Institute Report 2010-2011 Institute for Sanitary Engineering, Water
Transcription
Institute Report 2010-2011 Institute for Sanitary Engineering, Water
Universität Stuttgart Universität Stuttgart Universität Stuttgart Institute Report 2010-2011 Chair of Sanitary Engineering and Waterrecycling o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: +49 (0) 711/685-63723 Resouces Management und Industrial Waste | RIK Institute for Sanitary Engineering, Water Quality and Solid Waste Management Dipl.-Ing. Gerold Hafner Tel.: +49 (0) 711/685-65438 Emissions | EMS Dipl.-Ing. Carsten Meyer Tel.: +49 (0) 711/685-63754 Industrial Water and Wastewater Technology | IWT Prof. Dr.-Ing. Uwe Menzel Tel.: +49 (0) 711/685-65417 Urban Drainage | SE Dr.-Ing. Ulrich Dittmer Tel.: ++49 (0) 711/685-69350 Water Quality Management and Water Supply | WGW Dipl.-Ing. Ralf Minke Tel.: +49 (0) 711/685-65423 Chair of Waste Management and Emissions o. Prof. Dr.-Ing. Martin Kranert Tel.: +49 (0) 711/685-65500 Biological Air Purification | ALR Prof. Dr. rer. nat. Karl-Heinrich Engesser Tel.: +49 (0) 711/685-63734 Solid Waste Management | SIA Dr.-Ing. Martin Reiser Tel.: +49 (0) 711/685-65416 | ALR Chair of Hydrochemistry and Hydrobiology | AWT o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Tel.: +49 (0) 711/685-63721 | BiOS Hydrochemistry and Analytical Quality Assurance | CH Dr.-Ing. Michael Koch Tel.: +49 (0) 711/685-65444 | CH Hydrobiology and Analysis of Organic Trace Compounds | BiOS Dr. rer. nat. Bertram Kuch Tel.: +49 (0) 711/685-65443 Sewage Treatment Plant for Research and Education | LFKW Dipl.-Ing. Peter Maurer Tel.: +49 (0) 711/685-65420 Administrative Office Dipl.-Ing. Stephan Mollweide Tel.: +49 (0) 711/685-63713 Dr.-Ing. Klaus Fischer Tel.: +49 (0) 711/685-65427 Bandtäle 2 70569 Stuttgart Germany Tel.: +49 (0) 711/685-63721 Fax: +49 (0) 711/685-63729 www.iswa.uni-stuttgart.de | EMS Institute Report 2010-2011 Wastewater Technology | AWT | IWT | LFKW | RIK | SE | SIA | WGW Institute report 2010-2011 Institute for Sanitary Engineering, Water Quality and Solid Waste Management | ISWA Bandtäle 2 70569 Stuttgart Content Institute for Sanitary Engineering, Water Quality 5 and Solid Waste Management Chair of Sanitary Engineering and Waterrecycling 11 Wastewater Technology | AWT 22 Industrial Water and Wastewater Technology | IWT 42 Urban Drainage | SE 56 Water Quality Management and Water Supply | WGW 64 Chair of Waste Management and Emissions 79 Solid Waste Management | SIA 98 Resource Management and Industrial Recycling | RIK 122 Emissions | EMS 130 Biological Air Purification | ALR 136 Chair of Hydrochemistry and Hydrobiology 143 Hydrochemistry and Analytical Quality Assurance | CH 156 Hydrobiology and Analysis of Organic Trace Compounds | BiOS 162 Sewage Treatment Plant for Research and Education | LFKW 172 3 4 Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Bandtäle 2 70569 Stuttgart Germany Tel.: +49 (0) 711/685-63721 Fax: +49 (0) 711/685-63729 www.iswa.uni-stuttgart.de 5 Universität Stuttgart The Institute for Sanitary Engineering, Water Quality, and Solid Waste Management (ISWA) is a research and training facility of the University of Stuttgart (Universität Stuttgart) within the faculty of “Civil and Environmental Engineering Sciences”. The University’s Sewage Treatment Plant for Research and Teaching, which is situated within the institute, is unique throughout Europe. Experts from various engineering and natural sciences work together at our institute on an interdisciplinary basis. Our principal areas of expertise are the classical engineering tasks in the environmental fields of water, wastewater, solid waste, soil, and exhaust air. The continuous development of technical facilities and practical methods in the fields of industrial and municipal supply and disposal are the focus of our interest. Our experience is also incorporated into the monitoring and development of quality assurance measures and management systems. We offer a large variety of study courses Our institute offers numerous courses and internships in basic and specialized studies, as well as, student research projects, dissertations, Bachelor and Master’s theses for the following courses of study: • • • • • Our institute, which is known today as the Institute for Sanitary Engineering, Water Quality and Solid Waste Management (ISWA), was founded as the “Institute for Sanitary Engineering and Health Technology” in the early 1950s. At that time, it was the first educational establishment in Germany for civil engineers in the field of water and solid waste in urban development. In the 1970s the first chair of solid waste management at a German university was created. Today, our institute is one of the largest of its kind in the world. The three chairs at the ISWA – Sanitary Engineering and Water Recycling, Solid Waste Management and Exhaust Air, Hydrochemistry and Hydrobiology in Sanitary Engineering – represent the broad spectrum of environmental issues that occupy us in one department and nine sections. 6 • • • Civil Engineering Environmental Engineering Real Estate Engineering and Management WAREM (Water Resources Engineering and Management) WASTE (Air Quality Control, Solid Waste and Waste Water Process Engineering) Infrastructure Planning Technical Biology EDUBRAS-MAUI (Meio Ambiente Urbano e Industrial – municipal and industrial environmental protection) Master study in Curitiba / Brasilien For the first time, ISWA introduced a Master of Science course under German administration at the public university UFBR of Curitiba, Brazil. The project is named “Export of German University education” and is funded by the DAAD. Therewith, courses of ISWA are also offered in non-European countries. In addition, there are courses for students in process engineering, biology, and chemistry. We also participate in the international doctoral candidate program ENWAT (Environment Water) at the University of Stutt- Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA gart (Universität Stuttgart), as well as, in programs for non-university education and training. Scientific collaboration Under the auspices of the ISWA, scientific colloquia and congresses on current topics of national significance relating sanitary engineering and solid waste management have been held since 1957. Our academic employees are representatives on numerous national and international boards as well as, on technical and standardization committees of various technical-scientific organizations. The ISWA facilities The institute currently employs around 105 people; four professors, six civil servants, about 47 academic employees as well as, approximately 48 employees in technical service. Furthermore, there are between 70 to 140 academic and student assistants as well as, over 15 fellows who prepared their doctoral thesis at the ISWA. All necessary facilities, the research treatment plant, testing facilities and laboratories, lecture rooms, the technical library as well as, computer workstations equipped with specialist applications, are available for university teaching and research. One of the special features of our institute is the sewage treatment plant for research and education, which routinely also cleans the wastewater from the campus in Vaihingen and the district Stuttgart Büsnau. Our laboratories are excellently equipped for extensive investigations in a wide variety of environmental fields (water, wastewater, solid waste/soil, air). We have a large amount of (online) measuring equipment available for experiments on a laboratory scale, semitechnical scale and technical scale. In particular, this includes equipment for organic trace analysis; in part, these are operated using special coupling techniques for mass spectrometry (GCMS-MS, HPLCMSMS). We also utilize computer supported prediction methods in various scientific disciplines. With the aid of specially designed computer applications, modelling of processes in water and wastewater treatment is possible; measures in the fields of rainwater management and waste management concepts can be modeled, as well as, geochemical simulations being carried out. The continuously improved computer simulations serve process control or decision making at various levels. Focal points of teaching and research Our activities under the chairs of Sanitary Engineering and Water Recycling are concentrated around the minimization of the anthropogenic influence on water bodies and the natural hydrologic cycle during water extraction. Also, we are engaged in the optimized treatment and sustainable use of water resources and the effective and environmentally friendly wastewater discharge and treatment. Water resources management, in particular, is of increasing international importance in the rapidly growing urban areas of the developing and emerging countries. The chair of solid waste management and exhaust air, develops solutions ranging from waste avoidance to routes for material recycling and energy exploitation of waste, and their environmentally friendly disposal, including controlling the resulting emissions. Waste management is interdisciplinary embedded in both a 7 Universität Stuttgart scientific-technical and socio-economic context. Here, too, international cooperation projects are highly valued, but also regional integration, e.g. via the Kompetenzzentrum Umwelttechnik – KURS e.V. (Competence Centre Environmental Engineering). The chair of Hydrochemistry and Hydrobiology in Sanitary Engineering addresses questions on sanitary engineering and solid waste management using natural scientific methods. In particular, the occurrence and behaviour of environmental chemicals (e.g. eliminability, accumulation, mobility) in surface waters and groundwater, in water and wastewater treatment, as well as, in soil and waste are investigated. Moreover, analytical quality assurance takes a high priority. The close association of interdisciplinary research, teaching and practice in all areas of our institute is achieved by a constant discourse with external partners and research facilities as well as with clients, public and private facilities. Besides working on research and development projects, we offer external partners numerous services, consulting and expert’s advisory services as well as training. The Water Research Centre Stuttgart (wfz) Water in urban and natural systems is one of the most important issues of our century. Many water-related issues are the focus of our institute. Thus, an essential aspect is a global improvement of water supply and wastewater disposal. However, this cannot be achieved alone through the establishment of technical supply and disposal systems. The consideration of the entire water system is of fundamental importance. In addition, water is not only the most important food but is also an environmental and biotope design element. To understand the complex system water in all its aspects and interactions, concepts and strategies are needed that are based upon extensive scientific knowledge. Therefore, the hydrological regime with the associated nutrient loads and the interaction with the processes in the aquatic habitats are examined in order to derive appropriate modeling approaches and management strategies and to develop new technologies. This goes far beyond the core competencies of our institute and was the motivator for the professors at the ISWA to found the Water Research Centre in Stuttgart in 2007 together with colleagues at the Institute for Water and Environmental Systems (IWS). Since that time, colleges from other faculties with a focus in water related research joined, so that the water research center has been established as a crossfaculty, engineering oriented research center supported by institutes of the University of Stuttgart. The aim is to network, to combine activities, to expand, and in cooperation with other national and international actors to develop integrated water management solutions for the varied questions about the system water. First cross-institutional projects of the wfz have already been completed and new ones are currently being realized. 8 Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Managing Director: o. Prof. Dr.-Ing. Heidrun Steinmetz Board of Management: Full professors — Department Heads Manager of the Waste Water Treatment Plant — Head of Administrativ Office Chair of Sanitary Engineering and Water Recycling o. Prof. Dr.-Ing. Heidrun Steinmetz Wastewater Technology Industrial Water and Wastewater Technology Dipl.-Ing. Carsten Meyer, Regierungsbaumeister Prof. Dr.-Ing. Uwe Menzel, Akad. Direktor Urban Drainage Water Quality Management and Water Supply Dr.-Ing. Ulrich Dittmer, Akad. Rat Dipl.-Ing. Ralf Minke, Akad. Oberrat Chair of Waste Management and Emissions o. Prof. Dr.-Ing. Martin Kranert Biological Air Purification Solid Waste Management Prof. Dr. rer. nat. Karl-Heinrich Engesser Dr.-Ing. Klaus Fischer Resource Management and Industrial Recycling Emissions Dipl.-Ing. Gerold Hafner Dr.-Ing. Martin Reiser, Akad. Oberrat Chair of Hydrochemistry and Hydrobiology o. Prof. Dr. rer. nat. habil Jörg W. Metzger Hydrochemistry and Analytical Quality Assurance Hydrobiology and Analysis of Organic Trace Compounds Dr.-Ing. Michael Koch Dr. rer. nat. Bertram Kuch, Akad. Rat Demonstration and Research Wastewater Treatment Plant Dipl.-Ing. Peter Maurer Administrative Office ISWA Dipl.-Ing. Stephan Mollweide, Akad. Oberrat www.iswa.uni-stuttgart.de 9 10 Chair of Sanitary Engineering and Water Recycling o. Prof. Dr.-Ing. Heidrun Steinmetz Wastewater Technology | AWT Dipl.-Ing. Carsten Meyer, Reg. Baumeister Industrial Water and Waste Water Technology Prof. Dr.-Ing. Uwe Menzel, Akad. Direktor IWT Urban Drainage SE Dr.-Ing. Ulrich Dittmer, Akad. Rat Water Quality Management and Water Supply Dipl.-Ing. Ralf Minke, Akad. Oberrat WGW 11 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Sanitary Engineering and Water Recycling Research The Chair of Sanitary Engineering and Water Recycling is engaged in a wide spectrum of activities both in the fields of fundamental and applied research. The activities also include consulting of state and municipal authorities, as well as, contract research on behalf of private, industrial, and public clients. The Chair’s four departments “Waste Water Technology”, “Industrial Water and Wastewater Technology”, “Urban Drainage” and “Water Quality Management and Water Supply” have individual core competencies. They cooperate closely in order to achieve the goals of modern sanitary engineering, that is achieving high levels of comfort in water supply and wastewater disposal and equally applying the best possible practice in terms of water protection, sustainable resources management and energy management. Being integrated in expertise networks, participating in standardization committees, trade associations and professional bodies, the Chair has many national and international contacts and collaborates as well with public as industrial research institutions both in Germany and abroad. The main focus of the activities in the department “Waste Water Technology” (AWT) is the optimization and development of methods for biological and advanced wastewater treatment in research and practice. Special emphasis is put on wastewater and nutrient recycling, anaerobic treatment, measurement, control, and regulation technologies, wastewater disinfection, and membrane and fixed-bed technologies. Aiming at contributing to the goal of sustainable water supply and wastewater disposal the department AWT investigates and tests future-oriented concepts and technologies to minimize emissions and energy consumption in wastewater treatment plants, to use alternative energy sources for wastewater treatment, and to recover valuable materials and nutrients from the material flows in wastewater treatment processes. Customized water reuse concepts are designed for worldwide application, and dimensioning principles are developed in order to use existing technologies in other climatic regions, e.g. in the tropics. A strong practical focus are also the offered non-committed performance evaluation of wastewater treatment plants, as well as, the evaluation of individual process steps, e.g. oxygen supply in aeration tanks. The department “Industrial Water and Wastewater Technology” (IWT) deals with all issues related to process and production-integrated environmental 12 protection, as well as, minimization of industrial emissions via internal recirculation and treatment of process wastewater, at regional and international levels. Due to a systematic approach and many years of experience, it is possible to provide customers from various industry branches with a wide range of solutions to improve their environmental and economical potential. In addition to internal and decentralized solutions, centralized solutions are developed through developing advanced purification procedures for the treatment of industrial wastewater in municipal treatment plants. Prior to this antecedent aerobic and anaerobic biological degradation tests were carried out. As an example, in the 90s the ISWA developed the AAF-method (Adsorption-Precipitation-FiltrationMethod) to eliminate reactive dyes, originating from the textile finishing industry, in municipal wastewater treatment plants. In light of the current discussions on the elimination of micro pollutants, the AFF-method has once again become a focal point and is currently being applied to different municipal wastewater treatment plants in order to eliminate micro pollutants by adsorption. Another prime focus is the treatment of landfill leachate by means of biological and physio-chemical processes. For example, customized modular processes are developed for the aftercare of landfills at reduced levels of leachate and pollutant concentrations, in which the use of activated carbon adsorption and membrane technology play an essential role. The separation of loaded activated carbon is an issue for other industrial branches as well as, for municipal wastewater treatment plants, who depend on the department for solutions. The department IWT also deals with the recycling of water and other valuable materials, as well as, the conservation of resources. For instance, the department offers experts’ assessments on the suitability of using industrial residues as an alternative fuel source in the cement industry, co-incineration of sewage sludge in cement plants or the production of bio-plastics from wastewater. Other focal points are on consulting clients from the catering and food industry, cosmetics and pharmaceutical industry, chemical industry as well as the metal and automotive industries. In an official testing laboratory neutral performance evaluations are carried out for plants that reduce hydrocarbons from wastewater containing mineral oil. The department “Urban Drainage” (SE) deals primarily with the description of runoff and sediment transport processes in urban drainage systems and waterways. Methodological focal points of the research are measurements of runoff volume and quality, the Chair of Sanitary Engineering and Water Recycling modeling of the rainfall-runoff process and the associated mass transfer. In the area of field measurements, online-sensors are combined with automatic samplers. Due to the high temporal resolution of the online measurements, the dynamics of the transport processes, especially during heavy rain, can be mapped. The analysis of parallel obtained samples provides the basis for the calibration of the sensors. In addition, the samples are used to measure concentrations of substances for which there are no online tools available. These are increasingly micro pollutants. In the area of simulations, ongoing research deals with the modeling of sediment transport in sewers. Here too, field measurements in real sewer systems form the basis. Other topics include the effects of climate change on rainfall-related emissions as well as the simulation of the heat balance in drainage systems. The latter shall provide the basis for an efficient heat recovery. The department “Water Quality Management and Water Supply” (WGW) works on researching and modeling the water quality status of flowing and stagnant waters. Special emphasis is put on the effect of water saving measures, measures related to the rainwater harvesting, as well as, on the influence of residual pollution loads from treated municipal and industrial wastewater and agricultural sources. Significant importance has the work related to preventive protection of drinking water resources such as the research of the input pathways of pesticides in surface waters, hazard analysis and risk assessment in drinking water protection areas, and the interaction of wastewater pretreatment processes and wastewater management practices in industry with the wastewater treatment processes at municipal wastewater treatment plants. The department has special expertise in modeling and simulating the behavior of industrial indirect discharge during the wastewater transport and co-treatment in municipal wastewater treatment plants. Further focus is the development of a process technology, ecologically and economically optimized water recycling and wastewater pre-treatment approaches in a variety of different industry branches such as textile finishing and paper industries. The department is very active in the area of transfer, adaptation and implementation of drinking water and wastewater treatment technologies in Southeast Asia (India, China and Vietnam). Another issue handled in the field of water supply is the subterranean treatment of groundwater for the removal of iron, manganese, arsenic and nitrification. The department also investigates the applica- tion of membrane technology, advanced oxidation and anaerobic-biological processes for the treatment of drinking water and process water for industrial purposes. In addition, the department deals with all problems related to transport, storage and distribution of drinking water, e.g. the hygienic problems that may arise as a result of long hydraulic residence time in the public water supply network. A particular focus is on increasing energy efficiency in all areas of water supply. Courses and Lectures Chair professors, research staff and lecturers supervise students in the following courses: • In the Bachelor-Program civil engineering the basic courses “Sanitary Engineering” and “Water Quality Management” are offered. In addition, the chair is instrumental in the course “Water Management”. In the Master-Program civil engineering the following core lectures are offered: “Water Treatment Processes”, “Design of Water Supply Facilities”, “Design of Wastewater and Sludge Treatment Plants”, as well as the complementary courses: “Urban Drainage and Wastewater Treatment Processes”, “Industrial Water Technology I”, “Industrial Water Technology II”, “Operation of Wastewater Treatment Plants”, “Planning and Design of Water Supply Facilities”, „Optimization and Recycling Potential in Wastewater Technology“, “Special Aspects of Water Supply”, “Simulation and Rehabilitation of Drainage Systems“, and “Special Aspects of Urban Water Management”. • In the Bachelor-Program environmental engineering the basic courses “Sanitary Engineering” and “Water Quality Management” are offered. In the Master-Program environmental engineering the following core lectures are offered: “Water Treatment Processes”, “Industrial Water Technology I”, “Industrial Water Technology II”, “Design of Water Supply Facilities”, “Design of Wastewater and Sludge Treatment Plants”, as well as the complementary courses: “Urban Drainage and Wastewater Treatment Processes“, “Operation of Wastewater Treatment Plants”, “Planning and Design of Water Supply Facilities”, “Optimization and Recycling Potential in Wastewater Technology“, “Special Aspects of Water Supply”, “Simulation and Rehabilitation of Drainage Systems“, and “Special Aspects of Urban Water Management”. • In the English-speaking foreign-oriented MasterProgram Water Resources Engineering and Management (WAREM) the following courses are 13 Institute for Sanitary Engineering, Water Quality and Solid Waste Management offered: “Wastewater Technology”,“Water Demand, Supply and Distribution”,“Design of Sewer Systems and Stormwater Treatment”, “Design of Wastewater Treatment Plants”, “Water Qualitiy Management”, “Water Treatment”, “Treatment of Industrial Waste Water”, “Case Study”, “Planning and Design of Water Supply Facilities”, “Scientific Seminar”, “Rainwater Harvesting and Management”, as well as parts of the module “Sanitary Engineering - Practical Class”. • In the English-speaking foreign-oriented MasterProgram Air Quality Control, Solid Waste and Waste Water Process Engineering (WASTE) the same core and optional lectures in all fields of municipal and industrial wastewater disposal and treatment as well as water quality and management are offered as in the Master-Program WAREM. • In the English-speaking Master-Program Infrastructure Planning the following courses are offered: “Water Demand Supply and Water Distribu- tion”, “Water Quality Management”, “Wastewater Technology”, and “Water Treatment” with lectures on municipal supply and disposal as well as water quality management. • In Curitiba / Brazil the Master-Program „MAUI“ (Meio Ambiente Urbano e Industrial - Municipal and industrial environmental protection introduced) was indroduced under German leadership and German standards in cooperation with the Universidade Federal do Paraná (UFPR) and the National Environmental Centre in the industry association FIEP (Federação the Industrias do Estado do Paraná) and its section for vocational training SENAI-PR (Serviço Nacional de Aprendizagem Industrial ) in Curitiba / Paraná. In this MasterProgram, Brazilian students are qualified in the scope of the German Program “Study Proposals by German Faculties Overseas”, sponsored by the German Academic Exchange Service (DAAD). The Master-Program was evaluated in March 2009 by the DAAD and awarded with the title „Excellent“ and called a „role model project“. Given the 2011 excursion with german and international students at several hydraulic structures and urban water management systems in Luxemburg and the Netherlands; here to be seen, the pilot plant at the Harnaschpolder wastewater treatment plant for the reuse of the effluent 14 Chair of Sanitary Engineering and Water Recycling academic excellence and positive feedback throughout Brazil, the DAAD decided to continue funding the project even after the end of the first financial support phase. As part of the program Education Export to lay a textbook series in Brazil an application for a financial increase has been approved. Furthermore, a project extension of two years has been applied for. During this period, the international accreditation as well as the realization of a double degree is to be realized. Furthermore, some lectures are offered for students of process engineering. The proposed lectures are completed by various excursions of one or more days. Beside the education of students from different programs of study, this chair is also integrated in a structured education of postgraduates. In the International Doctoral Program “Environment Water” (ENWAT) doctoral students are not only supervised during their research but are also prepare for their dissertation through obligatory participation in seminars, etc. and are in close technical exchange with other students and tutors of the program. By means of seminars and colloquia, a high number of events for continuing education are offered. These are preferably organized in co-operation with DWA, DVGW, and BWK. Other events to be emphasized are the periodic colloquia for Wastewater Treatment and Potable Water, the course for Water Sampling by order of The Ministry for Environment of Baden-Württemberg, the Stuttgart round of sewer rehabilitation and courses for training and continuing education for certified water treatment plant specialist and canal guards. In addition, training courses are available for companies. The chair’s international activities continuously increase in importance. Apart from the Master-Program “MAUI” other courses are offered internationally. A training course on landfill technology and landfill leachate treatment is offered in Brazil, for example. In addition, training courses for the operation of sewage treatment plants in the nonEuropean countries are offered, as well as „train the trainer“ programs. Finally, the supervision of study seminars, independent studies, bachelor and master theses as well as design works is an important aspect for the formation of junior researchers. The students are closely involved in working on current issues and ongoing research projects. 15 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Conferences - Seminars - Colloquia 5th German-Brazilian Symposium on Sustainable Development at the University of Stuttgart Sustainable environmental strategies were focused on the 5th German-Brazilian Symposium on Sustainable Development from July 18th to July 22th 2011 at the University of Stuttgart, completing the German-Brazilian Year of Science 2010/11. More than 230 participants from science, research and industry took part at the event, including more than half of Brazil. On the focus of the 5th German-Brazilian Symposium on Sustainable Development –Climate and Resource Protection- were current environmental issues, such as the use of renewable energies and the proceeding climate warming. The event was managed by the professors Jörg Metzger and Uwe Menzel from ISWA in cooperation with the Baden-Wuerttemberg Brazil Center of the University of Tuebingen and Baden-Württemberg International (bw-i). After welcoming speeches by Prof. Jörg Metzger (organizing team Germany) and Prof. Dieter Bredemeier (organizing team Brazil), Prof. Dr. Wolfram Ressel (Rector of the University of Stuttgart), Prof. Stefan Laufer (Rector of the Brazil Center at the University of Tübingen, Sueli Pavani (Brazilian Consulate General in Munich) and Assistant secretary of state Dr. Simone Schwanitz (Ministry of Science, Research and Arts of Baden-Wuerttemberg), Prof. João Steiner, an astrophysicist at the prestigious University of São Paulo (USP) and member of the Brazilian Academy of Sciences hold the opening lecture on excellent research in Brazil. The conference program touched a wide range of topics, ranging from issues of renewable energy, regional development and environmental technology on to water, wastewater, soil, waste up to the issues of climate and sustainable forest management and other priorities. Prof. Dr. Uwe Menzel and Daniel Neuffer from ISWA gave a lecture in the session „Bilateral Programs“ on the cooperation projects with Brazil over the past ten years. The session was completed by presentations from Wolfgang Wolf from the Environmental Engineering Platform of the National Association of Baden Wurttemberg Industry (LVI), Hartmut Reichl from the BW Ministry of Economics and Prof. Dr. Sergio Roberto Arruda from Senai, Florianopolis. Overall, more than 50 presentations and 100 posters presented recent research results on the main issues. During the conference there was also an industrial exhibition and a Project and Cooperation Forum with the participation of Baden-Württemberg International. This is designed to promote scientific exchanges and concrete projects, as well as merge donors, funding 16 institutions, universities and ministries. Sociologist Professor Ortwin Renn, Professor at the University of Stuttgart and Director of the Interdisciplinary Research Unit on Risk Governance and Sustainable Technology Development at the International Center for Cultural and Technological Research on sustainable development, gave the final lecture on interaction between environmental protection, economic prosperity and social justice. A variety of excursions to scientific interesting destinations in the region completed the bilateral event. The participants visited e.g. The Fraunhofer Institute for Interfacial Engineering and Biotechnology (IGB) in Reutlingen, which does research on the production of energy (biogas) from algal biomass, the in-plant process water and wastewater treatment plant of a brewery, the municipal wastewater treatment plant in Bönnigheim, which is designed for wine wastewater and the ultra-modern drinking water treatment plant of the Association of Lake-Constance-water supply. Excursion to WWTP Bönnigheim (viniculture wastewater) The positive response from participants at the final event demonstrated the success of the symposium as well as the great interest for environmental topics. The German-Brazilian Symposia take place in a two year rhythm, alternating between the two countries Germany and Brazil. Host of the next one, in 2013, will be the Universidad Federal do Oeste do Pará (UFOPA) in Santarém, Brazil. Chair of Sanitary Engineering and Water Recycling Closing event: Farewell of the parcipitants by Prof. Menzel. Financing Institution: Ministry of Science, Research and Arts BadenWürttemberg; International Bureau of the Federal Ministry of Education and Research (BMBF); German Research Association (DFG); Aggregation of friends of the University of Stuttgart German Academic Exchange Service (DAAD); et al. Contact: Prof. Dr.-Ing. U. Menzel (IWT) Prof. Dr. rer. nat. habil. J. W. Metzger (CH) Dr.-Ing. D. Neuffer (IWT) Dipl.-Ing. C. Stagl (IWT) Internet: http://www.uni-stuttgart.de/deutschbrasilianisches-symposium2011 http://www.uni-tuebingen.de//uni/bzc/ Project partner: Baden-Wuerttemberg Brazil Center of the University of Tuebingen; Baden-Württemberg International (bw-i) Colloquia 86. Siedlungswasserwirtschaftliches Kolloquium (2011): „Neue Verfahren und Betriebsstrategien in der Abwasserbehandlung“. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 208,Oldenbourg Industrieverlag GmbH, ISBN: 978-3-8356-3306-3, 13.10.2011. 2. Stuttgarter Runde - Expertenforum zur Kanalsanierung (2011): „Kanalsanierung - Werterhalt durch Wissensvorsprung“. http://www.stuttgarterrunde.de/index.html, 14.04.2011. 25. Trinkwasserkolloquium (2011): „Herausforderungen und Lösungen für die Wasserversorgung - Wettbewerb, Versorgungssicherheit, Innovation, Effizienzsteigerung“. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 206,Oldenbourg Industrieverlag GmbH, ISBN: 978-3-8356-3239-4, 24.02.2011. 85. Siedlungswasserwirtschaftliches Kolloquium (2010): „Regenwasserbehandlung in Abwasseranlagen - Prozesse und Lösungsansätze“. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 204,Oldenbourg Industrieverlag GmbH, ISBN: 978-3-8356-3208-0, 14.10.2010. 1. Stuttgarter Runde - Expertenforum zur Kanalsanierung (2010): „Kanalsanierung - Werterhalt durch Wissensvorsprung“. http://www.stuttgarterrunde.de/index.html, 15.04.2010. 24.Trinkwasserkolloquium (2010): „Grundwasser und Grundwasserleiter - Nutzungskonflikte und Lösungsansätze““. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 201,Oldenbourg Industrieverlag GmbH, ISBN: 978-3-8356-3203-5, 25.02.2010. 17 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Dissertation Fabio Chui Pressinotti (2010): Adaptation of trickling filter technology to hot climate regions. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 205 (196 S., 82 Abb., 22 Tab.), Oldenbourg Industrieverlag. Maurer, Peter (2011): Optimierungsstrategie für Belebungsbecken am Beispiel des LFKW der Universität Stuttgart. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag GmbH, München, Band 208, 125 -137, ISBN 978-3-8356-3306-3. Publications Menzel, U.; Neuffer, D. (2011): Bilateral Projects and a Master Program in Environmental Engineering in Brasil. Tagungsband des 5. Deutsch-Brasilianischen Symposiums, Universität Stuttgart, 18.-22.07.2011. 2011 Antakyali, D.; Kuch, B.; Preyl, V.; Steinmetz, H. (2011): Effect of Micropollutants in Wastewater on Recovered Struvite. Proceedings of the WEF Conference Nutrient Recovery and Management, Miami, USA, 9.-12.01.2011. Drenkova-Tuhtan, A.; Meyer, C.; Steinmetz, H. (2011): Einsatz der Nanotechnologie in der Abwasserreinigung. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag GmbH, München, Band 208, 55 - 79, ISBN 978-3-8356-3306-3. Guney, K. (2011): Phosphorus recovery as MAP-Struvite from digested sewage sludge. Chapter 17 in Sewage Sludge Management: From the Past to our Century, Nova Science Publishers, ISBN 978-1-61324-393-0. Locher, C.; Minke, R.; Steinmetz, H. (2011): Anaerobic treatment of concentrates originating from membrane filtration of wastewater from a Deinking-process and of raw wastewater from a Deinking-process. Conference proceedings of X Latin American Workshop and Symposium on Anaerobic Digestion (DAAL), Ouro Preto (Brasilien), 23.-27.10.2011. Locher, C.; Minke, R.; Steinmetz, H. (2011): Anaerobic treatment of concentrates originating from membrane filtration of wastewater from a TMP-process and a Deinking-process. Conference Proceedings of Water & Industry 2011 IWA Specialist Conference Chemical Industries, Valladolid. Mariakakis, I.; Bischoff, P.; Krampe, J.; Meyer, C.; Steinmetz, H. (2011): Effect of organic loading rate and solids retention time on microbial population during bio-hydrogen production by dark fermentation in large lab-scale. International Journal of Hydrogen Energy, 36, pp 10690-10700. Mariakakis, I.; Bischoff, P.; Krampe, J.; Meyer, C.; Steinmetz, H. (2011): Effect of Organic Loading Rate and Solids Retention Time on Microbial Population Dynamics during Bio-Hydrogen Production by Dark Fermentation. Presentation and proceedings on the IWA conference „Microbes in Wastewater and Waste Treatment, Bioremedation and Energy Production“. Goa, India, 24-26.01.2011. 18 Meyer, C.; Krauss, M.; Steinmetz, H. (2011): Simultaneous Drinking Water Winning and Treatment by In-Situ-Bioreactors University of Stuttgart. 5th European Water & Wastewater Management Conference – Proceedings (digital: http://www.aquaenviro.co.uk/ view-product/5th-European-Water-and-WastewaterManagement-Conference-Proceedings-), London, Great Britain, 25-26.09.2011 Meyer, C.; Preyl, V.; Steinmetz, H. (2011): Großtechnische In-situ-Phosphorrückgewinnung aus Klärschlämmen. Tagungsband zum 3. Internationalen Symposium „Re-Water Braunschweig“ Implementierung und Realisierung, Gesellschaft zur Förderung des Institutes für Siedlungswasserwirtschaft an der Technischen Universität Braunschweig e. V. (Hrsg.) Band 81, S. 45-58, ISSN 0934-9731. Neft, A.; Meyer, C.; Steinmetz, H. (2011): Phosphorfraktionen im Ablauf kommunaler Kläranlagen - Bedeutung im Hinblick auf die Umsetzung der WRRL. DWA (Hrsg.) Tagungsband zum Expertenforum Kläranlage - Phosphorelimination, Stuttgart, 25.11.2011, Abschnitt 3. Neft, A.; Nobis, R.; Minke, R.; Steinmetz, H. (2011): Evaluation of an applicable extraction method for the determination of bioavailable phosphorus. van Bochove E., Vanrolleghem P.A., Chambers P.A., Thériault G., Novotná B. und Burkart M.R. (Hrsg.) Issues and Solutions to Diffuse Pollution: Selected Papers from the 14th International Conference of the IWA Diffuse Pollution Specialist Group, DIPCON 2010. Online verfügbar unter: http://www.dipcon2010.org/DIPCON2010_ Issues_and_Solutions_to_Diffuse_Pollution.pdf. Neft, A.; Schmidt, S.; Meyer, C.; Steinmetz, H. (2011): Umsetzung der Wasserrahmenrichtlinie im Bearbeitungsgebiet Neckar: Eine neue Dimension der Phosphorelimination? DWA (Hrsg.) Tagungsband der DWA Landesverbandstagung Baden-Württemberg, Fellbach, 20.-21.10.2011, 43-60. Peña, K.; Bréthaut, Y.; Lampard, A.M.; Liew, A.; Parsand, R.; Biovin, P. (2011): Economic systems: to en- Chair of Sanitary Engineering and Water Recycling sure the energy neutrality of Wastewater Treatment Plants. Conference Proceeding, World Engineers Convention, Geneva, Switzerland, 4.-9.09.2011. tration Membrane Concentrates originating from the Pulp and Paper Industry. Conference Proceedings of 1st Wastewater Reuse Asia, S. 67-75. Peña, K; ; Steinmetz, H. (2011): Feasibility of using Bio-hydrogen and biogas as renewable energy sources in WWTP, through sludge in an AD process, Study case No1:pre-treatments. Conference Proceeding, 5th Germany Brazilian Symposium - Sustainable Development, Stuttgart, 18.-20.07.2011. Tews, S.; Minke, R.; Steinmetz, H. (2011): Membrane Filtration of Wastewater Split Flows originating from Paper Industry and Biological Wastewater Treatment of the generated Membrane Concentrates. GWF international 11/2011 (152), 70-77. Platz, S.; Menzel, U.; Schaub, M.; Amrehn, J. (2011): Adaption of a German MBT Process to the Boundary Conditions of Newly Industrialized Countries - Results of a pilot plant operated in Thailand. Waste-to-Resource 2011, 4. Internationale Tagung - MBA und Sortieranlagen, Tagungsband, ISBN 978-3-86955-747-2, Cuvellier Verlag, 05/2011, Seite 328-343. Yilmazel, Y.D.; Morgenschweis, Ch.; Mutlu, A. G.; Antakyali, D.; Steinmetz, H.; Demirer, D.N. (2011): Phosphorous Recovery Potential in Anaerobic Digestion Residues. Proceedings of the WEF Conference Nutrient Recovery and Management, Miami, USA, 9 – 12.01.2011. Platz, S.; Menzel, U.; Steinmetz, H.; Wett, M. (2011): Abtrennung von Pulveraktivkohle - Gegenüberstellung geeigneter Verfahren. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag GmbH, München, Band 208, 81 - 111, 978-383563306-3. Platz, S.; Schaub, M.; Menzel, U. (2011): Development of an efficient and robust MBT process suitable for newly industrialized countries – First results of a pilot plant operated in Thailand. Proceedings of the International Conference on Solid Waste 2011- Moving Towards Sustainable Resource Management, Hong Kong SAR, P.R. China, 2. - 6.05.2011. Steinmetz, H. (2011): Neuartige Sanitärsysteme. Proceedings of the wat + Wasser Berlin, Fachkongress der Wasserwirtschaft, CD. Steinmetz, H. (2011): Neuartige Sanitärsysteme. UmweltMagazin, April – Mai 2011. Tews, S.; Fechner, I. (2011): Regenwasserbehandlung in Abwasseranlagen - Prozesse und Lösungsansätze / 85. Siedlungswasserwirtschaftliches Kolloquium in Stuttgart. KA - Korrespondenz Abwasser - Abfall 10/2011 (58), 910 - 913, ISSN 1866-0029. Tews, S.; Minke, R.; Steinmetz, H. (2011): Behandlung von TMP- Abwasserkonzentraten aus der Papierindustrie mittels anaerob- und aerob-biologischen sowie oxidativ-chemischen Prozessen. Tagungsband, Industrietage Wassertechnik, Frankfurt am Main, S. 94-102. Tews, S.; Minke, R.; Steinmetz, H. (2011): Biological Wastewater Treatment of Ultrafiltration- and Nanofil- 19 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 2010 Dittmer, U.; Gutjahr, N. (2010): Beschreibung des Transportes von Spurenstoffen anhand indirekter Messungen. Oldenbourg Industrieverlag, Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 204, S. 91 – 113, ISBN 978-3-8356-3208-0. Fechner, I.; Launay, M. (2010): Kanalsanierung - Werterhalt durch Wissensvorsprung. Bericht zur 1. Stuttgarter Runde, Wasserwirtschaft, 7-8/2010, S. 62-63. Guney, K.; Minke, R.; Steinmetz, H. (2010): Investigating water reuse potential of bleaching-washing process. Proceedings of the IWA Regional Conference and Exhibition on Membrane Technology and Water Reuse, Istanbul Turkey, 244-250. Guney, K.; Minke, R.; Steinmetz, H. (2010): Water reuse potential of dye-wash process: in Turkey and in Germany. Proceedings of the IWA Regional Conference and Exhibition on Membrane Technology and Water Reuse, Istanbul Turkey, 251-258. Krauss, M. (2010): In-situ-Verfahren zur Grundwasseraufbereitung - Arsenelimination. Stuttgarter Berichte zur Siedlungswasserwirtschaft. Von der Ressource bis zum Lebensmittel höchster Qualität / 23. Trinkwasserkolloquium am 12.02.2009. Band 196, S. 61-76, ISBN 978-3-8356-3174-8. Krauss, M.; Meyer, C.; Rott, U.; Steinmetz, H. (2010): Sustainable In-situ Treatment of Groundwater containing Arsenic, Iron and/or Manganese. Proceedings of the IVth World Aqua Congress, New Delhi, India, Vol. I, 199 – 203. Locher, Ch.; Meyer, C.; Steinmetz, H. (2010): Operational experiences with a molten carbonate fuel cell at Stuttgart-Möhringen wastewater treatment plant. Proceedings of the 1st IWA Austrian Young Water Professionals Conference, Vienna, IWA-4186, USB Flash Drive. Locher, Ch.; Minke, R.; Steinmetz, H. (2010): Anaerobic treatment of retentates from membrane treatment of paper industry wastewater. Conference Proceedings of the 1st International Conference on Anaerobic Digestion of Waste and Wastewater, Anaerobic Digestion Asia 2010, Bangkok, 88-98. Locher, Ch.; Tews, S.; Minke, R.; Steinmetz, H. (2010): Biologische Behandlung von Konzentraten aus der Membranbehandlung prozessnah erfasster Abwasserteilströme aus der Papierindustrie. Wasser und Abfall (9), 10-17. 20 Mariakakis, I.; Krampe, J.; Steinmetz, H. (2010): Effect of pH control and substrate concentration on the hydrogen yield from fermentative hydrogen production. Proceedings of the IWA 12th World Congress on Anaerobic Digestion, Mexico, 11/2010. Mariakakis, I.; Mouarkech, K.; Krampe, J.; Steinmetz, H. (2010): Determination of Suitable Substrates Originating from Wastewater Treatment Processes for Biological Hydrogen Production by Dark Fermentation at Various Process Conditions. Proceedings of the IWA Austrian National Young Water Professionals Conference, Vienna, IWA-4306. Meyer, C.; Steinmetz, H.; Preyl, V. (2010): Pilotanlage zur großtechnischen Phosphorrückgewinnung (MAP) aus Klärschlämmen von Kläranlagen mit simultaner Phosphat-Elimination mittels Eisensalzen. Tagungsband der 24. Karlsruher Flockungstage, Schriftenreihe SWW, Band 139, S. 163-174, ISBN 978-3-9813069-2-7. Minke, R.; Steinmetz, H. (2010): Anaerobic Pre-Treatment of Textile Wastewater. Proceedings of the IVth World Aqua Congress, New Delhi, India, Vol. II, 267 - 273. Morgenschweis, C.; Yılmazel, D.; Mutlu, G.; Antakyali, D.; Steinmetz, H.; Demirer, G. (2010): Modelling of Struvite Precipitation Experiments Conducted in Synthetic Solutions and Different Anaerobic Digester Effluents by Using the Geochemical Model PhreeqC. In proceedings of: International IWA Conference on Sustainable Solutions for Small Water and Wastewater Systems, Girona, Spain, 19.-22.04.2010. Neft, A.; Claus, M.B.; Schmidt, S.; Minke, R.; Steinmetz, H. (2010): Looking closer on phosphorus fractions in WWTP effluents: Implications on the optimisation of phosphorus removal. Proceedings of the 1st IWA Austrian Young Water Professionals Conference, Vienna, 09.-11.06.2010, IWA-4306. Neft, A.; Nobis, R.; Minke, R.; Steinmetz, H. (2010): Evaluation of an applicable extraction method for the determination of bioavailable phosphorus. Proceedings of the 14th International Conference IWA Diffuse Pollution Specialist Group Diffuse Pollution and Eutrophication, Québec City, 31-34, CD-ROM. Neuffer, D.; Menzel, U. (2010): Relevance of international cooperations - Example EDUBRAS /MAUI. Artikel in der Zeitung Waste News, Ausgabe Nr. 6, Seite 5. Platz, S.; Menzel, U. (2010): Waste to Power - Klimaschutz mittels mechanisch-biologischer Abfallbehandlung in Thailand. Artikel in der Zeitung Umweltschutztechnik, Ausgabe Nr. 8, Seite 11. Chair of Sanitary Engineering and Water Recycling Contact Steinmetz, H. (2010): Sanitary Systems of the Future – from Disposal to Recovery. Proceedings of “54. Betontage”, Neu-Ulm, 09.-11.02.2010. Steinmetz, H.; Dittmer, U. (2010): Regenwasserbehandlung gestern, heute – und morgen? Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag GmbH, München, Band 204, 7- 14, ISBN 978-3-8356-3208-0. Steinmetz, H.; Pressinotti, F.; Krampe, J. (2010): Adaption of the Trickling Filter Process and Dimensioning to Hot Climates. Proceedings of the IVth World Aqua Congress, New Delhi, India, Vol. II, 392-404. Tews, S. (2010): Abwasserbewirtschaftung im Spannungsfeld politischer, klimatischer und technischer Entwicklungen, Bericht zum 84. Siedlungswasserwirtschaftliches Kolloquium. gwf- Wasser/Abwasser Jahrgang 151(3/2010), S. 308-311. Tews, S. (2010): Abwasserbewirtschaftung im Spannungsfeld politischer, klimatischer und technischer Entwicklungen , Bericht zum 84. Siedlungswasserwirtschaftliches Kolloquium. KA - Korrespondenz Abwasser - Abfall Jahrgang 57(8/2010), S. 740 - 743. Zhang, Q.; Krauß, M.; Neft, A.; Kuch, B.; Minke, R.; Steinmetz, H. (2010): Assessment of River Water Quality in a Watershed Affected by Large-scale Rubber Plantations-Pesticides and other organic trace substances. Proceedings of the 14th International Conference IWA, Diffuse Pollution Specialist Group Diffuse Pollution and Eutrophication, Québec City,12.17.09.2010, 166, CD-Rom. o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: +49 (0)711/685-63723 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Secretary´s office Gabriele Glaßmann Tel.: +49 (0)711/685-63711 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Dörte Hahn Tel.: +49 (0)711/685-63721 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Wastewater Technology Dipl.-Ing. Carsten Meyer, Reg.Baumeister Tel.: +49 (0)711 / 685-63754 Fax: +49 (0)711 / 685-63729 E-Mail: [email protected] Industrial Water and Wastewater Technology Prof. Dr.-Ing. Uwe Menzel, Akad. Direktor Professor coláborador (Universidade Blumenau) Tel.: +49 (0)711/685-65417 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Urban Drainage Dr.-Ing. Ulrich Dittmer, Akad. Rat Tel.: +49 (0)711 / 685-65420 Fax: +49 (0)711 / 685-67637 E-Mail: [email protected] Water Quality Management and Water Supply Dipl.-Ing. Ralf Minke, Akad. Oberrat Tel.: +49 (0)711/685-65423 Fax: +49 (0)711/685-63729 E-Mail: [email protected] 21 Chair of Sanitary Engineering and Water Recycling Wastewater Technology Fields of research and practice: • Nutrient recycling and wastewater reuse • Optimisation of phosphorus removal • Removal of persistent organic micropollutants • Biological hydrogen production • Nanotechnology for wastewater treatment • Fixed-bed processes for biological wastewater treatment • Wastewater disinfection • Use of fuel cell technology in wastewater treatment plants • Process and plant optimisation • Membrane processes for wastewater treatment • Treatment of process water from sludge treatment • Decentralised wastewater treatment • Concepts for material flow-oriented and resource-economical urban water management • Practical testing of small wastewater treatment systems according to EN 12566-3, certified by the German Institute for Building Technology (DIBt) • Clean water oxygen transfer tests The department „Wastewater Technology” teaches, researches and advises on the various areas of municipal wastewater treatment Our main activities are the academic training of students in sanitary and environmental engineering, the research on current issues in wastewater technology, the training of personnel for treatment plants/sewerage networks and the provision of independent advice to WWTP operators and engineers in all aspects of WWTP operation and planning. The aim of our training, research and consultancy work is to achieve sustainable water resources protection with respect to economic considerations. Our department contributed to significant developments in the field of wastewater treatment in Germany. For example, in 1982, the first experiments on the separation of activated sludge by membranes took place at ISWA. In current research projects, we are dealing with innovative wastewater treatment processes, such as the targeted use of membrane technology for the retention of pathogens and organic trace substances, and the application potential of nanotechnology in wastewater treatment. Besides improvement of the treatment efficiency of sewage treatment plants, we develop and test strategies for the future use of energy and valuable material from wastewater and sewage sludge. Approaches to the closure of energy and material flow cycles are both the subject of basic research and applied research. Current research topics include the production of secondary fuels such as hydrogen from wastewater and the recovery of valuable materials such as the nutrients nitrogen and phosphorus from sewage sludge and wastewater. But we also deal with problems related to the daily wastewater practice, such as the effects of extraneous water on the sewage treatment plant or the optimisation of phosphorus removal. We offer concepts and solutions. 22 Wastewater Technology AWT In addition, our department runs a certified test field for the testing of small wastewater treatment systems according to EN 12566-3. We also carry out basic and advanced training for domestic and foreign wastewater professionals. The potential of the continuously improving technical level of foreign treatment plants can only be optimally utilised by qualified personnel. Also, this training is of great importance for the development of new markets for German companies. 23 Chair of Sanitary Engineering and Water Recycling AQUA-Study Award Dipl.-Ing. Asya Drenkova-Tuhtan, M.Sc., from Bulgaria graduated from the master program Water Resources Engineering and Management (WAREM) and is now a researcher at the Chair of Sanitary Engineering and Water Recycling. She has been awarded with the AQUA-Study Award 2011 from the Foundation AQUA of the Faculty of Civil- and Environmental Engineering of the University of Stuttgart. The AQUA Foundation annually awards a prize to a student of the water-related subjects at the Faculty of Civil- and Environmental Engineering at the University of Stuttgart. The award recognizes outstanding academic achievement, meaning excellent diploma, master and doctoral theses, as well as student commitment. The AQUA-Study Award 2011 was awarded to Ms. Asya Drenkova-Tuhtan in recognition of her outstanding academic achievements and her master thesis „Application of Zero-Valent Iron Nanoparticles in Wastewater Treatment“. At a high scientific level and with great commitment, she has made an innovative contribution to the municipal wastewater treatment. With the aim to investigate the applications of zerovalent nano-iron as a sorbent and a reducing agent in the municipal wastewater treatment, laboratory tests have been conducted to determine to what extent poorly biodegradable pollutants in wastewater can be converted or eliminated by nZVI (nanoscale zerovalent iron). For the examined pollutants the conventional wastewater treatment shows no or nearly no effect. Furthermore, the suitability of the iron nanoparticles as an alternative to eliminate phosphate was investigated. The kinetics and other parameters were determined until optimal conditions and a phosphate elimination of> 95% were achieved. Three different commercial nZVI products were analyzed and compared. In addition, the potential of nZVI for the elimination of 9 frequent micropollutants in the domestic wastewater at different pH values was investigated as well as, the efficiency of nZVI to bind some selected heavy metals. The achieved elimination rate was very high (> 90%), particularly for heavy metals and some organic micropollutants. Furthermore, the separation of the nanoparticles by means of sedimentation, filtration, and magnetic separation was investigated. 24 The AQUA - Study Award 2010 was awarded to Karen Mouarkech, from Lebanon and a graduate of the master program Air Quality Control, Solid Waste and Waste Water Process Engineering (WASTE), in recognition of her outstanding academic achievements and her master thesis „Determination of suitable substrates originating from wastewater treatment processes for biological hydrogen production by dark fermentation at various process conditions.“ With a high degree of initiative and systematic work, she has mastered the complex issue that requires both a broad basic knowledge and a deeper understanding of anaerobic treatment processes. Abstract of the Master Thesis: Hydrogen fuel is an environmentally friendly gas. The production of hydrogen from substances derived from wastewater treatment is therefore a sustainable process. Therefore, various substrates (primary sludge, secondary sludge, wastewater from the sugar production, wastewater from the beer production) were examined with regard to the possible production of hydrogen. Experiments with primary and secondary sludge were done in a 4-liter experimental reactor at a temperature of 35°C, at different pH values, and different „Food to Microorganism Ratios“ (F: M). This way methane was produced. The sludge was pretreated by heating and acidification which inhibited the methanogenesis and a minimal amount of hydrogen could be produced. In general, it was found that an acidic medium is required for the highest hydrogen production. With wastewater from the sugar production the highest hydrogen production was achieved. Further investigations will be carried out. In 2010 and 2011, two students were awarded. Wastewater Technology AWT Research Development of the Material Flow Management model in order to achieve sustainable Material Flow Management (MFM) was established as a policy tool after the UN conference in Rio de Janeiro. Soon afterwards the MFM methodology was defined by the German parliament as “targeted, responsible, integrated and efficient influence on material systems whereas the target accrued from environmental and economical fields under consideration of social aspects” (Enquete Kommission, 1994). MFM combines holistic and systemic thinking while aiming on optimizing material and energy streams in a defined system in order to achieve Circular Economy. This research project has an aim to develop a MFM model in order to achieve sustainable wastewater treatment for Serbia. For the purpose of the research project two cities, namely the city of Krusevac and the city of Cacak, have been chosen as show cases for the MFM model development. The three-year research project is intended to serve as a base for further scientific research and better assimilation of the MFM and its tool Material Flow Analysis in the water management sector by providing the practical guidelines how to implement Integrated Water Resource Management on the regional level. Financing Institution: Bundesministerium (BMBF) für Bildung und Forschung Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Biol. J. Ćosić, M.Sc., M.Eng. Duration: 04/2011 - 03/2014 Wastewater is carrier of significant amount of material (e.g. nutrients) and energy (e.g. heat) flows which can be re-used and in that way may reduce ecological backpacks of different production processes. The MFM model will take into consideration possibilities of wastewater re-use as well as nutrients and energy recovery and their subsequent re-use in industry/ agriculture. In order to estimate additional potentials of generating regional added value (such as energy), biodegradable municipal solid waste flows will be considered as an additional flow. Consequently, technologies for the energy recovery (e.g. biogas technology) will be taken into consideration for the model development. Moreover, the model will suggest the selection of the sustainable, energy efficient wastewater treatment technologies applicable for the two selected cities and the entire country. For the model development, rural and urban settlements will be considered, and the best suitable centralized and decentralized solutions are going to be analyzed and selected. The outcomes of the research project are meant to assist researchers, decision makers and managers in infrastructural wastewater projects through the implementation of the MFM concept. The model is intended to serve as a ‚‘best practice‘‘ approach for a sustainable wastewater management of the city of Krusevac and the city of Cacak. Additionally the model should be replicable in the entire country and further on to a transition and developing countries facing similar problems in wastewater management like Serbia. 25 Chair of Sanitary Engineering and Water Recycling Development of functionalized micro-particles for the recovery of valuable substances from waste water streams (BioSuPaWert) Current trends show that the resources for some industrially important raw materials are depleting rapidly. Hence, the recovery and recycling of these valuable materials is essential and will gain even greater importance in the future. Therefore, in the present it is necessary to establish the fundamentals of a method for the efficient recovery of valuable substances, which can later on be of significant use to compensate for the global depletion of resources and meet the future demand. In that sense a higher priority will have methods which are able to recover a variety of different valuable substances by undergoing only slight modifications. The method to be developed in this project involves recovery of dissolved substances from liquid systems with the help of magnetic separation. The recovery of phosphate as a lead compound, irreplaceable nutrient and scarce, finite resource will be performed as a particular example within this project. The goal is to establish a basis for an environmentally friendly method, which will be applicable for the recovery of phosphate from liquid media, even at low concentrations, and will allow its further reuse. Well suited for that purpose are custom-designed modified small particles with functionalized properties which bind phosphate and can be separated from the dispersion under a magnetic field. After separation of the phosphate-loaded particles, the phosphate fraction will be extracted in the form of a concentrated solution which can be further reused as a valuable material. Due to the stability of the functionalized particles they can be recovered and reintroduced into the process. Another task in this project is to define other potential target substances which can be recovered in a similar fashion. For that purpose the functionalization of the particles has to be adapted accordingly. The final goal is to develop a method, which will become a basis for the recovery of valuable substances with a relatively broad spectrum of application. 26 Financing Institution: Baden-Württemberg Stiftung gGmbH Contact: Prof. Dr.-Ing. H. Steinmetz, Prof. Dr. rer. nat. habil. J. W. Metzger Dipl.-Ing. RBM C. Meyer, Dr. rer. nat. B. Kuch Dipl.-Ing. A. Drenkova-Tuhtan, M.Sc. Project partner: Fraunhofer-Institut für Silicatforschung (ISC), Außenstelle Bronnbach Institut für Arbeitswissenschaft und Technologiemanagement (IAT), Universität Stuttgart; Duration: 01/2011 - 03/2013 Wastewater Technology AWT Combined energy and nutrients recovery from black water and urine and ist potential integration in Lebanon Feasibility of using bio-hydrogen and biogas as renewable energy source in WWTP, through sludge in an anaerobic digestion process Sustainability offers challenges for developing different concepts for treating wastewater. Unlike the conventional wastewater systems which focus on the end of pipe technology, innovative ecological sanitation aims at resources recovery. These sanitation concepts aim at the separation of household wastewaters into separate flows with different loads. These are mainly divided into black water originating from toilets and grey water resulting from other water uses. Designing the proper concept has to consider different aspects; environmental, technical, social and economical. A Wastewater Treatment Plant (WWTP) is an essential public service, but, at the same time, it consumes a large amount of energy. However, there is excellent conservation potential through the use of biogas in-situ. To increase the conservation potential, the use of pretreatment provides a brand new focus to anaerobic digestion (AD) and its by-product (sludge). In Lebanon, water quality is getting deteriorated due to the presence of old sewers with a 60% national coverage and due to the presence of septic tanks, mostly without a bottom sealing and contributing to groundwater pollution. The challenge of introducing innovative ideas within rural and developing areas offers potentials in resources recovery and reduces the depletion of natural resources in Lebanon. Limited research has been investigated in the recovery of resources (nutrients and energy) from black water. This research concept has several objectives. The first objective is the recovery of renewable energy (biogas) from high concentrated black water originating from toilets. The second objective is the combined recovery of Magnesium Ammonium Phosphate (MAP), a fertilizer substance, from digested black water and urinals. The final aim is the assessment of the concept integration and the end products applicability in Lebanon. Financing Institution: International Postgraduate Studies in Water Technologies (IPSWaT-BMBF) Stipendium und Eigenmittel Contact: Prof. Dr.-Ing. H. Steinmetz, M.Sc. Karen Mouarkech Duration: 10/2010 - 10/2013 The aim of the three-year research is to study the feasibility of using biowaste to produce renewable energy (bio-H2), thru a two-stage anaerobic digestion (AD) process. The results of this study will be used to justify the energy neutrality of anaerobic digesters when applying the Best Available Technology (BAT) for the use of these renewable energy sources at a WWTP in developing countries. This project has the potential to apply as a Clean Developing Mechanism (CDM) or as Nationally Appropriate Mitigation Action (NAMAS) project. Therefore 3 study cases have been selected. The aim of this study case no. 1 is to select the most suitable pre-treatment for increasing the amount of H2 in a two-stage AD. Several pre-treatments have been identified such as temperature shock or chemical addition. If the pre-treatment increases hydrogen production at least 20%, we could ensure the energy neutrality of WWTP by implementing processes that consume a limited amount of energy (electricity) from the grid and maximise the in-situ energy production, particularly from biomass. Nevertheless, there are several challenges to overcome, such as understanding the metabolic pathway from the time of pre-treatment to the production of hydrogen, the cost and mass production of certain pre-treatments, and how to integrate open energy systems and major energyenvironmental requirements, if H2 production can be stabilized, in order to adapt to the diverse and intermittent renewable energy sources. Of interest, each cubic meter of biogas produced without pre-treatment contains the equivalent of 7-9 kWh of calorific energy, if the composition of CH4 lies between 60-80% of the total biogas composition. With pre-treatment, studies indicate the production of calorific energy will increase approximately two-fold because hydrogen has the highest energy content per unit weight of any known fuel (120.21 MJk/g), while CH4 is only 50.2 MJ/kg. This is of particular interest because there are additional socio-economic benefits to using H2 as a source of energy such as the reduction of green-house gas emissions and the creation of a viable alternative energy source. 27 Chair of Sanitary Engineering and Water Recycling Financing Institution: Internationales Klimaschutz-Stipendium der Alexander von Humboldt-Stiftung und Eigenmittel Contact: Prof. Dr.-Ing. H. Steinmetz, Kristy Peña Muñoz, M.Sc. Duration: 10/2010 - 10/2011 28 Large-scale Application of Phosphorus (Struvite) Recovery from Digested Municipal Sludge Phosphorus is almost exclusively recovered by exploitating geological deposits, leading to a reduction of mineral rocks and thus is contradictory to the understanding of sustainability. Therefore, alternatives to the production of phosphorus from phosphate ore have been investigated since some years. Considering the organic municipal wastes in Germany, it is obvious that the highest potential for recovery is in sewage sludge. The direct application of sewage sludge on agriculture is debatable, as the sludge is a sink for the organic and inorganic pollutants contained in the wastewater. The federal land Baden-Württemberg follows up the spreading of sewage sludge for agricultural application due to reasons of prevention and sustainable protection of soil and groundwater. In addition, research has shown that the phosphorus contained in the sludge is partially hardly available for plants, which results in debatable effeciency of fertilizer. At the Institute of sanitary engineering, water quality and solid waste management of the University of Stuttgart in cooperation with the IB iat-engineering consultancy, Stuttgart, the so-called „Stuttgart Process“ has been developed for phosphorus recovery from anaerobically stabilised sludge as magnesium ammonium phosphate (MAP, Struvite). The process is distinguished by the fact that municipal sewage sludge from wastewater treatment plants with simultaneous phosphate elimination with iron salts could be used without any changes in the process of wastewater purification (e.g. bio-P mode). The resulting product MAP can be applied, for example, directly as fertilizer in agriculture. The procedure has been developed in the years 2003 and 2004 and tested in laboratory scale. Based on these experiments, a semi-technical pilot plant (reactor volume approx. 1 m³) has been operated after the „Stuttgart Process“ for phosphorus recovery. It has been shown that the process can run in half technical scale with stable characteristics. The interest in the large-scale implementation of technologies for phosphorus recovery has increased in particular due to shortage of natural easily available phosphorous deposits and with the increasing phosphorus prices. For the technical implementation of the „Stuttgart Process“ one of the wastewater treatment plants of the association of treatment plants of the region Offenburg has been selected as the location of the pilot plant. The expansion capacity of the wastewater treatment plant is about 200,000 P.E., with about 160,000 connected P.E. The pilot plant is dimensioned by the plant designer in a way to treat a partial flow of sewage Wastewater Technology AWT sludge with an approximate equivelant of 5,00010,000 P.E. Iron salts are used as precipitants agents for the elimination of phosphorous in the wastewater treatment plant. The pilot plant is installed in a building which was formerly used for drying sewage sludge. The operation of the pilot plant is in batch system. A charge is about 10 m³ digested sludge as the starting basis for the further steps. The pilot plant consists of two batch tanks, a sedimentation tank and a chamber filter press as well as holding tanks and dosing equipment for the operational resources. In the batch tank 1 dissolution of sewage sludge is carried out. After the dissolution step, solid / liquid separation takes place. The dissolved digesting sludge is mixed with a stock solution of polymer and process water in the feeding line leading to the chamber filter press. The digested slurry filtrate from the chamber filter press is transfered to the batch tank 2. The complexation, the neutralisation and the MAP precipitation of digested slurry filtrate will be carried out in batch tank 2. After the MAP precipitation, the sewage sludge filtrate with the precipitates are transfered to the sedimentation tank. In the settling or crystallization tank close to the surface, the filtrate supernatant will be drained out and pumped from the bottom with an upflow current. Finally, a sedimentation step, in which a part of the disposed precipitates is retrieved and dried in a further step in the process. On the 18th of November 2011, the official commissioning of the MAP pilot plant was launched by the Minister of Environment, Franz Untersteller. Financing Institution: Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer Dipl.-Ing. V. Preyl Projekt partner: Abwasserzweckverband Raum Offenburg; iat - Ingenieurberatung für Abwassertechnik GmbH, Stuttgart Duration: 01/2010 - 05/2012 Schematic of the „Stuttgart Process“ for phosphorus recovery 29 Chair of Sanitary Engineering and Water Recycling Optimisation of inlet structures in final sedimentation tanks through scumboards with variable height In conventional final sedimentation tanks (FST), water and sludge mixture is fed in a constant height. The selection of the inlet height is very important, since high structures cause a stringer density flow and thus a hydraulic overloading of the tank, where low structures lead to a stir in the bottom sludge. Ideal case would be feeding the sludge directly into the water/sludge separation line, yet the line can move depending on the hydraulic state. This movement can be covered only by a construction with variable height. With this idea on mind, the project aims at investigations by means of a scumboard with variable height. Financing Institution: Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg Contact: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. RBM C. Meyer Dr.-Ing. J. Gasse, D. Antakyalı, M.Sc. Project partner: Abwasserzweckverband Ermstal, Metzingen; iat - Ingenieurberatung für Abwassertechnik GmbH, Stuttgart; Fa. Gröpler GmbH, Metzingen; hydrograv GmbH, Dresden Duration: 12/2009 - 04/2012 WWTP Metzingen was selected as pilot plant for this project. There are two identical FST in the plant, and one of them was equipped with a variable scumboard. The other one remained without any change, to enable a comparison. Hydraulic load for both tanks was equal. Within the past investigation period, a measurement program mainly consisting of sludge index and sludge level in the FSTs, as well as total suspended solids in the effluent was conducted. Sludge level measurements presented a clear difference between two tanks, the one having the variable scumboard (FST 2) indicating lower sludge levels. Also the sight depth indicated a clear improvement in the FST 2. Suspended solids measurements did not produce meaningful results. This can be explained by very low suspended solid levels in the effluent, in fact close to the detection limit. A further way to determine the impact of the scumboard was the comparison of tanks in case of an overload. Through the past operational values, the absolute maximum hydraulic load for the tanks was known. During an overloading by 20% regarding the absolute maximum, the variable scumboard prevented the sludge outflow into the effluent for 90 minutes. Hence the experiment produced very clear and visible evidence on the positive impact of the variable scumboard. More comparable experiments are planned to strengthen the results. 30 Scumboard with variable height, installed in final sedimentation tank Wastewater Technology AWT A 2-stage concept for fermentative hydrogen and biogas production by means of an innovative gas treatment Worldwide, the energy demand is still predominantly supplied from fossil fuels. Increasing energy consumption, limited natural resources and global warming as a result of the excessive CO2 emission connected with the burning of fossil fuels require the development of alternative methods for energy production. Fuel cells that use hydrogen as fuel present a promising alternative for energy production. However, current methods for hydrogen production are still quite energy-consuming. For this reason, biological production of hydrogen is investigated as a possible alternative. Anaerobic sludge digestion presents an efficient and cost-effective process for the production of hydrogen, as the largest part of the equipment required is already available in wastewater treatment plants and as the energy needed for the process is constantly delivered in the form of carbon compounds in the inflow of the treatment plant. During anaerobic sludge digestion, hydrogen is produced as an intermediate product, which is subsequently converted to methane in the methanogenic phase. By choosing suitable boundary conditions (such as ph value, partial pressure of hydrogen, nutrient supply, retention time in the reactor, organic loading rate, inhibition of methanogenic bacteria) it seems to be possible to increase the hydrogen content in the produced biogas considerably. By enrichment with the help of gas separation by means of innovative ion exchangers, hydrogen might be separated and used for an almost emission-free energy production with fuel cells. In lab-scale tests, the optimum conditions for hydrogen production will be determined. Major aim is the maximisation of gas yield and hydrogen content. Several different types of sewage sludge and industrial wastewater shall be tested for their suitability as regards hydrogen production. The possibility of co-fermentation of biological waste will be investigated as well. Subsequently, long-term experiments will be carried out, using the promising parameter values determined before in order to assess the stability of the process. Special attention is paid to the stabilisation of sludge in order to facilitate subsequent disposal. For this reason, a two-stage digestion process will be tested, which should yield stabilised sewage sludge as end product as well as a considerably higher amounts of energy in the form of hydrogen and methane. The possibility of biopolymer production in form of PHA (polyhydroxyalkanoates) by the utilization of the end products of the incomplete substrate fermentation during biohydrogen production should also be investigated. Financing Institution: Bundesministerium (BMBF) für Bildung und Forschung Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer I. Mariakakis, M.Sc. Project partner: Institut für Feuerungs- und Kraftwerkstechnik (IFK), Universität Stuttgart; EnBW AG; Purolite Deutschland GmbH; RBS wave GmbH Duration: 03/2009 - 02/2012 Schematic of the test facility for fermentative hydrogen and biogas production 31 Chair of Sanitary Engineering and Water Recycling Completed Research Projects Phosphorus fractions in municipal wastewater treatment plants in the Neckar catchment The implementation of the Water Framework Directive (Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy) requires a reduction of nutrient emissions into surface waters. Despite the large nutrient removal efforts of the past, point sources still contribute significantly to the total nutrient emissions into surface waters. For reaching the good ecological state in river Neckar, ambitious target values for total phosphorus (TP) in the effluent of municipal wastewater treatment plants (WWTPs) were introduced. These ambitious target values for TP require a detailed consideration of phosphorus fractions in the effluent, as the fractions significantly differ in terms of ecological and technical relevance. The following mass balance was introduced: So far, hardly any reliable data on the nominal concentration of DUP and PP in effluents of wastewater treatment plants were available. Within the project, data on effluent concentrations of DUP and PP were collected systematically and consistent for the first time (see figure). Only the concentrations of PP and DUP are displayed since the sum of PP and DUP provides insight into the amount of phosphorus which can not be further removal by the operator without extension of the treatment plant (in contrast to o-PO4-P). From the data displayed, it becomes evident that the composition of phosphorus fractions in wastewater treatment plant effluents varies significantly. For a relevant number of wastewater treatment plants in the Neckar catchment, for which the ambitious target values for TP were introduced, it will be impossible to meet these target values without extension of the plants. Financing Institution: TP = o-PO4-P + DUP + PP o-PO4-P DUP PP orthophosphate phosphorus dissolved unreactive phosphorus particulate phosphorus Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer Dipl.-Ing. A. Neft Duration: 01/2011 - 06/2011 PP/DUP concentrations in the effluent of 20 municipal wastewater treatment plants 32 Wastewater Technology AWT Investigations on extended phosphorus removal for the WWTPs Ditzingen, Plieningen and Möhringen The implementation of the Water Framework Directive (Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy) requires a reduction of nutrient emissions into surface waters. Despite the large nutrient removal efforts of the past, point sources still contribute significantly to the total nutrient emissions into surface waters. For reaching the good ecological state in river Neckar, ambitious target values for total phosphorus (TP) in the effluent of municipal wastewater treatment plants (WWTPs) were introduced. From latest 2013 on, the wastewater treatment plants of SES have to achieve in annual mean phosphorus effluent concentrations of maximal 0.5 mg TP/L (WWTPs Ditzingen and Möhringen) and 0.3 mg TP/L (WWTP Plieningen), respectively. Based on the results of field measurements, an expert opinion was requested on • how the WWTPs can comply with the TP target values • which maximal TP concentration can be declared for random samples, as this is the relevant concentration for the effluent discharge fee The probability of compliance with any limit value for TP can be quantified transparently with these indices. The success of optimisation measures for phosphorus removal can be quickly evaluated by comparing the results for CIt(TPLV) for different optimisation measures. Since the probabilistic approach uses basically available data only, hardly any additional measurements are needed. Based on the field measurements, the maximal efficiency of the WWTPs was quantified as the following: Wastewater treatment plant TP concentration in random samples [mg P/L] TP concentration in annual mean [mg P/L] GKW Ditzingen KW Möhringen KW Plieningen 0,6 0,7 0,3 0,45 0,5 0,2 Table: Maximal efficiency for SES WWTPs without extension Generally, it is hardly possible for WWTPs to guarantee TP effluent concentrations lower than a limit value at any moment of time. Consequently, a probabilistic approach was developed within this project. The scientific basis for this approach is given by the mutual independence of o-PO4-P and ΔP (= TP - o-PO4-P). This independence given, online o-PO4-P data can be concatenated with a ΔP probability function for any temporal resolution desired. For each online o-PO4-P measurement or aggregation of online measurements, respectively, the probability of compliance with TP limit values can be calculated using this approach. Financing Institution: Eigenbetrieb Stadtentwässerung Stuttgart (SES) Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer Dipl.-Ing. A. Neft Dipl.-Ing. S. Schmidt Duration: 01/2010 - 06/2011 Two indices were defined to assess the probability of compliance: Probability Index PIt(TPLV): Target probability of compliance with a limit value (LV) for any temporal resolution Compliance Index CIt(TPLV): C I t (TPLV ) = O ∑o - P 4 - P measuremen ts with adequate probability o f compliance 4 - P measuremen ts in temporal resolution t O ∑o - P 33 Chair of Sanitary Engineering and Water Recycling Potential for abatement of phosphorus emission from municipal wastewater treatment plants into the surface waters of Neckar catchment The implementation of the Water Framework Directive (Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy) requires a reduction of nutrient emissions into surface waters. Despite the large nutrient removal efforts of the past, point sources still contribute significantly to the total nutrient emissions into surface waters. For reaching the good ecological state in river Neckar, regulatory target annual average values for o-PO4-P concentrations were set; 0.1 mg o-PO4-P/L for the lock-regulated part of the river Neckar and 0.2 mg o-PO4-P/L for all its tributaries. These annual average values require further phosphorus removal in wastewater treatment plants in the catchment. Basic questions in the project were: • To which extent can municipal wastewater treatment plants in the Neckar catchment contribute to reaching the good ecological status? • What are the costs for further reducing o-PO4-P emissions? • Which wastewater treatment plants can achieve o-PO4-P reduction for the least costs? Cost types included in cost calculation were expenditures for investment, staff, energy, chemicals and sludge disposal. The cost data support that abatement measures for large wastewater treatment plants are to be implemented primarily since specific costs are the lowest. Accounting for the relevant phosphorus loads in effluents of small and medium size wastewater treatment plants, it is conjecturable that these wastewater treatment plants will also have a share in emission abatement. In total, wastewater treatment plants in the Neckar catchment could further reduce their emissions by 460 t o-PO4-P/yr. The Ministry of the Environment, Climate Protection and the Energy Sector Baden-Württemberg has implemented the results of the project by introducing effluent phosphorus target values for wastewater treatment plants larger than 5,000 population equivalents, leading to a reduction of approximately 200 t o-PO4-P/yr. Financing Institution: Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer Dipl.-Ing. A. Neft Dipl.-Ing. M. Krauß Dipl.-Ing. M. Launay Duration: 11/2008 - 06/2009 ; in 2010/11 continuously updatet Mean specific costs for further o-PO4-P emission abatement for municipal wastewater treatment plants in the Neckar catchment; tPE: 10³ population equivalents 34 Wastewater Technology AWT Development of a mobile treatment plant for the biological purification of black water in camping vehicles and boats as well as the development of an inspection process and analysis of the treatment plant perfomance As object of support from the Federal Ministry of Economics and Technology, within the framework of the central innovation program financing medium size projects, a mobile mini-treatment plant for biological purification of faecal wastewater in recreational caravans and boats was developed. Through the development of an innovative biological wastewater treatment plant of appropriate size it should be possible to quit the introduction of chemical substances, as it is usually employed in sanitary facilities of recreational caravans and boats. In addition, the unpleasant task of emptying a sewage holding tank could be avoided. The faeces wastewater should be treated through the biological mini-treatment plant to a level that the plant effluent could be, with or without a buffer storage (eg. grey water tank), directly and safely discharged into the sewer system or for example, into a stream. The following are the main goals of the project work at the Institute for Sanitary Engineering, Water Quality and Waste Management at the University of Stuttgart as summarized below: • Overview of quality requirements and regulatory environmental conditions for the purification of domestic wastewater and the deduction of requirements for direct discharge of treated black water • Analysis of black water (material composition) in order to derive requirements for a biological treatment • Determining the treatment efficiency of the wastewater pre-treatment plant (Aqualizer) based on inflow and outflow analysis • Development of the downstream Aqualizer biological treatment stage for further treatment of black water • Investigation of the operational performance and of the treatment efficiency of the mini-treatment plant at different loads conditions. With the Aqualizer as a mobile stand-alone treatment, effluent concentrations could not meet the legal requirements for municipal wastewater treatment plants or small wastewater treatment plants. Based on the carried out experiments, it is recommended, when employing a mini-treatment plant in caravans or boats, to include a submerged membrane within the biological treatment process since it provides both structural advantages, as well as a better treatment efficiency for the removal of carbon and ammonium. With further optimization of the mini-treatment plant with a membrane-activated stage, the requirements for wastewater treatment plants of size class 1 or of small wastewater treatment plants (COD: 150 mg/L; AbwV; DIBt) could be largely achieved. Financing Institution: Bundesministerium für Wirtschaft und Technologie Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. RBM C. Meyer K. Mouarkech, M.Sc. Project partner: HRZ Reisemobile GmbH Duration: 08/2008 - 02/2011 Experimental setup 35 Chair of Sanitary Engineering and Water Recycling Development of a treatment process for nanofiltration and reverse osmosis concentrates from industrial waste waters The papermaking industry is one of the biggest water consumers in Germany and also in the world. Through recirculation, reuse and saving methods the consumption could be drastically reduced up to 10,4 l/kg produced paper (2007) in the last few decades. However, there remains a great potential in the closure of internal process water cycles and the associated possibility of saving fresh water. The elimination of suspended solids is already realized by the flotation process, filtration and sedimentation. Dissolved substances, which disturb the process of paper making, can not be eliminated through this procedure. Here the use of membrane technology can find application. This failed mainly because of the expensive disposal of the nanofiltration- and reverse osmosis concentrates. In this research project a treatment concept for the retentates was developed. The study examined various wastewater treatment processes in different sequences. In addition to aerobic and anaerobic treatment, oxidation methods like Ozonation and Fenton Process (Hydrogen peroxide & iron as a catalyst) were applied. The advantages of anaerobic treatment are little sludge production, no use of energy for aeration and the production of biogas which can be used for energy recovery, is one of the main processes. The aerobic purification process is required to reach the desired outflow values for the cleaned wastewater. Oxidative cleaning processes can eliminate resistant compounds on one hand. On the other hand the BOD5/COD-ratio can be increased through Ozonation or Fenton process. The main goal of the research project was to develop a suitable adaption of each process and to find out an appropriate order of each process to clean the retentates. Financing Institution: Willy-Hager Stiftung Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. R. Minke, AOR Dipl.-Ing. C. Locher Dipl.-Ing. S. Tews Duration: 07/2008 - 09/2011 Strategies for the subsequent processing of retentates from industrial wastewater treatment (paper industry) 36 Wastewater Technology AWT Independant Studies Investigations on nutrient recovery from anaerobic digestion residues with different compositions The aim of the project was to investigate the practicability of struvite precipitation to recover nutrients from digestion residues. The investigation mainly consisted of laboratory scale experiments and comparative using computer applications. The duration of the project was 24 months. The work was conducted by two institutions. Middle East Technical University operated laboratory scale batch anaerobic reactors for the digestion of poultry manure and wastewater treatment plant sludge mixtures in different ratios, and conducted struvite precipitation experiments in both solid and fluid phases of digestion residues. The University of Stuttgart conducted struvite precipitation experiments in synthesised digestion liquor in order to understand the system and determine the mechanisms. The resulting products were examined using microscope and X-ray diffraction techniques. Additionally, the concentrations of N, P, Mg and other significant metals were determined so that a mass balance could be prepared. Meanwhile, the results were transferred onto a chemical model together with the chemical data from the analyses of the partner institution to estimate the potential reactions in the investigated complex type of process waters. The modeling phase was followed by a short verification phase applying struvite formation on real digestion residues. The resulting products were also examined as mentioned above. Results allowed the determination of critical concentrations of metals which influence the struvite formation. The cooperation supported besides research engineers also 3 students for scientific research during the project. A close collaboration could be achieved by visits from both institutions, enabling an ambilateral exchange of experience. Optimization of the Anascreen process Michael Stapf (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Coupling free flow and flow in porous media Adimensional analysis Vinay Kumar (WAREM) (2011) Supervisor: Prof. R. Helmig, Prof. Steinmetz Biological hydrogen production; dominant bacterial population for various process conditions Ana Stavar (WASTE) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, I. Mariakakis, MSc. Nitrite peaks in the effluent of municipal WWTP give cause Thi Phuong Vu (WASTE) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. P. Maurer Challanges and potentials in blackwater treatment: An overview. Anita Ziegler (WASTE) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz Technological Solutions for Coping with Water Scarcity – Literature Review & Evaluation Kara McElhinney (2011) Supervisor: Dipl.-Ing. C. Meyer RBM Financing Institution: International Bureau of the Federal Ministry of Education and Research (BMBF) Contact: Prof. Dr.-Ing. H. Steinmetz, Prof. Dr.-Ing. G. Demirer, D. Antakyalı, M.Sc. Project partner: Ortadogu Teknik Universitesi, Ankara, Türkei Duration: 02/2008 - 01/2010 37 Chair of Sanitary Engineering and Water Recycling Theses (Diploma) Studies on the anaerobic biodegradability of membrane concentrates from the thermo-mechanical pulping in the paper industry Investigation in the decomposition of chlorine dioxide and the generation of chlorite in drinking water Christiane Ansorge (Umweltschutztechnik) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dr.-Ing. Xiaohu Dai Eva Christina Bollmann (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM (2010) Effect of powdered activated carbon on the microbiological activity in activated sludge Anne-Marie Harras (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM, Dipl.-Ing. P. Maurer The application of microstrainers for the separation of activated carbon from municipal waste water Tanja Jordan (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM, Dipl.-Ing. P. Maurer, Dr.-Ing. B. Kuch Optimisation of the procedural processes linked to phosphorus recovery from sewage sludge. Volker Preyl (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Nitrogen cycling in the permaculture landscape at the environmental technology centre at Murdoch University, Perth Sven Wildermuth (Umweltschutztechnik) (2010) Supervisor: Prof. Goen Ho Dr. Martin Anda (Murdoch University, Perth), Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Studies on the design and operation of fluidized bed process Xiaoting Zhou (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Further analysis to the EISENMANN FENTOX®method Vera Bäuerle (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM 38 Investigation of the applicability of external carbon sources for the increased nitrogen removal in the WWTP Mühlhausen, Stuttgart, and developing an assessment methodology for the selection of suitable products Jens Iglauer (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Magnesium Ammonium Phosphate (MAP) recovery from blackwater Klaus Lenz (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Development of a control plan of the subterranean groundwater treatment as a preliminary stage for the climatisation of buildings Katharina Merz (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Commissioning of a pilot scale membrane bioreactor for treating waste water from factories of metal surface treatment Matthias Schlagenhauf (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. C. Meyer RBM Investigation of return sludge strategies with the support of dynamic simulation in a semiindustrial wastewater treatment plant Alexander Steiner (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. P. Maurer Wastewater Technology AWT Redesign of mining and treatment procedures of process water for the Deutsche Elektronen Synchrotron Hamburg in Hamburg (DESY) with innovative and flexible combination of in-situ and on-site treatment Sarika Wahi (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Study of chorine demand of strongly acidic resigns as a basis for the design of chlorine cells für the disifection of softeners Roman Woclaw (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Theses (Master) Application of Nanoparticles in (WASTE)water Treatment Asya Drenkova (WAREM) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. C. Meyer RBM Development of a reactor design for vacuum UV irradiation ww. Jorge Mario Toro Santamaria (WASTE) (2011) Supervisor: Prof. Dr. Thomas Hirth, Prof. Dr.-Ing. H. Steinmetz Phosphorus recovery from sewage sludge - ecological, econmic and technical aspects Pengfie Wang (MIP) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz 39 Chair of Sanitary Engineering and Water Recycling Contact Dipl.-Ing. C. Meyer, Regierungsbaumeister Dipl.-Ing. Volker Preyl Tel.: +49 (0)711 / 685 - 63754 Fax: +49 (0)711 / 685 - 63729 E-Mail:[email protected] Tel.: +49 (0)711 / 685 - 63702 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Scientists Laboratory Demet Antakyalı, M.Sc. Tel.: +49 (0)711 / 685 - 63895 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Jovana Cosic, M.Sc., M. Eng. Tel.: +49 (0)711 / 685 - 63949 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Asya Drenkova-Tuhtan, M.Sc. Tel.: +49 (0)711 / 685 - 63720 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dr.-Ing. Juliane Gasse Tel.: +49 (0)711 / 685 - 65410 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Christian Locher Tel.: +49 (0)711 / 685 - 65422 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Iosif Mariakakis, M.Sc. Tel.: +49 (0)711 / 685 - 65405 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Karen Mouarkech, M.Sc. Tel.: +49 (0)711 / 685 - 63740 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Kristy Peña Muñoz, M.Sc. Tel.: +49 (0)711 / 685 - 65439 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] 40 Chief: Heidi Hüneborg Tel.: +49 (0)711 / 685 - 63728 E-Mail: [email protected] Chemical technical employee Harald Duvinage Bärbel Huber Harald Müller Meanwhile quittet: Dipl.-Ing. Sebastian Tews Industrial Water and Wastewater Technology IWT 41 Chair of Sanitary Engineering and Water Recycling Industrial Water and Wastewater Technology Research topics: • Process and production integrated environmental protection • Treatment and reuse of process water e.g. in the automobile industry • Adsorption processes in industrial water and wastewater technology, e.g. in the textile industry • Reduction of lipophilic substances in the food and cosmetics industries • Biological and chemo-physical treatment of industrial wastewater • Aerobic and anaerobic degradation tests • Testing Centre of the German Institute for Construction Technology (DIBt) • International Consulting andexport-oriented research for example Middle and South America • Implementation of international master courses It will all come out in the wash At the department IWT (Industrial Water and Wastewater Technology), we specialize in refining internal plant processes and aim at integrating environmental protection as well as minimizing the industrial emissions by implementing a water circulation and plant-internal treatment processes, also in international scale. We plan environmental moderations for customers in the industrial process as well as integrated solutions in the manufacturing process. The first step we take in order to make a current assessment of the situation at the plant is an on-site inventory survey. According to the survey we can then localize water consumption, wastewater amount and dirt load accruement points. In order to determine the dirt loads accumulated during the manu-facturing process, partial wastewater flows are sampled and the relevant parameters are then analyzed. After consulting with the respective company, the tap water quality required for the production process can be specified, in order to minimize fresh water consumption. This can be done by implementing a water circuit consisting of treated wastewater. Production related water consumption and wastewater volumes are then determined by precise recording of the productions figures. This subsequent changes in the production figures allow precise projections of the associated parameters. Based on the survey and the formulation of goals a customer-specified procedure for wastewater treatment can then be agreed upon, which normally leads to further in-depth tests, such as e.g. determination of biodegradability. Due to our systematic procedures and many years of experience we are able to represent our customers with new sustainable solution and potentials. 42 Industrial Water and Wastewater Technology IWT We emphasis mainly in offering our professional advice to clients from the textile finishing industry and paper industry, gastronomy- and food-industry, the cosmetic and pharmaceutical industry, the chemical as well as the metal and automobile industry. Alongside plant internal solutions we also create decentral as well as central solutions by developing extensive purification processes for the treatment of industrial wastewater at communal treatment plant. Therefore a series of aerobic and anaerobic biological degradation tests are carried out in advance. Further emphasis of ours is the treatment of leachate of landfills using biological and chemical-physical processes. For example we are developing adaptable modular processes for the aftercare operations of landfills at reduced leachate levels and toxic concentrations. Therefore the use of carbon adsorption processes and membrane processes play an essential role in our work. Here at the IWT department we also deal with topics such as water and waste recycling as well as saving resources. Exemplary is our expert’s assessment of industrial residues as alternative fuel in the cement industry as well as the sludge incineration in cement plants. for a further two-year extension of the project has already been lodged. By the end of this period, the international accreditation and the implementation of the double degree will have been realised. Under the direction of the Premier, Winfried Kretschmann, a delegation visit to Argentina and Brazil from 13th to 21th of November 2011 was carried out. Within the scope of this visit, a networking event was held in Curitiba on the 16th of November 2011, in order to address the topic of sustainability in the industry association FIEP. At this event the University of Stuttgart rector, Prof. Wolfram Ressel, and the EDUBRAS project manager, Prof. Menzel, presented the Master’s Degree Program to the widely diverse international audience and the media. In addition, Prof. Menzel visited the capital city Brasilia, as a member of the political delegation, where Mr. Kretschmann presented the bilateral projects and the ISWA’s Master’s Degree Program to the environmental minister, Texeira at the Ministery of Environment. Our department is an official control center of the “Deutsches Institut für Bautechnik (DIBt)” in Berlin which is responsible for controlling plants for the limitation of hydrocarbons in wastewater including mineral oils. Our department also offers its courses at different universities abroad, e.g. to Brazil and cooperates with Latin American facilities. Which enables such programs as the cooperation of the Universidade Federal do Parana (UFPR) and the national environmental protection industry Servico Nacional de Aprendizagen Industrial (SENAI/ PR) in Curitiba/ Brazil to create the new Masters program EDUBRASMAUI (communal and industrial environmental protection) under management of the IWT Department and under German standards. The master’s degree “EDUBRAS-MAUI – communal and industrial environmental protection” was evaluated by the DAAD in March 2009 and was thereby awarded the rating “excellent” and was described as being “a showpiece project of highest distinction”. Due to the standard of academic excellence and the positive reception in Brazil, the DAAD has decided to continue its support for the program after the first funding phase comes to an end. An application for additional funds within the framework of the export education program, in order to publish a series of textbooks in Brazil has already been approved and an application 43 Chair of Sanitary Engineering and Water Recycling Research MIKROFLOCK - Upgrading municipal sewage treatment plants with flocculation - filtration units by the use of activated carbon By addition of activated carbon, micropollutants can be reduced to a certain degree from the liquid phase at sewage plants. Herewith, the inert COD in the effluent of the sewage plant may be significantly reduced. Many of the larger sewage plants in Northrhine-Westfalia are equipped with final filtration units, which may be used for this purpose: the construction already exists, the filter inflow shows no or only less particulate matter and an emission of loaded activated carbon into the receiving water is reliably avoided. In this R+D-project different technological approaches shall be investigated on their technical, operational and economical realisation in full scale at existing filter units in Northrhine-Westfalia. At Buchenhofen STP the dosing of powder activated carbon (PAK) into the submerge of one filter chamber and at Düren-Merken STP a change of the existing filter material against granular activated carbon (GAK) will be investigated. In addition, the dosage of PAK into the effluent of the final settling tank with a technical carbon separation prior to the filtration unit will be tested in laboratory and/or pilot scale. A technical scale test of this approach is considered as an option for an on-going R+D-project. The investigations are completed by an assessment of different activated carbons prior to the testing. For constructional details two consultancies participate in the project. The results will be summarised in a praxis-orientated report. The report will also include an assessment for an implementation of the investigated approaches at other sewage plants with filtration units in Northrhine-Westfalia. Financing Institution: Ministerium für Klimaschutz, Umwelt, Landwirtschaft, Natur- und Verbraucherschutz des Landes Nordrhein-Westfalen Contact: Prof. Dr.-Ing. Uwe Menzel M.Sc. Dipl.-Ing. Sebastian Platz Project partner: SAG – Ingenieure, Ulm Joint research project partners: Wupperverband (WV) Institut für Siedlungswasserwirtschaft (ISA) der RWTH Aachen AVT Aachener Verfahrenstechnik WVER Wasserverband Eifel-Rur Emschergenossenschaft Lippe Verband Tuttahs & Meyer Ingenieurgesellschaft The official inspection office, responsible for carrying out practical tests at different plants to ensure the reduction of hydrocarbon in wastewater containing mineral oil As a result of Prof. Menzel being appointed part of the expert-committees - Abscheider und Mineralölhaltiges Abwasser -A-(428) - Mineralölhaltiges Abwasser –B 3-(428c) - Mineralölhaltiges Abwasser –B 4-(428d) by the “Deutsches Institut für Bautechnik (DIBt)” in Berlin, the Institute for Sanitary Engineering, Water Quality and Solid Waste Management at the University of Stuttgart (IWT department) was then appointed as the official inspection office. The department is responsible for carrying out practical tests at different plants to ensure the reduction of hydrocarbon in wastewater containing mineral oil. Financing Institution: Deutsches Institut für Bautechnik (DIBt), Berlin Contact: Prof. Dr.-Ing. Uwe Menzel Input of micropollutants into wastewater by pharmaceutical products 44 Industrial Water and Wastewater Technology IWT Resource and Energy Efficiency Network Santa Catarina (REEF Santa Catarina) One of the central tasks of the Environmental Centre in Santa Catarina, is the transference of know how and technology in the field of environmental protection with the goal of promoting the emergence of a market for environmental technology. The centre was set up as a result of the long-standing collaboration between the states of Santa Catarina and Baden-Württemberg and also through the leading support of both the University of Stuttgart and National Brazilian Service for Industrial Training (SENAI). The Environmental Centre Santa Catarina, alongside its educational programs, in the future plans to offer environmental consulting for industries in the region and is therefore very interested in the establishment of the network REEF Santa Catarina. Though such a network, the Environmental Centre hopes to win advantageous contacts to providers of environmental services and technologies from Germany, thus intensifying the transfer of new technologies and know-how. WEHRLE Umwelt is taking the first step to concretisation of this initiative by following the successful example of existing environmental networks in Germany and together with the University Stuttgart and the Environment Centre Santa Catarina setting up a network for resources and energy efficiency in Santa Catarina (REEF Santa Catarina). WEHRLE Umwelt has commissioned the renowned environmen- tal consultancy Argum, from Munich, to build up this environmental network. Over the last ten years Argum has been successful in implementing operational environmental networks in over 60 regions in Germany and this approach has already been successfully transferred to countries such as China and India. As a member of the National Industrial Association of Baden-Württemberg (LVI), WEHRLE Umwelt can make use of its contacts on the platform of environmental technology at the LVI and as necessary can further involve German companies in the transfer of technology and know-how. Financing Institution: DEG - Deutsche Investitions- und Entwicklungsgesellschaft Contact: Prof. Dr.-Ing. Uwe Menzel Project partner: Wehrle Umwelt GmbH, Emmendingen Arqum GmbH, München SENAI-SC Umweltzentrum des Industrieverbandes im Bundesstaat Santa Catarina Landesverband der baden-württembergischen Industrie (LVI) Duration: ab 09/2010 Industrial Wastewater treatment plant of a textile finishing company Malwee 45 Chair of Sanitary Engineering and Water Recycling Development of a mechanical-biological treatment process based on the BIOPERCOLAT®process in order to reduce the waste amount and to create refuse derived fuel For most of the developing countries and especially for many newly industrialized countries waste is getting more and more a serious problem for the environment and for the society. So far the most common way of waste disposal is to dump it into landfills. Usually these landfills are simple dumps without any sealing or coverings. Hence, leachate water cannot be collected and be treated with treatment plants as we know them from Europe or other developed countries. As a consequence the surrounding environment suffers severe impacts and damages. In a global scale this way of waste disposal heavily contributes to the global warming by emitting the greenhouse gases CO2 and Methane. In Europe the usage of landfills for the disposal of household waste is prohibited by law since 2005. The old landfills still need a long and expensive maintenance up to 50 years. Nowadays waste incineration plants, composting plants, recycling facilities and mechanicalbiological waste treatment (MBT) plants are state of the art. The big advantage of MBT plants is the low energy consumption for the operation, low emissions of greenhouse gases and a high energy recovery. Even the invest costs are relatively low, compared the waste incineration plants. Also the rate of return is very high, as MBT plant can produce valuable refuse derived fuel (RDF) and biogas. The biogas can be used to produce electrical energy and heat by using combined heat and power plant (CHP) or modern gas turbines. Pilot plant in Thailand 46 As boundary conditions differs from country to country and especially between developed and developing/ newly industrialized countries the in Germany well approved MBT technology cannot be used for waste of other countries one-to-one. One of the biggest differences in the waste composition is the higher organic as well as the higher water content. Beside that the climate and the weather can have a big influence on the performance. The University of Stuttgart, in cooperation with the German company WEHRLE Umwelt GmbH, Emmendingen is working on the development of a new MBT technology. This technology is based on a well approved German technology, which is positively fieldtested and successfully in use at the site Kahlenberg, Ringsheim for more then 5 years. The main task of the development is the adaption of the technology to other boundary conditions. Hence, the University of Stuttgart planed and installed a MBT pilot in central Thailand in the province Petchaburi. During the operation the suitability is going to be tested. The local Thai company Cemtech Co. Ltd. and the „King Mongkut‘s Institute of Technology Ladkrabang” (KMITL) are supporting the project. The advantages by using the planed MBTtechnology for the waste disposal are: • Very low impacts on the local and global environment (global warming) • Relatively low investment costs • High rate of return • Clean Development Mechanism (CDM) ->Selling of carbon credits • Low tipping fees for the population • Production of CO2-neutral and valuable RDF • Production of CO2-neutral biogas Industrial Water and Wastewater Technology IWT Extensive treatment processes for water and wastewater. Post-graduation-specializing course at the “FACULDADE DE TECNOLOGIA SENAI BLUMENAU”, the national environmental protection center of the industry (SENAI-SC) in Blumenau/Santa Catarina Brazil. The national environmental protection center of the industry (SENAI-SC) in Blumenau/ Santa Catarina offers a post-graduate-specializing course “Gerenciamento de Aquas e Efluentes”. RDF produced in Thailand Fnancing Institution: Umweltministerium Baden-Württemberg Contact: Prof. Dr.-Ing. Uwe Menzel M.Sc. Dipl.-Ing. Sebastian Platz Project partner: As part of these courses Prof. Menzel gives a series of lectures called “Advanced Treatment Technologies for Process-Water and Wastewater”. Contact: Prof. Dr.-Ing. U. Menzel Project partner: Nationales Umweltschutzzentrum der Industrie (SENAI) in Blumenau WEHRLE Umwelt GmbH, Emmendingen Development of a compact and efficient Wastewater Treatment System for the schoolboat SAMAÚMA II in the Amazon Development of a process to produce bioplastic on municipal wastewater treatment plants The ambition of this research project is to find an economic, effective process to pro-duce bioplastic out of waste water. The state of the art of the bioplastic production is the basic idea of this project. Wastewater as raw material for the bioplastic production has not been an object of research so far and offers the opportunity to transform the waste water treatment plant into a bioplastic factory. Today, plastic is made out of unlasting crude oil. So it is obvious, that the production of bioplastic includes some benefits and fits to the main idea of sustainability. Bioplastic, for example, enables preservation of resources, is compostable and biodegradable. Financing Institution: Willy Hager Stiftung Contact: Prof. Dr.-Ing. Uwe Menzel Dipl.-Ing. Timo Pittmann The aim of this project is to develop a Wastewater Treatment System for SAMAÚMA II, SENAI’s second school-boat. The project is based on the Memorandum of Understanding signed between SENAI and the University of Stuttgart, particularly its Department of Industrial Water Technology (IWT), Solid Waste, (SIA) and Hydrochemistry at the Institute of Sanitary Engineering, Water Quality and Management Solid Waste (ISWA), Germany, on December 19, 2008. In its endeavor to bring vocational education to every corner of Brazil, SENAI developed in 1980 a boat-school - the SAMAÚMA - adapted to the local transport conditions and the demands for technical and vocational education in the Amazon. The SAMAÚMA turned 30 in February this year, certifying throughout that period more than 40 000 students. SENAI’s boat-school has already arrived in 43 of 62 municipalities in the region, and also reaches municipalities in the states of Pará, Acre and Roraima. However, the technological advances which occurred in industry in this period and SENAI’s commitment to environmental sustainability have led the institution to revise its strategies and educational technologies. Within this context, and attentive to the particularities of the Amazon region, SENAI will launch a public bid for 47 Chair of Sanitary Engineering and Water Recycling the construction of its second fluvial mobile unit, named SAMAÚMA II, which will be an example of sustainable use of natural resources to be followed by local population. The boat-school will bring innovative technologies and practices, both in its physical infrastructure and educational environments and in its operation. In order to do this, the systems and equipment of the boat-school will be selected considering the requirements of sustainability, efficiency and applicability to local realities. SAMAÚMA II will be the first high performance technical and vocational education unit. Among these systems and equipment, SAMAÚMA II will have a Wastewater Treatment Station to manage all waste generated in the boat. An ideal effluent treatment solution for SAMAÚMA II should be compact and highly efficient, producing waste that is not harmful to the environment, and must be constructed to be used as a teaching resource Thus, this project represents an opportunity for SENAI to lead Brazilian industry to cutting-edge environmentally friendly technologies and incorporate them in its technical and vocational education courses. This project will contribute to the spread of sustainable technical and vocational education practices, civic values and environmental responsibility to the Amazon riverine people. for students of the courses SAMAÚMA II will offer. In this sense, SENAI, whose history of cooperation in technological areas with German partners is very successful, envisioned the possibility of developing this ideal wastewater treatment solution for SAMAÚMA II in conjunction with the University of Stuttgart, which is an international partner of SENAI and has recognized expertise in the area. Its Institute for Sanitary Engineering, Water Quality and Waste Management (ISWA) is currently one of the most important European centers in the area of wastewater treatment, supply and management of water quality, solid waste management and development of biological technologies for cleaning environment. The IWT-Team in front of the of the ship SAMAUMA II in the Amazon Contact: Prof. Dr.-Ing. Uwe Menzel (IWT) Project partner: Serviço Nacional de Aprendizagem Industrial (SENAI-DN), Brasilia l National Serviço Nacional de Aprendizagem Industrial (SENAI-AM), Manaus Encontro das Áquas (Confluence of the Rio Negro and Rio Solimões to the Rio Amazonas) 48 construction Industrial Water and Wastewater Technology IWT International curriculum exchange Study course offers from German universities and academies abroad. The initiation of German environmental Master of Science programs at Brazilian universities under German supervision and at German standards –EDUBRAS-MAUI In the course of an onward industrialisation, environmental pollution causes central problems in emerging and developing countries. In Brazil, which is the most populous country in South America, this is particularly visible in densely populated areas. Lecturers of the University of Stuttgart have many years of experience in building up new environmental study courses such as the study course “Umweltschutztechnik” and the English Master of Science programs WAREM and WASTE, which have been successful for the past 10 years. This experience ought to be exported to Brazil, initially to the state of Paraná, as a pre-operating study. The basics of the planned study program were established by the environmental inventory of Prof. Dr. Menzel during the research project “Export orientated research on the field of water supply and water disposal, Part 2: Wastewater treatment and water reuse” funded by the German Federal Ministry for Education and Research (BMBF)”. This revealed the urgent need of exporting environmental technologies to Brazil. At the same time there is a need to educate skilled specialists, who are able to operate the imported technologies sustainable. The Summer-School-courses from 2002 until 2005 with the topics wastewater / industrial wastewater and waste / industrial waste showed the great interest for environmental topics but also the need to enlarge the offer in the form of permanent study courses in Brazil. Finally the know-how and the qualification of the appropriate specialised staff are casting for the sustainability and therefor the success of all environmental procedures. The program “Course offers from German Universities in foreign countries“ will offer study modules, study matters and also an additional study course shall be developed and offered directly at an university in Brazil. The master program “EDUBRAS-MAUI – municipal and industrial environmental protection” was inducted at the national university “Universidade Federal do Paraná - UFPR” in Curitiba in August 2008 together with the industrial alliance SENAI. The final degree „Master of Science“ will be acquired after the fourth and the sixth semester respectively. The “Master of Science” shall be accepted in Brazil or alternatively in Germany and Brazil and its accreditation is aimed. The study program will be financed by tuition fees. The linking of university lectures and research is implemented on the one hand by a closely cooperation with the University of Stuttgart and on the other hand with the project partners UFPR and SENAI as well as partners from the industry. The lectures will be held in German as well as in Portuguese. Accompanying the lectures, German language courses will be offered to intensify the contacts to Germany. Lecturers from Germany will take part in the forming of the course‘s design and they will be jointly responsible for the Excursion with students to the: drinking water abstraction of the water reservoir„Piraquara II“ and its treatment for the megacity Curitiba 49 Chair of Sanitary Engineering and Water Recycling quality control of the course. The structure of the study program offers a wide variety in the field of environmental engineering and the positions will be filled out from Brazilians and Germans. The cooperation with the project-partner UFPR is regulated by a cooperation treaty. The master’s degree “EDUBRAS-MAUI – communal and industrial environmental protection” was evaluated by the DAAD in March 2009 and was thereby awarded the rating “excellent” and was described as being “a showpiece project of highest distinction”. Due to the standard of academic excellence and the positive reception in Brazil, the DAAD has decided to continue its support for the program after the first funding phase comes to an end. An application for additional funds within the framework of the export education program, in order to publish a series of textbooks in Brazil has already been approved and an application for a further two-year extension of the project has already been lodged. By the end of this period, the international accreditation and the implementation of the double degree will have been realised. Pro headmaster Segio Scheer (UFPR), university headmaster Prof. Ressel ans EDUBRAS- project director Prof. Menzel at the network event on sustainability at the industy association FIEP in Curitiba Political delegation visiting a brazilian cathedral Under the direction of the Premier, Winfried Kretschmann, a delegation visit to Argentina and Brazil from 13th to 21th of November 2011 was carried out. Within the scope of this visit, a networking event was held in Curitiba on the 16th of November 2011, in order to address the topic of sustainability in the industry association FIEP. At this event the University of Stuttgart rector, Prof. Wolfram Ressel, and the EDUBRAS project manager, Prof. Menzel, presented the Master’s Degree Program to the widely diverse international audience and the media. In addition, Prof. Menzel visited the capital city Brasilia, as a member of the political delegation, where Mr. Kretschmann presented the bilateral projects and the ISWA’s Master’s Degree Program to the environmental minister, Texeira at the Ministery of Environment. Financing Institution: German Academic Exchange Service (DAAD) Contact: Prof. Dr.-Ing. U. Menzel (IWT) Dr.-Ing. D. Neuffer (IWT) Dr.-Ing. K. Fischer (SIA) Prof. Dr. rer. nat. J. Metzger (CH) Dr.-Ing. Karen Amaral (IWT) Dr.-Ing. Andreas Grauer (IWT) Project partner: Universidade Federal do Paraná (UFPR) Serviço Nacional de Aprendizagem Industrial (SENAI) Homepage: http://www.ppgmaui.ufpr.br/ https://www.edubras-maui.uni-stuttgart.de Opening ceremony course 2010. Farewell of the representative of the University of Stuttgart in Curitiba Dr. Daniela Neuffer and welcoming of her followers Dr. Karen Amaral and Dr. Andreas Grauer 50 Industrial Water and Wastewater Technology IWT Summer School Brazil Alongside political and legal conditions it is also crucial to obtain the know-how and qualified personal in order to create a sustainable environmental protection program and solve environmental problems. As part of the model-project “Environmental engineering study offers in Brazil- Summer School” at Fundacentro (Fundação Jorge Duprat Figueiredo de Segurança e Medicina do Trabalho (research institute at the ministry of work) in São Paulo and UTFPR (Universidade Tecnológica Federal do Paraná) in Curitiba, lecturers of the University of Stuttgart hold a three week learning event in Brazil in which the fields of waste economy, waste technology and industrial water and wastewater technology are taught. Environmental problems present a global issue, which not only concern industrialized but also emerging and developing countries. Water and air pollution as well as waste treatment also apply big problems particular with regard to rapidly growing urban centers in Brazil. Brazil takes up a central position due to the fact that it is the most populous and largest country in South America. In recent years Brazil´s southeast with its federal states of São Paulo, Paraná, Santa Catarina and Rio Grande do Sul showed a strong economic development. Particularly the two main cities São Paulo (about 20 Million inhabitants) in the federal state of São Paulo and Curitiba (about 2 Million inhabitants) in the federal state of Paraná are cities with intense economic growth. A prospective important engineering topic in Brazil will be the solution of environmental problems in the fields of wastewater and waste. Urgent problems are demanding concepts and environmentally sound proposals for solution in municipal as well as in industrial areas. The export of environmental protection technology only does not suffice. After the challenge to protect water and air were recognized in the respective countries, it is now time to establish appropriate conditions for acting. Besides political and legal framework, know-how and skills of appropriate experts are essential. In the past years Germany achieved a high level in environmental engineering and environmental protection. At the University of Stuttgart exists an extensive and diverse knowledge in this field of environmental engineering. In many research projects and teaching, this long-standing expertise is shown, e.g. in the cross-disciplinary Master, Diploma and Bachelor degree programs of environmental engineering, which are supported by 40 institutes from 10 faculties. This knowledge is made internationally available. Through the internationally oriented Master of Science program “Air Quality Control, Solid Waste and Waste Water Process Engineering (WASTE) with focus on air pollution, wastewater treatment and waste management the internationalization of the University of Stuttgart becomes apparent. Within the DAAD program “Export of German study offers” courses of the Master degree “WASTE” should be offered through a tree-week local summer school called “Environmental engineering study offers in Brazil- Summer School”, taking place in the Brazilian cities Curitiba and São Paulo. The current highest standard in environmental technology is indicated by the course content. On the other hand the placement of simple and to Brazil’s standards adapted “low-tech” and “low-cost” methods are especially on focus. This is warranted by the “on location” situation of the Summer School and the change of the lecturer to implicate the local situation into the lecture e.g. in the context of excursions. The Summer School participants should be able to apply their acquired knowledge in order to contribute to the environmental protection in Brazil. The participants include professors, students from higher semesters and colleges, as well as professionals from industrial and communal branches. The Summer Schools are executed due to strong cooperation between the Institute for Sanitary Engineering, Water Quality and Solid Waste Management at the University of Stuttgart and Brazilian universities and academic institutions in Brazil. The experiences and contacts made during this model project should contribute to the development of new study events and programs in Brazil as well as create a bond to the University of Stuttgart. As far as the participating partners are concerned this project is an opportunity to cooperate in the fields of science, research, joined projects as well as student and scientist exchange programs. Teaching topics of the Summer Schools: „Industrial Waste Water Treatment“ • Intro waste water treatment technology • Volume, types and contents of waste water • Fundamentals of industrial watermanagement • Abstract of process technologies • Preparing measures • Mechanical-physical treatment • Biological treatment • Conditioning of sludge and sludge disposal • Physicochemical treatment • Case study: combined processes • Examples of practical applications • Exercises in groups • Excursion 51 Chair of Sanitary Engineering and Water Recycling Consulting „Solid Waste Management and Treatment“ • Environmental aspects of solid waste • Source, composition, quantities of solid waste • Waste management systems • Collection and transport of solid waste • Sorting and recycling • Waste disposal – landfill, incineration • Composting and anaerobic digestion of separate collected biowaste • Air purification • Analysis of solid waste Financing Institution: Deutscher Akademischer Austauschdienst DAAD Execution and report of a biodegradation test via DIN 38405 (Sapromat), Interpretation of the results Client: Fa. Mikro-Technik GmbH & Co KG Separation of powdered activated carbon with hydrocyclones Client: Dürr Systems GmbH Independant Study Contact: Prof. Dr.-Ing. U. Menzel Dr.-Ing. D. Neuffer Dr.-Ing. K. Fischer (SIA) Dipl.-Geol. D. Clauß (SIA) Project partner: Fundacentro (Fundacao Jorge Duprat Figueiredo de Seguranca e Medicina do Trabalho (Forschungsinstitut am Arbeitsministerium) in Sao Paulo; CEFET (Centro Federal de Educacao Tecnologica do Parana) in Curitiba Comparison of different methods for water removal from industrial and municipal sludge Lea Böhme (Umweltschutztechnik) (2011) Supervisor: Dr.-Ing. D. Neuffer Thesis (Bachelor) Separation of powdered activated carbon with hydrocyclones Mirka Papenheim (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, M.Sc. Dipl.-Ing. S. Platz 52 Industrial Water and Wastewater Technology IWT Theses (Diploma) Applicability of a Membrane-Bio-Reactor in a company for fast moving consumer goods Rui Fang (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl.-Ing. T. Pittmann Improvement of the Bioavailability of persistent wastewater substances in the solar cell industry Guangwen He (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl.-Ing. T. Pittmann Investigation of different boundary conditions during the fermentation of municipal wastewater in terms of the production of biopolymers Claudia Stagl (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl.-Ing. T. Pittmann Planning and implementing of a pilot plant for mechanical-biological treatment of municipal solid waste of emerging countries David Vu (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, M.Sc. Dipl.-Ing. S. Platz Optimisation of the fermentation of wastewater in terms of the production of volatile fatty acids for the production of bioplastics Anodic oxidation for wastewater treatment in terms of the application for landfill leachate water treatment Julia Schuster (Umweltschutztechnik) (2011) Supervisor: Prof. Dr. rer. nat. T. Hirth, Prof. Dr.-Ing. U. Menzel Treatment of wastewater with surfactants and their raw materials by the example of a manufacturing company from the detergent and cosmetic base material industry Yves Steinbauer (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl. -Ing. T. Pittmann Book of Knowledge of the process- and environmental technology: Configuration of planning standards Daniel Stock (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl.-Ing. T. Pittmann Optimization of different operating pilot plants for the removal of powdered activated carbon from wastewater Luwei Zhang (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, M.Sc. Dipl.-Ing. S. Platz Florian Kogel (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, Dipl.-Ing. T. Pittmann Biohydrogen production by dark fermentation of solid an liquid waste Liang Lu (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, Prof. Dr.-Ing. H. Steinmetz Implementation of a test field for the investigation of different separation methods of powdered activated carbon of the adsorptive removal of micropollutants in wastewater Alexander Lutz (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, M.Sc. Dipl.-Ing. S. Platz 53 Chair of Sanitary Engineering and Water Recycling Theses (Master) Optimização da Flotação na ETE Atuba Sul Optimization of the flotation plant at the WWTP in Atuba Sul Gisele Kovaltchuk (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, Dr.-Ing. K. J. Amaral Utilização de bioreator a membrana para o tratamento de efluente de aterro industrial no Brasil Application of a bio-membrane-reactor for wastewater treatment of an industrial landfill in Brazil Ane Mery Pisetta Gorigoitía (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel Avaliação da correlação entre a concentração de poluntes Atmosféricos e a mortalidade de idosos no município de Evaluating the correlation between concentration of atmospheric pollutants and mortality of elderly people in the municipality of Curitiba Guiherme Augusto Robiles Exquivel (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2010) Supervisor: Prof. Dr.-Ing. U. Menzel, Prof. J. Gomes, Dr. -Ing. A. Grauer Avaliação comparativa entre os procedimentos técnicos, legais e administrativos de outorga para lançamento de efluentes em rios adotados no Brasil e na Alemanha Comparative assessment of the technical, legal and administrative framework in Brazil and Germany for permit to discharge wastewater Cristiane Schappo Wessling (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2010) Supervisor: Dr.-Ing. D. Neuffer, Dipl.-Ing. C. Meyer, Dr.-Ing. K. J. Amaral Estudo do reúso de efluente tratado como água de processo na indústria automotiva Study of treated effluent as industrial water in automotive industry Leopoldo Erthal (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Prof. J. W. Metzger, Dr.-Ing. D. Neuffer 54 Proposta de Reuso de Águas na Indústia de Produção de Celulose e Papel KRAFT Proposal for water reuse in the KRAFT production industry of pulp and paper Mario Kossar Junior (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. K. J. Amaral, Prof. Dr. S. Martinelli Análise da qualidade do rio Iguaçu como ferramenta para gestão Measurement of the quality of rio Iguaçu as a management tool Andrea Menighini (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Prof. Dr.-Ing. U. Menzel, Dr.-Ing. K. J. Amaral Análise da Potencialidade do Reúso indireto Potável: Estudo de Caso da ETE Atuba Sul, Região Metropolitana de Curitiba Analysis of the potential indirect potable water reuse: Case study of WWTP Atuba Sul,region Curitiba Pedro Luís Prado Franco (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. D. Neuffer, Dr.-Ing. K. J. Amaral Identificação de Oportunidades no Mercado de Crédito de Carbono nas Cooperativas Agropecuárias Paranaenses Identification of market opportunities of carbon credits in agricultural cooperatives of Paraná Marcos Pupo Thiesen (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. A. Grauer, M. Kawano Remoção de Micropoluentes Emergentes em Efluentes Sanitários Através de Carvão Ativado Removal of micropollutants from domestic wastewater with activated carbon Juliano César Rego Ferreira Wessling (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. D. Neuffer, Dr. B. Kuch, Dr.-Ing. K. Amaral, Prof. J. W. Metzger Industrial Water and Wastewater Technology IWT Contact Estudo do Reuso nao potavel de Água de Processo e Efluente tratado em Indústria de Bebidas Study of reuse of process water and treated wastewater for applications without the quality requirement for drinkingwater in the beverage industry Michel Ribas Galvão (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. D. Neuffer, Dr.-Ing. K. J. Amaral Avaliação da Capacidade de Degradação de Micropoluentes Orgânicos através de Tratamento com Radiação UV e UV/H2O2 Evaluation of degradation of micropollutants by treatment with UV radiation and combination of UV radiation and H2O2 Telma Soares (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. D. Neuffer, Dr. B. Kuch, Dr.-Ing. K. Amaral, Prof. J. W. Metzger Construção e Testes de Valiação de Amostradores Passivos para Dióxido de Nitrogênio e Ozônio Construction and testing of passive samplers for Nitrogen Dioxide and Ozone Magali Vieira Santiago Bucco (Professioneller Masterkurs MAUI - Kommunaler und Industrieller Umweltschutz, Brasilien) (2011) Supervisor: Dr.-Ing. A. Grauer Prof. Dr.-Ing. Uwe Menzel Tel: +49 (0)711/685-65417 Fax: +49 (0)711/685-63729 Mobil: +49 (0)172/7303330 Email:[email protected] Scientists Dr.-Ing. Daniela Neuffer Tel: +49 (0)711/685-65419 Fax: +49 (0)711/685-63729 Email:[email protected] Dipl.-Ing. MSc. Sebastian Platz Tel: +49 (0)711/685-65470 Fax: +49 (0)711/685-63729 Email:[email protected] Dipl.-Ing. Timo Pittmann Tel: +49 (0)711/685-65852 Fax: +49 (0)711/685-63729 Email:[email protected] Dr.-Ing. Karen Amaral Email:[email protected] Dr.-Ing. Andreas Grauer Email:[email protected] Laboratory CTA Silvia Brechtel Tel: +49 (0)711/685-63731 Fax: +49 (0)711/685-63729 Email: [email protected] Meanwhile quittet: Dipl.-Ing. Claudia Stagl 55 Chair of Sanitary Engineering and Water Recycling Urban Drainage Research topics: • Sustainable urban drainage systems (SUDS) • Treatment of wet-weather flows in combined and separate sewer systems • Real-time control based on quantity and quality parameters • Treatment of highway runoff • Infiltration water management • Monitoring of sewer systems Our department covers all aspects related to discharge and treatment of stormwater and wastewater in urban areas. The implementation of novel drainage concepts over the last decades and new technical possibilities facilitate an increasingly sophisticated management of urban wet-weather flows. Prominent examples are the use of seminatural devices in stormwater management (generally known as SUDS or BMPs), quality-based separation of different types of stormwater and real-time control of entire sewer networks. Due to these developments urban drainage systems play a more important role for the management of water and pollutant fluxes. Another aspect is the risk of urban flooding that receives higher attention as climate change is expected to result in a higher frequency of extreme events. To address these themes adequately in research and education the department of urban drainage was founded in 2009. 56 Urban Drainage SE Research Concentration of Micropollutants in surface waters with strong urban-oriented catchment areas - Acquisition of pollutants flows and evaluation of elimination measures at wastewater treatment plants by taking the example of the Schwippe by Sindelfingen In order to reduce the emission of micropollutants from urban areas, an additional step of treatment is planned or already in operation in several wastewater treatment plants. The concentration micropollutants in surface waters depends on background pollution, emissions from wastewater treatment plants, as well as, stormwater runoff from urabn areas and combined sewer overflows. The impact of emissions of micropollutants is high for the river Schwippe, which receives wastewater and stormwater runoff from large urban areas (Böblingen and Sindelfingen). At the BöblingenSindelfingen wastewater treatment plant, a plant with activated carbon adsorption for the elimination of micropollutants as fourth step of treatment was started on the 17th of October 2011. The effect of advanced wastewater treatment technologies on organic micropollutants in the river Schwippe is determined with the help of two phased field investigations, before and after the start of the activated carbon adsorption plant. In this project, flows of micropollutants from the wastewater treatment plant and from the upstream urban catchment areas are determined with sampling and online measurements, in dry and wet weather. Turbidity, conductivity, concentrations of O2, and pH are measured online in the river Schwippe. For each sample, these parameters are determined: suspended solids, chemical oxygen demand (COD), NH4-N, NO3-N, NO2-N, Ptot and PO4-P. The analyse of micropollutants focuses on pollutants where the concentration in surface waters is under legal regulations. Analysis is done at the laboratory of the BIOS department at ISWA. Financing Institution: Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg Contact: Dr.-Ing. Ulrich Dittmer Dr. rer. nat. Bertram Kuch Dipl.-Ing. Marie Launay Project partner: Department of Hydrobiology and analysis of organic trace compounds, ISWA Duration: 01/2011 - 05/2012 Climate Change impacts on the overflow characteristics of combined sewer systems This project investigates climate change impacts upon storm water overflow characteristics in combined sewer systems. Furthermore, measures to counter negative effects caused by climate are investigated. The core of the investigations are long-term pollution load simluations for several standardized representative sewer systems. The precipitation data for the future (2025 - 2034) has been generated with the precipitation generator NiedSim-Klima that has been developed by the Institute for Modelling Hydraulic and Environmental Systems of the University of Stuttgart. The projected future changes in the precipitation behavior differ spatialy. To account for this heterogeneity, several different locations across BadenWuerttemberg representing the typical regions are being investigated. During the first project phase, it was investigated how well NiedSim-Klima precipitation data represents measured data. Long-term measured precipitation data was statisticaly investigated with generated precipitation data for several locations in BadenWürttemberg. Examples of how the data was investigated are by comparing for example mean yearly precipitation, several descriptive parameters, and the frequency distributions of different duration periods. In general, it can be observed that the simulated precipitation data overestimates yearly precipitation by aprox. 15%. Due to missing values in the measured data the actual overestimation is less the 15%. The number of dry days per year is being underestimated or overestimated by 10% depending upon the location. Looking at the frequency distibutions for each duration period, it can be observed that precipitation events with a low or average intensity are being underestimated and ones with a high intensity are being overestimated. In the second project phase, NiedSim-Klima precipitation data of the past and future has been statistically compared to assess the impacts of climate change upon precipitation characteristics. It was concluded that the mean yearly precipitation amount only increses by 4%. The amount of dry days per year decreses by up to 30%. Great changes can be observed in the frequency distibutions of the different duration periods. This becomes appared when looking at the 10 highest precipitation events each year for different duration periods (Figure 1). In the future a greater amount of the daily precipitation will fall down in a shorter time. In the now running third project phase, the simulated precipitation data for the past and future are used in long-tern pollution load simulations with the 57 Chair of Sanitary Engineering and Water Recycling simulation software KOSIM (itwh, Hannover). The results are being investiagated by comparing, for example, the mean yearly overflow volume and duration as well as, frequency distributions of reservoir filling and overflow (duration and volume). First simulations for the future with a standardized sewer system resulted in a 7% decrease in the mean yearly overflow volume, a 20% increase in the reservoir filling duration, and a 6% decrease in the overflow duration. The use of simulated precipitation data results in uncertainierts. Therefore, long-term pollution load simulations for the past are carried out and compared using measured and simulationed precipitation data. In general, simulated data underestimates the mean yearly overflow volume (17%), overestimates the reservoir filling duration (8%), and underestimates the overflow duration (31%). These deviations are mainly the result of the differences in the frequency distributions of the precipitation intensites for the different duration periods. Financing Institution: Ministry of the Environment, Climate Protection and the Energy Sector, Baden-Wuerttemberg Contact: Dr.-Ing. Ulrich Dittmer Dipl.-Ing. David Bendel Project partner: Institute for Modelling Hydraulic and Environmental Systems, University of Stuttgart Duration: 06/2011 - 12/2012 Figure 1: Change of the 10 highest precipitation events for each year and duration period (dp) of the precipitation station in Wuestenrot, blue: NiedSim-Klima Past (NSK), red: NiedSim-Klima Future (NSK2030) 58 Urban Drainage SE Operation of storm water overflow tanks – code of practice and training material Within the scope of this project commissioned by “Landesverband DWA Baden-Württemberg” a code of practice with the subject “Operation of storm water overflow tanks” should be provided. The proper functioning of storm water tanks is associated with high technical and personal requirements which also cause substantial costs. At the same time, it is a necessary requirement for effective water protection. Practical experience has shown that it is necessary to give in particular small and medium operators of wastewater systems recommendations for an efficient and cost-effective operation of storm water overflow tanks. Until now, there has only been a few general guidelines for the operation of storm water overflow tanks in the EKVO Baden-Württemberg and the technical frameworks of the DWA. The project objective is to elaborate a code of practice and presentation slides for the training courses of the operating personnel in order to assist these operators of wastewater systems. The experiences of operators, public authorities, manufacturers, civil engineering companies, and suppliers are also being incorporated in the project. The code of practice is divided into theoretical and practical parts. The theoretical part concentrates on the didactic preparation of the basic knowledge concerning the wastewater discharge and the treatment of combined sewage. The practical part contains the recommendations regarding the organization, the equipment (mechanical, process measuring and control technology), the maintenance, and the common ways of documentation. Storm water overflow tanks Financing Institution: DWA Landesverband Baden-Württemberg Contact: Dr.-Ing. Ulrich Dittmer Dipl.-Ing. Christian Klippstein Duration: 01/2011 - 12/2011 Modification of a software for the simulation of wastewater temperature to conditions in BadenWürttemberg and reactivation of a wastewater heat exchanger With an average temperature ranging from 10 °C and 20 °C wastewater is a constantly available energy source. Heat recovery from wastewater is a topic of rising importance in Germany. Heat can be recovered from sewers with the help of heat exchangers and heat pumps and could be used for heating of buildings within their proximity. However, many factors affect the temperature of wastewater which results in a complex behaviour of its dynamics within sewer systems. A simplified approach to estimate the gradient of temperature in sewers has not been reached until now. In the last years, EAWAG (Zurich) has developed a model able to describe precisely the decisive processes of the heat balance. The software TEMPEST (Temperature Estimation) is a tool for the dynamic simulation of wastewater temperature. However, the application of this software in practice is constricted due to a lack of measured data for material properties, particularly for heat transfer. The project addresses this lack of field data. Field investigations were conducted in the sewer system of a German city with over 50 000 inhabitants. Several criteria were considered in the selection of the investigation area and the location of the measuring stations: the urban framework and population density, the topography of the sewer lines, the effect of infiltration water from different groundwater levels, and the impact of rainfall on the wastewater temperature. The temperature and wastewater flow and the ground temperature have been measured at twelve stations within a 40 km sewer system during the period of January through December 2011. As an example figure 1 shows the effect of a rain event on the wastewater temperature. The measurements will help to obtain a solid database to calibrate the simulation model TEMPEST and to validate the forecasting capability of the model. 59 Chair of Sanitary Engineering and Water Recycling Fig 1: Wastewater flow and temperature in a sewer for a rain event (26.02.2011) A second part of the project is dedicated to the reactivation of a wastewater heat exchanger that has been installed over 30 years ago. In 1982, an installation for wastewater heat recovery came into operatio at Salemer Pfleghof in Esslingen / Neckar. A few years later, because of excessive maintenance costs of the heat pump, the system was shut down. In the last few years, the technical development in the heat pumps sector has been very fast and modern systems require lower maintenance. The old heat exchanger is still in the sewer (see Fig 2) but the heat pump had to be removed. It is a good opportunity to demonstrate how durable the incorporated technology in sewers is and to obtain data for the calculation and profitability of wastewater heat exchangers. Fig 2: A 30 year old wastewater heat exchanger in Salemer Pfleghof in Esslingen 60 Financing Institution: Ministry of the Environment, Climate Protection and the Energy Sector, Baden-Wuerttemberg Contact: Dr.-Ing. Ulrich Dittmer Dipl.-Ing. Marie Launay Project partner: Ingenieur Büro Klinger und Partner, Stuttgart Steinbeis-Transferzentrum Esslingen Duration: 12/2009 - 03/2012 Urban Drainage SE Consulting Independant Study Design of a bed load trap for the WWTP Stuttgart-Möhringen Client: Stadtentwässerung Stuttgart (SES), 2010 Analysis of the loading regime of Biofilters for CSO treatment considering regional variations in precipitation patterns Project Management for the Urban Drainage Master Plan for the City of Reutlingen Client: Stadtentwässerung Reutlingen (SER), 2011 Simulation Study on Management and Rehablilitation of CSO structures in catchment StuttgartMöhringen Client: Stadtentwässerung Stuttgart (SES), 2011 Theresia Heißerer (Umweltschutztechnik) (2011) Betreuer: Dr.-Ing. U. Dittmer, Dipl.-Ing. F. Beck Theses (Diploma) Characterization of the pollution of urban surface runoff. Nina Gutjahr (Umweltschutztechnik) (2010) Betreuer: Prof. Dr.-Ing. H. Steinmetz, Dr.-Ing. U. Dittmer Approaches to the intergration of particle transport into hydrodynamic sewer quality models. Tim Schneider (Umweltschutztechnik) (2010) Betreuer: Prof. Dr.-Ing. H. Steinmetz, Dr.-Ing. U. Dittmer Rehabilitation of a Sewer Network Considering Hydraulic Capacity and Physical State of the Pipes. Christian Klippstein (Bauingenieurwesen) (2011) Betreuer: Prof. Dr.-Ing. H. Steinmetz, Dr.-Ing. U. Dittmer Calibration of a water quality model for a combined sewer system using Info Works CS. Michael Stapf (Umweltschutztechnik) (2011) Betreuer: Prof. Dr.-Ing. H. Steinmetz, Dr.-Ing. U. Dittmer 61 Chair of Sanitary Engineering and Water Recycling Contact Dr.-Ing. Ulrich Dittmer (Akad. Rat) Tel.: +49 (0)711 / 685 - 69350 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Scientists Dipl.-Ing. David Bendel Tel.: +49 (0)711 / 685 - 65788 Fax.: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Hyd. Isabelle Fechner Tel.: +49 (0)711 / 685 - 63739 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Mehari G. Haile, M.Sc. Tel.: +49 (0)711 / 685 - 65439 Fax: +49 (0)711 / 685 - 63729 E-Mail:[email protected] Dipl.-Ing. Christian Klippstein Tel.: +49 (0)711 / 685 - 65410 Fax: +49 (0)711 / 685 - 63729 E-Mail:[email protected] Dipl.-Ing. Marie Launay Tel.: +49 (0)711 / 685 - 65445 Fax: +49 (0)711 / 685 - 63729 E-Mail:[email protected] Meanwhile quittet: Dr.-Ing. Gebhard Stotz 62 Industrial Water and Wastewater Technology IWT 63 Chair of Sanitary Engineering and Water Recycling Water Quality Management and Water Supply Research topics: • Water collection and water treat ment • Removal of iron, manganese and arsenic by subterranian groundwater treatment • In-situ bioreactors for decentralized groundwater treatment and supply • Ecosystem research of rivers and groundwater • Stormwater run-off management, rainwater harvesting and water conservation • Protection of drinking water resources • Investigation of anaerobic treatability of wastewaterand concentrates • Water quality management and its interaction with indirect dischargers and operation of the wastewater treatment plant With us, effluent is just water under the bridge Our field of work consists of all aspects of extraction and provision of water from surface and groundwater sources. Most notably, this involves subterranian groundwater treatment, and all questions relating to the transport, storage and distribution of water. The technical, economical and hygienic aspects play the primary role in this. In the field of water supply, we deal with the problems shown in the margin, whereby the technology of groundwater treatment is increasingly applied to contaminated site remediation. For the treatment of water for industrial use, we employ membranes, oxidation, UV disinfection and anaerobic biological processes. The transport and distribution of drinking water, and the associated hygienic problems, are also subjects of our investigations. We have also listed the focal points of our work in water quality management. Generally, this involves anthropogenic influences on water quality and the protection of drinking water resources. One important example of our research is the investigation of the interaction between wastewater pretreatment in industry and the operation of municipal wastewater treatment plants, and their influence on water quality. The final aim is the optimum disposal of sewage from both a business management and an economical point of view. The development, optimization and implementation of sustainable, cost effective and ecologically sensible water treatment technologies on the one hand and technologically advanced procedures on the other, remains a central task in view of the global drinking water supply crisis. One of the main research areas for the future will therefore be the analysis and defeat of transfer and implementation restraints. In addition, it is also necessary, due to the limited global water resources, to increase research in the fields of water resource control and management in terms of safeguarding drinking water supplies. 64 Water Quality Management and Water Supply WGW Research International Cooperation Research with India in Education and The objective of the project was to submit a proposal to the European Commission in the Seventh Framework Programme (FP7), targeting at international cooperation with India in the field of natural water treatment systems. In total, 17 partners from Germany, France, Great Britain, Israel, India and Vietnam participated in the proposal. The objective of the proposal was to develop selfsupporting and sustainable concepts based on natural water treatment systems and services for India to cope with the ever-growing problems in the water sector. There is an urgent need for offering suitable and cost-effective technologies like natural water treatment (NWT) to satisfy the ever-growing demand for drinking and process water. The proposal was focussing on NWT systems & services to improve the water availability in urban areas as they offer promising solutions in terms of technical, socio-economic and environmental sustainability. NWT systems & services are available in the European/Israeli market, but have not penetrated adequately into the Indian market, although they may be a solution of high sustainability for solving the existing water related problems. This lack of penetration may be attributed to existing market barriers that may be found on both supply and demand side. Financing Institution: DLR, International Bureau of the German Federal Ministry of Education and Research Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. Sabine Schmidt Dipl.-Ing. Andreas Neft Duration: 07/2010 - 11/2010 The approach of the proposal was to solve problems in India with performance and reliability of NWT systems and to establish technologies which are technically cost-efficient and easy to operate and maintain. In addition, the aim was to establish and improve research partnerships and to create added value for SMEs in the sector of natural water treatment systems. In the course of the project, the criteria relevant for understanding the needs of the NWT supply and demand side were to be identified and evaluated in order to identify these NWT systems & services that have potential to be self-supporting and sustainable solutions in India. The core outputs of the project, a technical matrix for NWT systems & services for the NWT supply side and a decision support matrix for NWT systems & services for the decision makers in the Indian water sector, were aimed to eliminate market barriers for NWT systems & services to the benefit of SMEs and the Indian people. Die European Commission evaluated the proposal with “good” in all aspects. However, the evaluation result was not sufficient for funding. 65 Chair of Sanitary Engineering and Water Recycling INDO-GERMAN WATER NETWORK - Planning and Rehabilitation of communal and industrial water supply and wastewater disposal systems in India The network „Planning and Rehabilitation of communal and industrial water supply and wastewater disposal systems in India“ (INDO-GERMAN WATER network) is a research network in the field of water supply, wastewater systems and environmental technologies. The INDO-GERMAN WATER network covers a deep and broad portfolio of experience, ranging from research activities to highly application oriented solutions and their implementation. The network took part in the campaign “India and Germany – Strategic Partners for Innovation”, that was supported by the German Federal Ministry of Education and Research. Detailed information of the INDO - GERMAN WATER network, its activities and members are available at www.indo-german-water.net. Target is to develop and carry out projects concerning planning or rehabilitation of wastewater disposal and water supply systems that lead to a sustainable and economical system operation. This is the base to provide water supply and wastewater disposal for humans and industrial purpose regarding to people’s health, economical development and environmental protection. The objective of the project and of the network is to form Indian-German co-operation teams bringing forward R&D or industrial projects concerning water and wastewater systems. The specific aims are: • Improve water supply and wastewater disposal for humans and industrial purposes, taking into consideration people’s health, economical development and environmental protection. • Integrate Indian and German know-how in these areas and adapt solutions to the special needs of India. • Identify potential fields for co-operations and areas for joint Indo-German research activities in India. • Establish Indo-German projects in the field of communal and industrial water supply and wastewater disposal. Workshops were organized in India to present the fields of work and the experience of the German project partners as well as of the potential Indian partners. The special challenges for Indo-German teams will be discussed there. This comprises investigations of the needs concerning water and wastewater management in India, and of general conditions relating to projects in the mentioned fields. A conference has been organized to present the potential of the German and Indian R&D institutes and companies 66 to strengthen the cooperation and to inform and integrate promising partners, e.g. authorities, system operators or companies. In 2010 INDO GERMAN WATER network was participating at EmTech India 2010 in Bangalore, at the 16TH TECHNOLOGY SUMMIT & TECHNOLOGY PLATFORM in New Delhi and at the IVth World Aqua Congress in New Delhi. Participants at the IVth World Aqua Congress in New Delhi Financing Institution: German Federal Ministry of Education and Research (BMBF) Contact: Prof. Dr.-Ing. Heidrun Steinmetz Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. Manuel Krauss Project partner: Engineering Consultants Scheer, Sonthofen Institut für Wasserwesen der Universität der Bundeswehr München Tandler.Com–Gesellschaft für Umweltinformatik mbH BAYIND - Bayerisches Kooperationszentrum für Wirtschaft und Hochschulen für Indien, Fachhochschule Hof Duration: 11/2008 – 12/2010 Water Quality Management and Water Supply WGW LILAC -Living Landscapes China – Module „Land use change and water bodies“ Changes in land use can directly and indirectly affect the river water quality, sediment input and hence the river ecology due to increased land erosion in local as well as in regional extent. The Naban River Watershed National Nature Reserve (NRWNNR) has been greatly affected by land use changes in the past decades. The impacts of land use changes on rivers have been evaluated in terms of changed sediment conditions and water quality and quantity. The evaluation is carried out by comparing the measured and modeled values of several indicators at different locations in the watershed. The measured and modeled indication values range from physical/chemical parameters and organic trace substances to hydromorphological factors and simulated habitat suitability for local fish species. This study focuses on the evaluation of water quality as well as sediment and water ecology. Additionally, water supply system, drinking water quality and performance of wastewater treatment plants have been studied in order to analyze the use of river water and water management in term of water quality. The result shows that: (1) the river water has relatively high phosphorous and nitrogen concentrations and therefore the backwater area before the confluence into Mekong River is threatened by eutrophication; (2) the river water is highly disturbed by various pesticides and organic trace substances; (3) the amount of fine sediments is unnaturally high and consequently affects the habitats of fish species; (4) it is necessary to build more wastewater and water treatment plants with high performance. The obtained results can be used as a base for developing strategies for an integrated water resources management. The project was conducted in cooperation with the Institute for Modelling Hydraulic and Environmental Systems, University of Stuttgart (IWS) within the Water Research Center (wfz) Stuttgart. Financing Institution: German Federal Ministry of Education and Research (BMBF) Contact: Prof. Dr.-Ing. H. Steinmetz Prof. Dr.-Ing. S. Wieprecht (IWS) Dipl.-Ing. R. Minke, AOR Dr. rer. nat. Bertram Kuch Dipl.-Ing. Manuel Krauss Dipl.-Ing. Qingfan Zhang Project partner: Deutschland: Institut für Wasserbau (IWS) der Univ. Stuttgart Universitäten Hohenheim, Hannover, Passau, Kassel Humboldt-Universität Berlin, Justus-Liebig-Universität Giessen Deutsches Institut für tropische und subtropische Landwirtschaft GmbH China: Tongji University Shanghai Tsinghua University Beijing Xishuangbanna Tropical Botanical Garden, Chinese Academy of Science (CAS) China Agricultural University (CAU) Yunnan Agricultural University (YAU) Yunnan Academy of Social Sciences (YASS) Naban River Watershed National Nature Reserve Bureau (NRWNNRB) TianZi Biodiversity Research and Development Centre Duration: 11/2009 – 10/2010 Results of land use changes (cleared woodland) in Yunnan, China 67 Chair of Sanitary Engineering and Water Recycling SURUMER - Sustainable Rubber Cultivation in the Mekong Region. Development of an integrative land-use concept in Yunnan Province, China Subproject 3: Development and appliance of a strategic water management tool The overall objective of SURUMER is to develop an integrative, applicable, and stakeholder validated concept for sustainable rubber cultivation in a highly diverse ecoregion (southern Yunnan, representing the Greater Mekong Subregion). This concept is based on multi-, inter- and transdisciplinary approaches, involving nine research subprojects (SP) of different disciplines and sectors, and the Project Management Coordination subproject PMC. Trade-offs and synergies between ecosystem functions (ESF) and services (ESS) on the one hand and socio-economic aims and constraints on the other are being identified, in order to achieve the safeguarding of biophysical features that ensure the flow of ESS within the socio-ecological system. ESF and ESS are analyzed in a comparative approach. Studies are conducted in two regions of contrasting land use, representing a close-to-nature catchment area dominated by natural forest, and a catchment area dominated by rubber plantations. After the initiation phase including infrastructure establishment and baseline study, the following aim will be reached in three over-lapping phases of totally five years: Phase 1: Assessment and quantification of major ESF and ESS of forest- and rubber dominated land use systems by applying and developing scientific methods across different sectors and spatial scales, which include biophysical features, biodiversity-related features and economic and socio-economic issues, including stakeholder analysis. These activities are accompanied by a transdisciplinary process involving participation of stakeholders of all relevant sectors. Phase 2: Integrative analysis: The obtained data and results on ESF and ESS are analyzed and evaluated in inter- and multidisciplinary approaches including modeling and upscaling, in order to quantify the spatial and temporal flows of services. The developed outputs and scenarios are communicated to stakeholders, and their continuous feedback facilitates the development of alternative land use strategies. Strategic planning: Along with results from economic analyses and valuations, tradeoffs and synergies between alternative land use strategies (focussing on the provision of ESF and ESS) and economic viability and goals are identified. Researchers and stakeholders then develop strategic objectives and specific actions for the safeguarding of ESS, which will be tested in experimental approaches. Monitoring and evaluation: The feasibility of the intended measures will be analyzed with stakeholders and then applied to onplot experiments established to test techniques of sustainable rubber cultivation that ensure the flow of ESS to the beneficiaries. Robust indicators for impact assessment will be defined which, together with economic indicators, provide the basis for impact monitoring and valuation. Intensified rubber cultivation with strong impact on water bodies 68 Water Quality Management and Water Supply WGW Phase 3: Implementation: The final phase includes the transdisciplinary valuation of designs and concepts by the disciplines and stakeholders. This ensures that all sectors accept and adopt appropriate solutions for achieving longterm resilience of the social-ecological system associated with ESS. This process is followed by the analysis of framework conditions for implementation and diffusion with focus on political-administrative hierarchies, landuse policies, and property rights. Prospects: The outcomes of the proposed project will not only refer to the regional situation of the study region. Rather, they provide a wider application for other potential rubber cultivation areas across the Greater Mekong Subregion facing the same problems. The concepts for sustainable rubber cultivation developed in this project provide a practical implementation framework to all stakeholders and political institutions of such counties. The concept can further be adapted to other socio-ecological environments of large-scale tropical production systems of renewable resources such as oil palm plantations. Subproject 3: Specific aim of this subproject is the development and appliance of a strategic water management tool to protect water resources. The conversion of natural forest into rubber plantations does not only affect the local water balance, but also affects the quality and quantity of groundwater and surface waters as resources. ESF and ESS affected include the provision of drinking and process water, of energy (water availability related to hydropower), the regulation of the local water cycle, and the condition of soil and biodiversity in general. Several impacts on ESF and ESS connected to water have already been reported from the Xishuangbanna area. To deal with changed land use due to rubber cultivation and its impacts on water resources in Xishuangbanna, water management plans are needed containing a program of measures to meet ESF and ESS that are defined by physical, chemical and biological characteristics as well as by socio-economic effects. The responsible authorities and decisionmakers must have tools to assess the present status and the likely impact of management options that might be employed to mitigate any existing and future problem. Water Resources Management offers solutions to control natural and humanmade water resources systems for beneficial uses. In general, water management deals with water supply, wastewater and water quality services, flood control, hydropower, navigation, recreation, and water for the environment, fish and wildlife. Therefore, this subproject aims to develop and apply a sophisticated Water Management Tool (WMT) with an immission based approach to monitor the water resources and to pro- tect them against land use pressure, especially through rubber cultivation. Both water quality and quantity aspects will be considered relating to the groundwater and surface waters as important drinking and process water resources, and to the surface waters as natural habitats. Subproject 3 will be conducted in cooperation with the Institute for Modelling Hydraulic and Environmental Systems, University of Stuttgart (IWS) within the Water Research Center (wfz) Stuttgart. Financing Institution: German Federal Ministry of Education and Research (BMBF) Contact: Prof. Dr.-Ing. H. Steinmetz Prof. Dr.-Ing. S. Wieprecht (IWS) Dipl.-Ing. R. Minke, AOR Dr. rer. nat. Bertram Kuch Dipl.-Ing. Manuel Krauss Dipl.-Ing. Lydia Seitz (IWS) Project partner: Deutschland: Universität Hohenheim (Leitung des Gesamtprojekts) Leibniz Universität Hannover Humboldt-Universität Berlin Justus-Liebig-Universität Gießen Deutsches Institut für tropische und subtropische Landwirtschaft GmbH Deutsche Gesellschaft für Internationale Zusammenarbeit (GIZ) China: Tongji University Shanghai Tsinghua University Beijing Yunnan Institute of Environmental Science World Agro-Forestry Centre China Institute of Zoology, Chinese Academy of Sciences, Beijing Beijing Normal University China Agricultural University, Beijing Center for Chinese Agricultural Policy, Chinese Academy of Sciences Yunnan Academy of Social Sciences (YASS) Naban River Watershed National Nature Reserve Bureau (NRWNNRB) Foreign Investment and Cooperation Department & Hainan Rubber Cultivation Research Institute, Ministry of Agriculture Duration: 12/2011 – 11/2016 69 Chair of Sanitary Engineering and Water Recycling Industrial Wastewater Reuse in Textile Industry by Application of Appropriate Membrane Treatment Technology and Investigating Pre-treatment Methods, Fouling Phenomenon and Cleaning of Fouled Membranes The usable water resources in the world are decreasing in amount, leading not only an increase in water price but also stringent wastewater discharge quality limits which increases wastewater treatment cost. Textile industry requires significant amount of process water for cleaning, bleaching, dyeing and washing/rinsing purposes. One of the effective ways for sustainable and economical usage of water for a textile industry can be the implementation of wastewater reuse. In this sense each type of textile wastewater should be thought as a new water resource and should be reused as much as possible without causing any quality decrease in produced textile. Application of membrane treatment technology in segregated wastewater treatment and reuse concept allows in-situ treatment and reuse. Although membrane filtration gives enormous results, membrane treatment has one main disadvantage, which is membrane fouling. Membrane fouling is mainly categorized as inorganic fouling, organic fouling and biofouling. Fouling is an important problem for economical sustainability of the membrane treatment process and it should be minimized by investigating adequate pre-treatment and membrane cleaning methods. Therefore the project aims were classified as: • selecting appropriate membrane application for each wastewater stream in a textile dye-house • selecting water reuse potential of each wastewater stream in a textile dye-house • investigating effective pre-treatment methods for the selected membrane applications • investigating effective membrane cleaning methods for the selected membrane applications • investigating non-Phosphorus based antiscalant usage and formation of biofouling. Investigations are conducted with laboratory scale and pilot scale membrane units by using original textile dyehouse wastewaters. NF270 nanofiltration membrane and XLE reverse osmosis membrane were found effective for the treatment and reuse of washing/rinsing wastewaters. MF/UF pre-filtration was found effective for NF/RO treatment of washing/rinsing wastewaters. Alkaline membrane cleaning was found effective for the cleaning of fouled membranes. Investigating not only the effect of non-Phosphorus based antiscalants on the membrane treatment performance and on biofouling formation but also the removal of biofouling by membrane cleaning and regeneration of 70 biofouling after membrane cleaning will be performed to complete the project. According to the initial results, more than 55% overall water reuse and more than 50% salt reuse was observed. Financing Institution: DLR, International Bureau of the German Federal Ministry of Education and Research Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. Ralf Minke, AOR M.Sc. Kenan Güney Project partner: Technische Universität Istanbul, Türkei Duration: 01/2009 – 06/2012 Water Quality Management and Water Supply WGW AKIZ – Integrated Wastewater Concept for Industrial Zones with near-to-source measures to recover energy and valuable materials for developping countries in tropical regions Sub-project W2: Elimination of Toxic Substances – Chemical and Physicochemical Processes for Persistent Organic Pollutants Removal from WastewaterVietnam has a large number of about 200 registered industrial zones (IZ) without sustainable wastewater concepts. As a result of a selection process, carried out with the consent of the International Bureau of the BMBF in co-operation with KfW, a „Flagship Project“ is proposed for the IZ Tra Noc, Can Tho City, in the Mekong Delta. In consideration of the planed KfWfounded central sewage treatment plant of the IZ, the BMBF research project will develop an integrated wastewater concept for tropical IZ (AKIZ, Integriertes Abwasserkonzept für Industriezonen), to secure the efficiency and sustainable functioning of the whole system including all its components (life cycle optimization). Taking representative factories within the IZ Tra Noc, near-to-source measures shall be demonstrated, such as the pre-treatment of wastewater (e.g. from veterinary pharmaceutical production to remove toxic substances), or the generation of energy from wastewater (e.g. for a fish producing company), and the reclamation of valuable substances and water-re-use from wastewater (e.g. for a brewery or chemical factory). Pilot plants in technical scale (not in full scale), mounted in containers, will be used to adapt and verify high-tech solutions to the local conditions. Additionally, appropriate technologies and concepts for the disposal respectively for the utilisation of different sewage-sludges have to be developed, and the links with solid waste and contaminated sites management have to be analyzed and considered. Based on the pilot test plant results, an overall Management Concept will be created for AKIZ, which will cover the technical as well as the economic, financial functions of all facilities and organizations within the IZ. The decentralized measures within the BMBF research project have to be included, protecting and accomplishing the central sewage treatment plant financed by the BMZ through the KfW. Furthermore, sociological and ecological aspects, relevant to apply AKIZ, have to be considered. The sustainable implementation of AKIZ will be supported through capacity building with stakeholders and local partners. In the sub-project W2 of the joint project AKIZ it should be exemplarily examined which industrial companies of the Industrial Zone Tra Noc discharge sewage water, which will be critical to the operation of a central mechanical-biological treatment plant. Furthermore the waste water could cause problems for the future sewage disposal and/ or, as result of persistence and non-elimination, end up in the receiving water and can therefore reach the aquatic environment. Accordingly steady and safe near-to-source detoxification methods have to be selected. Therefore three companies of the pharmaceutical, veterinary pharmaceutical, chemical, fertilizer or pesticide production sector should be selected and their waste water sampled and analyzed. Based on analysis and the expected concentrations, loads and inhibitory effects at the end of phase „ba- Delegates of AKIZ Joint-Workshop in Can Tho, Vietnam, 28./29.11.2011 71 Chair of Sanitary Engineering and Water Recycling sic evaluation“ two companies for the further project phases are to be determined and suitable detoxification techniques have to be selected. Several methods like the application of precipitation-/flocculation-/neutralization-methods, oxidation methods (e.g. ozonization or H2O2/ UV-methods), adsorption methods with active coal, as well as membrane filtration methods (nano membrane and reverse osmosis), membrane bio reactor should be set up. These procedures are chosen because in the field of waste water detoxification they are the state -of -the art. In addition new methods such as high voltage probes and oxidation using diamond electrodes should be investigated on site and also within the scope of further studies in the laboratory for individual sub-stream effluents. The effectiveness of alternative methods such as the use of non-bacterial cells and specific isolated enzymes can be analyzed. For the selected companies, adapted pretreatment methods will be chosen to design a mobile pilot container. In the development and optimization phase, a mobile container will be constructed by HST GmbH to be operated at two selected companies. With the objective of determining the optimal detoxification process, several points such as reliability, cost, acceptance and integration into production process or the optimal combination of techniques and their optimal process parameters are to be investigated. In addition, the detoxification technology should be adapted and developed from the points of temperature, humidity, level of infrastructural and organizational constraints, also process-specific and specific scientific questions should be clarified. According to the work schedule the pilot plant will be designed and built by HST Hydro-Systemtechnik GmbH (Meschede) and then be shipped to Vietnam and put into operation. There, the plant will be operated by members of ISWA in close cooperation with HST. In a 2 1/4-anually experimental phase, the pilot plant will be operated in a manner to achieve the above mentioned objectives. If it turns out that due to local conditions in the first industrial company the research objectives cannot be achieved, the plant will be transferred to another industrial company. 72 Financing Institution: Bundesministerium (BMBF) für Bildung und Forschung Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. Ralf Minke, AOR Dr. rer. nat. Bertram Kuch Dipl.-Ing. Thi Thi Vu Dipl.-Ing. Alexander Kilian Project partner: Institut für Umwelttechnik und Management an der Universität Witten/Herdecke GmbH (IEEM) HST Hydro - Systemtechnik GmbH, Meschede Institut für Siedlungswasserwirtschaft und Abfalltechnik (ISAH) an der Leibniz Universität Hannover Passavant-Roediger GmbH, Hanau Institut für Wasserversorgung und Grundwasserschutz, Abwassertechnik, Abfalltechnik, Industrielle Stoffkreisläufe, Umweltund Raumplanung (WAR) an der Technischen Universität Darmstadt EnviroChemie GmbH, Rossdorf LAR Process Analysers AG, Berlin Institut für Siedlungswasserwirtschaft an der Technischen Universität Braunschweig Duration: 11/2009 – 04/2014 Water Quality Management and Water Supply WGW Leakage Detection and Control in Ghana‘s Urban Water Supply System: A Case Study of Saltpond Distribution Network Non-Revenue Water (NRW) is simply water supplied into a system for which does not bring revenue in return. A major component of NRW is Water loss which is made up of real loss (physical loss—leakages and bursts) and apparent loss (commercial loss—illegal connections, meter inaccuracies etc.). Water loss is a challenge for most developing countries like Ghana where about 50% of water supplied is lost. This project will focus on the physical loss aspect leakage detection and control. For this study, a system which has been zoned is required. The chosen Saltpond water distribution network was built in the 1960s and rehabilitated and upgraded in 2008. The system was zoned with each zone having a bulk meter. The project aims at 1. developing an optimization-based model for predicting leakage spots 2. quantifying physical and apparent losses 3. defining system-specific performance indicators 4. preparing a rehabilitation plan or scheme using PiReM software (from RBS Wave) 5. investigating the transferability to other water distribution networks in Ghana and other developing countries Internationally accepted practices such as the Minimum Night Flow (MNF) Analysis will be used to assess the amount of water lost in the system and an optimization model will be developed to predict leakages hotspots while the Pipe Rehabilitation Management (PiReM Trinkwasser) Software developed by RBS Wave and its partners will be used for the rehabilitation planning. Considering the pillars of leakage analysis as well as the management framework below, it is clear that whiles leakage detection modeling and minimum night flow analysis enables active leakage control thereby enhancing the speed and quality of repairs, PiReM also ensure asset management. At the end of this research, the following will be the outcomes: 1. Scientific tool to determine leakage spots in the distribution system 2. Decision support system for the repair or replacement of sections of network 3. System-specific performance indicators (targets) for Ghana Financing Institution: Ghana Education Trust Fund/ University of Ghana Contact: Prof. Dr.-Ing. H. Steinmetz Dipl.-Ing. R. Minke, AOR M.Sc. Peace K. Amoatey Duration: 11/2010 – 11/2013 Fig.1: Four pillars of Leakage Management Fig.2: Four pillars of Leakage Analysis (Farley, 2008) (Islam, 2010) 73 Chair of Sanitary Engineering and Water Recycling Consulting Independant Studies Scientific Advice for a Treatment Test using Insitu-Treatment for the removal of iron and manganese at Campus of University of Heidenheim Client: Ed. Züblin AG, Stuttgart Assessment of the applicability of the in-situ (Iron, Arsenic) removal in Mexico Examination of anaerobic degradability of splitflow samples from a paper mill Client: Hager & Elsässer GmbH, Stuttgart Examination of various Wastewater parameters from Voith Paper Technology Center Client: Voith Paper GmbH & Co. KG, Heidenheim Examination of Nitrification Inhibition Tests according to DIN EN ISO 9509 Client: Dr.-Ing. W. Götzelmann + Partner GmbH, Stuttgart Scientific Advice for a Test of a Press- and Filtersystem to compact waste from large kitchens Client: Bendig & Krause GmbH, Düsseldorf Scientific Advice for Planning and Optimisation of a decolouration step at the Wastewater treatment Plant Burladingen Client: Stadt Burladingen Jose Antonio Castillo (WASTE) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Phosphorus fractions and bioavailability Manuel Claus (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Investigating Water Reuse Potential of Textile Wastewater Francisco Javier Montoya Espinoza (WASTE) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR SWOT-Analysis of agricultural reuse of treated (WASTE)water Manoj Paneru (WASTE) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Analysis of the Relationship Between the Effluent Concentration of Phosphorus Fractions and the Effluent Concentration of Total Suspended Solids and Chemical Oxygen Demand in Municipal Wastewater Treatment Plants Pengfie Wang (Infrastructur Planning) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR (2010) Theses (Bachelor) Application of the test for inhibition of xoygen consumption by activated sludge at DIN EN ISO 8192on membran conentrates af TMP- and Deinking-effluents from the paper industry at oxidative and biologiclal treatment Anna Bachmann (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR 74 Water Quality Management and Water Supply WGW Theses (Diploma) Evaluation of the applicability of decentralised subterranean treatment of groundwater containing iron and arsenic for the provision of drinking water in rural India Andreas Buchner (Umweltsicherung, Hochschule Weihenstephan-Triesdorf) (2010) Supervisor: Prof. Prof. Dr. Asmus, Dipl.-Ing. R. Minke AOR Water and Salt Recovery by Using Nanofiltration and Reverse Osmosis comparing turkish and german textile rinsing water Ilka Johanna Eisele (geb. Scheiding) (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Application of Ozone and Fenton Reagent to membrane concentrates in the pulp and paper industry Katrin Erdmann (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Influence of pressure on fouling in gravity driven dead end ultrafiltration Maximilian Grau (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Analysis and Evaluation of Rainwater Harvesting as a Contribution to Resource-Efficiency in the Water Supply at Mercedes-Benz Plant in Sindelfingen Philip Koch (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Design of an Ultrafiltrationunit for treatment of surface water with high particel-concentrations in emergencies Ulli Lenz (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Assessment of the bioavailability of organic and inorganic phosphorus compounds using algal assay and Pi-Test Rike Nobis (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Development of a Drinking-Water Supply in Emergency for the City of Sindelfingen Carolin Marie Louise Salewski (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Develeopment, verification and application of a rapid test for the determination of the CaSO4und CaCO3-scaling inhibition efficiency of different antiscalants Zhaoping Shi (Umweltschutztechnik) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Hazard and risk assessment for the protection of drinking water source: Case study Burgberg Maren Burkert (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Investigation of the anaerobic biodegradability of waste water concentrates from several papermills Chen Fengdong (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Anaerobic treatment (thermophilc vs. mesophilic) of waste water concentrates from pulp and paper industry Ruben Manuel (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Investigation on the impact of sulphate on the anaerobic degradation of wastewater Ales Mujdrica (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR 75 Chair of Sanitary Engineering and Water Recycling Theses (Master) Assessment of the anthropogenic impact of drinking water quality for four water catchments south-east of Munich Development of an adapted concept of operation for rural water supply networks in Gunung Kidul, Java, Indonesia Immanuel Pache (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Alexander Mack (WAREM) (2010) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Optimisation of Riverwater pretreatment for subsequent microfiltration Optimization of biological aerobic treatment of membrane concentrates from pulp and paper industry in combination with other treatment processes Judith Christina Richter (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Decontamination of industrial wastewater containing pesticides in tropical climates: case study company CPC, Can Tho, Vietnam Eduard Rott (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Elevated Storage Tank Reißing -an important element for a safe water supply in region „Gäuboden“, Bavaria Tobias Wallinger (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Investigation of pH-Influence on anaerobic biodegradability of Deinking-Concentrate with high sulphate-concentrations Jingjie Xiong (Umweltschutztechnik) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR 76 Hoang Phuong (WAREM) (2011) Supervisor: Prof. Dr.-Ing. H. Steinmetz, Dipl.-Ing. R. Minke AOR Water Quality Management and Water Supply WGW Contact Dipl.-Ing. Ralf Minke, Akad. Oberrat Laboratory Tel.: +49 (0)711/685-65423 Fax: +49 (0)711/685-63729 E-Mail: [email protected] CTA Ellen Raith-Bausch CTA Giuseppina Müller Secretary´s office Tel.: +49 (0)711/685-65400 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Gabriele Glaßmann Tel.: +49 (0)711/685-63711 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Scientists M. Sc. Kenan Güney Tel.: +49 (0)711 / 685 - 63700 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Manuel Krauß Tel.: +49 (0)711 / 685 - 63700 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Andreas Neft Tel.: +49 (0)711 / 685 - 65425 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Eduard Rott Tel.: +49 (0)711 / 685 - 60497 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Thithi Vu Tel.: +49 (0)711 / 685 - 65849 Fax: +49 (0)711 / 685 - 63729 E-Mail: [email protected] Meanwhile quittet: Dipl.-Ing. Sabine Schmidt Dipl.-Ing. Quingfan Zhang 77 Chair of Sanitary Engineering and Water Recycling 78 Chair of Waste Management and Emissions o. Prof. Dr. -Ing. Martin Kranert Solid Waste Management Dr.-Ing. K. Fischer SIA Resources Management and Industrial Waste RIK Dipl.-Ing. G. Hafner Emissions EMS Dr.-Ing. M. Reiser Biological Air Purification ALR Prof. Dr. rer. nat. K.-H. Engesser 79 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Waste Management and Emissions The aim of research and education at the Chair of Waste Management and Emissions is to assure resource conservation and climate protection in a sustainable manner. Within this context, material flows that become waste as result of the use of resources, their treatment processes, along with the emissions from waste treatment plants, are considered. The topic of biological waste air purification is dealt in a special department within the chair. Considering that sustainable waste management gives priority to actions that counteract the generation of waste, fundamental waste management processes, which serve as cornerstones for sustainable resource management, span from the generation of waste and its avoidance, over the recovery of materials and energy from waste, up to the environmentally sound disposal of wastes and the control of the associated emissions. Education and research encompass a holistic approach to waste management, from waste avoidance, to the valorisation of wastes, up to the environmentally sound disposal of residual waste. Beside the lectures offered for Civil Engineering students, courses are specially tailored for the German taught Environmental Engineering program, and the international Master of Science program „Air Quality Control, Solid Waste and Waste Water Process Engineering – WASTE”. Dr.-Ing. Dipl.-Chem. Klaus Fischer is in charge of solid waste working group; Dipl.-Ing. Gerold Hafner leads the working group for resource management and industrial recycling and Dr.-Ing. Dipl.-Chem. Martin Reiser is responsible for the emissions working group. The research team for IGNIS project is led by MSc Nicolas Escalante and Dipl.-Geogr. Agata Rymkiewicz. Since 2011 Dr. Sc. agr. Dipl.-Ing. Sigrid Kusch heads the research group „Organic Resources“. Starting from October 1, 2011 Dr. Kusch is deputy Professor for Waste Management at the TU Dresden, in replacement of Prof. Dr.-Ing. habil. Dr. h.c. Bernd Bilitewski. Research is focused on the following fields: • Modelling, simulation and evaluation of waste management systems and concepts taking into consideration resource conservation and climate protection. • Biotechnological waste treatment processes (composting, anaerobic digestion), concentrating specially on process modelling and simulation of anaerobic systems, and regenerative energy recovery from organic waste and renewable resources. • Examination and evaluation of decentralized disposal systems for the joint treatment of solid waste and wastewater, as well as energy recovery (zero waste and wastewater processes e.g. tourist areas, islands). 80 • Infrastructure development for future megacities, particularly in developing and emerging economies. Scientific accompaniment of the implementation of sustainable material management systems and waste treatment technologies. • Surveys on food waste generation and development of food waste reduction strategies • Analysis of wastes and emissions • Laser based method of measuring methane emissions from area sources • Stabilization of landfills by in-situ aeration The Chair of Waste Management and Emissions is a member of several competence networks e.g. Competence Centre Environmental Engineering (Kompetenzzentrum für Umweltschutz Region Stuttgart (KURS e.V.)) and several standardization committees and scientific advisory boards, and as a result has established numerous contacts and cooperation agreements with several research institutions, public waste management authorities, private enterprises, and ministries. Cooperation with foreign universities and research institutions have been established through international research projects. Activities in Education The Chair’s staff, including lecturers, researchers and external readers, holds lectures covering several study courses, and supervises students from different academic programmes. From winter semester 08/09 the diploma programmes Civil Engineering and Environmental Engineering have been converted to Bachelor-/ Master programmes and modularized course are now being offered. Bachelor of Science programme Civil Engineering and Environmentl Engineering: • Waste Management and Biological Air Purification Master of Science Programme Civil Engineering: • Master course „Waste Treatment Engineering“ Master of Science programme Environmental Engineering: • Specialization field „Waste, Wastewater, Emissions“ with the Master courses „Waste Treatement Engineering“ and „Waste Management“, with 11 specialization modules. International Master Programme „WASTE“ (Established in 2002): • Sanitary Engineering, course Solid Waste Management • Mechanical and Biological Waste Treatment • Design of Solid Waste Treatment Plants Chair of Waste Management and Emissions • • • • • • • • • Industrial waste and contaminated sites Independent Study Biological Waste air purification and adsorption International Waste Management Sanitary Engineering: Practical class Ressourcenmanagement Environmental relevance Biogas Waste management systems International Master Programmee Planning“ and „WAREM“: • Solid waste Management • Ecology III „Infrastructure Seminars, laboratory work, design exercises, and excursions supplement the lectures. International Cooperation agreements in research and education have established with the Institute of Environmental Engineering and Biotechnology at the Tampere University of Technology (Finland) as well as the Dokuz Eylül University at Izmir (Turkey), Montanuniversität Leoben (Austria), the University of Salerno (Italy), the University of Thessaloniki (Greece), the Technical University of Temesvar (Romania), the Universitesi Saints Malaysia (Malaysia), the Guangxi - University (China), the Universidad Católica Boliviana „ San Pablo“ /Bolivia, the Universidad Costa Rica (Costa Rica), the Universidade Federal do Parana (Brazil), and the Universidade Federal do Santa Catarina (Brazil). Furthermore, several staff members of the Chair are active as associated lecturers at other institutions worldwide. It is important to highlight the activities of lecturers in the Master programme EDUBRAS held in cooperation the Universidade Federal do Parana in Curitiba (Brasil). Conferences Beyond research and academic activities, the Chair is involved in the continuing education and advanced training of professionals. Conferences organized by the Chair include the “Baden-Wuerttembergischen Waste Days”, hosted together with the Environmental Ministry of the Federal State of Baden-Wuerttemberg; the waste management colloquia; the landfill seminars, in association with the Environmental Protection Agency of the Federal State of Baden-Wuerttemberg; continuing education courses in cooperation with the Society of Engineers for Water Management, Waste Management and Agricultural Infrastructure (Bund der Ingenieure für Wasserwirtschaft, Abfallwirtschaft und Kulturbau (BWK)); as well as lectures in the field of waste management within the scope of the Distance education programme “Water and Environment” offered by the Bauhaus-Universität Weimar. Finally, in collaboration with the Turkish Environmental Ministry, the tradition of the German-Turkish Conferences has been revived. Committees Staff members are also involved in several committees, including academic councils, professional associations and advisory boards. Prof. Kranert is the Chairman of the Joint Commission of Environmental Engineering, and manager of this master program is Dipl-Biol. Andreas Sihler. Prof. Kranert is also member of the committees of the WASTE, WAREM, and MIP study programmes. Since April 1st, 2011 Prof. Kranert is the Dean of the Faculty fo Civil and Environmental Engineering. Furthermore, Prof. Kranert is member of the Alumni associations KONTAKT e.V. and WASTE Club. Additionally, Prof. Kranert is an active member of several professional associations and commitees. These include the German Institute of Stadardization (DIN), the Association of German Engineers (VDI e.V.), the Society of Engineers for Water Management, Waste Management and Agricultural Infrastructure (Bund der Ingenieure für Wasserwirtschaft, Abfallwirtschaft und Kulturbau (BWK)), Working Group for the Valorization of Municipal Solid Waste (Arbeitskreis zur Nutzbarmachung von Siedlungsabfällen (ANS e.V.)), German Association for Water, Wastewater and Waste (DWA e.V.), Association for Quality Control of Compost derived from Sewage Sludge , Association for Quality Assurance of Fertilization and Substrates (VQSD eV), the ORBIT Association, the European Compost Network (ECN), and the Federal Compost Quality Association (Bundesgütegemeinschaft Kompost (BGK)). Prof. Kranert is the chairman of the Quality Committee of the BGK, the Chair of the Trustees of the Professors of Waste Disposal Community for the German waste disposal industry, spokesman for the Group of Professors in Solid Waste Management in RETech under the initiative of the Federal Environment Ministry and a member of the Sustainability Advisory Board of the State of Baden-Wuerttemberg. Additionally, the chairholder serves as referee for several research funding institutions, scholarship foundations and accreditation agencies. Furthermore, several staff members play a leading role in the Competence Centre “Environmental Engineering” (Kompetenzzentrum für Umweltschutz Region Stuttgart (KURS e.V.)). 81 Chair of Waste Management and Emissions International Cooperation Project Indo-German-Center for Sustainability (IGCS) am IIT-Madras, Solid Waste Management Sustainable waste management is one of the most important issues in emerging countries. On the one hand side improper solid waste management causes serious environmental damages by polluting water, air, soils and landscape and can affect people’s health; in addition untreated methane emissions from dumpsites and landfills increase the effect of global warming. On the other hand side waste is a resource. By re-use, recycling and recovery of waste resource efficiency can be improved, energy and fertilizers are saved and soils are ameliorated by increasing fertility and water capacity. It also can lead to income generation for the population by valorizing the waste streams. 82 At the IGCS the focus will be on sustainable waste management systems, especially on organic waste. Organic waste covers more than two-thirds of municipal solid waste in India. This waste has a very small recycling quota in India up to now. By recycling this waste fraction harmful emissions can be reduced on a big scale, at the same time an organic fertilizer can be produced by composting and renewable energy is produced by biogas plants. Research aspects are potentials of organic waste, (separate) collection, waste composition, aerobic (composting) and anaerobic (biogas production) processes and products from organic waste. Beside biochemical, microbiological and process oriented questions the link to energy, water and land use plays an important role. Projects will include different scales; from lab scale up to technical scale new scientific findings will be generated. It has to be mentioned that adapted solutions concerning the situation in India and the very different socioeconomic structures between rural areas and megacities have to be taken into account. The cooperation between scientists in India and Germany will be deepened. In addition the link between theory and practice will be intensified. Chair of Waste Management and Emissions Conferences – Seminars – Colloquia Abfalltag Baden-Württemberg, 2011 „Rohstoffsicherung durch Abfallvermeidung und Recycling“, Schirmherrschaft: Franz Untersteller MdL, Minister für Umwelt, Klima und Energiewirtschaft des Landes Baden-Württemberg, 19. Oktober 2011, Haus der Wirtschaft, Stuttgart Stuttgarter Berichte zur Abfallwirtschaft, Volume 103, Oldenbourg Industrieverlag, ISBN 978-3-8356-3270-7 V. Deutsch-Türkische Abfalltage - TAKAG 2011, „Handlungsstrategien und Technologien für eine nachhaltige Kreislaufwirtschaft“, 27.-30. September 2011, Universität Stuttgart Stuttgarter Berichte zur Abfallwirtschaft, Volume 102, Oldenbourg Industrieverlag, ISBN 978-3-8356-3269-1 Doktorandenseminar 2011 in Neresheim, 18. bis zum 21. September 2011 Große Exkursion Umweltschutztechnik 2011 Fakultät Bau- und Umweltingenieurwissenschaften Universität Stuttgart, Juli 2011 Zeitgemäße Deponietechnik 2011 „Nachsorge und Nachnutzung mit Programmteil SufalNet4eu - Modellvorhaben für die nachhaltige Nachnutzung von Deponien“, 16. März 2011, ISWA, Stuttgart IV. Deutsch-Türkische Abfalltage - TAKAG 2010, „Ressourcenschutz durch Umsetzung nachhaltiger Abfallwirtschaft“, 25.-27. November 2010, Izmir IV. Türkisch-Deutsche Abfalltage - TAKAG 2010 Oldenbourg Industrieverlag GmbH, ISBN 978-3-8356-3228-8 Abfalltag Baden-Württemberg, 2010 „Neue Perspektiven der Kreislaufwirtschaft - Anforderungen an die Praxis“, Schirmherrschaft: Tanja Gönner, Umweltministerin Baden-Württemberg, 4. November 2010, Haus der Wirtschaft, Stuttgart Stuttgarter Berichte zur Abfallwirtschaft, Volume 100, Oldenbourg Industrieverlag, ISBN 978-3-8356-3229-5 Doktorandenseminar 2010 in Manigod 5. bis zum 8. September 2010, Manigod, Frankreich Zeitgemäße Deponietechnik 2010 „Perspektiven des Deponiebetriebs mit der neuen Deponieverordnung“, 11. März 2010, ISWA, Stuttgart Stuttgarter Berichte zur Abfallwirtschaft, Volume 99, Oldenbourg Industrieverlag, ISBN 978-3-8356-3199-1 Stuttgarter Berichte zur Abfallwirtschaft, Volume 101, Oldenbourg Industrieverlag, ISBN 978-3-8356-3240-0 83 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Organisation and scientific advising of conferences Prof. Dr.-Ing. Martin Kranert is member of the scientific advisory boards and organising comitees: Conference Chairman: Member of International Advisory Boards: Abfalltag Baden-Württemberg 2011 Rohstoffsicherung durch Abfallvermeidung und Recycling, Schirmherrschaft: Franz Untersteller MdL, Minister für Umwelt, Klima und Energiewirtschaft des Landes Baden-Württemberg, Stuttgart, 19.Oktober 2011 SARDINIA 2011 13th International Waste Management and Landfill Symposium, Cagliari (Italien), 03.-07. Oktober 2011 V. Deutsch-Türkische Abfalltage - TAKAG 2011 Handlungsstrategien und Technologien für eine nachhaltige Kreislaufwirtschaft, in Kooperation mit Prof. Dr.-Ing. Ertuğrul Erdin, Prof. Dr. Nuri Azbar und Assist. Prof. Dr. Görkem Akıncı, Stuttgart, 27.30. September 2011 Zeitgemäße Deponietechnik 2011 Nachsorge und Nachnutzung mit Programmteil SufalNet4eu - Modellvorhaben für die nachhaltige Nachnutzung von Deponien, Stuttgart, 16. März 2011 IV. Deutsch-Türkische Abfalltage - TAKAG 2010 Ressourcenschutz durch Umsetzung nachhaltiger Abfallwirtschaft, in Kooperation mit Prof. Dr.-Ing. Ertuğrul Erdin, Prof. Dr. Nuri Azbar und Assist. Prof. Dr. Görkem Akıncı, Izmir (Türkei), 25.-27. November 2010 Abfalltag Baden-Württemberg 2010 Neue Perspektiven der Kreislaufwirtschaft - Anforderungen an die Praxis, Schirmherrschaft: Tanja Gönner, Umweltministerin Baden-Württemberg, Stuttgart, 4. November 2010 Zeitgemäße Deponietechnik 2010 Perspektiven des Deponiebetriebs mit der neuen Deponieverordnung, Stuttgart, 11. März 2010 84 GIS 2011 1st International Conference on Waste Management in Developing Countries and Transient Economies, Mauritius (Afrika), 05.-08. September 2011 1. Wissenschaftskongress Abfall- und Ressourcenwirtschaft Straubing, 29. - 30. März 2011 12. Münsteraner Abfallwirtschaftstage Münster, 15.-16. Februar 2011 VENICE 2010 3rd International Symposium on Energy from Biomass and Waste, Venedig (Italien), 08.-11. November 2010 CRETE 2011 2nd International Conference on Industrial and Hazardous Waste Management, Chania (Griechenland), 05.-08. Oktober 2010 ORBIT 2010 7th International Conference Organic Resources in the Carbon Economy, Heraklion (Griechenland), 29. Juni 03. Juli 2010 WasteEng 3rd International Conference of Engineering for Waste and Biomass Valorisation, Beijing (China), 17.19. Mai 2010 Chair of Waste Management and Emissions Prizes and Awards Nicolas Escalante, MSc., Scholarship from the German Society for Waste Management (DGAW). Samuel Sasu, MSc., First prize for best poster at the 11th Annual IAHR-BW-Colloquium. Han Zhu, MSc., Honorable mention in the category ‚oral presentation‘ at the 1st DGAW Research Congress. Gülsen Öncu, MSc., Honorable mention in the category ‚poster presentation‘ at the 1st DGAW Research Congress. Group photo with the prize winners and organizers:(from left to right): Prof. Dr.-Ing. Gerhard Rettenberger, Dipl.-Ing. Dennis Blöhse, DGAW-President Dipl.-Ing. Thomas Obermeier, M.Sc. Han Zhu, Dipl.-Wi.-Ing. Eva Hamatschek, Prof. Dr.-Ing. Martin Faulstich (Photograh: Lehrstuhl für Rohstoff- und Energietechnologie, TU München) Samuel Sasu, MSc., received first prize for the best poster 85 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Doctoral Dissertations Treatment of Liquid Hazardous Waste and Industrial Highly-Loaded Industrial Wastewater by Photo-Fenton Process including Noxiousness Assessment Recently about 145 000 substances are identified which play an important role in global economic life. Since most of these substances sooner or later become components of waste and wastewater, one of the major tasks of environmental technology is to remove these substances from the biosphere, mainly by microbiological degradation in sewage plants. In order to get rid of remaining hardly degradable hazardous substances, chemical-technical destruction methods prior to biological sewage treatment must be developed – e.g. by using extremely strong oxidizers, like OH radicals. This is the field of so-called AOP (Advanced Oxidation processes), an appropriate technology for problematic industrial wastewaters and liquid wastes with volume flows of some m3/h. (Remark: In the current work, the terms liquid hazardous waste and industrial wastewater are used interchangeably since in practice there is no difference between them). The main goal of the current work is the further technical development of one of the most efficient AOPs – the photo-Fenton process using high-power UV-C radiation, hydrogen peroxide (H2O2) as an OH radical source, iron-II ions as homogeneous catalysts and, from case to case, titanium dioxide (TiO2) as a heterogeneous catalyst. Thus, the photo-Fenton process for the treatment of highly loaded and dark coloured industrial wastewaters needs an adequate photoreactor. Further investigations make it clear that conventional reactors with submerged UV-radiators are not qualified because of fouling problems concerning the UVradiator quartz protection tubes. Basic principle of the adapted short-term respirometry tests Test facility in countinous flow operation (pilot scale) Consequently a UV-Free Surface Reactor (UV-FSR), developed at University of Stuttgart, was used which is characterised by a contact-free arrangement between the UV-radiator and the treated liquid. This was achieved by positioning the unshielded UV-radiator a few centimetres above the liquid’s surface. Therefore, this reactor type has no fouling problems. The UV-FSR was studied in a laboratory scale (10 litres) with model wastewaters containing high concentrations of hazardous substances such as phenol, p-chlorophenol, 2,4-dichlorophenol, mixture of phenols and 2,4-dinitrotoluene but also with two heavily loaded real wastewaters. The reactor can be operated batch wise or continuously. 86 Technical concept of the treatment plant under study Chair of Waste Management and Emissions Another decision must be made: which UV-radiator type - low pressure radiator, medium pressure radiator or excimer radiator - is the optimal one for an UV-FSR? To this end, reactor characterisation numbers were created which included the reactor’s UV-C power, reactor volume and wastewater treatment time. Further considerations of the pros and cons made it obvious that the medium pressure UV-radiator is the optimal one since it provides maximal UV-C power with a minimum of required space on top of the UV-FSR. Besides conventional wastewater analysis, the success of treatment was evaluated by using a newly developed short-term (5 minutes) noxiousness test based on a modified activated sludge respiration test which was carried out before and after photochemical treatment. The noxiousness disappearance depends on the removal of the amount of noxious substances which are components of COD (Chemical Oxygen Demand), the catalyst and H2O2 addition during the treatment process. Noxiousness disappeared completely if enough H2O2 and Fe-II ions are available. If H2O2 and Fe-II ions are deficient, the noxiousness is not much influenced. Based on the experience with the laboratory scale UVFSR, another UV-FSR on a technical scale was studied (1,000 litres, 2 x 17 kW). Step test tracer experiments show that the 1 m3 reactor vessel is an almost ideally mixed reactor, and short circuit flow and dead zones are minimal. Another important aspect was examined as well: the transferability of pretest results from the 10-litre, 1.7 kW laboratory-scale UV-FSR to the 1,000-litre, 2 x 17 kW UV-FSR. For this purpose it was hypothesised that the above-mentioned reactor characterisation numbers are linearly related. This assumption was fully confirmed and it was experimentally demonstrated that the predictions concerning the most interesting wastewater treatment times are definitely correct. Based on these important pretests, the technicalscale UV-FSR was applied in practice, using a wastewater from an exhaust gas scrubber of an aluminium foundry. The wastewater (up to 70 m3 per month, COD - stage 2: Photochemical treatment with a 1 m3, 34 kW UV-FSR for lowering phenol index and cyanide of the aqueous phase. - Stage 3:Heavy metal (zinc) hydroxidic precipitation in a stirred tank reactor with subsequent sludge treatment. The photochemical processes were investigated in two modes: photo-Fenton mode and TiO2 mode. Both can fulfil the limits and both have advantageous but also disadvantageous ecological aspects: photo-Fenton mode: effluent salinity increase, TiO2 mode: handling with the health risky TiO2 powder. The investment cost of the multi stage wastewater treatment plant with a photochemical stage can be estimated to 236,000 € (excluding cost for planning, mounting and start-up), the running costs range about 96 €/m3. (For comparison: the current disposal route for the wastewater is incineration in a hazardous waste incineration plant, with a price of 400 €/m3). Ibrahim Abdel Hafiz Abdel Alim Abdel Fattah (2011) Supervisor: Prof. Dr.-Ing. Martin Kranert Co-Supervisor: Prof. Dr. rer. nat. Detlef Bahnemann (Leibniz-Universität Hannover) Prof. Dr. rer. nat. Jörg Metzger (Universität Stuttgart) Ibrahim Abdel Hafiz Abdel Alim Abdel Fattah „Treatment of Liquid Hazardous Waste and Industrial Highly-Loaded Industrial Wastewater by PhotoFenton Process including Noxiousness Assessment“, (2011), Forschungs- und Entwicklungssinstitut für Industrie- und Siedlungswasserwirtschaft sowie Abfallwirtschaft e.V. Stuttgart (FEI). München: Oldenbourg Industrieverlag GmbH, 2011. (Stuttgarter Berichte zur Abfallwirtschaft; Volume 102), 113 S., 62 pic., 20 tables, ISBN 978-3-8356-3245-5 up to 50,000mg/L ) was highly loaded with noxious pyrolysis products from resin decomposition and contains oil and suspended matter as well. Depending on the preset limit values for phenol index, cyanide and zinc, a multi stage wastewater treatment concept must be worked out. The concept shows that wastewater treatment entails not only AOP, but needs pre and post treatment stages, as follows: - stage 1:Oil and sediment separation within a large storage and calming tank. 87 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Co-Supervision of Dissertations and Habilitations Composting of organic waste: quantification and assessment of greenhouse gas emissions (2010) Jacob Kragh Andersen Supervisor: Prof. Thomas Christensen PhD, Department of Environmental Engineering, Technical University of Denmark, Kgs. Lyngby Co-Supervisor: Prof. Håkan Jönsson, Institute of Energy and Technology, Swedish Univerity of Agricultural Sciences, Uppsala, Swden Dissertation Systematischer Ansatz zur Abschätzung länderspezifischer Sachbilanzen im Rahmen der Ökobilanz (2010) Cecilia Tiemi Makishi Colodel Supervisor: Prof. Dr.-Ing. Klaus Sedlbauer, Lehrstuhl für Bauphysik, Universität Stuttgart Dissertation 88 Vom Substitutionspotential und der Energiebilanz des Komposts zum Entwurf eines Effizienzpasses für biologische Abfallbehandlungsanlagen (2010) Christian Springer Supervisor: Prof. Dr.-Ing. habil. Werner Bidlingmaier, Bauhaus-Universität Weimar Dissertation Chair of Waste Management and Emissions Editor of Books and Journals Guest Editor: Jungbluth, Oechsner, Kranert, Kusch: Special Issue: Biogas. Engineering in Life Sciences, Wiley-VHC, Weinheim. In progress Abfalltag 2011, Rohstoffsicherung durch Abfallvermeidung und Recycling, Stuttgarter Berichte zur Abfallwirtschaft, Band 103, Oldenbourg Industrieverlag, 2011 Treatment of Liquid Hazardous Waste and Highly-Loaded Industrial Wastewater by Photo-Fenton Process including Noxiousness Assessment, Autor: Ibrahim Abdel Hafiz Abdel Alim Abdel Fattah, Stuttgarter Berichte zur Abfallwirtschaft, Volume 102, Oldenbourg Industrieverlag, 2011 Zeitgemäße Deponietechnik 2011, Nachsorge und Nachnutzung mit Programmteil SufalNet4eu - Modellvorhaben für die nachhaltige Nachnutzung von Deponien, Stuttgarter Berichte zur Abfallwirtschaft, Volume 101, Oldenbourg Industrieverlag, 2011 V. Deutsch-Türkische Abfalltage - TAKAG 2011, Handlungsstrategien und Technologien für eine nachhaltige Kreislaufwirtschaft, Oldenbourg Industrieverlag, 2011 (Co-Editor) Münsteraner Schriften zur Abfallwirtschaft, Band 14, Münster, 2011 (Co-Editor) Guest Editor: Kusch, S.; Kranert, M; Reiser, M.: Progress in Landfill Management and Landfill Emission Reduktion. International Journal of Environment and Waste Management (IJEWM), Inderscience Publishers. IJEEV3N4 2011 Abfalltag 2010, Neue Perspektiven der Kreislaufwirtschaft - Anforderungen an die Praxis, Stuttgarter Berichte zur Abfallwirtschaft, Volume 100, Oldenbourg Industrieverlag, 2010 Zeitgemäße Deponietechnik 2010, Perspektiven des Deponiebetriebs mit der neuen Deponieverordnung, Stuttgarter Berichte zur Abfallwirtschaft, Volume 99, Oldenbourg Industrieverlag, 2010 Kranert, Martin, Cord-Landwehr, Klaus: Einführung in die Abfallwirtschaft, Vieweg + Teubner Verlag, 2010 IV. Türkisch-Deutsche Abfalltage - TAKAG 2010, Ressourcenschutz durch Umsetzung nachhaltiger Abfallwirtschaft, Oldenbourg Industrieverlag, 2010 (Co-Editor) Publications 2011 SASU, METZGER, KRANERT, KÜMMERER: Biodegration of the Antituberculosis Drug Isoniazid in the Aquatic Environment. CLEAN, Wiley VCH, submitted (2011) KRANERT, KUSCH, HUANG, FISCHER: Anaerobic Digestion of Waste. In Karagiannidis Hrsg.): Waste to Energy, Springer-Verlag London (in print), 29 p. (2011) KRANERT, FISCHER, LÖFFLER: Endbericht 2011 - Forschungsprojekt „Biogene Gase - Unterer Lindenhof“; Bioenergieforschungsplattform Baden-Württemberg. AP 2: Modellierung und Steuerung; TP 2.2: Modellierung und Steuerung von NaWaRo-Biogasanlagen unter Einsatz einer innovativen online Messmethode (NIRS), Steuerungssystem, Eigenverlag, (2011) SASU, KÜMMERER, KRANERT: Assessment of pharmacentical waste management at selected hospitals and homes in Ghana. Waste Management and Research, SAGE, accepted (2011) WERNER, ZAPF-GOTTWICK, KOCH, FISCHER: Toxic substances in Photovoltaic modules, Int. Conf. Photovoltaic, Fukuoko, Japan , 30.11.2011, Proceedings (2011) KRANERT, HAFNER, BARABOSZ, SCHULLER: Nahrungsmittelabfälle, eine unterschätzte Größe? Humustag der Bundesgütegemeinschaft Kompost, 30.11.2011 in Fulda, published in conference proceedings (2011) LÖFFLER, KRANERT, FISCHER: Controll of anaerobic digestion processes based on methane production and the state of the process. Poster beim 12th IAHRBW Colloquium, Technical and social vulnarabilities due to natural hazards, IAHR Young Scientist Forum, an der Universität Stuttgart ausgestellt, 03.11.2011 (2011) ZHOU, LÖFFLER, KRANERT: Model-based predictions of anaerobic digestion of agricultural substrates for biogas production. In: Bioresource Technology, Elsevier, Issue 102, p. 10819-10828 (2011) 89 Institute for Sanitary Engineering, Water Quality and Solid Waste Management ZHU, REISER, KRANERT: Estimation of methane emissions from landfills using laser measuring technology. BIT‘s 1st Annual Low Carbon Earth Summit, 19.-26.10.2011, Dalian, China, Proceedings, pp.912 (2011) KRANERT, ESCALANTE, RYMKIEWICZ: Future Megacities - A challenge for waste management research. 1. International Conference on Waste management in developing Countries and Transient economies, Mauritius, 5.-9. September 2011, proceedings CDROM, University of Mauritius, pages 1-12 (2011) ÖNCÜ, REISER, KRANERT: Aerobic in-situ stabilization of landfill Konstanz Dorfweiher-leachate quality after one year of operation. In: Proceedings SARDINIA 2011, Thirteenth International Waste Management and Landfill Symposium, 3-7 October 2011, S. Margarita die Pula, Cagliari, Sardinia, Italy. pp. 241-242 (Full paper in CD-ROM) (2011) ESCALANTE: Sustainable Waste and Resource Management Policy Design in Low and Middle-Income Countries through Dynamic Modeling and Simulation. In: 29th International Conference of the System Dynamics Society. Juli 24-29, 2011 in Washington D.C., USA (2011) KRANERT: Strategische Ansätze für eine nachhaltige Kreislaufwirtschaft. 5. Deutsch-Türkische Abfalltage, Stuttgart, 27.-30. September 2011, in: Kranert et al (Hrsg.): Proceedings Deutsch-Türkische Abfalltage 2011, Oldenbourg Industrieverlag, München, p. 103116 (2011) KRANERT, ESCALANTE, RYMKIEWICZ: Waste management research in a future megacity. 5. Deutschbrasilianisches Symposium Nachhaltige Entwicklung, 18. - 22.07.2011 Stuttgart, in Metzger et al (Ed.): Book of Abstracts, Brasilianisches Zentrum Uni Tübingen, p. 36 (2011) PANIC, KUSCH, KRANERT: Mikrogasnetze - mehr Energieeffizienz durch innovative Konzepte zur Verwertung biogener Gase. in: Kranert et al (Ed.): Proceedings Deutsch-Türkische Abfalltage 2011, p. 643-648 (2011) KUSCH, SCHÄFER, KRANERT: Dry digestion of organic residues. In: Sunil Kumar (Ed.): Integrated Waste Management - Volume I. InTech, Rijeka, 2011, Chapter 7, p. 115-134 (2011) ÖNCÜ, REISER, KRANERT: Leachate quality and quantity during aerobic in situ stabilization of old landfills (Poster article). In: Kranert et al (Ed.): Proceedings Deutsch-Türkische Abfalltage 2011, p. 635-641 (2011) KRANERT, CLAUSS: Stärkt die Wertstoff-Tonne das Recycling? 20 Jahre Abfallwirtschaft, Herstellerentwicklung, Produktpolitik, 14. - 15. September 2011. In: Bilitewski et al (Ed.) Beiträge zur Abfallwirtschaft und Altlasten, Volume 79 , Eigenverlag des Forums für Abfallwirtschaft und Altlasten, Dresden 2011, p. 93-100 (2011) FISCHER, HUANG, ESPINOZA: Integration of Bioplastics in Solid Waste Management systems, International Conference on Waste Management in Developing Countries and Transient Economies, Mauritius, Africa, Proceedings No. 104, 5.-9. September 2011 (2011) HUANG, FISCHER, KRANERT: Economic and Ecological Analysis of Household Biogas Plants in China , International Conference on Waste Management in Developing Countries and Transient Economies, Mauritius, Africa, Proceedings No. 103, 5.-9. September 2011 (2011) 90 STOCKL, LÖFFLER, OECHSNER, LEMMER, JUNGBLUTH, FISCHER, KRANERT: Überwachung und Regelung des Biogasprozesses. Poster beim Symposium „Perspektiven biogener Gase in Baden-Württemberg“, 04.07.2011 (2011) ÖNCÜ, REISER, KRANERT: The change of nitrogen loads in leachate during aerobic in situ stabilization of an old landfill in Germany: Results after one year of operation. In: Proceedings AGRO2011, 8th International IWA Symposium on Waste Management Problems in Agro Industries, 22-24 June 2011, Cesme, Turkey, pp. 199-205, (2011) STOCKL, LÖFFLER, OECHSNER, KRANERT: Online Messung flüchtiger Fettsäuren im Biogasfermenter mit Nah-Infrarot-Reflektions-Spektroskopie. In: VDI (Hrsg.): VDI Wissensforum „Prozessmesstechnik in der Biogasanlage“, 10.06.2011, Braunschweig. VDI Wissensforum, p. 63-74 (2011) KRANERT, BERECHET, CLAUSS: „Graue Energie in Konsumgütern - eine unterschätzte Größe. Müll und Abfall 4/11, p. 158-162, (2011) Chair of Waste Management and Emissions DOBSLAW, WILDE, ENGESSER: Potential waste air treatment techniques for emissions out of sewage sludge drying. In: Proceedings of Water & Industry 2011 IWA Specialist Conference Chemical Industry, May 1-4, 2011, Valladolid, Spain, 11 pages (2011) LÖFFLER, KRANERT, FISCHER: Control of anaerobic digestion proecesses based on methane production and the state of the process. In: Progress in biogas II. Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen; biogas production from agricultural biomass and organic residues; International congress, University of Hohenheim, March 30 - April 01, 2011. Kirchberg an der Jagst: Förderges. für nachhaltige Biogas- und Bioenergienutzung (FnBB e.V.), Teil 2 - Part 2, p. 113 - 116 (2011) LÖFFLER, KRANERT: Konzeption, Simulation und Versuchsbetrieb der Regelung des Vergärungsprozesses nach Methanproduktion und Prozesszustand. In: Deutsche Gesellschaft für Abfallwirtschaft e.V. (DGAW) (Ed.) 1. Wissenschaftskongress Abfall- Ressourcenwirtschaft am 29. und 30. März 2011 in Straubing. Wissenschaftsverlag Putbus, p. 91-96 (2011) ÖNCÜ, REISER, KRANERT: Influence of aerobic in situ stabilization of old landfills on leachate quality and quantity (Poster article). In: Deutsche Gesellschaft für Abfallwirtschaft e.V. (DGAW) (Ed.) 1. Wissenschaftskongress Abfall- Ressourcenwirtschaft am 29. und 30. März 2011 in Straubing. Wissenschaftsverlag Putbus, p. 315-318 (2011) ESCALANTE: Sustainable policy design through dynamic modeling and simulation of waste and resource management in future megacities. In: Deutsche Gesellschaft für Abfallwirtschaft e.V. Tagungsband. I. Wissenschaftskongress. Abfall- und Ressorcenwirtschaft. Am 29. und 30. März 2011 in Straubing, Wissenschaftsverlag Putbus, p. 177-180 (2011) ZHU, REISER, KRANERT: Evaluation of Landfill Methane Emission Rates with Tuneable Diode Laser Absorption Spectrometer. Deutsche Gesellschaft für Abfallwirtschaft e.V. (DGAW) (Ed.) 1. Wissenschaftskongress Abfall- Ressourcenwirtschaft am 29. und 30. März 2011 in Straubing. Wissenschaftsverlag Putbus, p. 137-139 (2011) RYMKIEWICZ: GIS-basierte Modellierung der abfallwirtschaftlichen Rahmendaten in den zukünftigen Megastädten, Fallstudie Addis Ababa. In: Deutsche Gesellschaft für Abfallwirtschaft e.V. Tagungsband. I. Wissenschaftskongress. Abfall- und Ressorcenwirtschaft. Am 29. und 30. März 2011 in Straubing. Wissenschaftsverlag Putbus, p. 219-224 (2011) KRANERT, FISCHER, LÖFFLER: Sachbericht 2011 Zukunftsoffensive IV; Forschungsprojekt „Biogene Gase – Unterer Lindenhof“; Bioenergieforschungsplattform Baden-Württemberg. AP 2: Modellierung und Steuerung; TP 2.2: Modellierung und Steuerung von NaWaRo-Biogasanlagen unter Einsatz einer innovativen online Messmethode (NIRS), Steuerungssystem, März 2011 (2011) SASU, KRANERT, METZGER, KÜMMERER: Health care waste management in Ghana- Case study on Pharmaceutical waste. In: Tagungsband zum I. Wissenschaftskongress Abfall- und Ressourcenwirtschaft am 29. und 30. März 2011 in Straubing / Deutsche Gesellschaft für Abfallwirtschaft e. V. DGAW (2011), Wissenschaftsverlag Putbus, p. 181-185 (2011) BI: Framing GHG Mitigation and Income Generation In MSW Management In Addis Ababa (A VER Case Study). In: Deutsche Gesellschaft für Abfallwirtschaft e.V. Tagungsband. I. Wissenschaftskongress. Abfall- und Ressourcenwirtschaft. Am 29. und 30. März 2011 in Straubing, Wissenschaftsverlag Putbus (2011) KUSCH, AZODANLOO, FRANK, HAFNER, BACHLER, KRANERT: Interdisciplinary approaches to advances in sustainable biogas production in Europe. In: FnBB/ GERBIO (Ed.): Progress in Biogas II - Biogas production from agricultural biomass and organic residues. Proceedings of the International Congress Progress in Biogas 2011, Stuttgart, p. 52-55 (2011) KRANERT, CLAUSS: Die Wertstoff-Tonne - Hintergrund, Motivation, Zielsetzung: 12. Münsteraner Abfallwirtschaftstage, 15.-16.02.2011, Münster, in: Flamme et al (Ed.),Conference Proceedings, Münster (2011) RYMKIEWICZ, ESCALANTE, KRANERT: Characterization of the Waste Management System in Addis Ababa. Wastesafe 2011, 2nd International Conference on Solid Waste Management in Developing Countries. Khulna, 13.-15.02.2011 (2011) 91 Institute for Sanitary Engineering, Water Quality and Solid Waste Management ESCALANTE, RYMKIEWICZ, KRANERT: Residential Waste Quantification and Characterization in Addis Ababa, Ethiopia. Wastesafe 2011, 2nd International Conference on Solid Waste Management in Developing Countries. Khulna, 13.-15.02.2011 (2011) KRANERT, CLAUSS: Solid Waste Management - from „end of pipe“ to sustainable solutions! 3rd IndoGerman Conference on Research for Sustainability: Water and Waste Management. Organized by BMBF and Department of Science and Technology, Government of India, JJT Delhi, New Delhi, 3.-4. Febr. 2011, BMBF, Publishing, Bonn, p.42-46 (2011) KUSCH, SCHUMACHER, OECHSNER, SCHÄFER: Methane yield of oat husks. In: Biomass and Bioenergy 35, 2011, p. 2627-2633 (2011) KUSCH, KRANERT, REISER (Hrsg): Special Issue on Progress in Landfill Management and Landfill Emission Reduction, Int. J. Environmental Engineering, Vol. 3, Nos. 3/4, 2011 (2011) SASU, KRANERT, METZGER, KÜMMERER: Investigating pharmaceutical waste management in Ghana. A glance at the world column of Waste Management on issue 31(2011) 2361-2364 (2011) KRANERT, ESCALANTE, RYMKIEWICZ: Megacities of Tomorrow - a Challenge for Solid Waste Management. 3rd Indo-German Conference on Research for Sustainability: Water and Waste Management. Organized by BMBF and Department of Science and Technology, Government of India, JJT Delhi, New Delhi, 3.-4. Febr. 2011, BMBF, Publishing, Bonn, p. 147-156 (2011) KUSCH, AZODANLOO, FRANK, HAFNER, BACHLER, KRANERT: Interdisciplinary approaches to advances in sustainable biogas production in Europe. In: FnBB/ GERBIO (Ed.): Progress in Biogas II - Biogas production from agricultural biomass and organic residues. Proceedings of the International Congress Progress in Biogas 2011, Stuttgart, p. 52-55 (2011) PANIC, HAFNER, KRANERT, KUSCH: Mikrogasnetze - eine innovative Lösung zur Steigerung der Energieeffizienz von Vergärungsanlagen. energie wasserpraxis, 2/2011, p. 18-23 (2011) KUSCH, KRANERT, BI, FISCHER: Influence of regulatory frameworks on biogas plant types - the example of Germany. BIT‘s 1st Annual World Congress of Bioenergy, Dalian, China, 2011, proceedings, p. 225 (2011) KUSCH, KRANERT, REISER: Preface to the Special Issue ‚Progress in Landfill Management and Landfill Emission Reduction’. International Journal of Environmental Engineering (IJEE), vol. 3, no. 4, 2011, p. 207-209 (2011) SASU, KRANERT, METZGER, KÜMMERER: Investigating pharmaceutical waste management in Ghana. A glance at the world column of Waste Management on issue 31(2011) 2361-2364 (2011) KUSCH, REISER, KRANERT (Hrsg.): Progress in Landfill Management and Landfill Emission Reduction. International Journal of Environmental Engineering (IJEE), Guest Edited Special Issue, vol. 3, no. 4, 2011, p. 207-409 (2011) REISER, LAUX, LHOTZKY, KRANERT: Pilotprojekt zur Deponiebelüftung und Methanoxidation an der Deponie Konstanz-Dorfweiher, Ergebnisse nach 1 Jahr Betriebszeit. Fachtagung Stillegung und Nachsorge von Deponien, Trier 10. - 11. Januar 2011, in Rettenberger, Stegmann (Ed.): Stilllegung und Nachsorge von Deponien 2011. Verlag Abfall aktuell, Stuttgart, 2011, p. 63-74 (2011) DOBSLAW, ENGESSER: Degradation of 2-chlorotoluene by Rhodococcus sp. OCT 10. Applied Microbiology and Biotechnology, DOI: 10.1007/s00253-011-35435 (2011) 92 2010 KRANERT, CORD-LANDWEHR: Herausgeber des Lehrbuchs Einführung in die Abfallwirtschaft. Vieweg+Teubner, Wiesbaden, 4th Edition 2010, 665 pages (2010) KRANERT, HUBER: Abfallwirtschaftliche Planung und Abfallwirtschaftskonzepte auf Ebene der öffentlichrechtlichen Entsorgungsträger. In: Kranert, CordLandwehr (Ed.): Einführung in die Abfallwirtschaft, Vieweg+Teubner, Wiesbaden, 4th Edition, p. 459-494 (2010) KRANERT, FISCHER, CIMATORIBUS: Biologische Verfahren. In Kranert, Cord-Landwehr (Ed.): Einführung in die Abfallwirtschaft, Vieweg+Teubner, Wiesbaden, 4th Edition, p. 185-292 (2010) Chair of Waste Management and Emissions KRANERT, BIDLINGMAIER: Abfallvermeidung. In Kranert, Cord-Landwehr (Ed.): Einführung in die Abfallwirtschaft, Vieweg+Teubner, Wiesbaden, 4th Edition 2010, p. 73-90 (2010) KRANERT: Biologische Abfallverwertung - ein Beitrag zum Klimaschutz? 17. Kolloquium Abfall und Altlasten, TU Dresden am 09.12.2010, Conference Proceedings (2010) REISER, LAUX, KRANERT: In-situ Aerobisierung von Altdeponien - das Projekt Deponie Dorfweiher. IV. Deutsch-Türkische Abfalltage TAKAG 2010, 25. 27. November 2010 in Izmir. In: Erdin, Kranert et al (Ed.): Ressourcenschutz durch Umsetzung nachhaltiger Abfallwirtschaft (TAKAG 2010), Oldenbourg Industrieverlag, München, p. 99 - 114 (2010) RYMKIEWICZ, ESCALANTE, KRANERT: Megastädte von Morgen – Eine Herausforderung für die Abfallwirtschaft“. In: Umweltschutztechnik No 8. p. 10. (2010) BI: Framing GHG Mitigation and Income Generation in the Municipal Solid Waste Management of Addis Ababa - A Case Study of VER. In: Konferenzband ‘Future Megacities in Balance’ Young Researchers’ Syposium in Essen: Am 9. - 10. Oktober 2010, Essen. p. 112-116. Organizer: Deutscher Akademischer Austausch Dienst. (2010) KRANERT, GOTTSCHALL, HAFNER, BRUNS, SCHIERE, SEIBEL: Composting or energy recovery? The example of green-waste based on CO2-balances. OVAM-Conference „Don‘t waste your bio waste“ 21. September 2010, Brüssel, Conference Proceedings, 10 pages, (2010) KRANERT, CLAUSS, BERECHET: Graue Energie in Konsumgütern - eine unterschätzte Größe. IV. DeutschTürkische Abfalltage TAKAG 2010, 25. - 27. November 2010 in Izmir. In: Erdin, Kranert et al (Ed.): Ressourcenschutz durch Umsetzung nachhaltiger Abfallwirtschaft (TAKAG 2010), Oldenbourg Industrieverlag, München, p. 135-146 (2010) ZHU, REISER, KRANERT: Contact-free methane measurements on landfills using tunable diode laser absorption spectrometer. Doktorandenschule Abfall 2010, Tagungsband zum 15. Doktorandenseminar der Abfalltechnik, 5.-8.09.2010, Manigod, Frankreich. pp.101-111 (2010) KRANERT, CLAUSS, BERECHET, ESCALANTE: Evaluation of Waste Management systems regarding the balance of carbon dioxide and costs. Venice 2010, 3rd International Symposium on Energy from Biomass and Waste. in: Cossu et al, Conference Proceedings (CD-ROM) (6 pages) (2010) ÖNCU, REISER, KRANERT: Influence of aerobic in situ stabilization of old landfills on leachate quality and quantity. In: Doktorandenschule Abfall 2010, Tagungsband zum 15. Doktorandenseminar der Abfalltechnik, pp. 43-52, 5.-8. September 2010, Manigod, Frankreich (2010) ESCALANTE, RYMKIEWICZ, KRANERT: Understanding waste management in a Megacity: experiences in Addis Ababa, Ethiopia. ISWA World Congress, 15.18. November 2010 in Hamburg, proceedings (10 pages) (2010) LÖFFLER, KRANERT: Regelung des Vergärungsprozesses basierend auf Methanproduktion und Prozesszustand. In: Bohn (Ed.): Doktorandenschule Abfall 2010. Tagungsband zum 15. Doktorandenseminar der Abfalltechnik, 5.-8.September 2010 in Manigod, Frankreich. Darmstadt: Verein zur Förderung des Inst. IWAR (Schriftenreihe IWAR, 211), p. 159-170 (2010) RAPF, RAUPENSTRAUCH, THOMANETZ, EDLINGER: Rückgewinnung von Phosphor aus Klärschlamm. Depotech 2010, Leoben, Österreich, 3. bis 5. November 2010; Oral presentation without article in conference proceedings (2010) RAPF, PFLANTZ: Determination of the Biological Activity of Industrial Wastes. Depotech 2010, Leoben, Österreich, 3. bis 5. November 2010. Poster presentation and article in conference proceedings, p. 769 - 772. (2010) RYMKIEWICZ, ESCALANTE, KRANERT: Megastädte von Morgen - eine wissenschaftliche Herausforderung für die Abfallwirtschaft. Müll und Abfall 8/10, p. 371378 (2010) KRANERT: Grünabfälle - besser kompostieren oder energetisch verwerten? EdDE-Veranstaltung 14.09.2010 IFAT 2010 München: Klima- und Ressourcenschutz durch Abfallwirtschaft - Forschungsergebnisse des Kuratoriums der EdDE e.V., Conference Proceedings (2010) ESCALANTE, KRANERT, TSEGAYE: Residential Waste Quantification and Characterization from Households. Results from sorting analysis. IGNIS Stakeholder Meeting 2010. Addis Ababa, 5.07.2010 (2010) 93 Institute for Sanitary Engineering, Water Quality and Solid Waste Management RYMKIEWICZ, TESHOME, SHIFERAW: Socioeconomic data collection. Results of validation of different housing types.” IGNIS Stakeholder Meeting 2010. Addis Ababa, 5.07.2010 (2010) LAUX, REISER, KRANERT: Pilot Scheme to Reduce the Aftercare Period on the Dorfweiher Landfill by in Situ Stabilization. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010), Proceedings, page 178. CD-Rom, pages 930-937 (2010) BERECHET, KRANERT, CLAUSS, ESCALANTE: Ecological Evaluation of Different Separate Collection Systems for Municipal Waste. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010), Proceedings, page 153, CD-ROM, pages 823-829 (2010) ESCALANTE, RYMKIEWICZ, KRANERT: Municipal Solid Waste Quantification and Characterisation in emerging megacities Experiences from Addis Ababa, Ethiopia. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.03.07.2010, Heraklion Crete, Greece (2010), Proceedings page 246; CD-ROM, page 1187 (2010) ESCALANTE, KRANERT, ASSEFA, MELAKU, GETANEH: Methodological Development for the Characterization of the Waste Management System and the Quantification of Material Flows in Addis Ababa, Ethiopia. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010) Proceedings, page 125, CD-ROM, pages 667-673 (2010) LÖFFLER, KRANERT: Simulation-Based Evaluation of Control Strategies for Anaerobic Digestion. Proceedings page 71: ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010), ORBIT Proceedings, p. 398-405 (2010) ZHU, REISER, KRANERT: Estimation of Methane Emissions from Landfills Using a Tuneable Diode Laser Absorption Spectrometer. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010), Proceedings, page 68, CD-ROM, pages 381-388 (2010) 94 ANTONOPOULOS, KARAGIANNIDIS, KONTOGIANNI, KRANERT, BERECHET, HAFNER, SCHMIDT, WEIDEMA, BRUNNER, VILLENEUVE, LEMIERE, REJMAN-BURZYNSKA, JEDRRYSIK, DAXBECK: Forecasting Organic Waste Quantities by Tracing Physical Flows and Stocks of Resources in EU-27 For the Next 25 Years. ORBIT 2010, Organic Recources in the Carbon Economy, 7th International Conference, 29.06.-03.07.2010, Heraklion Crete, Greece (2010), Proceedings, page 22; CD-ROM pages 109-116 (2010) KUSCH, SALTER: Biogas made in England. UmweltMagazin, Issue June 2010, p. 124-125 (2010) FISCHER, HUANG: Traditional natural technology together with new and helpful technologies for waste management, International Conference on Environmental Research and technology (ICERT), Proceedings, p.1-6, 2.-4. Juni 2010, Penang, Malaysia (2010) KRANERT, GOTTSCHALL, HAFNER, BRUNS, SEIBEL: Kompostierung oder energetische Verwertung von Grünabfällen? DWA-Seminar: Landwirtschaftliche und landschaftsbauliche Verwertung von Klärschlämmen und Bioabfällen. 19.-20. Mai 2010 in Marburg, Conference Proceedings (12 pages) (2010) COLODEL, SEDLBAUER, EYERER, KRANERT: Systematischer Ansatz zur Abschätzung länderspezifischer Produktökoprofile am Beispiel Portlandzement. Bauphysik 32 (2010), Issue 4, p. 233 - 239. (2010) HUANG, FISCHER, KRANERT: Development of Biogas Plants in Latin America and Africa. 3rd International Conference on Engineering for Waste and Biomass Valorisation. 17.-19.05.2010. Beijing, China, In: Nzihou, Liu Book of Abstracts and CD, proceedings Ecole des Mines d‘Albi Carmaux, Albi (F) (2010), page 161 (2010) FISCHER, HUANG: Degradable plastics from renewable resources, 3rd International Conference on Engineering for Waste and Biomass Valorisation, Proceedings, p.129-C, 17-19 Mai, 2010, Beijing, China (2010) HUANG, FISCHER, KRANERT: Household biogas plants in rural area in China. International Conference on Environmental Research and technology (ICERT). 2.-4.06.2010. Penang, Malaysia. Proceedings, page 605-610. (2010) Chair of Waste Management and Emissions KRANERT, CLAUSS, BERECHET, ESCALANTE: (17. 19.05.2010): CO2-Balance of systems for separate collection of recyclables. Development of Biogas Plants in Latin America and Africa. 3rd International Conference on Engineering for Waste and Biomass Valorisation. 17.-19.05.2010. Beijing, China, In: Nzihou, Liu Book of Abstracts and CD, proceedings Ecole des Mines d‘Albi Carmaux, Albi (F) (2010), p. 15 (2010) FISCHER: Geruchsminderung bei Abfallverwertungsanlagen, VDI-Wissensforum, Mannheim, 27.4.2010 (2010) KRANERT, LÖFFLER, HUANG: Workshop Biogas in China and Germany. Veranstaltung vom 26.04.2010. Leipzig. Veranstalter: Deutsches Biomasseforschungszentrum (DBFZ), Conference Proceedings (2010) KRANERT, GOTTSCHALL, HAFNER, BRUNS, SCHIERE, SEIBEL: Ökologischer und ökonomischer Vergleich der stofflichen und energetischen Nutzung von Grünabfällen. 43. Essener Tagung, 17. - 19. März 2010, Essen. In: Pinnekamp (Hrsg.): Gewässerschutz, Wasser - Abwasser, Volume 220, p. 48/1-48/12, Aachen 2010 (2010) KRANERT: Kreislaufwirtschaft - Luxus oder Notwendigkeit? Göppinger Technikforum e.V., Göppingen 17. März 2010. Published in conference proceedings. (2010) WILDE, DOBSLAW, ENGESSER: Applicability and limits of biological waste air treatment techniques. In: TISD2010 - The 3rd Technology and Innovation for Sustainable Development International Conference, March 4-6, 2010, (2010), Nong Khai, Thailand, 6 pages (2010) DOBSLAW, WOISKI, ENGESSER: Umsetzbarkeit der TA-Luft 2002 in Altanlagen: Ein Biowäscher zur kombinierten Behandlung von Abluft und Abwasser in einem Sonderabfallbehandlungsbetrieb. CIT - Chemie Ingenieur Technik, 82 (2010) Issue 12, p.2161-2170, DOI: 10.1002/cite.201000117 (2010) DOBSLAW, WILDE, ENGESSER: Möglichkeiten der ablufttechnischen Behandlung von Emissionen aus der Klärschlammtrocknung. VDI-Berichte 2110, p. 237242, (2010) Volume 2110, ISBN: 978-3-18-092110-5 (2010) KRANERT, FISCHER, LÖFFLER: Sachbericht 2010 Zukunftsoffensive IV; Forschungsprojekt „Biogene Gase – Unterer Lindenhof“; Bioenergieforschungsplattform Baden-Württemberg. AP 2: Modellierung und Steuerung; TP 2.2: Modellierung und Steuerung von NaWaRo-Biogasanlagen unter Einsatz einer innovativen online Messmethode (NIRS), Steuerungssystem, Februar 2010 (2010) SASU, KRANERT, METZGER, KÜMMERER: Assessing Pharmaceutical Waste Management in GhanaDegradation of Antituberculosis in the Aquatic Environment. In: Tagungsband des 6. Interuniversitären Doktorandenseminar “Abfallmanagement-Stand der Forschung an ausgewählten Lehrstühlen des Abfallmanagements” der Universitäten Stuttgart, Weimar, Essen, Innsbruck, Wien, Darmstadt (2010) KUSCH, KRANERT, REISER: Preface to the Special Issue ‚Progress in Landfill Management and Landfill Emission Reduction’. International Journal (2010) KRANERT, CLAUSS, BERECHET, ESCALANTE: Ökologische Bewertung der getrennten Sammlung von trockenen Wertstoffen aus Haushalten. 8. ASA-Abfalltage 24.- 26. Februar 2010 in Hannover. In: MBATechnologie-Schaltstelle für Stoffströme und Energieeffizienz. ORBIT Weimar, p. 321-330 (2010) KRANERT, GOTTSCHALL, BRUNS, HAFNER: Energy or compost from green waste? - A CO2-based assessment. Elsevier Waste Management 30 (2010), 697701 (2010) 95 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Contact o. Prof. Dr.-Ing. Martin Kranert Research Group Organic Resources Tel.: +49 (0)711/685-65500 oder 65495 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Dr. sc. agr. Dipl.-Ing. Sigrid Kusch Secretary´s office Tel.: +49 (0)711/685-65409 Fax: +49 (0)711/685-65460 E-Mail: [email protected] (seit 01.10.2011 TU Dresden) Gudrun Heinl IGNIS Research Project Tel.: +49 (0)711/685-65495 Fax: +49 (0)711/685-65460 E-Mail: [email protected] M.Sc. Nicolas Escalante Central functions of teaching and research Tel.: +49 (0)711/685-65456 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Geol. Detlef Clauß Dipl.-Geogr. Agata Rymkiewicz Tel.: +49 (0)711/685-65502 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Tel.: +49 (0)711/685-65456 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Solid Waste Biological Air Purification Dr.-Ing. Klaus Fischer Prof. Dr. rer. nat. habil. Karl-Heinrich Engesser Tel.: +49 (0)711/685-65427 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Tel: +49 (0)711/685-63734 Fax: +49 (0)711/685-63785 E-Mail: [email protected] Resource management and industrial recycling Environmental Engineering study course Dipl.-Ing. Gerold Hafner Study course manager Dipl.-Biol. Andreas Sihler Tel: +49 (0)711/685-65438 Fax:+49 (0)711/685-65460 E-Mail: [email protected] Tel.: +49 (0)711/685-65498 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Emissions Constanze Sanwald M.A. Dr.-Ing. Martin Reiser Tel.: +49 (0)711/685-65416 Fax: +49 (0)711/685-63729 E-Mail: [email protected] 96 Tel.: +49 (0)711/685-65413 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Chair of Waste Management and Emissions 97 Chair of Waste Management and Emissions Solid Waste Management Research topics: • Waste avoidance • Development of new waste management strategies • Simulation of solid waste management systems • Collection and transport of solid waste • Recycling of valuable materials • Biological treatment: composting and fermentation • New measurement methods for the analysis of odour, dust and germs • Decentralized waste management systems in tourist regions • Physical and chemical analysis of solid waste In our job, we’re on top of the pile Waste is a potentially valuable material in the wrong place. This statement is the central principle of many activities of our municipal solid waste section. Focal points are avoidance, utilisation and environmentally friendly treatment of municipal and commercial waste. Both ecological and economical aspects are dealt with. It has been shown, e.g., that avoidance of waste in commercial operations can be financially interesting for the companies concerned. We are intensively busy with the question of how waste management of the future may look. Some questions here are: which waste types should continue to be collected separately? Which mixtures of substances can be separated using new technical methods? Can part of the waste be economically transported by rail? Several research projects are occupied with the treatment of biological waste, among others with the questions: do pollutants exist in organic wastes? Are these pollutants reduced during composting? What energy potential is concealed in organic waste, if they are used in fermentation plants to generate biogas or employed in biomass power stations? For the creation of waste management concepts for communities or counties, the simulation and modelling of waste streams and utilisation techniques play a major role. Because even humans can become a waste problem from an ecological point of view, we have carried out investigations on the ecological effects of burials and cremations. For a number of communities, our investigations on decentral concepts for waste treatment in tourist regions are of particular interest. These island solutions allow processes for waste and sewage treatment to be combined with the generation of service water and power. Decentral and adapted technology is of prime importance for the sustainable development of third-world and fast-developing countries. This is why we have established cooperation and joint projects with institutions in Brazil, Costa Rica, Egypt, Turkey, China and other countries. 98 Solid Waste Management SIA Research Resource management in Baden-Wuerttemberg - Waste and anthropogenic storage as a resource Financing Institution: Umweltministerium Baden-Württemberg Contact: Baden-Württemberg has worldwide an important task as an industrial and technology centre. However, Baden-Wuerttemberg is also a resource-poor state that depends on imports for manufacturing its products. The aim of this study is to determine the need of (raw) materials and its quantities as well as to give an estimate of which resources can be found within the state and which imported materials can be replaced by own resources. A special focus will be the recovery of valuable materials from waste (from landfills, etc., or directly from industrial material flows). Dr.-Ing. Klaus Fischer Dipl. Ing. Sannah König Duration: 10/2011 - 03/2012 Important Resources for Baden-Württemberg Industry 99 Chair of Waste Management and Emissions SEBE - Sustainaible and Innovative European Biogas Environment In the European strategy for achieving the responsibilities of the Kyoto agreement, an ambitious target of supplying 20 % of the total energy supply from RE was set by the European national governments. One of the future key technologies for achieving this target is the production of biogas. But what type of technologies, policy measures and framework conditions do we need to promote and enforce the dissemination of biogas technology in Europe? The EU project SEBE (Sustainable and Innovative European Biogas Environment) is the biggest biogas project in the Central European region. Fourteen partners from nine different countries (Austria, Germany, Czech Republic, Hungary, Italy, Poland, Romania, Slovakia and Slovenia) are striving together for one common goal: the identification of legal, technological and economic framework conditions for ensuring a sustainable development of biogas technology in Europe. One key output is the development of network of new competence centers and knowledge transfer in new EU member states that lacking experience in developing innovative measures in the area biogas technology. Different Systems of Microgas Grids 100 The chair of Waste Management and Emissions of the University of Stuttgart is specifically dealing with the innovative topic of micro-gas grids (MGG) as one of the promising technical concepts for efficient use of energy from biogas. Furthermore the University of Stuttgart is also partly responsible for the assessment of economic, legal and logistical framework conditions. For the assessment of micro-gas grids a holistic approach is being applied. The overall objective is the analysis of the energy optimization potential of microgas grids for conventional biogas routes (e.g. biogas to CHP, biogas to bio-methane). Thereby economic, ecologic and technical parameters of the micro-gas concept will be analyzed. Solid Waste Management SIA Concretely following research questions are to be assessed in the micro-gas grid study? • What type of MGG asserted oneself in Germany and what future developments are to be expected? • How can MGG provide for optimized energy provision and what are necessary framework conditions? • What are necessary realization steps for successful implementation of MGG? • What is the potential of MGG to contribute to accelerated integration of bio-methane into the energy market? Based on the research results a guideline for biogas operators and a regional concept is planned to be published. Financing Institution: EU DG Research Contact: Prof. Dr.-Ing. Martin Kranert Dr.-Ing. Klaus Fischer Dr. Sigrid Kusch M. Sc. Olga Panic Project Partner: • ICS Internationalisierungscenter Steiermark GmbH, Austria; Resource Management Agency (RMA), Austria; Energiepark Bruck/Leitha, Austria • Institute for Sanitary Engineering, Water quality and Solid Waste Management, Germany; Association of promotion the use of Renewable Energies, Germany • Foundation for Sustainable Environment of South Great Plain, Hungary • Regional Development Agency, Poland; Central Mining Institute, Poland • ÖTGW-RCHS, Österreich-tschechische Gesellschaft, Wirtschaft, Czech Republic • Research Centre on Animal Production, Italy; Environment Park S.p.A. - Science & Technology Park for the Environment, Italy • Romanian Association for Promotion of Renewable Energy, Romania • Citizenship Association No Gravity, Slovakia • Scientific research centre Bistra Ptuj, Slovenia Duration: 03/2010 - 02/2013 Visit of the Biogas Plant Cooperativa Agricola Territoriale in Corregio/Italy in October 2011 101 Chair of Waste Management and Emissions Photovoltaic modules - environmental impact and recycling opportunities The „green technology“ photovoltaic also contains pollutants that due to the global installation of photovoltaic modules are distributed worldwide. Considering that photovoltaic modules have an average life span of 20 years, the expected amount of waste PV modules for the year 2030 results from the number of modules produced in the year 2010. While 5000 t of PV module waste were only expected in 2010, about 200000 t of PV module waste (per year!) are expected worldwide for the year 2030. The research project addresses several questions, such as whether pollutants of photovoltaic modules can get into the environment? A particular question is related with the possible contamination of rainwater coming from drainages of roof areas where PV modules are installed and its impact due to an infiltration into soil filters (ecological stormwater management), or an introduction into the local sewer system. Broken parts of Photovoltaic modules 102 A question that has not been answered yet deals with the consequences that might be expected if modules or shredded module parts are not disposed of correctly (e.g. through the municipal waste, waste glass containers). The project also seeks to identify possible organization ways for the collection of used PV modules and describe possible requirements for an efficient recycling system of waste modules. Financing Institution: Umweltministerium Baden-Württemberg Contact: Dr.-Ing. Klaus Fischer Project Partner: Lehrstuhl für Hydrochemie und Hydrobiologie, Institut für Photovoltaik der Universität Stuttgart Duration: 01/2010 - 11/2011 Solid Waste Management SIA City with Energy Efficiency - SEE Stuttgart Optimization potential The project LAKE traced to the following objectives: 1. Development of a macroscopic balance model 2. Development of a microscopic model strategy 3. Identification of optimization potential 4. Creating a Road Map „energy“ by 2050 5. Implementation of identified actions 6. Evaluation of operations and performance review Prerequisite for a sustainable society is in addition to economic prosperity and social well-being also a healthy environment. It is necessary to reduce emissions of pollutants - in particular climate-relevant pollutants - and to increase significantly the efficiency of resources use. As undisputed the need for energy and resource efficiency in society and politics is, so difficult is the setting of concrete goals and the understanding on the „right“ strategies and actions. Reasons for this include the difficulties of assessing impact of measures in the framework of formulation of policy / planning strategies (overall effectiveness, as well as the contribution of well targeted measures to achieve the objectives) and the uncertainty about the nature and scope of opportunity costs in the case of scope achievement as well as the potential distributional effects of social costs. A suitable tool for municipal planning strategy may be models that allow assessing the effects of various measures in terms of their individual as well as cumulative effect. In this framework, with the project SEE it is meant to develop a macro and a microscopic balance and strategy model to support the development of the local strategies and action planning. The project SEE has the following objectives: 1. Development of a macroscopic balance model 2. Development of a microscopic strategy model 3. Identification of optimization potential 4. Creating a Road Map „energy“ up to 2050 5. Implementation of identified measures 6. Evaluation of measures and performance review Key activities of the Chair of Solid Waste Management and Exhausted Air: • Macroscopic balance model for the energy consumption of consumer goods in Stuttgart • Microscopic balance and strategic model for energy consumption of households in Stuttgart caused by the consumption of goods • Development and evaluation of measures in the waste and consumption area Balance and strategy model Evaluation of performance Implementation of optimization measures Balance and strategy model Financing Institution: Bundesministerium für Bildung und Forschung BMBF, Förderinitiative „Wettbewerb Energieeffiziente Stadt“ Contact: Prof. Dr.-Ing. Martin Kranert M.Sc.agr. Annika Hilse Dipl.-Geol. Detlef Clauß Projekt Partner: Landeshauptstadt Stuttgart , EnBW Energie Baden-Württemberg AG, Fraunhofer-Institut für Bauphysik, Universität Stuttgart • Institut für Eisenbahn- und Verkehrswesen (IEV) • Institut für Raumordnung und Entwicklungsplanung (IREUS) • Institut für Siedlungswasserbau, Wassergüteund Abfallwirtschaft; Lehrstuhl für Abfallwirtschaft und Abluft (ISWA, AFW) • Institut für Sozialwissenschaften; Internationales Zentrum für Kultur- und Technikforschung (IZKT); Interdisziplinärer Forschungsschwerpunkt Risiko und Nachhaltige Technikentwicklung (ZIRN) • Institut für Straßen- und Verkehrswesen; Lehrstuhl für Verkehrsplanung und Verkehrsleittechnik (VuV) Duration: 04/2009 - 10/2014 103 Chair of Waste Management and Emissions Composition of Municipal Solid Waste from selected Urban Structures in Romania In the framework of the increasing concern about the environmental protection in Romania in year 2007 was initiated a cooperation between the environmental ministries Umwelt Ministerium Baden Württemberg and Ministerul Mediului Romania. This cooperation was meant to support Romania in finding the appropriate solutions for the treatment of municipal solid waste. The first step was to define the composition of the municipal solid waste from Romania. In this scope, at the request of Umwelt Ministerium Baden Württemberg, the Institute for Sanitary Engineering, Water Quality and Solid Waste Management carried on the research project in collaboration with “Politehnica” Timisoara University, as well as Retim (Timisoara) and Goscom (Vaslui). In agreement with National Environmental Protection Agency from Romania there were selected two locations with different economic development levels, Timisoara a city with a dynamic development and low unemployment rates and Vaslui, a city with a precarious economical situation and high unemployment rates. Due to financial reasons Vaslui could not continue participating in the project. Therefore the sorting campaigns were organized only in Timisoara, in two different seasons (summer and autumn). Sorting waste in Timisoara In Timisoara were analyzed the content of the container from the conventional collection system as well as the “wet container” from a new introduced collection system, in which the “wet container” is meant for the residual waste while the “dried container” for the recyclable materials. The samples were collected from residential areas with well determined features and analyzed on the basis of the methods described by the Guidelines Brandenburg. The results indicated the presence of the biological waste in a high percentage, as well as a high quantity of plastics, paper and glass, therefore a considerable potential for material and energy recovery. Comparison Between 1-Container and 2-Containers Systems [Mass.-%-MS] Organic waste Organic waste (<40mm) Plastics Paper, cardboard Non organic waste(<40mm) Construction waste Glass (excluding flat) Diapers Textiles and shoes Composite materials Hazardous waste Metals Inert materials WEEE 0% 5% 10% 15% 20% 25% 30% 35% 40% Comparison between 1-container-system and 2-containers-system from Timisoara and the data from BadenWürttemberg 1-Container-System 104 2-Containers-System: Residual waste bin Solid Waste Management SIA Financing Institution: Umweltministerium Baden-Württemberg Contact: Prof. Dr.-Ing. Martin Kranert Dr.-Ing. Klaus Fischer Dipl.-Ing., M.Sc. Mihaela Berechet Dipl.-Ing. Oliver Schiere Project Partner: Universität Stuttgart, Institut für Siedlungswasserbau, Wassergüte- und Abfallwirtschaft - Lehrstuhl für Abfallwirtschaft und Abluft; Universitatea Politehnica „Timisoara“, Facultatea de Hidrotehnica; Agentia Nationala de Protectie a Mediului; Retim Ecologic Service SA; Goscom Vaslui SA Duration: 2008-2009 Modelling and Control of Agricultural Biogas Plants Including an Innovative Online Measuring Method (NIRS), Control System With the change of energy production to renewable energies in progress, the amount of biogas plants, especially of agricultural biogas plants utilizing manure and energy crops, are continues growing. Due to limited availability of (crop)land and keeping in mind maximum levels of sustainable expansion of the biomassbased anaerobic digestion technology, more and more attention concentrates on technical as well as systemic further development to use the existing potentials as good as possible. This accounts especially for the potential of systemic and technical – measurement and process engineering – innovations for the actual pool of existing biogas plants as well as for improvements in the area of crop production. Thematically this is where the research project “Modelling and Control of Agricultural Biogas Plants” was established within the “research platform on bioenergy, Baden-Württemberg”. On the process level possibilities to optimize the operation of the anaerobic digestion process with applicable control strategies were investigated with the help of process simulations (ADM1) and were then tested in experiments within this project. The investigations in this context refer to the utilization of the Schematic set-up of the control strategy 105 Chair of Waste Management and Emissions near-infrared spectroscopy (NIRS) as an innovative online measuring method, which is investigated within a partner project at the State Institute of Agricultural Engineering and Bioenergy at the University of Hohenheim. The online-availability of measurements with NIRS, opens up the possibility to include those measurements directly into the control of the process. The control of the process aims to optimize the anaerobic digestion process according to the settings of the plant operator. Usability, automation, resource efficiency, low-cost and easy implementation as well as safety in terms of process stability and reliability of the control are namely the further objectives a control strategy developed has to accomplish. A control strategy (s. figure 1) was developed, adjusted and tested on the model, without cost- and time-consuming actual experiments. Subsequently experiments were conducted on lab-scale digesters. The general capability of the developed control concept could be confirmed in simulations and first operational experiments (s. figure 2). Financing Institution: Federal State of Baden-Württemberg: Ministry for Rural Areas and Consumer Protection, Baden-Württemberg Stiftung gGmbH. Contact: Prof. Dr.-Ing. Martin Kranert Dr.-Ing. Klaus Fischer Dipl.-Ing. Daniel Löffler Project Partner: Direct cooperation with: University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA 740) Research platform on bioenergy, Baden-Württemberg: University of Hohenheim, Reutlingen University; University of Applied Forest Sciences Rottenburg, Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden Württemberg (ZSW), Karlsruhe Institute of Technology (KIT), University of Stuttgart (IFK, IER), Ministry of environment, climate and energy Baden-Württemberg Duration: 10/2008 – 12/2011 Experimental and simulated results of the control operation 106 Solid Waste Management SIA IGNIS – Income Generation and Climate Protection through the Sustainable Valorisation of Municipal Solid Wastes in Emerging Megacities (IGNIS) Increasing urbanization in rapidly growing urban centres in developing countries has lead to the increase environmental pressure on natural resources, but at the same time it opens an opportunity window for the exploration of new approaches in order to help these countries direct their efforts towards sustainable development. The research project “IGNIS - Income Generation and Climate Protection through the Sustainable Valorisation of Municipal Solid Wastes in Emerging Megacities” strives to develop a new concept for the improvement of waste management and the local environment while generating new workplaces, increasing general welfare, considering occupational safety and health and reducing greenhouse gas emissions. Funded by the German Ministry of Education and Research (BMBF) through it Future Megacities programme, the IGNIS project takes on a systemic research approach to resource recovery from wastes in large urban centres in developing countries by implementing the project in the Ethiopian capital, Addis Ababa. The project consortium, composed by the AT-Association, the Universitaet Stuttgart, the Institute for Future Energy Systems and the Federal Institute for Occupational Safety and Health, from Germany, and the Environmental Development Agency for the Third World, Faculty of Technology and the Centre for Regional and Local Development Studies of the Addis Ababa University and the Environmental Protection Agency of Addis Ababa, from Ethiopia, will will holistically assess constraints of the existing waste management system, introduce decentralized pilot projects and evaluate their environmental, economic and social impacts, develop a decision support system and carry out extensive training of the local authorities and personnel. At the end of the project, the extent to which the results and insights gained from research are transferable to other emerging megacities will be evaluated. Within the scope of the IGNIS Project understanding the material and energy flows that move through the urban metabolism is of great importance in order to establish their environmental, economic and social relevance. Materials consumed by households, commercial and public institutions are converted into wastes and enter the municipal waste management system. A large part of these materials are landfilled without treatment or recovery, while only part of the secondary resources with market value are recovered and reintroduced in the economic cycle. Informal solid waste management in Addis AbebaSeptember 2009 Socio-Economic Interview of Households in Addis Abeba, November 2009 In most megacities in developing countries, the fate of postconsumer materials, organic waste and other residuals are not well known. This is a result of the lack of a system of data collection along the waste management chain. In many cases there is no systematic recording and assessment of the amount of waste collected and transported by the municipal or private enterprises. Additionally, some of the final disposal sites lack of a weighing bridge to register the amount of residues landfilled and little or no information is 107 Chair of Waste Management and Emissions available about the streams of valuable materials recovered and recycled. The previous situation is compounded by the fact that large amounts of recyclables are recovered by an army of informal waste pickers, which is practically invisible to the waste management authorities, that scavenge for materials on the streets and at the final disposal sites. Based on the case study of the Ethiopian capital, the IGNIS project strives to structure the waste management system by identifying the actors that determine the dynamics of the system and by quantifying the material flows. For this purpose the project consortium is currently developing a methodology to characterize in detail how the different subsectors of the waste management chain function. This involves eliciting which factors influence the performance of the collection, transportation and street sweeping sector, which interactions determine how much material is recovered and recycled by both the formal and informal recovery sectors, and what are the reasons for the amount of waste currently being disposed. Residential waste sorting analysis 108 In order to guarantee that the project findings are well founded, a reliable data basis must be collected. This data basis includes relevant information of spatial, socioeconomic, and waste management structures, which in many cases is missing or incomplete. The quantification and characterization of the resource potential in the municipal wastes being generated actually and in the future is a key step towards completing this data pool. Especially for planning purposes, it is not enough to know the composition of the waste, but also the per capita waste generation. For this purpose, standard methodologies used in industrialized countries for the characterization and quantification of municipal solid wastes have been taken as a basis, and have been adapted and synthesized into a solid waste analysis procedure appropriate for considering the restrictions and local conditions. Since working conditions during waste collection and sorting were not comparable with the European situation, occupational safety and health standards for the respective activities had to be adapted as well by using Solid Waste Management SIA the locally procurable means. Efficient and inexpensive solutions on a low technical level were developed and integrated into the solid waste analysis procedure. As a result of the methodological development and validation, an applicable waste sorting analysis procedure was achieved, while finding a compromise between data quality, workers safety and health and available resources. Furthermore, since standard sample survey techniques have been taken into consideration, sampling errors and uncertainty levels have been accounted for, thus guaranteeing the collection of statistically representative data. Financing Institution: Bundesministerium für Bildung und Forschung BMBF Contact: Prof. Dr.-Ing. Martin Kranert Dipl.-Geogr. Agata Rymkiewicz M.Sc. Nicolas Escalante Project Partner: Universität Stuttgart, Lehrstuhl für Abfallwirtschaft und Abluft; Verband zur Förderung angepasster, sozial- und umweltverträglicher Technologien e.V. (AT-Verband); Bundesanstalt für Arbeitsschutz und Arbeitsmedizin (BAUA); Institut für Zukunftsenergiesysteme (IZES); Environmental Development Action in the Third World (ENDA); Addis Abeba Universität, Faculty of Technology; Addis Abeba Universität, Institute of Regional and Local Development Studies; Addis Abeba Environmental Protection Agency (EPA) Duration: June2008 - June 2013; Project evalution autumn 2010 Internet: www.p-42.de/ignis GIS Map, Socio-Economic Interview of Households in Addis Abeba, November 2009 109 Chair of Waste Management and Emissions Development of new technologies for production and application of plastics from renewable resources. The annual output of petrochemical plastics of the global production from crude oil is more than 300 million tonnes. Plastics are used in numerous applications for our daily life. But after their useful life as plastics materials they will be disposed in landfills, dumpsites, or delivered to composting plants or to incinerators. The degradability in general is very slow, in the case of landfills we are expecting to last hundreds of years. In incinerators they are used for producing energy, but with this oxidising process plastics from crude oils are contributing to increasing amounts of the greenhouse gas carbon dioxide (CO2). Degradability of plastics is known as a non biotic process with the influence of UV, light and oxygen. A second way for degradation is the biological influence of micro organisms. Also some of the petrochemical plastics can be biologically degraded, e.g. polyesters. But also in this case we will have increasing amounts of the greenhouse gas CO2. Degradability of lignin based bioplastic - Respirometric Test Therefore during the last years new plastics were developed, plastics from renewable resources and biologically degradable by micro organisms. Our own project research was done with a very new degradable plastic from lignin, a by-product in the cellulose pulping process for papermaking .The degradability of this new product based on lignin was tested in aerobic conditions with respirometric tests and also in a composting process. The velocity of the degradation process is depending on the composition of the plastics. In the respirometric tests we found for the different products a degradation rate of about 30% up to 80 % in a time of 80 days, using longer testing time, the degradation rate was increasing up to 50 % up to 100 % in 120 days. Degradability of lignin based bioplastic - Respirometric Test Sponsorship: Plastics have an important impact on the environment. Bioplastics can be produced from renewable raw material and are partially biologically degradable. Currently the production of bioplastics is relatively low. In the case of bigger amounts this material should be integrated in the waste management. The new bioplastics based on lignin that we have analyzed could be considered as well degradable in the respirometric tests. AIF The usability for many applications seems to be really good. As it is a material from renewable resources, the degradation process will not give any influence to the greenhouse effect. April 2008 - March 2010 110 Projekt partner: • Fa. Tecnaro GmbH • Fa. Bauer Kunststofftechnik • Institut für Siedlungswasserbau, Wassergüteund Abfallwirtschaft; Lehrstuhl für Abfallwirtschaft und Abluft (ISWA, AFW) Duration: Contact: Dr.-Ing. Klaus Fischer Dipl.-Ing. Jingjing Huang Solid Waste Management SIA WasteNet – A new international network for research activities in the area of sustainable solid waste management WasteNet brings together 12 partners from 3 continents committed to action for conflict transformation through sharing of skills, knowledge, experiences and resources in the area of sustainable solid waste management. WasteNet members from universities and institutions participating in the programme are as follows. Latin America: Costa Rica, Bolivia, Columbia, Brazil, Chile Asia: China, Malaysia und Thailand Europe: Finland, Turkey und Germany. Aim of WasteNet? Developing countries have sometimes restricted access to information sources concerning solid and hazardous waste management which has led to a generalised lack of knowledge about the problem, resulting in nonexistent, inappropriate or incomplete technical, political and operational measures. On the other hand, countries with advanced know-how about waste management and treatment technologies are unaware of the research and policy needs in developing countries, being unable to access these potential markets. Through the establishment of an international knowledge network for the advancement of sustainable and appropriate waste management both issues can be addressed. In this sense, WasteNet strengthens the international research in sustainable and appropriate waste management strategies and technologies. WasteNet can thereby act as a platform for communication with its highly qualified scientists from Latin America, Asia and Europe to intensify multilateral exchange of experiences and knowledge in the field of waste management. The first meeting of Latin America Partner took place in October 2007 in Bogota, Columbia. Despite some differences between individual partner countries, the evaluation of solid waste management in urban and rural areas has shown a surprisingly high compliance. Recyclable Waste Seperation in Bogota 111 Chair of Waste Management and Emissions One important insight gained through this meeting is: Whereas almost all big cities in each partner country can ensure a relatively good collection and treatment of waste, the situation in the rural areas is yet completely unsatisfying. In many cases only a minor part of the waste collected, the disposal happens in illegal dump sites, in rivers or anywhere in the landscape. Even that the situation in the partner countries is not entirely comparable, our estimations still show that more than 50% of waste appearance occurs in rural areas and therefore is treated inadequately. The environmental impact on soil, ground and surface water and on the atmosphere is without any doubts profound. A further critical point has been elaborated: Waste from hospitals and hazardous waste (industrial as well as household waste, e.g. batteries or fluorescent tubes). As one of the first Latin-American countries, Columbia compiles a cadastral register of hazardous waste. The next step will be the development of waste treatment and disposal facility plants. Results, examples and other useful information including dictionary for solid waste management in German, English, Spanish can be found in our website www.wastenet.de . Financing institution: EU, DG International Cooperation INCO Project partner: • Costa Rica; Universidad de Costa Rica San Pedro de Montes de Oca, San Jose • Brazil; Centro Integrado de Tecnologia e Educação Profissional da Cidade Industrial de Curitiba • Bolivia; Catholic Bolivian University „San Pablo“, La Paz • Chile; Technical University Federico Santa María, Valparaiso • Colombia; Los Andes University, Bogota • Thailand; King Mongkut‘s Institute of Technology North Bangkok • Malaysia; University Sains Malaysia, Penang Duration: 2007 - 2008 Contact: Dr.-Ing. Klaus Fischer M.Sc. Angkhana Klongkarn M.Sc. Maria Espinoza Photo of Participants - WasteNet Meeting at Los Andes University in Bogota /Columbia 112 Solid Waste Management SIA FORWAST: Project full title: Overall mapping of physical flows and stocks of resources to forecast waste quantities in Europe and identify lifecycle environmental stakes of waste prevention and recycling. Project summary: The FORWAST project intends to provide: • an inventory of the historically cumulated physical stock of materials in EU-27 (EU-25 plus Romania and Bulgaria), and to forecast the expected amounts of waste generated, per resource category, in the next 25 years. • an assessment of the life-cycle wide environmental impacts from different scenarios of waste prevention, recycling and waste treatment in the EU27. The work programme is designed to favour the synergy between these objectives, by applying a generic model for material flows, stocks and emissions. The proposed model is an environmentally extended, physical, quasi-dynamic input-output model. This model combined with a robust method of Material Flow Analysis will guide the mining of new data, which is the main focus of the project. It will take place as a combination of “in-depth” studies in selected countries where highquality statistics are available, and an EU-wide effort consolidating and calibrating different statistical and technical data sources. The model will be applied to historical time series of resource inflows into the economy, and calibrated to known quantities of waste generation, the core question being to estimate coefficients for stocks life time for the different materials (sand/gravel, wood, metals, paper, etc.) and interpret dynamically the causes of the variation of stocks (accumulation versus waste generation or dispersive losses). The policy relevance of the project will be strengthened by the definition of 25 years horizon scenarios of waste generation combined with technological options for waste prevention and recycling. The waste with the higher stakes to reduce environmental pressures will be assessed trough simulations. It is expected that the FORWAST project will bring a new insight into Life Cycle Thinking, and above all, more confidence in the use of environmental indicators in natural resources and waste management policies. Project objective(s): The FORWAST project intends to provide comprehensive and validated data on the material flows, stocks and environmental pressures coming from the different sectors of the life cycle of resources to waste. In the wider context of sustainable development and environment protection, the connections between the use of natural resources, their accumulation in Conceptual system description 113 Chair of Waste Management and Emissions economy and waste generation and management need to be more clearly understood. Waste management policies may affect potentially all sectors. Their influence on the use of natural resources must also account for the potential recovery of these resources from stocks, the technical and economical constraints of recycling, the side effects on the by-products associated with natural resources, and at the end, the global balance of the environmental costs and benefits. The current uncertainties on the environmental stakes of waste policies are pre-dominantly due to a lack of real physical data on the quantities and qualities of flows of resources, either natural or coming from waste recovery. Particularly important for the latter is to account for the actual stocks of these resources that will end-up in the waste flows in the future. The objectives of the proposed FORWAST project are therefore to: • Provide an inventory of the historically cumulated physical stock of materials in EU-27 (EU-25 plus Romania and Bulgaria), and to forecast the expected amounts of waste generated, per resource category, in the next 25 years. • Provide an assessment of the life-cycle wide environmental impacts from different scenarios of waste prevention, recycling and waste treatment in the EU-27. Materials balance for sand and Gravel in Austria 2001 114 With this STREP proposal, sound experiences on resources and waste management are combined in order to give direct decision and policy support. The partnership experience is mainly characterised by: • European and National experience in policy support; • The access to data from various countries (particularly East and South); • Availability of a successfully applied assessment tool (NAMEA, MFA), along with more insight in processes for various waste streams (AWAST simulator); • An extensive network in resources and waste management. The project aims at accounting for all sectors in the economy (the figure below shows a possible conceptual organisation of the system) the flows, stocks and linked environmental pressures to increase the reliability of source data used in “Life Cycle Approaches” to waste management issues. Waste policies influence the „primary production“ due to recycling and prevention, the „manufacturing and consumption“ stages due to recycling, reuse and prevention and the „waste management“ sector. The input/output (I/O) balance of each stage is (dynamically) linked to the others. Solid Waste Management SIA As an example, the following figure shows the situation of sand and gravels in Austria. The net balance between the consumption and the stock (104-10 Tg/ year) represent the net balance of the primary sector (105-9 Tg/year), which means that the evolution of this stock (age) is of primary importance for a policy aiming at resources saving. The difficulties of establishing that type of figure for resources saving in Europe are at two levels: • Data quality: considering the disparity of I/O country data quality in the EU, it is anticipated to set out a global mapping of materials cycles in three steps: 1) elaboration of a global model for matter balance applicable in all countries, 2) calculation of the so-called “transfer coefficients” with “reliable and complete” country data (four countries), and 3) extension to EU-27 macro-economic data. • Completeness: considering the variety of resources, and eventually associated secondary resources (as in ores), and their mixed occurrence in the products, it will be necessary to combine the “materials flows and stocks setting” approach with a more global Input/output modelling for individual countries and for EU. Further, the objective is to forecast the waste generation in the next 25 years. The need is to establish a relation between stocks quantities and qualities and waste generation, the core question being to estimate stocks life time for the different materials (sand/gravel, wood, metals, paper, etc.), products and waste types, and interpret dynamically the causes of the variation of stocks (accumulation versus waste generation or dispersive losses). As a result, the following support can be given directly to policy and decision makers: • Estimation of the material stock of the EU-27. • Overall mapping of environmental pressures of waste, enabling an understanding of the environmental issues of waste; • As a result of scenarios simulations, links between the stocks and waste generation in terms of quantities and quality/composition in the next 25 years. Additionally, the “leaks” of materials in the system above mentioned as “uncontrolled waste disposal” point out the difficulties in making reliable balances on materials life-cycle. These quantified data anyhow allow the drawing of tracks of interpretation. These will be explored providing the knowledge gaps to be filled for assessing the environmental impacts over the entire life cycle including dispersive losses of the physical stocks to the environment (e.g. corrosion and weathering) and losses of materials as a result of materials management (e.g. transport and processing), including energy use of recycling. Financing Institution: EU DG Research Contact: Prof. Dr.-Ing. Martin Kranert Dipl.-Ing. Gerold Hafner Project Partner: • Bureau de Recherches Géologiques et Minières, Orléans • 2.-0 LCA consultants ApS, Copenhagen • Resource Management Agency, Vienna • University of Technology - Institute for Water Quality and Waste Management, Vienna • University of Stuttgart – Institute of Sanitary, Water Quality and Solid Waste Management • Aristotle University of Thessaloniki • Central Mining Institute, Katowice Duration: 2007 - 2009 Internet: http://forwast.brgm.fr/ The identification of the costs and benefits associated with: • Prevention of the wastes has the highest potential to reduce the environmental pressures on the use of resources; • Recovery or recycling of the waste has the highest potential to reduce the environmental pressures on the use of resources; and • Treatment of the wastes is the most polluting. 115 Chair of Waste Management and Emissions Internationale Lehrexporte Summer School Brasilien In cooperation with FUNDACENTRO Sao Paulo (Fundacao Jorge Duprat Figueiredo de Seguranca e Medicina do Trabalho), SENAI Curitiba (Serviço Nacional de Aprendizagem Industrial), CEFET Curitiba (Centro Federal de Educacao Tecnologica do Parana) and JAP (Instituto Ambiental do Paranà) in the following cities summer schools were given in Sao Paulo, Curitiba ( Parana), Belo Horizonte (Minas Gerais) and Recife (Pernambuco). The contents are: • Sanitary Engineering • Mechanical and Biological Waste Treatment • Design of Solid Waste Treatment Plants • Industrial waste and contaminated sites • Biological Waste air purification and adsorption • Environmental relevance of solid waste and waste water Summer School Curitiba (Parana) Summer School Sao Paulo (Sao Paulo) Summer School Recife (Pernambuco) 116 Solid Waste Management SIA Cooperation with the Guangxi University in Nanning, Guangxi, China The Guangxi University is one of the largest and most important universities in southern China. The Institute of Environmental Engineering concentrates on many issues, which include the treatment of municipal and industrial waste, landfill technology and thermal waste treatment. A particular focus lies on the anaerobic treatment of organic household waste, which is carried out in cooperation with the Ministry of Forestry. Guangxi is the Chinese Centre for the Development of anaerobic technologies. The program for the construction and dissemination of decentralized biogas digesters is supervised from here. In the meanwhile, there are operating about 25 million of such small biogas plants in China. The collaboration between the Institute of Environmental Engineering of the Guangxi University and the Institute of Sanitary Engineering, Water Quality and Waste Management of the University of Stuttgart is mainly based on the field of digestion plants. The experiences gained during the long running time of these small decentralized plants in China and the large central plants in Europe may lead to new fruitful approaches for this technology. Contact: Dr.-Ing. Klaus Fischer Dipl. Ing. Jingjing Huang Project Partner: • Institut für Siedlungswasserbau, Wassergüteund Abfallwirtschaft - Lehrstuhl für Abfallwirtschaft und Abluft • Guangxi University in Nanning, Guangxi, China • Ministerium für Forstwirtschaft Decentral biogas plant with a toilet in a village near Nanning, Guangxi, China 117 Chair of Waste Management and Emissions Cooperation with the Universidad Católica Boliviana « San Pablo », in La Paz, Bolivia In collaboration between the Department of Civil Engineering of the Universidad Católica Boliviana and the Institute of Sanitary Engineering, Water Quality and Waste Management of the University of Stuttgart, an exchange of know-how and information is taking place in all the fields of environmental technology and environmental analysis with a focus on waste management. This cooperation developed on the basis of the EU project WasteNet, which is going to be continued in other fields, including student exchange to carry out Bachelor and Master Thesis. In addition to this, block courses will be offered in La Paz for several degree Landfill with leachate ponds in La Paz 118 courses in the fields of environmental engineering and environmental analysis. An intensive know-how exchange is taking place with regards to biological waste treatment with emphasis on digestion plants. Other priorities include the recycling of waste tires, mining waste, hazardous household waste and the recovery and treatment of electrical and electronic wastes. Contact: Dr.-Ing. Klaus Fischer M.Sc. Maria Alejandra Espinoza Project Partner: • Institut für Siedlungswasserbau, Wassergüteund Abfallwirtschaft - Lehrstuhl für Abfallwirtschaft und Abluft • Carrera de Ingeniería Civil de la Facultad de Ciencias Exactas e Ingeniería de la Universidad Católica Boliviana « San Pablo Solid Waste Management SIA Master Course EDUBRAS-MAUI in Curitiba/Brazil The Master’s programme in Environmental Protection Engineering is introduced at the public university “Universidade Federal do Paraná – UFPR” in Curitiba in July 2007. The programme runs over 4 semesters and ends with a Master of Science degree that is to be recognized in Brazil and Germany. The project aims to combine university teaching and research, initially in close cooperation with the University of Stuttgart and later by creating a respective infrastructure at the UFPR. Financing Institution: DAAD - FUNDACENTRO Brasilien Contact: Dr.-Ing. Klaus Fischer Dipl.-Geol. Detlef Clauß Project Partner: FUNDACENTRO - SENAI - IAP - CEFET ISWA (SIA & IWT) The teaching is delivered in Portuguese and German. German language teaching is offered in a course integrated format to intensify contacts with Germany. Lecturers from Germany together with lecturers from Brazil are designing the course teaching .The programme structure offers plenty of scope for academic participation, with positions to be filled by Germans and Brazilians. Independent Studies Diploma Thesis Scrap Tires, Diagnosis of the current situation in Mexico Abfallwirtschaftliche Betrachtung des Recyclings von Photovoltaik-Modulen am Beispiel China und Japan Gisela Tejada (WASTE) (2011) Supervisor:Dr.-Ing. K. Fischer, Dr.-Ing. M. Reiser Ting He (WASTE) (2011) Supervisor:Dr.-Ing. K. Fischer, Dr.-Ing. M. Reiser Treatment processes for infectious wastes Widita Vidyaningrum (WASTE) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Konsumverhalten und Entstehung von Lebensmittelabfällen in Musterhaushalten Jakob Barabosz (UMW) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Green house gases and other pollutants in Iraq Sawsan Mohamed (WAREM) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Options for collection and Transportation in Makkah Yusoff Mohd Famey (WASTE) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Modellierung der Wärmeausbreitung von Feuchtesensoren zur Biofilterüberwachung Jan-Filip Lutz (UMW) (2011) Supervisor:Dr.-Ing. K. Fischer, Dr.-Ing. M. Reiser Erarbeitung der Grundlagen zur Einführung der Umweltmanagementnorm DIN EN ISO14001 Raphael Degler (UMW) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert 119 Chair of Waste Management and Emissions Alliances and Partnerships in Recycling in Cape Town, South Africa Verwertung und Entsorgung von Baggergut aus Flüssen Jeannine Tischler (Geographie) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Alessandra Heinrich (EDUBRAS) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr. J. Metzger Computer Recycling Computing possibilities and Green Abfallwirtschaftliche Brasilien Varianten für Curitiba/ Eric Thöni –Hortal (ERASMUS) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Werner Kessler (EDUBRAS) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr. J. Metzger Untersuchungen zur Anpassung des AT4-Tests an industrielle Abfälle Vergleich der gesetzlichen Regelungen für Krankenhausabfälle in Brasilien und Deutschland Raffaela Pflanz (UMW) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. M. Kranert Matilde Soares (EDUBRAS) (2010) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. U. Menzel Bachelor Thesis Recycling von Kunststoffen und die Anwendbarkeit auf biologisch abbaubare Kunststoffe Nataly Kreutter (Erneuerbare Energien Universität Hohenheim) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr. Müller Recycling von Photovoltaikanlagen Dominik Maier (Erneuerbare Energien Universität Hohenheim) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr. Müller Master Thesis Greenhouse gas emissions from composting, incineration and landfill treatment methods Cristhel Denise Mora Cavazos (WASTE) (2011) Supervisor:Dr.-Ing. K. Fischer, Dr.-Ing. M. Reiser Municipal solid waste treatment proposal for Makkah Municipality Famey Bin Yussuf (WASTE) (2011) Supervisor:Dr.-Ing. K. Fischer, Dr.-Ing. M. Reiser 120 Solid Waste Management SIA Contact Dr.-Ing. Klaus Fischer Laboratory Tel.: +49 (0)711/685-65427 Fax: +49 (0)711/685-67634 E-Mail: [email protected] CTA Axel Goschnick Tel.: +49 (0)711/685-63712 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Research Assistants CTA Catharina Le Huray-Horel Dipl.-Ing., M.Sc. Mihaela Berechet Tel.: +49 (0)711/685-62567 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Tel.: +49 (0)711/685-65436 Fax: +49 (0)711/685-67634 E-Mail: [email protected] M.Sc. Nicolas Escalante Doctorial Candidates Tel.: +49 (0)711/685-65456 Fax: +49 (0)711/685-65460 E-Mail: [email protected] M.Sc. Ke Bi MSc. Maria Alejandra Espinoza Tel.: +49 (0)711/685-65477 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Ing. Jingjing Huang Tel.: +49 (0)711/685-65477 Fax: +49 (0)711/685-67634 E-Mail: [email protected] Dipl.-Ing. Daniel Löffler Tel.: +49 (0)711/685-62567 Fax: +49 (0)711/685-65460 E-Mail: [email protected] MSc. Olga Panic Tel.: +49 (0)711/685-63759 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Geogr. Agata Rymkiewicz Tel.: +49 (0)711/685-60356 Fax: +49 (0)711/685-67634 E-Mail: [email protected] Dipl.-Ing. Marie-Emilie Mollaret Tel.: +49 (0)711/685-67635 Fax: +49 (0)711/685-65460 E-Mail: [email protected] M.Sc. Carlos Pacheco Tel.: +49 (0)711/685-63709 Fax: +49 (0)711/685-67634 E-Mail: [email protected] M.Sc. Samuel Sasu Tel.: +49 (0)711/685-65379 Fax: +49 (0)711/685-63729 E-Mail: [email protected] MSc. Sebnem Bastan Yilman Tel.: +49 (0)711/685-62567 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Tel.: +49 (0)711/685-65456 Fax: +49 (0)711/685-65460 E-Mail: [email protected] 121 Chair of Waste Management and Emissions Resources Management and Industrial Waste Research topics: • Waste and resources management in industry and public bodies • System optimization by material and substance balancing • Food and food waste balances and prevention strategies • Thermo-chemical recovery of phosphorus from sewage sludge ash • Dangerous reactions and emissions caused by industrial wastes • Wet oxidation of liquid hazardous wastes • Pyrolysis of organic residues With our help there‘ll be not much left for your bin Concerning problems from industry and public bodies, RIK’s expertise covers the preparation of material and substance balances, development of management systems and technical processes to prevent, recycle and treat all kinds of wastes and residues. With most of its projects, RIK aims to turn waste management in real closed loop recycling management. Currently we are working on the following topics: • Sustainable management and use of the resource „food“: We sum up and balance the amounts of disposed food and food waste in Germany and develop out of these prevention measures and action plans for policy-makers. We are developing a standardized method for the classification and evaluation of new food management approaches, which shall be later established all over Germany and Europe. • Recovery of phosphorus from sewage sludge ash: In an EU-funded cooperative project we help to develop an innovative thermo-chemical process by which sewage sludge ash can be turned into phosphorus and other useful products. RIK’s contributions to the project are firstly the performing of experiments as well as the management of input and output materials. • Renewable energy and energetic use of waste streams („waste to energy“): We develop concepts to use unavoidable wastes in an ecologically and economically optimal way to substitute fossil energy. • Wet oxidation of liquid hazardous wastes/industrial wastewaters: We perform experiments with real wastewaters, thus evaluate the feasibility of AOP treatment, and subsequently set up overall treatment concepts from the point of origin to the canal. • Pyrolysis of organic residues: Various organic residues can be transformed into coke and energy-rich gas by means of pyrolysis. Adapted to the according local conditions, concepts and reactors for pyrolysis recycling including gas treatment are developed and tested. • Further fields of activity: Resources in wastes, residues and anthropogenic deposits; treatment and utilization of sewage sludge; treatment and disposal of solid, pasty and liquid industrial wastes; microbial regeneration of adsorbents; waste adequate special analysis and test methods; sampling of solid, pasty and liquid wastes. 122 Resources Management and Industrial Waste RIK Research Determination of discarded food and proposals for a minimization of food wastage in Germany („Ermittlung der weggeworfenen Lebensmittelmengen und Vorschläge zur Verminderung der Wegwerfrate bei Lebensmitteln in Deutschland“) One important topic of RIK‘s scientific work at ISWA is the investigation of food waste. In 2011 the quantities of food waste in Germany and measures for the minimization of food wastage have been elaborated within a study for the German Federal Ministry of Food, Agriculture and Consumer Protection. Therefore data has been researched and reviewed not only for Germany but also for Europe and Northern America. The whole food chain was investigated: • retail • transport + logistics • large scale consumers • households • other Edible food from a residual waste bin Data was taken from literature, federal statistics, interviews of relevant stakeholders, own investigations. As a result, the relevant massflows of food, food waste and by-products could be identified. The data quality was examined and further need of research to close data gaps (amount and quality) could be named. The most relevant and avoidable mass-flows of food waste have been determined. Applicable measures have been researched in an international frame (Europe + Northern America). The researched measures against food wastage have been evaluated within a benefit analysis matrix including aspects of transferability to Germany. Cooking with food waste Another important outcome of the study was the definition of the expression “food waste”. This definition has been harmonized with experts and stakeholders throughout Europe and could become an international standard, which enables experts and decision makers to compare studies and published data in the international context. Financing Institution: Bundesministerium für Ernährung, Landwirtschaft und Verbraucherschutz (BMELV) Contact: Dipl.-Ing. Gerold Hafner, Dipl.-Ing. Jakob Barabosz, M.Sc. A. Hilse Duration: 06/2011 – 02/2012 Meal from disposed food - bon appetit! 123 Chair of Waste Management and Emissions EU-Forschungsprojekt, INTERREG IVB North West Europe: Green Cook transnational strategy for global sustainable food management GreenCook is aimed at reducing food wastage and to make North-West Europe a model region for sustainable food management, by in-depth work on the consumer-food relationship thanks to a multisectoral partnership. Food wastage is a challenging problem, directly linked with the questions of waste, consumption and climate change. A quarter of the food produced in the world each year ends up in the dustbin, without having been consumed. As a reflection of our overconsumption society, food wastage also reinforces social inequalities and is ethically unacceptable. The negative impacts of this wastage are real: for households (useless expenditure), for local authorities (overproduction of waste to be treated, increased costs), for the environment (pointless use of resources and pollution), and for the economy (falling prices). Its diversified partnership intends to show the added value of united, transversal action, and to influence EU policies, in order to get a new European sustainable food model to emerge. The project involves 12 partners from Belgium, France, Netherlands and Germany. The institute ISWA is consulting the other partners with their pilot actions and develops a method to evaluate the pilot actions within social, ecological and economical aspects. Financing Institution: European Regional Development Fund Contact: Dipl.-Ing. G. Hafner M.Sc. C. Maurer Project Partner: Event “Sustainable Cooking” in the course of the project GreenCook Lately, tools and methods are under experimentation to help consumers to improve their food management while controlling their purchasing behaviour. They aim at changing behaviour as well as altering the offer at supermarkets, restaurants or canteens. It is alas hard for them to be generalised, because of the complexity of the levers that have to be activated. GreenCook’s ambition is to create this lever effect, by generating a dynamic that motivates all of the food players and by throwing pathbreaking bridges with the fields of health, welfare and economic development. 124 • Espace Environment, ASBL (B) • Bruxelles Environment, IBGE (B) • Research institute for consumers’ organisation, CRIOC (B) • Fost Plus (B) • Euro Toques (B) • sustain „the alliance for better food and farming“ (UK) • Wageningen UR Food & Biobased Research (NL) • Communauté d’Agglomeration de l’Artois (F) • Conseil Régional Nord-Pas de Calais – DFI (Direction des Formations Initiales) (F) • Green Tag (F) • Abfallverwertungsgesellschaft des Landkreises Ludwigsburg mbh, AVL, (D) • De Proeftuinen (NL) Duration: 2010 – 2013 Resources Management and Industrial Waste RIK R+D-project: Elimination of hardly biodegradable substances from wastewater with a microbially regenerating Adsorbent Immersion Contactor In the effluent of sewerage plants low concentrations of pharmaceuticals and other organic industrial chemicals are present, which can have negative effects on the endocrine systems of aquatic organisms living in the receiving water of the plant. It is well known that these refractory substances can be removed from wastewaters with adsorbents like activated carbon. The aim of this research project was, to develop and test a reactor in which organic substances can be concentrated in the pores of coarse granular activated carbon, to be hence degraded slowly by microorganisms populating the surface of the granules. Four lab-scale Adsorbent Immersion Contactors In specially developed lab-scale immersion contactors, long-term experiments have been performed with loaded and populated carbon pellets to find out their remaining sorption capacity and their change in behaviour over the time. A pilot plant in half-technical scale has been planned, built and put into operation. First pilot experiments have been performed. As a result it can be said that, even after more than two years of constant loading, the populated carbon granules are still adsorptive, however less than the respective unloaded product; refractory substances do not accumulate in the pores of the adsorbent. Because of the high adsorbent “concentration” in the adsorbent immersion contactor, the latter can minimize the remaining substance concentrations in sewerage plant effluents significantly within a short time, and thus eliminate its endocrine activity completely. Adsorbent Immersion Contactor for the elimination of hardly biodegradable organic substances from wastewater – pilot scale, top view Financing Institution: Gefördert von der Willy-Hager-Stiftung Contact: Dipl.-Ing. Matthias Rapf, CTA Brigitte Bergfort Duration: 2008 - 2011 Biofilm detached from loaded and populated activated carbon 125 Chair of Waste Management and Emissions Expertises Study: Scientific monitoring of a pilot test a for residual waste-free waste management in the district Neckar-Odenwald Waste management has become an essential tool for managing scarce resources. Additionally to waste prevention, the energetic use of biogenic materials is of particular importance, as well as the further intensification of recycling. Modern material flow management can optimize materials and energy recovery pathways. Allowing for specific regional conditions an optimal recovery cycle of nutrients and carbon can be achieved as well as a reduction of greenhouse gases due to substitution of fossil fuels. A maximized recovery of non-biogenic materials is particularly efficient if it is collected separately in a dry recycling bin. Studies have been carried out in the district NeckarOdenwald to establish an innovative waste management concept without a residual waste bin. The collection of the organic waste in a “bio energy bin” and the establishment of a “dry recyclables bin” are planned. These two new collection systems are intended to replace the existing residual waste collection. The existing systems for the separate recovery of recyclable materials will remain. The collected dry recyclables are processed in a sorting plant and supplied largely to a material recycling. On the other hand the organic municipal waste from the new “bio-energy bin” will be used for the production of biogas. The fermentation residues can be conditioned to a refuse derived fuel (RDF). Initially the feasibility and efficiency of the new system has been verified in a pilot project. The pilot project was implemented in the municipality Rosenberg and scientifically supported by the Chair of Waste Management and Emissions, working group RIK. Financing Institution: AWN Abfallwirtschaftsgesellschaft des Neckar-Odenwald-Kreises mbH Contact: Dipl.-Ing. Gerold Hafner Duration: 2010 - 2011 126 Study: Biomass concept of organic municipal waste in the district of Calw The aim of this study was the evaluation of conceptual approaches to the future treatment of the arising organic municipal waste in the county of Calw. The assessment is carried out under ecological and economic points of view and considered the technical feasibility, with particular attention to existing waste treatment facilities (including composting plant). The main objective of the study is to analyze scenarios focused on the generation of energy from organic waste using anaerobic digestion (biogas production). In addition to the evaluation of the biomass accruing in the district of Calw itself, another assessment was carried out including organic waste from the neighbouring district of Freudenstadt. Financing Institution: AWG Abfallwirtschaft Landkreis Calw GmbH Contact: Dipl.-Ing. Gerold Hafner Duration: 2009 - 2010 Resources Management and Industrial Waste RIK Independent Studies Master Thesis Phosphorus Recovery from Sewage Sludge – Review and Evaluation of Existing Techniques Bewertung der Lebensmittelabfälle aus Großküchen und Kantinen Rodrigo Haro de la Peña (WASTE) (2011) Supervisor:M. Rapf, G. Hafner Anastasiou Konstantinos (ERASMUS) (2011) Supervisor:G. Hafner, Dr.-Ing. K. Fischer Rare Earth Metal Recovery from Electronic Scraps Arunee Tan (WASTE) (2011) Supervisor:M. Rapf, Dr.-Ing. K. Fischer Vorbehandlung von Abwasser aus Vergärungsanlagen zwecks Nährstoffrückgewinnung In cooperation with Wehrle Umwelt GmbH, Emmendingen Diploma Thesis Ana Stavăr (WASTE) (2011) Supervisor:M. Rapf, Dr.-Ing. K. Fischer Production of Bio-Char from Organic Wastes by an Appropriate Technology Untersuchung und Bilanzierung der Nahrungsmittelströme in Kantinen und Großküchen am Beispiel der Universitätsmensa auf dem Campus Vaihingen Manuel Claus (Diplom UMW) (2011) Supervisor:Dr.-Ing. K. Fischer, Prof. Dr.-Ing. E. Thomanetz Untersuchungen zur Kompostierung des Klärschlamms der Kläranlage Gaobeidian, China In cooperation with AWN Abfallwirtschaftsgesellschaft des Neckar-Odenwald-Kreises mbH Mingxi Zhao (Diplom UMW) (2011) Supervisor:G. Hafner, M. Rapf Untersuchungen zur Anpassung des AT4-Tests für Industrielle Abfälle Raffaela Pflantz (Diplom UMW) (2010) Supervisor:M. Rapf, Dr.-Ing. K. Fischer Bachelor Thesis Abschätzung des Gefährdungspotentials ausgehend von leichtflüchtigen organischen Verbindungen in einer Anlage zur Konditionierung industrieller Dünnschlämme In cooperation with Daimler AG, Werk Wörth Yun Chin Wong (WASTE) (2011) Supervisor:G. Hafner, Dr.-Ing. K. Fischer Dissertations in progress Basisdaten für Material- und Stoffstromanalysen in der Abfallwirtschaft – EDV-gestützte Untersuchung von Material- und Stoffflüssen Dipl.-Ing. Gerold Hafner Supervisor:Prof. Dr.-Ing. M. Kranert, Prof. Dr.-Ing. E. Thomanetz Entropieerzeugung als Maß für die Umweltauswirkungen technischer Prozesse an Beispielen aus der Abfallwirtschaft Dipl.-Ing. Matthias Rapf Supervisor:Prof. Dr.-Ing. M. Kranert, Prof. Dr.-Ing. B. Weigand (ITLR) Yishu Liu (Bachelor UMW) (2011) Supervisor:G. Hafner, M. Rapf Entropy mnemonics S= Q/T, unfortunately not applicable in English 127 Chair of Waste Management and Emissions Contact Dipl.-Ing. Gerold Hafner Tel: +49 (0)711/685-65438 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Reseach Assistants Dipl.-Ing. Jakob Barabosz Tel.: +49 (0)711/685-67636 Fax: +49 (0)711/685-67634 E-Mail: [email protected] M. Sc. Annika Hilse Tel.: +49 (0)711/685-62567 Fax: +49 (0)711/685-65460 E-Mail: [email protected] M. Sc. Claudia Maurer Tel.: +49 (0)711/685-65407 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Ing. Matthias Rapf Tel.: +49 (0)711/685-65428 Fax: +49 (0)711/685-65460 E-Mail: [email protected] Laboratory CTA Brigitte Bergfort Tel: +49 (0)711/685-63709; +49 (0)711/685-67636 Fax: +49 (0)0711/685-67634 E-Mail: [email protected] 128 Resources Management and Industrial Waste RIK 129 Chair of Waste Management and Emissions Emissions Research topics: • Landfill aeration • New methods to methane emission quantification • Research of emissions from waste treatment plants • Gas chromatographic odorant analysis by means of “sniffing port (GC-MS-o)” And sometimes, the job just stinks If it stinks, the people in this workspace are in their element. In the working area “Emissions”, people care about almost all the existing gaseous matters. Preferentially at waste treatment plants, landfills and sewage treatment plants, but other emissions are also “welcome”. The topics of “acceptance” and “gaseous emissions” of waste treatment facilities are always strongly connected to each other. This involves, on one side, preventing harassment or keeping threshold values; but also resource conservation and sustainability on the other side. Thus, the minimization of emissions of greenhouse gases in the disposal and recycling of waste is still an important research area. In the working area EMS, to avoid methane generation and methane-monitoring is currently a major focus. The researches can be applied to landfill aftercare reduction, reducing emissions at the MBA and developing methane measuring methods. In cooperation with companies and public authorities, the available possibilities of gas analysis were always required in the reporting period. Available equipment ranges from classical methods such as gas chromatography with mass spectrometer and flame ionization detectors to more unusual methods such as olfactometry, laser absorption spectrometry and “sniffing-port” (GC-MS-o). Our work is embedded in both in the scientific and technical context as well as in the economic context. Our experiences incorporate formulations of national and international rules. 130 Emissions EMS Research Pilot project to reduce the aftercare period of a domestic waste landfill – accelerated decomposition of organic waste through extensive interval aeration in BA IV of Landfill Dorfweiher The district of Konstanz intends to reduce the aftercare period of landfill Dorfweiher. In situ treatment process was developed and executed by the University of Stuttgart, Institute for Sanitary Engineering, Water Quality and Waste Management (ISWA) in cooperation with the Engineering Company Lhotzky & Partners, Braunschweig; with the treatment process, the known methods will be combined in a project section of Landfill Dorfweiher and the techniques will be improved. The Ministry for the Environment, Climate and Energy Economics of Baden-Württemberg supports the project financially. The aeration period is set to be three years. Then the effects of the aerobic treatment on the landfill are evaluated during a two-year observation. The results of the project will play an important role in the required design and the choice of the final surface sealing. The aim of the pilot project is to treat the landfill body aerobically and thus to achieve a discharge from the aftercare within a foreseeable time period. Using the proposed method, the conversion and degradation of the organic constituents in the landfill should be accelerated. As a result, settlements can be anticipated and harmful landfill gas emissions can be greatly reduced. The quality of the leachate can also be improved significantly. In parallel, in the framework of academic supervision to the pilot project, further insights will be developed. In a close temporal and spatial raster scanning, plenty of measuring data are recorded. For example, information about the required aeration rates and pressures as well as the gas, leachate, temperature and settlement developments can be obtained, so that the aeration strategy can be optimized. Furthermore, it is also of interest that how effective is the exhaust gas treatment of the biofilter, and how much leachate should be recycled so that the biological processes in the landfill could run optimally. The technical constructions and equipment are constructed in a modular design. After completion of the project, it would be possible to use some parts of the technical components for the treatment of another section of the Landfill “Dorfweiher” or other landfills. Details of carbon, nitrogen and water balance will be elaborated. For carbon, it will be only possible mainly through gas analysis. The results will be evaluated to the effect, whether the in-situ treatment method can be transferred to other landfills. Financing Institution: District of Konstanz / Ministry for Environment, Climate and Energy Economics of Baden-Württemberg Contact: Dr.-Ing. Martin Reiser Dipl.-Ing. M. Rapf Dipl.-Ing. M. Kieninger Project Partner: Lhotzky + Partner Ing. Gesellschaft mbH, Braunschweig Duration: 12/2009 - 12/2014 A section of the Landfill Dorfweiher with aeration lances during construction of the biofilter 131 Chair of Waste Management and Emissions Development of a simple measuring method for greenhouse gas emission rates from area sources (“EKG”) The aim of the project was the development of a practical software tool, to estimate the emission rates of greenhouse gases from diffusive area sources, based on laser absorption long-distance measurements (TDLAS). Requirement of emission rates from small-scale sources always exists, where due to statutory mandatory report or measures for climate protection, precise values are more demanded than the current freights out of theoretical estimations or rather qualitative measurements. A Lagrangian model was used as dispersion model, and the concentration measurements were carried out as open-path measurements with measuring distance up to 500 m. With the measuring results, the freight emitted from area source can be evaluated using the modified dispersion modelling. For environment protection, the project results bring the following advantages: • Climate-relevant emissions from area sources can be determined much more precisely than with the current measuring and estimation methods. • According to our previous measurements, the calculated data are rather too high than too low. Measures targeted to the important sources can be taken with more precise knowledge of the emitted freight. • Monitoring of existing (or future) threshold value for greenhouse gases emissions from area sources is thus relatively simple and cost-effective. Financing Institution: DBU – Deutsche Bundesstiftung Umwelt, Osnabrück Contact: MSc. Zhu Han Dr.-Ing. Martin Reiser Project Partner: Ingenieurbüro Lohmeyer, Karlsruhe A similar method is not available until now. Duration: 09/2009 - 06/2011 Gasfinder®-Measurement on a domestic waste landfill 132 Emissions EMS Expertises Analysis of the odorant in the exhaust gas from sewage system with gas chromatography/mass spectrometry in combination with olfactory detection (GC-MS-o) By combining the traditional GC/MS coupling with a so-called olfactory detector (or “sniffing port”), it is possible to determine the actual odorous components from a mixture of gaseous air pollutants. In case of exhaust gas from sewage system play the constituents belonging to the terpene group an important role. Client: KompetenzZentrum Wasser Berlin GmbH FTIR measurements at different exhaust gas purification systems in the semiconductor and solar cell manufacturing or solar cell industry Combination of gas chromatography and olfactory analysis In order to investigate the efficiencies of various exhaust gas purification systems, exhaust gas analysis was conducted at different production facilities of the semiconductor and solar cell manufacturing with a portable FTIR spectrometer. The large amount of inorganic and organic components in the exhaust gas streams are often classified as the greenhouse gases (e. g. nitrous oxide, sulfur hexafluoride, etc.). Client: Centrotherm AG, Blaubeuren Olfactometry analyses to determine the odorant concentration and gas chromatographic analysis of gas samples from different facilities (waste disposal plants, sewage treatment plants, and different manufacturing companies). FTIR measurement at the exhaust gas purification system in the semiconductor manufacturing Client:Various Hydrogen sulphide measurements at different spots of the ARA in a slaughterhouse, and regular sampling of raw and clean gas from the connected biological gas treatment system Client: Ulmer Fleisch GmbH, Ulm Investigation on detection and reduction of odour emissions from the drying of sludge at the sewage treatment plant Niederkirchen Client: Verbandsgemeinde Deidesheim / Ingenieurbüro Lohmeyer, Karlsruhe Maintenance of the container-biofilter from waste water treatment system in a slaughterhouse 133 Chair of Waste Management and Emissions Diploma Thesis Investigation of water flows and stocks during in situ aeration of landfill Dorfweiher Goeske de Jong Boronat (WASTE) (2011) Supervisor: Dr.-Ing. M. Reiser, Dr.-Ing. K. Fischer Behaviour of CO2 and O2 in a landfill body during aeration process Javier Armando Melo Cadima (WASTE) (2010) Supervisor: Dr.-Ing. M. Reiser, Dr.-Ing. K. Fischer Ermittlung gasförmiger Emissionen von Biopolymeren durch Thermoextraktion Daniel Morrison (Umweltschutztechnik) (2010) Supervisor: Dr.-Ing. M. Reiser, Dr.-Ing. K. Fischer Effect of combined aeration and biofilter application on methane emission of a landfill site Michelle Fischer (WASTE) (2010) Supervisor: Dr.-Ing. M. Reiser, Dr.-Ing. K. Fischer 134 Emissions EMS Contact Dr.-Ing. Martin Reiser Laboratory Tel.: +49 (0) 711/685-65416 Fax: +49 (0) 0711/685-63729 E-Mail: [email protected] Hans-Jürgen Heiden (CTA) Tel.: +49 (0) 711/685-65503 Fax: +49 (0) 711/685-63729 E-Mail: [email protected] Research Assistants Axel Goschnick (CTA) Dipl.-Ing. Martin Kieninger Tel.: +49 (0) 711/685-63733 Fax: +49 (0) 0711/685-63729 E-Mail: [email protected] Tel.: +49 (0) 711/685-63712 Fax: +49 (0) 711/685-63729 E-Mail: [email protected] M.Sc. Han Zhu Doctoral Candidate Tel.: +49 (0) 711/685-65409 Fax: +49 (0) 711/685-63729 E-Mail: [email protected] M.Sc. Gülsen Öncü Tel.: +49 (0) 711/685-65409 Fax: +49 (0) 711/685-63729 E-Mail: [email protected] 135 Chair of Waste Management and Emissions Biological Air Purification Research topics: • Detection of degradative potentials • Isolation of xenobiotics degrating bacteria and fungi • Elucidation of bacterial degradative pathways by use of genetical, chemical and biochemical techniques • Development of new waste air purification concepts • Design, dimensioning and operation of Biological Waste Air Purification (BWAP) plants • Biosynthesis of fine chemicals with high value It’s not just hot air to us The biological cleaning of exhaust air and the biodegradation of xenobiotics (i.e. non-biodegradable substances) by bacteria represent the focal point of our work. In addition, the department provides assistance in the planning and dimensioning of biofiltration apparatus of various types (biofilter, biotrickling filter and biowasher). Moreover, it is possible to provide scientific supervision of these apparatus and equipment during normal operations and in case of faults. This is in the interest of research in a real practical context, because the weaknesses revealed in any of the functions can be drawn upon to develop new or optimised concepts. A further field of research is the degradation of xenobiotics: exposing degradation potential, isolating xenobiotic degrading bacteria strains and fungi, investigating bacterial degradation paths and, as a spinoff, the biosynthesis of materials. 136 Biological Air Purification ALR Research Anti-Clogging Measures PU-Foam System biology in the Genus Pseudomonas Natural as well as technical package materials for biofiltration processes often do exhibit inhomogeneities with respect to structure, gas distribution and biological settlement as well as pressure loss. In case of high specific loadings of contaminants, increase in biomass will lead to clogging phenomena of the package material and will inevitably result in decrease of efficiency. Knowing these clogging phenomena, up to now biological waste air treatment plants were constructed with increased size to counterbalance this effects and establish lower specific loadings of the contaminants. This however results in increased costs. In this project, the production of low molecular organic compounds by bacteria is investigated. During this research, metabolic networks as well as the genetics of the relevant bacterial strains are examined. Due to a confidentiality obligation, no further information of this project could be shared. PU-foam materials may represent a technical and economically feasible solution for this problem. Based on their defined pore structure, high specific surface, low package density and low pressure loss, the construction of energy-efficient and compact biotrickling filters is possible. Complying with the BioStoffV, in addition non-pathogenic bacteria could be immobilised on the carrier thereby increasing specific reaction rates. However, the compact construction of these biotrickling filters clearly leads to higher risks of clogging. Financing Institute: By BMBF and BASF Contact: Dr.-Ing. Niko Strunk M.Sc. Diego Salamanca Duration: 01/2009-12/2011 The aim of this project therefore is to develop, test and apply anti-clogging methods for this PU-foam carriers applied in biotricklingfilters at laboratory and semitechnical scale (25 L / 5 m³) with respect to efficiency, practicability and economy. Within the first phase in laboratory scale, an artifical waste air is used for these tests. In a second phase the semi-technical system is used for treatment of a real waste air to verify the efficiency parameters of the laboratory scale phase. These data are the base for scaling-up procedures in order to introduce this technology into the market. Financing Institute: BMBF with carrier PT-DLR Contact: Dr.-Ing. Daniel Dobslaw Duration: 10/2011-09/2013 137 Chair of Waste Management and Emissions Expertise and assignments Development of a suitable waste air cleaning concept for the drying of sintered molding blanks in compliance with the maximum concentrations given in the german guideline “TA-Luft” Due to an existing confidentiality agreement no in depth details for this project can be stated here. In a sintering process, the waste air is loaded with a solvent. This solvent must be eliminated using a suitable process to comply with the maximum compulsory concentration limits. The main focus when choosing the appropriate type of process and its construction details lies on environmental compatibility issues like minimizing water and energy consumption. Advisor: Dr.-Ing. Niko Strunk, Dipl.-Ing. Steffen Helbich Feasibility of biological treatment of waste air from the production of cylinder head gaskets Within the production process of high-temperature stabile cylinder head gaskets for car engines, the sealing material is mixed with a defined solvent recipe. The resulting paste is coated into the relevant notches. During coating and drying of these sealings, high volume waste air flows with concentrations of VOC at an average of 200 mg C/m³ occur. In this project, the biodegradability of these VOCs was tested at laboratory scale as well as within a two stage pilot plant, consisting of a prescrubber and a biofilter stage, built up at the factory. The analytical data gained thereby were used for designing a biological waste air purification process at this location. Advisor: Dr.-Ing. Daniel Dobslaw Cylinder head gasket Optimisation of a spray tower for combined elimination of NH3, H2S and VOC During the drying process of industrial as well as municipal sludges, high volume flows of waste air are generated containing compounds at concentrations up to 300 mg N/m³ for ammonia, up to 20 mg S/m³ for hydrogen sulfide and up to 400 mg C/m³ for VOCs. State of the art technology for treatment of these kind 138 of waste air is a combination of an acidic scrubber, basic scrubber followed by a biological treatment step as the third stage. To reduce investment costs, there is a large interest in simplifying the three stage system to a two stage system consisting of a scrubber and a biological stage only. Therefore, process parameters for this scrubber have to be redefined. Within this project tests for optimisation of the simultaneous absorption of these defined contaminants were carried out. Advisor: Dr.-Ing. Daniel Dobslaw Treatment of styrene containing waste air streams by a two stage non-thermal plasma system Fibre-glas reinforced plastics are widely used, because of their high chemical, mechanical and thermal stability as well as their low weight. During coating processes, a styrene containing recipe is used. Thus, styrene emissions to be treated inevitably do occur. To reduce heating power demands within the factory, a recirculation of the treated air is highly interesting. Therefore, a non-thermal plasma system combined with an activated charcoal filter is used to treat styrene and avoid toxic secondary emissions. Within the project the process parameters were to be optimized in order to get a high efficient treatment of styrene at low energy consumption making use of a non-thermal plasma stage. Advisor: Dr.-Ing. Daniel Dobslaw, Dipl.-Ing. Steffen Helbich Waste-free elimination of ammonia in biomass power plants Facilities like cement plants, brown coal power plants and biomass power plants use pretreted industrial and municipal sludges as alternative fuels. During pretreatment waste air flows with high concentrations of ammonia occur. The ‘state of the art’ technique is the elimination i.e. absorption of ammonia by an acidic scrubber. However, to get the so called financial ‚NaWaRo‘ - Bonus, a complete waste water - free process of this biomass power plant is obligatory. According to this guidline an elutriation of the swamp liquid into the sewage water system is not allowed. Within this assignment, the economical feasibility of ammonia treatment in the biofiltration stage complying to TA-Luft limit values for ammonia and odour, the accumulation of nitrite and nitrate as well as toxicity phenomena of ammonia were evaluated. Advisor: Dr.-Ing. Daniel Dobslaw Biological Air Purification ALR Diploma Thesis Biological treatment of a waste air containing 2-ethylhexylacetate, methylisobutylketone and methylethylketone using biofilters and biotrickling filters In this study the biodegradability of a waste air containing a VOC mixture of 60 vol% 2-ethylhexylacetate, 34 Vol% methylisobutylketone (MIBK) and 6 vol% methylethylketone (MEK) was analysed. Bacterial cultures able to biodegrade these components were isolated, characterised and finally used as inocula in biological waste air treatment plants in semi-technical scale (biofilter and biotrickling filter). The latter were optimised within the test period. Biotrickling filters, using polyurethane foam cubes or hiflow rings as a package material, showed high performances and this way a high usability for this waste air problem. Using polyurethane foam package material elimination capacities up to 200 g org. C/(m³*h) at a residence time of 10 s were achieved. In difference, the biofilter system showed no stabile process conditions and elimination capacities were poor. These effects were caused by clogging phenomena of the package material. All systems showed a high demand on nitrogen caused by denitrifiers like Acidovorax aerodenitrificans, which were part of the established biocoenosis. In substrate patterns the isolated strains showed strong growth with alcohols, ketones, carbonic acids, cyclic aromatics as well as ternary carbon branched components. During biochemical characterisation of the isolates bayer-villiger monooxygenases, relevant for the initial step in the biodegradation of MIBK and MEK (Kieninger, 2007), respectively, were detected. For detailed characterisation multiple sequence alignments were proceeded and the native enzymes were characterised by substrate patterns. These patterns showed that the enzymes induced by MIBK can simultaneously degrade MEK and the other way as well. However, transformation rates of the cooxidised substrates were significantly lower than for the native substrate. Biological Butane Degradation Topic of this thesis was the characterization of monooxygenase systems of several bacterial strains, which are able to use n butane as a sole source of energy and carbon. A suitable strain had to be identified, whose monooxygenase transforms the substrate n butane into 1,4 butanediol by terminal oxidation two times over. Aspired pathway: α,ω-oxidation of n butane to 1,4-butanediol. Butane degrading strains on an agar petri dish. In preliminary work, the butane degrading strains were enriched and isolated from soil samples and activated sludge. n alkane substrate pattern from methane to eicosane showed high specificity of the strains towards certain areas of carbon chain length. Where one strain was only able to grow on linear alkanes from ethane to hexane, another showed growth by using ethane to eicosane. In a growth experiment of whole cells in liquid culture it could be demonstrated that 1 butanol induces expression of a butane monooxygenase, as there occurred no lag-phase during a switch of those substrates. Thomas Gerl (Umweltschutztechnik) (2011) Advisor: Dr.-Ing. Niko Strunk, Dr.-Ing. Daniel Dobslaw A potent alcoholdehydrogenase inhibitor was identified during the measurement of enzyme kinetics in crude extract. In contrast, there was no effect of this inhibitor on whole cells, nor could there any accumulation of primary alcohols be observed. Tolerance towards organic solvents was determined in rich and selective liquid medium. A forced expression of the soluble butane monooxygenase could be achieved by facing the strain with 139 Chair of Waste Management and Emissions almost copper free conditions in selective liquid medium with n butane as a sole source of energy and carbon. The distinct types of monooxygenases could be shown in all the strains by this method, as well as by genetic methods, like the multiple sequence alignment. Further, transposon mutagenesis was carried out to determine the role of the butane monooxygenase. Steffen Helbich (Umweltschutztechnik) (2011) Advisor: Dr.-Ing. Niko Strunk Biological degradation of benzoate under saline conditions plenty of different software tools or mathematical approaches like two-film theory, permeation theory or NTU-HTU – model, there is a lack of these tools and approaches for nozzle floor scrubbers. In cooperation with a plant manufacturer, a semi-technical model of a nozzle floor scrubber was constructed and the efficiency of this system was characterised using acetone, ethanol and isopropanol as model contaminants. Additionally, the effect of process parameters like residence time, gas to water – ratio, nozzle size, number of stages, water hold up and further parameters was also characterised. Based on these results, a simple software tool for dimensioning of this kind of scrubber was established. Lukas Magacz (Umweltschutztechnik) (2011) Advisor: Common microorganisms degrading native as well as xenobiotic compounds tolerate concentration of sodium chloride up to 3.5 w%. This concentration is nearly equivalent the sea salt concentration level. In habitats with higher sodium chloride concentrations like salt refineries, solar salt refineries, brines of olive oil production or special industrial waste water only specialised microorganisms are able to survive. Additionally, the waste water of olive oil production and industrial waste water posses commonly high concentrations of COD. The examination of the biodegradation process of benzoate as key component under saline conditions and the technical application of this process were the topics of this diploma thesis. Based on an industrial application the stages of a waste water treatment plant have to be defined and designing procedure should be done. As a consequence of this special habitats bacterial strains capable to degrade benzoate under these conditions were isolated and charakterised in laboratory and half-technical scale. A main focus was led on the examination of the stability of the biocoenosis over the runtime of the process. Josephine Hartmann (Umweltschutztechnik) (2011) Advisor: Dr.-Ing. Daniel Dobslaw Development of a software tool for dimensioning of nozzle floor scrubbers A state of the art technique for treatment of waste air flows containing well soluble VOCs is the absorption. One possible type of absorption process is the nozzle floor scrubber. In difference to spray towers and packed columns, which can be dimensioned by a 140 Dr.-Ing. Daniel Dobslaw Degradation behavour of 2-butoxyethanole and evaluation of of these data for designing a bioscrubber treatment plant In this thesis, the degradation of 2-butoxyethanole by the bacterial strain BOE 100 was examined. Butoxyethanole is a solvent mainly used in paints and lacquers but also for cleaning KHE WHICH agents, cosmetics and textiles. The strain BOE 100 is able to completely degrade butoxyethanol. A 16S rDNA analysis showed that this strain is belonging to the species Pdeusomonas putida. It’s doubling time lies between 120 and 140 minutes at concentrations of butoxyethanol ranging from 2.5 to 10 mmol/L. KHE growth was observed Even at a concentration of 60 mmol/L. The degradation pathway of butoxyethanole was examined by using transposon mutagenesis. Using this method, butoxyacetic acid, butanol and butyric acid could be identified as metabolites. The second part of this thesis was focusing on the degradation of a selected mixture of solvents (60 vol% of which are butyl acetate) by biological means in a bioscrubber run by a hazardous waste treatment plant. Butoxyethanol is part of this mixture at a concentration of 7 vol-%. The degradation capacity of the bacteria involved was determined by constructing a regenerator at half technical scale and giving varying amounts of the solvent mixture to the reservoir until the capacity limit was reached. Christine Woiski (Umweltschutztechnik) (2010) Betreuer: Dr.-Ing. Niko Strunk Biological Air Purification ALR Comparison of biological and non-biological waste air treatment techniques for treatment of waste air streams out of belt dryers in cement industry under the aspect of ecology, economy and efficiency Within endothermic clincer birck production processes made of lime, high amounts of fossile fuels were necessary in the cement industry. Modern processes base on a thermal use of cadaver, animal meal, tyres, municipal and industrial sewage sludges instead of fossile fuels. About 5 % of the total energy demand is covered by the thermal use of sewage sludges, which are not directly combustible in the rotary furnaces, because of their high water contents. A thermal pre-drying procedure using waste heat of the rotary furnace is an efficient system. Within an air flow the evaporated water as well as volatile organic compounds as well as anorganic compounds like H2S and NH3 are separated from the dried matter. Poorly, high fluctuation in the composition of this air stream occured. A treatment of this high odorant air containing high carbon freights was necessary. Up to now state of the art techniques are not adequate to fulfil the limit values of 20 mg C/ m³ and 500 OU/m³ defined by the TA-Luft, respectively. The main task of this thesis was to choose adequate procedures for efficient treatment of this contaminated air and to verify and compare the efficiency of the choosen techniques during treating a real waste air of a cement plant. The focus lied on an evaluation of the procedures, feasibility of specific optimisation potential and selective treatment of single as well as mixed waste air streams, which occured on-site. Christian Wilde (Umweltschutztechnik) (2010) Advisor: Dr.-Ing. Daniel Dobslaw Study works Master Thesis Comparison of various biological air treatment techniques for treating waste air of an automobile industry Micro-pollutants removal from (waste)water by biological treatment with membrane technology and its comparison with other biological treatment methods The focus of this work was the comparison of two biological waste air treatment systems, namely biotrickling filter and biofilter, under the aspect of applicability to treat VOC containing waste air flows from automobile industry. In a first phase bacterial strains able to biodegrade these contaminants were isolated and – after laboratory characterisation – used as inocula for both plants (about 170 L volume). Process parameters of both techniques were similar to real waste air situation (concentration: 172 mg C/m³; residual time: 30 s; resulting volume flow: 19,2 m³/h; waste air contaminants: MEK, MIBK, 2-Ethylhexyl acetate). As a package material PU-foam cubes (PPI 10, 20 mm size) and wood chips (corn size about 2 cm) were used, respectively. After 45 days dominated by adsorption processes a continuous increase in efficiency was observed. The efficiency of the biotrickling filter was continuously lower than the efficiency of the biofilter system. In both systems substance specific elimination capacity decreased with in increase of the hydrophobic behaviour of the waste air contaminants. The aim of this project is the elimination and mineralisation of micro-pollutants in water and waste water by biodegradation processes based on innovative process concepts. In case of these innovative process concepts, the focus lies on biomembrane processes. Alternative biological processes are analysed at laboratory as well as semi-techical scale and allow a well documented comparison to the results of the biomembrane processes. In this master thesis the central task is to isolate bacterial strains capable to biodegrade defined waste water contaminants, namely ibuprofene, diclofenac, triclosane, prozac and paracetamol. In a second phase these isolates are characterised under the aspect of morphology, specifity against contaminants and the degradation kinetics of single compounds. The technical application is the core aspect of a doctor thesis. Shelesh Agrawal (Waste) (2011) Advisor: Dr.-Ing. Daniel Dobslaw Shelesh Agrawal (Waste) (2011) Advisor: Dr.-Ing. Daniel Dobslaw 141 Chair of Waste Management and Emissions Contact Prof. Dr.-rer. nat. habil. K.-H. Engesser Dipl.-Ing. Christine Woiski Tel: +49 (0) 711/685-63734 Fax:+49 (0) 711/685-63729 Email: [email protected] Tel: +49 (0) 711/685-65467 Fax:+49 (0) 711/685-63729 Email: [email protected] Secretary´s office Andrea Matzig Tel.: +49 (0) 711/685-63708 Fax: +49 (0) 711/685-63729 E-Mail: [email protected] Research Assistants Dr.-Ing. Niko Strunk Tel: +49 (0) 711/685-63730 Fax:+49 (0) 711/685-63729 Email: [email protected] Dr.-Ing. Daniel Dobslaw Tel: +49 (0) 711/685-65406 Fax:+49 (0) 711/685-63729 Email: [email protected] Doctoral Candidate Thomas Gerl Tel: +49 (0) 711/685-65474 Fax:+49 (0) 711/685-63729 Email: [email protected] Dipl.-Ing. Steffen Helbich Tel: +49 (0) 711/685-65474 Fax:+49 (0) 711/685-63729 Email: [email protected] M. Sc. Diego Salamanca Tel: +49 (0) 711/685-65467 Fax:+49 (0) 711/685-63729 Email: [email protected] 142 Chair of Hydrochemistry and Hydrobiology o. Prof. Dr. rer. nat. habil Jörg W. Metzger Hydrochemistry and Analytical Quality Assurance | CH Dr.-Ing. Michael Koch Hydrobiology and analysis of organic trace compounds | BiOS Dr. rer. nat. Bertram Kuch 143 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Hydrochemistry and Hydrobiology The Chair of Hydrochemistry and Hydrobiology deals with practically based oriented environmental topics and develops solutions in interdisciplinary cooperation with natural scientists and engineers. A sound basic knowledge in natural sciences is required to understand interdisciplinary contexts concerning all areas of Environmental Engineering. Biological and chemical processes are of elemental importance for various kinds of technologies for drinking water and wastewater treatment as well as for composting of solid and green waste or for the decontamination of groundwater. The quality of water, no matter if it is wastewater, surface water, groundwater or drinking water, depends on chemical and microbiological parameters, for which the legislator has defined limits (e.g. in the Drinking Water Ordinance). In order to guarantee that these limits are not exceeded it is important to reiterate the analytical monitoring process at regular intervals. The task of the Environmental Analysis is to develop and to apply methods which allow to identify and quantify inorganic and organic compounds, either as single substances or in total - as so called summary parameter- in various environmental compartments, such as water, waste water, landfill leachate, soil, sediment, sewage sludge etc. The high toxicity of various environmental chemicals as well as potential ecotoxicological properties, e.g. the tendency to undergo geo- or bioaccumulation, requires the determination of substances as specific and selective as possible and in very low concentrations independent of potential interferences with disturbing matrix components. Therefore, the methods applied have to be constantly optimized and the inherent uncertainty of measurement of the analytical data has to be kept in mind. New technologies in wastewater treatment or drinking water purification can be most effectively developed by a close cooperation of engineers and natural scientists. A typical example is the the determination of the efficiency of a process for water purification, a second one is effect-related analysis, in which the concentrations of a pollutant in a sample are correlated with its biological effects. The latter constitutes a basis for a risk-assessment, an area where biology and chemistry directly meet. Suitable biological test systems (bioassays), preferably as simple as possible, are required as basis for the practical applicability of this concept. Also, the elucidation of the environmental behaviour of natural and anthropogenic substances - pathways of degradation, formation of metabolites, identification of microorganisms participating in transformation reactions - requires that chemists and biologists work hand in hand. 144 The Chair for Hydrochemistry and Hydrobiology at the ISWA has been supervised by Prof. Dr. rer. nat Jörg W. Metzger since 1996. It consists of the division of Hydrochemistry and Analytical Quality Assurance headed by Dr.-Ing. Michael Koch and the division of Hydrobiology and Organic Trace Analysis headed by Dr. rer. nat. Bertram Kuch. Teaching Activities The Chair of Hydrochemistry and Hydrobiology offers a broad range of basic and advanced lectures and practical work for Bachelor and Master students of the courses Civil Engineering and Environmental Engineering as well as for the international master programs WAREM and WASTE at the University of Stuttgart. They are intended to transmit basic and advanced knowledge in Chemistry of Water and Waste Water, Water- and Soil Protection and Environmental Analysis. The students can get a deeper insight into these issues and a better understanding of the theory by attending training courses for sampling or practical laboratory work where the students learn how to perform environmental analyses and how to carry out experiments in the chemical and microbiological laboratories of the institute. Teaching Modules (G: in German; E: in English): Name of Module Biology and Chemistry for Civil Engineers (G) Basics of Environmental Analysis Methods of Measurement with Practical Work (G) Ecological Chemistry (G) Biology and Chemistry of Water and Wastewater with Practical Work (G) Industrial Wastewater Technology I (G) Environmental Analysis: Water, Soil (G) Biology and Chemistry for Environmental Engineers (E) Industrial Waste Water (E) Sanitary Engineering - Practical Class (E) VL P x Teaching BSc. MSc. Course BAU x x x UMW x x x UMW BAU CH x x x x x UMW BAU x x x x UMW BAU x x x UMW x WAREM WASTE x x WAREM WASTE WAREM WASTE x x x x x x x x x Chair of Hydrochemistry and Hydrobiology Lectures and Practical Classes (G: in German; E: in English): Title VL P Chemical Basis for the Prevention of Water Pollution (G) Measurement and Analysis of Water Pollutants with Practical Work (G) Analysis of Pollutants with Practical Work (G) Environmental Analysis with Practical Work (G) x x x x x x x Chemistry of Water and Wastewater with Practical Work (G) x x Biology and Chemistry for Civil Engineers Chemistry for Civil Engineers I (G) Chemistry for Civil Engineers II (G) Basics of Environmental Analysis Methods of Measurement with Practical Work Determination of Chemical Parameters (G) Ecological Chemistry Ecotoxicology and Assessment of Pollutants (G) Structure and Properties of Water and Aqueous Solutions (G) Environmental Chemistry with Practical Work (G) Behaviour and Toxicity of Environmental Pollutants (G) Biology and Chemistry of Water and Wastewater with Practical Work Chemistry of Water and Wastewater (G) Chemistry of Water and Wastewater - Practical Work (G) Industrial Waste Water Technology I (G) Chemical Water Technology (G) Chemical Water Technology - Practical Work (G) Environmental Analysis: Water, Soil Analysis of Pollutants in Soil and Water (G) Instrumental Analysis (G) Environmental Analysis - Practical Work (G) Quality Assurance in Analytical Chemistry (G) Teaching Dipl. BSc. MSc. Course UMW x UMW x UMW x UMW x UMW x BAU x x BAU BAU x x x UMW x x x x x UMW BAU CH x x x x x UMW BAU x x x x UMW BAU x x x x x x UMW x x WAREM WASTE x x x WAREM WASTE x x WAREM WASTE x x x x Biology and Chemistry for Environmental Engineers Organic Chemistry (E) Industrial Waste Water Water Analysis and Analytical Quality Control (E) Sanitary Engineering - Practical Class Part Chemistry and Microbiology (E) x x International Within the professional postgraduate master course EDUBRAS-MAUI lectures have been offered twice a year by Prof. Metzger since March 2008 in Curitiba, Brazil. The course has the aim to transfer knowledge and instruct Brazilian students in municipal and industrial aspects of environmental protection. It is a cooperation between the ISWA (University of Stuttgart), the Universidade Federal do Paraná and the Brazilian association SENAI, Paraná. EDUBRAS-MAUI Title of Lecture Química ambiental (Environmental Chemistry) Química da água e dos efluentes (Chemistry of Water and Waste Water) Analítica ambiental (Environmental Analysis) Ecotoxicologia e avaliação dos poluentes (Ecotoxicology and Risk Assessment of Pollutants ) 145 Institute for Sanitary Engineering, Water Quality and Solid Waste Management In cooperation with the Norwegian Centre of Soil and Environmental Research, Bioforsk, the Norwegian University of Life Sciences (UMB), and the University of Helsinki (Finland) digestates resulting from the anaerobic treatment of biowastes were investigated in order to determine the presence and concentration of persistant organic pollutants. Within the activities of proficiency testing in analytical chemistry (AQS Baden-Württemberg) the institute has cooperations with the following organisations: • Finnish Environment Institute, Helsinki, Finnland • Health and Safety Laboratory, Buxton, Derbyshire UK • Institute of Nuclear Chemistry and Technology, Warszawa, Polen • IRMM EU Institute for Reference Materials and Measurements, Geel, Belgien • Istituto Superiore di Sanità, Rom, Italien • Kenya Bureau of Standarts, Nairobi, Kenya • Laboratory of the Government Chemist, Teddington, UK • Mauritius Standarts Bureau, Port Louis, Mauritius • Metrology Institute of the Republic of Slovenia, Ljubljana, Slowenien • Namwater, Windhoek, Mamibia • National Accreditation Board for Testing and Calibration Laboratories (NABL), India • National Center for Public Health, Budapest, Ungarn • Petroleum Research Laboratory, Ankara, Türkei • Quintessence Enterprise, Nicosia, Zypern • Southern African Development Community Cooperation in Measurement Traceability, Pretoria, Südafrika • Tanzania Bureau of Standards, Dar es Salaam, Tansania • Uganda National Bureau of Standarts, Kampala, Uganda 146 Chair of Hydrochemistry and Hydrobiology Theses (Diploma) Analysis of siloxanes in wastewater and sewage sludge Barbara Fey (Umweltschutztechnik) (2010) Supervisor: Prof. Jörg W. Metzger, Dr. Bertram Kuch Summary During digestion of sewage sludge volatile siloxanes are able to get into sewage gas, which due to its composition (methane and carbon dioxide) is suitable to be burned in combined heat and power units (CHP). During combustion of siloxanes silicon dioxide is formed, which can lead to quartz-like deposits in the CHP and related engine damages. The elimination of siloxanes from sewage gas by activated carbon is associated with significant investment and operational costs. Therefore it is examined whether adjustments of the conventional treatment process and modifications of the advanced wastewater treatment technologies can contribute to reduce siloxane concentrations in sewage gas. As part of the thesis, methods for determining the siloxane concentration in wastewater and sewage sludge are developed and tested, since it is necessary to know/understand the behavior of siloxanes in WWTP. For this purpose several extraction methods for wastewater and sewage sludge were tested, since the - according to literature - used method is very time-consuming (stripping the siloxanes and collecting via XAD-resin). The concentration of siloxanes were determined using GC/MS analysis. For wastewater samples the micro-separation with hexane could be identified as suitable preparation methods. The preparation of sludge samples via stirring and centrifuging with hexane turned out to be most effective. To prove the practicality of the extraction processes, separate series of measurements for mass balance studies of activated sludge process and rotating immersion disc technology of the teaching and research WWTP Büsnau were conducted. During mass balance studies of the activated sludge process it has been established, that the concentration of hexamethylcyclotri- and octamethylcyclotetrasiloxane in the activated sludge tank decreases through volatilization, while the concentration of decamethylcyclopentasiloxane changes not significantly. Balancing the rotating immersion disc technology micro-separation has been applied in an Erlenmeyer flask, which proved to be susceptible to changes in stirring rate. Since the concentration of siloxanes vary greatly within a few minutes, composite samples should be used for further studies. Additionally the optimal stirring rate should be determined. Organophosphorus flame retardants in two southern German surface waters - entry and concentration gradients Jonas Schmidinger (Umweltschutztechnik) (2011) Within the framework of WESS-Project (Water & Earth System Science Competence Cluster) Supervisor: Prof. Jörg W. Metzger, Dr. Bertram Kuch Summary Organophosphorus flame retardants nowadays are used in large quantities and versatile. Since some of these substances are considered of toxicological concern and show persistent environmental behavior, within the thesis two small German streams (Ammer and Körsch) with varying wastewater content were investigated on the occurrence of organophosphorus flame retardants and possible entries of these compounds. In addition to concentration gradients at individual sampling days residual analysis were performed to represent the deviations of the individual sampling points from the average concentration across the river. It became apparent that the concentration profiles of the two chlorinated substances TCPP and TDCPP show a similar pattern along the course of the river Körsch. Generally TCPP showed on average the highest measured concentrations in both waters and only minor degradation or dilution effects. The phase distribution of the observed flame retardants in the surface waters was determined by measuring membrane-filtered samples. With the exception of triphenyl phosphate, whose concentrations measured in unfiltered river water exceeded the values of the filtered samples by an average of five times, the substances showed low sorption to filterable solids. As the main source of entry into the aquatic environment the discharge of purified wastewater from municipal sewage treatment plants could be identified. Likewise, occuring concentration peaks could be attributed to storm water overflow discharge. 147 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Theses (Bachelor) Entry, occurrence and environmental behavior of the biocide triclosan and the transformation product methyltriclosan in aquatic environments Alexander Kilian (Umweltschutztechnik) (2011) Within the framework of WESS-Project (Water & Earth System Science Competence Cluster) Supervisor: Prof. Jörg W. Metzger, Dr. Bertram Kuch Summary Since the 70s triclosan is used as a disinfecting agent and preservative in medical and private sectors. WWTP are the main entry path for triclosan and its transformation product methyltriclosan into surface waters, where they have a high sorption capacity (enrichment in sediments). Furthermore methyltriclosan tends to bioaccumulate in fish. As part of the thesis the small rivers Körsch and Ammer, and the Goldersbach (reference river) were investigated regarding the two compounds. For this purpose water samples (monthly random samples during the period June 2010 - April 2011) along the rivers and brown trouts of the Ammer and the Goldersbach (captured in October 2010) were analyzed using GC/MS. The aim was to determine the pollution of rivers, elucidate the effect of treatment plants, as well as to investigate the environmental behavior of the two substances. Both substances were detected in the Ammer and the Körsch, but could not be found in the reference stream Goldersbach. As the main entry path WWTP was confirmed, whereat the contribution of the individual wastewater treatment plants to water pollution varies greatly. The concentrations of triclosan and methyltriclosan in the Körsch (up to 217 ng/L and 29 ng/L) compared with the Ammer (up to 94 ng/L and 5 ng/L) are higher. The decay behavior varies both between the two substances (decay of triclosan is more pronounced then decay of methyltriclosan) and between the rivers (along the Ammer more pronounced decay). Compared to other rivers, the concentrations are elevated in the Körsch while they are comparable in the Ammer. It becomes apparent that in small, heavily by WWTP affected rivers, concentration problems with possible adverse effects on the environment occur. In brown trouts of the Ammer methyltriclosan in concentrations of up to 34 µg/kg fresh weight for the filet samples and up to 70 µg/kg fresh weight for the whole fish has been demonstrated. Immediately after the WWTP, the concentrations were elevated compared to fish samples from other rivers, whereas in the further course of the Ammer concentrations were comparable 148 Elimination of ten organic micropollutants in water via advanced ocidation processes (AOPs) Greta Petrova (Extern, Universität Duisburg-Essen) (2010) Supervisor: Prof. Torsten Schmidt, Universität Duisburg-Essen Dr. Bertram Kuch Summary Selected anthropogenic waste indicators (AWIs) including three pharmaceuticals, two synthetic musks, phosphorous flame retardants and an insect repellent were investigated for their removal potential by UV-base processes (UV and UV/H2O2) in a real STP effluent matrix by variation of the irridation time and amount H2O2 added. The compounds were selected on the basis of reported persistence in the STP effluents, structural difference, ability for analysis at low levels and availability of isotope-labelled internal standards for enhancement of the analysis qualitity, and were analysed in the samples by gas chromatography coupled with mass spectrometry (GC/MS). A strong dependency on the elimination efficiency was observed, being the combination of UV/H2O2 with excess of peroxide the best option for eight of the ten investigated compounds accomplishing 90 % or more removal efficiency. Chair of Hydrochemistry and Hydrobiology Application of powdered activated carbon for improved elimination of organic micropollutants in municipal sewage treatment process using the example of selected substances Anna Mayer (Extern Hochschule Reutlingen) (2011) Supervisor: Prof. Dr. W. Honnen (Reutlingen), Dr. Bertram Kuch Summary To minimize the entry of organic micropollutants in the aquatic environment, strategies have to be developed that help to optimize the elimination of these compounds in the wastewater treatment process. One strategy is concerned with the use of powdered activated carbon for improved elimination of various micropollutants. As part of the bachelor thesis adsorption characteristics of selected substances (synthetic musk fragrances: AHTN, HHCB and HHCB-lactone; medicines: diclofenac, carbamazepine and dibenzo[b,f]azepine; insect repellents: diethyl toluamide) on powdered activated carbon (PAC), and the influence of the PAC-amount (2 mg/L – 30 mg/L) and minutes of contact time (2 min. – 60 min.) - based on samples of the teaching and research WWTP Büsnau – are examined. Following the implementation of contact experiments and separation of powdered activated carbon, the organic micropollutants were enriched using liquidliquid extraction and the concentrated extracts were analyzed by GC-MS in full scan mode. The results of adsorption experiments with powdered activated carbon showed that at an economically justifiable PAC-initial weight of 10 mg/L carbamazepine against expectations shows the best adsorption (up to 79 %). For all studied compounds, except for DEET (38 %), good elimination rates (58 % for HHCB, AHTN 69 %) were observed. In studies on the effect of contact time could be determined that an extension of the treatment period of 30 to 40 minutes resulted in no further increase of elimination. In summary, it can be stated that the use of powdered activated carbon contributes greatly to improved elimination of the studied micropollutants. Subsequent studies should address the combination of methods such as use of additional UV radiation or ozonization for complete elimination of these compounds. Elimination of organic micropollutants from municipal waste water by powdered activated carbon and precipitating agents Ümit Tastan (Chemie) (2011) Supervisor: Prof. Jörg W. Metzger, Dr. Bertram Kuch Summary Recently the multiplicity of organic trace compounds (e.g. pharmaceuticals, synthetic fragrances or synthetic additives), which is released into surface waters via municipal wastewater, are a matter of particular interest. These compounds are detected increasingly in surface waters in recent decades. In order to minimize the entry of these substances into the environment, some WWTPs are already using advanced wastewater treatment technologies such as ozonization, H2O2/UV-oxidation or activated carbon filtration units to improve the elimination of organic trace compounds. Inter alia the use of powdered activated carbon is considered to be very promising. In the present work, the elimination of selected organic micropollutants with powdered activated carbon, inorganic precipitation agents and their combinations was studied. Different application fields and entry pathways, as well as different physical-chemical properties were used as selection criteria for the investigated trace substances. As precipitating agent inter alia iron-(III)-chloride, which is used in municipal wastewater treatment plants to improve the sludge sedimentation behavior and for phosphorus removal, was applied. Good elimination efficiencies of more than 60 % could be achieved by using 10 mg/L powdered activated carbon at a contact time of 20 min. for all substances - with the exception of the insect repellent DEET. Elimination rates of more than 95 % could be achieved for the disinfectant triclosan and methylthiobenzothiazole (MTBT; industrial chemical used in the production of rubber). In first approximation, the tendency for sorption increases with increasing phase partition coefficients (log Kow) of the compounds, an explicit correlation to the elimination efficiency achieved with the log Kow value of the analytes could not be found. Far less influence on the elimination of trace substances showed the precipitation agents used at dosages of 5 mg/L to 110 mg/L. Even during combined using of precipitants with powdered activated carbon, no significant effects were observed on the removal efficiency. In summary, it can be stated that the use of powdered activated carbon contributes greatly to improved limination of various organic trace substances from municipal waste water and the influence of precipitation agents and their combination with powdered activated carbon on the elimination is negligible. 149 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Theses (Master) Doctoral Dissertations Removal of Anionic Colloidal Impurities in Process Water from the Pulp and Paper Industry by an Electrolytikc Process Using Saveificial Aluminium Electrodes Francisco Miguel Terán Camarena, Master of Science (2011) Studiengang: WASTE Supervisor: Prof. Dr. Thomas Hirth (IGVT), Prof. Dr. Jörg Metzger Leachate prognosis: possibilities and limitations of laboratory and field studies Study of treated effluent as industrial water in automotive industry Estudo do reúso de efluente tratado como água de processo na indústria automotiva Leopoldo Erthal, Master of Science (2011) Studiengang: EDUBRAS-MAUI - Brasilien Supervisor: Prof. Dr. Jörg Metzger, Dr.-Ing. Daniela Neuffer Advanced wastewater treatment technologies - Elimination of organic micropollutants via powdered activated carbon Tecnologias avançadas de tratamento de efluentes – Remoção de micropoluentes orgânicos através de carvão ativado em pó Juliano César Rego Ferreira, Master of Science (2011) Studiengang: EDUBRAS-MAUI - Brasilien Supervisor: Prof. Dr. Jörg Metzger, Dr.-Ing. Daniela Neuffer Advanced wastewater treatment technologies - Elimination of organic micropollutants via UVirradiation and hydrogen peroxide Tecnologias de Tratamento Avançado de Águas Residuais – Eliminação de Micropoluentes Orgânicos através de Irradiação UV e UV/H2 O2 Telma Soares, Master of Science (2011) Studiengang: EDUBRAS-MAUI - Brasilien Supervisor: Prof. Dr. Jörg Metzger, Dr.-Ing. Daniela Neuffer Sylvia Mackenberg (Dissertation 2010) Supervisor: Prof. Dr. Jörg W. Metzger Prof. Dr. I. Neuweiler Prof. Dr. T. Streck Treatment of Liquid Hazardous Waste and Highly-Loaded Industrial Wastewater by PhotoFenton Process, using a Newly-Developed Photoreactor including Noxoiusness Assessment Ibrahim Abdel Fattah (Dissertation 2010) Supervisor: Prof. Dr.-Ing. M. Kranert Prof. D. Bahnemann Prof. Dr. Jörg W. Metzger Persistent organic micropollutants in compost and digestates from biomass fermentation Degree of contamination, degradation and evaluationg Jessica Stäb (Dissertation 2011) Supervisor: Prof. Dr. Jörg W. Metzger Prof. Dr. Dr. Richert Prof. Dr. Stubenrauch Contamination of the Lake Constance with organic micropollutants - Determination of polychlorinated biphenyls and polybrominated diphenyl ethers in sediments, mussels and fish Jörg Alexander Pfeiffer (Dissertation 2011) Supervisor: Prof. Dr. Jörg W. Metzger Prof. Dr. H.-D. Görtz Prof. Dr.-Ing. R. Helmig Temporal behaviour of biozides in surface coatings for building materials during perennial field experiments Regina Cordula Schwerd (Dissertation 2011) Supervisor: Prof. Dr.-Ing. F. Berner Prof. Dr.-Ing. K. Sedlbauer Prof. Dr. Jörg W. Metzger 150 Chair of Hydrochemistry and Hydrobiology Publications Antakyali, D.; Kuch, B.; Preyl, V.; Steinmetz, H. (2011): Effect of Micropollutants in Wastewater on Recovered Struvite. Proceedings of the WEF Conference Nutrient Recovery and Management, Miami, USA. Bari, M. A.; Baumbach, G.; Brodbeck, J.; Struschka, M.; Kuch, B.; Dreher, W.; Scheffknecht, G. (2010): Characterisation of particulates and carcinogenic polycyclic aromatic hydrocarbons in wintertime wood-fired heating in residential areas. Atmospheric Environment, doi:10.1016/j.atmosenv.2010.11.053. Bari, M. A.; Baumbach, G.; Brodbeck, J.; Struschka, M.; Kuch, B.; Scheffknecht, G. (2010): Characterisation of carcinogenic PAH exposure in wintertime wood-fired heating in residential areas. Tagungsband: International Specialty Conference „Air Pollution and Health: Bridging the gap from sources to health outcomes“, San Diego, California, 22 - 26.03.2010, 330. Bopp, K.; Kuch, B.; Roth, M. (2010): Hormonelle Aktivität in natürlichen Mineralwässern? Deutsche Lebensmittel-Rundschau 106, 489 - 500. Dowideit, K.; Scholz-Muramatsu, H.; Miethling-Graff, R.; Vigelahn, L.; Freygang, M.; Dohrmann, A. B.; Tebbe, Ch. C. (2010): Spatial heterogeneity of dechlorinating bacteria and limiting factors for in situ trichloroethene dechlorination revealed by analyses of sediment cores from a polluted field site. FEMS Microbiology Ecology 71(3), 444-459, March 2010, Article first published online: 26 NOV 2009, DOI: 10.1111/j.15746941.2009.00820.x. Drenkova-Tuhtan, A.; Meyer, C.; Steinmetz, H. (2011): Einsatz der Nanotechnologie in der Abwasserreinigung. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag GmbH, München, Band 208, 55 - 79. Bari, M. A.; Baumbach, G.; Kuch, B.; Scheffknecht, G. (2010): Particle-phase concentrations of polycyclic aromatic hydrocarbons in ambient air of rural residential areas in southern Germany. Air Quality, Atmosphere & Health, 3/2, 103 - 116. Govasmark, E.; Stäb, J.; Holen, B.; Frøseth, R. B.; Nesbakk, T. (2011): Contaminants in anaerobically digested residue in full-scale biogas plants and their fate in agricultural production. Agronomy for Sustainable Development - Eingereicht. Bari, M. A.; Baumbach, G.; Kuch, B.; Scheffknecht, G. (2010): Temporal variation and impact of wood smoke pollution on a residential area in southern Germany. Atmospheric Environment DOI 10.1016/j.tmosenv.2010.06.031, 1 - 10. Govasmark, E.; Stäb, J.; Holen, B.; Hoornstra, D.; Nesbakk, T.; Salkinoja-Salonen, M. (2011): Chemical and microbiological hazards associated with recycling of anaerobic digested residue intended for agricultural use. Waste Management, 31(12), 2577-2583. Bari, M. A.; Brodbeck, J.; Struschka, M.; Baumbach, G.; Kuch, B.; Scheffknecht, G. (2010): Importance of Clean Biomass Combustion for the Air Quality in Residential Areas. Tagungsband: 1st International Conference on the Developments in Renewable Energy Technology“ held in Dhaka, Bangladesh on 1719.12.2009. Govasmark, E.; Stäb, J.; Holen, B.; Hoornstra, D.; Salkinoja-Salonen, M. (2010): Biorest - en risiko i økologisk landbruk. Bioforsk FOKUS 5(2), 40-41, ISBN: 978-82-17-00600-8, ISSN: 0809-8662. Baumeister, F.; Borchers, U.; Koch, M. (2010): PTWFD: the network of PT providers to support the implementation of the European water framework directive. Accred. Qual. Assur. 15, 193-198. Boley, A.; Fink, W.; Kieninger, M.; Müller, W.-R. (2010): Vorrichtung zur schonenden Durchmischung von Stoffgemengen beispielsweise zur Durchführung von Abbauuntersuchungen unter aeroben, anoxischen und anaeroben Bedingungen. Patentanmeldung DPMA. Boley, A.; Narasimhan, K.; Kieninger, M.; Müller, W.-R. (2010): Ceramic Membrane Ultrafiltration of Natural Surface Water with Ultrasound Enhanced Backwashing. Wat. Sci. Technol. 61(5), 1121-1127. IGKB (2010): Keine Gefahr durch Flammschutzmittel. Internationale Gewässerschutzkommission für den Bodensee (IGKB), Seespiegel 31, 4. Koch, M. (2010): Basic Statistics. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry - Training and Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 161 – 181. Koch, M. (2010): Calibration. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry - Training and Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 183 – 200. Koch, M. (2010): Interlaboratory Tests. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry - Training and 151 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Poster Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 303 - 326. Koch, M. (2010): Measurement Uncertainty. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry - Training and Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 247 – 272. Koch, M. (2010): Quality Manual. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry - Training and Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 143 – 159. Koch, M.; Gluschke, M. (2010): Control Charts. In: Wenclawiak, B.W., Koch, M., und Hadjicostas, E. (Hrsg.): Quality Assurance in Analytical Chemistry Training and Teaching. Springer-Verlag, Berlin Heidelberg 2010 2nd Edition, 273 – 288. Kuch, B. (2010): Messung von Spurenstoffen im Regen- und Mischwasserabfluss. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Oldenbourg Industrieverlag, Band 201, 51 - 63. Magunsson, B.; Koch, M. (2011): Measurement Quality in Water Analysis. In: Peter Wilderer (ed.) Treatise on Water Science, Oxford: Academic Press, Elsevier Ltd., vol.3, 153-169. Wenclawiak, B. W.; Koch, M.; Hadjicostas, E. (Hrsg.) (2010): Quality Assurance in Analytical Chemistry Training and Teaching. 2nd Edition, Springer-Verlag, Berlin Heidelberg 2010. Baumeister, F.; Koch, M.; Borchers, U. (2011): Recent activities of the PT-WFD network. EURACHEM 2011 7th Workshop - Proficiency testing in analytical chemistry, microbiology and laboratory medicine, Istanbul, Turkey, 3.-6.10.2011. Conradi, M.; Koch, M. (2011): Proficiency Testing Scheme for Chemical Analysis of Water in Africa. EURACHEM 2011 - 7th Workshop - Proficiency testing in analytical chemistry, microbiology and laboratory medicine, Istanbul, Turkey, 3.-6.10.2011. Govasmark, E.; Stäb, J.; Holen, B.; Hoornstra, D.; Salkinoja-Salonen, M. (2010): Contaminants in digestate from household waste in Norway - a fertilizer? 7th international conference ORBIT 2010 - Organic Resources in the Carbon Economy, Heraklion Crete, Greece, 29.06.-03.07.2010, ISBN 978-960-6865-25-1. Govasmark, E.; Stäb, J.; Holen, B.; Hoornstra, D.; Salkinoja-Salonen, M. (2011): Contaminants in digestate from household waste in Norway. NJF 24th Congress - Food, Feed, Fuel and Fun - Nordic Light on Future Land Use and Rural Development, Uppsala, Sweden, 14.-16.06.2011. Gutjahr, N.; Kuch, B.; Neft, A.; Dittmer, U. (2010): Assessment of pollutant loads in stormwater runoff by a combination of online-monitoring and sampling. 14th International Conference IWA Diffuse Pollution Specialist Group Diffuse Pollution and Eutrophication, Québec City, 12.-17.09.2010. Koch, M.; Baumeister, F. (2011): On the Use of Consensus Means as Assigned Values. EURACHEM 2011 7th Workshop - Proficiency testing in analytical chemistry, microbiology and laboratory medicine, Istanbul, Turkey, 3.-6.10.2011. Koch, M.; Magnusson, B. (2011): Evaluating measurement uncertainty over the concentration range from proficiency testing data. EURACHEM 2011 - 7th Workshop - Proficiency testing in analytical chemistry, microbiology and laboratory medicine, Istanbul, Turkey, 3.-6.10.2011. Mbwambo, K.; Lyimo, E.; Dentons Kaviiri, Ph. H.; Kerubo Nyakoe, F.; Irungu, A.; Koch, M. (2011): Profisiency Testing for Analytical Chemistry Laboratories organized in the East African Community Countries. EURACHEM 2011 - 7th Workshop - Proficiency testing in analytical chemistry, microbiology and laboratory medicine, Istanbul, Turkey, 3.-6.10.2011. Pfeiffer, J. A. (2010): Spurenstoffe im Bodensee. Institut für Seenforschung, Langenargen, 11.03.2010. 152 Chair of Hydrochemistry and Hydrobiology Pfeiffer, J. A.; Kuch, B.; Hetzenauer, H.; Schröder, H. G.; Metzger, J. W. (2010): Flammschutzmittel in Bodenseeorganismen (FLABO) - Bestimmung von PBDE und PCB in Sedimenten, Muscheln und Fischen des Bodensees. Jahrestagung der Wasserchemischen Gesellschaft - Fachgruppe der GDCh, Bayreuth, 10.12.05.2010. Stäb, J.; Govasmark, E.; Kuch, B.; Metzger, J. W. (2010): Organic pollutants in Compost and Digestate from Norway and Germany. 3rd EuCheMS Chemistry Congress, Nürnberg, 29.08.-02.09.2010. Stäb, J.; Govasmark, E.; Kuch, B.; Metzger, J. W. (2010): Organic pollutants in German Compost and Digestate. 7th international conference ORBIT 2010 - Organic Resources in the Carbon Economy, Heraklion Crete, Greece, 29.06.-03.07.2010, ISBN 978-9606865-25-1. Zhang, Q.; Krauß, M.; Neft, A.; Kuch, B.; Minke, R.; Steinmetz, H. (2010): Assessment of river water quality in a watershed affected by large-scale rubber planations-pesticides and other organic trace substances. 14th International Conference IWA Diffuse Pollution Specialist Group Diffuse Pollution and Eutrophication, Québec City, 12.-17.09.2010. 153 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Contact Chairholder o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Tel.: +49 (0)711/685-63721 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Secretary´s office Dörte Hahn Tel.: +49 (0)711/685-63721 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Hydrochemistry and Analytical Quality Assurance Dr.-Ing. Michael Koch Tel.: +49 (0)711/685-65444 Fax: +49 (0)711/685-554449 E-Mail: [email protected] Hydrobiology and analysis of organic trace compounds Dr. rer. nat. Bertram Kuch Tel.: +49 (0)711 685-65443 Fax: +49 (0)711 685-63729 E-Mail: [email protected] 154 Chair of Hydrochemistry and Hydrobiology 155 Chair of Hydrochemistry and Hydrobiology Hydrochemistry and Analytical Quality Assurance In the Division of Hydrochemistry and Analytical Quality Assurance the focus is on topics from environmental chemistry and the related analysis as well as all issues of quality assurance in analytical chemistry. The focus of the analytical tasks in this division is mainly on the hydrochemical analytical services for engineering departments in the institute. Especially the following analyses are carried out: • Digestion for element analyses - Aqua regia extract - Microwave supporte digestion (MLS Ethos 1600) • Element determination - using ICP-OES (PerkinElmer Optima 3000) - using Continuum Source Atomic Absorption Spectrometry with flame and graphite furnace (AnalytikJena contrAA 700) - using Hydride Technique Atomic Absorption Spektrometry (PerkinElmer 2100) - using Atomic Fluorescence (for mercury) (AnalytikJena mercur) • Adsorbable Organic Halogens AOX (AnalytikJena multi X 2000) • Determination of anions using ion chromatography (Dionex ICS-1000) • Determination of the Total Petroleum Hydrocarbon index using gas chromatography (PerkinElmer Autosystem GC) • Determination of highly volatile compounds (PerkinElmer Autosystem GC und PerkinElmer Autosystem XL GC) • other wet chemical and photometrical analyses Besides the measurements we provide advice to our colleagues from other divisions about analytical questions. From time to time we are directly involved in research projects. So presently we are working in a research project on the environmental compatibility of photo voltaic modules. 156 Hydrochemistry and Analytical Quality Assurance CH Research In the field of Analytical Quality Assurance the main focus of our work is on providing proficiency testing interlaboratory comparisons in co-operation with TGZ AQS Baden-Württemberg of the Technologie-TransferInitiative GmbH at the University of Stuttgart. These proficiency tests mainly are provided on behalf of the government of Baden-Württemberg, but are offered throughout whole Germany and beyond. In order to keep their license for analysing waste and drinking water numerous water laboratories in Germany are obliged to participate in these proficiency tests. Our special scientific interest is on the development of proficiency testing techniques, especially for the preparation of samples and for the statistical evaluation and assessment. Here we also operate internationally. For chemical analytical laboratories there is a big need for advanced training on quality assurance issues. Therefore we are organizing courses and in-house trainings. Strengthening the quality infrastructure in developing countries is an important condition for strengthening the economies in such countries, and also for the protection of public health and environmentyl protection. In developing projects of the German Metrology Institute (Physikalisch-Technische Bundesanstalt) we are organizing trainings and do consultance for proficiency test providers. Establishment of a regional quality infrastructure in the East African Community (EAC) An effective regional quality infrastructure (QI), in which all parties recognise each other mutually, plays a central role for the development of a common market in the member countries of the East African Community (Tanzania, Kenya, Uganda, Rwanda and Burundi) since it enables, to a large extent, a mutual and free movement of goods as well as the development of environmental and consumer protection on a liberalised market. In a project of the German metrology institute Physikalisch-Technische Bundesanstalt (Project executing agency: Secretariat of the East African Community) this QI is to be strengthened. For this purpose among other things proficiency test for the chemical analysis of food (edible salt, wheat flour, edible vegetable oil) are performed. Scientific support and consultancy of these PT schemes is the task of ISWA in this project. Financing Institution: Physikalisch-Technische Bundesanstalt (PTB) Contact: Prof. Dr. Jörg W. Metzger, Dr.-Ing. Michael Koch Duration: since 12/2007, for an unlimited period 157 Chair of Hydrochemistry and Hydrobiology Photovoltaikmodule - Umweltfreundlichkeit und Recyclingmöglichkeiten The market for photovoltaic (PV) modules registers strong growth rates. It is assumed that solar modules produce energy on the average for 25 years. Afterwards they must be disposed of and/or recycled. It is a goal to introduce a sustainable recirculation system for PV products with a comprehensive collecting system including civic amenity sites; in addition suitable efficient recycling procedures must be developed, which allow a complete separation of valuable material in high purity and do not cause subsequent disposal problems. The level of knowledge for the liberation of pollutants from photovoltaic modules under different environmental condition at present is still small. Liberation of pollutants during the operation of the modules according to information from manufacturers is impossible. The possibility of a release of pollutants, e.g. after stone impact, hail, fire, effect of acid rain or oxidizing agents etc. must be examined however. In addition it must be examined, what consequences appear, if modules and/or crushed modules are inappropriately disposed of (domestic waste, glass waste). Financing Institution: Ministerium für Umwelt, Naturschutz und Verkehr Baden-Württemberg Contact Prof. Dr. rer. nat. habil. Jörg W. Metzger Prof. Dr.-Ing. Martin Kranert Dr.-Ing. Michael Koch Dr.-Ing. Klaus Fischer Prof. Dr. Jörg W. Metzger Project Partner: ISWA, Arbeitsbereich Siedlungsabfall, Dr. Klaus Fischer Institut für Physikalische Elektronik, Arbeitsgruppe Industrielle Solarzellen, Dr. Renate Zapf-Gottwick ISWA, Arbeitsbereich Hydrochemie und Analytische Qualitätssicherung Dr. Michael Koch Duration: seit 12/2010 - 11/2011 The project covers: • Investigation and evaluation of recycling procedures for different solar modules • Investigation of the liberation potential for pollutants from photovoltaic modules during the operation, in particular under strongly changing climatic conditions, and after the end of the lifetime under different conditions • Evaluation of the environmental behavior and the recycling procedures regarding the situation in threshold and developing countries • Investigation of the possibilities to avoid the liberation of pollutants and development of proposals for environmentally more friendly solar modules and recycling practices. • Evaluation of the results. Photovoltaic modules made of crystalline silicon 158 Hydrochemistry and Analytical Quality Assurance CH AQS Baden-Württemberg The Ministry of the Environment, Climate Protection and the Energy Sector Baden-Württemberg (UM) and the Ministry of Rural Affairs and Consumer Protection Baden-Württemberg (MLR) commissioned the Institute for Sanitary Engineering, Water Quality and Solid Waste Management of the University of Stuttgart with providing external quality control measures for the chemical analysis of waste, ground and drinking water. The main task is the provision of proficiency testing (PT) interlaboratory comparisons in the field of water testing, adjusted to the special requirements for analytical quality control. In 2004 the German drinking water proficiency test provider decided to co-operate and to work in a harmonized way that is in accordance with the “Recommendation for the provision of proficiency tests for drinking water analysis” of the German Federal Environmental Agency, published in Bundesgesundheitsblatt in 2003. Two PT schemes were installed working in a time co-ordinated way. One of these schemes is located in Northrhine-Westphalia (State Agency for Nature, Environment and Consumer Protection LANUV ), the other one is run bei AQS Baden-Württemberg together with the Institute for Hygiene and Environment of the Authority for Health and Consumer Protection in Hamburg. The chemical parameters to be analyzed according to the German drinking water ordinance were distributed to 10 different PT rounds. Both PT schemes offer the whole programme with a one year time shift. For waste water PTs the existing co-operation with other PT providers in environmental authorities in other German states was extended and strengthened. Also on behalf of the UM PTs for rapid tests in waste water treatment plants (WWTP) are provided. Successful participation is required for a special notification of WWTP laboratories in the regulator sector in Baden-Württemberg. In the framework of an European network of proficiency test providers (PT-WFD) for the European Water Framework Directive, AQS Baden-Württemberg organizes PTs for surface water on an European level. The co-operation partner „TGZ AQS-Baden-Württemberg“ of TTI GmbH organizes together with the ISWA the annual meetings for AQS BW as well as courses for waster water sampling and quality control charts. In 2010 and 2011 the programme of these course was extended to measurement uncertainty estimation. In 2010 the following PT rounds were provided by AQS BW: • PT 1/10 - TW A1 – Anions in drinking water: bromate, fluoride, nitrate, nitrite, chloride, sulfate, phosphorous, cyanide, turbidity • PT 2/10 - TW O5 – Special organic organic parameters in drinking water: glyphosate, AMPA and selected pesticide metabolites • PT 3/10 - 24. LÜRV - Ions in waste water: NH4+-N, NO3--N, NO2--N, Cl-, SO42-, CrO42• KARV 2010 – 11th PT for rapid tests in waste water treatment plants - COD, NH4+-N, NO3--N, Nges, (sum of inorg. + org. N), Pges, TOC (optional) • PT 5/10 - TW O1 – Pesticides 1: N- and P-pesticides in drinking water. Atrazine, desethylatrazine, terbutylazine, simazine, propazine, chlortoluron, diuron, isoproturon, metobromuron, metribuzin • PT 6/10 - WFD - Prioritary Substances according to Water Framework Directive: Polybrominated diphenylethers – BDE 28, BDE 47, BDE 99, BDE 100, BDE 153, BDE 154 In 2011 the following PT rounds were provided by AQS BW: • PT 1/11 - TW A2 – Trace elements in drinking water: Chromium, copper, lead, cadmium, nickel, chromium(VI), silicate • PT 2/11 - TW O2 - VOC/Benzene in drinking water: 1,2-Dichloroethane, tetrachloroethene, trichloroethene, trichloromethane, bromodichloromethane, dibromochloromethane, tribromomethane, benzene • PT 3/11 - 26. LÜRV – Sum parameters in waste water: AOX, TOC, BOD5, COD, TNb • KARV 2011 - 12th PT for rapid tests in waste water treatment plants - COD, NH4+-N, NO3--N, Nges, (sum of inorg. + org. N), Pges, TOC (optional) • PT 4/11 - TW A3 - Cations in drinking water, part 1: Aluminium, iron, manganese, sodium, potassium, colour (SAC436) • PT 5/11 – WFD - Pesticides from the list of priority substances in the WFD: aclonifen, alachlor, atrazine, bifenox, chlorfenvinphos, chlorpyrifos, cybutryne, diuron, isoproturon, quinoxyfen, simazine, terbutryn, trifluralin 159 Chair of Hydrochemistry and Hydrobiology Client: Sample preparation for the proficiency test (PT) Ministerium für Umwelt, Klima und Energiewirtschaft Baden-Württemberg, Ministerium für Ländlichen Raum und Verbraucherschutz BadenWürttemberg, Landesanstalt für Umwelt, Messungen und Naturschutz Baden-Württemberg Project Co-ordinator: o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Project manager AQS-BW: Dr.-Ing. Michael Koch Technical manager AQS-BW: Dr.-Ing. Frank Baumeister Secretary‘s office: Heidemarie Sanwald Further Informations: http://www.aqsbw.de High-grade steel vessel (2,1 m3) for pasteurisation of waste water, drinking water and ground water High-precision balances for the net weight of chemicals and solutions Chemicals used for the production of PT samples 160 Stock solutions for the preparation of PT samples Hydrochemistry and Analytical Quality Assurance CH Contact Devision Manager CH & AQS Hydrochemistry and Analytical Quality Assurance Laboratory staff Michael Braun (Chemo Technician) Dr.-Ing. Michael Koch Tel: Tel: +49 (0)711/685-65446, -65444 Fax: +49 (0)711/685-63769, -55444 E-Mail: [email protected] +49 (0)711/685-65447 Maria Gebauer (CTA) Tel: +49 (0)711/685-65454 Secretary´s office Gertrud Joas (CTA) Heidemarie Sanwald* (AQS) Tel: +49 (0)711/685-65454 Cornelia Orth (Dipl.-Ing., FH) Tel: +49 (0)711/685-65446 Fax: +49 (0)711/685-63769 E-Mail: [email protected] Tel: +49 (0)711/685-65435 Dörte Hahn (Hydrochemie) Ellen Raith-Bausch (Chemo Technician) Tel: +49 (0)711/685-63721 Fax: +49 (0)711/685-63729 E-Mail: [email protected] Tel: +49 (0)711/685-65454 oder +49 (0)711/685-65400 Technical Manager AQS Dr.-Ing. Frank Baumeister* Tel: +49 (0)711/685-65442 Fax: +49 (0)711/685-55442 E-Mail: [email protected] Scientists Dipl.-Biol. Biljana Marić* Tel: +49 (0)711/685-65447 E-Mail: [email protected] * Assistants for the Transfer centre and Foundation centre (TGZ) 161 Chair of Hydrochemistry and Hydrobiology Hydrobiology & analysis of organic trace compounds Research topics: • Environmental analysis • Organic micropollutants • Examination of occurence and fate as well as risk assessment of environmentally relevant chemicals • Biological in-vitro test systems, for the determination of hormonal actiivity of environmental samples, i.e. E-Screen-Assay • Biological degradation and risk assessment of pollutants, chemicals and organic solid substrates as well as polymers in water and soil matricess • Biological remediation of organic pollutants from contaminated aquifers The department of hydrobiology and analysis of organic trace compounds focuses mainly on topics of environmental analysis and bioremediation processes. Some research, for example, go into the question of the extent to which ordinary used chemicals such as pharmaceuticals and ingredients of personal care products occur in domestic wastewater, their behavior in wastewater treatment plants (WWTP) and their influence on the ecology - especially on aquatic organisms. Particularly relevant is in which amount these chemicals are retained in WWTP, either by degradation processes in various stages of purification or accumulation in sewage sludge. Chemicals, which are not completely eliminated in the WWTP, reach the surface waters. Consequently, investigations are conducted in surface waters, especially with the question of whether and to what extent chemicals are absorbed by aquatic organisms (e.g. fish), enriched in them or are eliminated or converted by their metabolism. For these tests a number of trace analytical methods are available, some of them specially developed in the department of hydrobiology and analysis of organic trace compounds. Furthermore, we deal with the question which substances in water are capable to interfere with the biological treatment processes - especially the nitrification/denitrification - in WWTP. For this purpose biosensor test systems are used that help to identify nitrification-inhibiting substances. Another focus of the department of hydrobiology and analysis of organic trace compounds concentrates on the biological remediation of contaminated sites. Many ground-water reservoirs in Germany are contaminated by industrial chemicals. Among the most common pollutants are the chlorinated solvents. In the framework of a Federal Ministry of Economics and Technology funded project studies for the rehabilitation of contaminated areas were conducted. The aim of this project is to get a basic understanding about the involvement of microorganisms in the implementation of volatile chlorinated hydrocarbons (VOC), as well as to determine the most effective dosage of a suitable electron donor. Another important parameter is the determination of total estrogenic activity of environmental samples (surface waters, WWTP-influent and -effluent, etc.). Due to its high sensitivity (LOQ < 0.1 ng/L) the E-screen assay is a suitable substitute for the expensive and time-intensive targeted instrumental single substance analysis. As a routine procedure the robust E-screen assay is used in the framework of subcontracted analysis. Furthermore the estrogenic activity of single substances can be determined using this biological test system. 162 Hydrobiology and analysis of organic trace compounds BiOS Final Reports of the Chair Flame retardants in organisms of Lake Constance (FLABO) The Lake Constance is an important habitat for fish and therefore a large food resource - the fishing quota for 2008 was around 725 tones. Organic micro-pollutants, especially persistent lipophilic compounds enter Lake Constance and accumulate in the sediments, as well as in fish and shellfish. Typical representatives of these contaminants are polychlorinated biphenyls (PCBs) which were banned because of their toxic properties already over 20 years ago, but can still be detected in various environmental samples. Polybrominated diphenyl ethers (PBDEs) have been used since the 1970s as flame retardants in textiles and electrical housings and also showed rising environmental levels over the last few decades. Since the industry signed a voluntary negotiated agreement on production and application concentrations seem to have stagnated. The study of dated sediment cores from Lake Constance in 2004/2005 (Interreg III) showed an increase of PBDE-concentrations in younger sedimentary layers. Within the current project, the PBDEs compared to the group of PCBs were determinated in fish (bream - Abramis brama), zebra mussels (Dreissena polymorpha) and sediments of Lake Constance. The bream is a species of fish living close to the sediment partly feeding on zebra mussels. In addition obtaining information on the present load, the aim was to have a closer look on substance accumulation along the food chain. The contaminants could be detected in all investigated environmental samples. The concentrations of PCBs in the sediments were at similar levels as in 2004/2005 and are thereby lower than quality objectives of the WFD (20 micrograms / kg dry matter). On examination of the upper layers lower concentration levels than in the older deeper layers could be determinated. The PCB concentrations in the mussels were at small levels similar to those in the sediment. The congener pattern (concentration distribution of the various individual compounds) showed similarities with the technical mixture „Chlophen-A60“. The pattern of the PBDEs also shows similarities with the technical penta-bromo diphenyl ether mixture. While the PCB pattern between the investigated environmental samples looked similar, the PBDE profile of the various samples were significantly different. This gives us an indication of specific uptake or degradation of certain PBDE congeners. The maximum PCB-concentrations found in the fillets of bream are far below the threshold limit for fresh water fish (Schadstoff-Höchstmengen Verordnung). Compared to PCB concentrations the PBDE concentrations are lower by an order of magnitude. Threshold limits do not exist for the group of PBDEs. Trip with the research ship of the Institute of Lake Research, Langenargen (LUBW) for sediment and mussel sampling. 163 Chair of Hydrochemistry and Hydrobiology Biogas residue - a safety risk in organic farming? Zebra mussels (Dreissena polymorpha) stick on a piece of wood. The largest specimens examined reached a shell length of 1.8 cm. Financing institution: Aim of the project is to determine the potential of biorest from biogas plants as fertilizers in organic farming. The focus is is thereby put on organic pollutants, pesticides, heavy metals, Escherichia coli (E.coli) and Bacillus cereus (B. cereus). For this during one year on a monthly basis samples of a norwegian biogas plant are taken and analysed. The biogas residue is afterwards composted and the compost is sampled likewise. For the determination of the bio-availability plants and compost worm samples are analyzed, in addition the survival of the found bacteria in grain and milk products is observed. In this joint project the ISWA is responsible for the analysis of the organic pollutants. INTERREG IV Contact: Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dipl.-Ing. Jörg Alexander Pfeiffer Project partner: Dr. Heinz Gerd Schröder, Institut für Seenforschung des Landes Baden-Württemberg, Langenargen Wasserwirtschaftsamt Kempten Vorarlberger Institut für Umwelt und Lebensmittelsicherheit Amt für Umwelt der Kantone St. Gallen und Thurgau Amt für Gesundheits- und Verbraucherschutz der Kantons St. Gallen Duration: 01/2008 - 10/2009 Container for the composting of biowaste and digestate Financing institution: Research Council of Norway, P.O. Box 2700 St. Hanhaugen, 0131 Oslo Contact: Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dipl.-Chem. Jessica Stäb Project partner: Bioforsk (Norwegen), Norwegian University of Life Sciences (UMB), und der University of Helsinki (Finnland). Duration: 01/2008 - 12/2010 164 Hydrobiology and analysis of organic trace compounds BiOS Development of Novel Processes for Simultaneous Elimination of Organic Pollutants and Nitrate from Drinking Water by Means of Biodegradable Solid Substrates Even with many legislative regulations not everywhere efforts have been successful to diminish concentrations of Nitrate and Pesticides in groundwater. The aim of this project is the development of a simple and costeffective combined process which allows not only the biological removal of Nitrate but also Pesticides. In this technology we use biodegradable polymers (BDP) as substrates for the heterotrophic denitrification process, e.g. PHB (Poly-ß-Hydroxy Butyric Acid) or PCL (Poly-εCaprolactone). The water insoluble polymer granules act as growth surface for microorganisms and at the same time as organic substrate which can be activated via bacterial exoenzymes and on this way being used for denitrification. In addition the polymers perform as sorbents for the dissolved organic contaminants, e.g. pesticides. In the scope of the project different technical realizations in form of reactor configurations and reactor types are being examined. The performance of different available biodegradable polymers is tested in advance with long term biological test processes thus complementing the pilot testing with semi-technical reactors. As this process is aimed to be applied in drinking water treatment all aspects of the use of BDPs shall be examined. This means between others the examination of the „leachate“ products of the biodegradable polymers, the products which occur during the anoxic biodegradation step and of course also the examination of the biocenosis in the reactors. A check of potentially pathogenic bacteria will be carried out. A long-term objective of the project is the authorization of polymers according to the „List of Treatment Substances and Disinfection Processes“ as per § 11 of the German Drinking Water Ordinance (TrinkwV 2001) and the treatment processes connected with. This List is maintained at the Federal Environment Agency on behalf of the Federal Ministry of Health, Berlin. Financing institution: Forschungszentrum Karlsruhe - Bereich Wassertechnologie und Entsorgung, for the German Federal Ministry of Education and Research (BMBF) Contact: Dr. Angela Boley Dipl.-Ing. Martin Kieninger Project partner: • Forschungszentrum (Research Center) Karlsruhe (FZKA) • Technologie Zentrum Wasser, Karlsruhe (TZW) • Universität Karlsruhe, Engler-Bunte-Institut, Ber. Wasserchemie (EBI) • Martin-Luther-Universität Halle-Wittenberg (MLU) • Firma Nordic Water GmbH • Firma Formtechnik in Südbaden GmbH & Co. KG • Kooperation mit Tsinghua University, Beijing Duration: 10/2006 - 03/2010 Pilot plant for the denitrification and pesticide removal with biodegradable polymers „Dynasand-Reactor“ (Nordic Water) „Roto-Bio-Reactor“ (Formtechnik in Südbaden) 165 Chair of Hydrochemistry and Hydrobiology Research Development of a procedure with significantly improved efficiency and increased environmental compatibility for remediation of groundwater contamination - especially in case of contamination with volatile chlorinated hydrocarbons (VOC), sub-project „Microbiological process fundamentals for the optimization of the electron donor application“ Summary The aim of the microbiological and process engineering studies is the development of new rehabilitation strategies for effective and entire dechlorination of chlorinated ethenes with energy-saving and environmentally friendly use of electron donor in the aquifer. For this purpose electron donors are identified which selectively stimulate the reductive dechlorination and promote by lipophilic properties the mass transfer of volatile chlorinated hydrocarbons from the DNAPL* phase to the electron donor phase. For the most suitable electron donor the economically dosage with minimized DOC-concentrations (dissolved organic carbon) and decreased accumulation of the toxic vinyl chloride and methane are determined in laboratory and field trials. * DNAPL: dense non-aqueous phase liquid Experimental set up for determination of dechlorination with lipophilic electron donors in undisturbed sediment cores from the test field. 166 Financing institution: Bundesministerium für Wirtschaft und Technologie, ZIM (Zentrales Innovationsprogramm Mittelstand) Contact: Prof. Dr. rer. nat. habil. Jörg W. Metzger Dipl. Chem. Claudia Lange, Dr. Bertram Kuch Project partner: Firma ISTEV GmbH Innovative Sanierungstechnologien und –verfahren, Berlin, Dipl.-Geol. Peter Hein Firma Geolog, Braunschweig, Dipl.-Geol. Dr. Johannes Körner und Geophysiker Dr. Eugeniu Martac Duration: 05/2009 - 07/2011 Hydrobiology and analysis of organic trace compounds BiOS Determination of the total estrogenic activity in various matrices (subcontracted analysis) The E-screen assay is an in vitro test system for determination of receptor-mediated estrogenic effects. The endpoint of the assay is the estrogen-dependent proliferation of estrogen receptor-positive human breast cancer cells (MCF-7) compared to controls with and without 17β-estradiol (E2). Via the dose-response curve the EEQ (estradiol equivalent concentration) is obtained as a sum parameter of total estrogenic activity in a sample expressed in equivalents of the reference substance 17β-estradiol (E2). No information about the nature of the compounds being responsible for the total estrogenic activity in environmental samples are given by the E-screen assay. The most potent compounds are the natural hormone 17β-estradiol, its degradation product estrone and the synthetic hormone ethinylestradiol used as a contraceptive. Due to its high sensitivity (LOQ < 0.1 ng/L) the E-screen assay is a suitable substitute for the expensive and time-intensive targeted instrumental single substance analysis. As a routine procedure the robust E-screen assay was and is used in the framework of subcontracted analysis to determine the total estrogenic activity in various samples. 2010/11 inter alia surface water, wastewater treatment plant influents and -effluents, nutritional supplements, as well as mineral water were investigated. Contact: Dipl. Chem. Claudia Lange, Dr. Bertram Kuch Fig.1: Stained cells in 96-well plate Fig.2: Via Tablecurve 2D generated dose-response curve of the reference subtsance 17β-estradiol. 167 Chair of Hydrochemistry and Hydrobiology WESS: Water and Earth System Science Competence Cluster – sub-project: “Chemical inventory and input-output mass balances in WESS test catchments” campaign with a focus on springs and ground water in the catchments of the rivers Ammer and Goldersbach is conducted (ongoing). Financing institution: WESS - the Water and Earth System Science Competence Cluster - was founded by the Universities of Tübingen, Stuttgart and Hohenheim and the Helmholtz Centre for Environmental Research (UFZ) in 2009. The aim is to strengthen research cooperation between these institutions and to facilitate interdisciplinary research in the field of waters in the catchment as a function of climate and land use changes. Funded by the State of Baden-Württemberg and the federal government Numerous chemical compounds pass through human activities (industry, agriculture, treated or untreated wastewater) into the environment and nowadays are ubiquitous prevalent in water, soil and air. The transport of these compounds is coupled mainly to the water cycle. The crucial question in terms of water quality is which compounds have a potential for accumulation in the water cycle and the extent to which they accumulate. This requires knowledge about the distribution of pollutants in the environment and in-depth understanding of the processes that regulate the long-term fate and transport of these substances in soil, groundwater and surface waters. Universität Tübingen Universität Hohenheim Helmholtz-Zentrum für Umweltforschung (UFZ) Contact: Dr. Hermann Rügner, Universität Tübingen, Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dipl. Chem. Claudia Lange, Dr. Bertram Kuch Project partner: Duration: 2009 - 2013 As part of the subproject comprehensive monthly sampling of surface waters (Ammer, Goldersbach, Steinlach, Körsch and parts of the Neckar near Tübingen) are performed. The catchments differ only slightly in geology, but clearly in land use (agriculture, forested, urban) under similar climatic conditions. At approx. 30 locations more than 100 parameters were analyzed with a focus on organic trace substances (2009-2011). In addition, a monthly sampling Fig. on the top: Brown trout from the river Ammer Fig. to the left: Sampling: Hermann-LönsWell 168 Hydrobiology and analysis of organic trace compounds BiOS Development of an Environmental Friendly Technology for the Removal of Nitrogen and MicroParticles in Recirculated Aquaculture systems Due to overfishing and water pollution the natural fish stocks have decreased dramatically in the last 20 years. As a consequence, the amount of fish, molluscs and crustaceans produced in aquaculture increases continuously. Today already 50 % of the global demand for fish is covered by aquaculture. Compared to conventional flow-through-systems (e.g. trout rearing), aquaculture re-circulation systems have a very low water demand. However, in order to optimize the utilization of fresh water, an extensive water treatment is required. The use of aqua-culture recirculation systems is advantageous especially if quality and quantity of fresh water is not sufficient and if costs for supply of fresh water and discharge of wastewater are high. Especially in the neighborhood of protected nature conservation areas or river basins, the quality requirements of the effluent from fish production systems will increase. The optimization of the water treatment in aquaculture systems is of essential im-portance for fish health and welfare. Suboptimal water conditions can affect the growth and quality of fish. In addition, stress reactions and outbreaks of infectious diseases are favored. This leads to a deterioration of productivity, food quality and environmental acceptance of fish farms and increasingly hinders the further devel-opment of aquaculture. In order to improve the water quality and to reduce the use of fresh water, nitrate must be removed from the water besides ammonia and carbon dioxide. With a bio-logical denitrification system, nitrate is reduced to gaseous nitrogen (N2) and thus removed from the system. In the same process, the acid formed during nitrification is neutralized. A further stress factor for fish in recirculating systems is the accumulation of sus-pended micro-particles (size < 20 µm), which can not be removed by sedimentation or microstrainers. For this reason, the use of membrane technology is particularly advantageous. Therefore a space- and cost-saving combination of denitrification and membrane cleaning shall be developed. A high performance biological denitrification process for the biological removal of nitrate is combined with a membrane unit for elimination of solids, such as bacteria, parasites and other micro-particles. In addition increase of biomass concentration with a factor up to five in the denitrification reactor can be achieved. Special materials are used as carrier for the growth of bacteria and exposed to nitrate-containing water in a fluidized bed reactor. With the movement of these carriers a friction-abrasion effect is produced, by which the cleaning of the membrane surface is achieved. First, the mechanical interaction of various carrier materials with membrane surfac-es is investigated to prevent damage to the membrane surface. Then the combination of denitrification and membrane cleaning will be examined in the laboratory. The effects of different substrates in aquariums with fishes are investigated to avoid negative influences of the process. The welfare of the fishes is an important compo-nent of the project conception, because poor water quality can affect the growth of the fishes and enhance the risk of infectious diseases. This leads to a reduction in productivity, food quality and consumer acceptance. Therefore stress parameters are determined in addition to an observation of the fishes and the measurement of their growth. Financing institution: Deutsche Bundesstiftung Umwelt (German Foundation Envi-ronment) Contact: Dr. Angela Boley Project partner: MaxFlow Membran Filtration GmbH Fischtechnik International Engineering GmbH Zentrum für Infektionsmedizin, Abteilung Fischkrankheiten und Fischhaltung der Stiftung Tierärztliche Hochschule Hannover Duration: 09/2010 - 04/2012 Investigation of the mechanical interaction of various carriers with membrane surfaces. 169 Chair of Hydrochemistry and Hydrobiology Participation in the DIN-working committee: NA 119 Normenausschuss Wasserwesen (NAW) NA 119-01-03-05-09 AK working committee Hormonal effects (Xenoestrogens) (ISO/TC 147/SC 5/WG 9) The German Institute for Standardization is a registered association and as such provides a platform for the so-called „stakeholders“ (companies,associations, industry, science, etc.) to develop standards. These serve inter alia quality assurance, assurance of serviceability, the consumer and environmental protection. Because of international standards trade barriers are dismantled and thus supports the competitiveness of individual countries. The DIN working committee Hormonal effects (Xenoestrogens) - established in November 2010 - deals with the standardization of a test method for detecting the estrogenic activity in environmental samples. Hormone-like acting substances can interfere with the hormonal balance of organisms and inter alia adversely affect reproduction. Via environmental quality standards (EQS) for priority substances already taken action from a regulatory perspective indeed, however these are insufficient to determine the additive mixture-toxicity of receptor-coupled effects of hormone-like substances. Bioassays are indispensable for complementation of risk assessment and monitoring of chemical emissions. Currently there is no standardized procedure for the determination of hormonal activity in aquatic environment. The aim of the working committee, in which employees of numerous scientific institutions and companies participate, consequently is the standardization of a bioassay procedure as an international standard. Contact: Dipl. Chem. Claudia Lange, Dr. Bertram Kuch SchussenAktiv: Reduction of micropollutants by activated carbon in wastewater treatment plants and their effect on fish and their prey organisms: model study on the treatment plant Langwiese and at the Schussen in the Lake Constance catchment More than 90 % of all contaminants and nutrients are removed from wastewater by well-developed wastewater treatment plants (WWTP). What remains are trace substances such as pesticides, drug residues, flame retardants, industrial chemicals and other compounds which are released into surface waters as micropollutants. For many of these trace compounds 170 can be assumed that they - even in low concentrations - have an adverse effect on the environment. A literature study conducted by Triebskorn showed that the Schussen is burdened by numerous micropollutants - in concentrations, which in some cases are considerably above the effect threshold of aquatic organisms. Since these micropollutants ultimately enter the Lake Constance via Schussen, the expansion of the WWTP Langwiese (association for sewage treatment Mariatal) in Ravensburg is appreciated. To examine whether the decrease of trace compounds by activated carbon filtering is reflected in improving the health status of fish and prey organisms in the Schussen, an effect related „before-after study” should be conducted. Furthermore should be demonstrated how existing endocrine potentials can be reduced and to what extent this reduction affects aquatic organisms. By combining biological effect studies and chemical analysis in a temporal (before and after WWTPextension) and spatial gradient (up- and downstream of wastewater effluent) is guaranteed to bring the causes and effects in exposed organisms in correlation and to document the success of the treatment plant expansion. As part of the SchussenAktiv-project samples are tested for both micropollutants (GC/ MS analysis) as well as for estrogenic activity (via E-screen assay) at the ISWA. Financing institution: Ministerium für Umwelt, Naturschutz und Verkehr, Baden Württemberg Contact: Prof. Dr. Rita Triebskorn (Universität Tübingen), Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dr. Bertram Kuch, Dipl. Chem. Claudia Lange Project partner: University of Tübingen Institut für Seenforschung Langenargen (ISF) DVGW-Technologiezentrum Wasser, Karlsruhe (DVGW-TZW) University of Frankfurt Masaryk University, RECETOX, Brno Biologiebüro Weyhmüller (BBW) Gewässerökologisches Labor Starzach HYDRA-Institut Konstanz Regierungspräsidium Tübingen Duration: 2010 - continuously Hydrobiology and analysis of organic trace compounds BiOS Contact Dr. rer. nat. Bertram Kuch Tel: +49 (0)711/685-65443 Fax: +49 (0)711/685-67809 E-Mail: [email protected] Scientists Dr. rer. nat. Angela Boley Tel.: +49 (0)711 685 65441 Fax: +49 (0)711 685 63729 E-Mail:[email protected] Dipl.-Ing. Asya Drenkova-Tuhtan, M.Sc. Tel.: +49 (0)711 685 63720 Fax: +49 (0)711 685 63729 E-Mail: [email protected] Dipl.-Chem. Claudia Lange Tel.: +49 (0)711 685 65741 Fax: +49 (0)711 685 63729 E-Mail:[email protected] Laboratory staff Suse Gaiser (BTA) Tel: +49 (0)711/685-65496 Regina Görig (LTA) Tel: +49 (0)711/685-65452 Andrea Kern (LTA) Tel: +49 (0)711/685-65741 Matthias Mischo (CTA) Tel: +49 (0)711/685-65452 Giuseppina Müller (CTA) Tel: +49 (0)711/685-65454 Since 2010 retired: Dr.-Ing. Wolf-Rüdiger Müller, Akad. Oberrat 171 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Sewage Treatment Plant for Research and Education The facilities of the LFKW play an important part in the traditionally practice-oriented education at our institute. Within the scope of practical training measures, the assistance in research projects and working on Master’s theses, the students are provided with plenty of opportunities to become familiar with the details of the equipment and the operation of a highly mechanized sewage treatment plant. The LFKW is operating under real conditions: its primary task is the purification of the wastewater from the university campus in Stuttgart-Vaihingen and from the nearby Büsnau district of which the total daily volume is about 2.000 cubic metres. In order to comply with the strong official discharge regulations and to provide opportunities for research at the same time, the LFKW has a multitrack purification system: all process steps required for advanced wastewater treatment consist of at least two parallel units. In this way separate plant components can be used at any time for fullscale research, independent of the other units and without any adverse effects on the quality of the final effluent. Additional experimental areas inside and outside of a large two-storey hall offer a wide variety of options for research work and individually contracted investigations on a semi-technical scale. The LFKW also offers its services to technical companies, operators of municipal environmental facilities and engineer’s offices: from the testing of measuring devices, chemical aids etc. under practical conditions through the manufacturing of laboratory test equipment to the leasing of complete pilot plants for the treatment of wastewater, sludge and exhaust air. 172 Sewage Treatment Plant for Research and Education LFKW 173 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Annual Report 2010 - Overallview 174 Sewage Treatment Plant for Research and Education LFKW 175 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Annual Report 2010 - Monthly Data 176 Sewage Treatment Plant for Research and Education LFKW 177 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 178 Sewage Treatment Plant for Research and Education LFKW Annual Report 2010 - Performance Diagram Performance Diagram: Ablauf Performance Diagram: Zulauf 179 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Annual Report 2011 - Overallview 180 Sewage Treatment Plant for Research and Education LFKW 181 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Annual Report 2011 - Monthly Data 182 Sewage Treatment Plant for Research and Education LFKW 183 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 184 Sewage Treatment Plant for Research and Education LFKW Annual Report 2011 - Performance Diagram Performance Diagram: Ablauf Performance Diagram: Zulauf 185 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Contact Dr.-Ing. Peter Maurer Tel: +49 (0)711/685-63724 Fax: +49 (0)711/685-67637 E-Mail: [email protected] 186 Imprint Publisher: Institute for Sanitary Engineering, Water Quality and Solid Waste Management Bandtäle 2 70569 Stuttgart Germany www.iswa.uni-stuttgart.de/index.en.html Cover: Solutioncube GmbH Conception: Dipl.-Geol. Detlef Clauß M.A. Constanze Sanwald Dörte Hahn © 2012 187 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 188 Universität Stuttgart Universität Stuttgart Universität Stuttgart Institute Report 2010-2011 Chair of Sanitary Engineering and Waterrecycling o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: +49 (0) 711/685-63723 Resouces Management und Industrial Waste | RIK Institute for Sanitary Engineering, Water Quality and Solid Waste Management Dipl.-Ing. Gerold Hafner Tel.: +49 (0) 711/685-65438 Emissions | EMS Dipl.-Ing. Carsten Meyer Tel.: +49 (0) 711/685-63754 Industrial Water and Wastewater Technology | IWT Prof. Dr.-Ing. Uwe Menzel Tel.: +49 (0) 711/685-65417 Urban Drainage | SE Dr.-Ing. Ulrich Dittmer Tel.: ++49 (0) 711/685-69350 Water Quality Management and Water Supply | WGW Dipl.-Ing. Ralf Minke Tel.: +49 (0) 711/685-65423 Chair of Waste Management and Emissions o. Prof. Dr.-Ing. Martin Kranert Tel.: +49 (0) 711/685-65500 Biological Air Purification | ALR Prof. Dr. rer. nat. Karl-Heinrich Engesser Tel.: +49 (0) 711/685-63734 Solid Waste Management | SIA Dr.-Ing. Martin Reiser Tel.: +49 (0) 711/685-65416 | ALR Chair of Hydrochemistry and Hydrobiology | AWT o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Tel.: +49 (0) 711/685-63721 | BiOS Hydrochemistry and Analytical Quality Assurance | CH Dr.-Ing. Michael Koch Tel.: +49 (0) 711/685-65444 | CH Hydrobiology and Analysis of Organic Trace Compounds | BiOS Dr. rer. nat. Bertram Kuch Tel.: +49 (0) 711/685-65443 Sewage Treatment Plant for Research and Education | LFKW Dipl.-Ing. Peter Maurer Tel.: +49 (0) 711/685-65420 Administrative Office Dipl.-Ing. Stephan Mollweide Tel.: +49 (0) 711/685-63713 Dr.-Ing. Klaus Fischer Tel.: +49 (0) 711/685-65427 Bandtäle 2 70569 Stuttgart Germany Tel.: +49 (0) 711/685-63721 Fax: +49 (0) 711/685-63729 www.iswa.uni-stuttgart.de | EMS Institute Report 2010-2011 Wastewater Technology | AWT | IWT | LFKW | RIK | SE | SIA | WGW