución clara
• MBC es un excelente estabilizante para Avobenzone
Page 24
PARSOL MCX
INCI name: Ethylhexyl Methoxycinnamate (OMC)
E11 = 835 - 865 (Ethanol)
max: 308 nm (UVB absorber)
• PARSOL® MCX es facil de manejar. Se mantiene liquido y no
cristaliza en la formulacion.
Puede ser facilmente disuelto en la fase oleosa de la formulación
• PARSOL® MCX es un excelente solvente paras otros filtros UV
Page 25
E11 = 920 - 1000 (Water)
max: 306 nm (UVB absorber)
PARSOL HS
INCI name: Phenylbenzimidazole Sulfonic Acid
• Filtro UVB soluble en água. Necesita neutralización, con las bases: (para 1g
de PARSOL® HS)
–
–
–
–
–
KOH 100%
NaOH 100%
TEA 100%
AMP 100%
Tromethamine 100%
0.20 g
0.15 g
0.65 g
0.35 g
0.50 g
• Usando AMP o TEA como neutralizante no disminuye la viscosidad de la
emulsión
• Formular siempre en pH mayor que 7,0 para evitar cristalización
Page 26
PARSOL EHS
INCI name:
E11 = 168 - 182 (Ethanol)
max: 306 nm (UVB absorber)
Ethylhexyl Salicylate
• EHS es facil de manejar. Se mantiene liquido y no cristaliza en
la formulacion.
Puede ser facilmente disuelto en la fase oleosa de la
formulación
• EHS es un optimo solubilizante para PARSOL® 1789
Page 27
PARSOL HMS
INCI name:
E11 = 170 - 180 (Ethanol)
max: 305 nm (UVB absorber)
Homosalate
• HMS es facil de manejar. Se mantiene liquido y no cristaliza en
la formulacion.
Puede ser facilmente disuelto en la fase oleosa de la
formulación
• EHS es un optimo solubilizante para PARSOL® 1789
Page 28
PARSOL TX
INCI name:
Titanium Dioxide, Silica, Dimethicone
• Primary particle size: 17-23*nm (mean value)
Rutile Titanium Dioxide Core,
Silica, Dimethicone,
max: 316 nm (UVB absorber)
Page 29
PARSOL TX
• TX es fácil de dispersar. Puede ser añadido directamente en la
fase oleosa de la formulación.
• TX es compatible con la Avobenzone y la gran mayoría de
losingredientes cosméticos, especialmente espesores de
acrilato
• TX50 AB es la dispersion del PARSOL TX en Alkyl Benzoate
Page 30
PARSOL SLX
INCI name:
E11 = 160 - 190
max: 312 nm (UVB absorber)
Polysilicone-15
• PARSOL® SLX es estable en pH del 4-9. puede ser añadido en
la fase oleosa y calentado hasta 80°C por 6 hs sin perder
actividad.
• PARSOL® SLX es compatible con filtros organicos e
inorganicos, emolientes y emulsificantes mas usados
• PARSOL® SLX es aprobado en EU con máxima concentración
de uso permitida de 10% en formulaciones cosméticas
Page 31
PARSOL SLX
Aplicaciones
Sun Care/ Skin Care
• PARSOL® SLX contribuye para la obtención de alta protección
solar
• Para productos Sun Care y Daily Care, para productos para
pieles sensitivas
Hair Care
• Protege el color de los cabellos teñidos
• Mejora la peinabilidad del cabello después de la radiación UV
cuando es comparado con el placebo
• Silicon base product: efecto condicionante, aumento del
brillo, …
Page 32
Natura Plant Verano Summer Combing Cream
Company:
Natura Cosmeticos
Country:
Argentina
Date Published: Feb 2012
1736314
Sub-Category:
Hair Treatments
Price (local):
Price (major
currencies):
ARS56.0
$13.14 / €9.91
The Natura Plant Verano range is enriched with coconut lipids and
UV filter and claimed to hydrate and restore damaged hair
strands, preparing them for sun exposure while providing a
protective anti-UV layer to provide long-lasting protection.
Available as part of the range are: Crema para Peinar (Summer
Combing Cream), retailed in a 170ml pack; and Mascaril…
Ingredients: Aqua, Cetearyl Alcohol, PPG-15 Stearyl Ether, Dimethicone, Dimethiconol, TEAdodecylbenzenesulfonate, Elaeis Guineensis Oil, parfum, Polysilicone-15, Behentrimonium
Chloride, Cetrimonium Chloride…
Claims:
33
Page
Seasonal, Damaged Hair, Botanical/Herbal, Ethical - Environmentally Friendly Package, UV
Protection, Long-Lasting*, Moisturising / Hydrating
Schwarzkopf Gliss Hair Repair Color Protection 30 Refle…
Company:
Schwarzkopf & Henkel
Country:
Israel
Date Published: Jul 2009
1141687
Sub-Category:
Hair Treatments
Price (local):
Price (major
currencies):
ILS39.99
$10.19 / €7.34
Schwarzkopf Gliss Hair Repair Color Protection 30 Reflex-Shine
Treatment repairs coloured, dyed hair from inside out. The leavein treatment protects the colour from fading, and gives up to
90% colour retention after 30 applications. The product repairs
the hair structure and smoothes the hair surface for an
immediate, shimmering shine. It offers tangibly no…
Ingredients: Aqua, Alcohol Denat. (Denatured), Polyquaternium-37, Trisiloxane, Dimethicone, Mica,
Amodimethicone, Polyquaternium-11, parfum (fragrance), Prunus Armeniaca Kernel Oil, Panthenol,
Propylene Glycol, dicaprylate/dicaprate, Polysilicone-15, Glycerin, Laurdimonium Hydroxypropyl
Hydrolyzed Wheat Protein (Hydrolyzed), Polyquaternium-10, Linalool, Hexyl Cinnamal, Lactic Acid,
PPG-1 Trideceth-6, Cetrimonium Chloride, Cyclomethicone, Hydrolyzed Keratin (Hydrolyzed),
Trideceth-12, Butylphenyl Methylpropional, Benzyl Alcohol, L-limonene, Coumarin, CI 77891
Claims: Brightening / Illuminating*, Time/Speed, Damaged Hair
34
Page
Fotoestabilizantes para Avobenzona
Filtros UV
1.PARSOL® 340
Octocrylene
2. PARSOL® 5000 4-Methylbenzylidene
Camphor
Estabilizantes
6.Tinogard Q
Tris(tetramethylhydoxypiperidinol) citrate
7.Tinogard TL Benzotriazolyl Dodecyl
p-Cresol
8. Corapan TQ Diethylhexyl 2,6-Naphthalate
3.Eusolex 4360
Benzophenone-3
9.Hallbrite BHB Butyloctyl Salicylate
4.PARSOL® SLX
Benzophenone-3
5.Tinosorb S Bis-Ethylhexyloxyphenol
Methoxyphenyl Triazine
10. Polycrylene Polyester-8
11. Oxynex ST Diethylhexyl Syringylidene
Malonate
Photostability tests have been done in film:
70% ethanol / 30% Finsolv TN + Myritol 318
Page
Método de análisis de la fotoestabilidad
light
Glass plate 10cm2
layer 2mg/cm2
irradiation
25 MED
~ 70% evaporation
analysis of solution :
- spectrofotometric
- chromatographic
(e.g. HPLC)
drying
Dissolving in 50
ml Ethanol
Page 39
Eficácia de los fotoestabilizantes
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
Butyl Methoxydibenzoyl Methane
Butyl Methoxydibenzoyl
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
4.0%
Methane
3.6%
Octocrylene
4.0%
4.0%
2-5% stabilizer
2.0%
Octocrylene
4-Methylbenzylidene Camphor
Bis Ethylhexyloxyphenol
Methoxyphenyl Triazine
Diethylhexyl Syringylidene-malonat
4-Methylbenzylidene
Bis Ethylhexyloxyphenol
Camphor
Methoxyphenyl Triazine
Benzophenone-3
Benzophenone-3
Benzotriazolyl Dodecyl pCresol
Polysilicone-15
Tris(tetramethylhydroxypiper
idinol)citrate
Benzotriazolyl Dodecyl p-Cresol
2% stabilizer
4.0%
2.0%
4.0%
2.0%
4.0%
2.0%
5.0%
2.0%
4.0%
2.0%
2.0%
2.0%
Polysilicone-15
Tris(tetramethylhydroxypiperidinol)citrate
Butyloctyl Salicylate
Polyester-8
2.0%
2.0%
Diethylhexyl
Butyloctyl Salicylate
Syringylidenemalonat
3.0%
2.0%
Polyester-8
Diethylhexyl-2,6-Naphthalate
2.0%
Diethylhexyl-2,6Content of BMDBM after 25 MED 23%
Naphthalate
Content of BMDBM after
25 MEDPage
23%
5.0%
77%
90%
70%
87%
69%
82%
58%
81%
53%
80%
53%
45%
53%
44%
53%
43%
53%
42%
5.0%
2.0%
50%
34%
50%
47%
Mezclas de estabilizantes
Butyl Methoxydibenzoyl
Methane
4,0%
4,0%
4,0%
4,0%
4,0%
Octocrylene
4,0%
4,0%
4,0%
4,0%
4,0%
2,0%
4,0%
Bis Ethylhexyloxyphenol
Methoxyphenyl Triazine
4-Methylbenzylidene
Camphor
4,0%
Polysilicone-15
Content* BMDBM after
25MED
4,0%
90%
100%
95%
100%
95%
* deviation ±5%
100% de estabilización de la Avobenzona es posible !!
Page 41
Recubrimiento del TiO2
Coated TiO2
Rutile or Anatas core
Silica, or Al2O3, Stearic Acid
between 3% and 30% coating
material
Dimethicone, Simethicone
PARSOL TX
Page 44
INCI of ingredient
CAS No.
EINECS
Titanium Dioxide
13463-67-7
236-675-5
Silica
7631-86-9
262-373-8
Dimethicone
(C2H6OSi)xC4H12Si
9016-00-6
polymer exempt
Influencia del tamaño de los cristales en
propiedades de absorción
Page 45
Cual es la mejor
opción?
Page 46
Estabilidad del desempeño de Avobenzona
y TiO2
•
BMDBM and TiO2 is a common combination
in sun-care and day-care in Europe and Asia Pacific.
•
Al2O3 is one of the most commonly used coating
material for TiO2.
•
As a result, BMDBM - Al 3+ complex is formed
•
Reduced amount of BMDBM is detected
if a formulation is analyzed, leading to potential
problems in UVA protection, but more important
is the risk of crystal formation do to the lower
solubility of this complex.
•
Solubility of 1789/Al complex 2% in Finsolv TN
•
Problems with customers and authorities
(reduced content of used and eventually charged Parsol 1789)
Page 47
Estabilidad del desempeño de Avobenzona
y TiO2
400x
•
Formulation 3 months at 43°C,
formulated with 10% Al coated
TiO2
Page 48
400x
•
Same formulation, same storage
time with 10% of Parsol TX doesn’t
have any crystals
Estabilidad del desempeño de Avobenzona
y TiO2
Formation of Al - BMDBM complex
• 4% BMDBM
• 10% TiO2 /
Aluminium Hydroxide /
Stearic Acid
• HPLC Method
%
An Al - BMDBM complex appears already after 2 weeks
Page
49
Agenda
•
Sol y piel – porque necesitamos la protección UV?
•
Cambios Regulatórios y Retos
•
Eligiendo filtros UV y sinérgia entre ellos
•
Fotoestabilidad y desempeño de PARSOL® 1789
•Tendencias de Mercado Europa
Page 56
Protección Solar &
Cuidado diário
Consumer‘s Habits & Attitudes in Sun Care
Page
Enfasis en alto SPF, protección UVA, y
Conveniencia
•
More than sunburn prevention—it's balanced sun
damage protection.
The truth is, most sunscreens don't protect against
both UVB and UVA rays. But, now from Neutrogena,
comes a complete line of Sun Protection products
featuring breakthrough Helioplex™ technology. Never
before has skin protection against the sun's rays been
so complete—or balanced.
"Helioplex™ delivers unbeatable UVA
protection. It works better to help
prevent damaging UVA rays from
penetrating deep under skin's surface.
Dry-Touch technology absorbs excess
sunscreen oils, leaving a clean,
lightweight, non-shiny finish."
Page 58
Anti-edad, Protección UVA y UVB
New ultralight formula to hydrate the skin.
Waterproof
Protects DNA cells against damage caused by the
sun
Innovative system of protective UVA and UVB
filters with folic acid to provide better
protection from marks, lines and sun damage.
Page 59
Helioplex- Protección UVA/UVB avanzada
PIZ BUIN® IN SUN LOTION
Helioplex™ technology provides photostable UVA/UVB broadspectrum
protection while Vitamin E helps neutralise free radicals which cause
premature skin ageing. A rich hydration complex helps your skin
remain moisturised all day, leaving it smooth and silky soft. Sweat
and water-resistant.
AVAILABLE SPF's: 200ml - SPF 6, 10, 15, 20, 30, 50+
PIZ BUIN® ACTIVE FRESH COOLING
The ACTIVE Fresh Cooling Spray cools the skin
continuous spray system is easy to apply
non-greasy formula dries within seconds
enriches the skin with moisture and essential vitamins
Helioplex™, a breakthrough technology newly
developed by PIZ BUIN®, provides photostable,
efficient protection against harmful UVA/UVB rays
Sweat -and very water- resistant.
AVAILABLE SPF's: 20, 30
Page 60
Combinaciones de Filtros UV en productos
BDF lanzados a partir de octubre 2011:
Butyl Methoxydibenzoylmethane (25),
Octocrylene (17), Bis-ethylhexyloxyphenol
Methoxyphenyl Triazine (14), Ethylhexyl
Methoxycinnamate (11), Homosalate (9), Sodium
Phenylbenzimidazole Sulfonate (8), Ethylhexyl
Salicylate (7), CI 77891 (5) Titanium Dioxide,
Ethylhexyl Triazone (4), Diethylhexyl Butamido
Triazone
Page
New Product Launches BDF since 11.2011
•
Nivea Sun Kids Caring Sun Spray SPF 50 + offers very high and
immediate protection for children's delicate skin. The product is
very water resistant and has a non-sticky, easily absorbed formula
that offers deep and long lasting moisture for smooth skin. It is
formulated to help reduce the risk of sun allergies and has been
skin compatibility dermatologically tested and approved. The
product retails in a value size 300ml pack.
•
aqua, glycerin, octocrylene, butylene glycol dicaprylate/dicaprate,
alcohol denat., butyl methoxydibenzoylmethane, bisethylhexyloxyphenol methoxyphenyl triazine, homosalate,
titanium dioxide, sodium phenylbenzimidazole sulfonate,
ceteareth-20, methyl propanediol, C18-36 acid triglyceride,
tocopheryl acetate, diethylhexyl butamido triazone, ethylhexyl
methoxycinnamate, VP/hexadecene copolymer, acrylates/C10-30
alkyl acrylate crosspolymer, trimethoxycaprylylsilane, trisodium
EDTA, ethylhexyl glycerin, methylparaben, ethylparaben,
phenoxyethanol, BHT, limonene, linalool, benzyl benzoate,
hydroxyisohexyl 3-cyclohexene carboxaldehyde, hexyl cinnamal,
benzyl salicylate, butylphenyl methylpropional, alpha-isomethyl
ionone, eugenol, citronellol, coumarin, parfum
Page
Nivea Sun Alpin Cream & Stick SPF 30
Nivea Sun Alpin Cream & Stick SPF 30 is claimed to combine two
products in one: a cream and a stick; offering immediate protection
of the face and lips under extreme conditions, protecting the skin
against the winter sun, cold, and wind. The cream is designed to
protect the face, while the stick is for the lips.
Aqua (water), butylene glycol dicaprylate/dicaprate, C12-15 alkyl
benzoate, butylene glycol, glycerin, PEG-30 dipolyhydroxystearate,
titanium dioxide, butyl methoxydibenzoylmethane, ethylhexyl
triazone, isopropyl stearate, cera microcristallina, alcohol denat.,
paraffinum liquidum, bis-ethylhexyloxyphenol methoxyphenyl
triazine, panthenol, tocopheryl acetate, glycine, C18-36 acid
triglyceride, cetyl dimethicone, sodium starch octenylsuccinate,
trimethoxycaprylylsilane, magnesium sulfate, trisodium EDTA,
ethylhexylglycerin, phenoxyethanol, methylparaben,
propylparaben, limonene, linalool, benzyl benzoate,
hydroxyisohexyl 3-cyclohexene carboxaldehyde, hexyl cinnamal,
benzyl salicylate, butylphenyl methylpropional, alpha-isomethyl
ionone, eugenol, citronellol, coumarin, parfum
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Nivea Sun Baby Bloqueador Solar
(Baby Sunblock SPF 60)
Nivea Sun Baby Bloqueador Solar (Baby Sunblock SPF 60) is now
available in a newly designed 115g pack. It features a
dermatologically tested, water-resistant formula, designed to
protect baby's delicate skin against UVA and UVB sun rays, helping
to prevent sunburn. Free of fragrance, alcohol and colourants,
the product retails in a 115ml pack.
aqua, butylene glycol dicaprylate/dicaprate, C12-15 alkyl
benzoate, titanium dioxide, butyl methoxydibenzoylmethane,
alcohol, glycerin, bis-ethylhexyloxyphenol methoxyphenyl
triazine, dicaprylyl carbonate, ethylhexyl triazone,
phenylbenzimidazole sulfonic acid, cetearyl alcohol, cetyl
alcohol, glycine, C18-36 acid triglyceride, glyceryl stearate SE,
hydrogenated coco-glycerides, tocopheryl acetate,
VP/hexadecene copolymer, xanthan gum, PEG-40 castor oil,
trisodium EDTA, sodium cetearyl sulfate, triethoxycaprylylsilane,
zinc sulphate, magnesium sulphate, ethylhexyl glycerin,
phenoxyethanol, methylparaben, propylparaben, sodium
hydroxide
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Combinaciones de Filtros UV en productos
L'Oreal lanzados a partir de octubre 2011
Butyl Methoxydibenzoylmethane (378), Octocrylene
(367), Drometrizole Trisiloxane (292), Ethylhexyl
Triazone (239), Terephthalylidene Dicamphor Sulfonic
Acid (238), Ethylhexyl Salicylate (101), Bisethylhexyloxyphenol Methoxyphenyl Triazine (96),
Ethylhexyl Methoxycinnamate (46), Titanium Dioxide
(25), Phenylbenzimidazole Sulfonic Acid (13),
Diethylhexyl Butamido Triazone (11), Benzophenone-3
(9), 4-methylbenzylidene Camphor (8), Homosalate (3
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Vichy Laboratoires Capital Soleil Ansigt Solcreme
Vichy Laboratoires Capital Soleil Ansigt Solcreme (Facial
Sun Crème SPF 25) is suitable for normal to dry skin and is
formulated without parabens. It is foto-stable and made
with Mexoryl-XL and DHC for cellular protection.
Aqua (water), octocrylene, glycerin, alcohol denat.,
propylene glycol, C12-15 alkyl benzoate,
cyclohexasiloxane, ethylhexyl salicylate, butyl
methoxydibenzoylmethane, ethylhexyl triazone, bis
ethylhexyloxyphenol methoxyphenyl triazine, talc,
drometrizole trisiloxane, acrylates/C10-30 alkyl acrylate
crosspolymer, aluminum hydroxide, aluminum starch
octenylsuccinate, ascorbyl glycoside, citric acid,
ethylhexylglycerin, isohexadecane, methylsilanol/silicate
crosspolymer, neohesperidin dihydrochalcone, parfum
(fragrance), pentasodium ethylenediamine tetramethylene
phosphonate, phenoxyethanol, polysorbate 60, polysorbate
80, sodium hyaluronate, sodium polyacryloyldimethyl
taurate, sorbitan oleate, stearic acid, titanium dioxide,
tocopherol, triethanolamine
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Ambre Solaire UV-Ski Extreme
Conditions Protection FSP 50+
Ambre Solaire UV Ski Extreme Conditions Protection Cream
SPF 50+ is claimed to offer a superior level of UVA
protection, and is suitable for sun intolerant skin.
Aqua (water), C12-15 alkyl benzoate, cyclohexasiloxane,
cyclopentasiloxane, alcohol denat., isohexadecane,
ethylhexyl salicylate, propylene glycol, titanium dioxide,
bis-ethylhexyloxyphenol methoxyphenyl triazine,
octocrylene, butyl methoxydibenzoylmethane, PEG-30
dipolyhydroxystearate, glycerin, terephthalylidene
dicamphor sulfonic acid, lauryl PEG/PPG-18/18 methicone,
ethylhexyl triazone, tocopherol, dodecene,
phenoxyethanol, ethylparaben, triethanolamine,
poloxamer 407, dimethicone, pentasodium
ethylenediamine tetramethylene phosphonate,
drometrizole trisiloxane, propylparaben, isobutylparaben,
sorbitol, methylparaben, butylparaben, opuntia
coccinellifera flower extract, glycine soja (soybean oil),
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Ice Effect Moisturising Sun Milk SPF 30
L'Oréal Solar Expertise Icy Protection Leche Solar
Hidratación Efecto Hielo (Ice Effect Moisturising Sun Milk
SPF 30) features a non-greasy, non-sticky, water- and
sweat-resistant, moisturising formula with SPF 30 sun
protection against UVA/UVB rays and a blend of water
micro-drops with hydrating milk.
aqua (water), glycerin, alcohol denat., octocrylene,
ethylhexyl salicylate, butyl methoxydibenzoylmethane,
butylene glycol, ethylhexyl triazone, titanium dioxide,
dimethicone, phenoxyethanol, sodium acrylates
crosspolymer, drometrizole trisiloxane, glyceryl stearate,
behenyl alcohol, triethanolamine, terephthalylidene
dicamphor sulfonic acid, methylparaben, caprylyl glycol,
menthol, glyceryl stearate citrate, disodium ethylene
dicocamide PEG-15 disulfate, ethylparaben, ammonium
polyacryldimethyltauramide, ammonium
polyacryloyldimethyl taurate, acrylates copolymer,
disodium EDTA, aluminium hydroxide, stearic acid,
tocopherol, sodium hyaluronate, linalool, silica, CI 42090
(blue 1), parfum (fragrance)
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Delial Ambre Solaire Resisto Niños SPF 50
Garnier Delial Ambre Solaire Resisto Niños SPF 50 Leche
Hidratante Muy Alta Proteción (SPF 50 Childrens High
Protection Moisturising Sun Milk) features a patented Mexoplex
filter system to protect kids sensitive skin against UVA and
UVB rays. Enriched with vegetable wax, it is claimed to be two
times more resistant to water than other suncreams.
Aqua (water), C12-15 alkyl benzoate, alcohol denat.,
isohexadecane, ethylhexyl salicylate, propylene glycol,
titanium dioxide, cyclohexasiloxane, butyl
methoxydibenzoylmethane, PEG-30 dipolyhydroxystearate,
bis-ethylhexyloxyphenol methoxyphenyl triazine, octocrylene,
glycerin, cyclopentasiloxane, lauryl PEG/PPG-18/18
methicone, terephthalylidene dicamphor sulfonic acid,
synthetic wax, ethylhexyl triazone, tocopherol, dodecene,
triethanolamine, silica, poloxamer 407, dimethicone,
ammonium polyacryldimethyltauramide, ammonium
polyacryloyldimethyl taurate, simmondsia chinensis (jojoba
seed) oil, pentasodium ethylenediamine tetramethylene
phosphonate, drometrizole trisiloxane, isopropyl lauroyl
sarcosinate, isostearyl alcohol, caprylyl glycol,
disteardimonium hectorite,
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Eau Thermale Avène Sol Lotion
(Sun Lotion SPF 50+)
Eau Thermale Avène Sol Lotion (Sun Lotion SPF 50+) is suitable
for babies' sensitive skin and is very water resistant with very
high UVA and UVB protection. The hypoallergenic and noncomedogenic product is fragrance- and paraben-free. It retails
in a 100ml pack
avene aqua, octocrylene, cyclomethicone, dicaprylyl ether,
methylene bis-benzotriazolyl tetramethylbutylphenol, aqua,
butyl methoxydibenzoylmethane, cetearyl isononanoate,
glycerin, titanium dioxide, bis-ethylhexyloxyphenol
methoxyphenyl triazine, C12-15 alkyl benzoate, diisopropyl
adipate, potassium cetyl phosphate, stearyl alcohol,
PVP/eicosene copolymer, caprylic/capric triglyceride, caprylyl
glycol, decyl glucoside, dimethicone, disodium EDTA, glyceryl
behenate, glyceryl dibehenate, propylene glycol, silica, sorbic
acid, tocopheryl glucoside, tribehenin, xanthan gum,
tocopherol
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Eau Thermale Avène Crema para Zonas
Sensibles
Eau Thermale Avène Crema para Zonas Sensibles (Cream for
Sensitive Areas) is now available in a newly designed 15ml
pack. This water resistant product features SPF 50+ providing
UVA and UVB protection, is designed for intolerant skin, is
hypoallergenic, fragrance- and paraben-free and noncomedogenic. It can be used on sensitive areas such as nose,
cheeks, lips and scars
Avene thermal water (Avene aqua), titanium dioxide, isodecyl
neopentanoate, triethylhexanoin, C12-15 alkyl benzoate,
cyclomethicone, glycerin, polyglyceryl-4 isostearate, C30-45
alkyl methicone, cetyl PEG/PPG-10/1 dimethicone, hexyl
laurate, alumina, water (aqua), stearic acid, hydrogenated
castor oil, caprylic/capric triglyceride, disodium EDTA, iron
oxides (CI 77492), iron oxides (CI 77491), octyldodecanol,
silica dimethyl silylate, sodium chloride, sodium myristoyl
glutamate, sorbic acid, tocopheryl glucoside,
triethoxycaprylylsilane, xanthan gum, tetradibutyl
pentaerithrityl hydroxyhydrocinnamate
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Muchas gracias por su atención!
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