Chemical Stockroom Handbook

Transcription

Discover. Synthesize. Analyze. Customize.
Chemical Stockroom Handbook
Essentials & Storage Guidelines
Reliability.
Purity.
Certainty.
Introduction
The four proprietary brands of Fisher Scientific chemicals: Fisher Chemical, Fisher BioReagents, Acros Organics, and Maybridge cover the demands
of various applications. These products come in various packaging options, from convenient off-the-shelf products to high-volume solvent delivery
systems. When off-the-shelf products just won’t do, Specialized Chemical Services manufactures custom solutions to meet your unique needs.
As the stockroom manager, you are charged with the safe handling of hazardous chemicals every single day. Your responsibilities are
far-reaching … extending beyond the storeroom walls to lab personnel, building staff, campus residents and the environment. Fisher Scientific
offers this little-big-book of safety resources. Inside you’ll find storage recommendations, chemical compatibility charts, and recommended essential
products to stock to accommodate various research applications undertaken by your customers.
Table of Contents
Introduction................................................................................................. 2
What’s on our Chemical Label .................................................................. 13
Periodic Table of the Elements..................................................................... 2
FisherLOCKTM Solvent Caps ....................................................................14
Fisher Chemical Purity Chart....................................................................... 3
Fisher Chemical Products in the Safe-Cote Bottle ..................................... 15
Fisher Chemical Stockroom Essentials..................................................... 4-5
EcoSafPakTM Packaging ............................................................................ 16
Fisher BioReagents Purity Grades............................................................... 6
Chemical Storage/Handling Recommendations......................................... 17
Fisher BioReagents Stockroom Essentials................................................ 7-8
Incompatibilities by Hazard Class.............................................................. 17
Acros Organics Stockroom Essentials.................................................... 9-10
Chemical Incompatibilities........................................................................ 18
Specialized Chemical Solutions ................................................................ 11
Chemical Resistance and Physical Properties of Plastics........................... 19
Understanding GHS .................................................................................. 12
Chemical Resistance of Labware Materials ......................................... 20-21
Periodic Table of the Elements
key
Hydrogen
1
H
Numbers in brackets are mass
numbers of the most stable or
most common isotope. Atomic
weights conform to the Bulletin
of the International Union of Pure
and Applied Chemistry, volume 56,
number 6 1984. Scaled to Ar (c12) = 12
1s1
1.0079
2.1
3
Lithium
2
1s22s1
6.941
1.0
Sodium
3
[Ne]3s1
22.9898
0.9
Potassium
5
Boron
atomic symbol
filling of electrons:
1s1
1.0079
2.1
atomic weight
electronegativity
12
on s level on f level on d level on p level
Magnesium
14
6
Carbon
C
15
7
Nitrogen
20
21
3
Scandium
22
4
23
5
24
6
Titanium
Vanadium
Chromium
[Ar]3d34s2
50.9415
1.6
[Ar]3d54s1
51.996
1.6
25
7
Manganese
26
8
Iron
27
9
Cobalt
28
10
Nickel
29
11
Copper
30
12
Zinc
16
8
Oxygen
N O
9
17
Fluorine
He
1s2
4.0026
10
Neon
F Ne
1s22s22p1
10.811
2.0
1s22s22p2
12.0107
2.5
1s22s22p3
14.0067
3.0
1s22s22p4
15.9994
3.5
1s22s22p5
18.9984
4.0
1s22s22p6
20.179
13
14
15
16
17
18
Silicon
Phosphorus
Al Si P
[Ne]3s2
24.305
1.2
Calcium
B
Aluminium
[Ar]4s2
40.078
1.0
[Ar]3d14s2
44.9559
1.3
[Ar]3d24s2
47.867
1.5
[Ar]3d54s2
54.938
1.5
[Ar]3d64s2
55.8457
38
39
40
Zirconium
Niobium
Molybdenum
42
43
44
Ruthenium
Rhodium
Palladium
[Kr]5s1
85.4678
0.8
[Kr]5s2
87.62
1.0
[Kr]4d15s2
88.9059
1.3
[Kr]4d25s2
91.224
1.4
[Kr]4d45s1
92.9064
1.6
[Kr]4d55s1
95.94
1.8
[Kr]4d55s2
98.9062
1.9
[Kr]4d75s1
101.07
2.2
55
56
57
72
Strontium
Yttrium
Sulfur
Chlorine
Argon
S Cl Ar
[Ne]3s23p1
26.9815
1.5
[Ne]3s23p2
28.0855
1.8
[Ne]3s23p3
30.9738
2.1
[Ne]3s23p4
32.066
2.5
(Ne)3s23p5
35.453
3.0
(Ne)3s23p6
39.948
31
32
33
34
35
36
[Ar]3d104s24p3
74.9216
2.0
Gallium
Germanium
[Ar]3d104s24p1
69.723
1.6
[Ar]3d104s24p2
72.5961
1.8
Arsenic
Selenium
Bromine
Krypton
41
Technetium
1.8
[Ar]3d84s2
58.6934
1.8
[Ar]3d104s1
63.546
1.9
[Ar]3d104s2
65.39
1.6
[Ar]3d104s24p4
78.96
2.4
(Ar)3d104s24p5
79.904
2.8
(Ar)3d104s24p6
83.80
46
47
48
Cadmium
Indium
49
50
Tin
Antimony
51
52
53
54
[Kr]4d85s1
102.9055
2.2
[Kr]4d10
106.42
2.2
[Kr]4d105s1
107.868
1.9
[Kr]4d105s2
112.41
1.7
[Kr]4d105s25p1
114.82
1.7
[Kr]4d105s25p2
118.710
[Kr]4d105s25p3
121.760
1.9
[Kr]4d105s25p4
127.60
2.1
(Kr)4d105s25p5
126.9045
2.5
(Kr)4d105s25p6
131.29
[Ar]3d74s2
58.9332
1.8
45
Silver
Tellurium
Iodine
Xenon
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Barium
Lanthanum
73
Hafnium
Tantalum
Tungsten
74
75
76
77
78
79
Gold
Mercury
Thallium
Lead
82
83
84
85
86
[Xe]4f145d106s1
196.9665
2.4
[Xe]4f145d106s2
200.59 2.2
[Xe]4f145d106s26p1
204.383
1.8
[Xe]4f145d106s26p2
207.2
1.8
[Xe]4f145d106s26p3
208.9804
1.9
[Xe]4f145d106s26p4
(209)
2.0
(Xe)4f145d106s26p5
(210)
2.2
(Xe)4f145d106s26p6
(222)
112
113
Ununtrium
Flerovium
115
116
117
118
[Rn]5f146d107s2
(285)
[Rn]5f146d107s27p1
(286)
[Rn]5f146d107s27p2
(289)
[Rn]5f146d107s27p4
(293)
[Rn]5f146d107s27p5
(294)
[Rn]5f146d107s27p6
(294)
Rhenium
Osmium
Iridium
Platinum
80
81
1.8
Bismuth
Polonium
Astatine
Radon
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
[Xe]6s1
132.905
0.7
[Xe]6s2
137.33
0.9
[Xe]5d16s2
138.9055
1.1
[Xe]4f145d26s2
178.49
1.3
[Xe]4f145d46s2
180.9479
1.5
[Xe]4f145d46s2
183.85
1.7
[Xe]4f145d56s2
186.207
1.9
[Xe]4f145d66s2
190.2
2.2
[Xe]4f145d76s2
192.217
2.2
[Xe]4f145d96s1
195.08
2.2
87
88
89
104
105
106
107
108
109
110
[Rn]7s1
(223)
0.7
[Rn]7s2
226.0254
0.9
[Rn]6d17s2
(227)
1.1
[Rn]5f146d27s2
261.11
[Rn]5f146d37s2
262.11
[Rn]5f146d47s2
263.12
[Rn]5f146d57s2
262.12
[Rn]5f146d67s2
265
[Rn]5f146d77s2
266
[Rn]5f146d97s1
269
59
60
61
62
63
64
65
Rutherfordium
Dubnium
Seaborgium
Bohrium
Hassium
Meitnerium
Darmstadtium
111
Roentgenium
Copernicium
114
Ununpentium
Livermorium
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
Actinium
actinide
series
lanthanide
series
Radium
58
Cerium
Praseodymium
Neodymium
Promethium
Samarium
Europium
Gadolinium
Terbium
[Rn]5f146d107s1
(272)
66
Dysprosium
Holmium
67
68
69
Erbium
Thulium
[Rn]5f146d107s27p3
(289)
70
Ytterbium
71
Lutetium
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
[Xe]4f15d16s2
140.12
1.1
[Xe]4f36s2
140.9077
1.1
[Xe]4f46s2
144.24
1.20
[Xe]4f56s2
(147)
[Xe]4f66s2
150.36
1.2
[Xe]4f76s2
151.96
[Xe]4f75d16s2
157.25
1.1
[Xe]4f96s2
158.9254
1.2
[Xe]4f106s2
162.50 1.2
[Xe]4f116s2
164.9304
1.2
[Xe]4f126s2
167.26
1.2
[Xe]4f136s2
168.9342
1.2
[Xe]4f146s2
173.04
1.1
[Xe]4f145d16s2
174.967
1.2
90
91
92
93
94
95
96
97
98
99
100
101
102
103
Thorium
Protactinium
Uranium
Neptunium
Plutonium
Americium
Curium
Berkelium
Californium
Einsteinium
Fermium
Mendelevium
Nobelium
Lawrencium
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
[Rn]6d27s2
232.0381
1.3
2
H
[Ar]4s1
39.0983
0.8
Francium
7
13
37
Caesium
6
electronic structure
1s22s2
9.0122
1.5
atomic number
Hydrogen
18
2
Helium
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rubidium
5
Beryllium
1
Na Mg
19
4
4
Li Be
11
Smart Chemistry Solutions
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2
1
1
[Rn]5f26d17s2
231.0359
1.5
[Rn]5f36d17s2
238.0289
1.7
[Rn]5f46d17s2
237.0482 1.3
[Rn]5f67s2
(242)
1.3
[Rn]5f77s2
(243)
1.3
[Rn]5f76d17s2
(247)
[Rn]5f97s2
(247)
[Rn]5f107s2
(251)
[Rn]5f117s2
(252)
[Rn]5f127s2
(257)
[Rn]5f137s2
(258)
[Rn]5f147s2
(259)
[Rn]5f146d17s2
(260)
Ununseptium
Ununoctium
Fisher Chemical: Purity Grades for Every Application
Grade
Definition
Application
Certificate of Analysis
UHPLC-MS Optima™
Solvents specifically qualified for UHPLC-MS instrumentation. Signal to Noise specification
greater than ten when measured with 250 ppt Propazine using MS/MS; allowing the
solvents' quality to be linked directly to the sensitivity of the MS. Packaged in borosilicate
glass and tightened metal specifications minimizes metal ion adduct formation. UHPLC-MS
Gradient Suitability specification based on higher ionization efficiency to detect organic
contaminants in full scan MS with the absence of an additive. Meets stringent purity
requirements with 0.1 micron filtration to make particle free. Screened for UV-absorbing
contaminants at every wavelength in the 200 to 400 nm range which is ideal for dual
detection with an UV detector.
Meets stringent purity requirements of LC/ MS and UHPLC by addressing the need for
minimal organic contamination with 0.1 micron filtration to make particle free. Evaluated for
17 metal impurities at ppb concentrations for minimal metal mass adduct formation. High
ionization efficiency to detect organic contaminants at 50 ppb max (positive) and 300 ppb
max (negative) in full scan MS. Screened for UV-absorbing contaminants at every wavelength
in the 200 to 400 nm range to afford smooth baselines and to reduce interferences.
Ideal mobile phase for
UHPLC-MS applications
in pharmaceutical,
biotechnology, clinical,
environmental and food
safety industries.
Available on request
Ideal mobile phase for
LC/MS and UHPLCUV applications in
pharmaceutical,
biotechnology, clinical,
environmental and food
safety industries.
HPLC, GC, plasma/ICP,
spectrophotometry, and
pesticide residue analysis
Optima™ LC/MS
Optima™
HPLC
GC Resolv™
Pesticide
Environmental Grade
Certified ACS Plus
Certified ACS
Certified
Spectranalyzed™
Plasma Grade
TraceMetal
USP/NF/FCC/EP/
BP/JP
Histology
Biotechnology
Scintanalyzed™
Electronic
Laboratory,
Technical and
Reagent
Place your order today!
Acids and solvents of extremely high purity. Acids are analyzed for 65 metals by ICP/MS;
impurity levels in ppt. Solvent impurity levels in ppm. UV absorbance curves and sample
chromatograms available on request. For Optima acids, a typical lot analysis is given in the
catalog. Impurity levels in an actual lot received may vary from the amount listed.
Solvents manufactured specifically for use with HPLC instruments. Meet all ACS
specifications. Submicron filtered.
Solvents with the highest purity and lot-to-lot consistency. Free of contaminants to the ppb
level, including those listed in Contract Laboratory Program Target Compound List. Meet ACS
specifications. Chromatogram available on request.
Solvents for use in analysis of pesticide residue. Meet or exceed ACS standards of purity for
pesticide residue analysis.
HPLC and
spectrophotometry
procedures
Gas Chromatography (GC)
GC with electron capture
detector (ECD), pesticide
residue analysis
Solvents for use in HPLC analysis, trace-organic analysis, and environmental testing.
HPLC, trace-organic
Packaged in precleaned glass bottles in M3.5 (Class 100) cleanroom. Shipped with Certificate analysis, environmental
of Analysis.
testing.
Acids that, in addition to meeting or exceeding the latest specifications of the ACS, are
Analytical applications with Available on request
analyzed for more than
tighter metal specifications
16 metals. Actual lot analysis on label.
Reagent chemicals that meet or exceed the latest ACS Specifications. Actual lot analysis on
Analytical applications
label.
requiring tight
specifications
Reagent chemicals for which the purity standard is established by Fisher Scientific. Purity is
General analytical
guaranteed to meet published maximum limits of impurities.
procedures
Solvents for use in spectrophotometry. Also meet ACS specifications. Actual lot analysis on
Ultraviolet and visible
label.
wavelength detectors
(UV-Vis)
Solvents manufactured for use with plasma/ICP instruments. Impurity levels in ppt. Packaged Plasma/ICP, environmental Available on request
in acid-cleaned polyethylene bottles.
testing,
trace-metal analysis
Primarily used in digestion Available on request
Acids manufactured to achieve low metal contamination measurable in ppm to ppb range.
of samples prior to
Each lot is analyzed for more than 55 metals by ICP/MS. For TraceMetal acids, a typical
instrument (ICP) analysis
lot analysis is given in the catalog. Impurity levels in an actual lot received may vary from
amounts listed.
Reagent chemicals that meet or surpass specifications of the United States Pharmacopeia
Food and drug
20L or greater;
(USP), the National Formulary (NF), the Food Chemicals Codex (FCC), the European
laboratories, biological
10kg or greater
Pharmacopeia (EP), the British Pharmacopeia (BP), and/or the Japanese Pharmacopeia (JP).
testing
Solvents and products that are specially prepared for use in the histology laboratory setting.
Tissue processing, clinical Available on request
Solvents are filtered for tissue processing applications.
or histology procedures
Solvents and reagents that have been specially purified and assayed for biotechnology
Electrophoresis, molecular Available on request
applications.
biology, sequencing,
and peptide and
oligonucleotide synthesis
Solvents, fluors, and prepared cocktails for liquid scintillation counting. Includes
Liquid scintillation
nonflammable, nontoxic, biodegradable ScintiSafe™ cocktails.
counting
Solvents manufactured to ensure low levels of metal contamination. Meet Semiconductor
Electronics and circuit
Equipment and Materials Institute (SEMI) requirements. Actual lot analysis on label.
board manufacturing
Chemicals of reasonable purity for situations where no official standard for quality or impurity Manufacturing and
levels exist.
general laboratory use
Fisher Scientific US: 1-800-766-7000 | www.fishersci.com/chemicals
Fisher Scientific Canada: 1-800-234-7437 | www.fishersci.ca/chemicals
3
Fisher Chemical Stockroom Essentials
Delivering: Reliability. Purity. Certainty.
• All chemicals are manufactured in FDA licensed, ISO 9001:2008-certified facilities
• Rigorous quality assurance and testing procedures throughout the production process ensure the lot-to-lot consistency required for uniform analysis
• OptimaTM and HPLC-grade solvents are sealed with FisherLOCKTM Tamper Evident Caps, packaged in Safe-CoteTM bottles to prevent spills, and arrive in
EcoSafPakTM containers, a 100% recyclable shipper
• For the complete portfolio of Fisher Chemical products and promotions, please visit www.fishersci.com/fisherchemical
Optima UHPLC/MS Grade: Highest purity, ideal mobile phase for UHPLC/MS
Description
Pack
Size
Acetonitrile, Optima UHPLC/MS New!
1L
Methanol, Optima UHPLC/MS New!
1L
Water, Optima UHPLC/MS New!
1L
Fisher Scientific
Cat. No.
A9561
A4581
W81
EMD Millipore*
Equivalent
Sigma*
Equivalent
JT Baker*
Equivalent
Macron*
Equivalent
X
142611L
9853-01
X
X
142621L
9853-01
X
X
142631L
9853-01
X
Optima LCMS Grade: Ultra-high purity Ideal mobile phase for LC/MS and UHPLC/UV applications
Description
Pack
Size
Fisher Scientific
Cat. No.
EMD Millipore*
Equivalent
Sigma*
Equivalent
JT Baker*
Equivalent
Macron*
Equivalent
2-Propanol, Optima LC/MS with UHPLC/UV Spec.
4L
A4614
X
349652.5L
9827-03
X
Acetonitrile, Optima LC/MS with UHPLC/UV Spec.
4L
A9554
AX0156-1
349674L
9829-03
X
Methanol, Optima LC/MS with UHPLC/UV Spec.
4L
A4564
MX0486-1
349664L
9830-03
X
Water, Optima LC/MS with UHPLC/UV Spec.
4L
W64
WX0001-1
392531LR
9831-03
X
Fisher Scientific
Cat. No.
A4644
A9964
H3034
A4544
D1514
EMD Millipore*
Equivalent
Sigma*
Equivalent
JT Baker*
Equivalent
Macron*
Equivalent
PX18341
6504474L
909503
V55510
AX01421
349984L
901203
H45410
HX02961
6505524L
X
H48710
MX04881
6463774L
909303
H48810
DX08311
6504634L
931503
H48510
Fisher Scientific
Cat. No.
A9494
A9984
H3024
A4524
A452SK4
W54
EMD Millipore
Equivalent
Sigma
Equivalent
JT Baker
Equivalent
Macron
Equivalent
AX01151
2707254L
900203
243510
AX01451
348514L
901703
285610
HX02901
348594L
930903
X
MX04751
348604L
909303
304110
MX0475P1
348604L
909333
H08010
WX00081
2707334L
421803
X
Optima Grade: Ultra-high purity for more reliable analysis and cost savings
Description
Pack
Size
2-Propanol, Optima, also meets ACS specifications
4L
Acetonitrile, Optima, also meets ACS specifications
4L
Hexanes, Optima, also meets ACS specifications
4L
Methanol, Optima, also meets ACS specifications
4L
Methylene Chloride, Optima, also meets ACS specifications
4L
HPLC Grade Solvents
Description
Pack
Size
Acetone, HPLC, also meets ACS specifications
4L
Acetonitrile, HPLC, also meets ACS specifications
4L
Hexanes, HPLC, also meets ACS specifications
4L
Methanol, HPLC, also meets ACS specifications
4L
Methanol, HPLC, also meets ACS specifications
4L
Water, HPLC grade
4L
Histology Grade Solvents: The only products that offer the environmentally friendly F-Style poly bottle, which maximizes bench and shelf space
Description
Acetone, histological
Acetone, histological
Alcohol, Reagent, histological
Ethanol, Anhydrous, histological
Formaldehyde Solution, 10% w/w, Histological
Methanol, histological
Xylenes, histological
Pack
Size
4L
20L
4L
4L
20L
4L
1 gal.
Fisher Scientific
Cat. No.
A16P4
A16S20
A962P4
A405P4†
SF9620
A433P4
X3P1GAL
Products might not be available in all regions. Contact your local sales representative for details.
†
4
EMD Millipore
Equivalent
AX01254
AX01253
EX02811
X
X
MX04904
X
Sigma
Equivalent
5340644L
53406420L
6768294L
X
X
X
534056
JT Baker
Equivalent
X
X
A47809
X
X
907601
X
Macron
Equivalent
X
X
X
X
H12109
X
866816
Fisher Chemical Essentials (Contd.)
ACS Grade
Description
Pack
Size
Fisher Scientific
Cat. No.
EMD Millipore* Sigma*
Equivalent
Equivalent
JT Baker*
Equivalent
Macron*
Equivalent
2-Propanol, certified ACS plus
4L
PX18355
190764
908403
X
2-Propanol, certified ACS plus
500mL
PX18356
190764
908401
X
Acetic Acid, glacial, certified ACS
500mL
X
A6283
950802
V19314
Acetone, certified ACS
20L
AX01203
179124
900607
244310
4L
AX01208
179124
900603
244310
500mL
A4164
A416500
A38500
A1820
A184
A18500
AX01206
179124
900601
243704
Chloroform, approx. 0.75% ethanol as preservative, certified ACS
4L
C2984
CX10559
319988
918003
444008
Chloroform, approx. 0.75% ethanol as preservative, certified ACS
500mL
C298500
CX10556
319988
918001
444004
Ethyl acetate, certified ACS
4L
EX02405
319902
928003
499208
Ethyl acetate, certified ACS
20L
EX02403
319902
928007
499219
Ethyl acetate, HPLC, also meets ACS specifications
4L
EX02451
34858
928203
H07810
Ethyl ether, anhydrous, BHT stabilized, certified ACS
1L
EX01906
346136
924422
084810
Ethyl ether, anhydrous, BHT stabilized, certified ACS
4L
EX01903
346136
924405
084812
Hexanes, certified ACS
20L
HX02993
178918
930907
518922
Hexanes, certified ACS
4L
HX02995
178918
930903
518908
Hydrochloric acid, certified ACS plus
500mL
H060314
258148
953502
H61305
Hydrogen peroxide, 30%, certified ACS
100mL
HX06351
216763
218601
V34004
Hydrogen peroxide, 30%, certified ACS
500mL
HX06351
216763
218601
V34004
Methanol, certified ACS
4L
MX0485P4
179337
907033
H48810
4L
MX04853
179337
907005
H48810
1L
MX04858
179337
907001
H48806
4L
MX04857
179337
907003
H48810
500mL
MX04856
179337
907001
H48806
Methylene chloride, stabilized, certified ACS
4L
DX083513
676583
932403
488108
Methylene chloride, stabilized, certified ACS
20L
E1454
E14520
E1954
E1381
E1384
H29220
H2924
A144500
H325100†
H325500
A412SK4
A412P4
A4121
A4124
A412500
D374
D3720
DX08355
d65100
932407
488119
Methylene chloride, stabilized, HPLC, also meets ACS specifications
4L
D1434
DX08381
34856
931503
487910
Sodium chloride, crystalline, certified ACS
3kg
59888
362405
758106
500g
SX04201
59888
362401
758112
Sodium hydroxide, pellets, certified ACS
500g
S2713
S271500
S318500
SX04203
Sodium chloride, crystalline, certified ACS
SX05901
221465
372228
770810
EMD Millipore
Equivalent
Sigma
Equivalent
JT Baker
Equivalent
Macron
Equivalent
BX16321
223565
565601
X
BX16411
223573
565501
X
BX16281
223557
565701
X
Certified
Description
Pack
Size
Buffer solution, pH 7.00, color-coded yellow, certified
500mL
Buffer solution, pH 10.00, color-coded blue, certified
500mL
Buffer solution, pH 4.00, color-coded red, certified
500mL
Fisher Scientific
Cat. No.
SB107500
SB115500
SB101500
Description
Pack
Size
Fisher Scientific
Cat. No.
EMD Millipore
Equivalent
Sigma
Equivalent
JT Baker
Equivalent
Macron
Equivalent
Buffer Solution, Total Ionic Strength Adjustment Buffer (TISAB II)
20L
SB17520
X
89466-500ML
X
X
SI864
A4114
SP3394
SP24220
X
318981-500ML
X
X
X
X
X
X
X
319228-2L
X
X
X
X
X
X
Laboratory Grade
Iodine (Iodine-Iodide) Solution, 0.1 N
4L
Methanol, laboratory
4L
Perchloric Acid Solution, 0.1 N
4L
Potassium Iodide Solution 10% w/v
20L
†
5
Fisher BioReagents: Purity Grades for Every Application
Material Grade
Definition
Analytical Grade
Designates reagents suitable for use in analytical procedures.
Certified
Reagent chemicals for which the purity standard is established by Fisher Chemical*. Purity is guaranteed to
meet published maximum limits of impurities.
Certified ACS
Reagent chemicals that meet or exceed the latest ACS specifications.
Certified ACS Plus
Acids which meet or exceed the latest ACS specifications, and analyzed for more than 16 metals.
DNA Grade
Designates reagents suitable for use in Molecular Biology applications involving the manipulation of DNA.
Tested for specific contaminants such as DNase and protease.
DNA Synthesis
Designates reagents suitable for use with automated DNA synthesis instrumentation.
Electrophoresis
Material used specifically for electrophoresis applications.
Genetic Analysis Grade
Material that is specially prepared for various molecular cloning applications. Tested for specific
contaminants such as DNase and RNase.
Solvents manufactured specifically for use with HPLC instruments. Meet all ACS specifications. Submicron
filtered.
HPLC
IEF Grade
Material suitable for use with isoelectric focusing of proteins.
Islet Isolation Grade
Material suitable for isolation of pancreatic islets.
Molecular Biology Grade
Designates reagents suitable for use in Molecular Biology applications. Tested for specific contaminants such
as nucleases and bacteria where appropriate.
Molecular Genetics
Reagent chemicals that have been specifically purified and assayed for Molecular Genetics applications.
PCR Grade
Material suitable for use in Polymerase Chain Reaction (PCR).
Peptide Synthesis
Designates reagents suitable for use with protein synthesis instrumentation.
Protein Electrophoresis Grade
Material used specifically for protein electrophoresis applications.
Sequencing
Material designed for use with automated DNA or protein sequencing equipment.
Super Pure
Material with a purity level exceeding the various monograph grades.
Tissue Culture Grade
Materials of superior quality where there are no published standards, and that are suitable for use in Tissue
Culture applications.
Fisher BioReagents Stockroom Essentials
Vital Reagents for Life Science
• High-purity products that meet stringent industry specifications and application requirements
• Pre-qualified for dedicated applications; eliminate the need for redundant testing
• Designed for a wide range of molecular biology, protein chemistry, cell biology
and microbiology applications
For more product choices and promotions, please visit www.fishersci.com/fisherbioreagents
Immunodetection
6
Description
Pack
Storage
Condition
Fisher Scientific
Cat. No.
Sigma
Equivalent
Bio-Rad
Equivalent
Bovine serum albumin, fraction V, cold-ethanol precipitated
100g
RT
BP1605100
A4503-100G
X
Fisher BioReagents Essentials (Contd.)
Core Bioreagents
Description
Pack
Storage
Condition
Fisher Scientific
Cat. No.
Sigma*
Equivalent
Bio-Rad*
Equivalent
Bovine serum albumin, fraction V, heat shock
treated, suitable for immunological studies
100g
RT
BP1600100
A3294-100G
X
Dimethyl sulfoxide
100mL
RT
X
4L
RT
BP231100
BP28184†
34869-100ML
Ethanol, Molecular Biology Grade
E7023-4x4L
X
Ethylenediamine tetraacetic acid, disodium salt
dihydrate, crystalline powder, electrophoresis
500g
RT
BP120500
E5134-500G
X
Formamide, molecular biology
500mL
4ºC
BP227500
47671-250ML-F
X
Formamide, super pure
100mL
4ºC
BP228100
F9037-100ML
X
Glycerol, molecular biology
1L
RT
BP2291
G7893-1L
X
Glycerol, molecular biology
4L
RT
BP2294
G7893-4L
X
Isopropanol, Molecular Biology Grade
500mL
RT
BP2618500
I9516-500ML
X
JustPURE Ethylenediaminetetraacetic Acid Disodium Salt Dihydrate
100g
RT
BP2927100
E1644-100G
X
Methanol, peroxide-free, sequencing
4L
RT
BP11054
494437-2L
X
70% Molecular Biology Ethanol solution New!
1L
RT
BP82011
X
X
4L
RT
BP82014
X
X
1L
RT
BP82021
E7148-500ML
X
4L
RT
BP82024
E7148-1GA
X
PBS Tablets
100g
RT
BP2944100
P4417-100TAB
X
Phosphate buffered saline, 10X powder concentrate, white granular powder
2 x 1L
RT
BP6651
P3813-1PAK
31098
Phosphate buffered saline, 10X solution
1L
RT
BP3991
79378-1L
161-0780
Phosphate buffered saline, 10X solution
500mL
RT
BP399500
79378-1L
161-0780
Sodium chloride (dry basis), >99.5%
1kg
RT
BP3581
31434-1KG-R
X
Sodium chloride (dry basis), >99.5%
2.5kg
RT
BP358212
31434-1KG-R
X
Sodium dodecyl sulfate, white powder, electrophoresis
500g
RT
BP166500
L4509-500G
161-0302
Tris base, white crystals or crystalline powder, molecular biology
1kg
RT
BP1521
93362-1KG
161-0719
5kg
RT
BP1525
93362-1KG
161-0719
500g
RT
BP152500
93362-250G
161-0716
Tris buffered saline, 10X Solution, pH 7.4, molecular biology
1L
RT
BP24711
T5912-1L
170-6435
Tween 20
100mL
RT
BP337100
P2287-100ML
170-6531
Tween 20
500mL
RT
BP337500
P2287-500ML
170-6531
Water, Molecular Biology Grade
1L
RT
BP28191
W4502-1L
X
Water, DNA grade
1L
RT
BP24701
W4502-1L
163-2091
Water, for RNA work, DEPC-treated and nuclease-free, molecular biology
1L
RT
BP5611
95289-1L
700-7253
Water, nuclease free
100mL
RT
BP2484100
95284-100ML
700-7253
Water, nuclease free
50mL
RT
BP248450
95284-100ML
700-7253
†
7
Fisher BioReagents (Contd.)
Protein and Nucleic Acid Electrophoresis
Description
Pack
Storage
Condition
Fisher Scientific
Cat. No.
Sigma*
Equivalent
Bio-Rad*
Equivalent
Agarose, broad separation range for DNA/RNA, genetic analysis grade
Agarose, low-EEO/multi-purpose, molecular biology grade
Agarose, low-EEO/multi-purpose, molecular biology grade
Ethidium bromide, 1% solution, molecular biology
MES, fine white crystals
Methanol, peroxide-free, sequencing
Phenol, saturated, liquid, pH 6.6/7.9
Sodium Dodecyl Sulfate (SDS), Micropellets New!
TEMED, Electrophoresis
Tris–Borate–EDTA, 10X solution, electrophoresis
100g
100g
500g
10mL
100g
4L
400mL
100g
500g
5kg
20g
1L
RT
RT
RT
RT
RT
RT
4ºC
RT
RT
RT
RT
RT
BP1356100
BP160100
BP160500
BP130210
BP300100
BP11054
BP1750I400
BP8200100
BP8200500
BP82005
BP15020
BP13331
A9539-100G
A6013-100G
A6013-500G
E1510-10ML
M3671-50G
494437-2L
P4557-400ML
74255-250G
74255-250G
74255-250G
T9281-25ML
93290-1L
161-3101
161-3101
161-3102
161-0433
X
X
X
X
X
X
X
161-0733
Description
Pack
Storage
Condition
Fisher Scientific
Cat. No.
Sigma
Equivalent
Bio-Rad
Equivalent
2XTY Broth (Granulated) New!
Agar
Agar, Granulated New!
Ampicillin Sodium Salt, crystalline powder
CellPURE* PBS 10X, Cell Culture Grade
D-Sucrose, molecular biology
Glycine, white crystals or crystalline powder
Isopropyl-8-D-thiogalactopyranoside, dioxane-free
Kanamycin Sulfate, white powder
LB Agar, Miller
LB Agar, Miller
LB Agar, Miller
LB Broth, Miller
LB Broth, Miller
LB Broth, Miller
LB Broth, Lennox
LB Broth, Lennox, (Powder)
LB Agar, (Lennox L Agar), Granulated New!
LB Agar, (Lennox L Agar), Granulated New!
LB Broth, Miller, (Powder)
LB Broth, Miller, (Powder)
Phosphate Buffered Saline, 10X solution
Puromycin Dihydrochloride
Rapamycin
SOB Broth (Capsules)
Tryptone
Tryptone (Granulated)
Tryptone (Granulated)
Vancomycin
Water, Microbial Cell Culture Grade
Yeast Extract
Yeast Extract (Granulated)
Yeast Extract (Granulated)
500 g
2kg
5kg
500g
500g
2kg
5kg
25g
4L
1kg
1kg
5kg
500g
1g
5g
500g
2kg
500g
2kg
500g
5kg
500g
500g
500g
2Kkg
500g
2kg
4L
100mg
1mg
500g
500g
2kg
500g
1g
500mL
500g
2kg
500g
RT
RT
RT
RT
RT
RT
RT
4ºC
RT
RT
RT
RT
RT
4ºC
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
BP9743500
BP97432
BP97435
BP1423500
BP9744500
BP97442
BP97445
BP176025
BP29404
BP2201
BP3811
BP3815
BP381500
BP17551
BP9065
BP9724500
BP97242
BP1425500
BP97232
BP9723500
BP97235
BP9722500
BP1427500
BP9745500
BP97452
BP1426500
BP14262
BP3994
BP2956100
BP29631
BP9737500
BP1421500
BP97262
BP9726500
BP29581
BP2820500
BP1422500
BP97272
BP9727500 †
Y2627-1KG
Y2627-1KG
Y2627-1KG
A1296-500G
05040-1KG
05040-1KG
05040-1KG
A0166-5G
P5493-4L
S0389-1KG
G8898-500G
G8898-500G
G8898-500G
I6758-1G
K1377-5G
L3147-1KG
L3027-1KG
L3027-1KG
L3522-1KG
L3522-1KG
L3522-1KG
L7658-1KG
L3022-1KG
L7533-1KG
L7533-1KG
L3522-1KG
L3522-1KG
79378-1L
P7255-100MG
R0395-1MG
H8032-500G
T7293-1KG
T2559-1KG
T2559-1KG
V1130-1G
W3500-500ML
Y1625-1KG
Y1626-1KG
Y1626-1KG
X
X
X
X
X
X
X
166-0407EDU
X
X
161-0718
161-0724
161-0718
X
X
X
X
X
X
X
X
X
X
X
X
X
X
161-0780
X
X
X
X
X
X
X
X
X
X
X
Cell and Tissue Culture
†
8
Acros Organics Stockroom Essentials
Off-the-Shelf Products Backed by Expertise in Sourcing,
Manufacturing and Technology
A leading supplier of fine chemicals, Acros Organics continues to expand its
range of products and services to meet today’s requirements for organic,
medicinal, analytical and biological chemistry.
AcroSealTM Dry Solvents and Organometallic Compounds feature:
• Next-generation, triple-sandwich septum, which reseals even the most
aggressive solvent/reagent and enables multiple puncture points
• Quadrant-style cap for a tight seal between septum and bottle
For a full listing of products, please visit www.fishersci.com/acrosorganics.
AcroSeal
Solvent
Purity
Quantity
Packaging
Fisher Scientific
Cat. No.
Sigma*
Equivalent
Acetonitrile, anhydrous
99.9%, Extra Dry
1L
Amber Glass
AC610220010
271004
Acetonitrile, anhydrous
99.9%, Extra Dry
100mL
Amber Glass, Safe-Cote*
AC610961000
271004
Chloroform, anhydrous
Extra Dry
100mL
Amber Glass
AC610281000
372978
Dichloromethane, anhydrous
Extra Dry
1L
Amber Glass
AC610300010†
270997
Dichloromethane, anhydrous
Extra Dry
100mL
Amber Glass, Safe-Cote
AC610931000
270997
Methanol, anhydrous
99.8%, Extra Dry
1L
Amber Glass
AC610400010†
322415
Methanol, anhydrous
99.8%, Extra Dry
100mL
AC610981000
322415
Methyl Sulfoxide, anhydrous
99.7%, Extra Dry
1L
Amber Glass
AC610420010
276855
Methyl Sulfoxide, anhydrous
99.7%, Extra Dry
100mL
AC610971000
276855
N,N-Dimethylformamide, anhydrous
99.8%, Extra Dry
1L
Amber Glass
AC610320010
227056
N,N-Dimethylformamide, anhydrous
99.8%, Extra Dry
100mL
AC610941000
227056
Tetrahydrofuran, anhydrous
99.9%, Extra Dry
1L
Amber Glass
AC610450010
401757
Tetrahydrofuran, anhydrous
99.9%, Extra Dry
100mL
AC610921000
401757
Tetrahydrofuran, stabilized, anhydrous
99.9%, Extra Dry
1L
Amber Glass
AC610900010
186562
Tetrahydrofuran, stabilized, anhydrous
99.9%, Extra Dry
100mL
AC610911000†
186562
Toluene, anhydrous
99.8%, Extra Dry
1L
Amber Glass
AC610460010
244511
Toluene, anhydrous
99.8%, Extra Dry
100mL
AC610951000
244511
Solvent
Purity
Quantity
Packaging
Fisher Scientific
Cat. No.
Sigma
Equivalent
Chloroform-d, 99.6+ atom % D
For NMR
100mL
Amber Glass
AC174881000
151823
Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS
For NMR
100mL
Amber Glass
AC209561000
225789
Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS
For NMR
100mL
Amber Glass
AC166261000
151831
Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS
For NMR
50mL
Amber Glass
AC166260500
151831
Chloroform-d, 99.8 atom % D
For NMR
100mL
Amber Glass
AC166251000
151823
Chloroform-d, 99.8 atom % D
For NMR
50mL
Amber Glass
AC166250500
151823
Deuterium Oxide, 99.8 atom % D
For NMR
100mL
Amber Glass
AC166301000
617385
Methanol-d4, packaged in 0.75mL ampules, 99.8 atom % D
For NMR
10 x 0.75mL
.75 Ampules
AC320750075
441384
Methyl sulfoxide-d6, 99.5+ atom % D
For NMR
10g
Amber Glass
AC321290100
175943
Methyl Sulfoxide-d6, 99.9+ atom % D
For NMR
10 x 0.75mL
.75 Ampules
AC320770075
151874
Deuterated Solvents
†
9
Acros Organics Essentials (Contd.)
Ethanol
Solvent
Quantity
Packaging
Fisher Scientific
Cat. No.
Sigma*
Equivalent
Ethanol, absolute, 200 proof, ACS reagent
4L
Amber Glass
Ethanol, 190 proof, for spectroscopy ACS
4L
Amber Glass
Ethanol, 190 proof, for spectroscopy ACS
1L
Amber Glass
500mL
Amber Glass
1L
Amber Glass
2L
Amber Glass
Ethanol, anhydrous, 200 proof
100mL
Amber Glass
Ethanol, anhydrous, 200 proof
2L
Amber Glass
Ethanol, denatured, for HPLC
4L
Amber Glass
AC615090040†
AC615110040†
AC615110010†
AC615095000†
AC615090010†
AC615090020†
AC615101000†
AC615100020†
AC611050040
X
X
X
X
X
X
459836
459836
X
Solvent
Quantity
Packaging
Fisher Scientific
Cat. No.
Sigma
Equivalent
Boron Trichloride, stab., 1M sol. in methylene chloride
100mL
Amber Glass, AcroSeal*
Diisobutylaluminium Hydride, 1M solution in hexane
100mL
Amber Glass, AcroSeal
Diisobutylaluminium Hydride, 20% wt. solution in toluene, 1.2M
100mL
Lithium aluminium Hydride, 1M solution in THF
100mL
Lithium Diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene
100mL
Methyllithium, 1.6M solution in diethyl ether (± 5% w/v)
100mL
n-Butyllithium, 1.6M solution in hexanes
100mL
800mL
100mL
800mL
sec-Butyllithium, 1.3M solution in cyclohexane/hexane (92/8)
100mL
tert-Butyllithium, 1.6M solution in pentane
100mL
AC176681000
AC183791000
AC201081000
AC199491000
AC268831000
AC188751000
AC181271000
AC181278000
AC213351000
AC213358000
AC187541000
AC181281000†
178934
190306
192724
212776
361798
197343
186171
186171
230707
230707
195596
186198
Organometallic and Reactive
†
FisherbrandTM Products Offer Excellent Quality and Value for Your Lab!
When making buying decisions, look for Fisherbrand products for quality, reliability and value. With a portfolio of over 10,000 products in 126 product categories
and more than 100 years of experience in serving the scientific community, you can trust Fisher Scientific to have the products you need, when you need them.
Fisherbrand Premium and Recycled Delicate
Task Wipers
The Fisherbrand Delicate Task Wipers are a piece of tissue made with 100%
virgin fiber used to ‘clean without damaging’ delicate surfaces, parts and
equipment. This three-tier product offering includes: Fisherbrand Premium
Plus, Fisherbrand Premium and Fisherbrand Recycled Delicate Task Wipers.
Top-selling Fisherbrand Wipers Cat. Nos.:
• 07-301-003
• 07-301-004
• 07-301-005
Fisherbrand Glassware
The Fisherbrand Reusable Glassware portfolio includes beakers, graduated
cylinders, volumetric flasks, Erlenmeyer flasks, boiling flasks, filter flasks,
funnels, media bottles and test tubes! All products meet ASTM* specifications
and come in a variety of
sizes to support daily use in every laboratory.
Several top-selling Fisherbrand
Glassware Cat. Nos. including:
• FB100-250 (Beaker)
• FB201-250 (Round bottom flask)
Also available from Fisherbrand:
• Balances, Hotplates, Pipets, Scoops, Spatulas, Vials, Weigh dishes and
more!
• Visit www.fishersci.com/fisherbrand for a complete listing of our
Fisherbrand product offering
10
Fisher Chemical Specialized Chemical Services
From Discovery to Production
Whether you are engaged in initial research or scaling up to full production, save time and resources through our Custom
Services and Solutions:
1. Semi-bulk and Bulk Chemical Service: Through our extensive supply-chain
2. Multicompendial, Enhanced Traceability and Documentation: Offering the
network, we can secure and manage the supply of semi-bulk and bulk volume
proper paperwork that verifies the product, re-packaging and distributing sites, and
products using either internal manufacturing or select partners worldwide
regulatory information needed
 High Volume Solvent Delivery Systems
• FisherPak: Environmentally friendly, reusable Fisher Chemical 316 stainlesssteel container is pressurized with an inert gas to deliver the solvent, so the
system remains closed and the solvent remains pure for virtually unlimited
applications, thus enhancing safety and improving productivity within your lab
when handling large quantities of solvent
• BasicPak: This Fisher Chemical returnable, reusable drum is made from
high-grade 304 stainless steel. This system is designed to deliver inert gas
safely to the drum with 7-15psig without contamination.
• DelPak: DelPak combines the strength and durability of steel with the
chemical compatibility of polyethylene.
• NowPak I: The inner liner is constructed with an inert fluorocarbon polymer
that is compatible with all high purity solvents. The inner liner collapses around
the dip tube during dispensing, which prevents air from entering the system.
• NowPak II: The NowPak II precleaned liner technology is offered in a
pressurizable, stainless-steel overpack. The system permits ultra-clean
chemical dispensing without direct contact of the chemical with the drive gas.
3. Special Testing: Our extensive in-house laboratory, QC capabilities and utilization
of accredited external partners allows us to respond quickly to specific quality
control testing at your request
4. Custom Batch Size Packaging and Labeling: Our products are available in a
wide variety of innovative packaging options designed for safety, environmental
protection, convenient handling and storage and preservation of product integrity,
while complying with all relevant regulations
5. Tailored Solvents and Solvent Blends: Our experience in manufacturing,
processing and testing high-purity solvents enables customization of solvents to
your specifications
6. Special Solutions: Special aqueous or non-aqueous solutions can be expertly
manufactured to your exact requirements
7. GMP Products: Through FDA-registered facilities change control and notification
on non-regulated and regulated products
Drive gas pressure is applied to the outside of the liner, minimizing gas
entrainment or micro-bubble formation.
11
What is GHS?
GHS = Globally Harmonised System of Classification and Labelling
• Created by the UN, the purpose is to “harmonize” the world’s chemical classifications and
the way we communicate that information to workers across the globe. OSHA has revised
its Hazard Communication Standard (HCS) to align with it and they
are shown below in each square.
What is new?
GHS Pictograms on the label - black on white symbol inside
a red diamond – represents a different type of hazard.
GHS02 Flame = Flammable, chemicals can
catch fire easily and burst into flames
GHS03 Flame over circle = Oxidizing, can
react with other materials causing them to
burn or explode
GHS04 Gas cylinder = Gas under pressure : GHS05 Corrosion = Corrosive: may cause
chemical can explode, rocket or harm health skin corrosion/ burns; eye damage; eat away
if the cylinder is heated, ruptured or leaking. clothing, working surfaces, and or metals.
GHS06 Skull and crossbones = Toxic : highly
poisonous material; can cause immediate and
possibly serious health problems.
GHS01 Exploding bombs = Explosive,
self reactive; heating may cause
fire or explosion
GHS07 Exclamation mark = Other Hazard irritant (skin and eye), skin
sensitizer, acute toxicity, narcotic effects, respiratory track
irritant, harmful if swallowed, toxic if inhaled.
GHS08 Health hazard = Specific health hazard including–
Carcinogenic; Mutagenic; Toxic for Reproduction : may cause
asthma or damage to specific organs of the body
GHS affects all of us, and Fisher Scientific has you covered. Training programs and materials, resources
and products that comply with the new requirements are conveniently accessible right here!
For more information, go to: www.fishersci.com/ghs
12
What’s On the Label? Safety Guidelines!
7
15
4
10
11
12
1
5
9
3
8
2
Fair Lawn, New Jersey 07410
Tel. (201) 796-7100 Fax. (201) 796-7102
www.fishersci.com
14
6
13
1
The bar code is an alphanumeric code widely used by industry for inventory and
tracking control. This “three-of-nine” code meets the Health Industry Bar Code
(HIBC) Supplier Labeling Standard as prepared by the Health Industry Business
Communication Council (HIBCC).
2
This area contains the appropriate precautionary signal word, i.e., DANGER,
WARNING, and highlights the potential health hazards, both acute and chronic,
of the product.
3
QR Codes on Label: SDS (formally called the material safety data sheet) provides
procedures for handling that substance and lot specific Certificate of Analysis which
proves the lot of substance adheres to the standards of the product specifications.
Scan Label by using Smartphone and get instant access to this information.
For the complete list of products that offer a QR on our label, please visit:
www.fishersci.com/QR
4
5
6
The Maximum Limits of Impurities are indicated.
7
GHS Pictogram - black on white symbol inside a red border – represents a different
type of hazard.
The full Product Name and Purity Grade are listed.
8
The U.S. Dept. of Transportation (DOT) shipping information includes the UN/ NA
Number identifies the United Nations/ North America numerical designation for
transportation hazards and the DOT proper Shipping Name.
9
In this area product composition is listed along with the product Chemical Abstract
Service (CAS) Registry Number.
10
Package Size: The amount of material per unit.
11
The catalog number is shown for identification and reference.
12
Lot Number
13
14
15
The address and telephone number of the manufacturer is listed.
Name and logo of the brand.
Chemical formula.
ChemAlert Guide: Which matches rim color of Fisherlock.
The five storage colors and their descriptions are listed below.
NOTE: ChemAlert is an instant reference only. It should be supplemented by reading the rest of the label (which provides detailed instructions in the event of accidental exposure,
spill or fire, and applicable OSHA, DOT, GHS, ANSI* data), the appropriate SDS, Cofa,and standard references.
ChemAlert storage codes provide guidelines will match the bottom rim of out Fisherlock cap
R
B
Red: Flammable. Store in area segregated for flammable reagents.
Y
Yellow: Reactive and oxidizing reagents. May react violently with air,
water or other substances. Store away from flammable and
combustible materials.
Blue: Health hazard. Toxic if inhaled, ingested or absorbed through
skin. Store in secure area.
White: Corrosive. May harm skin, eyes, mucous membrane. Store
W away
from red-, yellow- and blue-coded reagents.
Presents no more than moderate hazard in any of the
G Gray:
categories above. For general chemical storage.
EXCEPTION: Reagent incompatible with other reagents of the same color.
Store separately.
13
Fisher Chemical Solvent FisherLOCKTM Closure
Lock in Quality and Safety
FisherLOCK caps place a patented tamper-evident secure seal applied during
manufacturing to our amber glass bottles that holds the bottle’s lips and preserves
integrity of the chemical
• Easy release: Outer shell of the cap is designed to make it effortless to open
and readily reseal
• Tamper-evident, interior ring of the cap is visible from various angles, offers
resistance until it separates from the cap when the bottle is initially opened,
ensuring integrity —without the drawbacks and complications of a plastic
seal over the cap.
• Color-coded bands at the bottom of the cap, that match the bottom right of a
Fisher Chemical label, are for easy hazard identification based on well known
industry standard color coding guidelines that are shown below for proper storage
and handling.
Through packaging enhancements, Fisher Chemical -FisherLOCK is easy to use, and
supports: product, quality, reliability of use, and safety for the chemical products you
purchase.
To learn more visit: www.fishersci.com/fisherchemical
Exclusive color-coded design provides storage guidelines
Red (R): Flammable. Store in area segregated for flammable
reagents.
Blue (B): Health hazard. Toxic if inhaled, ingested or
absorbed through skin. Store in secure area.
Yellow (Y): Reactive and oxidizing reagents. May react violently
with air, water or other substances. Store
away from flammable and combustible materials.
White (W): Corrosive. May harm skin, eyes, mucous
membrane. Store away from red-, yellow- and
blue-coded reagents.
Gray (G): Presents no more than moderate hazard
in any of the categories above. For general chemical storage.
EXCEPTION: Reagent incompatible with other reagents of the same color bar.
Store separately.
The FisherLOCK Cap LOCKS in quality, safety, reliability and convenience:
QUALITY
RELIABILITY
• Provides a tight, tamper-evident, secure seal to ensure chemical
contents arrive fresh and unopened
• Rigorously tested for chemical compatibility
• Eliminates polyethylene glycol contamination that is possible with
a plastic overseal
SAFETY
• Caps are designed to resist back-off during transport, reducing risk
of leakage
• Color-coded rings indicate storage requirements and hazard
categories, and enhance proper recognition, handling and storage — even
before the bottle is removed from the case
14
• Bottle threads are unchanged, allowing attachment of the opened bottle to
standard equipment
CONVENIENCE
• Cap design facilitates correct initial torque application during
manufacturing, thus eliminating caps that may be hard to open
• Larger ridges on the exterior of the cap make it easier to open
• Caps readily reseal after initial opening
Fisher Chemical Safe-Cote Solvents – Safely Serving Science
Description
Purity Grade
Size
Cat. No.
Description
Purity Grade
Size
Cat. No.
1-BUTANOL
HPLC/ACS
1L
A383SK-1
METHCHLORIDE
HPLC
1L
D150SK-1
HPLC
4L
D150SK-4
1-BUTANOL
HPLC/ACS
4L
A383SK-4
METHCHLORIDE
2-PROPANOL
Certified ACS Plus
4L
A416SK-4
METHYLENE CHLORIDE
HPLC/ACS
1L
D143SK-1
2-PROPANOL
HPLC/ACS
1L
A451SK-1
METHYLENE CHLORIDE
Certified ACS
4L
D37SK-4
2-PROPANOL
HPLC/ACS
4L
A451SK-4
METHYLENE CHLORIDE
HPLC/ACS
4L
D143SK-4
2-PROPANOL
OPTIMA
4L
A464SK-4
METHYLENE CHLORIDE
OPTIMA
4L
D151SK-4
HPLC/ACS
4L
D138SK-4
ACETONE
Certified ACS
4L
A18SK-4
METHYLENE CHLORIDEW/CYCLOHEXENE
ACETONE
HPLC
1L
A949SK-1
N-BUTYL CHLORIDE
HPLC
4L
B429SK-4
OPTIMA/ACS
4L
H306SK-4
ACETONE
HPLC/ACS
4L
A949SK-4
N-HEXANE95% L
ACETONE
OPTIMA/ACS
4L
A929SK-4
PENTANE
HPLC
1L
P399SK-1
ACETONITRILE
HPLC/ACS
1L
A998SK-1
PENTANE
HPLC
4L
P399SK-4
ACETONITRILE
HPLC/ACS
4L
A998SK-4
PETROLEUM ETHER
Certified ACS
4L
E139SK-4
ACETONITRILE
OPTIMA/ACS
4L
A996SK-4
PETROLEUM ETHER
OPTIMA/ACS
4L
E120SK-4
Certified
4L
T397SK-4
CHLOROFORM
HPLC/ACS
4L
C606SK-4
TETRAHYDROFURAN
CHLOROFORM
Certified ACS
4L
C298SK-4
TETRAHYDROFURAN
HPLC/ACS
1L
T425SK-1
HPLC/ACS
4L
T425SK-4
CHLOROFORM
HPLC/ACS
1L
C606SK-1
TETRAHYDROFURAN
CHLOROFORM
Spectranalyzed
4L
C574SK-4
TETRAHYDROFURAN
OPTIMA/ACS
4L
T427SK-4
CHLOROFORM W/Pentene
HPLC/ACS
1L
C607SK-1
TOLUENE
Certified ACS
4L
T324SK-4
CHLOROFORM W/Pentene
HPLC/ACS
4L
C607SK-4
TOLUENE
HPLC/ACS
1L
T290SK-1
CYCLOHEXANE
HPLC/ACS
1L
C620SK-1
TOLUENE
HPLC/ACS
4L
T290SK-4
OPTIMA
4L
T291SK-4
CYCLOHEXANE
HPLC/ACS
4L
C620SK-4
TOLUENE
ETHYL ACETATE
HPLC/ACS
1L
E195SK-1
TOLUENE
Scintanalyzed/ACS
4L
T313SK-4
HPLC
1L
W5SK-1
ETHYL ACETATE
HPLC/ACS
4L
E195SK-4
WATER
ETHYL ACETATE
Certified ACS
4L
E145SK-4
WATER
HPLC
4L
W5SK-4
ETHYL ACETATE
OPTIMA
4L
E196SK-4
WATER
OPTIMA
4L
W7SK-4
ETHYL ALCOHOL
Denatured
4L
A407SK-4
XYLENES
Certified ACS
4L
X5SK-4
HEPTANE
HPLC
1L
H350SK-1
HEPTANE
HPLC
4L
H350SK-4
HEXANE
HPLC
1L
H302SK-1
HEXANE
HPLC
4L
H302SK-4
HEXANE
OPTIMA/ACS
4L
H303SK-4
HEXANES
Certified ACS
4L
H292SK-4
• Innovative safety bottle with FisherLOCK* tamper evident cap
ISO-OCTANE
HPLC/ACS
1L
O296SK-1
ISO-OCTANE
HPLC/ACS
4L
O296SK-4
• Convenient storing and
METHANOL
Certified ACS
4L
A412SK-4
METHANOL
HPLC/ACS
1L
A452SK-1
METHANOL
HPLC/ACS
4L
A452SK-4
METHANOL
OPTIMA/ACS
4L
A454SK-4
METHANOL
Scintanalyzed/ACS
4L
A408SK-4
View our video and see the difference at:
www.fishersci.com/safecote
These Fisher Chemical products are protected by Safe-Cote PVC
bottles that provide the purity of glass and most of the benefits
of plastic for storing and dispensing chemicals. If they break,
glass fragments and liquids are more likely to remain trapped.
dispensing
• Packaged in the
100% recyclable
Styrofoam-free
EcoSafPak
Products might not be available in
all regions. Contact your local sales
representative for details.
†
15
Safer, Smarter, and Eco-friendly Packaging
Styrofoam®-free EcoSafPak™
packaging. We now deliver all
4 × 4L, 1 × 4L, 6 × 1L, 6 × 500mL,
1 × 2.5L, 1 × 1L, 1 × 500mL, 2 × 4L,
2 × 1L and 2 × 500mL glass bottles
(including the Safe-Cote™ glass
bottles) of your favorite products
in eco-friendly EcoSafPak
packaging manufactured by an
SFI certified manufacturer.
EcoSafPak packaging minimizes the use of
non-recyclable material through the use of the
revolutionary Hexacomb design inserts.
The Hexacomb is:
• Fully Recyclable
• Sturdy and Durable
• Versatile
Improved safety & handling:
• EcoSafPak is the only package of its kind to pass the most
demanding ISTA (International Safe Transport Association)
“3A” test, consisting of:
• 17 drops to simulate real-world parcel shipment handling
• Shock testing
• Vibration testing
• Corrugated material is shock absorbing
• Greater stability in the frame of the box
• Staggered handholds for ease of transport
16
The EcoSafPak is now manufactured by an SFI-certified
manufacturer.
The Sustainable Forestry Initiative® (SFI) program:
• is based on the premise that responsible environmental
behavior and sound business decisions can co-exist
• is a comprehensive system of principles, objectives, and
performance measures developed by professional foresters,
conservationists, and scientists
• promotes the perpetual growing and harvesting of trees
with the long-term protection of wildlife, plants, soil,
and water
SFI’s Nine Objectives:
•
•
•
•
•
•
•
•
•
Sustainable Forestry
Responsible Practices
Reforestation and Productive Capacity
Forest Health and Productivity
Long-Term Forest and Soil Productivity
Protection of Water Resources
Protection of Special Sites and Biological Diversity
Legal Compliance
Continual Improvement
Chemical Storage/Handling Recommendations
Chemical Incompatibility
Acids and Bases
Chemicals should react in the lab, not in the stockroom. The inadvertent
mixing of inventory can produce toxic vapor/gas, fire or explosion. Stay safe in
the storeroom; adhere to the following prescribed precautions and consult the
chemical compatibility tables (below) for caustic combinations. For productspecific information, refer to the Material Safety Data Sheet (MSDS) provided
with purchase.
Isolate acids:
General Guidelines
• Store acids and bases in air-tight containers with snug-fitting caps; avoid
loose lids or glass stoppers; use vented caps when necessary
to prevent over-pressurization
• Protect eyes and skin: lab safety glasses with side shields, lab coats and
closed-toe shoes must be worn for basic personal protection
• Safely space shelves and racks to accommodate the upright removal of
the largest chemical container; prevent tipping and dripping with adequate
clearance
• Identify and substitute safer chemical alternatives
• Keep hazardous materials away from heat and direct sunlight to prevent the
degradation of chemicals and deterioration of storage containers and labels
• From reactive metals, including sodium, potassium and magnesium
• From sodium cyanide, iron sulfide, calcium carbide and other compounds
that can react to produce toxic fumes/gases
• Place combustible organic carboxylic acids (i.e., acetic acid) in a flammable
storage locker; store inorganic acids in acid storage cabinets
• Keep piranha etch and aqua regia in a fume hood at all times
• Use non-aluminum drip trays for aqueous sodium and potassium hydroxide
solutions; isolate nitric acid when utilizing secondary containment
• Safely transfer containers of acid and base solutions using
bottle carriers
• Never pour water into acid; slowly add the acid to the water and stir
• Do not store hazardous materials (except cleaners) under sinks
Flammable and Combustible Liquids
• Avoid chemical stockpiling; procure hazardous materials as needed
• Store flammable and combustible liquids away from oxidizers and heat
producers
• Limit fume hood storage of hazardous materials
• House flammable and combustible liquids in excess of 10 gallons
(per room) in approved flammable storage cabinets (under the hood or
stand-alone); limit liquids in secondary containers (i.e., squeeze bottles)
to 10 gallons or less
• Conduct periodic cleanouts to minimize accumulation of chemicals
• Keep all food (including gum), beverages, tobacco and open cosmetics
outside the work area
• Adhere to OSHA regulations for safe storage: 60 gallons of Class I
and/or Class II liquids or 120 gallons of Class III liquids per cabinet;
Class I liquids cannot be stored in a basement or pit without an approved
ventilation system
• Use only approved and well-labeled refrigerators and freezers for storing
flammable liquids; never store lunch with science
Incompatibilities by Hazard Class
Acids,
Inorganic
Acids,
Oxidizing
Acids,
Organic
Alkalis
(Bases)
Oxidizers
Poisons,
Inorganic
Poisons,
Organic
WaterOrganic
Reactives Solvents
Acids, inorganic
X
X
X
X
X
X
Acids, oxidizing
X
X
X
X
X
X
X
X
X
Acids, organic
X
X
Alkalis (bases)
X
X
Oxidizers
X
X
X
X
X
X
X
X
X
X
X
X
Poisons, inorganic
X
X
X
Poisons, organic
X
X
X
X
Water-reactives
X
X
Organic solvents
X
X
X
X
X
X
X
X
X
X
X
X
X indicates incompatibility between two chemical product groups. Incompatible products should not be stored in close proximity.
17
Chemical Incompatibilities
Chemical
Store Separately From
Acetic acid
Chromic acid, nitric acid, perchloric acid, peroxides, permanganates and other oxidizers
Acetone
Concentrated nitric and sulfuric acid mixtures, and strong bases
Acetylene
Chlorine, bromine, copper, fluorine, silver, mercury
Alkali metals
Water, carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens
Ammonia, anhydrous
Mercury, chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid
Ammonium nitrate
Acids, metal powders, flammable liquids, chlorates, nitrites, sulfur, finely divided organic or combustible materials
Aniline
Nitric acid, hydrogen peroxide
Arsenic materials
Any reducing agent
Azides
Acids
Bromine
Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide,
turpentine, benzene, finely divided metals
Calcium oxide
Water
Carbon (activated)
Calcium hypochlorite, all oxidizing agents
Carbon tetrachloride
Sodium
Chlorates
Ammonium salts, acids, metal powders, sulfur, finely divided organic or combustible materials
Chromic acid and chromium trioxide
Acetic acid, naphthalene, camphor, glycerol, glycerin, turpentine, alcohol, flammable liquids in general
Chlorine
Same as Bromine
Chlorine dioxide
Ammonia, methane, phosphine, hydrogen sulfide
Copper
Acetylene, hydrogen peroxide
Cumene hydroperoxide
Acids, organic or inorganic
Cyanides
Acids
Flammable liquids
Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens
Hydrocarbons
Fluorine, chlorine, bromine, chromic acid, sodium peroxide
Hydrocyanic acid
Acids
Hydrofluoric acid
Ammonia, aqueous or anhydrous bases and silica
Hydrogen peroxide
Copper, chromium, iron, most metals or their salts, alcohols, acetone, organic materials, aniline, nitromethane, flammable liquids
Hydrogen sulfide
Fuming nitric acid, other acids, oxidizing gases, acetylene, ammonia (aqueous or anhydrous), hydrogen
Hypochlorites
Acids, activated carbon
Iodine
Acetylene, ammonia (aqueous or anhydrous), hydrogen
Mercury
Acetylene, fulminic acid, ammonia
Nitrates
Sulfuric acid
Nitric acid (concentrated)
Acetic acid, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids, flammable gases, copper, brass, any heavy metals
Nitrites
Acids
Nitroparaffins
Inorganic bases, amines
Oxalic acid
Silver, mercury
Oxygen
Oils, grease, hydrogen; flammable liquids, solids, or gases
Perchloric acid
Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease and oils
Peroxides, organic
Acids (organic or mineral), avoid friction, store cold
Phosphorus (white)
Air, oxygen, alkalis, reducing agents
Potassium
Carbon tetrachloride, carbon dioxide, water
Potassium chlorate and perchlorate
Sulfuric and other acids, alkali metals, magnesium and calcium
Potassium permanganate
Glycerin, ethylene glycol, benzaldehyde, sulfuric acid
Selenides
Reducing agents
Silver
Acetylene, oxalic acid, tartaric acid, ammonium compounds, fulminic acid
Sodium
Carbon tetrachloride, carbon dioxide, water
Sodium nitrite
Ammonium nitrate and other ammonium salts
Sodium peroxide
Ethyl or methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene glycol, ethyl acetate, methyl acetate, furfural
Sulfides
Acids
Sulfuric Acid
Potassium chlorate, potassium perchlorate, potassium permanganate (or compounds with similar light metals: sodium, lithium, etc.)
Tellurides
Reducing agents
(From Manufacturing Chemists’ Association, Guide for Safety in the Chemical Laboratory, pp. 215–217, Van Nostrand)
18
All Plastics Are Not Created Equal
Differentiating between glass and plastic for chemical storage is fairly intuitive; selecting the most compatible plastic, well, that’s another story. Labware is constructed from a variety of polymers — polyethylene (low and high density), polypropylene, PVC, etc. — possessing unique and varying degrees of resistance to
the laundry list of chemicals. To maintain the structural integrity of the chemical containers and ensure safe handling, please consult the chemical resistance
tables before transferring materials.
Chemical Resistance and Physical Properties of Plastics
Resin Codes
ECTFE:
ETFE:
FEP:
FLPE:
FLPP:
HDPE:
LDPE:
NYL:
PPCO:
PC:
PETG:
PK:
PFA:
PMMA:
PMP:
PP:
PS:
PSF:
PTFE:
PUR:
PVC:
PVDF:
TPE:
XLPE:
Ethylene- chlorotrifluoroethylene copolymer
Ethylenetetrafluoroethylene
Fluorinated ethylene propylene
Fluorinated high-density polyethylene
Fluorinated polypropylene
High-density polyethylene
Low-density polyethylene
Nylon (polyamide)
Polypropylene copolymer
Polycarbonate
Polyethylene terephthalate copolyester
Polyketone
Do not store strong oxidizing agents in plastic
labware except if made of FEP, PFA or PTFE. Other
plastics will become brittle after prolonged exposure.
Perfluoroalkoxy
Polymethyl methacrylate
Polymethylpentene
Polypropylene
Polystyrene
Polysulfone
Polytetrafluoroethylene
Polyurethane
Polyvinyl chloride
Polyvinylidene fluoride
Thermoplastic elastomer
Cross-linked high-density polyethylene
Do not place plastic labware directly in a flame
or on a hotplate unless specified.
Use these charts as a reference only. They are
recommendations, not guarantees, of fitness
for particular uses. Test materials under actual
conditions before using them for your applications.
Chemical Resistance Summary
†
Classes of substances;
temperature 68°F (20°C)
ECTFE/ETFE
FEP/PTFE/PFA
FLPE
HDPE/XLPE
LDPE
NYL
PC
PETG
PK
PMMA
PMP
PP/PPCO
PS
PSF
PUR
PVC
PVDF
TPE ‡
E — No damage after 30 days of constant exposure.
Acids, weak or dilute
Acids†, strong or concentrated
Alcohols, aliphatic
Aldehydes
Bases
Esters
Hydrocarbons, aliphatic
Hydrocarbons, aromatic
Hydrocarbons, halogenated
Ketones
Oxidizing agents, strong
E
G
E
E
E
E
E
E
E
G
F
E
E
E
E
E
E
E
E
E
E
E
E
E
E
G
F
E
E
E
G
E
F
E
E
E
G
E
G
G
G
F
G
F
E
E
E
G
E
G
F
F
N
G
F
F
N
N
F
F
E
E
E
G
E
N
E
N
G
F
N
N
F
N
N
N
N
E
N
E
N
N
N
E
N
N
N
N
E
G
G
E
G
E
E
E
E
E
G
G
N
N
G
F
N
G
N
N
N
N
E
E
E
G
E
G
F
F
N
F
F
E
E
E
G
E
G
G
F
F
G
F
E
F
E
N
E
N
N
N
N
N
N
E
G
G
F
E
N
G
N
N
N
G
G
F
F
G
N
N
E
N
N
N
N
E
E
E
N
E
N
E
N
N
N
G
E
E
E
E
E
G
E
E
N
N
G
E
F
E
N
E
N
N
N
N
N
N
For oxidizing acids, see table entry “Oxidizing agents, strong.”
‡
G — Little or no damage after 30 days of constant
exposure.
F — Some effect after seven days of constant exposure.
Depending on the plastic, the effect may be cracking,
crazing, loss of strength or discoloration. Solvents may
cause softening, swelling and permeation losses with
PPCO, PP, PMP, LDPE and HDPE; the solvent effects on
these materials are normally reversible.
N — Not recommended for continuous use. Immediate
damage may occur. Depending on the plastic, the effect
will be severe cracking, crazing, loss of strength, discoloration, deformation, dissolution or permeation loss.
TPE gaskets
Superior Poly Packaging for Fisher Chemical
TraceMetal Acids and Bases
Selected TraceMetal Grade Acids and Bases are now available in poly bottles. Constructed with a new,
high-density polyethylene — made from a proprietary resin — the innovative bottles provide up to 80%
less metallic extractables (vs. glass).
Packaging Advantages
• Poly bottles are lighter, easier to handle and less likely to break during transport
• FisherLOCK tamper-evident cap safeguards chemicals; drip lip feature prevents spills when pouring
• 100% recyclable package reduces waste and all-poly bottle facilitates disposal (no PVC coating to be removed)
• Poly bottles occupy less space than glass bottles and enable better storage space utilization in the lab
19
20
NN
NN
EE
GG
NN
NN
NN
GG
NN
GF
GG
EE
EE
GF
EE
GG
GG
GG
EE
EE
NN
NN
NN
FF
NN
FF
NN
NN
NN
NN
NN
NN
NN
GF
GF
GF
GG
GG
EE
NN
NN
NN
FF
NN
NN
NN
NN
NN
NN
NN
NN
FF
EE
NN
NN
NN
NN
NN
NN
NN
NN
FF
GG
FF
NN
NN
GF
GG
NN
NN
EG
EG
NN
NN
NN
NN
FF
FF
NN
EE
FF
EE
EE
NN
GF
EE
—
EE
EE
NN
EE
GF
—
—
—
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EF
EE
EE
EE
—
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
—
EE
EE
EE
EG
EE
EE
E–
—
EE
EE
EG
—
EE
EE
EE
—
EE
EE
—
EG
NN
EG
EE
—
NN
—
NN
—
EG
NN
EE
EE
—
NN
NN
EE
NN
NN
EE
EE
—
EE
EE
—
EE
L
NN
EE
EG
GG
NN
NN
NN
EE
EE
GF
GG
GG
EE
GF
EE
EE
EF
GF
EE
GG
NN
NN
NN
NN
NN
GG
NN
NN
NN
NN
NN
NN
NN
EG
GG
EE
NN
GG
GF
EE
NN
NN
NN
NN
FN
NN
GN
NN
NN
EE
FF
NN
EG
NN
NN
NN
NN
NN
NN
NN
NN
NN
GG
NN
NN
EG
NN
EE
NN
NN
FN
GF
NN
NN
NN
NN
GN
FN
NN
EE
NN
NN
GG
NN
FN
EG
EE
FN
NN
EE
EE
EG
EF
EG
NN
EE
NN
EG
FF
EG
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PV
CO
/P
P
EC
Do not store strong oxidizing agents in
plastic containers except those made of
Teflon* FEP, PFA or PTFE. Other plastics
will become brittle after prolonged
exposure.
FE
P
Warning!
PM
P
Chemicals may affect the weight, strength,
color, dimensions, flexibility and surface
appearance of labware. The basic models
of interaction that cause these changes
are:
(1) chemical attack on the polymer
chain, with resultant reduction in physical
properties, including oxidation; reaction of
functional groups in or on the chain; and
depolymerization;
(2) physical change, including absorption
of solvents, resulting in softening and
swelling of the plastic; permeation of
solvent through the plastic; or dissolution
in a solvent; and
(3) stress-cracking from the interaction of
a ‘‘stress-cracking agent’’ with molded-in
or external stresses.
The reactive combination of compounds
of two or more classes may cause a
synergistic or undesirable chemical
effect. Other factors affecting chemical
resistance include: temperature, pressure,
internal or external stresses (such as
centrifugation), and length of exposure
to and concentration of the chemical.
As temperature increases, resistance to
attack decreases.
Acetaldehyde
Acetamide, sat.
Acetic acid, 5%
Acetic acid, 50%
Acetone
Acetonitrile
Acrylonitrile
Adipic acid
Alanine
Allyl alcohol
Aluminum hydroxide
Aluminum salts
Amino acids
Ammonia
Ammonium acetate, sat.
Ammonium glycolate
Ammonium hydroxide, 5%
Ammonium hydroxide, 30%
Ammonium oxalate
Ammonium salts
n-Amyl acetate
Amyl chloride
Aniline
Benzaldehyde
Benzene
Benzoic acid, sat.
Benzyl acetate
Benzyl alcohol
Bromine
Bromobenzene
Bromoform
Butadiene
n-Butyl acetate
n-Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Butyric acid
Calcium hydroxide, conc.
Calcium hypochlorite, sat.
Carbazole
Carbon disulfide
Carbon tetrachloride
Cedarwood oil
Cellosolve acetate
Chlorine, 10% in air
Chlorine, 10% (moist)
Chloroacetic acid
p-Chloroacetophenone
Chloroform
Chromic acid, 10%
Chromic acid, 50%
Cinnamon oil
Citric acid, 10%
Cresol
Cyclohexane
DeCalin
o-Dichlorobenzene
p-Dichlorobenzene
Diethyl benzene
Diethyl ether
Diethyl ketone
Diethyl malonate
Diethylene glycol
Diethylene glycol ethyl ether
Dimethyl formamide
Dimethylsulfoxide
1,4-Dioxane
Dipropylene glycol
Ether
Ethyl acetate
Ethyl alcohol (absolute)
Ethyl alcohol, 40%
Ethyl benzene
Ethyl benzoate
Ethyl butyrate
Ethyl chloride, liquid
Ethyl cyanoacetate
Ethyl lactate
Ethylene chloride
Ethylene glycol
Ethylene glycol methyl ether
Ethylene oxide
Fluorides
Fluorine
Formaldehyde, 10%
PP
Effects of Chemicals
on Labware
CHEMICAL
HD
PE
Use This Chart as a General Guide
Only. Test each chemical before storing
in labware. The first letter of each pair
represents the resistance rating at 20°C;
the second at 50°C.
E — No damage after 30 days
of constant exposure.
G — Little or no damage after
30 days of constant exposure.
F — Some effect after 7 days of
constant exposure. Depending on the
material, the effect may be cracking,
crazing, loss of strength or discoloration.
Solvents may cause softening, swelling,
and permeation losses with PA, PP, PMP,
LDPE and HDPE; the solvent effects on
these materials are normally reversible.
N — Not recommended for continuous
use. Immediate damage may occur.
Depending on the material, the effect
will be severe cracking, crazing, loss
of strength, discoloration, deformation,
dissolution or permeation loss.
LD
PE
How to Use This Chart
/P
TF
E/
PF
A
TF
E/
ET
FE
PC
Chemical Resistance of Labware Materials
EE
EE
EE
EE
EE
EG
EG
EG
—
EE
EE
GG
—
EE
EG
—
EE
EE
EE
EE
EE
EG
EG
GG
GG
EG
GG
GG
EE
GG
GG
GG
GG
EE
EE
EE
GG
GG
EE
—
EE
GG
—
GG
FF
FF
GG
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PT
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HD
PE
LD
PE
O
CHEMICAL
Formaldehyde, 40%
Formic acid, 3%
Formic acid, 50%
Formic acid, 98 to 100%
Freon® TF
Fuel oil
Gasoline
Glacial acetic acid
Glycerine
n-Heptane
Hexane
Hydrochloric acid, 1 to 5%
Hydrochloric acid, 20%
Hydrochloric acid, 35%
Hydrofluoric acid, 4%
Hydrofluoric acid, 48%
Hydrogen peroxide, 3%
Isobutyl alcohol
Isopropyl acetate
Isopropyl alcohol
Isopropyl benzene
Kerosene
Lactic acid, 3%
Lactic acid, 85%
Methoxyethyl oleate
Methyl alcohol
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl propyl ketone
Methylene chloride
Mineral oil
Nitric acid, 1 to 10%
Nitric acid, 50%
Nitric acid, 70%
Nitrobenzene
n-Octane
Orange oil
Ozone
Perchloric acid
Perchloroethylene
Phenol, crystals
Phosphoric acid, 1 to 5%
Phosphoric acid, 85%
Pine oil
Potassium hydroxide, 1%
Potassium hydroxide, conc.
Propane gas
Propylene glycol
Propylene oxide
Resorcinol, sat.
Resorcinol, 5%
Salicylaldehyde
Salicylic acid, powder
Salicylic acid, sat.
Salt solutions, metallic
Silver acetate
Silver nitrate
Sodium acetate, sat.
Sodium hydroxide, 1%
Sodium hydroxide, 50% to sat.
Sodium hypochlorite, 15%
Stearic acid, crystals
Sulfuric acid, 1 to 6%
Sulfuric acid, 20%
Sulfuric acid, 60%
Sulfuric acid, 98%
Sulfur dioxide, liq., 46 psi
Sulfur dioxide, wet or dry
Sulfur salts
Tartaric acid
Tetrahydrofuran
Thionyl chloride
Toluene
Tributyl citrate
Trichloroethane
Trichloroethylene
Triethylene glycol
Tripropylene glycol
Turpentine
Undecyl alcohol
Urea
Vinylidene chloride
Xylene
Zinc stearate
FE
FA
te
el
Chemical Resistance of Labware Materials (contd.)
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
EE
—
NN
EG
EG
EG
EE
EE
EE
—
EE
EE
EE
—
EE
EE
EE
—
EE
EE
EE
NN
NN
EE
EE
EE
—
EE
EE
EE
EE
EE
—
GF
NN
NN
EE
—
—
—
—
EE
EE
—
—
EE
EE
GE
NN
EG
EE
EG
GG
NN
NN
NN
EE
—
EE
EE
EE
EE
—
EE
EE
—
—
EE
—
EE
—
EE
EE
Warning!
The plastic resin information in these
tables (does not include SS, glass or
ceramic) has been provided by Thermo
Scientific* Nalgene* and is reprinted
with their permission. It should be used
ONLY as a guide for selecting labware
for testing.
Test the labware for 72 hours under
expected or proposed conditions of use,
BEFORE putting into service. Test with
care to avoid injury or property damage.
Fisher Scientific does not warrant
(neither express nor implied) that the
information in these tables is accurate
or complete.
21
Notes
22
Notes
23
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Chemical Stockroom Handbook

Transcription

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