the Abstract Book - 2nd ICOCEE
Transcription
the Abstract Book - 2nd ICOCEE
INTERNATIONAL CONFERENCE ON CIVIL AND ENVIRONMENTAL ENGINEERING Dedeman Cappadocia Hotel & Convention Center, Nevşehir, Turkey Conference Book 20 – 23 May 2015 Welcome to Cappadocia, Nevşehir The idea of providing a scientific basis for discussing and solving, emerging problems in the fields of only environmental engineering such as water sources, pollution treatment technologies, aquatic life and etc. This idea initiated the first “International Conference on Environmental Science & Technologies (Cappadocia, Turkey in 2013)” that we also hosted and involved in the organization. However, environmental engineering is a whole with civil engineering in many countries in the World. Thus, basis idea of the second conference, which is named as International Conference on Civil and Environmental Engineering (ICOCEE), has been formed. “International Conference on Civil and Environmental Engineering” will provide a comprehensive overview of effective strategies on the fields of civil and environmental engineering. Also, the ICOCEE conference will provide the opportunity to discuss and evaluate the solutions to the regional and global problems. All parties of civil and environmental engineering areas such as universities, industrial organizations, public institutions and organizations, local governments and legislators are welcome to attend to the conference in order to the share their experiences and to bring a common body of knowledge for the solutions of problems in the fields of civil and environmental engineering. The topics of the conference will include almost all areas of civil and environmental engineering. Cappadocia (named as “land of the beautiful horses”) is selected as the conference venue since it is one of the most fascinating and historical place in Turkey. It is also famed for its wine, valleys, underground cities, carved-from-rock churches & hotels, hot-air balloons, trekking and horseback riding tours. Owing to these prominent features of the place, participants will enjoy their stay besides benefiting from the conference. The four- day ICOCEE – Cappadocia’2015 conference that is going to be launched on May 20, 2015 in Cappadocia, Nevsehir, Turkey, provides a fruitful, international and unique forum for exchange of views among participants currently working in the areas of civil and environmental engineering. We hope you enjoy ICOCEE – Cappadocia’2015 conference and your stay in Cappadocia, Turkey. Conference Chairmen Assoc. Prof. Dr. Serkan ŞAHİNKAYA Assist. Prof. Dr. Erkan KALIPCI CONTENTS 1 Comparison Of Exhaust Emissions Of A DI Diesel Engine Fueled With Methyl Ester, Ethyl Ester, Petro-Diesel And Their Blends H. Sanli, M. Canakci, E. Alptekin, A. Turkcan, A. N. Ozsezen 2 Pcbs In Ambient Air In Istanbul And Izmir-Turkey Kurt-Karakus PB, Gungormus E, Okten E, Celik H, Ugranlı T, Sofuoglu A, Gedik K, Sofuoglu S, Alegria H, Jones KC 3 Prediction Of Surface Ozone Concentration By A Semi-Empirical Photochemical Model Kh. Ashrafi, M. Zamani, Gh.R. Nabi-Bid Hendi 4 Air Quality Modelling In Barcelona From The Analysis Of Climate, Territorial And Traffic Variables D. Jato-Espino, E. Castillo-Lopez, S. M. Charlesworth, J. Rodriguez-Hernandez 5 Pbdes In Ambient Air In Istanbul And Izmir-Turkey P.B. Kurt Karakus, E. Gungormus, H. Celik, E. Okten, T. Ugranlı, A. Sofuoglu, K. Gedik, S. Sofuoglu, H. Alegria, K.C. Jones 6 The Research Of CO And Nox Emissions Revealed From Linear Sources İn Kocaeli City Korfez District By ISCST-3 And AERMOD Model Programs K.O. Demirarslan, Ş. Çetin Doğruparmak 7 Levels Of Bioaerosols In Indoor Environments In Ankara E. Aghlara, G. Güllü 8 Bioaerosol Removalby Simultaneous Adsorption And Photo-Oxidation Of Ag-Doped Tio2/PU Under Visible Irradiation Thanh-Dong Pham, Byeong-Kyu Lee 9 An Overview Of Chiral Pollutants As A Tracer Of Cycling Of Pops E. Can Güven, D. Bolat, K. Gedik, P.B. Kurt Karakuş 10 A Preliminary Investigation Of Legacy Organochlorine Pesticides In The Atmosphere Of An Agricultural Area In Antalya E. Can Güven, D. Bolat, K. Gedik, P.B. Kurt Karakuş 11 Analysis And Assessment Of Heavy Metal Pollution Of Road Dust In Düzce, Turkey F. Taşpınar, M. Atasoy, Z. Bozkurt, B. Poyraz, O. Uzun 12 Compration Of Indoor And Outdoor Vocs Levels At Children Homes S. Lakestanı, B. Karakaş, S. Acar Vaizoğlu, B. Güçiz Doğan, Ç. Güler, B. Şekerel, A. Taner, G. Güllü 13 Economic And Environmental Contributions Of Declaration Of The Marmara Region As Emission Control Area (ECA). D. Yıldırım Pekşen, G. Bilen Alkan 14 Airborne Particle Concentrations Prediction Using Artificial Neural Network Ya-Chin Teng, Ho-Wen Chen, Wei-Yea Chen, Wei-Lun Lin 15 Illustration Of Air Quality Change Using Innovative Trend Analysis Method Y.S. Güçlü, E. Şişman, İ. Dabanlı, Z. Şen 16 Clear-Cut, Easy And Safe Air Purifying Technique H. Habibazarfard, A. Cemal Saydam 17 Atmospheric Pollution Monitoring Using Neural Networks M. Rouaïnia, N. Djebri 18 Heavy Metal Concentration Of House Dust P. Babaei, İ. Durukan, G. Güllü 19 Analysis Of Vocs In The Indoor Air L. Meciarova, S. Vilcekova 20 Dispersion Of The Nox Emissions From Chimneys And Road Traffic Around Industrial Sites: Case Study Of The Company Fantazia. H. Gourgue, A. Aharoune, A. Ihlal Ahmed 21 Indoorairqualityand Construction Specifications B. Öztür, H. Aykaç, H. Çelebi 22 Analysis Of SO2 And PM Concentrations With Artificial Neural Network: A Case Study Of Erzurum City Center F. Ekmekyapar Torun, Z. Bingül, M.Y. Çodur 23 Investigation Of Air Pollution Parameter Variation On Between 2007-2014: The Case Of Igdir (Turkey) S. Dogru, T. Bayram, Y.A. Argun, A. Altikat 24 Level And Sources Of Particulate Matter (Pm10, Pm2.5) In Turkey G. Güllü, Z. Gemici, B. Keskin Çatal 25 Dynamic Stiffness Of Resilient Materials For Reduction Of Floor Impact Sound Jung-Min Kim, Jung-Yoon Lee, Hye Sun Lim, Byungkoo Jun, Seong Jun Hong 26 Thinking Of Noise Control In A Positive Way: Soundscape Concept N. Akbulut-Çoban, K. Gedik 27 Evaluation Of Quiet Area Characteristics Of An Educational Area: A Case Study Of Akdeniz University Campus, Antalya A. G. Göküş, H. Güleç, Z. Aslan, N. Akbulut-Çoban, K. Gedik 28 Determination Of Noise Pollution In Main Arterial Roads Of Nevsehir City Center E. Kalıpcı, İ. Bilgen 29 Hydrogen Peroxide Aided Sulphuric Acid Pre-Treatment Of Electronic Waste For İmproving Gold Recovery By Metabolically-Engineered Strain Of Chromobacterium Violaceum S. Das, Y.P. Ting 30 Düzce Potential Investigation Of Domestic And Industrial Solid Waste Recoverable G.F. Gökçe, N. Mazlum, P. Hasanoğlu 31 Ground Improvement Via Chrome And Steel Slags M. Vekli, C.C. Çadır, F. Şahinkaya 32 A Newbitumen Geosynthetic Barrier Mainly Based On Boron Production Waste Clay For Landfill Liner Systems D. Ulutaş, Z. Çokaygil, A. Özkan, Y. Güney, M. Banar 33 Solid Waste Management In Erzurum Z. Bingül, F. Ekmekyapar Torun 34 Effect Of Soil Minerology On Electrokinetic Remediation G. Demirel Bayık, A. Altın, Ö.F. Çapar 35 Environmental Quality Of Compost: Can Composting Earthworms (Eisenia Fetida) Help Manage Compost Nutrient Ratios? K. Bellitürk, J.H. Görres, H.S. Turan, S. Göçmez, M.C. Bağdatlı, M. Eker, S. Aslan 36 Evaluation Of The Mechanical And Hydrological Characteristics Of A Bioreactor Landfill Using Laboratory Simulators. P. Lakshmikanthan, L.G. Santhosh, G.L. Sivakumar Babu 37 Environmental Research Of Old Waste Landfill “Vardariste”, Skopje, Macedonia B. Kovachevikj, E. Raleva, M.Markov, Z. Ilijoski 38 Bioconversion Of Food Wastes For The Production Of Value Added Products Bioconversion Of Food Industry Wastes B. Zorlugenç, F. Kiroğlu Zorlugenç 39 Utilization Of Food Industry Wastes F. Kiroğlu Zorlugenç, B. Zorlugenç 40 Effects Of Different Barn Planning System On Waste Characteristics – Case Study Of Turkey H. E. Polat 41 Constraints Of Local Waste Management System In Lagos, Nigeria A.O Abisuga, A.A Akinpelu, D.O Olanrewaju 42 California Bearing Ratio Of A Clay With Waste Carpet Jute M. Öztürk, A. F. Çabalar 43 Porosity Analysis Of Ceramic Wall Tile Derived From Blast Furnace Slag E.Eren Gultekin, Z. Bayer Ozturk 44 Selective Sodium Hydroxide Leaching Of Zinc From Waste Zinc-Carbon And Alkaline Battery Mixture B. Andak, A. N. Bulutcu 45 Evaluation Of Performance Of MSW Landfill Barrier Systems At Laboratory Scale And Using HELP Model Simulations L.G. Santhosh, P. Lakshmikanthan, G.L. Sivakumar Babu 46 Solid Waste Management And Recycling In Igdir Y.A. Argun, A. Altikat, S. Dogru, T. Bayram 47 Management Of Solid Waste In The Sample Of A Small Sized Turkish Town, Erzurum T. Bayram , Y.A. Argun, A. Altikat, S. Dogru 48 Industrial Waste – Red Mud As Catalyst For Hydro-Dealkylation Á. Rédey, T. Juzsakova, T. Fráter, A. Csavdari, L. Ráduly, I. Ráduly 49 GIS Application On Disposal Of Dredge Materials S. Dağlı, A.Dönertaş, H. M. Basar, İ.Yolcubal, E.Sangu, L. Tolun 50 Preventative Medicine For The Environment: Developing And Implementing Environmental Programs That Work F. Oztaş 51 A Proposed Designed Of Compost Pile Facility In Batangas State University Main Campus I J.A. Almarez, S.J. R. Driz, R. Joy I. Jumangito 52 Recycling Ways Of Waste Bread Crumbs S.M. Seçen, K.E Gerçekaslan 53 Characterization Of Wastewaters From Eskişehir State Hospital P. Gültekin 54 Key Environmental Challenge Of Seawater Desalination F. Saffarimiandoab, I. Koyuncu, H. Kilzer 55 Identification Of A Potential Isolate For Degradation Of Sodium Dodecyl Sulfate In Wastewater Systems H. Ulusoy, F. Yilmaz, A. Ergene, B. Icgen 56 Isolation Of Bacteria Efficient In The Removal Of Anionic Detergents S. B. Salik, F. Yilmaz, A. Ergene, B. Icgen 57 Potential Of Pseudomonas Species For The Treatment Of Heavily Detergent-Polluted Waters L. Goksu, F. Yilmaz, A. Ergene, B. Icgen 58 Halonitromethanes Formation In Drinking Water: Occurrence And Precursors S. Genisoglu, Z. Ozturk, B.İ. Harman, S.S Kaplan Bekaroglu 59 Chlorine Dosing Management Strategies For Water Utilities Using GIS, SCADA And Modelling Tools: Case Study Of Yeşilbayir-Antalya T. Akdeniz, H. Muhammetoğlu 60 Influence Of Characteristic Of Butterfly Valve Closing On Water Hammer Run. A. Kodura 61 Utilization Chitosan As A Color Absorbent On Textile Industry Liquid Waste H.H. Mumtaza 62 Biosorption Of Commercial Yellow 2G And Indigo Textile Dyes By Powder Hawaiian Spirulina Pacifica G. Dogdu, A. Yalcuk 63 Efficiency Of UV And UV H2O2 Processes For Amoxicillin Treatment Ş. Doğan, R. Kidak 64 Ceramic Membrane Applications In Industrial Wastewater Treatment M. Genisoglu, H. Koseoglu, B.I. Harman 65 Evaluation Of The Dispersive Component Of The Surface Energy Of Al-Pillared Sepiolite And Al-Pillared Montmorillonite As Determined By Inverse Gas Chromatography C. Bilgiç, N. Karakehya 66 Occurrence Of Illicit Drugs And Pharmaceuticals In Municipal Wastewater And Possibilities For Their Removal I. Bodík, T. Mackuľak, M. Fáberová, M. Mosný 67 Isolation Of Efficient Diesel Oil Degraders Harbouring Alkb And C23O Genes G. Onur, F.Yilmaz, B. Icgen 68 A Clean Technology For Tanneries Unhairing Waste Waters: Neutralization By CO2 , Water Recycling And Free Amino Acids Recovery S. Tamersit, Kamel-Eddine Bouhidel 69 Effect Of Some Pharmaceuticals On The Production Of Biogas At Anaerobic Digestion Process M. Fáberová, L. Ivanová, I. Bodík, T. Mackuľak 70 Study On The Sorption-Desorption-Recovery Performance Of Ion Exchange Resin For Removing Phosphate From Aqueous Solutions T. E. Köse, B. Kıvanç 71 Flow Reactor Model For UV Treatment Of Amoxicillin R. Kidak, Ş. Doğan 72 Treatment Of Olive Mill Wastewater By Photooxidation To Nano-Zno-Bentonite Composite And Recovery Of OMW M. Balaban, D.T. Sponza 73 Removal Of Olive Mill Wastewater Pollutants By UV And Sunlight Irradition With NanoSio2/Fe3O4 Composite And Reuse Properties Ç. Ulusoy, Delia Sponza 74 A New Approach For Sludge Disintegration & Stabilization: Solid Tio2 Thin Films T. Tunçal, D. İ. Cifci, O. Uslu 75 Wastewater Treatment In Poland Taking Into Special Consideration Anaerobic Reactors K. Umiejewska 76 The Cycle Of Pharmaceuticals, Drugs And Their Metabolites In Four Dominant Treatment Plant In Slovakia And The Czech Republic T. Mackuľak, L.Birošova, I. Bodík, M. Fáberová 77 Biodegradation Of The Non-Steroidal Anti-Inflammatory Pharmaceutical Flurbiprofen K. Yanaç, R.W. Murdoch 78 Effect Of Impregnation Ratio On Properties Of Activated Carbon Prepared From Biochar By Chemical Activation D. Angın, S. Güneş, S. Şensöz 79 Adsorption Of Orange 13 From Aqueous Solutions Using Activated Carbon Prepared From Orange (Citrus Sinensis L.) Pulp D. Angın, G. Demir, S. Güneş, A. Ilci 80 Biogas Production By Anaerobic Digester Exposed To Ammoniachangedwith Changing Bacterial Population Dynamics M. S.Ak, F. Yilmaz, B. Icgen 81 Adsorption Of Methylene Blue Dye On Multi-Walled Carbon Nanotubes (Mwcnts) - A Response Surface Methodology (RSM) Approach V. Selen, Ş. Taşar, M. Çakmak, D. Özer, A. Özer 82 Removal Of Astrazon Golden Yellow 7GL From Colored Wastewater Using Activated Clay M. Çakmak, Ş. Taşar, V. Selen, A. Özer, Dursun Özer 83 Assessment Of Anaerobic Microbial Community Structure In The Presence Of Nonylphenoldiethoxylateusing Fluorescence In Situ Hybridization F. Kara Murdoch, F.Dilek Sanin 84 Comparison Of Methylene Blue Removal Efficiency From Aqueous Solutions By Walnut Shell And Activated Walnut Shell S.N. Giray, D. Aktaş, M. Kozak, T. Kaymaz, M. Dolaz 85 The Separation Of Emulsified Oils From Wastewater By The Application Of Electric Field C. Eryılmaz, A. Genç 86 An Economic Analysis Of Sewage Sludge Management Methods In Kocaeli Ö. Kaplan, M. Gündüz, G. Turan, K.S. Yiğit 87 The Effect Of Different Ph At Constant Temperature On Biohydrogen Production From Sewage Sludge I. Senturk, H. Buyukgungor 88 Biodegradation Of Various Azo Dyes In Anaerobic Batch Reactors Ö. Aktaş, Y. Toker, E. Şahinkaya 89 Simultaneous Nitrate And Perchlorate Reduction In Elemental Sulfur Based Autotrophic And Heterotrophic Processes D. Ucar, E. Cokgor, E. Sahinkaya, A. Yurtsever 90 Aerobic Treatment Of Olive Mill Wastewater By Batch Reactor: A Kinetic Study S. Kul, A. Nuhoğlu, E. Aladağ 91 Synthesis Of Carboxymethyl Starch From Food Industry Waste S. Akarsu, C. A. Zıba, F. Dincer, M. Dolaz 92 Evaluation Of The Adsorption Capacity Of The Expanded Perlite To Remove Linear Alkyl Benzene Sulphonic Acid (LABSA) From Aqueous Solution D. Akin Sahbaz, S. Balbay, C. Acikgoz 93 Investigating Color Removal Of Textile Wastewater Using Constructed Wetlands E. Karaçetin, Sevim, O. 94 Adsorption And Kinetic Studies Of Molecular Size Fractions Of Humic Acid Onto Anion-Doped TiO2 Specimens P. Akan, M. Bekbolet 95 Comparision Of Biological And Advanced Treatment Processes For Ciprofloxacin Removal In Raw Hospital Wastewaters G. Guney, D.T. Sponza 96 Integrating Storage Sizing And Slow Sand Filtration For Residential Rainwater Harvesting Applications In The Philippines M.P. Lumbera, R. Ello P. Cabungcal 97 Removal Of Color From Textile Wastewater By Adsorption On Sunflower Seed Shell E.B. Duran, S. Akarsu, Y. Cuci, M. Dolaz 98 Do Personal Care Detergents Pose Risk In The Aquatic Environment: Characterization And Ecotoxicity Investigation O. Kizek, İ.D. Çiftçi, F. Ekmekyapar, A. Sicigliano, S. Meriç 99 Adsorption Of Dyestuff From Wastewater Using Calcined Waste Eggshell T. E. Köse 100 Comparative Photocatalyticdegradation, Detoxification And Demineralization Of A Biologically Treated Textile Effluent Using Tio2 And Znonanoparticles D.İ. Çifçi, S. Terzi, S. Meriç 101 Role Of Plant Biomass Structures On Performance Of Engineered Wetland For Treating Boron (B) Mine Effluents O. C. Türker, C. Türe, H. Böcük, A. Çiçek, A. Yakar 102 Removal Of Eriochrome Black-T From Aqueous Solutions Using Nzvi And S. Cerevisiae Modified With Nzvi U. A. Guler, O. Kundakci 103 Removal Of Tetracycline From Aqueous Solutions By Nanostructured Fe(III)-Cu(II) Binary Oxide U.A. Guler, H. Celik 104 Decolorication Of Reactive Black 5 By Potassium Ferrate (K2FeO4) S. Şahinkaya, E. Kalıpcı, H. Cüce 105 Recovery Of Acid And Heavy Metal In Surface Coating Industry By Best Available Techniques T. Kotan, G. Bakan 106 Removal Of Acid Violet 90, Basic Yellow 28 And Direct Blue 86 By Fe3O4 Embedded Polymer C.S. Keskin 107 Decolorization Of Disperse Blue 56 And Reactive Yellow 145 By Acrylamide Based Polymer C.S. Keskin 108 Biosorption Of Disperse Blue 56, Basic Yellow 28 And Acid Violet 90 By Aspergillus Tamarii S. Yılmazer Keskin, A. Güler 109 Removal Of Direct Blue 86 And Reactive Yellow 145 By Dead Biomass S. Yılmazer Keskin, A. Güler 110 Effect Of Anions On Arsenic Removal From Groundwater By Air Feed Electrocoagulation Reactor Using Iron Ball Anodes E. Şık, E. Gengeç, M. Kobya, E. Demirbas, M.S. Oncel 111 Preparation Of Polyacrylonitrile Ion Exchange Fibre (PAN-IEF) For The Removal Of Arsenic K. Qureshi, I. Bhatti, Z. Solangi 112 Applıcatıons Of Hybrıd System In Water And Wastewater- Review G.K. Akkaya, M.S. Bilgili 113 Removal Of Nickel (II) Pollution In Water By Diatomite M. Bilgin, Ş. Tulun 114 Adsorption Kinetic Studies For The Removal Of NH4-N From Landfill Leachate By Natural Adsorbent F.A. Temel, A. Kuleyin 115 Preparation Of The Poly(Glycidyl Methacrylate) Grafted Onto Crosslinked Poly(3-Chloro2-Hydroxypropyl-Co-EGDMA) With Sorbitol Group And Use For Removing Boron From Water G. Torunoglu Turan, B.F. Senkal 116 Removal Of Maxilon Red GRL From Aqueous Solutions Using Niğde (Bor) Grape Molasses Soil As A Low-Cost Adsorbent F. Çiner, S. Şahin, S. Battal, E. Sezer, A. Dumlu 117 Removal Of Total Nitrogen By Juncus Acutus And Cortaderia Selloana From Domestic Wastewater In Horizontal Subsurface Flow Constructed Wetland F.Aydın Temel, Y. Ardalı, E. Avcı 118 Removal Of Nitrate From Domestic Wastewaters Using Algae M. Izhar, S.L. Sanin, A. Akbulut 119 Heavy Metals Contamination And Chemical Speciation Of Water And Soils İn The Vicinity Of Sungun Porphyry Copper Deposit, NW Iran K. Esmaeili, N. Pirouznia, F. Moore 120 European Market For Decentralized Waste Water Systems E. Dorgeloh, D. Verschitz 121 Comparison Of Wastewater Treatment Potential Between Arthrospira Platensis And Chlorella Vulgaris R. Rezaei, A. Akbulut, S.L. Sanin 122 Bioelectricity Generation From Wastewater Sludge Using Microbial Fuel Cells S. Ömeroğlu, F.D. Sanin 123 Treatment Of Anaerobic Batch Reactor Of An Automotive Industry Wastewater: Influence Of Substrate-İnoculum Ratio And Wastewater Co-Substrate Ratio M. Sarioglu Cebeci, Ö.B. Gökçek 124 Laboratory Scale Submerged Membrane Bioreactors (SMBR) For The Treatment Of Rural Areas Wastewater O. Özkan, M. Oğuz, Ö. Özdemir, Ş. T. Azgın, A. Solmaz, İ. Uyanık 125 Effect Of Influent COD/TAN Ratio On Carbon And Nitrogen Removal Efficiency And Stability Of Aerobic Granules I. Kocaturk, T.H Erguder 126 Monitoring Of Molecular Weight Distribution By HPSEC With Ultraviolet Diode Array And Refractive Index Detectors In Biologically Treated Bakery Yeast Wastewater E. Gengeç, M. Kobya 127 Nickel Removal From Aqueous Solution By Iron Oxide Coated Sepiolite İ. Kıpçak, C. Gürakan Akın 128 Effects Of Operational Parameters On The Removal Of Acid Blue 161 Dye From Aqueous Solutions By Electrocoagulation With Aluminum And Stainless Steel Electrodes S. Ustun, N. Beyazit, H. Büyükgüngör 129 Evalution Of Non-Catalytic Wet Air Oxidation Variables For Removal Of Orgonophosphrous Pesticide Malathion Using Box-Behnken M. Isgoren, E. Gengec, S. Veli 130 Partial Nitrification Of Domestic Wastewater Under Oxygen Limited Conditions B. Alpaslan Kocamemi, E. Çiçek 131 Tetracycline Removal Via Waste Turkish Coffee M. Erşan, F. Düğenci, Ü.A. Güler 132 Adsorption Of Basic Yellow 2 From Aqueous Solutions Onto Montmorillonite O. Sözüdoğru, B.A.Fil, R. Boncukcuoğlu, E. Aladağ, S. Kul 133 Investigation Of Nitrate Treatment Potential Of Tea Waste A. Bilgin 134 Preparation Of The Poly (Styrene) Based Quaternary Chloroacetamide Modified Sorbent For Removal Of Phenol E.Yavuz, F.Bildik, B.F. Şenkal 135 Transport Of Heavy Metals Through The Supported Liquid Membrane B. T. Gemici, S. Altin 136 Adsorption Of Heavy Metals From Aqueous Solution By Non-Modified Clinoptilolite In Fixed-Bed System M. Balintova, M. Holub 137 Cluster Analysis Of Water Quality In Water Reservoir Ruzin I., Slovakia E. Singovszka, M. Balintova 138 Decolorization Of Brillant Blue R Contaminated Solutions By Chitosan-Eggshell Modified Products İ. Tosun Satır, B. Bulut Kocabaş 139 The Role Of Water In Recycling The Physicochemical Treatment Sludge As Concrete Admixture M. Sogancioglu, U. Sultan Keskin, E. Yel 140 Removal Of Oil-Grease From Dairy Industry Wastewater Using An Adsorbent Obtained From Waste Material N. C. İskender, M. Sogancioglu, E. Yel, N. Yilmaz 141 Reduction Of Nitrate By Combined Ultrasound And Zero-Valent Magnesium Under Ph Uncontrolled Conditions O. Ayyildiz, B. Ileri, O. Apaydin 142 Degradation Of Synthetic Textile Dyes Using Fungal Bioreactor And Photocatalytic Reactor E.Ü. Deveci, N. Dizge, H.C. Yatmaz, Y.Aytepe 143 Batch And Column Removal Of Textile Dye From Aqueous Solution Using Activated Carbon Prepared From Olive Stone Ö.Gerçel, H.F. Gerçel 144 Adsorption Of Remazol Blue RN From Aqueous Solutions Using Activated Carbon Prepared From Black Cumin Residue U. Selengil, H.Demiral 145 Removal Of Natural Organic Matter By Hydrogen Peroxide In The Presence Of IronCoated Pumice Particles A. Alver, M. Karaarslan, A. Kılıç 146 Removal Process Of Chloroform In Treatment Wetlands: From Mass Balance To Microbial Analysis Y. Chen, J. Vymazal 147 The Effect Of Mixing Time On Rate For Ammonium Removal From Waters By Emulsion Liquid Membrane Technique İ. Şimşek, L. Altaş 148 Effects Of Winemaking Practices On The Characteristics Of Wastewater Originated From Wineries K. Şen, F. Kiroğlu Zorlugenç 149 Monitoring Of Antibiotics In Urban Wastewater In Tekirdag City: A Comparison With Predicted Environmental Concentrations G. Varol Saraçoğlu, C. B. Özkal, S. Göçmez, F. Ekmekyapar, A. Koruyucu, S. Meriç 150 Energy And pH Dependency Optimization Of Degradation, Mineralization And Detoxification Of Ampicilline By Photocatalysis C. B. Ozkal, A. Koruyucu, S. Meric 151 Anion Selectivity Of Sepiolite And Its Surface Active Agents-Modified Forms S. Dikmen, H. Bircan, G. Yılmaz 152 Optimization Of Electrocoagulation Process To Treat Young Landfill Leachate Using Response Surface Methodology A. Aygun, B. Nas, A. Berktay 153 Adsorption Of Cationic Dye (Methylene Blue) From Aqueous Solution By Eggshells Z. Hattab, Y. Berredjem, R. Mazouz, N. Filali, K. Guerfi 154 An Exploitation Evaluation Of Pimuce Stone For Water And Wastewater Treatment Use D.İ. Çifçi, M. Yıldırım, B. Birden, S. Meriç 155 Organic Pollutants In The Groundwaters Used For Irrigation Purpose Within A Coal-Bearing Basin Of Northern Greece A. Iordanidis, J. Schwarzbauer, K. Gudulas 156 Methicillin-Resistant Surface Water Isolates Monitored By Meca-Specific DNA Probes E. Seyedmonir, F.Yilmaz, B. Icgen 157 Numerical Modelling And Monitoring Of Coastal Water Quality K. Cebe, L. Balas 158 Assessment Of The Cations And Anions Concentration Distribution İn Underground Potable Waters, Ph Solution Analysis Subject To The Temperature And Content Of Technogenic Sodium Chloride. Z. Maymekov, D. Sambaeva, J. Izakov, A. Isaev, J. Sydykov 159 Monitoring Of Seasonal And Spatial Variations In Marine Water Quality At The Mid-Black Sea Coast Of Turkey I. Senturk, S. Ustun, M. Oztel, H. Ozkaynak, E. Akcam, E. Gecer, F. Akbal, G. Bakan, H. Buyukgungor 160 Spatial Variation And Heavy Metal Concentration In Sediments Of Bued River: A Preliminary Assessment Of A River Nearby Small-Scale Mining Sites In The Philippines C.R. Orozco, R.Q. Macasieb, B.J.M. Tapales, A.C. Resurreccion 161 Evaluation Of Uncertainty For Trace Elements Measurement In Drinking Water With ICPMS O. Tunc Dede 162 Eastern Black Sea Region Of Domestic Water Capacity: The Case Of Artvin B. Yalçın Çelik, K.O. Demirarslan 163 Assessing The Mobility And Bioavailability Of Metals In An Aquatic Environment G. Jacks, X. Kumanova, G. Leka 164 Numerical Prediction Of The Efficacy Of Treated Wastewater Recharge To Impede Seawater Intrusion In The Coastal Aquifer Of Gaza- Palestine H. Sirhan, M. Koch, K. Qahman 165 The Knowledge Of The Residents From The Blackfoot Disease (BFD) Area Concerning The Health Risk Of Arsenic (As) Pollution Ming-Chao Lin, Jen-Chun Ou, Ting-You Liu, Bo-Sen Huang, Ying-Tai Hsu 166 Determination Of Diyarbakır Basalt Aquifer Water Quality Parameters And Obtain Thematic Maps With Using GIS Technique R. Çelik 167 Occurence And Precursors Of Haloacetonitriles In Drinking Water –A Review C. Ozgur, S.S. Kaplan Bekaroglu 168 Mogan Lake (Ankara) Water Quality Ö. Saylar, S. Benzer, S. Düzel, G. Gül, A. Gül, M. Yılmaz 169 Sediment And Water Pollution Status Of The Mid-Black Sea Coast Of Turkey E. Akçam, G. Bakan 170 A Research Of The Effects Of Sedıment Layer On Trophıc Level In Shallow Lakes; The Case Of Cernek Lake H. Cüce, G. Bakan 171 Investigation Of Relationship Between Water Pollutants: A Case Study From Istanbul A.O. Pektas, I.I. Ozyigit, I.E. Yalcin, N. Yilmaz, G. Demir 172 Microcosm Evaluation Of Greenhouse Gas Emission Potentials Of Aan Eutrophic Lake E. Ogun, A. Aksoy, S.L. Sanin 173 Evaluation Of Greenhouse Gas Emissions Of A Shallow Eutrophic Lake Using A Field Column E. Ogun, A. Aksoy, S.L. Sanin 174 Water Management Policies In The European Union: Finnish Integrated Water Management Example Ç.F. Karafakı 175 Application Of Low Intensity Ultrasound To Enhance Biological Phosphorus Removal B.Alpaslan Kocamemi, N. Gure, F. Sarialioglu, C. Kuzey, A.M. Saatçi 176 Effects Of Forest Fires On Water Sources A. Bilgin, M. Aybar, B. Sağlam 177 Characterıstıcs And Phosphorus Release Rates Of Sedıments In Two Shallow Lakes (Kızılırmak Delta, Turkey) H. Cüce, G. Bakan 178 Water Quality Of The River To The Kızılırmak River In The Province Of Nevsehir S. Aras, Ö. Fındık, E. Kalıpcı, S. Şahinkaya 179 Beneficial Use Alternatives For Dredged Materials: Landfill Daily Cover H.M. Başar, S. Dağlı, P. Özer, Erdoğan, B. Güzel, L. Tolun 180 Quantitative Determination Of Policyclic Aromatic Hydrocarbons İn Drinking And Potable Water Resources Of Diyarbakir Region H. Kara, Z. Tunay, M.A. Yilmaz, H. Temel 181 Disinfection By-Product Formation Of Natural Organic Matter A. Alver, E. Baştürk, A. Kılıç 182 Biofilms In Drinking Water Distribution Systems, Cappadocia 2015 I. Var, B Zorlugenç, Ö. Atasever Savaş, S. Sağlam 183 Assessment Of Natural Radioactivity By Gross Alpha And Beta Measurements In Drinking Water Samples In Ereğli, Turkey M. E. Korkmaz, O. Agar 184 Modeling The Relationships Between Water Temperatures And Meteorological Parameters At Kızılırmak River Using Artificial Neural Networks M. Temizyürek, F. Dadaser-Celik 185 A Study On Importance Of Pollution Monitoring And Control In Buyuk Menderes Basin C. Koc, Y. Bayazıt 186 Interaction Of Low-Impact Development Techniques And Urban River Flooding On The Zoning – Case Study Qomroud 1M.R.Kavianpour, A. Behzadipour 187 Integrated River Basin Management M.Y. Kılınç, E. Alkan 188 The Effect Of Heavy Metals In Soil And Plants Around A Lime Factory In The Bartin City In Western Black Sea Region H.B. Özel, H. Ucun Özel 189 An Investigation Of Lead Metal Pollution Along The Tem Motorway Agricultural Soils İn Tekirdağ S. Adiloğlu, M.T. Sağlam 190 Used The DPSIR Framework And Structural Equation Models To Applied To Environmental Risk Communication - As Emerging Contaminants In Wuxi River Yu-Ting Su, Wei-Yea Chen , Wei-Lun Lin, Yu-An Yu 191 Some Inorganic Species In Groundwater Of Health Concern – A Global Overview G. Jacks, P. Bhattacharya, M. Hossain 192 Lead Content In Local Paints In Pakistan A.K. Durrani, M. Rehan Khan, M. Ahmad 193 Environmental Modeling Approaches For Exposure And Risk Assessment Of Prioritize Chemicals In Industries G. Bakan, S. Laçin 194 Multicriteria Analysis For Flood Vulnerable Areas In Southeastern Slovakia M. Zeleňáková, P. Blišťan, P. Purcz 195 Implementation Of Watershed Sustainability Index On Turkey: Meriç-Ergene Specimen C. Gök, S. L. Sanin 196 Enviromental Impacts Of Medical Drugs And Cosmetics Waste Ç.F. Karafakı, L. Karafakı 197 Land Use Change In Izmit Bay Catchment G. Önkal Engin, M. Çelen 198 Unplanned Urbanization Be Evaluation in Terms Of Landscape Architecture (ICOCEE), Cappadocia 2015 G. Sandal Erzurumlu 199 Life Cycle Assessment Of Fossil Fuel-Fired Thermal Power Plant E.Ü. Deveci, Ç.Ş. Sağlam, Ü.K. Çakir, K. Bayraktar 200 From Environmental Audit Of Land To Baseline Report: Polish Implementation Of The EU Directive On Industrial Emissions In The Context Of Soil Protection A. Kulig 201 Development Of Novel Cements With Optimized Carbon Capture Capabilities C. Unluer 202 Different Climate Conditions Effect On Thermal Conductivity Coefficient And Indoor Environment D. Yilmaz, H. Bezci Zeren, C. Yilmaz, T. İnce 203 Some Physical And Chemical Properties Of The Building Structure Stones Used In Arapgir, Malatya S. Aksungur, T. Koca, A.T. Özgüler 204 Investigate Some Physical Properties Of The Structure Stones Located In Çemişgezek And Analysis Of The Use As Building Element A.T. Özgüler, T.Koca, S. Aksungur 205 Development Of Lightweight Cement Composites With Low Thermal Conductivity For Energy Efficient Buildings Min-Hong Zhang, Yunpeng Wu 206 A Study On Anisotropy Of Composites And Nanomaterials Used In Construction Industry Ç. Dinçkal 207 Experimental Study On Stabilization Of Sand Soil By Cement And Marble Dust A. Pekrioğlu Balkıs 208 The Moisture Damage Characteristic Of Polymer And Wax Modified Asphalt Mixtures M. Bayazit, Y.Taşdemir, E. Kolay, G.Küçük 209 Mgo-Cement Based Matrix Composites Reinforced With Hemp Hurds N. Stevulova, J. Cigasova, I. Schwarzova, J. Junak 210 Multi-Objective Decision Model Of Supplies Performed By Means Of Distribution Center For Small And Medium Construction Enterprises M.Tomczak, R. Bucoń 211 Thermal Energy Storage Using Phase Change Materials In A Building For Better Energy Efficiency In Summer Period F. Boudali Errebai, S. Chikh, L. Derradji, M. Amara 212 Use Of Phase Change Materials In The Walls To Improve Thermal Comfort L. Derradjı, A. Hamıd, M. Amara, F. Boudalı Errebaı, Y. Maoudj 213 Investigation Of Infill Wall Effect For The Seismic Performance Of RC Structures S. Mert, Ö. Boztaş, G. Arslan 214 Contribution To The Amelioration Of Mechanical Behavior Of Mortar Based On Limestone Mineral Admixture Substitution At Curing Temperature I. Aguida Bella, A. Asroun, N. Bella 215 Correlation Analysis As A Method For Concrete Deterioration Investigation V. Ondrejka Harbulakova, A. Estokova, P. Purcz, A. Luptakova 216 The Effect Of Zeolite Additive As A Durability Improver Of Building Materials A. Estokova, M. Kovalcikova, A. Sicakova 217 The Water Absorption By Capillarity In Structural Lightweight Concrete J. Alexandre Bogas, M. Glória Gomes, S. Real 218 Chloride Migration Resistance Of Structural Lightweight Concrete J. Alexandre Bogas, Sofia Real, M. Glória Gomes 219 Effect Of Sand Gradatıon On The Engıneerıng Propertıes Of Sand-Cement Mıxtures (A Comparative Study) S. H. Al-Hadama, A. Al Shenawy, T. Y. Elkady 220 Improvements In Folding And Tessellation As Plate Structures M.M. Balkıs 221 Investigation Of Relation Of Between Compressive Strength And Ultrasonic Pulse Velocity In The Foam Concrete With Different Density M. Davraz, Ş.Kılınçarslan 222 Investigation Of Salt Effect On Stability Of Warm Mix Asphalt H. Köse, M. Bayazit, Y. Taşdemir 223 The Effects Of Different Plasticizers On The Behavior Of Mortars E. Arıöz, Ö. Ariöz, Ö.M. Koçkar 224 An Investigation On Suitability Of Dredge Materials On Road Construction G. Cevikbilen, B. Teymur, U. Karadogan, H. M. Basar, S. Dağlı, L. Tolun 225 Turkey’s Public-Private Partnership Model In The Health, Energy, And Educational Sectors: An Overview And Critique Of The Issues With Recommendations For Improvement G. Tunc, E. Ozsarac 226 Investigating The Relationships Between The Main Contractors And Subcontractors In Turkey G.Polat, E. Eray, E.M. Goktepe 227 The Barriers To Adoption Of Electronic Document Management Systems On Turkish Construction Industry S. Aydınlı, M. E. Öcal, E. Laptali Oral 228 Predicting Construction Project Duration For Bid Packages: A Case Study Of Pakistan S.H. Khahro, T.H. Ali, M.A.A. Talpur 229 Supplier Selection In The Construction Industry: Evidence From Turkish Contractors G.Polat, E. Eray 230 Multi-Criteria Decision Model For Supporting Residential Building Maintenance R. Bucoń, M. Tomczak 231 Key Performance Indicators (KPI) Model For Measuring Performance Of Subcontractors B.N. Bingol, G. Polat 232 5S Systematic Practice Steps On A Corporate Business G. Gürsoy, A.E. Keleş 233 A Conceptual Perspective Via Meta-Heuristic Optimization Algorithms For Resource Leveling Problem In Project Networks Ş. Ebesek, H. Yaman 234 Application Of An Engineering Method For Preservation Of Cultural Heritage: Fuzzy Logic M. Ulukan 235 The Structural Analysis And Design Of Buildings With Shear Wall And Rigid Basements G. Tunc, Z. Khayyat 236 The Outsourced Design Coordination In Brazilian Civil Construction P.S. Okamoto, S.B. Melhado 237 Impact Of Physical Treatment Of Hemp Hurds On The Biocomposites Properties N. Stevulova, I. Schwarzova, E. Terpakova, J. Junak 238 Seismic Response Of Cylindrical Liquid Storage Tanks According To The Characteristics Of Structure D. Bae, C.K. Oh, J.H. Park 239 Construction Stage Analysis Of Prefabricated Structure F. Sunca, M. Akköse 240 A Study On Concrete-FRP-Steel Composite Honeycomb Structure For Bridge Deck M. Suh, D.H. Ha, J.F. Choo 241 Seismic Isolation Of Reinforced Concrete Structures «Nonlinear Dynamic Method» N. Adjou, N. Haddadou 242 An Analysis Of The Influence Of Wall Stiffeners On The Fundamental Periods Of Steel Liquid Storage Tanks M. Hadj Brahim, M. Djermane 243 Determination Of The Importance Of Materials In Structural Cost Via Architectural Project Examples Z. Ö. Parlak Biçer, E. İlhan, D. Kırmızıgül, A. Akmeşe, E. Davutoğlu, A. Keskin, A. Can Koç, R. Gurbangeldiyev 244 A Sample Study Area For The Costs Of Arrangements Intended For Disabled People Erciyes University Z. Ö. Parlak Biçer, İ. Kuşkaya, Ç. İşbilir 245 The Study Of Advantages And Disadvantages Of Tunnel Design Construction System Based On Mass Construction Approach A. Arefian, Z. Mohammadkhani, O. Moarrefianfard 246 Shape Optimization Of Sheeting Cross Section For Roof Subjected To Different Loading Combination A. Janushevskis, A. Melnikovs 247 Design Of Roofing By Using: Tensile Structures A.T. Al-Shareef, T. Ekmekyapar, D. Bakbak 248 Towards An Sustainable Architecture By Use Of Ancestral Knowledge O. Kadouri 249 Response Spectral Analysis Of Orthotropic Steel Deck As Per Turkish Local Design Spectrums A. Fettahoglu, S. Bekiroglu, İ. E. Bal 250 A Case Study Of Green Building Design E. Geçer, H. Büyükgüngör 251 Variation Of Poisson Ratio Depending On Different Tensile And Pressure Creep Moduli In IDT Test A. Fettahoglu 252 Producibility Of Cement-Based Lightweight Construction Material From Coal Bottom Ash Of The Bor Sugar Factory (Turkey) N. Doğan-Sağlamtimur, A. Bilgil, H. Akbulut, M. Dursun, S. Yıldırım 253 Stability Analysis For A Deep Landslide In Istanbul: A Case Study S. A. Berilgen, G. Allamyradov 254 Optimum Design Of Reinforced Concrete Retaining Walls Using Artificial Bee Colony Algorithm U. Dağdeviren, B. Kaymak 255 Real-Time Monitoring Of Pavement Structures For Geo-Environmental Purposes B. Hatipoglu, C.H. Benson, T.B. Edil 256 Comparative Life Cycle Assessment Of Ground Improvement Techniques M. Kucukvar, N. C. Onat, O.Tatari, A. Elgamal, K. Mackie 257 Influence Of Separation Gap On The Structural Response Of Colliding Structures Under Earthquake Excitation B. Sołtysik, R. Jankowski 258 Determining The Behavior Of Gravity Retaining Walls Under Dynamic Loads Constructed In Saturated Clay O. Yavan, M. İnanç Onur, A. Tuncan 259 Vertical Stress Isobars For Rectangular Foundations Under Different Loading Conditions U. Dağdeviren, M.A.Salman 260 Effect The Lowering Ground Water Table On Behavior Of Piled Raft Under Vertical Load On Dense Sandy Soil A.O. Alshenawy, T.O. Al-Refeai, N.M. Al-Sanabani 261 Comparison Of Damage Criteria For Structures To Near-Field Blast-Induced Ground Motion Damage Estimated By The Different Countries D.M. Özcan, A. Bayraktar, A.C. Altunışık 262 Determination Of Horizontal Bulk Material Pressures In Rigid Cylindrical Slender Silos Under Seismic Excitation Using FEM And EN1998-4 A. Durmuş, R. Livaoğlu 263 The Effects Of Local Soil Conditions On Structural Behaviour In Adapazarı Z. Kaya, E. Uncuoğlu, A. Erol, A. Erken, H.B. Kara, Ş. Yaltır 264 Evaluation Of Seismic Performance Of Prefabricated Structures Using Push-Over Analysis F. Sunca, M. Akköse, A. Türkay 265 Improving Seismic Behavior Of Vierendeel And X-Diagonal Stmfs By Their Configuration Optimization A. Badakhshan, F.A. Koloo 266 Experimental Behavior Of The 1/3 Scaled Composite Shear Wall Having L Shape Steel Made-Up Sections As Longitudinal Reinforcement In Boundary Regions S.B. Yüksel, A. Ünal 267 Experimental Behavior Of The 1/3 Scale Reinforced Shear Wall With Intensive Boundary Reinforcement A. Ünal, S.B. Yüksel 268 Investigation Of Bracing Performance On High Rise Circular Steel Buildings Under Dynamic Loads T. Ekmekyapar, M. Rashid 269 Dynamic Analysis Of A Cantilever Retaining Wall Including Soil-Structure Interaction T. Cakir 270 Experimental And Analytical Investigation Of Modal Parameters Of A Historical Masonry Arch Bridge E. Alpaslan, K. Hacıefendioğlu, O. Köksal 271 Finite Element Based Investigation Of Backfill Effects On Seismic Behavior Of A Cantilever Wall T. Cakir 272 Evaluation Of Geotechnical Properties Of Soils With Geographic Information System (GIS): A Case Study In Gürsu, Turkey E. Seyrek, S. Topçu, A. Orhan 273 Performance Of A Conceptual Hydrological Model In Hydropower Generation For A Mountainous Tropical Catchment In Costa Rica M. Mendez 274 Uncertainty Analysis Of Open Channel Flow: Stochastic Approach To Advection–Diffusion Equation H. Khorshidi, N. Talebbeydokhti, G. Rakhshandehroo 275 Frequency Analysis Of Low And High Flows In Climate Change Y.S. Güçlü 276 Experimental And Numerical Investigation Of Flow Around A Pipeline With Spoiler A.A. Öner 277 Comparison Of Performance Of Labyrinth And Piano Key Weirs In Increasing The Spillway Capacity Of Dams D. Karaeren, Z. Bozkuş 278 Improving Design Storm Estimation By DAD Curves In Watershed Considering NonUniform Rainfall. Case Study: Khersan Basin M. Fazaee, A. Sourinejad, B. Jamshidieini 279 A New Area Based Parameter Estimation Methodology For Leaky Aquifer System A.U. Şahin 280 Numerical Simulation Of Wave-Structure Interaction Using A Ghost-Cell Immersed Boundary Method E. Demirel 281 Assessment Of Diyarbakır Basalt Aquifer Hydrogeological Analyzed And Obtains Thematic Maps With GIS Geostatistical Analyst Tool. R. Çelik 282 The Effect Of Some Aquifer Characteristics On Permeable Reactive Barriers Efficiency For Groundwater Remediation S. Atashin, A. Abrishamchi, M. Vossoughi 283 Potential Of Image Processing Methods Based On Intensity Values Captured By TLS For Surface Condition Assessment J. Zaczek-Peplinska, K. Osińska-Skotak, D. Wujanz, M.E. Kowalska 284 Selection Of Reference Fields For Statistical Analysis Of Point Clouds (TLS) In A Process Of Technical Condition Assessment Of Concrete Water Dam J. Zaczek-Peplinska, M. E. Kowalska, E. Nowak 285 Flow Measurement Using One Point Method For The Rectangular And Triangular Free Overfalls E. Abrari, M. Ergil, M.K. Beirami 286 Assessing The Sensitivity Of SWMM Model To Variations In Hydrological And Land Use Parameters Z. Akdoğan, B. Güven, I. Balcıoğlu 287 Determination Of System Deficiencies With WDS Models A. Uslu, G. Bakan 288 The İmpact Of The Soil Data Quality On The Effectivness Of Hydrological Modelling. Case Study: Upper Raba Catchment (Poland) E. Wojtas, M. Sawczak, T. Bergier, W. Drzewiecki 289 Remote Sensing Based Impermeability Coefficient Estimation And Its Influence On Hydrological Modelling Efficiency E. Wojtas, T. Bergier, W. Drzewiecki, M. Sawczak 290 The Importance Of Land Use Changes And Data Quality For Hydrological Modelling E. Wojtas, M. Sawczak, T. Bergier, W. Drzewiecki, M. Pierzchalski, P. Wężyk 291 Comparative Study For Discharge Coefficient Prediction Of Compound Broad Crested Weir By Two Soft-Computing Techniques G. Yıldırım 292 State-Of-The-Art Review On Explicit Approximations To The Implicit Colebrook-White Friction Factor Equation G. Yıldırım 293 Innovative Test Set Up On Shake Table To Assess Out-Of-Plane Behavior Of Infill Masonry Walls O. Onat, P.B. Lourenço, A. Koçak 294 Fabrication And Critical Decomposition Of High Resistance Interlocking Flooring With Magnetically Treated Water From Iron-Boron-Neodymium Magnets P.H.S. Queiroz, F.H.S. Sales, A. Lopes 295 Experimental Bearing And Abrasion Analysis Of Concrete Specimen Produced By Waste Marble Dust And Waste Marble Particle S. Cemalgil, O. Onat 296 Experimental And Numerical Analysis Of Flow Around Circular Pier O. Şimşek, M.S. Aköz, N.G. Soydan, V. Gümüş 297 Structural Behavior Of RC And PSC Concrete Members With High Strength Shear Reinforcement B. Jun, S.J. Hong, J. Lee, J.-M. Kim, H.S. Lim, J.Y. Lee 298 Effects Of Soil Foundation Structure Interaction On Performance Based Seismic Design: A Case Study A. Abdelhamid, B. Tiliouine 299 A Simple Structural Evaluation Technique For Building Components N. Djermane, N. Lahbari 300 Effect Of Curing Conditions On Fiber Concrete Roads C. Karakurt. Y. Bayazıt, K. Kahveci 301 Effect Of Supplementary Cementing Materials On Fresh Properties And Stability Of SelfConsolidating Rubberized Concrete M.K. Ismail, A.A.A. Hassan 302 Mechanical Properties Of Self-Consolidating Rubberized Concrete With Different Supplementary Cementing Materials M.K. Ismail, M.T. De Grazia, A.A.A. Hassan 303 Seismic Fragility Of Weir Structures Due To Sliding Effect W.Y. Jung, K.Y. Kim, B.S. Ju 304 Comparison Of Static Pushover And Nonlinear Dynamic Analyses Of Reinforced Concrete Buildings B. Yön, M.E. Öncü, Y. Calayır 305 A Parametric Study On The Response Of Cooling Towers Experiencing Various Circumferential Distribution Of Wind Loading A.İ. Karakaş, K. Ozgan, A.T. Daloğlu 306 Seismic Behavior Dependence On The Geometrical Characteristics Of Cooling Towers A.İ. Karakaş, K. Ozgan, A.T. Daloğlu 307 Strength Performance Of Pervious Concrete Subjected To Acid Rain C.R. Orozco, M.D.M. Ibanez, P.J.F. Robles 308 Utilization Through Immobilization Of Dredged Sediment Using Alkali-Activated Slag Jae-Ho Shim, Joo-Yang Park 309 The Importance Of The Validation Of Numerical Models With The Experimental Modal Analysis F. Aras 310 Assessing The Seismic Performance Of Reinforcement Coupler Systems In Turkey K. Taskin, K.Peker 311 Design Factors And Finite Element Modeling Of Cubic Type Voids In RC Slabs K. Taskin, K.Peker 312 The Influence Of Fibers And Mineral Additives On Self Compacting Concrete H. Naima, C. Rabah, A. Naima, B. Malik 313 Direction Effects Of Travelling Waves On Nonlinear Seismic Response Of Arch Dams M. Akköse 314 Effects Of Mıx And Water/Cement Ratıo On Compressıve Strength And Modulus Of Elastıcıty Of Laterızed Concrete O.O. Deborah, A.A Akinpelu 315 Deterministic And Probabilistic Analysis Of The Fire Resistance Of The Technology Support Structures In NPP J. Králik, J. Králik, Jr. 316 Risk Assessment Of NPP Safety In Slovakia J.Králik 317 Predicting The Performance Of Roadheaders From The Needle Penetration Resistance S. Kahraman, A. S. Aloğlu 318 Analytical Evaluation Of Thermal Expansion Of Steel Construction İn Buildings Using Debye Model A.Yamçicier 319 Removal Of Zinc Via Chlorination Roasting From Steelmaking Byproduct I. Jaafar, A. Griffths 320 Stabilization Of Clayey Soil By Waste Steel Pieces Z. Karabash, A.F. Çabalar 321 Development Of Fragility Curves For Self-Supporting Trussed Towers In The Philippines Considering Severe Wind Loads D.H.M. Aquino, J.Y. Hernandez, Jr., E.A.D. Robles 322 The Empirical Correlation Using Linear Regression Of Settlement Ratio Under Embankment Load For Surabaya Compressible Soil Putu Tantri KS, Yudhi Lastiasih 323 Influence Of Blast-İnduced Ground Motion On Dynamic Response Of Masonry Minaret Of Yörgüç Paşa Mosque K. Hacıefendioğlu, O. Köksal 324 Structural Performance Of Sheikh Suleiman Masjid And Its Strengthening T. Tetik, Z. Celep 325 Effect Of Stress Increase On The Geotechnical Properties Of Sand A. K. Hindu 326 Measurement Of Small Strains In Steel Samples Using Digital Imaging Technigues Ş.Sözen, M.Güler 327 Investigation Of Design Criteria For The Type Of Gabion Walls E. Uray, Ö. Tan 328 The Importance Of Tie-Rods In Masonry Arches S. Tugrulelci, M. Kayabasi, F.K. Firat 329 Design Parameters And Special Features Of Next Generation Wind Energy Structures E. Efthymiou 330 On The Buckling Analysis Of Steel Tubular Wind Turbine Towers With Vertical And Horizontal Stiffeners N. Stavridou, E. Efthymiou, C.C. Baniotopoulos 331 Compressive Strength Of Steel And Polypropylene Fiber Reinforced Coal Ash Concrete A. Akyıldız 332 Investigation Of Mode I Fracture Toughness And Fracture Process Zone Of Rock-Like Material With Continued Thermo-Induced Damage Under Semi-Circular Bend Using Acoustic Emission Technique H.W. Liu, L.H. Chen, Y.C. Chen, Y.C. Chang 333 Equilibrium Scour Depth Calculation With Artificial Neural Networks (Ann) M.Ö.Yeleğen, A. Uyumaz 334 Reduction Of The Settlment Of A Collapsible Soil By The Addition Of Lime, Use Of The Double Consolidation Methode. N. Bakir, K. Abbeche, A. Lahmadi 335 Production Of Pumice-Based Geo-Polymer Concrete A. Bilgil, E.Yeşilyurt, M.V. Gökçe 336 Mechanical, Dynamic And Durability Analysis Of Structural Concrete Reinforced With Nano-Silica Particles S.Erdem, E. Gürbüz 337 Buckling Restrained Braces With Different Casing Systems R. Ozcelik, Y. Dikiciaşık 338 Nano-Scale Investigation Of Passive Layer For Corroding Steel Bars In Concrete Under Severe Environmental Conditions R.R. Hussain, A.M. Alhozaimy, A.I. Al-Negheimish, R.Z. Al-Zaid 339 Free Vibration Analysis Of Axially Accelerating Timoshenko Beams Using Differential Transform Method B. Bozyigit, Y. Yesilce 340 The Behavior Of Beam To Column Connections Which Contain Shape Memory Alloys In Moment Steel Frame S. Jamalpour, A. Akbarpour 341 Numerical Simulation Of Dynamic Load On Pavements J. Melcer 342 Effect Of Aggregate Maximum Size On Properties Of Fiber Reinforced Concrete G.İ. Sezer, Ş. Yazıcı 343 Unconfined Compressive Strength, Chloride-Ion Penetration And Freezing-Thawing Resistance Of Cement Stabilized Clay İ. Kalıpcılar, A. Mardani-Aghabaglou, A. Sezer, G.İ. Sezer, S. Altun 344 Mechanical Properties Of Heavy And Normal Weight Concretes Produced With Barite And Limestone H. Bozkurt, C. Karakurt, C. Kandemir 345 Investigating The Effect Of Joint Behaviour On The Optimum Design Of Semi-Rigid Steel Frames S. Şeker, E. Doğan, M.P. Saka, C. Kozanoğlu 346 The Effects Of Viscous Bulk Compressibility For Cantilevered Cylindrical Helices M. Ermiş, H. Argeso, N. Eratlı, M.H. Omurtag 347 Influence Of Steel Fibers On The Shear Strength Of RC Beams Without Stirrups M.İ. Birincioğlu, S. Ulusoy, G. Arslan 348 Study On Flow And Compressive Strength Properties Of Mortars Using Waste Slag O. Karahan, C.D. Atiş, S. İlkentapar, Z.A. Özcan 349 CFRP Strengthening Of Solid Wood Under Bending Loads A.W.E. Shahreen, J.M. Zamin, A.K.M.K. Alam 350 Dynamic Characterization Of Timber Beams Strengthened With CFRP Plate A.W.E. Shahreen, J.M. Zamin 351 Use Of Fly Ash In The Design Of Controlled Low-Strength Material Mixture Ma. D.E. Candelarıa, K.M.David S. Maurıllo, N.B. Dıola 352 Utilization Of Geopolymers In Self-Consolidating Concrete K. Mermerdaş, S.M. Oleiwi 353 Strength And Durability Characteristics Of Soil Stabilized With Local Philippine Cements For Slope Protection Applications J.A.S. Victor, L.B. Martinez 354 The Use Of Fly Ash In Self Compacting Fiber Reinforced Concrete Pavements Ş. Bilgiç, M. Canbaz, S. Mutyilmaz 355 A Delamination Modeling Based On Fracture And Contact Theories For Multilayered Composite Plate E. Kormaníková, K. Kotrasová 356 A Comparison Of The Effect Of Pre-Stressed Strand Diameters, Providing Beam-To-Column Connection M. Kaya 357 The Investigation Of Concrete Quality In Aksaray Region C. Tanrıverdi, D. Koç, İ. Kayabaşı, İ. Çıtak 358 Applicability And Limitations Of 4th Power Law In Design Of Low Volume Roads Against Rutting V.E. Uz, M. Saltan, İ. Gökalp 359 Computerized Decision Tree For Anti-Icing/Pretreatment Applications As A Result Of Laboratory And Field Testings N. İkiz, E. Galip 360 The Aspects Of The Urban Transformation Process In Turkey C. Avci Karatas 361 Alternative Signalized Intersection Design To Enhance Left Turn Efficiency E. Radwan, H. Abou-Senna, S. Tabares 362 Effect Of Waiting Time, Flow And Speed On U-Turn Critical Gaps At Median Openings Under Mixed Traffic Suprabeet Datta, P.K. Bhuyan 363 Sustainable Landscape Maintanance For Highway Planning H. Bozkurt, E.T. Bozkurt 364 The Effect Of Lane Discipline To Intersection Capacity: A Sample Study Of Isparta E. Eriskin, B. Capali, S. Sargin Karahancer, S. Gokova, M.C. Bayrak, S. Terzi, M. Saltan 365 Examining The Effect Of Sustainable Traffic Control Of The Safety Belt And Helmet Use: A Sample Study In Isparta B. Capali, E. Eriskin, S. Sargin Karahancer, S. Gokova, M.C. Bayrak, S. Terzi, M. Saltan 366 Development Of Regression Based Trip Generation Models For Intercity Bus Journeys In Turkey Y. Vitosoglu 367 Why Are Trees Still Such A Major Hazard To Drivers In Poland? M. Budzynski, K. Jamroz, L. Jelinski, M. Antoniuk 368 Road Safety Inspection As A Tool For Road Safety Management – The Polish Experience M. Budzynski, M. Kiec 369 Polish District Heating Systems – Development Perspectives K. Wojdyga 370 Establishment Of The Recycling Plants For Fresh Concrete Wastes: A Cost Management Perspective A. Kazaz, S. Ulubeyli, B. Er, V. Arslan, M. Atici , A. Arslan 371 Educational Experiments Performed On A Model Structure Made Up Of Balsa Wood. A.Elif Özsoy, H.Özkaynak, M. Çağlar, M.Şenturk 372 The Structure Of Academic Surveying Programs In Nigeria As An Educational Pathway To Land Surveyor Registration A.A Akinpelu, A.O. Abisuga 373 Examination And Comparison Of Level For Radon Awareness At High School Institutions: A Sample Of Nevşehir D. Sarıtaş, M. Polat 374 An Investigation Into The Environmental Sensitivity In Sarayönü M.K. Öden, S. Küçükçongar, Z. Gök 375 Education In The Field Of Sustainability Assessment Of Buildings S. Vilcekova, E. Kridlova Burdova 376 Green Cıvılızatıon Strategy (Jakarta Coastal Management Of The Concept Based Mangrove Forest Green Environment In The Future) Hadiana, Akrom Muflih 377 Modeling Of Drying Kinetics Of Potatoes And Fresh Carrot In South Algeria. S. Manaa, N. Moummi, D. Karlo 378 Effects Of Lining Concrete Cooling Towers On The Growth Of Legionella Pneumophila K.R. Jaroor, M.A. Maraqa, K.A. El-Tarabily 379 Experimental Study Of Natural Sorbent For Oil Spill J.A. Al-Najar, A.A. Alwassiti, Ş. Saçmacı 380 The Impact Of Different Growth Media On The Algae Development: An Association With Atmospheric Dust A. Rashidi, A. Akbulut, A.C.Saydam 381 An Opportunity For The Sustainable Ecological Renewal: European Green Capitals N.S. Özcan 382 Compaction Mitigation Potential Of Biotillage And Subsurface Tillage In Dairy Pasture Soils J.H. Görres, Rachel Gilker, J.J. Colby, K. Bellitürk 383 Environmental Contamination And Residential Exposure Of Mercury In Artisanal Gold Mining Area In Benguet, Philippines Ma. B.L.D. Diola, A.C. Resurreccion 384 Mathematical Modeling Of The Drying Kinetics In Thin Layers Of The Local Potato Of Adrar S. Manaa, A. Beatrız, D. Karlo, N. Moummi 385 Detoxification Of Aflatoxin B1 In Various Foods By Nocardia Corynebacteriodes Nrrl B-184 B. Zorlugenç, İ.B. Evliya 386 Cypermethrin Induced Changes In Oxidative Stress Biomarkers In Paramecium Tetraurelia And Elevation Effect Of Some Antioxidant A. Rima, D.M. Reda, M. Ouissem, A. Zoubir, A. Amel, O. Hadjer, B. Marwa, Z. Ibtissem, A. Amira, B. Sana, B. Houria 387 Evaluation Of Two Ornamental Plants For Phytoremediation Of Cd-Contamined Soil S. Çay, A. Uyanık 388 Chickpea Ascochyta Blight Disease Severity İn The Bosphorus Region Of Turkey S.Bulgak, F.N. Kafadar, K. Sarpkaya, C. Can, S.Güneş 389 Elevated Salinity Effects On White Clover (Trifolium Repens L.) Growth A. Karlsons, G. Cekstere 390 Application Of Artificial Neural Networks For Growth Forecasting Of Crayfish (Astacus Leptodactylus Eschscholtz, 1823) S. Benzer, R. Benzer, Ç. Karasu Benli 391 Comparison Between Traditional Methods And Artificial Neural Networks For Growth Forecasting In Crayfish (Astacus Leptodactylus Eschscholtz, 1823) S. Benzer, R. Benzer, Ç. Karasu Benli 392 Effects Of Zinc Oxide Nanoparticles On Hemocytes Of Galleria Mellonella (L.) (Lepidoptera: Pyralidae) Z.U. Nurullahoğlu, A. Eskin, S. Kaya 393 Effects Of Titanium Dioxide Nanoparticles On Hemocytes Of Galleria Mellonella (L.) (Lepidoptera: Pyralidae) T. Zorlu, Z.U. Nurullahoğlu, S. Kaya 394 Investigation Of Heavy Metals In Soil Transport Mechanism M. Bilgin, Ş. Tulun 395 Separation And Purification Of Lipase Using Cu Nanoparticle Embedded Poly (HEMAMatrp) Cryogels K. Erol, K. Köse, D.A. Köse, G. Alp Avcı, L. Uzun 396 Fe(II)-Co(II) Double Salt Incorporated Magnetic Hydrophobic Microparticles For Invertase Adsorption K. Köse, K. Erol, A.A. Emniyet, D.A. Köse, G. Alp Avcı, L. Uzun 397 The Determination Of Oxidative Stress Level Of Nano And Non-Nano Boron İn Chodatodesmus Mucranulatus B. Yilmaz Öztürk, Y. Özkan, B. Aşikkutlu, C. Akköz 398 Effect Of Agtio2 Nanoparticles On Chlorophyll-A, B And Carotenoids Of Desmedesmus Multivariabilis Y. Özkan, B. Yilmaz Öztürk, C. Akköz, B. Aşikkutlu 399 The Comparative Effects Acute Toxicity Of Nano And Non-Nano Boron Particles İn Artemia Salina (Brine Shrimp) Y. Özkan, G. Kilinç 400 Determining The Effect Of The Bioaccumulations And Oxidative Stres Of Chodatodesmus Mucranulatus Exposed To Zno-Tio2 Nanoparticles Y. Özkan, B. Yilmaz Öztürk 401 The Comparative Determination Of Oxidative Stress Level Of Nano And Non-Nano Boron İn Desmodesmus Multivariabilis Y. Özkan, B. Yilmaz Öztürk 402 Investigation Of The Effect On The Pigment Density Of Zno-Tio2 Nanoparticles On Chodatodesmus Mucranulatus B. Yilmaz Öztürk, Y. Özkan, B. Aşikkutlu 403 The Effects Of Levels Reactive Oxygen Species (ROS) And Bioaccumulations Desmodesmus Multivariabilis Exposed To AgTiO2 Nanoparticles B. Yilmaz Öztürk, Y. Özkan 404 A Study On Electrochemical Investigation Of Histamine In Bee Venom A. Kekillioğlu, M. Çalışkan 405 Polen Analysis Of Regional Propolis Of Turkey A. Kekillioğlu, Z. Koçal 406 Ecological Succession Of Arthropoda (Insecta) In Forensic Entomology A. Kekillioğlu 407 The Importance Of Planting Open - Green Field: The Case Of Nigde G. Sandal Erzurumlu, B. Kahveci 408 The Mixture Toxicity Of Synergistic Compounds Combined With Pesticides In Tuta Absoluta M. Yalcin, C. Turgut, P.B. Kurt-Karakus 409 The Acute Toxicity Of Mercury (II) Chloride Upon Pseudorasbora Parva (Temminck & Schlegel, 1846) M. Yılmaz, A.Gül, N. Uzel, S. Kubilay, Ö. Saylar, S. Benzer 410 The Acute Toxicity Of Fenitrothion Upon Pseudorasbora Parva (Temminck & Schlegel, 1846) A. Gül, M. Yılmaz, S. Kubilay, S. Benzer, Ö. Saylar 411 Effect Of Ph Level On Bacterial Induced Cementation Of Sands A. Gurbuz, Y. Dursun Sarı, Z.N. Yuksekdag 412 Determination Of Pesticide Residual Levels Of Grapes Produced In Nevsehir E. Kalıpcı, S. Şahinkaya, K. Şen 413 Physiological And Cytogenetic Effects Of Insecticide Korban 25 W On Allium Cepa L. N. Gömürgen, G. Baysal Furtana, R. Tıpırdamaz 414 Paleoenvironment Setting And Benthic Foraminiferal Assemblage Of Çamardı (Niğde) Eocene Sediments F. Dinçer, N. Avşar 415 Phytoremediation Of Cadmium (Cd) From Agricultural Soils Using Dock (Rumex Patientia L.) S. Adiloğlu, A. Adiloğlu F. Eryilmaz Açıkgöz T.Yeniaras, Y. Solmaz 416 Ammonia Removal From Chicken Manure R.Ö. Surmeli, A. Bayrakdar, R. Molaey, B. Calli 417 Distribution Of Copepoda Species In The Southern Black Sea In 2006-2007 F. Üstün, L. Bat, Ş. Beşiktepe 418 Western Blot Analysis Used To Detect Van-Encoded D-Alanine-D-Lactate Ligase In Surface Water Isolates M. Nakipoglu, F. Yilmaz, B. Icgen 419 The Effect Of Vitamin Supplement On Reproduction And Growth Of Guppy (Poecilia Reticulata Peters, 1860) D. Şahin, O. Aral 420 A Smart Solar Energy-Based Cooling System Design&Application For Sustainable Trout Farming In Keban Dam Lake G. Bayrak, M. Cebeci, A.A. Uslu, G. Karakaya, N. Örnekçi 421 Some Biochemical Blood Parameters In Mogan Lake Economic Fish Species S. Benzer, Ö.Saylar, S. Düzel, G. Gül, M. Yılmaz, A. Gül 422 Capacity Building Key Issues On Integrated Coastal Zone Management For Turkey Black Sea Coast O. Gökkurt Baki, L. Bat 423 Water Quality Simulation Of Lakes Cernek And Balık At The Kızılırmak Delta Of The Black Sea Region Of Turkey K. Küçük, H. Cüce, G. Bakan 424 Monitoring The Thermal Stratification Of Lakes Using Simple And Current Single Point Temperature Measurement Equipment’s S. Göncü 425 Effect Of Seasons On Fatty Acid Composition Of Carassius Carassius L. In Beysehir Lake, Turkey A.Aktumsek, G. Zengin, G.O. Guler, O.B. Citil, Y.S. Cakmak 426 Fatty Acid Composition Of Trout Species In Gezende Dam Lake G. Zengin, A. Aktumsek, G.O. Guler, Y.S. Cakmak 427 The Negative Effects Of High Temperature And Low Moisture On Aftercrop Silage Maize A. Beyhan Ucak, M.C. Bagdatli 428 Evaluation Of Agricultural Drought With GIS In Some Irrigation Areas: The Sample Of Nevsehir Province In Turkey M.C. Bagdatli, S. Savci, A.B. Ucak, O. Gokdogan 429 Trend Detection In Climatic Time Series Using Mann-Kendall M. Zeleňáková, P. Purcz, H. Hlavatá 430 Drought Analysis In Konya Closed Basin A. Bilgil, O. Arslan, E. Aras 431 An Investigation Of The Effect Of Climate On Global Solar Radiation Using The Satellite Data For Nevşehir S.E. Rusen 432 Do Cultural Differences Matter In Education On Environment? D. Nedelcheva Bebenova-Nikolova 433 To Explore The Use Of Analysis Of Cognitive Hillside By Using SEM – An Example Of Te-Chi Reservoir Watershed Tzu-Yin Chen, Ho-Wen Chen , Wei-Lun Lin, Yao-Jhou Zeng 434 Use Of Unconventional Water With Sustainability Approach In Iran J. Tabatabaei 435 Prospect Of Iran Natural Gas Export Projects H. Omıdvar 436 Use Of The Wind Energy As A Renewable Energy İn Traditional Architecture Of Iran As Natural Ventilation D. Rezaei, S. Rezaei 437 Advances Of Energy Tree Method In Calculation Of Gross Hydropower Potential S. Alashan, Z.F. Toprak, Z. Şen 438 The Use Of Active Solar Energy Systems For Heating Greenhouse: Central Anatolia Case Study B.Kendirli, H.E.Polat, S.Avcı 439 Energy Effıcıncy Of A Residentıal Flate In Egypt N.M. Guirguis 440 Prediction Of Basic Wind Speed For Oman S.S.S. Al-Maawali 441 Biodiesel Feedstock Production From Mixed Culture Of Microalgae And Yeast Using Fermented Rice Noodle Wastewater As Substrate M. Puangbut, T. Papone, R. Leesing 442 Effect Of Trace Metal Supplementation In Anaerobic Digestion Of Chicken Manure R. Molaey, A. Bayrakdar, R.Ö. Surmeli, B. Calli 443 New Chernobyl Metsamor Nuclear Power Plant A.Altikat, S. Dogru, Y.A. Argun, T. Bayram ICOCEE COMMITTEES Honorable Chairs of ICOCEE Prof. Dr. Filiz KILIC Rector of NevsehirHaciBektasVeliUniversity Prof. Dr. Ali SURMEN Rector of BursaTechnicalUniversity Chairs of ICOCEE Assoc. Prof. Dr. Serkan ŞAHİNKAYA Nevsehir Haci Bektas Veli University Assist. Prof. Dr. Erkan KALIPCI Nevsehir Haci Bektas Veli University Organizing Committee Assist. Prof. Dr. Erkan KALIPCI Nevsehir Haci Bektas Veli University Assoc. Prof. Dr. Serkan ŞAHİNKAYA Nevsehir Haci Bektas Veli University Assist. Prof. Dr. Seval ARAS Nevsehir Haci Bektas Veli University Assist. Prof. Dr. Hüseyin CUCE Nevsehir Haci Bektas Veli University Assist. Prof. Dr. Ahmet AYGÜN Bursa Technical University Assoc. Prof. Dr. G. Özmen GÜLER Necmettin Erbakan University Scientific Committee Prof. Dr. Ali Fuat AYDIN Istanbul Technical University, Turkey Prof. Dr. Ayfer ERKEN Istanbul Technical University, Turkey Prof. Dr. Aynur KAZAZ Akdeniz University, Turkey Prof. Dr. Baolin DENG University of Missouri, USA Prof. Dr. Bulent KESKINLER Gebze Institute of Technology, Turkey Prof. Dr. Bulent TOPKAYA Akdeniz University, Turkey Prof. Dr. F. Dilek SANIN Middle East Technical University, Turkey Prof. Dr. Fehiman CINER Nigde University, Turkey Prof .Dr. Ferhan CECEN Bogazici University, Turkey Prof. Dr. Gülay ALTAY Bogazici University, Turkey Prof. Dr. Güleda ENGİN Yildiz Technical University, Turkey Prof. Dr. Gülfem BAKAN OndokuzMayıs University, Turkey Prof. Dr. Gülen GÜLLÜ Hacettepe University, Turkey Prof. Dr. Haydar OZTAS Necmettin Erbakan University, Turkey Prof. Dr. Hilmi ACAR Akdeniz University, Turkey Prof. Dr. Işık KABDAŞLI Istanbul Technical University, Turkey Prof. Dr. Iwona SKOCZKO BialystokUniversity of Technology, Poland Prof. Dr. Jan Peter Van Der HOEK DelftUniversity of Technology, Holland Prof. Dr Julia STEGEMANN London’s Global University, England Prof. Dr. Kemal Önder ÇETİN Middle East Technical University, Turkey Prof. Dr. Kemalettin YILMAZ Sakarya University, Turkey Prof. Dr. Krzysztof WOJDYGA WarsawUniversity of Technology, Poland Prof. Dr. Madalena ALVES University of Minho, Portugal Prof. Dr. Mehmet Emin AYDIN Necmettin Erbakan University, Turkey Prof. Dr. Mehmet Faik SEVİMLİ Selcuk University, Turkey Prof. Dr. Mete SÜMER Istanbul University, Turkey Prof. Dr. Mustafa ODABAŞI DokuzEylul University, Turkey Prof. Dr. Nadezda STEVULOVA Technical University of Kosice, SlovakRepublic Prof. Dr. Neşe TÜFEKÇİ Istanbul University, Turkey Prof. Dr. Oral BÜYÜKÖZTÜRK Massachusetts Institute of Technology, USA Prof. Dr.PascaleCHAMPAGNE Queen's University, Canada Prof. Dr. Rainer HELMIG University of Stuttgart, Germany Prof. Dr. Rédey ÁKOS University of Pannonia, Hungary Prof. Dr. Recep BONCUKÇUOĞLU Ataturk University, Turkey Prof. Dr. Robert DAMO University of Korça, Albania Prof. Dr. Seval SÖZEN Istanbul Technical University, Turkey Prof. Dr. Shun-Cheng LEE Hong Kong Polytechnic University, China Prof. Dr. Sureyya MERIC PAGANO Namık Kemal University, Turkey Prof. Dr. Tze Ling NG Hong KongUniversity of Science and Technology, Hong Kong. Prof. Dr. Uwe STILLA Technical University of Munich, Germany Prof. Dr. Yiannis G. MATSINOS University of the Aegean, Greece Prof. Dr. Yücel TAŞDEMİR Uludag University, Turkey Prof. Dr. Yusuf CHISTI Massey University, New Zealand Prof. Dr. Yuh-Shan HO Asia University, Taiwan Prof. Dr. Zekai ŞEN Istanbul Technical University, Turkey KEYNOTE SPEAKERS Prof. Dr. Beatrice LE DESERT, University of Cergy-Pontoise, FRANCE. Prof. Dr. Derin ORHON, Istanbul Technical University, TURKEY. Prof. Dr. Erdogan YUZER, Istanbul Technical University, TURKEY. Prof. Dr. F. Necati CATBAS, University of Central Florida, USA. Prof. Dr. Mohamed ABDEL-ATY, University of Central Florida, USA. Prof. Dr. Oral BUYUKOZTURK, Massachusetts Institute of Technology, USA. Prof. Dr. Uwe STILLA, Technical University of Munich, GERMANY. Prof. Dr. Zekai SEN, Istanbul Technical University, TURKEY. CONFERENCE INFORMATION Conference Date The ICOCEE – Cappadocia2015 conferencewill beheldbetween 20 – 23 May, 2015. Conference Venue The 5 star Dedeman Cappadocia Hotel & Convention Center in Nevşehir, Türkiye. Conference Language The official language of the conference is English. Conference Web Site Further information and updates about the conference can be found at http://www.icocee.org CONFERENCE TOPICS The ICOCEE - Cappadocia 2015 is an interdiciplinary scientific forum focusing on first Civil and Environmental Engineering for the presentation of technological advances and scientific research results in a wide spectrum. The ICOCEE - Cappadocia 2015 is soliciting state-of-the-art research papers in the following areas of interest: Air Pollution & Control Building Materials Engineering Economics Noise Pollution & Control Construction Management Engineering Law, Politics and Policy Solid Waste Management Construction Technologies Aquatic Livings Water Technologies Digital Methods Ecology Wastewater Technologies Geotechnical Engineering Hydrobiology Water Pollution Hydraulic Engineering Education on Environment River Basin Management Structural Engineering Engineering Education Environmental Impact Analysis Structural Mechanics Climate Change Water Chemistry Transportation Engineering Renewable Energy Sources PRESENTATIONS Oral Presentations A slide projector and a computer will be available in the presentation rooms. Each presenter will have 15 minutes for his/her presentation. Poster Presentations Poster should be prepared according to the poster template (80 cm widthand, 120 cm height). The poster presenters are kindly requested to stand in front of the irown posters during the poster sessions to answer arising questions. The posters should be hanged/withdrawn by the presenters. THE SOCIAL PROGRAMME Welcome Lunch and Openning & Award Ceremony, 20 May 2015 from 11:00 to 13:30 The participants (delegates, students and listeners) warmly invited to join us for the Openning& Award Ceremony that takes place in the main hall of the DedemanCapadocia Hotel and Convention Center, after the conference registration. It will be an entertaining and eventful introduction to the meeting. After the Opening Ceremony, the organization committee will give an award to the authors presenting the best paper(s) and the invited speakers. After the award ceremony, the participants will go to the lunch meeting. Gala Dinner, Cappadocia Turkish Night Show, 22 May 2015 from 20:00 to 22:00. The gala dinner will take place in the Social Facilities of Nevşehir Hacı Bektaş Veli University. The participants (delegates, students and listeners) warmly invited to experience Turkish culture, traditions and meals by the performers in a Turkish Night Show. ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison of Exhaust Emissions of a DI Diesel Engine Fueled with Methyl Ester, Ethyl Ester, Petro-diesel and Their Blends H. Sanli* 1,3, M. Canakci 2,3, E. Alptekin 2,3, A. Turkcan 2,3, A. N. Ozsezen 2,3 1 Golcuk Vocational School, Kocaeli University, 41650, Golcuk, Turkey. (E-mail: [email protected]) 2 Department of Automotive Engineering, Faculty of Technology, Kocaeli University, 41380, Izmit, Turkey. (E-mail: [email protected], [email protected], [email protected], [email protected]) 3 Alternative Fuels R&D Center, Kocaeli University, 41275, Izmit, Turkey ABSTRACT Petroleum-based fuels are still the dominant energy sources for the road transportation sector. In 2035, the amount of petroleum used in road transport is predicted to be 60% of total consumption which was 57% in 2010. As an expected result of this high usage, road transport is one of the main reasons of air pollution, contributing to global warming, acid rains and ozone formation, etc. Among the petroleum -based fuels, the largest usage belongs to diesel fuel and it is estimated to increase. For example, in Turkey, between 2009 and 2013, the number of gasoline engine cars decreased 14.38% while the number of diesel engine cars increased 124.6%. When considering the increasing petro-diesel usage, it can be said that environmentally friendly alternative diesel fuel is very important. In the literature, it is well known that biodiesel has better emission profiles than petro-diesel. However, when the related literature is viewed, it is seen that the number of engine emission tests performed with ethyl ester fuel is too stricted when compared to methyl ester. Therefore, in this study, methyl and ethyl ester fuels were produced from waste frying oil. Bioethanol was used in transesterification reaction to get a complete bio-fuel which is ethyl ester. And then, to compare the exhaust emissions of the ester fuels, petro-diesel and their blends (20% ester fuel – 80% petrodiesel), a six-cylinder, turbo-charged, intercooled, direct injection (DI) diesel engine was used. The engine tests were carried out at constant load of 600 Nm and three engine speeds of 1100 rpm, 1400 rpm, and 1700 rpm. When compared to petro-diesel, ester fuels emitted less CO and THC emissions but they caused to more NOx. CO2 emissions were very close to each other. In general, ethyl ester released relatively less emissions than methyl ester. Keywords: Air Pollution, Diesel Engine, Exhaust Emissions, 1 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 PCBs in Ambient Air in Istanbul and Izmir-Turkey Kurt-Karakus PB1,*, Gungormus E2, Okten E3, Celik H4, Ugranlı T5, Sofuoglu A6, Gedik K7, Sofuoglu S8, Alegria H9, Jones KC10 1 EnvironmentalEngineeringDepartment, Bursa Technical University, Turkey. (E-mail: [email protected]) 2,5,6,8 EnvironmentalEngineeringDepartment, İzmir Institute of Technology, Turkey. (E-mail: [email protected], [email protected], [email protected], [email protected]) 3 EnvironmentalEngineeringDepartment, BahcesehirUniversity, Turkey. (E-mail: [email protected]) 4,7 EnvironmentalEngineeringDepartment, Akdeniz University, Turkey. (E-mail: [email protected], [email protected]) 9 Chemistry Department, University of South Florida St. Petersburg, FL, USA. (E-mail: [email protected]) 10 LancasterAcademicCentre, LancasterUniversity, UK. (E-mail: [email protected]) ABSTRACT Levels and sources of persistent organic pollutants (POPs) in Turkey should be determined regularly due to the requirements of Stockholm Convention that has been signed by Turkey in 2001. Polychlorinated biphenyls (PCBs) are classified as one of the restricted/banned groups of POPs. In this study, the concentration profiles of PCBs were obtained for the ambient air of Istanbul and Izmir. These metropolitan provinces in Turkey are populated with industrial facilities in and around, thus have potential sources areas for PCBs.Atmospheric PCBs collected from two background sites between December 2013-March 2014 on a weekly basis by using high volume samplers and were measured individually in gas and particle phase. Gas chromatography–mass spectrometry was used to detect and quantify PCB congeners in the collected samples after the preparation procedure (extraction, cleanup, concentration). Results showed that the measured PCB concentrations in Izmir were higher in some cases compared to those in Istanbul. This study was a preliminary assessment study to extend the research for a long term monitoring starting in May 2014. Keywords: Istanbul, Izmir, PCBs, POPs Acknowledgment: This study is being conducted in frame of a TUBITAK Research Fund (TUBITAK Project # 112Y315). The authors would like to thank to The Scientific and Technological Research Council of Turkey (TUBITAK) for the financial support. 2 ICOCEE – CAPPADOCIA2015 Nevsehir, TURKEY, May 20-23, 2015 Prediction of Surface Ozone Concentration by a Semi-empirical Photochemical Model Kh .Ashrafi1, M. Zamani* 1 and Gh. R Nabi-Bid hendi1 1 Graduate Faculty of Environment, University of Tehran, Tehran, Iran (E-mail:[email protected], [email protected], [email protected]) ABSTRACT Modelling of photochemical smog and the prediction of tropospheric ozone require utilization of a proper chemical procedure. One of these procedures is the Generic Reaction Set (GRS) photochemical mechanism, which consists of seven condensed reactions and is based on principal reactions of photochemical smog production. This method has been developed by the Division of Energy Technology of Commonwealth Scientific and Industrial Research Organization (CSIRO) and uses the smog chamber data. Unlike common methods for chemical processes which are complicated and time consuming, the GRS method is simple and requires a much less calculation time. The main concern of present work is to predict the surface ozone using box model in Tehran, in 2010. Photochemical production of ozone is simulated by GRS. For this purpose, 14 days of summer days which were polluted by ozone have been selected, 10 days for calibration and four days for prediction. An average correlation factor of 0.848 between modelling results and observations as well as a Relative Root Mean Square Error (RMSE) of 0.43 indicate a good precision and accuracy for the model. Also, an Index of Agreement (IOA) greater than 0.7 for all days is another verification of proper performance for the model. Keywords: tropospheric ozone, GRS mechanism, semi-empirical, box modeling, smog. 3 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Air quality modelling in Barcelona from the analysis of climate, territorial and traffic variables Daniel Jato-Espino*1, Elena Castillo-Lopez2, Susanne M. Charlesworth 3 and Jorge RodriguezHernandez4 1, 4 GITECO Research Group, Universidad de Cantabria, Spain (E-mail: [email protected]; [email protected]) 2 Department of Geographical Engineering and Graphic Expression Techniques, Universidad de Cantabria, Spain (E-mail: [email protected]) 3 Centre for Agroecology, Water and Resilience (CAWR), Coventry University, United Kingdom. (E-mail: [email protected]) ABSTRACT Air has become a key factor when assessing human welfare over the years, since its cleanliness is vital to ensure the health and development of any living being. However, its quality is being progressively compromised by population growth and environmentally harmful human activities, such as industrialization or increased energy use and transportation. Big and crowded cities like Barcelona are particularly conducive to the generation of this kind of effects and are therefore more sensitive to undergo dangerous decreases in air quality. For this reason, this paper aims to model the air quality in such city by building regression models that enable estimating the relationship between two air pollutants (NO2 and PM10), whose point measurements are interpolated throughout the area enclosed by Barcelona’s boundaries using GIS techniques, and a series of explanatory variables related to the climate (wind and proximity to coast and mountains), territory (greenspaces and building density) and traffic volume. The results provided by these models are intended to bring an improvement in urban planning, since they allow the detection of areas requiring of priority actions to control air pollution. Keywords: Air quality; Geographic information system; Regression analysis; Urban planning. Acknowledgments: This paper was possible thanks to the research project RHIVU (Ref. BIA2012-32463), financed by the Spanish Ministry of Economy and Competitiveness with funds from the State General Budget (PGE) and the European Regional Development Fund (FEDER). The authors also wish to express their gratitude to the Barcelona City Council for providing the data necessary to develop this study. 4 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 PBDEs in Ambient Air in Istanbul and Izmir-Turkey Kurt-Karakus PB1,*, Gungormus E2, Celik H3, Okten E4, Ugranlı T5, Sofuoglu A6, Gedik K7, Sofuoglu S8, Alegria H9, Jones KC10 1 EnvironmentalEngineeringDepartment, Bursa Technical University, Turkey. (E-mail: [email protected]) 2,5,6,8 EnvironmentalEngineeringDepartment, İzmir Institute of Technology, Turkey. (E-mail: [email protected], [email protected], [email protected], [email protected]) 3,7 EnvironmentalEngineeringDepartment, Akdeniz University, Turkey. (E-mail: [email protected], [email protected]) 4 EnvironmentalEngineeringDepartment, BahcesehirUniversity, Turkey. (E-mail: [email protected]) 9 Chemistry Department, University of South Florida St. Petersburg, FL, USA. (E-mail: [email protected]) 10 LancasterAcademicCentre, LancasterUniversity, UK. (E-mail: [email protected]) ABSTRACT Taking into account that there is a lack of database on polybrominateddiphenyl ethers (PBDEs) in Turkey, PBDE levels were investigated in air samples collected from background sites in Izmir and Istanbul between December 2013-March 2014 on a weekly basis. Particle and gas phase samples were collected on glass-fiber filters and polyurethane foam, respectively, with a high volume sampler. The samples were extracted, cleaned up, concentrated and then analyzed using a gas chromatography–mass spectrometry. PBDEs are at detectable levels in ambient air of Istanbul and Izmir with concentration ranges of 2.53-18.77 pg/m3 and 15.12-458.29 pg/m3, respectively. These statistics showed that higher concentrations of PBDEs were found in Izmir, most probably due to the sampling location which shows more semi-urban characteristics compared to that in Istanbul. Besides, PBDEs tended to be more in gas phase in both locations. This was a preliminary assessment study to extend the research for a long term monitoring at 32 different locations across Turkey starting in May 2014. Keywords: Istanbul, Izmir, PBDEs Acknowledgment: This study is being conducted in frame of a TUBITAK Research Fund (TUBITAK Project # 112Y315). The authors would like to thank to The Scientific and Technological Research Council of Turkey (TUBITAK) for the financial support. 5 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The research of CO and NOx emissions revealed from linear sources in Kocaeli city Korfez district by ISCST-3 and AERMOD Model Programs Kazım Onur Demirarslan*1, Şenay Çetin Doğruparmak2 1 2 Artvin Çoruh University, Faculty of Engineering, Department of Environmental Engineering, TURKEY. (E-mail: [email protected]) Kocaeli University, Faculty of Engineering, Department of Environmental Engineering, TURKEY. (E-mail: [email protected]) ABSTRACT In this study the distributions of CO and NOx emissions occurring in Istanbul – Ankara highway 25 km of which passes through Kocaeli city Korfez district and D-100 highway 20 km of which passes through Kocaeli city Körfez district were examined by using AERMOD (American Meteorolojical Society/Environmental Protection Agency Regulatory Model) and ISCST-3 (Industrial Source Complex Short Term) model programs. These two highways on the area of study have very dense traffic. The reason of this can be shown as these routes being a connection between Istanbul and Trachea region to Anatolia and as they are dense in terms of industry. The daily numbers of vehicles passing from these routes were taken from the reports prepared by Strategy Development Head of Department Transportation and Cost Researches Branch Directorate in May 2009, while the CO and NOx emission rates used as a data in modelling were calculated by task based emission factors of CORINAIR. As a result of the modeling study, daily and yearly distribution maps were obtained. When the maps were examined, highest daily concentrations obtained for CO were found respectively for AERMOD and ISCST-3 as 1031,66 µg/m3, 274,03 µg/m3, while yearly calculated concentrations were found to be 103,53 µg/m3, 55,13 µg/m3 Highest concentration amounts forecasted for NOx emission were found respectively for AERMOD and ISCST-3 as 1650,75 µg/m3, 438,91 µg/m3, while yearly calculated concentrations were calculated as 165,52 µg/m3, 88,16 µg/m3 . When distribution maps formed by using the programs were examined for both polluters, the most densely polluted section was found to be Körfez district section of D-100 highway in terms of both daily and yearly time options. When the results of programs were examined it was understood that two programs give different results from each other. The reasons of this fact were interpreted after being supported by literature research. Keywords: AERMOD, ISCST-3, Körfez District, Traffic Pollution 6 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Levels of bioaerosols in indoor environments in Ankara Elham AGHLARA1*¹ ,Gülen GÜLLܹ 1 .Hacettepe University, Faculty of Engineering, Environmental Engineering Department E-mail: [email protected], [email protected] ABSTRACT Asthma and allergy has become more frequent worldwide during the past decades. Even though the air in many cities is much cleaner than in the past, the prevalence of allergy and asthma has increased worldwide. This study was undertaken in Ankara inorder to identify the effects of the indoor bio-aerosols and their effects on indoor air quality. Air samples were collected from indoor and outdoor environments of 94 dwellings at 15 different districts of Ankara during the summer and winter of 2011. The concentration and type of bacteria and fungi were measured by NIOSH Method-0800 with three types of agar plates (Plate -Count, Sabourad-Antibiotic and Blood Agar) and one vacuum pump with a flowrate of 28.3 L/min for 4 minutes duration. Throughout the study, environmental parameters such as temperature (°C), relative humidity (%) and CO2 (ppm) concentrations were also recorded in in-and outdoor environments. It was found that, bacteria and fungi levels were generally higher in the bedrooms compared to sitting room and outdoor environments. The dominant bacteria species present in the air of examined dwellings are Staphylococcus spp.(56%), Corynebacterium spp.(20%), Bacillus spp(15%). The fungi dominant in the air of examined dwellings are Penicillium spp(52%), Sporothrix spp,(43%) and Stachybotrytis spp(15%). Home characteristics as predictors of multiple microbial biomarkers were also taken in account. Air samples that were taken from 15 sampling sites, located in Ankara showed that, concentration of bacteria were high in Sincan (857 CFU/m³), Altındağ (496.4 CFU/m³), Etlik (435.3 CFU/m³) and for fungi, Akyurt (459 CFU/m³), Çankaya(335.6 CFU/m³). Keywords: Bio-aerosol, Bacteria, fungi, Indoor air pollution 7 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Bioaerosol removalby simultaneous adsorption and photo-oxidation of Ag-doped TiO2/PU under visible irradiation Thanh-Dong Pham, Byeong-Kyu Lee* Department of Civil and Environmental Engineering, University of Ulsan, Daehakro 93, Namgu, Ulsan 680749, Republic of Korea E-mail: [email protected]. ABSTRACT Ag doped TiO2 immobilized on polyurethane (Ag-TiO2/PU) was synthesized by a sol-gel method. Ag was used as a doping agent to enhance photocatalytic activity of TiO 2 to apply photocatalyst under visible light. Polyurethane (PU), a porous honeycomb material, was used as a substrate to immobilize the Ag doped TiO 2 in order to integrate the adsorption property to the photocatalysts.The prepared photocatalysts were characterized usinga scanning electron microscope (SEM) for morphology, a Brunauer-Emmett-Teller (BET) isotherm for specific surface area, an UV-Visible absorption spectrometer (UV-Vis) for optical properties and X-ray photoelectron spectroscope (XPS) for elemental state determination. The synthesized materials were used for removal of Candida famata(C. famata), a very common yeast in aerosols.Under dark conditions, the removal capacities of C. famata in the aerosol by PU, TiO2/PU, and Ag-TiO2/PU were 1.6×105, 3.5×105, and 7.5.0×105 (CFU/Cm3), respectively. The Ag-TiO2/PU exhibited much improved removal capacity of C. famata in the aerosol because the photocatalyst had the highest specific surface area and surface roughness. Under visible light irradiation, the removal capacities of C. famata in an aerosolby PU, TiO2/PU, and Ag-TiO2/PU were 1.6×105, 3.5×105, and 2.1×106 (CFU/Cm3), respectively. The main reason for the greatly improved C. famata removal capacity by Ag-TiO2/PU under visible light was Ag dopant effect. Keywords: Bioaerosol removal, Ag doped, photo-oxidation, adsorption, removal capacity. Acknowledgment: This work was supported by the National Research Foundationof Korea (NRF) grant, funded by the Ministry of Education(2013R1A2A2A03013138). 8 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Overview of Chiral Pollutants as a Tracer of Cycling of POPs Emine Can-Güven* 1, Dilek Bolat 1, Kadir Gedik1, Perihan B. Kurt-Karakuş2 1 Department of Environmental Engineering, Akdeniz University, Antalya, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 2 Department of Environmental Engineering, Bursa Technical University, Bursa, TURKEY. (E-mail: [email protected]) ABSTRACT The increase of pollution due to population growth, urbanization and industrial activities has led to a stress on all living organisms and environment. Any undesirable and toxic chemicals present in the environment may be considered as an environmental pollutant. Among these pollutants, especially synthetic organic chemicals draw attention because of their toxic effects and have a feature of chirality. The term of chirality comes from the Greek word “hand” and human hands are probably the most universally recognized example of chirality. It is because the left hand is a non-superimposable mirror image of the right hand; no matter how the two hands are oriented, it is impossible for all the major features of both hands to coincide. In this study, chirality and the chiral chemicals which have significance for the determination of environmental cycling of persistent organic pollutants were reviewed. Chirality exists everywhere in the universe from living organisms to natural or synthetic organic materials. The most common chiral pollutants are pharmaceuticals, pesticides, polycyclic musks, drugs, etc. The enantiomers have same physical and chemical properties but they show different biological activities. The degradation of these chemicals is enantioselective which is a useful tool in the assessment of fate of chiral chemicals in the environment. This means that the nature of pollution may be interpreted as whether it is newly released or not. Enantiomer fraction is a tool to evaluate the enantiospecific analysis of chiral pollutants. A deviation from 0.5 in samples is an indicator of bioactivity. In the literature, there exist many studies that conducted to measure chiral pollutants in environmental mediums. On the other hand, chiral pollutants have already become subject to environmental monitoring studies in Turkey. Therefore, a general overview of potency of chiral pollutants in the Turkish environment and the needs for future research trends were discussed. Keywords: Achiral, Biodegradation, Chromatography, Enantiomer, Pesticides. Acknowledgment: This study was supported by The Scientific and Technological Research Council of Turkey (TÜBİTAK: CAREER Project No. 112Y175). 9 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Preliminary Investigation of Legacy Organochlorine Pesticides in the Atmosphere of an Agricultural Area in Antalya Emine Can-Güven* 1, Dilek Bolat1, Kadir Gedik1, Perihan B. Kurt-Karakuş2 1 Department of Environmental Engineering, Akdeniz University, Antalya, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 2 Department of Environmental Engineering, Bursa Technical University, Bursa, TURKEY. (E-mail: [email protected]) ABSTRACT Organochlorine pesticides (OCPs) have been used for agricultural purposes until some were banned globally due to their toxic characteristics. The aim of this study is to investigate the presence, levels and distribution of these legacy OCPs in air in an agricultural region considered to be released from past sources or illegal usage. The current work is a part of a larger scale project and the sampling was conducted in Kumluca, a district of Antalya located in the Mediterranean coast and a region with intense agricultural activities such as greenhouse facilities. Passive air samplers consisting of polyurethane foam disks were used to collect atmospheric OCPs and located at three sampling points near greenhouse facility areas that have a potential risk of contamination to represent an initial spatial distribution of contamination in the region. In addition, a background point which is far from settlement and agricultural activities was selected as reference site. Accordingly, 17 passive air samples (monthly (n=6) and bimonthly (n=3) from one sampling point, and quarterly (n=2) from four sampling point) were collected at four different sites from May to November 2013. Sampling rate and the amount of air volumes collected were derived from the losses of depuration compounds. Soxhlet extraction method was used to extract pollutants and the analyses were performed by using Shimadzu QP2010 Ultra GCMS. While the concentration of Ʃ 29 OCPs ranged from 42.1 to 61.9 pg/m3 (45.9±6.76), pentachlorobenzene and o,p'- DDE were the most abundant ones in samples. Total OCPs concentration showed an increasing trend by increased temperature and these were comparable to studies conducted in similar regions. Although the production and usage of OCPs has been banned, results show that some of them could still be found in air. Their presence may be result of atmospheric transport or the degradation of formerly used pesticides. Keywords: Greenhouse area, Passive sampling, Persistent organic pollutants. Acknowledgment: This study was supported by The Scientific and Technological Research Council of Turkey (TÜBİTAK: CAREER Project No. 112Y175). 10 ICOCEE –CAPPADOCIA 2015 Nevşehir, TURKEY, May 20-23, 2015 Analysis and Assessment of Heavy Metal Pollution of Road Dust in Düzce, Turkey F. Taşpınar 1, M. Atasoy 1*, Z. Bozkurt1, B. Poyraz2, O. Uzun3 1 Düzce University,Engineering Faculty, Environmental Eng. Dept., Düzce, TURKEY (E-mail: [email protected], [email protected]) 2 3 Düzce University, Central Research Laboratory, Düzce, TURKEY (E-mail: [email protected]) Düzce University, Faculty of Forestry, Dept. of Landscape Architecture, Düzce, TURKEY (E-mail: [email protected]) ABSTRACT An environmental monitoring survey on metal contamination in road dust was conducted to assessthe extent of metal pollution due to dense vehicle traffic, collecting many samplesfrom the state roadD-100 passing through in Düzce, Turkey. According to characteristics of the road, more than twenty sampling point were selected for characterizing the entire area, following a route alongfrom west to eastand to north of the city. The concentrations of Fe, Ba, Al, Mo, Sr, Pb,Cu, Mn, Sn, Cr, V, Co, Sc, Ni, B, Sb, As andCd in road dust samples have been determined using ICP-MS. The meanconcentrations with standard deviations(mg/kg) of these heavy metals and metalloidsare in decreasing order as follows: Fe (106527,46±40620,50), Ba (10023,77±6130,57), Al (6585,48±2917,55), Mo (4857,98±2407,09), Sr (4498,13±2228,78), Pb (1007,54±826,2), Zn (842,96±331,88), Cu (531,1±318,4), Mn (528,82±259,26), Sn (481,72±130,56), Cr (397,61±194,93), V (342,08±98,38), Co (337,95±147,18), Sc (288,47±114,05), Ni (220,89±103,24), B (144,85±60,65), Sb (96,34±26,11), As (36,47±18,95) and Cd (3,75±1,13). The metal contamination of road dust anddegree of enrichmenthave been assessed using enrichment factors (EFs), geo-accumulation index (Igeo) and pollution index (PI). Considering the values of Igeo per element obtained fromthe mean concentrations, results showed that some sampling sites moderately polluted, namely grade-2 pollution with respect to Pb, Fe, Cr, Cd, Cu and Mn, while most of the samplingpoints were at grade-1 pollution level with respect to Al, Mo, Sn, Co, Ni and grade-0 with respect to the rest of elements. Also, EFs give an insight of human influence degree of urban road dusts and PIs indicate heavy metals of road dust polluted moderately high. High contents of the elements could be attributed to anthropogenic effects clearly related to dense traffic volume of the state road studied. Keywords:Road Dust, MetalPollution, Pollution Indices, Vehicle Traffic. Acknowledgment: The authors thank toDüzce University, Scientific Research Project Funding (DÜBAP) for their financial support [DÜBAP-2013.06.02.203]. 11 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Compration of indoor and outdoor VOCs Levels at children homes S. LAKESTANI1, B. KARAKAŞ1, S. ACAR VAİZOĞLU2, B. GÜÇİZ DOĞAN2, Ç. GÜLER2, B. ŞEKEREL3, A. TANER4, G. GÜLLÜ1 1 Hacettepe University, Faculty of Engineering, Environmental Engineering Department; Hacettepe University, Environmental Engineering Department, 06800 Beytepe, Ankara-TURKEY; [email protected], [email protected], [email protected] 2 Hacettepe University, Faculty of Medicine, Department of Public Health; Hacettepe University, Department of Public Health, 06100 Sihhiye, Ankara-TURKEY;[email protected], [email protected], [email protected] 3 Hacettepe University, Faculty of Medicine, Pediatric Allergy and Asthma Unit; Hacettepe University, Pediatric Allergy and Asthma Unit,06100 Sihhiye, Ankara-TURKEY; [email protected] 4 TOBB ETÜ Hospital, Microbiology and Clinical Microbiology; Yasam Caddesi No: 5 06510 Sögütözü, Ankara-TURKEY; [email protected] ABSTRACT Volatile Organic Compounds (VOCs) are a large group of carbon-based chemicals that easily evaporate at room temperature. Volatile Organic Compounds are chemicals that easily turn into gases and contaminate indoor air. Some of these chemicals cause developmental damage as well as damage to the liver and central nervous, respiratory, and reproductive systems. Many products we have in our homes release VOCs. Some examples of sources of VOCs are building materials, home and personal care products and behaviors. Indoor air VOCs were collected simultaneously from variety of indoors (e.g. living rooms, baby’s rooms) and outdoor environments which were voluntarily selected throughout Ankara. Studies have shown that the level of indoors VOCs is generally higher than the level of outdoors. Babies spend about 95% of their time in indoor environment, the time has been spent in indoor might be more during winter times. Their organs, immune system and neurological system are still developing, and because of their lower body weight, they breathe in a relatively greater volume of air than adults. This is the first comprehensive study done in Turkey including prenatal and postnatal periods. VOCs levels were measured over 74 homes. Average of total VOCs in the living rooms and baby’s rooms in winter varied between 159.77 to 172.60 µg/m3 .According to the sampled indoor environments of the study, it was found that the levels of indoor air volatile organic compounds in the baby’s rooms were higher than the living rooms. Our findings suggest that there is a relationship between indoor VOCs levels and infants health. As there are no standards for indoor residential air quality, additional researches are needed to assess the impacts of indoor pollution exposure for infants. Keywords: Indoor air, Volatile Organic Compounds (VOCs), Infant health, Living Rooms, Baby’s Rooms Acknowledgment: This study was supported by grants obtained by The Scientific and Technological Research Council of Turkey (TÜBİTAK, Project No: 110Y082). We are grateful to all the mothers who are taking part in the Project, especially those who have allowed us access to their homes. 12 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Economic and Environmental Contributions of Declaration of the Marmara Region as Emission Control Area (ECA). D. Yıldırım Pekşen 1, G. Bilen Alkan 2 1 Maritime and Port Management, Yalova University, Yalova, TURKEY. (E-mail: [email protected]) 2 Maritime Transportation Management Engineering, Istanbul University, Istanbul, TURKEY (E-mail: [email protected]) ABSTRACT Nowadays maritime transport has become an essential part of the international trade due to the massive capacity of carriage of cargoes overseas. In fact that it also impacts to global economy as positively by providing to transport of almost 90 percent of total cargoes between countries. On the other hand, air pollution caused by exhausts emissions of ship traffic which is increasing day by day has led to global warming and health problems. This situation has forced the International Maritime Organization (IMO) to bring new regulations. As a result, Annex VI ‘Prevention of air pollution from vessels’ has been added to 73/78 MARPOL Convention and it brings global and regional limits on SO x and NOx emissions. Turkey has also adopted above-mentioned annex on 26.02.2013 but not announce any Emission Control Area (ECA) yet. Every year more than 50,000 ships are passing from the Sea of Marmara and the Turkish Straits which are important seaways in international maritime transport and surrounded by the crowded cities about 20 million people. Therefore, it is appear that how human health and environment can be benefited by reducing ship emissions if such a cruci al important area as Marmara Region has been announced as ECA. In this study, amount of total emissions caused by ships will be estimated by comparing released exhaust gases into air in a year before and after ECA proclamation on Marmara Region. In addition, methods to reduce ship emissions according to ECA limits such as alternative fuels and new engine technologies will be discussed. On the other hand, from an economic point of view, external costs of ship emissions on human health and environment will be calculated by using EXIOPOL (A New Environmental Accounting Framework Using Externality Data And Input-Output Tools For Policy Analysis) formula. Keywords: Air pollution, ECA, Marpol Annex VI, the Sea of Marmara, ship emissions. 13 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Airborne Particle Concentrations Prediction Using Artificial Neural Network Ya-Chin Teng* 1, Ho-Wen Chen 2, Wei-Yea Chen 3, Wei-Lun Lin4 1,2,3,4 Department of environmental science and engineering, Tunghai University, Taiwan (Address: No.1727, Sec.4, Taiwan Boulevard, Xitun District, Taichung 40704, Taiwan R.O.C.) (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT As the wind velocity is increased, it will increase the emission of airborne particles from bare ground. In the dry season, the river dust has become an important emission source of PM10. To avoid the damage from airborne particle, it is important for decision makers to develop a reliable prediction model to control air quality. Thus, this study uses official monitoring data around Da-Jia River and Ta-An River as database to build a prediction model by using artificial neural network (ANN). It was building three kinds of models with different time series, namely yesterday (t-1), two days ago (t-2), three days ago (t-3) to predict today concentration of PM10(t). The best architecture of artificial neural network has a hidden layer and nine neurons in hidden layer, then the assessment of all the simulation results were reasonable. Delimit the PM10 > 75µg/m3 to be a standard of warning issued, then the current discriminant ratio were 70~85%. Represents this model can be used as the basis warning mode of river dust for future. Keywords: river dust, PM10, artificial neural networks (ANN) 14 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Illustration of Air Quality Change Using Innovative Trend Analysis Method YavuzSelimGüçlü*1, EyüpŞişman2, İsmail Dabanlı3, Zekai Şen4 1, 3 Istanbul Technical University, Faculty of Civil Eng., Department of Hydraulics,TURKEY (E-mail: [email protected], [email protected]) 2 Yildiz Technical University, Faculty of Civil Eng., Department of Hydraulics,TURKEY (E-mail: [email protected]) 4 Turkish Water Foundation, TURKEY (E-mail: [email protected]) ABSTRACT Insurance and protection of fresh air is necessary not only for people, but also for many species to survive and maintain a healthy life. For this purpose, air pollution records in Turkey by fully automatic stations since 2005 provide a basis to control air pollutionandimproveair quality. In this study, different major Turkish cities,namely, Nevşehir, Şanlıurfa, Antakya, Ereğli ve Zonguldakare selected for the application of innovative trend analysis. Air pollutants’data such as SO2, NO2, NO, PM10 and COmeasured at these cities provide the basic data setfor the model application. The methodology requires division of the available record length into two parts as for the first and second halves. The ranked data in these two halves are plotted against each other for the visual identification of the possible trend components in the low, medium and high pollutant values. Keywords: Air quality,air pollutants, analysis, innovation,trend. 15 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Clear-cut, easy and safe air purifying technique. H. Habibazarfard1 and A. Cemal Saydam1 1, Environmental Engineering Department, Hacettepe University, Ankara, TURKEY. (E-mail: [email protected],[email protected]) ABSTRACT Indoor air quality is inevitably linked to ambient air quality. What controls ambient air quality also affects indoor air quality. The desert belts and their respective dust plumes on a global basis regula te ambient air quality. Each desert has its own exclusive extension zone and during the period of cyclonic depressions millions of tones of dust is injected into the atmosphere. These dust particles having 10micron size or less can traverse long distances and are composed of clay minerals and embedded bacteria fungus and viruses. It has been shown that when inhaled it may trigger genes that is responsible from the production of specific proteins that results with the triggering of migraine. Basing on this work we have developed simple water based air purifier system that can effectively removes 90 % of particles in an hour and ultimate purification is reached within 120 minutes in one cubic meter experimental chamber. Of course increase in air flux will inevitably shorten the time necessary for ultimate purification for a given environment. The air purifying system consists of an aquarium pump hose and air stone and simple 1.5 l water bottle. The basic principle behind the purification system based on the fact that during the rise of air bubble the friction with water creates a vortex assisting the transfer of clay particles and associated bacteria fungus and virus to water phase. With this simple purification system the adverse effect of dust particles can effectively be removed from indoor. Renewing the water is the only thing required for the continuation of effective purification. The water is not wasted and can be used to irrigate the flowers lawns etc. Such systems also offer an ideal low cost pre- cleaning filtering that can be used to extent the operational life of expensive filtering systems. Keywords: Air quality, bacteria, dust, filtration, 16 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Atmospheric pollution monitoring using neural networks Mounira Rouaïnia* 1, Nadjet Djebri 1, 2 Department of petrochemistry and process engineering, University 20 août 1955- Skikda, Algeria ([email protected], [email protected]) 3 Department of electrical engineering, University 20 août 1955- Skikda, Algeria ([email protected]) ABSTRACT Air pollution is a global environmental challenge that receives more worldwide attention since last decades, despite the recent declining concentration of atmospheric pollutants following stringent environmental protection regulations. The major source of this pollution remains industrial emissions. The evolution of pollutants in the atmosphere depends on varied a phenomenon, that is why it is necessary to follow these pollutants and to predict the evolution of their concentrations in the atmosphere. In this study we consider industrial emissions monitoring using neural networks. After a review of the models applied in monitoring ambient air quality, we will focus on the application of the MLP neural networks ( Multi-Layers Perceptron ) in the forecast of pollutants of air. Considering three atmospheric pollutants in an industrial site (NO2, SO2 and O3) and after dispersion modelisation by the MLP, we study the adaptation of neural networks to their concentrations evolution prediction. Then we develop and assess neural network soft sensors for emission prediction based on simulated and reel emissions data measurements. The performance of the proposed soft sensor is then evaluated using actual data from an industrial boiler. The developed soft sensor achieves comparable accuracy to the continuous emission monitor analyzer, however, with substantial reduction in the cost of equipment and maintenance Keywords: Air quality monitoring, dispersion models, neural networks, Multi-Layer Perceptron 17 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Heavy Metal Concentration Of House Dust Parisa.BABAEİ 1, İlknur DURUKAN 2 and Gülen GÜLLÜ 3 1, 3 Hacettepe University, Environmental Engineering Department, 06800 Beytepe, Ankara, Turkey. (E-mail:[email protected]; [email protected]) 2 Hacettepe University, Chemistry Department, 06800 Beytepe, Ankara, Turkey. (E-mail: [email protected]) ABSTRACT Poor indoor air quality is widely regarded as a significant health, environment and economic problem. In this study, house dust samples were collected from 47 dwellings in several spots of the Ankara during the period April, 2012 to June, 2012 in order to investigate the occurrence of heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Sb, Sn, V and Zn) and associated levels according with locations. All samples were analyzed using AAS. According to the statistical analysis the highest arithmetic means were observed for the elements Mg (8900.34 μgg-1), Fe (4408.57 μgg-1), Zn (449,983 μgg-1) and Cu (104,515 μgg-1). Results of heavy metal analysis revealed that the concentrations change with the proximity to the main street of houses, to the floor type of the houses, wall paint type, home heating source type, frequency of disinfectant use and smoking in the house. Factor analysis (FA) model was used for source allocation and estimation of contributions from specified sources to the concentration of each parameter. By factor analysis, five source types were identified as the house wall paint type, frequency of disinfectant use, traffic and roadside soil, Coal burning and polluted soil explaining about 63.27% of the total variance. Keywords: Abstract, indoor air quality, house dust, Ankara, heavy metals, AAS, Factor analysis Acknowledgment: We would like to thank the Scientific and Technological Research Council of Turkey (TÜBİTAK-CAYDAG-110Y082) for its financial support. 18 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Analysis of VOCs in the Indoor Air L. Meciarova* 1, S. Vilcekova 2 1, 2 Faculty of Civil Engineering, Technical University of Kosice, SLOVAKIA. (E-mail: [email protected], [email protected]) ABSTRACT Volatile organic compounds have been studied over recent years in many countries . However, construction processes, building materials, building types and the method used for the collection and analysis of VOCs vary from one country to another. At the same time constant technical and scientific progress has brought new materials that can emit completely different VOCs than older mater ials. A similar type of study was carried out long time ago also in Slovakia. The results from this study already do not provide representative data for today. Therefore, this study is focused to determine the current state of occurrence and level of concentrations of VOCs. The studied building is located in east Slovakia. Gas chromatography with surface acoustic wave technology was used for analysis of individual VOCs in the indoor air. Total volatile organic compounds concentration was determined with photoionization detector with UV lamp and expressed as concentration of toluene. Air temperature and relative humidity was also set during measurements. The results were compared with the guide values of other countries, because there are no guideline values for TVOC concentrations and limits are set only for a small amount of VOCs in Slovakia. Keywords: Emissions, GC/SAW, Indoor air, VOCs Acknowledgment: This study was financially supported by Grant Agency of Slovak Republic to support of projects No. 1/0405/13. 19 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Dispersion of the NOx emissions from chimneys and road traffic around industrial sites: case study of the company Fantazia. H. Gourgue 123*, A. Aharoune 1, A. Ihlal Ahmed 2 1 2 3 Laboratoire de ThermodynamiqueetEnergétique (LTE), FSA Agadir, Morocco Laboratoire de Matériauxet Energies Renouvelables (LMER), FSA Agadir, Morocco Laboratoire de Procédés, Energieetenvironnement (P2E) Universiapolis, Agadir, Morocco *Corresponding Author. E-mail: [email protected]; Tel: (+212660008349) ABSTRACT Urban areas are major sources of air pollution. This case is particularly serious close to industrial sites or traffic, industrialization and energy consumption are remarkable. This work represents a combination, of a model of emissions from road traffic, and a dispersion improved Gaussian model of pollutants from point sources, in order to estimate emissions from point and line sources, and predict the dispersion of these emissions. In this work, we developed a new numerical model that combines the two approaches top-down and bottomup to quickly produce the inventory of road traffic emissions by calculating the total emissions and distribute them in time and space. A first attempt was made using the model and the data available. The results and analysis of their uncertainties have led to the development of strategies to improve the input parameters and results of the second application of the model. We also used a Gaussian model that we had improved to calculate the emissions generated by the chimneys (point sources) and the dispersion of these emissions in the surrounding area of the industrial site. We chose the industrial site of the company FANTAZIA in the industrial area of Agadir city-Morocco to study the dispersion of NOx emissions generated by the company and those generated by road traffic around the surrounding area. We also used the NOx analyzer to measure the concentrations of this pollutant in order to compare them with the results obtained using numerical models. The simulations performed by the models give encouraging results compared to measurements. This helps to understand the physical and chemical phenomena related to the dispersion to well suggest emission reduction scenarios, and improve the air quality in agglomerations. Keywords:air pollution, industrial sites, road traffic, emission factors, dispersion. Acknowledgment: The authors thank the leaders within the company Fantazia, for their collaboration in this work. 20 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 IndoorAirQualityand Construction Specifications Bahtiyar ÖZTÜR, Hülya AYKAÇ, Hasret ÇELEBİ OndokuzMayisUniversity, EngineeringFaculty, Environ. Engng. Dept. 55200 Samsun ABSTRACT Indoor air pollution (IAP) is a case that pollutants such as gas, particulate and vapour exist in indoor atmosphere at a level that affects health and comfort of people who live inside. Indoor air quality (IAQ),which affects occupant health, comfort, and productivity, and in some cases even building usability, may suffer due to any number of problems in design, materials and equipment selection or construction. Preventing of air circulation between indoor and outdoor, wrong design or lack of ventilation and air conditioning systems, existing of pollution sources in indoor and entering pollutants from outdoor create air pollution inside the buildings. Also, construction materials cause health hazard for human. Therefore U.S. Environmental Protection Agency (US-EPA) developed new specifications to recognize new homes equipped with a comprehensive set of indoor air quality features. Potential benefits of an improved IAQ include lower healthcare costs, reduced sick leaves of occupants, better performance in work, lower turnover of employees, and lower cost of building maintenance due to fewer complaints about indoor air quality. People consider that energy efficient homes have poorer indoor air quality. Not necessarily, it is possible to achieve both energy efficiency and healthy indoor air quality through (1) properly designed building construction and technologies, and (2) proper home maintenance practices.Effective, properly designed heating, ventilation, and air conditioning systems, bathroom and kitchen exhaust fans, and a tight building shell not only remove excessive moisture and cooking odors in the building, but also can ensure that most outdoor pollutants do not enter the home in the first place. Many design decisions that can lead to poor IAQ are made in the early phases of design and are difficult to modify or correct later on. Early design missteps can be avoided if IAQ is put on the table as a key design issue at the start. Examples are inadequate space for mechanical equipment, limiting access for inspection and maintenance, and selection of interior finishes that can lead to high levels of volatile organic compound (VOC) emissions or to moisture problems in the building envelope.There are two primary reasons to include IAQ considerations in the earliest stages of project planning: avoiding problems that occur when IAQ is treated as an afterthought and allowing consideration of alternative design concepts that involve decisions made early in the design process. Keywords: Indoor air quality, building design, construction 21 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Analysis of SO 2 and PM Concentrations with Artificial Neural Network: A Case Study of Erzurum City Center F. Ekmekyapar Torun* 1, Z. Bingül 2, M.Y. Çodur 3 1 2 3 Atatürk University, Department of Environmental Engineering, Erzurum, TURKEY. (E-mail: [email protected]) Erzurum Provincial Directorate of Environment and Urbanization, Department Directorate of Environmental Impact Assessment, Permit, Erzurum, TURKEY. (E-mail: [email protected]) Erzurum Technical University, Faculty of Engineering and Architecture, Department of Civil Engineering, Erzurum, TURKEY. (Email: [email protected]) ABSTRACT Erzurum where is one of the highest and the coldest city of Turkey has a harsh continental climate. Climate conditions usually last as freezing cold and snowy in winters and hot and dry in summers. For this reason in Erzurum during the winter months air pollution originated from heating reaches high values by the effects of city topography with bowl-shaped, irregular urbanization and meteorological factors. In this study, during 2014-2015 winter period, air pollution level in terms of SO 2 and particle material parameters were studied in the center of Erzurum city and the results were evaluted. Data for the period of 2014 October-2015 April were taken from Ministry of Environmental and Urbanization Air Quality Monitoring Station which is located at the city center and compared with the air quality values prescribed by Air Quality Assessment and Management Regulation and the World Health Organization and Environmental Pollution Agency. The relationship between air pollutants and climate elements such as temperature, wind speed and humidity is determined by using artificial neural network. Key Words: Erzurum, air pollution, artificial neural network, SO2 , particle material, meteorological factors 22 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Air Pollution Parameter Variation on Between 2007-2014: The Case of Igdir (Turkey) Dogru S. *1, Bayram T. 2, Argun Y.A. 3 and Altikat A. 4 1, 3 2 Environmental Helath Programme, Vocational School of Health Services, Igdir University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Engineering Faculty, Yuzuncu Yil University, TURKEY. (E-mail: [email protected]) 4 Department of Civil Engineering, Engineering Faculty, Igdir University, TURKEY. (E-mail: [email protected]) ABSTRACT In the study it has been investigated the annual and winter’s season air pollution values of Igdir centrum between the years 2007-2014 by means of the data obtained from the meteorological observation station found in the same city. For this purpose, it has been used the values of sulfur dioxide (SO2) and particle substance (PM10) in Igdir city center between 2007 and 2014, which were obtained from the web site of the Ministry of Environment and Urban Planning. Measurement values have been analyzed in deference to Air Quality Evaluation and Management Regulation and limit values determined by the European Union (EU). When analysing the results of air qualities of Igdir between 01 January 2007 and 31 December 2014, the average PM10 has been found out 118 µg/m3 and the average of SO2 has been determined as 11 µg/m3. When analysing the results of air qualities for heating season between 01 October 2006 and 31 March 2014, the average PM10 has been found out 172 µg/m3 and the average of SO2 has been ascertained as 18 µg/m3. The annual PM10 and SO2 value averages have been found lower than the heating season averages. When the obtained average values were compared with the Long-term Turkey Limit Value (LTL) it has been observed that PM10 was above the expected limit values between 2007 and 2014 and SO 2 did not exceed the expected value limits within the same years. Simultaneously, when EU and LTL values were compared, annual PM10 values have been observed to be exceeded for all years and SO2 values have been observed to be acceptable only in 2011. According to the results, measurements for the refinement of the air quality of Igdir must be taken. The Ministry of Environment and Urban Planning must increase the air pollution inspections and take the necessary precautions during the days when critical limit is exceeded. Keywords: Air pollution, Igdir, Particulate matter 10 (PM10), SPSS, sulfur dioxide (SO2). 23 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 LEVEL AND SOURCES OF PARTICULATE MATTER (PM10, PM2.5) IN TURKEY Gülen GÜLLÜ 1, ZELİHA GEMİCİ 2, Betül KESKİN ÇATAL 2 1 Hacettepe University, Environmental Engineering Department, 06800 Beytepe, Ankara, Turkey. ([email protected]) 2 Ministry of Environment and Urbanization, General Directorate of Environmental Impact Assessment, Permit and Inspection, Department of Laboratory, Measurement and Monitoring, Ankara, Turkey ([email protected]; [email protected]) ABSTRACT Spatial and temporal variations of PM and factors affecting these variations in Turkey from the year 2009 to the end of 2014 are investigated in this study. The PM characteristics were identified according to three main stations types; industry, curbside, residential and urban background stations. The PM10 levels (anual mean) ranged from 11 to 120 µg/m3 at industry sites, 17 to 39 µg/m3 at urban background sites, from 12 to 143 µg/m3 at residential sites and 44 to 106 µg/m3 at curbside sites. PM2.5 levels were ranging from 16 to 56 µg/m3 at residential sites and 27 to 55 µg/m3 at curbside sites. The PM2.5/PM10 ratio is highly dependent on the types of site and season and varied from 0.28 to 0.50 with a mean of 0.40. The PM2.5/PM10 ratio in European cities generally in the range of 0.6 to 0.8, indicating majority of the particulate mass is in the fine fraction, whereas majority of particulate mass is in the coarse fraction in Turkey. State of PM levels of Turkey is determined through comparison with air quality data generated in other countries and available air quality standards. Based on this comparison, although air quality has improved in recent years, it is still not one of the clean cities around the world. Although measured concentrations of pollutants mostly comply with standards in the Turkish Air Quality Regulation, further reduction in concentrations will be necessary, when EU directives become effective in the country. Keywords: Particulate matter, PM10, PM2.5, urban air quality, Turkey. 24 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Dynamic Stiffness of Resilient Materials for Reduction of Floor Impact Sound Jung-Min Kim*1, Jung-Yoon Lee 2, Hye Sun Lim3, ByungKoo Jun4, and Seong Jun Hong5 1, 2, 3 Department of Civil. Architectural, and Environmental System Engineering, Sunkyunkwan University, Republic of Korea (E-mail: [email protected], [email protected], [email protected]) 4, 5 Department of Global Construction Engineering, Sunkyunkwan University, Republic of Korea (E-mail: [email protected], [email protected]) ABSTRACT High-rise apartment houses have advantages to use effectively relatively small land area, whereas they have also disadvantages in housing environments. One of the big residential environment concerns in living apartment houses is noise pollution induced by floor impact sounds caused by footsteps, falling objects, moving furniture, etc. There are two types of floor soundproofing solutions to reduce impact noise, acoustic matting or floating floors; both solutions can reduce impact noise transferring through wooden and concrete floor structures. In case of floating floors, resilient materials are normally placed between concrete or wooden slab and finishing materials. The resilient materials effectively reduce impact sound through a floor by reducing the vibration caused as an item hits the floor. The dynamic stiffness of resilient material is strongly influenced on the sound reduction level of resilient material which decreased as the increase of dynamic stiffness. If resilient materials with low dynamic stiffness are layered on top of resilient materials with high dynamic stiffness, the dynamic stiffness of the layered structure is similar to that of the resilient materials with low dynamic stiffness. Many studies on the effects of types and density of resilient materials have been performed to examine the sound insulation of buildings. On the other hand, few test results are currently available regarding the long-term dynamic stiffness of resilient material for the floor sound insulation systems. In this study, a total of 16 resilient material specimens subjected to long-term load for 270 days were tested and the long-term dynamic stiffness was thus assessed. The experimental and analytical results indicate that the dynamic stiffness of resilient material increased as the loading period increased. As a result, the sound reduction level of resilient material subjected to long-term load was much smaller than that of resilient material subjected to short-term load. Keywords: Dynamic stiffness, Floating floors, Floor impact sound, Long-term load, Resilient materials. 25 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Thinking of Noise Control in a Positive Way: Soundscape Concept Nilgün Akbulut-Çoban* 1,2 and Kadir Gedik1 1 2 Department of Environmental Engineering, Akdeniz University, TURKEY. (E-mail: [email protected]) Provincial Directorate of Ministry of Environment and Urbanization, Antalya, TURKEY. (E-mail: [email protected]) ABSTRACT Noise pollution which is considered as the third most hazard environmental type of pollution after air and water pollution has been increasing day by day due to rapid urbanization and industrialization. In this noisy life situation, people try to access calm areas to take fresh breath. Directive 2002/49/EC implying the assessment and management of environmental noise confirmed the need for preventing or reducing noise levels that may negatively affect human health, including annoyance and sleep disturbance. In addition, it emphasizes the need to preserve quiet areas. However, in spite of the attempts to develop the criteria for identification of quiet areas, there is still no common guide. This leads “soundscape concept mainly focusing on how people perceive the acoustic environment” as an alternative method to be able to use in defining quiet areas in urban places. In this study, the point of soundscape concept in environmental noise control and approaches used to determine the soundscape perception which is a hot topic in recent scientific researches especially in European countries were reviewed. Moreover, the current situation of research trends in noise pollution in Turkey was investigated by conducting bibliometric and content analysis. According to the preliminary results based on Web of Knowledge and Scopus database, the percentage of studies resulting from traffic, industrial plants, mechanical equipment and air conditioners is found as 24%, 13%, 10%, 8%, respectively. Moreover, 48% of those were on sound level measurement and modeling, and approximately %20 was related to the noise exposure and annoyance. The other point to be attracted is that researches are not necessarily concentrate on soundscape concept. This shows that the soundscape concept will become a potential study area especially on defining the quiet areas required to be determined also according to Turkish Environmental Noise Regulation. Keywords: Bibliometric analysis, Noise directive, Quiet area, Urban planning. 26 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Quiet Area Characteristics of an Educational Area: A case study of Akdeniz University Campus, Antalya Ahmet Gökhan Göküş1, Hasan Güleç 1, Zeynep Aslan 1, Nilgün Akbulut-Çoban* 1,2 and Kadir Gedik1 1 2 Department of Environmental Engineering, Akdeniz University, TURKEY. (E-mail: [email protected]) Provincial Directorate of Ministry of Environment and Urbanization, Antalya, TURKEY. (E-mail: [email protected]) ABSTRACT Environmental noise pollution has been becoming an important issue to be solved in the last decades especially for densely populated urban areas considering its negative impacts to human health and their wellbeing. The present study provides an evaluation of environmental noise levels in Akdeniz University Campus and also it provides an assessment of this campus in terms of “quiet area” characteristics according to the Turkish Regulation on Environmental Noise (with an official number of 2011/27601). To determine the environmental noise levels, 20 measurement points were selected and A-weighted equivalent noise levels (LAeq) were obtained. Moreover, the questionnaire was held with 378 people in order to take the perception of people on noise levels in the campus and to evaluate the “quiet area” characteristic of this area based on people’s thought. According to results, the equivalent noise levels in the campus were in the range of 41,4 dB(A) -74,1 dB(A) with an arithmetic average of 55,4±6,03 dB(A). Although, there is no certain and common guide for which areas should be considered as a quiet area, the approach mostly used for identification of such areas in the first step is the use of noise mapping to conclude whether the noise levels are below or equal to 55 dB(A) deciding that human beings are not affected negatively. Accordingly, this area with some exemptions can be regarded as “quiet area” based on acoustic measurements. However, the results of the study show that acoustic parameters alone are not enough to define the quiet areas. The data obtained from questionnaires show that the environmental noise leading to change in natural sound balance in campus has become a serious factor that affects the social life of people. Keywords: Environmental noise, Noise perception, Noise pollution, Urbanization. Acknowledgment: The authors thank to TUBITAK (Project: 2209-A) for their financial support. 27 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination of Noise Pollution in Main Arterial Roads of Nevsehir City Center Erkan KALIPCI* 1 and İsmet BİLGEN 2 Department of Environmental Engineering, Nevsehir Hacı Bektas Veli University, 50300 Nevsehir, Turkey. (E-mail:[email protected], [email protected]) ABSTRACT In this study, the precautions that might be taken in order to determine the level of noise pollution caused by traffic in main arterial roads of Nevsehir city center and to minimize negative effects of this experienced noise pollution on people were indicated. Moreover, it was aimed to form a database by using the measurements via authorized institutions in order to take precautions for the areas having high noise pollution caused by traffic. Totally 20 measurement points were determined on main arterial roads in Nevsehir city center where traffic is heavy. The noise measurements were carried out in accordance with TS ISO 3744, TS ISO 1996-1 and 19962 standards. The coordinates of measurement points were determined by Magellan brand hand-held GPS receiver. During measurements, temperature and wind measurements were carried out with anemometer device. The noise levels at measurement levels were measured via Svantek brand Type I noise measurement device. It was determined in noise measurements of totally 20 measurement points that equivalent noise measurement levels of streets were in the range of 78-95 dBA in the afternoon and 65-85 dBA in the evening. Since the results obtained were harmful in terms of human health, the precautions that should be taken are mentioned briefly. Consequently, it was determined that equivalent noise measurement levels (Leq) of totally 20 measurement points on the main streets and arterial roads in Nevsehir city center were higher than limit values mentioned in regulations, OSHA, ISO and WHO and were at such a level which threatens the health of human beings. Key Words: Noise pollution, Traffic, Nevsehir, Effects on human health. Acknowledgment: The authors gratefully acknowledge the Nevsehir Haci Bektas Veli University, Scientific Research Project Funding (NeU BAP) for financially supporting this work. 28 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Hydrogen peroxide aided sulphuric acid pre-treatment of electronic waste for improving gold recovery by metabolically-engineered strain of Chromobacterium violaceum Subhabrata Das and Yen-Peng Ting* 4 Engineering Drive 4, Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585. (E-mail: [email protected], [email protected]) ABSTRACT Electronic waste (e-waste) contains higher concentration of gold than natural gold ores. The use of bioleaching microbes for the extraction of gold from e-waste is a sustainable and environment-friendly approach. However, the presence of a large amount of copper in e-waste competes with the gold extraction process since copper also forms a stable complex with the cyanide lixiviant produced by the bioleaching microbes. Hence, to mitigate the problem, pre-treatment of e-waste from printed circuit boards (PCBs) was conducted in sulphuric acid solution using hydrogen peroxide as an oxidant to remove copper from the shredded particles. This work evaluated the effect of different system parameters on copper removal, such as sulphuric acid concentration, hydrogen peroxide concentration, e-waste particle size, temperature and treatment time. Sulphuric acid and hydrogen peroxide had a significant influence on the overall pre-treatment process. The reaction orders of sulphuric acid and hydrogen peroxide were determined as 1.11 and 1.09, respectively. Particle size also played an important role in the pre-treatment; the leaching rate was proportional to the inverse of the square of the initial average particle diameter. The pre-treatment of e-waste for copper removal was found to be diffusion-controlled and fitted the kinetic model: 1 - 2x/3 - (1-x)2/3 = kt. A metabolically engineered strain of Chromobacterium violaceum pBAD was used for bioleaching experiments to achieve greater cyanide production and enhanced gold recovery. As e-waste is toxic to the microorganism, two-step bioleaching and spent medium leaching were adopted. At 0.5% (w/v) pulp density of e-waste, spent medium bioleaching using bacterial cell free secondary metabolites achieved a gold recovery of 36.4%, compared to 24.7% under two-step bioleaching for Chromobacterium violaceum pBAD strain. Over all our results demonstrated the advantages of e-waste pre-treatment and metabolic engineering of bioleaching microbes for improving the efficiency of gold recovery. Keywords: e-waste; bioleaching; cyanide lixiviant; kinetic model; metabolically engineered strain. 29 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Düzce Potential Investigation of Domestic and Industrial Solid Waste Recoverable G.Funda GÖKÇE* 1, Nazire MAZLUM 2 and Pınar HASANOĞLU 3 1, 2,3 Environmental Protection and Control, Düzce University, TURKEY (E-mail:[email protected]) Environmental Engineering, Süleyman Demirel University, TURKEY. (E-mail:[email protected]) ABSTRACT In this thesis, Düzce City investigated the potential for domestic and industrial solid waste, recyclable waste. Potential of domestic and recyclable waste was determined by survey, the views of the people. The information was compiled from relevant authorities in determining the recoverable potential of industrial waste. 56.07% of household waste in the province of Düzce and kitchen waste was determined as 43.93% of recyclable waste. Industrial establishments operating in the province of Düzce First Organized Industrial Zone consist of an annual 370 tonnes of packaging waste. Information on waste accumulation and disposal of industrial organizations has been compiled. In this study, the most important environmental problems of Düzce City, which is one source, separate collection for household and industrial waste and recycling collection can be provided in large quantities have been determined. Keywords: Integrated waste management, Solid waste, Solid waste management, Solid waste recycling. 30 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 GROUND IMPROVEMENT VIA CHROME AND STEEL SLAGS First M. Vekli* 1, Second C.C. Çadır2 and Third F. Şahinkaya 3 1, 2, 3 Civil Engineering, Bozok University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT There are many types of waste materials in Turkey. Unless these materials are recycled in different ways, they will cause negative effects on environment and thus on nature. This damage will be minimized by reusing these materials and ensuring their recycling. There have been many scientific studies conducted and still being conducted on recycling of waste materials around the world and also in Turkey. In this study, the exchange rate of the physical characteristics and strength features of the ground will be experimentally examined as a result of Liquid limit, Plastic limit, Grain size curve, Permeability test, Compaction test, Unconfined compression test and Shear box test practiced by separately adding chrome and steel slags onto an argillaceous ground in the rates of 5%, 10% and 15% in terms of weight. As a result of this study, while improvement will take place in the physical characteristics and strength features of argillaceous grounds, the environmental damage of an industrial waste material will be minimized by ensuring recycling. Keywords: Chrome slag, Extrinsic stabilization, Ground stabilization, Steel slag, 31 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A NewBitumen Geosynthetic Barrier Mainly Based on Boron Production Waste Clay for Landfill Liner Systems DeryaUlutaş*1, Zerrin Çokaygil2, Aysun Özkan3,Yücel Güney4, Müfide Banar5 *1 Anadolu University, Department of Chemical Engineering, Turkey (Email: [email protected]) 2,3,5 Anadolu University, Department of Environmental Engineering, Turkey (Email: [email protected], [email protected],[email protected]) 4 Anadolu University, Research Institute of Earth and Space Sciences, Turkey (Email: [email protected]) ABSTRACT Geosyntheticbarriers are generally used for various construction applications and contain a broad range of different materials. Among the geosynthetic barriers geomembranes and reinforced geosynthetic were usedas an impermeable liner forsolid waste landfills. Bituminous geosynthetic barriers, one types of the reinforced geosynthetics, include a molten mix of bituminous, an elastomeric polymer and mineral fillers. In this study, unlike available applications, boron production waste clay (CW) was used to produce a geosynthetic barrier with bitumen as a binder. CW/waste tire/bitumen mixtures were prepared by using a laboratory mixer at 150°C. Hot mixtures were extruded into strips by using a lab-scale co-rotating twin screw extruder (L/D:40) at the screw speed of 20 rpm followed by die casting (2 mm x 100 mm). The temperatures of the various barrel elements were set between 70°C (bitumen introduction) and 38°C (extruder exit). The extruded strips were thenpassed on a conveyor belt at a speed of 1 rpm. The required main characteristics for geosynthetic sampleswere determined as to be thickness, mass per unit area, water permeability and tensile properties according to TS EN 13493. According to analyses resultsthe optimum material was determinedas to be an impermeable liner for solid waste landfill. As a conclusion, this study has an importance from the point of sustainable waste management principles with its aim to product a new material by usingwaste materials. Keywords: Boron waste clay,Bitumen,Geosynthetic, Landfill, Waste tire Acknowledgement: This study was supported by TUBITAK (The Scientific and Technological Research Council of Turkey) under the Grant No.: 113Y122 and Anadolu University Scientific Research Projects Commission under the Grant No.: 1301F037. 32 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 SOLID WASTE MANAGEMENT IN ERZURUM Z. Bingül* 1, F. Ekmekyapar Torun 2 1 Erzurum Provincial Directorate of Environment and Urbanization, Department Directorate of Environmental Impact Assessment, Permit, Erzurum, TURKEY. (E-mail: [email protected]) 2 Atatürk University, Department of Environmental Engineering, Erzurum, TURKEY. (E-mail: [email protected]) ABSTRACT Nowadays, the amount of municipal solid waste increased with the effects of the population growth, technological development and industrialization. The solid waste, which is a major problem for the environment and human health, should be collected and disposed to reduce the harmful effects. One of the duties of the municipalities is to collect, transport and dispose of solid wastes. There are three district municipalities within the boundaries of Erzurum Metropolitan Municipality, the total population of which is 380.000. The wastes are collected by district municipalities and are brought to the landfill that is operated by Erzurum Metropolitan Municipality. “Erzurum Solid Waste Landfill” was established in Aziziye District, Adaçay Neighborhood and it is 18 kilometers away from the city center. The landfill has three business stages and its total area is 55 hectares. Lot 1 of the landfill which has the economic life of 20 years has almost been completed and the construction of Lot 2 has started. The wastewater treatment in the plant, which has 280400 tons average daily rate of disposal solid waste, is performed by reverse osmosis which is one of the advanced treatment systems. In this study, the quantity, collection, transportation and disposal and the municipal management of solid wastes in Erzurum were examined. Keywords: Erzurum, solid waste, solid waste management, collection, landfill 33 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Soil Minerology on Electrokinetic Remediation Gülçin Demirel Bayık* 1, Ahmet Altın 2 and Ömer Faruk Çapar 3 1,2 Environmental Engineering Department, Bulent Ecevit University, TURKEY. (E-mail: [email protected], [email protected]) 3 Civil Engineering Department, Bulent Ecevit University, TURKEY. (E-mail: [email protected]) ABSTRACT While remediating a polluted site, the physical and chemical properties of soil is very important just because it affects the degree of the treatment and which method to choose. Electokinetic remediaton is an emerging technology which relies on the application of direct current on soil. Use of electrokinetics has been studied by several authors but there are few studies that reveals the effects of soil minerology on electrokinetic remediation. This study investigates the effect of soil minerology on electrokinetic heavy metal removal. A benchscale electrokinetic remediation set up which consist of an electrokinetic extraction cell, fluid and gas volume measurement devices, a DC power supply and a multimeter was conducted. Cadmium polluted soil samples were prepeared by mixing different amounts of dolomite (2.5%, 5%, 10%) in kaolin. Throughout the experiment the current and fluid level change were continously monitored. Results of the study shows that cadmium concentration is higher near the cathod e due to accumulation, while concentrations decrease close to the anode. Removal efficiency of %0 dolomite and %2,5 dolomite sample is smilar and higher, whereas efficiency decreases for %5 and %10 dolomite concentrations. For %10 dolomite concentration very little accumulation was occured which supports the adverse effects of minereological structure to electrokinetic remediation. Keywords: Electrokinetics, Heavy Metal, Soil Remediation, 34 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Environmental Quality of Compost: Can Composting Earthworms (Eisenia fetida) Help Manage Compost Nutrient Ratios? Korkmaz Bellitürk*1 Josef H. Görres2 H. Sevim Turan3 Selçuk Göçmez4 5 6 M. Cüneyt Bağdatlı Merve Eker Sevinç Aslan7 1 Namık Kemal University, Faculty of Agriculture, Department of Soil Science and Plant Nutrition, Tekirdağ/Turkey (E-mail: [email protected]) 2 The University of Vermont, Plant and Soil Science, Burlington/Vermont/USA (E-mail: [email protected]) 3 Republic of Turkey Ministry of Food, Agriculture and Livestock, Olive Research Institute, Bornova/İzmir/Turkey (E-mail: [email protected]) 4 Adnan Menderes University, Faculty of Agriculture, Department of Soil Science an Plant Nutrition, Tekirdağ/Turkey (E-mail: [email protected]) 5 Nevşehir Haci Bektaş Veli University, The Faculty of Engineering and Architecture, Department of Biosystem Engineering, Nevşehir/Turkey (E-mail: [email protected]) 6 Yapı Kredi Bank, Head Office/ Retail Credits Management, İstanbul/Turkey (E-mail: [email protected]) 7 Agriculture Chamber, Tekirdağ/Turkey (E-mail: [email protected]) ABSTRACT While composts are important organic and conventional fertility amendments, the stoichiometry of mature composts can affect environmental sustainability of organic food production. High P:N ratio wastes may cause an over-application of P to cropland which can result in algal blooms and thus surface water degradations in agricultural watersheds. This is of particular importance in watershed with high dairy production where manure application enriches soil phosphorus content. Composting agro-industrial wastes, such as manure and olive pruning wastes, may not affect the P:N ratio of the waste. In vermicomposting however growing populations of earthworms may reduce the amount of P by bio-accumulation of P and thus diminishing it in the final product. In this project, vermicompost was prepared under laboratory conditions from olive prunings, cow manure and a mixture of the two with and without Red Wiggler earthworms (Eisenia fetida). There were three replicates per treatment. All treatments were incubated for 180 days in the laboratory. Samples were taken after 30, 60, 90 and 180 days. We tested the hypothesis that total P:total N ratio will be significantly reduced by vermicomposting. After 180 days vermicompost had lower P:N ratios in all treatments, probably due to accumulation in the earthworm biomass. There were strong inverse linear relationships of P:N ratio (P< 0.001) with time for the earthworm treatments, but for the compost produced without earthworms, P:N ratio increased or did not change over 180 days. Earthworms can thus be used to engineer composts with lower P:N ratios and thus less impact on water quality. Vermicompost may become a tool in the environmental management of sustainable soil fertility. Keywords: Vermicompost, P:N Ratio, Environmental Management, Sustainable, Agriculture Acknowledgment: The authors thank Namık Kemal University, Scientific Research Project Funding (NKU BAP) for their financial support [Project number: NKU.BAP.00.24.AR.13.15]. 35 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of the Mechanical and Hydrological Characteristics of a Bioreactor Landfill using Laboratory Simulators. Lakshmikanthan P*1, Santhosh L. G2, Sivakumar Babu G. L3* 1 Research Scholar, Centre for Sustainable Technologies, Indian Institute of Science, Bangalore 560012, India, e-mail: [email protected] 2 Research Scholar, Centre for Sustainable Technologies, Indian Institute of Science, Bangalore 560012, India, e-mail: [email protected] 3 Professor, Department of Civil Engineering, Indian Institute of Science, Bangalore 560012, India, e-mail: [email protected] ABSTRACT Municipal solid waste disposal has become a challenge to the engineers in the present world. Good pretreatment methods coupled with landfilling are looked as potential means of disposal of municipal solid waste (MSW). Bioreactor landfill is a suitable option which increases the biodegradation rate of MSW through leachate recirculation. Enhanced biodegradation affects the properties of MSW. In the present study two bioreactor landfill simulators were used to investigate the effect of limited leachate recirculation and enhanced leachate recirculation on the compressibility and strength characteristics of mechanically biologically treated (MBT) municipal solid waste (MSW) at a laboratory scale. The setup was monitored for a period 365 days. After one year of operation, the residues of the waste in the simulators were analysed. Consolidation tests, creep tests and triaxial tests were performed on initial and final wastes. The variation in the primary compression ratio, secondary compression ratio, cohesion and friction angle values are analysed and the results are presented. Keywords: Bioreactor landfill, Sustainability, stabilization, leachate recirculation 36 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Environmental research of old waste landfill “Vardariste”, Skopje, Macedonia B. Kovachevikj* 1, E. Raleva 2 , M.Markov 3, Z. Ilijoski 4 1 Institute for Energy, Construction and Environment, Drezdenska 52, MACEDONIA (E-mail: [email protected]; [email protected]) 2,3,4 Geotechics Department, Civil Engineering Institute Macedonia, Drezdenska 52, MACEDONIA (E-mail: [email protected],[email protected], [email protected];) ABSTRACT The aim of the research study is determination of current state of the old landfill "Vardarište" in city of Skopje, Macedonia, in order to develop strategy for remediation and redevelopment of the area. The landfill "Vardarište" is located on the left bank of the river Vardar at about 7 km downstream from the town center. Between 1976 and 1996 year landfill was operational as not engineered dump site. The total surface of the landfill is 42ha and the thickness of the body of the landfill is about 10 - 12m. In the landfill are deposited municipal waste, non-hazardous industrial waste, medical waste, construction waste, etc. Different tests of examination are carried out at “Vardariste” and are determined composition and volume of the waste, morphology of the landfill, hydro-geological conditions and permeability, distance from surface and underground water, and biogas detection. Also analysis of contamination of soil, surface and underground water were performed. Waste from different depth was analyzed and compared related to composition and leachate constituents. Results from analysis of underground water indicate highly contaminated environment with different pollutants. Parameters that are characteristic for organic species pollution have high values and are typical for leachate from the landfill waste. Great content of organic components indicates a process of fermentation that will last long, probably decades. Heavy metals are present in water samples, where chromium and nickel exceed the limit values. According to the results of analyzes of groundwater, waste and biogas can be concluded that the landfill is in methanic (IV) or long time phase . The Landfill “Vardariste” examined in this study, will be example for development of strategy for remediation and redevelopment of contaminated areas and old landfills for municipal waste in Macedonia. Keywords: landfill, leachate quality, strategy for remediation, waste composition Acknowledgment: The authors thank to City of Skopje , Macedonia for their support 37 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Bioconversion of Food Wastes for The Production of Value Added Products Bioconversion of Food Industry Wastes ZORLUGENÇ, Bülent* 1,KIROĞLU ZORLUGENÇ, Feyza 1 1, ZORLUGENÇ, B., KIROĞLU ZORLUGENÇ, F., Food Engineering Department, Nevşehir Hacı Bektaş Veli University Engineering and Architecture Faculty. TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Food waste is a serious global problem. Currently, landfilling and incineration are the major practices for managing these wastes in many countries. These practices, however, may cause severe environmental pollutions and adds burden to the economy. Food industry produces a lot of waste products and these wastes contain useful organic components such as carbohydrates, proteins, etc. Many efforts have been recently made to exploit waste biomass through a biorefinery approach, for the production of value added products such as single-cell protein, enzymes, animal feeds and feed additives, organic acids, pigments, ethanol, biofuels and various other products. This work is an overview of the value-added products that obtained by bioconversion of food industry wastes. Keywords: Food, Waste, Industry, Microorganism, Biorefinery 38 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Utilization of Food Industry Wastes KIROĞLU ZORLUGENÇ, Feyza* 1, ZORLUGENÇ, Bülent 1 1, KIROĞLU ZORLUGENÇ, F., ZORLUGENÇ,B., Food Engineering Department, Nevşehir Hacı Bektaş Veli University Engineering and Architecture Faculty. TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Food wastes represent a serious environmental problem. Currently, the animal and plant origin wastes are treated in traditional ways, such as land filling, incineration, composting, low quality animal feed and land spreading. Recent years, there is an increasing global trend towards the efficient utilization of natural resources. Sustainable food production and value-addition of wastes is the most important issue in the food processing industries. At present, the European Union legislation encourages the exploitation of by-products. This valorization can be achieved through the extraction of high-value components such as proteins, polysaccharides, pectins, fibers, flavor compounds, and phytochemicals, which can be re-used as nutritionally and pharmacologically functional ingredients. This work is an overview of the value-added products that only obtained by various extraction techniques from food industry wastes. Keywords: Food, Waste, Industry, High Value Product 39 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Different Barn Planning System on Waste Characteristics – Case Study of Turkey Havva Eylem Polat * * Assist.Prof.Dr., Department of Farm Structures and Irrigation, Faculty of Agriculture, Ankara University, TURKEY. (E-mail: [email protected]) ABSTRACT Determining the daily amount of manure produced and which characteristics of manure are important issues in designing the livestock waste management systems. In this study, the amounts of solid and liquid manure from 140 barns were measured daily period for two years. Total nitrogen, total phosphorus, unit volume weight, moisture content and total solids parameters were determined by th e standard methods on waste samples taken each 15 days from barns. According to the results, 28.0 kg ± 4.2 kg/day of solid manure and 10.2 ± 1.08 kg/day liquid manure were obtained as average from the live weight of 452 kg of cattle. The total amount of waste derived from a cattle average of 38.4 kg / day, this value was calculated as 35.0 kg/day in tie-stall systems, 33.0 kg/day in free-stall systems, 36.3 kg/day closed and loose housing system, 32.4/day kg in closed and grid -based systems, 42.1 kg/day in semi-open system and 39.8 kg/day in open the systems. According to the calculations, solid waste was obtained from 6.7% of barns, semi-solid waste from 73.3% of barns and liquid waste from 20% of barns. These changes are seen in barn to barn were found statistically significant (P<0.01). Total nitrogen ratio, total phosphorus ratio, unit volume weight, total solids and moisture content are varies in the range of orderly 5.0% - 1.9%, 5.6% - 2.3%, 888 kg / m3 - 1286 kg / m3, 53.0% - 1.7% and are also 98.3% -% 47.0. These changes in different planning systems were found statistically significant (P<0.01). It was determined that solid waste is obtained from open systems, liquid waste from closed free-stall system and closed -grid-based systems and semi-solid waste from closed-tie-stall systems, loose housing systems and semi-open systems. Briefly, it was concluded that the different planning systems have important effects on amount of waste produced, waste characteristics and so waste management system design. Keywords: Cattle, Manure, Moisture, Nitrogen, Phosphorus, Total Solids, Waste Amount 40 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Constraints of Local Waste Management System in Lagos, Nigeria A.O Abisuga 1, A.A Akinpelu 2*, D.O Olanrewaju 3 1,2,3 Department of Building Technology, Lagos State Polytechnic, Nigeria. ( [email protected],2aaakinpelu@ yahoo.com,3 [email protected]) 1 ABSTRACT Lapses in the waste management system in Nigeria are causing serious societal, environmental menace, especially in highly populated cities like Lagos State in the country. Stakeholder participation in waste management, administration at the local district level have not been effective and efficient. These local waste administrators deserve more attention from researchers and government to improve service delivery. The factors that hinder the effective performance of the local waste management administrators in Lagos State were assessed in this study. A systematic and simple random sampling methods were employed in the sample survey across the local government areas (LGAs) and local council development areas (LCDAs) in the State . A descriptive research approach was adopted for the analysis of collected data. The results of the study show that a lack of organizational structure, professional competence and education, funding and incentives, non cooperation of the residents, accessibility to residence and disposal locations, high level of illiteracy of home users were identified as significant constraints on the local waste management system. If a corrective measure can be driven along these outcomes, an environmentally sound waste management system will be achieved. Keywords: Lagos State, Local waste administrator, stakeholder, waste management 41 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 California Bearing Ratio of a Clay with Waste Carpet Jute Murat Öztürk1, Ali Fırat Çabalar *,2 1, 2 Civil Engineering Department, University of Gaziantep, TURKEY. (e-mail: [email protected]) ABSTRACT Proper management of waste carpet jutes is an environmental problem in many regions of the world. Instead of disposal in landfills, waste carpet jutes can be used in some engineering applications, thereby reducing their potential impact on the environment. The goal of this study is to investigate the behaviour of a clay using waste carpet jutes. We prepared various mixtures of clay containing 0, 1, 3 and 5% waste carpet jutes by weight, and determined their California Bearing Ratio (CBR) values. The test results indicate that the CBR value of specimens increases with the addition of waste carpet jute. Keywords: CBR, clay, waste carpet jute. 42 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Porosity analysis of ceramic wall tile derived from blast furnace slag Elif Eren Gultekin* 1, Zahide Bayer Ozturk 2 1 2 Department of Ceramic and Glass Design , Nevşehir Hacı Bektaş Veli University, Nevsehir, TURKEY. (E-mail: [email protected]) Department of Metallurgical and Materials Engineering, Nevşehir Hacı Bektaş Veli University, Nevsehir, TURKEY. (E-mail: [email protected]) ABSTRACT Recycling of industrial wastes for production of building material and cement is very important for preventing environmental pollution, reducing production costs and saving of energy, storage. In production of iron-steel process, great amounts of solid wastes are produced especially in the flotation. These wastes have consisted of oxides of silicon, calcium, aluminium and magnesium which may be a good source for building ceramic production. The production of building materials is still based mainly conventional raw materials such as clay-quartz-feldspar. In this research the possibility of using a blast furnace slag as a raw material for production of ceramic wall tile is studied. A basic mixture, almost suitable for producing ceramic wall tiles with raw materials provided from Yurtbay Ceramic Company (Eskişehir/Turkey), with the same composition as that used in industry was prepared. The compositions were prepared where the waste replaces limestone and kaolin in the basic mixture, either partially or totally. The physical (color parameters of body, water absorption, and linear shrinkage) and mechanical properties of tiles were analyzed. The crystallinity of the obtained samples was evaluated by X-ray diffraction (XRD). In order to determine porosity measurement mercury porosimetry is performed. The results showed that the new wall tile samples with waste showed low water absorption. The mechanical properties measured according to ISO 10545-4. When observed samples were compared with standard, the samples with waste showed high strength due to amount of crystalline phases. The results indicate that there is a potential secondary raw material for production of wall tile from this blast furnace slag Keywords: Blast furnace slag, Ceramic wall tiles, Recycling, Waste. 43 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Selective Sodium Hydroxide Leaching of Zinc from Waste Zinc-Carbon and Alkaline Battery Mixture Bayram Andak* 1, Ahmet N. Bulutcu 2 1 2 Chemistry Institute, TUBITAK Marmara Research Centre, Kocaeli 41470, Turkey (E-mail: [email protected]) Dept. of Chemical Engineering, Istanbul Technical University, Istanbul 34469, Turkey. (E-mail: [email protected]) ABSTRACT This paper describes the multi-staged sodium hydroxide leaching behavior of zinc, manganese and iron from waste zinc-carbon and alkaline battery mixture. For experimental studies, a 250-kg-sample was randomly collected from waste zinc-carbon and alkaline batteries at such a ratio that it could simulate the waste battery characteristics in Turkey. A physical procedure which includes crushing, sieving and magnetic separation was applied to this mixture. All fractions of non-magnetic materials were collected and ground under 250 microns. The ground black mass with a metal composition of 23,26 % Zn, 27,53% Mn, 2,60 K and 1.93% Fe was used for multi-staged leaching experiments under different temperatures. The concentration of sodium hydroxide, agitation speed and pulp density were kept constant as 30 % w/w, 250 rpm and 1/5 respectively. The black mass was washed with distillated water three times at 25°C before leaching experiments. Potassium extraction of 92,8% was achieved after 3-staged washing at 25°C and with 1/5 pulp density. Zinc concentrations of the first stage leachates were analyzed as 2,98 %, 2,97 % and 2,98 % at 40 °C, 60°C and 80°C respectively. It is determined as 5,59 %, 5,48 % and 5,56 % at 40 °C, 60°C and 80°C respectively for second stage. At final stage, zinc concentrations were 6,29 %, 6,47 % and 6,96 % at 40 °C, 60°C and 80°C respectively. It was observed that temperature does not have a serious effect on the zinc concentration obtained expect for the one at third stage. This is due to the fact that at third stage the solubility limit is reached and solubility is a function of temperature. Keywords: Alkaline, battery, selective leaching, zinc-carbon. Acknowledgment: Most of the work reported in this paper was performed within a continued project funded by TUBITAK (The Scientific and Technological Council of Turkey) through its 1007 Support Programme for Research Projects of Public Institutions (1007). The financial support is gratefully acknowledged. 44 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of performance of MSW landfill barrier systems at laboratory scale and using HELP model simulations Santhosh L. G*1, Lakshmikanthan P2, Sivakumar Babu G. L3* 1 Research Scholar, Centre for Sustainable Technologies, Indian Institute of Science, Bangalore 560012, India, e-mail: [email protected] 2 Research Scholar, Centre for Sustainable Technologies, Indian Institute of Science, Bangalore 560012, India, e-mail [email protected] 3 Professor, Department of Civil Engineering, Indian Institute of Science, Bangalore 560012, India, e-mail: [email protected] ABSTRACT Municipal Solid Waste landfills are one of the significant sources of environmental pollution. This has become a challenge to the engineers to design landfills to avoid threat to the environment. A typical engineered MSW landfill includes cover system and liner system which act as barriers between waste and environment. Evaluations of these components are essential to check its performance at local climatic conditions prior construction of landfills. In the presented study, a MSW landfill cover system was monitored 90 days during the monsoon season in an open field to estimate the head accumulated above the liner system. The studies conducted at laboratory scale were validated and simulated in HELP model for a period of five years. The accuracy of the model predictions by HELP model was found to be more than 94%. Therefore the HELP model, though a simple model was able to predict the results appropriately for Bangalore, India. Keywords: Cover system, HELP model, Landfill, Liner system, Municipal solid waste 45 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Solid Waste Management and Recycling in Igdir Argun Y.A. *1, Altikat A.2, Dogru S. 3 and Bayram T. 4 1, 3 Environmental Helath Programme, Vocational School of Health Services, Igdir University, TURKEY. (E-mail: [email protected], [email protected]) 2 4 Department of Civil Engineering, Engineering Faculty, Igdir University, TURKEY. (E-mail: [email protected]) Department of Environmental Engineering, Engineering Faculty, Yuzuncu Yil University, TURKEY. (E-mail: [email protected]) ABSTRACT Iğdır, was raised to the status of the province in 1992 by splitting up Kars, is a settlement of 190.409 people according to 2013 census and has four municipalities of the districts named Center, Aralık, Karakoyunlu and Tuzluca and four municipalities of the towns named Taşburun, Halfeli, Hoşhaber and Melekli. Because of the province experience and history limited as a local management, some problems have been encountered about the fulfillment of the responsibilities required of urbanization by understanding, planning and bureaucratic. Solid waste and recycling are the most important of the ongoing problems. It was given information about solid waste type and quantities of Iğdır, its districts and towns, existing storage methods and locations and landfill which was come into operation in 2013 and packaging waste collection separation facility that have been designed. Landfill is constructed and operated to solve problem about solid waste of Municipality of Iğdır, its four districts and its four towns and Iğdır Special Provincial Administration, Municipality of Doğubayazıt and Diyadin. Solid Waste Management Project made by these 10 municipalities and Iğdır Special Provincial Administration is a plant required for disposal and recycle complying with National Solid Waste Regulations and EU Directives. A project about collecting and recycling of packaging wastes has been presented and accepted to SERKA by Igdir province of Environmental Services Association. Area that planned as a garage in solid waste landfills has been transformed to Collecting and Separation of Packaging Wastes facility (TAT) within the project but could not operate due to the cancellation of the procurement. It has been assessed current status of the landfill, the problems about packaging waste collection and separation facilities, TAT facilities in terms of cost. Keywords: Igdir, Local management, Landfill, Recycling, Solid waste. 46 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Management of Solid Waste in the Sample of a Small Sized Turkish Town, Erzurum Bayram T. *1, Argun Y.A. 2, Altikat A. 3 and Dogru S. 4 1 2, 4 Department of Environmental Engineering, Engineering Faculty, Yuzuncu Yil University, TURKEY. (E-mail: [email protected]) Environmental Helath Programme, Vocational School of Health Services, Igdir University, TURKEY. (E-mail: [email protected], [email protected]) 3 Department of Civil Engineering, Engineering Faculty, Igdir University, TURKEY. (E-mail: [email protected]) ABSTRACT Rapid and consistent growth of human population has caused a considerable increase in the total amount of solid waste disposed to nature all over the world, which has turned out to be a great threat for public health and environment. Ever increasing threat of solid waste on humans and their environment forced nations to seek for efficient and suitable technologies and make effective regulations to eliminate this threat and control waste at least at its so urce. Until recently, solid wastes were disposed without considering possible consequences of disposal techniques in this process. Turkey is a country at the edge of accessing the European Union, therefore; it must regulate its legal frames conveniently with those of the Union in every sector and subject including environmental matters. The city of Erzurum is small sized and nearly unindustrialised city in the north -eastern part of Turkey, which suffers less from any type of pollution than the western part of the country; however among main environmental problems of which is solid waste. The aim of this study is to present a road map on legal basis for developing countries like Turkey considering and comparing the current legal frames for environment and giving an application example for the management of solid waste in a Turkish city. Keywords: Environmental laws, Environmental matter, Erzurum, Solid waste, Solid waste management. 47 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Industrial Waste – Red Mud as Catalyst for Hydro-Dealkylation Á. Rédey* 1, T. Juzsakova 2, T. Fráter 3, A. Csavdari 4, L. Ráduly 5 and I. Ráduly 6 1, 2 Institute of Environmental Engineering, University of Pannonia, Veszprém, HUNGARY. (E-mail: [email protected], [email protected]) 3 Introduction of the National Food Chain Safety Office (NFCSO), Pesticide Residue Analytical Laboratory, Velence, HUNGARY (E-mail: [email protected]) 4 Faculty of Chemistry and Chemical Engineering, University of Babes-Bolyai, Cluj-Napoca, ROMANIA (Email: [email protected]) 5,6 Faculty of Economics and Business Management, University of Babes-Bolyai, Cluj-Napoca, ROMANIA. (E-mail: [email protected]) ABSTRACT Red mud is a waste of the bauxite processing industry obtained during the alkaline extraction of alumina from bauxite ore. The worldwide aluminum production in large scale has generated huge amounts of red mud for decades. Red mud is a caustic material having pH=11-13. Thus its storage has potential threats to environment, to flora, fauna and human beings. Several suggestions/trials for the comprehensive utilization of the red mud were made such as recovery of metal components from the red mud, utilization as construction material. Unfortunately, these technologies have not been used in wide scale. The red mud is a mixture of metal oxides/metals such as Fe2O3, Al2O3, ZnO, MgO, Ni, Ga etc. which have catalytic feature. Therefore the red mud can be utilized as cheap catalyst as well. The aim of this work was to investigate the Hungarian red mud catalytic activity in hydro-dealkylation of toluene. The acidic treatments of red mud were applied in order to reduce its pH value. The toluene hydro-dealkylation reactions were carried out in batch reactor in the temperature range from 250 to 450°C. For all runs the starting hydrogen pressure of the reaction was 30 bar. The main products of reaction were cyclohexane in the liquid phase and methane in the gas phase. The conversion of toluene to cyclohexane was below 1-6 % up to 400°C and increased to 1520 % at 450°C depending on pretreatment of red mud. Influence of the acidic treatment of the red mud on the catalytic activity was studied and it was compared with earlier work on ethyl-benzene hydro-dealkylation where conversion was up to 58%. The specific surface areas of the samples were determined by BET method. The acidity of the samples was determined using the pulse chemisorption with ammonia as acid probe molecule. The catalytic activity of the red mud samples were correlated with their morphology and surface properties. Keywords: BET, Hydro-dealkylation, Toluene, Red mud as catalyst. 48 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 GIS application on disposal of Dredge Materials S. Dağlı*1, A.Dönertaş 2,H. M. Basar 3, İ.Yolcubal 4, E.Sangu5 , L. Tolun6 4,5 Department of Geology Engineering, Faculty of Engineering, Kocaeli University, TURKEY. (E-mail: [email protected]) 1,2,3,6 TUBITAK Marmara Research Center, Environment and Cleaner Production Institute, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Uncontrolled dumping of dredged material in coastal and marine areas had been a common practice for a long time in Turkey. However, some of the dredged material is contaminated to an extent that major environmental constraints need to be applied when developing management options. Considering the possible adverse environmental effects, contaminated sediments need to beneficially used or be disposed on land if it is categorized as hazardous waste. In other words, regulations ban dumping of these sediments if they behave as hazardous waste. Turkish Regulation on landfilling of wastes describe the technical requirements on landfill facilities such as distance to surface water, depth to the wa ter table, permeability, geological, geomorphologic and geotechnical conditions, natural risks (flood, landslide, avalanche, erosion and earthquake) etc. It is important to use GIS (Geographical Information Systems) software by sort of the criteria as precedence factors as a tool of multiple decision support system. This study illustrates the preliminary results of the selection of possible landfill sites placed at pilot locations at Black Sea, Marmara Sea, Aegean Sea and Mediterranean Sea of Turkey. The ma in parameters processed by GIS are as follows; regular-irregular storage location (distance-availability), the current-abandoned mine sites, geological structure of current storage sites, local hydrological - hydro geological systems, transportation infrastructure, land use, water basins and protected sites, existing local restrictions, current environmental territorial plans etc. The findings as an output of GIS were evaluated and selected sites were inspected on site respectively. All the sites were evalua ted according to Turkish Master Plan on Waste Management. Keywords:GIS, dredge materials, landfillingAcknowledgment: The work is a part of DİPTAR Project, financially supported by the Turkish Scientific and Technological Research Council (TUBITAK) 1007Programme [Project Number 111G036]. We specially acknowledge the Ministry of Environment and Urbanization, Ministry of Transport, Maritime Affairs and Communications and Highways 1 st Regional Directorate for their supports in the ports. The authors would like to thank, BarışGüzel,PembeErdoğan and RecepKarademirfor their helps in the field . 49 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Preventative Medicine for the Environment: Developing and Implementing Environmental Programs that Work Dr.Fulya Oztas Selçuk University, Vocational Health School, Campus, Konta e-mail:[email protected] ABSTRACT Hospitals are the largest sector that operating, continuously twenty-four hours per day. The medical waste products contribute to a wide variety of environmental and related health concerns. It is well known that the use and disposal of medical materials are threatening the availability of clean air, water, and ecosystems. Medical waste materials generate in hospitals are in tremendous variety and quantity which thus waste matters may represent real occupational and environmental health threats. Also hospitals are consistently within the top water users that their waste water products mostly contain toxic lab and cleaning chemicals and pharmaceutical compounds, many of which are not broken down in sewage treatment plants and are disposed of in landfills, result in sewage sludge applied to farmland, or are released in rivers and streams. In the past it has been largely ignored by the environmental regulators. However, it has been known that medical wastes was the largest source of dioxin emissions, The hospital waste contamination sourced by the way may cause the acid rain and heavy metal particulate emissions mostly cause to asthma and other health problems. In this study we intend to work out how hospital managing their hazardous chemicals identifies and disposing of them properly? The goal of this paper is also to suggest steps in moving from the theoretical aspects of why hospital facilities should adopt acceptable environmental principles and to how to do it. Key words: Hospital waste, environment, education, medical waste 50 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A PROPOSED DESIGNED OF COMPOST PILE FACILITY IN BATANGAS STATE UNIVERSITY MAIN CAMPUS I Joeylyn A. Almarez1, Sarah Jane R. Driz*2 and Roxette Joy I. Jumangito3 Civil and Environmental and Sanitary Engineering Department, Batangas State University, Philippines. ( [email protected], [email protected]) Civil and Environmental and Sanitary Engineering Department, Batangas State University, Philippines. ([email protected]) ABSTRACT The compost pile facility is designed to accommodate compostable wastes to be converted into compost as fertilizer. This facility has significant positive impact to the environment, benefits to the management such as hygienic surrounding and income generation for sold fertilizer. The study focused on the design of the compost pile facility in Batangas State University Main Campus I, including the calculation of the compostable waste, preparation of the facility layout plans, detailed drawings of the compost pile structures, and detailed estimate of the total project. Project management plan for the implementation of the proposed design and construction were presented in the study. Quantitive method was used in the data collection that developed the questions and hypothetis distinctively. The average daily generation of compostable wastes collected during one week in the summer was 265.5 kg. The total volume generation in a week was 1547.5 kg. With this, there would be 90 percent of compostable wastes that can be turned into compost as a fertilizer. From the bill of materials and cost estimation of the compost pile facility, the cost of construction of the facility is sustainable due to availability of the fund from the Environmental Management Unit, and cost-effective due to standard materials available at mínimum cost. The Environmental Management Plan for the operation and maintenance of the compost pile facility with five elements that induces positive impact to the environment, health and property. Keywords: Compostable, Fertilizer, Pile, Structure, Waste 51 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Recycling Ways of Waste Bread Crumbs Selçuk Mustafa SEÇEN * 1 and Kamil Emre GERÇEKASLAN 1,2 2 Nevşehir Nevşehir Hacıbektaş Veli University, Faculty of Engineering and Architecture, Department of Food Engineering, Nevşehir/TURKEY (e-mail: [email protected], [email protected]) ABSTRACT Bread is the most basic foodstuffs of people from all walks. Bread production technology is simple and cheap, and bread can be stored easily, it plays an important role in daily nourishment consumption. However, there is considerable amount of bread loss and waste in our country. The bread waste is the difference between production and consumption amount of bread and this waste leads to an ineffective use of resources of the country. Approximately 6% of the bread produced in our country’s is wasted. We can approach to this matter from two aspects. Firstly, there are too many bakeries and their capacities are higher than those needed in big villages, and because of competition, bread production is beyond the consumption. Secondly, consumers are buying bread more than their need. Improvements can be considered important were achieved as a result of s ustained campaigns about daily bread waste since the beginning of 2013. In 2012, 5.9% of the daily bread production was being wasted; in 2013, this rate has dropped to 5.4%. Therefore, more than 1 million daily bread has been saving and the total amount of waste has been reduced from 5.9 million to about 4.9 million units. According to the researches, the stale bread has had many ways of using it again. Foremost, in order to make bread fresh, water is sprinkled on them and put in the oven wrapped in foil t o heat or convert to completely dried bread flour by drying them. One of the largest customers of stale bread are the feed mills. Another way to recycle the stale bread is drying sliced bread and using it as bread -shaped pizza base. Keywords: Bread, economic loss, staling, recycling. 52 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 CHARACTERIZATION OF WASTEWATERS FROM ESKİŞEHİR STATE HOSPITAL Pınar GÜLTEKİN* Technology and Production Command, Department of Quality Assurance, 1. Air Supply and Maintenance Center Command, Eskişehir, Turkey ([email protected]) ABSTRACT Medicines for diagnostic and therapeutic purposes are used on patients both in hospitals and at homes after prescribed by doctors. While some of the medical substances are used with metabolisms, some of them excreted by the patients after administration and therefore reach the municipal sewage and wastewater treatment plants with the excretion. If they are not biodegraded or eliminated in the wastewater treatment plants, they are emitted into surface water and finally they may reach drinking water. Hospital wastewaters include wastewaters having household characteristics and wastewaters coming from different departments such as services, laboratories, morgue, blood bank and laundry. Waters from each department have a high concentration of contamination but they seem to be dissolved in the waters having household characteristics. In this project, the wastewaters from Eskişehir State Hospital were analyzed to define their characteristics. Therefore, chemical and bacteriological analyses were done. Furthermore, anion and cation analyses of the hospital wastewaters were also performed. According to the results of these analyses, the wastewater of the hospital was found to be very contaminated. Key words: Eskişehir, hospital, wastewaters. 53 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Key Environmental Challenge of Seawater Desalination Farzin Saffarimiandoab* 1, Ismail Koyuncu 1 and Hanna Kilzer 2 1 Environmental Engineering Department, Istanbul Technical University, Turkey. (E-mail: [email protected], [email protected]) 2 Mechanical Engineering, RWTH Aachen University, Germany. (E-mail: [email protected]) ABSTRACT Earth as a water rich planet contains 71% water. Freshwater makes only 3.5% of this abundant water resource and occurs in glaciers, ground waters, rivers and lakes; on the other hand, rapid growth of population, industrial, agricultural activities, and diminishing fresh water resources make it necessary to provide alternative water resource. Desalination of sea water as alternative way becomes prevalent chiefly in arid countries. Desalination plants generate highly saline byproduct as well as chemicals from pre-treatment and post-treatment side-streams which dumped back into the ocean. This discharge has unavoidable potential of adverse effect on marine environment and life, so in order to debarment any negative chronic and acute effect on aquatic life and environment, discharge has to be managed and disposed in sustainable way. In this paper, composition and characteristics of byproducts as well as their potential impacts on marine environment and life were studied. Concentration management, disposal options based on regulatory organization limits beside their advantages and drawbacks were investigated in order to evaluate these methods from cost profitability and effectiveness perspectives. Keywords: Seawater desalination, concentrate management, disposal methods, environmental effects. 54 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Identification of a Potential Isolate for Degradation of Sodium Dodecyl Sulfate in Wastewater Systems H. Ulusoy* 1, F. Yilmaz 2, A. Ergene 3 and B. Icgen4 1,3 2,4 Department of Biology, Kırıkkale University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Sodium dodecyl sulfate (SDS) is one of the most widely used anionic detergent in households and industry. It is mostly discharged in large quantities into the water bodies like lakes and rivers. The toxicity of SDS to the health and survival of aquatic organisms in these water bodies is well-documented. Therefore, the bacteria efficient in SDS degradation are of great importance due to their potential in the biological removal of these anionic detergents from the contaminated waters. Current study aimed at isolating and identifying SDS degrading bacteria from the detergent contaminated river water. Initial selection of SDS degraders from the collected water samples was done by the use of enrichment culture technique with a minimal medium containing 1% SDS as a sole source of carbon. After enrichment method, the efficient isolates were determined by using maximum tolerable SDS concentration and degradation capabilities of the isolates selected. Out of four, one SDS degrading isolate showed significantly (p<0.05) high SDS degradation capability with 88% after two days incubation. This isolate was identified as Pseudomonas fluorescens through phylogenetic analysis of 16S rRNA gene. The results indicated that P. fluorescens might be a potential isolates for the treatment of SDS-contaminated wastewaters. Keywords: Anionic detergents, SDS-contamination, SDS degraders Acknowledgment: The authors would like to thank Middle East Technical University Research Fund Project for their financial support. 55 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Isolation of Bacteria Efficient in the Removal of Anionic Detergents S. B. Salik* 1, F. Yilmaz 2, A. Ergene 3 and B. Icgen4 1,3 Department of Biology, Kırıkkale University, TURKEY (E-mail:[email protected], [email protected]) 2,4 Department of Environmental Engineering, Middle East Technical University, TURKEY (E-mail:[email protected], [email protected]) ABSTRACT The anionic detergents remain chemically unchanged during the washing process and they are discharged down the drain with the dirty wash water. In the vast majority of cases, the drain is connected to a sewer and ultimately to a wastewater treatment plant; where the detergents present in the sewage can be removed by biological and physical-chemical processes. Sodium dodecyl sulfate (SDS) is one of the anionic detergents with high industrial usage. Therefore, its biodegradation by potential microorganisms has taken greater attention for the biological processes. In this study, out of fifty, four SDS-degrading bacteria designated as SDS4, SDS7, SDS10-2, and SDS10-3 were isolated from SDS-contaminated surface waters and searched for their ability to degrade SDS. The isolates exhibited optimum growth at an SDS concentration of 1 g/L, but tolerated up to 55-75 g/L SDS. The isolates were identified by 16S rRNA sequence analysis as Pseudomanas corrugate, P. resinovorans, Aeromonas veronii, and P. koreensis with SDS degrading abilities of 52, 55, 74 and 87%, respectively. Preliminary experiments showed that four isolates obtained in this study were strong gratuitous degraders of SDS. However, their relative importance in soil, sewage, and wastewater treatment plants remains to be assessed. Keywords: Anionic detergents, SDS-degrading bacteria, surface waters Acknowledgment: The authors would like to thank Middle East Technical University Research Fund Project for their financial support. 56 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Potential of Pseudomonas Species for the Treatment of Heavily Detergent-Polluted Waters L. Goksu* 1, F. Yilmaz 2, A. Ergene 3 and B. Icgen4 1,3 2,4 Department of Biology , Kırıkkale University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering , Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Detergents, originating from domestic-industrial discharges, reach to the aquatic environments, accumulate and cause negative effects on the aquatic life. Due to their high foaming capabilities, they also cause serious problems in wastewater treatment plants. Efficient biological treatment of detergent-contaminated waters at the wastewater treatment plants help decreasing these problems. Thus, isolation and identification of bacteria efficient in the biological treatment of detergent like sodiım dodecyl sulfate are a big challenge. In this study, detergent-degrading bacteria were screened for their efficiency in the detergent-polluted waters. Detergent degradation ability of the screened isolates was varied in between 88-94%. These isolates were found to be the species of Pseudomonas after 16S rRNA sequence analysis. The distance matrix generated highlighted the distances among the sequences aligned. These distances were used for the phylogenetic analysis at species level. The 16S rRNA gene sequences were deposited to GenBank using Bank It submission tool. Based on the phylogenetic analysis, the isolates were identified as P. migulae, P. kilonensis, P. koreensis and P. baetica. The result revealed that Pseudomonas species could be the potential candidates to decrease the problems in wastewater treatment plants under the pressure of detergent-contaminated waters. Keywords: SDS pollution, SDS treatment, wastewater treatment plants Acknowledgment: The authors would like to thank Middle East Technical University Research Fund Project for their financial support. 57 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Halonitromethanes formation in Drinking Water: Occurrence and Precursors Sebnem GENISOGLU* 1, Zehra OZTURK 1, B. İlker HARMAN 1, S. Sule KAPLAN BEKAROGLU 1 1, Department of Enviromental Engineering, Suleyman Demirel University (E-mail: [email protected], [email protected], [email protected], [email protected],) ABSTRACT Drinking water disinfection by-products (DBPs) result from the reaction of disinfectants, such as chlorine or chloramines, with natural organic matter (NOM) and/or bromide/iodide present in drinking water supplies. Over the last 30 years, significant amount of research efforts have been directed towards improving our understanding of DBPs, and to date it is estimated that 600–700 DBPs have been reported from the use of chlorine, ozone, chlorine dioxide and chloramines. Characteristic functional group is nitrogen for nitrogenous DBPs (N -DBPs) such as haloacetonitriles (HANs), cyanogen halides (CH), and halonitromethanes (HNMs). Among these N-DBPs, HNMs received special attention because of their potential hightoxicity and their occurrence in finished waters at some treatment facilities. There are a total of 9 species of chorine and bromine substituted HNMs including chloro-(CNM), dichloro- (DCNM), trichloro- (TCNM), bromo(BNM), dibromo- (DBNM), tribromo-(TBNM), bromochloro- (BCNM), bromodichloro-(BDCNM), and dibromochloronitromethane (DBCNM). The concentrations of N-DBPs are generally at a lower level (ng/L to μg/L) than those of carbonaceous-DBPs, but are more toxic. The recent toxicology studies conducted on emerging DBPs showed that HNMs are one of the most cyto- and genotoxic classes among the emerging DBPs, having orders of magnitude higher toxicity than trihalomethanes (THMs) and haloacetic acids (HAAs). Especially brominated halonitromethanes (HNM) is expected to be regulated by U.S. Environmental Protection Agency (USEPA). For the sum of HNMs, median and maximum levels of 1 and 10 µg/L were recorded during the 2000-2002 US survey. Chloropicrin is the most frequently reported HNM and was quantified at 0.2–0.5 µg/L in the US 2000–2002 and 2006–2007 surveys, respectively. Recent studies showed that dissolved organic nitrogen (DON) that could be a source of precursors for nitrogenous DBPs such as HNMs. Laboratory FP tests showing that various disinfection protocols produced HNMs in the following order: ozonation −chlorination ˃˃ ozonation − chloramination > chlorination > chloramination. Ozonation before chlorination can dramatically enhance HNM formation. Meanwhile, UV and ozone disinfection of the same effluents formed insignificant levels of HNMs. This paper aims to review the state of research on HNM formation in drinking water including with their types and occurence, possible health effects and precursors. up to date information on HNMs in drinking water available in the literatures have been reviewed in this paper. Keywords:, Disinfection, Disinfection by products (DBPs), Drinking Water, Halonitromethanes (HNMs), Toxicity. 58 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Chlorine Dosing Management Strategies for Water Utilities Using GIS, SCADA and Modelling Tools: Case Study of Yeşilbayir-Antalya Tuğba AKDENİZ 1 & Habib MUHAMMETOĞLU 2 (1) Antalya Metropolitan Municipality, Antalya Water and Waste Water Authority (ASAT), Antalya, Türkiye (E-mail: [email protected]) (2)Dept. of Env. Engineering, Akdeniz University, Antalya, Türkiye. (E-mail: [email protected]) ABSTRACT Antalya City is one of the most preferred touristic destinations of Turkey. Antalya Water and Wastewater Administration (ASAT) of Antalya Metropolitan Municipality is responsible to provide water and wastewater services all over Antalya Province. Municipal water demand of Antalya city is supplied from Duraliler, Gürkavak, Boğaçay and Termessos groundwater resources. Termossos drinking water distribution network (WDN) consists of three sub-zones namely Yeşilbayır, Odabaşı-Kirişçiler and Duacı. In 2005, SCADA system was put into use by ASAT to monitor water distribution networks in Antalya City. ASAT SCADA System, that cost approximately 4 million Euros, provides online surveillance of water quality and hydraulics in many monitoring stations throughout the current WDN. The system comprises 9 pumping stations, 17 reservoirs and several groundwater wells. SCADA Stations collect continuous on-line data on energy consumption of pumps, flow rate, pressure, and many water quality parameters including chlorine concentration in WDN in order to increase the system efficiency. The aim of the current study is to emphasize the importance of SCADA, GIS and modelling tools for water quality management. For this purpose, EPANET hydraulic and water quality model has been applied to a certain section of Antalya drinking WDN. The study was carried out on Yeşilbayır sub-zone of Termessos WDN using data obtained from SCADA and GIS. The model calibration and verification were carried out using both on-site manual and online measurements of water pressures and free residual chlorine concentrations. Comparison of modelling results to field measurements in the study area of Yeşilbayır showed that model predictions agrees with field measurements. The average prediction errors of water pressures, chlorine concentrations and flow rates were 0.16 bar, 0.06 mg L-1 and 1m3 h-1, respectively. It was possible to determine the required suitable chlorine dosage at the chlorine feeding station and chlorine concentrations throughout the WDN using the SCADA, GIS and modeling tools. Based on this study, the developed system can be defined as a useful tool for local authorities, planners and decision makers for similar applications in other regions. Keywords: Chlorine, Drinking Water Distrubition Network, GIS, Modelling, SCADA. Acknowledgment: The authors thank Akdeniz University, Scientific Research Project Funding for their financial support, ASAT and Antalya Metropolitan Municipality. 59 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Influence of characteristic of butterfly valve closing on water hammer run. Apoloniusz Kodura Warsaw University of Technology, Environmental Engineering Faculty, POLAND. (E-mail: [email protected] ABSTRACT Water hammer is the most common example of transient flow in pressure pipelines. During this phenomenon, transformation of kinetic energy to pressure energy makes significant changes of pressure, which can lead to significant problems in management of pressure networks. The phenomenon is very complex and a large number of different components has influence on its run. In the case of water hammer determined by valve closing, the characteristic of gate operating is one of very important issues. However, this factor is rarely investigated. In this paper, the results of physical experiments of water hammer run in steel and PE pipelines were described and analyzed. For each water hammer run, characteristic of pressure change and butterfly valve closing were stored. The results were compared with calculations by using common methods, applied by engineers - Michaud's and Wood and Jones. As the result, very significant differences between calculations and results of experiments were observed. In addition, characteristic of butterfly valve closing has significant influence on water hammer run, what should be taken under consideration by analyzing the phenomenon. The analysis of comparison of experiments with theoretical methods of calculations leads to indicating the necessity of improving methods of calculations and ways of searching for new solutions. Keywords: butterfly valve, pressure characteristic, transient flow, water hammer. 60 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Utilization Chitosan As A Color Absorbent On Textile Industry Liquid Waste Hamasyah Hamzah Mumtaza* 1 1 Department of Aquatic Product Technology, Bogor Agricultural University, INDONESIA (E-mail: [email protected]) ABSTRACT Textile industry is one of the major industries in Indonesia. The industry produces a lot of waste as a result of looking side. Liquid waste generated in the form of color components that will pollute the environment.Textile industry is one of the producers of wastewater from dying processes which have a high pigment content. If this Textile wastewater flowed directly into the aquatic environment without any prior management of the environment will degrade the quality of these waters. a wide variety of aquatic environments polluted by color components generated from textile iindustri. This study was expected to reduce the adverse effects of wastewater from textile industry. Textile wastewater treatment may be done using chitosan as absorbent material. Chitosan can be used as an absorbent in Textile wastewater treatment industry. The research was conducted using the method of deposition and fluidation. The success of this study was to analyze the water quality, including measurement of levels of color substance use chromameter, pH value and turbidity measurement use a multimeter, DO and BOD measurement use DO-meter and measurement of metal content use Atomic Absorbent Spectrophotometry (AAS). Study the effectiveness of the use of chitosan as an absorbent material in the Textile wastewater by the method of deposition and fluidation performed with various concentrations of chitosan, namely 1.5 ppm, 15 ppm, 150 ppm and 1500 ppm. pH value result is between 8.07 to 8.43. Turbidity value result is between 0 to 14.8 NTU. Brightness value result is between 53.14 to 74.86. DO value result is between 4.10 to 6.03. BOD value result is between 1.93 to 4.4 Textile mg / l. COD value result is between 700-1000 mg / l. The results of the analysis of metal content of Textile wastewater shows that wastewater Textile are still in a safe condition for its metal content is less than the standard. Keywords: Textile, chitosan, wastewater, BOD, COD. Acknowledgment: The authors thank Bogor Agricultural University 61 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biosorption of Commercial Yellow 2G and Indigo Textile Dyes by Powder Hawaiian Spirulina pacifica Gamze Dogdu* 1, Arda Yalcuk2 Department of Environmental Engineering, Abant Izzet Baysal University, Faculty of Engineering and Architecture, Gölköy Campus-Bolu, Turkey (E-mail: [email protected], [email protected]) 1,2 ABSTRACT Approximately 10,000 different dyes and pigments are used industrially and over 7x tons are produced annually worldwide. Two out of three of these dyes are azo dyes. Considerable amount of dyestuff that are used in textile industry are discharged to natural environment after production and it leads to many hazards about environment and people health. As a result of the degredation of many azo dyes produce aromatic amines that are carcinogenic. Hence, dyestuffs in textile wastewaters must be removed before discharge to the environment. Pollution causing these dyestuffs is possible to reduce with biological methods. Today, biosorption process is very popular due to its efficiency and cost. Low-cost and effective biomaterials used for dyes removal from wastewater have been of great concerns for environmental scientists. Until now, new, economical, locally available and highly effective dye biosorbents are still under development and using certain low-cost biosorbents for dye removal has been extensively reviewed. On the basis of this concern, the objective of our study is biosorption of commercial Yellow 2G and Indigo dyes using of new, commercially available, low cost as regards to production processes and completely ecological powder Hawaiian Spirulina pacifica biosorbent. For these dyes, biosorption potential of powder Hawaiian Spirulina pacifica investigated variation in parameters of pH, agitation time, initial dye concentration, adsorbent concentration, contact time and temperature to estimate equilibrium conditions at batch mode within 120 minutes. Optimum conditions were found as 100 rpm, 60 min pH 2, 25 °C, 100 ppm dye concentration, 3 g/L adsorbent concentration for Indigo and 150 rpm, 10 min, pH 2, 25 The equilibrium biosorption data were analyzed by Langmuir and Freundlich isotherm models. Equilibrium data fitted well to the Freundlich isotherm model for commercial Yellow 2G and Indigo dyes. Moreover, adsorption of dyes on the cell surface was proved by SEM (scanning electron microscope) of biomass before and after of dye loading. Keywords: Biosorption, Commercial Hawaiian Spirulina pacifica, Dyestuff, Indigo, Yellow 2G. Acknowledgment: The authors thank Abant İzzet Baysal University, Scientific Research Project Funding (İBU BAP) for their financial support [Project number: 2013.09.04.677]. 62 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Efficiency of UV and UVH 2O 2 Processes for Amoxicillin Treatment Şifa DOĞAN* 1, Rana KIDAK 2 1, 2 Environmental Engineering Department, Cyprus International University, Nicosia, North Cyprus. (E-mail: [email protected], [email protected]) ABSTRACT Advanced Oxidation Processes (AOPs) are the powerful oxidation techniques to apply in such conditions where conventional treatment processes are inefficient to treat organic pollutants such as pharmaceuticals. Nowadays, pharmaceutical compounds are concerned to cause various adverse effects on living organisms including, development of resistant microorganisms to pharmaceutical compounds in ecosystems and endocrine disruptive effects. UV and UV/H 2O2 techniques are the mostly applied advanced oxidation technologies in large scale treatment plants therefore; investigation of the elimination of these “newly discovered compounds” is a serious task to provide complete treatment of wastewaters. In this study removal efficiency, byproduct profile, mineralization and toxicity of the model compound, amoxicillin, were discussed and compared for the UV and UV/H 2O2 techniques. The UV dose has been calculated by chemical actinometry and it was found as 2.3 W.m-2. Three different concentration of H2O2 (2.85, 5.70 and 17.03 mM) was used to find the optimum dose. The maximum removal was recorded as 27 % (UV) and 43 % (UV/H2O2) amoxicillin after the optimum residence time (25.6 minutes). Carbon mineralization was measured as COD in mg O2.L-1 and found as 14 % after UV and 30 % after UV/H 2O2 processes. Sixteen byproducts were identified after UV treatment and eight products were observed after UV/H2O2. Phenol, aminophenol, pyridine, benzene, aliphatic and heterocyclic organic compounds have been formed after UV based treatment of amoxicillin. UVH2O2 treatment showed different aliphatic and heterocyclic structures. Generally treated effluents showed toxic nature (EC50% < 15) for each process. For total elimination more reaction time was needed such as 150 minutes (UV/H2O2) and 270 minutes (UV). Further investigations should be done to reduce toxicity. This might be achieved by using more UV lamps in a reactor or increasing the total reaction time to cause more elimination. Keywords: Amoxicillin, UV, UV/H2O2, removal, toxicity. Acknowledgment: Cyprus International University, Instrumental Analysis Laboratory. 63 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Ceramic Membrane Applications in Industrial Wastewater Treatment Mesut GENISOGLU* 1, Hasan KOSEOGLU 2 and Bilgehan Ilker HARMAN 3 1, 2, 3 Department of Environmental Engineering, Suleyman Demirel University (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Industrial pollution is a major threat on aqueous environment. Specific treatment necessity of industrial wastewaters is another challenge for treatment plant operators and decision makers. The concern to control the environmental impact lead to the European Directive 2008/1/EC on integrated pollution prevention and pollution control (IPPC), which sets out measures to prevent or reduce emissions of defined industrial activities. It is essential to select appropriate techniques, especially when an operating company is functioning in an environmentally sensitive area. The character of industrial wastewater depends on the type of industry. Some industrial wastewaters may contain toxic substances or high percentages of organic materials or solids which make treatment difficult via conventional treatment processes. Membrane filtration is a powerful alternative for the treatment of industrial effluents. Both organic and inorganic membranes have been applied for the treatment of industrial effluents; however, ceramic membranes offer several advantages over polymeric ones such as superior thermal, chemical, mechanical stabilities and long lifetime. They work well within a pH range of 1 to 14 and can be operated at temperatures as high as 500 °C. They can also operate under high pressure differentials. These characteristics make them particularly appropriate for the treatment of industrial effluents. Nevertheless, ceramic membranes are substantially more expensive though this may be compensated by higher fluxes and extended lifetime. Moreover, the cost of cera mic membranes has been continuously reduced during the last years. As a result, several authors have proven the feasibility of bringing this technology to the industrial wastewater management systems. In this context, the application of ceramic membranes has been proposed as a promising technology for treatment of industrial wastewater. In this paper; innovative technologies in ceramic membranes and success stories in industrial wastewater treatment have been discussed in detail. Keywords: Ceramic Membrane, Heavy Metal, Industrial Wastewater, Separation 64 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EVALUATION OF THE DISPERSIVE COMPONENT OF THE SURFACE ENERGY OF ALPILLARED SEPIOLITE AND AL-PILLARED MONTMORILLONITE AS DETERMINED BY INVERSE GAS CHROMATOGRAPHY Ceyda Bilgiç*, Naile Karakehya+ * Department of Chemical Engineering, Faculty of Engineering and Architecture, Eskişehir Osmangazi University, 26480 Eskişehir, Turkey [email protected] + Environmental Control and Protection Programme, Eskişehir Vocational School, Eskişehir Osmangazi University, 26480 Eskişehir, Turkey [email protected] ABSTRACT Inverse gas chromatography (IGC) is a derivation of conventional gas chromatography but, unlike analytical chromatography, the material being evaluated is in the stationary phase in the gas chromatography column. The retention volume of mobile phase (probe) indicates the interaction between the probe and the surface of the material in the column. IGC provides an excellent method to measure the surface energy of rough and porous powders [1,2]. According to the IUPAC definition of pillared clays (enlarged to pillared layered solids): pillaring is a process by which a layered compound is transformed in a thermally stable micro- and/or mesoporous material with retention of the layer structure [3]. Pillared clays are a new class of materials, in which large surface and pore volumes can be obtained according to the type of pillars [4]. These solids have enormous potential for application in adsorption and catalytic processes [5]. In this study, two kinds of pillared clays were investigated. Al-pillared sepiolite was prepared from meerschaum processing wastes and Al-pillared montmorillonite was purchased from commercial supplier. Pillared clays were characterized by Fourier transform infrared (FTIR) spectroscopy and IGC. For IGC studies, retention time of n-hexane, n-heptane, n-octane and n-nonane were measured at infinite dilution conditions, between 300 and 330 °C. Dispersive component of the surface energy of pillared clays were calculated. The dispersive component of the surface free energy for the Al-pillared montmorillonite was higher than the Al-pillared sepiolite. FTIR spectra of Al-pillared sepiolite and Al-pillared montmorillonite were compared. Keywords: Sepiolite; Montmorillonite; Pillared-clay; Inverse gas chromatography; Waste utilization 65 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Occurrence of illicit drugs and pharmaceuticals in municipal wastewater and possibilities for their removal I. Bodík* 1, T. Mackuľak2, M. Fáberová 3 and M. Mosný 4 1, 2,3,4 Department of Environmental Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, SLOVAKIA. (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT The aim of this study was to analyse illicit drugs and pharmaceuticals and their metabolites in wastewater from Slovak wastewater treatment plants. Urinary bio -markers of Methamphetamine (pervitine), Cocaine, Cannabis (marihuana) and Ecstasy use were analysed by LC-MS/MS. More than 300 wastewater samples from all larger Slovak towns were analysed between March 2013 and November 2014. Based on the concentrations of drugs in wastewater and the corresponding d aily flow rate of wastewater in the treatment plant, daily quantities of drugs in wastewater were obtained. These values were specifically related to 1000 inhabitants of the city connected to the WWTP. The information thus obtained represents the specific presence of the drug in relation to the population on a given day (mg/day/1000 inhabitants). Thus obtained drug consumption values can be compared with the results achieved by other researchers. It was found that Methamphetamine and Cannabis have a relatively constant consumption rate during the week, and only a slight increase was observed over the weekend. Ecstasy is used mainly during the weekend in Bratislava (9 mg/day/1000 inhabitants) and in Petržalka (8 mg/day/1000 inhabitants). In large cities, the loads of Ecstasy during weekends were doubled or even quadrupled (Bratislava on Wednesday - 2 mg/day/1000 inhabitants, Sunday - 9 mg/day/1000 inhabitants), this was not observed in Piešťany. Important part of presented study was also to define the removal efficiency of target illicit drugs and pharmaceuticals on treatment processes on WWTPs. Some of analysed drugs are removed under very low removal efficiency, on the other hands, some of drugs are successfully removed from wastewater. Keywords: illicit drugs, pharmaceuticals, removal processes, Slovak WWTPs, wastewater. Acknowledgment: This work was supported by the Slovak Research and Development Agency under the contract No. APVV-0122-12 66 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Clean Technology For Tanneries Unhairing Waste Waters : Neutralization By CO2 , Water Recycling And Free Amino Acids Recovery Sabrina.TAMERSIT*1 ,Kamel-eddine.BOUHIDEL2, 1,2 Laboratory of Chemistry & Environmental Chemistry LCCE , Team : Water Chemistry , Environment & Desalination . Faculty of Sciences , University Hadj Lakhdar Batna 05000 Batna Algeria ([email protected], [email protected]) ABSTRACT This research work proposes a clean technology application for CO 2 direct capture . This gas is used to neutralize unhairing alkaline waste waters , effluent of the tanning industry . Contrarily to the nowadays expensive capture technologies , the present application has given excellent economical and environmental experimental results : The treated waste waters are totally recyclable : The pH ( from 13 to 4.5 ) , conductivity ( from 8000 to 2000 μS ) and COD ( 20000-80000 to 3000 mg O2/l ) , are drastically reduced . The injected CO2 has permitted to precipitate selectively CaCO3 , then different proteins according to their pKa ; These precipitated proteins are an excellent bioressource ( agriculture , …) . The neutralization by CO2 permits a smooth pH decrease ; The treated water contains free valuable and recoverable identified collagen amino acids ; Briefly , It is really a clean technology : Water economy , polluting by products (COD) recovery and environment protection . This original applied study is completed by a deep theoretical chemical study : optimal pH of CaCO3 precipitation , sulphide and calcium speciation ( evolution , complex formation with proteins , …) , neutralization curves study ( comparison of CO2 , HCl and H2SO4, …) , free amino acids identification and CO2 consumption … This laboratory pilot scale study has used synthetic CO2 and , both , synthetic and industrial waste waters from an industrial large plant . Keywords: Amino acids, COD, tanning industry, CO2 neutralisation 67 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Isolation of Efficient Diesel Oil Degraders Harbouring alkb and C23O Genes G. Onur* 1, F.Yilmaz 2 and B. Icgen 3 1,2,3 Middle East Technical University, Department of Environmental Engineering, TURKEY (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Hydrocarbon contamination can be as a result of various sources such as; accidents during fuel transportation by trucks and ships; leaking of oil from underground storage tanks, extraction and processing oil. Interests about the possibility of water and soil contamination by oil and oil byproducts gains importance since they are one of the major pollutants in the environment. Petroleum hydrocarbon polluted areas can be treated through physical, chemical and biological methods. During cleaning up, microbial degradation processes aid the elimination of spilled oil from the environment after critical removal of large amounts of the oil by different physical and chemical methods. Therefore, this study aimed at isolating bacteria from diesel oil contaminated surface waters and measuring their degradation ability to use in the remediation processes. The catabolic genes and enzymes responsible for diesel oil degradation were also investigated in the bacteria. Presence of the enzymes alkane monooxygenase encoded by alkb and catechol 2, 3- dioxygenase encoded by C23O were confirmed in the bacteria isolated. 61-92% diesel oil degradation by two bacteria harbouring both alkb and C23O genes was determined through gas choromatographic analysis. Key words: Diesel oil, alkb, C23O, alkane monooxygenase, catechol 2, 3- dioxygenase Acknowledgment: The authors would like to thank Middle East Technical University Research Fund Project for their financial support and Petroleum and Natural Gas Engineering Department of Middle East Technical University for their helps in gas chromatographic analyses. 68 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of some pharmaceuticals on the production of biogas at anaerobic digestion process M. Fáberová* 1, L. Ivanová2, I. Bodík3, and T. Mackuľak4 1, 2,3,4 Department of Environmental Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, SLOVAKIA. (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Many of the current pharmaceuticals are not completely removed by the natural decomposition, or they are resistant to degradation at all. This means that they are ever-present in the water sources and the land areas. Their biodegradation may take months, particularly in anaerobic conditions. The aim of this study was to determine the biodegradability of selected pharmaceuticals (diclofenac, tramadol, ibuprofen, carbamazepine and amoxicillin) in the waste water in the process of mesophilic (37oC) and thermophilic (55oC) anaerobic fermentation and monitoring of their inhibitory effect. The pharmaceuticals concentration in the tested sludge was 10 mg / l and 500 mg / l, respectively. The results have shown that the pharmaceuticals have an influence on the amount of biogas produced in the case of the same therapeutic group. Higher temperatures in the thermophilic reactor caused a reduction in production of biogas compared to mesophilic process. Keywords: pharmaceuticals, wastewater, anaerobic biodegradation, biogas production Acknowledgment: This work was supported by the Slovak Research and Development Agency under the contract No. APVV-0122-12 69 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Study on the Sorption-Desorption-Recovery Performance of Ion Exchange Resin for Removing Phosphate From Aqueous Solutions T. E. Köse*, B. Kıvanç Chemical Engineering, Eskişehir Osmangazi University, TURKEY. (E-mail: [email protected], bkivanc@[email protected]) ABSTRACT Phosphate anions concentration exceeding about 2 µM in water reservoirs can negatively impact aquatic ecosystems and human health. Therefore, extra phosphate in water should be removed with an appropriate method. To obtain low phosphate concentration, advanced treatment methods such as adsorption and ion exchange must be used. In this study, phosphate removal from aqueous solutions was examined using Lewatit Monoplus M600 anion exchange resin. The sorption behaviour of resin was investigated as a function of contact-time and temperature, resin dosage, initial phosphate concentration of solution, initial pH of the solution and effect of the other ions. The maximum sorption (99%) value for phosphate from 100 mg/L phosphate solution was observed at pH 10 and 25 oC for 3 hours. Poor effect of sulfate, nitrate and ammonium ions on phosphate removal was observed. Desorption (with NaOH or NaCl) and recovery (with CaO) of phosphate studies were carried out. The ion exchange mechanism was determined as the Ash Layer Control according to Unreacted Core Model and the Particular Diffusion Control according to Infinite Solution Volume Model. In the isotherm studies, the Langmuir, Freundlich and Dubinin–Radushkevich (DR) isotherm models were applied. The results indicate that Freundlich equation is well described with the phosphate sorption. The thermodynamic parameters such as ΔG◦, ΔH◦ and ΔS◦ were calculated to estimate the nature of sorption. Keywords: Ion exchange, Isotherm, Kinetic model, Lewatit Monoplus M600, Phosphate 70 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Flow Reactor Model for UV Treatment of Amoxicillin Rana KIDAK* 1, Şifa DOĞAN 1 1, Environmental Engineering Department, Cyprus International University, Nicosia, North Cyprus. (E-mail: [email protected], [email protected]) ABSTRACT Based on the worldwide surveys, antibiotics are reported to be the mostl y used pharmaceutical compounds. This extreme consumption and production of the drug pose great threat for the safety of drinking and consumable water standards. Researchers have been marked pharmaceutical compounds as an endocrine disruptive due to their adverse effects may cause disorder in common functio ns of endocrine systems in living organisms. Several studies including European Union projects selected “Advanced Oxidation Techniques” to be the best option to treat pharmaceutical compounds because they are not easily biodegradable and they are mostly high soluble in water matrices which provides their escape in conventional treatment facilities without being decomposed. In this study UV treatment process was experimented to remove 25mg.L -1 model antibiotic compound, amoxicillin, from aqueous media. A cylindrical flow reactor was used to carry out the UV process. UV lamp and the quartz protection glass were place in the middle of the reactor. The dimensions of the cylindrical flow reactor were as follows: 3.55 cm radius, 33 cm length, 550 cm 2 surface area of irradiation, 1.75 cm radius of the quartz tube, and the path length was 1.8 cm. Total reaction volume was 650 ml and various pumping rates (30, 40, 50, 60 and 90 rpm) were applied to the system by using a peristaltic pump to optimize the residence time. UV dose was calculated by chemical actinometric method and found as 4.86×10-6 Einstein.m-2.s-1. The maximum removal rate was observed when the system was operated under 30 rpm conditions and the residence time was calculated as 25.6 minutes. According to the results 27 % removal of amoxicillin and 14% COD mineralization were occurred after the optimum residence time. Under 60 and 90 rpm pump rate conditions no removal was achieved. Kinetics studies were showed in order to totally eliminate amoxicillin, 270 minutes is needed. Phenol, aminophenol, pyridine, benzene, aliphatic and heterocyclic organic compounds have been formed after UV based treatment of amoxicillin. This study provides information for a flow reactor model which has not been studied in literature up to date. Keywords: Amoxicillin, UV treatment, Flow reactor, byproduct, removal. Acknowledgment: Cyprus International University Instrumental Analysis Laboratory. 71 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Template for Abstracts of the International Conference on Civil and Environmental Engineering (ICOCEE), Cappadocia 2015 Treatment of Olive Mill Wastewater by photooxidation to Nano -ZnO-Bentonite Composite and Recovery of OMW 1, 2 Merve Balaban* 1 and Delia Teresa Sponza 2 Dokuz Eylül University, Engineering Faculty, Environmental Engineering Department, 35160, İzmir; TURKEY ([email protected]; [email protected]) ABSTRACT Olive mill wastewater (OMW) has a COD value of 220 g/L and also contain large amounts of suspended solids (190 g/L) and high phenolic compounds (10 g/L) exhibiting hard non-biodegradable and quite phytotoxic properties. In this study, Bentonite was immobilized to Nano-ZnO to treat the OMW by photodegradation of the pollutants with Nano-ZnO-bentonite composite. Magnetite minerals, is an excellent filter for Nano-metal composites. Economic advantages of the magnetite are their low cost and they are widely distributed around the world. Magnetites have specific surface area, high chemical and mechanical stability and variety of surface and structural properties. Magnetite’s swelling and adsorption properties make them supporting materials for nanoparticles. ZnO nanoparticles also are stable, recyclable and easily separable and have many advantages, such as low price and high initial rates. In this study the removals of COD, total phenol and total solids (TS) in OMW were investigated by photocatalytic oxidation on the Nano-ZnO-Bentonite at concentrations varying between 0,5 g/L, 2, 3, 4, 8 and 16 g/L. The effects of irridation times, nanocomposite concentrations and pH on photocatalytic oxidation were investigated. The photocatalytic oxidations were performed under sun light and UV irradiation. The effects of sun and UV lamp powers and irradiation time on photocatalitic oxidation were investigated. The maximum pollutant removal efficiencies for COD, total phenol and TS were obtained as 78%, 63% and 61% , respectively, under sunlight at 8 g/L Nano-ZnO-Bentonite for 24 hours, while the removals for COD, total phenol and total solids were 80%, 56% and 71%, respectively, under UV as under throughout photocatalysis at 8 g/L Nano-ZnO-Bentonite after 24 hours retention time in OMW. It was continued to the removal of OMW were steps three and four sequential times to research the recovery of the treated OMW as quenching of soils and washing subjects. Keywords: Bentonite, Nanoparticles, Photocatalytic degradation, Sunlight, UV Irradiation, ZnO. Acknowledgment: The authors would like to express appreciation for the support of the sponsors; (TUBİTAK PROJECT NUMBER: TOV 113O558). 72 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Template for Abstracts of the International Conference on Civil and Environmental Engineering (ICOCEE), Cappadocia 2015 Removal of Olive Mill Wastewater Pollutants by UV and Sunlight Irradition with Nano- SiO2/Fe3O4 Composite and Reuse Properties Çağlar Ulusoy * 1, Delia Sponza 1, 2 *2 Dokuz Eylül University, Engineering Faculty, Environmental Engineering Department ,Buca- Izmir, Turkey. (e-mail:[email protected], [email protected]) ABSTRACT Olive mill wastewater (OMW) are found primarily to process olives for the extraction of olive oil, but they produce olive kernel residue and olive mill effluent wastewater as by-products. OMW can be a serious nuisance when disposed of untreated, due to its significantly high organic load, its phototoxic properties and its relatively low biodegradability. SiO2 microcrystal showed also good photocatalytic activity for wastewater containing phenol. One of the most promising methods to increase the photocatalytic efficiency is the surface modification of SiO 2, with the addition of metal oxides such as Fe3O4 and doping into the of SiO2 catalyst. This work aims to treatment of OMW with photooxidation under UV and sunlights with using nano- SiO2/ Fe3O4 synthesized under laboratory conditions for the removal of COD, total phenol and total solids present in the olive mill wastewaters. The photocatalytic activity of the synthesized nano- SiO2/ Fe3O4 nanoparticles was evaluated by degradation possibilities of phenol, COD and total solids in batch reactor made in kuvars glasses under UV and sun lights. The effects of irradiation time and light power were investigated on the photocatalytic activity of nano- SiO2/ Fe3O4 nanoparticles and COD, total solids and phenol removals. The maximum removal yields of COD, total phenol and total solids were obtained as 76 %, 66 %, 43%, respectively, at 8 g/L nano- SiO2/ Fe3O4 under sunlight irradiation after 24 hours retention time while COD, total phenol and total solids treatment efficiencies of OMW under UV irradiation were detected as 80%, 61%, 73%, respectively, at 8 g/L nano- SiO2/ Fe3O4 for 24 hours retention time. These treatments were sequentially three and four times to detect the utilizability of the treated OMW as irrigation or as refrigeration waters. Keywords: Nano- SiO2/ Fe3O4 , Olive Mill Wastewater, Photooxidation, Sunlight, UV Acknowledgment: The authors would like to express appreciation for the support of the sponsors; (TUBİTAK PROJECT NUMBER: TOV 113O558). 73 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A New Approach for Sludge Disintegration & Stabilization: Solid TiO 2 Thin Films T. TUNÇAL1, D. İ. CİFCİ 1, O. USLU 3 1 Department of Environmental Engineering, Çorlu Engineering Faculty, Namık Kemal university, 59860, Çorlu, Tekirdağ, Turkey 2 Civil Engineering Department, Engineering Faculty, Yeditepe University, 34755, Kayışdağı, İSTANBUL E-mail of the corresponding author: [email protected] ABSTRACT Disintegration of mechanically dewatered sludge (MDS) using thin film (TF) method was investigated scientifically. MDS samples were placed between two TF coated glass substrates and irradiated by four different UV sources emitting around 240 nm, 310 nm, 380 nm and 450 nm. Obtained TF(s) were annealed at 550°C for 1h and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). The effectiveness of the applied method was assessed observing the changes in physicochemical structure of the sludge. In addition to the direct mass distortion (MD), variations in several critical parameters including, lost on ignition (LOI), drying rate (SDR), and sludge bound water content sludge (BWC) were also investigated through the experimental study. Economics of the method were also discussed considering the energy demands of current dewatering/drying equipment. After 3-hour irradiation period under the wavelengths shorter than 400 nm, average decrease in volatile solids (VS) level was 40%±5. Average BWC(s) of raw and photo-catalytically treated MDS samples were %52±1 and %30.6±1 respectively. The average light energies used through photocatalytic and drying experiments were 1,142±10 Joule g-1 VSremoved and 861±28 Joule g-1 H2Oevaporated respectively. Following the advanced oxidation period (λ<400 nm), sludge was irradiated at 450 nm for 2 hours and sludge moisture content decreased from 60±1% to 10±0.6%. Keywords: Sludge minimization, disintegration, TiO2 thin film, nano-technology, dewatering, drying Acknowledgment: This work is founded by The Scientific and Technological Research Council of Turkey TÜBİTAK (Project 111Y209) and Çerkezköy Organized Industrial Zone Management. 74 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Wastewater Treatment in Poland Taking into Special Consideration Anaerobic Reactors Katarzyna Umiejewska* Warsaw University of Technology, Faculty of Environmental Engineering, Division of Water Supply and Sewage Disposal, Poland e-mail:[email protected] ABSTRACT Poland has been European Union’s member since May 1 st 2004. Therefore, EU regulations including The Council Directive 91/271/EEC concerning urban wastewater treatment, became obligatory in our country. According to the Directive, the National Program for Municipal Wastewater Treatment was endorsed in December 2003. It states that all of the agglomerations above 2000 PE (Population Equivalent) should be equipped with sewage network and municipal wastewater treatment plants (WWTP). The aim of the article is to indicate changes in Polish wastewater treatment in 2000-2014, including the progress in the usage of anaerobic reactors. Nitrogen and phosphorus removal from wastewater has become priority in the National Program for Municipal Wastewater Treatment. Hence, a new Decree was introduced on July 24th 2006 by the Environment Minister. It concerns the conditions of discharging sewage into water and ground. As a consequence of the Decree, the number of wastewater plants, removing biogen compounds has risen significantly. From 2005 to 2012 the percentage of municipal wastewater plants with biogen removal increased from 55,9% to 80,4%. According to the Directive, discharges from food-processing industry shall be treated biologically (aerobically or anaerobically) as well. First anaerobic reactor in Poland was built in 1997. At present, there are 33 anaerobic reactors treating 75400 m3d-1 and 399,4 tons COD per day which is equivalent to the population of 6,65 milion PE. These represent 2,04% of industrial wastewater treated biologically. The reactors IC (11), EGSB (8) and UASB (6) are most frequently used. As an effect of European and Polish legislation, capacity of aerobic plants with increased biogen removal has been rising. Also, anaerobic reactors has been used for the treatment of high strength industrial effluents most frequently . Key words: anaerobic reactors, Poland, wastewater 75 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The cycle of pharmaceuticals, drugs and their metabolites in four dominant treatment plant in Slovakia and the Czech Republic T. Mackuľak* 1, L.Birošova2, I. Bodík3 and M. Fáberová 4 1,,3,4 Department of Environmental Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, SLOVAKIA. 2 Department of Nutrition and Food Assesment, Faculty of Chemical and Food Technology, Slovak University of Technology, SLOVAKIA. (E-mail: [email protected], lucia. [email protected], [email protected], [email protected], [email protected]) ABSTRACT Nowadays, the attention of experts in the analysis of environmental micropollutants is predominately aimed on the incidence, fate and the impact of drugs and their metabolites on the aquatic organisms. In our study, we have analyzed and compared the incidence of 30 frequently prescribed pharmaceuticals, illicit drugs and their metabolites in Slovak and Czech wastewater. We were also interested in their fate in various technological stages of WWTP. Using LC-MS / MS analysis, we have found that antibiotics (ciprofloxacin, clarithromycin, azithromycin) and beta blockers (metoprolol) are the most concentrated pharmaceuticals in wastewater of both countries. Concentration of illicit drugs and psychoactive pharmaceuticals has not exceeded micrograms per liter. In case of these micropolutants, tramadol, methamphetamine and venlafaxine have dominated in wastewater. Fate of pharmaceuticals and drugs in WWTP differs; some of them only partially undergo biodegradation, photodegradation, oxidation or sorption. Many of them pass into recipient. This was confirmed especially for tramadol, venlafaxine and certain types of antibiotics such as clarithromycin or azithromycin. According to analysis of sludge water, we have also found that certain types of pharmaceuticals and drugs are capable to concentrate itself in the anaerobic process. Analysis of sludge water revealed the presence of clarithromycin, azythromycin, tramadol, or methamphetamine in the concentration higher than microgram per liter. However sludge water is returned to the water line of WWTP, micropollutants such as pharmaceuticals and drugs are circulating in different technological parts of WWTP. Keywords: illicit drugs, pharmaceuticals, WWTPs, sewage water, wastewater. Acknowledgment: This work was supported by the Slovak Research and Development Agency under the contract No. APVV-0122-12 76 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biodegradation of the Non-Steroidal Anti-Inflammatory Pharmaceutical Flurbiprofen Kadir Yanaç1 and Robert W. Murdoch 2* 1 Environmental Engineering Department, Middle East Technical University, TURKEY. (E-mail: [email protected]) 2 Environmental Engineering Department, Middle East Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT 2-(3-fluoro-4-phenyl-phenyl)propanoic acid, or flurbiprofen, is a non-steroidal anti-inflammatory (NSAID) pharmaceutical popularly sold in Turkey under the brand-name Majezik®. Approximately 22% of consumed flurbiprofen (flb) is excreted unmodified or as an easily hydrolysable conjugate. In Turkey, flb is the most popular NSAID and the third most popular pharmaceutical overall. However, the fate of flb in the environment is entirely unknown. In order to begin to understand how bacteria metabolize flb, flb was spiked into activated sludge samples at concentrations of 50 and 500 ppm. Flb was quantified by reverse phase HPLC with detection at 247nm. Only ~30% of spiked flb was removed from the 500ppm treatment after 76 days while an average of ~80% was removed from 50 ppm treatments after 76 days, indicating that flb is recalcitrant and potentially toxic. During degradation, a novel peak was detected that appeared as flb was disappeared and in proportion to the amount of disappearance. The novel peak was fractionated by HPLC and subjected to GC/MS structural characterization. Spiked activated sludge was also used as a source of enrichment cultures with the goal of isolating bacteria able to use flb as sole carbon and energy source. Enrichments on 100 ppm flb in minimal medium were monitored for flb concentration and culture density. A fter three rounds of serial enrichment, which took three weeks each, cultures were streaked onto 100 ppm flb solid medium with 20 ppm yeast extract and twelve unique isolates were recovered. Isolates were grouped by RFLP analysis of the 16S rRNA gene and unique strains were sequenced in order to characterize their phylogenies. This work represents the first investigation of the bacterial metabolism of the NSAID pharmaceutical flurbiprofen. Keywords: Emerging contaminants, pharmaceuticals and personal care products, non-steroidal antiinflammatory, biodegradation Acknowledgment: This project was funded by Middle East Technical University BAP [Project number: 20130080]. 77 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Impregnation Ratio on Properties of Activated Carbon Prepared from Biochar by Chemical Activation D. Angın* 1, S. Güneş 2, S. Şensöz 3 1, 2 3 Department of Food Engineering , Sakarya University, Sakarya, TURKEY. ([email protected], [email protected]) Department of Chemical Engineering, Eskisehir Osmangazi University, Eskişehir, TURKEY. ([email protected]) ABSTRACT Activated carbon is a black solid substance resembling granular or powder charcoal and are carbonaceous material that have highly developed porosity, internal surface area and relatively high mechanical strength. They have been used for a long time as adsorbents in many applications. The properties of biochar are different from activated carbon, though both of them are carbon -rich material. Generally, biochar is a not fully carbonized product because its production by pyrolysis is often operated under low temperatures. However, after physical or chemical activation, the surface areas and internal pore structures of activated carbon are greatly enhanced and improved compared to biochar that only experiences the carbonization treatment. Thus, biochar may act as a precursor matter to manufacture activated carbon. The most important characteristics of an activated carbon is its surface area and adsorption capacity, which are highly influenced by the activated carbon preparation conditions, such as activation temperature, impregnation ratio and activation time. In this study, the influence of impregnation ratio on the product yield, chemical and surface properties of the activated carbons were investigated. This purpose, activated carbons were prepared by chemical activation with potassium hydroxide (KOH) of the biochar obtained through pyrolysis of safflower seed press cake. The biochar were activated at KOH:biochar impregnation ratio ranging from 1:1 to 4:1, heating rate of 10 °C min-1 and 900 °C activation temperature under nitrogen atmosphere. The chemical and surface properties of the activated carbons were investigated by elemental analysis, BET surface area, and scanning electron microscope (SEM) images. The highest BET surface area was achieved as 1652 m2 g-1 at 4:1 of KOH:biochar impregnation ratio. The results showed that both chemical and surface properties of the activated carbon were significantly affected by the impregnation ratio. Keywords: Activated carbon, Biochar, Characterization, Impregnation ratio. Acknowledgment: The authors thank Sakarya University, Scientific Research Project Funding (BAP) for their financial support [Project number: 2010-01-16-003]. 78 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of Orange 13 from Aqueous Solutions Using Activated Carbon Prepared from Orange (Citrus sinensis L.) Pulp D. Angın* 1, G. Demir 2, S. Güneş2, A. Ilci2 1, 2 Department of Food Engineering , Sakarya University, Sakarya, TURKEY. ([email protected], [email protected], [email protected], [email protected]) ABSTRACT Nowadays, dyes have created serious environmental problems with the rapid development of various industries, such as paper, plastic, textile, cosmetic, leather, and coating. Colored dye effluents have mainly the complex nature and most of them are toxic to aquatic life, mutagenic and carcinogenic and can cause some health problems. The adsorption method was proven to be more sophisticated and efficient compared to traditional physico-chemical methods such as coagulation, ultrafiltration, ozonation, oxidation, sedimentation, reverse osmosis, flotation etc. for dye removal from wastewater, due to its low-cost, easy availability, simplicity of design and ease of operation. Activated carbon can be produced from any carbonaceous solid precursor, which is largely dependent on its availability, cost and purity. Activated carbon is the most widely used adsorbent for the removal of dyestuff from wastewater because it has an excellent high surface area and high adsorption capacity for organic compounds, but its use is usually limited due to its high cost. For this reason, many researchers have investigated more cheaper and efficient activated carbons for the removal of dyes from wastewater. In this study, activated carbon was produced from orange (Citrus sinensis L.) pulp by chemical activation with zinc chloride (ZnCl2) and an adsorption capacity of activated carbon for removal of reactive dyestuff (Orange 13) from aqueous solutions was investigated. The characteristics of activated carbon were examined by scanning electron microscopy, nitrogen adsorption isotherm and elemental analysis. In the batch mode adsorption studies, the effects of initial pH, adsorbent dosage, and initial concentration of solution were examined. Equilibrium data were fitted to the Langmuir, Freundlich and Dubinin-Radushkevich (DR) isotherm equations. Also, this study has demonstrated that high surface area activated carbons can be prepared from the chemical activation of orange pulp with zinc chloride as activating agents. Keywords: Activated carbon, Adsorption, Characterization, Orange 13, Orange pulp. Acknowledgment: The authors thank Sakarya University, Scientific Research Project Funding (BAP) for their financial support [Project number: 2013-01-16-014]. 79 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biogas Production by Anaerobic Digester Exposed to AmmoniaChangedwith Changing Bacterial Population Dynamics M. S.Ak* 1, F. Yilmaz 2and B. Icgen3 1,2,3 Department of Environmental Engineering, Middle East Technical University, TURKEY (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Anaerobic treatment is more favorable process than other unit operations due to its high loading rate capacity and low sludge production rate. In addition to these advantages, biogas (methane) production makes this process more attractive. The sensitivity of the process towardschanging concentrations of inhibitors like ammoniaisone of the main drawbacks. For the efficient biogas production, the knowledge about the changes in the microbial population within the digester exposed to varying concentrations of ammonia needs to berevealed. However, up to now, this requirement is mostly predicted without revealing the real population dynamics. Therefore, in this study, the effect of ammoniaon microbial population of anaerobic sludge digester and its biogas productionwere investigated. For this purpose, total gas production, methane percentage in the off-gas, chemical oxygen demand (COD), total solids (TS), volatile solids (VS)of the sludge, and changes in bacterial population were followed during digestion process with lab-scale bioreactors exposed tovaryingconcentrations of ammonia. The changes in microbial population were followed by using fluorescence in situ hybridization technique with oligonucleotide probes specific for each anaerobic consortium. Keywords:Biogas production, anaerobic digestion, ammonia, population dynamics Acknowledgment: The authors thank The Scientific and Technological Research Council of Turkey for their financial support through a 1001 project. 80 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of Methylene Blue Dye on Multi-walled Carbon Nanotubes (MWCNTs) - A Response Surface Methodology (RSM) approach Veyis Selen 1*, Şeyda Taşar 1, Meltem Çakmak1, Dursun Özer 1 and Ahmet Özer 1 1 Department of Chemical Engineering, Firat University, 23279 Elazig, Turkey. (E-mail: [email protected]*; [email protected]; [email protected]; [email protected]; [email protected]) ABSTRACT Dyes may be defined as organic compounds used to color other substances, and usually may be found in effluent water from many sectors of industry. These colored compounds are widely used in the textile, food, cosmetic, pharmaceutical, tanneries, electroplating factories and other industries. Adsorption techniques have been proved to be an excellent way to treat effluents, offering advantages over conventional process, especially from the environmental point of view. In this study, the adsorption potential of multi-walled carbon nanotubes (MWCNTs) was investigated for removal of Methylene blue (MB) from aqueous solutions. The multi-walled carbon nanotubes used in this study were characterized by XRD, TEM, FTIR and pHzpc. Adsorption of MB in aqueous solution by MWCNTs was studied by using Placket–Burman (PB) and Central Composite Design (CCD). Adsorption process was described mathematically by using Response Surface Methodology (RSM). Initial MB concentration, initial pH of solution, adsorbent dosage, temperature, particle size, shaking speed and contact time were selected as independent variables and the adsorption yield was chosen to be response for the adsorption process in the PB design. The adsorption experiments were conducted in 12 runs to study the effect of the selected variables. All of the experiments were repeated twice, ie a total of 24 experiments were performed for adsorption of MB. Based on the results of PB and the combined effect of contact time, initial pH of solution, MB concentration and adsorbent dosage on the MB adsorption was studied using CCD. Other parameters for adsorption process were kept constant at a temperature of 298 K; particle size of -200 mesh, shaking speed of 150 rpm. Each factor in the design was studied at five different levels. Data obtained from experimental runs were analyzed using the “Design Expert” software (version 6.0, Stat-Ease, Inc., Minneapolis, USA) statistical package. Analysis of variance (ANOVA) showed a high coefficient of determination value (R2 = 0.94). It was observed that the linear and quadratic effects of the adsorbent dosage, initial pH of solution and initial concentration of MB, additionally linear effect of contact time were very significant (P<0.05) for adsorption of MB. The interaction between initial MB concentration and contact time showed remarkable effect on adsorption process. This study showed that MWCNTs particles can effectively remove MB from wastewater. Keywords: adsorption, central composite design (CCD), methylene blue (MB), multi-walled carbon nanotubes (MWCNTs) and placket–burman (PB) and. 81 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Astrazon Golden Yellow 7GL from Colored Wastewater Using Activated Clay Meltem Çakmak1, Şeyda Taşar 1*, Veyis Selen 1, Ahmet Özer 1, Dursun Özer 1 1 Department of Chemical Engineering, Firat University, 23279 Elazig, Turkey. (E-mail: [email protected]; [email protected]; [email protected]; [email protected]; [email protected]) ABSTRACT The dyes and pigments which are generally complex aromatic molecular structure and synthetic origin are contain more double bonds and various functional groups. The wastewaters polluted by dyes and pigments impairs the aesthetic nature of the receiving environment, reduces the light penetration through the water’s surface and the solubility of gases. This pollution affects the photosynthetic activity of aquatic life. It is known that discharging the untreated wastewater containing organic dyes into natural water reserve can cause a serious environmental hazard. For that reason the removal of synthetic organic dyestuffs from waste effluents is becoming important for water ecosystem. In this study, chemically modified clay (CMC) was used as an adsorbent for the removal of Astrazon Golden Yellow 7GL (AGY-7GL), which is a basic dye, from wastewater. For this purpose, firstly the chemically modified clay was characterized by determining zero point of charge (pH zpc), and using BET, SEM and FTIR. Then effects of operational parameters on adsorption of AGY-7GL were studied in a batch system. The efficiency and capacity of adsorption were investigated under various parameters such as contact time (0 -180 min), pH (2-8), temperature (293-323 K), CMC dosage (0.075-0.5 mg/g) and initial AGL-7GL concentration (75-250 mg/L) for the removal of AGY-7GL. The adsorption experimental result revealed that pH was not significant effect on uptake of dye, whereas adsorption capacity was increased when contact time, temperature and initial dye concentration were increased. As a result of evaluation of the research data’s was concluded that the adsorption process was endothermic. Optimum conditions for the removal process were found to be contact time of 105 min, initial dye concentration 250 mg/L, initial pH 6 and adsorbent concentration 0.25 g/L at 323 K. The maximum adsorption capacity was determined to be about 370 mg/g at the optimum condition. Thermodynamic and kinetic parameters were calculated from the results of the adsorption experiment. The pseudo first order and the pseudo second order kinetic model equations were used to predict the adsorption parameters. The evaluation of kinetic models showed that data were best fitted by the pseudo second order model. The adsorption data were evaluated with linear and nonlinear Freundlich and Langmuir isotherm models equations and compare with each other. It was determined that the adsorption equilibrium data showed an excellent description to the Freundlich isotherm model. Thermodynamic parameters such as ∆H° (19.0 kj/mole), ∆G° (28.8 kj/mole) and ∆S° (0.148 kj/mole) were also determined. These parameters showed that the adsorption mechanism was physical and spontaneous. According to experimental results, it was concluded that CMC could be used as an alternative and low cost potential adsorbent for the removal of AGY-7GL from wastewater. Keywords: adsorption, astrazon golden yellow 7GL (AGY-7GL), chemically modified clay (CMC), thermodynamic and kinetic parameters. 82 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessment of Anaerobic Microbial Community Structure in the Presence of NonylphenolDiethoxylateUsing Fluorescence In Situ Hybridization Fadime Kara Murdoch* 1 and F.Dilek Sanin 2 1, 2, Department of Biotechnology, Middle East Technical University, TURKEY. (E-mail:[email protected]) Department of Environmental Engineering, Middle East Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT Due to their properties such as being lipophilic, toxic and endocrine -disruptor, Nonylphenol(poly)ethoxylates (NPnEO) received special attention during the last years for their ability to accumulate in sludge. Nonylphenols can be degraded to a certain extent in wastewater treatment plants especially in activated sludge units; however since they accumulate in sludge, understanding of their fate during sludge treatment and determination of microbial community structure becomes important. In this respect, the aim of this research was to monitor degradation of NP2EO into degradation products (nonylphenolmonoethoxylate (NP1EO) and nonylphenol (NP)) in lab -scale semicontinuous anaerobic digesters with gas chromatography-mass spectrometry (GC/MS) and to assess microbial community structure at taxonomic level by using Fluorescence in Situ Hybridization (FISH) method. Lab scale semi-continuous anaerobic digesters having 2L working volume were operated as replica at 35oC. 3 mg/L NP2EO was dosed and then degradation products were monitored for 145 days of digester operation period. Extraction of NP compounds from sludge samples was carried out by sonication assisted extraction for 5 min. The biogas composition of the anae robic digesters was determined with a Gas Chromatography equipped with Thermal Conductivity Detector (TCD). For in situ identification and quantification of the relative abundances of five different phylogenetic groups (alpha, beta and gamma proteobacteria, archaea and methanogens) in anaerobic digesters, taxon-specific fluorescently-labeled oligonucleotide probes were used. Samples were examined with a Carl Zeiss Axio Scope.A1 epifluorescence microscope equipped with a 100 W high pressure mercury lamp and a charged coupled device (CCD) camera.The results indicated that following NP2EO spike into semi-continuous anaerobic digesters, there were changes in the relative abundances of major phylogenetic groups. Keywords:anaerobic digester, fluorescence in situ hybridization, nonylphenol, nonylphenoldiethoxylate, phylogenetic groups. 83 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison Of Methylene Blue Removal Efficiency From Aqueous Solutions By Walnut Shell And Activated Walnut Shell Giray, S.N* 1, Aktaş D. 2, Kozak, M. 3, Kaymaz T3., and Dolaz M. 4 1,2,3,4 Kahramanmaras Sutcu Imam University, Engineering and Architecture Faculty, Department of Environmental Engineering, TURKEY (E-mail: [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT Methylen blue (MB) removal from aqueous solution by adsorption using wa lnut shell (WS) and activated walnut shell (AWS) was aimed in this study, Dyes are released into the environment and lead to the acute toxic effects on the flora and fauna of the ecosystem. In addition to being aesthetically displeasing, the release of colored effluents in water bodies reduces the photosynthesis as it impedes penetration of light in water. Thus, dye-containing wastewaters should be treated before their discharge. Adsorption is an effective and cheap method for treatment of this kind of wastewaters. In this study, waste WS were used as adsorbent. All experiments were carried out with the adsorbent sample in 200 mL flasks at the jar test to optimize the experimental parameters including pH, MB concentration, adsorbent concentration, contact time, agitation speed. In the first part of this study, waste WS were collected locally, washed, dried, grinded and stored in an airtight container until use. The optimum MB removal was found 86,37% under the optimum conditions as pH 2, 5 ppm of MB concentration, 10 g/L of adsorbent concentration, 90 minutes of contact time, 150 rpm of agitation speed at room temperature. by adsorption using WS. In the second part of this study, washed, dried and grinded WS was treated with HCl for 24 hours. pH of the WS was arranged to 7 by NaOH, washed by dilute water, dried and placed into a muffule furnace at 550 oC for 2 h. Prepared adsorbent was stored in an airtight container until use. The optimum MB removal was found 86,37% under the optimum conditions as pH 6.2, 5 ppm of MB concentration, 5 g/L of adsorbent concentration, 9 minutes of contact time, 150 rpm of agitation speed at room temperature by adsorption using AWS. Keywords: activated, dye removal, Methylen blue, walnut shell 84 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Separation of Emulsified Oils from Wastewater by the Application of Electric Field C. Eryılmaz* 1, A. Genç2 1,2 Department of Environmental Engineering, Bülent Ecevit University, TURKEY. (E-mail: [email protected], [email protected],) ABSTRACT Emulsified oils (cutting fluids) are widely used in metal working industries and usually composed of a mineral oil (40-80 %), a surfactant, and some additives such as biocides, anti-degrading and anti-corrosive chemicals. Cutting fluids lose their properties and effectiveness because of thermal degradation and the production of suspended metal particles during their usage. Therefore, cutting fluids have to be replaced periodically. But their treatment from wastewaters can be problematic because they form stable emulsions. Coagulation, flotation and membrane technologies are generally used for the treatment of wastewaters containing metal cutting fluids. Biological processes can also be used for the treatment since cutting oils can contain biocides to prevent their degradation. In addition, the electrokinetic treatment methods have been attracting great attention recently for the treatment of oily wastewaters. It has been shown in the literature that as high as 99% cutting oil removal efficiencies can be reached in electrocoagulation using aluminum/iron electrodes. In this study, the synthetic wastewaters were prepared by using two metal cutting fluids and their separation was investigated by electroflotation/electrosedimentation using stainless steel electrodes. The experiments were performed by using horizontal and vertical electrokinetic units. Turbidity, pH, conductivity, current and voltage were monitored during the experiments. In addition, chemical oxygen demands (COD) were measured at 15 minutes intervals. The oil removal efficiency shows a trend of increasing with electric field strength. In addition, the attained removal efficiencies at the vertical electrokinetic unit were higher in comparison to the horizontal ones. Keywords: Electrokinetic methods, electrosedimentation, emulsified oils, cutting fluids. Acknowledgment: The financial support by Bulent Ecevit University [BAP: 2014-YDK-77047330-02] is gratefully appreciated. 85 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Economic Analysis of Sewage Sludge Management Methods in Kocaeli Özgür Kaplan* 1, Mustafa Gündüz 2, Gülcan Turan 3 and Kadri S. Yiğit 4 1, 4 2 Mechanical Engineering Department, Kocaeli University, TURKEY. (E-mail: [email protected], [email protected]) BRG Energy, Kocaeli University Technology Development Zone , TURKEY. (E-mail: [email protected]) 3 42Evler WWTP, Kocaeli Water and Sewage Administration, TURKEY (E-mail: [email protected]) ABSTRACT Sewage sludge is produced continuously by the waste water treatment facilities (WWTPs). Sewage sludge management includes transportation, treatment and disposal of the sludge. 35000 m 3/day waste water is treated in ISU 42Evler WWTP in İzmit, Kocaeli, Turkey and sewage sludge is produced as byproduct. Currently this sludge is dewatered and 35 tons/day dewatered sludge is transferred by trucks to either cement factories or landfill sites for final disposal. In this study two cases are investigated under economic terms which are current disposal method and anaerobic digestion of the sewage sludge. Monthly electricity, polymer, truck renting and sludge disposal costs and monthly sludge production are considered in the economic analysis. It’s found out that under current disposal method and anaerobic digestion process total costs are 1,101,606 $ and 470,155 $ respect ively. It is determined that with anaerobic digestion process, sludge disposal is 57% cheaper than current method. Keywords: Anaerobic digestion, Sewage Sludge, WWTP. Acknowledgment: The authors thank ISU 42Evler WWTP for providing data. 86 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effect of Different pH at Constant Temperature on Biohydrogen Production from Sewage Sludge I. Senturk* and H. Buyukgungor Ondokuz Mayis University, Engineering Faculty, Environmental Engineering Department, Samsun, TURKEY. (E-mail: [email protected]*, [email protected]) ABSTRACT The aim of this study is to investigate the usability of sewage sludge, a waste from waste water treatment facility, at constant temperature and different pH conditions in the biohydrogen production by dark fermentation. Activated sludge used in the study was obtained from return sludge pumping station of a sewage treatment plant located in Bafra, Samsun. In order to product hydrogen from sludge, a 2 liter bioreactor operating in batch system was used. Before fermentation, the internal part of the reactor was purged with nitrogen gas for 3 minutes to provide anaerobic conditions. After sealing, the reactor was placed into an incubator operating at 35±1 °C and 150 rpm and operated at pH values ranging from 4 to 8. Gas production and gas contents of each reactor were measured at certain intervals daily. H2 and CH4 concentrations in the biogas produced were measured using a gas chromatography equipped with a thermal conductivity detector and the measured values were expressed as mL/m 3 (ppmv = gas / gas). With the samples obtained at different times (before and after fermentation), characteristics of the sludge in the fermentor was identified. All experiments continued until hydrogen production stopped or decreased. It was understood from the results that biohydrogen production varies according to the characterization of activated sludge. In the experiments performed at different pH values at 35±1 °C, maximum hydrogen production was achieved within the first 24 hours. Except for one performed at pH 8, H 2 gas release was observed at other pH values within 2 hours. However, according to the results obtained at the 24th hour, maximum H2 production (2489 mL/m3H2) was observed at pH 8. With the increase in methane bacteria in the medium, hydrogen producing ability and hydrogen content of the sludge gradually decreased. In general, hydrogen production after the second day was less. In addition, there was a relationship between protein, carbohydrates and chemical oxygen demand concentration in the medium and hydrogen production. Keywords: Biohydrogen production, Dark fermentation, Renewable energy sources, Sewage sludge. 87 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biodegradation of Various Azo Dyes in Anaerobic Batch Reactors Ö. Aktaş*, Y. Toker and E. Şahinkaya Istanbul Medeniyet University, Bioengineering Department, Goztepe, Istanbul, TURKEY (E-mail: [email protected], [email protected], [email protected]) ABSTRACT In the treatment of textile wastewaters, classical activated sludge process usually cannot remove color sufficiently and the discharge limits are exceeded because of the toxic effects of dyes on aerobic microorganisms. Particularly successive anaerobic-aerobic biological treatment is mandatory for azo dyes which are very difficult to be biodegraded in aerobic conditions. Anaerobic treatment serves as pretreatment for color removal and also has the advantages such as the production of methane gas for energy recovery and less sludge production. The azo bond (-N=N-), which is the chromophore group in the chemical structure of these dyes, can be much more easily broken down in anaerobic conditions compared to aerobic. Anaerobic degradation of various azo dyes was examined in this study. Remova l of organic matter and color as well as biogas production were tested in batch reactors fed with azo dyes at various concentrations. For this purpose, anaerobic sludge, synthetic wastewater involving glucose and dye within a total volume of 100 mL were placed in 200 mL bottles fixed with aluminum screw caps to prevent air intake. The azo dyes used were Remazol Brilliant Violet 5R (λmax: 560 nm), Acid Orange 8 (λmax: 488 nm), Naphtalene Blue Black (λmax: 610 nm) and Remazol Black B (λmax: 595 nm), which have different colors and chemical structures. These batch studies showed that significant biogas production was obtained in the presence of azo dyes at concentrations ranging between 10 -500 mg/L. This showed that azo dyes did not inhibit the anaerobic process even at high concentrations. Besides, color removal reaching up to 98% showed that azo dyes were degraded almost completely. However, removal of COD with an initial concentration of about 2000 mg/L remained usually below 50% and this was attributed to inhibition caused by aromatic amines produced as a result of anaerobic degradation of azo dyes. Keywords: anaerobic process, azo dyes, biological methane potential, textile wastewater. Acknowledgment: The authors thank Istanbul Medeniyet University, Scientific Research Project Funding (IMU BAP) for their financial support [Project number: FBA-2013-354]. 88 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Simultaneous nitrate and perchlorate reduction in elemental sulfur based autotrophic and heterotrophic processes D. Ucar*1, Cokgor E2, E. Sahinkaya3 A. Yurtsever 4 1, 2 Environmental Biotechnology Department, Istanbul Technical University, Turkey. ([email protected], [email protected]) 3 4 Bioengineering Department, Istanbul Medeniyet University, Turkey. ([email protected]) Environmental Engineering Department, Yildiz Technical University, Turkey. ([email protected]) ABSTRACT Perchlorate is a persistent inorganic pollutant often used in its salt form. It has been used an oxidizer in rocked propellants, explosives, road flares and air bags. It also found in some fertilizers together with nitrate and commonly found in groundwater together with nitrate. Perchlorate competitively inhibits the iodine uptake by the thyroid which results a decrease in thyroid hormones. Two elemental sulfur based autotrophic processes with different alkalinity sources (NaHCO3 and limestone fed) and a methanol based heterotrophic process were investigated to simultaneous nitrate and perchlorate reduction in ground water. In batch assays, excellent nitrate reduction with NaHCO3 fed autotrophic and heterotrophic processes was obtained under 25 mg/L NO3--N and various (100–1500 µg/L) initial perchlorate concentrations. Average nitrate reduction for limestone fed reactor was between 95% in the end of 90h. Complete perchlorate reduction was observed in 72h for heterotrophic reactor whereas NaHCO 3 fed autotrophic reactor showed 97% perchlorate removal in the end of 90h. The perchlorate reduction performance of limestone fed reactor was varied between 51.8 and 92% depending on the influent perchlorate concentration. Sulfate was produced as a result of elemental sulfur based autotrophic denitrification and 257.20±12.50 and 238.90±28.9 mg/L SO 42- were produced for NaHCO3 and limestone fed reactors respectively. Organic electron donors are of concern due to risks for bacterial growth in distribution systems and disinfection byproducts. Study shows that simultaneous nitrate and perchlorate reduction is possible with elemental sulfur without using organic electron donors. Keywords: Autotrophic Denitrification, Heterotrophic Denitrification, Nitrate Reduction, Perchlorate Reduction Acknowledgment: This research was supported by The Scientific and Technological Research Council of Turkey (TUBITAK/Project no: 113Y023). 89 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Aerobic Treatment of Olive Mill Wastewater by Batch Reactor: a Kinetic Study Sinan KUL*1, Alper NUHOĞLU 2 and Erdinç ALADAĞ 3 1, 2 Atatürk University, Department of Environmental Engineering, TURKEY. (E-mail: [email protected], [email protected]) 3 Yüzüncü Yıl University, Department of Environmental Engineering, TURKEY. (E-mail: [email protected]) ABSTRACT Olive oil production has a economic and social importance in Mediterranean countries. This study includes the investigation of olive mill wastewater treatment, which is a significant contaminant, under aerobic conditions in a batch reactor and calculation of its kinetic parameters and values. Treatment of olive mill wastewater concentration within 50-1000 mg COD/L has been examined. 42,63 % removal rate was achieved for 12.44 mg COD/L for initial concentration, for 130.34 mg COD/L initial concentration that reached maximum reproduction rate, the removal rate was 57.18 %. In other attempts as initial concentration has increased, microorganisms’ adaptation time has lengthened, and concordantly COD relief time has increased. Finally, in the attempts with 927 mg COD/L initial concentration, removal rate has receded up to 8.88%. Specific growth rate has been calculated for each test through taking the logarithm of division of initial microorganism concentration by microorganism concentration at the t time and through drawing a graph between found values and time and using the slope of linear part. Initial COD concentrations (S 0) and specific growth rate (µ) has been subjected nonlinear regression and µmax, Ks and Ki values included in Haldane equation have been calculated. For nonlinear regression nonlinear estimation module has been used in STATISTICA 6.0 software by using Statistica 6.0 Userguide. For the relation between initial olive mill wastewater concentration and specific growth rate Haldane bio-kinetic equation has been preferred, and in this equation, the values belong to µ max, Ks and Ki parameters has been calculated as 0.44 h-1, 56.69 mg/L and 497.14 mg/L, respectively. Keywords: Biological treatment, chemical oxygen demand (COD), Haldane, Kinetic parameters, Olive Mill Wastewater. 90 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Synthesis of carboxymethyl starch from food industry waste Sümeyye Akarsu* 1, Cengiz A. Zıba 2, Ferhat Dincer 3 and Mustafa Dolaz 4 1,4 Kahramanmaras Sutcu Imam University, Engineering and Architecture Faculty, Dept. of Environmental Engineering, Kahramanmaras, Turkey. (E-mail: [email protected], [email protected]) 2 Kahramanmaras Sutcu Imam University, Vocational School of Goksun, Kahramanmaras, Turkey. (E-mail: [email protected]) 3 Kahramanmaras Sutcu Imam University, Vocational School of Afsin, Kahramanmaras, Turkey. (E-mail: [email protected]) ABSTRACT Using the potential of raw materials in our country, to increase our competitiveness in the industry, should be given great importance to technological, research and development activities. Increasing population and technological developments have resulted reduction of the raw materials and growing need for renewable energy sources. The effects of oil and its derivatives are harmful to human health. As a result of this, the increase in demand for biomaterials and modified biomaterials for various i ndustrial applications in recent times is caused by their qualities such as low cost, biocompatibility, biodegradability and non -toxicity. Among these materials, carboxymethyl starch (CMS) is one of the most important starch ether derivatives. CMS is a biodegradable and non-toxic natural polymer. It has popular applications in the oil drilling industry, pharmaceutics, cosmetics, nutrients, pesticides, foodstuff, and capsulation of cell (Fedorova ve Bordarenco, 1985). CMS is also used in recovery of materials from waste water (Kim ve Tim, 1999; Xu ve ark., 2005). The purpose of this work is to synthesize CMS samples from waste potato. Waste potato starch is obtained from potato chips production while slicing, peeling and cleaning water. Before carboxymethylation waste potato purified with H 2O2 and NaOH at desired temperature. Carboxymethyl reaction of potato starch was carried out in a aqueous-isopropanol (IPA) media. Potato starch, IPA and sodium hydroxide were added in into a flask with a mechanical stirrer. The temperature was raised to 35 oC and the mixture was constantly stirred for 45 min. The reaction was started by adding sodium monochloro acetic acid (SMCA). At the desired reaction time the reaction was stopped. The sample was cooled, neutralized, filtr ated and washed a few times with 80% alcohol. CMS was characterized by FT-IR, 1H-, 13C-NMR and X-ray diffraction. The morphology of these composites was studied by SEM. Keywords: Starch, carboxymethylation, waste, potato, SEM References Kim, B.S., Lim, S.T. Removal of heavy metal ions from water by cross-linked carboxymethyl corn starch. Carbohydr. Polym. 1999, 39, 217–223. Fedorova, G.A., Bordarenco, N.T. Preparation and study of carboxymethyl starch. Chem. Nat. Comp. 1985, 20 (6), 653–657. Xu,S., Feng, S., Peng, G., Wang, J., Yushan, A. Removal of Pb (II) by crosslinked amphoteric starch containing the carboxymethyl group. Carbohydr. Polym. 2005, 60, 301–305. Acknowledgment: The authors thank Kahramanmaras Sutcu Imam University, Scientific Research Project Funding (BAP) for their financial support [Project number: 2014/3-12 YLS]. 91 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of The Adsorption Capacity of The Expanded Perlite to Remove Linear Alkyl Benzene Sulphonic Acid(LABSA) from Aqueous Solution D. Akin Sahbaz*1, S. Balbay2, C. Acikgoz3 1 Afyon Kocatepe University, Faculty of Engineering, Department of Chemical Engineering, TURKEY. (E-mail:[email protected]) 2, 3 Bilecik Şeyh Edebali University, Faculty of Engineering, Department of Chemical and Process Engineering, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Linear alkyl benzene sulphonic acid (LABSA) is the major anionic surfactant material used in detergent formulations so that it is frequently present in domestic and civil wastewater. In this study, r emoval of LABSA has been carried out from its aqueous solutions by using the expanded perlite (EP) as potential adsorbent. Perlite products are made from an amorphous alumino-silicate rock, which has some very special properties: it contains water, which expands into steam on heating, producing a foamed structure. The EP particles used for adsorption process were in the range of 0.85 -1.6 mm. Optimum parameters for the adsorption of LABSA over EP have been determined by studying the effect of pH, temperature, concentration of LABSA, amount of adsorbent and contact time. LABSA has been adsorbed over under batch measurements and adsorption process is monitored using UV spectrophotometer. The optimum pH value for adsorption capacity and removal efficiency of LABSA were 9.00 by (EP). The contact time of 3 hours was found to be sufficient to reach equilibrium, and so it was selected in further experiments. Thermodynamic parameters such as enthalpy change (∆H°), free energy change (∆G°) and entropy change (∆S°) were estimated. The experimental isotherm data were analyzed using Langmuir and Freundlich isotherm models. Experimental data were also evaluated in terms of kinetic characteristics of adsorption and it was found that the adsorption process obeyed the pseudo second order kinetic model. The present study has demonstrated that PE can be employed for the removal of LABSA from wastewater and potential as a cheap alternative to commercial adsorben ts. Keywords: Adsorption, Expanded perlite, LABSA. 92 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigating Color Removal of Textile Wastewater using Constructed Wetlands E. Karaçetin* 1, Sevim, O. 1 Erciyes University, Environmental Engineering Department, Kayseri, Turkey. (E-mail: [email protected]) ABSTRACT Constructed wetlands are designed systems to treat wastewater in a semi-controlled environment, imitating the natural processes. Currently, these systems are being adapted to different purposes from treating municipal wastewater to agricultural runoff and one of these purposes is the treatment of textile wastewater. This study concentrated on the color removal of textile wastewater. Because of the recent and increasing trend in natural dyeing, especially in rural areas, we concentrated on natural dyeing. We prepared our textile wastewater using walnut extract, one of the most commonly used natural dye. We prepared a laboratory scale hybrid constructed wetland composed of two reactors; a vertical flow cylindrical reactor combined to a horizontal flow rectangular pool. To test the influence of plants, two systems with plants and without plants were constructed. The plants in the “with plant system” were Typha latifolia in the vertical flow reactor and Phragmites australis in the horizontal flow reactor. The system was fed with wastewater continuously for a month and color removal was recorded. COD efficiency was approximately 90% and color removal was between 71% and 96%. This study shows that constructed wetlands are quite effective in removal of color and can be very practical especially in small residential areas where natural dying methods are readily applied. Keywords: color removal; constructed wetlands, textile wastewater. Acknowledgment: The authors thank Erciyes Universtiy, Scientific Research Project Funding (ERÜ BAP) for their financial support [Project number: 4596]. 93 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption and Kinetic Studies of Molecular Size Fractions of Humic Acid onto Anion-Doped TiO2 Specimens P. Akan*1 and M. Bekbolet2 1 Hacettepe University, Environmental Engineering Department, 06800 Beytepe, Ankara, Turkey. *([email protected]). 2 Bogazici University, Institute of Environmental Sciences, 34342, Bebek, Istanbul, Turkey. ([email protected]). ABSTRACT Natural organic matter mainly composed of humic substances react with various oxidants and disinfectants used during purification of drinking water produces disinfection by-products (DBPs) namely trihalomethanes and haloacetic acids. Due to various toxic effects, fromation of DBPs cause serious public health problems primarily related to central nervous system and bladder cancer. Photocatalysis occurring through a surface oriented mechanism is one of the novel methods applied for the removal of humic substances from water in treatment facilities. Currently, visible light activated TiO2 specimens are developed by modifications through the use of various dopants. In the assessment of the degradation of humic substances during photocatalysis, understanding of the surface interactions prevailing between doped oxide surface and humic subfractions is required. The objective of this study was to explore equilibrium and kinetic studies of surface interactions between diverse humic molecular size fractions and TiO2 namely bare TiO2 and anion doped TiO2 (C-doped, N-doped, S-doped and N-S co-doped) Hombikat UV-100 specimens used as adsorbents in the range of 0.11.0 mg mL-1. Batch adsorption experiments were implemented with humic acid solutions having different molecular size fractions (0.45 µm filtered fraction, 100 kDa fraction and 30 kDa fraction). In equilibrium studies, the data obtained by adsorption experiments were evaluated by Freundlich, Langmuir and DubininRadushkevich isotherm models. The results representing the relationship between decreasing humic molecular size fractions and dopents on TiO2 specimens exhibited significant differences in relation to the respective morphological properties of TiO2 specimens. Kinetic data were further evaluated by various kinetic models. Keywords: Adsorption, kinetic studies, anion doped TiO2 specimens, humic acid Acknowledgment: The support provided by the Research Fund of Bogazici University [Project number: 6750]. The authors thanks to Prof. Z. Cinar from Yildiz Technical University for the preparation of the anion doped TiO2 specimens. 94 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparision of Biological and Advanced Treatment Processes for Ciprofloxacin Removal in Raw Hospital Wastewaters G. Guney* 1 and D.T. Sponza 2 1, 2 Dokuz Eylul University, Engineering Faculty, Environmental Engineering Department, Tinaztepe Campus, 35160, Buca/Izmir/TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT This study presents the comparision of biological and advanced treatment of ciprofloxacin antibiotic which is an important micropollutant from hospital effluents. The treatability of this antibiotic was investigated using an anaerobic/aerobic sequential reactor system, sonicator, and a photocatalytic reactor with titanium (IV) oxide nanoparticle in a raw hospital wastewater. Effect of temperature, sonifiction time and sonicator frequency were chosen for operating parameters of the sonicator. UV light power, effect of retention time and effect of nanoparticle concentration on the micropollutant yield were determined for the operating parameters of photocatalytic process. COD and ciprofloxacin yields were determined. Methane gas productions and VFA concentrations were also monitored in anaerobic reactor. pH changes, dissolved oxygen variations, and redox potentials were monitored in anaerobic and aerobic reactors. Furthermore, the effects of HRT on the pollutant yields was researched in both reactors. For the mentioned reactors, it was found that the high treatment yields for COD (90%) and ciprofloxacin (95%) pollutants were obtained with sonication and photocatalytic processes. Keywords: Biological treatment, Ciprofloxacin, Photocatalytic, Sonication, Titanium (IV) oxide nanoparticle. 95 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Integrating Storage Sizing and Slow Sand Filtration for Residential Rainwater Harvesting Applications in the Philippines Engr. Maxell P. Lumbera* 1, Engr. Rodgie Ello P. Cabungcal 2 1, 2 Institute of Civil Engineering, College of Engineering, University of the Philippines – Diliman, PHILIPPINES. (E-mail: [email protected], [email protected]) ABSTRACT With the increase in population coupled with the inadequacy of water supply, rainwater harvesting technology plays a vital role. Rainwater harvesting (RWH) technologies refer to methods employed to collect and store rainwater to supplement the demand of the population. The design of its components, specifically the storage component, is highly dependent on the rainfall pattern for a given locality. The main objective of the study is to develop guidelines that for rainwater harvesting that will provide water for residential non-potable applications. In this study, the researchers analyzed the rainfall patterns of each climatic region by considering representative areas such as Sangley (Cavite), Daet (Camarines Norte), Tanay (Rizal), and Davao City (Davao del Sur) to determine the recommended tank size for each region. Using the Yield-After-Spill Algorithm, we found out that rainwater harvesting systems are more reliable in Daet in Camarines Norte Province (Type II Climate) and least for Sangley in Cavite Province (Type I Climate). Reliability curves, showing the portion of the time that the demand is being met by the RWH system, are made to aid in decision making. To improve the quality of harvested rainwater, the study proposed to incorporate the following treatment technologies: leaf guards, first flush diverters and slow sand filtration. Actual rainwater harvesting and treatment systems were incorporated to the UP BRS Model House. Finally, ways to promote RWH technology were also discussed such as education and awareness programs, demonstration projects, and networking between government and non-government institutions. Keywords: Rainwater harvesting, Reliability, Slow sand filtration, Yield-after-spill algorithm Acknowledgment: To be filled up soon 96 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Color From Textile Wastewater By Adsorption On Sunflower Seed Shell , Cappadocia 2015 Elif B. Duran* 1, Sumeyye Akarsu 2, Yakup Cuci 3 and Mustafa Dolaz 4 1,2,3,4 Kahramanmaras Sutcu Imam University, Engineering and Architecture Faculty, Dept. of Environmental Engineering, Kahramanmaras, TURKEY (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Carbon prepared from waste plants for the treatment of dyeing industry effluents has high significance in environmental sustainability and economic viability. There are five main methods used for the treatment of dye-containing effluents: adsorption, oxidation–ozonation, biological treatment, coagulation–flocculation and membrane process [1]. Adsorption process is noted to be superior to other removal techniques because it is more economical, simpler and it is capable to efficiently treat dyes in a more concentrated form. Activated carbon is the most popular and widely used dye absorbent. Because ; its surface area is very large. In this paper, the potentional of low-cost adsorbent such as sunflower seed shells in the removal of the synthetic dye from aqueous solutions was investigated. Sunflower seed shells were preferred because it has a rich content of organic angle. In this study, it was carried out that two different types of activated carbon were produced and characterized from sunflower seed shell with chemical and physical activation. Optimum conditions for the adsorption process were determined by using of resulting activated carbons for removal of methylene blue and Mn from aqueous solution, investigating adsorption properties under various conditions (pH, temperature, adsorbent dosage, contact time, methylene blue and Mn concentrations). Adsorption kinetics, isoterms and thermodynamic (ΔH0, ΔS0, ΔG0) parameters were examined. Results obtained indicate that the removal efficiency of Methylene Blue varies from 88 to 91,3% by rising the temperature from 30 to 60°C at pH from 6 to 8. The removal efficiency of Mn varies from 83 to 83,7% by rising the temperature from 30 to 60 °C at pH from 6 to 8. With reference to the values obtained in the study result shows that the chemical adsorption occurs . The results fit the Freundlich model for adsorption of Methylene Blue and Mn on sunflower seed shell carbon. Keywords: Adsorption , Methylene Blue , Sunflower Seed , Activation , Textile Wastewater References [1] G.M. Walker, L. Hansen, J.A. Hana, S.J. Allen. Kinetics of a reactive dye adsorption onto dolomitic sorbents. Water Res., 37 (2003), pp. 2081–208. 97 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Do Personal Care Detergents Pose Risk in the Aquatic Environment: Characterization and Ecotoxicity Investigation Kizek O. 1, Çiftçi İ. D. 2, Ekmekyapar F. *3, Sicigliano A.4 and Meriç, S5. 1, 2, 3, 5 Department of Environmental Engineering, Faculty of Çorlu Engineering, Namık Kemal University, TURKEY. (E-mail: [email protected]; [email protected]; [email protected], [email protected]) 4 Department of Biology, Ecotoxicology Research Laboratory, Naples University, ITALY (E-mail: [email protected]). ABSTRACT Micro-pollutants (MP s) are mainly known to originate from human activities and discharged to aquatic environment. Most of MP are harmful to aquatic organisms. Acute and chronic toxicity tests have been reported that some of MPs displayed different end points of corresponding aquatic organisms even at low concentrations. Personal care products, composed of various chemicals as comp lex mixture nature, are evaluated among those MPs found often in treated sewage or grey water. Among personal care products, detergents are forming specific complex mixtures containing various endocrine disruptor chemicals, to be handled accurately. Hence, in this study, acute toxicity of seven personal care detergents was investigated. Two main groups of personal care detergents including shampoo (4) and shower gel (3) collected from different Hotels located in different countries were studied. Chemical characterization (Chemical oxygen demand, Total organic carbon) and pH were performed according to Standard Methods. TOC was measured using a Shimadzu TOC analyzer (6KVA model) at Center Laboratory of Namık Kemal University (NABILTEM). Acute toxicity of synthetic solutions prepared by dissolving personal care detergents in distilled water was assessed on two freshwater crustaceans Daphnia magna and Ceriodaphnia dubia according to ISO 6341 Method. New born daphnids (<24 h) were exposed to the solutions at various dilution ratios after adjusting pH at 8.0. Experiments were performed as four replicate and 5 daphnids were tested in each replicate. Acute toxicity was assessed for 24 and 48 h of exposure time by dividing the number of immobile organisms by total tested organisms (20) and immobilization percentiles were scored for each sample tested. By this way it was possible to calculate the concentration which gave rise to a 50% population immobilization, indicated as EC50 using PROBIT program. The results of chemical characterization showed that the biodegradability by means of TOC/COD ratio of personal care detergents was low. Ceriodaphnia dubia was observed to be more sensitive than Daphnia magna regarding lower EC50. All tested chemicals were found to be harmful according to EC toxic chemical’s evaluation scoring system. Keywords: Acute toxicity, characterization, personal care detergents, risk evaluation 98 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of dyestuff from wastewater using calcined waste eggshell T. E. Köse Chemical Engineering, Eskişehir Osmangazi University, TURKEY. (E-mail: [email protected]) ABSTRACT Many industries like the textile industry used dyes to color their products and thus produce wastewater containing organics with a strong color. The removal of color from waste effluents becomes environmentally important because even a small quantity of dye in water can be toxic and highly visible [1]. In this study, removal of dyestuff (Reactive Levafix Rot, 543 nm) from wastewater was examined using calcined waste eggshell (CWE). The pore properties including the BET surface area, pore volume, pore size distributions of waste eggshell (WE) and calcined waste eggshell (CWE) were characterized. After calcinations, the major inorganic composition was identified as CaO (95.91%) and MgO (1.5%) , C (2.5%) was the minor compositions. Calcination increased the pore structure of the eggshell. In the batch mode adsorption studies, the effects of calcinations temperature of eggshell, contact time, initial dyestuff concentration of solution, adsorbent dosage, on the dyestuff adsorption by the CWE have been studied. The maximum sorption (100%) value for dyestuff from 50 mg/L dyesstuff solution with 0,5 g CWE with calcination temperature of 800oC was observed at 25 oC for 4 hours. A comparison of kinetic models applied to the adsorption of dyestuff onto CWE was evaluated for the pseudo -second order kinetic model. In the isotherm studies, the Langmuir, Freundlich and Dubinin–Radushkevich (DR) isotherm models were applied. The results indicate that Langmuir equation is well described with the dyestuff adsorption. Keywords: Dyestuff, Adsorption, Eggshell, Kinetic, Isotherm. Reference [1] A.Y. Zahrim, C. Tizaoui, N. Hilal. “Coagulation with polymers for nanofiltration pre-treatment of highly concentrated dyes: A review” Desalination, 266, 1-16 (2011). Acknowledgements I thank to my diploma project students. 99 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparative photocatalyticdegradation, detoxification and demineralization of a biologically treated textile effluent using TiO 2 and ZnOnanoparticles DenizİzlenÇifçi1*, Sema Terzi 1, SüreyyaMeriç 1 Department of Environmental Engineering, Çorlu Engineering Faculty,Namık Kemal University, Çorlu 59860- Tekirdağ, TURKEY. (E-mail:[email protected]) ABSTRACT Textile industry wastewater treatment effluent generally contains large volume of colored effluents, and contain various textile chemicals which are assessed to be toxic,carcinogenic posing harmful effect to aquatic environment.Besides, soluble or particulate COD in the effluent in the biologically treated effluents general cause a need to search advanced treatment technologies to comply with the strict discharge limits. Advanced Oxidation Processes (AOPs) have been studied as innovative and emerging alternativesin this manner.AOPs provides a high or complete removal of color, COD and toxicity in the effluents. However these processes always need a toxicity based optimization to obtain safe effluent for the environment. The present study aimed to compare the photocatalytic activity of TiO2 and ZnO in textile wastewater treatment effluents and to investigate the effect of catalyst concentration and pH on the rate of photocatalytic degradation. Tretated textile wastewater effluents were collected by three different times from a dyeing and finishingtextile industry biological wastewater treatment plant. Chemical oxygen demand (COD), Total organic carbon (TOC), total suspended and volatile solids (TSS and VSS), conductivity, total khejdahlnitrogen, ammonia-nitrogen, alkalinty, and pH parameters of the effluents were determined according to Standard Methods.Photocatalytic treated samples using ZnO and TiO2 namoparticles (Sigma Aldrich) were analyzed by means of COD, TOC (Shimadzu TOC analyzer (6KVA model)), color (UV436UV525 and UV620), and aromaticity (UV254) (Shimadzu UV-2401).Acute toxicity of the oxidized samples was assessed on freshwater crustaceans Daphnia magna(new born daphnids <24 h)according to ISO 6341 Method. All analyses and treatment studies were performed at NKU Environmental Engineering Department and Central Laboratory (NABİLTEM). Photocatalytic experiments displayed a complete decolorization within 3 hoursfor both TiO2 and ZnO catalyst treated samples.The oxidation results indicate that removal rates of TOC, COD and color are severely dependent on catalyst concentration and pH. Photocatalytic oxidation rate in TiO2treated samples were obseved to be higher than the ZnO treated samples. This is attributed to the lower nanoparticle size of TiO2 than ZnO. Acute toxicity significatly decreasedin both TiO2 and ZnO treated samples after 3 hours ofoxidation. It is concluded that photocatalytic process is promising for reuse of treated textile wastewaters. Keywords:Acute toxicity, textile wastewater, photocatalytic degradation 100 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Role of plant biomass structures on performance of engineered wetland for treating boron (B) mine effluents Onur Can TÜRKER* 1, Cengiz TÜRE2, Harun BÖCÜK 2, Arzu ÇİÇEK 3 and Anıl YAKAR 2 1 Aksaray University, Faculty of Science and letters, Department of Biology, TURKEY (E-mail: [email protected]) 2 Anadolu University, Faculty of Science, Department of Biology, TURKEY (E-mail: [email protected], [email protected], [email protected]) 3 Anadolu University, Center for Applied Environmental Research, TURKEY (E-mail: [email protected]) ABSTRACT Engineered or constructed wetlands (CWs) are designed for different type of wastewaters such as mine effluent due to their simple operation, low cost construction and maintenance. In recent years, several studies corresponded to determine how constructed wetlands can be applied for boron (B) removal in laboratory and field conditions. However, effect of plant biomass on B treatment process in constructed wetlands is still lacking. The objection of this research was to investigate effect of plant biomass structures on performance of CWs for B mine effluents. The study was performed for 154 days in Kırka-Eskisehir where the largest borax reserves in all over the world. Totally, ten subsurface CWs with different plant biomass structure have been established in research area for treating B mine effluent. The constructed wetlands were to: 1 unplanted, 4 monocultures (15 plants/CW) of Typha latifolia, Typha angustifolia, Phragmites australis and Juncus gerarrdii, and 5 polycultures of four species mixtures (5 plants/species/CWs). The CWs were operated under controlled by environment and influent and effluent from each CWs were sampled every 2 weeks and physico -chemical parameters (pH, EC and Temperature) and B concentration were analyzed. The results of this study indicated that monoculture CWs have shown better B removal performance compare to polyculture CW systems. On average, we found that monoculture CW planted by T. latifolia has greater B removal capacity among the monocultures CWs. Consequently, the study had shown that B removal performance of CWs could be affected by presence of plants in CWs, plant community structure and wetland type in terms of monoculture or polyculture. Keywords: Constructed wetland, Boron (B) removal, B mine effluent, plant structure. Acknowledgment: The authors thank the scientific and technological research council of Turkey (TÜBİTAK) [Project number: 113Y335] and Anadolu University, Scientific Research Project Funding (AUBAP) for their financial support [Project number: AUBAP 1403F098]. 101 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Eriochrome Black-T from aqueous solutions using nZVI and S. cerevisiae modified with nZVI U. A. Guler*1, O. Kundakci 1 Department of Environmental Engineering, Engineering Faculty, Cumhuriyet University, Sivas 58140, TURKEY 1 (E-mail: [email protected]; [email protected]) ABSTRACT Azo dyes are the major group of dyestuffs and have been extensively used in textile, printing, cosmetics and leather industries. The azo dyes such as Eriochrome black-T (EBT) is hazardous and its degradation products are stil more carcinogenic. In the present study, nZVI and S. cerevisiae modified with nZVI (S.cerevisiaenZVI) have been synthesized and used as adsorbents for removal of EBT from aqueous solutions. S.cerevisiae-nZVI was used to enhance reactivity of nZVI and prevent aggregation. The nZVI and S.cerevisiae-nZVI were characterized by FTIR, XRD and SEM. The specific surface areas (SBET) of nZVI and S.cerevisiae-nZVI were found as 12.41 m2/g and 21.01 m2/g, respectively. The adsorption studies were carried out under various parameters, such as pH, composite amount, contact time, initial EBT concentration, temperature and different cations (Cu2+ and Na+). The maximum removal efficiency of EBT by nZVI and S.cerevisiae-nZVI was found as 45% and 85%, respectively. Langmuir, Freundlich and DubininRadushkevich (D-R) isotherm models were applied to the equilibrium data. The maximum adsorption capacities for EBT of nZVI and S.cerevisiae-nZVI were determined as 5.38 mg/g and 30.27 mg/g from Langmuir isotherm model, respectively. The kinetic and thermodynamic studies were done. As a result, S.cerevisiae-nZVI have better removal efficiency compared with nZVI and it plays an important role in the treatment process of EBT wastewaters. Keywords: Eriochrome Black T, S. cerevisiae, nZVI, characterization, removal Acknowledgment: The authors thank Cumhuriyet University, Scientific Research Project Funding (CUBAP) for their financial support [Project number: M-547]. 102 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of tetracycline from aqueous solutions by nanostructured Fe(III)-Cu(II) binary oxide U. A. Guler*1, H. Celik1 Department of Environmental Engineering, Engineering Faculty, Cumhuriyet University, Sivas 58140, TURKEY 1 (E-mail: [email protected]; [email protected]) ABSTRACT Antibiotics are widely used therapeutically for humans and animals and disease control. Significant concerns have been raised over the presence of antibiotics including tetracyclines (TCs) in aquatic environments. In the present study, a novel nanostructured Fe(III)-Cu(II) binary oxide has been synthesized with basic coprecipitation method and used as adsorbent for removal of TC from aqueous solutions. The Fe(III)-Cu(II) binary oxide was characterized by FTIR, XRD and SEM. The experimental studies were carried out under various parameters, such as pH (2-4-6-8-10), initial TC concentration (25-50-75-100-150-200-300-500 mg/L), amount of Fe(III)-Cu(II) binary oxide (1-2.5-5 g/L), contact time (5-10-15-30-60-120-180 min), and temperature (298-308-318 K). The maximum removal efficiency of TC by Fe(III)-Cu(II) binary oxide was % 93 at pH 4. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models were applied to the equilibrium data. The maximum adsorption capacities for TC of Fe(III)-Cu(II) binary oxide was found as 157.48 mg/g from Langmuir isotherm model. The kinetic and thermodynamic studies were done. As a result, Fe(III)-Cu(II) binary oxide could be a very promising material in the removal process of TC from wastewater because of its a good performance and simple and low-cost synthesis process. Keywords: Tetracycline, Fe(III)-Cu(II) binary oxide, characterization, removal 103 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Decolorication of Reactive Black 5 by Potassium Ferrate (K2FeO4) Serkan Şahinkaya*, Erkan Kalipci and Huseyin Cüce Department of Environmental Engineering, Nevsehir Hacı Bektaş Veli University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT In this study, the color removal from the solution containing Reactive Black 5 (RB 5) dye and polyvinyl alcohol (PVA) was investigated by potassium ferrate (K2FeO4). K2FeO4 is an environmentally-friendly chemical reagent containing iron in the + 6 oxidation state and can be used for color removal from the wastewaters as an oxidant. The effects of the oxidant concentration, initial solution pH, dye concentration and temperature on color removal were studied, and the removal efficiencies of chemical oxygen demand (COD) and total organic carbon (TOC) were also examined at room temperature. While approximately 90% decolorizing efficiency was achieved by K2FeO4, the removal of COD and TOC removal were 55,4% and 18,6%, respectively. Keywords: COD, color removal, potassium ferrate, PVA, RB 5. 104 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Recovery Of Acid And Heavy Metal In Surface Coating Industry By Best Available Techniques Tarık Kotan a, Gülfem Bakanb A Yeşilyurt Demir Çelik Vocational School of Higher Education, 19 Mayıs University, 55300 Tekkeköy, Samsun, Turkey, e-mail: [email protected] B Department of Environmental Engineering, 19 Mayıs University, 55215 Atakum, Samsun, Turkey, e-mail: [email protected] ABSTRACT This study focuses on improvements in process and acid (H2SO4) and metal (Cu) recovery with recovery technologies through use of Best Available Techniques in metal plating industry. Chances of recovery during activation stage and plating stage have been evaluated. Administrative and technological measures to minimize the losses resulting from drag out in system have been reviewed. Concerning this, it was noted that an acid and metal recovery of 25-30% could be obtained if the shaking duration was between 15 and 20 seconds. However, activation and plating baths have been handled separately and especially technologies on acid and metal recovery from the wash water within these processes have been reviewed. Acid retardation system has been used for activation process and this system has been designed to work as a closed system with the addition to water. As a result of the laboratory scaled applications, it was noted that an acid (H2SO4) recovery of 75-80% could be obtained. By this means, it was noted that S04-2 concentration to wastewater treatment plant has been reduced by 80%. However, Best Available Techniques for metal recovery in plating system have been reviewed and two different processes for cyanide and acidic plating have been designed. This system has been added to the end of washing baths at the end of the plating baths. Here, ion exchange system and nanofiltration (NF) have been used and thanks to this, 70-80% of copper has been recovered. In addition 80-85% of water has also been recovered. It was estimated that copper concentration to wastewater treatment plant may have been reduced by 75-80%. With regard to this study, it was determined that evaluation of recovery chances would be more economic and the investment would pay for itself in a shorter period. Besides, waste production may be prevented substantially by first taking administrative measures in best technique practices. Keywords:Sustainable production, Best Available Techniques, Surface Coating Industry 105 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Acid Violet 90, Basic Yellow 28 and Direct Blue 86 by Fe3O4 Embedded Polymer C.S. Keskin* 1 1 Faculty of Arts and Science, Department of Chemistry, Sakarya University, TURKEY. (E-mail: [email protected]) ABSTRACT Dyes are extensively used in many fields such as textile, leather, paper, food industries. These extensive applications of synthetic dyes create environmental pollution and the ir toxic properties cause health risk. In recent years, nanomaterials are also commonly used for the removal of dyes. The non modified and modified magnetic nanoparticles are also used for removal processes. The iron oxide based magnetic nanomaterials are preferred due to small size, high surface area, easy separation and reusability features of these nanoparticles. The objective of the present work was to find out the dye removal capability of Fe 3O4 embedded polymer. For this purpose, the Fe 3O4 nanoparticles were synthesized and added to the polymer network while polymerization. The synthesized Fe3O4 embedded polymer is treated with aqueous solution containing Acid Violet 90 (AV 90), Basic Yellow 28 (BY 28) and Direct Blue 56 (DB 56) by batch system. The dye concentrations in treated solutions were analyzed in UV-VIS spectrometer after centrifugation. The treated and non-treated Fe 3O4 embedded polymer were analyzed by fourier transform infrared spectroscopy to prove the adsorption. The obtained results showed that BY 28 can be fully adsorbed by Fe 3O4 embedded polymer. The color removal efficiencies for AV 90, BY 28 and DB 56 were 33.5%, 100% and 22% respectively under the conditions of adsorption time 150 min, agitation rate 150 rpm, temperature 25°C, initial dye concentration 50 mg/L and the Fe 3O4 embedded polymer dosage 0.2 g. Keywords: Fe3O4, Dye, Removal. 106 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Decolorization of Disperse Blue 56 and Reactive Yellow 145 by Acrylamide Based Polymer C.S. Keskin* 1 1 Faculty of Arts and Science, Department of Chemistry , Sakarya University , TURKEY. (E-mail: [email protected]) ABSTRACT Increasing international demand for textile materials has led to increasing demands for dyes. As more dye is used, huge amounts of polluted water is discharged into rivers. If those pollutants are not removed from the water, they affect the ecological system. Acrylamide is a monomer used to produce copolymers of polyacrylamide. Triazine derivatives have found widespread applications in the pharmaceutical, textile, plastic, rubber industries and also used as copolymer agent. This study aims to investigate the decolorization of Disperse Blue 56 (DB 56) and Reactive Yellow 145 (RY 145) from aqueous solution using Fe 3O4 embedded acrylamide based polymer. The acrylamidetriazine polymer was synthesized by UV photo initiation radical polymerization method. The synthesized polymer was washed with double distilled water and vacuum drying at 25°C. The removal experiments were carried out by adding 0.2 g acrylamide based polymer with rotary shaker. In order to measure dye concentrations, the solutions were analyzed by UV-Vis spectrometer. A single wavelength used to calculate the amount of dyes in solutions. The functional groups of acrylamide-triazine polymer were characterized by fourier transform infrared spectroscopy. According to the results, it is observed that the Fe3O4 embedded acrylamide based polymer is useful for the decolarization of DB 56. The color removal efficiencies for DB 56 and RY 145 were 100% and 41.1% respectively under the conditions of adsorption time 150 min, agitation rate 150 rpm, temperature 25°C, initial dye concentration 50 mg/L and acrylamide based polymer dosage 0.2 g. Keywords: Acrylamide, Decolorization, Polymer. 107 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biosorption of Disperse Blue 56, Basic Yellow 28 and Acid Violet 90 by Aspergillus Tamarii S. Yılmazer Keskin* 1 and A. Güler 1 1 Faculty of Arts and Science, Department of Chemistry, Sakarya University, TURKEY. (E-mail: [email protected], agü[email protected]) ABSTRACT Biosorption is one of the widely used methods for the removal of dye pollutants from dye contaminat ed effluents. Low cost, high efficiency, minimization, no additional chemical, regeneration are some advantages of biosorption. Mechanism of biosorptions is classified as extracellular accumulation, cell surface sorption, and intercellular accumulation. Fungi, yeast and algae are some of biomass materials used for biosorption studies. Aspergillus is a fungus widely used for most of removal of organic and inorganic pollutants. Several Aspergillus species have been used for biosorption such as niger, fumigatus, niveus, versicolor, flavus, terreus, cristatus and tamarii. This study aims to investigate the potential of dye adsorption capability of A. tamarii. For this purpose, A. tamarii is treated with aqueous solution containing Disperse Blue 56 (DB 56), Basic Yellow 28 (BY 28) and Acid Violet 90 (AV 90) by batch system. In order to measure dye concentrations, the solutions were analyzed by UV-Vis spectrometer. A single wavelength used to calculate the amount of dyes in solutions. The treated and non-treated biomass were analyzed by fourier transform infrared spectroscopy to prove the adsorption. According to the results, it is observed that AV 90 is more powerfully adsorbed dye among the studied dyes by dead A. tamarii biomass. The color removal efficiencies for DB 56, BY 28 and AV 90 were 69.5%, 8.2% and 95.5% respectively under the conditions of biosorption time 150 min, agitation rate 150 rpm, temperature 25°C, initial dye concentration 100 mg/L and biomass dosage 0.5 g. Keywords: Aspergillus tamari, Biosorption, Dye. 108 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Direct Blue 86 and Reactive Yellow 145 by Dead Biomass S. Yılmazer Keskin* 1 and A. Güler 1 1 Faculty of Arts and Science, Department of Chemistry, Sakarya University, TURKEY. (E-mail: [email protected], agü[email protected]) ABSTRACT Dyes are common pollutants in a large variety of industrial wastewaters and the treatment of these wastes has been extensively studied by adsorption. The greatest environmental concern with dyes is their absorption in water and reflection of sunlight, which interferes with the growth of bacteria, limiting it to levels which are insufficient to biologically degrade impurities in the water. For the removal of pollutants from the wastewaters, many chemical and physical methods different techniques have been used and adsorption have gained considerable importance in recent years because of their proven efficiency. The objective of the present study is to investigate the removal of Direct Blue 86 (DB 86) and Reactive Yellow 145 (RY 145) from aqueous solution via adsorption using dead biomass. The fungus A. tamarii Kita MRC 72400 was autoclaved to obtain dead biomass and filtered off and washed with double distilled water. UV-VIS spectrometers are used for concentration calculations which based on measurement at a wavelength corresponding to maximum absorbance of dye. The calibration procedure was carried out by using 9 calibration standards prepared using different concentration of each dye. DB 86 and RY 145 concentrations were varied between 0.1 to 100 mg/L. The functional groups of dead biomass were characterized by fourier transform infrared spectroscopy. The color removal efficiencies for DB 86 and RY 145 were 93.5% and 84.6% respectively under the conditions of adsorption time 150 min, agitation rate 150 rpm, temperature 25°C, initial dye concentration 100 mg/L and dead biomass dosage 0.5 g. Keywords: Adsorption, Dye, Dead biomass. 109 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Anions on Arsenic Removal from Groundwater by Air Feed Electrocoagulation Reactor Using Iron Ball Anodes E. Şık1, E. Gengeç 2, M. Kobya 3, E. Demirbas 1 and M.S. Oncel 3 1 Environment and Cleaner Production Institute, Tübitak Marmara Research Center, TURKEY. (E-mail: [email protected]) 2 Department of Environmental Protection, Kocaeli University, Arslanbey-Kocaeli,TURKEY. (E-mail: [email protected]) 3 Department of Environmental Engineering, Gebze Technical University, TURKEY. (E-mail: [email protected], [email protected]) 4 Department of Chemistry, Gebze Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT Removal of arsenic from groundwater by the air-injected electrocoagulation (EC) reactor using Fe ball anodes was investigated and the operating conditions were optimized. Effects of anions such as CPO4-P (1-10 mg/L), CSiO3-Si (20-80 mg/L), CHCO3 (130-670 mg/L), CF (2-10 mg/L), CB (5-10 mg/L), CNO3-N (5-35 mg/L) on the removal efficiency of arsenic at 0.15 A, Fe ball size of 7.5 mm, pH 7.5 and air flow rate of 6.0 L/min in the EC reactor were evaluated with Box-Behnken statistical experiment design. The model program provided with responses such as effluent arsenic concentration, removal efficiency, and operating cost of the EC process. Analysis of variance for all variables had confirmed the predicted models by the experimental design within 95% confidence level (R2: 0.92, Adj-R2: 0.83), which ensured a satisfactory adjustment of the quadratic model with the experimental data. Removal efficiency of arsenic was reduced with increasing concentrations of CSiO3-Si from 50 to 80 mg/L and CPO4-P from 5.5 to 10 mg/L while its removal efficiency is increased with increase in operating time. The rest of the anions show hardly noticable effect on the removal effciency of arsenic. The maximum removal efficiency of arsenic and minimum operating cost at the optimized conditions (CPO4-P = 1.80 mg/L, CSiO3-Si = 22.95 mg/L, CHCO3 = 623.6 mg/L, CF = 2.07 mg/L CB = 7.88 mg/L, CNO3-N = 23.12 mg/L ve tEC = 6.9 min for As concentration of 200 μg/L were obtained as 99.4%, 0.0384 $/m3, 9.0 μg As/mg Fe (removed capacity of arsenic per mg) and effluent concentration of 0.4 μg/L, respectively. Keywords: Arsenic removal, Anion, Electrocoagulation, Operating cost, Optimization Acknowledgment: The authors thank TUBITAK for their financial support [Project number: 111Y103]. 110 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Preparation of Polyacrylonitrile Ion exchange fibre (PAN-IEF) for the removal of arsenic Khadija Qureshi* 1, Inamullah Bhatti 2 and Zulfiqar Solangi 3 1, 2 Department of Chemical Engineering, Mehran University of Engineering and Technology Jamshoro,PAKISTAN. (E-mail:[email protected] [email protected] 3 Department of Chemical Engineering, Mehran University of Engineering and Technology Jamshoro, PAKISTAN (E-mail: [email protected]) ABSTRACT Efficient Ion exchange fiber was produced from semi-carbonized polyacrylonitrile fiber using diethylenetriamine as crosslinking agent and hydrolyzed to develop the carboxyl and amine groups. . Different techniques such as Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy were used for modification of the PAN fiber The FTIR showed the adsorption peaks in the range of 2220 cm 1, nitrile group 1700-1750 cm-1 carboxyl group and 500-900 cm-1 amines groups. The SEM showed that the surface of ion exchange fiber got rougher due to hydrooxlation of nitrile group. GA/TGA study indicated lowest degradation temperature 40 C and highest degradation temperature of 525 C. With the reduction in time the Tenacity 90% and elongation rate reduced to 70 %. The average stretching resistance of 0.9 N was detected. The column study was also conducted which revealed arsenic adsorption capacity of 9mg/gm. Keywords: Crosslinking, Column, Fiber, FTIR, SEM, Acknowledgment: The authors thank Pak-US Science and Technology Program for providing the research project to conduct this study. 111 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 APPLICATIONS OF HYBRID SYSTEM IN WATER AND WASTEWATER- REVİEW 1 Gülizar K. Akkaya, 2M. Sinan Bilgili 1,2 Gülizar Kurtoğlu Akkaya, Mehmet Sinan Bilgili, Yıldız Technical University, Faculty of Civil Engineering, Deparment of Enviromental Engineering, İstanbul. (E-mail: [email protected], [email protected] ) ABSTRACT One of the major challenges facing many countries around the world with incresing population is to provide clean water for various human activities such as agricultural, industrial and drinking. Recently, the available conventional wastewater treatment tecnologies are no longer responding to new standarts in conjuction with thightened wastewater discharge standards. Therefore, there is an increasing desire for the development of innovative, more effective and inexpensive techniques for wastewater treatment. The aim of this work was to review studies, conducted with submerged electro-membrane bioreactor “seMBR” system which is a new treatment method. “seMBR system”. seMBR system is one hybrid system which comprise of the three main processes in only unit: biological treatment, electrocoagulation and membrane filtration. Their combination would produce an excellent quality effluent. There are a lot of studies related to waste water and water recovery with this system and these studies showed that this method realized better a biological treatment and it is well good in developing floc formation compared to convantional systems. Also, when it is looked at the recent researches related to this system, the problems in membrane fouling is observed in much less quantities as opposed to conventional systems. Reseaches on the treatment of real and synthetic wastewater which have different and specific properties are still continuing. The obtained data showed that seMBR system is a promising method in water and wastewater treatment owing to advantages such as a system containing many processes together, remediation of the sludge characteristics and decreasing of problems in membrane fouling. Keywords: Wastewater, seMBR, Biological, Membrane, Electrocoagulation. 112 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Nickel (II) Pollution in Water by Diatomite Melayib BİLGİN 1, Şevket Tulun* 2 1, 2 M. Bilgin, Ş.Tulun’ Faculty of Engineering, Aksaray University, AKSARAY. (E-mail: [email protected], [email protected]) ABSTRACT In our industry one of the biggest environmental problem is the water which is mixed nickel and its compounds. In this study the nickel which is the reason of pollution was tried to be eliminated by the absorption method using diatoma. In this study NiCl2 * 6H2O solution was used and firstly discontinuous system optimization was made. In the first step specifications of the sorbent was determined for this reason proper quantity and 4 different amount of sorbent was used. After then contact time to effect of absorption was determined. The effect of the pH to absorption was evaluated with using 5 different pH value. As a result of experiments Nickel was removed % 81, 47 from the waste water in conditions of using 5 gr material at pH 5 for 60 minutes. Figure 1. Effect of pH on the removal of Ni(II) (initial concentration of Ni(II), 100 mg/L; diatomite concentration, 5g/L; shaking speed, 250 rpm; contact time, 60min.; temperature, 293 K). Key words: Nickel, Diatomite, Adsorption, Water Pollution. 113 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption kinetic studies for the removal of NH4-N from landfill leachate by natural adsorbent Fulya Aydın Temel* 1, Ayşe Kuleyin 2 1 Department of Environmental Engineering, Engineering Faculty, Giresun University, TURKEY. (E-mail: [email protected]) 2 Department of Environmental Engineering, Engineering Faculty, Ondokuz May University, TURKEY. (E-mail: [email protected]) ABSTRACT The aim of this study is to investigate the removal of NH4-N from landfill leachate using natural Turkish zeolite by adsorption process. The effects of pH (2-8), contact time (5-1440 min), adsorbent dosage (30-150 g L-1), agitation speed (100-300 rpm), initial concentration (263.2-1363.6 mg L-1) and particle size (10-65 mesh) were examined on the adsorption process. The optimum conditions in the adsorption process were established as follows: pH (no significant in this study), 60 min of contact time, 100 g L-1 of adsorbent dosage, 200 rpm of agitation speed, 263.2 mg L-1 of initial concentration, and -20+35 mesh of particle size. The adsorption kinetics was used to understand the adsorption mechanism using three kinetic models, i.e., Elovich, intraparticle diffusion, the pseudo second order reaction kinetic models. Correlation coefficients of kinetic parameters were calculated. It is shown that the best conformity kinetic model is the pseudo second order reaction kinetic model (R2>0.99) for present study. The results indicate that zeolite was the most efficient cation-exchanger for NH4-N removal from landfill leachate. Keywords: landfill leachate, zeolite, kinetic, NH4-N, adsorption Acknowledgment: This work was financed by a scholarship of the Ondokuz May University for support of Scientific/Technological Research (Project MF-054). I thank the Ondokuz May University for providing the opportunity to research. 114 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Preparation of the poly(glycidyl methacrylate) Grafted onto Crosslinked poly(3 -Chloro-2Hydroxypropyl-Co-EGDMA) with Sorbitol Group and Use for Removing Boron from Water Gulcin Torunoglu Turan* 1, Bahire Filiz Senkal 1 1 Chemistry Department, Istanbul Technical University, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Although boron is an important micronutrient for plants, animals, and humans, its range between deficiency and excess is very narrow [1]. Molecules with three or more hydroxyl functions tend to bind boric acid tightly by forming either neutral boron ester or borate complex anion with a proton as counter io n. Since hydroxyl functions are non-reactive for common metal ions and other species in ordinary conditions complexation of these types of compounds produces a means of specific boron binding. In aqueous environments (neutral pH), boron is mainly present as boric acid, which cannot be easily removed by desalination membranes and conventional water treatment processes due to its high solubility mostly in an undissociated form. Up to the present, the most efficient adsorbent for separating boron from aqueous media is the boron-specific resin, typically the polystyrene-based resin with N-methyl-D-glucamine functional group [2-4]. In this study, crosslinked poly(3-chloro-2-hydroxypropyl-co-EGDMA) was synthesized and poly(glycidyl methacrylate) (PGMA) was grafted onto the prepared resin. PGMA grafted resin was reacted with excess of sorbitol to give sorbitol modified polymeric sorbent. The resulting polymeric sorbent has been demonstrated to be an efficient and regenerable specific sorbent for removal of boron in parts per million (ppm) levels. Kinetics of boron sorption and regeneration of the polymer were also investigated. Keywords: Boron removal, polymeric sorbent, sorbitol, glycidyl methacrylate References: [1] I. Novozamsky, V.J.G. Houba, J.J. van der Lee, R. van Eck, M.D. Mignorance (1993). A convenient wet digestion procedure for multielement analysis of plant materials. Commun. Soil Sci. Plant Anal. 24, pp. 2595–2605. [2]. W.R. Lyman, A.F. Preuss (1957). Boron adsorbing resin and process for removing boron compounds from fluids. US Patent 2813838, Rohm & Haas Company, 1957. [3]. R. Kunin, A.F. Preuss (1964). Characterization of a boron specific ion exchange resin. Ind. Eng. Chem.: Prod. Res. Dev. 3, pp.304–306. [4]. S. Sahin (1996). Mathematical model of boron adsorption by ion exchange, ACH: Models Chem. 133, pp.143–150, 1996. 115 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Maxilon Red GRL from Aqueous Solutions Using Niğde (Bor) Grape Molasses Soil as a Low-cost Adsorbent F. Çiner* 1, S. Şahin2, S. Battal 3, E. Sezer 4 and A. Dumlu5 1, 2,3,4,5 Environmental Engineering Department, Niğde University, TURKEY. (E-mail:[email protected], [email protected], [email protected], [email protected], [email protected] ) ABSTRACT Dyes are widely used in industries such as textiles, dyestuff, leather, paper, cosmetics, plastics, foods, etc., to color their products. Because many organic dyestuffs are harmful to human beings and hazardous to aquatic organisms, removal of dyestuffs from wastewater has received considerable attention over the past decades. Various methods such as adsorption, coagulation, advanced oxidation, aerobic and anaerobic degradation, membrane separation process, and reverse osmosis are used in the removal of dyes from wastewater. Adsorption is one of the most effective processes of advanced wastewater treatment which industries employ to reduce hazardous inorganic/organic pol lutants present in the effluent. In this study, the removal of Maxilon Red GRL from aqueous solutions by adsorption onto raw soil sample known as Niğde (Bor) grape molasses soil was studied. This soil which constituted of mostly calcite was used for sedimentation for making grape molasses. The effects of various experimental parameters such as pH, temperature, contact time, initial adsorbent dose, and initial dye concentration on adsorption efficiency were investigated. Langmuir and Freundlich isotherm models were applied to the equilibrium data. The experimental data were modeled by Langmuir and Freundlich isotherm models. Langmuir model resulted in the best fit of the adsorption data. This study indicated that the Niğde (Bor) grape molasses soil can be used as a low-cost adsorbent for the removal of a textile dye Maxilon Red GRL from its aqueous solutions. Keywords: Adsorption, Color, Isotherm, Grape molasses soil, Maxilon Red GRL. Acknowledgment: The authors thank the Scientific and Technological Research Council of Turkey (TÜBİTAK), for their financial support [TÜBİTAK 2209-A Project]. 116 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of total nitrogen by Juncus acutus and Cortaderia selloana from domestic wastewater in horizontal subsurface flow constructed wetland Fulya Aydın Temel*1, Yüksel Ardalı 2, Esin Avcı3 1 Department of Environmental Engineering, Engineering Faculty, Giresun University, TURKEY. (E-mail: [email protected]) 2 Department of Environmental Engineering, Engineering Faculty, Ondokuz May University, TURKEY. (E-mail: [email protected]) 3 Department of Statistics, Science and Art Faculty, Giresun University, TURKEY (E-mail: [email protected]) ABSTRACT In this study, a horizontal subsurface flow constructed wetland (HSFCW) system was designed and built to treat domestic wastewater in Kızılcaören village. The treatment bed was divided into two equal parts using curtain walls to evaluate the efficiencies of two different plant species (Juncus acutus and Cortaderia selloana) during the construction. Total nitrogen was evaluated during the operation period of 7 months. The average removal efficiencies of Juncus acutus and Cortaderia selloana plants were found as % 24 and % 40 for TN, respectively. However, two-way ANOVA between groups was applied to determine any difference for the removal of TN parameter between the plant types and months on the mean values of pollutant removal. As a result of the performed studies, it is seen that the subsurface flow constructed wetlands are quite efficient in the treatment of domestic wastewater. Moreover, it is proved that these systems are much more economical in terms of establishment and maintenance costs in comparison with the conventional treatment systems. Keywords: Juncus acutus; Cortaderia selloana; wastewater; constructed wetland, statistic Acknowledgment: This work was financed by a scholarship of the Ondokuz May University for support of Scientific/Technological Research (PYO.1904.11.017). I thank the Ondokuz May University for providing the opportunity to research. 117 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Nitrate from Domestic Wastewaters Using Algae Mohammad Izhar, Dr. Selim L. Sanin, Aydın Akbulut Hacettepe University, Department of Environmental Engineering, ANKARA, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Nitrogen is the most widely occurring element in our environment forming many inorganic ionic species, such as nitrate, nitrite and ammonium ions.The main anthropogenic sources of nitrates in the environment are domestic and industrial wastes and artificial fertilizers. The reactive form of N is nitrate, is the prominent form of nitrogen impurities in surface and groundwater. As like other world in Afghanistan also most communities rely on groundwater and surface water for their drinking needs. Nitrate is sensible in groundwater in Afghanistan and it has significant human health concern. Drinking water with high levels of nitrates may lead to health issues, including methemoglobinemia (also called blue-baby syndrome). Nitrate cause to many more negative effects including: euthrophication, turbidity, odor, taste and color etc. In this study three type of microalgae are investigated including spirulina platensis, chlorella vulgaris and scenedesmus obliquus in two medium, normal culture medium (BG11 and BBM) and the second one domestic wastewater (DWW) medium. The method of culture was batch reactor, in 600ml of culture medium (BG11, BBM and DWW) 60ml of microalgae was added From our laboratory stock by 1/10 part. 24 hours after cultivation the chlorophyll-a and COD has measured. The chlorophyll-a and COD of spirulina platensis, chlorella vulgaris and scenedesmus obliquus were measure for 8days, 26day and 26days respectively and the filtered sample have kept in refrigerator for further analysis by ion chromatography at next coming days. During the examinations COD shows decreases in early days, but increases by end of experiments. Some part of chlorella vulgaris in DWW medium has examined and shows the predominant decrease in nitrate that consumed by chlorella vulgaris. Keywords: COD, Nitrate, DWW, BG11,BBM DWW: domestic wastewater 118 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Heavy Metals Contamination and Chemical Speciation of water and Soils in the Vicinity of Sungun Porphyry Copper Deposit, NW Iran Kobra Esmaeili1, Naser Pirouznia2 and Farid Moore3 1: Department of Earth Sciences, College of Sciences, Shiraz University, Shiraz, Iran [email protected] 2: superintendent in geology at sungun copper mine,ahar,iran [email protected] 3:professor of department earth science,shiraz university,shiraz,iran [email protected] ABSTRACT In recent decades, attentions to preservation of environment have increased which affected the mining plans and activities. In this way, the Sungun Porphyry Copper Deposit which is located in the east Azerbaijan province, northwest of Iran was studied in this paper from the environmental point of view. It seems that river water and soils (pasture land) of this area are exposed to heavy metals contamination due to the geological condition and mining activates. The contamination degree of selected heavy metals (Cu, Mo, Pb, Zn and Ni) in water samples (44 samples) was calculated by the ratio of metal concentration to local background and global standards. Also, the relation between the elements in water and sediment samples was investigated using correlation coefficients analysis and factor analysis. The results show that concentration of selected heavy metals (Cu, Mo, Pb, Zn and Ni) exceeds the maximum allowable concentrations in water. Also, the results of multivariate analyses indicate that heavy metals in the water samples have similar behavior (except for Mo) during transportation in the riverine environment. The mean concentrations of Cu, Mo, Pb, Zn, Ni and Cd in the soil samples (39 samples) are above the critical levels of these elements in the soils. The results of sequential extraction (Tessier's method) of the above metals indicate that the most percentages of Cd and Mo are associated with the exchangeable fraction and have high environmental risk. According to risk assessment code, the soils of the Sungun area show medium environmental risk with respect to Zn. Also Cu, Pb and Ni contents in the third fraction are imperceptible in most of the samples which are posing a low environmental risk. Key words: Sungun Porphyry Copper Deposit, Environmental Assessment, Heavy Metal Contamination, Factor Analysis, Sequential Extraction, Risk Assessment Code. 119 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 European Market for Decentralized Waste Water Systems Dr.-Ing. Elmar Dorgeloh, Daniel Verschitz Development and Assessment Institute in Waste Water Technology at RWTH Aachen University, Germany E-mail: [email protected] PIA GmbH, Testing Institute for Wastewater Technology, Germany (NB 1739) E-mail: [email protected] ABSTRACT In terms of decentralized wastewater treatment, small wastewater treatment plants are suitable and state of the art. In Europe there is a need of approximately 20 million plants. A successful CE-marking and a correct declaration of performance is necessary to enter this market. To ensure a functional product all requirements regarding to construction and environmental aspects must be fulfilled. These requirements are defined in the European Construction Products Regulation and they are implemented in detail in EN 12566. This harmonized standard describes the different tests applicable to small waste water treatment plants. These are as follows: Proof of structural behaviour Treatment efficiency Test of watertightness Release assessment of dangerous substances Reaction to fire Determination of durability Power consumption Beside the activated sludge method, sequencing batch technology and fixed bed systems are common treatment processes among others. Beyond that small wastewater treatment plants can consist of different materials like concrete, plastic or steel and they can be deployed underground or in the basement of a house. The diversity and complexness leads to a significant number of applicable tests which shall be carried out by a notified testing laboratory. This procedure of assessment and verification of constancy of performance is the basic prerequisite of unimpeded access to the European single market. Keywords: CE-marking, Construction Products Regulation, Declaration of Performance, European Harmonized Standard, Notified Body, Small Wastewater Treatment Plants 120 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison of Wastewater Treatment Potential between Arthrospira platensis and Chlorella vulgaris Reza Rezaei, Aydın Akbulut and Selim L. Sanin Hacettepe University, Department of Environmental Engineering, Ankara, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Nutrient removal is one of the major challenges in the urban wastewater treatment. Excess concentrations of nitrate and phosphate in the wastewater can lead to algal bloom which is one of the main causes of fish deaths. Also some subsequent effects of algal bloom include release of toxins and its further health and environmental problems, depletion of dissolved oxygen in the water, intensive biomass accumulation and economic losses in some sectors like fishing and tourism. This study investigates the ability of nutrient removal in optimum pH and temperature in the artificial wastewater via two microalgae species Arthrospira platensis and Chlorella vulgaris. Achievement results show that more than 90% of nitrogenous compound (nitrate, nitrite and ammonium) and 70% of phosphate are removed over a short time from incubation. Because of the fluctuation in urban wastewater circumstance, the ability of adaptation is probed in two algae species and the removal amount of nutrient is measured in high nutrient concentration. To best of our knowledge the effect of algae acclimation to wastewater over the removal rate has been less rega rded in the literature, thus we consider this issue in this study. Keywords: Algal acclimation, Microalgae, Nutrient removal. 121 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Bioelectricity Generation from Wastewater Sludge Using Microbial Fuel Cells Seçil ÖMEROĞLU* 1 and F. Dilek SANİN 2 1, 2 Department of Environmental Engineering, Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Today, the energy of the global community is met using fossil fuels. The exploitation of oil and coal reserves resulted in a global energy crisis, raising questions about the future energy supply. Besides, current energy practices emit large amounts of greenhouse gases (GHGs) to the atmosphere, polluting the air we breathe in and contributing to global warming. As a result, within the last decade, countries have devoted significant efforts to investigate renewable energy technologies and bioenergy is one of the examples. Bioenergy is the conversion of biomass resources (i.e. agricultural residues, wastes, sludge) into useful energy forms through different technologies. Microbial fuel cells (MFCs) are one of the bioenergy technologies converting the chemical energy in organic wastes into electricity through the biocatalytic reactions of microorganisms. The fact that energy can be produced via degradation of organic wastes has been known for a century, but the use of this information to generate energy via MFCs has started to draw attention recently. MFCs can serve multiple purposes, not solely energy production. The microorganisms degrade the organic waste while generating electricity and this makes MFCs not only a renewable energy alternative but a perfect candidate for wastewater and sludge treatment. Especially, considering the energy consumption of conventional wastewater and sludge treatment systems, MFCs offer a sustainable solution that supply the energy required while achieving high levels of treatment. In addition to these, MFCs can be used in sensors, biohydrogen production and bioremediation. However, the technologic and economic problems with MFCs and their solutions have not been very well understood, limiting their large scale applications. The purpose of this study is to investigate the energy production and efficiency in MFCs fed with different types of wastewater sludges. The effect of key operational parameters will be identified and optimized to achieve high energy conversion efficiencies. Keywords: Bioenergy, Electricity Generation, Microbial Fuel Cell, Wastewater Sludge, Sludge Stabilization 122 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Treatment of anaerobic batch reactor of an automotive industry wastewater: Influence of substrateinoculum ratio and wastewater co-substrate ratio M.Sarioglu(Cebeci) * 1, Ö.B. Gökçek2 1, Environmental Engineering, Cumhuriyet University, TÜRKİYE. (E-mail: [email protected]) *2 Environmental Engineering, Niğde University, TÜRKİYE. (E-mail: [email protected]) ABSTRACT A study of the anaerobic treatment of an automotive industry wastewater was conducted at mesophilic temperature in batch mode. In this study, molasses was used as a co-substrate. The batch experiments were carried out with sample prepared as 500 ml bottles using a shaker in 35 ◦C temperature conditions. The concentration of inoculum was prepared to be 5000 mg/l VSS. Substrate-inoculum ratios (SIR) was determined as 0.5, 0.75, 1.0, and 1.25 and also molasses-waste water ratio was 1/3, 1.00 and 3. All tests were carried out against controls of inoculum without substrate. Speed of 150 rpm for the sample bottles was applied and in experiments were examined COD, pH, alkalinity, total solid, volatile fatty acid (VFA) and total gas analysis. Keywords: anaerobic batch reactor, ınoculum, substrate, co-substrate ,automotive industry. Acknowledgment: The authors thank Cumhuriyet University, Scientific Research Project Funding (CUBAP) for their financial support [Project number: CUBAP M-542]. 123 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Laboratory Scale Submerged Membrane Bioreactors (SMBR) for the Treatment of Rural Areas Wastewater O. Özkan1, M. Oğuz 1, Ö. Özdemir 2, Ş. T. Azgın 1, A. Solmaz 3, İ. Uyanık* 1 1 Department of Environmental Engineering, Engineering Faculty, Erciyes University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected]) 2 Malatya Water and Sewerage Administration, TURKEY. (E-mail: [email protected]) 3 Kayseri Organize Industrial Zone Treatment Plant, TURKEY. (E-mail: [email protected]) ABSTRACT Membrane systems have advantages over conventional treatment methods as they are small, easy to operate and low investment costs. Rural areas like small villages and towns have the capacity of pollution because their wastewater is not treated in most of the developing countries. Although they have small volumes of wastewater their potential to pollute water sources are huge. This study investigated the operation of a lab scale Submerged Membrane Bioreactor (SMBR) treating synthetic domestic wastewater. We set 2 polyethylene reactors (1 for primary settling, 1 for membrane filtration) as shown in Figure 1. Effective volume of the SMBR was 600 L and the flowrate was 50 L/h in two different recycle rates 100% and 200 % in a constant hydraulic retention time of 15 hours (HRT). 140 days of operation of the SMBR reactor was successfully finished in two phases: 90 days of constant influent COD concentration, (1090 mg/L), and 2 fold of this concentr ation for the rest of the study. COD removal efficiencies of the reactor were always more than 97,2% which indicated a good removal efficiency. The removal rates of the SMBR system for Total Nitrogen (TN) was between 60 -70% as the recycle rate was 100 %. It was increased to 76-84 % when the recycle rate was 200%. This difference was arise from the increase of the denitrification potential. When the COD of the wastewater were doubled, there was almost no difference in TN removal rates (between 52 % and 73 %) . Keywords: Membrane, Removal, Rural areas, Submerged Acknowledgment: The authors thank Erciyes University, Scientific Research Project Funding (ERU BAP) for their financial support [Project number: FBA-09-557 124 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Influent COD/TAN Ratio on Carbon and Nitrogen Removal Efficiency and Stability of Aerobic Granules Irem Kocaturk, Tuba H Erguder* Environmental Engineering Department, Middle East Technical University, Ankara, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Granular sludge is advantageous over the conventional activated sludge due to its high biomass content, settleability and tolerance for shock loadings. Aerobic granules eliminate the drawbacks of anaerobic granules such as long start-up period, relatively high operation temperature and inability to remove N. In particular, aerobic biogranulation is a suitable and up-to-date technology for N removal. There are many factors affecting the aerobic granulation and treatment efficiency. One of these is the Chemical Oxygen Demand (COD) to Total Ammonifiable Nitrogen (TAN) ratio. Relative amounts of N and COD in the substrate are also known to affect the composition and characteristics of the granules. The aim of this study was, therefore, set as to determine the optimum influent COD/TAN ratio and concentration range that provides the maximum TAN and COD removal efficiencies and stable aerobic granules. Two identical sequencing batch reactors (SBRs) seeded with aerobic granules were operated with varying COD/TAN ratios (1-30). R1 was operated at increasing COD/TAN ratios (7.5, 10, 20, 30), while R2 was operated at decreasing COD/TAN ratios (7.5, 5, 3.5, 2, 1). The results indicated that high COD/TAN ratios (7.5-30) provided high COD removal efficiency (around 92%) and low TAN removal (33%), favoring heterotrophs that form white, fluffy flocs and large granules. Maintenance of high treatment efficiency and granular stability is hard due to high growth rate of heterotrophs. On the other hand, low COD/TAN ratios (25) provided high TAN removal efficiency up to 100%, while COD removal was relatively low (60%); leading to small, dense, orange granules enriched in nitrifiers with slow-growing but stable characteristics. The optimum COD/TAN ratio in terms of high COD and TAN removal and granular stability was found as 7.5. It was found out that bacterial population distribution among nitrifiers and heterotrophs can be adjusted by changing influent COD/TAN ratios. Keywords: COD/TAN ratio, granulation, nitrification, SBR, simultaneous denitrification Acknowledgment: The authors thank Scientific and Technological Research Council of Turkey (TUBITAK) for their financial support [Project number: 111Y176]. 125 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Monitoring of molecular weight distribution by HPSEC with ultraviolet diode array and refractive index detectors in biologically treated bakery yeast wastewater Erhan Gengeç*1, Mehmet Kobya2 1 2 University of Kocaeli, Department of Environmental Protection, 41275, Kartepe, Kocaeli, Turkey Gebze Institute of Technology, Department of Environmental Engineering, 41400, Gebze, Turkey ABSTRACT Treatment of Baker’s yeast wastewater (BYW) is a necessary operation in order to recycle water and to meet discharge limits for the natural water environment. Effluents generated from Baker’s yeast manufacturing plants contain numerous organic matters as well as dark brown colored components (melanoidins). Several treatment processes such as chemical oxidation, adsorption, membrane processes, chemical coagulation, biological oxidation such as anaerobic-aerobic and electrocoagulation have been used in treatment of the BYW. Generally, anaerobic – aerobic treatment systems are used for removal of Chemical Oxygen Demand (COD). However, they are not effective for complete removal of color. The different removal efficiencies of COD and color intensity show that components causing COD and the color intensity are different from each other. Therefore, it is important to monitor the molecular weight distributions (MWDs) to understand the removal mechanism during anaerobic – aerobic stages. In this study, MWDs during anaerobic – aerobic stages is investigated by High Performance Size Exclusion Chromatography (HPSEC) with ultraviolet diode array (DAD) and refractive index detectors (RID). The chromatograms results show that there are three main fractions; high molecular weight components (HMWCs), intermediate molecular weight components (IMWCs) and low molecular weight components (LMWCs). IMWCs and LMWCs are biodegradable compounds in BYW. IMWCs have high amount of COD and low color intensity whereas LMWCs have low amount of COD and high color intensity. On the other hand the HMWCs are hardly biodegradable compounds which have low amount of COD and high color intensity in BYW. So conventional biological treatment systems are effective in removing COD from BYW; however, they are not sufficient for the removal of color. Probably the insufficient color removal in biological treatment systems is due to the aromaticity of components. The removal mechanism depends on the biodegradation of LMWC and biotransformation from HMWCs to LMWCs in the biological treatment. Keywords; Baker’s yeast wastewater, Molecular weight distribution, HPSEC 126 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Nickel Removal from Aqueous Solution by Iron Oxide Coated Sepiolite İ. Kıpçak* and C. Gürakan Akın Department of Chemical Engineering, Eskişehir Osmangazi University, Eskişehir, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Industrial wastewater very often contains nickel because it is widely used in a large number of industries such as electroplating, batteries manufacturing, mining, metal finishing , porcelain enameling and paint formulations. Nickel and its compounds are carcinogenic and may pose danger to human health and other life forms. Therefore, the concentration of nickel ions in wastewater should meet the applicable water quality criteria. Many conventional methods including adsorption, ion exchange, membrane filtration, flotation and precipitation have been reported in the literature to remove nickel ions from waste water. Adsorption can be considered as one of the most popular methods due to its low cost, simplicity of design and high removal efficiency. Iron, aluminum and manganese oxides are frequently used for coating of adsorbents, because these oxides usually have a large surface area, porous structure and an abundance of binding site metal ions are easily bound to them. The aim of this study was to investigate the removal of nickel ions from aqueous solution by adsorption using iron oxide coated sepiolite. Batch adsorption experiments were conducted using synthetic aqueous solution of nickel ions and the effects of adsorbent dosage, pH, contact time, initial metal concentration and temperature were investigated. The kinetics of adsorption has been studied, and various kinetic models, such as pseudo first order, pseudo second order and intraparticle diffusion models were tested with experimental data for their validity. The pseudo second order kinetic model was determined to correlate well to the experimental data. The Langmuir and Freundlich isotherms were utilized for the analysis of adsorption equilibrium. The Langmuir isotherm model was found to describe adequately the adsortion process. Maximum Langmuir adsorption capacit y was found as 46.95 mg/g for 25°C. Thermodynamics of the adsorption process has also been studied and the changes in Gibbs free energy, enthalpy and the entropy have been determined. Keywords: Adsorption, Iron oxide, Nickel removal, Sepiolite. 127 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of operational parameters on the removal of Acid Blue 161 dye from aqueous solutions by electrocoagulation with aluminum and stainless steel electrodes Sevde USTUN* 1, Nevzat BEYAZIT2 and Hanife BUYUKGUNGOR 3 1,2,3 Ondokuz Mayis University Environmental Engineering Department, 55200, Samsun,TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Pollutants such as dyes are harmful to humans and the environment. Therefore, it must be properly treated so that it does not cause more damage to the environment. Electrocoagulation (EC) is based on creating metallic ions and hydroxide flocks within the water by electrodissolution of the anode, usually made of iron or aluminum. The resulting metal ions and hydroxides have the ability to break emulsions and colloidal solution and to remove metal ions and organic pollutants, such as dyes by adsorption. The aim of this study is to investigate removal of Acid Blue 161 of 100 mg/L (color index number: 15706; anhydrated molecular weight: 1353.2; molecular formula: C 20H13N2O5SNaCr x; dye content: 45%; a commercial mono-azo dye, Sigma-Aldrich catalog number A4770) from synthetic solution by EC in a batch mode using aluminum (Al) and stainless steel (SS) electrodes. For this aim, effects of operating parameters such as electrocoagulation time (5-100 min), initial pH (3-9), current density (50150 A/m2), presence of NaCl as electrolyte (500-2000 mg/L) on the removal efficiencies and electrical energy consumptions have been investigated. For EC experiments, a rectangular Plexiglas reactor with dimensions of 9x9x8.5 cm was used. Aluminum and stainless steel electrodes were used as anode and cathode, respectively. The electrodes (grade 304 with 4.35 cm width x 5.70 cm length x 0.3 cm thickness) were placed in the reactor in monopolar parallel mode and vertical position, and connected to a direct current power source. In ea ch stage of the experiment, 2 anode and 2 cathode electrodes with 94.64 cm 2 total active anode surface area were used. The distance between the anode and cathode were set to 9 mm. In order to determine the changes in dye concentrations in the EC cell, 6 ml samples taken periodically from the EC reactor were filtered through a micro-porous membrane filter with 0.45 µm pores, then dye concentrations remaining in aqueous solutions were measured colorimetrically using a spectrophotometer. Keywords: Acid Blue 161, Aluminum and Stainless Steel Electrodes, Electrocoagulation 128 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EVALUTION OF NON-CATALYTIC WET AIR OXIDATION VARIABLES FOR REMOVAL OF ORGONOPHOSPHROUS PESTICIDE MALATHION USING BOX-BEHNKEN M. Isgoren*1, E. Gengec2 , S. Veli3 1,2 University of Kocaeli, Department of Environmental Protection,41275 Izmit, Kocaeli,Turkey e-mail: [email protected], [email protected] 3 Department of Environmental Engineering, University of Kocaeli, 41380 Izmit, Kocaeli, Turkey e-mail: [email protected] ABSTRACT This paper deals with finding optimum reaction conditions for wet air oxidation (WAO) of malathion aqueous solution (organo phosphorous pesticide) by Box-Behnken. Malathion is an insecticide widely used in agricultural areas and observable in environmental samples and food chain. They are reported to be genotoxic and endocrine disrupter that entail infertility. Treatment of malathion with different techniques are subjected to many researches such as fotocatalytic and radiolytic degradation, nanofiltration, photo-fenton oxidation etc. Efficiency of WAO process is based upon the proportion of dissolved oxygen in the aqueous media at different reaction conditions. The reaction conditions; temperature (60-120 0C), pressure of the system (20-40 bar), pH value of solution (3-7) and reaction time (0-120 min), were chosen as independent parameters in this study. The interactions of parameters were evaluated by Box-Behnken, and the quadratic model fitted well with the experimental data (29 runs). R2 correlation coefficients (>95%) for the removal efficiencies showed a high significance of the model. 600ml hestelloy reactor filled with 400 ml of synthetic wastewater (20ppm malathion) and then the heater was opened and awaited until the internal temperature of the reactor reach to the desired level. After that, the reactor was filled by dry air allowing to reach the reaction pressure value that was determined before. This point was the beginning of the reaction. Malathion concentrations were determined by HPLC (UV detector; 202 nm, C18 column; 1 mL/min of flow rate). And also, toxicity tests were performed according to the BiotoxTM flash method based on the bioluminescent response of Vibrio fischeri bacteria, which is probably the most widely applied bacterial test. The completely removal efficiencies were obtained at pH of 3, 120 min, 20 bar and 120 0C. The toxicity results show that the WAO is an important alternative for treatment of toxic materials. Keywords: wet air oxidation, pesticide, malathion, optimization, Box-Behnken. Acknowledgment: The authors thank Kocaeli University, Scientific Research Project Funding (KOUBAP) for their financial support [Project number: 2013-073]. 129 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Partial Nitrification of Domestic Wastewater under Oxygen Limited Conditions Bilge ALPASLAN KOCAMEMİ 1*, Esra ÇİÇEK 2 1, * Environmental Engineering Department, Engineering Faculty, Marmara University, Istanbul Turkey (E-mail: [email protected]) 2, Environmental Engineering Department, Engineering Faculty, Marmara University, Istanbul Turkey ABSTRACT Recently developed novel biological nitrogen removal processes (e.g., Anammox, Canon, Oland) seem attractive alternatives to the conventional nitrification-denitrification process considering their potential for minimization of oxygen and external carbon consumption in nitrogen removal. One of the main limitation in the application of these processes is partial nitrification requirement as preliminary treatment. However, in case of low ammonium containing wastewaters (e.g., domestic wastewater) it is very difficult to maintain stable partial nitrification under normal operating conditions. The possibility of achieving partial nitrification by modifying the dissolved oxygen (DO) concentration (i.e., aeration patterns) seems to be an attractive solution considering energy consumption in air supply accounts for a high percentage of the total energy consumption in wastewater treatment systems. In the present study, partial nitrification of domestic wastewater was studied under limited DO conditions. The effect of the DO level on ammonium oxidation and nitrite accumulation were investigated in the long term through 365-days continuous-flow experiments in a suspended-growth sequential batch reactor (SBR) and a submerged packed bed biofilm reactor. The results showed that in both systems limited DO conditions caused ammonium and nitrite accumulation. In the SBR system, ammonium and nitrite accumulations were initially observed upon decrease of DO from 1 to 0.54 mg/L, whereas in the biofilm system they were initially observed upon decrease of DO from 3.64 mg/L to 1.21 mg/L. In both systems, nitrite accumulation and ammonium accumulation occurred in parallel with each other, indicating that free ammonia concentration partially effective on nitrite accumulation. In the biofilm system limited DO conditions caused higher nitrite accumulation than in the SBR system and higher nitrite accumulation/ammonium accumulation ratio was observed with respect to the SBR system. In the biofilm system, the stable ammonium and nitrite accumulations observed under limited DOconditions exhibited changes in the long term due to increasing population of bacteria in the system. Keywords: Activated sludge, biological treatment, nitritification, partial nitrification, wastewater Acknowledgment: The financial support of this study by the Scientific and Technological Research Council of Turkey (TÜBİTAK) (1001-107Y117) is gratefully acknowledged. 130 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 TETRACYCLİNE REMOVAL VİA WASTE TURKISH COFFEE Chemical Engineering (ICOCEE), Cappadocia 2015 Mehtap Erşan1,FerideDüğenci 2and Ülker Aslı Güler 3 1, 2 Cumhuriyet University, Faculty of Engineering,Chemical Engineering Department, 58140, Sivas , Turkey Cumhuriyet University, Faculty of Engineering,Environmental Engineering Department, 58140, Sivas , Turkey (E-mail:[email protected],[email protected]) 3 ABSTRACT Antibiotics are substances of widespread use, frequently detected in natural surface water. They are excreted via urine and feces. Hence, substantial quantities of antibiotics are detected in wastewaters from hospitals, residential, aquaculture, as well as waste from drug production facilities. Effluents containing antibiotics are of concern as there is potential to promote or maintain bacterial resistance and disrupt key cycles/processes critical to aquatic ecology or crop and animal production. Tetracyline is a wide spectrum antibiotic. In this study the removal of tetracycline (TC) from aqueous environment by organic waste material, Turkish coffee, was studied in a batch system. The experimental parameters (pH, Cinitial, time (min), temperature, ionic strength) that affect the sorption of TC were optimized to achieve maximum removal yield. Coffee plant is a genus of the family Rubiaceae. Coffee contains a lot of caffeine. Caffeine has an impact inhaler andit is good for asthma patients. The stimulating effect has improves concentration. Therefore, quite a lot is consumed and the waste Turkish coffee reusable for removal tetracycline can lead cheap adsorbent usage. The Freundlich and Langmuir adsorption isotherms were conducted to deduce the mechanism of the tetracycline removal process. The kinetics of TC adsorption was moderately fast and almost reached equilibrium in 150 min. The assessment results were obtained with the Freundlich isotherm. It was observed consistent with Langmuir (R2 = 0.9 551). Examining the adsorption kinetics ΔH, ΔS and ΔG values were calculated. NaCl was used to investigate the effect of ionic strength on the adsorption efficiency. The ionic strength was observed to reduce the efficiency of adsorption. The results show that waste Turkish coffee can use removal antibiotics, tetracycline. Keywords:Waste Turkish coffee, tetracycline, adsorption, waste water, thermodynamic parameters. 131 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of Basic Yellow 2 from aqueous solutions onto Montmorillonite Onur Sözüdoğru1 , Baybars Ali Fil2, Recep Boncukcuoğlu3, Erdinç Aladağ*4, Sinan Kul5 1, 3, 5 Ataturk University, Department of Environmental Engineering, Turkey (E-mail: [email protected], [email protected], [email protected]) 2 Balikesir University, Department of Environmental Engineering, Turkey (E-mail: [email protected]) 4 Yüzüncü Yıl University, Department of Environmental Engineering, Turkey (E-mail: [email protected]) corresponding author: Erdinç Aladağ corresponding author e-mail: [email protected] ABSTRACT The removal of Basic Yellow 2 (BY2), a cationic dye, from aqueous solution by using montmorillonite as adsorbent was studied in batch experiments. Basic Yellow 2 (BY2) is generally used in textile mills, paper mills, leather and carpet production. Basic Yellow 2 (BY2), Auramine, (4,4’dimethylaminobenzophenonimide), and its hydrochloride salt are used in the coloring of paper, textiles and leather; and also as food dye. The effect of agitation speed, adsorbent dosage and initial dye concentration on the removal of BY2 was also investigated. Langmuir, Freundlich and Temkin isotherms were applied to fit the adsorption data of BY2 dye. Equilibrium data were well described by the typical Langmuir adsorption isotherm. The maximum monolayer adsorption capacity was calculated as 434.196 mg·g -1 from the Langmuir isotherm model. The adsorption data was fitted to both the pseudo-first-order, pseudo-second-order, Elovich and intra-particle kinetic models and calculated values of amount adsorbed at equilibrium (qe) by pseudosecond-order equations were found to be in good agreement with the experimental values. Keywords: Adsorption; kinetic; isotherm; Montmorillonite 132 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Nitrate Treatment Potential of Tea Waste Ayla Bilgin* 1, 1 Artvin Çoruh Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü ([email protected]) ABSTRACT, Tea plants are commonly grown in the Eastern Black Sea/Turkey. Tea plants are s produce about 30.000 t/year in the Eastern Black Sea region/Turkey. Tea plants wastes are generally used as a fuel in the tea production process. However, some small tea factory deposits them in depository area or occasionly discharge in small bay in the Black Sea. In this study, tea waste was taken from tea factory. Studies were conducted in batch reactors. Removal studies was made initial concentration 50 mg/L nitrate with 1,2,3,4,5 gram tea waste and pH=3,6,9. The contact time was kept constant for 1 hour. Chemicals were used as NaNO 3 (Merck). pH adjustment are made with H 2SO4/NaOH. As a result of work; Nitrate is desorbed from tea waste acidic conditions at pH=3. Desoprtion rate varies according to tea waste amount. The rate of desorption is for 1g tea waste 2%, 2g tea waste %6 and 3 gr tea waste %14. However, the desorption rate decreases in the nitrate alkaline conditions (pH=9). The rate of desorption at pH=9 is for 1g tea waste 0%, 2g tea waste %4, 3 and 4 gr tea waste %4 and 5 gr tea waste % 0. This study show that tea waste is not removal nitrate. Keywords: Nitrate, tea waste, water pollution 133 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Preparation of the Poly (styrene) Based Quaternary Chloroacetamide Modified Sorbent for Removal of Phenol E.Yavuz*, F.Bildik and B.F. Şenkal Department of Chemistry, Istanbul Technical University, Turkey. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Phenols are generally considered to be one of the most important organic pollutants discharged into the environment causing unpleasant taste and odor of drinking wáter. Among several methods used in wastewater treatment, adsorption is a convenient and effective technique to remove low concentrations of chemicals from water. Various adsorbents such as zeolites, polymeric sorbents, carbon nanotubes and clay have been investigated for the removal of phenol and phenolic pollutants from wastewater. In this study crosslinked copolymer beads were prepared by suspension polymerization of 4-vinylbenzyl chloride (VBC) and ethyleneglycole dimethacrylate (EGDMA) mixtures as a sorbent. The resulting copolymer beads with quaternary amide functions were prepared in two steps: (1) modification of N,Ndimethylethylenediamine (DMEA) with PVBC and (2) quaternization of (PVBC-DMEA ) resin with chloroacetamide (PVBC-DMEA-CAM). The phenol sorption capacity was around 0.22 g phenol / g resin in non-buffered conditions. The adsorption conditions (initial phenol concentration and pH) were varied to evaluate the mechanism of adsorption of phenol on the prepared resin. This resin is also able to remove phenol completely even from highly diluted aqueous phenol solutions. Keywords: Adsorption, phenol removal, polymeric beads. 134 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Transport of heavy metals through the supported liquid membrane B. T. Gemici* 1., S. Altin 2 1 Department of Environmental Engineering, Bartın University, TURKEY. (E-mail: [email protected], [email protected]) 2 Department of Environmental Engineering, Bülent Ecevit University, TURKEY. (E-mail: [email protected]) ABSTRACT Supported liquid membrane process has been developed to transport heavy metals such as Ag(I), Co(II) and Cr(III) from various resources. The supported liquid membrane is soaked with the solution of a specific extractant which facilitates the transfer of permeate from the feed to stripping solution in organic diluent. In this paper the use of different extractants to transport Ag(I), Co(II) and Cr(III) in SLM has been discussed. The recent literature data published in last 8 years showed that the special extractants were used for each metal and in some cases two extractant mixture used such as the mixture DP8R and Acorga M5640 for transport of Cobalt. Also for these metals, various parameters such as carrier concentration, initial metal concentration, the stirring speed in the feed and stripping phases and flow rates effect transport of heavy metals directly. Thus the effect of these parameters have been seperately discussed for each metal in detail. Keywords: Supported liquid membrane, extractant, Silver (I), Cobalt (II), Chromium (III) 135 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of heavy metals from aqueous solution by non-modified clinoptilolite in fixed-bed system Magdalena Balintova* 1 and Marian Holub 2 1, 2 Institute of Environmental Engineering, Civil Engineering Faculty, Technical University of Kosice, SLOVAKIA (E-mail: [email protected], [email protected]) ABSTRACT The mining activities represent considerable negative effect to the country. According to stringent effluent discharge regulations it is necessary to look into innovative technologies to remove considerable amount of effluent rather than discharging into surface water. Effluents from mines containing large amount of pollutants (heavy metals, sulphates) give rise to aesthetic unpleasantness as well as adverse effects on fauna, flora or human beings. To prevent or minimize the negative impacts of contaminated effluent, cheap and effective methods have to be applied. Sorption onto natural materials represents high efficient, low cost and easily useable process. High degree of modifiability and regenerability of the sorbents predetermines their utilization in various conditions and different setups. The present study is aimed at evaluating the adsorption behaviour of natural zeolite (clinoptilolite) in order to determine its applicability for heavy metals removal from model sulphuric acid solutions (pH 4) with the aim of AMD treatment in the real condition. For the purpose of determination of pollutants removal efficiencies using zeolite, adsorption experiments in fixed-bed column system were carried out. Keywords: heavy metals, sorption, zeolite, column. Acknowledgment: This work has been supported by the Slovak Grant Agency for Science (Grant No. 1/0563/15). 136 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Cluster analysis of water quality in Water Reservoir Ruzin I., Slovakia Eva Singovszka* 1 and Magdalena Balintova 2 1, 2 Technical University of Kosice, Civil engineering faculty, Institute of environmental engineering, SLOVAKIA. (E-mail: [email protected], [email protected]) ABSTRACT Water quality monitoring has one of the highest priorities in environmental protection policy. The main objectives are to control and minimise the incidence of pollutant-oriented problems, and to provide water of appropriate quality to serve various purposes such as drinking water supply, irrigation water, etc. Multivariate statistical methods including cluster analysis have been used successfully in hydrochemistry for many years. Surface water, groundwater quality assessment and environmental research employing multi-component techniques are well described in the literature. Multivariate statistical approaches allow deriving hidden information from the data set about the possible influences of the environment on water quality. Cluster analysis attempts to explain the correlations between the observations in terms of the underlying clusters, which are not directly observable. In the present study, cluster analysis is applied to physico-chemical parameters of Water Reservoir Ruzin I., Slovakia, with the aim to classify and summarize data as well as segmentation of large heterogeneous data sets into smaller homogeneous subsets that can be easily managed, separately modelled and analysed. Twelve parameters (pH, Ca, Mg, Fe, Mn, Al, Cu, Zn, As, Cd, Pb and SO 42-) were measured. This paper illustrates the usefulness of using statistical techniques in analysing environmental data for better understanding of the behaviour of different parameters. Keywords: acid mine drainage, cluster analysis, heavy metals. Acknowledgment: This work has been supported by the Slovak Grant Agency for Science (Grant No. 1/0563/15). 137 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Decolorization of Brillant Blue R Contaminated Solutions by Chitosan-Eggshell Modified Products İlknur Tosun Satır* 1and Buket Bulut Kocabaş 2 1, 2 Chemistry Department, Hitit University, Turkey (E-mail: [email protected], [email protected]) ABSTRACT Dyes and pigments are gradually being used in many industrial applications such as textile, paper, cosmetics, plastics, food etc. The removal of dyes that are toxic, mutagenic and carcinogenic, from contaminated effluents, is a major environmental problem due to the difficulty in treating such wastewaters by conventional treatment methods. The practical applications of this conventional treatment processes are sometimes restricted because of technical and/or economical draw back. Adsorption technology has emerged as promising alternative method with the advantages of low -cost, greater profitability, easy of operation and greater efficiency. In this study, batch adsorption study was carried out using chitosan-eggshell modified products for the removal of Brillant Blue R (BBR) dye from aqueous solutions. Adsorption conditions were examined with respect to initial pH, adsorbent amount, contact time, initial dye concentration, ionic strength effect. The results showed that the highest BBR adsorption capacity was found at pH 2 and the equilibrium time was 40 min. with adsorbent concentration of 2.0 g L-1. Adsorption process was better described by the pseudo-first-order kinetic and Freundlich isotherm models. All results found concluded that chitosan-eggsell modified products could be effectively employed as an effective new low cost adsorbent for the removal of BBR textile dyes from aqueous solutions. Keywords: Adsorption, Dye, Modification, Eggshell, Chitosan. 138 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Role of Water in Recycling the Physicochemical Treatment Sludge As Concrete Admixture Merve Sogancioglua, Ulku Sultan Keskinb, Esra Yela a Selcuk University, Department of Environmental Engineering, Konya, Turkey ([email protected], [email protected]) b Selcuk University, Department of Civil Engineering, Konya/Turkey ([email protected]) ABSTRACT In this study, the andesite processing wastewater physico-chemical treatment sludge was directly used as concrete admixture either in dried powder form or in suspension form (liquid sludge). The dried and liquid sludges, obtained with alum, sepiolite and FeCl3 coagulants, were used as concrete admixture (250 kg/m3 cement dosage) at different cement replacement ratios. The effects of the presence and absence of extra water coming with the liquid admixture on the concrete consistency and compressive strength were also investigated. The significance of the differences between compressive strengths of the samples at warying admixture conditions were statistically analyzed by one-way ANOVA. Admixture sludges produced with alum resulted in the highest compressive strength, followed by the FeCl 3 and sepiolite. All the concretes with these PCS admixtures can be characterized as medium-strength concretes according to resultant compressive strengths. There are two advantages of utilizing the sludge in liquid form. First, the drying cost in terms of time, energy, area, effort requirement could be saved. Second, the quantity water to be used in the mixture could be reduced since some of the required water will directly come from liquid admixture. Keywords: Admixture, concrete, consistency, compressive strength, excess water. Acknowledgment: The authors thank Selcuk University, Scientific Research Project Funding (SU BAP) for their financial support [Project number: 11101008]. 139 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Oil-Grease from Dairy Industry Wastewater Using an Adsorbent Obtained from Waste Material Nihan Canan İskendera , Merve Sogancioglua Esra Yela, Naciye Yilmazb, a Selcuk University Environmental Engineering Department, Konya, Turkey ([email protected], [email protected]) b Konya Seker Company, Konya, Turkey ABSTRACT Industrial milk processing wastewater contains high concentrations of oil-grease, organic carbon and nutrients that lead to eutrophication and deterioration of aquatic ecosystems. Direct discharge of these wastewaters into the environment will have considerable adverse effects. Municipal solid wastes (MSW) have increasing quantity, dependingly disposal problem and cost. About 35% by weight of MSW by weight is paper and paper products that a potential new material source for recycle. In this study, waste newspapers were converted into adsorbent (WNA), with citric acid modification and performence of this material in oil-grease adsorption from dairy industry wastewater was invastigated. Batch adsorption experiments were carried out in batch reactors under continuous stirring at 200 rpm and of 40-70 0 C. The WNA obtained with waste newspaper was used at between 1920 mg/L-15385 mg/L dosage. The oil concentration of wastewater samples were 10000-25000 mg/L. Maximum adsorbent capacity of 2500 mg/g was achieved. Ultimate, oil adsorption performence of WNA were 96.7% and 85.2% for initial oil-grease concentrations of 10000 and 25000 mg/L. Isotherm studies indicated that oil adsorption by these WNA adsorbents can be characterized by Freundlich model for optimum temperature (50°C). The adsorption sludge was dried and its utilization as alternative energy resource was evaluated. Keywords: Adsorption, dairy wastewater, waste newspaper. Acknowledgment: The authors thank TUBITAK for their financial support within the scope of 2241B-2014 projects. 140 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Reduction of Nitrate by Combined Ultrasound and Zero-valent Magnesium under pH Uncontrolled Conditions Onder Ayyildiz1*, Burcu Ileri1, and Omer Apaydin2 Çanakkale Onsekiz Mart University, Faculty of Engineering, Department of Environmental Engineering, Çanakkale, TURKEY (E-mail: [email protected], [email protected]) 1 2 Yildiz Technical University, Faculty of Civil, Department of Environmental Engineering, Istanbul, TURKEY (E-mail: [email protected]) ABSTRACT Zero-valent magnesium (ZVMg) was activated by ultrasound (US) in an aim to promote its potential use in water treatment. Nitrate reduction was studied at batch conditions without controlling pH and using various doses of magnesium powder ranging from 1.25 to 10 g/L, ultrasound powers of 25–100 watts, and frequencies of 20–1144 kHz. Ultrasound alone did not appear to be effective in reducing nitrate, in that the initial nitrate concentration remained almost constant throughout the treatment. Zero-valent magnesium itself was not also effective for nitrate reduction providing only 10% removal after 60 min even at the highest dose of magnesium powder (10 g/L) used. However, a combined use of US and ZVMg involved synergistic effects in which the nitrate reduction by the combined method increased significantly beyond the additive effect of individual treatments. For example, the sum of percent nitrate removal by individual US and ZVMg treatments was less than 15%, but more than 90% reduction was attained by the combined method. The rate of nitrate reduction by US/ZVMg enhanced with increasing ultrasonic power and magnesium dose, but decreased with increasing acoustic frequency. Nitrogen gas (N2), nitrite (NO2-), and ammonia (NH3) were detected as the major denitrification by-products. The proportion of nitrogen gas to the total amount of denitrification by-products increased with increasing ultrasonic power and magnesium dose. The synergistic effect of combined ultrasound and zero-valent magnesium treatment has been attributed to the surface cleaning effect of ultrasonic mechanical forces. SEM-EDS results revealed that the surface oxide level decreased significantly when the samples of ZVMg particles were exposed to high intense acoustic waves. The surface passivation of magnesium particles was successfully minimized by mechanical forces of ultrasound, which in turn paved the way to sustain the catalyst activity toward nitrate reduction. Keywords: ultrasound, zero-valent magnesium, nitrate, denitrification, pH 141 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Degradation of Synthetic Textile Dyes using Fungal Bioreactor and Photocatalytic Reactor E.Ü. Deveci 1*, N. Dizge 2, H.C. Yatmaz 3, Y.Aytepe 4 1 Environmental Engineering Department, Engineering Faculty, Nigde University, TURKEY (E-mail: [email protected]) 2 Environmental Engineering Department, Engineering Faculty, Mersin University, TURKEY (E-mail: [email protected]) 3 Environmental Engineering Department, Gebze Technical University, Gebze, Kocaeli, TURKEY (E-mail: [email protected]) 4 Department of Chemistry, Faculty of Arts and Science, Niğde University, TURKEY ABSTRACT The ligninolytic white-rot fungi are capable of breaking phenolic components of lignin and lignin derivatives. They have been extremely used for biodecolourisation of textile effluents and conventional dyes. Especially bacteria and fungi, have gained great attention for the treatment of effluents from textile industry. The present study was conducted using a white rot fungus, namely Phanerochaete chrysosporium, for the decolorization of Reactive Red 180 and Acid Red 88 dye. The decolourisation of these two dyes was investigated for using innovative hybrid process of fungal membrane bioreactor and photocatalytic membrane reactors. Photocatalytic oxidation was conducted with semiconductor catalysts (ZnO and TiO2) under UVA irradiation. Hybrid design of fungal membrane bioreactor and photocatalytic processes was performed sequentially. Initially the fungal membrane bioreactor was conducted and optimum pH value was found as 4.5 for Phanerochaete chrysosporium. Applying photocatalysis after fungal membrane process improved the COD degradation efficiency values and it reached 98% and 96% for Reactive Red 180 and Acid Red 88, respectively. However, color removal values after degradation were 99.9% for both dyes. Keywords: Photocatalytic fungal membrane bioreactor (PFMBR), Acid Red 88, Reactive Red 180, ZnO, TiO2, UVA, Phanerochaete chrysosporium Acknowledgment: The authors thank The Scientific and Technological Research Council of Turkey (TUBITAK) for their financial support [Project number: 113Y334]. 142 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Batch and Column Removal of Textile Dye from Aqueous Solution using Activated Carbon Prepared from Olive Stone Ö.Gerçel 1*and H.F. Gerçel 2 1 Environmental Engineering Department, Anadolu University, 26555, TURKEY. (E-mail: [email protected]) 2 Chemical Engineering Department, Anadolu University, 26555, TURKEY. (E-mail: [email protected]) ABSTRACT The present research deals with the production of activated carbon by chemical activation using olive stones and its adsorption behavior. Olive stone was chemically activated using potassium carbonate. Carbonization was performed under inert atmosphere to avoid oxidation of the carbonaceous material with air. The prepared activated carbon was used for the adsorption of textile dye from aqueous solution. Burderm Orange II was used as textile dye. In the batch and continuously adsorption study, granular activated carbon prepared from olive stone is chosen as an adsorbent to understand the adsorption of dye from aqueous system. Although batch adsorption studies provide useful information on the application of adsorption to the removal of dye, continuous column studies provide the most practical application of this process in wastewater treatment. In batch studies, the effects of initial pH, adsorption time and initial concentration on Burderm Orange II adsorption onto olive stone based activated carbon. The adsorption equilibrium parameters were determined from the Langmuir and Freundlich adsorption isotherm equations. The experimental equilibrium data were found to be well represented by the Langmuir adsorption isotherm model. The calculated adsorption capacity for Burderm Orange II onto activated carbon was 500 mg/g at 25 o C. The result of this study indicated the feasibility of fixed- bed adsorber for removing Burderm Orange II from aqueous solution. Keywords: Activated carbon, Adsorption, Chemical activation, Dye removal, Olive stone 143 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of Remazol Blue RN from Aqueous Solutions Using Activated Carbon Prepared from Black Cumin Residue U.Selengil* 1, H.Demiral2 1, 2 Chemical Engineering, Eskişehir Osmangazi University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Activated carbon is an effective adsorbent for the separation and removal of unwanted matters from industrial effluents. Agricultural wastes are very important starting materials for preparing activated carbon. Activated carbons can be produced basically by two methods: physical activation or chemical activation. Chemical activation is known as a single step method of preparation of activated carbon in the presence of chemical agents which are normally alkali and alkaline earth metal containing substances and some acid such as KOH, K2CO3, NaOH, Na2CO3, ZnCl2 and H3PO4. In this study, activated carbons were prepared from black cumin residue by chemical activation and the prepared activated carbons were used to remove dyestuff (Remazol Blue RN) from aqueous solutions. Chemical activation of black cumin residue was carried out using H 3PO4. H3PO4 were dissolved in water then impregnated into the black cumin residue with the ratios of 1:1 and 3:1. The impregnation ratio was calculated as the ratio of the weight of H 3PO4 in solution to the weight of the used waste. Chemical impregnated residue was carbonized in a vertical furnace at 500 and 600 oC under the nitrogen flow of 100 ml/min. Samples were held at the final temperature for 60 min. The resultant activated carbons were washed with distilled water. The N2 adsorption–desorption isotherms of the activated carbons were measured using an automatic adsorption instrument at 77 K (Quantachrome, Autosorb 1C) in order to determine the surface areas, pore volumes and pore size distribution. The maximum specific surface area of the activated carbon was about 1168 m2/g at 500 oC and at an impregnation ratio of 3:1. The resulting activated carbon was used for removal of Remazol Blue RN from aqueous solution. The effects of pH, initial concentration and contact time were investigated. Isotherm studies were carried out and the data were analyzed by Langmuir and Freundlich equations. Langmuir equation was found to fit the equilibrium data for Remazol Blue RN adsorption. Keywords: Activated carbon, Adsorption, Black Cumin, Remazol Blue RN 144 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of natural organic matter by hydrogen peroxide in the presence of iron -coated pumice particles Alper Alver*, Mihrican Karaarslan and Ahmet Kılıç Aksaray University, Engineering Faculty, Department of Environmental Engineering, Aksaray, TURKEY (E-mail: [email protected]) ABSTRACT Over the past 10–20 years the amount of the natural organic matter (NOM) has been increased in raw water supplies on several areas. The presence of NOM causes many problems in drinking water treatment processes, including: (i) negative effect on water quality by colour, taste and odor problems, (ii) increased coagulant and disinfectant dose requirements (which in turn results increased sludge and potential harmful disinfection by-product formation), (iii) promoted biological growth in distribution system, and (iv) increased levels of complexed heavy metals and adsorbed organic pollutants. In this study, removal of natural organic matter from water was investigated by catalytic oxidation process which is an advanced oxidation process. Removal of THM precursors which is formed by the reaction of natural organic matters with chloride, was performed with the hydroxyl radicals that is produced in catalytic oxidation process. The studies were carried out in three sections. In the first section, decomposition of hydrogen peroxide in pure water with the catalysis of iron coated pumice, in the second section decomposition of hydrogen peroxide in the humic acid medium with the catalysis of iron coated pumice, in the third section removal of humic acid by hydrogen peroxide with the catalysis of iron coated pumice. Removal of humic acid and total organic carbon content in water, and the variation of formation pot entials of THM was followed. At the end of this study it was observed that the decompositi on of hydrogen peroxide in the pure water and in the humic acid medium with the catalysis of iron coated pumice. Keywords: Catalytic oxidation process, Fenton-like process, Iron-coated pumice, Natural organic matter, Trihalomethane. Acknowledgment: We thank the Environmental Engineering Department of Aksaray University for providing laboratory equipment of the work described in this paper. 145 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal Process of Chloroform in Treatment Wetlands: From Mass Balance to Microbial Analysis Yi Chen* 1, Jan Vymazal 1 1 Department of Landscape Ecology, Faculty of Environmental Sciences, Czech University of Life Sciences Prague,16521, Czech Republic. (E-mail: [email protected]) ABSTRACT Chloroform is one of the common disinfection byproducts, which is not susceptible to degradation and poses great health concern. In this study, the chloroform removal efficiencies and contributions of sorption, microbial degradation, plant uptake, and volatilization were evaluated in six model constructed wetlands (CWs). The highest chloroform removal efficiency was achieved in litter -added CWs (99%), followed by planted (46%–54%) and unplanted CWs (39%). Mass balance study revealed that sorption (73.5%–81.2%) and microbial degradation (17.6%–26.2%) were the main chloroform removal processes in litter-added CWs, and that sorption (53.6%–66.1%) and plant uptake (25.3%– 36.2%) were the primary contributors to chloroform removal in planted CWs. Around 60% of chloroform got accumulated in the roots after plant uptake, and both transpiration and gas -phase transport were expected to be the drivers for the plant uptake. Sulfate-reducing bacteria and methanogenetic microorganisms were found to be the key microorganisms for chloroform biodegradation through co-metabolic dechlorination, and positive correlations were observed between functional genes (dsrA, mcrA) and biodegradation rates. Overall, this study suggests that wetland is an efficient ecosystem for sustainable chloroform removal, and that plant and litter can enhance the removal performance through root uptake and microbial degradation stimulation, re spectively. Keywords: Constructed wetlands; Plant biomass; Chloroform; Mass balance; Cometabolism. Acknowledgment: This work was financially supported by the National Science Foundation of China (51378372), the Fundamental Research Funds for the Central Universities (20113139) and Czech University of Life Sciences and ESF & MEYS (CZ.1.07/2.3.00/30.0040). 146 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The effect of mixing time on rate for ammonium removal from waters by emulsion liquid membrane technique İsmail Şimşek* and Levent Altaş Aksaray University, Engineering Faculty, Department of Environmental Engineering, Aksaray, TURKEY (e-mail: [email protected]) ABSTRACT The present study deals with the removal of ammonium from aqueous solutions by using the emulsion liquid membranes (ELM) technique. ELM treatment process represents an efficient advanced separation technique for the removal of ammonium from fertilizer and other industrial wastewaters, which contains high ammonium. Mixing rate and time are also important parameters for ammonium removal due to interaction between amonium and emulsion globules. The components to prepare emulsion are mineral oil and toluene as solvent, span 80 as surfactant and H2SO4 as an internal reagent. In experimental study for ammonium removal, effect of mixing time and rate were investigated. The optimum mixing rate was found 250 rpm at samples which are taken different time intervals. It was observed that 72 % removal efficiency occurred at these conditions. In addition, shortness of retention time presents an advantage rather than other treatment methods. Keywords: Ammonium, Emulsion Liquid Membran, Mixing Rate Acknowledgment: This study was supported by 2013-37 numbered project of Aksaray University Scientific Research Project Department 147 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EFFECTS OF WINEMAKING PRACTICES ON THE CHARACTERISTICS OF WASTEWATER ORIGINATED FROM WINERIES Kemal ŞEN*1 and Feyza KIROĞLU ZORLUGENÇ2 1, 2 Nevsehir Haci Bektas Veli University, Engineering Architecture Faculty, Department of Food Engineering, Nevsehir 50300, Turkey (E-mail: [email protected], [email protected]) ABSTRACT As long as it is not occured with an accurate engineering approach, winemaking industry produces high volume of wastewater which threatens the environment. As the number of wineries is increased in the last decade in Turkey, the adverse environmental effects of wastewater are deepened. Winemaking process includes entire steps from harvesting to bottling. It is important to have comprehensive knowledge of winemaking process to generate solutions for wastewater issue stemming from wineries. There are different production practices in many wineries which produces wastewater with different characteristics. Taking into account all of these, detailed characterization for every individual winery to manage wastewater has a great importance. However, popularizing winemaking practices which decreases wastewater volume in order to reduce work load of treatment systems and increase the effectiveness of solutions would be the primary step to resolve this problem. For this reason, it is important that production engineers and environmental engineers cooperate effectively in wineries. In this study, there have been made a general assessment by making a compilation of the studies regarding the effects of winemaking practices on wastewater composition and decreasing the volume of wastewater produced from wine industry. Key Words: winemaking processes, process wastewater, characteristics of wastewater 148 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Monitoring of Antibiotics in Urban Wastewater in Tekirdag City: a comparison with predicted environmental concentrations Gamze Varol Saraçoğlu 1, Can Burak Özkal 2, Selcen Göçmez Koruyucu 4, Süreyya Meriç *2 1 3, Füsun Ekmekyapar 2, Aslihan 2 Faculty of Medicine, Public Health Division, Namık Kemal Univesity, Tekirdağ, Turkey; Çorlu Engineering 3 Faculty, Environmental Eng. Depart., Namık Kemal University, Çorlu Tekirdağ, Turkey; Faculty of Medicine, 4 Pharmacology Department, Namık Kemal Univesity, Tekirdağ, Turkey; Çorlu Engineering Faculty, Textile Eng. Depart., Namık Kemal University, Çorlu, Tekirdağ, Turkey (*E-mail: [email protected]) ABSTRACT Antibiotics as the most common consumed group of pharmaceuticals, have been demonstrated to be present in the effluent of urban wastewater treatment plants since they are not either adsorbable on activated sludge or hardly biodegradable. There has also been evidence that antibiotics can promote the resistance of certain bacteria versus specific for antibiotic groups. Monitoring of pharmaceuticals, in particular, antibiotics have widely become emerging in the scientific literature during recent years while there are a few studies yet in Turkey for the survey of pharmaceuticals in urban wastewaters. This study attempts to determine spatial distribution of antibiotics in urban wastewater containing a major component of the effluents of hospitals within the project NKUBAP.00.20.BAP.13.08. Grab raw sewage samples were collected from 5 points through the main collector system in Tekirdağ city in June 2014 during morning hours (10:00-12:00 am). Antibiotics (Erithromycin (ERY), Clarithromycin (CLAR), Levofloxacin (LVF), Ampicillin (AMP)) (Sigma Aldrich) were measured in the NKU Center Laboratory (NABİLTEM) using LC-MS/MS (AB SCIEX, 300 QTRAP, USA) according to well described scientific literature. MEC of antibiotics were defined with a high linearity approval (>99 %) and a very good ion independency (80-95%) yielding high recoveries (>85%). Measured environmental concentrations (MEC) were compared with predicted environmental concentrations (PEC) defined by European Medicine Agency (EMEA) model, to assess the accuracy of sampling and sample handling procedures. Antibiotics consumption data derived from main two hospitals and central pharmacies were used to predict environmental concentrations after convertion to defined daily doses (DDD) value as described elsewhere. MEC results were found at g/L levels in accordance with the PEC values. These concentrations were noted to be suspected to antibiotic resistance. MEC values of antibiotics were defined versus sampling points as from 0 to 55,5 g/L of ERY, 0 to 9.5 g/L of CLAR, 0 to 0.4 g/L of AMP which were varied significantly among sampling points except LVF (2,6-2.7 g/L). The fluctuation of MECs were explained due to the dilutions on basis of flow rates from sewage collecting areas. Keywords: Antibiotics, Antibiotic resistance, LC-MS/MS, MEC, PEC, Urban Wastewater. 149 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Energy and pH Dependency Optimization of Degradation, Mineralization and Detoxification of Ampicilline by Photocatalysis Can Burak Ozkal * 1, Aslihan Koruyucu 2, Sureyya Meric 1, 1 2 Envrionmental Engineering, Namık Kemal University, Faculty of Engineering, Tekirdag, Turkey; Textile Engineering, Namık Kemal University, Faculty of Engineering, Tekirdag, Turkey (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Recent advances on safe re-use of treated wastewater effluents are globally progressing and legislations and regulations are being updated accordingly. Since most of antibiotics have been demonstrated to be low degradable in biological treatment systems, advanced oxidation processes (AOPs, particularly solar photocatalytic (PC) oxidation) have gained an essential attraction to oxidize them. Between suspended (SS) and immobilized photocatalysis processes, thin film (TF) has been reported being far less competitive with SS since a relatively smaller total surface area is available for the adsorption of organics which cause a reduced oxidation potential than. Unit ratio between quantities of catalyst and compound is important for providing a larger surface area for the adsorption as well as the higher potency of pairing of electrons to produce hydroxyl radicals for a higher oxidation effciency. This study attempts to optimize suspended PC oxidation using TiO 2 of two initial concentrations (50 and 100 mg/L) of ampicilline (AMP) by means of energy dependency and pH influence to system efficiency that was followed by degradation and mineralizaton rates as well as toxicity. The PC experiments were performed under varying energy levels but a final value of 49,4 W/m 2 of UV-A irradiation at 315-400 nm wavelength in heterogenous conditions to maintain most efficient total degradation (UV- vis Lamda 1800, Schimadzu, Japan), mineralization (TOC, 6KVA model, Schimadzu, Japan) as well as oxidation by-products (LC-MS/MS, AB SCIEX, 300 QTRAP, USA). Daphnia magna acute toxicity test was performed according to ISO 6341 method using 24 h new born daphnids for 24 and 48 h exposure times. Toxicity results and increasing TOC removal (30 to 60 min) for both initial AMP concentratio ns using 0.5 g/L TiO 2 indicated that simultaneous mineralization and degradation are essential to assure safe effluent with reduced and stabilized toxicity. As a key factor affecting the oxidation efficiency, ratio of TiO2/AMP was higher for the 50 mg/L AMP oxidation. That ratio was assumed to promote increased formation of by-products while surface sites were assessed to be mostly occupied by parent compounds rather than degradation by-products for the oxidation of 100 mg/L AMP. Keywords: AOPs, ampicilline, Daphnia magna, photocatalysis, TiO2 Acknowledgment: This research was funded by Namik Kemal University (NKU.BAP.00.17.AR.13.13). 150 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Anion Selectivity of Sepiolite and its Surface Active Agents-Modified Forms S. Dikmen* 1, H. Bircan2 and G. Yılmaz 3 1 2 3 Physics Department, Faculty of Science, Anadolu University, TURKEY. ([email protected]) Physics Department, Faculty of Arts and Science, Dumlupınar University, TURKEY. ([email protected]) Physics Department, Department of Constructions Division, Program in Building Inspection, Anadolu University, TURKEY. ([email protected]) ABSTRACT In this research, firstly the a natural clay mineral, which is sepiolite, was transformed into Na-sepiolite forms and then Na-sepiolite were modified by hexadecyltrimethylammonium (HDTMA) bromide [CH3(CH2)15N(CH3)3Br]. The effect of adsorban dosage, contact time and pH on the adsorption of HDTMABr onto Na-sepiolite surface was modified in order to produce organo-sepiolite (HDTMA-sepiolite). The characterization studies by using different methods (BET, XRF, XRD, SEM, FT-IR, TG/DTA, immersion heat and zeta potential measurement) were also carried out to identify the modification of natural sepiolite with HDTMA-Br and its adsorption behavior. Then, the adsorption of hazardous anions, which are present in wastewater or underground water with HDTMA-sepiolite were investigated in batch technique. In this manner, the effects of adsorban dosage, contact time and pH were investigated for the adsorption of nitrate, sulphate and phosphate onto HDTMA-sepiolite. Anion concentrations were determined by ion chromatography of the solutions. Adsorption kinetic and isotherm parameters were deduced by using experimental data. Pseudo-first-order, pseudo-second-order and Weber-Morris models and Langmuir and Freundlich isotherms were applied to the experimental data to obtain adsorption kinetics and adsorption equilibrium, respectively. According to this, the adsorption of phosphate data fit well with the pseudo-second order kinetic model (with high correlation coefficients) Keywords: Adsorption; Anion; HDTMA-sepiolite; Isotherm; Kinetic; Sepiolite Acknowledgment: The authors thank Anadolu University, Scientific Research Project Funding (AU BAP) for their financial support [Project number: 1001F58]. 151 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Optimization of electrocoagulation process to treat young landfill leachate using response surface methodology Aygun Ahmet 1, Nas Bilgehan 2, Berktay Ali 3 1 Department of Environmental Engineering, Bursa Technical University, TURKEY (E-mail: [email protected]) 2 Department of Environmental Engineering, Selcuk University, TURKEY (E-mail: [email protected]) 3 Department of Civil Engineering, Usak University, TURKEY (E-mail: [email protected]) ABSTRACT In the present study, Response Surface Methodology (RSM) was employed to investigate the effects of different operating conditions such as initial pH, applied electric current and electrolysis time on the removal of COD by the Electrocoagulation Process (EP) with iron and aluminum electrodes. Experiments were performed according to the Central Composite Design (CCD) experimental plan. A three factor-five coded level CCD consisting of 17 experimental runs was performed including three replicates at the center points. The statistical analysis of the results showed that the operating parameters had a significant effect on COD removal efficiency. The model adequacy was checked and confirmed using ANOVA method. The RSM results indicated that the fitted model could be appropriate to predict COD removal efficiency. Proposed models to estimate the COD removal efficiency was independent of the electrode materials and modified quadratic model was found to be suitable. The optimum conditions for COD removal (52.7 %) were established as 2.6 A applied electric current, initial pH of 8.58 and 45 min electrolysis time for Al electrodes. When using iron electrodes lower COD removal efficiency (46.5%) was achieved. At the optimum conditions, the operating costs for Al and Fe electrodes in terms of €/m3 were 3.08 and 3.98, respectively. From economic point of view, aluminum electrode is clearly preferable. A preliminary economic study shows that electrocoagulation may be competitive with current treatment technologies. Keywords: Electrocoagulation; Landfill; Leachate; Operating Cost; Response Surface Methodology (RSM) Acknowledgment: The authors thank Selcuk University, Scientific Research Project Funding (SU BAP) for their financial support [Project number: 09401049]. 152 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Adsorption of Cationic Dye (Methylene Blue) from aqueous solution by eggshells Z. Hattab*1, Y. Berredjem1, R. Mazouz1, N. Filali1 and K. Guerfi1. 1 Laboratoire de Traitement des Eaux et Valorisation des Déchets Industriels, Département de Chimie, Faculté des Sciences, Université Badji-Mokhtar, Annaba 23000, Algérie. (E-mail: [email protected] [email protected], [email protected], [email protected] ) 2 Centre Universitaire de Souk_Ahras 41000. Algérie (E-mail: [email protected]) ABSTRACT The adsorption of methylene blue by the eggshells was performed in static conditions. The study of the influence of parameters (contact time, stirring speed, pH, initial concentration and temperature), were used to determine the contact time which is equal to 10 minutes with a good removal efficiency for Initial substrate concentration of 20 ppm. The equilibrium adsorbate / adsorbent were well described by the kinetic model of pseudo-first order and the Freundlich adsorption model. The kinetic data led us to calculate some thermodynamic parameters (ΔH0, ΔS ° and ΔG0) that inform us about the nature of the conservation process. The negative value of ΔH° shows that the adsorption reaction is exothermic. The free energy Δ.G° is positive, indicating that the adsorption process of methylene blue on eggshells is not that imply a spontaneous chemical adsorption. The eggshells adsorbs better especially stirring speed = 50 rev / min, T = 25 °C and pH = 6.9 to 7.2. Keywords: adsorption; dye; eggshells; isotherm; kinetic model. 153 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 AnExploitation Evaluation OfPimuce Stone For Water And Wastewater Treatment Use DenizİzlenÇifçi1*, Mustafa Yıldırım1, BülentBirden 2, SüreyyaMeriç 1 1 Department of Environmental Engineering, Çorlu Engineering Faculty,Namık Kemal University, Çorlu 59860- Tekirdağ, TURKEY(E-mail:[email protected]; smericnku.edu.tr 2 SOYLU Group Raw Materials, İzmir, Turkey ([email protected]) ABSTRACT Pumice is a porousand amorphous material which mainly consists of SiO2,havinglargesurfaceareaandskeletonstructure, whichcontainsopenchannelsfollowingwaterandionstotravelintoandout of thecrystalstructure.It is formedwhenvolcanicgasesexsolvingfromviscous magma nucleatebubbles, whichcannotreadilydecouplefromtheviscous magma priortochillingtoglass. It is a commonproduct of explosiveeruptions (plinianandignimbrite-forming) andcommonlyformszones in upperparts of siliciclavas. Pumice has an averageporosity of 90%, andinitiallyfloats on water. Pumice surface ends with OH groups and oxygen bridges, which would perform as adsorption spots. In adsorption methods, it is vital to identify the features of these various adsorption spots or sites and gain a better understanding of their role in the adsorption process. Its surface principally comprises oxygen, nitrogen, hydrogen, halogen, etc. Pumice is a valuablescouring, scrubbing, andpolishingmaterialboth in powdered form and as pumicestone.It has been traditionally used in the construction industry and bio-medicine. Besides traditional applications, pumice has been also investigated in the field of water, wastewater and air treatment. The present study aimed to revise the use of pimuce stone for the treatment of water and wastewater. An essential revision of the scientific publications showed that most of the number of scientific publications from 1995 to 2014 deal with the construction materials and treatment use. Among 137 papers in the field of water and wastewater treatment for the removal of cadmium, dyes, color, the catalytic degradation of pchloronitrobenzene in the presence of ozone, phenol and 4-chlorophenol, water softening and so on, a 50% was dedicated on adsoption process while a 27% was used in biological treatment as a carrier media. Besides, a 20% was used as filtration media. During recent years there have been some studies on intgerating pumice with advanced oxidation processes (AOPs) too (15%). The use of pimuce in AOPs is expected to atract more scientists, in particular, integration with nanotechnology which will be evealuated in this study in detail. Keywords:Adsorption, micro materials, Pimuce stone, nanotechnology,water and wastewater treatment 154 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Organic pollutants in the groundwaters used for irrigation purpose within a coal-bearing basin of northern Greece Andreas Iordanidis 1*, Jan Schwarzbauer 2 and Konstantinos Gudulas 1 1 Department of Geotechnology and Environmental Engineering, Technological Educational Institute (TEI) of Western Macedonia, Kila, 50100 Kozani, GREECE (E-mail: [email protected], [email protected]) 2 Institute of Geology and Geochemistry of Petroleum and Coal, RWTH Aachen University, Lochnerstrasse 4-20, 52056 Aachen, GERMANY (E-mail: [email protected]) ABSTRACT The aim of this study is to identify potential toxic or environmentally relevant organic compounds in the aquifers of the Amynteo hydrogeological basin and to investigate a possible link of the identified organic contaminants with the Pliocene Amynteo lignites. For these purposes ten groundwater samples were collected from this area. A sequential liquid-liquid extraction procedure was applied to approximately 1000 mL aliquots of the groundwater samples using dichloromethane as extractant. All extracts were analysed by Gas Chromatography (GC) and Gas-Chromatography-Mass Spectrometry (GC-MS) by means of a non-target screening approach. The results of the GC-MS analyses of the extracts are presented and discussed in this work. The identified organic compounds with a potential environmental relevance are: 2,2,4-trimethyl-1,3-pentanediol diisobutyrate (TXIB), triacetine, isopropyl palminate, isopropyl myristate, tributyl-, triethyl- and trioctylphosphates, N,N-dibutyl formamide, methyl dihydrojasmonate, nonylphenols and bumetrizole. However, all these organic micropollutants can derive either by anthropogenic emissions (plasticizers, industrial pollutants, pesticides etc.) or by contaminations from the pump and the borehole structure itself. Noteworthy, coal derived organic molecules (such as anthracene, fluorene, pyrene, phenanthrene etc.) have not been detected. Hence, an influence of coal deposits to the groundwater quality is considered negligible. Keywords: Amynteo, GC-MS, liquid-liquid extraction, organics 155 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Methicillin-Resistant Surface Water Isolates Monitored by mecA-Specific DNA Probes E. Seyedmonir* 1, F.Yilmaz 2 and B. Icgen 3 1,3 2,3 Department of Biochemistry, Middle East Technical University, TURKEY (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Middle East Technical University, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Staphylococcus aureus strains resistant to methicillin (MRSA) are a major cause of nosocomial infections worldwide. Resistance to methicillin is caused by the mecA gene, which encodes the low-affinity penicillinbinding protein PB2A. The mecA gene is part of a 40- to 60-kb staphylococcal chromosome cassette SCCmec, a mobile genetic element that may also contain genetic structures such as Tn554, pUB110, and pT181, which encode resistance to non-β-lactam antibiotics. Although the origins of the mecA gene are unknown, mecA homologues with high similarity are also ubiquitous in the methicillin-resistant surface water isolates other than staphylococci. Our previous studies also revealed that the transfer of mecA from staphylococcal to non-staphylococcal might frequently occur in surface water isolates. These findings make the mecA gene a biomarker molecule for the monitoring of methicillin-resistant isolates. Therefore, this study aimed at monitoring of mecA harboring surface water isolates by using mecA-specific DNA probes. For that purpose, water samples collected from a river during the period of a year was monitored with mecA-specfic DNA probe through in situ fluorescent hybridization technique and image-analyzed microscopy. The oligonucleotide probe targeting mecA was labelled with fluorescein isothiocyanate at the 5’ end and was used to calibrate the optimal hybridization stringency for mecA harboring isolate. Strong linear relationships between the signal intensity and the target mecA gene was also observed (R2 = 0.91). Our results indicated that the mecA-specific DNA probe might be a potential analytical tool in selecting and in situ monitoring of methicillin resistant isolates in surface waters. Key words: MRSA, mecA, mecA probe, methicillin resistant, surface waters Acknowledgment: The authors thank The Scientific and Technological Research Council of Turkey for their financial support through a 1001 project. [Project No.113Z198]. 156 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Numerical Modelling and Monitoring of Coastal Water Quality Kağan CEBE*1 and Prof. Dr. Lale BALAS*2 1 PhD Student at Civil Engineering Department, Engineering Faculty, Gazi University, Ankara. (E-mail: [email protected]) 2 Civil Engineering Department, Engineering Faculty, Gazi University, Ankara. (E-mail: [email protected]) ABSTRACT In this study, water quality parameters have been modeled in enclosed coastal waters of inner Fethiye Bay by HYDROTAM-3D. The model simulations are compared with the site measurements. HYDROTAM-3D is a three-dimensional (3-D) baroclinic numerical model developed to simulate the water quality parameters as well as the hydrodynamic and transport mechanisms in coastal waters. The model predictions have been calibrated and tested by several field and laboratory measurements since 20 years. HYDROTAM-3D has been applied successfully to the bays along the Turkish coastline like Bay of Fethiye, İzmir, Marmaris, Bodrum, Mersin, İskenderun, İzmit, Antalya, Cardiff, Gökova and Göksu Lagoon and Ölüdeniz Lagoon. The water quality component of HYDROTAM -3D is based on a marine ecological submodel, aiming to simulate an idealized marine ecosystem. By using the gene ral conservation equations the nitrogen, phosphorus and the oxygen cycles have been simulated in the ecological submodel as well as the dominant aquatic life forms, namely phytoplankton, zooplankton and the pelagic bacteria. In this study, the physical and chemical parameters at -0,5m and -10m water depth (e.g. temperature, salinity, density, pH, concentration of dissolved oxygen DO, nitrite NO2 -, nitrate NO3-, turbidity, alkalinity and total dissolved solid TDS) are monitored by monthly field and laboratory measurements for 6 months in Fethiye Bay. The measurements for nitrite, nitrate and dissolved oxygen concentrations have been compared with the simulations of the water quality model. Measurements will be evaluated in accordance with the Surface Water Quality Management Regulation (2012) of Turkey. Keywords: water quality, ecological model, phytoplankton, zooplankton, pelagic bacteria Acknowledgement: This study is supported by DLTM Software Technologies Industry and Trade Co.Ltd. 157 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessment of the cations and anions concentration distribution in underground potable waters, pH solution analysis subject to the temperature and content of technogenic sodium chloride. Z. Maymekov1, D. Sambaeva2, J. Izakov3, A. Isaev4, J. Sydykov5 Kyrgyzstan Turkey Manas University, Bishkek, Kyrgyzstan ([email protected]); 2,5 Institute of Mining and Mining Technologies KGTU, Bishkek, Kyrgyzstan ([email protected]) 1,3,4, ABSTRACT Research and evaluation of salts’ technogenic influence on concentrated scattering of charged particles (cations and anions) in underground potable waters, as well as effects on the environments are vital from the perspective of environmental and economic value now days, since the chlorides of alkaline and alkaline earth metals are widely used in various fields of human activities. For instance, dry salts are used often for the snow and ice melting on the roads in Kyrgyzstan in a winter time aiming to ensure a higher efficiency of the frost gritting. However, those salts are imbibed by water and then diffuse in environment while water evaporates in the air gradually. In this case the chloride salts concentration in the components of the environment varies from 10-15 ppm to 130 -140 ppm. In this work, formation of the physico-chemical model implemented by the search of potential phases in equilibrium, dependent components and composition of the independent components of the system while minimizing the isobaric-isothermal potential. As a result of the research, for the first time is drawn up chemical matrix of groundwater according to the data of 235 wells (in moles): Na (0.00179), Ca (0.00107), Mg (0.00055), C (0.00251), Cl (0.00068), S (0.00085), N (0.00016), K (0.00006), H (111.02), O (55.52) and based on them performed simulations with a minimum Gibbs energy. Model takes into account the average chemical composition of groundwater and determined following pH and Eh of solution, water pH changed from 7.48 to 7.94, an average pH of 7.74. This implies, that the pH value of underground drinking water according to the data of 235 wells slightly alkaline (pH =7.74), apparently due to the fact that the water contains low concentrations of salt CaMg(CO3)2 (1.15e-04 mol) и KNO3 (4.53e-05 mol). In this work the concentration distribution of charged particles in an aqueous solution was found that can be used as the initial parameters for assessing the concentrations of cations and anions in water in the case of potential changes caused by the techno genic impact to the environment. There was studied content of technogenic sodium chloride in underground water model and based on them were obtained working formula to express evaluation of solution pH and the concentration of chloride ion in different waters: рН=29,17 ССl-0,44 (in the case of increasing the concentration of chloride ion in water, mg/l); рН=8,49 CCl -0,015 (in the case of decreasing the concentration of chloride ion in water, mg/l). Keywords: Anion, Cation, Sodium Chloride, pH value, Underground Water. 158 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Monitoring of Seasonal and Spatial Variations in Marine Water Quality at the Mid-Black Sea Coast of Turkey I. Senturk*, S. Ustun, M. Oztel, H. Ozkaynak, E. Akcam, E. Gecer, F. Akbal, Buyukgungor G. Bakan, H. Ondokuz Mayis University, Engineering Faculty, Environmental Engineering Department, Samsun, TURKEY. (E-mail: [email protected]*, [email protected], [email protected], [email protected], [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT The aim of this study was to investigate the seasonal and spatial variations in marine water quality at the Mid-Black Sea coast (Sinop, Samsun, Ordu) of Turkey. Marine water samples were collected from 39 stations at 3 different distances from the coast (500 m, 3 miles and 20 miles) during the winter (January), spring (April), autumn (November) and summer (July) seasons between 2013 and 2014. In this study, water quality data of several physical and chemical parameters for samples of shore, near-shore and off-shore stations along the mid-Black sea coast of Turkey were analyzed. Phenol, methylene blue active substances (MBAS), ammonium (NH4+-N) and nitrate-nitrogen (NO3--N) concentrations of the samples were measured with proper analytical kits using a PG-T70 UV/VIS spectrophotometer. Dissolved oxygen (DO), pH, temperature, total dissolved solids (TDS), electrical conductivity (EC), salinity and, redox potential (Eh) were measured on site using a field multi-probe (Consort C535). Nutrients (NH4+-N and NO3--N), dissolved salts (EC, TDS and, salinity), physical parameters (pH, Eh, DO and temperature) were the most important parameters in contribution to seawater quality variations. Results would provide useful technical supports for coastal pollution controls and environmental management works. When the results are evaluated in terms of marine water general quality criteria’s given in the water pollution control regulations of Turkey, it is seen that phenol concentration exceed 0,001 mg/L limit value. However, pH and DO values are usually convenient. Phenol concentrations in collected marine water samples is exceeded standard value (0,005 mg/L) required to provide of the coastal and marine waters used for recreational purposes. The highest concentrations of MBAS may be mainly due to domestic wastewater discharges. The highest concentrations of phenol were found which may be attributed to the industrial wastewater discharges. The result showed that contamination of coastal waters occurred mainly from domestic and industrial wastewater discharges and agricultural runoff. Keywords: Black Sea, Marine water quality, Monitoring, Physicochemical parameters. 159 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Spatial Variation and Heavy Metal Concentration in Sediments of Bued Rive r: A Preliminary Assessment of a River nearby Small-Scale Mining Sites in the Philippines Christian R. Orozco* 1, Reygie Q. Macasieb 2, Ben Joseph M. Tapales3 and Augustus C. Resurreccion 4 1, 2, 3, 4 Institute of Civil Engineering, University of the Philippines Diliman, PHILIPPINES (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Water bodies nearby mining sites like the Bued river are especially at risk of heavy metal contamination. In this study, preliminary assessment of Bued river in the Philippines was carried out by assessing heavy metal concentration in its river sediments. Bed sediment samples were obtained along ten sampling locations from upstream to downstream of Bued river. Concentrations of Hg, Pb and As in sediment samples were determined in the laboratory using cold vapor atomic absorption spectroscopy (AAS), flame AAS and hydride generation AAS respectively. Physico-chemical characteristics of sediment samples such as specific gravity, particle size distribution and pH were determined and correlated with the measured heavy metal concentrations. Strong correlation (r = 0.859; p<0.01) was observed between As and Pb which may be indicative of common sources for these two metals. Unlike As and Pb, mercury is found to be loosely correlated with the particle size. Significantly higher concentrations of Hg, Pb and As were observed in areas near mining operations. Maximum measured values of Pb (2646.24 mg/kg) and As (30.47 mg/kg) in sediments exceeded that of the toxic effects threshold of the Canada sediment quality guidelines while maximum Hg (0.373 mg/kg) measurement exceeded that of the minimal effects threshold. This indicates that heavy metals in Bued River may pose low to medium risk to the environment. Keywords: Assessment, Bued river, Contamination, Heavy metal, Mining Acknowledgment: The authors thank the Department of Science and Technology (DOST) of the Philippine government for funding this study through the project Mineral Extraction with Responsibility and Sustainability (MinERS) B: Modeling of Fate and Transport of Heavy Metals in Surface Water From Source at Mining Site to Downstream Receiving Water 160 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Uncertainty for Trace Elements Measurement in Drinking Water with ICP-MS Ozlem TUNC DEDE, Asst. Prof. Dr. Environmental Engineering Department, Faculty of Engineering, Giresun University, TURKEY (E-mail: [email protected]) ABSTRACT The estimation of uncertainty in the analytical measurements is a critical part of any quantitative analysis and it indicates the confidence of the produced results in the laboratories. It is also requirement of ISO/IEC 17025:2005 standard which is generally using as a guide for the accreditation of the laboratories. This study covers the evaluation of measurement uncertainty related with the analysis of eight trace elements (Pb, Zn, Cr, Mn, Cu, Cd, Hg and As) in drinking water by using Inductively Coupled Plasma-Mass Spectrometry (ICPMS) technique. Certified high purity standards were used for the preparation of the calibration solutions. All measurements were carried out according to EPA 200.8 method. The EURACHEM guide for quantifying uncertainty in analytical measurement was the main reference material for the estimation of uncertainty. Uncertainty evaluation involved three steps. First, uncertainty components (purity of calibration standards, volume, precision, recovery and calibration curve) were identified. In the second step, components were assembled to get total uncertainty. The last step involved the calculation of expanded uncertainties by using coverage factor of two (for an approximate level of confidence of 95%). The expanded uncertainties for eight trace elements were between ±0.6 and ±0.1 µg/L. Calibration curve and recovery are the major contributions to the measurement uncertainty. Keywords: Uncertainty, analytical measurement, ICP-MS, drinking water. Acknowledgement: The experimental part of this study has been conducted by the author during her professional working life in General Directorate of State Hydraulic Works (DSI), The Technical Research&Quality Control Department, Chemistry Laboratory (Turkey). The author would like to thank to those who contributed to laboratory analysis in DSI Laboratories. 161 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Eastern Black Sea Region Of Domestic Water Capacity: The Case Of Artvin Beste Yalçın Çelik1, Kazım Onur Demirarslan*2 1 Artvin Çoruh University, Faculty of Engineering, Department of Environmental Engineering, TURKEY. (E-mail: [email protected]) 2 Artvin Çoruh University, Faculty of Engineering, Department of Environmental Engineering, TURKEY. (E-mail: [email protected]) ABSTRACT Water resources consist of the total of superficial resources such as a lake or river in a basin, a region or in a country and the underground water resources. Humans satisfy their water needs from superficial waters and underground water resources. The usable water potential of Turkey is 110 billion m3. Of this potential, 16% is used as drinking and tap water, 72% is used in agricultural watering, and 12% is used in industry. The mean annual superficial water amount in eastern Black Sea Region is 25,741 million m3, and this equals with 13% of that of entire country. This indicates that eastern Black Sea cities are rich for superficial waters. Despite that eastern Black Sea region is the region receiving the most precipitation, due to its excessively sloping topography and volcanic character of its geologic structure, it is one of the poorest regions of our country in terms of resource and underground water potential. Since topographical and geological structure properties of southern part of eastern Black Sea region are different from that of northern part, this part is richer for resource and underground water even though it receives less precipitation. Due to high calcium carbonate content of geological units in southern part of Eastern Black Sea region and their aquifer character, the amount of resource and underground water is higher. Artvin city is located in easternmost point of Eastern Black Sea region. Its mean annual superficial water amount is 6.799 million m3, and it is the highest value among the eastern Black Sea region cities. The reason of this is River Çoruh constituting 88% of mean annual superficial water. Artvin city’s superficial water potential is 6,799.40 hm3/year. The largest river in the city is River Çoruh, and its mean flow rate is 154 m3/sec. This corresponds with averagely 5.9 billion m3 flow annually. Total securely withdraw able underground water potential of the city is 25 million m 3/year. Total water potential of the city is 6.83 billion m3’tür. Artvin is a city having a water potential higher than Turkey’s average. In this study, by revealing the water potential of Artvin city, the regulations and investments required for evaluating this potential in best way are discussed. Keywords: Artvin, Eastern Black Sea, Water Potential 162 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessing the mobility and bioavailability of metals in an aquatic environment Gunnar Jacks* 1, Xhume Kumanova 2 and Gjovalin Leka 2 1 Div. of Land and Water Resources Engineering, KTH, SE-100 44 Stockholm, SWEDEN. 2 Albanian Geological Survey, Rruga e Kavajes 153, Tirana, ALBANIA (E-mail: [email protected]; [email protected]) ABSTRACT Metals released and transported in streams, rivers and lakes may be transported as suspended, colloidal and more or less dissolved. Assessing the fractions of metals will give measures of mobility and bioavailability. There are experimental methods like filtration, ultrafiltration and dialysis. These methods can be complemented by speciation through geochemical modelling with PHREEQC and MINTEQ. This study has used filtration and dialysis in a river in Albania and in some streams in northern Sweden. The rivers Fani and Mati in northern Albania host large amounts of waste from mining and metallurgy in their catchments. The concerns in this connection is biotoxicity in the river itself, risk of spreading heavy metals into a large coastal aquifer (Kumanova et al. 2014) and uptake of heavy metals in blue mussels offshore. By analysing unfiltered, filtered (0.2 m), and dialysed (10 and 1 kDa pore size) in the river water is has been found that close to point sources, a large portion of notably copper is present in suspended form, thus less mobile and bioavailable. More mobile were zinc and nickel. The levels of the heavy metal decreased rapidly downstream point sources mirroring rapid settling of the suspended and colloidal fractions. Sequential extraction of river sediments indicates that chromium and nickel are abundant in silicate minerals, olivine and spinel, from the ophiolitic host rock of the ores. This is also evident from sequential extractions on sediments offshore the Drin and Mati rivers at the Adriatic coast (Rivaro et al. 2007).Total elemental analysis of sediments do overestimate the risk of notably chromium and nickel pollution. The study indicates that the bioavailability of the metals is low. Arsenic is high in sediments close to point sources but the ferric oxyhydroxides provide a very efficient sink for the arsenic at oxidising conditions (Jacks et al. 2013) Provision of sedimentation dams close to the point sources would decrease the transport which is likely to occur to a larger extent only during high flow occasions. An important factor in deceasing the mobility and bioavailability is the good buffering in the river water provided by carbonate rocks and not least the ophiolitic rocks that dominate the bedrock in the catchment. References Jacks G, et al. (2013) Appl. Geochem. 35:35-43. Kumanova Xh, et al. (2014) Hydrogeol. J. 22:883-892. Rivaro P, et al. (2007) Toxicol. & Environ. Chem. 87(4)481-498. 163 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Numerical Prediction of the Efficacy of Treated Wastewater Recharge to Impede Seawater Intrusion in the Coastal Aquifer of Gaza- Palestine Hasan Sirhan*1, Manfred Koch1 and Khalid Qahman2 1,2 Authors’ Department of Geohydraulics and Engineering Hydrology, Institute of Geotechnology and Geohydraulics, Kassel University, Germany. (E-mail: [email protected], [email protected]) 2 Author’s Department of Water Resources, Gaza University, Palestine. (E-mail: [email protected]) ABSTRACT The ongoing depletion of the coastal aquifer in the Gaza Strip due to overexploitation has led to the process of seawater intrusion, which has continually becoming a serious problem in Gaza over recent decades, as the seawater has invaded deeply inland at many sections along the coastal shoreline. In this context, prediction of the future behavior of the seawater intrusion process in the Gaza aquifer is thus of crucial importance to safeguard the already scarce groundwater resources in the region. To that avail, the coupled three-dimensional density-dependent groundwater flow and solute transport SEAWAT- model, as implemented in Visual MODFLOW, is applied to the Gaza coastal aquifer system to simulate the location and the dynamics of the saltwater–freshwater interface in the aquifer between the periods 2000-2010. After successful calibration of the solute transport model, various future groundwater management scenarios for the Gaza aquifer are studied. In the first, pessimistic scenario, it is assumed that pumping from the Gazaaquifer continues to increase in the near future to meet the rising water demands, and there is not further recharge to the aquifer than what is provided by natural precipitation. The second, optimistic scenario assumes that treated surficial wastewater can be used as a source of additional, artificial recharge to the aquifer which, in principle, could revert even some of the adverse present-day conditions in the aquifer (i.e. seawater intrusion). This scenario has been simulated using three distinct variants of the artificial recharge implementation that differ by the way of injection and located across the Gaza strip. The results obtained with the first (do-nothing) scenario indicate that there will ongoing negative impacts on the aquifer, which induced the propensity for strong seawater intrusion into the aquifer, where the amount of saltwater intrusion into the aquifer coastal part increases by about 35 %, meanwhile the saltwater-polluted (salinity) will be increased by 34 %.In contrast, all three cases of the second (artificial recharge) scenario group can partly revert the present seawater intrusion, as the artificial recharge option reduces the amount of water entering the aquifer by seawater intrusion by 81 %, 77 and 72 %, for the three recharge cases, respectively. Meanwhile, the saltwater-polluted (salinity) reduces by 15%, 32% and 26% for the three cases, respectively. Finally, one may note that the results of the various artificial recharge scenarios indicate that there is some success of aquifer recovery, as the presently existing saltwater intrusion is partly been reverted by the end of simulation period in year 2040. Keywords: Gaza aquifer, seawater intrusion, SEAWAT, recharge. 164 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The knowledge of the residents from the blackfoot disease (BFD) area conce rning the health risk of arsenic (As) pollution Ming-Chao Lin*1, Jen-Chun Ou2, Ting-You Liu2 , Bo-Sen Huang2 and Ying-Tai Hsu3 1 General Education Center, Nanhua University, TAIWAN. (E-mail: [email protected]) 2 Department of Environmental Biology and Fisheries Science, National Taiwan Ocean University, TAIWAN. (E-mail: [email protected]; [email protected]; [email protected]) 3 Department of Ethnology, National ChengChi University, TAIWAN. (E-mail: [email protected]) ABSTRACT Arsenic (As) has been well documented as a carcinogen. A significant exposure-response between As concentration and blackfoot disease (BFD) has been reported. Blackfoot disease, first observed in the 1930s and peaking in the 1950s, is correlated with the consumption of groundwater by local inhabitants living in the coastal area, southwestern Taiwan. Nowadays most of the people living in this area do not use groundwater as potable water, but the groundwater is still used for aquaculture. The groundwater cultured fish from this area have been evidenced contaminated with As. Ingestion of As-contaminated fish could result in As accumulation in inhabitants and lead to adverse health effects; h owever, if the residents from the BFD area realize this risk remains unknown until now. In this study, questionnaire was conducted to interview 102 residents from the BFD area. The resulting data show that the residents from the BDF area have lack of the knowledge concerning BDF and As contamination. There are 74% of the residents from the BDF area do not know that BFD is caused by As; 72% of the residents have never even heard of As. More environmental education concerning As pollution and the risk in human health needs to be undertaken. Keywords: Arsenic (As); Blackfoot disease (BFD); Environmental education; Groundwater; Water Pollution Acknowledgment: This work was financially supported by the National Science Council (NSC) of Republic of China [Project number: NSC101-2511-S-343-002]. The earlier draft of this manuscript benefited from the comments of Mr. Rudolf Regout. 165 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination of Diyarbakır Basalt Aquifer Water Quality parameters and obtain thematic maps with using GIS technique Recep ÇELİK* 1 1, Authors’ Asst. Proff. Dr. Dicle University Engineering Faculty. Civil Engineering Department, Diyarbakır/TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT In this study, groundwater quality and water features of Diyarbakır urban basalt aquifer which contains Bağlar, Kayapınar, Sur and Yenişehir residential areas, aimed to determine. At this location, water wells opened for drinking water as well as irrigation water is used in the agricultural field. Therefore in the study area which opened in water samples taken from water wells were examined. It was reformed in the field, water samples were taken from the predrilled water wells. Water wells in the same coordinates are determined by Garmin etrex 30 handheld Gps system. Chemical analysis of water samples taken in the laboratory was made. Some of the wells water’s pH, EC, and TDS features were acquired by Portable Hanna HI 98125 PH/EC/TDS/0C meter device at the field. At this study, basalt aquifer features are considered and water quality and water chemical properties determined in Diyarbakır City centre. PH, EC, TDS values of the water samples taken on site as well those water chemical analyses measured in the laboratory. Then they were modelled by using ARC INFO GIS programme and Geostatistical analyst extension tool. At the end of this process, thematic map of Diyarbakır’s basalt aquifer PH, EC, TDS were produced. Keywords: Groundwater, GIS, Water Quality, Diyarbakır City Center Acknowledgment: The authors thank Dicle University, Scientific Research Project Funding (DUBAP) for their financial support [Project number: MYO 147]. 166 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Occurence and Precursors of Haloacetonitriles in Drinking Water –A Review Cihan OZGUR* 1, and S. Sule KAPLAN BEKAROGLU* 2 1 Department of Environmental Engineering, Faculty of Engineering, University of Suleyman Demirel, TURKEY. (E-mail: [email protected]) 2 Water Institute, University of Suleyman Demirel, TURKEY. (E-mail: [email protected]) ABSTRACT Over the last 30 years, many academic studies, more than 700 disinfection by-products (DBPs) have been identified in drinking waters. However, only a small fraction of those DBPs are currently regulated. Trihalomethanes (THMs) and haloaceticacids (HAAs) are two major groups of DBPs commonly found in chlorinated water. Characteristic functional group is nitrogen for nitrogenous DBPs (N -DBPs) such as haloacetonitriles (HANs), cyanogen halides (CH), and halonitromethanes (HNMs). (N-DBPs) have been reported to be much more cytotoxic and genotoxic than the regulated THMs and HAAs. HANs are an unregulated class of N-DBPs. HANs are a group of emerging halogenated N-DBPs that can be formed as byproducts from the reactions between chlorine, chloramines or bromine disinfectants and organic nitrogen present in source water. From previous studies, specific HANs were determined including bromoacetonitrile (BAN), chloroacetonitrile (CAN), dibromoacetonitrile (DBAN), dichloroacetonitrile (DCAN),trichloroacetonitrile (TCAN), and bromochloroacetonitrile (BCAN). Although the total HANs levels in finished drinking water are about 10% of the THMs concentrations, the cytotoxicity and genotoxicity of some HANs are significantly higher than those of the regulated THMs or HAAs. The impact of human activity upon drinking water sources is increasingly being felt in the form of wastewater effluent and algal activity. Since these are both enriched in dissolved organic nitrogen (DON), their presence is likely to lead to raised concentrations of N-DBPs. Of the components of DON, amino acids are known to act as precursors of HANs. This paper aims to review the state of research on HANs formation in drinking water including with their types and occurence, possible health effects and precursors. Keywords: Disinfection, Disinfection by products (DBPs), Drinking Water, Haloacetonitriles (HAN),Toxicity. Acknowledgment: The authors thank Technical Research Council of Turkey (TUBITAK) for their financial support [Project number: 113Y416]. 167 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Mogan Lake (Ankara) Water Quality Ömer Saylar 1, Semra Benzer* 1, Sezin Düzel 2, Göktuğ Gül 3, Ali Gül 2and Mehmet Yılmaz 2 1 Science Education, Faculty of Education, Gazi Üniversity, TURKEY. (E-mail: [email protected], [email protected]) 2 Biology Education, Faculty of Education, Gazi Üniversity, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 3 Health Services Vocational School, Gazi Üniversity, TURKEY. (E-mail: [email protected]) ABSTRACT Environmental pressures on aquatic ecosystems are increasing rapidly in aquatic ecosystems and available water resources are dwindling. Park, residential areas and agricultural lands cause some negative impact on the lake water around Mogan Lake. Therefore, it is an aquatic system and ecological changes in terms of research. This study has been aimed to determine and evaluate the water quality and physico chemical parameters of Mogan Lake between September 2013 and June 2014. Physico-chemical parameters of water were measured by YSI Oxygenmeters and Palintest Photometer. The significance of differences between monthly values of water quality parameters t test (p <0.05) was determined. The obtained results of water quality parameters were evaluated in comparison with national and international standards. Monthly average annual value of the measured water quality parameters and maximum and minimum intervals were determined. The average value the water temperature (12.67 ºC), pH (6.81), dissolved oxygen (7.76 mg/L), conductivity (1665.55 µs/cm), SPC (2132.56 µs/cm), salinity (1.05 ppt), Total solids (1256.47 mg/L), pressure (691.70 mm/Hg), NH3 (0.17 mg/L), NO2 (0.02 mg/L); NO3 (0.589 mg/L), PO4 (45.63 mg/L), SO4 (182.44 mg/L), alkalinity (362.78 mg/L), hardness (223.89 mg/L), F (1.42 mg/L), Ca (36.89 mg/L), Cl (86.83 mg/L), Mg (80.778 mg/L), Si (3.22 mg/L), Mn (0.0005 mg/L); Fe (0.22 mg/L), Al (0.0001 mg/L), Cu (0.007 mg/L), Br (0.06 mg/L), Zn (0.014 mg/L), H 2O2 (0.22 mg/L); Cr (0.027 mg/L) and Ni (0.11 mg/L) were determined. The average hardness (223,89 mg/L), magnesium (80.78 mg/L) and nickel (0.11 mg/L) is higher than the national (YSKYY, 2012; TSE 266, 2005) and international (WHO, 1996) referance values. Conductivity (1665.55 S/cm) , sulfate (182.44 mg /L) and fluorine (1.42 mg/L) was found to be very close to the maximum value is the reference range. Lake water was determined to be in close feature to limit threats to some physico-chemical parameters. This should be based on the results of Mogan Lake continuous monitoring of water quality parameters and take the necessary measures for environmental threats are recommended. Keywords: Mogan Lake, physico-chemical parameters, water quality. 168 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Sediment and Water Pollution Status of the mid-Black Sea coast of Turkey E. AKÇAM* 1, G. BAKAN 1 1, Authors’ , Environmental Engineering Department, Engineering Faculty, OMÜ, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT The Black Sea is the world’s largest land-locked sea and has an area of 4.2*10 5 km2 with average depth of 1,240 m. Ninety percent of its water mass is anoxic, thus it contains the world’s largest anoxic water mass. The Black Sea has suffered from extensive pollution over the last few years due to unrestricted shipping, mineral exploitation, dumping of toxic wastes, discharge of domestic wastes from coas tal cities and pollutants carried by rivers. Chemical and microbiological pollution, synthetic organic contaminants, heavy metals, radionuclides and oil pollution have caused the environment of the Black Sea to deteriorate dramatically in terms of biodiversity, habitats, fisheries resources, aesthetic and recreational value and water quality. The Black Sea has been increasingly threatened by pollutants over the past decades as a result of accidental crude oil spills, dumping of toxic industrial wastes, dis charge of domestic wastes from coastal settlements and industrial and domestic pollutants carried by rivers. Some industrial areas, rivers, and coastal cities in the Black Sea have a tendency to create local pollution. The main aim of this study was to investigate the surface water and sediment quality of the Yesilırmak, Kızılırmak, Engiz, Kürtün, Mert rivers, discharged to Black Sea from the mid -Black Sea coast of Turkey. In addition to this study was to investigate the seasonal and spatial variations in surface water quality at the mid-Black Sea coast of Turkey. The samples were collected from five stations. Investigated parameter s were total organic carbon (TOC), dissolved oxygen (DO), pH, chl-a and electrical conductivity (EC) in water samples and sediment samples. The determine the trophic state and ecotoxicological potential of the streams, heavy metal analysis (Cr, Cu) were also performed. Keywords: Black Sea, Ecotoxicology, Sediment Pollution, Trophic State, Water Pollution 169 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A RESEARCH OF THE EFFECTS OF SEDIMENT LAYER ON TROPHIC LEVEL IN SHALLOW LAKES; THE CASE OF CERNEK LAKE Hüseyin CÜCE 1 Gülfem BAKAN 2 1,NevsehirHacıBektasVeli University, Faculty of Architecture and Engineering, Department of Environmental Engineering, Turkey(E-mail: [email protected]) 2,OndokuzMayıs University, Faculty of Engineering, Department of Environmental Engineering, Turkey(Email: [email protected]) ABSTRACT The aim of this investigation is to examine and to evaluate the effects of sediment layeron trophic level of shallow lakes. Cernek Lake, one of the shallow lake ecosystems, is selected for the area and the periodic changes on trophic level have been evaluated with geographic information systems by identifying existing water and sediment quality of the lake. Physico-chemical analyzes were carried out for the lake surface water/sediment samples taken from 6 stations periodically(for three seasons, 2010 2011). The trophic state of the lake was over eutrophic after the autumn turnover while it was mesotrophic during the spring turnover with regard to lake surface water quality. It was also found that there are increases in the nutrient levels of the southeastern coast of the lake close to the sea when compared to inland.The results obtained from surface sediments in the field studies showed that there was an increase in amounts of organic and inorganic pollution. The results also revealed that there were high-phosphate (annual average of 541 mg / kg PO4-P, dry weight) and high-organic carbon contents (annual average 22.4 g / kg TOC, dry weight) in the lake sediments. Findings, periodically monitored distribution maps created with ArcGIS exposed that the contaminated lake sediment layer would be higly effective in trophic level of the lake therefore it has revealed the necessity of taking measures for eutrophication. Keywords:lake sediment, lake eutrophication, trophic state, geographic information system (GIS), Cernek Lake 170 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of relationship between water pollutants: A case study from Istanbul Ali Osman Pektas* 1, Ibrahim Ilker Ozyigit 2, Ibrahim Ertugrul Yalcin 1, Nese Yilmaz3 and Goksel Demir1 1 Bahcesehir University, Faculty of Engineering and Natural Sciences, Department of Environmental Engineering, 34353, Besiktas / Istanbul – Turkey (*Correspondent author mail: [email protected], [email protected], [email protected]) 2 Marmara University, Faculty of Science and Arts, Department of Biology, 34722, Goztepe / Istanbul – Turkey ([email protected]) 3 Istanbul University, Fisheries Faculty, Freshwater Biology Department, 34470, Laleli / Istanb ul – Turkey ([email protected]) ABSTRACT Water is one of the most important resources on the earth required by all living organisms for continuation of vital activities. However, water reservoirs are limited and anthropogenic factors have adverse effects on water quality and quantity. Therefore, scientific studies regarding water pollution are highly valuable. These studies mainly focus on the dynamic structure of pollutants, the origin of pollution, the effects and results of pollutants, and pollution or time based analysis of pollution levels. In the present study, interrelationship of water pollutants in three main water supplies of Istanbul, which is one of the most crowded cities of Turkey as well as Europe, was investigated by cluster analysis. A total of 560 water samples collected from three main water supplies in 18 different sub regions (these sub-regions were labeled with numbers 1 to 18) have been analyzed for their heavy metal and mineral nutrient concentrations, and pH values. For this, concentrations of Al, B, Ca, Cd, Cr, Cu, Fe, K, Mg, Na, Ni, Pb and Zn in 560 samples were measured. In this study, we aimed to investigate the relationship between heavy metal concentration, mineral nutrient level and pH value as well as effects of the location on pollution level and type. Keywords: Cluster Analysis, Heavy Metal, Istanbul, Mineral Element, Pearson Moment, Water Pollution. 171 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Microcosm Evaluation of Greenhouse Gas Emission Potentials ofAan Eutrophic Lake E. Ogun* 1, A. Aksoy 2 and S. L. Sanin 1 1 2 Department of Environmental Engineering, Hacettepe University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Middle East Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT Eutrophic lakes are important source of greenhouse gases (CO2, CH4 and N2O) as a result of increased primary production CH4 emission in lakes is occurred under anaerobic conditions with easily degradable nutrients and consumed in aerobic conditions N2O, can produced as an intermediate product during nitrification and denitrification. Sediment is an important production and gas releasing zone of lake ecosystems. Conditions like temperature, oxygen concentration, nutrients, organic matter and redox potential are important factors which effect the mineralization and gas release from sediments. The main objective of this study to investigate the effects of temperature and light intensity on CH 4 and N2O emissions from the different zones of a hypereutrophic lake and determine the behaviour of a natural ecosystem with using a closed and controllable media. Moreover gas production potential is calculated per gram sediment and water. Sediment and water samples were collected and mixed from the five sampling points of eutrophic Lake Eymir. Microcosms were prepare with 110±2 ml of colorless glass bottles. Suitable incubators were used to obtain 4, 10 and 25°C temperatures with day-light fluorescent lamps. GC-µECD-FID system and was used to measure CH4 and N2O gases. Microcosm bottles which shows the highest gas emission were used to isolate pure microorganism cultures and 16S rRNA analysis were used to identify the bacteria species. According to our results CH4 production was higher in dark and 25°C conditions than the others. However the highest N2O production was observed both 25°C and 10°C temperature with dark conditions. The maximum gas production per gram of sediment and water was measured from the bottles which contains water and sediment together. The microcosm bottles under the dark conditions were used to identify dominant species which responsible for gas production. Dominant species under anaerobic conditions were Clostridium difficile, Bacillus amyloliguefaciens subsp. Plantarum, Paenibacillus apiaries, Achromobacter spanius. Keywords: Microcosm experiment; Eutrophic lake; Greenhouse gas Acknowledgment: This project is supported by The Scientific and Technological Research Council of Turkey (TUBITAK) [Project number: 108Y116]. 172 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Greenhouse Gas Emissions of a Shallow Eutrophic Lake Using a Field Column E. Ogun* 1, A. Aksoy 2 and S. L. Sanin 1 1 2 Department of Environmental Engineering, Hacettepe University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Middle East Technical University,TURKEY. (E-mail: [email protected]) ABSTRACT Freshwater ecosystems especially shallow lakes relative to their surface area are very important zones for greenhouse gas (GHG) emissions (CH4, N2O, CO2) and they are typically supersaturated with these gases. Ammonia is the very important alkaline particle in the atmosphere and neutralizes acidic compounds. To fill this gap, our aim in this study to investigate the GHG emission rates and calculates the gas flux from air-water interface with using suitable equations. Data was collected each month until September 2011 to December 2011, and once in June 2012 in a shallow hypereutrophic and dimictic Lake Eymir. In this study, a constructed water column is placed in sampling points and held overnight. Accumulated gas in the column was collected tedlar bags. This method is performed at least more than one time in a day to show daily changes. GC-ECD-FID system is used to evaluate greenhouse gases. Flux rates were calculated using two approaches, ideal gas and two film theory. According to the three years of field measurements, advection of organic compounds to the Lake Eymir’s surface water is changed between 19 – 157 mg/L (COD). Maximum and minimum ammonium and nitrate concentrations were measured between 0.02 - 3.87 mg/L and 0.01 – 9.70 mg/L respectively. Average total phosphorus (624 µg/L), chlorophyll-a (38 µg/L) concentrations, annual average (1,38 m) and minimum (0.25 m) secchi disk depths show that Lake Eymir is a hypereutrophic lake. Although CH4 flux results which were calculated by IGT and two film theory (TFT) show significant relationship with R2 value of 0.6, we couldn’t find the same relationship for N2O and NH3 gases. N2O, CH4 and NH3 fluxes were calculated with ideal gas theory (IGT) change between 68.40 - 4872.24 µmol.m-2day-1, 0.24 to 12.24 mmol.m-2day-1 3.84 to 102.96 µmol.m-2day-1 respectively. These results shows that Lake Eymir’s average annual GHG fluxes equals to annual electricity utilization of 577 houses for N2O and 118 houses for CH4 gases. Keywords: Methane, Nitrous oxide, Ammonia, gas flux; eutrophic lake Acknowledgment: This project is supported by The Scientific and Technological Research Council of Turkey (TUBITAK) [Project number: 108Y116]. 173 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Water Management Policies in the European Union: Finnish Integrated Water Management Example Karafakı Ç. F. 1 1 Niğde Univercity, Faculity of Architecture, Department of Landscape Architecture, TURKEY. (E-mail: [email protected]) ABSTRACT Sustainable water management requires an equilibrium between the amount of water at our disposal and the amount at demand. The water management policies of the EU aims to guarantee sufficient supply of water even under the pressures of a rising population. The EU water management regulations recognize the vital importance of water and thus focus on the prevention of wasteful use of it. The EU app roach to water management is an important guidance to Turkey which has been able to develop only 36% of its existing water resources. Finland, which is among the water rich countries of the EU, was ranked number one on the 2003 water development report published by UNESCO. Furthermore, Finland ranked amongst the richest of the 147 countries listed in a joint Water Poverty Index prepared by the World Water Council and the UK Centre for Ecology & Hydrology. Finland has developed many successful approaches to water management ranging from wastewater management to the development of local water resources for communities. The aim of this study is to analyze the water management strategies of Finland within the framework of water management regulations presiding in the EU. The findings derived from this analysis will be matched against the Turkish example and an effort will be made to investigate as to how the attainment, usage, recycling and sustainability of water in Turkey compares to what is currently prevalent in Finland. Keywords: EU water management, Finland water management, Hydro-politics, Integrated water management, Water regulations 174 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Application of low intensity ultrasound to enhance biological phosphorus removal Bilge ALPASLAN KOCAMEMİ 1*, Nazenin GURE 2, Feraye SARIALIOGLU 3, Cansu KUZEY 4, Ahmet Mete SAATCI 5 1, * Environmental Engineering Department, Engineering Faculty, Marmara University,Istanbul Turkey (E-mail: [email protected]) 2,3,4 Environmental Engineering Department, Engineering Faculty, Marmara University,Istanbul Turkey 5 Turkish Water Institute (SUEN), Ministry of Forestry and Water Affairs, Turkey (E-mail: [email protected]) ABSTRACT Phosphorus is a pollutant in water bodies since it causes diminished water quality, oxygen depletion, eutrophication, which ends up with loss of aquatic life. Among the various kinds of phosphorus removal technologies, chemical precipitation and biological phosphorus removal (BPR) are the most common technologies. However, chemical precipitation is costly and BPR has difficulties to meet the discharge standards. Recent studies have shown that the application of low intensity ultrasound to wastewater may stimulate enzyme activity, cell growth and biosynthesis. In view of these findings, low intensity ultrasound appeared as a possible effective tool that may increase the efficiency biological phosphorus removal by stimulating cell metabolism and hence phosphorus release and uptake rates. In this study, the effect of the ultrasound application on phosphorus release and phosphorous uptake were evaluated under oxic conditions for ultrasound level ranging between 11.1 -86.2 W/L and exposure time ranging between 1 - 10 minute through batch experiments. From the experimental results, optimum level and exposure time were determined as 15.3 W/L and 2.8 min for PO4 – P release, 15.6 W/L and 2.3 min for PO 4 – P uptake processes. For both release and uptake processes, optimum level and exposure time were defined as 14.7 W/L and 3 min. Keywords: Wastewater, biological treatment, biological phosphorus removal, ultrasound Acknowledgment: The financial support of Marmara University (Project number: FEN-A- 090512-01569) is acknowledged. 175 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Forest Fires on Water Sources Ayla Bilgin* 1, Mustafa Aybar 2 and Bülent Sağlam3 1 Artvin Çoruh University, Engineering Faculty, Department of Environmental Engineering, Artvin, Turkey ([email protected]) 2 Artvin Çoruh University, Artvin Vocational School, Forestry and Forest Products, Artvin, Turkey [email protected] 3 Artvin Çoruh University, Forestry Faculty, Department of Forestry Engineering, Artvin, Turkey [email protected] ABSTRACT Environmental pollution is the most important factor concerning destruction of water, soil and air ecosystems in the world. Water sources are one of the areas mostly affected by environmental pollution. It is required to obtain sustainable and accurate data concerning water quality so that qualifications, areal and temporal change of water sources can be understood. Quality of water sources from water basins consisting of forest lands might deteriorate due to natural disasters, forestry activities and use of forest lands for recreation purposes. Quality of water from forests which are not destructed or deteriorated due to natural disasters is generally quite high. Even though forest fires are favorable for the health of forests in the long term, they affect water quality of streams, lakes and rivers in water basins negatively. Researches reveal that forest fires or incineration of production waste in forests result in increase of chemical element amount on the soil surface. Certain amount of such elements remain dissolved, while others reach water sources through sediments. It is identified that N, P, K, Mg, Na, Ca, Mn, Cl and HCO 3 concentrations increase 2 to 100 times in these sources. According to statistical data of the last 25 years, 2070 (on the average) forest fires break out and 11245 ha forest area is damaged every year in our country. These forest fires result in pollution of water sources in addition to major environmental effects. Key words:Water quality, water pollution, forest fire 176 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 CHARACTERISTICS AND PHOSPHORUS RELEASE RATES OF SEDIMENTS IN TWO SHALLOW LAKES (Kızılırmak Delta, Turkey) Hüseyin CÜCE 1 Gülfem BAKAN 2 1, Nevsehir Hacı Bektas Veli University, Faculty of Architecture and Engineering, Department of Environmental Engineering, Turkey (E-mail: [email protected]) 2, Ondokuz Mayıs University, Faculty of Engineering, Department of Environmental Engineering, Turkey (E-mail: [email protected]) ABSTRACT The sediment plays an important role in the overall nutrient dynamics of shallow lakes. The pollutants may be released from the sediments if the overlying water quality changes. Shallow lakes typically act as a phosphorus (P) sink during spring and winter whereas they become a P source for the downstream surface waters during summer. Because phosphorus release occurs predominantly during late spring and early summer. The release of P from lake sediments is a highly complex phenomenon which involves a number of physical, chemical, and biological processes. The study site, Kızılırmak Delta, is located at the Mid-Black Sea coast of Turkey. Within the delta area (about 56 000 ha) can be found many shallow lakes, the surroundings wetlands are unique biological resources and highly important for sustaining biodiversity. The site is interesting in that several anthropogenic factors simultaneously have a marked effect on the quality of the wetland system. Two lakes situated in the east of the Kızılırmak Delta, Balık Lake and Cernek Lake were chosen for this study. Cernek Lake is one of the most important shallow water of the Delta coastline, with the average depth of about 1,5m and has an area of 4,1 km 2. The whole lake has suffered serious eutrophication. Balık Lake is a meso-to-eutrophic lake, an average depth of about 2,3 m and has a much larger watershed of 13,8 km 2. The water quality is much better than Cernek Lake; it is one of the better fishing lakes in the Delta area. Main objective of this study was to investigate the sediment qualities of this shallow lakes based on phsico-chemical parameters on seasonally basis. Secondary objectives were to (a) spatially characterize surface sediments of lakes, (b) determine the sediment P release rates, (c) estimate the relationship between P release and trophic state change as well as eutrophication in the lakes. A total of 6 surface sediment samples were collected periodically in 2010-2011 to describe the seasonal and spatial variation in sediments taken from Lakes Balık and Cernek. Laboratory studies were conducted to determine the effect of the rates of P release in lake sediments on trophic state change of that lakes. It was found that the sediments from Cernek Lake have P release rates ranging from 2.63 to 4.10 mg P/m2/d. Balık Lake exhibits lower P release rates (average 3,10 mg P/m2/d) than Lake Cernek. However both lake sediment types had relatively low P release rates compared with published values for eutrophic systems. These findings could contribute to more effective management of the studied lakes. Keywords: shallow lake, lake sediment, phosphorus release, Cernek Lake, Balık Lake 177 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Water quality of the river to the Kızılırmak River in the province of Nevsehir Aras Seval* 1, Fındık Özlem2 , Kalıpcı Erkan 3 and Şahinkaya Serkan 3 1, 3 2 Department of Environmental Engineering, Faculty of Engineering and Architecture, Nevşehir Hacı Bektaş Veli University, Nevşehir, TURKEY. ([email protected], [email protected], [email protected]) Department of Molecular Biology, Faculty of Arts and Sciences, Nevşehir Hacı Bektaş Veli University, Nevşehir, TURKEY. ([email protected]) ABSTRACT The Physico-chemical parameters (Water temperature, BOD, COD, pH, dissolved oxygen (DO), conductivity, suspended solids, nitrite (NO3), ammonium (NH4), ammonia (NH3), phospate (PO4), sulphate (SO4)) and some metal concentrations (Zn, Cu, B, Cr, Ni, Pb, Hg, As, Se, Cd and Al) were measured in the water samples to determine the water quality of the Kızılırmak river. Kızılırmak is the length river of Turkey. Six sampled stations are in the border Nevşehir province. The study was conducted seasonally in 2013-2014. Measured metals are determined lower than limit of SKKY. When the water quality classes were examined in terms of the measured physico-chemical parameters, it was detected that the river is IV class for nitrite, II. and IV. class for ammonium at autumn and spring respectively, III. and IV. class for BOD at summer and spring respectively. Keywords: Metals, Physico-chemical parameters, Kızılırmak river, water quality Acknowledgment: The authors thank Nevsehir Haci Bektas Veli University, Scientific Research Project Funding (NEUBAP) for their financial support [Project number: NEUBAP13F22]. 178 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Beneficial Use Alternatives for Dredged Materials: Landfill Daily Cover H.M. Başar* 1, S. Dağlı2, P. Özer Erdoğan 3, B. Güzel 4 and L. Tolun5 1,2,3,5 Environment and Cleaner Production Institute, TÜBİTAK MAM, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected]) 4 Department of Chemistry, Faculty of Arts and Science, Abant İzzet Baysal University, TURKEY. (E-mail: [email protected]) ABSTRACT Dredging is substantial for the maintenance, enlargement, deepening and development of ports, harbours and navigation waterways. This process generates high quantities of dredged material; hence, management of dredged material is a common problem all over the world. Dumping at sea poses a risk to the aquatic environment while upland disposal are expensive and require large areas. The development of alternative management strategies for dredged materials is therefore necessary. Conventionally, dredged material has been thought as a waste; however, it can be evaluated as a valuable resource in many beneficial use alternatives such as topsoil creation/enhancement, construction materials production, road applications, landfill daily cover, mine reclamation, beach nourishment, wetland creation, habitat restoration. The purpose of this work is to investigate the usability of dredged materials as an alternative landfill daily cover for our country in terms of technical and economical view. Firstly, the physico-chemical, morphological, toxicological properties and leaching potential of materials dredged from three pilot regions (Rize Port, Samsun Port, Yakakent Fishing Port) from Black Sea were determined; then, the analysis results were compared with the limit values stated in "The Regulation on the Landfilling of Waste-Appendix 2: The acceptance criteria of the landfilling of waste" and "The Regulation on the General Principles of Waste Management Appendix 3B: Hazardous waste threshold limits". The cost analyses were also conducted in order to compare three management options (dumping, disposal, landfill daily cover usage). The results showed that dredged material can be used as an alternative landfill daily cover and provides economic advantages among other management strategies. Keywords: Beneficial Use, Characterization, Daily Cover, Dredged Material, Landfill. Acknowledgment: This work is financially supported by the TÜBİTAK 1007 Programme [DİPTAR, Project No. 111G036]. The authors wish to thank Ministries of Environment and Urbanization and Transport, Maritime Affairs and Communications and İZAYDAŞ for their supports. 179 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Quantitative Determination of Policyclic Aromatic Hydrocarbons in Drinking and Potable Water Resources of Diyarbakir Region H. Kara*1, Z. Tunay2, Mustafa A. Yilmaz 3, H. Temel 4 1 GAP Agricultural Research Institute, Sanliurfa, Turkey 2 Vocational School of Diyarbakır, Dicle University, Diyarbakır, Turkey 3 4 Dicle University Science and Technology Research and Application Center (DÜBTAM) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Dicle University, Diyarbakir, Turkey ([email protected],[email protected],[email protected], 4 [email protected]) ABSTRACT It is a known fact that policyclic aromatic hydrocarbons (PAHs) are mutagenic, toxic and carcinogenic. Due to these dangers, it is important to know their amount in foods, drinks and the environment. PAHs might result from both natural and industrial reasons. Waste incineration, cement plants, oil refineries, coke and asphalt production, aluminum, iron and steel production are the main industrial examples that for PAHs’ apperance [1-2]. Province of Diyarbakır is a region where oil production activities are intensely carried out. Thus, for the sake of public health, it is significant to determine the PAH level in the water resources around the oil fields. For this purpose, drinking and potable water samples were taken from the districts of Diyarbakir close to the oil fields. HPLC-fluorescence technique was used to analyse. Some of the most toxic and carcinogenic PAHs that are benzo[a]pyrene (BaP), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF), chrysene (Chy), dibenzo[a,h]anthracene (DBahA), benzo[g,h,i]perylene (BghiP) were determined. In the majority of samples, the total PAH values were determined. It is lower than toxic limit value which are the allowable limit of World Health Organization (WHO) and other national and international organization. Key words: Diyarbakir, Drinking Water, PAH, HPLC- Fluorescence Acknowledgment: The authors thank Dicle University, Scientific Research Project Funding (DUBAP) for their financial support [Project number: 12ZEF94]. 180 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Disinfection by-product formation of natural organic matter Alper Alver, Emine Baştürk* and Ahmet Kılıç Aksaray University, Engineering Faculty, Department of Environmental Engineering, Aksaray, TURKEY (E-mail: [email protected]) ABSTRACT Natural organic matter is the precursor for disinfection by products in treated drinking water. The NOM concentration and characteristics significantly affect the formation of DBPs. NOM levels generally are measured as total organic carbon or dissolved organic carbon. Increasing the NOM level affect DBP formation in two ways. First, increasing the NOM level will increase the level of DBP precursors, which increases DBP formation. Second, increasing the NOM level will increase the chlorine demand of water. A high chlorine demand in turn requires a high chlorine dosage to maintain a proper chlorine residual in distribution system. This high chlorine dosage leads to a further increase in the formation of DBPs. In this study, DBP formation potential formed by chlorination of Sigma Aldrich humic acid and required chlorine dosage for various DOC concentrations, was investigated. The DBP concentration and speciation affected by many water quality parameters and operating conditions, including NOM concentration, chlorine residual, reaction time and bromide concentration. Keywords: Natural organic matter, Sigma Aldrich Humic Acid, DBP, Trihalomethane. Acknowledgment: We thank the Environmental Engineering Department of Aksaray University for providing laboratory equipment of the work described in this paper. 181 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biofilms in Drinking Water Distribution Systems, Cappadocia 2015 Işıl VAR 1, Bülent ZORLUGENÇ 2, Özlem ATASEVER SAVAŞ 1, Selin SAĞLAM 1 1 2 Cukurova University Agricultural Faculty, Food Engineering Department, Adana, TURKEY ( E-mail :[email protected], [email protected], [email protected] ) Hacı Bektaş Veli University Engineering - Architecture Faculty, Food Engineering Department, TURKEY (E-mail: [email protected]) ABSTRACT Water for human consumption is required to be free from any microorganisms that might pose a health risk. The microorganisms in drinking water systems can attach to piping materials and form biofilms on pipe surface. The presence of biofilms in the drinking water distribution system may play a role in the presence of pathogen microorganisms. Biofilms in drinking water distribution systems provide a mosaic of electrochemical and nutritive environments for microorganisms. Microorganisms in biofilms are more resistant than planktonic microorganisms to environmental conditions, so the presence of biofilms within a water drinking distribution system may act as a form of protection against extreme environmental conditions. Biofilms formed in water drinking distribution networks are known to cause public health problems, such as protecting and supporting pathogenic microorganisms, bacterial regrowth, and depletion of disinfection agents. Biofilms in drinking-water pipe networks can be responsible for a wide range of water quality and operational problems. Biofilms also can be responsible for loss of distribution-system disinfectant residuals, increased bacterial levels, reduction of dissolved oxygen, taste and odor changes, red or black water problems due to iron- or sulfate-reducing bacteria, microbial-influenced corrosion, hydraulic roughness, and reduced materials life. Microorganisms in biofilms can include bacteria (including coccoid round, rod-shaped, filamentous, and appendage bacteria), fungi, and higher organisms like nematode larvae. Recently, researchers have shown that viruses and parasites like Cryptosporidium can be trapped in biofilms. Although viruses and Cryptosporidium do not grow in a biofilm, they can attach to biofilms after a contamination event. This review will research community composition of biofilms formed in a drinking water distribution systems. Keywords: Biofilms, Distribution, Drinking Water, Systems 182 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessment of natural radioactivity by gross alpha and beta measurements in drinking water samples in Ereğli, Turkey Mehmet E. Korkmaz 1 and Osman AGAR 2,* 1 Karamanoglu Mehmetbey University, Department of Physics, Karaman, TURKEY (E-mail: [email protected]) 2 Karamanoglu Mehmetbey University, Department of Physics, Karaman, TURKEY (E-mail: [email protected]) ABSTRACT A monitoring of radioactivity content was carried out in drinking water samples collected from surrounding of Ereğli in Turkey. The gross alpha and beta activity concentrations of 12 different water samples were determined by using a gas-flow proportional counter. The measured values of gross alpha and beta concentrations were compared with recommended for drinking waters WHO (World Health Organisation) and ITS (Institution of Turkish Standards) guideline activity concentration. Radioactivity contour maps were produced and their data were evaluated statistically. Keywords: Radioactivity, drinking water, gross alpha, gross beta Acknowledgment: This work was supported by Karamanoğlu Mehmetbey University Scientific Research Project (14–M–14). 183 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Modeling the Relationships between Water Temperatures and Meteorological Parameters at Kızılırmak River using Artificial Neural Networks Merve Temizyürek1 and Filiz Dadaser-Celik* 2 1, 2 Dept. of Environmental Engineering, Erciyes University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT River water temperature is one of the most important water quality parameters. It not only affects all chemical and biological processes in water but also have important implications for aquatic life. Water temperature variations in rivers can be influenced by different factors, which are generally characterized as meteorological and geophysical parameters. This study aims to develop an artificial neural network (ANN) model to examine the relationships between water temperatures and meteorological parameters at Kızılırmak River in Turkey. In this study, monthly water temperatures measured at four stations and climatic data obtained from nearby climatic stations were used. A multi-layer perceptron type ANN model with one hidden layer was selected. The model included six input parameters: solar radiation, precipitation, air temperature, wind speed, relative humidity and historical water temperatures. The model output consisted of water temperatures. All data were available for the 1995-2007 period, with occasional missing records. Model training was accomplished by using 70% of the data and a scaled conjugate gradient backpropagation algorithm. The remaining 30% of data were used for model testing. The activation functions of the ANN model and the number of neurons in the hidden layer were determined by trial-and-error method. The performance of the model was evaluated by calculating the root mean square error (RMSE) between observed and simulated water temperatures. The analysis showed that ANN models can be used for simulating the water temperatures based on meteorological data at Kızılırmak River. Keywords: Artificial neural networks, water temperatures, Kızılırmak River Acknowledgment: The authors thank Erciyes University for the financial support [Project number: FYL2015-5645]. 184 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Study on Importance of Pollution Monitoring and Control in Buyuk Menderes Basin Cengiz Koc 1, Yıldırım Bayazıt* 2 1, 2 Civil Engineering Department, Bilecik Seyh Edebali University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Water use in agriculture has adverse impacts on the environment by changing terrestrial and aquatic ecosystems because of damming rivers and changing flow regimes, lowering groundwater, polluting soils and water, salinization and draining wetlands. Environmental impacts of water use in agriculture have been described and analyzed in numerous case studies and analyses, in particular, for large scale irrigation The study has been conducted at Büyük Menderes basin which is located in Southwest of our country and where different sectors (irrigation, drinking and using, industry, touri sm, ecology) related to the use and distribution of water sources compete with each other and where the water demands for important ecological considerations is evaluated and where the river pollution has reached important dimensions. Thus, in this study it is aimed to give importance of pollution monitoring and control in Buyuk Menderes basin. Keywords: Buyuk Menderes Basin, Control, Monitoring, Pollution 185 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Interaction of low-impact development techniques and urban river flooding on the zoning – Case study Qomroud 1M.R.Kavianpour , 2Arsalan Behzadipour, 1 Associate Professor and faculty member, Khaje Nasir University Of technology, IRAN. 2Arsalan Behzadi Pour ,M.A student of Civil Engineering - Hydraulic, Khajeh Nasir University of Technology, IRAN (E-mail: [email protected]) ABSTRACT In recent decades, and with Increasing of urban population and development of the city, the amount of impermeable surfaces has been increased. This cause urban runoff enhancement . This enhancement, especially in cities with urban river, increases the possibility of urban flooding caused by the river flooding interaction and urban runoff. In this research, we tried SWMM utilizes software development methods and practices that seek to reduce the impact of runoff to the river flows to reduce Qomroud and Effects using Arc GIS and HEC-RAS software on how we see the flood zone. As we will see in results, LIDs can reduce amount of runoff and subsequent flood zone extends into the lower regions. This will cause the economic profit. Keywords: flood management, flood zone , , runoff ,SWMM. 186 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Integrated River Basin Management M.Y. Kılınç* 1, E. Alkan2 1, 2 Department of Civil Engineering, Hasan Kalyoncu University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Ancient civilizations were born and developed along the rivers such as Euphrates of Mesopotamia, Niles of Egypt, Indus-Ganja of India. Since ancient times, main requirements and demands of man-kind had not been changed a lot. Since then, only means, tools and technologies were advanced. Basic requirements of people’s are fooding, clothing and sheltering. They are the same as before. In general, almost all these demands were supplied through engineering activities on the river basin (catchment or watershed). Demands of man are getting more and more sophisticated in quality and quantity. River basin includes all kind of natural resources which they are vital sources to produce goods and services for mankind to be survived. Therefore river basin should be managed such a way that the natural resources should be utilized in multipurpose and multi-use manner so that sustainable development could be successfully realized. All natural resources should be managed with permanently productive, without wasting; destroying, polluting and keeping enough sources for future generation . The river basin should be well managed and integrated manner, sustaining quality and quantity of production among the natural resources. In this paper, how river basin should be managed with integration among the natural resources without harming each other will tried to be explained and discussed. Keywords: Basin, Watershed Management, Natural Resources, Renewable Energy Sources, Integrated Watershed Management. 187 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 THE EFFECT OF HEAVY METALS IN SOIL AND PLANTS AROUND A LIME FACTORY IN THE BARTIN CITY IN WESTERN BLACK SEA REGION *Halil Barış ÖZEL1, Handan UCUN ÖZEL2 1) 2) University of Bartın, Faculty of Forestry, Department of Silviculture, 74100-Bartın/TURKEY University of Bartın, Faculty of Engineering, Department of Environmental Engineering, 74100Bartın/TURKEY *Corresponding author: [email protected] ABSTRACT In this study, which has been carried out around the Bartın Lime Factory, 10 distance levels have been established with 50m interval in order to determine the heavy metal pollution which the factory leads in soil and plants, and a control point has been taken in 800m distance. Through collecting soil samples from each of distance levels, it has been determined that Pb varied between 5.56 and 68.74mgkg-1, Zn varied between 23.18 and 988.34 mgkg-1, Ni varied between 6.48 and 21.33 mgkg-1, Cu varied between 4.36 and 17.86 mgkg-1, Cd varied between 1.73 and 13.54 mgkg-1, Mn varied between 65.58 and 258.69 mgkg-1, Cr varied between 13.65 and 78.93 mgkg-1, Fe varied between 1665 and 9875 mgkg-1, and As varied between 2.36 and 30.54 mgkg-1. As a result of analyses of samples taken from the leaves of Helianthemum nummularium subsp. nummularium (L.) Miller and Hypericum perforatum L. plants, it has been determined that Pb varied between 6.32 and 37.42 mgkg-1, Zn varied between 441.28 and 1647.56 mgkg-1, Ni varied between 9.56 and 21.52 mgkg-1, Cu varied between 22.48 and 65.33 mgkg-1, Cd varied between 3.75 and 9.72 mgkg-1, Mn varied between 15.42 and 62.53 mgkg-1, Cr varied between 7.52 and 48.52 mgkg-1, Fe varied between 130.45 and 894.53 mgkg-1, and As varied between 2.48 and 28.56 mgkg-1. As a result of implemented variance analysis and Duncan test, it is possible to state that the heavy metal pollution is denser in approximately 200250m away from the factory, and that the pollution level decreases after this distance level. 188 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Investigation of Lead Metal Pollution Along The Tem Motorway Agricultural Soils in Tekirdağ S. Adiloğlu* 1, M.T. Sağlam1 1, Namık Kemal University, Faculty of Agriculture, Dept. of Soil Science and Plant Nutrition, Tekirdağ, TURKEY. (E-mail: [email protected]) ABSTRACT Environment pollution is a big problem for our country and all over the world, nowadays. Heavy metal pollution is very important in environmental pollution. It was investigated lead pollution of near the motorway agricultural lands in this research. For this purpose, 25 different agricultural areas for each edge of motorway and total 50 soil samples were taken from research areas in Tekirdağ. Then extractable lead contents of soil samples were determined. According to the results, lead contents of soil samples were determined between 1,346 and 6,546 mg kg-1. These results were compared with critical values of this heavy metal. Lead pollution was obtained in research area soils. Lead pollution ratio was 60 % in the research are soils. According to the research results it should be recommended phytoremediation methods application in the research are lands for the improvement of lead pollution. According to the results of this research, the Pb pollution in the depth of 0-20 cm in the agricultural land along the motorways in the region should be treated through the use of hyperacumulator plants and fitoremeditation technique in order to reduce this pollution under the limits of toxicity that would allow the cultivation of plants. Keywords: Heavy metal acumulation, agricultural soils, pollution, motorway, Pb Acknowledgment: A part of phD Thesis. 189 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Used the DPSIR framework and Structural Equation Models to applied to environmental risk communication - as Emerging contaminants in Wuxi River Yu-Ting Su *1, Wei-Yea Chen 2, Wei-Lun Lin 3, Yu-An Yu 4 1,2,3 Environmental Science and Engineering Taichung Tunghai University, Taiwan. No.1727, Sec.4, Taiwan Boulevard, Xitun District, Taichung 40704, Taiwan (R.O.C.) (Email: [email protected], [email protected], [email protected], [email protected]) ABSTRACT As the technology development, some Emerging Contaminants interfered with our hormone in a long-term exposure. Using the DPSIR (Drive - Pressure - State - Impact - Respond) model to establishment architecture of environmental risk assessment index system. Through the questionnaire and interview, know that people understand level for the risk perception, stress and state. And use Structural Equation Models (SEM) to search for the best respond to improve the Emerging Contaminants concentration in Wuxi River. In this study, people do not know the Emerging Contaminants and the government’s policy. Though the communication, the government policy of reducing Emerging contaminants emissions that people mostly supported. In the Structural Equation Models, it shows that the Respond is higher relationship with Pressure than others Latent variables. So the government wants to improve the Emerging Contaminants concentration in Wuxi River, they have to ameliorate from Pressure’s index. And in Respond’s observed variables, the people accept for the government to coach the people and factory to how to use the Emerging Contaminants in the correct way and inspect the Emerging Contaminants concentration in the Wuxi River. So the government has to disseminate the Emerging Contaminants property and how to deal with it when people are left over. Keywords:DPSIR、Structural Equation Models、Emerging Contaminants、Wuxi River 190 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Some inorganic species in groundwater of health concern – a global overview Gunnar Jacks* 1, Prosun Bhattacharya 1 and Mohammad Hossain 1 1, 2 Div. of Land and Water Resources Engineering, KTH, SE-100 44 Stockholm, SWEDEN. (E-mail: [email protected]; [email protected]; ) ABSTRACT In general the inorganic species found in groundwater and of health concern tend to be a nions due to the rather poor adsorption of anions in soils and in aquifers materials. While cationic metals are adsorbed onto organic matter and clay minerals anions are adsorbed onto ferric oxyhydroxides. This implies that while the adsorption of cations increase with pH, the opposite is found for anions. Species found in excess in groundwater at levels considered to be a health threat includes fluoride, arsenic, chromate, selenite, nitrate and manganese. Groundwater with excess fluoride is a global problem especially in semi-arid areas. In India about 60 M people are exposed and dental and skeletal fluorosis is common. The sou rces of fluoride are hydroxyapatite and hydroxyl-minerals like pyroxene and biotite. Commonly high fluoride content occurs in groundwater of the Na-HCO3-type. In India it is seen that evapotranspiration causes precipitation of calcite, Mg-calcite and dolomite removing the calcium from solution. It has been considered that fluorite/fluorspar is a limiting specie for solubility of fluoride. However, fluorite tends to be under-saturated even in groundwater with more than 10 mg/l of fluoride. Arsenic has made a come-back as a major pollutant in groundwater the last three decades and the permissible limit has been lowered in most countries from 50 to 10 mg/l. Bangladesh is the worst affected country where about half the population is exposed to drinking water in excess of 10 mg/l. Arsenic is mobilized under natural conditions under by two mechanisms, in reducing groundwater with reduction of ferric hydroxides which under oxidating conditions are good sinks for arsenite.´and under high pH and oxidating conditions when the adsorption of arsenate is lost. In Bangladesh is has been found that oxidating sediment layers provide As-safe water with little risk of cross-contamination. Chromium as chromate is highly mobile and has been found at levels of several mg/l at depths of 50 m in alluvial aquifers in connection to electroplating industries in India. Manganese is mobilized under moderately reducing conditions in groundwater. While it has been considered a technical problem is has recently been found that chronic exposure of children may cause lowering of the intellectual capacity. Nitrate is commonly exceeding the permissible limt. The main health concern, albeit not common, is methaemoglobinemia in children below the age of about 8-10 months. 191 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Lead content in local paints in Pakistan Dr.Abdullah Khan Durrani * 1, Muhammad Rehan Khan 2 and Munir Ahmad 3 1, 2 Institute of chemical engineering & technology, Punjab University, Lahore, Pakistan. (E-mail: [email protected], [email protected]) 3 Progressive traders, Lahore Pakistan. (E-mail: [email protected]) ABSTRACT Lead and its compounds in paints are added as a pigment and to impart specific properties like durability, drying, fresh appearance and moisture resistant. Commonly used compounds of lead in paints are white lead (PbCO3), chrome yellow (PbCrO4) and red lead (Pb3O4). Lead is one of the main health and environmental hazard associated with paints. Lead is toxic and children are easily prone to it because of hand to mouth activities from dislodged and deteriorated paints. Not good for their developing brains, leading to their behavioral problems and low IQ scores. Lead can cause anemia, muscle weakness and brain damage, if swallowed in large amounts. Considering above adverse effects of lead, it is advisable that we should have a strict rules and regulations for the use of lead in paints. As some developed countries already have their defined limits for lead in paints. In United States this limit is 90 ppm, China 600 ppm, Singapore 600 ppm, South Africa 600 ppm and India has 1000 ppm limit for the lead in paints. Some developing countries including Pakistan have failed to regulate their lead contents. The present study was undertaken to determine the levels of lead in water-based, oil based and in dried old paint surfaces. Total 25 samples were analyzed of different colour, different brands and different location of university area for dried paint samples. It was founded that most of the samples contained much high level of lead contents comparing to international standards. However, in water based paint lead level was less than oil based and dried surfaces. Keywords:, Oil-based (enamel) paints, dried paint film. Water-based (latex) paints, Lead pollution Acknowledgment: The authors thank Three Star Chemicals, Lahore for help and University of the Punjab, Lahore Pakistan for financial support [Faculty research funding 2012]. 192 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Environmental Modeling approaches for exposure and risk assessment of prioritize chemicals in industries Bakan G* 1, Laçin S 1 1 Ondokuz Mayıs University, Engineering Faculty, Environmental End. Dept., Samsun/ TURKEY (E-mail:[email protected], [email protected]) ABSTRACT The development of technology and industry, greater use of natural resources leads to big problems in terms of environment. The resulting environmental degradation affects human health and the environment in a negative way and creates the risk of contamination to the environment. Manufactured chemicals are used extensively to produce a wide variety of consumer goods and are required by important industrial sectors. Presently, information is insufficient to estimate risks posed to human health and the environment from the over ten thousand chemical substances currently in use and the hundreds more that are introduced each year. New, more reliable approaches are needed to characterize thousands of environmental chemicals on the basis of both hazard and exposure in a rapid and efficient manner, and to prioritize chemicals based on potential risk. Exposure and risk assessment should be supported by a conceptual model. Exposure is calculated via breathing, digestion, dermal routes. The exposure scenario, including the mode of entry into the environment ( i.e. through air, water and sediment) appears to be an important determinant of the level of agreement between modeling approaches. Chemical Screening Tool For Exposures and Environmental Releases (ChemSTEER) estimates occupational inhalation and dermal exposure to a chemical during industrial and commercial manufacturing, processing, and use operations involving the chemical. It estimates releases of a chemical to air, water, and land that are associated with industrial and commercial manufacturing, processing, and use of the chemical. Exposure, Fate Assessment Screening Tool (EFAST2) provides screening-level estimates of the concentrations of chemicals released to air, surface water, landfills, and from consumer products. It estimates provided are potential inhalation, dermal and ingestion dose rates resulting from these releases. It modeled estimates of concentratio ns and doses are designed to reasonably overestimate exposures, for use in screening level assessment. Uncertainty in using estimated properties for exposure and risk assessment model inputs is expected to be substantial. The main aim of this study is to summarize environmental modeling approaches for exposure and risk assessment of prioritize chemicals in industries. Keywords: exposure and risk assessment, ChemSTEER, EFAST2, prioritize chemicals. 193 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Multicriteria Analysis for Flood Vulnerable Areas in Southeastern Slovakia M. Zeleňáková* 1, P. Blišťan2 and P. Purcz3 1 2 Institute of Environmental Engineering, Technical University of Košice, SLOVAKIA ([email protected]) Institute of Geodesy, Cartography and Geographical Information Systems, Technical University of Košice, SLOVAKIA ([email protected]) 3 Institute of Construction Technology and Management, Technical University of Košice, SLOVAKIA ([email protected]) ABSTRACT Floods are natural phenomena which cannot be prevented. The causes of flooding are extremely heavy rains or rapid melting of snow combined with a significantly reduced ability to detain stormwater in areas. However the negative human-based factors cause changes in runoff ratio and increase the risk of flooding. Human activities change flood behavior in many circumstances. Activities in flood plains and catchment areas such as land clearing for urbanization or agriculture, or construction of infrastructure such as highways, roads and bridges across the flood plain may increase the magnitude of flooding, which in turn increases the damage to property and lives. Determining the flood vulnerable areas is important for decision makers for planning and management activities. Multicriteria analysis methods (MCA) are used to analyze the flood vulnerable areas. Geographical information system (GIS) applications are used for managing, producing, analyzing and combining spatial data. The aim in integrating MCA with GIS is to provide more flexible and more accurate decisions to the decision makers in order to evaluate the effective factors. Some of the causative factors for flooding in watershed are taken into account as daily rainfall, size of watershed, land use, slope and the type of soil. The selection of criteria that has spatial reference is an important step in MCA. The objective of this article is to analyze the flood vulnerability in Bodva river basin, eastern Slovakia. We determined the flood-effective factors, estimate their significance and applied two different approaches of MCA inside the GIS environment. Keywords: analytical hierarchy process, causative factors, flood risk, geographical information system, ranking method. Acknowledgment: The contribution is written thanks to support of project VEGA 1/0609/14. 194 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Implementation of Watershed Sustainability Index on Turkey: Meriç-Ergene Specimen Caner GÖK* 1 and Selim L. SANİN 2 1 Department of Environmental Engineering, Hacettepe Univercity, TURKEY (E-mail: [email protected], [email protected]) 2 Department of Environmental Engineering, Hacettepe Univercity, TURKEY. (E-mail: [email protected]) ABSTRACT Increasing demand for the water resources and the absence of these resources in terms of desired quality and quantity depending on the spatial and temporal scale required to use the water resources in the most effective way among the economic, environmental and the social benefits. In other words, the water resources are required to be managed. Therefore, environmental, social, economic and political factors, which will affect the quantity and the quality of the water resources, should not be left behind in the management of the water resources. The integrated water resources management systems have to take into consideration all these factors. Several indices have been developed to see whether the integrated water resources management systems are being implemented in an efficient way or not. Thanks to these indices which include many environmental, social, economic and political factors, it can be identified whether the water resources management is carried out in a sustainable way and which the parts have lacking points. In this study, the current situation of the sustainable integrated water resources management in Turkey and its development between 2008-2012 have been elaborated, especially in Meric-Ergene basin with the HSI index. The lacking points and the positive developments have been identified, and the methods which will facilitate the use of this index in Turkey has been discussed. However, in this study, the modifications of HSI index and basins future development also has been interrogated. Keywords: indices, integrated management, meriç-ergene watershed, sustainability, watershed management. 195 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Enviromental Impacts of Medical Drugs and Cosmetics Waste Karafakı Ç. F. 1, Karafakı L. 2 1 Niğde Univercity, Faculity of Architecture, Department of Landscape Architecture, TURKEY. (E-mail: [email protected]) 2 Doctor of Medicine, TURKEY. (E-mail: [email protected]) ABSTRACT Medical drugs and chemicals of personal care products harm the environment, through effluent water and solid waste. Globally, this seems to be the most ignored problem. By medical drugs, it is not only meant the synthetic drugs but also naturally produced ones. All the living creatures metabolize these forementioned drugs and personal care products and release the end products by urine, faeces, perspiration and respiration. Afterwards, at the postmortem period, these products pollute the soil, water and air. The pollution revealed by these metabolites or their original molecules are not distinctly defined by law yet. However, in 31.12.2004, a regulation was published numbered 25687, named “Control of Water Pollution” defines “feacal waste” as “Urine, faeces or remains of people or warm blooded animals that bacteriologically pollutes a water supply” İn fact, feacal waste not only contents of bacterias but also contents antibiotics, hormones, anxiolytics, antidepressants, anesthetics and such drug chemicals and personal care products metabolites. These products has the capacity to harm the enviroment. Also, these drugs and products are designed to be resistant and last long. Moreover, it is possible to see side effects when they are given at high dose, as they cause the formation of drug resistant bacterias and , to threat public health when they are given low dose. The aim of this study is to determine the direct or indirect effects of the metabolites of drugs and personal care products after they mix in the ecosystem. İn the design of the study, first we analysed drugs and cosmetics as a pollution source, evaluating the elimination ways. Then, we manage to determine the waste products which are not able to eliminated by classic ways, pro ducts of drug factories and possible risks of them. At last we discuss possible precautions. Keywords: Cosmetics Waste, Drug waste, Feacal waste, Medical waste, Waste 196 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Land Use Change in Izmit Bay Catchment Güleda Önkal Engin* 1, Meltem Çelen 2 1 Environmental Engineering Department, Yildiz Technical University, Turkey. (E-mail: [email protected]) 2 Environmental Engineering Department, Gebze Technical University, Turkey. (E-mail: [email protected]) ABSTRACT Izmit bay located in north-west part of Turkey has a surface area of 261 km2 and the catchment area of the bay is 2255 km2. The bay can be divided into three sub-sections. The three sub-sections are connected to each other by narrow openings. The eastern part is about 15 km in length with an average depth of 30 m. The largest sub-region of the bay is the central part. Due to population increase, agricultural activity and urbanization along the coastal areas, the catchment of the Izmit Bay is facing severe water quality related problems. Some of the major problems faced by the region are deteriorating groundwater and stream water as well as coastal water quality due to nutrient inputs (nitrogen and phosphorous). There are other environmental problems related to land-use in the region. In this study it was intended to investigate the land-use change by comparing the data produced in 1960’s and in 2000’s. For this purpose Geographical Information System technology was utilized. It should be stated that the change in land use in the catchment started at the beginning of 1960s with industrialization. Decrease in agricultural activities along with industrialization and immigration are the most significant reasons that affect the change of land-use in the Izmit bay catchment. It was observed that the number of industrial areas have increased 10 fold whereas agricultural lands reduced by half. All these changes and their environmental impacts in the region are investigated thoroughly. Keywords: Izmit Bay Catchment, Land Use Change, Environmental Impact 197 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Unplanned Urbanization be Evaluation in terms of Landscape Architecture (ICOCEE), Cappadocia 2015 Gülden SANDAL ERZURUMLU Niğde University, Faculty of Architecture, Department of Landscape Architecture, Niğde, Turkey. E-mail: [email protected] ABSTRACT Unplanned Urbanization be Evaluation in terms of Landscape Architecture Environmental degradation has occurred due to the rapid population growth from the village to the city. Continuous flow of people from rural areas, has led to the growth of our city every year. A result of such a rapid population growth , the city is surrounded by a slum ; A large proportion of the urban population is trying to shelter in makeshift housing. Unconscious and unplanned development of settlements arisen itself without taking into consideration of the natural beauties of the land harms the ecologic balance by hindering sustainability of natural resources. This article reviews the studies on the effects of natural spaces on human well being and health, and provides a critical discussion of their results. Keywords:Environmental degradation, Landscape architecture, Nigde, Rural Areas, Urbanization. 198 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Life Cycle Assessment of Fossil Fuel-Fired Thermal Power Plant E.Ü. Deveci 1, Ç.Ş. Sağlam2*, Ü.K. Çakir 3, K. Bayrak4 1,3,4 2 Environmental Engineering Department, Engineering Faculty, Nigde University, TURKEY (E-mail: [email protected], [email protected], [email protected]) Boğaziçi University Fuel and Energy Technologies Program, M.Sci ([email protected]) ABSTRACT Thermal power plants are industrial facilities generating electricity power by means of combustion of fossil fuels such as coal, fuel oil and natural gas. Considering all generation steps, it is obvious that there are many environmental and social impacts resulted from termal power plant investments. If these impacts are not assessed, adressed and mitigated sufficiently, adverse impacts are unavoidable. Potential environmental impacts of a termal power plant can be classified as stack emissions, particulate matter emissions due to ash transport and disposal, coal mining, storage and transportation and excavation activities ; raw water usage from natural sources, waste water generation, environmental noise and vibration and solid wastes. Life cycle assessment is a method utilized to identify, report and manage possible environmental impacts throughout various stages of a product or service production starting from raw material supply to all related production, transportation, end-user cycle including waste disposal. In this study, it is aimed to apply life cycle analysis into thermal power plant investments and to determine optimum power generation process causing less environmental impact, address the impacts likely to occur during different life cycle stages and figure out how these impacts may change the environment if not mitigated properly, to select best available technologies in order to abate air pollution, water pollution and soil pollution. Emission abatement techniques are other focus area of the study to reduce environmental load of a fossil fuel-fired power plant. In the recent years, Turkey is one of the countries where many new thermal power plants are being invested and many existing thermal power plants are being renovated. The main purpose of this study enlightens environmental impacts of such facilities and how these impacts can be managed in a scientific point of view. Keywords: Thermal Power Plant, Fossil Fuel, Life Cycle Assessment, Environmental Impact 199 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 From Environmental Audit of Land to Baseline Report: Polish implementation of the EU Directive on Industrial Emissions in the Context of Soil Protection Andrzej Kulig1 1 Technical University of Warsaw, Faculty of Environmental Engineering, ul. Nowowiejska 20, 00-653 Warsaw, POLAND. (E-mail: [email protected]) ABSTRACT In Poland, in the past twenty five years, numerous transformations of the economic modus operandi and social rules were accompanied by fundamental changes introduced in the area of technical, organisational and, especially, legal environmental protection. Changes in the land protection proceeded at a relatively slow. The first regulations were introduced in this subject area under Environmental Protection Law Act of 2001. Regulation on Soil Quality Standards and Land Quality Standards from 2002, defined the permissible soil pollution level depending on the type of land development, soil properties (water permeability) and the depth of the examined horizon. A list of pollutants contains 57 substances, including 12 metals. The next regulation comes from the European Parliament and the Council of the European Union as Polish Environmental Damage Prevention and Repair Act in 2007. Under Availability of Information on Environment and Environmental Protection, and General Public Participation in Environmental Protection, and Environmental Impact Assessment Act of 2008, environmental research and assessments conducted and made in Poland encompass projected outcomes of implementation of various policies, strategies, plans or programmes as well as environmental impact assessments for planned projects. Additionally, Environmental Protection Law Act of 2001 provides for environmental (ecological) audits of installations or, more broadly, existing facilities. An Environmental Audit of Land carried out in order to determine the extent of land degradation and the reasons behind it is a specific form of analysis and assessment. Its scope depends mainly on the objective of the research as it is in the case of an environmental audit of a plant, facility or installation. Interpretation of the results produced by the field survey is made in accordance with formal requirements (i.e. qualitative criteria and standards). After a few years of those laws being in force, amendments have been introduced, resulting from the need to implement the EU directive on industrial emissions i.a. to soil and land. The paper present the brief history of legal regulation of the land protection in Poland and development of methodological aspects of the investigations of the state of soil pollution. Keywords: baseline report, environmental audit, land protection, legal environmental protection, soil pollution. 200 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Development of Novel Cements with Optimized Carbon Capture Capabilities C. Unluer* 1 1 School of Civil & Environmental Engineering, Nanyang Technological University, SINGAPORE (E-mail: [email protected]) ABSTRACT Currently produced at a rate of >3 Bt/year, Portland cement (PC) is the most widely used construction material in the world. It is responsible for 5-7% of anthropogenic CO 2 emissions, due to a combination of the decomposition of limestone and high calcination temperatures used for the process (1450˚C). Therefore, there are major global pressures on the cement industry to reduce its emissions. Mineral CO 2 sequestration, combining alkaline earth metals (i.e. Mg) with CO 2 to form stable carbonates, is a safe and rapid approach for reducing industrial CO 2 emissions. Reactive magnesia (MgO) cements have received significant attention in the technical press due to their technical and sustainability credentials over PC including their lower manufacturing temperatures (~700°C); ability to sequester significant quantities of CO 2, becoming carbon neutral and leading to high strengths; significant durability advantages; and complete recyclability when used alone. The presented work focuses on the use of reactive MgO in porous applications, where it carbonates by absorbing CO 2 and gains strength accordingly. The main goal involves maximizing the amount of CO 2 absorbed within construction products, thereby reducing the overall impact of the construction industry. Microstructural analyses including scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermogravimetry/differential thermal analysis (TG/DTA) are used in addition to porosity, permeability, and unconfined compressive strength (UCS) testing to understand the performance mechanisms. XRD Reference Intensity Ratio, acid digestion and TG/DTA are utilized to quantify the amount of CO 2 sequestered, with the goal of achieving 100% carbonation through careful mix design, leading to a range of carbon neutral products with high strengths. As a result, blocks stronger than those of PC were produced, where up to 1 ton CO 2/ton MgO was achieved in terms of CO 2 sequestration. This was equivalent to the amount emitted during the production of MgO, therefore resulting in carbon neutral products. Keywords: CO2 sequestration, Mechanical performance, MgO cements, Sustainable construction materials, Thermal decomposition 201 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Different Climate Conditions effect on Thermal Conductivity Coefficient and Indoor Environment Deniz YILMAZ* 1, Hande BEZCİ ZEREN 2, Cengiz YILMAZ3, Timuçin İNCE 4 1, 4 ISTANBUL AREL UNIVERSITY, Mechanical Engineering Department, TURKEY. (E-mail: [email protected], [email protected]) 3 2 ISTANBUL AREL UNIVERSITY, Civil Engineering Department, TURKEY. (E-mail:[email protected]) ISTANBUL TECHNICAL UNIVERSITY, Mechanical Engineering Department, TURKEY. (E-mail: [email protected]) ABSTRACT One of the most important criteria for the selection of building materials is the climatic conditions where the building is located. If traditional structures have been examined, it can be seen that they have been built with the best materials depending on the climatic characteristics. Selection of appropriate materials according to climate characteristics are very important in terms of energy savings which is today's most important research topics. Due to the Energy performance of buildings directive, identification is mandatory for all buildings. Due to the use of unsuitable building materials for present climatic conditions, the energy loss is occurred from buildings through heat transfer to the environment. As is known, if a rigid body has temperature differences, heat transfer takes place by conduction from low temperature to high temperature region. The conduction heat transfer is determined by the Fourier law. Fourier law includes a proportionality constant “k” called as the thermal conductivity coefficient that is a feature of the material and is a function of temperature. Therefore it is one of the most important parameters in choosing materials for heat transfer. In this study, considering the different climatic conditions (tropical, climate, moderate climate, cold climate conditions separately) and for the different building materials, and temperatures, thermal conductivity coefficient will be measured and determined. Using this data a building modeling has been done and temperature distribution within the building will be examined. Keywords: Climate, CFD, Thermal Conductivity. 202 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Some Physical and Chemical Properties of the Building Structure Stones Used in Arapgir, Malatya Serhat Aksungur* 1, Tarkan Koca 2 and Alper T. Özgüler 3 1 Inonu University, Malatya, TURKEY. (E-mail: [email protected]) 2 3 Inonu University, Malatya, TURKEY. (E-mail: [email protected]) Tunceli University, Tunceli, TURKEY. (E-mail: [email protected]) ABSTRACT In this study, the physical properties of the stone have been investigated which is used intensively in some village of Arapgir district of Malatya province, and preferred by the region people in terms of ease of processing and thermal properties of this stones. The purpose of this study, determine what type of features this stones have which is name "Sal Stone", as a structural element. For this, stone samples were taken, chemical analyzes were carried out, thermal conductivity and strength tests are made. As a result, the present day structural elements were compared with these stones. Keywords: Arapgir, Concrete, Sal stone, Structural element, Thermal conductivity, 203 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigate Some Physical Properties of the Structure Stones Located in Çemişgezek and Analysis of the Use as Building Element Alper T. Özgüler* 1, Tarkan Koca 2 and Serhat Aksungur 3 1 Tunceli University, Tunceli, TURKEY. (E-mail: [email protected]) 2 Inonu University, Malatya, TURKEY. (E-mail: [email protected]) 3 Inonu University, Malatya, TURKEY. (E-mail: serhat.aksungur@,inonu.edu.tr) ABSTRACT In this study, the physical properties of the stone have been investigated which is preferred in terms of ease of processing and situated extensively in Çemişgezek district of Tunceli province. The purpose of this study, determine what type of features this stones have as a structural element. For this, stone samples were taken, chemical analyzes were carried out, thermal conductivity and strength tests ar e made. As a result, this stones compared with present day structural elements and usability of this stone amongst present day structural elements was investigated. Keywords: Compressive strength, Concrete, Çemişgezek, Physical properties, Structural element. 204 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Development of lightweight cement composites with low thermal conductivity for energy efficient buildings Min-Hong Zhang* 1, and Yunpeng Wu 2 1, 2 Department of Civil and Environmental Engineering, National University of Singapore, SINGAPORE (Email: [email protected], [email protected]) ABSTRACT Energy efficient building is defined as achieving satisfactory internal environment and service with minimum energy consumption. One of the most important parameters that affect the heat transfer through building envelope is thermal conductivity. For concrete, the thermal conductivity is influenced primarily by the thermal conductivity of raw materials used, mix proportion, void content, and moisture condition of the concrete. The thermal conductivity of lightweight concrete is generally lower than that of normal weight concrete due to the lower thermal conductivity of air (0.03 W/m.K). Although introducing voids in concrete will reduce its thermal conductivity and increase its insulation capacity, mechanical properties such as strengths and elastic modulus are generally compromised. This study focuses on developing lightweight cement composites (LCC) which have low thermal conductivity but sufficient strength that may be used for structural applications. The lightweight was achieved by incorporating hollow cenospsheres from fly ash generated in thermal power plants. The LCC developed had 1-day densities of about 1150 – 1470 kg/m3 and 28-day compressive strengths of 33.0 - 69.4 MPa. Properties of the LCC were compared with those of cement pastes with comparable water/binder (w/b) and those of a concrete with 28-day compressive strength of about 65 MPa. Results indicate that the compressive strength, flexural tensile strength, and elastic modulus of the LCC were reduced with the decrease in density. However, compressive and flexural tensile strength of 69.4 and 7.3 MPa were achieved for the LCC, respectively, similar to those of the cement paste with w/b of 0.35 and the concrete. Thermal conductivity of the LCC was significantly lower than that of the cements pastes and concrete. The thermal conductivity of the LCC was 80% lower that of the concrete of comparable 28-day compressive strength. Keywords: cement composite, cenospheres, lightweight, mechanical property, thermal conductivity. Acknowledgment: Authors acknowledge the financiar support by Singapore National Research Foundation through the Singapore-Berkeley Building Efficiency and Sustainability in the Tropics (SinBerBEST) Program. 205 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Study on Anisotropy of Composites and Nanomaterials used in Construction Industry Çiğdem Dinçkal*1 1* Çiğdem Dinçkal’ Department of Civil Engineering, Çankaya University, TURKEY. (E-mail: [email protected]) ABSTRACT Anisotropic materials become the material of choice in civil engineering applications in the last century. Many construction materials are anisotropic and inhomogeneous due to the varying composition of their constituents. In order to perceive the physical properties of these materials, use of elastic constant tensor in various representations become important. Hence, this study aims at presenting a different procedure namely, orthogonal irreducible representations of elastic constant tensor by which elastic constant tensor of a material is decomposed into orthogonal irreducible decomposed parts. This means that decomposed parts are orthogonal to each other. Since orthogonality conditions have been fulfilled. The term ''irreducible'' indicates sets that cannot be resolved into subsets with separate linear transformations. The irreducible tensors of elastic constant tensor have special names; scalar (zero-rank tensor of valence 0), deviator (second-rank tensor of valence 2) and nonor (fourth-rank tensor of valence 4). In this study elastic constant tensor of any nanomaterials and composites can be written as the direct sum of these irreducible tensors in the Cartesian representation. This decomposition process has been applied to selected composites such as laminates and nanomaterials. Numerical examples have been given by using elastic constants of these materials. There are significant results inferred from this study. One of them is to demonstrate that it is possible to analyze anisotropic property of these materials in detail by this method. Other one is to introduce norm concept and its applications such as norm and norm ratio calculations of each irreducible decomposed parts for determination of anisotropy degree of laminates and nanomaterials. To summarize, this study offers a different outlook for investigating anisotropy of composites and nanomaterials used in construction industry with use of elastic constants only. Keywords: Anisotropy, Elastic constant tensor, Irreducible decomposed parts, Orthogonality, Norm. 206 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental Study on Stabilization of Sand Soil by Cement and Marble Dust A. Pekrioğlu Balkıs 1 1, Civil Engineering, Cyprus International University, TRNC. (E-mail: [email protected]) ABSTRACT Soil stabilization is needed to increase the soil strength and/or decrease its permeability. There are many materials used in soil stabilization. Soil stabilization is done generally by using cement, lime, fly ash and asphalt emulsions because of their relatively lower cost, ability to be applied easily and their existance. Due to excessive mining, natural resources are getting exhausted. Thus, it is advantagous to find the utilization area of waste materials in soil stabilization. Marble is one of the important materials used in the construction industry. Marble dust creates worldwide environmental problems. The present study is aimed to utilize waste marble dust in soil stabilization. In this study, marble dust which is the by-product of marble cutting industries has been used as a replacement material in cement mixtures to stabilize sand soil. Study covers, 5 mix groups (20, 40, 60 and 80% cement replacement) for a slump value of 150 mm were studied with 20, 40, 60 and 80% sand to examine the effect of cement replacement on the paste and how the mix proportions (combinations) changes the physical and mechanical properties of the sand. The compressive strength and porosity properties have been determined after stabilization. Test results indicated that the addition of cement to soil increases stiffness, brittleness, and peak strength. Marble dust addition improves the soil properties as it shows cementitious properties. Keywords: Marble dust, permeability reduction, sand, soil stabilization, strength 207 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Moisture Damage Characteristic of Polymer and Wax Modified Asphalt Mixtures M. Bayazit 1, Y.Taşdemir* 1 , E. Kolay 2 and G.Küçük3 1, 2 Bozok University, Department of Civil Engineering, Yozgat, TURKEY. (E-mail: [email protected], *[email protected]) Bozok University, Department of Geological Engineering, Yozgat, TURKEY. (E-mail: [email protected]) 3 11. Regional Directorate of Highways, Van, TURKEY. (E-mail: [email protected]) ABSTRACT The road construction phase is the one of sources of greenhouse gases which causes climatic changes. Researches are done to decrease greenhouse gases and energy consumption. The asphalt industry is getting more aware of the warm mix asphalt (WMA) technology. The viscosity of the bitumen which contain WMA additive is lower than normal bitumen at high temperatures. Therefore the mixing and compaction temperatures of the WMA mixtures may be lower, reduced mixing temperature leads to a reduction in emission and energy consumption. The scope of this study is to evaluate the moisture damage characteristics of the unmodified and polymer modified asphalt mixtures which contain WMA additives. The polymer modified bitumen were produced by adding polymer additive which is commonly used in Turkey in 70/100 penetration grade bitumen. Bitumen properties were determined by conventional test methods and, the mixing and compaction temperatures of the bitumen were determined by Brookfield viscometer. Two different types of additives (Fischer Tropsch wax, S and Montan wax, MW ) by weight of %4 were added to unmodified and polymer modified bitumen to produce asphalt mixtures. The crashed aggregate was obtained from Karayazi quarry of Nevşehir/Turkey and used to prepare asphalt mixtures. The mixture was designed using the Marshall Method. AASHTO T283 tests were used to evaluate the moisture susceptibility of mixtures. The wax S and wax MW modification the unmodified asphalt mixture become more moisture susceptible than unmodified asphalt mixture. The wax S and wax MW modification showed positive moisture performance on polymer modified asphalt mixtures. Keywords: AASHTO T-283 test procedure, Moisture Susceptibility, Polymer Modified Warm Mix Asphalt. Acknowledgment: The authors thank Bozok University, Scientific Research Project Funding for their financial support [Project number: 2013MMF A/59]. 208 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 MgO-cement based matrix composites reinforced with hemp hurds and N. Stevulova* 1, J. Cigasova 1, I. Schwarzova 1 and J. Junak1 1 Department of Material Engineering/Institute of Environmental Engineering, Faculty of Civil Engineering, Technical University of Kosice, SLOVAKIA. (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Innovative building solutions for conserving non-renewable resources are connected with the development of sustainable building materials based on the use easily renewable natural raw material resources. There is a growing interest in the utilization of natural lignocellulosic fibres (bio-fibres usually derived from plants) as organic filler and/or reinforcement into lightweight composites for sustainable constructions providing a healthy living in buildings. Such new materials made from natural fibres with inorganic matrix are called as “green” composites/concretes. Excellent physical and mechanical properties of annual plant belonging to the Cannabis family - hemp predetermine its use in building materials. Growing trend in using hemp hurds (fibres from core) as waste material from bast fibres production in lightweight composite preparation is recorded in recent years. This paper aims to summarize the results of our experimental study intending to the application of hemp hurds into composites using alternative binder of MgO-cement. The parameters (mean particle length, volume portion and chemical composition of hemp hurds; hardening time) affecting the physical (density, thermal conductivity coefficient and water sorption behaviour) and mechanical properties (compressive strength) of hemp composite were studied. Impact of chemical modification of filler (in three reagents) on properties of composites was monitored. The progress in the values of the strength parameters in dependence on hardening time for all composites was observed. The lower mean particle length and volume portion of hemp hurds led to higher compressive strength values. The values of thermal conductivity coefficient and density of hemp composites were comparable to other building materials. In case of composites based on chemically treated hemp hurds the lower values of compressive strength and thermal conductivity coefficient were observed in comparison to referential composite (based on original hemp hurds). The comparative study of long-term water sorption behaviour of composites reinforced with original and chemically modified hemp hurds confirmed that surface treatment of filler influences the sorption process. It relates to change in the chemical composition of hemp hurds after chemical modification. Keywords: hemp hurds, MgO-cement, lightweight composite Acknowledgment: The authors are grateful to the Slovak Grant Agency for financial support of the project [VEGA 1/0277/15]. 209 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Multi-objective decision model of supplies performed by means of distribution center for small and medium construction enterprises Michał Tomczak* 1 and Robert Bucoń 2 1, 2 Department of Construction Project Engineering, Faculty of Civil Engineering, Lublin University of Technology, POLAND. (E-mail: [email protected], [email protected]) ABSTRACT Despite the fact that 99% of construction firms in Europe are small and medium enterprises (SME), the literature on supply chain management in civil engineering focuses on issues typical for large corporations. Thus, the supply chain problems of small businesses are neglected. Furthermore, the character of the building trade impedes the direct implementation of modern logistic solutions into project and enterprise management. In this paper, authors present barriers and obstacles to applying the idea of integrated supply chain management to small and medium construction enterprises. This study proposes the concept of cluster supply chain which can contribute to increase of building SME’s competitive strength. Moreover, the paper describes a multi-objective mathematical model, which depicts the “milk runs” problem. Values of the criteria were based on a survey conducted among construction managers and engineers. The model can be implemented to describe operations of a distribution center, which is the part of a cluster supply chain. Keywords: mathematical programming, milk runs, multi-objective optimization, small and medium enterprises, cluster supply chain. Acknowledgment: This work was financially supported by Ministry of Science and Higher Education within the statutory research number S/63/2015. 210 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Thermal energy storage using phase change materials in a building for better energy efficiency in summer period F. Boudali errebai*1, S. Chikh2, L. Derradji3, M. Amara4 1, 3, 4 1, 2 Building Physics and Environment Devision (DPBE), National Centre for Building Integrated Studies and Research (CNERIB), Algiers, Algeria. (E-mail: [email protected], [email protected], [email protected]) Faculty of Mechanical Engineering & Process Engineering, University of Science and Technology Bab Ezzouar Houari Boumediene (USTHB), Algiers, Algeria. (E-mail: [email protected]) ABSTRACT In order to reduce building energy consumption and improve indoors comfort conditions, the envelope optimization is one of the most effective ways. Indeed, the supplied energy is not consumed by the building, but by the installed equipment (heating, air conditioning ... etc). To correct defects in the building envelope and ensure thermal comfort while reducing energy consumption and green house gas emissions, it is necessary to optimize heat transfer by designing a more efficient building envelope. This paper aims to study the thermal behavior of a building incorporating Phase Change Materials (PCM) in its envelope (as a way to improveits thermal inertia), through simulations, with the dynamic DesignBuilder software which uses the EnergyPlus calculation engine software. It aims too to study the influence of PCM on thermal comfort and energy consumption in the summer period. In this paper, a comparison is made between a home that has an ordinary envelope and homes which have an envelope containing different types of PCM (different phase change temperatures) with and without the integration of thermal insulation in the building envelope. These simulations have been made, taking into consideration the climate of northern Algeria which is of the mediterranean kind. The results found showed that the choice of the MCP melting temperature plays an important role in ensuring the energy efficiency of a home and the use of PCM in residential buildings contribute to the mitigation of fast fluctuations of temperature and prevent over heating during the summer period which improves the thermal comfort inside the home. It was also found that the use of MCP allows to limit heat gain through the envelope, which is an energy saving factor for cooling in summer. Keywords: Phase Change Material, Energy Efficiency, Energy Saving, Thermal Comfort. Acknowledgment: The authors are grateful to GIZ (Gesellschaft für Internationale Zusammenarbeit) for providing the DesignBuilder software license. 211 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Use of phase change materials in the walls to improve thermal comfort L. DERRADJI1,2*, A. HAMID3, M. AMARA4, F. BOUDALI ERREBAI5 ,Y. MAOUDJ6 1,4,5,6 National Center of Studies and Integrated Research on Building Engineering (CNERIB), Cité Nouvelle El Mokrani, Souidania, Algiers, Algeria. 2,3 Department of Mechanical Engineering, University of Blida, BP 270 route de soumma, Blida, Algeria. * (Corresponding author. Email: lotfi.derradji @ yahoo.fr) ABSTRACT In Algeria, the building sector is the largest consumer of energy among the economic sectors, with 41% of national energy and 21% of CO2 emissions. Much of this energy consumption is derived from the use of heating and air conditioning systems for thermal comfort to the occupants in winter time and summer, respectively. It is therefore necessary to reduce the energy consumption and the environmental impact of the sector in promoting the concept of low-energy buildings. The use of phase change materials (PCM) is a solution to improve the energy efficiency of buildings. The phase change materials (PCM) can store heat to compensate for the mismatch between supply and hourly heat demand in a building, such as the storage of solar thermal energy for heating during the evening. The main objective of this work is to demonstrate the possibility of using microencapsulated PCM with plaster to improve the thermal comfort under the algerian climate and to achieve energy savings for buildings. Three cells were built with the walls of the conventional type in Algeria using an interior coating plaster/PCM. The cells are located in the Algiers region, more precisely in the village of Souidania. Measurement instruments have been installed to determine the influence of PCM on the thermal behaviour of these cells during summer without cooling and during winter with heating. Thermocouples were installed inside the cells in order to measure the temperature of the inner face of the walls and the air temperature. The outdoor temperature and the direct solar radiation were also measured. The measurement results show that the use of a gypsum plaster incorporating 30 % PCM contributes to a reduction of the amplitude of indoor temperature of the cell by 4 °C in the summer period. Keywords: Phase change material, thermal behavior, energy efficiency, thermal comfort, cell. 212 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Infill Wall Effect for the Seismic Performance of RC Structures S. Mert 1, Ö. Boztaş* 2 and G. Arslan 3 1, 2 Department of Civil Engineering, Yıldız Technical University, İstanbul, Türkiye (E-mail: [email protected], [email protected]) 3 Department of Civil Engineering, Yıldız Technical University, İstanbul, Türkiye (E-mail: [email protected]) ABSTRACT In this study, the effect of infill walls on the structural performance of reinforced concrete (RC) buildings with distortional irregularity under earthquake excitation has been studied. With the aim to determine this effect, RC buildings with and without infill walls of 5 and 7 floors were modeled by using SAP2000 analysis program and their pushover curves have been obtained by Nonlinear Static Procedure (NSP) which is proposed in the Turkish Seismic Code (TSC, 2007). Earthquake performance has been obtained by NSP. At the phase of adding infill walls to the system material values indicated in TSC 2007 have been used and as a method which is accepted in conducted studies, the method of equivalent compression strut model has been used. According to the results, more damage has been said to occur in models without infill walls. Columns located in significant damage state have transited to the minimum damage state with the inclusion of infill walls. Whereas beams in heavy damage state have remained in significant damage state in the models with infill walls. As a consequence, RC buildings that do not satisfy life safety performance level designated in the TSC have satisfied life safety performance level when the contribution made to the building by infill walls against lateral loads is taken to account. Keywords: Infill wall effect; Performance evaluation; Reinforced concrete; Structures; Pushover analysis; Nonlinear analysis. 213 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Contribution to the amelioration of Mechanical Behavior of Mortar Based on limestone Mineral Admixture substitution at curing Temperature Ilham Aguida Bella* 1, Aissa Asroun 2 and Nabil Bella 3 1, 3 Department of civil engineer, Mohammed TAHRI University, ALGERIA. (E-mail: [email protected], [email protected]) 2 Department of civil engineer, Djillali Liabes University, ALGERIA. (E-mail: [email protected]) ABSTRACT Currently, the concrete material has become a very expensive material because the high price of aggregates, the aggregate factories consumes a big quantity of energy; by consequence, it costs money, in the other hand it produces a lot of SCM's. The main aspects which guide this study is the current tendency to make concrete based on a very abundant material, which are crushed limestone aggregates. The desired objective of this study is the use of local materials mainly SCM (sustainable concrete materials) in our case crushed limestone. Our SCM, is the result of crushed manufactory, contain 40 % of fine limestone, the other part is composed by different size of aggregates. Based on this context, This research is based on the use of the local material existing in very large quantity and available locally, the main aspect are economic and environmental parts, using local materials will be very important in the field of construction to decrease the price of concrete. Nowadays the technology in construction field offer several kind of chemical admixture, this different kind of chemical admixture offer different behaviour at the fresh state of the batch and by Consequence its result with different mechanical behaviour at the solid state of concrete, this study focus on the behaviour of the new kind of admixture at fresh and solid states. The results obtained in this study summarize up the importance of the curing temperature during development of the mechanical characteristics of mor tar based on SCM and new generation of superplasticizer. Keywords: curing temperature, limestone, mortar, substitution, superplasticizer. Acknowledgment: The authors grateful acknowledge to Sika Aldjazair stuff, especially Mr Billal Announ and Mm Khedim Khadidja (R&D Department) for providing chemical admixture. Also The authors grateful LTPO laboratory and GC laboratory of Bechar University. 214 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Correlation analysis as a method for concrete deterioration investigation V. Ondrejka Harbulakova 1, A. Estokova* 2, P. Purcz 3, A. Luptakova 4 1 Technical University of Kosice, Faculty of Civil Engineering, Department of Environmental Engineering, Institute of Environmental Engineering, SLOVAKIA ([email protected]) 2 Technical University of Kosice, Faculty of Civil Engineering, Department of Material Engineering, Institute of Environmental Engineering, SLOVAKIA ([email protected]) 3 Technical University of Kosice, Faculty of Civil Engineering, Department of Applied Mathematics, SLOVAKIA ([email protected]) 4 Slovak Academy of Science, Institute of Geotechnics, SLOVAKIA ([email protected]) ABSTRACT Existing evidence has shown corrosion problems in many concrete structures exposed to an aggressive aqueous environment containing soluble sulphates. Soluble calcium and sodium sulphates occur normally in the ground, in waste water and in various industrial processes. Magnesium sulphates are less common, although they are more destructive. Because of a lack of standardized methods, different test methods have been used, and various parameters have been modified to evaluat e the resistance of the concrete materials against sulphates exposition. The paper is aimed at the investigation of the aggressive aluminum sulphate influence on the concrete material with and without coal fly ash as cement replacement. Distilled water was used as reference medium. Si, Ca, Al, Fe, Mn and Cu ions dissolved from the cement matrix into leacha nts were measured. The laboratory experiment proceeded in five 7-day cycles. Determination of concentration of selected ions considering mutual dependence on pH and its dependency on time is presented. Very high closeness between the correlation coefficient of chemical elements and pH was observed for both media and both concrete compositions. High closeness was also determined between Ca-Si and Al-Fe in case of reference samples in distilled water. On the contrary, no Ca-Si correlation was calculated in aluminium sulphate solution. Keywords: Sulphate environment, Cement composite, Concrete deterioration, Chemical attack, Concrete leaching Acknowledgment: This research has been carried out within the Grant No. 2/0145/15 of the Slovak Grant Agency for Science. 215 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The effect of zeolite additive as a durability improver of building materials A. Estokova* 1, M. Kovalcikova 2 and A. Sicakova 3 1, 2, 3 Technical University of Košice, Faculty of Civil Engineering, Institute of Environmental Engineering, Vysokoškolská 4, 042 00 Košice, SLOVAK REPUBLIC (E-mail: [email protected], [email protected], [email protected]) ABSTRACT The use of natural zeolites as pozzolanic materials in construction dates back 3000 years, to the Greek and Roman periods when zeolites occurred as altered volcanic ash, tuff, and trass were used with lime in mortars and concretes for construction. The present studies provide laboratory investigations of the effects of incorporation of zeolite as a pozzolan at various levels of substitutions of portland cement (from 0 to 40 percent by mass of total cementitious materials) on the properties of fresh and hardened concrete and on concrete durability (alkali-aggregate reaction, drying shrinkage, chloride permeability, and resistance to acid and sulphate attacks). Sulphates and acids, naturally occurring in soil and groundwater, are the agents most likely to attack concrete material. The destructive effects can be serious resulting in expansion and softening of the concrete to mush. Therefore, durable concrete requires good specification for different uses and site environmental conditions. The paper presents the results of the comparative resistance study of the Slovak origin zeolite based cement composites exposed to the sulphate and chloride environment. The various aggressive media was used for the experiment: sulphuric acid with pH 4.2, hydrochloric acid with pH 5.07, drinking and distilled water, respectively. The laboratory experiment proceeded over a period of 90 days under model conditions. The mass changes of samples as well as the changes in the elemental concentrations of calcium and silicon in liquid leachates were observed. Experimental studies confirmed: the leaching of silicon ions calculated to 1 g of concrete sample was highest (7.951 mg/g) for concrete sample exposed to the sulphuric acid. The highest concentration of leached calcium ions (2.546 mg/g of sample) was observed for samples placed in distilled water. The calculated Si/Ca ratios in leachates varied from 1.22 to 7.94 in dependence on the medium. Keywords: cement composites, hydrochloric acid, leaching, sulphuric acid, zeolite. Acknowledgment: The authors thank the Slovak Grant Agency for Science for their financial support [Grant No. 2/0145/15]. 216 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The water absorption by capillarity in structural lightweight concrete J. Alexandre Bogas * 1, M. Glória Gomes 2 and Sofia Real 3 1, 2, 3 Department of Civil Engineering and Architecture. Instituto Superior Técnico, Technical University of Lisbon. Av. Rovisco Pais, 1049-001 Lisbon, Portugal. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT In this paper the capillary absorption of lightweight aggregate concrete (LWAC) produced with different types of expanded clay aggregates is characterized. To this end, a comprehensive experimental study was carried out on different concrete compositions with mea n compressive strengths from 30 to 70 MPa and density classes from D1.6 to D2.0. It was thus possible to cover the most usual LWAC. The influence of different parameters in the capillary absorption are analyzed: the volume and initial water content of lightweight aggregate (LWA); the cement content and its replacement by fly ash or silica fume; the partial replacement of normal weight aggregate by lightweight coarse or fine aggregate; different curing conditions. The initial and long-term absorption of LWAC shows to be higher than that of normal weight concrete (NWC). However, the coefficient of absorption is little affected by the type and volume of aggregate, even taking into account different w/c ratios. Silica fume shows to be effective in the reduction of capillary absorption, but the sorptivity increase as the replacement of cement by fly ash increases. The replacement of cement by fly ash increased The initial pre -saturation of LWA increases the capillary absorption of concrete. For a given strength cl ass, the sorptivity of LWAC tends to be lower that of NWC, because the capillary absorption is more strongly affected by the quality of the paste. Keywords: Lightweight aggregate; lightweight aggregate concrete; capillary absorption; pozzolanic additions. Acknowledgment: The research work presented herein was supported by the Portuguese Foundation for Science and Technology (FCT), under grant PTDC/ECM-COM1734/2012. The authors also wish to thank CEris-IST for funding the research and the Argex, Saint-Gobain Weber Portugal, BASF and SECIL for supplying the materials used in the experiments. 217 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Chloride migration resistance of structural lightweight concrete J. Alexandre Bogas * 1, Sofia Real 2 and M. Glória Gomes 3 1, 2, 3 Department of Civil Engineering and Architecture. Instituto Superior Técnico, Technical University of Lisbon. Av. Rovisco Pais, 1049-001 Lisbon, Portugal. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT In the present paper the chloride penetration resistance of structural lightweight aggregate concrete (LWAC) of very distinct strength (LC12/13-LC55/60) and density (D1.6-D2.0) classes is characterized by means of rapid chloride migration tests. The study takes into ac count four types of lightweight aggregates with very distinct porosities, w/c ratios ranged from 0.35 to 0.55 and seven types of binders, including different amounts of silica fume and class F fly. It was thus possible to perform a comprehensive study where the chloride penetration behavior of the most common LWAC is accessed. The resistivity of LWAC is also analyzed and compared to that of normal weight concrete of equal composition. It is shown that the chloride penetration resistance is little affected b y the type of aggregate and that high performance LWAC can be produced. However, the chloride penetration resistance can be strongly affected by the quality of the paste, i.e., the type of binder and water/binder ratio. A high exponential correlation is obtained between the coefficient of diffusion and w/c ratio, regardless the type of aggregate. The resistivity is mainly affected by the microstructure of concrete and composition of its pore solution. Contrary to what is suggested in some standards, the con crete strength cannot properly predict the chloride penetration behavior of LWAC. It is concluded that the durability performance of LWAC with less porous aggregates can be at least as high as that of normal weight concrete. Keywords: Lightweight aggregate; lightweight aggregate concrete; chloride penetration; pozzolanic additions. Acknowledgment: The research work presented herein was supported by the Portuguese Foundation for Science and Technology (FCT), under grant PTDC/ECM-COM1734/2012. The authors also wish to thank CEris-IST for funding the research and the Argex, Saint-Gobain Weber Portugal, BASF and SECIL for supplying the materials used in the experiments. 218 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EFFECT OF SAND GRADATION ON THE ENGINEERING PROPERTIES OF SAND-CEMENT MIXTURES (A COMPARATIVA STUDY) S. H. Al-hadama1, A. Al Shenawy1, T. Y. Elkady11 1 Civil Engineering Department, King Saud University, Riyadh, Saudi Arabia ([email protected] , [email protected]) ABSTRACT This paper aims to describe the comparative study of the (compaction curve, unconfined compressive strength (UCS), and durability of Sand-cement Mixtures after curing 7 and 28days with cement content 3%, 6%, 9%, and 12% per dry weight for both red and white sand. The results of the study showed the maximum dry unit weight of red sand and white sand was found to increase with the increase in the cement content while the optimum moisture content increasing marginally for white sand but decreasing for red sand with the increase in the cement content. White and red sands are satisfying the requirements for unconfined compressive strength at 12% cement content. The durability (weight loss) for white and red sands is satisfying the requirement for durability (weight loss) at 6% and 3% respectively. The curing time has effect significant on strength and durability of sand –cement mixtures. Keywords: Sand, Sand- cements mixture, unconfined compressive strength, Durability. 219 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Improvements in Folding and Tessellation as Plate Structures M.M. Balkıs * 1 1, Architecture Department, Faculty of Fine Arts, Cyprus International University, TRNC. (E-mail: [email protected]) ABSTRACT Folded structures are three-dimensional structures - spatial structures and it defines a folded form of construction, including structures derived from elements which form a folded structure by their mutual relationship in space. For very long time this type of construction has been realized in practice only in reinforced concrete and made on site, which conditioned the use of a very complicated shell. Development of prefabricated building led to improvements of this type of construction so that the folded structures could be derived by assembly of prefabricated elements. The principle of folding as a tool to develop a general structural shape has been known for a long time. The aerospace and the automotive industry, e.g. apply this principle to create self-supporting wall, mould and slab elements with a high load capacity out of flat and thin semi-manufactured metals. Tessellation is a pattern in which each side touches with no gaps or overlaps. The simplest type of tessellation is formed from regular polygons. Regular tessellations are tessellations that are made up of only one kind of regular polygon. Todays approach is to design a process and optimize the structures digitally and with analogue model. On one hand it is possible to generate digital models out of an analogue model with the help of a 3dscanner, on the other hand it is also possible to materialize the digital 3d model with a 3d printer. Through a parametric structure of the design in a CAD programme the different stages of the procedure of the planning and the generation of alternatives was simplified. Algorithms of triangulation, originally applied in finite elements analysis, are used for the discretisation and the form-finding of the textures of folded plate shells. In this study historical approach and todays approach for application of folded plates and tessellations will be detailed. Keywords: 3D Modelling, Building Envelope, Design, Folded Plate Structures, Tessellation 220 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of relation of between compressive strength and ultrasonic pulse velocity in the foam concrete with different density M. Davraz 1 and Ş.Kılınçarslan* 1 1 Natural and Industrial Building Materials Application and Research Center, Suleyman Demirel University, Isparta, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Foam concrete is the type of lightweight concrete. Foamed concrete generally consists of slurry of cement, water and prompted sand or fly ash. This slurry is further mixed with synthetic aerated foam in a concrete mixing plant. There is no need to heat treatment to produce foam concrete. The foam is created using a foaming agent, mixed with water and air from a generator. The foaming agent used must be able to produce air bubbles with a high level of stability, resistant to the physical and chemical processes of mixing, placing and hardening. Foam concrete is available floors and walls of the building. Foam concrete is provides heat, sound and water insulation. Foamed concrete mixture may be poured or pumped into moulds, or directly into structural elements. In this study, used type CEM I 42.5 R Portland cement, limestone powder, polypropylene fibers and superplasticizer additive was produced foam concrete in the range 12 different density from 300 to 1400 kg/m3. Produced samples (28 days) compressive strength, split tensile strength and ultrasonic pulse velocity were tested. Depending on test results obtained of ultrasonic pulse velocity and dry density foam for predicting the compressive strength of concrete relations is proposed. Keywords: Compressive strength, Foam concrete, Ultrasonic pulse velocity 221 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Salt Effect on Stability of Warm Mix Asphalt Hatice KÖSE1, Mehmet BAYAZİT2,* and Yüksel TAŞDEMİR2 1 Bozok University, Directorate of Building Maintenance and Technique, Yozgat, TURKEY. (E-mail: [email protected]) 2, Bozok University, Department of Civil Engineering, Yozgat, TURKEY. (E-mail: *[email protected], [email protected]) ABSTRACT The deicing chemicals are used to prevent of freezing on the asphalt pavement on winter conditions. De-icing chemicals have obvious negative impacts including asphalt concrete corrosion, and environmental pollution.The salt which is one of the deicing chemicals has been generally used on pavement surface with different amounts for winter maintenance. The asphalt industry is getting more aware of the warm mix asphalt (WMA) technology. The viscosity of the bitumen which contain WMA additive is lower than normal bitumen at high temperatures. Therefore the mixing and compaction temperatures of the WMA mixtures may be lower, reduced mixing temperature leads to a reduction in emission and energy consumption. Researches showed that warm mix asphalt may have increased rutting resistance depending on the used types of WMA additives without decreasing low temperature cracking resistance. In this study the effect of salt on warm mix asphalt mixtures was investigated. 70/100 penetration grade bitumen and FT Paraffin (Sasobit®) modified base bitumen were used in experimental study. Mixing and compaction temperature of asphalt mixtures were determined by Brookfield viscometer. The salt was added to distilled water by weight of 0.8%, 1.6%, 2.1%, 6.5%, 10.4% and salt solution was prepared. Marshall samples were soaked in the solutions and pure water for seven days. After curing period, Marshall stability and flow were determined. According to Marshall Test results, the salt affected the stability negatively. It is observed that warm mix asphalt samples are more resistance to salt effect than hot mix asphalt samples according to Marshall Stability values. Keywords: Marshall Stability, Salt, Warm Mix Asphalt. 222 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effects of Different Plasticizers on the Behavior of Mortars Evren Arıöz* 1, Ömer ARIÖZ2 and Ö. Mete KOÇKAR 1 1, 3 Anadolu University, Faculty of Engineering, Department of Chemical Engineering, 26555, Eskisehir, Turkey. (E-mail: [email protected], [email protected]) 2 Central Asia CBU Zone Manager, Chryso KAT Construction Materials, Turkey. (E-mail: [email protected]) ABSTRACT Concrete is one of the most important and most consumed material among structural materials in the world. In concrete ındustry, new technologies have been developed to improve the characteristics and the properties of concrete which is produced by mixing cement, water, aggregate, and if required admixtures. Cement, water, and fine aggregate mixture is called as mortar. Concrete is produced by adding coarse aggregate to the mortar. Recently, chemical admixtures are mainly used to enhance the performance of mortars and therefore concrete. Water/cement ratio is one of the most important factors in mortar and concrete production. Adding water increases the flowability and provides easy pumpability but reduces directly the compressive strength. Plasticizers are kind of chemical admixtures which provide high workability with low water amount. Plasticizers reduce the water/cement ratio of the mortars and can develop the compressive strength for cosntant workability. Plasticizers improve flowability for constant water/cement ratio. In this experimental study, cement, sand, water and two different plasticisers were used to produce mortars. The flowabilities and compressive strength of the mortars were measured and compared. Keywords: Admixture, Mortar, Plasticizer, Compressive Strength, Flowability 223 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Investigation on Suitability of Dredge Materials on Road Construction G. Cevikbilen* 1, B. Teymur 2 , U. Karadogan3, H. M. Basar4, S. Dağlı5, L. Tolun6 1, 2, 3 Department of Civil Engineering, Faculty of Civil Engineering, Istanbul Technical University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 4, 5, 6 TUBITAK Marmara Research Center, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Ports must be dredged at the time of construction, expansion or deepening, and periodically for maintenance. The dredged sediments are most commonly dumped in nearby marine waters. The use of these sediments as construction fill materials might be one of the beneficial usage alternatives. The nonhazardous dredged material can be assessed as a resource and therefore a raw material that will not be wasted. This study illustrates the preliminary findings of geotechnical evaluation of dredged sediments recovered from five port sites placed at Black Sea, Marmara Sea, Aegean Sea and Mediterranean Sea of Turkey. The grain size distribution and the consistency limit tests were performed to classify the samples according to AASHTO and Unified Soil Classification system. The variations of the water content versus dry unit weight of the soils were examined at Standard Proctor energy. The swelling characteristics of the soil samples compacted to Standard Proctor energy at optimum water content were observed. Furthermore the strength of the compacted soil samples was tested by California Bearing Capacity tests. The findings in accordance with the fill material properties determine by Technical Specifications of Republic of Turkey General Directorate of Highways were discussed. Keywords: CBR, consistency limits, dredge materials, fill layers Acknowledgment: The work is a part of DİPTAR Project, financially supported by the Turkish Scientific and Technological Research Council (TUBITAK) 1007 Programme [Project Number 111G036]. We specially acknowledge to the Ministry of Environment and Urbanization, Ministry of Transport, Maritime Affairs and Communications and Highways 1st Regional Directorate for their supports in the ports. The authors would like to thank, Barış Güzel, Pembe Erdoğan and Recep Karademir for their helps in the field. 224 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Turkey’s Public-Private Partnership Model in the Health, Energy, and Educational Sectors: An Overview and Critique of the Issues with Recommendations for Improvement G. Tunc* 1, E. Ozsarac2 1 2 Civil Engineering Department, Atilim University, TURKEY. (E-mail: [email protected]) Project Controls & Proposals Department, Hidro Dizayn, TURKEY. (E-mail: [email protected]) ABSTRACT This paper focuses on projects in Turkey that are currently being built using the public-private partnership (PPP) model. There are issues related to the model, and specifically to the projects, which are unique to Turkey. Issues related to the model will be studied in two separate categories: one pertaining to its legal aspects, the other pertaining to its engineering aspects. For the legal category, deficiencies of the model specific to Turkey will be studied. Current laws and legislation will be subjected to criticism in order to highlight uncertainties and problems plaguing the public and private sectors. Past and future amendments to the existing legal binding documents will be investigated and discussed in an attempt to understand the evolution of the PPP model in Turkey. The engineering aspect of the model will also be studied from the contract and construction management perspectives. Technical issues related to contract documents, as well as those related to their construction management, will be evaluated. Current construction projects, as well as some in the bidding phase, will be discussed at length in order to assess progress in this area. Financing and contract/construction documents will also be investigated as key risk parameters in the PPP model. Difficulties experienced during the adaption period of the PPP model to Turkey will be evaluated. The technical shortcomings of the PPP model will be discussed, and a road map for improvement will be determined to mitigate legal and technical setbacks. Keywords: Contract Management, Construction Management, Public-Private Partnership 225 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigating the Relationships between the Main Contractors and Subcontractors in Turkey Gul Polat* 1, Ekin Eray 2 and Enis Murat Goktepe 3 1, 2, 3 Department of Civil Engineering, Istanbul Technical University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT In general, several parties involve in construction projects. These parties mainly include owners, designers, consultants, main contractors, subcontractors, suppliers, etc. The overall success of construction projects highly depends on how these parties can work together without any serious problems. Subcontracting is a common practice in the construction industry. Nowadays, while main contractors tend to act as construction management agencies, and only control and coordinate the works of subcontractors, subcontractors carry out the actual production work. There fore, it can be concluded that the physical performance of a construction project is highly dependent on the capabilities of the subcontractors and good relationship between the main contractor and the subcontractors. In the literature, a great number of studies focused on the subcontracting practices in the construction industry. However, there are only a few studies, which predominantly investigate the relationship between the main contractors and subcontractors. This study aims to investigate the relatio nship between the main contractors and subcontractors in Turkey from the subcontractors’ viewpoints. For this purpose, a questionnaire survey was conducted among 74 construction companies, all of which act as subcontractors in different types projects. The questions in the questionnaire were based on an extensive literature review on subcontracting. The questionnaire includes 18 questions. The first four questions inquire about the background of the respondents. The second four questions ask about the background of the respondent companies. The remaining ten questions generally inquire about the relationship between the main contractor and subcontractor. The findings of this study revealed that the subcontractors become more loyal to main contractors if they have been working together with the same main contractors for a long period of time. In this case, the mutual trust becomes very important for doing business. Keywords: Construction projects, questionnaire survey, relationship, subcontracting. 226 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Barriers to Adoption of Electronic Document Management Systems on Turkish Construction Industry Serkan Aydınlı* 1, M. Emin ÖCAL 2 and Emel LAPTALI ORAL 3 1, 3 2 Department of Civil Engineering, Çukurova University, TURKIYE (E-mail: [email protected], [email protected]) Department of Civil Engineering, Osmaniye Korkut Ata University, TURKIYE. (E-mail: [email protected]) ABSTRACT Over the past decade the use of computer in business processes has been rapidly increased. Producing documents using computer supported methods has become common practice in the construction industry but the management of electronic documents is highly ignored by the majority of sector. The steakholders of the industry can increase efficiency of their documents through such systems. The aim of this study, determining the barriers of use of electronic document management systems (EDMS) in construction industry in order to increase the adoption of such systems. In this study, the survey was carried out in order to collect the research data. Survey was targeted 1.700 representative of companies in the Turkish construction industry. 149 of these responded the survey and according to results the barriers to adoption of EDMS are determined. The survey revealed that the main barriers to the rapid introduction of EDMS in construction are cost-related and organisational issues. Keywords: Information Technologies, EDM, Construction Industry, 227 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Predicting Construction Project Duration for Bid Packages: A Case Study of Pakistan Shabir Hussain Khahro 1, Dr. Tauha Hussain Ali 2, Mir Aftab Ahmed Talpur 3 1 Lecturer, College of Engineering Management, Prince Sultan University, Kingdom of Saudi Arabia (Email: [email protected]) 2 Professor, Department of Civil Engineering, MUET, Jamshoro, Pakistan (Email: [email protected]) 3 Lecturer, Department of City & Regional Planning, MUET, Jamshoro, Pakistan (Email: [email protected]) ABSTRACT Accurate prediction of project duration for planning and bid preparation stage should contain realisti c dates for the construction projects. Constructors use their previous experience to estimate the project duration for the new projects based on experience and intuition. It has been constant concern to both researchers and contractors to analyze the accurate prediction of project duration. In Pakistan, such study for time cost relationship has been lacked to predict time performance for the construction projects. This study is an attempt to explore the time cost relationship for construction projects, which will come up with a mathematical equation to predict the time of the construction projects in province of Sindh, Pakistan. The data of the projects has been collected from National Engineering Services (NESPAK), Pakistan and regression analysis has been carried out for the results. Significant relationship has been found between time and cost of the construction projects of Sindh and finally, this study concludes with a mathematical equation, which can be used by the contractors to predict the project duration for the upcoming projects. This provides the professionals with requisite knowledge to make more informed decisions regarding project duration, which is believed as one of the key aspect to win the projects in construction industry. Keywords: Project Time, Regression Analysis, Time-Cost Relationship Acknowledgment: The authors are thankful to Prince Sultan University, Kingdom of Saudi Arabia for providing financial support. The authors also extend their gratitude to NESPAK for proving data to complete study. 228 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Supplier Selection in the Construction Industry: Evidence from Turkish Contractors Gul Polat* 1, Ekin Eray 2 1, 2 Department of Civil Engineering, Istanbul Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Selecting the right supplier for the right job is very important in the construction industry. Any problem that occurs during the delivery of materials such as receiving fewer amount of material or receiving materials with wrong quality, can effect project’ success directly. Therefore, construction companies should pay attention to several criteria while choosing suppliers for their projects. In the literature, there are a great number of studies dealing with supplier selection process. Some of these studies aim to identify selection criteria that can be used in supplier selection process in many sectors, while other studies propose several methods and tools for selection process. The aim of this study is to investigate the importance levels of the supplier selection and evaluation criteria that are considered by small-scaled, medium-scaled and large-scaled construction companies and to explore whether there are any differences between different scaled companies’ answers. For this purpose, an extensive literature review was conducted and 17 supplier selection and 10 supplier evaluation criteria were identified. A questionnaire, which consists of 12 questions, was designed based on information gathered from the literature review. The questionnaire mainly comprises 5 sections. The first section includes 4 questions that aim to investigate the size of the respondent construction companies. Four questions in the second section inquire about the supplier selection process in the respondent company. The third and fourth sections have only one question that aim to identify the importance levels of 17 supplier selection and 10 evaluation criteria, respectively. The fifth section includes only one question that aims to find out the main problems encountered when working with suppliers and their suppliers and the frequencies of these problems. These questionnaires were completed by 52 construction companies. 20 of the respondent companies are small- scaled, 15 of them are medium-scaled and rests of them are large-scaled construction companies. The survey results revealed that the most of the responses of these companies do not significantly differ. Keywords: Construction projects, questionnaire survey, supplier selection, supplier evaluation. 229 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Multi-criteria decision model for supporting residential building maintenance R. Bucoń* 1, M. Tomczak2 1, 2 Department of Construction Project Engineering, Faculty of Civil Engineering and Architecture, Lublin University of Technology, POLAND. (E-mail: [email protected], [email protected] ) ABSTRACT Residential building management requires to maintain the building in non-deteriorated condition and obliges the administrator to reasonably invest funds for repairs. It involves necessity of carrying out repair works including modernisation. Deciding on the choice of repair solutions is a difficult and complex task. Building administrators have to consider both, the benefits of some repair works, and limitations due to the availability of funds. Selection of a repair solution, bearing in mind the above, requires a comprehensive approach that will allow assessment of the building condition and determining the repair scope required. The research conducted by the authors was aimed at developing a decision-making model and its computeraided implementation, taking into account a number of operating demands. The system algorithm proposed comprises a few stages including: building condition assessment, repair classification, multiple variants of repair and the choice of repair solutions. The article describes individual stages of the model in detail, giving numerical application examples of the method for repair solution choice for multi-family houses. In order to solve particular tasks the authors applied such methods as multicriterial decision making methods and linear programming. Keywords: building evaluation, operating requirements, repair, renovation solution. Acknowledgment: This work was financially supported by the Polish Ministry of Science and Higher Education within the statutory research number S/63/2014 230 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Key Performance Indicators (KPI) Model for Measuring Performance of Subcontractors Befrin Neval Bingol* 1 and Gul Polat 2 1, 2 Department of Civil Engineering, Istanbul Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT In the construction industry, a general contractor is mainly responsible for delivering the project on time, within budget and desired quality to the owner. In practice, general contractors usually perform construction activities via subcontractors in order to reduce the cost and time, improve quality, and share the risks of the project. Since the large portions of tasks are carried out by subcontractors, the performances of subcontractors play a critical role on the successful completion of the project. Selection of a subcontractor is mostly dependent on bid price in the construction industry. However, selecting the subcontractors on the basis of low bid prices leads to work with unqualified subcontractors and usually results in additional cost. Hence, it is necessary to measure the performance of subcontractors before selecting them. The aim of this study is to identify key performance indicators that can be used by general contractors when they select the subcontractors . In order to evaluate the performances of the subcontractors, the key performance indicator (KPI) model is selected in this study. For this purpose, an extensive literature review was conducted and the key performance indicators, which can be used in the performance evaluation of the subcontractors, were determined. Based on the literature review, 91 key performance indicators were identified. Then, these performance indicators were categorized into 8 major groups. Having identified and categorized these key performance indicators, a questionnaire was designed and delivered to the construction professionals via e-mail. 39 construction professionals duly completed questionnaires, who predominantly work in the large scale Turkish construction companies. In order to determine the importance levels of the key performance indicators on the selection of the subcontractor , the reliability and ranking analyses were performed on the collected data. Keywords: KPI, performance measurement framework, subcontractor selection, reliability & ranking analysis. 231 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 5S Systematic Practice Steps on A Corporate Business G. GÜRSOY* 1, and A. E. KELEŞ2 1 Çukurova University, The Faculty of Engineering and Architecture, Adana, TÜRKİYE. (E-mail: [email protected]) 2 Adana Science and Technology University, Faculty of Engineering and Natural Science, Adana, TÜRKİYE. (E-mail: [email protected]) ABSTRACT As well as the physical properties of the working environment for employees, ergonomics, easy access materials and efficient use of terms etc. from the aspect of suitability and ensuring employees feel safe is very important because of expectations of employee, workplace layout and health and safety. The systematic of management is 5S, which are created for the realization of these targets, was born in Japan. The initials which started 5-words in Japanese covers implemented and studies carried out in order of ensure the layout in the workplace, the prevention of unnecessary material stock, increasing employee productivity, made of smooth and easily accessible archive, the reduction of material and labor wasting. When the production process of many inputs and outputs of the investigation found that the construction and materials industries, is of critical importance for the efficiency of the implementation of established business operating system as indicated. In this study, the examining and sampling of implementation stages of the 5S Systematic which is applied in Iskenderun Iron and Steel Co. is discussed. Workplace layout, employee productivity, reduction of occupational accidents, timely and accurate archiving, removal of unnecessary documents, time management and etc. issues is considered to be positive contributions, the operation of this business which the corporate is, discussed the functioning of processes thereby awareness creation on a sectoral basis. Keywords: 5S, Health and Safety, Productivity, Time Management, Workplace Layout. 232 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Conceptual Perspective Via Meta-Heuristic Optimization Algorithms For Resource Leveling Problem In Project Networks Şafak EBESEK* 1, Hakan YAMAN2 1 Istanbul Technical University, Faculty of Architecture, Building Science Division, TURKEY. (E-mail: [email protected], [email protected]) 2 Istanbul Technical University, Faculty of Architecture, Building Science Division, TURKEY. (E-mail: [email protected]) ABSTRACT Scheduling plays a major part in project management. Indeed, the scheduling process amounts to deciding when the project activities will start and how they will use t he available resources. The standard resource-constrainedproject scheduling problem (RCPSP) can be defined as a combinatorial optimization problem, in terms of decision variables, constraints and objective functions. These algorithms are mainly used for computing lower bounds that are an interesting trade-off between efficiency and computation time.The precedence constraints prevent each activity from starting before the completion of its predecessors. The resource constraints ensure that, at each time peri od and for each resource, the total activity demand does not exceed the resource availability. Once started, an activity cannot be interrupted. Despite the simplicity of its definition, the RCPSP belongs to the class of NPhard optimization problems and is actually one of the most intractable classical problems in practice. The aim of this review is to present the latest results in the field, in an integrated manner and to describe the main metaheuristics algorithms for RCPSP. Keywords:metaheuristics,optimization, project management, resource leveling, scheduling. Acknowledgment: Funding: Thisstudy has beensupportedby [ ProjectNumber: 36237 ] 233 ITU-BAP ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Application of an Engineering Method for Preservation of Cultural Heritage: Fuzzy Logic Mehmet Ulukan* Assistant Pr. Faculty of Architecture, Nigde University, TURKEY. (E-mail: [email protected]) ABSTRACT There are some important criteria for preservation of cultural heritages. The determination of these criteria are undoubtedly based on the experiences that are works and studies of ver y long years. Proper protection of cultural properties which are one of the most important and concrete components that consolidate the identity case of a nation is the duty and social responsibility of that nation So when or how should the right and best protection be? The answer to this issue is shortly; never! At first glance, this kind of a response which is negative and revealing a desperate inference actually introduces a natural truth: the change. So how the change, which is an inevitable fact of the nature and the human, and the homoestatis, which means the preservation of cultural properties, will integrate? If the concept of protection of the cultural heritage would be addressed from the perspective of homoestatis, then would not it mean to contradict the change, (the inevitable fact of the nature and human)? It is clear that this creates a conflict when the subject is addressed by classical methods of thinking and approach. Then, the conservation methods convenient to the nature of the human kind should not have an unchangeable, rigid approach regarding the preservation of the cultural heritage. In a preservation work, an approach whose target is “as could be done…” is a better one than the “none or all” one. The breakpoint here, on the other side, is the implementation of this approach via scientific methods. In this study, the assessment of international preservation criteria for the conservation via the intermediate levels was studied. Fuzzy logic method which can make intermediate level assessments is recommended for this purpose. Use of fuzzy logic method, a mathematical method being used in various fields of engineering, in the decision mechanisms aimed at converting the verbal data of a field which has a verbal reasoning into numeric ones and at preserving cultural heritage is one of the first applications in its field. Keywords: Fuzzy Logic, Architectural Conservation, Preservation Acknowledgment: The author thanks to Prof. Zekai Şen and remember in memory of Prof. Ahmet Ersen. 234 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Structural Analysis and Design of Buildings with Shear Wall and Rigid Basements G. Tunc* 1, Z. Khayyat 2 1, 2 Civil EngineeringDepartment, Atilim University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT The seismic design of buildings is generally accomplished based on the results of dynamic analysis by considering a fixed-base support condition. The effect of soil flexibility, on which the building is resting, is usually ignored. Due to the differences in static and seismic responses of rigidly-supported buildings and elastically-supported buildings, it is essential to study the impact ofelastic behavior of soil on safety and cost. The behavior of soil flexibility causes the lengthening of the natural fundamental period due to the overall decrease in the lateral stiffness of a building. This leads to a decrease in the internal forces and moments in the connections. As a result, the overall cost of the building will be kept at a minimum. In this study, the dynamic behavior of rigid basement walls will be investigated. Two different layouts of reinforced concrete buildings will be utilized. These buildings will be assumed to be resting on a mat foundation with different thicknesses depending on the number of stories. Different support conditions will be used in this research to analyze and to design the buildings. A set of horizontal and vertical spring supports will be used in order to take the soil’s elastic behavior into account. Moreover, the results obtained by the different support cases will be compared with each other and the most suitable support case will be discussed. In this research, the dynamic behavior of the buildings will be assessed according to the response spectrum method using the SAP2000 package. The parameters of the research are: building height (low, moderate and high-rise); the soil parameter beneath the building (dense and medium-dense sand); and the number of underground basement stories. Keywords:Elastically-Supported Buildings,Rigid Basements, Dynamic Analysis 235 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The outsourced design coordination in Brazilian civil construction Patricia S. Okamoto* 1, Silvio B. Melhado 2 1, 2 Department of Civil Engineering – Escola Politecnica, University of São Paulo, BRAZIL. (E-mail: [email protected], [email protected]) ABSTRACT This qualitative work aims to highlight, through a case study, the strategic advantages and the importance of the activity called Building Design Coordination to a real estate and construction company in a context of outsourced design development. Facing this goal and trying to demonstrate the Building Design Coordination activity, a field research was carried out in a company specialized in residential projects. In this sense, information was collected with the analysis of documents used by the design coordination and interviews were conducted. It could be verified in this case study that the Building Design Coordination is very relevant once it interferes in the work organization, encouraging more integration, collaboration and reducing the time requested for the design development providing a better alignment between design tasks, outsourced designers and the clients’ interests and needs. However, at the end of this study, it was concluded that the performance and the strategic advantages potentially offered by the Building Design Coordination can be compromised by the way the contracts are prepared and conducted. Keywords: Work organizationl, Design process, Outsourcing, Strategy Acknowledgment: The authors thank University of São Paulo 236 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Impact of Physical Treatment of Hemp Hurds on the Biocomposites Properties N. Stevulova* 1, I. Schwarzova 2, E. Terpakova 3 and J. Junak4 1, 2, 3, 4 Department of Material Engineering, Institute of Environmental Engineering, Faculty of Civil Engineering, Technical University of Kosice, SLOVAKIA. (E-mail: [email protected], [email protected], [email protected] [email protected]) ABSTRACT Biocomposites based on natural fibres as organic filler are studied for several years because traditional building materials such as concrete are increasingly being replaced by advanced composite materials (fibre reinforced polymers and fibre reinforced cement). In this paper, the attention is given to the study of the properties of hemp hurds (the woody part of hemp plant) as filler and non-traditional binder. The hemp as a building composite component is rapidly renewable, carbon-negative, non-toxic, mildew-resistant and pestfree. Technical hemp is becoming a major focus of green housing because of its energy-efficient cultivation as well as its health benefits to living. Due to the low density and high porosity of the hemp hurds, the combination of hemp and binder creates a building material with good thermal and acoustic insulation properties. Today, hemp hurds can be used in high-quality products such as hemp concrete, fibre boards and biocomposites. The cohesion of the filler and binder is very important factor in the development of mechanical properties. This article includes the results of characterization of the properties of physically modified hemp hurds. Physical treatment of natural fibres was carried out in two ways: hydrothermal (by cooking in water for 1h) and ultrasonic treatment (by ultrasound for 1h). Chemical composition and degree of cellulose polymerization were also determined. Physically treated hemp hurds was used to the preparation of biocomposites based on this organic filler and on alternative binder MgO-cement. The impact of physical treatment to changes in the physical and mechanical properties (compressive strength, density, water absorbability, thermal conductivity) of the lightweight composites hardened in indoor condition for a time period is studied. Keywords: Biocomposites, Degree of polymerization, Hemp hurds, Physical treatment, Testing properties. Acknowledgment: The authors are grateful to the Slovak Grant Agency for financial support of the project [VEGA 1/0277/15]. 237 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Seismic Response of Cylindrical Liquid Storage Tanks according to the Characteristics of Structure D. Bae1, C. K. Oh* 2 and J. H. Park3 1, 2 School of Civil and Environmental Engineering, Kookmin University, Korea. (E-mail: [email protected], [email protected]) 3 Department of Civil System Engineering, Ajou University, Korea. (E-mail: [email protected]) ABSTRACT Cylindrical liquid storage tanks are widely used to store various type of liquid, such as water, petroleum, chemical, and liquefied gas. Safety and performance of theses liquid storage tank are required with respect to earthquake. However, inadequately designed liquid s torage tanks suffered several types of damage. Large stress in the tank wall by hydrodynamic pressure caused buckling of the tank wall, amplified sloshing of contained fluid damaged the roof or the top of the t ank wall, and base uplifting or settlement damaged piping connections. The flexibility of the liquid storage tank wall may cause the fluid-structure interaction and amplify hydrodynamic pressure acting on the tank wall and sloshing height under earthquake motions. Seismic analysis of cylindrical liquid storage tanks are performed by finite element met hod. This paper deals with the flexible steel cylindrical liquid storage tanks fixed to rigid foundations. The fluid motion is modeled as the irrotational motion of ideal fluid. Compatibility and equilibrium conditions are imposed along the interface of fluid element and structure element. A comparative analysis of the seismic response of cylindrical liquid storage tanks is conducted with various parameters of the tank, such as type of the roof, stiffness of the wall, and aspect ratio of the tank, to investigate the seismic response of cylindrical liquid storage tanks. Analysis results show aspects in dynamic characteristics of the cylindrical tank and in the hydrodynamic pressure distribution acting on the wall. Also investigated is sloshing motion in the cylindrical tank. Keywords: Cylindrical liquid storage tank, Fluid-structure interaction, Hydrodynamic pressure, Seismic response, Sloshing Acknowledgment: This research was supported by a grant (14CTAP-C077504-01) from Infrastructure and Transportation Technology Promotion Research Program funded by Ministry of Land, Infrastructure and Transport of Korean government. 238 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Construction Stage Analysis of Prefabricated Structure Fezayil SUNCA* 1 and Mehmet AKKÖSE 2 1 2 Department of Civil Engineering, Cumhuriyet University, TURKEY (E-mail: [email protected]) Department of Civil Engineering, Karadeniz Technical University, TURKEY (E-mail: [email protected]) ABSTRACT Prefabricated structures are built in some stages because of having individual characters. Therefore, stages of construction are critical for prefabricated structures. In finite element analysis of these structures, it is assumed that the structure is built and loaded in a second. Since construction periods of this type structures continue along time and loads change during this period, construction stages should be considered in the analysis to obtain reliable results. In this study, it is presented the construction stage analysis of an existing RC prefabricated industrial structure. This is performed by using a structural analysis program (SAP2000). The analysis results with and without construction stages are compared with each other. As analysis results, displacement and internal forces such as the moments, shear forces and axial forces for columns and other elements are presented in detail. It can be seen results that there are some important differences between responses of prefabricated structures with and without construction stages. Keywords: Construction Stage Analysis, Prefabricated Structure, Finite Element Analysis. 239 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Study on Concrete-FRP-Steel Composite Honeycomb Structure for Bridge Deck Minsung Suh* 1, Dong-Ho Ha 2 and Jinkyo F. Choo 3 1, 2, 3 Civil Engineering Department, Konkuk University, Republic of Korea ([email protected], [email protected], [email protected]) ABSTRACT Bridges are indispensable structures in our modern cities. Most of these bridges were made of concrete and erected in the seventies to sustain the economic development. Especially, prestressed concrete bridges were mostly adopted owing to their outstanding properties. However, the bridges in most countries and cities are today near the end of their service life and need to be replaced. Considering the tremendous costs required for the reconstruction or replacement of these bridges, it appears that a lightweight deck would be interesting since it may reuse the existing piers and allow accelerated construction in traffic-congested areas. Composite honeycomb structures have been used in numerous engineering and scientific applications like gliders, rocket substructure, furniture, etc. In the construction sector, the honeycomb structure has already extensively adopted in architectural design but its application in bridge deck has not been considered to date. This structure presents numerous advantages such as being economically efficient in terms of amount of material and weight, and being a torsion-free structure. Accordingly, this study proposes a new type of bridge deck presenting a thin concrete slab at its top, a honeycomb structure made of fiber reinforced plastic (FRP) playing the role of stiffening girder and a thin steel plate at its bottom. The presence of concrete and steel at the top and bottom of the section intends to provide sufficient inertial stiffness and protect the girder from exposure to environmental attacks, and the FRP honeycomb structure is adopted to offer high strength while having a minimal weight. In addition, this paper intends to find the overall geometry of the deck and optimal dimensions for each of the composing materials through a numerical example considering a single-span bridge and applying the serviceability criteria of the Korea Highway Bridge Design Code. Keywords: Bridge Deck, Fiber Reinforced Plastic, Optimal Dimensions, Serviceability, Steel Composite Honeycomb Structure Acknowledgment: This work is financially supported by Korea Minister of Ministry of Land, Infrastructure, and Transport as 「U-City Master and Doctor Course Grant Program」. 240 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Seismic isolation of reinforced concrete structures «Nonlinear Dynamic Method» N. ADJOU* 1 , N. HADDADOU 2 1 National Center of Studies and Integrated Research on Building Engineering, ALGERIA. ([email protected]) 2 National Center of Studies and Integrated Research on Building Engineering, ALGERIA. ([email protected]) ABSTRACT Seismic isolation is a relatively young technology compared to conventional met hods of prevention against earthquakes, its appearance goes back to the Early 20th century, its principle is quite simple, it consists in creating a discontinuity between the foundation and the superstructure, so that the seismic energy cannot be completely transmitted in the structure. The objective of this article is to show the effect of introducing seismic isolator in reinforced concrete structures built in zone of high seismicity within the framework of Algerian earthquake resistant regulations « RPA99 /version 2003». Therefore, the article includes numerical applications of nonlinear dynamics method on isolated structures. Keywords: damping, energy dissipation, isolator, nonlinear dynamic method, seismic isolation. 241 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An analysis of the Influence of Wall Stiffeners on the Fundamental Periods of Steel Liquid Storage Tanks Hadj Brahim M.* 1 , Djermane M. 2 1, 2 Laboratory FIMAS University of Bechar, Algeria. (E-mail: [email protected], [email protected]) 1 National Centre for Integrated Studies and Research Building (CNERIB). ABSTRACT Steel storage tanks are widely used in municipal and industrial activities. Their good behavior after a seismic is vital as well for aid operations as to avoid ecological catastrophes. The design of these structures is usually subject to the application of international codes. Although these codes are constantly updated -especially in the part governing the behavior of steel tanks under seismic loads- they have not yet examined the effect of the wall stiffeners on the behavior of these structures after seismic excitation. The use of these reinforcements in the design of steel tanks can be a suitable solution to improve their resistance in the absence of seismic excitation; but in seismic zones their use is not always reliable and can cause undesirable effects. In this work, we investigate the effect of the wall stiffening on the fundamental periods through a numerical frequency analysis of the tanks with different geometrical parameters. The results show that the fundamental periods are not disrupted by the wall stiffening. Keywords: Tanks, Stiffeners, Finite Elements, frequency analysis. 242 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination Of The Importance Of Materials In Structural Cost Via Architectural Project Examples Z. Ö. Parlak Biçer1, E. İlhan2, D. Kırmızıgül3, A. Akmeşe4, E. Davutoğlu5, A. Keskin6, A. Can Koç7, R. Gurbangeldiyev8 1, Architecture Department, Architecture Faculty, Erciyes University, TURKEY. (E-mail: [email protected], [email protected]) 2,3,4,5,6,7,8 Architecture Department, Architecture Faculty, Erciyes University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT One of the most important inputs in the building of a structure is financial sources. The correct guidance of these sources is distinctive for structural costs. The decision to use the materials determined by the architect is important in determining the cost. It is important that the material usage decisions are given correctly and thus the structural cost analysis is evaluated based on material. Structural cost is an area in which proper solutions can be developed throughout the process starting from the first stage of the design. The effect of material selection on structural cost has been examined in this study using important structures of significant architects as examples. The structures used in the study have been determined as; Farnsworth House, Fisher House, Glass House, Koshino House, Schröder House, Villa Kokkonen, Villa Savoye. Selecting examples of modern architecture in different countries was a significant criteria in this selection process. Because it was observed that local materials were used in every building according to the location. The use of local materials as well as the use of materials such as ferroconcrete or glass is a factor that affects structural cost. First, the unit prices of the current materials selected were calculated for the selected buildings. Afterwards, material selections suited to the structure were selected from among the alternative materials used today and cost was calculated using the unit prices of these new materials. It was determined that material selection has significant effects on structural cost. It was aimed to put forth the importance of materials in cost determination via selection of the sample buildings and the material study carried out. It is hoped that this study will contribute to the field of structure regarding the effects of material selection on the cost. Keywords: Cost analysis, materials 243 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Sample Study Area for the Costs of Arrangements Intended for Disabled People Erciyes University Z. Ö. Parlak Biçer 1, İ. Kuşkaya 2 and Ç. İşbilir 3 1, Architecture Department, Architecture Faculty, Erciyes University, TURKEY. (E-mail: [email protected], [email protected]) 2 TURKEY. (E-mail: [email protected]) 3 TURKEY. (E-mail: [email protected]) ABSTRACT Studies targeting disabled people, elderly people and children with limited movement ability gain importance for spatial designs intended to these groups. Architectural analyses that can enable disabled people to overcome physical difficulties are especially important. Even though various laws and regulations have went into effect for this issue, different problems can arise during the design and building stages of architectural analyses. In addition, required applications are always late since it is believed that analyses intended for disabled people will be costly. There are physical issues even in universities which are known as institutions that generate knowledge and apply it among government institutions. It is thought that universities should provide examples for their city with their social as well as physical attributes since they represent the highest level of education. The objective of this study is to carry out a comparison between the current physical attributes of universities and the attributes specified in the laws and regulations and to carry out a cost calculation. Erciyes University Central Campus has been determined as the sample area for the study. All buildings and additional structures of the different faculties, academies, vocational high schools and their additional buildings have been examined in the study. The examination that started with the determination of the suitability and/or inappropriateness of the physical arrangements intended for disabled individuals continued by determining what the costs of these arrangements will be. Since it was thought that the scope of the study would be too wide, the study that initially focused on disabled individuals later focused only on the visually impaired and the walking disabled individuals. Costs for the approaches to the structures in the campus and as well as the correct applications for the entry spaces have been calculated. It is hoped that this study will contribute to determining the costs for the arrangements that are made and that will be made for disabled individuals. Keywords: Disabled individuals, Architectural Applications, Erciyes University 244 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Study of Advantages and Disadvantages of Tunnel Design Construction System Based on Mass Construction Approach Amir Arefian*1 , Zeinab Mohammadkhani2 ,Omid Moarrefianfard3 1 PhD Scholar in Civil Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran (Email: [email protected]) 2 MA student in Civil Engineering, Shahriar Branch, Islamic Azad University, Tehran, Iran )Email: [email protected]( 3 MA student in Health,Safety and Environment Engineering, Ahar, Islamic Azad University, Tabriz, Iran (Email: [email protected]) ABSTRACT Regarding mass housing, one of the semi-industrial method which has been paid attention in recent years is the construction of high-rise residential towers based on tunnel design. In this system, bearing walls and reinforced concrete ceilings are concerted in a cellular and simultaneous way. In this study, after introducing this modern technology used in housing construction, some advantages and disadvantages of using this methods are pointed out. Also, some necessities are provided based on structural and architectural standpoints. Accordingly, some characteristics, capabilities, and limitations are raised so that a suitable or appropriate decision should be made for implementing this system by considering the available conditions. The factors under scrutiny were selected based on those variables which play a significant role in the process of optimal construction. The most important factors used in the present study include performance, elements, requirements, capabilities, and economic features. All these factors consist of some components by which the system under study is examined based on these elements. Finally, some conclusions are drawn for the scope of applying this system regarding the potentials and limitations of the current system . Key words: Tunnel design, performance speed, mass construction, industrializatio 245 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Shape optimization of sheeting cross section for roof subjected t o different loading combination A. Janushevskis 1, A. Melnikovs* 2 1, 2 Riga Technical University, Institute of Mechanics, LATVIA. (E-mail: [email protected], [email protected]) ABSTRACT Many building companies have continuous attention to sustainable design of steel structures utilizing advantages of stressed skin action. The implementation of such approach for the open plan buildings might give considerable savings of material and erection time. However, in many cases, the structure of roof trapezoidal sheeting that transfers load on the long sides of the frame to wind bracing is described by simplified analytical model and different effects of diaphragm behavior are neglected. Thereby, for instance, FOS may be overestimated, but the benefits of stressed diaphragm effect, in comparison with common framework, would be unnoticeable. On the other hand, complex FE-models are able to describe structural behavior of the roof diaphragms frame to some extent but such models usually require huge computational resources. Therefore, in this work, the alternative approach for designing of lightweight frames of the roof is demonstrated for the hangar building. Firstly, 3D-models of the hangar and its roof are considered and solved accurately using mixed shell-beam-solid FE. The combinations of loads on the structure are considered in accordance to relevant Eurocodes, with special emphasis on the lateral loads. The problems of structure stability and stiffness are solved in detail. The cross-section shape of sheeting for the roofs, as a crucial factor of buildings stiffness, is parameterized using CAD based NURBS curves in such a manner that number of control variables is minimal. Next, for the purpose of reduction of computational time, metamodels are created by recently developed original code “KEDRO” for design of experiments, analysis and multiobjective robust optimization, so cross-section shape of sheeting is bound to the structure responses. Finally, cross-section shape of sheets subjected to different load combination is obtained by global stochastic search procedure to maximize stiffness of stressed elements and at the same time with constrained mass, appropriate stresses and deflections. Keywords: Metamodeling, Shape Optimization, Roof Sheeting. Acknowledgment: This work has been supported by the European Social Fund within the Project No. 2013/0025/1DP/1.1.1.2.0/13/APIA/VIAA/019 “New “Smart” Nanocomposite Materials for Roads, Bridges, Buildings and Transport Vehicle”. 246 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Design of Roofing by using : Tensile Structures Alaa Tareq AL-SHAREEF* 1, Talha EKMEKYAPAR 2 and Derya BAKBAK 3 1, 2, 3 Authors’ Department of Civil Engineering University of Gaziantep, Gaziantep, Turkey, ([email protected], [email protected] and [email protected]) ABSTRACT Civil engineering roof systems for outdoor environments find use in bazaars, car park, outdoor sport facilities and places built to protect people or their goods from environmental effects such as sun and heavy rain. Therefore, such roofing systems have great amount of application and each country spends huge volumes of materials to build these roof systems to improve life quality of people in cities. Thus, it is evident that further research on these civil engineering structures has the potential to decrease the cost of these roof systems and build more efficient ones. Generally these roof systems are ma nufactured employing structural steel material. As is well known, steel has promising mechanical properties such as high strength and high stiffness which can be exploited in structures that expected to receive very high magnitude of loadings, such as earthquake resistant buildings. However, there also exist some disadvantages of completely using steel in these roof systems. Also steel construction is an expensive process considering measure of covered area for outdoor roof systems. Moreover, these kinds of roofs manufactured using completely steel are not flexible in use, that is to say, when it is unnecessary for some period of time it is not possible to remove the roof covering and re -cover it when it is necessary again. This paper investigates a novel concept in the world called as “tensile structures” used to cover wide outdoor areas. This concept actually combines civil engineering designs and some architectural aspects. Instead of using materials with high stiffness, tensile structures adapt membrane m aterials to cover wide areas. Cable elements accompany those membranes to transmit the internal forces and stresses to structural columns or ground. Although membrane materials have lower strengths compared to steel, these structures offer flexibility in use, light coverings, lower costs and faster construction time. In this paper special commercial software is used to investigate behaviour of tensile structures. Three different configurations are employed to cover a wide area. Structural analysis procedure s of those configurations are undertaken and stress distributions in membranes are investigated. Keywords: Tensile structures, outdoor roofing, structural mechanics. 247 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Towards an Sustainable Architecture by Use of Ancestral Knowledge O. KADOURI *1 1 Department of Architecture, University of Béchar. Béchar, ALGERIA ([email protected]) ABSTRACT Building according to the climate by integrating all its elements represents an alternative to improvements in comfort indoor and outdoor. This calls for sustainable architecture whose first principle is adaptation to climatic conditions of a given region. Although adaptation to climate has been a major concern for ancient civilizations and few contemporary architects and planners take the climate in consideration when developing their projects. The objective of this study is to have a clear idea about the degree of influence of the urban tissue on variations in microclimates and subsequently propose solutions in order to remedy the problems of overheating in summer, and to explain the harmful role of new cooling techniques. Although these systems are an effective solution to soften the inner atmosphere, they contribute to temperature increases in external environments. In order to show that the compact traditional tissue, made from local materials uses less energy, and the transformation of the urban tissue in terms of shapes and building materials inevitably leads to a transformation in the quality of the microclimate is itself the product of an interaction between the urban and the prevailing climate; We have established a comparative study between two tissues in the town of Bechar south of Algeria (our case study)which date from different periods (traditional and modern) allowed us to deduce that the traditional compact tissue consumes less energy. The study also allowed us to learn from traditional buildings and use our knowledge as a guiding principle in the design of contemporary buildings in order to integrate climatic factors in our design and create a microclimate suitable and comfortable in the spatial organization. Keywords: Indicators, Microclimate, Saharan Urban tissue. climate, Sustainable development, Traditional architecture, 248 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Response Spectral Analysis of Orthotropic Steel Deck as per Turkish Local Design Spectrums A. Fettahoglu* 1, S. Bekiroglu 2 and İ. E. Bal3 1, 2 Y.T.U. Department of Civil Engineering, TURKEY. (E-mail: [email protected], [email protected]) 3 Earthquake Engineering and Disaster Management Institute, TURKEY. (E-mail: [email protected]) ABSTRACT Orthotropic steel decks are used widely in construction of bridges due to their rather low self-weight when spanned at long distances. An orthotropic deck is composed of deck plate, cross- beams and ribs, in which deck plate forms the flange of cross- beams and ribs. The cross- beams provide the required stiffness, whilst ribs supply longitudinal stiffness to the deck structure to maintain the required stiffness in both directions. In the scope of this study, an orthotropic steel deck spanning between two cross- beams is modelled using a common FE- method. Afterwards, natural frequencies and modes of the sample deck are obtained by using eigenvalue analysis. Then response spectrum analyses are performed under four different seismic spectral curves, which represent four different soil classes. Finally, results are given to evaluate the behaviour of steel deck under seismic actions when various seismic load levels are applied. The novelty of the study is to incorporate the seismic actions with the complicated FE models of the orthotropic decks. Keywords: Orthotropic Deck; Natural Frequency; Free vibration; Response Spectrum Analysis, FEM. 249 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Case Study of Green Building Design E. GEÇER* 1, H. BÜYÜKGÜNGÖR 1 1, Authors’ , Environmental Engineering Department, Engineering Faculty, OMU, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Green Buildings are eco-friendly buildings which use natural energy sources effectively, do not damage environment, reduce energy consumption, and protect living beings around and in it. Design process of these buildings is studied by considering some topics and some certification systems are created. LEED examine the buildings under six topics about sustainability issues. Each of these topics has different point value on examination. These titles are sustainable land, effective usage of water sources, energy and atmosphere, material and sources, quality of internal life and innovation. In this study, Green Building concept and water and energy conservation which are results of this Green Building concept in real estate are investigated. Also systems which are designated sustainability criterias are studied and their contributions on Green Building design are presented. A rural house which is constructed on 3200 m2 area, 25 km from Samsun and 18 km from Çarşamba is selected to study and changes which are based on green building implementations are determined. Especially water management is brought into the forefront and rain water collection system, drip irrigation and grey water recycle systems are designed. Different usage areas are determined to use recycled water. Advantages and usability of solar and wind energy are studied for energy efficiency implementations on selected house. According to results energy sources that should be used in house is selected. Finally initial state of house and state of house after implementations are compared and point and certification value that house can reach according to LEED criteria is determined. Keywords: Ecological Building, Green Building Design, LEED, Sustainability, Water Management 250 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessment of stiffness moduli obtained from IDT test A. Fettahoglu* *Department of Civil Engineering, Yildiz Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT Indirect tensile test (IDT) is used to obtain material properties of wearing surfaces, which are used pavements of ordinary roads or bridges. In general, tensile and compressive displacements in orthogonal directions of test specimen are accepted to have similar creep module to make calculations simpler. Afterwards, Poisson ratio is obtained from classical equations as a function of time. Poisson ratio calculated based on this assumption indicated that it does not vary depending on time, but can be assumed independent on time. However, the first assumption, equal creep moduli for tensile and compressive strains results in nonsense Poisson ratio values, which forces changing of calculation method. In this study, creep module and Poisson ratio is calculated using classical assumptions and proved that the first assumption, same creep module under tensile and compressive stresses, does not hold, whereas second assumption, constant Poisson ratio is true as per IDT test results of Guβasphalt. Keywords: IDT, Creep module, Poisson ratio. 251 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Producibility of Cement-Based Lightweight Construction Material from Coal Bottom Ash of the Bor Sugar Factory (Turkey) N. Doğan-Sağlamtimur* 1, A. Bilgil 2, H. Akbulut 3, M. Dursun 4 and S. Yıldırım5 1, 3, 4, 5 Department of Environmental Engineering, Engineering Faculty, Nigde University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected]) 2 Department of Civil Engineering, Engineering Faculty, Nigde University, TURKEY. (E-mail: [email protected]) ABSTRACT Bottom ash is a waste resulting from coal combustion. In Turkey, storage of this waste requires high costs increasing day by day. In this study, the possibility of the production of cemented lightweight construction materials from this kind of waste was investigated. The experimental study in which TS EN standard series consisting of two stages were used. The lightweight construction material was produced from the bottom ash under 1 mm square mesh sieve in the first step. It was produced from aggregates forming from the bottom ash of appropriate granulometry with a maximum of 8 mm diameter in the second step. In the first step, mixing depending on volume basis was applied to the samples since specific bulk density of bottom ash and cement were different from each other. Cements were added in the weight range of 10-50% to the ash content and then the samples were prepared. Axial compressive strengths and specific bulk densities of the samples that were applied to cure conditions at different mixing ratios were measured from 6.30 to 9.05 N/mm2 and 3 1.2 to 1.8 g/cm , respectively. In the second step, lightweight construction materials have been planned to produce from the aggregates with maximum of 8 mm diameter by calculating concrete mixing. 7, 14 and 28 days of axial compressive strengths and specific bulk densities of these samples which were applied to cure conditions will be measured. Considering economic conditions for the first and second steps, after determining the optimum parameters on the compressive strength, standard tests will be performed for the produced lightweight construction material and then design parameters will be determined. Keywords: Bottom ash, building, lightweight construction material, reuse. 252 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Stability Analysis for a Deep Landslide in Istanbul: A Case Study S. A. Berilgen *1, G. Allamyradov 1, 2 2 Civil Engineering Faculty Geotechnical Department, Yıldız Technical University, ISTANBUL. ([email protected], sberilgengmail.com) ABSTRACT Mass movements are natural disasters that are as old as history of humanity. That is why many scientists in geotechnical engineering have been studying upon determining and preventing from destructive effects of landslides. Instability of slopes depends on slip surface of soil, soil properties, underground water level and some other mechanisms. With development of computer programs many borehole data that are received from big areas can be evaluated together. These programs can provide determination of soil properties and subsurface diagrams of soil. Besides they allow data transfer between other engineering programs. The scope of this study is to improve a stability of slope in landslide area and investigation of influence of capped pile foundation groups to slope’s stability. Also to reveal importance of performing enough and proper geotechnical investigations to calculate slip surface of landslide correctly. Studies also shown that if enough drainage conditions are performed along with preventing increase of pore pressure ratios in soil layers in landslide area, are enough to increase the factor of safety to a sufficient level. Moreover, influences of parameters like pile diameter, amount of pile foundations, length of pile; to system’s stability are researched. Keywords: Mass movement, pile groups, slope stability. 253 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Optimum Design of Reinforced Concrete Retaining Walls using Artificial Bee Colony Algorithm Uğur DAĞDEVİREN* 1, Burak KAYMAK 2 1, 2 Dumlupinar University, Engineering Faculty, Department of Civil Engineering, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Reinforced concrete retaining walls (RCRW) are most widely used to support earth and water in the civil engineering practices such as roads, bridge abutments and landscape constructions. Analysis and design of the RCRW are one of the important problems in geotechnical and structural engineering. In the design procedure of RCRWs, firstly, design variables such as cross-section dimensions and material grades are selected based on previous design experiences. Then, the pressures and forces acted on the wall are calculated by lateral earth pressure theories. Finally, static and dynamic analyses for wall are applied and checked in terms of external and internal design criteria. If the selected initial design variables are insufficient or excessive, design variables of the wall is redefined on a trial and error process. In order to economize the cost of the wall under the design constraints, these procedures are repeated several times. Since it is extremely difficult and time consuming to obtain optimal design satisfying all the stability requirements, it is beneficial to cast the problem as an optimization problem. In this paper, the artificial bee colony (ABC) algorithm was used to determine the optimum design of the reinforced concrete retaining walls. ABC algorithm is an optimization algorithm based on a particular intelligent behavior of honeybee swarms. The objective function of the optimization problem is to minimize the cost of the RCRW. Structural design was performed based on TS 500/2000 which is the Turkish Code for the requirements for design and construction of reinforced concrete structures. The numerical examples were presented to illustrate the performance of the present algorithm. Statistical evaluation for the results obtained by ABC algorithm was made for these examples. In order to determine the reliability of the ABC algorithm, bee colony sizes were selected as 20, 40, 60 and 100 in the problems. Experiments were repeated 30 times each starting from a random population with different seeds. Maximum number of cycle is limited by 1000. The best, mean and worst solutions for the objective function due to the results of the ABC algorithm were presented. The results showed that coefficient of variation was less than 0.2% for 100 bees .The results of the study indicated that the artificial bee colony algorithm can be successfully used for optimal design of the reinforced concrete retaining walls. Keywords: Artificial bee colony (ABC), Optimization, Optimum design, Retaining wall. 254 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Real-time Monitoring of Pavement Structures for Geo-Environmental Purposes Bulent Hatipoglu 1, Craig H. Benson 2 and Tuncer B. Edil 3 1 Power Generation, Rizzo Associates, 500 Penn Center Blvs, Pittsburgh, 15235, PA, USA. (E-mail: [email protected] ) 2,3 University of Wisconsin-Madison, 1415 Engineering Drive, Madison, 53706, WI, USA ([email protected], [email protected] ) ABSTRACT Monitoring systems were designed and installed at field sites in Wisconsin and Minnesota for environmental monitoring of pavements incorporating fly-ash stabilized layers. Hydrological conditions within the pavement are being monitored with water content reflectometers (WCRs) to determine water content and thermocouples to assess soil temperature. Water draining from the profile is captured with a 3 m x 3 m lysimeter. Meteorological conditions are monitored using a weather station adjacent to the roadway. Dataloggers are used for automatic data collection and a server at the University of Wisconsin-Madison regularly downloads data from the dataloggers. All of the instrumentation is powered by a battery that is recharged by a solar panel. This paper describes details of instrumentation program, challenges faced during the installation and data collection, a new method developed to calibrate the WCR sensors, and the data that have been collected. Keywords: Geo-Environmental, Geotechnics, Real-time monitoring, Pavement 255 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparative Life Cycle Assessment of Ground Improvement techniques M. Kucukvar1, N. C. Onat2, O.Tatari3, A. Elgamal4, and K. Mackie5 1 2,3,5 4 Department of Industrial Engineering, Istanbul Sehir University, Istanbul, TURKEY. (E-mail: [email protected]) Department of Civil, Environmental, and Construction Engineering, University of Central Florida, Orlando, FL, USA. (E-mail: [email protected], [email protected], [email protected]) Department of Structural Engineering, University of California-San Diego, La Jolla, CA, USA. (E-mail: [email protected]) ABSTRACT Ground improvement techniques are promising in terms of producing less environmental impact than other conventional deep foundation methods. Although economic saving is considered one of the most important motivations of selecting ground improvement methods, many government agencies are now suggesting a holistic analysis of environmental benefits of different ground improvement methods in addition to economic criteria. In this sense, current research aims to compare the total environmental impacts of traditional piling solution with a particular ground modification method, namely vibro stone column. To achieve this goal, economic input-output life cycle assessment model is utilized to quantify the direct and supply-chain related indirect environmental implications of both methods from a holistic perspective. Five environmental impact categories including energy consumption, carbon footprint, water withdrawal, hazardous waste generation, and toxic releases are analyzed. The results show that using ground improvement as a technically acceptable alternative to piling can provide significance environmental savings that exceed 92% depending on impact category. The use of alternative materials as a partial cement substitute in concrete piling and recycled aggregate in vibro stone columns can be sustainable strategies to reduce overall impacts of both methods. It is envisioned that the results of such analysis will help the decision makers to understand the capability of ground improvement to provide significant environmental benefits in comparison with piling solution. Keywords: Concrete Piling, Economic Input-Output Analysis, Ground Improvement, Vibro Stone Column, Sustainable Infrastructures. Acknowledgment: This material is based upon work supported in part by the National Science Foundation under Grant No. 1201195. 256 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Influence of separation gap on the structural response of colliding structures under earthquake excitation Barbara Sołtysik1, Robert Jankowski 2 1, 2 Department of Metal Structures and Construction Management, Faculty of Civil and Environmental Engineering, Gdansk University of Technology, POLAND. (E-mail: [email protected], [email protected]) ABSTRACT The high level of urbanization in the XXIst century forces the designers to design closely-separated structures and to take into account many factors influencing their response during moderate to strong ground motions. Interactions between adjacent buildings, known as the earthquake-induced structural pounding, may cause serious damage to the structures, leading even to its total collapse. The main reason of collisions between adjacent buildings during earthquakes, aside from insufficient distances between structures is related to the difference in dynamic parameters. The aim of this paper is to present the results of an experimental study of collisions due to insufficient separation gap between models of steel structures under earthquake excitation. To perform this study, models of three steel towers, with different dynamic parameters were constructed. To obtain the seismic excitation, the unidirectional shaking table, located at the Gdansk University of Technology (Poland), was used. To obtain different dynamic characteristics of structures, additional mass – concrete plates with the dimensions of 50 x 50 x 7 cm and 42.2 kg weight – were mounted at the top of each tower. In the experiment, two configurations of the towers were analyzed. The paper shows the results obtained for the configuration no. 1, in which two concrete plates were mounted at the top of external towers and only one concrete plate was mounted at the top of the middle tower. The influence of different separation gap (=0 mm, =20 mm, =40 mm, =60 mm ) was taken into consideration. The results clearly indicate that insufficient in-between separation distance may result in interactions between buildings with different dynamic properties during earthquakes, leading to the change of their responses. The best behavior of structures has been observed for the case of zero gap size as well as when the gap size is large enough to prevent pounding. Keywords: structural pounding, earthquake excitation, steel structures, experimental study Acknowledgment: The authors would like to thank Mr. Henryk Michniewicz and Mr. Hytham Ali Abd Elaziz Elwardany for their help in conducting the experiments. 257 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determining the Behavior of Gravity Retaining Walls under Dynamic Loads Constructed In Saturated Clay Onur Yavan 1, M. İnanç Onur* 2 and Ahmet Tuncan3 1, Department of Civil Engineering, Kırklareli University, TURKEY. (E-mail: [email protected]) 2, 3 Department of Civil Engineering, Anadolu University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Retaining walls are the most chosen earth structures in engineering applications. Retaining walls are constructed to provide lateral earth pressure for vertical slopes. Types of retaining walls can be said such as gravity retaining walls, cantilever retaining walls and counterfort retaining walls. A retaining wall design consists of determining lateral pressures acting on the wall and stability checks for overturning, sliding and bearing capacity. There are different types of lateral earth pressure theories but all of them use unit weight, friction angle and cohesion of the back soil. Dynamic loads can be act to the wall and cause displacement and stability failures in earthquake zone such as Turkey. In this study, behavior of gravity retaining walls under dynamic loads is investigated. For this purpose, firstly design parameters of the wall are determined. Safety factors are chosen minimum 2.0 for overturning, minimum 1.5 for sliding and minimum 3.0 for bearing capacity. Back soil is chosen as saturated clay type of soil and to identify effects of the cohesion on the behavior, cohesion values are chosen 1.0 t/m 2, 2.0 t/m2, 4.0 t/m2. The heights of the wall are chosen as 5, 10, 15 meters. Rankine active earth pressure theory is used for earth pressure calculations. Dynamic behavior is investigated by using Plaxis 2D Dynamic Module. Van earthquake records are used for dynamic analysis. At the end of the study, additional forces and displacements are found then recommendations are given for the safe design in the earthquake zones. The results of the models are compared and behavior of the saturated clays under earthquake loads is determined. Keywords: Gravity Retaining Wall, Dynamic Load, Plaxis 2D. 258 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Vertical Stress Isobars for Rectangular Foundations under Different Loading Conditions Uğur DAĞDEVİREN* 1, Mehmet Ali SALMAN2 1, 2 Dumlupinar University, Engineering Faculty, Department of Civil Engineering, Turkey (E-mail: [email protected], [email protected]) ABSTRACT When the soils are subjected to external loads due to buildings, embankments or excavations the state of stress within soil changes. Stress increments by the external loads are not constant under and around the structure and they vary along the depth in soil. The distribution of stress in soil has a great importance in foundation design. Vertical stress increment is particularly required to calculate the settlement values of the foundations. In geotechnical engineering, the stress increments are generally determined by Boussinesq’s equations which based on theory of elasticity. Boussinesq (1885) presented a mathematical solution for the distribution of stresses for a vertical point load applied on the soil surface. As the structure loads are transferred to the soil through foundations, the stress equations given for a point load are not realistic in many civil engineering problems. The stresses at any depth for the foundations subjected to different foundation geometries and different loading types can be obtained by integrating Boussinesq’s solution for point load over the loaded area. However, it is very difficult and time consuming process to make for all loading cases. In addition to, the analytical solution can only give stress increment under the corner points of the rectangular foundations. In case the vertical stress is desired at any point except the corner of the rectangular foundation, the loaded area must be divided into different rectangular parts and total vertical stress can be calculated with superposition rule. In order to eliminate these disadvantages of the analytical solution, the stress isobars can be used. An isobar is a line which connects all points of equal stress below the ground surface. The calculation of the vertical stress increment at any point with stress isobars is very easy and practical. In this study, a computer program was developed to calculate the vertical stress increment at any point (x; y; z) below the rectangular foundation under different loading conditions based on numerical solution of the Boussinesq’s equations. The calculated vertical stress increments by computer program for different loading conditions (uniform, triangular and trapezoidal) and ratio of foundation dimensions (L/B = 1, 2 and 5) were given as stress isobars which can be easily used to determine vertical stress increments. Keywords: Boussinesq’s equations, Numerical solution, Rectangular foundation, Vertical stress isobars. 259 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect the Lowering Ground Water Table on Behavior of Piled Raft under Vertical Load on Dense Sandy Soil Abdulhafiz O. Alshenawy * 1, Talal O. AL-Refeai 2 and Naif M. AL-sanabani 3 1, 2,3 Department of civil Engineering, King Saud University , Saudi Arabia. (E-mail: [email protected], [email protected] , [email protected]) ABSTRACT The foundation concept of piled rafts differ from traditional foundation of pile group design, in which the raft and piles in piled raft foundation are considered to transmit the superstructure load to subsoil. The piled raft has been proven to be an economical option. The behavior of piled raft is complex, because it consists three components raft, pile, and subsoil and it has three interaction raft-pile, raft-soil, and pile-soil. So the behavior of piled raft depends on geometric of raft and pile and site conditions (type of soils, ground water table, ect) In this paper, the three dimensional model of piled raft were developed by ABAQUS program to investigate the behavior of piled raft with lowering ground water table, the parametric study was performed in length of pile and lowering ground water table. The length of piles change as 10m, 15m, and 20m, the piled raft is considered at the ground surface. Initially the ground water table assumed to be at the ground surface. Then the GWT is lowering to -5m (case1) and to 10-m (case 2), after that the GWT is assumed to be at -5m from ground surface. Then the GWT is lowering to -5m. The pile diameter was kept constant (D=0.5m), and the space between the center of piles was also constant (S=5D).The verification was conducted by using PDR (Poulos Davis Randolph) model. The result indicate that the lowering GWT has a significant effect in increasing the average . the settlement of piled raft for lowering GWT to -10m is larger than settlement for lowering GWT to -5m by 31.5 %0 settlement of piled raft. The lowering GWT has significant effect in increase the load sharing of piles. Keyword: ABAQUS, Piles, Load Sharing, Settlement 260 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison of Damage Criteria for Structures to Near-Field Blast-Induced Ground Motion Damage Estimated by the Different Countries D. M. Özcan* 1, A. Bayraktar 2 and A. C. Altunışık3 1, 2,3 Civil Engineering, Bozok University, TURKEY. ([email protected]) Civil Engineering, Karadeniz Technical University, TURKEY. ([email protected], [email protected]) ABSTRACT In this study, aims to compare the existing damage standard for structures subjected to near -field blastinduced ground motions. For this purpose 64 different blasting records were collected from the selected quarry during twenty months in Trabzon, Turkey. Blasting characteristics such as peak particle velocities, dominant frequencies, air pressures, maximum accelerations and maximum displacements were measured during the blasting on hard soil. There are many damage criteria for d ifferent countries. Longitudinal, transverse and vertical peak particle velocities were evaluated using vibration standards or damage criteria such as Unites States, Germany, Sweden, India, England, Australia, and Turkey. According to the U.S., English and Turkish vibration standards, the measured blast-induced ground motions did not cause the significant damage on the structures as compared with the other standards. It was observed that U.S., English and Turkish standards are more suitable than other stand ard to evaluate the other standards the structural damage level of structures to near -field blast-induced ground motions. In addition, nonlinear dynamic analyses of masonry stone arch bridge were performed. The analytical model was constituted by ANSYS. From the analysis, displacements are increased along to the middle of the bridge. The maximum and minimum principal stresses are obtained at the region around the base of stone arch. Keywords: Analytical model, Damage criteria, Nonlinear dynamic analyses, Maximum and minimum principal stresses, Near-field blast-induced ground motion, Peak Particle Velocity, Structural damage. 261 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination of Horizontal Bulk Material Pressures in Rigid Cylindrical Slender Silos under Seismic Excitation using FEM and EN1998-4 Ayşegül Durmuş* 1, Ramazan Livaoğlu 2 1 Department of Civil Engineering, Karadeniz Technical University, TURKEY. (E-mail: [email protected]) 2 Department of Civil Engineering, Uludağ University, TURKEY. (E-mail: [email protected]) ABSTRACT The seismic design procedure is more complicated compared to the static design procedure for the silos due to the destructive effects of the earthquakes. It can be observed from experiences that failures of silos cause loss of stored material, environmental damage and probable injury or loss of life in recent earthquakes. Moreover, these failures indicate that the seismic behavior of silos is still not understood sufficiently. Hence, the reliability and/or stability of these special structures against failure under seismic loads are of critical concern, and must be understood clearly. In this sense, directly groundsupported cylindrical slender silos were considered in this study. The present proceeding aims to estimate the distribution and the magnitudes of the dynamic material pressures in such silos under seismic loading. To this end, a three dimensional finite element model is described for the simulation of the seismic behavior of such silos with ANSYS commercial program. The reinforced concrete silo and stored material are modeled by solid elements. The surface to surface contact with coulomb friction law is considered for the contact mechanism between the silo wall and the stored material. The obtained results via numerical model and EN1998-4 are discussed in terms of dynamic material pressure and equivalent shear force responses for the considered system, comparatively. Finally, the comparisons showed that the seismic procedure proposed by Eurocode gives smaller dynamic material pressure response values than those obtained from more realistic numerical models for slender silos and the heightwise distribution of these responses are quite different especially for the silos with 3.0 and 4.0 aspect ratios. Keywords: Bulk material-silo wall interaction, Cylindrical Reinforced Silos, Seismic response, Slender silos. 262 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effects of Local Soil Conditions on Structural Behaviour in Adapazarı Kaya, Zulkuf 1; Uncuoğlu, Erdal 2; Erol, Aykut 3; Erken, Ayfer 4; Kara, H. Bekir 5, Yaltır, Şebnem6 1,2,3,5,6 Erciyes University, Faculty of Engineering, Department of Civil Engineering, Kayseri, Turkey ([email protected]; [email protected]; [email protected]; [email protected]; [email protected]) 4 Istanbul Technical University, Civil Engineering Faculty, Istanbul, Turkey ([email protected]) ABSTRACT During the 1999 Kocaeli Earthquake, Mw=7.4, much structural damages and many casualties have been occurred depending on the softening and the liquefaction of foundation soils. A widespread liquefaction phenomenon was observed in central districts located on thick alluvial deposits. In this study, an attempt is made to investigate the effects of local soil conditions on structural behavior. For this aim, a four storey residential building site in which liquefaction settlement and bearing capacity failure were observed has been selected as a case study. Local soil conditions at the site were determined using borehole logs, laboratory and in-situ test results. Liquefaction analyses and bearing capacity calculations have been performed. Also, post-liquefaction settlement has been predicted based on the methods proposed by Ishihara and Yoshimine (1992) and Tokimatsu and Seed (1984, 1987). The settlement values have been compared to results obtained from Plaxis 2D Dynamic. Keywords: Liquefaction, Settlement, Structural Damage. 263 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Seismic Performance of Prefabricated Structures Using Push-Over Analysis Fezayil SUNCA* 1, Mehmet AKKÖSE 2 and Alperen TÜRKAY 3 1 2 Department of Civil Engineering, Cumhuriyet University, TURKEY (E-mail: [email protected]) Department of Civil Engineering, Karadeniz Technical University, TURKEY (E-mail: [email protected]) 3 Department of Civil Engineering, Cumhuriyet University, TURKEY (E-mail: [email protected]) ABSTRACT In Turkey, %98 of the industrial buildings are located on high-risk seismic zones. These structures are ideal solutions to pass large spans without columns. Since they are mostly built as hinge connected prefabricated concrete buildings, their behavior under seismic loading is different from the moment resisting RC buildings. Therefore, seismic response of prefabricated concrete structures is very important. In this study, seismic performance of an existing RC prefabricated industrial structure is determined by nonlinear analysis method defined in Turkish Earthquake Code (TEC 2007). The seismic performance of the structural system has been carried out by using incremental equivalent seismic load method (pushover method) given in TEC-2007. The performance of the prefabricated structure has been evaluated under the design earthquake (the probability of exceedance of the design earthquake within a period of 50 years is %10) and maximum earthquake (the probability of exceedance of the design earthquake within a period of 50 years is %2). The pushover analysis of the structural system is performed by using a structural analysis program (SAP2000). The numerical results are given in tables and figures comparatively and discussed. Keywords: Prefabricated Structure, Seismic Performance Evaluation, Push-Over Analysis 264 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Improving Seismic Behavior of Vierendeel and X-diagonal STMFs by Their Configuration Optimization Armin Badakhshan 1, Farhad Ahadi koloo 2 1 Civil Engineering Department, Shahrood University of Technology, Iran. (E-mail: [email protected]) 2 Aerospace Engineering Department, University of Tehran, Iran. (E-mail: [email protected]) ABSTRACT In recent decades, the use of special truss moment frame (STMF) as a newly developed s teel frame system for seismic regions is spreading. Seismic energy would be damped through frames special absorber sections which are located near the girder beam span. In this paper, the Vierendeel and X diagonal configuration STMF with triangular load model has been studied. Behavior factor of STMF due to strength and ductility has been determined by nonlinear finite element modeling method via pushover static analysis. The plastic hinges are applied in the model in order to consider the nonlinear elasto-plastic material model. Plastic hinges formation places are assumed at the beginning and end of the beams and columns. The analysis for the Vierendeel and X-diagonal configuration of two and threespan for 3 to 8-storey building frames investigated and the results has been evaluated. Based on the results of 3 to 5 floor structures “R” is located in the range of 3.94<R<6.35 and for 6 to 8 floors, it’s obtained in range of 7.77<R<12.53. The results show that the behavior coefficient of Vierendeel frame than t he behavior coefficient of X frame that represents the seismic performance of structures is more appropriate. Behavior coefficient of Vierendeel frame is higher than X-diagonal configuration one that represents the more appropriate seismic performance of Vierendeel structures. The results show that, Behavior factor is strongly dependent on the structure height, so that by increasing the height, the coefficient is significantly increased. Furthermore, the proper forms of Vierendeel truss spans based on the ratio of the span wide of the truss special area and its height for is discussed to achieve the appropriate Behavior factor. Based on the results, by increasing of the ratio, the Behavior factor will be the subject of an increase. Keywords: Pushover static analysis, Seismic behavior, STMF, Vierendeel, X-diagonal. 265 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental behavior of the 1/3 scaled composite shear wall having L shape steel made -up sections as longitudinal reinforcement in boundary regions S. Bahadır Yüksel1, Alptuğ Ünal* 2 1, 2 Civil Engineering Department, Selcuk University, KONYA. (E-mail: [email protected], [email protected]) ABSTRACT The composite shear walls with steel encased profiles can be used as lateral-load resisting systems for buildings that require considerable large lateral-load capacity. The aim of this work is to propose the experimental work conducted on prefabricated composite shear walls (PKPD) h aving L section folded plate (L shape steel made-up sections) as longitudinal reinforcement in boundary regions. Severe complications occur during construction and placement of the longitudinal and transverse reinforcements at the boundary regions of the shear walls especially in the lower stories of the shear wall-frame type of buildings with large bays. High percentage of steel is needed at the end regions of the walls and limited dimensions of the elements cause extensive problems during construction and placing of the boundary reinforcements. The loss of material, labor and time due to the aforementioned difficulties damage economy. To overwhelm this difficulties, experimental work was conducted in order to be able to propose the new prefabricated composite shear walls (PKPD) with L sections as end longitudinal reinforcement to the literature. In the scope of this experimental study, PKPD test specimen was tested under reversed cyclic lateral loading in the Structural Mechanics Laboratory of the Civil Engineering Department of the Selçuk University. The tested 1/3 geometric scaled composite shear wall has aspect ratio of 3.2. The seismic behavior PKPD test specimen was investigated by evaluating and interpreting the hysteresis curves, envelope curves, rigi dity and consumed energy graphs of this tested element. In addition to this, the experimental results, deformation and cracking patterns were evaluated, interpreted and suggestions of the design recommendations were proposed. Keywords: Shear wall, composite shear wall, boundary reinforcement, earthquake resistant structural design, L section. Acknowledgment: The authors thank Selçuk University, Scientific Research Project Funding (SU BAP) for their financial support [Project number: 14101011]. 266 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental behavior of the 1/3 scale reinforced shear wall with intensive boundary reinforcement Alptuğ Ünal* 1, S. Bahadır Yüksel2 1, 2 Civil Engineering Department, Selcuk University, KONYA. (E-mail: [email protected], [email protected]) ABSTRACT Reinforced concrete shear walls are used commonly as the primary lateral -load resisting system because of their large lateral stiffness and strength. Severe complications occur during construction and placement of the longitudinal reinforcements and transverse reinforcements of the boundary regions of the shear walls especially in the lower stories of the shear wall-frame type of buildings with large bays. High percentage of steel is needed at the end regions of the walls and limited dimensions of the elements cause extensive problems during construction and placing of the boundary reinforcements. To be able to investigate seismic behavior of the shear walls having high percentage of vertical steel at the boundary regions, 1/3 geometric scaled reinforced concrete shear wall test specimen was tested under the reversible repeatable lateral loads simulating earthquake at the Structural Mechanics Laboratory of Selcuk University. Reinforced concrete shear wall test specimen was detailed to modern code requirements and standard practice and included heavily reinforced boundary elements. The hysteresis curves, envelope curves, rigidity and consumed energy graphs of this tested element is evaluated. In the final section, the experimental results, deformation and cracking patterns were interpreted and suggestions were made. The test data documenting the global and local behavior of the test units can serve as a reference point for the research community. The experimental results show the importance of the reinforcement content and the ductility properties of the boundary reinforcement for the deformation behavior of the walls. Keywords: Shear wall, reinforced concrete shear wall, seismic design, boundary reinforcement, earthquake resistant structural design. Acknowledgment: The authors thank Selcuk University, Scientific Research Project Funding (SU BAP) for their financial support [Project number: 14101011]. 267 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Bracing Performance on High Rise Circular Steel Buildings under Dynamic Loads Talha EKMEKYAPAR 1, Mustafa RASHID *2 1 Department of Civil Engineering, University of Gaziantep, TURKEY. (E-mail: [email protected]) 2 Natural and Applied Science, University of Gaziantep, TURKEY. (E-mail: [email protected]) ABSTRACT The present study assesses the effect of earthquake dynamic load on steel circular building for different type of bracing. There exist many researches on the effect of earthquake dynamic load on the rectangular buildings and a few or limited studies discuss the effect on circular buildings. Our study will treat high rise steel circular buildings -10,-20 and 30 stories under one direction earthquake dynamic load represented by response spectrum, and searching for the best bracing type to resist the deformation in structural parts. For bracing in this study we use the concentric bracing (x) type and the eccentrically bracing type with link distance equal to (L/5) in different locations in building inner, outer and in the span between core and inner beam. These configurations are modeled considering both the structural performance and properly use of building plan. The structural models will be subjected to different levels of earthquake conditions in one axis of building. Comparative study shows that the type and location of bracings lead different performances for steel circular buildings un der earthquake conditions. Proper use of these bracings has the potential to save the building itself and the people who live in it. Therefore, understanding the underlying mechanics of this behavior will help engineers to consider more effective designs for high rise circular steel buildings. Keywords: high rise steel buildings, earthquake analysis, bracing, circular building 268 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Dynamic Analysis of A Cantilever Retaining Wall Including Soil-Structure Interaction Tufan Cakir* 1 1 Department of Civil Engineering, Gümüşhane University, TÜRKİYE. (E-mail: [email protected]) ABSTRACT Examining the influences of earthquake on cantilever retaining walls has long been recognized as a necessary step to understand the natural hazards and its risk to the society in the long run. Previous investigations have shown that the material properties of the medium supporting the foundation play a very significant role in modifying the responses of the retaining walls. Soil -structure interaction gives rise to kinematic and inertial effects, resulting in modifications of the d ynamic properties of the structure and the characteristics of the ground motion around the foundation. An increase in the natural period and a change in the modal damping for the fundamental mode of vibration are produced by the inertial interaction. The increase in period is a result of the flexibility of the soil, whereas the change in damping results from the loss of energy in the soil by radiation and material damping. The main purpose of this paper is to contribute to a quantification of the effect of soil-structure interaction on seismic response of the cantilever retaining walls. Considering five different subsoil conditions, the seismic analyses of backfill-cantilever wall-soil/foundation interaction system were carried out in time domain through finite element method. The finite element model of the system was constructed using the finite element package ANSYS. The backfill-wall interface behavior was taken into account by using interface elements between the wall and soil to allow for de -bonding. Radiation damping and wave reflection effects were also considered by using artificial viscous boundaries. The response quantities examined incorporate the lateral displacements of the wall relative to the moving base and the stresses in the wall. The results show that soil-structure interaction is of critical importance for seismic design of cantilever retaining walls and accurate consideration of soil -structure interaction in modeling may lead to more realistic and reliable predictions. Keywords: Cantilever wall, Radiation damping, Seismic response, Soil-structure interaction, Wave reflection 269 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental and Analytical Investigation of Modal Parameters of A Historical Masonry Arch Bridge Emre Alpaslan* 1, Kemal Hacıefendioğlu 2 and Olgun Köksal 3 1, 2 3 Department of Civil Engineering, Ondokuz Mayıs University, TURKEY. (E-mail: [email protected], [email protected]) Kavak Vocational Junior College, Ondokuz Mayıs University, TURKEY. (E-mail: [email protected]) ABSTRACT This study aims to investigate dynamic response of a one-span historical masonry arch bridge to earthquakeinduced ground motion. With this reason, Sarp Dere historical masonry bridge, in Ordu, Ulubey, has 15.5m in length and 4.75m in width was chosen as a prototype model. A reduced-scaled model of one-span historical masonry arch bridge has been built in laboratory to estimate the dynamic characteristics of the prototype bridge model, which are natural frequencies, mode shapes and damping ratios. The reduced-scale bridge model and structural details including masonry bricks, mortar joints and filling material were carried out in the scale 1:12.5. In order to determine these modal parameters of the scaled model, Operational Modal Analysis (OMA) was performed under laboratory conditions. Sensitive one-axis accelerometers were located on critical points on the span and arch of the scaled model bridge and signals originated by accelerometers were collected in order to quantify the vibratory response of scaled bridge model. The experimental natural frequencies, mode shapes and damping ratios resulting from these measurements were figured out by using Enhanced Frequency Domain Decomposition and Stochastic Subspace Identification techniques. Threedimensional model of the reduced-scale historical masonry bridge were created in ANSYS finite element software to expose the analytical dynamic characteristics of the scaled bridge model. Experimental results were compared with those of the finite element analysis of the bridge. Calibration of the finite element model was utilized depending on the Operational Modal Analysis results of the reduced-scale model of the bridge. Correlation studies were conducted between the experimental and analytical modal parameters results of the reduced-scaled historical masonry arch bridge to minimize the uncertain finite element modeling parameters such as material properties and boundary conditions. Keywords: Operational Modal Analysis (OMA), Reduced-Scale model, Finite Element Model (FEM), Historical Masonry Arch Bridge. 270 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Finite Element Based Investigation of Backfill Effects on Seismic Behavior of A Cantilever Wall Tufan Cakir* 1 1 Department of Civil Engineering, Gümüşhane University, TÜRKİYE. (E-mail: [email protected]) ABSTRACT Although retaining systems are seemingly simple and easily constructed structures, their seismic design is a rather complicated task. This is mainly attributed to the fact that their dynamic response has not been yet completely understood, despite the numerous studies that have been carried out in the past. Moreover, cantilever retaining walls are critical geotechnical engineering structures which have become widespread during the recent decades following the introduction of reinforced concrete construction techniques, especially in connection with the protection of transportation facilities and/or residential areas. For this type of retaining wall, structural weight is not predominant as equilibrium depends mainly on backfill actions and the resistance of foundation soil. Dynamic loads have come to be forefront of attention due to a number of events that affected retaining structures all over the world, clearly indicating that this issue is important for purposes of stru ctural design. The widespread damage to retaining structures due to earthquakes may have a substantial impact on the economy of the region in terms of both direct and indirect losses. Therefore, knowing the behavior and seismic design of retaining walls is of great importance. In this study, a series of finite element analyses were conducted to investigate the backfill effects on seismic behavior of a cantilever wall incorporating backfill and subsoil interactions. Considering four different backfill soil conditions, the dynamic analyses of backfill-cantilever wall-soil/foundation system were carried out in time domain. The cohesionless soil was modeled as an elasto-plastic medium with viscous boundary applied on the artificial boundary of soil to simulate t he wave energy absorption. Backfill-wall interface behavior was taken into account by using interface elements between the wall and soil to allow for de-bonding. The magnitudes of lateral displacements and stresses were determined. Consequently, based on the response amplification/reduction pattern observed, it is highlighted that the earthquake behavior of cantilever walls can change considerably due to the backfill interaction. Thus, it should be considered in design criteria of cantilever walls. Keywords: Artificial boundary, Backfill interaction, Finite element analysis, Seismic behavior 271 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Geotechnical Properties of Soils with Geographic Information System (GIS) : A case study in Gürsu, Turkey E. Seyrek1, S. Topçu2 and A. Orhan 3 1 Assist. Prof. Dr., Department of Civil Engineering, Faculty of Engineering, Dumlupınar University,Turkey (E-mail: [email protected]) 2 Lecturer, Kütahya Technical Vocational High School, Dumlupınar University, Turkey (E-mail: [email protected]) 3 Assist. Prof. Dr., Department of Geological Engineering, Faculty of Engineering-Architecture, Nevsehir Haci Bektas Veli University,Turkey (E-mail:[email protected]) ABSTRACT Gürsu, selected as investigation area is located at eastern of Bursa and is founded on arable soil. It spreads on 110 km2 area with a population about 70.000. There are many industrial investments around Gürsu and it takes place on a thick bedded alluvium deposit. Scope of the study is to evaluate the properties of foundation soil of Gürsu with Geographic Information Systems (GIS). Recently, geographic information systems Software’s are widely used in geotechnical and earthquake engineering applications. In order to determine the geotechnical behavior of the region, physical and mechanical characteristics of the soil profile were obtained from geotechnical reports of private companies. Test results about ground water level (GWL), sieve analysis, atterberg limits, soil classification, specific gravity and unconfined and/or triaxial compression were picked up from these reports. Topographic, lithological and geotechnical data of the region were compiled as a database in computer to produce geo-engineering maps. Geological cross-sections and also cross-sections for Standart Penetration Test (SPT) values were drawn to decipher specifically the alluvial deposits in detail in densely populated areas. In this respect, the sub-surface of the study area is fully visualized and useful predictor maps and cross-sections are performed to be used in further studies for researchers and designers. Keywords: Cross-sections, GIS, Gürsu, Micro-Zonation, SPT. 272 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Performance of a conceptual hydrological model in hydropower generation for a mountainous tropical catchment in Costa Rica Maikel Mendez* 1 1, Construction Engineering School, Department, Institute, Costa Rica Institute of Technology, Costa Rica. (E-mail: [email protected], [email protected]) ABSTRACT The upper Toro River catchment, a mountainous tropical catchment located in north-western Costa Rica plays an important role in the hydropower generation context of the country. The catchment is situated in one of the rainiest and steepest mountainous areas of the country with a mean annual precipitation of 3200 mm and an average slope of 23%. Following the importance in water utilization, the conceptual HBV -light hydrologic model was selected to study the watershed response to precipitation and develop water balances at daily and hourly timesteps. The HBV-light hydrological model was selected for this study. A 5-year weather and streamflow historical record (2006-2010); was used for calibration (2006-2008) and validation (2009-2010). The model-independent parameter optimization program PEST was used for calibration and sensitivity analysis. The Nash and Sutcliffe efficiency criterion, the Nash and Sutcliffe efficiency with logarithmic values, the Percent Bias and the Absolute Percent Bias were used to evaluate the goodness of fit and model efficiency. Model results indicate good representation of the hydrological processes for daily time -steps but poor performance for hourly time-steps, suggesting that the model is unable to properly describe the complex hydrological processes in steep terrains for high temporal resolutions. Regardless of the temporal resolution; PERC (percolation) K1 (upper zone recession coefficient), K2 (lower zone recession coefficient) and soilFC (maximum soil moisture storage) were the most sensitive parameters. For hourly time-steps, a physically based model is recommended. Keywords: Calibration and Validation, HBV, PEST, Sensitivity Analysis. Acknowledgment: This research was supported by Instituto Costarricense de Electricidad (ICE). The author is grateful to Dirección de Estudios Básicos at ICE for providing observed data for the Upper Toro River catchment. 273 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Uncertainty Analysis of Open Channel Flow: Stochastic Approach to Advection–Diffusion Equation Hossein Khorshidi * 1, Nasser Talebbeydokhti 2 and Gholamreza Rakhshandehroo 3 1 Department of Civil Engineering, Marvdasht Branch, Islamic Azad University, Marvdasht, IRAN. (E-mail: [email protected]) 2,3 Department of Civil and Environmental Engineering, School of Engineering, Shiraz University, Shiraz, IRAN. (E-mail: [email protected], [email protected]) ABSTRACT Advection-Diffusion equation (ADE) arises in various field of applications such as modeling flood, dambreak flows, tides and storm surge. The flow field parameters are often accompanied with uncertainty due to the lack of understanding of the natural open channel properties including roughness coefficient and bed slope, initial and boundary conditions. This paper presents a stochastic approach to describe uncertainty and its propagation based on the ADE. Our investigation is aimed at obtaining higher-order solutions to the statistical moments of the flow depth. To assess the uncertainty in free surface flow, randomly initial condition is imposed in the framework of one-dimensional open cannel flow. Karhunen–Loeve method (KLM) is adopted to decompose the uncertain parameter (initial free surface elevation), as an infinite series containing a set of orthogonal Gaussian random variables. Eigenstrucure (eigenvalues and eigenfunctions) of the covariance function associated with free surface elevation is extracted from Fredhulm’s equation. They play a key role in computing the coefficients of the series. The flow depth is also represented as an infinite series of its moments which are obtained through decomposing by polynomial expansions in terms of the products of random variables. The coefficients of these series are governed by a set of recursive equations that are derived from the ADE. The mean value and variance for the flow depth were expanded up to the third-order. Monte Carlo simulation (MCS), as a reliable approach, is carried out for several realizations and compared with the results of different orders of the present stochastic scheme. The present results highlight various statistical properties of free surface elevation including correlation length and variance. It was found that when higher-order approximations are used, the results of KLM compare well with the Monte Carlo simulation. Keywords: Advection-Diffusion equation, Karhunen–Loeve method, Monte Carlo simulation, Open channel flow, Stochastic solution. 274 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Frequency Analysis of Low and High Flows in Climate Change Yavuz Selim Güçlü Istanbul Technical University, Faculty of Civil Engineering, Department of Hydraulics, TURKEY. (E-mail: [email protected]) ABSTRACT The climate change is an important factor affecting hydrological variables, significantly. In this study, the frequency analyses of low and high flows are performed depending on the duration under the pressure of climate change. Durations of average flows are selected as monthly, seasonal, 6-month and annual values with considering the frequency of 2-year, 5-year, 10-year, 20-year, 50-year, 100-year, 200-year and 500-year. Then, positive or negative trends are determined for the assessment of the low and high flows through the obtained graphs. For the purpose, frequency-flow-duration (FQD) curves similar to frequency-intensityduration (FID) curves are obtained instead of flow-duration-frequency (QDF) curve analogous to intensityduration-frequency (IDF) curve. Additionally, the flow values for n-year frequency are calculated using two parameter Gamma cumulative probability distribution function (CDF). Finally, application is made using the measurement on Görele River as an intact river in Trabzon, Turkey. Keywords: FQD curves, Frequency analysis, High flows, Low flows, QDF curves. 275 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental and Numerical Investigation of Flow Around a Pipeline with Spoiler Öner, Ahmet Alper Civil Eng., Dept., Erciyes Unv., Engineering Fac., TÜRKİYE. (E-mail: [email protected]) ABSTRACT This paper presents the experimental and numerical results of a 2D turbulent flow around a smooth pipeline with and without a spoiler at ReD=4150 and 9500 with G/D=0.3. PIV technique is used to measure the flow velocities around the pipeline and ANSYS® 11 (CFD) program package based on FEM is used to solve the governing equations. The k- and k- turbulence models on different mesh densities are used to simulate the flow field. The k- turbulence model on the finest mesh is found better than k-, in the simulation. The results show that the spoiler increase the length of the separation areas around the pipeline and quite contrary to the speculation that the increase in the process of local scouring under the pipeline with spoiler is due to the increase of flow through the gap, in this study it was observed that the rate of flow through the gap do not increase significantly due to the spoiler on the pipeline. Keywords: Pipeline, Spoiler, Turbulent Flow. 276 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison of Performance of Labyrinth and Piano Key Weirs in Increasing the Spillway Capacity of Dams Deniz Karaeren* 1 and Zafer Bozkuş2 1, 2 Civil Engineering Department, Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Dams play an important role in infrastructure of our country and provide drinking water, flood protection, renewable hydroelectric power, navigation, and irrigation as well as facilities for sports activities. However, dams in Turkey are gradually aging and in order to assure the safety of those aging dams, rehabilitation is necessary. Very often, increasing the capacity of a spillway would be required in rehabilitation works. Thus, it is the main goal of this study to investigate some practical methods used in increasing the spillway capacity of dams. In this respect, labyrinth and piano key weir types were selected as the two effective methods to achieve that mentioned goal. Design procedure of labyrinth weirs and piano key weirs were outlined and each one applied in five different existing projects. Comparisons were made with linear weirs, it was concluded that labyrinth and piano key weirs increase the effective crest length of a dam spillway significantly for a given spillway width, therefore, in return, they increase the flow capacity for a given operating head. Moreover, different geometric parameters were also studied to see their effect in changing the discharge capacity. Keywords: spillways, capacity, labyrinth, piano key weirs Acknowledgment: The authors thank State Water Works (DSI) for providing data for the dams used in the study. 277 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Improving Design Storm Estimation by DAD Curves in Watershed Considering Non-uniform Rainfall. Case study: Khersan Basin M. Fazaee* 1 and A. Sourinejad2 B. Jamshidieini 3 1 Ghods Niroo engineering company. IRAN (E-mail: [email protected]) 2 University of Payame-Noor. IRAN (Email: [email protected]) 3 University of Tehran. IRAN (Email: [email protected]) ABSTRACT A significant portion of disaster-related damage of hydraulic structures results from flash flooding. Therefore, design flood estimation is a crucial part of design and sizing of all hydraulic structures such as dams. Since storms are the main cause of the floods, reliable flood estimation needs accurate estimation of the storms. Estimation of probable maximum precipitation (PMP) and using depth-areaduration (DAD) curves are two well-known techniques of the design storm approximation. Synoptic based probable maximum precipitation is a reliable method for design storm estimation but the result obtained for whole basin cannot be generalized to its subbasins. In contrast, DAD curves can be used in subbasins as well as whole basin. However, it is not as reliable as the synoptic method. Khersan basin is located in southwest of Iran and comprises of two wet areas in south and west and one arid area in northeast. In this study, we use traditional DAD curves to estimate the design storm. Afterwards, the basin is divided into three sub-basins according to long-term precipitation and DAD curves plotted for each subbasin separately. The results showed that if a basin is a combination of arid and wet areas, especially in the presence of barriers like mountains, there is a risk of design storm overestimation in the arid areas. Finally, current study suggested that dividing the basin into a few subbasins can reduce the overestimation of design storm and prevent the overdesign of hydraulic structures. Keywords: DAD, Design storm, Flood estimation, Non-uniform 278 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A New Area Based Parameter Estimation Methodology for Leaky Aquifer System A. Ufuk ŞAHİN* 1 1 Department of Civil Engineering, Hacettepe University, TURKEY. (E-mail: [email protected]) ABSTRACT A new integration based estimation methodology is developed to elaborate the hydraulic parameters for leaky aquifer systems. The field data obtaining from the pumping test are traditionally superimposed with the set of non-equilibrium type curves drawn by the assumptions such as homogeneous aquifer, no well losses and wellbore storage, etc. Any deviations from the ideal settings may lead a difficult matching with theoretical curve family, which, therefore, causes the misinterpretation of aquifer parameters. In the proposed method, referred as Area Based Estimation (ABE), the leakage factor ( r / B ) could be easily estimated to avoid the need of curve match process. The performance and reliability of the ABE method were tested under different aquifer settings including synthetically homogenous and real field examples and compared with the available methods used in the groundwater literature. The results verify that the ABE procedure could be employed as a viable approach in order to estimate leaky aquifer parameters. Keywords: Aquifer Parameters, Area Based Estimation (ABE), Heterogeneity, Leaky aquifer. 279 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Numerical Simulation of Wave-Structure Interaction Using a Ghost-Cell Immersed Boundary Method E. Demirel Civil Engineering Department, Eskisehir Osmangazi University, TURKEY. [email protected] ABSTRACT In this work, a ghost-cell immersed boundary method is proposed for the numerical simulation of nonlinear free surface waves and their interaction with a stationary solid boundary. The numerical method employs a second order accurate two-step projection algorithm to solve Navier-Stokes equations on a staggered grid system. Two different test problems, flows over a stationary circular cylinder and propagation of solitary wave on a sloping beach, are simulated to demonstrate the accuracy of the present numerical method, and the results are compared with previous numerical and experimental results. The comparisons show that the present immersed boundary method can accurately simulate the interaction of surface waves with complex structures. Keywords: Immersed Boundary Method, Solitary Wave, VOF, Wave-Structure Interaction. Acknowledgment: The numerical calculations reported in this study were performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA Resources). 280 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessment of Diyarbakır Basalt Aquifer hydrogeological analyzed and obtains thematic maps with GIS Geostatistical Analyst Tool. Recep ÇELİK* 1 1, Authors’ Asst. Proff. Dr. Dicle University Engineering Faculty. Civil Engineering Department, Diyarbakır/TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Diyarbakır basalt aquifer is volcanic-rock aquifers which contains high quality water. It used to use for drinking water of Diyarbakır city center drinking demand up to Dicle Drinking Water Project in 2005. Somewhere basalt aquifer groundwater still uses for irrigation in rural areas of Diyarbakır city. In our study, Diyarbakır city center’s -which is located on the Tigris river basin’s- basalt aquifer groundwater potentials and hydrogeological features examined and modeled by using GIS programmer. Firstly, general geological data, meteorological data and general information about natural water sources collected together, afterwards logs of well drilled by public institutions and private individuals within the Diyarbakır city center are analyzed . Static water level, dynamic water level, pumps productivity rates are classified in these logs. Then, thematic maps produced with the help of Arc Info Professional GIS programmer with Geostatistical Analyst tool. Groundwater source potential of Diyarbakır examined with by means of these thematic maps. In hydrogeological research, productivity by aquifer features, water retention capacity and groundwater level data evaluated with geological structure of area taken into consideration. Key Words: Diyarbakır city centre,basalt aquifer, groundwater, groundwater static level, dynamic water level, pump flowrate efficient, GIS (Geographical Information Systems) Keywords: Groundwater, GIS, Water Quality, Diyarbakır City Center Acknowledgment: The authors thank Dicle University, Scientific Research Project Funding (DUBAP) for their financial support [Project number: MYO 147]. 281 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effect of Some Aquifer Characteristics on Permeable Reactive Barriers Efficiency for Groundwater Remediation S. Atashin* 1, A. Abrishamchi 2 and M. Vossoughi 3 1 2 Civil Engineering, Student of Sharif University of Technology, IRAN. ([email protected]) Civil Engineering, Profesor of Sharif University of Technology and UNESCO Chair in Water and Environment Management for Sustainable Cities, IRAN. ([email protected]) 3 Chemical and Petroleum Engineering, Profesor of Sharif University of Technology, IRAN. ([email protected]) ABSTRACT Today, groundwater contamination has raised deep concerns among environmental scientists. Since groundwater cleanup is generally very expensive and complex process, introducing cost effective ways such as in-situ remediation method brings much benefit. This research has considered permeable reactive barrier (PRB) method among in-situ remediation technologies and tries to find the suitable condition for its reactivity. To achieve this goal, the effect of two aquifer characteristics, hydraulic conductivity and hydraulic gradient, on the efficiency of groundwater contaminants removal by permeable reactive barriers are studied. In this research, computer simulation is done via two dimensional finite difference groundwater flow model, MODFLOW. The results show that the contaminant removal percentage is reduced when the barrier gets less permeable such that at low KAquifer /KPRB ratios the contaminant removal percentage is equal to zero. It is also concluded that, hydraulic gradient has no significant effect on the contaminant removal percentage by PRB . Keywords: Groundwater, Hydraulic Conductivity, Hydraulic Gradient, In-Situ Remediation, PRB, Acknowledgment: We offer our sincere appreciation to Dr. Gholami and Dr. Alamolhoda, professors of Sharif University of Technology, since this work is benefited from their comments and suggestions. 282 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Potential of image processing methods based on intensity values captured by TLS for surface condition assessment J. Zaczek-Peplinska*1, K. Osińska-Skotak2, D. Wujanz 3 and M.E. Kowalska 4 1, 2, 4 Warsaw University of Technology, Faculty of Geodesy and Cartography, POLAND. (E-mail: [email protected], [email protected],[email protected]) 3 TechnischeUniversität Berlin, Institute for Geodesy and Geoinformation Science, GERMANY. (E-mail: [email protected]) ABSTRACT Laser scanning technology provide fresh opportunities for monitoring of engineering object s, such as concrete water dams, whose failure might endanger both life and property of local inhabitants. Laser scanning allow to collect in a very short time millions of highly accurate points, for which, apart from spatial coordinates, intensity value is registered. Laser beam deflection intensity value depends in large extent on properties of surface, allowing to analyze its condition. This paper presents examples of application methods of digital image analysis in reference to data obtained in the proce ss of laser measurements using Terrestrial Laser Scanning (TLS). Clustering algorithms applied among others in the processing of multi- and hyperspectral images, in the following research, were utilized to indicate areas of concrete surface with similar properties/characteristics, helping to determine areas requiring closer inspection. Experiment utilize TLS measurements data, obtained using two laser scanners with different technical parameters of laser beam, including electromagnetic radiation wavelength – Leica C10 (green laser) and Z+F Imager 5006h (red laser). Measurements of surveyed objects were performed at the same weather conditions, from exactly the same testing base positions. Measurement outcomes were processed using following algorithms: ISODATA, minimum distance and maximum likelihood. Obtained results indicate, that digital image processing methods adopted for Intensity images allow for obtaining information regarding the condition of concrete surface. Effectively, conducted analysis permitted for indication of areas requiring conservation and preservation. Keywords:Clustering algorithms,Laser Scanning, Supervised classification, Technical Control of Dams,Unsupervised classification. 283 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Selection of reference fields for statistical analysis of point clouds (TLS) in a process of technical condition assessment of concrete water dam J. Zaczek-Peplinska *1, M. E. Kowalska 2 and E. Nowak3 1,2,3 Warsaw University of Technology, Faculty Geodesy and Cartography, Chair of Engineering Geodesy, Measurement and Control Systems, POLAND (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Periodical measurements of concrete dams conducted within geodetic monitoring can be performed using terrestrial laser scanners (TLS), which allow for obtaining point models (of quasi-continuous character) that are suitable to further processing and analysis. The main parameter distinguishing laser scanners from other, classical geodetic instruments, apart from rate of work and high number of registered points, is a registration of Intensity value (I) – laser beam reflection strength. Analysis of registered I values might have a practical application for structure condition diagnosis. At present, spatial data obtained using laser scanning are most often utilised to elaboratearchitecturalinventory. Performed experimental measurements indicate, that the TLS technology can be successfully applied to assess condition, strength and hardness of concrete surfaces, as well as filtration rates and cracks of a water dam surface (especially of the downstream face at low water). This paper will present the new approach to data (point clouds) obtained using TLS technique. It will also describe research leading to development of selection methodology for the reference fields . Authors propose taking into consideration factors such as: points distribution depending on distances between the scanner and the surveyed surface, laser beam angle, predefined scan density and reflection intensity value. Condition for true analysis of point clouds obtained in a course of periodi cal TLS is the correct definition of the quality and accuracy of analysed data (for both, separate scans and point clouds). In order to enhance credibility of determined deformations and displacements authors propose point clouds classifications method, that is marking out areas of different “quality” category, as well as determining reference fields basing on research conducted “in situ” - e.g. non-destructive surface test methods and visual techniques. Keywords: deformations of engineering structures, engineering geodesy, reference fields, technical condition assessment, terrestrial laser scanning (TLS) 284 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Flow Measurement Using One Point Method for the Rectangular and Triangular Free Overfalls Ehsan Abrari* 1, Mustafa Ergil 2 and Mohammad Karim Beirami 3 1, 2 3 Civil Engineering Department, Eastern Mediterranean University, T.R.N.C. (E-mail: [email protected], [email protected]) Civil Engineering Department, Islamic Azad University, Estahban Branch, Estahban, IRAN. (E-mail:[email protected]) ABSTRACT This paper presents a simplified theoretical method to analyze the free overfall in the rectangular, triangular channels. Applying the continuity equation, a new theoretical approach is presented to obtain the end depth ratio (EDR) using the non-uniform velocity distribution at the centroid of the brink section. In sub-critical flow regimes, the EDR related to the critical depth are found to be 0.7071 and 0.8091 for the rectangular and triangular channel cross sections, respectively. The method of estimation of the end depth discharge (EDD), for sub-critical flow regime, is also presented. The computed results are in acceptable agreement using some of the pertaining experimental and theoretical studies. Keywords: End depth; Flow measurement; free overfall. 285 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessing the Sensitivity of SWMM Model to Variations in Hydrological and Land Use Parameters Zeynep Akdoğan* 1, Başak Güvenr2 and Işıl Balcıoğlu 3 1, 2, 3 Institute of Environmental Sciences, Boğaziçi University, TURKEY. (E-mail: [email protected], [email protected], balcı[email protected]) ABSTRACT Increasing human activities, urbanization and land use changes in recent years have contributed to water quality degradation by affecting the transport of contaminants to receiving waters by overland flow. This necessitates the development of modeling approaches for planning and management of catchments that play a significant role on water supply. However, data gathering and harmonization are one of the most challenging steps towards developing distributed catchment models due to the spatial variability of data. The main objective of this study is to develop a semi-distributed hydrological model, and to determine the effects of precipitation and land use changes on runoff production in the Marmara Region. Storm Water Management Model (SWMM) was chosen to develop the catchment hydrological model. Spatial data obtained from Geographical Information Systems (GIS), and land use and cover information were used as input parameters for the SWMM. 55 years of time series precipitation data were used for model simulations. Finally, a one-ata-time parametric sensitivity analysis was carried out to determine the most important parameters affecting SWMM outcomes. Model’s sensitivity was assessed based on the variations in eight major parameters of the model affecting runoff quantity and quality. Sensitivity of runoff quality was assessed using buildup and washoff functions, which were analyzed based on the loads of relatively soluble metals in water, such as Cu and Zn. According to the analysis results, the most significant parameters include precipitation, area, and maximum buildup of contaminants. The model is also quite sensitive to changes in buildup rate constant, while exponential washoff functions has an average influence. On the other hand, percent imperviousness and percent slope have the lowest influence on model outputs. Results also revealed that GIS incorporated SWMM modeling approach could be used as an efficient tool for developing hydrological models for catchments within the Marmara Region. Keywords: Catchment hydrology, Geographical Information Systems (GIS)Land use, Parameter Sensitivity Analysis, Storm Water Management Model (SWMM) Acknowledgment: The authors thank Boğaziçi University, Scientific Research Project Funding (BAP) for their financial support [Project number: 6643]. 286 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination of System Deficiencies with WDS Models *1 Ayşenur USLU , Gülfem BAKAN 2 1 Department of Civil Engineering, Ondokuz Mayis University, Samsun/TURKEY (e-mail: [email protected]) 2 Department of Environmental Engineering, Ondokuz Mayis University, Samsun/TURKEY (e-mail: [email protected]) ABSTRACT Before the start of the construction, not to take into account the situations that may occur in a real system causes errors of no return when designed system is presented to service. Therefore in order to help water system designers, operators and managers, modeling tool has been developed by the time. The fundamental goal of hydraulic modeling for water distribution systems is to develop and maintain a model that sufficiently simulates the performance of the distribution system. In this study, Samsun 19 Mayis district, the adequacy of drinking water distribution system was examined in terms of using hydraulic modeling software. In the first stage, information about the existing system was gathered and database of the drinking water distribution system was created using Geographic Information System (GIS). In the second phase of the study, the network components of the real system is transferred from Geographic Information System database to the model through MIKE URBAN WD water distribution system software, the water demand inputs and topographic inputs have been identified. In the third stage model results were compared with field observations and model input parameters were calibrated. In the fourth stage of the study, steady state analysis of calibrated model of the 19 Mayis district drinking water distribution system were performed according to maximum daily water consumption, maximum hourly water consumption and maximum daily water consumption with fire flow scenarios. The adequacy of the existing system was examined according to analysis results and suggestions were offered in order to eliminate system deficiencies. Keywords: Fire flow analysis, MIKE URBAN WD software, Steady state analysis, Scenario. Acknowledgment: The authors thank Ondokuz Mayis University, Scientific Research Project Funding (OMU BAP) for their financial support [Project number: PYO.MUH.1904.11.016]. 287 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The impact of the soil data quality on the effectivness of hydrological modelling. Case study: Upper Raba Catchment (Poland) E. Wojtas 1, M. Sawczak* 2, T. Bergier 3 and W. Drzewiecki 4 1, 2, 3 4 AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Environmental Management and Protection, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected], [email protected], [email protected]) AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Geoinformation Photogrammetry and Remote Sensing of Environment, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected]) ABSTRACT Information about soils is beside the digital terrain model and the structure of land use an essential part in delineation of the hydrological response units (HRU), which are the basis to perform the process of hydrological modelling. The main factors affecting modelling results are soil map resolution and the accuracy of parameters describing soil conditions, among others granulometric compositions, bulk density, infiltration rate and organic matter content. The objective of this study was to determine and to assess the impact of soil data quality on model efficiency. For this purpose data from two sources were used: a detailed soil map by Institute of Soil Science and Plant Cultivati on (IUNG, State Research Institute) and highly generalized The European Soil Database (ESDB). Simulation of runoff and evaluation of its effectiveness was performed by using Jena Adaptable Modelling System the hydrological model J2000-S and was carried out in the study area of Upper Raba Catchment (~640 km2, Malopolska, Poland) and two subbasins (~90 km2 and ~165 km2) with different characteristic. The spatial data preparation was covered by two different HRU delineations: a cluster analysis with overlaying of soil map and cluster analysis with overlaying of land use map, allowing a more complex soil data type importance analysis. The results showed differences in modelling effectiveness depending on soil data resolution and source as well as the role of the soil map in HRU delineation process. Keywords: hydrological modelling, model J2000-S, soil data Acknowledgment: The article was realized in SaLMaR project, funded by the National Centre for Research and Development in the context of Polish-German Sustainability Research Cooperation. 288 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Remote sensing based impermeability coefficient estimation and its influence on hydrological modelling efficiency E. Wojtas* 1, T. Bergier2, W. Drzewiecki 3 and M. Sawczak4 1, 2, 4 3 AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Environmental Management and Protection, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected], [email protected], [email protected]) AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Geoinformation Photogrammetry and Remote Sensing of Environment, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected]) ABSTRACT A common approach in hydrological modelling in terms of impermeability distinguishes between two main classes of land use called urban areas and rural areas. The values representing their impermeability are assigned basing on expert knowledge or program recommendations which introduces a large simplification of the data provided. Extensively studied and proven influence of urbanization and what follows surface sealing on infiltration, surface runoff and consequently catchment runoff is the starting point to consideration about providing more detailed land use and land surface impermeability information. The goal of this study was to determine an optimum number of impervious areas classes basing on the data provided with use of remote sensing. For this purpose a mean impermeability coefficient for land use vectorised map features was estimated and the reclassification of rasterized land use map was made in several different ways. The evaluation of each was carried out by comparing runoff modelling efficiencies with each other and with basic results from two classes approach modelling. Keywords: hydrological modelling, impermeability. Acknowledgment: The article was realized in SaLMaR project, funded by the National Centre for Research and Development in the context of Polish-German Sustainability Research Cooperation. 289 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The importance of land use changes and data quality for hydrological modelling E. Wojtas*1, M. Sawczak2, T. Bergier 3, W. Drzewiecki4, M. Pierzchalski5 and P. Wężyk6 1-3 AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Environmental Management and Protection, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected], [email protected], [email protected]) 4 AGH University of Science and Technology, Faculty of Mining Surveying and Environmental Engineering, Department of Geoinformation Photogrammetry and Remote Sensing of Environment, al. Mickiewicza 30, 30-059 Krakow, POLAND (E-mail: [email protected]) 5 6 ProGea Consulting, ul. Pachońskiego 9, 31-223 Kraków, POLAND (E-mail: [email protected]) Laboratory of Geomatics, Department of Forest Management, Geomatics and Forest Economics, Institute of Forest Resources Management, Faculty of Forestry, University of Agriculture in Krakow, POLAND (E-mail: [email protected]) ABSTRACT The significant influence of land use and land management on water cycle can be reflected in hydrological modelling by entering a parameterized land use map into the program. However, relatively long periods used in hydrology in the context of rapidly changing land cover exclude constant projection of catchment response to the precipitation throughout the period of modelling, thereby hindering model parameterization and evaluation. The goal of this study was to estimate the actual size of these observations for the purpose of land use scenario preparation. The implementation of JAMS (Jena Adaptable Modelling System) model J2000 -S was carried out for a former rural mountainous catchment and its two subcatchments in order to differentiate land use, scale and elevation impact on the land use data significance in modelling. In this approach three models using different land development stages were parameterized and calibra ted for the time interval of 20 years, while model efficiencies were calculated for years representing the state of land cover reflected by land use map entered into the model. The comparison of model efficiencies for all catchments and time intervals was used to assess the importance of the land use map accuracy depending on the type of catchment and modelling period. Keywords: hydrological modelling, land use, water cycle Acknowledgment: The article was realized in SaLMaR project, funded by the National Centre for Research and Development in the context of Polish-German Sustainability Research Cooperation. 290 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparative study for Discharge Coefficient Prediction of Compound Broad Crested Weir by two Soft-Computing Techniques Gürol Yıldırım1 1 Gürol Yıldırım Civil Engineering Department, Aksaray University, TURKEY. (E-mail: [email protected]) ABSTRACT Compound broad-crested-weir is a typical hydraulic structure that provides flow control and measurements at different flow depths. Compound broad-crested weir mainly consists of two sections; first relatively small inner rectangular section for measuring low-flows, and wide rectangular section at higher flow depths. In this paper, series of laboratory experiments was performed to investigate the potential effects of length of crest in flow direction, and step height of broad-crested weir of rectangular compound cross section on the discharge coefficient. For this purpose, 15 different physical models of broad-crested weirs with rectangular compound cross sections were tested for a wide range of discharge values. The results of examination for computing discharge coefficient were yielded by using multiple regression equations based on the dimensional analysis. Then, the results obtained were also compared with Genetic Programming (GP) and Artificial Neural Network (ANN) techniques to investigate the applicability, ability and accuracy of these procedures. Comparison of results from the GP and ANN procedures clearly indicates, the ANN technique is less efficient in comparison with the GP algorithm, for the determination of discharge coefficient. To examine the accuracy of the results yielded from the GP and ANN procedures, two performance indicators (determination coefficient (R2) and Root Mean Square Error (RMSE)) were used. The comparison test of results clearly shows that, the implementation of GP technique is sound satisfactory regarding the performance indicators (R2 = 0.952 and RMSE= 0.065), with less deviation from the numerical values. Keywords: Broad-Crested Weir, Compound, Discharge Coefficient, Genetic Programming (GP), Artificial Neural Network (ANN), Soft Computing. 291 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 State-of-the-Art Review on Explicit Approximations to the Implicit Colebrook-White Friction Factor Equation Gürol Yıldırım1 1 Gürol Yıldırım Civil Engineering Department, Aksaray University, TURKEY. (E-mail: [email protected]) ABSTRACT The implicit Colebrook-White equation has been widely used to estimate the friction factor for turbulent fluid-flow in rough-pipes. In this paper, the state-of-the-art review for the most currently available explicit alternatives to the implicit Colebrook-White equation, is presented. An extensive comparison test was established on the 20×500 grid, for a wide range of relative roughness ( / D ) and Reynolds number (R) 6 2 3 8 values ( 1 10 / D 5 10 ; 4 10 R 10 ), covering a large portion of turbulent flow zone in the Moody’s diagram. Based on the comprehensive error analysis, the magnitude points in which the maximum absolute and the maximum relative error are occurred at the pair of / D and R values, are observed. A limiting case of the most of these approximations provided friction factor estimates that are characterized by a 4 3 mean absolute error of 5 10 , a maximum absolute error of 4 10 whereas, a mean relative error of 1.3% and a maximum relative error of 5.8%, over the entire range of / D and R values, respectively. For practical purposes, the complete results for the maximum and the mean relative errors versus the 20 sets of / D value, are also indicated in two comparative figures. The examination results for error properties of these approximations gives one an opportunity to practically evaluate the most accurate formula among of all the previous explicit models; and showing in this way its great flexibility for estimating turbulent flow friction factor. Comparative analysis for the mean relative error profile revealed, the classification for the best-fitted 6 equations examined was in a good agreement with those of the best model selection criterion claimed in the recent literature, for all performed simulations. Keywords: Fluid mechanics; turbulent flow; Colebrook-White equation, friction factor; Moody’s diagram; closed form solution; explicit scheme; steady-state analysis; Excel spreadsheet; Techdig 2.0 software. 292 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Innovative Test Set Up on Shake Table to Assess Out-of-Plane Behavior of Infill Masonry Walls Onur ONAT* 1, Paulo B. Lourenço 2 and Ali Koçak3 1 Graduate School of Science, Yıldız Technical University, İstanbul, TURKEY. (E-mail: [email protected]) 2 3 Civil Engineering Department, ISISE, Guimaraes, PORTUGAL. (E-mail: [email protected]) Civil Engineering Department, Yıldız Technical University, İstanbul, TURKEY. (E-mail: [email protected]) ABSTRACT This paper aims to discuss new test set up on shake table to assess out of plane behavior of infill masonry walls subjected to bidirectional earthquake load. For this purpose 1:1 scale single bay single storey reinforced concrete frame and infill wall was produced. Then special steel boundary conditions were placed on shake table to simulate 7 th floor of 8 storey building. Also infill wall was connected to reaction wall from one side with strut. Dimensions of this specimen are 6.4 m length and 3.25 m height. Earthquake loads were applied in 5 steps with incremental load. However, during the test, there was a problem with boundary condition. This problem was a gap between reaction wall and reinforced concrete frame. Due to this gap problem, bizarre results were came up after processing datas. However, processed datas are compatible with general cracks of structures and this specimen. General out-ofplane behaviors of mid part of infill wall were simulated with 3-D graphs. Crushed parts of infill are demonstrated with damage maps along in-plane direction. Furthermore, other purposes of this paper are to discuss result of this experiment, precautions for next tests and suggestions. Keywords: Infill, Masonry, Out-of-Plane Behavior, Shake Table 293 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Fabrication and Critical Decomposition of High Resistance Interlocking Flooring with Magnetically Treated Water from Iron-Boron-Neodymium Magnets Paulo H. S. Queiroz* 1, Fábio H. S. Sales2 and Andrey Lopes 3 1 Civil Engineering Department, Federal Institute of Technology of Maranhão, BRAZIL. (E-mail: [email protected]) 2 3 Physics Department, Federal Institute of Technology of Maranhão, BRAZIL. (E-mail: [email protected]) Civil Engineering Department, Federal Institute of Technology of Maranhão, BRAZIL. (E-mail: [email protected]) ABSTRACT The presented project aims to fabricate and decompose critically concrete using instead of drinking water available in the network common distribution, water conducted through magnetic treatment magnets neodymium-iron-boron, also known as rare earth magnets. The interlocking tiles are used extensively in construction, since besides being great aesthetic solution for a multitude of uses are easy to maintain. However, the low quality in the manufacture of this floor type interferes heavily in the choice of this material in construction sites works in general. By using the magnetic ionization offered by magnets neodymium in the water used in the manufacture of concrete, we will be raising quality of interlocking flooring high strength through the use of a non-polluting process, without the involvement of chemical additives. Beyond determine the guidelines and bases for the production of interlocking flooring quality, this project will bring results that enhance the production of this type of concrete in Maranhão, which would generate employment opportunities and income. For ease of application and maintenance, the use of this type of floor will increase the rate of employability of the workforce Maranhão, which encounters difficulties when it comes to qualifying. The research will assess the compressive strength of different specimens, and find the trace appropriate when the effects of past water by magnetic treatment may be able to meet the aforesaid purpose. For magnetization water, massive permanent neodymium magnets are used. We will make cylindrical specimens for the testing of Simple at 7, 28, 56, 120 and 240 days compression according to the standards techniques (NBR 05 739; ABNT, 1994). The material produced in this project present very low cost, which shows that it problematic streamlines the low quality of interlocking floors in Maranhão and optimizes service and costs at the construction site, increasing productivity without harming the environment. Keywords: Concrete, Interlocked Floors, Magnetical Treatment, Water. Acknowledgment: The authors thank Fundação de Amparo à Pesquisa do Estado do Maranhão – FAPEMA for their financial support. 294 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental Bearing and Abrasion Analysis of Concrete Specimen Produced by Waste Marble Dust and Waste Marble Particle Selim Cemalgil 1, Onur ONAT *2 1 Civil Engineering Department, Tunceli University, Tunceli, TURKEY. (E-mail: [email protected]) 2 Civil Engineering Department, Tunceli University, Tunceli, TURKEY. (E-mail: [email protected]) ABSTRACT The head goal of this paper is to present mechanical properties of concrete specimen produced by Waste Marble Dust used replaced by cement and Waste Marble Particles replaced by aggregate. Due to huge amount marble production, there is a huge amount materials are wasted every year to environment. The biggest challenge is to reuse waste materials in concrete in near future. Possibility of using marble waste was investigated in this paper and also to show the differences of mechanical and abrasion properties between marble dust replaced by cement and marble particles replaced by aggregate. Only compressive strength and abrasion resistance was investigated in this study. In this study two types of experiments were implemented on specimens. These are compressive strength and abrasion resistance tests. For this purpose three set concrete were casted. Number M0 set represents control specimen, number M1 set represents concrete specimens casted by Marble Aggregate and finally number M2 set represents concrete specimen contains marble dust as cement and marble aggregate as aggregate. Specimens were casted into 100x100x100 mm mold. Compression tests were done on the base of regulation number TS EN 12390-3. Abrasion resistance was investigated on the base of ASTM-C 944 regulation with rotating-cutter method. Experimental results were discussed and explained by suitable graphs. Keywords: Waste, marble, concrete, engineering properties, marble cement, marble aggregate 295 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental and Numerical Analysis of Flow around Circular Pier Oğuz ŞİMŞEK 1, M. Sami AKÖZ2, N. Göksu SOYDAN* 3 and Veysel GÜMÜŞ 4 1, 2,3 Authors’ Civil Engineering, Cukurova University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 4 Author’s Civil Engineering, Harran University, TURKEY. (E-mail: [email protected]) ABSTRACT Measurement of the three-dimensional turbulent flow field around a circular pier is complex due to separation and generation of multiple vortices. This topic has a great interests for researchers in recent years due to design of bridge piers and determine of scour holes. In this study, the characteri stics of open channel flow around a circular pier in a laboratory channel are investigated experimentally. The governing equations of the present three-dimensional turbulent flows are solved numerically by using ANSYS Fluent package program based on the Finite Volume Method for the flows having the same conditions with experiments. The volume of fluid (VOF) method is used to compute the free surface of the flow. Grid Convergence Index (GCI) is performed to examine the effect of the selected grid structure on the numerical results. In the numerical simulations, Standard k-ε, Renormalization Group k-ε and Realizable k-ε turbulence closure models are employed. The numerical results for the flow characteristics from the turbulence models are validated by using t he experimental data. Experimental validations of the numerical results show that computations by using the turbulence model are successful in predicting the flow characteristics around circular pier. Keywords: Circular Pier, Numerical Simulation, Grid Convergence Index, Volume of Fluid 296 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Structural Behavior of RC and PSC Concrete Members with High Strength Shear Reinforcement ByungKoo Jun* 1, Seong Jun Hong2, Jaeman Lee 3, Jung-Min Kim 4, Hye Sun Lim5, and Jung-Yoon Lee6 1, 2 Department of Global Construction Engineering, Sunkyunkwan University, Republic of Korea (E-mail: [email protected], [email protected]) 3, 4, 5, 6 Department of Civil. Architectural, and Environmental System Engineering, Sunkyunkwan University, Republic of Korea (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT The use of high-strength concrete is indispensable for high-rise reinforced and prestressed construction to ensure the sufficient strength of the structure. The effect of high-strength concrete can be significantly improved by the use of high-strength, large size reinforcing bars. In particular, footing beams or the beams of a concrete frame structure subjected to high lateral force are usually subjected to high shear force, and heavier shear reinforcement is needed. Recently, due to a lack of raw materials, the price of reinforcement has steadily increased. Accordingly, the demand for high strength steel reinforcement has significantly increased. For the purpose of adopting high strength shear reinforcement, the concrete members in which the reinforcement is employed need to be evaluated in terms of material properties, structural performance, and serviceability. In particular, when adopting a very high strength shear reinforcement, extensive cracks and deflection can occur in these members. Consequently, the evaluation needs to include ductility, fatigueresistance, shear and torsional resistance, anchoring, and seismic capacities. Although there are many studies regarding the behavior of concrete beams subjected to shear, only a limited number of studies on concrete beams regarding the yield strength of shear reinforcement are available. In this study, a total of eight concrete beam specimens incorporating high strength shear reinforcement were tested and the applicability of the high strength reinforcement was thus assessed. The experimental and analytical results indicate that the limitation on the yield strength of shear reinforcement in the design code is somewhat under-estimated and needs to be increased for high-strength concrete beams. Keywords: Shear reinforcement, High strength, Concrete beams, Diagonal crack width, Shear design. 297 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Soil Foundation Structure Interaction on Performance Based Seismic Design: A Case Study A. Abdelhamid* 1,2, B. Tiliouine 2 1 Structural Division, National Centre for Studies and Integrated Research on Building, ALGERIA. (E-mail: [email protected] ) 2 Laboratoire de Génie Sismique et de Dynamique des Structures, Ecole Nationale Polytechnique, ALGERIA. (E-mail: [email protected]) ABSTRACT Observations from past and recent earthquakes have shown that Soil Foundation Structure Interaction (SFSI) can greatly influence the overall performance of building structures. Nevertheless, little attention, if any, is usually given to SFSI effects on the dynamic behavior of structures despite the fact that their collapse is often due to soil foundation system failure and that SFSI is prescribed in performance based seismic design by various codes and agencies (e.g. Eurocode 8, IBC, FEMA 440, ATC 40…etc). Furthermore, neglecting kinematic interaction and foundation damping effects may lead to erroneous conclusions in the assessment of seismic performance of structures under strong ground motions. In this study, effects of kinematic soil structure interaction and foundation soil damping, on the performance based seismic design of a manufacturing plant of photovoltaic modules for solar power exploitation purposes, are investigated. This structure with plan dimensions (171m x 108m), is supported by a reinforced concrete slab founded at 1.5m depth over a soft soil. The plant is located in Algiers an area of high seismicity. A site-specific spectrum has been developed and used as the basic free field ground motion model. Pushover analyses based on nonlinear static procedures incorporating suggested improvements from FEMA 440 are used to estimate maximum displacement, capacity curve and hence the performance point. Issues concerning soils and structural nonlinearities are taken into consideration in the methodology. Results obtained from the present study show, among others, the importance of slab averaging and foundation damping effects on the demand spectrum: in particular, the resulting Foundation Input Motion is found to differ significantly from the free field motion. Effect of embedment has been found insignificant in the present study. It also is concluded that safer and more economical building design can be achieved by properly accounting for the SFSI effects. Keywords: Case Study, Demand Spectrum, Seismic Design, Soil Foundation Structure Interaction, Structural Performance. 298 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Simple Structural Evaluation Technique for Building Components Nacerddine Djermane* 1, N. Lahbari 2 1 Department of mechanical engineering, Sciences and Applied Science, Oum el bouaghi University, ALGERIA. ([email protected]) ABSTRACT This research has explored the applicability of a simple structural evaluation technique for building components such as masonry elements (load bearing walls, columns) or concrete elements (sl abs and beams) based on the identification of their dynamic properties. It includes a state – of – the art review, a parametrical sensitivity study, an experimental work under laboratory conditions and a study of implementing dynamic testing for different purposes. A finite element model was developed to simulate the full load – unload process and to obtain the natural frequencies after every load step. The non-linear parameters, like tension stiffening or constitutive equations of materials are fundamental when damage models are studied. The modification of strain modulus or contour conditions due to loading influenced seriously the dynamic properties of evaluated building components. Parameters such as dead load, boundary conditions, strain modulus, reinfo rcement ratio or geometry properties have a direct influence in the dynamic response of the structural component. Stiffness degradation (due to flexural cracking) in RC beams produced an important reduction of the frequencies (reaching 40%). Prestressed and reinforced concrete slab can be studied by two different test lay-outs: o a deployment of multiple sensors with identification of frequencies and modal shapes; o a reduced version using only one sensor and measuring only natural frequencies. Finally, this study has permitted to conclude that a combined implementation of a simple dynamic testing and numerical modeling is able to characterize the current structural conditions of single concrete or masonry building elements such as concrete beams, concrete slab s, masonry walls or stone piers. Keywords: Concrete, Dynamic testing, building, Sensor technology, frequency 299 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Curing Conditions on Fiber Concrete Roads Karakurt. C 1, Bayazıt. Y*2, Kahveci.K 3 1, 2 Civil Engineering Department, Bilecik Seyh Edebali University, TURKEY. 3 Civil Engineering Department, Anadolu University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Conrete roads are significant to heavily vehicles loads. As known there are lots of heavily vehicle in our country. According to experiments, concrete roads more strength than other pavement types. Thus, concrete roads should be develop in our country. In this study it is researhed that how effects of curing condition of concrete roads. In experimental study, it is prepared three type of concrete as reference (non-fiber), polypropylene fiber and steel fiber. Firstly, to supply site conditions con crete is prepared out of the laboratory and the concrete was put in formwork has shape 1mx1mx0.15m. Beside, the same concrete mixes have been put in cubic specimens 0.15mx0.15mx0.15m on laboratory conditions. Taken core drilled has 10 cm diameter from formwork which out of the laboratory and hardened concrete experiments have been done on the core drilled specimens and cubic specimens. Surface hardness with Scmitdt hammer, pulse velocity, compressive strength, concrete density are tested on the examples. It will be determined performance of concrete road mixes relations with fiber types and curing conditions from the experimental studies. Mechanical properties of the specimens are out of the laboratory and on the laboratory conditions are compared. Keywords: Concrete roads, Core drilling, Curing conditions, Poylpropylene fiber, Steel fiber 300 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Supplementary Cementing Materials on Fresh Properties and Stability of Self Consolidating Rubberized Concrete Mohamed K. Ismail 1 and Assem A. A. Hassan 1* 1 Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John’s, Newfoundland, Canada, A1B3X5 (E-mail:[email protected],[email protected]) ABSTRACT This study was conducted to study the development of self-consolidating rubberized concrete (SCRC) with enhanced fresh properties and stability. The study particularly aimed to maximize the percentage of used crumb rubber (CR) in SCRC while minimizing the reduction of the strength and stability of the developed mixtures. The experimental test para meters included percentage of CR (0-40% by volume of sand) and different supplementary cementing materials (SCMs) (fly ash, slag, and metakaolin). The performance of the developed SCRC was evaluated based on the results of compressive strength, flowability, passing ability, high-range water-reducer admixture (HRWRA) demand, coarse aggregate segregation, and the distribution of CR in the mixture. The results indicated that mixtures with 550 kg/m 3 binder content showed acceptable strength, fresh properties, and stability with up to 20% replacement of CR. Compared to the other tested SCMs, the addition of metakaolin (MK) significantly improved the mixture viscosity and particle suspension/distribution, which allowed up to 30% CR to be used with acceptable compr essive strength (40 MPa) and without any sign of segregation. Keywords: crumb rubber, fresh properties, metakaolin, self-consolidating concrete, stability. 301 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Mechanical Properties of Self-Consolidating Rubberized Concrete with Different Supplementary Cementing Materials Mohamed K. Ismail 1, Mayra T. de Grazia1, and Assem A. A. Hassan 1* 1 Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John’s, Newfoundland, Canada, A1B3X5 (E-mail:[email protected], [email protected], [email protected]) ABSTRACT This paper investigates the mechanical properties of self-consolidating rubberized concrete (SCRC) mixtures with high percentages of crumb rubber (CR). The effect of metakaolin (MK) compared to other supplementary cementing materials (SCMs) on enhancing the mechanical properties and stability of SCRC mixtures was highlighted in this research. The variables were percentage of CR (0-40% by volume of sand), type of SCM (fly ash, slag, and metakaolin). The mechanical properties of the tested mixtures were investigated based on their compressive strength, flexural strength (FS), splitting tensile strength (STS), and modulus of elasticity (ME). The results indicated that increasing the CR replacement from 0% to 40% decreased the 28-day compressive strength, STS, FS, and ME by 59.25%, 52.41%, 35%, and 46.1%. However, all developed mixtures exceeded the minimum strength for structural applications (17 MPa).The results also indicated that using MK has the most significant effect on improving the mixture stability and particle suspension, which facilitated the development of SCRC mixtures with a high percentage of CR (30%) and with acceptable stability/strength and with a density of less than 2100 kg/m3. Keywords: crumb rubber, fresh properties, supplementary cementing materials mechanical 302 properties, self-consolidating concrete, ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Seismic Fragility of Weir Structures due to Sliding Effect Woo Young Jung 1, Ki Young Kim2 and Bu Seog Ju* 3 1 Department of Civil Engineering, Gangneung-Wonju National University, Korea (E-mail: [email protected]) 2 3 Infrastructure Research Center, K-water Institute, Korea (E-mail: [email protected]) Institute for Disaster Prevention, Gangneung-Wonju National University, Korea (E-mail: [email protected]) ABSTRACT The damage or collapse of the hydraulic systems can comprise a significant proportion of the economic loss in upstream and downstream area and the failure of the weir structures can cause loss of life and the serious flooding problem in the area during a seismic event. Consequently, dams or weir structures as hydraulic systems must remain functional and operational during and after an earthquake. In recent year, in order to mitigate the risk or secure the safety of the hydraulic systems, the Probabilistic Seismic Risk Assessment (PSRA) has been issued as a key area of the research. The primary objective of this paper was to evaluate the seismic fragility of weir structures by incorporating nonlinear Finite Element (FE) model for the contact interfaces among weir-mass concrete-soil foundation in the weir structure. Gangjeong-Goryeon weir, located in Daegu Metropolitan City in Southeastern part of Korea was selected in this study. The seismic fragility of the weir structure corresponding to the sliding Limit State 13 mm (LS I) and 153 mm (LS II) was determined from multiple nonlinear time-history analyses based on Monte-Carol simulation accounting for the uncertainties such as material nonlinearity and ground motions with respect to near field faults and far field faults. The results showed that the sliding failure of the weir structure corresponding to LS I started from 0.1 g, but the weir system under LS II had no failure up to 0.4g. Besides, in the case of LS I, the weir subjected to near field faults was more fragile than that subjected to far field faults, whereas the result corresponding to LS II was reversed. Keywords: Contact, Earthquake, Fragility, PSRA, Weir Acknowledgment: This Research was supported by a grant (13SCIPA01) from Smart Civil Infrastructure Research Program funded by Ministry of Land, Infrastructure and Transport (MOLIT) of Korea government and Korea Agency for Infrastructure Technology Advancement (KAIA). 303 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison of Static Pushover and Nonlinear Dynamic Analyses of Reinforced Concrete Buildings Burak Yön* 1, Mehmet Emin Öncü 2 and Yusuf Calayır 3 1, 2 Civil Engineering, Dicle University, TURKEY. (E-mail: [email protected], [email protected]) 3 Civil Engineering, Fırat University, TURKEY. (E-mail: [email protected]) ABSTRACT In this paper, static pushover analysis and nonlinear dynamic time history analyses of reinforced concrete buildings were compared by using the distributed plastic hinge approach which includes material and geometric nonlinearity of the structural members. For numerical study, a sample reinforced concrete frame building was selected and pushover analysis and nonlinear dynamic time history analyses were performed. For nonlinear analyses, three earthquake acceleration records were selected and adjusted to be compatible with the design spectrum defined in TSC by considering various effective ground accelerations with soil classes. As result of analyses, interstory drifts, capacity curve and maximum responses of the building were obtained. These analyses results were compared each other and evaluated. Keywords: Seismic zones, local site conditions; distributed plastic hinge; time history analysis. Acknowledgment: The authors thank to Seismosoft for providing free academic license for SeismoStruct and SeismoArtif software. 304 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Parametric Study on The Response of Cooling Towers Experiencing Various Circumferential Distribution of Wind Loading Ali İhsan Karakaş* 1, Korhan Ozgan 2 and Ayse T. Daloğlu 3 1, 2, 3 Civil Engineering Dept., Karadeniz Technical University, Trabzon, Turkey. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Cooling towers are the essential components of thermal nuclear power stations and industrial power plants. They are huge thin shell structures with commonly complex double curvature hyperbolic geometry. Cooling towers may be subjected to a variety of loading conditions such as d ead, wind, earthquake, temperature and construction loads. In the present study only wind load is considered. The wind pressure is sensitive to the vertical variation of the wind for most structure and also to the circumferential variation which is peculiar to cylindrical bodies such as cooling towers. The circumferential variation is strongly dependent on the roughness properties of the shell wall surface of the towers. The circumferential distribution curves of wind pressure are determined by laboratory a nd field measurements as a function of roughness parameter k/a in which k is the height of the rib and a is the mean distance between ribs measured at about 1/3 of the height of the tower. The maximum amplitude of the axial tension force in the shell wall along the meridian is strongly influenced by the circumferential distribution of the applied wind pressure which is a function of the surface roughness. Hence the required reinforcing steel is very sensitive to distribution curve considered. Therefore the design of the ribs is an important issue for a pure cooling tower design. For this purpose a computing tool coded in MATLAB employing SAP2000 OAPI (Open Application Programming Interface) functions is used to evaluate numerically the influence of circumfe rential wind load distribution curves for various k/a ratios on the responses of a hyperbolic cooling tower with supporting columns fixed at the base. The complex realistic wind pressure distributions are represented satisfactorily by the coded program as distributed pressure loads computed at thousand points of the cooling tower wall. The pressure values suggested by VGB design code for various k/a ratios are considered. Keywords: Cooling tower, wind load, Open Application Programming Interface, finite element analysis. 305 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Seismic Behavior Dependence on The Geometrical Characteristics of Cooling Towers Ali İhsan Karakaş* 1, Korhan Ozgan 2 and Ayse T. Daloğlu 3 1, 2, 3 Civil Engineering Dept., Karadeniz Technical University, Trabzon, Turkey. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Cooling towers are thin walled slender structures employed in thermal and nuclear power stations to reduce cooling-circuit water. They may be subjected to a variety of loading conditions such as self weight, wind load, earthquake load, temperature, construction and settlement loads. Earthquake loads constitutes the main loading for the design of cooling towers constructed around earthquake -prone areas. Therefore, seismic analyses of cooling tower structures are significant in the design process. The loads applied by a design earthquake to the shell and components of a cooling tower can be determined by the seismic dynamic analysis methods. In the present study a comprehensive parametric study is carried out to investigate the influence of geometrical parameters such as meridional curvature, thickness and throat level on the seismic response of cooling towers supported by V-shaped columns fixed at the base by employing time history analyses. For this purpose a computer program is developed in MATLAB to be able to model cooling towers parametrically by providing data flo w between MATLAB and SAP2000 via Open Application Programming Interface (OAPI) feature of SAP2000. The developed application provides an easy and fast way to model cooling towers parametrically. As a result of this parametric work it can be concluded that earthquake-induced stresses and displacements are considerable sensitive to geometrical properties of cooling towers. Results are presented in tabular and graphical format. Keywords: Cooling tower, seismic analysis, Open Application Programming Interface, finite element analysis. 306 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Strength Performance of Pervious Concrete Subjected to Acid Rain Christian R. Orozco* 1, Mark Daniel M. Ibanez 2 and Patrick Joseph F. Robles 3 1, 2, 3 Institute of Civil Engineering, University of the Philippines Diliman, PHILIPPINES (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Acid rain has been an issue of widespread concern in Asia as it can greatly contribute to damage of various infrastructures. Pervious concrete, a new sustainable pavement construction material that allows water to directly pass through it, is one of those infrastructures that may be exposed to acid rain attack. Therefore, this study aims to investigate the strength performance of pervious concrete when exposed to acid rain. A total of 162 plain pervious cylinder concrete specimens with varying percent fine aggregates (5%, 10%, 15%) and water-to-cement ratio (0.30, 0.35, 0.40) were prepared and cured in the laboratory for 28 days. After 28-day curing, specimens were immersed for 30 days in a control solution with neutral pH and synthetic acid rain solution with varying pH (4.0, 4.5, 5.0 and 5.5). The specimens were tested for both permeability and compressive strength. Results of the experimental study showed that as the percent fine aggregate increases, permeability decreases and compressive strength increases. The highest dfference in the compressive strength (2.38 MPa) between the specimens immersed in the acid rain solutions and the control solution was observed to occur at solution pH of 4.0. Statistical analyses showed that the compressive strength of specimens immersed at pH 4.0 solution is significantly lower (p<0.05) compared to the compressive strength of specimens immersed in higher pH (5.0 and 5.5), suggesting the effect of acidity to compressvive strength of pervious concrete. Keywords: Acid rain, Compressive strength, Permeability, Pervious concrete Acknowledgment: The authors would like to thank the University of the Philippines Diliman Engineering Research for Development Foundation, Inc. (ERDFI) and College of Engineering for funding this research through the Faculty Research Dissemination Grant (FRDG). 307 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Utilization through Immobilization of Dredged Sediment using Alkali-Activated Slag Jae-Ho Shim* 1 and Joo-Yang Park2 1, 2 Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul, Republic of Korea. (E-mail: [email protected], [email protected]) ABSTRACT The smaller than 75 μm size of dredged sediment has be just in landfill, has not been used well for useful purpose because the smaller size of dredged sediment is too small to recycle, and is difficult to reduce the contaminants from strong ability of fine sediment to a bsorb contaminants. This paper focuses on the use of 10~30 μm size of dredged sediment from the coast of Gijang, Busan, South Korea by solidification/stabilization (S/S) with the alkali-activated slag (AAS). The ground granulated blastfurnace slag (GGBFS) is used as the binder that is an excellent alternative to the cement concrete. GGBFS occurs as a by-product of the production of iron from a blast furnace, so this study is the use two types of waste are immobilized. The S/S procedure relies on the alkali-activation of GGBFS-based systems with fine dredged sediment. The NaOH solution was used as an alkaline activator with various concentration (2, 4, 6, and 8% Na2O in the AAS matrix). The specimens were made according to the ASTM C 305 standards, the mechanical (flexural/compressive) strength tests were carried out according to the ASTM C 348 and 349. The S/S with slag was studied through the leaching characteristics and microstructure characteristics of samples were measured. The results of the toxicity characteristic leaching procedure (TCLP) test on 3 days samples confirmed that heavy metals were immobilized in AAS matrix as Not Detected (ND) of Cr, Cu, Cd, and Pb. The flexural/compressive strength values was related to concentration of Na 2O. The immobilized fine sediment in AAS can be utilized for some practical purposes such as breakwater and blocks that can be used in the construction sector depending on the concentration of Na 2O. Keywords: Alkali-activation, Dredged sediment, GGBFS, Immobilization Acknowledgment: This research was supported by a grant (code 13IFIP-B065893-01) from Industrial Facilities & Infrastructure Research Program funded by Ministry of Land, Infrastructure and Transport of Korean government. 308 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Importance of the Validation of Numerical Models with the Experimental Modal Analysis Fuat Aras* 1 1 Civil Engineering Department, Istanbul Medeniyet University, TURKEY. (E-mail: [email protected]) ABSTRACT Numerical models are frequently constructed to investigate the civil engineering problems related to design and assessment issues. Inherent characteristics of a struct ure are hidden in the dynamic properties of it since these properties are independent from external effects such as loading and they are related to the structure’s stiffness, mass and support conditions which govern the structural behavior. In that respect the modal properties such as modal periods and mode shapes are the key parameters to check the performance of a numerical model for a structure since the height of the structure, number of floors, structural elements and their configurations can give initial idea for the prediction of modal characteristics for a new design project. However there are always some uncertainties in modeling stemming from generalizations, assumptions and ignorance. Discrepancies between the numerical model and real conditions can be so huge that the numerical model cannot predict the real behavior of the structure. This case may valid especially for the modeling of existing structures with complicated structural system, not uniform material properties, complicated soil structur e interaction, undetermined boundary condition, unknown and hidden damages and other effects due to the old age of the structure. Under these conditions the numerical model should be validated. At this point, experimental modal analysis fills a gap by obtaining dynamic properties of real structures and enabling to adjust the suspicious parameters in the numerical model with dynamic identification procedures. In this study, the application of experimental modal analysis over two existing structures (a historical palace and a reinforced concrete building) is explained. The numerical models, before and after the dynamic identification, are presented for both structures. The differences are discussed and the importance of experimental modal analysis is underlined. Keywords: Dynamic analysis, Experimental modal analysis, Numerical modeling. Acknowledgment: The authors thank Istanbul Medeniyet University, Scientific Research Project Funding for the financial support [Project number: FUY-2014-448]. 309 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Assessing the seismic performance of reinforcement coupler systems in Turkey K. Taskin* 1 and K.Peker 2 1 2 Anadolu University, Engineering Faculty,Civil Engineering Department, Iki Eylul Campus, 26555 Eskişehir, TURKEY. (E-mail: [email protected]) ERDEMLI Engineering and Consulting Co. Ltd., Spor Caddesi , Babaefendi Sokak , Ufuk Palas 3/1, 34357, Beşiktaş / İstanbul, TURKEY. (E-mail: [email protected]) ABSTRACT Use of mechanical connection systems in reinforced concrete has become increasingly prevalent in Turkey. Mechanical connectors are an alternative to lap and welded splices, and many are capable of developing the full strength of the connected reinforcing bars. There are many advantages for using mechanical connector systems over conventional reinforcing bar lapping. Such examples are overcoming reinforcement congestion problems and convenience when installing precast constru ction members at sites. The design of reinforced concrete structures is based on several basic assumptions and tenants. Among these fundamental concepts is that reinforcement will be provided to resist any tension that may be present in themember. Moreover, it is assumed that the reinforcement is anchored – that is, developed -- and continuous in the regions where it is shown by analysis to be required. International literature reporting on reinforcing mechanical connection s ystem testing protocols and experimental studies conducted in the United States, Japan, and Europe were assessed to provide recommendations for an upcoming review of the Turkey reinforced concrete design standard. Both static and seismic conditions, in terms of their relevance in the Tukish context, were considered in the literature review. At conclusion of this exercise, new standard criteria for the use of mechanical connection systems in Turkey were proposed, and a range of couplers commonly used in Turkey were subjected to preliminary tests in accordance with the proposed standard criteria. Testing indicated that the couplers performed in a satisfactory manner. Keywords:Aassessment, experimental,lap splice, mechanical coupler,Reinforced concrete. Acknowledgment: The authors thank Bar-Us, Lenton, Sera Yapı A.Ş. 310 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Design Factors and Finite Element Modeling of Cubic Type Voids in RC Slabs K. Taskin* 1 and K.Peker 2 1 2 Anadolu University, Engineering Faculty,Civil Engineering Department, Iki Eylul Campus, 26555 Eskişehir, TURKEY. (E-mail: [email protected]) ERDEMLI Engineering and Consulting Co. Ltd., Spor Caddesi , Babaefendi Sokak , Ufuk Palas 3/1, 34357, Beşiktaş / İstanbul, TURKEY. (E-mail: [email protected]) ABSTRACT The behaviors of biaxial hollow slab are influenced by the shape of void and cage. Long span flat slab systems with internal void formers have been used in Europe for a decade now. Nautilus® is the brand name of successful system, recently introduced in Turkey. It’s a bi-axial reinforced concrete fat slab system, with a grid of internal void formers. This paper examines a two -way, reinforced concrete slab with plastic voids construction in comparison to traditional flat plate re inforced concrete slab construction. The design process for plastic voided slabs is directly compared with traditional two -way flat plate reinforced concrete slabs through a design comparison of typical bays of 6m by 6m, 8m by 8m’ 10m by 10m, 12m by 12m, 14m by 14m, 16m by 16m, 6m by 9m, 6m by 12m, 8m by 12m, 8m by 16m, 10m by 15m, 10m by 20m, 12m by 18m, 12m by 24m, 14m by 21m and 16m by 24m. In order to understand the structural mechanism of the cubic spherical voided slabs, analysis are performed to compare of this new type of floor with a typical flat, solid concrete flat. A 3D solid slab and a cubic voided slab were constructed in SAP2000 with all the same dimensions and as two -way spanning floor systems. The solid slab and voided slab models were analyzed static response under a dead load 0.200 t/m2 and five different live load (0.200 t/m2, 0.350 t/m 2, 0.500 t/m2, 0.750 t/m2 and 1.000 t/m2). The traditional slab design process follows the TS 500 (Requirements for Design and Construction of Reinforced Concrete Structures-Turkish Standard), EN-1992-2004, ACI-318, 2011(Building Code Requirements for Structural Concrete) and CEB-FIB, 1990. The SAP2000 results show that the maximum moments, shear forces and in-plane stresses in the cubic voided slab floor 30-40% less than that of the solid concrete slab under the same conditions. Keywords:Aassessment, experimental,lap splice, mechanical coupler,Reinforced concrete. Acknowledgment: The authors thank Bar-Us, Lenton, Sera Yapı A.Ş. 311 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 THE INFLUENCE OF FIBERS AND MINERAL ADDITIVES ON SELF COMPACTING CONCRETE HADDADOU Naima1, 2, CHAID Rabah2, ADJOU Naima1& BOUZOUALEGH Malik1 [email protected] 1. National Center of Studies and Integrated Research on Building Engineering (CNERIB), Cité Nouvelle ElMokrani, Souidania, Algiers, Algeria 2. Research Unit: Materials, Processes and Environment (UR/MPE), University Boumerdes, Cité Frantz Fanon, 35000 Boumerdes, Algeria ABSTRACT Time, cost and quality are three important factors that play a critical role in the construction industry. Any progress or development that improves these factors is welcomed by civil engineers. One of the major environmental concerns is recycling waste materials. Marble processing plants and kaolin quarries produce millions of tons of waste in powder form every year. Having a considerable high degree of fineness in comparison to cement, these materials may be used as filler for the production of selfcompacting concrete which offers several economical and technical benefits. To extend its possibilities, the addition of fibers can improve a marginal improvement in the ultimate strength, but the critical problem is to accomplish uniform dispersion of fibers. Fibers act as a bridge by retarding crack’s propagation, and develop several characteristics and properties of self-compacting concrete. For this purpose, several self-compacting concretes were prepared by using three types of fibers made of steel, polypropylene, and glass, and three different types of mineral additions (marble powder, metakaolin and limestone powder). The water to cement ratio was held constant at 0.34 and fibers were used in combination, keeping the total fiber content constant at 60 kg/m3. Slump flow time and diameter, L-Box and stability were performed to assess the fresh properties of the concrete. Compressive strength, splitting tensile strength and ultrasonic pulse velocity of the concrete were determined for the hardened properties. Noteworthy performances were generally obtained, particularly for the self-compacting concretes prepared with steel fibers in association with polypropylene fiber and marble powder as mineral addition. Key-Words: self-compacting concrete, mineral admixtures, fibers, workability, hardened properties. 312 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Direction Effects of Travelling Waves on Nonlinear Seismic Response of Arch Dams Mehmet AKKÖSE 1 1 Department of Civil Engineering, Karadeniz Technical University, TURKEY (E-mail: [email protected]) ABSTRACT In many cases the size of a dam may be close to the length of the seismic waves that would arrive to the dam site in the event of an earthquake. As a consequence, when seismic waves reach on a large dam, the excitation of the dam-foundation rock interface is not uniform. Different points along the interface are under the effects of different foundation acceleration values at the same time. In other words, the seismic waves travel along the dam-foundation rock interface. The importance of this effect depends on the dam size, the length of the seismic waves and its direction of propagation but it seems clear that assuming a uniform excitation along the dam-foundation rock interface may lead to erroneous consequences. The objective of this study is to investigate direction effects of travelling waves on nonlinear seismic response of arch dams. The finite element idealization of arch dam-water-foundation rock system is presented in Fig. 1. The figure also depicts directions of the travelling waves on the arch dam-reservoir-foundation rock interaction system. It is evident that the seismic waves can reach on the dam site from any direction. In this study, it was considered that the seismic waves arrive to the dam site with several different angles (=0, 30o, 60o, 90o). The results obtained from non-linear analyses of the arch dam for the different angles are compared with each other. 313 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EFFECTS OF MIX AND WATER/CEMENT RATIO ON COMPRESSIVE STRENGTH AND MODULUS OF ELASTICITY OF LATERIZED CONCRETE Olanrewaju Deborah O*1. , Akinpelu A.A2 1,2 Department of Building Technology, Lagos State Polytechnic, Ikorodu, Lagos, Nigeria. (E-mail; [email protected]) ABSTRACT This paper reports the result of laboratory study, investigating the effects of mix and water/cement Ratio on compressive strength and modulus of Elasticity of laterized concrete. The research is intended to contribute to sustainable construction of low cost housing and development in Nigeria because of abundance of readymade laterite in the region. The test specimens were made with sieved samples of selected grain sizes of lateritic soil used as fine aggregate in conventional concrete. Batching of the specimens was by weight. Three mix ratios of (1:1.5:3), (1:2:4) and (1:3:6) were used. Water/cement ratio of 0.6,0.65,0.75and0.85 were used for each of the mix ratios. The specimens of size 150mm x 150mm cylindrical shape were tested at curing ages of 28 days using ELE 2000 manually operated hydraulic compression machine armed with dial gauges to determine both the longitudinal and lateral extensions in the specimens. The results showed that the richer the mix, the higher the compressive strength and modulus of Elasticity. It was also found that water/cement ratio have significant effects on both properties of laterized concrete. The results can be used to estimate the structural behaviour and integrity of laterized concrete component. Keywords: Concrete, Modulus of Elasticity, Laterized Concrete, Compressive Strength, Lateritic soil. Acknowledgement: The authors would like to express their appreciation to Dr Kolapo Olusola and the entire member of Building Department of Obafemi Awolowo University for providing us with insight and equipments 314 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Deterministic and Probabilistic Analysis of the Fire Resistance of the Technology Support Structures in NPP J. Králik * 1 and J. Králik, jr. 2 1, Department of Structural Mechanics, FCE STU Bratislava, SLOVAKIA. (E-mail: [email protected]) 3 Department of Structures, FA STU Bratislava, SLOVAKIA. (E-mail: [email protected]) ABSTRACT This paper presents the methodology of the reliability analysis of the fire resistance of the s teel structure of the cable way in nuclear power plants (NPP). The deterministic and probability analysis of the fire resistance of the steel structures are considered. The executed fire resistance analysis of the steel structures is investigated as the influence of temperature, permanent and variable loads. The Response Surface Method (RSM) for the nonlinear probabilistic analysis of the fire structure reliability was used on program ANSYS. In consequence of the economic and life lost due to fire accident the new regulation was created in European countries. The objective of this paper is to describe a performance based more realistic and credible approach to the analysis of structural safety in case of fire, which takes also account of structural models, which should be as realistic as possible. This paper deals with the possibility of the deterministic and probabilistic analysis of the reliability of the cable way support structures depending on variability of the load, material and model characteristics. The analysis of the fire resistance of four types of cable way structures by deterministic as well as probabilistic calculation is shown in this paper. The 49 simulations using approximate method RSM for four cases were calculated in the real time on PC ( max CPU=728sec). The nonlinear solution was running in max 191 steps. The output quantities were determined from 10 6 MONTE CARLO simulations. The probabilistic method shows that the probability of the failure of all structures is less than target probability p d = 7,23.10 -5. However, the probabilistic calculation provides us with possibility of sensibility analysis, on the base of which the extreme load conditions on the cable way structures can be identified or also modified. Keywords: Fire, nonlinearity, plasticity, probability, cable way, NPP, RSM, ANSYS Acknowledgment: The project was realized with the financial support of the Grant Agency of the Slovak Republic (VEGA). The project registration number is VEGA 1/1039/12. 315 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Risk Assessment of NPP Safety in Slovakia J.Králik * 1 1 Department of structural mechanics, FCE SUT Bratislava, SLOVAKIA. (E-mail: [email protected]) ABSTRACT This paper gives the results of the risk-based safety analysis of the nuclear power plants in Slovakia. The probabilistic assessment of NPP structures for Probabilistic Safety Analysis (PSA) level 2 of VVER 440/213 in the case of the extreme external even without the earthquake is presented. On the base of the meteorological monitoring of the locality the extreme load parameters were defined for the return period 10 4 years using the MONTE CARLO simulations. There is showed summary of calculation models and calculation methods for the probability analysis of the structural resistance. The general purpose of the probabilistic analysis of the NPP structure resistance was to define the critical places of the structure elements and to estimate the structural collapse. The numeric al simulations on the base of the LHS method were realized in the system ANSYS and FReET . The International Atomic Energy Agency set up a program to give guidance to its member states on the many aspects of the safety of nuclear power reactors. The risk of the NPP performance from the point of the safety must be calculated by consideration of the impact of the all effects during plant operation. The probabilistic safety analysis (PSA) is one from the effective methods to analyze the safety and reliability of the NPP. This paper proposed the methodology of the PSA 2 level analysis of the NPP hermetic structures penetration under accident events. The general purpose of the probabilistic analysis of the containment integrity was to define the critical places of the structure elements and to estimate the structural collapse. The uncertainties of the loads level (longtime temperature and dead loads), the material properties (concrete cracking and crushing, reinforcement, and liner) and other influences following the inaccuracy of the calculated model and numerical methods. The critical steel segment was the reactor hermetic door with failure pression pu.0,95=839kPa (95% failure probability). The critical concrete structures were the walls of the rooms A525 and A526 under steam generator box. Their failure pressure is equal to pu.0,95= 486kPa (95% failure probability). Keywords: Risk, Safety, Reliability, Probability, Nonlinearity, Nuclear Power Plants. Acknowledgment: The project was realized with the financial support of the Grant Agency of the Slovak Republic (VEGA). The project registration number is VEGA 1/1039/12. 316 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Predicting the Performance of Roadheaders from the Needle Penetration Resistance S. Kahraman* 1, and A. S. Aloğlu 2 1 Mining Engineering, Hacettepe University, TURKEY. ([email protected]) 2 CİNER Group, TURKEY. ([email protected]) ABSTRACT Roadheaders have been widely used in the excavation of soft to medium strength rocks in tunneling and mine developments for about 50 years. They are very flexible and can be used for excavating the openings with different size and shape. The demand for tunnels and underground spaces has been increasing especially in developed and developing countries. Having some prior knowledge of the potential performance of a selected roadheader is very important for the planning and cost estimation purposes in tunnel projects. Several researchers have suggested some performance prediction models for roadheaders. These models generally include direct testing methods. The aim of this study is to investigate the predictability of roadheader performance from the needle penetration test which is a simple and practical test, and can easily be applied in the field. The performance measurements of Dosco Mk-2B roadheader were carried out during roadway excavations in Çayırhan Coal Mine (Beypazarı/Ankara). The cutting times of the machine were recorded at different locations. The volume of the material cut for each location was calculated by using the sectional area of cut and the depth of cut. Then, the net cutting rate (NCR) values were calculated by dividing the volume of the material cut by cutting time. The needle penetration tests were also carried out at the tunnel faces during performance measurements and the needle penetration resistance (NPR) values were calculated. The NCR and NPR values evaluated using regression analysis and a relation having a good correlation coefficient was found between the two parameters. The validation of the derived equation was checked by the t–test, the F-test. Concluding remark is that the derived model is significant and can be practically used for the estimation of the NCR of roadheaders for the similar formations and conditions. Keywords: Needle penetration resistance, Performance prediction, Roadheaders. Acknowledgment: The authors thank TUBITAK (The Scientific and Technical Research Council of Turkey) for the support of the project (Project No. 114M836). 317 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Analytical evaluation of thermal expansion of steel construction in buildings using Debye model A.Yamçicier Department of Physics, Faculty of Arts and Sciences, Gaziosmanpaşa University, Tokat, Turkey (E-mail:[email protected]) ABSTRACT It is well known that the steel construction is widely used in modern buildings because of its high tensile strength and low cost. Notice that steel materials have thermal expansion which is the tendency of matter to change in volume depending on a temperature variation through the heat transfer. Therefore, the steel thermal expansion should be considered by civil engineers in junction points of buildings. In this study using Debye model, efficient algorithm is presented for the accurate calculation of the thermal expansion of steel depending on temperature. Notice that the Debye model plays a central role in the study of many problems arising in solids. Keywords: Steel construction, Thermal expansion, Heat capacity, Debye model. 318 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Removal of Zinc via chlorination roasting from steelmaking byproduct I. Jaafar1, A. Griffths2 1 School of Liberal & Fundamental Knowledge, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia (Email : [email protected]) 2 School of Engineering, Cardiff University, Queen’s Building, The Parade, Cardiff CF24 3AA, United Kingdom ABSTRACT Iron and steel production generates significant quantities of solid wastes in the form of dusts and sludge and generally showing an increasing generation trend year on year. The recycling and utilisation of these byproducts has long been promoted in the industry. Due to the recent drive in improving environmental regulations, these wastes must be treated safely or recycled completely. Zinc is the element that causes the most problem in treating Basic Oxygen Steelmaking (BOS) dusts and also hinders the direct recycling of dust back into steelmaking furnaces. Chlorination is the process by which metal chlorides are obtained by dry methods. The process is applied to ores and concentrates; to isolate the metal values or convert them into a more amenable form. In this study, chlorination roasting by means of pyrometallurgical extraction was conducted towards BOS byproduct. Operational parameters such as roasting temperature, roasting time, chemical stoichiometry and surface area were applied. It is possible to remove >90% Zinc from the BOS byproduct, thus makes it possible to be reused in the steelmaking production route or safe disposal. Keywords:. Basic Oxygen Steelmaking (BOS), Chlorination, Extraction, Pyrometallurgy, Zinc Acknowledgment: The authors would like to thank Universiti Malaysia Terengganu and TATA Steel , for their financial support. 319 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Stabilization of clayey soil by waste steel pieces Zuheir KARABASH1,2, Ali Fırat ÇABALAR1 1 University of Gaziantep, Department of Civil Engineering, 27310, Gaziantep, Turkey 2 University of Mosul, College of Engineering, Mosul, Iraq ([email protected], [email protected]) ABSTRACT The metal industry produces substantial amounts of the waste steel which have fairly engineering properties and the disposal of these materials have financial and environmental problems. The objective of the present study is to investigate the applicability of these waste materials in the soil stabilization and their effects on the some geotechnical properties of clayey soil. A series of the unconfined compression and modified compaction tests were conducted during the experimental work. The amounts of the waste steel pieces used were 0%, 5%, 10%, 15%, and 20% by the dry weight of the samples. The results showed that as the percentages of the waste steel pieces content increases in the mixture the optimum moisture content decrease and the maximum dry unit weight increase. Generally, a significant modification in the unconfined compression strength was observed as the amount of the waste steel content increase until 10% and then decrease. Keywords: Clay, waste steel pieces, compaction, UCS. 320 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Development of Fragility Curves for Self-Supporting Trussed Towers in the Philippines Considering Severe Wind Loads Diocel Harold M. Aquino* 1, Jaime Y. Hernandez 2, Jr., Edgar Allan D. Robles3 1, 2, 3 Institute of Civil Engineering, University of the Philippines Diliman, PHILIPPINES. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT On the average, eight or nine tropical storms make landfall in the Philippines every year, having severe winds that cause damage and/or destruction to structures and other prope rties. Among the structures susceptible to the effect of severe winds are the self-supporting trussed towers. This paper aims to evaluate the fragility of self-supporting trussed towers to severe winds. Models of various configurations and sizes for these trussed towers were developed and analyzed for wind speeds ranging from 200 kph to 300 kph, in increments of 10 kph, considering different wind directions. Percentage of failed members were recorded and tallied against damage states. Three d amage states were defined: no damage, slight (>10% damage), and complete destruction – the state that renders the tower irreparable. Self-supporting trussed towers were found to be vulnerable to progressive failure, wherein failure of a member results to an instant redistribution of loads, which then leads to failure of more members. Because of this, fragility curves developed for slight damage is almost coincident with that for complete destruction. The towers were found assume a state of complete destruction at wind spe eds greater than 260 kph with 100% probability. Keywords: Fragility, Towers, Trusses, Wind. Acknowledgment: The authors thank the Department of Science and Technology (DOST) through the ERDT Faculty Research Dissemination Grant and the UP College of Engineering for financial support on this research. 321 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The empirical correlation using linear regression of settlement ratio under embankment load for Surabaya compressible soil Putu Tantri KS 1, Yudhi Lastiasih 2 1,2 Department of Civil engineering, Sepuluh Nopember Institute of Technology, Keputih Sukolilo, Surabaya,Indonesia 60111. (E-mail: [email protected]) ABSTRACT The development of settlement calculation under an embankment is usually taken as granted that the maximum settlement occurs in the center is the priority of soil settlement calculation under embankment. The settlement at the toe of embankment is always assumed as zero value which means that there is no settlement under the toe embankment. Whereas, soil settlement can occur in areas affected by embankment where not appropriate under embankment. The possibility of the settlement value under the toe embankment can be found from the stress increase under the embankment toe due to the embankment load itself. The one dimensional settlement by Terzaghi empirical formula shows that the stress increase could impact the value of soil settlement. It can be concluded that the settlement that occurs right at the toe embankment is not always zero. So, the major part of this paper is on challenges to predicting the ratio of settlement under the toe embankment, outer side of embankment and the center of embankment. The methods used in this study are the empirical approach from the expert recent study to estimate the index compression value (Cc) for compressible clay soil: Kosasih&Mochtar (1999), Nishida (1956), Shower (1970) and the formula of one dimensional consolidation. This study uses several variables such as the depth of soft soil layer in accordance with the soft soil in Surabaya Indonesia, the width of embankment and the height of embankment. Those variable uses to compare the ratio of settlement depend on those variables. The results of this study are to determine the empirical formula using linear regression of the settlement ratio in Surabaya compressible soil under the toe embankment and under the center embankment due to the variable used. Keywords: soil settlement, embankment, compressible soil, consolidation, settlement ratio, empirical correlation 322 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Influence of blast-induced ground motion on dynamic response of masonry minaret of Yörgüç Paşa Mosque K.Hacıefendioğlu 1, O.Köksal* 2 1 2 Ondokuz Mayıs University,Department of Civil Engineering, TURKEY. (E-mail: [email protected]) Ondokuz Mayıs University, Kavak Vocational Junior College, TURKEY. (E-mail: [email protected]) ABSTRACT This paper focus on the dynamic response analysis and presents crack areas of masonry minaret of Yörgüç Paşa Mosque subjected to artificially generated surface blast-induced ground motion by using a three-dimensional finite element model. The mosque is located in the town Kavak of Samsun, in Turkey. This study intended to determine the ground motion acceleration values due to blast-induced ground motions (air-induced and direct-induced) calculated by a random method. In order to model blast-induced ground motion, firstly, peak acceleration and the time envelope curve function of ground motion acceleration were obtained from distance of the explosion center and the explosion charge weight and then blast-induced acceleration time history were established by using these factors. Non-stationary random process is presented as an appropriate method to be produced the blast-induced ground motion model. As a representative of blast induced ground motion, the software named BlastGM (Artificial Generation of Blast induced Ground Motion) was developed by authors to predict ground motion acceleration values. Artificial acceleration values generated from the software depend on the charge weight and distance from the centre of the explosion. According to the examination of synthetically generated acceleration values, it can be concluded that the explosions cause significant effective ground movements. In the paper, three-dimensional finite element model of the minaret was designed by ANSYS. Moreover, the maximum stresses anddisplacements as well as crack areas of the minaret were investigated. The results of this study indicate that the masonry minaret has been affected substantially by effects of blast induced ground motion. Keywords: Masonry minaret, Blast induced ground motion, Random process 323 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Structural Performance of Sheikh Suleiman Masjid and Its Strengthening Tuğçe Tetik* 1 and Zekai Celep 2 1 2 Department of Civil Engineering, Namık Kemal University, TURKEY. (E-mail: [email protected]) Department of Civil Engineering, Istanbul Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT As being host to many civilizations in history, Turkey has a rich cultural heritage. Especially from the Ottoman Empire, including mosques, mausoleums, bathhouses, bridges and aqueducts. On the other hand Istanbul is very close to a major earthquake source of Turkey, i.e., the North Anatolian Fault Line. There are several statements that a major earthquake is likely to strike Istanbul in a short time. Several Turkish national institutions including the Istanbul Metropolitan Municipality and the Directorate General of Foundation are at work to mitigate the effect of a probable earthquake on historical buildings, one of them is related to the seismic evaluation of the historical buildings in the city. Generally a survey of the existing structural elements is carried out and the material used and cracks or damages due to environmental conditions and abuse are determined. All previous documents available related historical building is collected and all previous structural and architectural interventions are determined. Structural safety is evaluated by modeling the building and strengthening interventions are determined, when it is necessary. At the final state a application drawings are prepared and implementation of the architectural and structural intervention is carried out under proper supervision. In the present study, Sheikh Suleiman Masjid located in Istanbul Historical Peninsula, is investigated by considering gravity loads and seismic loads. The masonry building is modeled by adopting finite element technique where linear and plane elements are used. Proper material properties have been assigned to the model. However, sensitivity of these parameters is studied as well. Stress concentrations in the structural elements obtained from the analysis are compared with the existing crack patterns and damages. Various strengthening methods for increasing the structural and seismic performance of the building are discussed in detail. The paper presents a summary of the results of the structural response analyses of the building, including its response under gravity and seismic loads. Keywords: Finite elements method, Historical masonry structures, Seismic performance, Strengthening, Structural Analysis 324 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Stress Increase on the Geotechnical Properties of Sand A. K. Hindu * 1 1 Professor and Co-Chairman, Department of Civil Engineering, Mehran University of Engineering and Technology, Jamshoro, Sindh, PAKISTAN. (E-mail: [email protected]) ABSTRACT It is a common practice that before construction of civil engineering projects the soil properties were evaluated and accordingly the foundations/embankments etc were designed. However due to construction of structure/embankment or due to application of live loads the stress intensity on the soil will increase. This may result in the crushing of underlying soil particles, particular when the soil is coarse grained soil like sand. This study is thus aimed to evaluate the effect of increase in normal stress on the various geotechnical properties of sand. In the study the pressure molds were utilized to apply 5 MPA, 10 MPA, 15 MPA and 20 MPA normal stress on the sand. The results showed that the increase of stress caused breakage of soil particles which resulted in the decrease of coefficient of permeability of the soil even for the same void ratio. It was also seen that with the increase of stress intensity the relative density of soil gradually decreased. The shear strength test results showed that the soil subjected under higher stresses possess lower angle of internal friction under same testing conditions. It was also observed that with increase in stress the behavior of soil may change from dense state to loose state. Keywords: Permeability, Relative Density, Sand, Shear Strength, Stresses Acknowledgment: The author thanks Department of Civil Engineering, Mehran University of Engineering and Technology for providing facilities to conduct this research. 325 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Measurement of Small Strains in Steel Samples Using Digital Imaging Technigues Ş.Sözen* 1, M.Güler 2 1 Gaziosmanpaşa University, Department of Civil Engineering, TURKEY, 2Middle East Technical University, Department of Civil Engineering, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Small strains are generally measured using electrical resistance strain gages in structural engineering applications. Strain measurement using these sensors, however, has certain limitations depending on measurement conditions, i.e., environment temperature, material type, and strain magnitude. Digital image correlation method offers significant advantages over the other means of strain measurements under demanding conditions. In this study, calculated strains based on the digital image correlation method are compared with measured strains using electrical resistance strain gages. The study is carried out by uniaxial tension tests conducted up to the yield point of test specimens that are furnished with strain gages. Digital pictures are taken from the gage locations and recorded onto a hard disk for analysis. Based on the correlation of successive images, on-surface deformations hence strains are calculated. The comparison of both methods indicates that measured yield strains compare well with those of strains from digital images. The method allows to measure strains without having contact with the specimen surface. Keywords: Digital image correlation, strain, steel. 326 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Design Criteria for the Type of Gabion Walls Esra Uray * 1 and Özcan Tan 2 1 Faculty of Civil Engineering, KTO Karatay University, TURKEY. (E-mail:[email protected]) 2 Faculty of Civil Engineering, KTO Karatay University, TURKEY. (E-mail:[email protected]) ABSTRACT In this study, design criteria of gabion wall which commonly used in civil engineering has been investigated by using Taguchi method. Main factors affecting design of gabion retaining wall are height, length of base, slope, angle of internal friction of backfill and slope of backfill of the wall. In this study, in order to investigate affecting factors to shear safety factor, overturning safety factor and tensile strength between gabion baskets, 16 different design tables have been chosen according to Taguchi method. Designs obtained by using Taguchi method, has been modelled with computer program. By using results of this program for each design “S/N, Signal/Noise”, “Variance, ANOVA” and optimization analysis have been applied and plotted their diagrams. The safety factors obtained by computer analysis for shear, overtur ning and tensile strength between gabion baskets are studied and by using statistical methods found parameters which is effective on stability of gabion retaining wall. Keywords: Design Criteria, Gabion Structures, Gabion Retaining Wall, Retaining Structures, Taguchi Method 327 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Importance of Tie-Rods in Masonry Arches Sukran Tugrulelci* 1, Mehtap Kayabasi 1, Fatih Kursat Firat 1 1 Aksaray University, Department of Civil Engineering, Aksaray, TÜRKİYE ([email protected], [email protected], [email protected]) ABSTRACT In the most of historical buildings made by the world’s most ancient civilizations and survived to modern times, arches are the types of structures. In Anatolia, considering the historical buildings remaining from especially Ottoman, arches have wood or iron tension members, commonly called tie-rods, is between the thin and slender pillars; the main function of which is to ensure the stability of the arch when subjected to large vertical loads. In this study first of all, it is informed about the arches located in historical structure and also tie-rod is examined in terms of the influence and importance on the general structural behavior. One arch model which have no tie-rod and one model with tie-rod was evaluated by using the Finite Element Methods (FEM). The nonlinear properties of materials are taken into consideration in numerical analysis. Numerical models are constitued by using a computer program LUSAS (2012). At the end of the study, it is indicated that tie-rod is of great importance for the protection of the stability of arches under vertical load. Besides, according to the results obtained from the numerical analysis, the capacity of the arches with tie-rod increases considerably in comparison with arches without tie-rod. Keywords: Arches, Drucker-prager criterion, Finite element methods, LUSAS software, Tie-rod. 328 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Design parameters and special features of next generation wind energy structures Evangelos Efthymiou* 1 1 Department of Civil Engineering, Aristotle University of Thessaloniki, GREECE. ([email protected]) ABSTRACT In the field of wind energy structures, the combination of industrial, technological and scientific progress that has been carried out throughout the years, resulted in their evolution in terms of morphology and constructional configuration. The traditional Dutch windmill of the 18th century has given place to gigantic turbines with rotating machines, while in the last decade new taller towers with hub height over 100m-120m have been adopted by relative companies, the so called next generation wind energy structures, aiming to exploit the greater wind speeds corresponding at this altitude. The latter represent an attractive choice towards the goal of making onshore wind energy the most competitive energy source, however due to their recent introduction, structural behavioural aspects of these structures are characterized by uncertainties and issues related to their cost -efficiency need to be enlightened. The present paper examines the design parameters of next generation wi nd turbine towers and identifies their special features with respect to transportation, economy and construction. It involves primarily the design loads determination as wind profile at these heights combined with seismic actions compose a complex loading framework, particularly in earthquake prone areas. For the purposes of the current work, prototypes of steel wind turbine towers are configured and finite element analysis is implemented, towards achieving better understanding of the tower’s structural response. In this context, the study summarizes the latest developments concerning the structural forms and innovative design concepts of the towers, so that both safety and material economy can result in cost -efficient power generators. Keywords: design parameters, morphology, next generation wind energy structures, special features. Acknowledgment: The author would like to express his gratitude to Aristotle University of Thessaloniki’s Research Committee (ELKE AUTH) for the financial support provided regarding his research on the field of next generation wind energy structures. 329 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 On the buckling analysis of steel tubular wind turbine towers with vertical and horizontal stiffeners Nafsika Stavridou* 1, Evangelos Efthymiou 2 and Charalambos C. Baniotopoulos 3 1, 2 Civil Engineering Department, Aristotle University of Thessaloniki, GREECE. (E-mail: [email protected], [email protected]) 3 School of Civil Engineering, University of Birmingham, United Kingdom. (E-mail: [email protected]) ABSTRACT The constantly increasing energy demand makes the use of alternative energy sources imperative in order to sustain and improve the current environmental conditions. Wind energy as a promising sustainable energy sector necessitates the exploitation of the infinite wind potential in benefit of energy production. Therefore the increase in number of wind turbines and the amelioration of their components is considered of high importance in order to expand the wind energy production facilities and meet the future energy needs. Towards taking advantage of greater wind speeds, the construction of taller wind power plants is encouraged and the challenge for civil engineers i s to design and construct safer, more durable and more robust structures. The most common structural configuration of such structures is a tapered steel shell with circular cross-section due to its capability of carrying heavier loads coupled with facilitation in mounting. In this present work a new attempt to secure steel shells against buckling is introduced. Configurations consisting of internal stiffening rings and vertical stiffeners are investigated separately and a parametric study is being conducted to explore the correlation between the number of stiffeners and their effectiveness against buckling phenomena. For the investigation of the proposed stiffening methods, finite element models are analyzed and significant outcomes are being obtained. The overall tower response is being addressed and special remarks are made concerning the tower’s structural behavior against variable loading. Keywords: numerical analysis, steel structures, stiffening rings, vertical stiffeners, wind turbine tower. Acknowledgment: The first author wants to express her gratitude to IKY for financial support of the research activities on performing her PhD thesis through the IKY Fellowship of Excellence for Postgraduate Studies in Greece – SIEMENS Program 330 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Compressive Strength of steel and polypropylene fiber reinforced coal ash concrete A. Akyıldız* * Department of Civil Engineering, Çorlu Engineering Faculty, Namık Kemal University, Çorlu/ Tekirdağ (E-mail: [email protected]) ABSTRACT Concrete is the most important engineering material and the addition of some other materials may change the properties of concrete. The objectives of this study was to investigate the effect of polypropylene and steel fiber reinforcement in concretes made with binder containing coal ash on concrete properties such as compressive strength. Compressive strength was determined at 2, 7 and 28 days. Concrete series, 5 in all, with binder containing 20% by mass of coal ash were produced. The first being the control series with no fiber, the second through fifth being the test series, containing 30 kg/m3 of ZP 308 (ℓ/d=40) steel fiber, 30 kg/m3 of RC 80/60 BN (ℓ/d=80) steel fiber, 0.2% by mass of M12 type polypropylene fiber, 0.2% by mass of F19 type polypropylene fiber, respectively. The test results show that use of fibre improves material properties of the concrete. Keywords: Coal Ash, Compressive Strength, Concrete, Polypropylene Fiber, Steel Fiber 331 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Mode I fracture toughness and Fracture Process Zone of Rock-like Material with Continued Thermo-induced Damage under Semi-circular Bend using Acoustic Emission Technique Hung Wei Liu* 1, Li Hsien Chen 2 , Yao Chung Chen 3 and Yu Cheng Chang 4 1 Professional Engineer, FUANHON Construction Ltd, TAIWAN (E-mail: [email protected]) 2 Associate Professor, Department of Civil Engineering, National Taipei University of Technology, TAIWAN. (E-mail: [email protected] ) 3 Professor, Department of Civil and Construction Engineering, National Taiwan University of Science and Technology, TAIWAN. (E-mail: [email protected] ) 4 Engineer, Raiteku Co. Ltd., TAIWAN. (E-mail: [email protected] ) ABSTRACT Thermal effect impacts the engineering safety, such as tunnel fire and nuclear waste storage. If engineers could understand better the distribution of thermo -induced damage, they can either improve the design by considering the protective measures beforehand, or they can provide better repa ration plans by predicting the damage zones more accurate after tunnel fire. Traditionally, discrete heat treatment method is used to prepare the specimens, for which predictions between data points cannot be accurate. In this research, continued heat treatment method was used to prepare the specimens; the tensile strength and fracture toughness of the heat -treated specimens were investigated. Furthermore, the material fracture is related to fracture parameters, fracture toughness and fracture process zone. Hence, this study tries to measure the fracture process zone of Semi-circular bend (SCB) sample using acoustic emission (microscopic technique) for calculating the fracture toughness compared with the fracture toughness from SCB test (macroscopic theory). Based on test results, a more rational and accurate prediction equation is proposed and the critical damaging temperature is found to be about 540~550℃. The fracture toughness from micro-technique and macro-test are found to compare well. Keywords: Thermal-induced fracture, Semi-circular bend, Fracture toughness, Fracture process zone, Acoustic emission. Acknowledgment: The authors acknowledge the funds by the National Science Council of Taiwan (NSC 992221-011-069-MY3). 332 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 EQUILIBRIUM SCOUR DEPTH CALCULATION WITH ARTIFICIAL NEURAL NETWORKS (ANN) Mehmet Öner YELEĞEN*1, Ali UYUMAZ2 1 Fatih Sultan Mehmet Vakif University, Civil Engineering Department, Haliç, İstanbul (E-mail: [email protected]) 2 Istanbul Technical University, Civil Engineering Department, Hydraulics Laboratory, Maslak, İstanbul (E-mail: [email protected]) ABSTRACT Scouring is one of the most commonly failure effect on bridges. In the literature, there are many analytical and especially empirical formulae available to calculate the scour depth based on some observations from laboratories or fields. Furthermore, many approaches and alternative ways have been used by researchers to predict the scour depth. Artificial neural network (ANN) is a way to predict the unknown system outputs. Scouring is a complex mechanism and there is almost no unified method to determine the input variables, which change from model to another. The proposed ANN method tries to determine the most related scour causative input variables for better solutions. The linear tendency between one to one input-output variables determines the most relevant input variables. The results are compared with the available formulae results in the literature. It has been found that the input variables of the ANN approach are the most relevant parameters for scour calculations. Key words: Artificial Neural Network, Equilibrium, Model, Prediction, Scour, Tendency. 333 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 REDUCTION OF THE SETTLMENT OF A COLLAPSIBLE SOIL BY THE ADDITION OF LIME, USE OF THE DOUBLE CONSOLIDATION METHODE. N. BAKIR*1, K. ABBECHE2, A. LAHMADI3 1,3 2 Department of Civil Engineering, University of M'sila, ALGERIA (E-mail : [email protected], [email protected]) Department of Civil Engineering, University of Batna, ALGERIA (E-mail : [email protected]) ABSTRACT Collapsible soils are defined as unsaturated structures, which can undergo radical rearrangement of its particles and a sharp decrease in volume after wetting with or without load. Most of these soils are loess or eolian deposits constituted of silt and sand which are located in arid or semi-arid area. Southern Algeria is constituted largely of loess formations and is nowadays an area with a high potential for agricultural development. The occupation of this region is at risk of collapse of structures erected on land "Collapsibles". Therefore, we propose treatment solutions which are economic and easy to implement. This paper presents an experimental study of the treatment of collapsible soil which is reconstituted in the laboratory by different contents in lime using the method of double consolidation. Samples of this soil with different moisture contents are compacted with different energy levels. The expected purpose of this study is to reduce the potential of subsidence of these soils to an acceptable level. Keywords: collapse, treatment, flooding, compaction energy, arid zone. 334 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Production of pumice-based geo-polymer concrete Ahmet BİLGİL1, Ergün YEŞİLYURT2, Mehmedi Vehbi GÖKÇE3 1. Niğde University, Faculty of Engineering, Department of Civil Engineering, Turkey, [email protected]. 2. Erciyes University –Kayseri Vocational High School, Department of Construction, Turkey, [email protected]. 3 . Niğde University, Faculty of Architecture, Department of Architecture, Turkey, [email protected]. ABSTRACT Pumice is included in the industrial raw materials and Turkey has vast, rich reserves throughout its territory. As a common practice, pumice is currently used in the production of non-load-bearing, lightweight building components with cement as binder. However, main issues in this practice are that cement causes aggregate reactivity with pumice, and heat transfer coefficient and unit weight are relatively high. In this study a new, high-performance product was aimed to be produced by binding ground pumice with sodium silicate and then exposing the mixture to heat-processing. In the study, pumice obtained from Nevşehir quarries was used after getting ground to the fineness from 0 to 500 µ. Volumetric ratio and molarity are based on in the mixtures considering that unit weights of pumice and sodium silicate are significantly different. Pastes were prepared by adding sodium silicate to pumice at the ratios of 10 to 50% of the pumice volume increasing by 10 increments. The samples were cured in the medium at room temperature up to 60 days, and then compressive strengths were measured. The samples cured less than 25 days did not yield measurable strengths but could only reached to measurable values after this period. The samples were also heat-processed starting from 50 ºC reaching up to 1100 ºC increasing in 100 increments. Thus, optimum mixture parameters were determined considering compressive strengths and unit weights. Other standard tests will also be performed on the samples as a next step to determine production parameters for a better, new generation product to be presented to the construction industry. Keywords: Pumice, geo-polymer concrete, lightweight building component, sodium silicate. 335 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Mechanical, Dynamic and Durability Analysis of Structural Concrete Reinforced with Nano Silica Particles Savaş ERDEM* 1 and Ezgi GÜRBÜZ 2 1, 2 School of Civil Engineering, University of Istanbul, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT In the recent years, the application of nanotechnology in the construction industry has increased exponentially. One nanomaterial that deserves the attention of researchers is amorphous silica with particles size in the nano-range. In this study, the influence of different percentages ( % 0.5, % 1 and % 1.5 by volume) nano-silica particles on the mechanical, dynamic and durability properties of structural concrete has been studied through measurement of compressive strength, fracture energy under impact loading and water permeability. In addition, a range of techniques including scanning electron microscopy and X-ray computed tomography accompanied by digital image analysis were used to characterize the nano-silica and micro-structures. The experimental results show that the compressive strength and water permeability of the concrete mixed with the nano-particles were much better than those of the control concrete. The micro-structural analysis also indicated that the nano-silica particles filled the pores at the cement matrix producing a denser and stronger cement paste-aggregate interfacial zone. However, the fracture energy of concrete under short-duration impact loading decreased with the increasing percentage of nano-silica and thus, a more brittle failure mode was observed. Keywords: Concrete, Impact resistance, Nano silica, Permeability, Strength. 336 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Buckling Restrained Braces with Different Casing Systems Ramazan Ozcelik* 1, Yagmur Dikiciaşık1 1, Department of Civil Engineering, Akdeniz University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT This paper presents experimental investigation of buckling restrained braces (BRBs) with different casing systems. The BRBs consist of core plate and casing member. The casing member prevents the core plate from buckling. Hence, the core plate can yield under tension and compression demands. The component tests for five BRBs were performed in order to exam the different casing systems namely steel tube-concrete, confined and unconfined concrete and built-up sections. In un-bounded steel tubeconcrete BRB, steel hollow sections were attached on the restrained elastic and plastic part on the core plates to prevent the local buckling. The built-up sections were consisted of four steel hollow sections connected to each other via batten and lattice plates. The confined and unconfined concrete were used for casing members of BRBs to obtain economical and practical casing systems. All BRBs was loaded cyclically up to 3.0% strain which core plate performed. The testing of the BRBs with different casing systems indicated that the cyclic performance of the BRBs were satisfactorily up to 2% strain of core plate. Consequently, the BRBs with different casing systems which is stiff to resist the out-off plane buckling at both ends has acceptable cyclic performance. Furthermore, connection details, isolation materials and their application techniques have been also investigated for improved BRB design in this study. Keywords: Buckling Restrained Brace, Casing members, hysteretic behavior. 337 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Nano-scale Investigation of Passive Layer for Corroding Steel Bars in Concrete under Severe Environmental Conditions Raja Rizwan Hussain*1, Abdulrahman Mohammed Alhozaimy 2, Abdulaziz I. Al-Negheimish3 and Rajeh Zaid Al-Zaid4 *1Corresponding Author: Associate Professor, CoE-CRT, Civil Engineering Department, College of Engineering, King Saud University, Riyadh, Saudi Arabia. (e-mail: [email protected]) 2-4 Professor, CoE-CRT, Civil Engineering Department, College of Engineering, King Saud University, Riyadh, Saudi Arabia. (e-mail: [email protected]) ABSTRACT Corrosion due to chloride attack is the main cause of deterioration in reinforced concrete structures in the Kingdom. Chloride ions break the passive film developed on the steel bar embedded in concrete protecting the steel from corrosion. This situation is further aggravated by the hot weather conditions. The passive layer is believed to be a few nanometers in thickness and primarily composed of iron oxides; however, little is known about its chemical composition and structure as well as the passive film breaking process. This makes it difficult to characterize corrosion which is highlighted by the fact that the chloride threshold value of steel reinforced concrete measured by conventional electro chemical techniques can vary greatly. While these techniques measure corrosion in a macro scale, th e growth and deterioration of passive film actually take place at the nano -scale and is governed by the elemental compositions and nano-microstructure of the steel as well as the chemistry of the concrete and the environment around the rebar which has been incorporated in this paper. This research paper focuses on characterization of passive layer at the nano-scale as well as on finding out what happens when the film breaks down especially due to chloride attack under hot weather. Keywords: Corrosion; concrete; Nano-technology; rebars; Acknowledgment: This project was supported by the NSTIP Strategic Technologies Program, grant number 09-NAN 674-02, Kingdom of Saudi Arabia. 338 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Free Vibration Analysis of Axially Accelerating Timoshenko Beams Using Differential Transform Method Baran Bozyigit* 1, Yusuf Yesilce2 1, 2 Dokuz Eylul University, Department of Civil Engineering, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT In the recent years, axially moving beams have been playing an impor tant role in many type of engineering problems such as air cable tramways, pipe-conveying fluids, power transmission belts, high speed magnetic tapes, band saws and transportation of structural members like precast beams. The axial speed of a beam directly effects its vibration characteristics and dynamic stability. Thus, it is important to know the axial speed-dependent dynamic characteristics for the successful design. In this study, an axially accelerating beam, which can be defined as a special case of a moving beam, is used to analyze the natural frequencies and modes shapes of axially accelerating beams on different supports by using Timoshenko Beam Theory (TBT) and Differential Transform Method (DTM). First of all, the governing equations of motion of the accelerating Timoshenko beam in free vibration are derived using Hamilton’s principle. Due to acceleration, the axial speed and axial tensile force are assumed as harmonically varying about a constant velocity and tensile force. Parameters for the nondimensionalized multiplication factors for the velocity and axial tensile force are incorporated into the equations of motion in order to investigate their effects on the natural frequencies. The natural frequencies are calculated directly from the analytical solution of the differential equations according to TBT. After the analytical solution, DTM which is an effective mathematical technique is used to solve the governing differential equations of the motion. The calculated natural frequencies of accelerating Timoshenko beams with three combinations of boundary conditions using DTM are presented in several tables and figures. In addition to this, results obtained from DTM are compared with the results of the analytical solution and proximity of results is observed. At the end, the fundamental mode shapes are presented in graphs. Keywords: Accelerating Timoshenko beam, Differential Transform Method, free vibration, natural frequencies. 339 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Behavior of Beam to column connections which contain Shape Memory Alloys in Moment Steel Frame Saeed jamalpour * 1, Abbas akbarpour 2 1, 2 M.S. student of Structural engineering- I. A. University - south Tehran branch, Iran. member of Engineering faculty- I. A. University- south Tehran branch, Iran (Email:[email protected], [email protected]) ABSTRACT The Moment Steel Frames are designed to waste a substantial amount of energy which induced by earthquake when yield limit of sections in beams and columns is reached, so non-elastic deformation occurred in these sections. These deformations are permanent in the structure in a way that occasionally strengthening is impossible and structure must be torn down. Thus for the sake of functional design, designers require new structural systems and members with high capacity in deformation & ductility, restoration or permanent deformations reduction. The vulnerability of connections of Moment Steel Frames under lateral loads inevitably makes application of materials or substances with high behavioral and functional change capacity. Shape Memory Alloys (SMA) have super elastic attribute which enables them to bear large amounts of nonelastic stresses, and return to its original state after unloading. Application of such substances in steel frame connections, which bear significant moments during earthquake which eventually causes major dislocation of frame or complete breakdown of connection, can prominently affect the behavioral change and the increase in ductility. Current essay examines the function of beam to column connections which contain Shape Memory alloys. Keywords: Shape Memory Alloys, beam to column connections, super elastic attribute 340 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Numerical simulation of dynamic load on pavements J. Melcer* 1 1 University of Zilina, Faculty of Civil Engineering, Department of Structural Mechanics Univerzitna 8215/1, 010 26 Zilina, Slovak Republic. (E-mail: [email protected]) ABSTRACT Dynamic effect of moving load on transport structures can be followed in the literature from the year 1849. It was induced by the collapse of the Chester Rail Bridge in England in the year 1847. At the early stage the analytical methods were applied. The development of computers brings the revolution and qualitative jump in the development of solution. The submitted paper is dedicated to the numerical simulation of moving load effect on road structures in the time domain. The dynamic load from vehicles on pavements is the subject of interest. The multi-body computing models of vehicles on various levels are introduces. The equations of motions are derived in the form of ordinary differential equations. The equations of motions are solved numerically by the use of stepby-step integration method in the environment of program system Matlab. The road unevenness as the main source of kinematical excitation of vehicle is modeled as the random rod profile by the use of the power spectral density functions. The vehicle moves along the road by various speeds and time histories of wonted functions are calculated. Especially the time histories of tire forces as the source of dynamic load of pavements are the object of interest. When the magnitude of unevenness runs over certain value the contact between the tire and the pavement is missed. It is unwelcome situation for the pavement and for the vehicle. The conclusions are focused on the influence of the road profile quality on the values of tire forces. Keywords: Numerical simulation, dynamic load, computing models, pavements, tire forces. Acknowledgment: This contribution is the result of the research supported by Grant National Agency VEGA of the Slovak Republic, project No. 1/0295/12 341 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of aggregate maximum size on properties of fiber reinforced concrete Gözde İnan Sezer, Şemsi Yazıcı Ege University Civil Engineering Department, İzmir, TURKEY (E-mail, [email protected], [email protected]) ABSTRACT In this study, the effect of maximum aggregate size on impact resistance of fiber reinforced concrete was investigated. Using limestone aggregate with 10, 15, 20 and 25 mm of maximum size, different fiber reinforced concretes were produced. Water/cement ratio and cement dosage of concrete mixtures are 0.5 and 400 kg/m3, respectively. Besides, super plasticizer and steel fibers were used in concrete production. Hookedend bundled steel fibers with l/d ratio of 65 and 1.0% fiber volume were used. After 28 days standard curing, compressive strength, split tensile strength and ultrasonic pulse velocity tests were performed on 150/150/150 mm cube specimens. Additionally, impact resistances of concrete specimens were determined using impact test apparatus described in ACI 544.3R-93. 150x300 mm cylinders were prepared for impact resistance tests. After 28 days curing, these specimens were cut and 150x64 mm special discs were prepared. Impact resistance test were performed on these special discs. Experimental results were evaluated corresponding to presence of steel fiber and aggregate maximum size. Keywords: Impact effect, aggregate maximum size, fiber reinforced concrete, mechanical properties. 342 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Unconfined compressive strength, chloride-ion penetration and freezing-thawing resistance of cement stabilized clay İrem Kalıpcılar* 1, Ali Mardani- AGHABAGLOU 2, Alper Sezer 3, Gözde İnan Sezer 4, Selim Altun 5 1, 2,3,4,5 Ege University, Department of Civil Engineering, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT In this study, the changes in unconfined compressive strength, chloride -ion penetration and freezingthawing resistance of cement stabilized soils were investigated. For this purpose, an ordinary portland CEMI42.5R type cement and kaoline were used. In addition to the control mixture without any cement content, three different mixtures were prepared by addition of cement at ratios of 5, 10 and 15 % of dry weight of kaoline. The mixtures were compacted at their optimum moisture contents by use of standard Proctor energy, leading to corresponding maximum unit weight values. The specimens were cured in room conditions with relative humidity of 95% for 1, 7 and 28 days and the outer surfaces of specimens were moistened by water pulverization every 3 days. Afterwards, the unconfined compressive strength, chloride-ion penetration and freezing-thawing resistance of specimens were obtained in accordance with ASTM D 2166, ASTM c1012 and ASTM C 666 standards, respectively. The specimens were exposed to 6 and 12 freeze-thaw cycles and after then unconfined compression strength tests were performed to determine the freezing-thawing resistancevalues. It was observed that the unconfined compressive strength reduction of the specimens decreased due to freezing -thawing action. Consequently, test results were discussed in detail. Keywords: Freeze-thaw, cement stabilization, kaoline, unconfined compressive strength, chloride ion penetration. Acknowledgment: The authors appreciate the contributions of Scientific and Technological Research Council of Turkey (TUBITAK) and Ege University Science and Technology Centre - Technology Transfer Office (EBILTEM) for their financial support [Project numbers: 113M202 and 2014-BIL-009]. 343 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Mechanical Properties of Heavy and Normal Weight Concretes Produced with Barite and Limestone H. Bozkurt*, C. Karakurt 1, C. Kandemir Department of Civil Engineering, Bilecik Seyh Edebali University, Bilecik/TURKEY (E-mail: [email protected], [email protected]; [email protected]) ABSTRACT High-density concrete aggregates called heavy weight concrete manufactured with high specific gravity (heavy concrete) is used for preventing against carcinogenic effects of radiation on human body and it can be used for to prevent radioactive leaks in the nuclear structures. Heavy concrete is mainly used to create a screen against harmful rays and heavy weight concretes unit weight is higher than normal weight concrete. Heavy weight concretes are used in nuclear reactors shield structures, hospitals radiation room where radiation treatment of the sections shown. In this study, it is investigated that comparison of the mechanical properties of normal weight concrete with heavyweight concrete. A type of iron ore and barite was used as heavyweight aggregate in the heavy weight concrete mixtures. In addition the reference normal weight concrete was produced with limestone aggregate. The mix design of both concretes was made in accordance with same volume of heavy and normal weight aggregates. In the experimental part of the study, heavy and normal weight concrete cubic and prismatic specimens were produced in dimension with 15 cm cube and 10x10x50 cm prismatic form respectively. The compressive strength, flexural strength and ultra sound pulse velocity tests were performed on heavyweight and normal weight specimens at 3, 7 and 28 days curing ages. According to fresh concrete properties the workability of heavy concrete specimens was 28 % lower than normal concrete. In addition the hardened concrete test results showed that the streng th properties of heavy concrete specimens for all ages were decreased with the increase of the unit weights. It is also determined that the unit weight of heavy concrete was 36 % higher than normal concretes unit weight. Keywords: Heavy weight concrete; Normal weight concrete; Mechanical properties; Barite 344 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigating the Effect of Joint Behaviour on the Optimum Design of Semi-Rigid Steel Frames Soner ŞEKER *1, Erkan DOĞAN 2, Mehmet Polat SAKA 3, Celalettin KOZANOĞLU 2 1 Uşak University , Department of Civil Engineering , 64200 , Uşak , Turkey (E- mail : [email protected]) 2 Celal Bayar University , Department of Civil Engineering , 45140 , Manisa , Turkey 3 University of Bahrain, Department of Civil Engineering, Isa Town, Bahrain ABSTRACT This study aims to carry out the effect of beam-to-column connections on the minimum weight design of steel plane frames. In the practical analysis of steel frames, end connections are assumed to be either fully restrained or pin-connected. However, experiments reveal that the real behavior is between these extremes and should be taken into account for the realistic design of structures. Hunting search algorithm is used for the automation of optimum design process. It is a numerical optimizatio n method inspired by group hunting of animals such as wolves and lions. It is proven that it is a reliable and efficient technique for obtaining the solution of discrete structural optimization problems. Present design algorithm developed on the basis of hunting search algorithm selects w- sections for the members of semi rigid steel frame from the complete list of w- sections given in LRFD- AISC (Load and Resistance Factor Design, American Institute of Steel Construction). The design constraints are implemented from the specifications of the same code which covers serviceability and strength limitations. The selection of w-sections is carried out such that the design limitations are satisfied and the weight of semi- rigid frame is the minimum. Three different steel frames are designed by the optimum design algorithm presented to demonstrate its efficiency. The designs obtained by use of this algorithm are also compared with the ones produced by particle swarm optimization method. Keywords: Stochastic Search techniques; hunting search algorithm; optimization problems; semi-rigid steel frames 345 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effects of Viscous Bulk Compressibility for Cantilevered Cylindrical Helices M. Ermiş* 1, H. Argeso 2, N. Eratlı 3 and M. H. Omurtag 4 1, 3, 4 Department of Civil Engineering, Istanbul Technical University, Istanbul, Turkey. ([email protected], [email protected], [email protected]) 2 Department of Manufacturing Engineering, Atılım University, Ankara, Turkey. ([email protected]) ABSTRACT The dynamic response of a cantilevered viscoelastic cylindrical helicoidal rod is investigated by using the mixed finite element method. The rod has a circular cross section and subjected to a rectangular type of impulsive load acting from its free end. The finite element formulation is based on Timoshenko beam theory and the element matrices for two nodded curvilinear elements are obtained in Laplace space. In the formulations, elastic-viscoelastic analogy (correspondence principle) is used to implement the viscoelastic material behavior. The system matrices of finite element method are solved in Laplace space and the results obtained are transformed back to time space by using the modified Durbin's algorithm. It is assumed that, the viscoelastic material exhibits standard type of distortional behavior and Kelvin type of bulk compressibility. Parametric analyses are carried out for the aim of investigating the effects of helix geometry and the viscous bulk compressibility on the dynamic response of helicoidal rod. Keywords: cylindrical helix, Laplace space, mixed finite element method, Timoshenko beam theory, viscoelasticity. Acknowledgment: This research is supported by The Scientific and Technological Research Council of Turkey under project no 111M308 and by the Research Foundation of ITU under project no 38078. These supports are gratefully acknowledged by the authors. 346 ICOCEE - CAPPADOCIA2015 Nevsehir, TURKEY, May 20-23, 2015 Influence of steel fibers on the shear strength of RC beams without stirrups M.İ. Birincioğlu* 1, S. Ulusoy 2 and G. Arslan3 1, 2 Department of Civil Engineering, Yıldız Technical University, İstanbul, Türkiye (E-mail: [email protected], [email protected]) 3 Department of Civil Engineering, Yıldız Technical University, İstanbul, Türkiye (E-mail: [email protected]) ABSTRACT This research studied the shear strength of six beams reinforced with longitudinal bars and steel fibers. The beams including two reference and four reinforced concrete (RC) beams with steel fiber have been tested under concentrated loads at mid-span to determine the shear strength. The variable parameters are concrete compressive strength, shear span-to-depth ratio (a/d) and volume fraction of steel fibers. Based on the test results, it is concluded that as the fiber volume increases, the shear strength and ductility of the beams increases, providing significantly higher shear strength than the strength calculated according to the ACI 318 Code. When the beams with a/d=2.5 and 3.5 are compared, it is observed that the load carrying capacity of the beam with a/d=2.5 is 18% greater than the one with a/d=3.5, where the volume fraction of fibers is 2% for both of them. Keywords: Steel fiber; Reinforced concrete; Beam; Shear strength. 347 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Study on Flow and Compressive Strength Properties of Mortars Using Waste Slag O. Karahan* 1, C.D. Atiş 1, S. İlkentapar 1 and Z.A. Özcan 2 1 Civil Engineering Department, Erciyes University, TÜRKİYE. (E-mail: [email protected], [email protected], serhan @erciyes.edu.tr) 2 Tomarza Vocational High School, Erciyes University, TÜRKİYE. (E-mail: [email protected]) ABSTRACT This study presents the flow and compressive strength properties of mortar containing waste slag. Zinc - Lead production institution waste materials are used in mortar s. For this purpose, standard reference mortar mixture was made with reference sand, CEM I 42.5R Portland cement and natural spring water. The sand-cement and water-cement material ratios were chosen as 3.0 and 0.5, respectively. Reference mortar mixture was modified using waste slag as cement replacement. Waste slag was used in four different replacement levels (5%, 10%, 15% and 20%). Series of three 40×40×160 mm prismatic specimens from each mortar were prepared. The workability and compressive strength of waste slag mixtures were determined according to TS EN 1015-3 and TS EN 196-1, respectively. The compressive strengths were determined at 7 and 28 days. As a result of laboratory study, the workability of mortar containing waste slag was found to be better than that of mortar made with cement up to 15% replacement level. However, a slight reduction in strength properties was observed with waste slag replacement for cement. Keywords: Mortar, Strength, Waste Slag, Workability. Acknowledgment: The authors thank CINKOM Zinc Lead Metal & Mining for their support. 348 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 CFRP Strengthening of Solid Wood under Bending Loads AW Ezahtul Shahreen* 1, J Mohd Zamin2 and AKM Kawsher Alam3 1, 2, 3 Department of Civil Engineering, University of Malaya, MALAYSIA. (E-mail: [email protected], [email protected]) ABSTRACT Numerous of application of Fibre Reinforced Polymer (FRP) material as reinforcement in timber structure studied within last decade. Most recent studies on strengthening of glulam reinforced with FRP. In Malaysia the usage of engineered wood such as glulam still new and less acceptance because of the cost and availability of the materials. Solid timber still renowned by engineers and architects as structural element even tough solid timber properties are limited by natural defect. Furthermore, studies on the strengthening of tropical solid timber were limited and need to be explored. This research was conducted to investigate the behaviour of flexural strength of low grade tropical timber beam incorporating carbon fibre reinforced polymer (CFRP) as reinforcement using Sikadur-30 as bonding agent. The timber beams were strengthened by CFRP plates as external reinforcement and CFRP rods for near surface mounted system (NSM) technique over its entire length. Five beams for each technique with the dimension of 50 mm x 150 mm x 2700 mm length were tested to failure under four point loading. Three un-strengthened beams will be act as control beam. From this research, it is obtained that, the strengthening with only CFRP plate bonding is more effective with gave a maximum 64% load capacity increment compared to NSM. As predicted the strength grade also moved from Strength Group 7 to Strength Group 5. By incorporating CFRP plate as reinforcement, demonstrate the good potential of lower grade species to be used as structural beam and replaced the expensive species normally used in construction. Keywords: Fiber, Flexural strength, Low grade timber, Reinforcement 349 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Dynamic Characterization of Timber Beams Strengthened with CFRP Plate AW Ezahtul Shahreen* 1, J Mohd Zamin 2 1, 2 Department of Civil Engineering, University of Malaya, MALAYSIA. (E-mail: [email protected], [email protected]) ABSTRACT The structural utilization of timber is usually limited by the relatively low bending stiffness and strength. One possible solution to increase the stiffness and strength of the timber is by reinforcing them with reinforcing material. Nowadays, timber structures strengthened with FRP composites are gaining popularity, and there is a growing need to understand and compare the behavior of these structures before/after FRP composite strengthening. To fulfil the structural safety evaluation requirements, structural design should incorporate structure deflection under natural frequencies in the serviceability limit state checking. The main objective of this paper was to study the dynamic behavior of timber beams reinforced with carbon fiber reinforced polymers (CFRP). Meranti (Shorea spp.) species used in this study is not high performance material for structural usage because of its low strength, and is prone to check properties. This species has been choose to study the feasibility of utilizing the low to medium hardwoods species for structural usage by strengthened it with reinforcing material was specially selected by visual grading. Eight timber beams with the cross-section of 75 mm x 150 mm and 2700 mm length were strengthened by CFRP plates as external plate bonding (EPB) at 2150 mm from its entire length using Sikadur-30 as bonding agent. The dynamic properties will achieved by using impact hammer with a piezoelectric sensor. For the static test, the timber will tested to failure under four point loading. The results from both static and dynamic test will be compared. It is predicted that a general trend could be produce from this study. Having baseline data of dynamic characteristic can provide designer a lot of standard on dynamic consideration. Therefore, by completing both static and dynamic in structural design, designers can have a higher level confidence with their efforts to the public. Keywords: Fiber, Flexural Test, Modal Analysis, Reinforcement, Solid Wood 350 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Use of Fly Ash in The Design Of Controlled Low-Strength Material Mixture Ma. Doreen E. CANDELARIA*1, Kaz Mikhail David S. MAURILLO1, Nathaniel B. DIOLA1 1, 2, 3 Institute of Civil Engineering, University of the Philippines Diliman, Quezon City, PHILIPPINES (E-mail: [email protected], [email protected], [email protected]) ABSTRACT The main purpose of the study is to create a preliminary design guideline in mixing Controlled Low-Strength Materials (CLSM) using locally manufactured Class F fly ash by mixing actual CLSM and initial testing for fresh (flow consistency and setting time) properties. The main design target for CLSM is to ensure the mixes made are flowable, self-leveling, easy to pump in place, will not settle, will not exert uplift pressures due to swelling, and will be excavatable at later ages when specified. This study aims to determine the initial proportions of material components of CLSM, namely cement, Class F fly ash, fine aggregate, and water to ensure proper density, flowability, and ease of pumping. Mixes of increasing fly ash from the threshold content that satisfies flowability to the maximum allowed by ACI 229 are mixed, and tested for the main properties of flow (slump), density, and hardening. New adjusted mix proportions will then be made and tested for performance based on interpolations from the satisfactory trial mixes. From the actual data obtained, guidelines for mix design of CLSM will be made that would be of use to other designers. A general procedural manual will also be made based on the application of Class F fly ash in Controlled Low Strength Material mix designs after testing for hardened properties (excavility). Keywords: fly ash, CLSM, low-strength materials, class F fly ash 351 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Utilization of geopolymers in self-consolidating concrete K. Mermerdaş* 1, S.M. Oleiwi 2 1, 2 Department of Civil Engineering, Hasan Kalyoncu University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Self-consolidating concrete (SCC), is highly fluid concrete that can flow under its own weight through restricted sections without segregation and bleeding. Such concrete should have a relatively low yield stress value to ensure high flow ability, a moderate viscosity to resist segregation and bleeding, and to maintain its homogeneity during transportation, placing and cur ing to ensure adequate structural performance and long term durability Geopolymer concrete results from the reaction of a source material that is rich in silica and alumina with alkaline liquids. Geopolymer is an inorganic alumina-silicate polymer synthesized from predominantly silicon and aluminum materials of geological origin or by-product materials. The aim of this study is to further investigate the effect of alkaline activation content and size on fresh and hardened properties of the geopolymer self-compacting concretes, made by using fly ash and ground granulated blast furnace slag as source material and combination of sodium hydroxide and sodium silicate as alkaline activator. The conformity of self-compacting characteristics will be analyzed. Thereafter, the concrete satisfying the condition for self compactibility will be tested for fresh properties. Keywords: Self consolidating concrete, geopolymer, fresh properties, cement replacement 352 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Strength and Durability Characteristics of Soil Stabilized With Local Philippine Cements for Slope Protection Applications Jaime Angelo S. Victor* 1 and Lorielyn B. Martinez 2 1, 2 Institute of Civil Engineering, University of the Philippines Diliman, PHILIPPINES. (E-mail: [email protected], [email protected]) ABSTRACT Protection of in-situ soils is one of the most common methods of slope condition improvement. Weak surface soils often affect slope stability. The objective of this study is to investigate the effect of cement treatment to the shear strength and erodibility of stabilized soil. The results of the study are potentially useful for slope protection applications. Soil samples were collected and treated with three types of cement (Type I, Type IP and Type P) at 6%, 8% and 10% concentration by mass. To determine the specific effects of each cement type and amount, factors such as water content, size of the specimens and curing period were kept constant. Unconsolidated undrained shear strength of the samples was measured using Unconfined Compressive Strength Test, while the erodibility was determined by quantifying the percent of soil loss after exposing the specimens into an accelerated rainfall simulation setup with an intensity of 900,000 mm/hr. The shear strength and resistance to erosion of the treated soil were generally observed to increase with the incre ase in cement content. Both the shear strength and erodibility tests show that among the three cement types of cement utilized in this study, Type I cement is potentially the most efficient in stabilizing soil as slope protection material. Type P cement was observed as the least effective. Keywords: Slope Protection, Soil Stabilization, Cement, Compressive Strength 353 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Use of Fly Ash in Self Compacting Fiber Reinforced Concrete Pavements Şafak Bilgiç* 1, Mehmet Canbaz2 and Safa Mutyilmaz3 1, 2, 3 Eskişehir Osmangazi University, Civil Engineering Department, 26480, Eskisehir, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT An asphalt pavement contains some negative effects to earth health like thinning of the ozone layer, toxicity effect to human, acidification, depletion of biotic and abiotic life etc. Concrete pavements are more environmentalists. Additionally by using coal reactor waste fly ash in concrete content; more durable concrete can be produced. Pretty much fly ash can be used in concrete, during pavement construction. For example; in three – lane highway construction, average of 250 tons/km fly ash be evaluated. Besides with using waste fly ash some positive effects will be obtained. They are; decreasing hydration heat, reducing shrinkage cracks, increasing some strength values in the long term. So using fly ash is attractive. Large Concrete Pavement areas deficit to external effects, therefore some micro and macro cracks discernible. Concrete additive fibers are used to control the growth and branching cracks. In this study mechanical and physical characteristics were determined of fiber reinforced self compacting concrete produced with using constant cement ratio and different ratio of fly ash. For this purpose cubic, cylindrical, prismatic and plate shape of specimens were produced, then standard cure applied. According to the experiments using of waste fly ash up to 30 % rate is available on fiber reinforced self compacting concrete. Also when cement ratio fixed, the strength values of concrete are increasing up to 15%. Self compacting concrete requires more fine materials and these requirements are resolved by using fly ash. So the solution is more economical and environmental. By using fly ash, shrinkage cracks and hydration heat will decrease. Growing of micro cracks will be inhibited by using fibers. High abrasion resistance can be obtained by using high strength concrete on road pavement. Consequently, using of fly ash in concrete pavement is recommended for enhancing the performance of pavement and reducing the environmental impacts. Keywords: Concrete pavement, fly ash, self compacting concrete, steel fibers. 354 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Delamination modeling based on fracture and contact theories for multilayered composite plate E. Kormaníková* 1 and K. Kotrasová 2 1, 2 Department of Structural Mechanics, Institute of Structural Engineering, Faculty of Civil Engineering, Technical University of Košice, SLOVAKIA. (E-mail: [email protected], [email protected]) ABSTRACT Delamination is defined as the fracture of the plane separating two plies of a laminate or sandwich composite structure. A two-subplate sandwich model which incorporates interface models based on fracture and contact mechanics has been proposed in the paper. The main objective of the present paper is the characterization of the mixed-mode delamination in sandwich plates. To this purpose a mixed-mode delamination failure model is solved. This failure model is implemented in ANSYS code to calculate the damage propagation parameters. The analysis is based on the Finite Element Method (FEM) and interface techniques. The standard First Order Deformation Theory is used. Using FEM analyze a sandwich plate comprising two subplates is solved in the numerical example. Numerical results are given for typical mixed mode delamination problem by implementing the method in a 2D analysis, which utilizes shear deformable plate elements. These elements are joined at the interfaces inside each sublaminate using coupling elements. Finite element model and contour plot of displacements in x, y and z direction are designed. The individual components of spring reaction forces for response mode I, II and III along the delamination front are depictured. Expressions for point-wise energy release rates associated with the direction normal to the delamination plane (mode I) and normal and tangential directions to the delamination front (mode II and III, respectively) are given. The results point to which response mode is predominant or negligible in the delamination modeling. Keywords: Core, Delamination, Facesheet, Interface elements, Plate elements, Sandwich. Acknowledgment: The scientific research and the paper presented as its result were supported by the project VEGA 1/0477/15: Numerical analysis and modeling of interactive problems in multilayered composite structural members. 355 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Comparison of the Effect of Pre-stressed Strand Diameters, Providing Beam-to-Column Connection Mustafa KAYA PhD, Aksaray University, Faculty of Engineering, Aksaray, Turkey ABSTRACT In this study, the effect of pre-stressed strand diameters, providing the beam-to-column connections, was investigated from both experimental, and analytical aspects. In the experimental studies, the strength, stiffness, and energy dissipation capacities of the precast specimens comprising two pre-stressed strand samples of 12.70 mm, and 15.24 mm diameters, were compared with the reference specimen. The precast specimen with strands of 15.24 mm reached 96% of the maximum strength of the reference specimen; the amount of energy dissipated by this specimen until end of the test reached 48% of the amount of energy dissipated by the reference sample, and the stiffness of the same specimen at a 1.5% drift of reached 77% of the stiffness of the reference specimen at this drift. Parallel results were obtained during the analytical studies from the aspects of strength, and behavior, but the initial stiffness of the analytical models was lower than that of the test specimen. Keywords: Precast beam-to-column connection; post-tensioned connections, finite element method 356 moment resisting connection, ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Investigation of Concrete Quality in Aksaray Region Cihan Tanrıverdi* 1, Derya Koç 2, İsa Kayabaşı 3, İrfan Çıtak4 1 2 Secretary General of Special Provincial Administration, Aksaray, TÜRKİYE. ([email protected]) 3 4 Cömertler Construction Firm, Aksaray, TÜRKİYE. (cihantanrı[email protected]) Ulubaşlar Construction Firm, Aksaray, TÜRKİYE. ([email protected]) Department of Civil Engineering, University of Aksaray, Aksaray, TÜRKİYE ([email protected]) ABSTRACT Aksaray called as the gate of Cappadocia is located in the western part of Cappadocia. In this study, one of the aims is to obtain an idea about quality of concrete production in Aksaray region. The most important property that affects the quality of production is compressive strength, which contributes to other quality properties proportionately. Considering compressive strength of concrete and its variation according to streng level and years, the quality of concrete production is investigated statistically. Data that belong to 2010, 2011, 2012, 2013 and 2014 years are examined comprehensively and data that belong to previous years are also taken into consideration for the sake of comparison. Besides, the some modifications in standards are expressed and considered in this study. The concrete quality is investigated in terms of years and concrete classes on the basis of two statistical parameters, mean and coefficient of variation of compressive strength of cube samples. At the end of this study, it can be inferred that higher concrete classes has been used over the years. Besides, the mean concrete compressive strength is increased on the average of % 60. Keywords: Concrete, Quality of concrete production, Compressive strength, Coefficient of variation. 357 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Applicability and Limitations of 4 th Power Law in Design of Low Volume Roads against Rutting Volkan Emre UZ1, Mehmet SALTAN 2 and İslam GÖKALP 3 1, 3 Civil Engineering Department, Adana Science and Technology University, TURKEY. (E-mail: [email protected] , [email protected]) 2 Civil Engineering Department, Suleyman Demirel University, TURKEY. (E-mail: [email protected]) ABSTRACT A flexible pavement structural design consists of determining the properties of materials used in layers and the thickness design of these pavement layers under the certain traffic and climate conditions without reaching the terminal serviceability index over its design life. Rut accumulation (plastic deformation) is most common pavement failure type of flexible pavements. For that reason the main goal of the design is prevent rutting. Since the overlying layers constructed by selective high performance materials according to the related specifications many design manuals assume that rutting only occurs in subgrade. In fact the situation is not as much as reasonable especially for with no, or thinly overlaid low-volume road pavements, where the major structural layer is comprised of unbound granular material and where the principal distress mechanism is rutting in the aggregate or subgrade layers. The main input parameters in the design stage are subgrade bearing capacity (CBR,Mr,σd) and the design traffic. The “traffic” term is determined by Equivalent Standard Axle Load (ESAL) repetitions. The standard axle load usually is 80 kN single axle load. Although it is not too difficult to determine an axle load for an individual vehicle, it becomes quite complicated to determine the number and types of axle loads that a particular pavement will be subject to over its design life. A generalized 4th Power Law has been used for more than a half century to calculate Load Damage Factors of different load and axle configurations. The aim of this study is to indicate the limitations and difficulties faced on reliably applying a power law relationship to design or evaluation of granular pavements with no, or only thin seals, where the major structural layer is comprised of unbound granular materials and where the principal distress mechanism is rutting in the aggregate or subgrade layers. Furthermore, if a power law relationship should be used due to its simplicity than, the value of the power may vary over a large range as a function of several parameters. Such as stress dependent behavior of unbound granular materials and the selected distress type. Keywords: 4th Power Law, Plastic Deformation, Equivalent Single Axle Load, Granular Pavements. 358 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 N. İkiz* 1 1, 2 Civil Engineering, Gediz University, TURKEY. (E-mail: [email protected]) ABSTRACT The Ohio Department of Transportation (ODOT) pretreats the roadways of Ohio two times a week with 23% NaCl at 40 gallon/lane*mile application rate when weather conditions warrant. To be able to come up with the most effective anti-icing program for ODOT, field and laboratory investigation of pretreatment was studied on pavements. Brine decay was studied on highways ATH-50 PCC and PICK-23 AC versus time, traffic and humidity. The field tests for brine were conducted with modified versions of the SOBO 20 by Boschung Megatronic AG (YSI and Wally BO). Humidity values were obtained from RW IS data. The laboratory part included the detailed investigation of issues encountered in the field due to the grooved texture of concrete and porous texture of asphalt pavements. Correction factors for the salt readings on porous asphalt and grooved concrete surfaces were developed. Based on lab data grooved and porous surfaces appeared to decrease the efficacy of pretreatment. Correction equations due to pavement-fluid temperature difference were developed. A roadway field study was conducted on a nontrafficked road to study application of salt at two different truck speeds. An in situ test was conduct ed using CaCl2 and NaCl on street adjacent to Stocker Engineering building in order to compare the effectiveness of two anti-icing chemicals. CaCl2 survived on the pavement for about the same time compared to NaCl; however, it is seven times more expensive according to pretreatment needs of Ohio. The modeling of the salt decay on state roads provided statistically good results with high R2 values. The laboratory data were integrated with the field study results by the construction of a decision tree which is the product of this research. Remaining salt density after certain time or traffic can be found from the decay equations for porous and grooved pavements and the freezing point temperatures can be obtained before an ice/snow event. By this way, the personnel can decide when to pretreat and can know to what temperature extent the salt on the pavement is effective. Keywords: Anti-Icing, Brine Solution, ODOT, Pretreatment Acknowledgment: The author thanks to Ohio University and also to Ohio Department of Transportation their academic and financial support. 359 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Aspects of the Urban Transformation Process in Turkey Cigdem Avci-Karatas* 1 1 Asst. Prof., Department of Transportation Engineering, Faculty of Engineering, Yalova University, Yalova, TURKEY. (E-mail: [email protected]) ABSTRACT This work aims to analyze urban transformation process and applications in Turkey. To reach this goal, two major objectives are pursued: (i) to contribute to a better understanding of the urban transformation law in Turkey called as “Law on the Transformation of Areas at Risk of Natural Disaster” (Law no. 6306 dated 2012) and (ii) to analyze legal and technical dimensions of urban transformations processes in example city of Istanbul. The article concentrates on the second stage. The main conclusion of this work is that it is possible to obtain reasonably efficient aspects of the urban transformation process. Keywords: Urban Transformation,Turkey, Istanbul Acknowledgment: This paper has been produced with the assistance of the Republic of Turkey Ministry of Environment&Urbanization, Istanbul Infrastructure&Urban Transformation Department. The technical supports provided by the Republic of Turkey Ministry of Environment& Urbanization, Infrastructure&Urban Transformation Department on urban transformation law in Turkey are very much appreciated. The findings and conclusions presented in this paper are, however, those of the author alone. 360 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Alternative Signalized Intersection Design to Enhance Left Turn Efficiency Essam Radwan 1, Hatem Abou-Senna 2, and Sebastian Tabares3 1, 2, 3 Center for Advanced Transportation System Simulation, University of Central Florida, Orlando, Florida 32816-2450, USA. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Accommodating and addressing left-turning traffic has been a challenge for traffic engineers as they seek balance between intersection capacity and safety; these are two conflicting goals in the operation of a signalized intersection that are mitigated through signal phasing techniques. Exclusive left-turn lanes and protected left-turn phases are commonly used to minimize the impact of left-turning traffic. Cycle lengths typically have to increase and the addition of extra time from through phases must be sacrificed. This may contribute to an increase in delay or decrease in operational performance at these intersections. Hence, to increase the left-turn capacity and reduce the delay at the intersections, researchers and traffic engineers found protected/permitted left turn (PPLT) control to be the most effective, thus far. In addition to these operation treatments, new designs have been proposed to enhance left turn capacity including Continuous Flow Intersection, Diverging Diamond Interchange, Double Crossove r Intersection, Median U-Turn, Restricted Crossing U-Turn, Quadrant Roadway Intersection, and Roundabouts. This paper provides a comprehensive literture review of these design concepts and briefly assess their operational benefits and challenges. Based on the various reports and studies presented along with the advantages and disadvantages of each alternative, these alternative designs proved to outperform most conventional intersections and have enhanced arterials in various ways. Although there is not much field data available for some of these new designs, micro-simulation analyses showed that they are effective and improve safety and efficiency which are usually two conflicting goals. Majority of the alternatives showed positive results through simulations and field data. Keywords: Left Turn, Intersection Design, Traffic Signal Control. Acknowledgment: The authors thank the Florida Department of Transportation for their sponsorship of this project 361 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Waiting Time, Flow and Speed on U-turn Critical gaps at Median Openings under Mixed Traffic Suprabeet Datta* 1, P.K. Bhuyan 2 1, 2 Civil Engineering, National Institute of Technology, Rourkela, INDIA. (E-mail: [email protected], [email protected]) ABSTRACT The objective of this study is to deal with the effects of driver waiting time, conflicting traffic flow and speed on U-turn critical gaps at median openings without left-turn lanes. Video graphic data of nine conventional mid-block median openings on four and six lane urban roads were assembled. All these sites belong to the three cities of Bhubaneshwar, Rourkela and Ranchi situated in the eastern province of India. A new concept of “Merging Behavior” for U-turns is introduced for the first time to estimate critical gaps at these sites. Driver waiting times were calculated after processing the raw video data in the AVIDEMUX software. Conflicting traffic speed and flow were obtained in a similar manner. Flow was converted to standard passenger car units per hour (PCU/hr.) from vehicles per hour according to Indian traffic norms. The traffic composition was splitted into fo ur motorized vehicular classes for simplicity. Empirical relationships between critical gaps and all the other factors were formulated after performing regression analysis in Statistical Package for Social Sciences (SPSS) . The relationships thus formulated, concluded that conflicting traffic speed linearly affects U-turn critical gaps. Waiting time and critical gap followed power regression variation for all three modes except three wheelers (3W) which in turn followed a positive exponential variation. Also, longer waiting times affect U-turn critical gaps irrespective of the gap sizes. Critical gaps are also affected by conflicting traffic flow even durin g off-peak periods. At last, Vissim simulation outputs from the extracted field data are illustrated in order to signify the problems frequently encountered by U-turn drivers under mixed traffic situations. Keywords: Critical gap, INAFOGA, Gap acceptance, Median openings, U-turn vehicles Acknowledgment: The authors would like to express their special appreciation and thankfulness towards Dr. Partha Pratim Dey, Assistant Professor and Mr. Smruti Sourava Mohapatra, Research Scholar in the School of Infrastructure at Indian Institute of Technology, Bhubaneshwar for their kind assistance in providing the data required for this study. Also, the author would like to take this opportunity to express his sincerest gratitude towards IIT Bhubaneswar for allowing them collect all necessary audio-visual data which led to a successful completion of the study. 362 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Sustainable Landscape Maintanance for Highway Planning H.BOZKURT* 1, E.T.BOZKURT 2 1, Civil Engineering Department,Bilecik Seyh Edebali University, TURKEY (E-mail:[email protected]) 2 Landscape Architect. (E-mail: [email protected]) ABSTRACT Design and construction phases of a project set the stage for maintenance programs by planting and establishing vegetation consistent with engineering needs, safety standards, sustainability, and aesthetic considerations. Immediately after completion of a project and long afterward, vegetation maintenance influences road safety by reducing or increasing risk associated with roadside vegetation. Other safety issues for providing safe and reliable transportation include: Sustainable Landscape Maintanance approach is based on the principles of Integrated Vegetation/Pest Management which appropriately combines the use of mechanical, chemical, biological and cultural methods for controlling weeds and other pests. Similar to an Integrated Vegetation/Pest Management, Sustainable Landscape Maintenance is a decision-making process that integrates and applies the most appropriate vegetation management tools in a sustainable manner. This decision making involves that you continuously monitor, evaluate and modify these tools to meet the goals of roadside vegetation maintenance. Sustainable Landscape Maintenance is a continuous process evolving to meet the changing needs of roadside vegetation. In this study, it is investigated that sustainable landscape maintanance zone (LMZ) is the area along the roadsides. It extends from the edge of the road (usually the white line) into surrounding land (right-of-way). Roadside vegetation maintenance provides a safe driving experience. Sight distances must be maintained for important signs and intersections. Roadsides may provide a recovery area that allows drivers to pull off the road when necessary According to these explanations ;different factors may affect maintenance decisions, such as an urban versus rural landscape, property ownership boundaries or community expectations.It is also determined that how is planning sustainable highway lanscape factors. Keywords: Sustainable landscape, Highway planning, Vegetation/pest management 363 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effect of Lane Discipline to Intersection Capacity: A Sample Study of Isparta E. Eriskin 1, B. Capali*2, S. Sargin Karahancer 3, S. Gokova 4, M. C. Bayrak5, S. Terzi 6, M. Saltan 7 1, 2, 3, 4, 5, 6, 7 Department of Civil Engineering, Suleyman Demirel University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT Nowadays, many road users don’t adapt the lane discipline at intersections, so they wait more than two vehicles side by side in a two lane road. Thereupon when the light goes to green they all start to move. As a result, they move more slowly than expected because of giving way to each other to avoid congestion. The slowly move of the vehicles reduces the capacity level of the intersection and causes to pass less vehicles. In our study, an intersection is chosen where many of the road users don’t adapt the lane discipline. Then it is recorded how many vehicles pass the intersection and the delay in passenger car unit – hour per hour. In addition, the intersection delay and how many vehicles can pass will be calculated by using Webster method. Last of all the results and how the lane discipline influence the intersection capacity will be compared. Keywords: Lane discipline, capacity, delay, Webster method 364 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Examining the Effect of Sustainable Traffic Control of the Safety Belt and Helmet use : A Sample Study in Isparta B. Capali* 1, E. Eriskin 2, S. Sargin Karahancer 3, S. Gokova 4, M. C. Bayrak5, S. Terzi 6, M. Saltan 7 1, 2, 3, 4, 5, 6, 7 Department of Civil Engineering, Suleyman Demirel University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected], [email protected], [email protected], [email protected]) ABSTRACT In the world of fatal traffic accidents are the most important reason for the passenger and driver safety provided. Seat belts and helmets as an integral component in passenger and driver safety systems are proven to reduce crash injury risk. Seat belt and helmet save lifes. In this study, sustainable traffic control of the safety belt and helmet use were investigated in the city of Isparta in Turkey. Seat belt and helmet use, counts and survey were made in two street. With survey study, seat belt and helmet use by age distribution were determined. Counts were compared with two years ago counts. Seat belt and helmet use, change of the counts were investigated. Keywords: Traffic safety, accidents, traffic control 365 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Development of Regression Based Trip Generation Models for Intercity Bus Journeys in Turkey Yasar Vitosoglu* 1 1 Dumlupınar University, Faculty of Engineering, Department of Civil Engineering, TURKEY. (E-mail: [email protected]) ABSTRACT Using conventional methods based on home surveys or roadside interviews in order to determine origindestination (O-D) matrices is generally costly, time consuming and labor intensive. The validity of data is very short in developing countries where rapid changes occur in land use and demographic structure, and it is necessary to revise frequently the data obtained by using relatively inexpensive methods. Therefore, various methods that are cheaper and do not require intensive labor have been developed in order to form and revise O-D matrices. Thus, since the early 1980s, the idea of determining trip matrices from traffic counts has attracted attention of the researchers considerably, and various methods have been suggested on this subject. The model developed by Bell in 1983 is also one of these methods, and it has been used for obtaining the OD matrix related to intercity bus journeys made in Turkey. After this matrix was obtained, the total trip generations resulting from every province were calculated by founding the row totals in this matrix. Finally, regression analyses were performed in order to develop the trip generation models for the intercity bus journeys. In these regression analyses, the total trip generations resulting from every province were defined as dependent variable. As for independent variables, some macroeconomic and demographic indicators of provinces such as population and gross domestic product were employed. As a result, several trip generation models were developed for the intercity bus journeys made in Turkey. These models were also compared with respect to some statistical criteria such as r square values, t statistics and F statistics. Finally, the results obtained from this study were discussed briefly. Keywords: O-D Matrix, Regression, Trip generation. 366 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Why are trees still such a major hazard to drivers in Poland? Marcin Budzynski*1, Kazimierz Jamroz 2, Lukasz Jelinski3, Marcin Antoniuk4 1, 2, 3, 4 Gdansk University of Technology, POLAND (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Roadside trees are one of Poland’s most serious road safety issues. Since 2009 more than 2800 people have been killed as a result of tree collisions; this represents about 15% of all of Poland’s accident fatalities between 2009 and 2013. In some of the country’s regions striking a tree caused more than 30% of all road accident fatalities. With no proper regulations, guidelines or examples of good practice, roadside environments are posing a serious danger to safety. Trees pose a particular hazard. The paper analyses and evaluates the following factors which cause safety risks on roadsides with trees: strategic level: historic factors – tree alleys, high vehicle speeds, lack of road safety standards, tactical level – region, road class, length of road sections with trees, type of section, time, operational level – road narrowing forcing drivers to use the oncoming traffic lane (head-on collisions), limited visibility at junctions and exits (side crashes), blocking view of road signs (road layout lacking clarity, no place for pedestrians and blocking visibility at pedestrian crossings), causing damage to road infrastructure. The paper will present ways to eliminate risks caused by roadside trees and how effective they are in reference to the three levels: strategic level – ensuring that road layouts are clear and homogenous, vehicles remain in their lane, building safe roadside environments, securing hazardous objects, tactical level – building a new road, cutting down trees, putting in safety barriers, speed management, hazard notification, operational level – improving visibility using special marking or cutting down trees where they affect visibility at junctions, using the “2-1” layout, speed reduction, special marking. Finally, the paper will present the preliminary results of analyses studying the effects of trees on road safety. Models will be presented describing safety levels for different road categories and classes. Keywords: hazard identification, road safety, trees 367 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Road safety inspection as a tool for road safety management – the Polish experience Marcin Budzynski*1, Mariusz Kiec 2 1 Gdansk University of Technology, POLAND (E-mail: [email protected]) 2 Krakow University of Technology, POLAND (E-mail: [email protected]) ABSTRACT The road network in Poland, despite the transformations, still does not conform to safety standards, at the same time the lack of these standards is rarely given as the cause of road accidents. Lack of safety standards is associated with defects of the road network which directly threaten road users or encourage participants errors. It is necessary to identify and eliminate these defects and adapt the existing road network to the required safety standards. The defects are identified on the basis of conducted road safety inspections. Their implementation has been imposed on the EU member states by the European Directive 2008/96/EC on road infrastructure safety management. In Poland, road inspections were implemented in June 2014 on all national roads. Since 2013, approximately 300 people have been trained in the procedures and rules for the conducting of inspections. Previously conducted traffic surveys mainly related to the technical condition of roads, signs and markings; other safety issues were overlooked. The main problem that occurs during inspection is an inspector’s subjective qualitative assessment which affects the classification of the sources of hazard on the road. The result of incorrect classification of hazards can slow implementation of measures to improve traffic safety. The paper presents an analysis of the variability of the qualitative assessments of defects on the road, classified by different teams of inspectors. On this basis, the guidelines were developed for the classification of risks based on the relationship between sources of hazard on the road and the personal and economic losses of road accidents. These relationships are quantified using mathematical models to simulate the impact of the variability of a set of sources of hazard on the effects of selected causes of road accidents on the sections of road network. Keywords: inspection, models, road safety 368 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Polish district heating systems – development perspectives Krzysztof Wojdyga Faculty of Environmental Engineering, Warsaw University of Technology, POLAND. (E-mail: [email protected] ABSTRACT The most economical and rational means of heat supply for city inhabitants are district heating systems. Heat generated in power plants and large heat sources is cheaper than heat from individual sources. The reason for that is the amount of heat generated and the fuel used (coal for most heat sources). District heating, a very important energy sub-sector for the Polish economy, provides heat supply to centralised heating systems, which, on average, satisfy 72% of the demand for heat in Polish cities. Therefore, several million Polish citizens use heat from district heating systems that produce heat in professional, industrial and municipal power plants. In Europe, over 100 million citizens use district heating systems. The present situation of the Polish district heating sector is a result of Poland’s political transformation that took place at the beginning of the 1990s. The reform put the obligation of heat supply on the local authorities, on the municipality, instead of the state. Along with the transformation, district heating also made huge technological and technical progress. Increasing expectations of recipients posed new challenges for the branch, however. Keywords: District heating systems, Emissions of pollutants from LCP, Forecast of heat demand in DH, Polish energy mix in DH. 369 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Establishment of the Recycling Plants for Fresh Concrete Wastes: a Cost Management Perspective Aynur Kazaz* 1, Serdar Ulubeyli 2, Bayram Er 3, Volkan Arslan 4, Murat Atici 5 and Ahmet Arslan 6 1, 3, 5, 6 Department of Civil Engineering, Akdeniz University, TURKEY. (E-mail: [email protected], [email protected], [email protected], [email protected],) 2, 4 Department of Civil Engineering, Bulent Ecevit University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT In today’s competitive construction industry, ready-mixed concrete (RMC) batching plants should produce and operate in a green manner when the related legal regulations on the protection of natural environment and urban life are taken into account. According to the statistics about the concrete production in the world, the more the use of concrete over time, the worse the environment. One of the most important causes of this pollution is originated by concrete wastes. At the end of each working day, both residual and over-ordered fresh concrete in truck-mixers returns to RMC batching plants. However, for these wastes, there are fresh concrete recycling plants which make aggregate and water reusable and decompose sand and cement from the fresh concrete. In some countries, such plants are not popular because of financial and economic reasons, and thus, it becomes inevitable that the concrete waste pollutes the external environment. Similarly, it is reported that only 25% of RMC batching plants in Turkey have their own fresh concrete recycling plants and that most of them do not use them regularly. Therefore, in the current study, the establishment of such a recycling plant for fresh concrete wastes will be investigated from a cost management perspective. In doing this research effort, components of the life cycle cost analysis will mainly be examined. In fact, these are composed of all fixed and variable costs related with the investment throughout the recycling plant’s whole life. These costs can be listed as follows: (i) initial investment cost, (ii) operating cost, (iii) maintenance cost, (iv) salvage cost, (v) replacement cost, (vi) financing cost, and (vii) taxes. Consequently, in the scope of this study, the recycling concept in RMC batching plants will be discussed in detail from a cost-focused viewpoint, including the relevant research, practical, and social implications. Keywords: Concrete recycling plant, Concrete waste, Cost management, Fresh concrete, Life cycle cost. Acknowledgment: The authors thank TUBITAK Scientific and Technological Research Projects Funding Program for its financial support [Project number: 113M428]. 370 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Educational experiments performed on a model structure made up of Balsa Wood. A.Elif Özsoy* 1, H.Özkaynak2, M. Çağlar 3 and M.Şenturk4 1, 2, 3 Civil Engineering Department, Beykent University, TURKEY. ([email protected], [email protected], [email protected]) 4 Civil Engineering Department, Beykent University, TURKEY. ([email protected]) ABSTRACT In this study, educational dynamic tests were performed on a prototype structure which is made up of balsa wood in the content of a graduation project of civil engineering students. This study aims to highlight the importance of testing activities in the scope of civil engineering education incorporating with the structural dynamics and structural design topics. Civil engineering program covers several lectures which needs extensive laboratory and field activities. Some experiments should be performed in order to demonstate basic theory in the scope of the related course during the mid-term. Specifically, understanding how the structures respond to dynamic loads is of great importance for civil engineering students to enhance their engineering skills for the seismic design and assessment of structures. Thus, there is a need to improve the content of civil engineering undergraduate program integrating the structural design courses with experimental studies. This may be achieved by experiments performed on scaled models simulating the seismic excitation. Within the scope of this study, the students were assigned to design and construct a 3D moment resisting frame structure using balsa wood. One another group of undergraduate students were required to develop a home-made small scale shake table device. The displacement response of the model structure is recorded by a middle high speed camera which is capable of capturing 50 pictures per second. The analytical model is developed in SAP 2000 in order to compare the results with the data obtained from the shake table tests. As a conclusion, it was apparently observed that the graduate students were highly involved and motivated to the lecture and collaborated with each other. This project helped students to understand more in the basic concepts of structural and material behaviors to represent them with a simple analytical model. Keywords: Education, Civil Engineering, Structural Dynamics, Shake Table, Balsa Wood. 371 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Structure of Academic Surveying Programs in Nigeria as an Educational Pathway to Land Surveyor Registration 1 1,2 A.A Akinpelu*, 2A.O Abisuga Department of Building Technology, Lagos State Polytechnic, Nigeria. (1 [email protected],2abisuga_olatunji@ yahoo.com) ABSTRACT Nigeria as a nation is experiencing a shortage of qualified personnel within the surveying prof ession. This leads to the disorderliness of land administration in the country today. There is a need to cushion this problem by providing sufficient qualified personnel and entrants to the profession with appropriate training and education to meet the required professional certification to practice the surveying profession. A qualitative research approach was adopted for the study using content analysis and interview. The current structures of the academic programs and the registration and certification process for land surveying practices in Nigeria was reviewed. The basic academic challenges facing the profession were highlighted, and possible ways to improve the entrance of undergraduate to undertake a surveying program was also suggested. The recommendations of the study will benefit education policy maker’s and professionals in the built environment. Keywords: Academic, built environment, land surveying, land administration, surveying profession 372 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Examination and Comparison of Level for Radon Awareness at High School Institutions: A Sample of Nevşehir D. Sarıtaş* 1, M. Polat 2 1, 2 Elementary Science Education Department, Nevşehir Hacı Bektaş Veli University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT The aims of this study are to examine and compare high school students’ and teachers’ awareness’ levels for radon gas. It has also been investigated whether this levels of awareness is in relationship with outcomes that are related to harmful natural substances for environment and human health, in science curriculum. The sample of the study is composed of 554 randomly selected 9th and 12th grade students who are studying at three different schools (Anadolu High School, Science High School and Vocational High School) and 63 teachers that are employees in these schools in Nevşehir center. Survey method and document analysis were used as research method. Data were collected by questionnaire that designed by the authors within consideration the relating literature. Content analysis, Chi-square, independent T-test and Pearson's correlation technique was used to analyze the data. These findings at that stage in the study were obtained: Radon awareness of the students is at very low levels. For example; the 249 participants in the study (49.9%) stated that they heard from radon, but only 181 (32.7) stated that they know the radon. It was determined that outcomes that are related to harmful natural substances for environment and human health, in educational programs for all school types. However, it was observed that awareness levels of the students are not desired. Analysis of data for teachers is ongoing. This study is foreseen to offer environmental education and contribute to the field of literature relevant point for environmental awareness. Keywords: Radon Awareness, Education on Environment, Science Outcomes, High School, Nevşehir 373 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 AN INVESTIGATION INTO THE ENVIRONMENTAL SENSITIVITY IN SARAYÖNÜ Muhammed Kamil ÖDEN1*, Sezen KÜÇÜKÇONGAR2, Zehra GÖK1 1 Selcuk University, Sarayonu V.H.S., Environmental Pro. and Cont. Prog. Sarayonu/Konya-TURKEY [email protected], [email protected] 2 Selcuk University, Eng. Fac., Department of Environmental Eng., 42031/Konya-TURKEY [email protected] ABSTRACT The purpose of this study is to determine the environmental sensitivity and awareness level of the inhabitants in Konya, Sarayönü districts. In today’s world, the environment is rapidly being polluted and pollution rate is being increased by human beings. In this regards, the viewpoints of Sarayönü people on the environment and environmental elements are revealed. For this purpose, a research include variables such as gender, age, job and education level was carried out by using a questionnaire made up of 16 questions. The questionnaire was applied to 314 males and 286 females, totaling 600 participants. The research serves to raise an awareness of environment and environmental sensitivity. The findings showed that the people in Sarayönü have a high level of environmental sensitivity. Females tended to reflect a higher level of sensivitiy to the environment than males. The participants opted for air pollution as being the most important environmental element among the air, water, soil etc. pollution. Keywords: Environmental sensitivity, Environmental awareness, Environmental Pollution, Sarayönü, Statistics 374 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Education in the Field of Sustainability Assessment of Buildings S. Vilcekova* 1 and E. Kridlova Burdova 2 1, 2 Department of Environmental Engineering, Institute of Environmental Engineering, Technical University of Kosice, SLOVAKIA. (E-mail: [email protected], [email protected]) ABSTRACT The responsibility to coming generations for civil and environmental engineering education especially in sustainability building design and assessment will follow directly from these thoughts. All stages of buildings life cycle should be involved to education focused on sustainable buildings. Typical building construction, operation and demolition contribute significantly to environmental problems. The aim of sustainable building design and its assessment is to reduce the negative impact of the buildings on human health and natural environment during entire building life cycle. Sustainability assessment of buildings is a process that requires an integrated and multidisciplinary approach. It is important the cooperation among civil engineers, architects, environmentalists and other exp erts. The answer on the question why it is necessary to implant the sustainable building design and assessment into civil engineering education is based on the fact that human health problems and also indoor and outdoor environment problems are mostly connected with building engineering. The sustainable building sciences educational activities are particulars implement at Technical university of Kosice to Building Engineering study by various ways. The level of professional knowledge in this field depends on the study program. Sustainable building design graduate study contents parts concerning to economic benefit, planning and urban design, materials selection, energy performance, indoor environmental quality, renewable technology, water, sewage and waste management. We welcome to a new kind of science because it helps us to educate the highly complex problems of many scientific fields. Some basic considerations that may suggest a new view for understanding of relationships between architectural, building and environmental engineering will be presented in the paper. Keywords: Building, Education, Environmental Assessment, Sustainability. Acknowledgment: The authors thank Grant Agency of Slovak Republic (VEGA) for their financial support [Project number: VEGA 1/0405/13]. 375 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 GREEN CIVILIZATION STRATEGY (JAKARTA COASTAL MANAGEMENT OF THE CONCEPT BASED MANGROVE FOREST GREEN ENVIRONMENT IN THE FUTURE) Hadiana. Author * 1and Akrom Muflih. Author 2 1, 2 Department of Aquatic Resources Management, Faculty of Fisheries and Marine Science, Bogor Agricultural University. Indonesia (E-mail: [email protected], [email protected]) ABSTRACT Indonesia is a country that has the largest mangrove ecosystem in the world. However, the level of the highest mangrove ecosystem damage. The main threat is the mangrove ecosystem sustainability of human activities, such as creating a pond, deforestation, environmental pollution, and urban development without regard to ecological functions. Therefore, conservation and rehabilitation of mangrove forests is one of the efforts to conserve the coastal environment are important ecosystems, pelestarikan also be in line with the development of coastal areas. Based on the available facts indicate that technological progress and development that took place in the city to make green environmental degradation healthy and pollution meningkanya pollutants into the environment. Alternative management of coastal areas that we ask is the concept of 'green stategy civilization', namely the planning and management of coastal cities that promote green plant functions such as mangrove trees as well as a major resource for the development of tourist attraction of the city. Mangrove forest resources (in this case-shore coastal waters and estuaries) used as the central point of the development of other aspects of development, such as economic activity, industrial, social activities, urban architecture, tourism, and others. This concept rests on the paradigm that the biological resources of coastal areas, namely as a primary resource for the development of a tourist area in synergy with the development of the city. This concept utilizes especially the coastal city that has the mangrove forest area that is wide enough that the city of Jakarta. The concept of good urban planning needs to be done in line with the management of urban development, but the application must be supported from all stakeholders both government policy, private, and community to the achievement of which is expected to happen and make the city as a center of civilization Jakarta Indonesia with the greening of the city and surroundings healthy. Keywords: Green, alternative, mangrove, forest. 376 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Modeling of Drying Kinetics of Potatoes and Fresh Carrot in South Algeria. S. MANAA* 1,2, N. MOUMMI 2 and D. KARLO 1 3 Hydrocarbon and Renewable Energy Department, Faculty of Science and Technology, African University of ADRAR -ALGERIA. (E-mail: [email protected] ) 2 Mechanical Engineering Department, University of Biskra , Biskra-ALGERIA. (E-mail : [email protected]) 3 The Laboratory of Solar Energetic and Building Physics (LESBAT), High School of Engineering and Management, Western Switzerland, SWITZERLAND. (E-mail : [email protected] ) ABSTRACT Drying the solid product based on the balance between the water contained in the product and water in gaseous form in air. This equilibrium can be promoted in a direction or the other according to the water content of the air and product. Thus, to dry a solid by training, said dry air (that is to say, that has a low water content) is broken above the product, the water balance will tend to increase the water content of the dry air (this water comes from the water held by the product). Since air is constantly renewed, the water content of the product decreases more and more. But there is always a certain water content in the product cannot be removed, the water is bound water, and she enters the product composition. This work concerned the study of the influence of the drying parameters on the water loss of the potatoes and carrot. This study was undertaken in a drier designed and produced in a arid area. Drying was carried out at various temperatures 45; 50 and 55°C and at various speeds of the a ir circulation (0.5;1 and 1.5 m/s). The water content initial of the carrot and potatoes samples were 90% and 78%. We followed during drying, the loss of weight of the samples. It arises from the results that the temperature and the air velocity drying have a significant influence over the time of drying. The modeling of the experimental data shows that the exponential model represents perfectly the behavior of this products; some is the cases of figure considered. This work would allow a better valorizat ion of the local resources, the reduction of the losses post harvests, the reduction of the consumption of energy. Keywords: Modeling, drying parameters, water loss, drying kinetics, vegetable. 377 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Lining Concrete Cooling Towers on the Growth of Legionella pneumophila Kamal R. Jaroor 1,*, Munjed A. Maraqa2 and Khaled A. El-Tarabily3 1 Facilities Management Department, Khalifa University, UNITED ARAB EMIRATES. (E-mail: [email protected]) 2 Civil and Environmental Engineering Department, United Arab Emirates University. UNITED ARAB EMIRATES. (Email: [email protected]) 3 Department of Biology, United Arab Emirates University, UNITED ARAB EMIRATES. (E-mail: [email protected]) ABSTRACT Efforts to minimize Legionella pneumophila counts in cooling towers greatly depend on the level of understanding of the factors that promote the growth of the bacteria in these systems. Rough (unlined) concrete surfaces may facilitate the formation of biofilm that acts as a harbor for L. pneumophila and may create water stagnation within the exposed large pores that enhance their growth. In this study, the effect of lining cooling towers interior walls with a ceramic-like material on the growth of L. pneumophila was investigated. The cooling tower at Dubai Hospital, United Arab Emirates and constructed concrete tanks were utilized to determine L. pneumophila counts during the hot and cold seasons. The constructed concrete tanks consist of two tanks; one lined and the other unlined. Both water and swab samples from the lined and unlined cooling tower and concrete tanks were analyzed for L. pneumophila counts over a period of 10 weeks in each season. Results revealed that lining the interior walls of concrete tanks does not eliminate L. pneumophila but reduces its growth by about 45%. The results were consistent for both swab and water samples. This study further revealed that there is an enhanced growth of L. pneumophila during the hot season as compared with its growth in the cold season, but the increase was generally less than double with a 14.3 oC increase in temperature between the two seasons. Keywords: Biofilm, Cooling tower, Legionella pneumophila, Lining; Temperature 378 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Experimental Study of Natural Sorbent for Oil Spill Jenan A. Al-Najar*1, Asawer A. Alwassiti 2 and Şerife Saçmacı3 1 Chemical Engineering Department, University of Technology, Iraq. (E-mail: [email protected]) 2 Petroleum Technology Department, University of Technology, Iraq. (E-mail: [email protected]) 3 Chemistry Department, University of Erciyes, Turkey, Kayseri. (E-mail: [email protected]) ABSTRACT Oil spill pollution is one of the most important issue in recent decade, due to its impact on environment. There are many methods to reduce the impact of oil spill including the using of adsorption process. In recent years, there is a great attention in using natural material in this process. This research in vestigate the use of peel beans as a natural sorbent in oil spill treatment. The effect of different parameters such as particle size, weight of sorbent and time on adsorption rate were studied. The sorbent material was characterized using FTIR and SEM technique. The adsorption rate was calculated depending on spectrophotometer analyzing. The results show that the peel beans has a high oil sorption capacity and this capacity increases with decreasing particle size. The equilibrium data were analyzed by Langmuir and Freundlich isotherm models. The kinetic of adsorption was studied using different models. Keywords: Adsorption, Natural Sorbent, Oil Spill, Peel Beans . Acknowledgment: The authors thank Instrumental Analysis Laboratory in University of Technology for their help during this study. 379 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The impact of different growth media on the algae development : an association with atmospheric dust Adeleh Rashidi, Aydın Akbulut and A. Cemal Saydam Hacettepe University, Department of Environmental Engineering, Ankara, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Environmentally algae is an essential plant like organism since they can trap solar light energy and use this energy via photosynthesis and to produce food in the from of complex sugar molecules. Ecologically algae are important since microscopic algae are the source of much of Earth's oxygen and they are also act as a sink for atmospheric carbon dioxide. Algae are also very important ecologically because they are the beginning of the food chain for other animals at both directions since upon termination of their life cycle they are consumed by organisms called decomposers mostly fungi and bacteria. Thus environmental factors that control their lifecycle are outmost importance for ecology. Its further known that atmospheric dust during the course of their long-range transport can be altered within the clouds via the action of its bacteriological fraction and results with the formation of reduced iron various essential trace elements and amino acids. The association of the growth of Spirulina platensis and atmospheric dust has been investigated before and it has been found that equal and better growth can be achieved by using atmospheric dust as compared to Zarrouk growth solution. This time we have investigated the impact of atmospheric dust on the growth of Chlorella and Scenedesmus obiquus by using BBM growth media and on Spirulina platensis by using BG11 growth media. Once again it have been shown that algae growth parameters obtained by using atmospheric dust is comparable and if not better than those obtained by using solutions composed of various chemicals that are assumed to be an ideal growth solutions. We have further tested the most effective atmospheric dust concentrations and found that 10 g/l concentration serves as a best growth medium. Keywords: Algae, Dust, Growth Medium 380 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Opportunity for the Sustainable Ecological Renewal: European Green Capitals Nur Sinem ÖZCAN* 1 1 City and Regional Planning Department, Dokuz Eylul University, TURKEY. (E-mail: [email protected] / [email protected]) ABSTRACT The demand for the natural resources is constantly increasing to meet the energy requirements due to the growth in population and economy. Many countries have led to reconsider their energy policies because of the increasing energy requirement and the awareness of the fact that the world’s natural resources are limited. Since the early 1990s, many authorities have undertaken crucial enterprises in order to create awareness of global issues. The Earth Summit in Rio (1992), the Kyoto Protocol (1997), the Copenhagen Accord (2009), the Rio+20 Conference (2012) are examples for these enterprises. The Earth Summit in Rio is regarded as a landmark in terms of global collaboration and the "sustainable development" concept has been first put forward in this summit. The aim of the study is to examine “European green capital” cities which are constitute d as examples for other world cities in terms of the environmental policies and to evaluate these cities’ policies comparatively. These policies include minimizing problems in the environment that is one of components of the sustainable development, reconsidering the limited natural resources and developing the renewable energy sources. In this context, the selected cities as “European green capital” are examined such as Stockholm, Hamburg, Vitória - Gasteiz, Nantes, Copenhagen and Bristol. Also, the selection criteria are discussed using the selection process of the green capital city. As a method, the qualitative comparison method is used. The statistical values are obtained from World Widelife Fund, the official web sites of the European Green Capital and selected cities. As a result, it’s found that the urban renewal attack is not only a concept which examined the spatial and economic dynamics, but a change opportunity to show sensitivity to the ecology and natural environment as an ecological renewal. Additionally, the consumption and dissemination of renewable energy sources have become more necessary instead of the use of fossil fuels. Keywords: Ecological renewal, green capital, natural environment, renewable energy sources, sustainable development 381 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Compaction Mitigation Potential of Biotillage and Subsurface Tillage in Dairy Pasture Soils Josef H. Görres*1 Rachel Gilker2 Jenn J. Colby2 Korkmaz Bellitürk3 1 The University of Vermont, Plant and Soil Science, Burlington/Vermont/USA (E-mail: [email protected]) 2 Center for Sustainable Agriculture, University of Vermont, Burlington Vermont (E-mail: [email protected] and [email protected]) 3 Namık Kemal University, Faculty of Agriculture, Department of Soil Science and Plant Nutrition, Tekirdağ/Turkey (E-mail: [email protected]) ABSTRACT In the majority of dairy and beef cattle production, herds are kept in concentrated feedlot operations. However, recently environmental and food quality concerns have resulted in a trend that puts cattle back on pastures. Pastures maintained year-round reduce nutrient runoff thereby preventing impact of dairy and beef production on freshwater ecosystems. However, pastures have to be appropriately managed to remain productive. High pressure exerted on soils, particular when wet, by cattle hoofs can cause serious compaction jeopardizing the benefits of pasture production. Modern, rotational grazing systems allow longer recovery periods for forage thus increasing productivity and the concomitant environmental benefits for water quality. However, the high animal densities in small paddocks may exacerbate the compaction problem. Rotational grazing systems need to be engineered to either avoid compaction or to include a component that rejuvenates soils annually. We investigated two agricultural systems for pasture soil rejuvenation: Biotillage with Daikon radish (Raphanus sativum) and subsurface tillage by key line plowing. Both methods affected several soil quality parameters positively. In particular, the observed 30% reduction in volumetric soil moisture in the treated pastures can help prevent soil compaction and lengthen the time that the pastures can be used every year. In addition, 30 – 40% increase in earthworm populations indicated better fertility in the treated pastures. Thus, alternative methods of compaction mitigation show potential to become part of well-designed rotational pasture systems. As such they are important component of practices that can reduce the environmental impact of dairy production. Keywords: Agroecology, Rotational Grazing, Mitigation of Soil Compaction, Biotillage, Soil Quality Acknowledgment: Funding for this project was provided by the University of Vermont’s Agricultural Experiment Station through a Hatch Grant, the USDA Natural Resources Conservation Service through a Conservation Innovation Grant, and The Scientific and Technological Research Council of Turkey (TÜBİTAK) through a Visiting Scientist Grant. 382 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Environmental Contamination and Residential Exposure of Mercury in Artisanal Gold Mining Area in Benguet, Philippines Ma. Brida Lea D. Diola* 1 and Augustus C. Resurreccion 1 1, 2 Institute of Civil Engineering, University of the Philippines - Diliman, PHILIPPINES. (E-mail: [email protected], [email protected]) ABSTRACT One of the primary sources of mercury (Hg) emission into the environment is artisanal gold mining. The study site for this research is the municipality of Tuba in Benguet Province, Philippines which is known for artisanal mining activities. Untreated wastewater from the processing plants, which may contain Hg and other heavy metals, may contaminate receiving water bodies, such as Bued River. This study aims to investigate mercury contamination in different environmental media in the study area in which residents can possibly be exposed to. Also, this study estimates the exposure and daily intake of mercury of the residents. Surface water and bottom sediments in 14 sampling points from upstream to downstream of Bued River and its tributaries were collected monthly from November 2013 to March 2014. Fish, drinking water, soil and hair samples were also collected. All samples were analyzed for Hg content using flameless cold-vapor atomic absorption spectrometry (AAS). The results of this study showed that all Hg measurements in surface water were within the 2 ppb limit set by the Philippine standard (DAO 34). Hg in sediments ranges from 0.004 to 2.1 mg/kg. Significantly higher concentrations were observed in areas near mining sites. Several sampling points were observed to have exceeded the Canada Sediment Quality Guidelines threshold effect level (0.17 mg/kg). Hg in drinking water and fish samples were found to be below detection limits while Hg in residential soils ranges from 0.1-1.5 mg/kg. Hair Hg concentrations range from 0.03 to 24.17 ppm with a geometric mean of 0.224 ppm. Elevated concentrations of Hg in hair may be due to direct external exposure to mercury vapor. The average daily intake dose derived from the hair Hg measurements was estimated to be 22 ng/kg-bw/day, within acceptable limit. The results of this study can be used in human health and ecological risk assessments. Further study is recommended to determine if remediation of the area is needed. Keywords: Artisanal, Benguet, Exposure, Mercury, Mining Acknowledgment: The authors thank the Department of Science and Technology (DOST) and the Mineral Extraction with Responsibility and Sustainability (MinERS) program for funding this research. 383 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Mathematical Modeling of the Drying Kinetics in Thin Layers of the Local potato of Adrar S. MANAA* 1,4, A. BEATRIZ 2, D. KARLO 3 and N. MOUMMI 4 1 Hydrocarbon and Renewable Energy Department, Faculty of Science and Technology, Ahmed Draia University - ADRAR -ALGERIA. (E-mail: [email protected] ) 2 National Food Institute, Technical University of Denmark, Kgs. Lyngby, Copenhagen, Denmark. (E-mail : [email protected] ) 3 The Laboratory of Solar Energetic and Building Physics (LESBAT), High School of Engineering and Management, Western Switzerland, SWITZERLAND. (E-mail : [email protected] ) 4 Mechanical Engineering Department, University of Biskra , Biskra-ALGERIA. (E-mail : [email protected]) ABSTRACT The aim of our work is to study the behavior of the local potatoes of Adrar during a drying operation by hot air. Also we are interested in the macroscopic experimental approach is to determine the kinetics of potatoes during their drying under conditions of temperature and air flow controlled. The experimental curves of drying obtained are approximated by four mathematical models, empirical and semi theoretical, existing in the literature in order to describe the convective drying in thin layers of the variety of potato studied. A determination of the desorption isotherms was carried out. The obtained desorption curves are then approached by a semi-theoretical model to determine the equilibrium moisture content of the product investigated. Keywords: Modeling, Drying kinetics, sorption isotherm, potatoes. 384 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Detoxification Of Aflatoxin B1 In Various Foods By Nocardia Corynebacteriodes Nrrl B-184 ZORLUGENÇ Bülent* 1, EVLİYA, İbrahim Bülend 2 1, ZORLUGENÇ, B., Food Engineering Department, Nevşehir Hacı Bektaş Veli University Engineering and Architecture Faculty. TURKEY (E-mail: [email protected]) 2. EVLİYA, İ.B., Food Engineering Department, Çukurova University Agriculture Faculty. TURKEY (E-mail: [email protected]) ABSTRACT In this study, the ability of Nocardia corynebacteriodes NRRL B-184 strain to remove aflatoxin B1 in PB solution and dry red pepper, corn, black olive, soy bean, dry fig and also hazelnut, was investigated. The activated N. corynebacteriodes strain was incubated in TSB at 30°C for 95 h and growing curve was obtained. According to non-linear regression analysis, Modified Gompertz model was fitted best with experimental data. The µmax and λ were found as 0.073 h-1 and 5.244 h-1, respectively. It was observed that N. corynebacteriodes strain increased by 2.7 log and reached to the stationary phase within 45 h. The bacteria were still in that phase at 95 h. First order reaction kinetics was fitted best with the degradation kinetics in PB and food mediums. In PB medium, the “k value” was found higher and followed by milled dry fig and whole black olive. At the end of incubation, the reduction of aflatoxin B 1 content were resulted in the range of 84.28% and 98.84% at soy bean and hazelnut, respectively. After incubation, aflatoxin content of milled red pepper, dry fig and hazelnut that contain 500 ng g-1 aflatoxin B1 and whole hazelnut (1000 ng g-1 aflatoxin B1) was decreased to permitted level of this toxin in Turkish Food Codex. Keywords: F. aurantiacum, N. corynebacteriodes, Aflatoxin B1, Detoxification, Kinetic Acknowledgment: The authors thank Çukurova University, Scientific Research Project Funding (ÇUBAP) for their financial support [Project number: FBE2001 D106]. 385 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Cypermethrin induced changes in oxidative stress biomarkers in Paramecium tetraurelia and elevation effect of some antioxidant Amamra Rima*1, Djebar Mohamed Reda1, Moumeni Ouissem1, Azzouz Zoubir1,Alayat Amel1, Otmani Hadjer1, Benamara Marwa1, Zeriri Ibtissem1, Atailia Amira1, Benosman Sana1, Berrebbah Houria1 1 Laboratory of Cellular Toxicology, Department of Biology, Faculty of Sciences, Badji Mokhtar University, Annaba, ALGERIA. (E-mail: [email protected]) ABSTRACT Oxidative damage by increased production of reactive oxygen species have been involved in the toxicity of several pesticides. Thus, the aim of this study was to investigate the effect of cypermethrin, a widely used type II pyrethroid, on the oxidative stress biomarkers and the respiratory metabolism of Paramecium tetraurelia. Increasing concentrations of the insecticide were incubated with paramecium cells. The 96h (IC50) was determined. Variations in lipid content and oxidative stress biomarkers such as: Malondialdehyde (MDA), Glutathione (GSH), Glutathione peroxidase (GPx) and Catalase (CAT) were carried. Moreover, respiratory metabolism was followed up. The estimated 96h (CI50) value for Paramecium tetraurelia exposed to cypermethrin in our study was in a range of µg/l. Decrease was observed in total lipids content. Cypermethrin exposure has led to a lipid peroxidation supported by a significant increase in (MDA) level which might be associated with decreased level of (GSH). (GPx) and (CAT) activities, antioxidant enzymes, were significantly induced. The response was concentration dependent especially for the highest concentration. A strong disturbance in respiratory metabolism was observed. In summary, under the current experimental conditions, cypermethrin has show a toxic effect to the freshwater ciliate Paramecium tetraurelia. Exposure to low concentrations showed significant adverse on growth accompanied with the induction of oxidative damage supported by the respiratory activity. Keywords: Biomarkers, Cypermethrin, Oxidative stress, Paramecium tetraurelia, Respiratory metabolism. 386 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Two Ornamental Plants for Phytoremediation of Cd-Contamined Soil Seydahmet ÇAY1*, Ahmet UYANIK2 1* Environmental Engineering Department, Faculty of Engineering, Giresun University, Giresun, Turkey. (Email: [email protected]) 2 Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayıs University, Kurupelit, Samsun, Turkey. (E-mail: [email protected]) ABSTRACT The use of living plants to clean contaminants from soil, surface and groundwaters called phytoremediation has a great environmental potential in recent years. Most ornamental plants do not place in food chain, therefore they may safely be employed as an alternative for the environmental cleaning purposes. It is well known that ornamental plants present many advantages including abundant species, exuberant vitality, fast growth and also beautifying the natural and designed environment. Little information, however, is available on their use and abilities to remediate especially contaminated soils. In this study, two ornamental plants Lonicera japonica Thunb and Salvia virgata Jacq. (Lamiaceae) growing in the natural vegetation of Black Sea Region were investigated for their potential use in the removal of Cd(II) from artificially contaminated soil of 10, 25, 50 ve 100 mg kg-1 concentration. The study was conducted as a pot experiment in MaySeptember 2013 at the Botanical Garden of Gazi Boarding School, Vezirköprü, Samsun, Turkey (N41°08.699’, E035°26.248’). The results of the study suggest that two selected ornamental plants have a tolerant ability to live in Cd(II) contaminated soils, but Salvia virgata shows greater ability than Lonicera japonica. In addition, Lonicera japonica has greater values in BCF or TF than that of Salvia virgata. It may be concluded that studied ornamental plants show remarkable potential to be used for phytoremediation of Cd(II) contaminated soils and using ornemental plants seems to be a promising alternative of the future. Keywords: Cd, Lonicera japonica, ornamental plant, Phytoremediation, Salvia virgata. Acknowledgements: The work was financially supported by Ondokuz Mayis University Project Office (No: PYO-FEN 1904.12.008). 387 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Chickpea Ascochyta blight disease severity in the Bosphorus region of Turkey S.Bulgak1, F.N. Kafadar2, K. Sarpkaya 3, C.Can4 , S.Güneş5 1, 2 Biology Department, Gaziantep University, Gaziantep (E-mail: [email protected], [email protected]) 3 Pistachio Research Station, Gaziantep (E-mail: [email protected]) 4,5 . Biology Department, Gaziantep University, Gaziantep (E-mail: [email protected], [email protected]) ABSTRACT Chickpea (Cicer arietinum L.) is an important crop plant in which consumed both as appetizers and culinary manners. Chickpea has an important proportion among legumes that is planted on 3.885,175 ha in Turkey and the yield is 450.000 tones (TUIK, 2014). Ascochyta blight caused by Didymella rabiei (Kovachevski) von Arx [anamorph: Ascochyta rabiei (Passerini) infects both cultured and wild chickpea species (Cicer spp) and was reported from all the chickpea growing countries in the world, as the main disease restricting yield and seed quality. This study aimed to investigate Ascochyta blight disease incidence in chickpea growing provinces of the Bosporus region of Turkey. Chickpea fields of Çanakkale, Bursa, Tekirdağ, Bilecik and Balıkesir provinces were surveyed in 2014 and the plants were evaluated according to the 1-9 scale for disease severity (Reddy and Sing, 1984). Nodulation, altitude and weed density were also determined in a total of 65 fields. Disease severity values were 34,78%, 30,75%, 21,75%, 45,09% and 69,5% for Bursa, Balıkesir, Bilecik, Çanakkale and Tekirdağ, respectively. Tekirdag and Çanakkale provinces had the highest Ascochyta blight disease incidences. Correlations of disease incidences with altitude, nodulation and weed density is discusses to explain the differences among provinces of the Bosporus region. Keywords: Ascochyta blight, chickpea, disease incidence, Bosporus region Acknowledgement: This study was supported by The Scientific and Technological Reserch Council of Turkey (TUBİTAK) with Project number 1130071 388 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Elevated salinity effects on white clover (Trifolium repens L.) growth A. Karlsons*, G. Cekstere Institute of Biology University of Latvia, LATVIA. ([email protected]) ABSTRACT The aim of this research was to examine the effect of different salinity levels and K supply induced responses and tolerance in the T. repens L variety ‘Daile’, a variety which is used in urban greenery. To analyze the impact of increased soil salinity and antagonistic effect of K, gradually rising NaCl (0; 20; 40; 60; 80; 100 mM) and K (+0; +100; +200; +300 mg/l) levels were used in a pot experiment. Concentrations of 12 nutrients and Na, Cl in the plant shoots and roots were determined, as well as plant weight, Pv/Fm, P index (photosynthetic performance) and proline content. The results revealed that increased substrate salinity led to accumulation of both Na and Cl- in tissues of T. repens. Na and Cl concentrations in the plant above ground parts showed linear growth, but in the roots content of both elements reached its saturation at 20 mM. High NaCl concentrations in the substrate significantly reduced Mg, but increased Na, Cl- accumulation in the plant shoots. In the roots significant decrease of N, K, Mg, S, Mo and increase of Na, Cl-, Ca, Fe, Mn, Cu, Zn content was stated. Elevated soil salinity showed a slight impact on the photosynthetic performance of T. repens. Significant decline in the fresh and dry biomass of the plant shoots was stated under all salinity treatments. In conditions of increasing soil salinity and K content in the substrate T. repens possessed several mechanisms of adaptive value, as well as changes in mineral nutrition. According to the results, cultivation of T. repens variety 'Daile' in urban areas with slight or moderate salinity is possible. Keywords: salinity stress, sodium chloride, white clover Acknowledgment: The study was financially supported by the European Social Fund, the project No. 2013/0060/1DP/1.1.1.2.0/13/APIA/VIAA/041. 389 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Application of Artificial Neural Networks for Growth Forecasting of Crayfish (Astacus leptodactylus Eschscholtz, 1823) Semra Benzer* 1, Recep Benzer 2 and Çağlan Karasu Benli 3 1 Gazi University, Gazi Faculty of Education, Ankara, TURKEY (E-mail: [email protected]) 2 3 Gazi University, Institute of Information, Ankara, TURKEY (E-mail: [email protected]) Gazi University, Institute of Natural and Applied Sciences, Ankara, TURKEY (E-mail: [email protected]) ABSTRACT An evaluation of the performance of artificial neural networks (ANNs) to estimate the metric properties of crayfish (Astacus leptodactylus Eschscholtz 1823) from Eğirdir Lake that uses measured predictor variables in presented, including total length (TL), total weight (TW); carapace length (CL), total weight (TW); carapace length (CL), total length (TL), chlea length (ChL), total weight (TW); sex (male, female and all individual). We present the relationships between total length (TL), total weight (TW); carapace length (CL), total weight (TW); carapace length (CL), total length (TL) and chlea length (ChL), total weight (TW) for Astacus leptodactylus from Eğirdir Lake between 2013 and 2014. The research was used 222 (75 female, 147 male). The research was found as 66 % male, 34 % female of crayfish thought investigation female and male ratios was of determined as to 0.51/1.00. Results of the research can be seemed as follows; avarage total length 128.40 mm for female 135.50 mm for male, average total weight 59.79 g for female 82.95 g for male. Lengthweight relation equation was found for females W = 0.05425196 x L 2.74, for males W = 0.05272102 x L 2.81 and for all gender W = 0.03589889 x L 2.94. The results obtained by artificial neural networks and lengthweight relation equation are compared to those obtained by the growth rate of the crayfish caught from the natural environment. Length-weight relation and artificial neural network MAPE results were examined. It was found MAPE value of the forecast of ANNs as a 0.846 and 2.508, while MAPE value of relationship results as a 2.142 and 3.132 for lentgh – weight of all gender. Artificial neural networks gives better results than length-weight relation. Artificial neural networks can be alternative as a evaluated for growth estimation. Keywords: Artificial Neural Networks, crayfish, length-weight relation. 390 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Comparison between traditional methods and artificial neural networks for growth forecasting in crayfish (Astacus leptodactylus Eschscholtz, 1823) Semra Benzer* 1, Recep Benzer 2 and Çağlan Karasu Benli 3 1 Gazi University, Gazi Faculty of Education, Ankara, TURKEY (E-mail: [email protected]) 2 3 Gazi University, Institute of Information, Ankara, TURKEY (E-mail: [email protected]) Gazi University, Institute of Natural and Applied Sciences, Ankara, TURKEY (E-mail: [email protected]) ABSTRACT This study aimed to determine some morphological characteristics of freshwater crayfish (Astacus leptodactylus Eschscholtz 1823) populations and to study length-weight relation and artificial neural networks for growth in crayfish between 2006 and 2007 in Mogan Lake. We present the relationships between total length (TL), carapace length (CL), chelae length (ChL), abdomen length (AL) and total weight (W) for Astacus leptodactylus from Mogan Lake. The research was used 112 (14 female, 98 male). The research was found as 87.5 % male, 12.5 % female of crayfish thought investigation female and male ratios was of determined as to 0.143 /1.00. Results of the research can be seemed as follows; avarage total length 108.71 mm for female 102.93 mm for male, average total weight 28.64 g for female 32491 g for male. Length-weight relation equation was found for females W=0.0022 x L2.01 for males W=0.00095 x- L2.23. The results obtained by artificial neural networks and length-weight relation equation are compared to those obtained by the growth rate of the crayfish caught from the natural environment. Length-weight relation and artificial neural network MAPE results were examined. It was found MAPE value of the forecast of ANNs as a 0.507 and 1.323, while MAPE value of relationship results as a 3.006 and 1.742 for lentgh – weight of all gender. Artificial neural networks gives better results than length-weight relation. Artificial neural networks can be alternative as a evaluated for growth estimation. Keywords: Artificial Neural Networks, crayfish, length-weight relation. 391 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Zinc Oxide Nanoparticles on Hemocytes of Galleria mellonella (L.) (Lepidoptera: Pyralidae) Z. Ulya NURULLAHOĞLU 1, Ata ESKİN 2* and Serhat KAYA 3 1 Marmara University, Faculty of Science and Arts, Department of Biology, Istanbul, TURKEY (*[email protected]) 2 Nevşehir Hacı Bektaş Veli University, Avanos Vocational School, Crop and Animal Production Department, Nevşehir, TURKEY, 3 Çanakkale Onsekiz Mart University, Faculty of Science and Arts, Department of Biology, Çanakkale, TURKEY. ABSTRACT In recent years, the use of nanoparticles has been rapidly increasing due to development of nanotechnology. Zinc oxide nanoparticles (NPs) are being widely used in electronic and fotonic devices and also sunscreens. The broad use of NPs raises concerns regarding potential environmental health risks and also they may induce significant DNA damage and cytotoxicity. Metal and metal oxide NPs present a series of challenges for terrestrial ecotoxicology. Therefore, because of the increasing use of industrial and commercial NPs, how to make an impact in terms of the organism and ecosystems are being studied. The Greater Wax Moth, Galleria mellonella is distributed in many places of the world and since its larvae feed on honeycomb inside bee nests may become an important pest for apiculture. On the other hand, G. mellonella is an excellent model organism for in vivo toxicity testing. In this study, G. mellonella larvae were reared on honeycomb in the laboratory at 27±2°C, 60±5% relative humidity and dark conditions. Different doses (100, 500, 1000, 3000 and 5000 ppm) of Zinc oxide NP were added to the diet of second instar larvae of G. mellonella and the effects of zinc oxide NP on the number of hemocyte of last instar larvae were determined. It was found that the number of hemocytes of the groups that were exposed to 1000, 3000 and 5000 ppm zinc oxide NP decreased significantly. Key words: Ecotoxicology, Galleria mellonella, Hemocytes, Zinc oxide nanoparticles. Acknowledgment: The authors thank Marmara University, Scientific Research Project Funding (BAPKO) for their financial support [Project number: FEN-C-DRP-100713-0334]. 392 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effects of Titanium dioxide Nanoparticles on Hemocytes of Galleria mellonella (L.) (Lepidoptera: Pyralidae) Tolga ZORLU1* and Z. Ulya NURULLAHOĞLU1 and Serhat KAYA2 1 Marmara University, Faculty of Science and Arts, Department of Biology, Istanbul, TURKEY ([email protected]) 2 Çanakkale Onsekiz Mart University, Faculty of Science and Arts, Department of Biology, Çanakkale, TURKEY ABSTRACT Nanomaterial contamination has become a global problem for ecosystem. Engineered nanomaterials have been used in both commercial and scientific studies in decade years, because of their properties. Investigation of the effects of nanomaterials on living organisms has been also increasing lately. Titanium dioxide (TiO 2) nanoparticles (NPs), is widely added to the structure of the various consumer products as in pharmacological and antibacterial products and used often at water treatment, self-cleaning applications, optic technology and air cleaning. However, its ecological and toxicological effects have not known. The Greater Wax Moth, Galleria mellonella (L.) (Lepidoptera: Pyralidae) is an important pest located almost everywhere on the earth and it’s a good model organism for the physiological and ecological studies. Cellular immune system of insects refer to hemocytes- mediated responses. Therefore, number of hemocytes are so many important to determine the toxicity for insects. In this study, G. mellonella larvae were fed on the diets each added 100, 500, 1000, 3000 and 5000 ppm TiO 2 NPs from the 2nd to last instar to determine the effects on the number of hemocytes. The mass rearing culture and the treatment groups of G. mellonella were reared in laboratory at 27±2°C, 60±5% relative humidity, and constant dark conditions. Results showed that higher doses (3000 and 5000 ppm) of TiO2 NPs caused of decrease in the number of hemocytes of the last instar larvae of G. mellonella. Keywords: Ecotoxicology, Galleria mellonella, Hemocyte, TiO2 nanoparticles. Acknowledgment: The authors thank to Marmara University, Scientific Research Project Funding (BAPKO) for their financial support [Project number: FEN-C-YLP-041213-0457]. 393 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of Heavy Metals in Soil Transport Mechanism Melayib BİLGİN 1, Şevket Tulun* 2 1, 2 M. Bilgin, Ş.Tulun’ Faculty of Engineering, Aksaray University, AKSARAY. (E-mail: [email protected], [email protected]) ABSTRACT This study investigated how transported heavy metals in the soil. Four different soil samples already prepared for the heavy metal solutions using a continuous flow system were filtration process. Half hour intervals samples were taken from the system, from the first sample examined changes in Ph. After removing the sample from the filtration step, a continuous flow system starting from the top portion 0 – 5, 5 – 10 and 10 – 15 cm long aliquot and DG – EN – 12 method of soil test are carried out for each piece. Heavy metal retention capacity of the soil each thread ICP device was investigated. Accumulation of heavy metals in the soil occurs at depths close to the surface. Decreases with increasing depth of soil heavy metal retention capacity. Soft texture and structure with clusters of heavy metals during filtration pH values didn’t change too much. Nickel has been found builds up as a heavy metal. Lead accumulates in the maximum observed a slight textured soils. Crome basic and slight texture soils tend to more accumulated. Depending on the nature of heavy metals in different soil types and soil layers held heavy metals. Heavy metals in the soil physical and chemical events in the transport mechanism of ion exchange was observed that significant influence. Key words: Heavy metals, Filtration, Soil pollution. 394 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Separation and Purification of Lipase using Cu nanoparticle embedded poly(HEMA -MATrp) Cryogels Kadir Erol*1, Kazım Köse2, Dursun Ali Köse3, Gülcin Alp Avcı4, Lokman Uzun5 1,3 Hitit University Faculty of Art and Science, Department of Chemistry, Çorum, TURKEY ([email protected], [email protected]) 2 Hitit University Scientific Technical Research and Application Center, Çorum, TURKEY ([email protected]) 4 Hitit University Faculty of Science Department of Molecular Biology and Genetics, Çorum, TURKEY ([email protected]) 5 Hacettepe University Faculty of Science Department of Chemistry, Ankara, TURKEY ([email protected]) ABSTRACT Quality and efficiency of techniques to be used for separation and purification lipase en zymes are commercially significant enzyme. Among such techniques, adsorption methods are extremely preferred. Cryogels have been quite extensively used as the synthetic adsorbents due to their macropores and interconnected flow channels. In this study, adsorption of lipase enzyme onto copper nanoparticles embedded poly(2-hydroxyethyl methacrylate-N-methacryloyl-L-tryptophan), poly(HEMA-MATrp) cryogels was studies for conditions with varying pH, interaction time, lipase enzyme initial concentration, temperature and ionic strength. Maximum lipase enzyme adsorption capacity of cryogel s was determined as 183.6 mg/g. Fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM) were used for characterization of cryogels. At the end of the adsorption process, in order to be sure that the purity of lipase enzyme desorbed from cryogels, SDS-PAGE analyses were performed and molecular weight of the lipase enzyme was determined as 58 kDa. Adsorption characteristic of cryogels were determined according to the results of Langmuir and Freundlich adsorption isotherm models. As a result of calculation run for adsorption isotherm models, Langmuir isotherm model was determined to be more appropriate. Key Words: Adsorption, Cryogel, Lipase, Seperation. 395 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Fe(II)-Co(II) double salt incorporated magnetic hydrophobic microparticles for invertase adsorption Kazım Köse*1, Kadir Erol2, Asiye Aslı Emniyet3, Dursun Ali Köse4, Gülcin Alp Avcı5, Lokman Uzun6 1 Hitit University Scientific Technical Research and Application Center, Çorum, TURKEY ([email protected]) 2,4 Hitit University Faculty of Art and Science, Department of Chemistry, Çorum, TURKEY ([email protected], [email protected]) 3 Hitit University, Institute of Science Department of Biology, Çorum, Turkey ([email protected]) 5 Hitit University Faculty of Science Department of Molecular Biology and Genetics, Çorum, TURKEY ([email protected]) 6 Hacettepe University Faculty of Science Department of Chemistry, Ankara, TURKEY ([email protected]) ABSTRACT Invertase (β-fructofuranoside fructohydrolase, EC 3.2.1.26) is an commercially importrant enzyme for the food industry. One of the main function of this enzyme is the formation of glucose and fructose through hydrolysis of sucrose. Magnetic poly(2-hydroxyethyl methacrylate-N-methacryloyl-Ltryptophan), mpoly(HEMA-MATrp), microparticles were synthesized for the separation and purification of this important enzyme from aqueous solutions. Magnetic properties of microparticles are analyzed using ferromagnetic Fe(II)-Co(II) double salt. Characterization studies of magnetic microparticles were performed via vibration sample magnetometer (VSM), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis. Specific surface area of magnetic microparticles is found 6.75 m2/g. Adsorption capability of magnetic microparticles was determined by different conditions such as pH, interaction time, initial invertase concentration, temperature, and ionic strength. The maximum adsorption capacity was found as 943 mg invertase/g magnetic microparticles. Purity of desorbed invertase enzyme was investigated using SDS-PAGE analysis. Key Words: Adsorption, Double Salt, Hydrophobic Microparticles, Invertase, Magnetic Seperation. 396 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Determination of oxidative stress level of nano and non-nano boron in Chodatodesmus mucranulatus Betül YILMAZ ÖZTÜRK1 Yeşim ÖZKAN2 Baran AŞIKKUTLU3 Cengiz AKKÖZ*3 1 Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) 2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) 3 Selçuk University Faculty of Science Department of Biology, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Nanomaterials found a wide area of use in the industry thanks to its new properties that emerge as the material’s dimensions approach nano-scale, and the developed products have entered the daily life quickly. One of these is titanium dioxide nanoparticles. Boron nanoparticles are being evaluated as a potential fuel source. Boron nanoparticles releases energy after metal oxidation, and medical research. The nanoparticles that are produced due to the fast development of nanotechnology are causing concern over their potential toxicity and ecotoxicity, and they also cause concern due to their health and environment hazards. It is a known fact that most of the industrial and urban wastes and waste water discharges flow into rivers, lakes and coastal waters. For this reason, it is inevitable for the nanoscaled industrial products and waste products to mix with aquatic environments. Green algae, which is part of the aquatic environment is affected by these nanoparticles. This algae lead to oxidative stres. In this study, the effect of nano boron and non-nano boron particles on the oxidative stress were studied. On the upshot, more oxidative damage cause by nano boron has been recorded. An indicator of oxidative stress is reactive oxygen species (ROS). ROS activity increased by nano boron is much higher than ROS activity increased by a non-nano boron particles in the same concentration. Moreover, it was observed that increasement of ROS activity was inversely proportional with nano boron particles concentration, on the other hand, it was proportional with non-nano boron concentration. Keywords: ROS, oxidative stres, boron nanoparticles, toxicity. 397 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of AgTiO2 Nanoparticles on chlorophyll-a, b and carotenoids of Desmedesmus multivariabilis Yeşim ÖZKAN 1 Betül YILMAZ ÖZTÜRK 2 Cengiz AKKÖZ*3 Baran AŞIKKUTLU3 1 2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) 3 Selçuk University Faculty of Science Department of Biology, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT The microscobic green algea are amazing organisms; living in lakes, rivers, seas and even on the ground/soil. In their structure they have chlorophyl-a, chlorophyl-b and carotenoid pigments However, due to they are forming the first footstep in the food pyramid, any variation they could have effect directly or indirectly the other organisms. Recently, the rapidly rising productions of the engineered nanoparticles and their releases to the environment by using them has been increased. Therefore, it’s urgent and necessary to examine and to determine the tolarence levels of this nanoparticles that are released to the environment. In this study, its been investigated the effects of the nanoparticles pervaded environment whether expose changing in the green algea, particularly on the amounts of the chlorophyl-a, chlorophyl-b and carotenoid pigments that are located in chloraplast which is the center of photosyntesis. To test and study this, it’s been used Desmodesmus multivariabilis algae. It was isolated in Beykavağı Göleti and designated by using molecular diagnostic methods. Treatment of the algae with acut was performed in the BG-11 medium by 0.1, 0.01, 0.001 mg/L concentrations. In the process of the treatment in every 24 hours 2 mL sample was taken and chlorophyl a, b and carotenoid levels were determined by Lichtenthaler and Wellburn methods. The lowest pigment amount of Desmodesmus multivariabilis for chlorophyl a is 72th hour 0.01 mg/L concentration for chlorophyl b 24th hour 0.01 mg/L and for Carotenoid 48th hour 0.1 mg/L. In Desmodesmus multivariabilis, treatment by 72 hours the amount of the pigments was changed. In this pigments the chlorophyl a is the highest effected one. However the algae cells were observed to adopt the environment in the treatment process. Keywords: Nanotoxicology, Chlorophyta, acute toxicity, Desmodesmus multivariabilis 398 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Comparative Effects Acute Toxicity of Nano and Non-Nano Boron Particles in Artemia salina (Brine shrimp) Yeşim ÖZKAN1 Gözde KILINÇ*2 1 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) 2 Amasya University Department of Veterinary, TURKEY (E-mail: gozde.kılınç@amasya.edu.tr) ABSTRACT Mostly chemical are released to rivers through sewage and causes pollution. It is a well known reality that most of the industrial wastes and urban waste water discharges is mixed with rivers, lakes and coastal waters. Therefore, mixing of nano-dimensional industrial products and byproducts to aquatic environments is unavoidable. Thus, aquatic species are used for ecotoxicological tests One of these chemicals are nanoparticles commonly mentioned in the recent years and the term nanotoxicology is accepted as a subbranch of toxicology in the science world. Nanotoxicology is considered as a new branch of toxicology that explains the health-threatening harmful effects originated from nanoparticles. Nanoparticles have different physical and chemical properties than those of conventional materials. As they are prone to aggregate and sink in the aqueous medium they are in, motion systems must be used to study their toxic behavior. Acute exposure test for Artemia nauplii was carried out according to the OECD 202 test guide. Artemia salina (crustacea, Anostraca) known as brine shrimp, that their typical inhabitants of uttermost salina biotopes. The Artemia salina (Brine shrimp) is an invertebrate complementary of the fauna the of aquatic environment. The determined concentration of nano and non-nano boron Particles were applied on the Artemia culture. after exposure to acute, nano boron, non-nano boron particles according to were recorded. Also, the artemia in the control group had no visible change in the digestive system and the intestines were almost empty. No missing extremities (antennae) or malformations were observed. The artemia subject to nanoparticles showed changes in the eye formation enlargement of the intestine malformations in the outer Shell and extremity loss and malformation (antennae) were the first observed changes under the microscope. Keywords: Boron, Nanotoxicology, Artemia salina, Acute toxicity, nanoparticles. 399 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determining the effect of the Bioaccumulations and oxidative stres of Chodatodesmus mucranulatus Exposed to ZnO-TiO2 Nanoparticles Yeşim ÖZKAN*1, Betül YILMAZ ÖZTÜRK2 1 2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) ABSTRACT To date an unprecedented, rapid change in environmental conditions is observed. These environmental changes mainly originate from anthropogenic activities, which have caused air and soil pollution, acid precipitation, soil degradation, salinity, increasing UV‐B radiation, climate change, etc. Especially in recent years, one of these anthropogenic activity is release and use of nanoparticles. Some of these stress factors may fluctuate significantly in intensity and duration on time scales of hours, days, seasons, or years; others may change slowly and gradually affect plant growth conditions. Oxidative damage to biological material is inflicted on compounds of all major chemical classes. Thus, oxygen toxicity has an impact on nucleic acids, proteins and free amino acids, lipids, and carbonhydrates. In this study, the effect of oxidative stres and bioaccumulations of the nanoparticles on the green algae was investigated. Chodatodesmus mucranulatus is a planktonic and unicellular organism that also have the feature of colony formation This organism generaly lives in freshwater. As a result of research, when the exposed groups compared with the control group, terms of reactive oxygen species (ROS) activity; especially, there is a serious increase in 0.1 mg/l concentrations. ROS activity decreases with decreasing concentration of nanoparticles.The accumulation of nanoparticles in algae. Increased with increasing concentrations. With reference to, the maximum accumulation 0.1 mg/l concentrations, minimum accumulations 0.001 mg/l concentrations. Keywords: Chlorophyta, AgTiO2 nanoparticles, ROS, Nanotoxicology, Acute toxicity. 400 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Comparative Determination of oxidative stress level of nano and non-nano boron in Desmodesmus multivariabilis 1 2 Yeşim ÖZKAN*1, Betül YILMAZ ÖZTÜRK2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) ABSTRACT The nanotechnology industry has made a rapid progress by introducing unusual properties to the substances at nano scales. Nanotechnology applications lead to changes in the basic, physical and chemical properties of conventional materials. These changes show rapid progress when conventional materials gain unseen properties on the nano-scale; therefore, new materials with excellent electrical, optical and mechanical properties are created. Such properties of nanoparticles have also raised concerns about their potential toxicities and ecotoxicology. Nanoparticles may cause a toxic effect through several different mechanisms on the living organisms. One of these effects is the cellular oxidative stress in the living organism caused by the in vivo free radicals that occur as the result of the main molecular mechanism of nanotoxicity. The free radicals that occur in the case of extreme exposure to nanoparticles cause damage in the biological components by giving rise to the oxidation of lipids, proteins and the DNA. boron particles were used in this study. Nano boron and non-nano boron particles is almost identical effects on oxidative stress caused by algae. Both nano boron and non-nano boron particles leads to different levels of oxidative stress. Key words: Desmodesmus multivariabilis, ROS, oxidative stres, boron nanoparticles, toxicity. 401 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Investigation of the effect on the pigment density of ZnO-TiO2 nanoparticles on Chodatodesmus mucranulatus Betül YILMAZ ÖZTÜRK*1 Yeşim ÖZKAN2 Baran AŞIKKUTLU3 1 Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) 2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) 3 Selçuk University Faculty of Science Department of Biology, TURKEY (E-mail: [email protected]) ABSTRACT Chodatodesmus mucranulatus is a planktonic and unicellular organism that also have the feature of colony formation. This organism generaly lives in freshwater. Like as other green algea have, there are chlorophyl a, b and carotenoid in it’s structure. The Word “nano” is used as a technical measurement unit and it means one billionth. The term “Nanotechnology” is a field of science that engage in the objects formed smaller than 100 nm. The increases of the usage of nanomaterilas and rapid development of nanotechnology have leaded to some concerns about the side effects of the nanoscaled materials. In this study, its been investigated the effects of the titanium dioxide-zinc oxide nanoparticles on green algea whether cause any change in chlorophyl a, chlorophyl b and carotenoid pigments. The Chodatodesmus mucranulatus test organism was isolated in Apa Dam Lake and species designation has been done by molecular methods. When they have reached enough number of growth treated 72 hours with the medium prepared with ZnO-TiO2 at the concentration of 0.1, 0.01 and 0.001 mg/L. In the process of the treatment in every 24 hours, 2 mL sample was taken and chlorophyl a, b and carotenoid levels were determined by Lichtenthaler and Wellburn methods. In the cultured algea, with 72 hours treatment, its been observed that ZnO-TiO2 nanoparticles has the toxic effects and in terms of photosynthetic activities carotenoids were effected the most. The reason for this could have been considered that during the treatment carotenoids were turned into chlorophyl-a. However the algae cells were observed to adopt the environment in the treatment process. Keywords: Chlorophyta, Chodatodesmus mucranulatus, Nanoparticles, Acute toxicity. 402 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Effects of Levels Reactive oxygen species (ROS) and Bioaccumulations Desmodesmus multivariabilis Exposed to AgTiO2 Nanoparticles Betül YILMAZ ÖZTÜRK*1 Yeşim ÖZKAN2 1 Eskişehir Osmangazi University Institute of Science and Technology, Department of Biotechnology and Biosafety, TURKEY (E-mail: [email protected]) 2 Ordu University Faculty of Art & Science Department of Biology, TURKEY (E-mail: [email protected]) ABSTRACT The nanotechnology industry has made a rapid progress by introducing unusual properties to the substances at nano scales. Such properties of nanoparticles have also raised concerns about their potential toxicities and ecotoxicology. Plants encounter plenty of stress factors. Plants affect growth and development throughout their life cycles owing to their sessile nature. These stress factors may be biotic and abiotic origin. And thereby, creates physiological and biochemical damage in plants. Several reactive oxygen species (ROS) are continuously produced in plants as by products of aerobic metabolism. Depending on the nature of the ROS species, some are highly toxic and rapidly detoxified by various cellular enzymatic and nonenzymatic mechanisms. The evolution of aerobic metabolic processes such as respiration and photosynthesis unavoidably led to the production of reactive oxyen species (ROS) in mitochondria, chloroplasts, and peroxisomes. A common feature among the different ROS types is their capacity to cause oxidative damage to proteins, DNA, and lipids. The purpose of this study, the effect of oxidative stres (reactive oxygen species) and bioaccumulations of the AgTiO2 nanoparticles on Desmodesmus multivariabilis was researched. Desmodesmus multivariabilis is a planktonic and unicellular organism that also have the feature of colony formation. This organism generaly lives in freshwater. As a result, When compared with a control group groups, exposed to AgTiO2 nanoparticles, at 0.001 mg /l concentration namely, maximum ROS activity was observed in the group of lowest concentration. 0.01 mg /l if the concentration is close to 0.001 mg /l concentration. Control group and 0.1 mg /l showed the same activity. Looking at the results accumulation, silver (Ag) and titanium (Ti) particles were evaluated separately. According to the Ti nanoparticles of Ag nanoparticles is much more accumulated. Both titanium and silver nanoparticles increased accumulation with concentration increases of nanoparticles in algae. Keywords: Chlorophyta, AgTiO2 nanoparticles, ROS, Acute toxicity. 403 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Study on Electrochemical Investigation of Histamine In Bee Venom A. Kekillioğlu 1, M. Çalışkan*2 1, 2 Nevşehir H.B.V. Uni, Faculty of Arts & Sciences, Dept. of Biology, 50300, TURKEY (E-mail: [email protected], [email protected]) Nevşehir H.B.V. Uni, Institute of Science and Technology Dept. of Biology, 50300, TURKEY (E-mail: [email protected]) ABSTRACT In this study, It is intended to detect the amount of histamine in the venom of Apis mellifera (Insecta Hymenoptera: Apidae). Histamine is a biogenic amine. Biogenic amines can cause direct or indirect toxicity when their concentration levels are high. Because of this there are many physiological and pathological effects of histamine in the organism metabolism. Therefore, determination of trace histamine is very important. Especially Apidae (Insecta: Hymenoptera: Apoidea) species venoms can comprise a high amount of histamine. According to current knowledge, diferent taxa of Hymenoptera venoms constitute of %1 - %2 histamine. In this study, electrochemical methods have been used for the analysis of histamine. Also the methods that histamine is electroactive and conditions are evaluated. The proposed method was successfully applied to the determination of histamine in Venom of Apis mellifera (Insecta: Hymenoptera: Apoidea). As a result of the application 2.53 mg of histamine was determine d in 1 g. bee venom. Keywords: Histamine, Determination, Bee, Venom, Electrochemical method. Acknowledgment: The authors thank Nevsehir Hacı Bektas Veli University, Scientific Research Project Funding (NeU BAP) for their financial support [Project number: NEUBAP 2011/13]. 404 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Polen Analysis of Regional Propolis of Turkey A. Kekillioğlu 1, Z. KOÇAL*2 1, 2 Nevşehir H.B.V. Uni, Faculty of Arts & Sciences, Dept. of Biology, 50300, TURKEY (E-mail: [email protected], [email protected]) Nevşehir H.B.V. Uni, Institute of Science and Technology Dept. of Biology, 50300, TURKEY (E-mail: [email protected]) ABSTRACT Propolis is a product based on resins collected from resinous sprouts and exudates of some plants by bees of Apis mellifera. In the beehive, the propolis is used by the bees to defend them from the invaders and promotes conservation of their bodies, protecting the beehive from the resultant plagues of putrefaction. Propolis has been used in the traditional medicine since the primordial times of humanity, having acquired popularity between Egyptians Arabs, Greeks, and many other civilizations In fact, different works attribute important properties to propolis, namely antibacterial, antifungal and anti-inflammatory For all these reasons, this natural product awakened interest in the pharmaceutical industry, mainly in Euro-Asian countries, being propolis introduced in different products for human consumption like drinks, foods and cosmetics. Pollen can occur in propolis firstly through sticking to plant resins in the case of wind pollinated flowers, secondly by being introduced from stored pollen loads inside the hives, or thirdly by being transported on the hairs of bees which have been in contact with pollen in the field. In this study, it is aimed to analyze the polen composition and the characteristics in some regional propolis of Turkey. Keywords: Propolis, Polen, Analysis, Apis mellifera, Turkey 405 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Ecological Succession of Arthropoda (Insecta) in Forensic Entomology A. Kekillioğlu* Nevşehir H.B.V. Uni, Faculty of Arts & Sciences, Dept. of Biology, 50300, TURKEY (E-mail: [email protected], [email protected]) ABSTRACT Insects are the most diverse and abundant forms of life on earth. There are over a million described species more than 2/3 of all known organisms. Forensic Entomology is the use of the insects and other arthropods that feed on decaying remains to aid legal investigations When an animal organism dies, insects will be attracted to the body. They enter exposed orifices or wounds and lay eggs or larvae. Determination of the time or site of human death based on identification of arthropods collected from or near corpses. Forensic Entomology is used to determine time since death (the time between death and corpse discovery) This is called postmortem interval or PMI). Ecological succession occurs as an unexploited habitat is invaded by a series of different organisms. The first invasion is by insect species which will alter the habitat in some form by their activities. These changes make the habitat attractive to a second wave of organisms which, in turn, alter the habitat for use by yet another organisms. Therefore Necrophages - Omnivores - Parasites and Predators – Incidentals are the main characters of decomposition ecology respectivelyin terms of ecological succession. Finally Examining the Arthropoda’s (Insecta) ecological successions involved in forensic entomology processes forms the basis purpose and content of the study. Keywords: Ecology, Succession, Forensic Entomology, Arthropoda 406 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Importance of planting open - Green Field: The Case of Nigde G.Sandal Erzurumlu* 1, B. Kahveci 2 1, 2 1,2 ( ) Niğde University, Faculty of Architecture, Department of Landscape Architecture, Niğde, Turkey. E-mail: [email protected], [email protected] ABSTRACT In urban environments green areas play an important part in forming good quality environments with their ecological, economical, physical, social and aesthetic functions.Creating a livable environment with open and green spaces has been an indispensable part of our lives. In this research, afforestation studies performed in open-green spaces of Nigde city were evaluated from viewpoint of choice of species, lanscape design and techniques, and some recommendations were introduced. In the current applications, use of limited number of species for afforestation, and as a result of this, formation of uniform planting design and some inappropriate technical approaches for planting and maintenance were determined as the principle problems. To solve the problems, ascertaining plant material used in landscape plans in Nigde province, related analyses were done with regard to planting design and also application problems and their solutions were discussed. Keywords: Green field, Landscape design, Nigde, Plant species, Urban environment 407 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The mixture toxicity of synergistic compounds combined with pesticides in Tuta absoluta M. Yalcin* 1, C. Turgut 1 and P. B. Kurt-Karakus 1, 2 Department of Plant Protection, Fac. of Agriculture, Adnan Menderes University, Aydin, Turkey (E-mail:[email protected], [email protected]) 2, Faculty of Natural Science Architecture and Engineering Dept. of Env. Eng., Bursa Technical University, Bursa, Turkey (E-mail: [email protected]) ABSTRACT The mixture toxicity of pesticides and three synergistic compounds were investigated using Tuta absoluta as test organisms collected from different locations. The mixture of five pesticides (indoxacarb, spinosad, azadirachtin, chlorantraniliprole and metaflumizone) and synergistic compounds (diethyl maleate (DEM), triphenyl phosphate (TPP) and piperonyl butoxide (PBO)) were measured by using dip bioassay method and compared with the LC50 values of the pesticides. Pesticide application alone exhibited low toxicity whereas pesticides mixed with diethyl maleate (DEM), triphenyl phosphate (TPP) and piperonyl butoxide (PBO) increased the toxicity of pesticides to Tuta absoluta. The mixture of PBO and pesticides caused the highest toxicity among tested pesticides. The application of spinosad mixed with PBO increased the toxicity of spinosad 27 times. In conclusion, the mixture toxicity of pesticides expecially with synergistic compounds is not easy to expect from different locations and varieties of organisms. Further studies with more pesticides combined with synergists are needed to conduct with different organisms. Keywords: pesticides, toxicity, mixture toxicity, Acknowledgment: The authors thank Adnan Menderes University, Research Project Funding for their financial support [Project number: ZRF12038]. 408 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Acute Toxicity of Mercury (II) Chloride upon Pseudorasbora parva (Temminck & Schlegel, 1846) 1 1 Mehmet Yılmaz Ali Gül* , Nurcan Uzel1 Sezin Kubilay1 Ömer Saylar2, Semra Benzer2 1 Gazi Üniversitesi, Gazi Eğitim Fakültesi, Fen Bilgisi Eğitimi ABD, 06500, Teknikokullar, Ankara 2 Gazi Üniversitesi Gazi Eğitim Fakültesi Biyoloji Eğitimi Anabilim Dalı, 06500, Teknikokullar, Ankara Sorumlu yazar e-posta: [email protected] ABSTRACT The industrial and agricultural activities are causing an excessive environmental pollution. The terrestrial pollution reaches to the aquatic ecosystem by various ways. The heavy metals and its compounds have a particularly important role in this process. Among these metals mercury is one of the major pollutants appears as two different forms in aquatic eco systems: An inorganic mercury and methyl mercury (CH 3Hg+). Mercury (II) chloride, water soluble mercury salt has a quite a big toxic effect. This study is concerned with the investigation of the toxicity and the behavioral effect of Hg 2Cl2 upon invasive Pseudorasbora parva species. The P. parva species investigated were obtained from Mogan Lake and subjected to a pre toxicity tests in order to determine the experimental concentration. There were 10 fishes selected for the control and experimental groups. The temperature was kept constant at 22±1 oC for 96 hours throughout the experimental period where the mortality rates and the behavioral changes were determined. The LC50 value was determined by the use of EPA Probit analysis and Behrens Karber method. The static acute toxicity 96 hour LC50 value by the use of EPA Probit analysis was 0.409 (0.332-0.490) mg/L. There were no mortalities in the control group. The LC50 value obtained by the use of Behrens Karber method was found to be 0,445 mg/L. There was not any statistically significant difference between these two values. The fish in the experimental group were observed to swim faster, whirl around their own axis and come to the surface much more frequently compared with the fish in the control group. The results revealed that Hg2Cl2 coming from various sources is toxic upon the invasive species of P. parva which has a very high level of tolerance against she ecological pressures. That is why its use needs to be restricted. Key words: Pseudorasbora parva, Mercury II chloride, LC50, acute toxicity 409 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The acute toxicity of Fenitrothion upon Pseudorasbora parva (Temminck & Schlegel, 1846) Ali Gül*1 Mehmet Yılmaz1, Sezin Kubilay1 Semra Benzer2, Ömer Saylar2 1 Gazi Üniversitesi Gazi Eğitim Fakültesi Biyoloji Eğitimi Anabilim Dalı, 06500, Teknikokullar, Ankara 2 Gazi Üniversitesi, Gazi Eğitim Fakültesi, Fen Bilgisi Eğitimi ABD, 06500, Teknikokullar, Ankara Sorumlu yazar e-posta: [email protected] ABSTRACT The effects of pollutants upon the living organisms are determined by the use of various acute toxicity tests. The most common acute toxicity test is the lethality test which determines the resulting lethality level and the degree of the effect of the organs had after being exposed to the toxic compound. Fenitrothion is an organic phosphorous containing insecticide which has been in use for the agricultural activities for a quite long time. This study is related to the investigation of lethal effects of Fenitrothion upon Pseudorasbora parva (Temminck & Schlegel, 1846) an exotic an invasive species which has a very large tolerance to the ecological pressures. P. parva is described as an invasive species since it rapidly propagates and spreads in the aquatic ecosystems and exert a pressure on other aquatic fish species. The P. parva species collected from Mogan Lake were subjected to statistical 96 hours bio tests to determine the mortality rate and behavioral abnormalities. The mortality, behavior and general conditions of the species were monitored and recorded throughout the study. EPA Probit Analysis and Behrens Karber LC50 values were found to be 16.854 mg/L (with a min. and max. values were 22.125 and 12.839 mg/L) and 17.0 mg/L which showed no statistical difference. There was no mortality observed in the control group. The fish displayed behavioral abnormalities such as haphazard swimming patterns, sudden twists around their own axis, loss of balance, gathering under the or top of the water in motionless manner, attempting to breath from the surface and sinking down the bottom and remaining motionless for prolonged periods. LC50 value obtained for P. parva sp against Fenitrothion, revealed that the compound is highly toxic and it use must be regulated in accordance to the environmental criteria. Key words: Fenitrothion, Pseudorasbora parva, LC50, acute toxicity 410 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of pH level on Bacterial Induced Cementation of Sands Ayhan GURBUZ1, Yasin Dursun SARI2 ,Zehra Nur YUKSEKDAG3 1 Gazi University, Faculty of Engineering, Civil Engineering Department, 06570, Ankara-Turkey, ([email protected] , [email protected]) 2 Atilim University, Engineering Faculty, Civil Engineering Department, 06836, Ankara-Turkey 3 Gazi University, Faculty of Sciences, Department of Biology, 06500, Ankara-Turkey ABSTRACT This study reveals the effect of pH level on the cementation concept of bacterial induced calcite precipitation generated by bacteria. Sporosarcina pasteurii, abundantly present in soils and aerobic type of bacteria, is grown in laboratory environment and injected to the matrix of both heat sterilized and non-sterilized specimens prepared in loose state from two types of sand. Subsequent nutrient mediums are introduced to the specimens to accelerate the development of cementation level. The images of scanning electron microscope are taken to identify the creation of cementation from precipitation of calcite on the surface and pores of sand matrix. Key words: pH level, Bacterial Induced Cementation, Sand, 411 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Determination of pesticide residual levels of grapes produced in Nevsehir Erkan KALIPCI*1, Serkan SAHINKAYA1, Kemal ŞEN2 1 Department of Environmental Engineering, Nevsehir Hacı Bektas Veli University, 50300 Nevsehir, Turkey. Phone: +90 384 228 1000, Fax: +90 384 228 1123 2 Department of Food Engineering, Nevsehir Hacı Bektas Veli University, 50300 Nevsehir, Turkey. Phone: +90 384 228 1000, Fax: +90 384 228 1123 (E-mail:[email protected], [email protected], [email protected]) ABSTRACT Many chemical substances are used in agricultural products in order to protect them from diseases and weeds. These compounds used in chemical control are called "pesticides". The pesticides in Turkey are especially used in fruit and vegetable growing potently. In grape growing, insecticides, fungicidals and herbicides are commonly used. Among them, 2,4-D and its esters known as a herbicide were illegalized in many countries all over the world due to their ecotoxic effects. However, usage of this pesticide in our country is legal and commonly applied in vineyards. In this study, residue amounts of totally 35 pesticides including 2,4-D and its esters in table grape samples were determined. Totally 50 grape samples were used in the analysis and they were obtained from local bazaars where they were presented to the consumption of the public. The pesticides were extracted by using multi-residue analysis method. In the calculation and description of pesticide amounts in grapes, GC-MS technique was used. In this research, residue amounts determined in grapes were assessed as 3 repetitions per sample according to "Turkish Food Codex, Regulation Related to Making Amendments in Maximum Residue Limit Regulations for Pesticides" (Official Journal: 03.01.2013; No: 28517). As a result of residue analysis, pesticide residues were not found in 63% of total samples among fresh grapes. According to the findings obtained in the research, residue was determined in 32% of total samples under MRL value and residue was determined in 5% of total samples above national and international MRL values. In the samples, the residue amounts of Aldrin, 2,4-D its esters, Endrin and Chlorpyrifos pesticides were found higher than maximum residue limits determined by both regulations mentioned above and joint commissions of United Nations Food and Agriculture Organization (FAO) together with World Health Organization (WHO) as well as according to European Union instructions permitted in European countries. Key Words: Grape, Pesticide, Residue amount, Nevsehir. 412 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Physiological and Cytogenetic effects of insecticide Korban 25 W on Allium cepa L. Nihal GÖMÜRGEN1, Gökçen BAYSAL FURTANA2, Rukiye TIPIRDAMAZ1 1 2 Hacettepe University, Science Faculty, Biology Department, Beytepe, Ankara/TURKEY Gazi University, Science Faculty, Biology Department, Tekniokullar, Ankara/TURKEY [email protected] ABSTRACT Cytotoxic and physiological effects of insecticide Korban 25 W (0,0-diethyl 0-(3, 5, 6 trichloro 2-pyridyl phosphorothioate) were investigated on Allium cepa L. The roots of 5 days old seedlings were treated with 0 g/lt (control=tap water), 2 g/lt, 3 g/lt and 4 g/lt concentrations of Korban 25 W for at 5 and 10 days. The results indicate that Korban 25 W significantly decreased Mitotic Index (MI) and increased the chromosome aberrations (micronucleus, chromosome bridge, sticky metaphase) at all concentrations and treatment periods when compared with their controls. It was also found that Korban 25 W enhanced the lipid peroxidation and caused an increase in Malondialdehide (MDA) level and the changes Superoxide dismutase (SOD) and Catalase (CAT) activities. All these changes were depending on dose and duration of applied Korban 25 W. Key words: Allium cepa, insecticide, chromosome aberrations, genotoxic effects, mitotic index, lipid peroxidation (MDA), antioxidants. 413 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Paleoenvironment setting and Benthic Foraminiferal Assemblage of Çamardı (Niğde) Eocene Sediments Feyza DİNÇER* 1 and Niyazi AVŞAR 2 1 Department of Geology Engineering, Nevşehir Hacı Bektaş Veli University, NEVŞEHİR (E-mail: [email protected]) 2 Department of Geology Engineering, Çukurova University, ADANA (E-mail: [email protected]) ABSTRACT Benthic Foraminiferal are the main skeletal carbonate producers in Eocene and their di versity and distribution of are controlled by different environmental factors. In this study, biostratigraphy of benthic Foraminiferal and paleoenvironmental changes of the middle Eocene formation are investigated in the Çamardı Region. The study area is situated in the southeast part of Niğde in central Anatolia. Çamardı Region is comprised of Pre-Paleogene, Neogene and Quaternary units. The study was carried out in Kaleboynu Formation which was aged Eocene. The formation is consists of limestone, sandston e, conglomerate and clayey and sandy limestone. Two different stratigraphic sections were measured in order to assess the biostratigraphy of this formation. As a result of the examination of 191 thin sections under the microscope, 6 genera and 15 species were identified to characterize Early and Middle Lutetian, systematically. Alveolina callosa Hottinger, A. aff. obtusa Montanari, A. obtusa Montanari, A. pinguis Hottinger, A. levantina Hottinger, A. frumentiformis Schwager, A. stercusmuris Mayer-Eymar, Asterigerina rotula (Kaufmann), Lockhartia alveolata Silvestri, Assilina exponens (Sowerby), Nummulites praediscorbinus Schaub characterize Early Lutetian. Nummulites beaumonti d’Archiac and Haime, N. millecaput Boubée, N. praeaturicus Schaub and Discocyclina cf. harrisoni Vaughan are placed within the Middle Lutetian layers. Based on the identified benthic foraminifera, three larger benthic foraminiferal zones (SBZ 13, 14 and 15) were identified for Kaleboynu formation. The benthic foraminiferal assemblages are typical for shallow marine environments. According to lithological characteristics and benthic foraminiferal content, it is concluded that the study area has formed under a reefal environment. Keywords: Benthic, Biozone, Çamardı, Eocene, Paleoenvironment. 414 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Phytoremediation of Cadmium (Cd) from Agricultural Soils Using Dock (Rumex patientia L.) S. Adiloğlu* 1, A. Adiloğlu 1, F. Eryilmaz Açıkgöz 2 T.Yeniaras1, Y. Solmaz 1, 1, Namık Kemal University, Faculty of Agriculture, Dept. of Soil Science and Plant Nutrition, Tekirdağ, TURKEY. (E-mail: [email protected]) 2 Namık Kemal University, Vocational School of Technical Sciences, Tekirdağ, TURKEY. ABSTRACT The aim of this research is to propound an innovative method to remediate the cadmium (Cd) pollution in agriculture soils by using dock (Rumex patientia L.) plant. For this purpose, a pot experiment was conducted on the campus of Namık Kemal University, namely its Faculty of Agriculture green house condition. Cadmium (100 mg/kg) as Cd(NO3)3 forms was applied to each pot. Then EDTA chelate was applied to each pot at four doses (0, 5, 10 and 15 mmol/kg) during the growing season of the plants. The plants were harvested two months after planting. The soil in the samples was classified with neutral pH, low lime and insufficient organic matter. The available phosphorus content and the exchangeable potassium content of research area were both found to be sufficient. The experimental area soil was classified to be in clay (C) texture. According to the field experiment results, root and shoot yield of plants decreased with increasing EDTA doses. On the other hand, cadmium amount of root and shoot of the plants increased with increasing EDTA application to the plants. These increases and decreases were found to be statistically significant at the level of 1 %. According to the results of the experiment, heavy metal pollution of dock (Rumex patientia L.) plant province can be remediated by the phytoremediation method. Keywords: Phytoremediation, Soil pollution, Dock (Rumex patientia L.), Cd. Acknowledgment: The authors thank Namık Kemal University, Scientific Research Project Funding (NKÜ BAP) for their financial support [Project number: NKUBAP.00.24.AR.14.03]. 415 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Ammonia Removal from Chicken Manure R.Ö. Surmeli*, A. Bayrakdar, R. Molaey and B. Calli Department of Environmental Engineering, Marmara University, 34722 Goztepe, Kadikoy, Istanbul, Turkey (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT Chicken manure (CM) is one of the best alternatives due to its high biodegradable organic matter for anaerobic digestion (AD). However, its high nitrogen content leads to inhibition for AD. Therefore, the aim of this study is to investigate the biological hydrolysis of organic nitrogen in CM to ammonia nitrogen and remove and recover ammonia from hydrolyzed CM by using separation techniques. Thus, the anaerobic digestion potential of CM can be improved. Batch experiments were done in 250 ml bottles (100±1 g CM) in duplicates. After transferring the CM, bottles were flushed with nitrogen gas to maintain anaerobic conditions. Batch tests were conducted at different temperatures (25, 35 and 55oC) and total solid concentrations (26%, 20% and 15%). Gas productions were monitored daily by using water displacement method and gas compositions were analyzed by a gas chromatograph 2-3 times/week. Ammonia nitrogen, TKN, total and soluble COD were determined by using nesslerization, semi-micro kjeldahl digestion and closed reflux colorimetric method, respectively. After 11 days, ammonia/TKN ratio increased from 9% to 15-32% with the increasing temperatures. Although total COD of the samples did not change significantly, soluble COD increased up to 91%. Decreasing in organic nitrogen and increasing in soluble COD concentrations might be a good solution for anaerobic digestion of CM. Next step in this study will be removal and recover of ammonia nitrogen from hydrolyzed CM. Keywords: Ammonia Recovery, Ammonia Removal, Biological Hydrolysis Acknowledgment: This study was financially supported by Scientific and Technological Research Council of Turkey (TÜBİTAK) [Project number: 113Y333]. 416 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Distribution of Copepoda Species in the Southern Black Sea in 2006-2007 Funda Üstün* 1, Levent Bat 2 and Şengül Beşiktepe 3 1, 2 Fisheries Faculty, Sinop University, TURKEY. (E-mail: [email protected], [email protected]) 3 The Institute of Marine Sciences and Technology, Dokuz Eylül University, TURKEY. (E-mail: [email protected]) ABSTRACT In the present study; distribution, composition and abundance of copepod species in the southern Black Sea (the Turkish EEZ) were studied at a total of 53 stations in June 2006, October 2006 and May 2007. Samplings were carried out vertically by using Nansen plankton net with a 112 μm mesh size and 70 cm diameter mouth opening. During the sampling periods eight copepods species were identified (Acartia clausi, Calanus euxinus, Centropages ponticus, Paracalanus parvus, Pontella mediterranea, Pseudocalanus elongatus, Oithona nana, Oithona similis). Total copepod abundance was 33507 ind/m3 in June 2006, 71047 ind/m3 in October 2006 and 52264 ind/m3 in May 2007. Seasonal succession of species showed difference; P. elongatus was the dominant species in June accounted for 28.6% of all copepods, A. clausi comprised almost half of the copepod community in October and O. similis was dominant in May, comprised 44% of all copepods in the Black Sea. Keywords: Abundance, Black Sea, Copepoda, Distribution, Turkey. Acknowledgment: The present work was funded by a project “TUBITAK CAYDAG-104Y289”. 417 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Western Blot Analysis Used to Detect Van-Encoded D-Alanine-D-Lactate Ligase in Surface Water Isolates M. Nakipoglu* 1, F. Yilmaz 2 and B. Icgen3 1,3 2,3 Department of Biotechnology, Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Middle East Technical University, TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT Antibiotic resistant bacteria excreted by humans and animals treated with antibiotics are discharged in the environment through untreated or partially treated sewage or manure runoff. Thus, the environment becomes a collecting vessel of antibiotic resistant bacteria and resistance genes. This may end up with the transfer of resistance genes among bacteria and appearance of novel combinations of species with multiple resistant genes. In our previous studies we screened vancomycin/teicoplaninresistant bacteria in the river waters and showed that not only enterococcal surface water isolates but also non-enterococcal ones harbored van genes. D-alanine-D-lactate ligase protein encoded by van genes was also shown in all vancomycin/teicoplanin-resistant surface water isolates through sodium dodecyl sulfate polyacrylamide gel electrophoresis previously. European Union and United States public health agencies have developed recommendations for preventing the transmission of vancomycin resistance. Current surveillance methods require a number of sequential steps and need a special series of culture media, identification tests and skilled professionals. This study aimed at detecting vancomycin/teicoplanin-resistant surface water isolates through western blot analysis with commercially available antibodies specific for Dalanine-D-lactate ligase protein. The commercially available D-alanine-D-lactate ligase-specific antibodies usually target van harboring enterococcal isolates. Therefore, the efficiency of these antibodies to detect van harboring non-enterococcal isolates also needs to be assessed. Once in the aquatic environment, bacteria of different origin come into physical contact and may exchange resistance genes with the indigenous bacteria. Therefore, surface waters may require different detection approaches for van harboring non-enterococcal isolates. Keywords: Vancomycin, teicoplanin, van genes, D-alanine-D-lactate ligase, surface waters Acknowledgment: The authors thank The Scientific and Technological Research Council of Turkey for their financial support through a 1002 project [Project number: 114Z973]. 418 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 THE EFFECT OF VITAMIN SUPPLEMENT ON REPRODUCTION AND GROWTH OF GUPPY (Poecilia reticulata Peters, 1860) ** D. Şahin*1 and O. Aral2 1 Sinop University Vocational School, Underwater Technology Programme, TURKEY ([email protected]; [email protected]) 2 Sinop University Fisheries Faculty Aquaculture Department,TURKEY ([email protected]) ABSTRACT This study was carried out to find the effects of water-soluble vitamin C and fat-soluble vitamin E on the reproductive capacity and growth of both guppies, Poecilia reticulata (Peters, 1860), a kind of live-bearing species. As for, the study included two different experimental stage. 16 different vitamin E and vitamin C including diets were used each experiment. In the first trial, in which the diet includes 1000 mg/kg of vitamin C and 300 mg/kg of vitamin E, the highest efficiency was observed in group 16 of adult guppies (p<0.05). The second trial had an ascending amount of both vitamin C and E in the diet and resulted with an increase in the developmental parameters in the offspring of guppies (p<0.05). In addition after a three month trial the group 16 of guppies had reached maturity, and juvenile. According to the results of this study, there is an increase in growth and survival of fry as the amount of vitamin C and E added in feed increases. Keywords: growth, guppy, Poecilia reticulata, reproduction, vitamin C, vitamin E **This study was an excerpt from doctorate thesis. 419 ICOCEE– CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 A Smart Solar Energy-Based Cooling System Design&Application for Sustainable Trout Farming in Keban Dam Lake Gökay BAYRAK 1*, Mehmet Cebeci2, Ali Atilla Uslu 3, Gökhan Karakaya 3, Nedim Örnekçi 3 1* Electrical and Electronics Engineering Dept., Nevsehir Haci Bektas Veli University, TURKEY. (E-mail: [email protected]) 2 3 Electrical and Electronics Engineering Dept., Firat University, TURKEY. (E-mail: [email protected]) Institute of Fishery Research, Ministry of Turkish Food, Agriculture and Livestock, TURKEY. (E-mail: [email protected]) ABSTRACT Increasing temperatures of water surface in the summer limits the amount of aquaculture activities and the production in dam lakes located in the continental climate. Due to these adverse conditions, trout farming in fish cages in the Keban Dam Lake are interrupted from April to October, and trout farming is not sustainable between these months. This study was carried out to develop a cage model that allows for sustainable trout farming throughout the year in dam lakes. The temperature of the groundwater is approximately 10 o C during the year at the Keban Dam Lake, so it is aimed to supply this cool water into the cage for cooling especially in summer months. In the study, a Photovoltaic (PV) system was designed to supply the systems’ required electrical power. A pump was used for taking cold water from the depth of the dam lake to cool the fish cage. All energy requirements of the system were supplied from designing solar energy-based PV system. The PV panels constituted on the fish cage, and temperature sensors were used to control the frequency of the motor driver for cooling the fish cage. Thanks to developed system the temperature of fish cage was fixed around 17 ° C, so trout farming could be sustained from April to October during the year. The average water temperature was decreased to about 17-20 ° C with the proposed method. This application study is the first research about this subject, and it is very important as its outputs put forward the problem clearly, and it will be an example study of future researches on this subject. Keywords: Aquaculture; Solar Energy; Photovoltaic System; Fish Cage 420 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Some Biochemical Blood Parameters in Mogan Lake Economic Fish Species Semra Benzer* 1, Ömer Saylar 1, Sezin Düzel 2, Göktuğ Gül 3, Mehmet Yılmaz 2 and Ali Gül 2 1 Science Education, Faculty of Education, Gazi Üniversity, TURKEY. (E-mail: [email protected], [email protected]) 2 Biology Education, Faculty of Education, Gazi Üniversity, TURKEY. (E-mail: [email protected], [email protected], [email protected]) 3 Health Services Vocational School, Gazi Üniversity, TURKEY. (E-mail: [email protected]) ABSTRACT Fish are used as bioindicators to determine the conditions and the change in the aquatic environment. Depending upon environmental factors blood chemistry and hematological values change. Blood parameters can also give information about fish health. In this study, some blood biochemical parameters were carried out on Cyprinus carpio (L., 1758), Tinca tinca (L., 1758) and Esox lucius (L., 1758) economic importance fish species living in Mogan Lake. Water and fish samples were taken from Mogan Lake in February, March and April 2014. Physico-chemical parameters of water were measured by YSI Oxygenmeters and Palintest Photometer. Blood samples were taken from the caudal vein and heart of each fish. Serum was obtained by centrifugation of the blood at 4000 rpm, 4 ºC for 10 min. Biochemical parameters were analyzed using Olympus AU 600 autoanalyzer. The relationship between blood biochemistry parameters of fish and water quality parameters with statistically Pearson correlation and according to the fish species differences in the blood chemistry parameters and months t-test (p <0.05 ) was investigated. Glucose (268.25), urea (17.14), uric acid (7.81) ve BUN (7.50) values were determined at the highest E.lucius in April; albumin (1.11) at the highest E.lucius in February; creatinine (0.82), ALT (383), AST (1949.50) at the highest T.tinca in March; total protein (3.37 g/dl), globulin (2.77 g/dl) at the highest T.tinca in April; triglyceride (195.50) at the highest C.carpio in April. Mogan Lake of the hunted fish individuals identified in blood chemistry parameters according to fish species and months differences were considered significant. Physical, chemical and organic change in water, has been found to affect the blood biochemistry of fish. This biochemical blood parameter values obtained in the research shows can be used as an indicator of the overall fish health. Keywords: Biochemical blood parameters Cyprinus carpio, Esox lucius, Tinca tinca 421 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Capacity Building Key Issues on Integrated Coastal Zone Management for Turkey Black Sea Coast O. Gökkurt BAKI* 1, L. BAT2 1 *Environmental Health Department of Vocational High School, Sinop University, Turkey (E-mail: [email protected]) 2 Department of Hydrobiology, Fisheries Faculty, Sinop University, Turkey (E-mail: [email protected]) ABSTRACT Capacity building is a term used to describe approaches which aim to increase the capability of knowledge base, planing and management decisions on coastal area. Besides, it is a well known fact that the Black Sea coast is always an important shoreline in economical and cultural means and face several problems due to rapid and unplanned urbanization and improper waste management. Capacity Building related issues in the context of ICZM implementation in Turkey Black Sea coast; no strategy between different building initiatives, lack of awareness/information on training opportunities, often replaces of the trained practitioners and policy-makers that have to push ICZM towards the center stage of the economic and environmental goals. In this research, we performed a need analysis for especially Black Sea Coast for capacity building requirements and key issues. The central of this research to demonstrate threats and stresses of Turkey Black Sea coastal area and institutional strengthening for implementation of Water Framework Directive and ICZM (Integrated Coastal Zone Management) principles and recommendations along the Turkey coasts. ICZM capacity building for Black Sea coast of Turkey should focus not only on the technical and scientific knowledge and skills for coastal management. It should be more professional focus on practice skills and knowledge, should include policy and decision-making, conflict resolution, and communications for sustainability. Key words: coastal management, capacity building, coast, sustainability Acknowledgment: The authors thank to EU Life Long Learning Leonardo da Vinci Transfer of Innovation Project CoastLearn Black Sea (Project Number: 2010-1-TR1-LEO05-16745 Period: 2010-2012) 422 ICOCEE –CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Water Quality Simulation Of Lakes Cernek and Balık at the Kızılırmak Delta of the Black Sea Region Of Turkey Kübra KÜÇÜK 1, Hüseyin CÜCE 2 Gülfem BAKAN 3 1, Ondokuz Mayıs University, Graduate School Of Natural And Applied Sciences, Turkey mail:[email protected]) (E- 2, Nevşehir Hacı Bektaş Veli University, Faculty of Engineering and Architecture, Department of Environmental Engineering, Turkey (E-mail: [email protected]) 3, Ondokuz Mayıs University, Faculty of Engineering, Department of Environmental Engineering, Turkey (E-mail: [email protected]) ABSTRACT The Kızılırmak Delta in the Central Black Sea region is defined as a Ramsar Area by vir tue of its natural habitats and rich biodiversity. The delta has very important wetlands whose natural features have been well-preserved. One of these wetlands, Lakes Cernek and Balık, constitutes a significant ecosystem in terms of agriculture, tourism and fishing. Kızılırmak Delta, in order to ensure sustainable management of Cernek and Balık lakes, decision-makers the information necessary for the decision support system is one of the tools that can be used in the design phase, water quality modeling is carried out. The elements which make shallow lake’s forms complicated are; interfering the water layers, the sediment which isn’t strong completely, is suspended, the nutrient loading which is sediment from water layer and the external load. For this purpose, the water quality simulation model WASP7.5, supported by the US Environmental Protection Agency (EPA). The model was calibrated using a set of data which Cernek and Balık lakes were sampled during the period of operation of the seasonal in May 2010 August 2011, for the parameters as the values of dissolved oxygen, chlorophyll-a, nitrate nitrogen and orthophosphate. The simulation results of Balık Lake represented that maximum, minimum nitrogen concentrations and maximum, minimum phosphate concentrations measured 1,35 mg/L, 0,412 mg/L, 0,12 mg/L, 0,03 mg/L, respectively. The Cernek lake represented that maximum, minimum, nitrogen concentrations and maximum, minimum phosphate concentrations measured 1,132 mg/L, 0,404 mg/L, 0,11 mg/L, 0,02 mg/L, respectively. According to the eutrophication limit of ‘Surface Water Quality Management Regulations’ the water quality of these lakes were above the natural protection area eutrophication limits Cernek and Balık lakes are eutrophic lakes, scenarios are made to improve water and sediment quality decrease the concentration of the pollution and solutions are presented for these lakes. Keywords:Water quality simulation,Kızılırmak Delta, Cernek and Balık Lakes, WASP 7.5 423 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Monitoring the Thermal Stratification of Lakes Using Simple and Current Single Point Temperature Measurement Equipment’s Serdar Göncü* * Anadolu University Environmental Eng. Dept., Engineering Faculty, TURKEY. (E-mail: [email protected]) ABSTRACT Water density is a property that changes based on the thermal characteristics of water. In large and deep water bodies, more dense water masses remain at the deeper layer while lighter water stays at the surface which leads to stratification. Temperature measurements need to be conducted to classify lakes according to stratification patterns. While temperatures can be measured with simple ther mometers at any location, more complicated Devices used for water quality sampling are also employed. More expensive and complicated Devices determining automatically temperature profiles are also present. This study aims to develop a simple temperature measuring device that can determine vertical temperature profiles at a single location continuously. The Borabey Pond in Eskişehir was chosen for the application. A temperature logger was employed to measure temperature profiles at a single location continuously. Besides, the vertical dissolved oxygen profile was also measured at tandem using HOBO DO logger. A DC motor was constructed using an Arduino circuit card which was used to move the measuring devices to the measurement points on the vertical profile a utomatically. The device developed was found to be able to determine the stratification patterns reliability without the application of expensive and high resolution sampling schemes. Keywords: Arduino, Monitoring, Temperature, Thermal Stratification Acknowledgment: The authors thank Anadolu University, Scientific Research Project Funding (A.Ü. BAP) for their financial support [Project number: 1306F190]. 424 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of seasons on fatty acid composition of Carassius carassius L. in Beysehir Lake, Turkey Abdurrahman AKTUMSEK*1, Gokhan ZENGIN2, Gokalp Ozmen GULER3, Ozcan Baris CITIL4, Yavuz Selim CAKMAK5 3 4 1 Department of Biology, Science Faculty, Selcuk University, Konya, Turkey ([email protected]) 2 Department of Biology, Science Faculty, Selcuk University, Konya, Turkey ([email protected]) Department of Biological Education, Ahmet Kelesoglu Education Faculty, Necmettin Erbakan University, Konya, Turkey ([email protected]) Department of Veterinary, Karapinar Aydoganlar Vocational School of Higher Education, Selcuk University, Karapinar, Konya, Turkey ([email protected]) 5 Department of Biotechnology and Molecular Biology, Science and Arts Faculty, Aksaray University, Aksaray, Turkey ([email protected]) ABSTRACT In this study, seasonal variation on total fatty acid composition of Carassius carassius muscle lipids in Beysehir Lake was determined. Total polyunsaturated fatty acids (PUFAs) of C. carassius were found to be higher than those of total saturated fatty acids (SFAs) and total monounsaturated fatty acids (MUFAs) in all seasons. In all seasons, palmitic acid (16.97-18.60%), oleic acid (11.31-16.58%) and docosahexaenoic acid (11.01-14.56%) were the most abundant SFA, MUFA and PUFA, respectively. The percentages of total ω3 fatty acids were higher than those of total ω6 fatty acids in the fatty acid composition of C. carassius. High level of ω3 fatty acids and ω3/ω6 ratio were observed in winter compared to other seasons. Keywords: Fatty acid composition, Beysehir Lake, Carassius carassius Acknowledgment: The authors thank to Selcuk University, Scientific Research Project Funding (S.Ü. BAP) for their financial support [Project number: SÜ BAP 10401084]. 425 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Fatty acid composition of trout species in Gezende Dam Lake Gokhan ZENGIN1, Abdurrahman AKTUMSEK2, Gokalp Ozmen GULER*3, Yavuz Selim CAKMAK4, 3 1 Department of Biology, Science Faculty, Selcuk University, Konya, Turkey ([email protected]) 2 Department of Biology, Science Faculty, Selcuk University, Konya, Turkey ([email protected]) Department of Biological Education, Ahmet Kelesoglu Education Faculty, Necmettin Erbakan University, Konya, Turkey ([email protected]) 4 Department of Biotechnology and Molecular Biology, Science and Arts Faculty, Aksaray University, Aksaray, Turkey ([email protected]) ABSTRACT Fatty acid composition of the muscle lipids of Salmo trutta macrostigma and Oncorhynchus mykiss in Gezende Dam Lake were determined. In all species, palmitic acid, oleic acid and docosahexaenoic acid were identified as major saturated fatty acid (SFA), monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA), respectively. Total PUFAs were found to be higher than total SFAs and MUFAs in all species. Salmo trutta macrostigma contained more palmitic acid, palmitoleic acid, α-linolenic acid, arachidonic acid, eicosapentaenoic acid, docosapentaenoic acid (C 22:5 ω3), total SFAs, total ω3 fatty acids and ω3/ω6 ratio compared to Oncorhynchus mykiss. Keywords: Fatty acid composition, Gezende Dam Lake, trout Acknowledgment: The authors thank to Selcuk University, Scientific Research Project Funding (S.Ü. BAP) for their financial support [Project number: SÜ BAP 11401067]. 426 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Negative Effects of High Temperature and Low Moisture on Aftercrop Silage Maize A. Beyhan Ucak1 M. Cuneyt Bagdatli 2 1 Department of Biosystem Engineering, Agriculture Faculty, Siirt University, Siirt/Turkey (e-mail:[email protected]) 2 Department of Biosystem Engineering, Faculty of Engineering-Architecture, Nevsehir Haci Bektas Veli University, Nevsehir/Turkey (e-mail:[email protected]) ABSTRACT This research was carried out to see the negative effects of high temperatures and low humidity on aftercrop silage maize cultivation in Siirt Province of Turkey. The average cultivation areas and production quantities of silage maize were respectively 4303.33 acres and 3904.50 kg/hectare during the last five years (2009-2013) in Siirt province conditions. However, high solar radiation and high temperature in 2014 was realized, whereas relative humidity was very low. Especially fertilization (8 days pollination) period as a result of changes in extreme climate has been seen in a year and reached a maximum temperature dropped to 39 °C and relative humidity up to 35%. Rain didn't fall down in aftercrop silage maize in field trials during the pollination. Pollination period was shortened due to high temperatures and low humidity. So grain retention rate in the maize cob decreased and fertilization did not take place at the optimum level. As a result, climate change have negatively affected the yield of aftercrop silage maize. Silage maize was cultivated on 10 acres in 2014 year and silage maize yield was obtained 2748.6 kg/acres in this area. Compared with the previous year's 29.6% (1156 kg/acres) less yield. During the long years with the coming to fertilization 8 daily temperature values were determined as Y=58,07x 2-867,7x+6335,2 ve R2=0.926*, (%1 significance level*) logarithmic relationship between yield. For 8 days with temperatures that fertilization occurs in the form of Y=71,42x2-250x+3257,1 ve R2=0.900*, had significantly logarithmic relationship between yield. All the summary of these studies, the most important factors of the external environment temperature, humidity and rainfall grown want to plant the optimum values upon emergence or fall below the made on agricultural activity can be seen a significant role. Keywords: Aftercrop Silage Maize, High Temperature, Low Moisture, Turkey 427 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Evaluation of Agricultural Drought with GIS in Some Irrigation Areas: The Sample of Nevsehir Province in Turkey M. Cuneyt Bagdatli 1, Serpil Savci 2, A. Beyhan Ucak 3 , Osman Gokdogan 1 1 Department of Biosystem Engineering, Faculty of Engineering-Architecture, Nevsehir Haci Bektas Veli University, Nevsehir/Turkey (e-mail:[email protected], [email protected]) 2 Department of Biosystem Engineering, Faculty of Engineering-Architecture, Bozok University, Yozgat/Turkey (e-mail:[email protected]) 3 Department of Biosystem Engineering, Agriculture Faculty, Siirt University, Siirt/Turkey (e-mail:[email protected]) ABSTRACT Agricultural drought is one of the most effective factors which reduces yield. Temperature and precipitation regime irregularities relating to global climate change, in recent years particularly play role in changing agricultural patterns as well as environmental and genetic factors. In this study, temperature, rainfall, humidity and sunshine duration are used for the years between 1990-2014 in Nevsehir, Avanos, Urgup and Cappadocia Airport meteorological stations in Nevsehir Province. Drought analyses are performed in Tatlarin, Ayhanlar and Damsa Dams and irrigation area within the scope of this study. The outputs are transferred to GIS and the geostatistical analysis is fulfilled then maps monitoring drought altering are done. According to the results of this study; the spatial humidity levels are variable for all three irrigation areas, the annual temperature data are increased and the rainfall decreased. It has been observed that humidity dispersion in the study area ranges between Nks:0,81-1,14 while drought coefficient varies between 0,88-1,23. Following all the calculations for a total of 26 years from 1990 to 2014, 18 years have been classified as dry, 4 years as arid and only 2 years have been classified as moist. Parallel with the temperature, humidity, rainfall changes the yield and patterns are changed too as for the assessment outcomes. Considering the outcomes of the analysis and assessments, it is essential to cultivate drought resistant ones for agricultural areas and to advance the breeding studies regarding the rapid changing global climate. Keywords: Agricultural Drought, Climate Change, Irrigation Areas, Nevsehir 428 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Trend Detection in Climatic Time Series Using Mann-Kendall M. Zeleňáková* 1, P. Purcz 2 and H. Hlavatá 3 1 2 Institute of Environmental Engineering, Technical University of Košice, SLOVAKIA ([email protected]) Institute of Construction Technology and Management, Technical University of Košice, SLOVAKIA ([email protected]) 3 Slovak Hydrometeorological Institute, Košice, SLOVAKIA. ([email protected]) ABSTRACT The Intergovernmental Panel on Climate Change provides a comprehensive review of the potential impacts on the hydrological variables of the man induced climate changes. It states that such changes will likely increase runoff in the higher latitude regions because of increased precipitation; also, the flood frequency is expected to change in some locations and the severity of drought events could also increase as a result of the changes both in precipitation and evaporation. Observations show that changes are occurring in the amount, intensity, frequency and type of precipitation. The frequency of extreme temperatures during the summer is likely to be higher. In this paper, the results of trend analysis applied to precipitation and temperature monthly data in eastern Slovakia are presented for the hydrological year (from November to October). Slovakia belongs to the northern moderate climatic zone. There are four seasons during the year – spring, summer, autumn and winter. The weather in Slovakia changes a lot by the influence of dry continental air from the west and the humid ocean air from the north. The topography of Slovakia is very diverse and the altitude is an important factor affecting the temperature and precipitation. The weather is usually warmer in the lowlands than in mountain. The Eastern Slovakia lowland is the warmest and the driest region of eastern Slovakia with an annual average temperature around 8°C and precipitation around 600 mm. The coldest places are mountainous area – the High Tatras in the north of eastern Slovakia with the average temperature of -3°C and with precipitation over 2000 mm. The Mann-Kendall non parametric test coupled with the Sen’s slope was applied to identify the significant long-term climatic trends, as well as the magnitude of those trends. It was found increasing trends in both analysed hydrological variables. Keywords: precipitation, temperature, trend analysis. Acknowledgment: The Centre was supported by the Slovak Research and Development Agency under the contract No. SUSPP-0007-09. 429 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Drought Analysis in Konya Closed Basin First A. Bilgil 1, Second O. Arslan2 and Third E. Aras* 3 1, 2 3 Civil Engineering Department, Nigde University, TURKEY. (E-mail: [email protected], [email protected]) Civil Engineering Department, Nigde University, TURKEY. (E-mail: [email protected]) ABSTRACT Konya Closed Basin which is located in Central Anatolia, is surrounded by Sakarya and Kızılırmak Basins in the north, Kızılırmak and Seyhan Basins in the east, Eastern Mediterranean Basin in the South and Antalya and Akarçay Basins in the west. It has a total area of 53,850 km2 and lies between latitudes 36°51' and 39°29' N, and longitudes 31°36' and 34°52' E. Konya Closed Basin is one of the most drought regions in Turkey receives low rainfall. Therefore, drought analysis in the basin is important for the planning and management of water resources in the basin. In this study, droughts in Konya Closed Basin were investigated by using Standardized Precipitation Index (SPI) based on monthly precipitation records of 4 meteorological stations (Konya, Niğde, Aksaray and Karaman). SPI values of each station for 1, 3, 6, 9 and 12-month time scales were calculated. According to the results, droughts in various intensities were determined. This study is in progress. Therefore, details and detailed results of this study will be given in the full text. Keywords: Drought Analysis, Konya Closed Basin, SPI. 430 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 An Investigation of the Effect of Climate on Global Solar Radiation Using the Satellite Data for Nevşehir Selmin Ener Rusen* Department of Energy Systems Engineering, Karamanoğlu Mehmetbey Univ., TURKEY. (E-mail: [email protected], [email protected]) ABSTRACT The solar irradiation values, on a horizontal earth surface and integrated over the whole spectrum range, is the most important component of the essential climate variables according to the Global Climate Observing System (GCOS) in August 2010. For the measurements of solar irradiation, ground network is not adequate and the data taken on the long-term are not quite reliable in most stations. Therefore, satellite-based methods for solar irradiation estimation such as the well known HELIOSAT method are quite promising and have been gradually improving in recent years. The general idea of the HELIOSAT is to deal with atmospheric and cloud extinction separately. In order to derive cloud extinction information, geostationary satellites such as METEOSAT which cover a large area with a very high spatial resolution and sufficient temporal resolution are used. This paper offers seasonal analysis aiming to observe the effects on the climate of solar radiation using a modified version of HELIOSAT method with METEOSAT visible channel images. Using five years data, seasonal average solar irradiation values for Nevşehir has been calculated and standard error analyses are carried out. The preliminary results are encouraging for the further studies on how about to use long term global solar irradiation data to determine a road map about climate change. Keywords: Climate, HELIOSAT, Satellite, Solar irradiation. Acknowledgment: The authors would like to thank Oldenburg University and Turkish State Meteorological Service (TSMS), for providing us with measured data. I would also like to thank Prof. Dr. B.G. Akınoğlu and Dr. A. Hammer for discussions and comments during the course of these studies. 431 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Do Cultural Differences Matter in Education on Environment? Diana Nedelcheva Bebenova-Nikolova* Business and Management, Ruse University ‘Angel Kanchev’, Bulgaria. (E-mail: [email protected]) ABSTRACT Going beyond the country borders, the current environmental challenges demand international cooperation of leaders for their solutions. However, once negotiated, environmental regulations might not be adopted in the concerned countries, as they might be extrinsic to national practices. A possible explanation is that differences in thinking and perceiving the environment have been ignored. The cultural anthropologist Geert Hofstede refers to ‘…such patterns of thinking, feeling, and acting’1 as culture patterns or mental programming. One such pattern is the relationship between individuals and environment. The answer to the question: ‘Am I part of the natural environment, or am I separate and perhaps superior to nature?’ influences the types of personal attitudes, environmental behaviors and practices, including the ones perceived and taught at school. Following that, it is interesting to survey school practitioners’ perceptions on environmental issues and apply Geert Hofstede cultural dimensions theory to explain the differences. This paper presents such findings about early years practitioners’ perceptions on global issues like: interconnectedness, environment and sustainability. The evaluation survey, implemented in four EU countries (UK, Poland, Bulgaria and Cyprus), is part of the project ‘The world at our doorstep’, funded by EuropeAid. The latter aims at including everyone in finding innovative ways to address the economic, political, environmental and social dimensions of inclusive sustainable development. Based on Hofstede cultural dimensions, the paper discusses the findings of the project survey and recommends some ideas on defining the content of the education on environment so that it becomes more culturally sensitive and thus more effective. Keywords: cultural dimensions, education, environment. Acknowledgment: The authors thank Nevsehir Haci Bektas Veli University, Scientific Research Project Funding (NeU BAP) for their financial support [Project number: NEUBAP13F8]. 432 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 To explore the use of analysis of cognitive hillside by using SEM – An Example of Te-Chi Reservoir Watershed Tzu-Yin Chen *1, Ho-Wen Chen 2 , Wei-Lun Lin 3, Yao-Jhou Zeng 4 1,2,3,4 Environmental Science and Engineering Taichung Tunghai University, Taiwan. No.1727, Sec.4, Taiwan Boulevard, Xitun District, Taichung 40704, Taiwan (R.O.C.) (Email: [email protected], [email protected], [email protected], [email protected]) ABSTRACT In recent years, the crops are quite popular in domestic. With the pressure of population and the demand for land, the economic-oriented over use of slopeland is aggravating each day. On the lands particularly in the reservoir watershed area, problems like debris flow and reservoir silting further arise and seriously affect the environmental conservation in watershed and the safety of household water. Using Taiwan Te-Chi Reservoir for an example, this study designs questionnaires and conducts questionnaire survey and Structural Equation Modeling as major research tools to test people’s cognition of environmental conservation and understanding about environmental policies and to assess the role and contribution of mass media and representatives of public opinion. Our results indicate that the interviewees reported having quite sure media objectivity, such as people know that the solpeland will accelerate the development of hillside reservoir sedimentation by media, the hillside overrun is caused by the use of the main cause of landslides, and so on. According to these examples, we can know that the media have some influence on the public perception of environmental conservation. Keywords:Te-Chi Reservoir Watershed、Structural Equation Modeling 433 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Use of unconventional water with sustainability approach in Iran Javad Tabatabaei Department of petroleum, Meymeh branch, Islamic Azad University, Meymeh, Iran (E-mail: [email protected]) ABSTRACT The Water shortage is inevitable that caused the attention of planners and water specialists to focus on the efficient use of water. Unconventional water as a sustainable water resources due to the limitation and problems of dehydration in Iran, is one of the main strategies to deal with the water crisis, and is considered one of the pillars of sustainable development. Crisis of global water challenges, requires comprehensive management of unconventional water use for the environmental sustainable. Due to the dry climate of the Iran plateau, the sustainable use of water resources to be considered the most important element of development these projects. In many part of the world in arid and semiarid, due to the severe drought phenomenon, the use of these resources as a major cause of economic and social development is very important. Therefore, to improve the efficient use methods of water resources especially unconventional water can be an important step in the management of problems associated with water crisis. Due to limited water resources, only 8.7 million hectars of land is under irrigation. Due to lack of sufficient water and an increase in population, there is no choice to use from unconventional water. Keywords: Arid and semiarid regions; Drought; Optimal use; Phenomenon; Water crisis 434 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Prospect of Iran Natural Gas Export Projects By: HEDAYAT OMIDVAR Member of IGU Marketing Committee Head of Communication Affairs with Science & Research Centers, Research & Technology Dept., National Iranian Gas Company No.77-Southern Aban St. - Karimkhan Ave.-Tehran-1598753113-Iran Tel:+98-21-81315646 Fax:+98-21-81315682 Email: [email protected] ABSTRACT Iran holds the second largest gas reserves in the word with over 34 trillion cubic meters (TCM) of natural gas. Due to lack of geological surveys in certain geographical regions in Iran. It is likely to explore further reserves in the future. Hence, for utilizing this energy carrier, it is essential to have comprehensive and explicit planning knowledge. The study of gas industry development policies is indicative of certain barriers in utilizing prospective opportunities. Iran is one of the largest gas rich countries in the world that production capacity exceeds domestic consumption and gas injection requirements. Gas can be utilized as feed stock in petrochemical plants and refineries or exported through pipeline or LNG. Through re-injection of gas to oil reservoirs, while increasing the oil recovery ratios, the produced gases from fields shared with other countries could be stored into domestic gas fields. Gas consumption in domestic markets and its substitution with oil products, in addition to providing environmental benefits, will also result in optimum consumption of these products and relieving the government from the heavy burden of existing and heavy expenditures of importing these products from foreign countries. The need for energy sources in the world along with the enormous natural gas reserves in the country opens broad economical/political dialogue scene towards us and contributes an outstanding strategic significance to our gas resources. Supplying gas requirements, proper and timely production and operation of joint reservoirs such as the south pars with the intention of supplying gas requirements and providing balance of supply and demand as well as maximum utilization of our share in these fields are other development requirements of this significant industry. For planning and policy making regarding the development of gas industry, it is essential to manage all aspects of gas from exploration and production to consumption, injection and exports and etc. through a sole administrative institution so that prearranged plans could be implemented without becoming subjected to such problems as lack of coordination parallel activities and organization al problems. Gas fuels consumption occupies one half of Iran's energy consumption, and to increment this share, the government should increase investment in the gas sector. Natural gas while being utilized as a clean fuel in domestic markets can become a device to implement gas injection to oil production from the countries reserves as well as gas exports towards presence in international venues and commercializing gas globally. Prediction indicates that natural gas being the favorable fuel of the present century, will enjoy the largest growth among items within the energy basket and during the next twenty years as well, the growth of natural gas demand in the world will exceed other conventional energy sources. In the future, due to various factors such as vaster accessible sources and reserves, developed technologies which in effect reduce project expenditure and construction periods and consequently improve the economy of developing gas transmission projects, as well as global endeavors to curtail emission of green house gases, are the major reasons for gas consumption growth. Iran, in respect to her geographical and political strategic situation, can play a leading role in global gas supply and act in Europe and Asia. Natural gas still maintains the fastest consumption growth rate among the world's primary energies and is realized to have the highest consumption growth among the developing countries. Gas has been recognizing as the fuel for the future. This is entirely evident as a result of decreasing global resources due to environmental considerations. According to IEA estimates, in year 2015, oil demand will reach 93 million barrels and natural gas demand will reach 64 million barrels of oil equivalent. This in effect is a 20% increase for oil and 45% for gas in regard to current figures in conclusion. It could be stated that more than ever before, gas has gained significance and is the leading basis for modern services in energy, and in the long term is considered a bridge towards a hydrogen resource based economy. Gas as a new fuel, provides the modern technology of fuel cell construction for vehicles possible. To portray the enormity of Iran gas reserves it is enough to consider that Iran's natural gas reserves alone exceeds the total volume of natural gas reserves in USA, Canada, Europe and the entire Asia pacific. 435 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Use of the Wind Energy as a Renewable Energy in Traditional Architecture of Iran as Natural Ventilation Davood Rezaei*1, Saeid Rezaei2 1 Architectural Department of University of Zanjan IRAN ([email protected]) 2 Architectural Department of Sariyan University,IRAN ([email protected]) ABSTRACT Lack of suitable access to the permanent energy resources motivates humans to look for sustainable source of energy like solar and blue energy. Wind is one of the renewable sources of energy in nature which must be controlled in order to use its capability to create energy. According to wind properties it can provide the optimum condition for human comfort. The needs for humidity and ventilation in desert areas have made it inevitable to look at wind as a natural phenomenon. In Iranian architecture capability of wind appears by using different sort of wind tower, wind scope and orientation of building and direction of wind tower structures and concentrating on some new solution for optimum use of wind energy. Keywords: wind energy, ventilation, wind tower, Iranian traditional architecture 436 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Advances of Energy Tree Method in Calculation of Gross Hydropower Potential Sadık ALASHAN 1, 2 Z. Fuat TOPRAK 3 and Zekai ŞEN 4 1 2 Research Assistant, Hydraulics and Water Resources, Bingol University, TURKEY. (E-mail: [email protected]) Ph. Dr. Student, Hydraulics and Water Resources, Istanbul Technical University, TURKEY. (E-mail: [email protected]) 3 Hydraulics and Water Resources Division of Dicle University, TURKEY. (E-mail: [email protected]) 4 Hydraulics and Water Resources, Istanbul Technical University, TURKEY. (E-mail: [email protected]) ABSTRACT Hydropower energy is required for wealthy life standards because of no greenhouse gases emission. Since it has highest production rates among other renewable energy resources, correctly estimating the gross hydropower potential become an important issue. This is essential for optimally using water resources. Several improved methods can be found in the current literature for calculation hydropower potential. Two of them, namely, “hypsographic curves” (HC) and “drawdown-flow” (DF) methods are often used for the hydro-electric energy calculation goals. The HC method is used for basins, which have insufficient flow data. So this method calculates approximately the gross hydro-power potential. The method is based on average basin altitude, inflow and outflow values . On the other hand, DF method is used for basins with sufficient flow data. So it is expected to be more sensitive in gross hydro-power potential calculations. The method based on elevations and flow data. Energy tree method (ETM) is another method for gross hydro-power estimation for any basin. In this method the flow is taken into account as a function of height (elevation-altitude). This approach is thought to be more sensitive in gross hydro-power calculation than the above mentioned two approaches. In this study, ETM is re-modified by adding the area (A, in km2) into to the valid expression and the last two expressions together with HC and DF are applied to the data obtained from the flow observation stations established on the main distributary of the Euphrates River. The gross hydro-power is calculated by using the three methods and the results are compared each other. By comparing the results, the modified energy tree method (METM) seems to be the best with the highest gross hydro-power estimation. Keywords: Hydropower, River basin, Energy Tree, Drawdown-Flow, Hypsographic Curves 437 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 The Use of Active Solar Energy Systems for Heating Greenhouse: Central Anatolia Case Study B.Kendirli 1, H.E.Polat *1 and S.Avcı 1 1 Department of Farm Structures and Irrigation, Faculty of Agriculture, Ankara University, TURKEY. (E-mail: [email protected], [email protected], [email protected]) ABSTRACT Heating requirement of greenhouse occurs during the periods of low external ambient temperatures. Due to the high cost of traditional energy sources, new and renewable energy sources for heating of greenhouses take advantage of great importance, today. Some alternative energy sources util ized in heating the greenhouse; solar energy, geothermal energy and industrial characterized waste heat energy. Solar energy is an important potential in our country; the maximum duration of the Sun in July has 365 h/month, and at least in December with 103 h/month including, and total has 2624 h/year. Nowadays, solar energy has more effective advantage for greenhouse heating and that gained great importance in practice, although it has some technically and economically problems. In this study, the amounts of heating requirements throughout the year in greenhouses were calculated taking into account the climatic conditions of Central Anatolia region. Also in created greenhouse models that have different types, sizes and materials; heating requirements have been calculated for Central Anatolia Region. According these calculations, active solar energy heat requirements and system costs were determined. Keywords: Central Anatolia region, greenhouse, heating, renewable energy, solar energy 438 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 ENERGY EFFICINCY OF A RESIDENTIAL FLATE IN EGYPT Nabil M. Guirguis Housing and Building National Research Center, Cairo , Egypt [email protected] ABSTRACT This paper evaluates the energy efficiency of a single flat residential building. A software package (VisualDoe) was used for this analysis. This flat is of total area 200 m2 with one façade openings. Three different climatic regions were used for this analysis, Cairo, Alexandria and Aswan cities with different weather conditions. Cairo is characterized with a moderate humid climate. Alexandria is classified as a moderate low humid climate. Aswan is of hot arid climate. The study includes the effect of wall construction and insulation thickness on the electric cooling energy consumption (using a split HVAC system) all over the year (Annual Energy Consumption), and also the effect of roof insulation. Different orientation of the flat was taken in place. The life cycle costs for different cases were also evaluated. The results give the minimum requirements of walls and roof insulation for different orientation and for different climatic regions. The results represent also a comparison between the roof insulation and shading. The North and North-East façade need less wall insulation than other façade. The roof needs more thick insulation than the walls especially in Aswan city. Also natural ventilation rate for night cooling were also evaluated. Keywords: Energy efficiency; electricity consumption; insulation; roof shading; life cycle cost 439 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Prediction of Basic Wind Speed for Oman Said Saif Salim Al-Maawali Assistant professor, Middle East College, Muscat, Oman [email protected] ABSTRACT In order to build safe and economical structures, it is important to have a thorough understanding of wind characteristics and issues related to wind-structure interactions. Oman has no Code of Practices for Wind Loading for Buildings yet. Hence, many designers adopted the value of basic wind speed from foreign codes of practice such as the British Standards (BS8110, BS6399). The aim of this study is to develop the value of basic wind speed using collected daily wind speed from 13 meteorological stations all around Oman for 5-23 years. The wind speed data have been statistically analysed using three different prediction methods (Gumbel, Cunnane and Gringorten) and two different data types [all data and Method of Independent Storms (MIS)]. Thus the value of basic wind speed are predicted. The recommended basic wind speeds for building design in Oman are as follows; Muscat (33 m/s), Salalah (36.5 m/s), Nizwa (33.5 m/s), Saiq (33.5 m/s), Sohar (32 m/s), Sur (31 m/s), Buraimi (34 m/s), Masirah (33.5 m/s), Thumrait (25.4 m/s), Khasab (32 m/s), Ibra (34.5 m/s), Ibri (33.5 m/s), and Qarn Alam (29.5 m/s). Keywords: Basic wind speed, Cunnane method, Gringorten method, Gumbel method, Method of independent storm, Oman. 440 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Biodiesel Feedstock Production from Mixed Culture of Microalgae and Yeast using Fermented Rice Noodle Wastewater as Substrate Mutiyaporn Puangbut 1, Thidarat Papone 1 and Ratanaporn Leesing *1, 2 1 2 Department of Microbiology, Faculty of Science, Khon Kaen University, THAILAND. (E-mail:[email protected], [email protected]) The Center for Alternative Energy Research and Development, Khon Kaen University, THAILAND. (E-mail: [email protected]) ABSTRACT Microbial oils are known as the third generation of biodiesel feedstock because of their similar fatty acid composition to that of vegetable oils and offer a unique alternative as it does not compete with agricultural food production. In this work, microbial oil production from mixed culture of microalgae Chlorella sp. KKU-S2 and oleaginous yeast Torulaspora maleeae Y30 was investigated using different concentrations of fermented rice noodle wastewater hydrolysate (FRNWH) as carbon substrate via batch mixotrophic growth under continuous illumination for 6 days and biodiesel production by direct transesterification from wet biomass obtained was studied. Comparing of growth and lipid yield, monoculture of Chlorella sp. KKU-S2 was also performed. In mixed culture, a maximum biomass of 6.54g/L and 6.35g/L with biomass productivity of 1.098g/L/d and 1.058g/L/d were found at 20 and 25g/L FRNWH, respectively. While a maximum biomass of 3.59g/L with biomass productivity of 0.598g/L/d was obtained from monoculture of Chlorella sp. KKU-S2 at 5g/LFRNWH. A maximum lipid yield of 2.56g/L with lipid productivity of 0.427g/L/d and 0.324g/L lipid with lipid productivity of 0.054g/L/d was obtained from mixed culture and monoculture of microalgae grown on 25g/L FRNWH, respectively. Biodiesel as fatty acid methyl ester (FAME) was synthesized by base-catalyzed and acid catalyzed direct transesterification from wet biomass using methanol as solvent via microwave-assisted technique at 480W microwave power for 1-3 min reaction time. The FAME was determined by Thin Layer Chromatography technique. The obtained result showed that fermented rice noodle wastewater can be use as cost-effective carbon substrate to produced biodiesel feedstock by mixed culture of microalgae and yeast and direct transesterification could apply for biodiesel production from wet cell of mixed culture. Keywords: Biodiesel, Fermented rice noodle wastewater, Microbial oil, Microalgae Oleaginous yeast. Acknowledgment: The authors thank The KKU research fund, The Center for Alternative Energy Research and Development and Fermentation Research Center for Value Added Agricultural Products, Khon Kaen University for their financial support. 441 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 Effect of Trace Metal Supplementation in Anaerobic Digestion of Chicken Manure R. Molaey*, A. Bayrakdar, R.Ö. Surmeli, B. Calli Department of Environmental Engineering, Marmara University, 34722 Goztepe, Kadikoy, Istanbul, Turkey (E-mail: [email protected], [email protected], [email protected], [email protected]) ABSTRACT The deficiency of trace metals leads to reduce the anaerobic digestion performance. Even though a variety of organic wastes is assumed to provide the sufficient amount of micronutrients, recent findings in anaerobic digestion are in contrast to this assumption. Therefore, the aim of this study is to investigate the effect of trace metals on anaerobic digestion and biogas yield of nitrogen rich chicken manure. In this study, the effect of trace metals supplementation on biogas production was investigated with batch biogas yield tests at different NH4-N concentrations. As substrate acetate, propionate, butyrate or raw chicken manure at a final concentration of 1000 mg COD/l was used. The biogas productions profiles and yields under TM supplementation and different ammonia concentrations were compared to the yields of control reactors. Batch tests were conducted in triplicates and the total active volume was 100 ml. Concentration of seed sludge taken from a laboratory scale chicken manure digester was adjusted to 2g/l volatile solids (VS) using dilution solution and the mixture was incubated overnight without addition of substrate at 36°C. Transfer of seed sludge and substrate to the reactors was done under anaerobic conditions. The reactors were sealed using special caps and incubated at 36oC. Biogas production continuously monitored using a multitube manometer set-up working based on water displacement. To prevent the dissolution of the gases, pH of the manometer solution was adjusted to 2 and 40 g/l NaCl was added. When the NH4-N concentration was below 3000 mg/L, trace metals supplementation improved the biogas production in reactors fed with VFAs and chicken manure by 7.5% and 6.4%, respectively. At elevated NH 4N, adding trace metals improved the biogas production in reactors fed with VFAs by 12.7%. On the other hand, no significant improvement was observed in biogas production in reactors fed with chicken manure. Keywords: Ammonium, Biogas, Chicken manure, Trace metals Acknowledgment: This study was financially supported by Scientific and Technological Research Council of Turkey (TÜBİTAK) [Project number: 113Y333]. 442 ICOCEE – CAPPADOCIA 2015 Nevsehir, TURKEY, May 20-23, 2015 New Chernobyl Metsamor Nuclear Power Plant Altikat A.* 1, Dogru S. 2, Argun Y.A. 3 and Bayram T. 4 1 2, 3 4 Department of Civil Engineering, Engineering Faculty, Igdir University, TURKEY. (E-mail: [email protected]) Environmental Helath Programme, Vocational School of Health Services, Igdir University, TURKEY. (E-mail: [email protected], [email protected]) Department of Environmental Engineering, Engineering Faculty, Yuzuncu Yil University, TURKEY. (E-mail: [email protected]) ABSTRACT Metsamor Nuclear Power Plant (Armenian Nuclear Power Plant-ANPP) in Metsamor, Armenia, is 30 km away from Igdir, located at the east of Turkey, and is a facility that meets the majority of Armenia's energy needs. The Armenian NPP consists of two power units with WWER-440/270 reactors. The Unit 1 was put into operation on December 22, 1976 and the Unit 2 was put into operation on January 5, 1980. The installed power of the units is 407,5 MW(e). In 1989 the The Union of Soviet Socialist Republics (USSR) Ministers Council made a decision on the shutdown of the Armenian NPP. The Unit 1 and the Unit 2 were shut down on February 25, 1989 and March 18, 1989, correspondingly. After the collapse of the USSR the following events resulted in severe energy crisis in Armenia. On April 7, 1993 the Government of Armenia made a decision on restart of the Unit 2. On November 5, 1995 the ANPP Unit 2 was restarted, after 6,5 years of shutdown. With restart of the Armenian NPP after severe energy crisis Armenia moved on to day-and-night power supply schedule. In this study it has given information about the history and operation of Armenian NPP and demonstrated the factors that led to shotdown of the plant for a period and the arised risks resulting from reopening it. In addition, it has presented recommendations about foundation and safe operation of nuclear power plants by the basis of Metsamor reference. Keywords: Igdir, Metsamor, Nuclear Power Plant. 443 International Conference on Civil and Environmental Engineering ICOCEE - Cappadocia 2015 Conference Programme Time Wednesday, 20 May 2015 08:30 - 11:00 Conference Registration* 11:00 - 12:00 Openning & Award Ceremony 12:00 - 13:30 13:30 - 14:00 14:00 - 14:30 14:30 - 15:00 15:00 - 15:30 15:30 - 16:00 16:00 - 16:30 16:30 - 17:00 17:00 - 17:30 17:30 - 18:00 Welcome Lunch Prof. Dr. Derin ORHON, Istanbul Technical University, TURKEY. Innovative Technologies in Wastewater Treatment. Prof. Dr. Beatrice LE DESERT, University of Cergy-Pontoise, FRANCE. Innovative Building Materials and Their Environmental Impacts. Prof. Dr. Zekai ŞEN, Istanbul Technical University, TURKEY. The importance of Philosophy and Science in Engineering, Architecture and Technology. Prof. Dr. Erdogan YÜZER, Istanbul Technical University, TURKEY. Two Divine Masters Who Kneaded Their Lives With Stone: Michelangelo & Sinan the Architect. Coffee Break Prof. Dr. Oral BÜYÜKÖZTÜRK, Massachusetts Institute of Technology, USA. Field Measurement Based System Identification of Tall Buildings. Prof. Dr. Uwe STILLA, Technical University of Munich, GERMANY. Digital Methods for the Built Environment. Prof. Dr. F. Necati ÇATBAŞ, University of Central Florida, USA. Structural Health Monitoring for Civil Infrastructure Systems. Prof. Dr. Mohamed ABDEL ATY, University of Central Florida, USA. Using Big Data Analytics for Pro-active Traffic Management. * Conference Registration for Delegates, Students and Listeners will be carried out on 20 May 2015. Daily Delegates will register on the day when they will present their study. Thursday, 21 May 2015 Time 09:00 - 09:15 09:15 - 09:30 09:30 - 09:45 09:45 - 10:00 10:00 - 10:15 10:15 - 10:30 Session 1 - A Session 1 - B Session 1 - C Chair: Prof.Dr. Derin ORHON Chair: Assoc.Prof. Dr. Igor BODIK Chair: Prof. Dr. Magdaléna Bálintová S. Das, Y.P. Ting Hydrogen peroxide aided sulphuric acid pre-treatment of electronic waste for improving gold recovery by metabolically-engineered strain of chromobacterium violaceum. D. Ulutaş, Z. Çokaygil, A. Özkan, Y.Güney, M.Banar A new bitumen geosynthetic barrier mainly based on boron production waste clay for landfill liner systems. I. Bodík, T. Mackuak, M. Fáberová, M. Mosný I. Kocaturk, T.H. Erguder Occurrence of illicit drugs and pharmaceuticals in Effect of influent COD/TAN ratio on carbon and nitrogen municipal wastewater and possibilities for their removal. removal efficiency and stability of aerobic granules. M. Vekli, C.C. Çadır, F. Şahinkaya Ground improvement via chrome and steel slags. Ş. Doğan, R. Kıdak Efficiency of UV and UV/H 2 O 2 processes for amoxicillin treatment. G.F. Gökçe, N. Mazlum, P. Hasanoğlu R. Kıdak, Ş. Doğan Düzce potential investigation of domestic and industrial Flow reactor model for UV treatment of amoxicillin. solid waste recoverable. A. Bilgin Investigation of nitrate treatment potential of tea waste. M. Balintova, M. Holub Adsorption of heavy metals from aqueous solution by nonmodified clinoptilolite in fixed-bed system. Z. Bingül, F. Ekmekyapar Torun Solid waste management in Erzurum. G. Doğdu, A. Yalçuk E. Singovszka, M. Balintova Biosorption of commercial yellow 2G and indigo textile Cluster analysis of water quality in water reservoir Ruzin dyes by powder Hawaiian spirulina pacifica. I., Slovakia. G. Demirel Bayık, A. Altın, Ö.F. Çapar Effect of soil minerology on electrokinetic remediation. Ç. Ulusoy, D. Teresa Sponza K. Ashrafi, M. Zamani, G.R. Nabi Bid Hendi Removal of olive mill wastewater pollutants by UV and Prediction of surface ozone concentration by a semisunlight irradition with nano- SiO 2 /Fe 3 O 4 composite and empirical photochemical model. reuse properties. Coffee Break 10:30 - 11:00 11:00 - 11:15 M. Balaban, D. Teresa Sponza E. Dorgeloh, D. Verschitz Treatment of olive mill wastewater by photooxidation to European market for decentralized wastewater systems. nano-ZnO-bentonite composite and recovery of OMW. Session 2 - A Session 2 - B Session 2 - C Chair: Assist.Prof. Dr. Korkmaz BELLİTÜRK Chair: Assoc.Prof.Dr. Bülent İÇGEN Chair: Assist.Prof. Dr. Ece Ümmü DEVECİ O. Ayyildiz, B. Ileri, Ö. Apaydin K. Bellitürk, J.H. Görres, H.S. Turan, S. Göçmez, M.C. D. Angın, G. Demir, S. Güneş, A. Ilci Bağdatlı, M. Eker, S. Aslan Environmental quality of compost: Can composting Adsorption of orange 13 from aqueous solutions using Reduction of nitrate by combined ultrasound and zeroearthworms (eisenia fetida) help manage compost nutrient activated carbon prepared from orange (citrus sinensis l.) valent magnesium under pH uncontrolled conditions. pulp. ratios? 11:15 - 11:30 11:30 - 11:45 11:45 -12:00 12:00 - 12:15 12:15 - 12:30 T. Bayram, Y.A. Argun, A. Altıkat, S. Doğru Management of solid waste in the sample of a small sized Turkish town, Erzurum. H.E. Polat Effects of different barn planning system on waste characteristics – Case study of Turkey. M. Öztürk, A.F. Çabalar California bearing ratio of a clay with waste carpet jute. K. Umiejewska Wastewater treatment in Poland taking into special consideration anaerobic reactors. K. Yanaç, R.W. Murdoch Biodegradation of the non-steroidal anti-inflammatory pharmaceutical flurbiprofen. T. Tunçal, D.İ. Çifçi, O. Uslu A new approach for sludge disintegration & stabilization: Solid TiO 2 thin films. E.Ü. Deveci, Ç.Ş. Sağlam, Ü.K. Çakır, K. Bayrak Life cycle assessment of fossil fuel-fired thermal power plant. M. Sogancıoğlu, Ü. Sultan Keskin, E. Yel The role of water in recycling the physicochemical treatment sludge as concrete admixture. E.Ü. Deveci, N. Dizge, H.C. Yatmaz, Y. Aytepe Degradation of synthetic textile dyes using fungal bioreactor and photocatalytic reactor. L.G. Santhosh, P. Lakshmikanthan, G.L.S. Babu M.S. Ak, F. Yılmaz, B. Içgen Evaluation of performance of MSW landfill barrier systems Biogas production by anaerobic digester exposed to at laboratory scale and using HELP model simulations. ammonia changed with changing bacterial population dynamics. P. Lakshmikanthan, L.G. Santhosh, G.L.S. Babu F. Kara Murdoch, F. Dilek Sanin Evaluation of the mechanical and hydrological Assessment of anaerobic microbial community structure in characteristics of a bioreactor landfill using laboratory the presence of nonylphenol diethoxylate using simulators. fluorescence in situ hybridization. H.B. Özel, H. Ucun Özel The effect of heavy metals in soil and plants around a lime factory in the Bartın city in western Black Sea region. Lunch Break 12:30 - 14:00 14:00 - 14:15 14:15 - 14:30 14:30 - 14:45 14:45 - 15:00 N.C. İskender, M. Sogancioglu, E. Yel, N. Yilmaz Removal of oil-grease from dairy industry wastewater using an adsorbent obtained from waste material. Session 3 - A Session 3 - B Session 3 - C Chair: Prof.Dr. Fulya ÖZTAŞ Chair: Prof. Dr. Haydar ÖZTAŞ Chair: Prof. Dr. Süreyya MERİÇ Á. Rédey, T. Juzsakova, T. Fráter, A. Csavdari, L. Ráduly, V. Selen, Ş. Taşar, M. Çakmak, D. Özer, A. Özer I. Ráduly Industrial waste – Red mud as catalyst for hydro- Adsorption of methylene blue dye on multi-walled carbon dealkylation. nanotubes (MWCNTs) - A response surface methodology (RSM) approach. S. Dağlı, A.Dönertaş , H. M. Basar, İ.Yolcubal, E.Sangu, L. M. Çakmak, Ş. Taşar, V. Selen, A. Özer, D. Özer Tolun GIS application on disposal of dredge materials. Removal of astrazon golden yellow 7GL from colored wastewater using activated clay. F. Öztaş C. Eryılmaz, A. Genç Preventative medicine for the environment: Developing The separation of emulsified oils from wastewater by the and implementing environmental programs that work. application of electric field. F. Saffarimiandoab, İ. Koyuncu, H. Kilzer Key environmental challenge of seawater desalination. G.V. Saraçoğlu, C.B. Özkal, S. Göçmez, F. Ekmekyapar, A. Koruyucu, S. Meriç Monitoring of antibiotics in urban wastewater in Tekirdag city: A comparison with predicted environmental concentrations. Y. Chen, J. Vymazal Removal process of chloroform in treatment wetlands: From mass balance to microbial analysis. C.B. Ozkal, A. Koruyucu, S. Meriç Energy and pH dependency optimization of degradation, mineralization and detoxification of ampicilline by photocatalysis. Ö. Kaplan, M. Gündüz, G. Turan, K.S. Yiğit S. Dikmen, H. Bircan, G. Yılmaz An economic analysis of sewage sludge management Anion selectivity of sepiolite and its surface active agents methods in Kocaeli. Modified forms. 15:00 - 15:15 15:15 - 15:30 T. Akdeniz, H. Muhammetoğlu Chlorine dosing management strategies for water utilities using GIS, SCADA and modelling tools: Case study of Yeşilbayir Antalya. Ç.F. Karafakı Water management policies in the European Union: Finnish integrated water management example. 16:15 - 16:30 16:30 - 16:45 D. Akın Şahbaz, S. Balbay, C. Açıkgöz O. Tunç Dede Evaluation of the adsorption capacity of the expanded Evaluation of uncertainty for trace elements measurement perlite to remove linear alkyl benzene sulphonic acid in drinking water with ICP-MS. (LABSA) from aqueous solution. Coffee Break 15:30 - 16:00 16:00 - 16:15 I. Şentürk, H. Büyükgüngör A. Aygün, B. Nas, A. Berktay The effect of different pH at constant temperature on Optimization of electrocoagulation process to treat young biohydrogen production from sewage sludge. landfill leachate using response surface methodology. Session 4 - A Session 4 - B Session 4 - C Chair: Assoc.Prof. Dr. Füsun EKMEKYAPAR Chair: Prof.Dr. Güleda ENGİN Chair: Prof. Dr. Gülfem BAKAN M.B.L.D. Diola, A.C. Resurreccion D. Uçar, E. Çokgor, E. Şahinkaya, A. Yurtsever Environmental contamination and residential exposure of Simultaneous nitrate and perchlorate reduction in mercury in artisanal gold mining area in Benguet, elemental sulfur based autotrophic and heterotrophic processes. Philippines. Z. Maymekov, D. Sambaeva, J. Izakov, A. Isaev, J. G. Güney, D. Teresa Sponza Sydykov T. Tetik, Z. Celep Structural performance of Sheikh Suleiman Masjid and its strengthening. G. Bakan, S. Laçin Assessment of the cations and anions concentration Comparision of biological and advanced treatment Environmental modeling approaches for exposure and risk distribution in underground potable waters, pH solution processes for ciprofloxacin removal in raw hospital assessment of prioritize chemicals in industries. analysis subject to the temperature and content of wastewaters. technogenic sodium chloride. C.R. Orozco, R.Q. Macasieb, B.J.M. Tapales, A.C. P. Akan, M. Bekbölet A. Kulig Resurreccion Spatial variation and heavy metal concentration in Adsorption and kinetic studies of molecular size fractions From environmental audit of land to baseline report: sediments of Bued River: A preliminary assessment of a of humic acid onto anion-doped TiO 2 specimens. Polish implementation of the EU directive on industrial river nearby small-scale mining sites in the Philippines. emissions in the context of soil protection. 16:45 - 17:00 B. Yalçın Çelik, K.O. Demirarslan Ö. Aktaş, Y. Toker, E. Şahinkaya G. Önkal Engin, M. Çelen Eastern Black Sea region of domestic water capacity: The Biodegradation of various azo dyes in anaerobic batch Land use change in İzmit Bay catchment. case of Artvin. reactors. 17:00 - 17:15 R. Çelik D. Karaeren, Z. Bozkuş E. Akçam, G. Bakan Determination of Diyarbakır basalt aquifer water quality Comparison of performance of labyrinth and piano key Sediment and water pollution status of the mid-Black Sea coast of Turkey. parameters and obtain thematic maps with using GIS weirs in increasing the spillway capacity of dams. technique. M.P. Lumbera, R.E.P. Cabungcal 17:15 - 17:30 17:30 - 17:45 17:45 - 18:00 18:00 - 18:15 Integrating storage sizing and slow sand filtration for Do personal care detergents pose risk in the aquatic Characterization and ecotoxicity residential rainwater harvesting applications in the environment: investigation. Philippines. S. Adiloğlu, A. Adiloğlu, F. Eryilmaz Açıkgöz, T.Yeniaras, J.H. Görres, R. Gilker, J.J. Colby, K. Bellitürk Y. Solmaz Phytoremediation of cadmium (Cd) from agricultural soils Compaction mitigation potential of biotillage and using dock (rumex patientia l.) subsurface tillage in dairy pasture soils. S. Benzer, R. Benzer, Ç. Karasu Benli Application of artificial neural networks for growth forecasting of crayfish (astacus leptodactylus eschscholtz, 1823). E. Demirel A.K. Durrani, M.R. Khan, M. Ahmad Lead content in local paints in Pakistan. T. Zorlu, Z.U. Nurullahoğlu, S. Kaya A.U. Şahin Effects of titanium dioxide nanoparticles on hemocytes of A new area based parameter estimation methodology for galleria mellonella (L.) (lepidoptera: pyralidae). leaky aquifer system. S. Bulgak, F.N. Kafadar, K. Sarpkaya, C. Can, S. Güneş F. Sunca, M. Akköse E. Geçer, H. Büyükgüngör Use of fly ash in the design of controlled low-strength A case study of green building design. material mixture. Friday, 22 May 2015 Time 09:00 - 09:15 Fe(II)-Co(II) double salt incorporated magnetic hydrophobic microparticles for invertase adsorption. Numerical simulation of wave-structure interaction using a Chickpea ascochyta blight disease severity in the Evaluation of seismic performance of prefabricated ghost-cell immersed boundary method. Bosphorus region of Turkey. structures using push-over analysis. D.E. Candelaria, K.M.D.S. Maurillo, N.B. Diola 18:15 - 18:30 O. Kizek, İ.D. Çifçi, F. Ekmekyapar, A. Sicigliano, S. K. Köse, K. Erol, A.A. Emniyet, D.A. Köse, G. Alp Avcı, Meriç L. Uzun Session 5 - A Session 5 - B Session 5 - C Chair: Assoc.Prof. Dr. P.B. KURT KARAKUŞ Chair: Assoc. Prof.Dr. G. Özmen GÜLER Chair: Prof.Dr. Abdurrahman AKTÜMSEK B. Alpaslan Kocamemi, N. Güre, F. Sarıalioğlu, C. Kuzey, P.B. Kurt Karakuş, E. Gungormus, E. Okten, H. Celik, T. T.E. Köse A.M. Saatçi Ugranlı, A. Sofuoglu, K. Gedik, S. Sofuoglu, H. Alegria, K.C. Jones PCBs in ambient air in İstanbul and İzmir-Turkey. Adsorption of dyestuff from wastewater using calcined Application of low intensity ultrasound to enhance waste eggshell. biological phosphorus removal. D. Jato Espino, E. Castillo Lopez, S.M. Charlesworth, J. D.İ. Çifçi, S. Terzi, S. Meriç Rodriguez Hernandez 09:15 - 09:30 09:30 - 09:45 09:45 - 10:00 10:00 - 10:15 10:15 - 10:30 Air quality modelling in Barcelona from the analysis of Comparative photocatalytic degradation, detoxification Do cultural climate, territorial and traffic variables. and demineralization of a biologically treated textile environment? effluent using TiO 2 and ZnO nanoparticles. 11:15 - 11:30 differences matter in education on H.M. Başar, S. Dağlı, P.Ö. Erdoğan, B. Güzel, L. Tolun P.B. Kurt Karakus, E. Gungormus, H. Çelik, E. Okten, T. T. Kotan, G. Bakan Ugranlı, A. Sofuoglu, K. Gedik, S. Sofuoglu, H. Alegria, K.C. Jones PBDEs in ambient air in İstanbul and İzmir-Turkey Recovery of acid and heavy metal in surface coating Beneficial use alternatives for dredged materials: Landfill industry by best available techniques. daily cover. E. Can Güven, D. Bolat, K. Gedik, P.B.Kurt Karakuş A preliminary investigation of legacy organochlorine pesticides in the atmosphere of an agricultural area in Antalya. E. Aghlara, G. Güllü Levels of bioaerosols in indoor environments in Ankara. E. Şık, E. Gengeç, M. Kobya, E. Demirbaş, M.S. Öncel Effect of anions on arsenic removal from groundwater by air injected electrocoagulation reactor using iron ball anodes. K. Qureshi, I. Bhatti, Z. Solangi Preparation of polyacrylonitrile ion exchange fibre (PANIEF) for the removal of arsenic. G.K. Akkaya, M.S. Bilgili A. Uslu, G. Bakan Applications of hybrid system in water and wastewater - Determination of system deficiencies with WDS models. Review. M.R. Kavianpour , A. Behzadipour Interaction of low-impact development techniques and urban river flooding on the zoning – Case study Qomroud. M.Y. Kılınç, E. Alkan Integrated river basin management. J. Tabatabaei Use of unconventional water with sustainability approach in Iran. Coffee Break 10:30 - 11:00 11:00 - 11:15 Diana N. Bebenova Nikolova Session 6 - A Session 6 - B Session 6 - C Chair: Dr. Sanaz LAKESTANİ Chair: Prof. Dr. Fehiman ÇİNER Chair: Prof. Dr. Nadezda STEVULOVA H. Sanli, M. Canakci, E. Alptekin, A. Turkcan, A. N. Ozsezen Comparison of exhaust emissions of a DI diesel engine fueled with methyl ester, ethyl ester, petro-diesel and their blends. K.O. Demirarslan, Ş.Ç. Doğruparmak The research of CO and NOx emissions revealed from linear sources in Kocaeli city korfez district by ISCST-3 and AERMOD model programs. E. Yavuz, F. Bildik, B.F. Şenkal G. Polat, E. Eray Preparation of the poly (styrene) based quaternary Supplier selection in the construction industry: Evidence chloroacetamide modified sorbent for removal of phenol. from Turkish contractors. F. Çiner, S. Şahin, S. Battal, E. Sezer, A. Dumlu B.N. Bingol, G. Polat Removal of maxilon red GRL from aqueous solutions using Key performance indicators (KPI) model for measuring Niğde (Bor) grape molasses soil as a low-cost adsorbent. performance of subcontractors. 11:30 - 11:45 11:45 -12:00 12:00 - 12:15 12:15 - 12:30 T.D. Pham, B.K. Lee, C.H. Lee F. Aydın Temel, Y. Ardalı, E. Avcı G. Gürsoy, A.E. Keleş Bioaerosol removal by simultaneous adsorption and photo- Removal of total nitrogen by juncus acutus and cortaderia 5S systematic practice steps on a corporate business. oxidation of Ag-doped TiO 2 /PU under visible irradiation. selloana from domestic wastewater in horizontal subsurface flow constructed wetland. F. Taşpınar, M. Atasoy, Z. Bozkurt, B. Poyraz, O. Uzun S. Ömeroğlu, F. Dilek Sanin N. Stevulova, I. Schwarzova, E. Terpakova, J. Junak Analysis and assessment of heavy metal pollution of road Bioelectricity generation from wastewater sludge using Impact of physical treatment of hemp hurds on the dust in Düzce, Turkey. microbial fuel cells. biocomposites properties. S. Lakestani, B. Karakaş, S. Acar Vaizoğlu, B. Güçiz M.İ. Birincioğlu, S. Ulusoy, G. Arslan Doğan, Ç. Güler, B. Şekerel, A. Taner, G. Güllü G. Tunc, Z. Khayyat Compration of indoor and outdoor VOCs levels at children homes. D. Yıldırım Pekşen, G. Bilen Alkan Economic and environmental contributions of declaration of the Marmara Region as emission control area (ECA). The structural analysis and design of buildings with shear wall and rigid basements. D. Bae, C.K. Oh, J.H. Park Seismic response of cylindrical liquid storage tanks according to the characteristics of structure. Lunch Break 12:30 - 14:00 14:00 - 14:15 14:15 - 14:30 14:30 - 14:45 Influence of steel fibers on the shear strength of RC beams without stirrups. J.A. Bogas, M.G. Gomes, S. Real The water absorption by capillarity in structural lightweight concrete. Session 7 - A Session 7 - B Session 7 - C Chair: Assist.Prof. Dr. Semra BENZER Chair: Assist.Prof. Dr. Z. Özlem PARLAK BİÇER Chair: Dr. Cise ÜNLÜER Y.S. Güçlü, E. Şişman, İ. Dabanlı, Z. Şen M. Suh, D.H. Ha, J.F. Choo C. Ünlüer Illustration of air quality change using innovative trend A study on concrete-FRP-steel composite honeycomb Development of novel cements with optimized carbon analysis method. structure for bridge deck. capture capabilities. P. Babaei, İ. Durukan, G. Güllü Z. Ö. Parlak Biçer, E. İlhan, D. Kırmızıgül, A. Akmeşe, E. A. Ünal, S.B. Yüksel Davutoğlu, A. Keskin, A. Can Koç, R. Gurbangeldiyev Heavy metal concentration of house dust. Determination of the importance of materials in structural Experimental behavior of the 1/3 scale reinforced shear cost via architectural project examples. wall with intensive boundary reinforcement. H. Gourgue, A. Aharoune, A.I. Ahmed A. Janushevskis, A. Melnikovs S.B. Yüksel, A. Ünal Dispersion of the NOx emissions from chimneys and road Shape optimization of sheeting cross section for roof Experimental behavior of the 1/3 scaled composite shear wall having L shape steel made-up sections as longitudinal traffic around industrial sites: Case study of the company subjected to different loading combination. reinforcement in boundary regions. Fantazia. 14:45 - 15:00 15:00 - 15:15 F. Ekmekyapar Torun, Z. Bingül, M.Y. Çodur A. Fettahoglu, S. Bekiroglu, İ. E. Bal M.M. Balkıs Analysis of SO 2 and PM concentrations with artificial Response spectral analysis of orthotropic steel deck as per Improvements in folding and tessellation as plate Turkish local design spectrums. structures. neural network: A case study of Erzurum city center. S. Dogru, T. Bayram, Y.A. Argun, A. Altikat F. Aras M. Davraz, Ş. Kılınçarslan Investigation of air pollution parameter variation on The Importance of the validation of numerical models with Investigation of relation of between compressive strength between 2007-2014: The case of Iğdır (Turkey). the experimental modal analysis. and ultrasonic pulse velocity in the foam concrete with different density. G. Güllü, Z. Gemizi, B. Keskin Çatal N. Doğan Sağlamtimur, A. Bilgil, H. Akbulut, M. Dursun, G. Çevikbilen, B. Teymur, U. Karadogan, H.M. Basar, S. S. Yıldırım Dağlı, L. Tolun 15:15 - 15:30 Level and sources of particulate matter (PM10, PM2.5) in Producibility of cement-based lightweight construction An investigation on suitability of dredge materials on road Turkey. material from coal bottom ash of the bor sugar factory construction. (Turkey). 15:30 - 16:00 Coffee Break 16:00 - 16:15 16:15 - 16:30 16:30 - 16:45 16:45 - 17:00 Session 8 - A Session 8 - B Session 8 - C Chair: Dr. Apoloniusz KODURA Chair: Prof. Dr. Mohamed ABDEL ATY Chair: Prof. Dr. Necati ÇATBAŞ A. Kodura J.M. Kim, J.Y. Lee, H.S. Lim, B.K. Jun, S.J. Hong Y.S. Güçlü Influence of characteristic of butterfly valve closing on Dynamic stiffness of resilient materials for reduction of Frequency analysis of low and high flows in climate water hammer run. floor impact sound. change. J. Zaczek Peplinska, K. Osińska Skotak, D. Wujanz, M.E. A.G. Göküş, H. Güleç, Z. Aslan, N. Akbulut-Çoban, K. S.A. Berilgen, G. Allamyradov Kowalska Gedik Evaluation of quiet area characteristics of an educational Stability analysis for a deep landslide in İstanbul: A case Potential of image processing methods based on intensity area: A case study of Akdeniz University campus, Antalya. study. values captured by TLS for surface condition assessment. H. Khorshidi , N.Talebbeydokhti, G.Rakhshandehroo U. Dağdeviren, B. Kaymak R. Çelik Uncertainty analysis of open channel flow: Stochastic Optimum design of reinforced concrete retaining walls Assessment of Diyarbakır basalt aquifer hydrogeological approach to advection – diffusion equation. using artificial bee colony algorithm. analyzed and obtains thematic maps with GIS geostatistical analyst tool. S.S.S. Al Maawali A. Durmuş, R. Livaoğlu E. Wojtas, M. Sawczak, T. Bergier, W. Drzewiecki Prediction of basic wind speed for Oman. Determination of horizontal bulk material pressures in The impact of the soil data quality on the effectivness of rigid cylindrical slender silos under seismic excitation hydrological modelling. Case study: Upper Raba catchment (Poland). using FEM and EN1998-4. 17:00 - 17:15 17:15 - 17:30 R. Molaey, A. Bayrakdar, R.Ö. Sürmeli, B. Calli U. Dağdeviren, M.A. Salman E. Wojtas, T. Bergier, W. Drzewiecki, M. Sawczak Effect of trace metal supplementation in anaerobic Vertical stress isobars for rectangular foundations under Remote sensing based impermeability coefficient estimation digestion of chicken manure. different loading conditions. and its influence on hydrological modelling efficiency. A. Altikat, S. Dogru, Y.A. Argun, T. Bayram New Chernobyl? Metsamor nuclear power plant. A. Badakhshan, F. Ahadi Koloo A.E. Özsoy, H.Özkaynak, M. Çağlar, M. Şentürk Improving seismic behavior of vierendeel and X-diagonal Educational experiments performed on a model structure STMFs by their configuration optimization made up of balsa wood. 17:30 - 17:45 S. Alashan, Z.F. Toprak, Z. Şen T. Çakır Advances of energy tree method in calculation of gross Dynamic analysis of a cantilever retaining wall including hydropower potential. soil structure interaction. 17:45 - 18:00 M. Yalçın, C. Turgut, P.B. Kurt Karakus The mixture toxicity of synergistic compounds combined with pesticides in Tuta absoluta. GALA DINNER 20:00 - 22:00 Saturday, 23 May 2015 Time 09:00 - 09:15 09:15 - 09:30 09:30 - 09:45 Session 9 - B Session 9 - C Chair: Prof. Dr. Aynur KAZAZ Chair: Assist.Prof. Dr. Ahmet AYGÜN Chair: Prof. Dr. Juraj KRALIK M.H. Zhang, Y. Wu G. Yıldırım Development of lightweight cement composites with low Comparative study for discharge coefficient prediction of thermal conductivity for energy efficient buildings. compound broad crested weir by two soft-computing techniques. D. Yılmaz, H. Bezci Zeren, C. Yılmaz, T. İnce G. Yıldırım Different climate conditions effect on thermal conductivity State-of-the-art review on explicit approximations to the coefficient and indoor environment. implicit colebrook-white friction factor equation. J. Králik, J. Králik, jr. Deterministic and probabilistic analysis of the fire resistance of the technology support structures in NPP. J. Králik Risk assessment of NPP safety in Slovakia. H. Köse, M. Bayazit, Y. Taşdemir O. Onat, P.B. Lourenço, A. Koçak S. Kahraman, A.S. Aloğlu Investigation of salt effect on stability of warm mix asphalt. Innovative test set up on shake table to assess out-of-plane Predicting the performance of roadheaders from the needle behavior of infill masonry walls. penetration resistance. Ç. Dinçkal 09:45 - 10:00 Session 9 - A B.K. Jun, S.J. Hong, J. Lee, J.M. Kim, H.S. Lim, J.Y. Lee Z. Karabash, A.F. Çabalar, H. Işık A study on anisotropy of composites and nanomaterials Structural behavior of RC and PSC concrete members with Stabilization of clayey soil by waste steel pieces. used in construction industry. high strength shear reinforcement. 10:00 - 10:15 M. Bayazit, Y. Taşdemir, E. Kolay, G. Küçük C. Karakurt, Y. Bayazıt, K. Kahveci The moisture damage characteristic of polymer and wax Effect of curing conditions on fiber concrete roads. modified asphalt mixtures. D.H.M. Aquino, J.Y. Hernandez, E.A.D. Robles Development