Water Quality of the Kharaa River Basin, Mongolia
Transcription
Water Quality of the Kharaa River Basin, Mongolia
UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Water Quality of the Kharaa River Basin, Mongolia: Pollution threats and hotspots assessment Final report with support of The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" GEF project “Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem” (Mongolia and Russia), 2011-2014 Technical report under Output 1.4 (pollution hotspot assessment) Water Quality of the Kharaa River Basin, Mongolia: Pollution threats and hotspots assessment (2013) International executing partner for Output 1.4 (pollution hotspot assessment) United Nations Educational, Scientific and Cultural Organization - UNESCO ©Batimaa, P., 2013 Figure 5. The Kharaa River at Baruunkharaa hydrological gauging station (21 July 2012) Photo credits: Batimaa Punsalmaa and Mongolia Water Forum The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Water Quality of the Kharaa River Water Quality of the Kharaa River Basin, Mongolia: Basin, Mongolia Pollution threats and hotspots assessment Pollution threats and hotspots assessment Final report Editor: Editor: Sarantuyaa Zandaryaa, UNESCO International Hydrological Programme Sarantuyaa Zandaryaa, UNESCO Prepared by: Punsalmaa, Mongolia Water Forum - Uskhelts Prepared Batimaa by: Erdenbayar Yadamsuren, Central Laboratory for Environment and Meteorology of Mongolia Batimaa Punsalmaa, Mongolia Water Forum - Uskhelts Tumurstooj Dashdorj, of Meteorology, Hydrology and Environment of Mongolia Erdenbayar Yadamsuren, CentralInstitute Laboratory for Environment and Meteorology Oyuntugs Tserendendev, National Water Committee of Mongolia Tumurstooj Dashdorj, Institute of Meteorology, Hydrology and Environment Batnasan, Mongolia Water Forum – Uskhelts Oyuntugs Davaadalai Tserendendev, National Water Committee of Mongolia Sarantuyaa Zandaryaa, UNESCO International Hydrological Programme Davaadalai Batnasan, Mongolia Water Forum – Uskhelts Sarantuyaa Zandaryaa, UNESCO (Paris, France) with support of Ulaanbaatar 2013 Ulaanbaatar The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 2013 project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" This report presents results of water quality assessment of the Selenge River Basin (Mongolia), with specific emphasis on assessment of pollution threats and pollution hotspots in the Kharaa River Basin. The study was conducted in the framework of UNESCO-executed activities under the UNDPGEF Project on “Integrated Natural Resources Management in the Baikal Basin Transboundary Ecosystem” (Mongolia and Russia). The project objective is to spearhead integrated natural resources management of Lake Baikal Basin, ensuring ecosystem resilience and reduced water quality threats in the context of sustainable economic development. The project is executed by UNOPS. UNESCO’s International Hydrological Programme (IHP) is an international executing partner for the project. This study was carried out by UNESCO, in collaboration with the National Water Committee of Mongolia, Mongolia Water Forum-Uskhelts and a national team of experts. The study and report preparation was coordinated by Sarantuyaa Zandaryaa, Division of Water Sciences, UNESCO. The national team of experts was coordinated by Tsend Badrakh, National Water Committee of Mongolia, and comprised the following experts: Batimaa Punsalmaa, Mongolia Water Forum - Uskhelts; Erdenbayar Yadamsuren, Central Laboratory for Environment and Meteorology; Tumurstooj Dashdorj, Institute of Meteorology, Hydrology and Environment; Oyuntugs Tserendendev, National Water Committee of Mongolia; and Davaadalai Batnasan, Mongolia Water Forum-Uskhelts. Tserendolgor Munkhtsetseg, Mongolia Water Forum - Uskhelts, assisted in the preparation of the report for publishing. Findings and recommendations of the study were discussed with relevant stakeholders at the National Workshop “Selenge – A River without Borders”, organized by UNESCO in collaboration with the National Water Committee and Ministry of Environment and Green Development of Mongolia, which took place in the State Palace in Ulaanbaatar on 04 June 2013. The workshop participants included representatives of the Ministry of Environment and Green Development, Ministry of Health, Ministry of Industry and Agriculture, River Basin Authorities, research institutions, universities, NGOs and the private sector. The key outcomes of the workshop discussions were incorporated in this final report. The report also benefited from discussions at the scoping meetings and workshops, organized by UNESCO in the framework of this study. The publication of this report was made possible with the support of Sergey Kudelya, Project Manager (Ulan-Ude, Russia), and Tumurchudur Sodnom, Technical Director (Mongolia), of the GEF project “Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem”. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. I UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" II The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Foreword by Prime Minister of Mongolia Throughout the human history, we, Mongolians, valued the water as the basis of all existence on the Earth and the Foreword by unique treasure of the world. The Government Mongolia attaches great Prime Ministerof of Mongolia importance to the protection and sustainable use of this precious resource and, in particunew challenges andresources threats resulting from lar, to establishing an effective and legal totransboundary water is essential. Throughout the human history, policy we, Mongolians, change the impacts on water resources. I framework water resources management. Furthermore, support of international valued the for water as the basis of all existence on climate am pleased that the project on “Integrated Natthe Earth and the unique treasure of the world. organizations is needed to strengthen ResourcetoManagement in challenges the Baikal and BaWater is a special resource that isattaches not confined cooperation face up to new The Government of Mongolia great ural Transboundary Ecosystem”, implemented toimportance a country’stoterritory or political threats resulting from climate change impacts the protection andboundaries. sustainable sin UN organizations, responds to this Mongolia is precious located inresource the heart of Central Asia, by onvarious water resources. I am pleased that the project use of this and, in particular, on “Integrated Resource Management to establishing an effective policymany and large legal need and to theNatural goals that the Mongolian Govwhere the headwaters of world’s in the Baikal Basin Transboundary Ecosystem”, framework for water resources management. rivers are formed by runoff from numerous ernment has prioritized for sustainable use and implementedofby various organizations, natural andUN water resources. I springs, snowmelt and glaciers of the Mongo- management responds to this need and to the goals that the Water is a special resource that is not confined lian mountains. Mongolians have a long tradi- would like to warmly congratulate the organizMongolian Government has prioritized for to a country’s territory or political boundaries. tion of conserving the purity of water resources ers and participants of the National Workshop sustainable use and management of natural Mongolia in the territory heart ofand Central that originateisinlocated our country’s flow entitled “Selenge—A River without Borders” for Asia, where the headwaters of world’s and water resources. I would like to warmly out to our neighboring countries. This tradition providing a platform to discuss the results of the many large rivers are formed by runoff from congratulate the organizers and participants has been preserved from generation to genera- project studies presented in this report on wanumerous springs, snowmelt and glaciers of of the National Workshop entitled “Selenge-A tion and has been enshrined in the Mongolian ter quality of the Kharaa River, which I consider the Mongolian mountains. Mongolians have a River without Borders” for providing a platform contribution Baigovernment’s on watertheresources to important discuss the results of to themaintain project the studies long traditionpolicy of conserving purity of manwater an kal Basin ecosystems that constitute the world’s agement. Mongolia is fully engaged in internaresources that originate in our country’s territory presented in this report on water quality freshwater heritage. tional cooperation our neighboring counof the Kharaa River, resource which I and consider an and flow out to ourwith neighboring countries. This magnificent tries on fair, equitable and sustainable use of tradition has been preserved from generation important contribution to maintain the Baikal share the same We the live world’s in the transboundary An example Basin ecosystems thatrivers. constitute to generation water and hasresources. been enshrined in the We same river basin. We drink water from the magnificent freshwater resource and heritage. isMongolian our cooperation with the Russian Federagovernment’s policy on water resources management. Mongolia is fully same rivers. Therefore, our common goal tion on the implementation of the “Agreement We share theprotect same rivers. We live inwater the same in international with must be to our precious reonengaged the Protection and Usecooperation of Transboundriver basin. We drink water from the same our neighboring countries on fair, equitable ary Waters”, which was signed between the sources and to use them sustainably to enrivers. the Therefore, our development common goal and must imbe and sustainable use two of transboundary water hance country’s governments of our countries in 1995. to protect our precious water resources and to resources. An example is our cooperation with prove the living standard of our people. use them sustainably to enhance the country’s the Russian Federation on the implementation Our water resources are becoming scarcer due the “Agreement on the Protection and Use development and improve the living standard toofclimate change. In view of climate change of Transboundary Waters”, which was signed of our people. impacts on water resources, international cobetween the governments of our two countries operation on fair and equitable use of transin 1995. Norov Altankhuyag boundary water resources is essential. FurtherPrime Minister of Mongolia more, support ofare international Watertheresources becomingorganizations scarcer due isto needed strengthen cooperation to face up Chairman, National Water NorovCommittee Altankhuyag climatetochange. In view of climate change impacts on water resources, international cooperation on fair and equitable use of Prime Minister of Mongolia Chairman, National Water Committee *This Foreword is based on the message of the Prime Minister of Mongolia to the National Workshop “Selenge—A River without Borders”, organized by UNESCO, National Water Committee and Ministry of Environment and Green Development of *This Foreword is based (State on the Palace) messageon of 04 theJune Prime Minister of Mongolia to the National Workshop “Selenge-A River Mongolia in Ulaanbaatar 2013. without Borders”, organized by UNESCO, National Water Committee and Ministry of Environment and Green Development of Mongolia in Ulaanbaatar (State Palace) on 04 June 2013. III III The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table of Contents List of Figures................................................................................................................... 5 List of Tables.................................................................................................................... 6 Acronyms ........................................................................................................................ 9 Executive summary........................................................................................................... 1 1. Introduction.................................................................................................................. 7 1.1. Background........................................................................................................... 8 1.2. Objectives of the study.......................................................................................... 10 1.3. Data and methodology.......................................................................................... 11 1.3.1. Monitoring sites............................................................................................... 11 1.3.2. Data................................................................................................................ 12 1.3.3. Methodology................................................................................................... 14 2. Water Resources of the Selenge River Basin, Mongolia................................................. 19 2.1. Hydrology............................................................................................................. 20 2.2. Hydrochemistry..................................................................................................... 20 2.3. Water quality......................................................................................................... 22 3. Water Quality Assessment of the Kharaa River Basin.................................................... 25 3.1. Hydrology and hydrogeology................................................................................ 26 3.1.1. Surface water.................................................................................................. 26 3.1.2. Groundwater................................................................................................... 28 3.2. Hydrochemistry..................................................................................................... 28 3.2.1. Major ions....................................................................................................... 29 3.2.2. Dissolved oxygen............................................................................................ 30 3.2.3. Biological Oxygen Demand............................................................................ 33 3.2.4. Nutrients......................................................................................................... 33 3.2.5. Metals............................................................................................................. 36 3.2.6. Suspended solids............................................................................................. 38 3.3. The Kharaa River water quality.............................................................................. 39 3.4. Aquatic ecology.................................................................................................... 39 3.5. Groundwater quality in the Kharaa River Basin..................................................... 43 4. Assessment of pollution hotspots in the Kharaa River Basin.......................................... 45 4.1. Pollution from urban areas.................................................................................... 46 4.1.1. Municipal wastewater..................................................................................... 46 4.1.2. Solid waste...................................................................................................... 50 4.2. Industrial pollution................................................................................................ 53 4.3. Mining................................................................................................................... 53 4.4. Agriculture............................................................................................................ 57 4.5. Pollution hotspots mapping................................................................................... 58 4.6. Environmental and health impacts......................................................................... 59 5. Conclusions and Recommendations............................................................................. 63 5.1. Conclusions........................................................................................................... 64 5.2. Recommendations................................................................................................. 68 References........................................................................................................................ 72 Annex............................................................................................................................... 74 Data analyses................................................................................................................... 75 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the IV project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" List of Figures Figure 1. Map of the Lake Baikal Basin, shared between Mongolia and Russia .............. 9 Figure 2. The Confluence of the Selenge and Orkhon rivers (29 June 2009.................... 11 Figure 3. Water quality index at the Sukhbaatar of the Selenge River.............................. 23 Figure 4. Biotic Index results at three sites of the Selenge River...................................... 23 Figure 5. The Kharaa River at Baruunkharaa hydrological gauging station (21 July 2012) ................................................................................................. 27 Figure 6. The Kharaa River Basin and water quality monitoring sites.............................. 27 Figure 7. Relationship between total dissolved salts and cations and anions (Kharaa-Zuunkharaa upper)............................................................................. 29 Figure 8. Relationship between total dissolved salts and cations and anions (Kharaa-Darkhan down).................................................................................. 30 Figure 9. Dissolved Oxygen concentration trends of the Kharaa River for the period 1985-2010...................................................................................................... 32 Figure 10. Biological oxygen demand concentration trend of the Kharaa River near Darkhan city for the period 1985-2010........................................................... 33 Figure 11.Trends in NH4-N concentrations at Zuunkharaa and Darkhan monitoring station........................................................................................... 35 Figure 12. Trends in NO3-N concentrations at Zuunkharaa and Darkhan monitoring stations............................................................................................................ 35 Figure 13. Trends in PO4-P concentrations at Zuunkharaa and Darkhan monitoring stations.......................................................................................... 36 Figure 14. Trends of Fe and Cr6+ at Zuunkharaa and Darkhan stations............................ 37 Figure 15. Trends of suspended solidsat Zuunkharaa and Darkhan stations...................... 38 Figure 16. Water quality of the Kharaa river at Zuunkharaa and Darkhan stations............ 39 Figure 17. Number of total individuals of Taxa and EPT................................................... 40 Figure 18. The Kharaa river water quality assessed by Biotic index................................... 41 Figure 19. Annual variation of the Kharaa river water quality assessed by Biotic index..... 41 Figure 20. Ecological assessment of the Kharaa River Basin ............................................. 42 Figure 21. The administrative units in the Kharaa River Basin........................................... 47 Figure 22. The Darkhan Wastewater Treatment Plant....................................................... 49 Figure 23. Wastewater treatment rate of the Darkhan WWTP........................................... 48 Figure 24. BOD concentrations of treatedwastewater of the Darkhan WWTP................... 48 Figure 25. Suspended solids concentrations in treated wastewater of the Darkhan WWTP.............................................................................................. 49 Figure 26. Mining areas of the Kharaa River Basin............................................................ 54 Figure 27. The Boroo Gold mining site............................................................................. 55 Figure 28. The tailing facility of the Boroo mining............................................................ 56 Figure 29. Cropland area on the Kharaa River bank.......................................................... 57 Figure 30. Bornuur cropland farming near the Boroo River bank...................................... 58 Figure 31. Map of areas of concern (potential pollution hotspots) in the Kharaa River Basin.......................................................................................... 59 Figure 32. Runoff forming and river bank protection zone................................................ 60 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. V UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" List of Tables Table 1. Kharaa River monitoring stations and parameters............................................. 13 Table 2. Hydrobiological monitoring stations................................................................ 13 Table 3. Water quality classification.............................................................................. 15 Table 4. Macroinvertebrates Biotic Index...................................................................... 16 Table 5. Water quality classification.............................................................................. 16 Table 6. Hydrological parameters of rivers in the Selenge River and its tributaries......... 21 Table 7. Long-term mean concentration of major ions in the Selenge River and its tributaries........................................................................................................ 21 Table 8. Long-term mean concentrations of chemical pollutants in the Selenge and its tributaries........................................................................................................ 21 Table 9. Ephemeroptera, Plecoptera,Trichoptera individuals found in the Selenge river and its tributaries............................................................................................. 22 Table 10. Summary analysis of Aquatic Macroinvertebrate at different stations in the Selenge River and its tributaries....................................................................... 23 Table 11. Exploitable groundwater resources of the Kharaa River Basin.......................... 28 Table 12. Annual distribution of average concentrations of total dissolved salts, or mineralization................................................................................................. 29 Table 13. Monthly mean concentrations of major ions of the Kharaa River..................... 31 Table 14. Annual distribution of dissolved oxygen concentrations................................... 32 Table 15. Monthly mean concentrations of ammonium of the Kharaa River.................... 34 Table 16. Concentrations of metals in the Kharaa River................................................... 36 Table 17. Heavy metals concentrations in the Kharaa River............................................ 37 Table 18. Monthly mean concentrations of suspended solids in the Kharaa River............ 38 Table 19. Groundwater quality parameters .................................................................... 43 Table 20. Quantities and composition of solid waste generated in Darkhan by source category ......................................................................................................... 51 Table 21. Results of chemical analysis of the monitoring wells ....................................... 56 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the VI project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Acronyms BOD DO EPT FAO GEF IHP MAC MNET MNS NSA NSO OCHA TSS UNDP UNEP UNESCO UNIDO USAG WHO WQI WWTP Biological oxygen demand Dissolved oxygen Ephemeroptera, Plecoptera, Trichoptera Food and Agriculture Organization Global Environment Facility International Hydrological Programme of UNESCO Maximum Acceptable Concentrations Ministry of Nature, Environment and Tourism of Mongolia Mongolia National Standard National Standard Agency of Mongolia National Statistics Office of Mongolia Office for the Coordination of Humanitarian Affairs of the United Nations Total suspended solids United Nations Development Programme United Nations Environmental Programme United Nations Educational, Scientific and Cultural Organization United Nations Industrial Development Organization Water Supply and Wastewater Company of Ulaanbaatar World Health Organization Water Quality Index Wastewater Treatment Plant The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. VII UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the VIIIproject. VIII Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Executive summary The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. ©Batimaa, P., 2013 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Mongolia has many beautiful freshwater lakes and rivers. Some of the world’s major rivers originate in Mongolia, including Selenge River, Yenisei and Irtysh. Most of Mongolia’s rivers are spread across the northern part of the country, where the river system is also most extensive. The Selenge River is the largest river by volume of flow, which is a major transboundary river in the heart of Asia flowing to Lake Baikal, located in Russia. About two-thirds of the surface runoff leaves Mongolia. The largest lakes of Mongolia, including Khuvsgul, Uvs and Khar-Us, are located in the northern and western regions of the country. Mongolia has substantial groundwater resources, which are unevenly distributed over the countryabundant in the north and very scarce, or non-existent, in the south. Driven by climate change, urbanization and rapid economic growth, Mongolia’s water resources are under increasing pressure. Water resources of Mongolia are limited, with the annual water reserves of 34.6 cubic kilometers-which is relatively low compared to other countries. Yet, the per capita annual renewable water availability exceeds 10,000 cubic meters, which is more than in most other countries in the world. This seeming contradiction can be explained by the country’s population density of only 1.8 persons per square kilometers, which is the lowest in the world1. Despite the huge amount of renewable water in the country, its availability is unevenly distributed in space and in time. Most of Mongolia’s territory lies in arid and semi-arid regions, which makes its water resources particularly vulnerable to climatic and human pressures. The Kharaa River Basin is one of the main tributaries of the Orkhon-Selenge River system. The Orkhon River originates in the Khangai Mountains in central Mongolia and flows northwards for 1,124 km before joining the Selenge River, which empties into Lake Baikal. The Orkhon River is the longest river in Mongolia and the valley along the river is an archaeologically-rich cultural landscape. The Orkhon Valley Cultural Landscape has been designated by UNESCO as a World Heritage Site. The pollution of the Kharaa River Basin is becoming a growing concern due to the high vulnerability of the basin to urban and industrial pollution from urban settlements and large industrial operations located in the basin. The Kharaa River Basin is shared among three administrative regions, called aimags (equivalent to provinces)-namely, Selenge aimag, Tuv aimag and Darkhan-Uul aimag. The basin also includes the rapidlygrowing industrial city of Darkhan, which is thethird largest city with 74,738 inhabitants (as of 2010)2. The entire population of the Kharaa River Basin is about 133,000. The Kharaa River Basin is under increasing pressure from rapid urbanization, rising water demand and climate change. The upper basin is in a relatively pristine state and has experienced minimal anthropogenic impacts. The lower basin is characterized by diverse economic activities such as industry, agriculture and livestock breeding, which may potentially have significant impacts on the quantity and quality of water resources of the basin. Furthermore, the basin provides drinking water for the rapidly-growing city of Darkhan, which water supplies largely rely on alluvial aquifers containing shallowdepth groundwater, and the inhabitants of small human settlements in the basin. Hence, growing pressures from climate change and anthropogenic activities on the Kharaa River may become a matter of concern in securing future water supplies in the area. The assessment of water quality and water pollution in the Selenge River Basin, undertaken by this study, focused on a casestudy on pollution hotspots and pollution threats in the Kharaa River Basin, including urban water pollution in the city of Darkhan, Mongolia. Ministry of Environment and Green Development, 2012. Integrated Water Management Plan of Mongolia 2010-2021: A Brief Introduction, Ulaanbaatar, Mongolia, December 2012. 1 Data from the National Statistical Office of Mongolia. 2 2 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The main were to toassess assessthe thecurrent current The mainobjectives objectivesofofthis this study study were state water quality of the Kharaa River Basin, assess state of of thethe water quality of the Kharaa River Basin, assess wapollution from diffuse andsources, point sources, identify terwater pollution from diffuse and point identify pollution pollution hotspots thedetermine basin, andthedetermine the main hotspots in the basin,inand main pressures on on theofwater quality River, of the with Kharaa River, withdea thepressures water quality the Kharaa a qualitative qualitative description of their impacts. The study focused scription of their impacts. The study focused on: the survey of on: the survey of water quality characteristics of the Kharaa water quality characteristics of the Kharaa River; the identifiRiver; the identification of anthropogenic impacts on the cation of anthropogenic impacts on the river’s water quality; river’s water quality; the identification of major threats thetoidentification of major threats to the water quality in the the water quality in the basin; and the development of basin; and the development of recommendations on pollution recommendations on pollution prevention and control in the prevention and Basin. control in the Kharaa River Basin. Kharaa River The water quality qualityininthethe Kharaa River Theassessment assessmentofof the the water Kharaa River is is based bothboth hydrochemical and hydrobiological parambasedon on hydrochemical and hydrobiological eters. The hydrochemical assessmentassessment is based on ishydrochemiparameters. The hydrochemical based on data by the Central calhydrochemical monitoring datamonitoring collected by the collected Central Laboratory for EnLaboratory Environmentforand thethrough period vironment andforMeteorology theMeteorology period from for 1986 fromThe 1986hydrobiological through 2011. The hydrobiological is 2011. assessment is based assessment on macroinbased on macroinvertebrates data collected by the Institute vertebrates data collected by the Institute of Meteorology, Hyof Meteorology, Hydrology andperiod Environment for the period drology and Environment for the from 2005 to 2010. The Kharaa River from 2005 to 2010. As part of the Mongolia’s freshwater quality monitoring netAs part of the Mongolia’s freshwater quality monitoring work, the Kharaa River water quality has been monitored at network, the Kharaa River water quality has been monitored four sampling points at at two 1986. at four sampling points twomonitoring monitoringstations stations since since 1986. The upper whichisisthe the reference of The uppermonitoring monitoring station, station, which reference sitesite of the thestudy, study,is is located near Zuunkharaa (a small urban settlelocated near Zuunkharaa (a small urban settlement) ment) has sampling two sampling points upstream and downstream and and has two points upstream and downstream from from Zuunkharaa. The second monitoring station is located Zuunkharaa. The second monitoring station is located near to near to Darkhan city two sampling points too—upDarkhan city and hasand twohas sampling points too-upstream and downstream from the city. stream and downstream from the city. The overall assessment of chemical the chemical composition has The overall assessment of the composition has shown shown good chemical conditions at the sampling sites on good chemical conditions at the sampling sites on the Kharaa the The Kharaa River. Theconcentrations monthly mean concentrations of River. monthly mean of total dissolved salts 2+ total dissolved2+salts +(the +sum of2+Ca2+, Na++K+, Mg , HCO - 3-, 2(the sum of Ca , Na +K , Mg , HCO3-, SO4 and Cl ), or SO42- and Cl-), or mineralization, in the Kharaa River vary mineralization, in the Kharaa River vary between 162.2-335.7 between 162.2-335.7 mg/l and show a tendency to increase mg/l and show a tendency to increase towards downstream. towards downstream. The concentrations of total dissolved The concentrations total dissolved salts increase salts increase alsoofduring snow melting periods.also In aduring vast snow melting periods. In a vast majority of the cases, the order majority of the cases, the order of abundance of cations is + + 2+ 2+ >Naof +K >Mg2+, of and the orof Ca abundance cations is the Ca2+order >Na++K+of >Mg , and abundance anions is 22->SO >Cl . derHCO of abundance of anions is HCO ->SO >Cl . 3 4 3 4 The Orkhon River The grassland of the Kharaa River Basin The concentrations (BOD) The concentrationsofofthe thebiological biological oxygen oxygen demand demand (BOD) are, mostofofthe thecases, cases, below below the the Maximum Acceptable are, in inmost Acceptable Concentrationofof5 5mg/l—the mg/l-the standard set Concentration set by by the the Mongolian Mongolian National Standard for Water Quality of the Aquatic National Standard for Water Quality of the Aquatic EnvironEnvironment: General Requirements MNS 4586-98 (NSA, ment: General Requirements MNS 4586-98 (NSA, 1998). 1998). This indicates that in general the river water is clean. However, This indicates that in general the river water is clean. However, The forest of the Kharaa River Basin The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 33 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" it should be noted that the BOD concentrations occasionally exceed the Maximum Acceptable Concentrations (5 mg/l) at both sampling sites during summer. This may show that organic pollutants originating from urban and industrial areas and livestock wastes enter the river with surface washing during heavy rainfall events in summer. Phosphorus and nitrogen concentrations show a decreasing trend near Zuunkharaa, while there is no trend near the city of Darkhan. The concentrations of NO3-N near Zuunkharaa have decreased since 1990s. Similarly, PO4-Pconcentrations have decreased near Zuunkharaa. There are no observed data on metals, except total Fe and Cr6+ at the downstream sampling points of both monitoring stations. The monthly mean concentrations of Fe range between 0.08 and 0.15 mg/l and increases during rainy seasons. The Cr6+ concentrations are between 0 and 0.01 mg/l and also increase in rainy season. The analysis of the macro-invertebrate communities at the two monitoring sites of the Kharaa River watershed indicates that the ecological condition of the river is good. The assessment of the fish communities has shown a good, or a very good, ecological status at the sites. A moderate status, detected at two sites in the watershed, is caused by the absence of ubiquistic species, showing no clear deficits in the ecological integrity of the fish fauna. Most of the fish species are known to occur in the Kharaa River Basin. The major point source of pollution appears to be the wastewater treatment plants in the cities of Darkhan and Salkhit. The treatment rate of the Darkhan Wastewater Treatment Plant ranges between 80-98%. The BOD concentrations in the outlet wastewater range between 3.1-33.6 mg/land very rarely exceed the Maximum Acceptable Concentrations (20 mg/l), set by the Mongolian National Standard for Wastewater Treatment MNS 4943-2000. 4 More than 60 percent of the total area of the Kharaa River Basin is pasture. Accordingly, the livestock herding at the river bank is the major non-point source of pollution during warm seasons, leading to the fecal contamination and direct nutrient inputs to the river water by domestic waste, including animal manure. The second largest non-point source is open mining. Several large mining reserves are found in the Kharaa River Basin and occupy an area of about 16 percent of the total area of the basin. Some of the mines are not yet exploited, which means that exploration and development licenses of these reserves may have been issued to mining companies, with mining operations not having started. The mining area under operation represents 1.5 percent of the total area of the basin, which is about 9.3 percent of the total area for mining purposes (Figure 26). There are no systematically observed data to assess the pollution from mining activities in the area. Heavy metals such as mercury, arsenic, and cyanide are commonly used in gold mines, which may have potentially serious impacts not only on surface water quality but also on groundwater and soil. An incident of a possible mercury and cyanide contamination of groundwater caused by a tailings spill from a small mining operation in Khongor soum was recorded in 2007. The results of the assessment indicate that the water quality in the Kharaa River Basin decreases occasionally to ‘moderatelypolluted’ and ‘very-polluted’ near urban and industrial settlements, which may become a concern in the future. The main sources of water pollution in the basin are urban areas, agriculture and mining activities. The assessment also shows that the selfpurification rate in the Mongolian rivers is usually high with the distance of selfpurification of 6-18 kilometers. The selfpurification distance of the Kharaa River appears to be 10 kilometers downstream from the city of Darkhan. Consequently, the Kharaa River water becomes clean at its outlet at the confluence with the Orkhon The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" quality Orkhon and Selenge rivers. quality ofof thethe Orkhon and Selenge rivers. overall, results of the study the water InInoverall, thethe results of the study showshow that that the water qualquality of the Kharaa River Basin is clean and good ity of the Kharaa River Basin is clean and has good has ecological ecologicalThe conditions. The of water of thedecreases Kharaa conditions. water quality the quality Kharaa River River decreases occasionally to ‘moderately-polluted’ occasionally to ‘moderately-polluted’ and ‘very-polluted’ and near ‘very-polluted’ near urban and industrial areas, as well as urban and industrial areas, as well as during high water periods during high water periods and snow melting times. This and snow melting times. This shows that moderate pollution shows that moderate pollution occurs near urban areas occurs urban areasperiods, and in snow periods, with no and innear snow melting with melting no serious degradation serious in of thethe water quality of the whole basin. in thedegradation water quality whole basin. The basin are are urban urban Themain mainsources sourcesofofwater water pollution pollution in in the the basin areas, agriculture and mining activities. Due to rapid urbanareas, agriculture and mining activities. Due to rapid ization and economic development, pollution from municiurbanization and economic development, pollution from municipal wastewater andactivities mining may activities mayabecome pal wastewater and mining become concern concern the future. Furthermore, the Basin Kharaais River inathe future.inFurthermore, the Kharaa River facing Basin is facing growing pressures change growing pressures from climate changefrom andclimate rising water deand rising water demands. Hence, the sustainable use and mands. Hence, the sustainable use and management of water management water River resources Kharaaimportance River Basinin resources of theofKharaa Basinof is the of crucial is of crucial importance in securing future water supplies securing future water supplies in the area. in the area. The Borоo Gold mining The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and and hotspots assessment Pollution threats hotspots assessment project. 55 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 6 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Introduction 1.1.Introduction The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. ©Batimaa P., 2013 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Life on Earth originated from water. Water is essential for human life. We drink it, we produce food and other products with it, and we use water for many socio-cultural activities. Our health and well-being depend on it. It is essential for the sustainable development of society. Water a resource that must be sustained for future generations. 1.1. Background With abundant water resources in some areas and shortages in others, Mongolia is facing a With abundant water resources in some areas and shortages in others, Mongolia is facing a challenge to use and manage its water resources for the country’s sustainable development and the prosperity of its people, while protecting and maintaining them for future generations. Mongolia has many beautiful freshwater lakes and rivers. Most of Mongolia’s rivers are spread across the northern part of the country, where the river system is also most extensive. The largest and longest rivers in Mongolia are the Orkhon River (1,124 km), the Kherlen River (1,090 km), the Tuul River (704 km), Zavkhan River (670 km) and the Selenge River (539 km). The Selenge River is the largest river by volume of flow. Many rivers are used as sources of water for livestock and irrigation. Because of the mountainous terrain, there is a great concentration of potential hydropower in the north. Most of the rivers are unsuitable for navigation. The largest lakes of Mongolia, including Khuvsgul, Uvs and Khar-Us, are located in the northern and western regions of the country. Lake Khuvsgul, located in northern Mongolia, is Mongolia’s largest freshwater lake and the 16th largest naturally formed lake in the world by water volume. Lake Khuvsgul contains 60 percent of the surface freshwater resources of Mongolia and is a constant source of clean freshwater flowing to the Selenge River through its outflow the Eg River. It is one of the ancient lakes of Asia and a sister lake of Lake Baikal. Lake Uvs (Uvs Nuur) is the largest lake in Mongolia by surface area. The Uvs Nuur Basin has been designated by UNESCO as a World Heritage Site for its rich steppe biodiversity. Mongolia has substantial groundwater resources, which are unevenly distributed over the country-abundant in the 8 north and very scarce, or non-existent, in the south. Most of Mongolia’s water resources belong to transboundary river basins of the Arctic Ocean and Pacific Ocean drainage. Some of the world’s major rivers have their origin in Mongolia, including Selenge River, Yenisei and Irtysh. The Selenge River is a major transboundary river in the heart of Asia and the main tributary of Lake Baikal, located in Russia. The Selenge River Basin is shared by Mongolia and Russia (Figure 1). It forms the headwaters of the Yenisei-Angara river system. About two-thirds of the surface runoff leaves Mongolia. Driven by climate change, urbanization and rapid economic growth, Mongolia’s water resources are under increasing pressure. Water resources of Mongolia are limited, with the annual water reserves of 34.6 cubic kilometers- which is relatively low compared to other countries. Yet, the per capita annual renewable water availability exceeds 10,000 cubic meters, which is more than in most other countries in the world. This seeming contradiction can be explained by the country’s population density of only 1.8 persons per square kilometers, which is the lowest in the world. Despite the huge amount of renewable water in the country, its availability is unevenly distributed in space and in time. Most of Mongolia’s territory lies in arid and semi-arid regions, which makes its water resources particularly vulnerable to climatic and human pressures. Mongolia’s water resources are faced with rapidly growing problems such as the impact of global climate change, overexploitation of water resources, wastewater discharge into rivers from point sources in urban and rural areas, and diffuse pollution from non-point sources like livestock and cropland (Batimaa et al, 2011). The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 1.Map of the Lake Baikal Basin, shared between Mongolia and Russia Figure 1. Map of the Lake Baikal Basin, shared between Mongolia and Russia The Kharaa of the mainmain tribThe Kharaa River RiverBasin Basinis one is one of the utaries of Orkhon-Selenge River River Basin (Figure tributaries of Orkhon-Selenge Basin 2). The2). Orkhon River originates in the in Khan(Figure The Orkhon River originates the Khangai Mountains in central Mongolia and gai Mountains in central Mongolia and flows flows northwards for 1,124 km before joining northwards for 1,124 km before joining the the Selenge River, which empties into Lake Selenge River, which empties into Lake BaiBaikal. Orkhon River is the longest river kal. TheThe Orkhon River is the longest river in in Mongolia and the valley along the river is Mongolia and the valley along the river is an an archaeologically-rich cultural landscape. archaeologically-rich cultural landscape. The The Orkhon Valley Cultural Landscape has Orkhon Valley Cultural Landscape has been been designated by UNESCO as a World designated by UNESCO as a World Heritage Site. Heritage Site. The pollution of Kharaa River The pollution of Kharaa River concern Basin is becomBasin is becoming a growing due to ing high a growing concern due to the high vulthe vulnerability of the basin to urban and nerability of the basin to urban andindustrial industrial pollution pollution from urban settlements settlements and and large large industrial operations located in the basin. industrial operations located in the basin. The The Kharaa River isBasin sharedthree among Kharaa River Basin sharedis among adthree administrative regions, called aimags ministrative regions, called aimags (equivalent (equivalent to provinces)—namely, Selenge to provinces)—namely, Selenge aimag, Tuv aimag, Tuv aimag and Darkhan-Uul aimag. aimag and Darkhan-Uul aimag. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 99 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The basin also includes the rapidly-growing industrial city of Darkhan, which is the third largest city with 74,738 inhabitants (as of 2010). The entire population of the Kharaa River Basin is about 133,000. The Kharaa River Basin is under increasing pressure from rapid urbanization, rising water demand and climate change. The upper basin is in a relatively pristine state and has experienced minimal anthropogenic impacts. The lower basin is characterized by diverse economic activities such as industry, agriculture and livestock breeding, which may potentially have significant impacts on the quantity and quality of water resources of the basin. Furthermore, the basin provides drinking water for the rapidly-growing Darkhan City, which water supplies largely rely on alluvial aquifers containing shallow-depth groundwater, and the inhabitants of small human settlements in the basin. Hence, growing pressures from climate change and anthropogenic activities on the Kharaa River may become a matter of concern in securing future water supplies in the area. Consequently, the assessment of water pollution in the Selenge River Basin focused on a case-study on pollution hotspots and pollution threats in the Kharaa River Basin, including urban water pollution in Darkhan, Mongolia. 1.2. Objectives of the study River water systems bring a multitude of benefits, called “ecological goods and services”, to the society. Water resources for human uses and ecological services depend on good natural ecological conditions of rivers. Furthermore, the availability of valuable fish populations in rivers and lakes and the self-purification capacity of rivers directly depend on water quality. The protection and maintenance of water quality is, therefore, required to ensure the sustainability of water resources and ecosystem goods and services. Climate change, rapid urbanization and expanding economic activities exert a wide range of pressures on the Selenge River Basin, particularly on the Kharaa River, which makes the Kharaa River Basin an ideal focus region of this study. There are growing concerns over the overexploitation of water resources and pollution from urban areas, agriculture and mining. The assessment of water pollution in the Selenge River Basin focused on a case-study on pollution hotspots and pollution threats in Kharaa River Basin, including urban water pollution in Darkhan, Mongolia. The main objectives of this study were to assess the current state of the water quality of the Kharaa River Basin, assess water pollution from diffuse and point sources, identify pollution hotspots in the basin, and determine the main pressures on the water quality of the Kharaa River, with a qualitative description of their impacts. The water quality assessment focused on: • the survey of water quality characteristics of the Kharaa River; •the identification of anthropogenic impacts on the river’s water quality; • the identification of major threats to the water quality in the basin; and • the development of recommendations on pollution prevention and control in the Kharaa River Basin. The scope of study includes: • Human impacts on water quality in the basin; • Major pollution threats to water quality; •Pollution hotspots, including major pollution sources, types and levels of selected main pollutants; •Urban pollution, including municipal wastewater, stormwater, and solid waste; •Negative impacts of water pollution on the sustainability of water resources in the basin, as well as on human health and ecosystems. The study is based on existing information and data that are available at national institutions. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 10 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 1.3. Data 1.3. Dataand andmethodology methodology Mongolia a surface water quality Mongoliahashas a surface water monitorquality ing network, which consists of national monitoring network, which consistssamof pling sites sampling at various sites locations and frequencies national at various locations and frequencies throughout Mongolia’s throughout Mongolia’s river network. Theriver wanetwork. The water quality monitoring aims ter quality monitoring aims to monitor the wato quality monitorofthe water of rivers and to ter rivers andquality to provide an overview provide an overview of the state of water of the state of water quality of Mongolia’s rivquality of Mongolia’s rivers in compliance ers in compliance with the Mongolian National with the for Mongolian National for Standard Water Quality of theStandard Aquatic EnWater Quality of the Aquatic Environment: vironment: General Requirements MNS 4586General Requirements MNS 4586- 98 98 (NSA, 1998). Water quality monitoring mea(NSA, 1998). Water quality monitoring surements include include physicochemical parameters measurements physicochemical such as temperature, pH, major ions, nutrients parameters such as temperature, pH, major and metals. Since 1995, the surface water ions, nutrients and metals. Since 1995, biothe monitoring network has been recognized an surface water biomonitoring network ashas been recognized as an integral part of the long- integral part of thequality long-term freshwater quality term freshwater monitoring network. monitoring network. It incorporates biological It incorporates biological information into information into traditional physicochemical traditional physicochemical water quality water qualityMacro-invertebrate monitoring. Macro-invertebrate monitoring. samples are collectedare forcollected use in assessing degradation samples for usethe in assessing the of aquatic ecosystems. degradation of aquatic ecosystems. The Selenge SelengeRiver River is ofone of the mostThe is one the most-extensiveextensively monitored rivers in As ly monitored rivers in Mongolia.Mongolia. As the study the study focuses on the Kharaa River Basin, focuses on the Kharaa River Basin, data from data from selected water quality monitoring selected water quality monitoring stations are stations are used in the study. Monitoring used in the study. Monitoring stations and stations and sampling sites selected for samthis pling sites selected for this study are described study are described in the respective sections in the respective sections hereafter of the rehereafter of the report. port. 1.3.1. Monitoring sites 1.3.1. Monitoring sites As the Mongolia’s Mongolia’s freshwater freshwater quality quality As part part of of the monitoring network, the Kharaa River water monitoring network, the Kharaa River water quality at two two stations stations quality has has been been monitored monitored at since 1986 (see Figure 6). since 1986 (see Figure 6). of study. ItIt has has two two sampling sampling points: points: the the of the the study. first sampling point (Zuunkharaa-upper) is first sampling point (Zuunkharaa-upper) lois cated upstream of Zuunkharaa; and the seclocated upstream of Zuunkharaa; and the ond sampling pointpoint (Zuunkharaa-down) is losecond sampling (Zuunkharaa-down) cated downstream from from Zuunkharaa in order is located downstream Zuunkharaa in The upper upper monitoring The monitoring station is located located near near to monitor the impact of the settlement on the order to monitor the impact of the settlement Zuunkharaa-a small on the of quality of the River Kharaa River water. Zuunkharaa—a smallurban urbansettlement. settlement.This This quality the Kharaa water. station has been chosen as the reference site station has been chosen as the reference site Figure 2. The Confluence of the rivers (29 June 2009) Figure 2. The Confluence of the Selenge and Orkhon Selenge and Orkhon rivers (29 June 2009) The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 11 11 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The second monitoring station is located near to Darkhan city, and has two sampling points: Darkhan-upper and Darkhan-down, which are located upstream and downstream from the city. 1.3.2. Data Water quality varies considerably throughout the year in relation to climatic conditions, runoff and human activities. In order to obtain a realistic view on surface water quality and to evaluate trends in the basin, monitoring data must be collected at different times of the year on same sampling sites. However, surface water sampling alone cannot characterize all the physical and biological conditions of surface water systems. In addition to surface water assessment, studies on sediments, habitats and biological diversity are also necessary to obtain a complete understanding of the state of water quality and ecological conditions of river basins and their changes. The assessment of the water quality of the Kharaa River Basin included an assessment of changes in both hydrochemical and hydrobiological parameters. The hydrochemical monitoring data, collected by the Central Laboratory for Environment and Meteorology for the period from 1986 through 2011, are used for the hydro-chemical study. The macroinvertebrates data collected by the Institute of Meteorology, Hydrology and Environment for the period from 2005 to 2010 are used for the hydrobiological study. Observed data on surface water quality Within the Mongolian national environmental monitoring network, there are 64 sampling sites for surface water quality monitoring. These sampling sites are located on 19 rivers and one lake. There are also two sampling sites in the Selenge River Basin for the analysis of wastewater discharges from wastewater treatment plants. It should be noted that data from only selected sampling sites are assessed for this report, as the study focuses on the Kharaa River Basin. The Kharaa River water quality is monitored at four sampling points at two monitoring stations—near Zuunkharaa and the city of Darkhan. The assessment of the water quality in the Kharaa River is based on both hydrochemical and hydrobiological parameters. Environment and Meteorology for the period from 1986 through 2011. The Kharaa River water quality is monitored at the Zuunkharaa monitoring stations with a monthly frequency during the months of April through November, whereas the monitoring is carried out once a month throughout the year at the Darkhan monitoring station. The water quality monitoring parameters at these stations are shown in Table 1. The hydrobiological assessment is based on macroinvertebrates data collected by the Institute of Meteorology, Hydrology and Environment for the period from 2005 to 2010. Table 2 shows hydrobiological monitoring stations in the Selenge River Basin. The hydrochemical assessment is based on hydrochemical monitoring data of the Kharaa River collected by the Central Laboratory for The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 12 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table Table 1. 1.Kharaa KharaaRiver Rivermonitoring monitoring stations stations and and parameters parameters № Stations Chemistry 2+ 1 Zuunkharaa upper Zuunkharaa down Darkhan upper Darkhan down 2 3 4 1 Zuunkharaa upper Zuunkharaa down Darkhan upper Darkhan down 2 3 4 + Suspended Solids + + + + + + + + + + + + + + + + + + Cl- + + + + + + + + + Ca Mg + + + + + + + O2 pH + Hardness + SO4-- 2+ Na +K BOD + NH4-N + HCO3 - Nitrogen NO3-N + Metals Cr PO4-P + Fe + + + + + + + + + + + + + + + + + Table Table 2. 2.Hydrobiological Hydrobiologicalmonitoring monitoringstations stations № Rivers 1 Selenge 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Selenge Selenge Chuluut Eg Orkhon Urdtamir Achuut Tuul Tuul Tuul Terelj Zuunturuu Ulaistai Selbe Selbe Kharaa Kharaa Ider Sharyin gol Station Location Khurag Latitude 49037’611 Longitude 102085’056 Khyalganat Sykhbaatar Chuluut Khantai Orkhon Tsetserleg Bulgan Ulaanbaatar Altanbulag Lun Terelj Bulgan Uliastai Sanzai Dambadarjaa Baruunkharaa Darkhan Tosontsengel Jimsnii stants 49. 046’833 50025’258 47054’250 49055’000 480.66’000 47044’722 48082’917 47088’333 47068’333 47085’000 47096’667 48082’917 48004’130 48013’333 47098’000 48091’089 49059’142 48074’111 49076’667 104037’944 106013’786 100024’722 103026’806 103056’778 101050’250 103050’306 106093’333 106028’330 105018’333 107046’667 103054’583 107006’255 106088’333 106092’000 106007’844 105085’908 98023’056 106016’667 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats hotspots assessment Pollution threats andand hotspots assessment project. 13 13 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Groundwater quality data Groundwater quality data Groundwater limited to to Groundwater quality quality monitoring monitoring is is limited only for for the the period beonly aanumber numberofoflocations locations period fore 1990. DataData on groundwater quality were before 1990. on groundwater quality were recorded for shallow andwells deepand wells recorded for shallow and deep inand included on mineral composition, cluded data ondata mineral composition, pH, and pH, and sometimes nitrogen-based sometimes nitrogen-based nutrients nutrients such as such as nitrite, ammonium, nitrate. As nitrite, ammonium, and nitrate.and As mineraliza- tion of aquifers of does not change significantly mineralization aquifers does not change within a few within decades, it was assumed that significantly a few decades, it was these datathat reflect roughly the current statethe of assumed these data reflect roughly current state of physico-chemical quality physico-chemical quality of groundwater. The of groundwater. Thesufficient availabletodata not available data are not assessare trends sufficient to assess trends of groundwater of groundwater quality in the Kharaa River Baquality in the Kharaa River Basin. sin. Reports, publications andand other materials Reports, publications other materials Many other published used reports of Many published reports were were reviewed reviewed used of the theongoing ongoingGerman-funded German-funded and used in this study in order to capture all project on “Integrated Water Resources and used in order to capture all project on “Integrated Water Resources Manavailable information informationon on the the water quality Management for Central Asia–MoMo” the available quality of of agement for Central Asia–MoMo” in the in basin. the Kharaa Rver Basin. The study extensively basin. the Kharaa Rver Basin. The study extensively 1.3.3. Methodology 1.3.3. Methodology In general, general, water quality is defined by In water quality is defined by the comthe composition of its constituents, position of its constituents, including: physical including: physical characteristics (such as characteristics (such as temperature, suspended temperature, suspended solids); chemical solids); chemical(such characteristics (suchnutrients, as major characteristics as major ions, ions, nutrients, oxygen, organic compounds); oxygen, organic compounds); and biological and biological characteristics (such as macrocharacteristics (such as macroinvertebrates). invertebrates). The assessment assessment of water the quality water monitorquality The of the monitoring data is based on the basic ing data is based on the basic statistical analystatistical analysis (arithmetic mean, max/ sis (arithmetic mean, max/min, trends, etc.) for min, trends, etc.) for each possible chemical each possible chemicalatparameter monitored parameter monitored the sampling points at the sampling points in the Kharaa River as in the Kharaa River as part of the national part the national waternetwork. quality monitoring waterofquality monitoring network. Water Quality Index Water Quality Index One of the key goals of implementing One of the key goals of implementing conserconservation practices is to maintain and vation practices to maintain anda improve waimprove water isquality within watershed. ter within Thecan overall state Thequality overall state aofwatershed. water quality serve as of water quality can serve as a simple first step a simple first step tool in efforts of evaluating tool in efforts of evaluating effects of the coneffects of the conservation practices in servation practices improving the and/or sustainimproving and/or insustaining quality of ing theinquality of water inOne the watershed. One water the watershed. of the methods to the describe the to overall statethe ofoverall water quality of methods describe state of is Water Quality Index (WQI). It is basedIt water quality is Water Quality Index (WQI). on information from a number of different is based on information from a number of difsources and and combines them into ferent sources combines them intoa asingle single number that represents an overall state of number that represents an overall state of the the quality of the water at a particular time and quality of the water at a particular time and location. Conventionally, WQI has been location. Conventionally, WQI has been dedeveloped and used for evaluating water veloped and used for evaluating water quality quality of water resources such as streams, of water resources rivers and lakes. such as streams, rivers and lakes. The Water Quality Index is used by the The Water Quality Index is used by the Central Central Laboratory for Environment and Laboratory for Environment and Meteorology Meteorology of Mongolia for the purpose of Mongolia for the purpose of assessing the of assessing the ecological status of surface ecological status of surface Mongolia. waters in Mongolia. Belowwaters is thein description Below is the description of the methodology of the methodology for determining the WQI, for determining the WQI, this study. used in this study. It is used basedin on: surfaceIt iswater based on: surface quality index; and quality index; water and biotic index. biotic index. Surface water quality index: The surface ) isThe defined a water quality index (W Surface water quality index: surfaceaswaqi simple expression ofqia) is more or less ter quality index (W defined as complex a simple combination a several which expression of aofmore or less parameters complex combinaserves as a measure for water quality (Bulgan, tion of a several parameters which serves as a 2008). Itforiswater estimated by the 2008). following measure quality (Bulgan, It is equation: estimated by the following equation: 𝐶𝐶𝐶𝐶 ∑𝑞𝑞𝑞𝑞 � 𝑞𝑞𝑞𝑞 � 𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑞𝑞𝑞𝑞 𝑊𝑊𝑊𝑊𝑞𝑞𝑞𝑞𝑞𝑞𝑞𝑞 = 𝑛𝑛𝑛𝑛 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 14 project. 14 Water Quality of Kharaa the Kharaa Basin, Mongolia: Water Quality of the RiverRiver Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table3.3.Water Waterquality qualityclassification classification Table Water quality classification I II II IV V VI Classification Very clean Clean Moderately polluted Polluted Highly polluted Extremely polluted Water Quality Index ≤0.3 0.1-0.89 0.90-2.49 2.50-3.99 4.00-5.99 ≥6.0 Where, Where, ismaximum the maximum concentration ith pollutant, i of of ithth pollutant, Pli isPlthe permisCCii isisconcentration pollutant in accordance with 4586the permissible level of i th sible level of i pollutant in accordance with the MNS MNS 4586- 98, and n is the total number of pollutants. 98, and n is the total number of pollutants. The water quality of rivers is then classified based on Wqi The water values, as quality shown of in rivers Table is3.then classified based on Wqi values, as shown in Table 3. In determining the WQI, the water quality parameters should be chosen according to the importance of assessing In determining water quality parameters data. should water quality the andWQI, the the availability of monitoring be chosen according to the importance of assessing water The following parameters were used in the water quality quality and the availability monitoring data. The following assessment of the Kharaa of River in the framework of this parameters were used in the water quality assessment of the study: Kharaa River in the framework of (NH4-N) this study: • ammonium-nitrogen • nitrate-nitrogen (NO3-N) (NH4-N) • ammonium-nitrogen • phosphate (PO4-P) (NO3-N) • nitrate-nitrogen • permanganate • phosphatevalue (PO4-P) • suspended solids. value • permanganate • suspended solids. The dissolved oxygen (DO) and biological oxygen demand (BOD) are the most preferable parameters for the water The dissolved oxygen (DO) and biological oxygen demand quality assessment. However, the DO and BOD are (BOD) are the most preferable parameters for the water qualmonitored only at the two sampling points of the Darkhan ity assessment. However, the the DOZuunkharaa and BOD are monitored monitoring station, whereas monitoring only at the of the Darkhan monitoring station doestwo notsampling include points these parameters, as shown in station, whereas the Zuunkharaa monitoring station does Table 1. Therefore, due to lack of data on DO and BODnot include these parameters, as shown in Table 1. Therefore, due at the Zuunkharaa monitoring station, these parameters to lacknot of data DOaccount and BOD the Zuunkharaa were takenon into theatcalculation of the monitorWater Quality Index of parameters the Kharaa were River.not taken into account the ing station, these calculation of the Water Quality Index of the Kharaa River. Biotic index: One of the methods that scale the water quality by the hydrobiology is the “Hilsenhoff Biotic Index”index: (Barbour 1999). The that Biotic Index based on Biotic Oneetofal,the methods scale theiswater quality categorizing macroinvertebrates by the hydrobiology is the “Hilsenhoff Biotic Index” (Barbour into categories depending on their response to organic et al, 1999). The Biotic Index is based on categorizing macropollution (i.e., the tolerance of various levels of dissolved invertebrates into categories depending on their response to oxygen) and the pollution tolerance scores and expanded organic pollution (i.e., the tolerance of various levels of dissolved oxygen) and the pollution tolerance scores and expanded the range from 0 to 10 (Table 4). The Borоо River dam The Borоо river dam The Bornuur irrigation channel The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats andand hotspots assessment Pollution threats hotspots assessment project. 15 15 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table Table 4. Macroinvertebrates Biotic Index Table4. 4.Macroinvertebrates MacroinvertebratesBiotic BioticIndex Index Group Group name name Biotic Biotic index index Ephemeoptera Ephemeoptera Ameletidae Ameletidae Baetidae Baetidae Baetiscidae Baetiscidae Caenidae Caenidae Ephemerellidae Ephemerellidae Ephemeridae Ephemeridae Heptageniidae Heptageniidae Isonychiidae Isonychiidae Leptophlebidae Leptophlebidae Metretopodidae Metretopodidae Oligoneyridae Oligoneyridae Polymitarcyidae Polymitarcyidae Potamanthidae Potamanthidae Siphlonuridae Siphlonuridae Plecoptera Plecoptera Capniidae Capniidae Chloroperlidae Chloroperlidae Leuctridae Leuctridae Nemouridae Nemouridae Perlidae Perlidae Perlodidae Perlodidae Pteronarcyidae Pteronarcyidae Taeniopterygidae Taeniopterygidae Odonata Odonata Aeshnidae Aeshnidae Calopterygidae Calopterygidae Coenagrionidae Coenagrionidae Cordulegastridae Cordulegastridae Corduliidae Corduliidae Gomphidae Gomphidae 00 55 44 66 11 33 33 11 33 22 22 22 44 44 22 00 00 22 22 22 00 22 33 66 88 33 22 33 Group Group name name Lestidae Lestidae Libellulidae Libellulidae Macromiidae Macromiidae Trichoptera Trichoptera Brachycentridae Brachycentridae Glossomatidae Glossomatidae Hydropsychidae Hydropsychidae Hydroptilidae Hydroptilidae Lepidostomatidae Lepidostomatidae Leptoceridae Leptoceridae Limnephilidae Limnephilidae Molannidae Molannidae Odontaceridae Odontaceridae Phryganeidae Phryganeidae Polycentropodidae Polycentropodidae Psychomyiidae Psychomyiidae Rhaycophilidae Rhaycophilidae Battle Battle Elmidae Elmidae Dytiscidae Dytiscidae Gyrinidae Gyrinidae Haliplidae Haliplidae Hydrophilidae Hydrophilidae Diptera Diptera Athericidae Athericidae Blepharoceridae Blepharoceridae Ceratopogonidae Ceratopogonidae Chaoboridae Chaoboridae RedChironomidae RedChironomidae Other Other Chironomidae Chironomidae Culicidae Culicidae Biotic Biotic index index 66 22 22 11 11 44 44 11 44 33 66 00 44 66 22 11 44 55 44 55 55 44 00 66 88 88 66 88 Group Group name name Biotic Biotic index index Dixidae Dixidae Emphididae Emphididae Ephydridae Ephydridae Psychodidae Psychodidae Simulidae Simulidae Muscidae Muscidae Syrphidae Syrphidae Tabanidae Tabanidae Tipulidae Tipulidae Homoptera Homoptera Corixidae Corixidae Megaloptera Megaloptera Corydalidae Corydalidae Sialidae Sialidae Lepidoptera Lepidoptera Pyralidae Pyralidae Pagurian Pagurian Gammaridae Gammaridae Asellidae Asellidae Translingual Translingual Acariformes Acariformes Pulmonate Pulmonate Lymnaeidae Lymnaeidae Physidae Physidae Planorbidae Planorbidae Sphaeridae Sphaeridae Clitellata Clitellata Oligochaeta Oligochaeta Hirudinea Hirudinea Turbellaria Turbellaria 11 66 66 88 66 66 10 10 55 33 55 44 44 55 66 88 44 66 88 77 88 88 10 10 44 The The Macroinvertebrates Biotic Index, Index, used used for for Where, Where, Where, The Macroinvertebrates MacroinvertebratesBiotic Biotic Index, used the the assessment assessment of of the the river river water water quality, quality, is is eses-group macroinvertebrates, macroinvertebrates, isis macroinvertemacroinverteis i-group macroinvertebrates, ti is for the assessment of the river water quality, xisisi -group timated timated by by the the following equation: equation: brates brates index, index, and and isis index, the the total total number number of of macmacmacroinvertebrates and n is the total is estimated byfollowing the following equation: number of macroinvertebrates. roinvertebrates. roinvertebrates. Biotic Biotic Index= Index= ∑ ∑xx tt The water based The water quality quality quality classification classification classification based based on on the the the Macroinvertebrates Biotic Index is given in Macroinvertebrates Macroinvertebrates Biotic Biotic Index Index isis given given in in TaTaTable 5 below. ble ble 55 below. below. ii ii nn Table Table 5. Water quality classification Table5. 5.Water Waterquality qualityclassification classification Classification Classification Biotic Biotic index index Very Very clean clean Clean Clean Slightlypolluted Slightlypolluted Polluted Polluted Very Very polluted polluted <4.18 <4.18 4.18-5.09 4.18-5.09 5.10-5.91 5.10-5.91 5.92-7.05 5.92-7.05 >7.05 >7.05 Source: Source: Bulgan, Bulgan, 2008 2008 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 16 project. 16 16 Water Quality of Kharaa the Kharaa River Basin, Mongolia: Water Water Quality Quality of of the the Kharaa River River Basin, Basin, Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The advantage of the Biotic Index is that it gives a possibility to assess the quality of water more precisely. But it requires that the analysis is done by specialized experts in a laboratory with special equipment. Water Quality Index The Mongolian National Standard for Water Quality of the Aquatic Environment: General Requirements MNS 4586-98, developed by the Centre of Standardization and Measure¬ments of Mongolia in 1998 (NSA, 1998) and still in force, provides a national standard for principal water quality parameters of the aquatic environment. This standard includes 27 parameters. The objective of this standard is control the quality of surface and groundwater in Mongolia. There is, so far, no internationally-agreed stan-dard for physico-chemical and ecological wa¬ter quality of the aquatic environment and water resources as rivers, streams and lakes. Hence, the MNS 4586-98 has been applied for this study to evaluate the quality of the Kharaa River water. Pollution hotspot assessment There are a number of methodologies on pollution hotspot analysis (Vidon et. al., 2010), which are used worldwide. One of them is the methodology developed by UNIDO (2013) in the framework of the GEF-funded project on the Dnieper River Basin (2000-2005). The ap¬proach used in this methodology is to assess and prioritize the sources of industrial efflu¬ent discharges (hotspots) in a river basin. Only point source pollutions are considered under this methodology (http:// www.unido.org/what- we-do/environment/). The following three steps are applied in this ap-proach: 1. Preliminary screening: The number of industries discharging their effluents into a river and its tributaries is significant. The goal of this step is to shortlist or reduce this number into a manageable number for the second step. The preliminary screening is based on available wastewater data such as biological oxygen de-mand (BOD5) or metal concentration. 2. Detailed evaluation: The objective of the evaluation is to gather information on the selected sites during the first step. Each hot spot is evaluated based on the impact of its discharges on the following issues: (i) pollution control, (ii) water quality and human health, (iii) biodiversity, and (iv) socio-economic. 3. Prioritization: Based on the data collected, each hot spot is scored. Higher score will be given to hot spot with higher negative impact. A rating is then established to classify the industrial hotspots based on their impact on the surface water. The basic principles of the UNIDO's hotspot assessment methodology are applied in the pollution hotspot assessment of the Kharaa Riv¬er Basin due to the availability of data and the timeframe required for conducting a compre-hensive assessment. Furthermore, there are only few point sources of pollution in the Kharaa River Basin, except two municipal wastewater treatment plants that discharge their treated wastewater into the Kharaa River. But there is no much informa¬tion of outflows of these wastewater treatment plants. Thus, the focus of the study was to ana¬lyze the Kharaa River water quality, as detailed as possible, using the available observed data on water quality monitoring. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. 17 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 18 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 2. Water of the 2.Resources Water Resources RiverRiver ofSelenge the Selenge Basin, Basin,Mongolia Mongolia The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. ©Batimaa P., 2013 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The Selenge River Basin covers seven provinces, including Zavkhan, Khuvsgul, Bulgan, Arkhangai, Uvurkhangai, Tuv, and Selenge. Ulaanbaatar—the capital city of Mongolia—is located on the bank of the Tuul River, which is part of the Tuul-OrkhonSelenge River system. Few other cities such as industrial cities of Darkhan (the second biggest city) and Erdenet (the third biggest city) are located in the Selenge River Basin. Approximately 80 percent of the basin landscape is classified as high mountain plateau and mountainous taiga, 90 percent is forest steppe and, 15 percent is steppe zone. Due to the large area of the basin, the soil conditions and formation processes present differ significantly from region to region. Within the Khangai, Khentii, and Khuvsgul mountains, taiga, tundra, and mountain soils prevail, while drysteppe soil is dominant in the wide valley areas of the Orkhon and Selenge rivers (Dorjgotov, 2003). The basin belongs to different geographical zones. The Selenge River Basin covers about 57.5 percent of the total Mongolian high mountain areas, 64.6 percent of the forest steppe, and 13.6 percent of the steppe zone area (National Atlas, 2009). The area of the Selenge River Basin does not have any desert, which indicates favorable ecological and climatic conditions of the area. 2.1. Hydrology The water resources of the Selenge River Basin contain about 50 percent of total surface water resources of Mongolia (Myagmarjav and Davaa, 1999). The Selenge River forms at the confluence of the Ider, Delgermuren and Bugsei rivers in the northern Mongolia. It is one of the biggest freshwater resources in Mongolia. Its drainage area is 282 154 square kilometers (Myagmarjav and Davaa, 1999). The Selenge River is a transboundary water system, located between latitudes 46 and 52°N and longitudes 96 and 109°E. The river flows northeastwards through Mongolia to Russia, emptying to Lake Baikal. The Selenge River forms a large delta on the southeast shoreline of Lake Baikal. Average annual precipitation is 350-400 mm in the upper river reaches of the basin in the Khangai, Khentii and Khuvsgul mountains and 300-350 mm in the middle water way, while it is in the range of, or lower than, 250-300 mm in downstream valleys. About 70 percent of the total annual precipitation falls during the summer months from June to September (National Atlas, 2009). The rivers directly flow into Selenge River are Orkhon, Eg and Khanui. The long-term average runoff data at the gauging stations on the Selenge River and its tributaries are given in Table 6 (Myagmarjav et al, 2012). 2.2. Hydrochemistry In terms of chemical composition, the rivers in the Selenge River Basin are similar in that calcium (Ca2+) and bicarbonate (HCO3-),are the dominant ions. About 90-100 percent of the all samples show the dominance of bicarbonate and 70-90 percent the dominance of calcium. During winter lowwater periods and in years of drought, the Na++K+ appear to be dominant ions. The long-term mean of total dissolved salts, or mineralization of the main river, varies between 128-255 mg/l (Table 7). The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 20 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table Table6.6.Hydrological Hydrologicalparameters parametersofofrivers riversininthe theSelenge SelengeRiver Riverand anditsitstributaries tributaries No River-station Period of observation Area, km2 1 2 3 4 5 7 11 12 13 14 16 17 Selenge-Khutag Selenge-Khyalgant Selenge-Zuunburen Ider-Zurkh Delgermuren-Muren Bugsei-Tumerbulag Eg-Erdenebulgan Eg-Khantai Orkhon-Kharkhorin Orkhon-Orkhon Orkhon-Orkhon Tuul Orkhon-Sukhbaatar 1945-2010 1982-2010 1975-2010 1960-2010 1947-2010 1964-2010 1973-2010 1959-2010 1970-2010 1945-2010 1971-2010 1950-2010 92300 143500 148000 21300 18900 2761 15300 41000 6410 36400 96000 132000 Mean elevation, m Discharge, m3 /sec Specific runoff, l/sec km2 1909 1220 1200 2179 2023 1980 1857 1708 2241 1900 1880 1200 132.7 306.6 248.5 33.9 36.1 1.57 26.6 99.2 13.3 41.6 81.1 129.4 Runoff depth, mm 1.44 2.14 1.68 1.59 1.91 0.57 1.74 2.42 2.08 1.14 0.84 0.98 45.4 67.4 53.0 50.2 60.3 17.9 54.8 76.4 65.5 36.1 26.7 30.9 Source: Myagmarjav et al, 2012. Accordingtotosome somestudies studies (Myagmarjav et. According (Myagmarjav et. al., al., 2012), the runoff of the Selenge River 2012), the runoff of the Selenge River Basin Basin has decreased in all seasons, except for winter for in theallperiod from 1945forthrough has decreased seasons, except winter 2008. for the period from 1945 through 2008. Table Table7.7.Long-term Long-termmean meanconcentration concentrationofofmajor majorions ionsininthe theSelenge SelengeRiverand Riveranditsitstributaries tributaries Rivers TDS Ca2+ Mg2+ Na++K+ mg/l mg/l mg/l mg/l HCO3mg/l SO4-mg/l Clmg/l Selenge 253.7 34.9 10.3 15.6 1578 18.6 5.9 Ider 162.2 25.2 6.8 14.0 104.6 14.1 7.9 Delgermuren 254.5 39.3 9.2 10.0 170.0 17.9 3.6 Eg 234.6 332 11.4 9.8 160.0 12.9 3.9 Orkhon 226.1 26.6 8.9 25.7 142.7 18.5 10.8 Eree 128.9 14.5 4.8 10.5 75.7 10.8 4.4 Data source:Central Laboratory for Environment and Meteorology Table 8. Long-term mean concentrations of chemical pollutants in the Selenge and its tributaries Table 8. Long-term mean concentrations of chemical pollutants in the Selenge and its tributaries Rivers NH4 NO3 PO4 Si Permanganate Value BOD O2 9.6 Selenge 0.190 0.265 0.037 5.9 3.2 2.1 Ider 0.170 0.280 0.015 4.1 3.2 1.5 Delgermuren 0.110 0.150 0.021 2.6 2.7 2.2 Eg 0.107 0.190 0.024 2.9 3.2 1.9 8.7 Hardness as Ca 2++Mg 2+ pH 2.4 7.8 1.9 7.5 2.8 7.7 2.4 7.7 Orkhon 0.247 0.357 0.040 5.8 3.5 2.7 10.4 2.1 7.6 Eree 0.224 0.311 0.030 6.7 4.0 1.5 11.1 2.6 7.7 Data source: Central Laboratory for Environment and Meteorology The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. Pollution threats and hotspots assessment 21 21 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 2.3. Water quality 2.3. Water quality The Selenge River’s water quality is generally The SelengetoRiver’s waterThe quality is generally considered be good. long-term mean considered to be good. The long-term mean concentrations main water quality parameters concentrations waterand quality parameters (such as BOD main and DO) concentrations (such as BOD and DO) and concentrations of chemical pollutants, ammonium-nitrogen, of chemical pollutants, ammonium-nitrogen, nitrate-nitrogen, orthophosphate and permannitrate-nitrogen, orthophosphate and ganate do not exceed the respective Maximum permanganate do not exceed the respective Acceptable Concentrations (Table 8). Maximum Acceptable Concentrations (Table 8). The pollution in in the the Selenge Selenge River, River, The nutrient nutrient pollution which cause of of water water which isis generally generally the the primary primary cause quality impairments in rivers and lakes, is very quality impairments in rivers and lakes, is very low. orthophosphate, as low.Low Lowconcentrations concentrationsofof orthophosphate, shown in Table 8, indicate that there no evias shown in Table 8, indicate thatisthere is dent risk of water quality impairments caused nothe evident risk of of chemical water quality impairments by presence fertilizers, polluted caused by the presence of chemical fertilizers, storm water run-off, and poorly treated sewage polluted water run-off, and poorly or leaking storm septic systems. treated sewage or leaking septic systems. With respect to hydrobiology and ecological With respect to hydrobiology and ecological water thethe Selenge RiverRiver and its tribuwater quality, quality,of of Selenge and its taries are also to be in tributaries areconsidered also considered to good be incondigood tions. The number of Ephemeroptera, Plecopconditions. The number of Ephemeroptera, tera, Trichoptera (EPT) individuals in the Plecoptera, Trichoptera (EPT) found individuals Selenge River its some tributaries aresome given found in theand Selenge River and its in Table 9. The summary of macroinvertebrates tributaries are given in Table 9. The summary macroinvertebrates isofshown in Table 10. is shown in Table 10. Table9.9.Ephemeroptera, Ephemeroptera,Plecoptera, Plecoptera,Trichoptera Trichopteraindividuals individualsfound foundininthe theSelenge Selengeriver riverand anditsitstributaries tributaries Table № 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Stations Selbe-Sanzai Selenge-Khutag Selenge-Sukhbaatar Selenge-Khyalganat Kharaa-Baruunkharaa Kharaa-Darkhan Achuut-Bulgan Zuunturuu-Bulgan Ider-Tosontsengel Tuul-Lun Tuul-Altanbulag Tuul-Ulaanbaatar Terelj-Terelj Urdtamit-Tsetserleg Chuluut-Chuluut Shariyngol-Jibsnii stants Eg-Khantai Total 2005 4 2 3 7 5 12 4 5 6 0 2 12 5 10 7 3 5 112 2006 6 4 22 11 8 6 6 4 2 0 5 20 11 7 6 2 6 140 2007 8 5 11 13 9 3 5 2 11 2 0 8 3 4 7 4 17 124 2008 6 16 5 11 31 10 3 4 10 0 3 4 18 18 3 4 18 168 2009 13 6 4 25 34 12 6 5 2 47 6 40 5 9 4 5 5 294 2010 0 0 77 0 0 1 0 0 0 0 38 66 1 0 0 4 0 276 Data source: Institute of Meteorology, Hydrology and Environment In order to evaluate the quality of the Selenge River water, flowingthe outquality of Mongolia at the In order to evaluate of the Selenge Mongolia-Russia border, dataatat the the River water flowing outmonitoring of Mongolia Mongolia-Russia border, monitoring data at outlet of the Sukhbaatar station on the Selenge the outlet the Sukhbaatar stationofon the River were of assessed for the period 2001Selenge River were assessed for the period 2010. The assessment is based on the Water of 2001-2010. Theparameters assessmentofis five based on Quality Index and major the Water Quality Index and parameters of five major chemical pollutants, described in chemical pollutants, described in section 1.3.3, using all observed/sampled between 2001 section 1.3.3, using all data observed/sampled and at the2001 station. to the WQI data2010 between andAccording 2010 at the station. According to the WQI based on these based on these parameters, the Selenge River parameters, Selenge Riverstation water appears quality water quality the at the Sukhbaatar at the Sukhbaatar station appears from from very clean to clean. The results are very preclean to The results are presented in sented in clean. Figure 3. Figure 3. Quality of the Kharaa River Basin, Mongolia: 22 The intellectual property rights belong to UNOPS and UNDP, the information should not beWater used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: 22 project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" In addition, the water quality of the Selenge River has been by the of Biotic at In addition, theassessed water quality the Index Selenge three sites—namely, Khutag, Khyalganat and River has been assessed by the Biotic Index at Sukhbaatar—for the period of 2005-2010. The three sites—namely, Khutag, Khyalganat and results are presented Figureof4.2005-2010. The water Sukhbaatar—for the in period The results presented 4. The quality of theare Selenge River in at Figure these sites apwater quality of the Selenge River at these pears to be also clean. Populations of pollutant sensitive insectstowere found at these sampling sites appears be also clean. Populations sites for the period of 2005 and 2010, indicatof pollutant sensitive insects were found at ing therefore thatsites the good quality of the these sampling for the period of water 2005 conditions. and 2010, indicating therefore that the good quality of the water conditions. Table 10. Summary analysis of Aquatic Macroinvertebrate at different stations in the Selenge River and its № Metric (by category) Chuluut Eg Sharyingol KharaaBaruunkha KharaaDarkhan Orkhonn Terelj Uliastai Selbe Tuul-UB Tuul-lun Table 10. Summary analysis of Aquatic Macroinvertebrate at different stations in the Selenge River and its tributaries (2005-2010) tributaries (2005-2010) 1 Total Taxa Richness 13 5 10 11 21 12 10 18 13 15 7 10 14 7 2 Taxa Richness of EPT 9 4 5 6 12 6 10 9 9 8 12 6 10 7 7 11 6 3 Simpson's Diversity Index Simpson's Reciprocal Index Total individuals of Taxa Individuals of EPT Taxa Individuals of Ephemeroptera Individuals of Plecoptera Individuals of Trichoptera 0.9 0.6 0.8 0.7 0.8 0.8 0.9 0.8 0.8 0.8 0.9 0.7 0.7 0.7 0.8 0.8 0.8 9.4 2.6 5.1 3 6 6.4 7.1 5.4 4.6 5.5 6.7 3.7 3 3.3 6.3 4.3 6 54 343 46 276 178 60 115 196 200 79 233 146 88 113 51 144 13 34 342 22 260 133 50 97 169 188 77 170 45 74 113 36 125 10 17 4 10 226 110 21 38 109 136 41 132 29 61 65 27 71 7 15 338 6 33 16 11 1 0 28 24 21 13 9 43 3 26 1 2 0 6 1 7 18 58 60 24 12 17 3 4 5 6 28 2 10 Dominant Taxon 18.5 53.1 37 43.5 33.1 26.7 18.3 32.1 38.5 31.6 25.8 48.6 56.8 41.6 31.4 43.1 38.5 11 EPT Taxa 69.2 80 50 54.5 57.1 66.7 90.9 64.3 75 80 66.7 46.2 66.7 100 70 78.6 85.7 12 EPT Individuals 63 99.7 47.8 94.2 74.7 83.3 84.3 86.2 94 97.5 73 30.8 84.1 100 70.6 86.8 76.9 13 Chironomidae 14.8 0 2.2 0 0.6 6.7 0 2.6 3 0 2.1 0 1.1 0 0 0 0 4 5 6 7 8 9 Zuunturuu Achuut SelengeKhyalgana t Urdtamir SelengeKhutag Ider Selenge River tributaries Richness and Diversity 9 11 14 Composition and Evenness Tolerance/Intolerance 14 Sensitive Organisms 45.3 100 67.5 96.3 61 78.4 96.4 54.3 62.1 48.5 71.1 84.6 83.2 68.2 72.4 63.8 37 15 Moderate-Sensitive Organisms Tolerant Organisms 24.5 - 30 2.1 26.3 14.8 2.7 33.4 11.1 38 10.9 13.9 10.7 27.1 7.9 32.4 51.1 30.2 - 2.5 1.6 12.7 6.8 0.9 12.3 26.8 13.5 18 1.5 6.1 4.8 19.7 3.8 11.9 16 Data source: Institute of Meteorology, Hydrology and Environment Figure 3. Water quality index at the Sukhbaatar of the Figure 3. Water quality index Selenge Riverat the Sukhbaatar of the Selenge River Pollution threats and hotspots assessment Figure 4. Biotic Index results at three sites of the Figure 4. Biotic Index results at three sites of the Selenge River Selenge River 23 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment 23 project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 24 project. 24 Water Quality ofof the Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" WaterQuality Quality 3.3.Water Assessmentof ofthe the Assessment Kharaa KharaaRiver RiverBasin Basin The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. Pollution threats and hotspots assessment ©Batimaa P., 2013 25 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The Kharaa River Basin is shared among three administrative regions, called aimags (equivalent to provinces)—namely, Selenge aimag, Tuv aimag and Darkhan-Uul aimag. The basin also includes the rapidly-growing industrial city of Darkhan, which is the third largest city with 74,738 inhabitants as of 2010 (NSO, 2010). The entire population of the Kharaa River Basin is about 133,000. The Kharaa River Basin is under increasing pressure from rapid urbanization, rising water demand and climate change. The upper basin is in a relatively pristine state and has experienced minimal anthropogenic impacts. The lower basin is characterized by diverse economic activities such as industry, agriculture and livestock breeding, which may potentially have significant impacts on the quantity and quality of water resources of the basin. Furthermore, the basin provides drinking water for the rapidly-growing Darkhan City, which water supplies largely rely on alluvial aquifers containing shallowdepth groundwater, and the inhabitants of small human settlements in the basin. Hence, growing pressures from climate change and anthropogenic activities on the Kharaa River (Figure 5) makes the basin an ideal example of river basins under a spectrum of climatic and anthropogenic pressures. 3.1. Hydrology and hydrogeology 3.1.1. Surface water The Kharaa River Basin is located in northern Mongolia, not far away from the capital Ulaanbaatar, between latitudes 47°53’ and 49°38’N and longitudes 105°19’ and 107°22’E. The catchment area of the basin is about 15,050 square kilometers (Battsetseg, 2011). The lowest elevation is about 654 meters a.s.l. and is found near the outlet of the catchment, whereas the highest point is about 2668 meters a.s.l. and is located in the vicinity of the Asralt Khairhan (2799 meters a.s.l.)—the highest peak of the Khentii Mountains range and the area of the headwaters of some important Mongolian rivers. In around 60 percent of the basin area, the elevation ranges between 900 and 1300 meters a.s.l. The average altitude of the whole catchment is 1,167 meters (Figure 6). At 291 km in length, the Kharaa River originates in the mountains north of Ulaanbaatar and passes through Selenge and Darkhan-Uul provinces in central northern Mongolia before emptying into the Orkhon River. The annual mean discharge ranged from 3.84 to 26.3 m3/s between 1991 and 2010 (Battsetseg, 2011). Together with the Orkhon River, the Kharaa River discharges to the Selenge River Basin, which is the main catchment region of Lake Baikal. The upper course of the Kharaa River is characterized by mid- to high mountain ranges of the Khentii Mountains, with steep valley slopes and rises. The summit region Asralt Khairhan, which peak altitude is 2799 meters a.s.l., is dominated by denudated, flattened and periglacially transformed mountains (MoMo, 2009). In the middle reaches, the relief is dominated by broad valleys with significant terrace levels and hilly uplands with gentle slopes, as well as remnants of denudated rocks. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 26 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" ©Batimaa, P., 2013 Figure The Kharaa Kharaa River River at at Baruunkharaa Baruunkharaa hydrological hydrological gauging gauging station station (21 (21 July July 2012) 2012) Figure 5. 5. The Figure The Kharaa Kharaa River River Basin water quality quality monitoring monitoring sites sites Figure 6. 6. The Basin and and water The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 27 27 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" In the the Kharaa River River flows In this thisriver riversection, section, Kharaa flows through wide floodplain has a through a widea floodplain and hasand a meanmeandering channel 25 meters dering channel of 10 of to10 25tometers widewide and and from 0.2 to 2 meters deep. Upstream from 0.2 to 2 meters deep. Upstream of the of the city of Zuunkharaa, the into riverseveral splits city of Zuunkharaa, the river splits into several small and shallow branches. small and shallow branches. The lower reaches The lower reachesstation from the gauging station from the gauging at Baruunkharaa to at Baruunkharaa to the confluence of the the confluence of the Kharaa River with the Kharaa River with the Orkhon River is an Orkhon River is an open steppe and lowland open steppe and lowland landscape. In the landscape. In Kharaa the lowlands, the Kharaa River lowlands, the River flows as a natural meandering rivermeandering system withriver ancient cut-off flows as a natural system with meanders in some places. ancient cut-off meanders in some places. Channelization was was conducted conducted only only in Channelization in some some very limited river areas. Therefore, the very limited river areas. Therefore, the floodfloodplain meadow still serves its natural plain meadow still serves its natural retention retention function, a situation which is function, a situation which is important for naimportant for nature conservation. ture conservation. 3.1.2. Groundwater 3.1.2. Groundwater The Kharaa River Basin is mainly characterized by unconfined alluvialcharacteraquifers. The Kharaa River Basin is mainly The unconfined groundwater aquifers ized by unconfined alluvial aquifers. The are uncharacterized by alluvial sandareand gravel confined groundwater aquifers characterwithby interlaced sandy (Batsukh, 2007). ized alluvial sand andloam gravel with interlaced Due to the porous media, the conductivity sandy loam (Batsukh, 2007). Due to the porous of the aquifer is high, mainly 10 is to high, 100 media, the conductivity of thefrom aquifer m/day and partly up to 300m/day. The main mainly from 10 to 100 m/day and partly up water bearing stratum extends with a width of to 300m/day. The main water bearing stratum 10 to 20 kilometers along the Kharaa River, extends width ofa 10 to 20 kilometers reaches with near aDarkhan thickness of 70 m, along the Kharaa River, reaches Darkhan and is divided up into differentnear layers. The a thickness of 70 m, and is divided up into dif- groundwater recharge from precipitation is very low in the Darkhan area. recharge from ferent layers. The groundwater The recharge depends inflowarea. of precipitation is very low inon thethe Darkhan groundwater from aquifers of the upper The recharge depends on the inflow of groundcatchment area where the precipitation and water from aquifers of the upper catchment groundwater infiltration are much higher. area where the precipitation and groundwater infiltration are much higher. The “exploitable groundwater resources” of the Kharaa River Basin has been estimated at The “exploitable groundwater resources” of 182 million cubic meters, as shown in Table the Kharaa River Basin has been estimated at 11 (Jadambaa, 2012). 182 million cubic meters, as shown in Table 11 (Jadambaa, 2012). Table 11. Exploitable groundwater resources of the Kharaa River Basin Table 11.Exploitable groundwater resources of the Kharaa River Basin Area (sq.km..) No of aquifers 1 3 7 8 11 12 13 Total 250 3121 46 67 4719 234 9026 17463 Resources per unit area, m3/sec per sq.km. 315000 31500 5203 5203 520 5203 94.6 Total resources per unit area, mln m3/year per sq.km. 79 98 0.24 0.35 2 1 1 182 Data source: Jadambaa, 2012 3.2. Hydrochemistry 3.2. Hydrochemistry In general, concentrations of the chemical composition of the headwaters of the Kharaa In general, concentrations of the chemical River are near the natural background composition of increase the headwaters the Kharaa conditions and towardsofdownstream River are near the natural background conditions and increase towards downstream along along the river. Slightly higher concentrations were observed after snow melting and heavy the river. Slightly higher concentrations were rainy periods and dry years (Batimaa, 1998). observed after snow melting and heavy rainy periods and dry years (Batimaa, 1998). The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 28 project. 28 Water Quality ofof the Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 3.2.1. Major 3.2.1. Majorions ions The monthly mean concentrations of total The monthlysalts, meanorconcentrations of total disdissolved mineralization, which 2+ + + 2+ solved the sum Mg is , HCO -, is the salts, sum or ofmineralization, Ca , Na +K ,which 3 2+ + + 2+ 22of , Na +K , Mg , HCO -, SO and Cl and Clions, in the Kharaa River vary SOCa 4 3 4 ions, in the Kharaa River vary between 162.2 between 162.2 and 335.7 mg/l and increase and 335.7 mg/land in the downstream are in downstream areincrease as along river length as along12). theThe riverconcentrations length (Table 12). con(Table also The increase centrations also increase during snow melting during snow melting periods. periods. Table 12. Annual distribution of average concentrations of total dissolved salts, or mineralization Table 12. Annual distribution of average concentrations of total dissolved salts, or mineralization Stations Zuunkharaa (upper) Zuunkharaa (down) Darkhan (upper) Darkhan (down) Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec - - - 199.2 - 189.4 166.2 168.4 213.0 188.3 214.8 - - - - 248.4 - 189.3 174.2 176.9 203.7 208.6 223.7 - 218.8 224.3 256.3 262.2 298.3 283.8 269.1 245.4 229.1 237.4 261.9 197.9 264.7 290.6 268.6 275.5 335.7 294.8 273.6 284.4 270.1 270.1 300.6 253.7 Data source: Central Laboratory for Environment and Meteorology In cases, the calcium and bicarIn most mostofofthethe cases, the calcium and bonate are the dominant ions at all monitoring bicarbonate are the dominant ions at all stations of thestations Kharaa of River. to the monitoring theAccording Kharaa River. Piper diagramtoandthe classifications of O.A. and AleAccording Piper diagram classifications of O.ofA.theAlekin, in order a vast kin, in a vast majority cases the of 2+ majority of of thecations cases is theCaorder of+abundance abundance >Na +K+>Mg2+ 2+ + 2+ >Na++Kof >Mg and theof cations and the orderisof Ca abundance anions is HCO 3 2order >Cl of abundance is upstream HCO3-> . This orderofis anions clearer in >SO 4 This order is clearer in upstream SO42->Cl areas, as .observed at the Zuunkharaa upper monitoring station on the Zuunkharaa Kharaa River upper (Figure areas, as observed at the 7). In the downstream from Darkhan city, the monitoring station on the Kharaa River order of 7). abundance of anions isfrom the same as in (Figure In the downstream Darkhan the station, while the order of abuncity,upstream the order of abundance of anions is the same as in the upstream station, while dance of anions becomes considerably unstathe as order of abundance of anions ble, observed at the Darkhan downbecomes monitorconsiderably unstable, as observed at the ing station on the river (Figure 8). Darkhan down monitoring station on the river (Figure 8). Figure salts and and cations cations and and anions anions Figure7. 7. Relationship Relationship between between total total dissolved dissolved salts (Kharaa-Zuunkharaa (upper)) (upper)) (Kharaa-Zuunkharaa The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 29 29 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure cations and and anions anions Figure8. 8. Relationship Relationship between between total total dissolved dissolved salts and cations (Kharaa-Darkhan (down)) (Kharaa-Darkhan (down)) Theoverall overall assessment the chemical The assessment of theofchemical compocomposition hasgood shown good chemical sition has shown chemical conditions at conditions at all sampling sites on the Kharaa all sampling sites on the Kharaa River. River. The Kharaa River water is moderately hard and ThepHKharaa water moderately hard its varies River between 6.9isand 8.2. Chloride and its pH varies between 6.9 and 8.2. concentrations appear to be higher in downChloride concentrations appear to be higher stream areas compared to in the upstream in downstream areas compared to in the region near the Zuunkharaa upper sampling upstream region near the Zuunkharaa upper point. Higher levels of chloride be indicasampling point. Higher levels ofmay chloride may tive of possibleofwater pollution. be indicative possible water pollution. The results results of the MoMo The MoMo (2009) (2009) study study show show very similar similarresults resultsofofthe thechemical chemicalanalysis analysis very of of the Kharaa River water quality. the Kharaa River water quality. In general, general, the the quality In quality of of surface surface waters waters in in the the mountainous region of the Kharaa River Basin mountainous region of the Kharaa River Basin is good with low nutrient concentrations, is good with low nutrient concentrations, tototal solids concentrations ranging from 17 tal solids concentrations ranging from 17 to 60 to 60 mg/l, very low chloride concentrations mg/l, very low chloride concentrations between 2 and 4 mg/l, and heavybetween metal 2concentrations and 4 mg/l, and heavybelow metal concentrations almost the detection almost the detection limits. However, in limits. below However, in the middle and lower the middle and lower reaches there are the nureaches there are the nutrient concentrations concentrations tend tothe increase, whereas Monthly concentrations of major ions, ions, trient Monthly mean mean concentrations of major tend to increase, whereas total dissolved total dissolved solids are as hardness monitoring stations are the hardnessand andpH pHatatallall monitoring stations solids concentrations areconcentrations as high as 100-340 are given in Table mg/lasand the chloride range high 100-340 mg/l andconcentrations the chloride concengiven in Table 13. 13. betweenrange 10 tobetween 17 mg/l.10 to 17 mg/l. trations 3.2.2. Dissolved oxygen 3.2.2. Dissolved oxygen Dissolved oxygen is absolutely essential for the survival of all aquatic organisms-not only Dissolved is absolutely such essential the fish, but oxygen also invertebrates as for crabs, survival of all aquatic organisms—not only fish, clams, zooplankton, etc. Moreover, oxygen but alsoa invertebrates such as water crabs, quality clams, affects vast number of other indicators inetc. terms of notoxygen only physical zooplankton, Moreover, affects a chemical andofbiological parameters of water vast number other water quality indicators quality, of the and esthetic in terms ofbut notalso onlyindicators physical chemical bioquality of river’s water like the odor, clarity logical parameters of water quality, but also inand taste. Consequently, oxygen is perhaps dicators of the esthetic quality of river’s water the most well-established indicator of water like the odor, clarity and taste. Consequently, quality.is The levelthe ofmost dissolved oxygen isina oxygen perhaps well-established dicator of water quality. The level of dissolved much more important parameter to measure water quality than faecal coliform (Hunt et oxygen is a much more important parameter al, 2000). to measure water quality than faecal coliform (Hunt et al, 2000).oxygen concentrations in The dissolved the Kharaa River water are monitored only at thedissolved two sampling of the Darkhan The oxygenpoints concentrations in the monitoring Kharaa River station: water areDarkhan monitoredupper only atand the Darkhan down. The dissolved oxygen two sampling points of the Darkhan moniconcentration is not upper measured at the toring station: Darkhan and Darkhan Zuunkharaa monitoring station. down. The dissolved oxygen concentration is not measured at the Zuunkharaa monitoring station. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 30 project. 30 Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table 13.Monthly mean concentrations of major ions of the Kharaa River Table 13. Monthly mean concentrations of major ions of the Kharaa River Months Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Zuunkharaa upper 2+ Ca Mg2+ Na+ +K+ HCO3 - - - - 30.4 9.4 - 27.5 9.2 25.6 7.3 25.3 7.0 23.7 6.0 27.9 8.4 32.0 8.9 - - - - 7.5 - 8.2 8.2 8.0 24.2 8.8 11.4 - - - - 133.5 - 129.4 119.8 114.8 142.8 127.0 142.7 - SO42- - - - 13.6 - 10.5 7.9 8.1 11.2 11.7 15.6 - - Cl - - - 4.2 - 3.9 3.6 4.2 5.1 4.0 3.9 - Hardness - - - 2.3 - 2.1 1.9 1.8 1.7 2.1 2.3 - pH - - - 7.4 - 7.3 7.4 7.0 6.9 7.3 7.2 - Zuunkharaa down Ca2+ - - - 33.6 - 26.7 27.2 27.5 25.6 29.6 33.2 - - - - 11.1 - 7.9 6.1 8.0 6.5 9.8 8.6 - Na +K - - - 9.9 - 9.8 7.1 7.2 7.4 9.2 7.6 - HCO3- - - - 170.7 - 122.4 111.8 117.4 106.8 133.0 133.5 - - - - 17.9 - 4.9 6.3 6.1 5.0 7.4 11.2 - Cl - - - 7.7 - 4.9 6.3 6.1 5.0 7.4 11.2 - Hardness - - - 2.6 - 2.0 1.8 2.1 1.8 2.3 2.4 - pH - - - 7.3 - 7.2 7.3 7.0 7.4 7.3 7.1 - 2+ Mg + SO4 + 2- - Darkhan Upper 2+ Ca 33.5 32.3 33.4 31.8 31.2 30.5 32.4 29.8 31.1 31.0 32.5 31.9 Mg2+ 11.6 14.6 14.7 12.8 12.9 12.5 13.0 10.5 10.5 12.6 12.9 12.6 27.7 30.1 24.7 23.9 27.2 28.2 23.3 25.6 24.9 26.4 29.4 25.7 182.2 190.8 166.8 164.0 169.8 157.1 160.3 162.1 159.7 161.4 182.7 170.2 + + Na +K HCO3 SO4 - 2- 35.5 28.6 34.6 31.9 35.7 30.4 34.9 28.8 32.8 35.5 31.4 26.2 Cl- 8.2 9.2 8.8 7.5 9.6 8.2 11.5 9.3 6.5 14.0 9.4 7.7 Hardness 2.7 2.8 2.8 2.6 2.7 2.7 2.7 2.4 2.6 2.7 2.7 2.7 pH 8.1 7.8 8.1 8.0 8.1 8.0 8.1 8.0 8.1 8.2 8.2 29.8 34.5 29.0 24.6 31.0 31.4 30.3 27.6 26.7 29.6 34.3 34.6 11.4 12.1 11.9 9.6 12.3 12.1 12.8 11.1 10.0 13.2 12.4 13.4 21.8 27.4 18.0 18.0 22.0 23.7 21.8 20.2 21.7 29.6 33.1 27.1 8.0 Darkhan down Ca2+ 2+ Mg + + Na +K HCO3 - 141.7 171.9 154.3 131.1 153.2 154.8 163.7 147.3 146.8 164.8 182.5 173.2 SO42- 28.9 31.3 23.6 26.7 30.4 29.8 29.2 27.1 30.8 34.1 36.8 29.9 - 13.7 15.8 11.7 8.6 11.4 9.1 12.9 8.4 9.1 13.2 11.7 13.4 Hardness 2.4 2.7 2.3 2.0 2.3 2.6 2.4 2.1 2.1 2.7 2.7 2.8 pH 8.1 8.2 7.9 8.1 8.1 8.1 8.0 8.0 8.2 8.2 8.2 Cl 8.1 Data source: Central Laboratory for Environment and Meteorology The dissolved oxygen concentrations at the and minimum concentrations of dissolved The dissolved oxygen concentrations at the mum concentrations of dissolved oxygen are Darkhan sampling points vary from 3.8 to oxygen are given below in Table 14. Darkhan sampling points vary from 3.8 to 14.0 given below in Table 14. 14.0 mg/l. The monthly mean, maximum mg/l. The monthly mean, maximum and mini- The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 31 31 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table Table14. 14.Annual Annualdistribution distributionof ofdissolved dissolvedoxygen oxygenconcentrations concentrations Months Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Darkhan upper Average 9.12 8.83 9.46 10.63 9.25 8.87 8.74 9.06 10.04 11.19 10.35 10.00 Max 12.16 12.10 12.00 18.80 14.00 11.60 11.20 12.40 13.60 13.40 13.60 12.09 Min 6.00 6.10 6.66 7.37 6.14 5.80 6.80 6.10 8.00 8.56 8.10 8.28 Darkhan down Average 8.47 9.89 9.89 9.43 8.82 8.93 8.21 8.87 9.50 10.96 9.91 9.59 Max 11.70 14.80 14.80 12.15 10.90 12.43 10.70 12.60 12.72 14.90 12.64 12.00 Min 6.33 7.80 7.80 4.03 6.00 6.40 6.10 1.20 5.40 5.44 5.21 5.80 Data source: Central Laboratory for Environment and Meteorology The regard to the waterwater qualThe trend trendwith with regard to river’s the river’s ity assessed for dissolved oxygen conditions quality assessed for dissolved oxygen over a twenty-five period is shown in Figconditions over ayears twenty-five years period is ure 9. Between and 2011, there no shown in Figure1986 9. Between 1986 andwas 2011, there was significant no statistically significant statistically trend in dissolvedtrend oxyin dissolved based the monthly gen, based on oxygen, the monthly spotonmeasurements. spotthe measurements. Ondissolved the other hand,conthe On other hand, the oxygen dissolved oxygen concentrations quitea year, vary centrations quite vary seasonally within seasonally within a year, as shown in Table as shown in Table 14. No clear reason can be 14. No reason change, can be while foundvariations for this found forclear this seasonal seasonal change, while variations from year from year to year can be caused by a variety of to year can be caused by a variety of factors, factors, such as the weather conditions precedsuch as the weather conditions preced¬ing ing sample collection,water water temperature, temperature, the the sample collection, other quality parameters (e.g., nutrients), other water water quality parameters (e.g., and the time of sample collection. In order to nutrients), and the time of sample collection. look assess any long-term in dissolved In order to look assess anychanges long-term changes oxygen concentrations and their in dissolved oxygen concentrations causes, and theira more continuous dissolved oxycauses, a more monitoring continuousofmonitoring of gen is needed to understand the daily fluctuadissolved oxygen is needed to understand tions and how it relatesand to weather the daily fluctuations how it conditions relates to and the quality of the and river’sthe water. weather conditions quality of the river’s water. The Mongolian National Standard for Water The Mongolian National StandardMNS for Water Quality of the Aquatic Environment 4586Quality of Maximum the Aquatic Environment MNS 98 sets the Acceptable Concentra458698 sets the Maximum Acceptable tion of dissolved oxygen at 4-6 mg/l. AccordConcentration of dissolved 4-6 ing to the observed data, thereoxygen were noat cases mg/l. According to the observed data, there when the dissolved oxygen concentrations fell were no cases when the dissolved oxygen below 4 mg/lin the upper stream of the Kharaa concentrations fell below 4 mg/l in the upper River. dissolved streamSlightly of thehigher Kharaa River. oxygen Slightlyconcenhigher trations, belowconcentrations, the upper limitbut of 6below mg/l, dissolvedbut oxygen were observed in very few cases downstream the upper limit of 6 mg/l, were observed in from citydownstream (Figure9). from Darkhan very Darkhan few cases city (Figure 9). Figure Figure 9. 9. Dissolved Dissolved Oxygen Oxygen concentration concentration trends trends of of the the Kharaa Kharaa River River for for the the period period 1985-2010 1985-2010 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 32 project. 32 Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 3.2.3. Biological Oxygen Demand 3.2.3. Biological Oxygen Demand The biological oxygen demand (BOD) is one of Thechemical biological oxygen demand (BOD)organic is one the parameters that measure of the chemical parameters that measure pollution in rivers and streams. organic pollution in rivers and streams. The BOD of the Kharaa River is monitored The BOD of the Kharaa River is monitored only at the two sampling points of the Darkhan only at the two sampling points of the monitoring station. The observed data for the Darkhan monitoring station. The observed period from the 1985-2010 in most of data for period show fromthat1985-2010 the cases, show thattheinBOD mostconcentrations of the cases,were the below BOD the Maximum Acceptable Concentration of 5 concentrations were below the Maximum mg/l (as set in the national water quality stan- Acceptable Concentration of 5 mg/l (as set in theMNS national water indicating quality standard dard 4586:98), that theMNS river 4586:98), indicating that the river water is clean. However, it should be water noted is clean. noted that that duringHowever, summer it theshould BOD be concentrations during summer the BOD concentrations occasionally exceeded the Maximum Acceptoccasionally exceeded the Maximum able Concentration in both sampling points Acceptable Concentration in both sampling (Figure10). This 10). may indicate thatindicate organic that polpoints (Figure This may lutants, urban and industrial organic originating pollutants,from originating from urban area of Darkhan city, and livestock wastes enand industrial area of Darkhan city, and ter the river with surface washing during heavy livestock wastes enter the river with surface rainfall events. washing during heavy rainfall events. Figure 10. Biological oxygen demand concentration trend of the Kharaa River near Darkhan city for the Figure 10. Biological oxygen demand concentration trend of the Kharaa River near Darkhan city for the period 1985-2010 period 1985-2010 As Figure 10, 10, there there isisno noincreasing, increasing, As shown shown in in Figure or decreasing, trends in BOD concentrations at decreasing, trends in BOD concentrations both sampling points.points. However, the concenat both sampling However, the concentrations downstream from the city are trations downstream from the city are notice- ably higher higher than those This may be noticeably thanupstream. those upstream. This caused by the discharge of Darkhan Wastewamay be caused by the discharge of Darkhan ter TreatmentTreatment Plant effluents. Wastewater Plant effluents. 3.2.4. Nutrients 3.2.4. Nutrients In Mongolia, the level of nutrients in rivers is generally influenced natural such in as In Mongolia, the bylevel of factors nutrients catchment geology, rainfall and river patrivers is generally influenced by flow natural terns. main source of nutrients urban factorsThe such as catchment geology,inrainfall and river flow patterns. The whereas main source areas is municipal wastewater, agriof nutrients in and urban areas manure is municipal cultural fertilizers livestock are the wastewater, whereas agricultural fertilizers major non-point-sources of nitrogen and phosand livestock manure are the major phorus in rural areas. Usually nutrients connon-point sources nitrogen andwater phosphorus centrations increaseofduring high periods in rural areas. Usually nutrients concentrations due to snowmelting and heavy rainfalls. This increase during high water periods due to is mainly due to Mongolia’s pastoral livestock snowmelting and heavy rainfalls. This is herding practices, as herders live along a river mainly due to Mongolia’s pastoral livestock bank. Traditionally, and streams are used herding practices, rivers as herders live along a as sources livestock water.rivers This leads to fecal river bank.ofTraditionally, and streams contamination and direct nutrient inputs the are used as sources of livestock water.toThis leads to fecal contamination and direct river water in warm seasons because animal manure washed into river riverswater with showmelt nutrient isinputs to the in warm and rainfall runoff (Batimaa, 1998). is washed seasons because animal manure into rivers with showmelt and rainfall runoff (Batimaa,mean 1998). Monthly concentrations of ammoniumnitrogen (NH4-N) range between 0.09 and 0.38 Monthly mean mg/, while the concentrations concentrations of of ammoniumnitrate-nitronitrogen (NH4-N) range between 0.09 gen (NO3-N) vary from 0.01 to 0.84 mg/l for the and 0.38 mg/, while the concentrations of period from 1985 to 2010. The concentrations nitrate-nitro¬gen (NO3-N) vary from 0.01 to of phosphate (PO4-P) are in the range from 0.01 0.84 mg/l for the period from 1985 to 2010. to 0.21 mg/l. The phosphate concentrations in The concentrations of phosphate (PO4-P) the Kharaa River were much lower than the niare in the range from 0.01 to 0.21 mg/l. The trogen concentrations. phosphate concentrations in the Kharaa River were much lower than the ni¬trogen concentrations. 33the The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 33 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The nutrient concentrations in the Kharaa The nutrient concentrations in the Kharaa River River water usually increased during spring water usually increased during spring and sumand summer time (Table 15) and sometimes mer time (Table 15) and sometimes exceeded exceeded the Maximum Acceptable the Maximum Acceptable Concentrations by Concentrations by the order of 2 to 3 times. However, the number of cases, in which the the order of 2 to 3 times. However, the number nutrient concentrations exceeded the MAC of cases, in which less the nutrient concentrations levels represents than 5 percent of all exceeded the MAC levels represents less than samples. 5 percent of all samples. Table15. 15.Monthly Monthlymean meanconcentrations concentrationsofofammonium ammoniumofofthe theKharaa KharaaRiver River Table Stations Jan Feb Mar Apr May Jun Jul Nov Dec NH4-N, (MAC is 0.5 mg/l) 0.32 0.20 0.14 0.28 0.34 0.11 0.19 - Zuunkharaa (upper) Zuunkharaa 0.38 0.32 0.21 (upper) Darkhan 0.09 0.10 0.10 0.25 0.39 0.24 0.22 (upper) Darkhan 0.13 0.09 0.09 0.45 0.29 0.18 0.22 (down) NO3-N, (MAC is 10 mg/l) Zuunkharaa 0.35 0.47 0.35 (upper) Zuunkharaa 0.25 0.28 0.84 (upper) Darkhan 0.17 0.01 0.15 0.19 0.17 0.25 0.24 (upper) Darkhan 0.50 0.01 0.56 0.35 0.34 0.49 0.80 (down) PO4-P, (MAC is 0.1 mg/l) Zuunkharaa 0.05 0.06 0.03 (upper) Zuunkharaa 0.07 0.03 0.06 (upper) Darkhan 0.04 0.04 0.04 0.06 0.03 0.03 0.02 (upper) Darkhan 0.01 0.04 0.04 0.09 0.07 0.04 0.06 (down) Aug Sep Oct 0.20 0.13 0.26 0.17 - 0.17 0.15 0.12 0.12 0.06 0.20 0.11 0.15 0.18 0.12 0.75 0.15 0.37 0.26 - 0.67 0.56 0.24 0.59 - 0.14 0.10 0.13 0.17 0.24 0.26 0.21 0.34 0.36 0.76 0.04 0.06 0.02 0.03 - 0.04 0.10 0.10 0.04 - 0.03 0.02 0.02 0.02 0.03 0.04 0.05 0.05 0.21 0.06 Data source: Central Laboratory for Environment and Meteorology Mostdomestic domesticand and industrial wastewaters Most industrial wastewaters have have much higher concentrations of much higher concentrations of ammonia, niammonia, nitrate, and thandoes. the trate, and phosphate thanphosphate the river water river water does. The Darkhan Wastewater The Darkhan Wastewater Treatment Plant, Treatment Plant, which is located in the study which is located in the study area, is a major area, is a major source of nutrient pollution source of nutrient pollution in the4.1.1). KharaaThus, River in the Kharaa River (see Section (see Section 4.1.1). Thus, higher concentrahigher concentrations of NH4-N,NO3-N tions of NH4-N,NO -N in and -Pobserved of in and PO4-P observed thePO downstream 3 4 the downstream of Darkhan city with respect Darkhan city with respect to other sampling to otherindicate samplingthat points indicate that municipoints munici¬pal wastewater pal wastewater streams of the discharges into discharges streams of into the basin increase the nutrient in the Kharaa basin increaseconcentrations the nutrient concentrations in River water. the Kharaa River water. Resultsofof trend analyses of nutrient Results thethe trend analyses of nutrient concenconcentrations since 1990 are illustrated in trations since 1990 are illustrated in Figures11 Figures11 13.inAs shown Figure through 13.through As shown Figure 11, in there are 11, there are no increasing, or decreasing, no increasing, or decreasing, trends in NH4trends in NH4-N concentrations in both N concentrations in both monitoring stations. monitoring stations. The concentrations of The concentrations of NO3-Nnear NO3-N near Zuunkharaa have Zuunkharaa decreased have decreased since 1990, while from since 1990, while data from the data Darkhan the Darkhan station monitoring station trend monitoring show no show trend no (Figure (Figure 12). Similarly, PO -P concentrations 12). Similarly, PO4-P concentrations have 4 have decreased Zuunkharaa, while there decreased near near Zuunkharaa, while there is isnonotrend trendnear nearDarkhan Darkhancity city(Figure (Figure13). 13). The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 34 project. 34 Water Quality of the Kharaa River Basin, Mongolia: Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 11. Trends in NH4-N concentrations at Zuunkharaa and Darkhan monitoring stations Figure 12. Trends in NO3-N concentrations at Zuunkharaa and Darkhan Figure 12. Trends in NO3-N concentrations at Zuunkharaa and Darkhan monitoring stations monitoring stations The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 35 35 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 13.Trends in PO4-P concentrations at Figure 13. Trends in PO4-P concentrations at Zuunkharaa and Darkhan monitoring stations Zuunkharaa and Darkhan monitoring stations 3.2.5. Metals 3.2.5. Metals There observed data data on metThere are arevery verylimited limited observed on als, except for iron (Fe) and chromium (Cr6+) metals, except for iron (Fe) and chromium 6+ ions Cr are6+ measured ions. total Fe total and Cr ions. The Fe and ions are (Cr6+)The at the downstream sampling sampling points ofpoints both measured at the downstream monitoring stationsstations in Zuunkharaa and Darkof both monitoring in Zuunkharaa and Darkhan. The monthly mean concentrations han. The monthly mean concentrations of Fe vary between 0.08 and 0.15 concenof Fe vary between 0.08 mg/l andwith 0.15 mg/l trations increasing during rainy seasons. The with concentrations increasing during rainy 6+ Cr concentrations range from below thefrom derange seasons. The Cr6+ concentrations tection levelde-tection to 0.01 mg/land in below the level to also 0.01increase mg/l and rainy seasons (Table 16). also increase in rainy seasons (Table 16). Table16.Concentrations 16.Concentrationsofofmetals metalsininthe theKharaa KharaaRiverstations Riverstations Table Stations Zuunkharaa (upper) Darkhan (down) Zuunkharaa (down) Darkhan (down) Jan Feb Mar - - - 0.09 0.09 0.09 - - - 0.00 0.00 0.01 Apr May Aug Sep Oct Nov Dec Fe, (MAC is 0.5 mg/l) 0.08 0.12 0.11 0.18 0.16 0.17 0.12 - 0.15 0.08 0.08 0.16 0.08 0.09 0.11 Cr6+, (MAC is 0.01 mg/l) 0.01 0.01 0.01 0.00 0.00 0.01 0.01 - 0.01 0.01 0.00 0.01 0.01 0.01 0.12 0.01 Jun 0.12 0.00 Jul 0.01 Data source: Central Laboratory for Environment and Meteorology The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 36 project. 36 Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" In over time, the the totaltotal Fe conZuunkharaa, while decreasing In terms termsofoftrends trends over time, Fe increased increased near Zuunkharaa, while Cr6+ have near concentrations decreased both at decreasing at station the Darkhan station (Figure centrations have have decreased in bothinstations the Darkhan (Figure 14). stations since The concentrations of 14). since 1990. The1990. concentrations of Cr6+ have 6+ Figure Trends of of Fe Fe and and Cr Cr6+ at Zuunkharaa Zuunkharaa and and Darkhan Darkhan stations stations Figure 14. 14. Trends at As part of the MoMo project, measurements As part of the MoMo project, measurements of of other metals and a number of heavy other metals number (As), of heavy metals, suchand as a arsenic leadmetals, (Pb), such as arsenic (As), lead (Pb), cadmium (Cd), cadmium (Cd), chromium (Cr), copper (Cu), chromium copper (Cu), (Ni), mernickel (Ni),(Cr), mer¬cury (Hg), nickel zinc (Zn), iron cury (Hg), zinc (Zn), iron (Fe) and manganese (Fe) and manganese (Mn), were conducted (Mn), were conducted on the Kharaa River at on the Kharaa River at the Darkhan the Darkhanstation monitoring station and outlet monitoring and the outlet of the the basin of the basin near Burentolgoi during the period near Burentolgoi during the period from from September to 2008 (Table September 20062006 to 2008 (Table 17). 17). Table 17. Heavy metalsconcentrations in the Kharaa River, mg/l Table 17.Heavy metalsconcentrations in the Kharaa River, mg/l Sampling site As Pb Cd Cr Cu Ni Hg Zn Fe Mn Kharaa-Darkhan 0.0021 n.d. n.d. 0.0025 0.0127 0.004 n.d. 0.013 0.95 0.091 Kharaa0.0025 n.d. n.d. 0.009 0.013 0.011 n.d. 0.026 1.645 0.158 Burentolgoi (river basin outlet) Data source: Central Laboratory for Environment and Meteorology The results of these measurements (MoMo, The results of these measurements 2009) indicate that the heavy metal (MoMo, concen2009) indicate that the heavy trations show increased levels, althoughmetal most concentrations show increased levels, of them being lower or near to the allowed although most of them being lower or near maximum concentration. Concentrations of to the allowed maximum concentration. dissolved heavy metals in the upper and midConcentrations of dissolved heavy metals dle reaches below detection limit in the upperare andoften middle reaches are often (e.g. cadmium and lead). Natural background below detection limit (e.g. cadmium and concentrations in suspended solids are low. lead). Natural ofbackground concentrations Concentrations arsenic, primarily originating in suspended solids are low. Concentrations from human activities, increase downstream of arsenic, primarily originating from human and show increasing values in Darkhan. Eleactivities, increase downstream and show vated concentrations of heavy metals were deincreasing values in Darkhan. Elevated tected especially in the Boroo River and downconcentrations of heavy metals were stream of the city of Darkhan. detected especially in the Boroo River and downstream of the city of Darkhan. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 37 37 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 3.2.6. Suspended solids 3.2.6. Suspended solids The concentration of total suspended solids The of total suspended solids (TSS)concentration is important for ecological and water (TSS) is important for ecological and water quality. Suspended solids in most freshwater quality. solidswatershed in most freshwater systems Suspended originate from sources, systems originate from watershed sources, polpollutant point sources and sediments. lutant point sources and sediments. In Mongolia, total suspended solids appear to beMongolia, more strongly to surface depositsto In total related suspended solids appear (such as river bank erosion) than to use be more strongly related to surfaceland deposits and to increase from headwater down along (such as river bank erosion) than to land use a river (Batimaa, 1998). and to increase from headwater down along a river (Batimaa, 1998). The results of suspended solids monitoring The of suspended solids monitoring data results at Zuunkharaa and Darkhan stations data at Zuunkharaa and Darkhan stations show a similar characteristic, as show the aconcentrations similar characteristic,as the concentrations increase during snowmelt increase during snowmelt and rainfall runoff. and rainfall runoff. In general, suspended In general, suspended-solids concentrations solids concentrations were highest in the spring-summer andspring-summer lowest in the were highest in the and winter lowest (Table 18). The increase during the springin the winter (Table 18). The increase during summer can be attributed to higher the spring-summer can be attributed to flows, higher surfacesurface washing and the associated increase flows, washing and the associated inin runoff and transport. The trend of crease in runoff and transport. The trend of sussuspended solids is shown in Figure 15. pended solids is shown in Figure 15. Table18.Monthly 18. Monthlymean meanconcentrations concentrations suspended solids Kharaa River Table ofofsuspended solids inin thethe Kharaa River Stations Zuunkharaa (upper) Zuunkharaa (down) Darkhan (upper) Darkhan (down) Jan Feb Mar Apr - - - 39.4 - - - 31.7 20.6 25.0 24.9 37.0 25.4 25.0 25.0 62.2 May Jun Jul Aug Sep Oct Nov Dec - 28.4 31.4 37.7 28.1 14.5 12.5 - 75.6 25.8 54.9 11.7 18.4 18.1 - 62.9 65.5 81.7 51.5 64.6 25.6 24.9 28.1 101.4 60.7 82.3 60.8 74.9 32.1 28.9 29.4 - Data source: Central Laboratory for Environment and Meteorology Figure15. 15.Trends Figure Trends of of suspended suspended solidsat solidsatZuunkharaa Zuunkharaa and andDarkhan Darkhan stations stations The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 38 project. 38 Water Quality of the Kharaa River Basin, Mongolia: Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 3.3. The water quality 3.3. TheKharaa KharaaRiver River water quality The Kharaa River water quality was assessed The RiverQuality water quality assessed usingKharaa the Water Index, was described in using the Water Quality Index, described in Section 1.3.3. In order to analyze trends in Section 1.3.3. all In observed order to data analyze trends in water quality, for the period water quality, all observed data for the period from 1991to 2011 were used, and results from 1991to 2011 were 16. used, and the results are presented in Figure are presented in Figure 16. At the upper reaches of the river near the Zuunkharaa thenear quality At the uppermonitoring reaches of station, the river the of the Kharaa River water can be classified Zuunkharaa monitoring station, the quality as of the Kharaa River water can be classified as ‘very ‘very clean’ to ‘clean’, except for few cases. clean’ to ‘clean’, few cases.in The river The river water except qualityfordecreased lower water quality decreased in lower reaches of the reaches of the river near the city of Darkhan. river of Darkhan. than 95 Morenear thanthe95city percent of theMore all samples percent of the all samples show that the rivshow that the river’s water quality can be er’s water quality can be classified as ‘clean’. classified as ‘clean’. A slight decline in theA river’sdecline water quality to thewater ‘slightly-polluted’ slight in the river’s quality to the level is observed level during highwaterduring periods of ‘slightly-polluted’ is observed highsnowmelt in April to May, as well as in lowwater periods of snowmelt in April to May, as water in June. well asperiods in low-water periods in June. Figure Water quality quality of of the the Kharaa Kharaa river river at at Zuunkharaa Zuunkharaa and and Darkhan Darkhan stations stations Figure 16. 16. Water 3.4. Aquatic ecology 3.4. Aquatic ecology The potential impacts of human activities on the ecological functions and services of the potential Kharaa impacts River ecosystems and their The of human activities on interactions have not been fully studied, or the ecological functions and services of the understood. According to the studies MoMo Kharaa River ecosystems and their interactions project (2009), monitoring programs for the have not been fully studied, or understood. Ac- ecological status of rivers and the trends of relevant impact factors are rare and not locally adapted in the basin. cording to the studies MoMo project (2009), monitoring programs for the ecological status of rivers and the trends of relevant impact factors are rare and not locally adapted in the basin. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 39 39 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" As are emerging as promisAsmacroinvertebrates macroinvertebrates are emerging as promising ecological of water ing ecological indicators indicators of water quality and quality andhealth. ecological Theof evaluation ecological The health. evaluation the ecoof the status ecological of the River logical of thestatus Kharaa RiverKharaa is based on is based on aquatic macroinvertebrate aquatic macroinvertebrate communities data communities datasites monitored at twoRiver sitesBain monitored at two in the Kharaa the Kharaa River Basin for the period from 2005 to 2010. sin the period fromindividuals 2005 to 2010. Thefor number of total of Taxa, and Ephemeroptera, Plecoptera, Trichoptera (EPT)number individuals found in the Kharaa The of total individuals of Taxa,River and are shown in Figure 17. Ephemeroptera, Plecoptera, Trichoptera (EPT) individuals found in the Kharaa River are shown in Figure 17. Figure Number of of total total individuals individuals of of Taxa Taxaand andEPT EPT Figure17. 17.Number The analysis of the macroinvertebrate communities at two of the Kharaa River The analysis of the sites macroinvertebrate comBasin indicates good ecological conditions munities at two sites of the Kharaa River Baof the river. good The number of conditions total individuals sin indicates ecological of the of Taxa is almost three times river. The number of total individualshigher of Taxaatis the Darkhan monitoring site than at the almost three times higher at the Darkhan moniBaruunkharaa site. However, the number of toring site than at the Baruunkharaa site. Howhighly pollution-sensitive individuals of EPT ever, the number of highly pollution-sensitive is almost the same. individuals of EPT is almost the same. The Kharaa River water quality has been also The River water been beenKharaa assessed using thequality Biotichas Index at also the been assessed using Index at the two monitoring sites. the The Biotic water quality of the two monitoring sites. The water quality of the the Kharaa River meets the ‘clean’ level of water River quality classification at both Kharaa meets the ‘clean’ level of thesites wain quality Baruunkharaa and atDarkhan, ter classification both sitesalthough in Baruthe waterand quality slightly decreases near unkharaa Darkhan, although the water Darkhan (Figure 18). However, the water quality slightly decreases near Darkhan (Figure quality of the Kharaa River at the near 18). However, the water quality of reach the Kharaa River at the reach near Baruunkharaa has de- Baruunkharaa has decreased since 2005 and has reached the same levels as those near creased since 2005 and has reached the same the city of Darkhan in 2009 and 2010. This levels as those near the city of Darkhan in 2009 shows that This the quality of the water at and 2010. shows that theriver’s quality of the the Baruunkharaa monitoring site has been river’s water at the Baruunkharaa monitoring continuously declining for the last six years, site has been continuously declining for the last while it stays stable near the city of Darkhan. six years, while it stays stable near the city of Darkhan. In terms of the annual distribution, water quality is lower during spring and autumn In terms the annual distribution, and getsof better in summer (Figure water 19). quality is lower during spring and autumn and gets better in summer 19).are similar to that The results of the(Figure two sites results of integrated ecological assessment that based produced The results on of benthic the twoinvertebrates sites are similar to that by MoMo project by mean value (Figure results of integrated ecological assessment 20). that As there no data between these sites by it based on was benthic invertebrates produced was not possible to compare results. MoMo project by mean value (Figure 20). As there was no data between these sites it was not possible to compare results. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 40 project. 40 Water Quality of Kharaa the Kharaa Basin, Mongolia: Water Quality of the RiverRiver Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure Kharaa river water quality asFigure 18. 18.The The Kharaa river water quality assessed sessed by Biotic index by Biotic index Figure 19. Annual Figure 19. Annual variation variation of of the the Kharaa Kharaa river river water quality assessed by Biotic index water quality assessed by Biotic index Due to lack of data, the assessment of the ecological water quality of the Kharaa River Due to lack of data, the available assessment of the is mainly based on the data. As ecological quality of of the the MoMo Kharaa project River is part of thewater first-phase (MoMo, 2009), the available ecology data. of theAsKharaa mainly based on the part of River was assessed based on monitoring of the first-phase of the MoMo project (MoMo, fish communities macroinvertebrate 2009), the ecology of and the Kharaa River was ascommunities. The monitoring was sessed based on monitoring of fishconducted communiat 10 between 2006communities. and 2009. The ties andsites macroinvertebrate The results of this MoMo project monitoring are monitoring was conducted at10 sites between summarized below. 2006 and 2009. The results of this MoMo project monitoring are summarized below. The analyses of fish community and of the chemical and physic-chemical components The of the fish results community of the wereanalyses based on of all and conducted chemical andwhere physic-chemical expeditions, an overall components amount of were based on the results of alland conducted ex54,789 fish were caught released. peditions, an of overall amount of 54,789 Since the where analysis the macroinvertebrate fish were is caught released. Since the analysamples muchand more time consuming due to the (un)availability of laboratory sis of the macroinvertebrate samplesfacilities, is much the results of only two expeditions could be more time consuming due to the (un)availabiliused to assess the ecological status.of However, ty of laboratory facilities, the results only two two different seasons were included andecothe expeditions could be used to assess the assessment was based on the analysis of logical status. However, two different seasons more included than 106,000 individuals. for were and the assessmentCriteria was based the selection of sampling points were: 1) on the analysis of more than 106,000 individuto include upper, middle and downstream als. Criteria for the selection of sampling points reaches of the basin; 2) to study the influences were: 1) tosettlements include upper, middle andsuch downof larger in the basin as stream reaches of the basin; 2) to study the inZuunkharaa, Baruunkharaa and Darkhan; and fluences of larger settlements the basin such 3) to study a typical range ofinanthropogenic as Zuunkharaa, Baruunkharaa and impacts like land use and mining. Darkhan; and 3) to study a typical range of anthropogenic impacts like land The assessment of use the and fish mining. communities has shown (MoMo, 2009) a ‘good’ or ‘very good’ ecological statusofatthe most the monitoring The assessment fishofcommunities has sites. A ‘moderate’ status, detected at two sites in the watershed, is caused by the shown (MoMo, 2009) a species, ‘good’ orshowing ‘very good’ absence of ubiquistic no ecological status at most of the monitoring clear deficits in the ecological integrity ofsites. the fauna. Most the fishatspecies known Afish ‘moderate’ status,ofdetected two sites in the to occur inisthe Kharaa Basin (Dulmaa, watershed, caused by River the absence of ubiqu1999) were detected; some species istic species, showing however, no clear deficits in the seem to be very rare such as taimen (Hucho ecological integrity of the fish fauna. Most of taimen), lenok known (Brachymystax and the fish species to occur inlenok) the Kharaa arctic Basin grayling (Thymallus arcticus). Even in River (Dulmaa, 1999) were detected; biocoenotic regions, where they find optimal however, some species seem to be very rare conditions, the average sum of adult fish of such as taimen (Hucho taimen), lenok (Brachythese species is very low, ranging from 0.5 mystax lenok) andcaught arctic during graylingone (Thymallus to 7.7 individuals hour of arcticus). Even in biocoenotic regions, where sampling. they find optimal conditions, the average sum of adultanalysis fish of these is very low, ranging The of species the macroinvertebrate from 0.5 to 7.7along individuals caughtRiver duringbasin one communities the Kharaa hour of sampling. has also indicated good ecological conditions at most of the monitoring sites. However, at many sites of main channel, i.e.commuin the The analysis of the macroinvertebrate loweralong part the of Kharaa the middle regionhasand nities River basin alsothe intransition to the down region, and also in dicated good ecological conditions at most its of tributaries, deficits benthicatcommunities the monitoring sites. in However, many sites of could bechannel, shown. i.e. These arelower mainly the main in the partcaused of the by the absence of the EPT individuals middle region and the transition to the down (Ephemeroptera, Plecoptera, Trichoptera) in region, and also in its tributaries, deficits in the community composition, the absence benthic communities be shown. These of so-called indicatorcould organisms, especially are mainly caused by the absence of the EPT of the order Plecoptera, and an abnormal individuals Triincreased (Ephemeroptera, percentage of Plecoptera, fine sediment choptera) in the community composition, the colonisers. absence of so-called indicator organisms, especially of the order Plecoptera, and an abnormal increased percentage of fine sediment colonisers. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats andand hotspots assessment Pollution threats hotspots assessment project. 41 41 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" ●blue: very good ●green: good ●yellow: moderate ●orange: poor ●red: bad ●gray: no data Figure 20. Ecological assessment of the Kharaa River Basin (MoMo, 2009) Figure 20. Ecological assessment of the Kharaa River Basin (MoMo, 2009) The analysis of the water quality conditions based on benthic invertebrates (MoMo, 2009) showed ecological deficits in the Kharaa The theofwater quality conditions Riveranalysis near theofcity Baruunkharaa and city based on benthic invertebrates (MoMo, of Khongor, as sensitive groups (EPT)2009) had low numbers in these areas. 20 shows showed ecological deficits in Figure the Kharaa River the integrated ecological assessment near the city of Baruunkharaa and city of based Khonon a five class category from ‘very good’ to gor, as sensitive groups (EPT) had low numbers ‘bad‘. As shown in the figure, the ecological in these areas. Figure 20 shows the integrated water quality ranked based ‘very good’ and ‘good’ ecological assessment on a five class catby mean value in all parts of the river. By the egory from ‘very good’ to ‘bad. As shown in worst values, the upper reaches of the river the figure, the ecological water quality ranked ranked ‘clean’, whereas in the river section ‘very good’ and ‘good’ by mean value in all between Baruunkharaa and Darkhan ranked parts the river. By worst the upfrom of‘moderate’ to the ‘bad’ andvalues, improved to per reaches of the river ranked ‘clean’, whereas ‘clean’ at the river outlet. in the river section between Baruunkharaa and Darkhan ranked from ‘moderate’ ‘bad’ and The above assessment shows thattothe water improved to ‘clean’ at the river outlet. quality of the Kharaa River Basin decreases occasionally to ‘moderately-polluted’ and The above assessment shows that the water quality of the Kharaa River Basin decreases ‘very-polluted’ near urban settlements such as Darkhan, Baruunkharaa and Zuunkharaa. This indicates that the Kharaa River water occasionally to vulnerable ‘moderately-polluted’ quality is highly to pollution,and in ‘very-polluted’ near close urbantosettlements such of as particular in areas point sources Darkhan, Baruunkharaa and Zuunkharaa. This pollution, such as urban areas, and in source areas of diffuse suchwater as agriculture indicates that thepollution, Kharaa River quality is and mining. highly vulnerable to pollution, in particular in areas close to point sources of pollution, such Onurban the areas, other and hand, the self-purification as in source areas of diffuse rate in the Mongolian rivers is usually pollution, such as agriculture and mining.high, with their self-purification distances ranging between 6 and 18 kilometers. The selfOn the other hand, the self-purification rate in purification distance of the Kharaa River is the Mongolian rivers is usually high, with their estimated 10 kilometers. self-purification distances ranging between 6 and kilometers. Thewater self-purification disThat 18 explains why the quality of the tance the Kharaa Rivertois ‘clean’ estimated 10 kiKharaaof River improved status at lometers. That explains why the water quality its outlet, having no negative impact on the of the Kharaa Orkhon River River waterimproved quality. to ‘clean’ status at its outlet, having no negative impact on the Orkhon River water quality. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 42 project. 42 Water Quality of Kharaa the Kharaa Basin, Mongolia: Water Quality of the RiverRiver Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 3.5. Groundwater in in thethe Kharaa RiverRiver BasinBasin 3.5. Groundwaterquality quality Kharaa The groundwater quality is the most important The groundwater quality is the as most important for the drinking water quality, groundwater for the drinking water quality, as groundwater is the main drinking water source in the isKharaa the main drinking water source inthere the Kharaa River Basin. Presently, is no River Basin. Presently, is no groundwater groundwater quality there monitoring network in quality monitoring network in the basin. the basin. Only a few groundwater wellsOnly are aused few groundwater used for drinking for drinking wells waterare extraction. Hence, groundwater quality datagroundwater is very scares. water extraction. Hence, quality data is very scares. The only available data on groundwater The only was available data on groundwater quality quality a single chemical analysis of was a single chemical analysis of groundwater groundwater at various locations in the Kharaa at various locations in theinKharaa River Basin, River Basin, reported an unpublished reported an unpublished technical report on technicalinreport on “The groundwater quality “The groundwater quality overview” (Jadamoverview” (Jadambaa, 2000). The results of baa,2000).The of thisinanalysis are prethis analysis areresults presented Table 19. sented in Table 19. Table 19. Groundwater quality parameters Table 19. Groundwater quality parameters Lon Lat TDS Ca Mg NaK HCO3 SO4 CI mg/l Hardness mg-eqv/l pH NH4 NO2 NO3 Fe mg/l 106.21 48.92 691 40.6 13.4 151. 262.3 143 81 3.15 8.0 0.00 0.00 10.0 0.00 105.92 49.49 611 40.5 14.7 110 366.0 45.0 35 3.84 7.2 0.00 0.03 8.0 0.00 105.98 49.43 527 40.1 25.5 80 231.8 114 36 4.10 7.5 0.10 0.50 0.0 0.20 106.75 48.64 504 40.1 11.5 77.9 335.6 34.5 4.3 2.95 7.0 0.10 0.00 0.0 0.00 105.93 49.3 413 32.1 15.8 65.8 213.5 18.1 68 2.90 7.2 0.20 0.00 0.0 0.20 106.63 48.85 351 22.1 12.2 57 213.5 25.0 21 2.10 6.7 0.30 0.01 0.0 0.30 106.27 48.82 509 58.1 22.5 56.3 286.7 62.5 23 4.75 7.9 0.20 0.00 1.0 0.00 105.92 49.5 478 44.1 25.5 55.6 305.1 15.6 32 4.30 7.0 0.00 0.00 0.0 0.00 106.48 48.85 417 52.1 17.0 44.6 244.0 45.2 14 4.00 7.9 0.30 0.01 1.0 0.00 106.08 48.91 426 54.1 15.7 38.9 237.9 65.8 14 4.00 7.8 0.20 0.00 2.0 0.00 106.78 48.82 330 43.1 12.2 28.1 189.1 47.1 10 3.15 7.1 0.10 0.00 0.0 0.30 106.48 48.81 291 36.1 14.6 26.2 164.7 34.6 15 3.00 7.9 0.10 0.00 1.0 0.00 106.52 48.8 243 32.1 10.9 16.1 140.3 34.6 8.9 2.50 7.5 0.40 0.00 1.0 0.00 106.26 49.49 233 27.1 13.4 15.6 143.4 25.0 8.9 2.45 7.0 0.00 0.00 0.7 0.00 106.76 48.64 340 50.1 26.1 4.65 213.6 34.5 11 4.65 7.0 0.40 0.05 2.0 0.00 Data source: Jadambaa, 2000 The chemical composition of groundwater is almost the same as in the Kharaa River water. The composition of groundwater is The chemical mineralization of groundwater is in the almost the same as in the Kharaa River water. range between 233 and 691 mg/l. Similar to The of groundwater is in and the the mineralization Kharaa River water, the calcium range betweenare 233 the and dominant 691 mg/l. Similar to bicarbonate ions in groundwater at allwater, sampled order of the Kharaa River the points. calciumThe and bicarbonate are the dominant ions in groundwater at all sampled points. The order of abundance of cations is Ca2+>Na++K+>Mg2+, and the abundance of cations is Ca2+>Na++K+>Mg2+, and the order of abundance of anions is 22order abundance ->SO >Cl-. of anions is HCO3->SO4 HCO3of 4 >Cl . According to nitrogen (N) concentrations, the nutrient level in groundwater in aquifers in According nitrogen concentrations, the the KharaatoRiver Basin(N) is very low, indicating that groundwater is clean. in aquifers in the nutrient level in groundwater Kharaa River Basin is very low, indicating that groundwater is clean. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats hotspots assessment Pollution threats andand hotspots assessment project. 43 43 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 44 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 4.Assessment Assessment of of 4. pollutionhotspots hotspots pollution inthe theKharaa Kharaa in River RiverBasin Basin The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. ©Batimaa P., 2013 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" An assessment of water pollution hotspots in the Kharaa River Basin was conducted as part of the water quality assessment of the basin. This included the identification of potential pollution hotspots and their effects on the water quality of the basin, as well as the identification of possible threats to the environment and human health. In general, a water pollution hotspot is an area where the concentration of a pollutant exceeds the standards. Pollution hotspots are characterized by both a high concentration, or loading, of a pollutant and a high risk that the pollutant enters adjacent water bodies such as rivers, lakes, groundwater aquifers, causing water pollution. The pollution hotspots assessment is useful in identifying areas with most serious pollution risks, thus allowing the decision-makers to target compliance efforts on the problem sites. The water quality assessment of the Kharaa River Basin, described in the previous section, shows that there are no potentiallyserious water quality problems in the basin, except for the localized and seasonal water quality degradation due to the impacts of municipal wastewater effluents on the river water quality downstream of urban areas and a potential risk of bacteriological contamination by livestock waste. However, the basin is becoming more sensitive to pollution, as there are growing pressures from population growth, urbanization, industrial development, and increasing farming and tourism activities that are likely to generate more pollution. The assessment focused on both point and diffuse pollution sources in the Kharaa River Basin in order to have a comprehensive overview of existing, or potential, pollution hotspots. 4.1. Pollution from urban areas The Kharaa River Basin includes several large and small urban areas. The largest urban area in the basin is the industrial city of Darkhan—the second biggest city of Mongolia with a population of about 75,000. Moreover, a total of 24 soums (an administrative unit equivalent to small towns) are located in the basin. The basin is shared by three provinces: Selenge, Tuv and Darkhan Uul aimags (Figure 21). The entire population of the Kharaa River Basin is about 133,000, which is approximately 5 percent of the total population of Mongolia. The basin has the highest population density in Mongolia, which is about 9.2 persons per sq.km. The Darkhan city has the highest population density of about 300 people per sq.km. In addition to being an industrial city, Darkhan is the second largest educational center in Mongolia too, with 10 universities and higher education institutions, 25 secondary schools and 14 pre-school establishments and kindergartens. In addition, several research institutions are located in the city of Darkhan, including: the Institute of Management and Development; Regional Business Development Center; and Horticultural and Agricultural Research and Training Institute. Every year, hundreds of students come Darkhan from other parts of Mongolia to study. 4.1.1. Municipal wastewater Municipal wastewater and runoff from urban areas are, in general, the largest point source of water quality impairments. The discharge of inadequately-treated municipal wastewater to surface water resources is a major water quality concern in the Kharaa River Basin. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 46 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure Basin Figure21. 21. The The administrative administrative units units in in the the Kharaa KharaaRiver river basin There are five Wastewater Treatment Plants (WWTPs) theWastewater Kharaa River Basin, two of There are in five Treatment Plants (WWTPs) in the Kharaa River Basin, two of which discharge their treated wastewater diwhichinto discharge theirRiver. treated rectly the Kharaa The wastewater other three directly into the Kharaa River. The other plants have no direct outlet to the Kharaa River. three plants have no direct outlet the Most soums (small towns) do not have to wasteKharaatreatment River. Most soums towns) do water facilities and(small infrastructure. A not have wastewater treatment facilities majority of households in soums use simpleand trainfrastructure. A majority of households in ditional pit latrines in their compounds. soums use simple traditional pit latrines in their compounds. The Wastewater Treatment Plant in the Darkhan treats bothTreatment municipal Plant and industrial The city Wastewater in the wastewater and discharges its effluents directly Darkhan city treats both municipal and to the Kharaa River. Theand Wastewater Treatindustrial wastewater discharges its ment Plant in Salkhit (a railway station town) effluents directly to the Kharaa River. The has mechanical and primary treatWastewater Treatment Plantbiological in Salkhit (a railway station town) has mechanical and ment processes and discharges its effluents directly to the Kharaa River, too. processes and primary biological treatment discharges its effluents directly to the Kharaa River,WWTPs too. The in Zuunkharaa, Baruunkharaa and Khongor soums, which are located in the The WWTPs in Zuunkharaa, Baruunkharaa upstream reaches of the basin, are smaller and and Khongor soums, which are located the have no direct outlet to the Kharaa River. in These upstream reaches of the basin, are smaller WWTPs have mechanical and primary biologiand have no direct outlet to the Kharaa River. cal treatment processes. The treated wastewaThese WWTPs have mechanical and primary ter of thesetreatment plants is discharged infiltration biological processes. to The treated ponds and the is disposed of in sludge wastewater of sludge these plants is discharged to fields close to the Kharaa River. Consequently, infiltration ponds and the sludge is disposed there is a potential risk oftopollution of groundof in sludge fields close the Kharaa River. water, soil and river water leakage from Consequently, there is abypotential risk the of sludge ponds. pollution of groundwater, soil and river water by leakage from the sludge ponds. Darkhan Wastewater Treatment Plant Darkhan Wastewater Treatment Plant The Darkhan Wastewater Treatment Plant is The Darkhan Wastewater Treatment Plant biggest in the Kharaa River Basin (Figure 22).isIt biggest in the Kharaa River Basin (Figure 22). was commissioned in1968. It was commissioned in 1968. The plant treats both municipal and industrial The plant treats both municipal biological and industrial wastewater. It has mechanical, and wastewater. It has mechanical, biological chemical treatment processes. Some biological and chemical treatment Some processes are affected by theprocesses. cold weather and biological by the cold slow down,processes or cease,are at affected lower temperatures weather and slow down, or cease, lower during winter. Due to the cold climate,atthe poltemperatures during winter. Due to the cold ishing ponds cannot be used in winter time. climate, the polishing ponds cannot be used in winter time. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 47 47 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The has no no denitrification denitrification system. system. Raw Raw The plant plant has wastewater entering the plant is initially passes wastewater entering the plant is initially through screens andscreens then treated passes mechanical through mechanical and then treatedin biologically primary sediand biologically primary and insecondary secondarytanks. sedimentation tanks. The plant mentation The plant has a chlorination has a chlorination unit for the disinfection unit for the disinfection of treated wastewater of treated wastewater before itsHowever, dischargethe to before its discharge to the river. the river. However, chlorination chlorination system is the temporarily out ofsystem order. is temporarily out of order. The Darkhan Wastewater Treatment Plant has a laboratory for the chemical analyses of wasteThe Darkhan Wastewater Treatment Plant water. has a laboratory for the chemical analyses of wastewater. The total capacity of the Darkhan The total capacity of the Plant Darkhan Wastewater Wastewater Treatment is 50,000 m3/ Treatment Plant is 50,000 m3/day. However, day. However, the plant is operating at one the plant at one third of its design third of isitsoperating design capacity, treating from capacity, treating from 15,000 to 17,000 m3/ 15,000 to 17,000 m3/ day wastewater. Only day wastewater. Only wastewater from apartwastewater from apartment buildings and administrative and administrative services areas,and which are ment buildings and services connected theconnected sewage system of the city, areas, whichtoare to the sewage sysis treated theisplant. tem of the at city, treated at the plant. The Darkhan Darkhan Thermal Thermal Power Power Plant The Plant (DTPP) (DTPP) isis the largest user of water in the city. the largest user of water in the city. ItIthas hasitsits own wastewater tratment facility. The own wastewater treatment facility. The wastewastewater of the plant is discharged into water of the plant is discharged into the Kharaa the Kharaa River through 12 oxidation River oxidationsystem. ponds and a biopondsthrough and a 12 bioaquifer However, aquifer system. However, the DTPP wastewathe DTPP wastewater treatment facility ter treatment facilitytechnical often encounters technical often encounters problems, and problems, untreated industrial wastewater untreated and industrial wastewater is discharged isinto discharged into thethe area outside the plant. the area outside plant. Figure 23.23. Wastewater treatment raterate of the DarkFigure Wastewater treatment of the han WWTP Darkhan WWTP This largely residential, and close the This area areais is largely residential, and to close ‘ger’ district (a district of traditional Mongolian to the ‘ger’ district (a district of traditional housing andhousing small houses). Mongolian and small houses). The ‘ger’ districts The districts and andsmall smallvillages villagesare arenot not connected to the sewage system of the city. connected the sewage system of the city. The wastewater The wastewater from from these these areas areasisisdischarged discharged into simple traditional pit latrines or soak into simple traditional pit latrines or soak pits. pits. Many of these latrines are inadequately Many of these latrines are inadequately mainmaintained, and overflowing latrines are tained, and overflowing latrines are often a maoften a major source of pollution in ‘ger’ jor source of pollution in ‘ger’ areas of the city, areas of the city, especially during heavy especially rainfalls. during heavy rainfalls. The Darkhan Water Water Supply Supply and andWastewater Wastewater The Darkhan Company USAG) is is responsible responsible for for Company (Darkhan (Darkhan USAG) water supply and wastewater collection treatwater supply and wastewater collection ment in theincity. treatment the city. In order to evaluate In evaluate the efficiency efficiency and rate rate of of wastewater treatment treatment of Darkhan the Darkhan wastewater of the WasteWastewater Treatment Plant, datachemical of the water Treatment Plant, data of the chemicalofanalyses treated wastewater at analyses treated ofwastewater at the plant the plant outlet have been analyzed for the outlet have been analyzed for the period from period from 2002 to 2012. The wastewater 2002 to 2012. The wastewater treatment rate treatment rate of the plantvariesbetween of the plantvariesbetween 76.8 and 98.1 per76.8 and 98.1 percent (Figure 23). However, cent (Figure most of the time, in most of 23). the However, time, theintreatment rate is the treatment rate is below 90 percent, which below 90 percent, which means to a certain means a certain extent that water extent to that polluted water is polluted discharged intois discharged the Kharaa River. the Kharaainto River. Figure 24.BOD of treatedwastewater Figure concentrations 24. BOD concentrations of of the Darkhan WWTP treatedwastewater of the Darkhan WWTP Thus, and suspended suspended isThe discharged into the Kharaa River. 24and The results Thus, concentrations concentrations of of BOD BOD and results are presented in Figure 25, solids of the treated wastewater have been anare presented in Figure 24and 25, respectively. solids of the treated wastewater have been respectively. alyzed to determine how how muchmuch polluted water analyzed to determine polluted water is discharged into the Kharaa River. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 48 48 project. Water Quality the Kharaa River Basin, Water of Quality of the Kharaa River Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The wastewater BOD concentrations at the outlet of the The wastewater concentrations at the the outlet The wastewater BOD at outlet ofofthethe plant range between 3.1concentrations and 33.6 mg/land rarely exceed plant range rangeAcceptable between3.1 3.1 and33.6 33.6mg/land mg/l rarelyexceed exceed plant between and Maximum Concentration of and 20rarely mg/l, set by the the Maximum Acceptable Concentration of 20 mg/l, set Maximum Acceptable Concentration of 20 mg/l, set bybythe Mongolian National Standard for Discharge of Treated Wastethe Mongolian National Standard for Discharge of Treated Mongolian Standard for Discharge of Treated water into National the Environment MNS:4943-2011 (NSA, Waste2011). Wastewater into the Environment MNS:4943-2011 (NSA, water into the Environment MNS:4943-2011 (NSA, 2011). This shows that even though the treatment rate of the plant is 2011). This shows that even though the treatment ratethe This shows that even treatmentdischarged rate of theinto plant is not high enough, the though treatedthe wastewater of the plant is not high enough, the treated wastewater not highRiver enough, thesignificant treated wastewater discharged into Kharaa has no organic pollutant in most of the discharged into the Kharaa River has no significant organic Kharaa cases. River has no significant organic pollutant in most of the pollutant in most of the cases. Figure 22.The Darkhan Wastewacases. terThe Treatment Plant Figure Darkhan Wastewater Figure22. 22.The Darkhan WastewaOn the other hand, the concentrations of suspended solids ter Treatment Plant Treatment Plant On the other hand, the concentrations of suspended solids On the other hand, the ofregularly suspended solids of treated wastewater areconcentrations quitehigh highand and regularlyexceed exceed of treated wastewater are quite of treated wastewater are quite high and regularly exceed the Concentration of 50 as per the Maximum MaximumAcceptable Acceptable Concentration of mg/l, 50 mg/l, the Maximum Acceptable Concentration of 50 mg/l, per MNS:4943-2011 (NSA, 2011). In general, the concentrations as per MNS:4943-2011 (NSA, 2011). In general, asthe MNS:4943-2011 2011). Insolids general, concentrations of suspended solids in wastewater are similar to those ofarethe concentrations of(NSA, suspended in the wastewater of suspended solids in Kharaa wastewater similar to those of the similar to those of the Riverare water. Kharaa River water. Kharaa River water. The Darkhan Wastewater Treatment Plant The Darkhan Wastewater Treatment Plant Figure 25.Suspended solids concentrations in treated in wastewater Figure 25. Suspended solids concentrations treated of the Darkhan WWTP wastewater of the Darkhan WWTPwastewater of Figure 25.Suspended solids concentrations in treated the Darkhan WWTP The Darkhan Wastewater Treatment Plant requires The Darkhan Wastewater Treatment Plant requires substansubstantial technical upgrading and construction The Darkhan upgrading Wastewater Plant requires tial technical andTreatment construction maintenance. Most maintenance. Most treatment process units of thesubstanplant tial technical upgrading and construction maintenance. Most treatment process units of the plant are outdated, with rather are outdated, with rather mediocre treatment efficiencies. treatment process units the wastewater plant areconstruction outdated, with mediocre treatment The of plant arather new The construction ofefficiencies. a ofnew treatment mediocre treatment efficiencies. The construction of a new wastewater treatment plant may be needed. may be needed. wastewater treatment plant may be needed. The (2009) developed a simulation modeling The MoMo MoMoproject project (2009) developed a simulation modeling ofproject the Darkhan Wastewater Treatment Plant The MoMo (2009) developed aPlant simulation modeling of the Darkhan Wastewater Treatment to improve and to improve and optimize the treatment processes of of the Darkhan Wastewater Treatment Plant to improve and optimize the treatment processes of the plant, in terms of both the plant, in terms of both the quality and quantity optimize the treatment the plant, inasterms the quality and quantityprocesses of treatedofwastewater, well of as both with of treated wastewater, as well as with regard to the the quality and quantity of treated wastewater, as well as with regard to the energy consumption of the plant for the aeration energy consumption of the plant for the aeration of the regard to the energy consumption of the plant the aeration of the biological tanks. In the framework of theforfollow up the biological tanks. In the framework of the follow up thethe of the biological tanks. In researchers the framework of Helmholtz the follow Centre up MoMo project first-stage, of the MoMo project first-stage, researchers of the Helmholtz MoMo project first-stage, researchers of have the Helmholtz for Environmental Research of Germany developedCentre an inCentre for Environmental Research of Germany have for Environmental Research of Germany have developed integrated concept for decentralized wastewater treatmentanand developed an integrated concept for decentralized tegrated concept for decentralized wastewater treatment and have built a pilot plant to test it in local Mongolian conditions. wastewater treatment and have built a pilot plant to have a pilot plant to testconditions. it in wastewater local Mongolian conditions. In the decentralized pilot2012, plantthe with testMay itbuilt in2012, local Mongolian In May In May 2012, the decentralized wastewater pilot plant with integrated woodwastewater production was handed decentralized pilotcommissioned plant with and integrated integrated wood production was commissioned andhanded handed wood production was commissioned and The Darkhan Wastewater Treatment Plant The Darkhan Wastewater Treatment Plant Outlet of the Darkhan WWTP Outlet of the Darkhan WWTP 49the The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with Pollution threats and hotspots assessment Pollution threats hotspots assessment Pollution threatsand and hotspots assessment project. 49 49 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" over to the College of Polytechnics in Darkhan of the Mongolian University of Science and Technology. This innovative concept was developed through the cooperation of Mongolian and German researchers with the aim to contribute to solving problems such as the lack of access to appropriate sanitation; increasing water scarcity and deforestation, caused by a high demand of wood for heating (www.ufz.de). In addition to municipal wastewater, wastewater from various industries and tanneries is combined with the municipal wastewater of Darkhan without any pretreatment, which may cause serious environmental and health problems. A wide variety of industries are located in Darkhan, including slaughter houses, wool factories, bakeries and confectioneries, pharmaceutical companies, hospitals, power stations, printing houses, vehicle repair shops, etc. 4.1.2. Solid waste At the national level, the amount of municipal solid waste is growing rapidly, while the composition of solid waste is becoming more and more diversified with increasing volumes of non-biodegradable waste such as plastics. In general, solid waste management is inadequate throughout the country and the absence of a proper waste disposal system creates significant environmental and health concerns. In early 1990s, outdoor burning of household garbage was commonly practiced as a method of waste disposal throughout the country to reduce household waste quantities and also to separate recyclable material from waste. Concerns about the impact of this practice on air quality led to its banning nationwide. However, no new solutions for waste management have been introduced thus far, and open burning continues to be practiced in some places. Only a small portion of solid waste is recycled despite a potential market for recycled waste materials such as plastics, glass bottles, and scrap metals. In 2012, the Parliament of Mongolia adopted a new “Law on Solid Waste”. This new law replaces the previously existing Law on Household and Industrial Waste and Law on Hazardous and Toxic Chemicals. It has introduced 3R ‘reduce, recycle, and reuse’ principles. Over the past years, solid waste management is becoming an increasingly significant problem the Kharaa River Basin, mainly due to the concentration of the population in urban areas, changes in economic structure, growing consumption and changing lifestyles, as in any other parts of Mongolia. There are growing concerns about inappropriate solid waste management and increasing litter. Municipal solid waste, including garbage from larger cities and small towns, account for the biggest share of solid waste generated and disposed of in the region. However, there are no systematic and comprehensive data to quantify the amount of solid waste generated in the Kharaa River Basin as a whole. While, in larger cities, municipal solid waste is collected and disposed of in landfills or dumpsites, most small towns do not have proper solid waste management systems. Solid waste management in Darkhan The city of Darkhan–the largest urban centre in the Kharaa River Basin–accounts for the biggest share of the municipal solid waste generated in the basin. A feasibility assessment of solid waste management in the city of Darkhan was conducted by the Ministry of Nature, Environment and Tourism of Mongolia, in cooperation with the Korea Environment Cooperation, in 2011 (MNET, 2011). Based on this assessment, the city’s solid waste generation has increased nine times during the past decade. The amount of municipal solid wastes collected and disposed of in the Darkhan area is summarized in Table 20. As shown in the table, total waste generation in the Darkhan city was approximately 49,640 tons in 2010, with a per capita waste generation of about 1,8 kg per day (MNET, 2011). The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 50 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Table category, 2010 (tons/ Table20.Quantities 20.Quantitiesand andcomposition compositionofofsolid solidwaste wastegenerated generatedininDarkhan Darkhanbybysource source category, 2010 (tons/ year, wet weight) year, wet weight) Source Paper Cardboard Glass Metal Plastic Wood/green waste Animal remains Other organic Other inorganic HHW Mixed waste Total Apartment building area 1057.3 2730.2 1588.6 1022.6 953.1 1444.5 680.1 585.8 1007.7 238.3 610.6 12613.5 ‘Ger’ district area 744.6 282.9 819.1 1027.6 794.2 1384.9 868.7 1310.5 2874.2 387.2 794.2 16832.9 Office buildings and service areas 2283.4 2591.2 2874.2 357.4 1360.1 1747.3 1653.0 1002.7 412.0 665.2 511.3 16277.0 Streets and public space 297.8 620.5 397.1 248.2 248.2 1092.1 516.3 496.4 3916.6 Total 4383.2 6224.9 5678.8 2655.7 3107.5 4825.0 4293.9 2899.0 4810.1 1290.6 2412.5 49640.0 Data source: MNET, 2011 In solid waste is deIn apartment apartmentbuildings, buildings,thethe solid waste is posited in in a aroom and deposited roomon onthe the ground ground floor and collected waste management management companies. companies. collected by by waste In areas with In with lower lower buildings buildings and andindividual individual houses, community communitybins bins available for houses, areare available for each each block. Residents of ‘ger’ districts are block. Residents of ‘ger’ districts are required required deposit their household wastes in to depositto their household wastes in designated designated areas. areas. The city’s city’ssolid solid waste is disposed the The waste is disposed of at of theatBaraBaraat central waste disposal site and other at central waste disposal site and other five unfive unofficial sites. Thewaste Baraat waste official disposaldisposal sites. The Baraat disposal disposal site at is the located at the northern edge site is located northern edge of the city in of the city in 15 kilometers from Darkha. 15 kilometers from Darkhan. The site covers an The site covers an area of 15.02 hectares. area of 15.02 hectares. The disposal site does The disposal site does not have a waste not have a waste sorting facility. sorting facility. The Public Utility Services Department of the The Public Utility Services Department of the Municipality of Darkhan is responsible for Municipality ofcollection Darkhan and is responsible for overseeing the transportation overseeing the collection and transportation of municipal solid waste from the apartment of municipal solid fromoffice the buildings, apartment buildings area, ‘ger’waste districts, buildings area, ‘ger’ districts, office buildings, service areas such as hotels, restaurants and service areas such as as hotels, and shopping centers, well asrestaurants for street and shopping centers, as well as for street and public space cleaning. Waste collection public cleaning. collection trucks space pick up mixed Waste solid wastes. All trucks solid pick up mixed solid wastes. wastessites are wastes are transported to All thesolid disposal transported to the disposal without presorting. There sites is nowithout system prefor waste separation source. has no sorting. There is noatsystem for The wastecity separation official recycling in place as of yet. at source. The city program has no official recycling program in place as of yet. In 2007, the city of Darkhan developed and implemented a project on rehabilitation of In 2007, the city of Darkhan developed and the Baraat central solid waste disposal site. The project was financed by the Ministry Pollution threats and hotspots assessment implemented a project on rehabilitation of the of Nature, Environment and Tourism. At Baraat central waste disposal site. The the request of solid the Ministry, the Institute of project was financed by the Ministry of Nature, Geo-ecology of the Mongolian Academy of Sciences developed general Environment and Tourism. At guidelines the requestfor of a landfill facility in Mongolia. In 2008,ofthe the Ministry, the Institute of Geo-ecology the solid waste Academy at the Baraat Mongolian of disposal Sciences developed site wasguidelines removed for to aasmaller disposal general landfill facility in Monarea in order to reduce the site area, through golia. In 2008, the solid waste at the Baraat disthe financial Ministry of posal site was support removedfrom to a the smaller disposal Nature, area in order to reduce the site area, through Environment and Tourism, as part of the the financial support from the Ministry of Naproject. Rehabilitation works and ture, Environment and Tourism, as part oftree the plantingRehabilitation works and tree planting project. works were wereimplemented, implemented,asaswell. well. works In 2010, the Municipality of Darkhan developed In 2010, the Municipality of Darkhan devela programme “Darkhan – a clean city”, oped a programme “Darkhan – a clean city”, adopted by the Darkhan City Council of adopted by the Darkhan City Council of RepRepresentatives. resentatives. Thewill programme will be impleThe programme be implemented mented for the period from 2010 for the period from 2010 to 2014.to 2014. This programme has three main objectives, This as programme has three main objectives, as follows: follows: Objective 1: Establish an efficient and Objective suitable 1: Establish an efficient and suitable system system for for waste wasteseparation separationatatsource: source: •• Develop Developa methodology a methodology determine to to determine the types andand composition of solid theamount, amount, types composition of solid from apartment buildings, ‘ger’ diswastes wastes from apartment buildings, tricts, enterprises and industrial plants,‘ger’ and districts,relevant studies on waste generaconduct enterprises and industrial plants, and tion; conduct relevant studies on waste generation; 51 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. 51 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" • Develop a database on solid waste generation in the Darkhan-Uul aimag (province), with an inventory system for solid wastes from households, business areas and industries; • Implement pilot projects of waste separation in selected districts and select optimal alternatives for waste separation in apartment building areas, ‘ger districts’, and business and service areas; • Establish a specific site for the collection of recycled waste materials in order to support the voluntary collection and sale of recyclable waste materials by individuals and residents; • Increase the involvement of enterprises in waste separation by providing waste separation containers to shops, supermarkets, service providers and in the streets. Objective 2: Establish a waste sorting and recycling plant and implement projects on reuse and recycling of household and industrial wastes and waste materials • Adopt economic tools to motivate to produce less waste and use the resources more efficiently in production, services and other sectors at the local level; • Operate a regular site for the exchange and sale of used materials (such as books, clothing, newspapers, journals, home furniture, etc.), as well as for sharing information and advertisements of enterprises that collect/ purchase secondary raw materials (recyclable waste materials), in order to support waste separation, recycling and reuse with increased participation of residents and individuals; • Conduct a study on the quantity, types and composition of secondary raw materials (recyclable waste materials) and on technical and economic feasibility of waste recycling, and build a waste recycling and sorting plant; • Implement projects on waste recycling/ reprocessing and sorting, based on the composition of wastes from different sources, including projects to separate and process organic wastes from households and restaurants to produce compost for use as a fertilizer; • Support enterprises operating storage, collection and transportation of secondary raw materials. Objectives 3. Improve the collection, transportation and disposal of solid wastes. • Transport all solid wastes from enterprises, public organizations and households; • Modernize waste disposal systems of enterprises; • Improve waste collection, storage and transportation services; • Select waste collection and storage sites taking into account of specific conditions of different areas such as service and business areas, public areas, apartment building areas, and ‘ger’ districts, respectively; • Increase public awareness by disseminating information handouts and training pamphlets about more efficient management of solid wastes; • Develop new routines and schedules for cleaning streets and public spaces, and waste collection from enterprises, apartments buildings and ‘ger’ districts; • Estimate costs of waste removal and the reclamation of land used by enterprises and individuals for the purposes such as unfinished construction and garages, and collect these costs from them; • Support public officers, administrators of local communities and public organizations, apartment co-ownership associations, enterprises and individuals for their accomplishments and efforts made in improving waste management in their communities; • Organize a “Organization with No Waste” competition amongst local communities, public organizations, apartment coownership associations, enterprises and industries with no open-waste disposal sites; • Implement technologies for solid waste disposal in landfills. Consequently, the solid waste management in the Darkhan city is expected to improve over the coming years, as a result of the “Darkhan – a clean city” programme. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 52 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 4.2. Industrial 4.2. Industrialpollution pollution The Darkhan, which is located in the in Kharaa BaThe city cityofof Darkhan, which is located the River Kharaa sin, is one of the largest industrial centres in Mongolia. It River Basin, is one of the largest industrial centres in is home to most country’s largeofindustries, steel proMongolia. It isofhome to most country’sincluding large industries, duction, and building material and manufacturing, includingconstruction steel production, construction building material and leather Many factories, textile andmanufacturing, leather factories, textile and food processing. other and food are processing. otherincluding industries areprocessing, located industries located inMany Darkhan, food in Darkhan, food processing, vehicle repair, including and the production of woolenvehicle textiles,repair, carpets, and thesheepskins, productionand of clothing. woolen textiles, carpets,dressed dressed Lime quarrying and metal sheepskins, clothing. Lime quarrying and metal foundries have and also experienced a large growth, becoming imfoundries have also experienced a large growth, becoming portant contributors to the local economy. There has been a important contributors to the local economy. There has significant growth in the dairy industry and milk production been a significant growth in the dairy industry and milk too. The Darkhan Thermal Power Plant (a coal power plant) production too. The Darkhan Thermal Power Plant (a coal supplies electricity for the city, as well as to other power plant) supplies electricity for the city, as larger well ascities. to The of these othersize larger cities.enterprises varies greatly. In general, most enterprises are quite small. The size of these enterprises varies greatly. In general, The industry, which once the biggest employmostconstruction enterprises are quite small.wasThe construction er, has been declining overthe thebiggest past years and now industry, which once was employer, hasemploys been declining over the pastlabor yearsforce andofnow only only six percent of the the employs city. In the lastsix few percent the labor has forcebegun of thetocity. In thewith last few years, years, theof economy diversify investments thetransportation, economy has begun diversify with owing investments in storage andtocommunications to good in transportation, and communications owing road and rail links to storage other large cities such as Ulaanbaatar and to good road and rail links to other large cities such as Erdenet. Ulaanbaatar and Erdenet. The steel production and processing industry has experienced The steel production and processing industry has the greatest growth in the past few years. The Darkhan Metalexperienced the greatest growth in the past few years. lurgical Plant, located in the city of Darkhan, is the The Darkhan Metallurgical Plant, located in the only city steel of and iron processing plant in and Mongolia. The plant was Darkhan, is the only steel iron processing plantestabin lished in 1994 and employs 500 staff. produces 100,000 Mongolia. The plant was established in It1994 and employs tons steelIt per year from iron ore and 500 of staff. produces 100,000 tons of scrap. steel per year from iron ore and scrap. Environmental impact assessments have not been conducted Environmental impact assessments have not been for most of small enterprises. conducted for most of small enterprises. Critical concentrations of toxic heavy metals were reported at concentrations of toxic heavy metals were reported aCritical sampling site one kilometer downstream of the city of Darkat a sampling site one kilometer downstream of the citysamof han (MNET, 2011).The concentration of mercury at the Darkhan (MNET, 2011).The concentration of mercury at pling site was 0,5 µg/l. Increased concentrations of chromium the sampling site was 0,5 μg/l. Increased concentrations were also detected, which can be caused by pollution from of chromium were also detected, which can be caused by leather industries in the city. pollution from leather industries in the city. The Darkhan city The Darkhan city 4.3. Mining 4.3. Mining Open mining is one of the major sources of pollution in the Open mining is one of the major sources of pollution study foundare in the Kharaa in thearea. studySeveral area. mining Several reserves mining are reserves found in River Basin and occupy an area of about 16 percent the the Kharaa River Basin and occupy an area of aboutof16 total areaofofthe thetotal basin. percent area of the basin. The Darkhan city The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 53 53 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Some of the mines are not yet exploited, which Some of mines areand notdevelopment yet exploited, means thattheexploration liwhich of these meansreserves that may exploration and censes have been issued development licenses of these reserves may to mining companies, with mining operations have been issued to mining companies, with not having started. The mining area under opmining operations not having started. The eration 1.5operation percent ofrepresents the total area mining represents area under 1.5 of the basin, which is about 9.3 percent of the percent of the total area of the basin, which is total area for mining purposes (Figure 26). about 9.3 percent of the total area for mining purposes (Figure 26). One of the most productive gold mining sites of Mongolia, the productive Boroo Goldgold Mine, is located One of the most mining sites of the Mongolia, the Boroo Gold Mine, is located in Boroo River Basin, which is one of the in the Boroo River Basin, which one of Gol the tributary of the Kharaa River. TheisSharyn tributary of the Kharaa River. The coal Sharyn Gol Coal Mines—the second largest mining Coal Mines-the second largest coal mining company in Mongolia, which produces over company in Mongolia, which produces over 1.000.000 tons of coal per year—is also locat1.000.000 tons River of coal per year—is also ed in the Kharaa Basin. located in the Kharaa River Basin. There are no systematically observed data to There are no systematically observed data to assess pollution from from mining mining activities activities in in assess the the pollution the basin, which may have serious negative imthe basin, which may have serious negative pacts not not onlyonly on surface water quality, but also impacts on surface water quality, on groundwater and soil. Heavy metals (such but also on groundwater and soil. Heavy as mercury andascyanide) used metals (such mercurywere and commonly cyanide) were in small-scaleused gold in mines mines until themines use of commonly small-scale gold mines until the use of mercury mercury for mercury mercury for mining and extract minermining and extract minerals was banned in als was banned in 2008. 2008. Figure 26. Mining areas of the Kharaa river basin Figure 26. Mining areas of the Kharaa River Basin An incident of a possible mercury and An incidentcontamination of a possible mercury and cyanide cyanide of groundwater contamination of groundwater caused by a caused by a tailings spill from a small mining tailings spillinfrom a small mining in operation Khongor soum was operation recorded in Khongor 2007. soum was recorded in 2007. As project project (2009), concenAs part partof the of MoMo the MoMo (2009), concentrations heavy metals waters in surface trations of heavy of metals in surface and waters and the river sediment were measured. the river sediment were measured. The study The studythat indicated that the concentrations indicated the concentrations heavy metals heavy metals in the river water and sediment in theariver water and had a correlahad correlation to sediment mining activities and tion to mining activities and tended to increase tended to increase in areas downstream from in areas sites. downstream from River, miningforsites. In the mining In the Boroo example, Boroo River, forof example, of concentrations arsenic in concentrations the surface water arsenic in the surface water were above the were above the threshold level for drinking threshold level drinking water of 10 µg/l, water of 10 μg/l,for and elevated concentrations of arsenic, chromium,of mercury and and elevatedlead, concentrations arsenic, lead, nickel were found in the sediment. chromium, mercury and nickel were found in the sediment. usedQuality by a third party before with the of the Kharaa Riverconsulting Basin, Mongolia: 54 The intellectual property rights belong to UNOPS and UNDP, the information should not beWater Water Quality of the Kharaa River Basin, Mongolia: 54 project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Boroo Gold GoldMine Mine Boroo Boroo Gold GoldMine Mine(Figure (Figure27) 27)is islocated located The Boroo in in 110 kilometers to the northwest of the 110 kilometers to the northwest of the capital capital city of Ulaanbaatar 230 city of Ulaanbaatar and aboutand 230about kilometers kilometers south of the boundary international to the southto of the the international with boundary with Russia, at 48°45’ Russia, at 48°45’ North and 106°10’North East. and 106°10’ East. The Boroo Mine was the first hard-rock gold The Mine in wasMongolia the first and hard-rock gold mineBoroo established the largest mine established andatthe foreign investmentininMongolia the country thelargest time foreign investment in the country at the time it began production. The Boroo Gold Mine is itowned began by production. The Boroo Gold Mine the Canadian mining company,is owned by the Canadian CenCenterra Gold Inc. Itmining begancompany, commercial terra Gold Inc. began commercial production inItMarch 2004 and production produced more than2004 46 tons gold through in March and ofproduced more the thanend 46 of 2010 (www.boroogold.mn). The Boroo tons of gold through the end of 2010 (www. project consists of a suspended open-pit boroogold.mn). The Boroo project consists of an inactive processing amine, suspended open-pitheap mine,leach an inactive heap facility, an operating processing plant, leach processing facility, an operating processa tailings facility, ore and waste rock ing plant, a tailings facility, ore and waste rock stockpiles, and other surface infrastructure stockpiles, and other surface infrastructure nornormally associated with an open pit mining mally associated with anand open pit mining opoperation. Wastewater sludge from the eration. mining operation of the Boroo Gold Mine is stored in a tailings facility (a reservoir behind Wastewater and sludge from the mining operaa dam). tion of the Boroo Gold Mine is stored in a tailings facility (a reservoir behind a dam). ©Batimaa P., 2013 Figure 27. The Boroo Gold mining site Figure 27. The Boroo Gold mining site The tailings facility is located in the Ikh Dashir Valley and connected to the process plant by a five-kilometer pipeline (Figure 28). This facility received the government’s approval in 2003. It has a storage facility designed to store used water for reclamation and re-use. The bottom of the tailings facility is sealed with a compacted clay liner and a high-density polyethylene liner on all embankments. In 2007, Centerra Inc. constructed an extension to the original tailings dam. In 2008, lateral dykes were constructed for water management purposes. In 2009, an additional storage capacity was created by increasing the height of dykes in the north. In 2010, the facility increased the height of the south, east and west walls for further ex- pansion. In 2011, the tailings dam walls were raised by 2.5 meters and its final design capacity for the existing Boroo mineral reserves was completed. The current design of the tailings facility provides a total storage capacity of 16.9 million cubic meters of tailings, which is sufficient to store the entire volume of tailings over the lifetime of the mine. The leaching of the tailings is monitored at eight monitoring wells (MW), located downstream of the tailing dam. The monitoring of both groundwater levels and the water quality in the aquifers is conducted by an independent company and is reported to the (former) National Water Authority. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats assessment Pollution threatsand andhotspots hotspots assessment project. 55 55 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 28.The tailing facility of the Boroo mining Figure 28. The tailing facility of the Boroo mining ©Batimaa P., 2013 Table 21. Results of chemical analysis of the monitoring wells Table 21.Results of chemical analysis of the monitoring wells Elements K Na CI SO4 NO2 NO3 pH CN total CN free MAC levels (MNS 6148:2010) na na 3 350 500 1 50 6.5-8.5 0.1 MW#4 CN WAD 0.005 <0.002 Cr AI Mn na 0.07 0.5 <0.05 <0.02 <0.015 Mo Ba Zn Ni Co Ag U Fe As Cd 0.1 0.04 2 5 0.1 na 0.02 0.3 0.01 0.003 <0.01 <0.03 <0.05 <0.01 <0.01 <0.05 0.016 0.02 <0.01 <0.005 Cu Pb Hg 1 0.05 0.002 <0.01 <0.01 <0.001 Se 0.04 <0.05 1.93 112.8 0.34 97 242.3 0.14 2.79 7 <0.002 Averages of 2012 samples (January -October) Monitoring wells MW#7 MW#8 MW#9 MW#14 MW#4A 8.34 284 0.32 324 1042 0.14 8.36 6.88 <0.00 2 <0.00 2 <0.05 <0.02 <0.01 5 <0.01 <0.03 <0.05 <0.01 <0.01 <0.05 0.016 0.02 <0.01 <0.00 5 <0.01 <0.01 <0.00 1 <0.05 MW#3 MW#1 1.66 129.4 0.3 98.7 212.7 0.02 2.9 7.0 <0.001 2.34 65.5 0.3 80.8 196.5 0.05 2 7.1 <0.001 2.7 139.4 0.34 112 251.7 0.02 2.18 7.1 <0.001 2.76 113.6 0.32 110 315.8 0.15 5.2 7.0 <0.001 2.7 83.2 0.37 82.8 420 0.02 5.3 7 <0.001 2.19 96 0.45 61.5 120.2 0.02 5.7 6.9 <0.001 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.001 <0.05 <0.001 <0.001 <0.05 <0.001 <0.001 <0.05 <0.001 <0.001 <0.05 <0.001 <0.001 <0.05 <0.001 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.001 <0.05 <0.05 <0.001 <0.05 <0.05 <0.001 <0.05 <0.05 <0.001 <0.05 <0.05 <0.001 <0.05 <0.05 <0.001 <0.05 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Data source: Boroo Gold Mine, 2013 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 56 project. 56 Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The The average averagedepth depthofofthese thesemonitoring monitoringwells wellsis 50-65 meters, the groundwater table is 38.2 is 50-65 meters, the groundwater table to is 44.62 meters yieldand is 0.02 l/s.to 0.9 38.2 to 44.62and meters yieldtois0.9 0.02 l/s. According to the average values of the water According to theof average values the quality parameters 2012 of these eightofmonwater quality parameters of 2012 of these itoring wells (Table 21), the concentrations of eightpollutants monitoring (Table 21), the most were wells below the Maximum Acconcentrations of most pollutants were ceptable Concentrations in most of the below monithe Maximum Acceptable Concentrations toring wells, set in the Mongolian National in most of the monitoring wells, set in the Standard on Water Quality: Permissible Levels Mongolian National Standard on Water for Groundwater Pollutants MNS 6148:2010 Quality: Permissible Levels for Groundwater (NSA, 2010). Pollutants MNS 6148:2010 (NSA, 2010). In case, the concentration of a pollutIn only onlyone one case, the concentration of a ant exceeded the MAC level, where the conpollutant exceeded the MAC level, where centration of sulfatesof(SO4) in the Monitoring the concentration sulfates (SO4) in the Monitoring Well No.7 wasthan twice than Well No.7 was twice higher thehigher Maximum Acceptable Concentration value. Also, it was the Maximum Acceptable Concentration not clear whether concentrations selected value. Also, it was not clearof whether pollutants and some heavy metals such as and cyaconcentrations of selected pollutants nide cadmium (Se), cobalt some(CN), heavy metals(Cd), suchselenium as cyanide (CN), cadmium (Cd), (Se), (Hg) cobalt (Co), arsenic (As)selenium and mercury in (Co), some arsenic (As) and mercury (Hg) some wells exceeded the MAC values. Theinconcenwells exceeded the MAC trations of these pollutants werevalues. reportedThe as concentrations of these pollutants were less than certain levels, without indicating their reported as less than certain levels, without exact values. indicating their exact values. However, it still should be noted that in case of However, it still should be noted that in case aofleakage, the tailings fromfrom the mine may cause a leakage, the tailings the mine may heavy metals contamination in the Boroo River cause heavy metals contamination in the (a tributary Kharaa and conseBoroo Riverof(a the tributary of River) the Kharaa River) quently will have potentially seriouspotentially impacts on and consequently will have both surface wateronand groundwater resources serious impacts both surface water and of the Kharaa River Basin.of the Kharaa River groundwater resources Basin. 4.4. Agriculture 4.4. Agriculture Mongolia’s productive agricultural areas Mongolia’smost most productive agricultural lands are in found in the Kharaa Riverand Basin are found the Kharaa River Basin the and the surrounding region. The soil region’s soil surrounding region. The region’s and natand natural climatic conditions are favorable ural climatic conditions are favorable for the for the cultivation cereals and vegetables, cultivation of cerealsofand vegetables, especially especially potatoes. There are 35 agricultural potatoes. There are 35 agricultural producers producers and agricultural in and agricultural cooperativescooperatives in the Kharaa the Kharaa River Basin. River Basin. ing wheat11.9 and percent basic vegetables and occupies occupies of the total area of the Kharaa RiverofBasin. 30 11.9 percent the totalThis areaarea of thecontains Kharaa Rivthousand hectares of soil suitable for arable er Basin. This area contains 30 thousand hectcrops and 1,287.8 thousand hectares for ares of soil suitable for arable crops and 1,287.8 vegetable production. thousand hectares for vegetable production. Despite the expansion of the urban economy, Despite the expansion themain urbanactivity economy, livestock farming is stillofthe and livestock farming is still the main activity and major means of sustaining livelihoods and food major means of sustaining livelihoods and security of the rural population. There are apThe cropland in the valleys along the Kharaa food security of the rural population. There The the valleys the Kharaa 130,000 heads heads of livestock in the Rivercropland and its in tributaries is along used mainly for proximately are approximately 130,000 of livestock River and its tributaries is used mainly for growDarkhan-Uul aimag (NSO, 2010). growing wheat and basic vegetables and in the Darkhan-Uul aimag (NSO, 2010). Figure 29. 29. Cropland Cropland area area on Figure on the the Kharaa Kharaa River River bank bank The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 57 57 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 30. Bornuur cropland farming near the Boroo Riverbank Figure 30. Bornuur cropland farming near the Boroo River bank In Mongolia, in Mongolia, the theuse useofofchemical chemicalfertilizers fertilizers agriculture is insignificant. Traditionally, fertilizin agriculture is insignificant. Traditionally, fertilizer is not forproduction. cereals production. er is not used forused cereals Currently, Currently, natural fertilizer such as animal natural fertilizer such as animal manure is the manure is the most widely used fertilizer most widely used fertilizer for vegetables. Acfor vegetables. According provided to the information cording to the information by the of3 of and the Ministry of provided by the officials ficials of the Ministry of Food Agriculture, Food and Agriculture, the total fertilizer use the total fertilizer use is about 1,200 tons per is about 1,200 tons per year in Mongolia. year in Mongolia. Consequently, the impact of Consequently, the impact of fertilizer use fertilizer use in agriculture on the water quality in agriculture on the water quality of the of the Kharaa River Basin is insignificant, Kharaa River Basin is insignificant, givengiven the the insignificant amount of fertilizer in insignificant amount of fertilizer used used in crop crop production. production. to, or directly on, the banks of the Kharaa close to, or directly on, the banks of Rivthe er (Figures 29 and 30). The the Kharaa River (Figures 29 proximity and 30). ofThe proximitytoofsurface the cropland to surface waters cropland waters may have potential may have potential impacts on water quality impacts on water quality and sedimentation of andriver sedimentation of the river systems of the the systems of the basin. basin. According to data of land use and land cover According to data of2006), land use andthan land60 cover studies (Hudelmer, more perstudies (Hudelmer, 2006), more than 60 cent of the total area of the Kharaa River Bapercent of the total area of the Kharaa River sin is used as pasture land for livestock grazBasin is used as pasture land for livestock ing. Hence, the livestock grazing is the ismajor grazing. Hence, the livestock grazing the non-point sourcesource of pollution to surface waters, major non-point of pollution to surface leading fecal contamination and direct nutriwaters, to leading to fecal contamination and ent inputs to the river water during warm seadirect nutrient inputs to the river water during However, thethe cropland is located close sons. However,some someofof cropland is located warm seasons. 4.5. Pollution hotspots mapping 4.5. Pollution hotspots mapping Based on the identification of major pollution sources in the Kharaa River Basin, a pollution Based onmapping the identification of major pollution hotspots was carried out. The areas sources in the Kharaa River Basin, a pollution of concern, or potential pollution hotspot, have been identified regard to The potential hotspots mapping waswith carried out. areas impacts on the of surface waters and of concern, or quality potential pollution hotspot, groundwater resources in regard the Kharaa River have been identified with to potential Basin. impacts on the quality of surface waters and groundwater resources in the Kharaa River Ba- The overview of the areas of concern in the Kharaa River Basin is shown in Figure 31. sin. overview of the areas of concern in the TheThe pollution hotspots mapping has shown Kharaa River Basin is shown in Figure 31. similar results as the major points of concern identified by the MoMo project (2009). The pollution hotspots mapping has shown similar results as the major points of concern identified by the MoMo project (2009). 3Statement of Mr. Sh. Baranchuluun, Senior officer at Ministry of Industry and Agriculture, during the National Workshop conducted in the framework of Mr. Sh.Mongolia, Baranchuluun, Senior officer at Ministry of Industry and Agriculture, during the NaofStatement this study in Ulaanbaatar, on 04 June 2013 3 tional Workshop conducted in the framework of this study in Ulaanbaatar, Mongolia, on 04 June 2013 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 58 project. 58 Water Quality ofofthe Water Quality theKharaa KharaaRiver RiverBasin, Basin,Mongolia: Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Figure 31. Map of areas of concern (potentialpollution pollution hotspots) Figure 31.Map of areas of concern (potential hotspots)ininthe the Kharaa River Basin Kharaa River Basin 4.6. Environmental and health impacts Kharaa River Basin became a Mongolia’s waters and groundwater systems across the 4.6.The Environmental and region health impacts major industrial and agricultural basin. Other environmental factors such as in the late 1950’s and early 1960’s with the establishment of the industrial city of The Kharaa River Basin became a and Mongolia’s Darkhan (on 17 October 1961) an agroindustrial farming complex to change the major industrial and agricultural region in the country’s base traditional late 1950’s and economic early 1960’s withfrom the establishlivestock production into modern ment of the industrial city of Darkhanindustrial (on 17 and agricultural economies. The political October and an agro-industrial and 1961) economic changes from the farming socialist complex to tochange the country’s economic regime a democratic system and a market base from traditional livestock production economy in 1990-1991 resulted ininto the collapse of agricultural production. Currently, modern industrial and agricultural economies. the agricultural sector is rebounding The political and economic changes from with the increasing wheat production over the past socialist regime to a democratic system and a several years. deforestation, over-grazing, and land use changes resulting from the extensive tillage offorpollutants tocrop surface waters and cereal and production havegroundwater become increasingly apparent, too. As a result of these systems across the basin. Other environmental environmental impacts of industrial andand factors such as deforestation, over-grazing, agricultural activities, the lower and middle land use changes resulting from the extensive reaches of the basin have shown degradation tillage cereal and crop production have beof the for pristine natural environment. come increasingly apparent, too. As a result of these environmental The water demand in impacts the basinofis industrial increasing and year after year due tothe population growth, agricultural activities, lower and middle industrialization, mining development, reaches of the basin have shown degradation of irrigated agriculture and lifestyle ofgrowth the pristine natural environment. changes. Furthermore, climate change impacts are becoming more evident. The The water in thechanges basin isand increasing current anddemand future climate their year after coupled year duewith to population impacts, enhanced growth, climate invariability, will likely increase water scarcity dustrialization, mining development, growth the Kharaa River Basin, as well as in ofin irrigated agriculture and lifestyle changes. treated municipal and industrial wastewater Mongolia as a whole (Batimaa et al, 2005 Furthermore, climate change impacts are bedue to outdated wastewater plants has led to and 2011). The industrial agricultural development of coming more evident. The current and future increasingand loadings of pollutants to surface market economy in 1990-1991 resulted in the collapse agricultural production.development Currently, Theof industrial and agricultural the agricultural sector is rebounding inof the region, hence, has become with the main driver of environmental change in the creasing wheat production over the past sevKharaa River Basin. The discharge of poorly eral years. the region, hence, has become the main driver climate changes and their impacts, coupled of environmental change in the Kharaa River with enhanced climate variability, will likely inThe intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Basin, Basin.Pollution The discharge ofassessment poorly treated munici- crease water scarcity in the Kharaa River 59 threats and hotspots project. pal and industrial wastewater due to outdated as well as in Mongolia as a whole (Batimaa et wastewater plants has led to increasing loadings al, 2005 and 2011). UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Hence, the impact of climate change on water resources’ and water availability is seen as an equally important concern for the future water Hence, thecountry. impact of climate change on supplies of the water resources’ and water availability is an equally important concern for the Sinceseen theas 1990 transition, mining activities future water supplies of the country. have grown significantly in the region and gold mining is playing an increasingly important part Since the 1990 transition, mining activities have grown significantly in the region and gold mining is playing an increasingly in the country’s economy. With the expansion of the mining industry, concerns over environmental and health impacts of mining activities important part in the country’s are becoming increasing important,economy. especially With the of the mining because theexpansion Boroo Gold Mine (one ofindustry, the most concerns over environmental and productive gold mines in Mongolia) is health located impacts of mining activities are becoming in the Kharaa River Basin. increasing important, especially because the Boroo Gold Mine (one of the most productive gold mines in Mongolia) is located in the Kharaa River Basin. Figure 32. Runoff forming and river bank protection zone Figure 32. Map of areas of concern (potential pollution hotspots) in the Kharaa River Basin Several incidents of releases of hazardous and highly toxic substances such as mercury and Several of releaseswere of hazardous cyanide intoincidents the environment caused and by highly toxic substances such as mercury and lack of compliance with environmental and cyanide into the environment were caused by health regulationswith for environmental the management lacksafety of compliance and and health disposal of tailings from mining activities. safety regulations for the management and disposal of tailings from mining activities. The The most serious incidentincident occurred occurred in Khongorin most serious April 2007 and was caused soumKhongor in Aprilsoum 2007inand was caused by the reby the release of large quantities of mercury lease of large quantities of mercury and cyanide the soil and groundwater into and the cyanide soil andinto groundwater from a smallfrom a smallscale mining operation. The scale mining operation. The Khongor incident Khongor incident has raised a serious has raised a serious concernthe over among the loconcern over among local population cal population over environmental and health over environmental and health effects effects which might result this environwhich might result fromfrom this environmental contamination. The initial investigations mental contamination. The initial investigations were conducted jointly by the World Health were conducted by the World Health Organization, the jointly joint UNEP/OCHA EnvironOrganization, the joint UNEP/OCHA ment Unit, and the Mongolian authorities and Environment Unit, and the Mongolian highlighted the need to conduct a health risk authorities and highlighted the need to assessment the population at risk. conduct a for health risk assessment for Upon the request of theatMongolian Government, Joint population risk. Upon request ofa the UN mission Government, consisting of international experts Mongolian a Joint UN mission consisting of international experts from the from the World Health Organization (WHO), World Health Organization (WHO), the the United Nations Environmental Programme United Nations Environmental Programme (UNEP) and the Food and Agriculture Organi(UNEP) and the Food and Agriculture zation (FAO), took place in February-March Organization (FAO), took place in February2008 to assess situation regardswith to efMarch 2008 the to assess thewith situation fects of mercury andofcyanide contamination regards to effects mercury and cyanideon human health, food animal health, contamination onproduction, human health, food production, animal health, The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 60 60 project. Water Quality of of thethe Kharaa River Basin, Mongolia: Water Quality Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" and TheThe results of neurological and medical and the theenvironment. environment. results of neurological and medical examinations conducted by WHO among the examinations conducted by WHO among the local population local at risk noteffects suggest any health effects at risk population did not suggest anydid health which could be attribwhich beexposure attributed mercury exposure or acute uted to could mercury or to acute cyanide poisoning. cyanide poisoning. To address growing concerns over environmental and concerns health impacts of the miningindustry, To address growing over environmental and health the Parliament of Mongolia adopted the Law on Prohibition impacts of the miningindustry, the Parliament of Mongolia of Mineral Exploration and Mining Activities in areas in adopted the Law on Prohibition of Mineral Exploration and the Headwaters of Rivers, River Protection Zones and Mining Activities in areas in the Headwaters of Rivers, River Forested Areas (2009). This law prohibits any economic Protection andthe Forested Areas of (2009). law prohibactivity in Zones areas of headwaters rivers,This streams, and its any economic activity inofareas the headwaters creeks and in a distance 200ofmeters and more ofinrivers, the streams, creeks and inConsequently, a distance of 200 more riparian and zone of a river. themeters formerand Water in the riparian of a river. the former Water Authority has zone identified riverConsequently, protection zones in all rivers Authority has identified river zones all rivers in in Mongolia. The Institute of protection Meteorology andinHydrology Mongolia. Thealso Institute of Meteorology and has dehas defined the headwaters areas ofHydrology all river basins of Mongolia. The map ofareas the of river protection zones and fined also the headwaters all river basins of Mongolia. headwaters areas the Kharaa River is shown inof The map of the riverofprotection zones andBasin headwaters areas Figure 32. the Kharaa River Basin is shown in Figure 32. The Orkhon River Valley A Hayland The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 61 61 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 62 The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Water Quality of the Kharaa River Basin, Mongolia: project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Conclusionsand and 5.5.Conclusions Recommendations Recommendations The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. ©Batimaa P., 2013 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 5.1. Conclusions The Kharaa River Basin is one of the main tributaries of the Orkhon-Selenge River system, which ultimately drains to Lake Baikal. The Orkhon River is the longest river in Mongolia and the valley along the river is an archaeologically-rich cultural landscape. The Orkhon Valley Cultural Landscape has been designated by UNESCO as a World Heritage Site. The Selenge River is the largest river by volume of flow. The upper basin is in a relatively pristine state and has experienced minimal anthropogenic impacts. The lower basin is characterized by diverse economic activities such as industry, agriculture and livestock breeding, which may potentially have significant impacts on the quantity and quality of water resources of the basin. Furthermore, the basin provides drinking water for the rapidly-growing Darkhan City, which water supplies largely rely on alluvial aquifers containing shallow-depth groundwater, and the inhabitants of small human settlements in the basin. Driven by climate change, urbanization and rapid economic growth, Mongolia’s water resources are under increasing pressure. The Kharaa River Basin is facing relatively high anthropogenic pressures on both water quality and water quantity from rapid urbanization, rising water demand and climate change. The pollution of the Kharaa River Basin is becoming a growing concern due to the high vulnerability of the basin to urban and industrial pollution. The assessment of water quality and water pollution in the Selenge River Basin, undertaken by this study, focused on a case-study on pollution hotspots and pollution threats in the Kharaa River Basin, including urban water pollution in the city of Darkhan, Mongolia. The main objectives of this study were to assess the current state of the water quality of the Kharaa River Basin, assess water pollution from diffuse and point sources, identify pollution hotspots in the basin, and determine the main pressures on the water quality of the Kharaa River, with a qualitative description of their impacts. The study focused on: the survey of water quality characteristics of the Kharaa River; the identification of anthropogenic impacts on the river’s water quality; the identification of major threats to the water quality in the basin; and the development of recommendations on pollution prevention and control in the Kharaa River Basin. The assessment of the water quality in the Kharaa River is based on both hydrochemical and hydrobiological parameters. The hydrochemical assessment is based on hydrochemical monitoring data collected by the Central Laboratory for Environment and Meteorology for the period from 1986 through 2011. The hydrobiological assessment is based on macroinvertebrates data collected by the Institute of Meteorology, Hydrology and Environment for the period from 2005 to 2010. As part of the Mongolia’s freshwater quality monitoring network, the Kharaa River water quality has been monitored at four sampling points at two monitoring stations since 1986. The upper monitoring station, which is the reference site of the study, is located near Zuunkharaa (a small urban settlement) and has two sampling points upstream and downstream from Zuunkharaa. The second monitoring station is located near to Darkhan city and has two sampling points too-upstream and downstream from the city. The overall assessment of the chemical composition has shown good chemical conditions at all sampling sites on the Kharaa River. The Kharaa River water is moderately mineralized and moderately hard. The monthly mean concentrations of total dissolved salts (the sum of Ca2+, Na++K+, Mg2+, HCO3 -, SO4 2- and Cl-), or mineralization, in the Kharaa River vary between 162.2-335.7 mg/l and show a tendency to increase towards downstream. The concentrations of total dissolved salts increase also during snow melting periods. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 64 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" In thethe order of of abundance of of catInaavast vastmajority majorityofofthe thecases, cases, order abundance 2+ 2+ + + + + 2+2+ >Na >Mg , and , andthe theorder orderof ofabundance abundanceof cations >Na +K+K>Mg ions is Cais Ca - 2->Cl-. The pH values range 2->SO of anions is HCO anions is HCO ->SO >Cl . The pH values range between 3 4 4 3 between 6.5 and 8.5, which is within the standard range 6.5 and 8.5, which is within the standard range for river wafor river waters. ters. Thedissolved dissolvedoxygen oxygen concentration of the Kharaa The concentration of the Kharaa RiverRiver range range from 3.8 to 14.0 mg/l. The concentrations biological from 3.8 to 14.0 mg/l. The concentrations biological oxygen oxygen demand (BOD) varies between 0.3 mg/l and 7.8 demand (BOD) varies between 0.3 mg/l and 7.8 mg/l. In most mg/l. In most of the cases, the BOD concentrations are of the cases, the BOD concentrations are below theofMaximum below the Maximum Acceptable Concentration 5 mg/l, Acceptable Concentration 5 mg/l, theNational standard Standard set by the the standard set by the ofMongolian Mongolian for Water Quality of the Aquatic for Water National Quality Standard of the Aquatic Environment: General Environment: MNS 4586-98.that ThisininRequirementsGeneral MNS Requirements 4586-98. This indicates dicates general is clean. However, generalthat the inriver waterthe is river clean.water However, it should be it should be noted that concentrations the BOD concentrations occasionally noted that the BOD occasionally exceed the Maximum Acceptable Concentrations (5 mg/l)(5atmg/l) bothat exceed the Maximum Acceptable Concentrations sampling sitessites during summer. ThisThis maymay show thatthat organic both sampling during summer. show organpollutants originating from urban and industrial areas ic pollutants originating from urban and industrial areasand and livestockwastes wastesenter enter river surface washing livestock thethe river withwith surface washing during duringrainfall heavyevents rainfallinevents in summer. heavy summer. Monthly mean concentrations of ammonium-nitrogen Monthly mean concentrations of ammonium-nitrogen (NH4(NH4-N) range between 0.09 and 0.38 mg/, while the N) range between 0.09 and 0.38 mg/, while the concentrations concentrations of nitrate-nitrogen (NO3-N) vary from of nitrate-nitrogen -N) period vary from 0.01 to 0.84 mg/l for the 0.01 to 0.84 mg/l(NO for 3the from 1985 to 2010. The period from 1985oftophosphate 2010. The (PO4-P) concentrations phosphate concentrations are in ofthe range (PO -P) are in the range from 0.01 to 0.21 mg/l. The phosphate from 4 0.01 to 0.21 mg/l. The phosphate concentrations concentrations in the Kharaa Rivermuch were much thanthe the in the Kharaa River were lowerlower than nitrogen concentrations. Both phosphate and nitrogen connitrogen concentrations. Both phosphate and nitrogen centrations showshow a decreasing trendtrend nearnear Zuunkharaa, while concentrations a decreasing Zuunkharaa, while there is no trend near the city of Darkhan. The there is no trend near the city of Darkhan. The concentrations concentrations of NO3-N near Zuunkharaa of NO3-N near Zuunkharaa have decreased since 1990s.have Simidecreased since 1990s. Similarly, PO4-P concentrations larly, PO4-P concentrations have decreased near Zuunkharaa. have decreased near Zuunkharaa. The nutrient concentrations in the Kharaa River water usually The nutrient concentrations in thetime Kharaa River water increased during spring and summer and sometimes exusually increased during spring and summer time ceeded the Maximum Acceptable Concentrations by the order and sometimes exceeded the Maximum Acceptable of 2 to 3 times. However, the number of cases, in which the Concentrations by the order of 2 to 3 times. However, nutrient concentrations MAC concentrations levels represents the number of cases, inexceeded which thethe nutrient less than 5 percent of levels all samples. exceeded the MAC represents less than 5 percent of all samples. There are very limited observed data on metals, except for are measured iron (Fe) (Cr6+) ions, There areand verychromium limited observed datawhich on metals, except forat 6+ the sampling(Cr points of both monitoring sites. The ) ions, which are measured at irondownstream (Fe) and chromium the downstream sampling points of both monitoring sites. monthly mean concentrations of Fe vary between 0.08 and The mg/l monthly mean concentrations of during Fe vary between 0.15 with concentrations increasing rainy seasons. 6+ 0.15 mg/l with concentrations increasing during 0.08 and The Cr concentrations range below the detection level to range below the rainymg/l seasons. Theincrease Cr6+ concentrations 0.01 and also in rainy seasons. detection level to 0.01 mg/l and also increase in rainy seasons. Water crown The Selenge River Bayangol crop area Horses under a tree A hot day The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 65 65 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" At the upper reaches of the river near the Zuunkharaa monitoring station, the quality of the Kharaa River water can be classified as ‘very clean’ to ‘clean’, except for few cases. The river water quality decreases in lower reaches of the river near the city of Darkhan. However, more than 95 percent of the all samples show that the river’s water quality can be classified as ‘clean’. A slight deterioration in the river’s water quality to the ‘slightly-polluted’ level is observed during high-water periods of snowmelt in April to May, as well as in low-water periods in June. The analysis of the macro-invertebrate communities at the two monitoring sites of the Kharaa River watershed indicates that the ecological condition of the river is good. The assessment of the fish communities has shown a good, or a very good, ecological status at the sites. A moderate status, detected at two sites in the watershed, is caused by the absence of ubiquistic species, showing no clear deficits in the ecological integrity of the fish fauna. Most of the fish species are known to occur in the Kharaa River Basin. According to the Biotic Index and EPT criteria, the water quality of the Kharaa River can be classified as ‘clean’ at both monitoring sites. However, the water quality of the Kharaa River has been decreasing at the reach near Baruunkharaa since 2005, while it stays stable at Darkhan. This shows that the quality of the river’s water at the reach near Baruunkharaa has been continuously declining for the last six years. In general, the water quality of the Kharaa River is lower in spring and improves in summer. The groundwater of the Kharaa River Basin has a similar chemical composition as the Kharaa River water. In general, the calcium and bicarbonate are the dominant ions at all groundwater sampling points. The order of abundance of cations is Ca2+>Na++K+>Mg2+,whereasthe order of abundance of anions is HCO3->SO4 2- >Cl-. The nutrient level in groundwater in aquifers in the Kharaa River Basin is very low, indicating that groundwater is clean. The major point source of pollution appears to be the wastewater treatment plants in urban areas. There are five wastewater treatment plants in the Kharaa River Basin, two of which discharge their treated wastewater directly into the Kharaa River. The other three plants have no direct outlet to the Kharaa River. Most soums (small towns) do not have wastewater treatment facilities and infrastructure. A majority of households in soums use simple traditional pit latrines in their compounds. The Darkhan WWTP is biggest in the basin and discharges its treated wastewater directly into the Kharaa River. The wastewater treatment rate of the plant varies between 76.8 and 98.1 percent. However, in most of the time, the treatment rate is below 90 percent, which means to a certain extent that polluted water is discharged into the Kharaa River. The WWTPs in Zuunkharaa, Baruunkharaa and Khongor soums, which are located in the upstream reaches of the basin, are smaller and have no direct outlet to the Kharaa River. On the other hand, the treated wastewater of these plants is discharged to infiltration ponds and the sludge is disposed of in sludge fields close to the Kharaa River. The sludge field of the Zuunkharaa WWTP is located particularly close to the river bank and therefore, there is a potential risk of pollution of groundwater, soil and river water by leakage from the sludge ponds. During high water periods, especially in snow melting times, the water quality of the Kharaa River deteriorates to ‘moderatelypolluted’ and ‘very-polluted’ near urban settlements such as Darkhan, Baruunkharaa and Zuunkharaa. This indicates that the Kharaa River water quality is highly vulnerable to pollution; in particular, in areas close to point sources of pollution, such as urban areas, and in source areas of diffuse pollution, such as agriculture and mining. Open mining is one of the major sources of pollution in the study area. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 66 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Several large mining reserves are located in the Kharaa River Basin and occupy an area of about 16 percent of the total area of the basin. Some of the mines are not yet exploited. The Boroo Gold Mine, which is one of the most productive gold mines of Mongolia, is located in the basin. There are no systematically observed data to assess the pollution from mining activities in the basin, which may have serious negative impacts not only on surface water quality, but also on groundwater and soil. Heavy metals (such as mercury and cyanide) were commonly used in small-scale gold mines until the use of mercury for mining and extract minerals was banned in 2008. Elevated concentrations of heavy metals, but not exceeding the MAC levels, were detected in groundwater in monitoring wells near the tailings facility of the Boroo Gold Mine. An incident of a possible mercury and cyanide contamination of groundwater caused by a tailings spill from a small mining operation in Khongor soum was recorded in 2007. Mongolia’s most productive agricultural areas are found in the Kharaa River Basin and the surrounding region. The region’s soil and natural climatic conditions are favorable for the cultivation of cereals and vegetables, especially potatoes. The use of chemical fertilizers in agriculture is insignificant. Traditionally, fertilizer is not used for cereals production. Natural fertilizer such as animal manure is the most widely used fertilizer for vegetables. According to the information provided by the officials of the Ministry of Food and Agriculture, the total fertilizer use is about 1,200 tons per year in Mongolia. Consequently, the impact of fertilizer use in agriculture on the water quality of the Kharaa River Basin is insignificant, given the insignificant amount of fertilizer used in crop production. However, some of the cropland is located close to, or directly on, the banks of the Kharaa River. The proximity of the cropland to surface waters may have potential impacts on water quality and sedimentation of the river systems of the basin. More than 60 percent of the total area of the Kharaa River Basin is used as pasture land for livestock grazing. Hence, the livestock grazing is the major non-point source of pollution to surface waters, leading to fecal contamination and direct nutrient inputs to the river water during warm seasons. The assessment also shows that the self purification rate in the Mongolian rivers is usually high with the distance of self purification of 6 to 18 kilometers. The self purification distance of the Kharaa River appears to be 10 kilometers downstream from the city of Darkhan. Consequently, the Kharaa River water becomes clean at its outlet at the confluence with the Orkhon River, with no adverse impacts on the water quality of the Orkhon and Selenge rivers. In overall, the results of the study show that the water quality of the Kharaa River Basin is clean and has good ecological conditions, although The water quality of the Kharaa River decreases occasionally to ‘moderatelypolluted’ and ‘very-polluted’ near urban and industrial areas, as well as during high water periods and snow melting times. This shows that moderate pollution occurs near urban areas and in snow melting periods, with no serious degradation in the water quality of the whole basin. The main sources of water pollution in the basin are urban areas, agriculture and mining activities. Due to rapid urbanization and economic development, pollution from municipal wastewater and mining activities may become a concern in the future. Furthermore, the Kharaa River Basin is facing growing pressures from climate change and rising water demands. Hence, the sustainable use and management of water resources of the Kharaa River Basin is of crucial importance in securing future water supplies in the area. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. 67 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 5.2. Recommendations Based on the results of the water quality assessment of the Kharaa River Basin, the following observations are made and recommendations for future improvements in key areas are outlined below. Water quality monitoring • The monitoring and analysis of key water quality parameters such as dissolved oxygen, biological oxygen demand, and heavy metals is limited to only the Darkhan monitoring station. It is recommended to modify the monitoring programme and include all these parameters in all sampling points of all monitoring stations in order to identify more reliably the sources of pollution. • The water quality monitoring does not hydrological parameters such as the river water discharge. It is recommended to measure the river streamflow at the time of water sampling. • The Kharaa River water quality monitoring is carried out once a month during the months from April through November at the Zuunkharaa (upstream) monitoring station, and once a month throughout the year at the Darkhan monitoring station. Samples are collected mostly in the second half of each month. It is recommended to increase the sampling/ monitoring intervals and carry out sampling according to hydrological conditions (for example, snowmelt, summer baseflow, heavy rain events, etc.) in addition to the routine sampling intervals. • The monitoring carries out the chemical analysis only of the river water, but not of bottom sediments and particulate matters in the river water. It is recommended to analysis particulate matters in the river water. Particulate matters and bottom deposits are an important factor in the study of water quality in that it yields valuable information about the source of settle able particulate solids, the effect of the sediments on the quality of the overlying water and the biological system that will predominate. • There is no regular groundwater quality monitoring in the Kharaa River Basin. The existing groundwater monitoring wells do not monitor the quality of groundwater. It is recommended to establish a groundwater monitoring network in the basin to monitor both the water level and quality of groundwater. • The sampling sites for chemical and biological monitoring are located in different parts of the basin. It is recommended to conduct biological, and chemical monitoring at the same sites, if possible. Wastewater management • The wastewater treatment plants are the main source of pollution. The wastewater treatment plants in the basin are outdated, poorly maintained and based on obsolete technology. There is a need to make substantial investment to upgrade existing wastewater treatment plants and build new ones. • The Darkhan Wastewater Treatment Plant, which is the biggest in the basin, is not able to fully treat raw sewage before discharging the treated wastewater directly into the Kharaa River. Its wastewater treatment rate is mostly below 90 percent. The Salkhit Wastewater Treatment Plant also discharges its treated wastewater directly into the Kharaa River after only primary mechanical and biological treatment. It is recommended to rehabilitate urgently the Darkhan and Salkhit Wastewater Treatment Plants, which discharge their effluents directly into the Kharaa River. • The wastewater treatment facilities in the small cities and villages in the Kharaa River Basin are mostly out of operation. Most of these facilities discharge their treated The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 68 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" wastewater in in infiltration ponds. The wastewater infiltration ponds. Thesludge sludgefrom fromthese theseplants plants is disposed of inofsludge fieldsfields located close close to the to Kharaa River. is disposed in sludge located the Kharaa River. This raises a concern over groundwater and This raises a concern over groundwater nutrientsnutrients and heavy heavy metal contamination leakage from sludge metal contamination by leakagebyfrom sludge fields. It isfields. recIt is recommended to reconstruct the wastewater treatment ommended to reconstruct the wastewater treatment plants in Zuunkharaa, Baruunkharaa, and Khongor soums in plants Zuunkharaa, Baruunkharaa, and Khongor soums and reand rehabilitate infiltration ponds and sludge fields of these habilitate infiltration ponds and sludge fields of these facilifacilities. ties. Agricultural pollution Agricultural pollution A groundwater well At the well river banks of the RiverRiver Basin—especially, the • • TheThe river banks of Kharaa the Kharaa Basin—especialBoroo River bank near Bornuur—are heavily used for ly, the Boroo River bank near Bornuur—are heavily used for cropland, leading to soil erosion. This, in cropland, leading to soil and and riverriver bankbank erosion. This, in turn, turn, causes increased suspended solids in the river water. causes increased suspended solids in the river water. It is rec-It is recommended to the limituse the use of river banksfor forcultivation cultivation ommended to limit of river banks and implement soil conservation tillage measures. and implement soil conservation tillage measures. useuse of chemical fertilizers in agriculture is insignificant. • • TheThe of chemical fertilizers in agriculture is insignifiCurrently, natural fertilizer such as animal manure is the the cant. Currently, natural fertilizer such as animal manure is most widely used fertilizer for vegetables. The impact of most widely used fertilizer for vegetables. The impact of fertilfertilizer use in agriculture the quality water quality of the Kharaa izer use in agriculture on the on water of the Kharaa River River Basin is insignificant, given the insignificant amount Basin is insignificant, given the insignificant amount of fertilizer of fertilizer used in crop production. It istoencouraged to used in crop production. It is encouraged avoid and/or avoid and/or restrict the use of chemical fertilizers in the restrict the use of chemical fertilizers in the future. future. A forest near the Kharaa River The rainbow Mining pollution Mining pollution • Open mining is one of the major sources of pollution in • Open mining is one of the major sources of pollution the study area. There are no systematically observed data to in the study area. There are no systematically observed data to assess the pollution from mining activities in the basin. The assess the pollution from mining activities in the basin. The wawater use and waste management is controlled in the most ter use and waste management is controlled in the most of the of the mining sites. However, the amounts of toxic waste mining sites. However, the amounts of toxic waste containing containing heavy metals particularly mercury and cyanide heavy metals particularly mercury and cyanide are unknown. are unknown. A more systematic monitoring and reporting A more systematic monitoring and reporting of compliance of compliance with environmental regulations needs to be with environmental regulations needs to be developed for developed for all mining operations. all mining operations. • Heavy metals (such as mercury and cyanide) were • commonly Heavy used metalsin(such as mercury cyanide) comsmall-scale goldand mines untilwere the use of monly used in small-scale gold mines until the use of mercury mercury for mining and extract minerals was banned in for2008. miningThere and extract minerals was banned in 2008. There up is is a need to implement measures to clean a need to mercury implement measures to clean up residual merresidual in the environment. cury in the environment. • An incident of a possible mercury and cyanide • contamination An incident ofofa possible mercury andcaused cyanide contamgroundwater by a ination of groundwater caused by a tailings spill from a small tailings spill from a small mining operation in mining operation soum was recorded in 2007. Khongor soum in Khongor was recorded in 2007. Such cases Such cases may have potentially serious impacts on the may have potentially serious impacts on the Tailing facility the Boroo mining Birds in the tailingoffacility of the Boroo mining The Orkhon River The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment Pollution threats and hotspots assessment project. 69 69 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" environment and human health and should be avoided in the future. There is an urgent need to implement “responsible mining” practices and closely monitor the environmental safety of mining operations in the basin. Mining pollution • Although the water quality of the Kharaa River Basin is clean and has good ecological conditions, the water quality of the Kharaa River decreases occasionally near urban and industrial areas. It is recommended to take necessary measures to enhance and protect the water quality of the Kharaa River from urban and industrial pollution. • Climate change is likely to increase the river bank erosion in addition to the impact of agricultural activities near the river banks. In order to reduce the river bank erosion, it is recommended to introduce river bank prevention measures, such as planting trees along the river bank. • The Kharaa River water at its confluence to the Orkhon River is still clean. It is, however, needed to make efforts to preserve the water quality of the river in order to maintain the integrity of the basin and its ecosystems. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 70 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the project. UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" References 1. Barbour, M.T., J. Gerritsen, B.D. Snyder, and J.B. Stribling. 1999. Rapid Bioassessment Protocols for Use in Streams and Wadeable Rivers: Periphyton, Benthic Macroinvertebrates and Fish, Second Edition. EPA 841-B-99-002. U.S. Environmental Protection Agency, Office of Water, Washington, D.C. 2. Batimaa, P., B.Bolortsetseg, T.Ganbaatar, B.Erdenetsetseg, M.Erdenetuya, T. Hudelmer, 2005. Climate change impact on natural resources base. The potential Impacts of Climate Change and V&A Assessment for the Livestock sector in Mongolia. Ulaanbaatar, Admon. pp.151. 3. Batimaa, P., 1998. Water chemistry and quality of the rivers in Mongolia. Executive summary of the Ph.D. Thesis. Ulaanbaatar. 4. Batimaa, P., B. Myagmarjav, N.Batnasan, N. Jadambaa, and P.Khishigsuren, 2011. Urban water vulnerability to climate change in Mongolia. Water Authority, Mongolia. pp.26-33. 5. Batsukh, N., 2007. Hydrogeological Report for Darkhan. Ulaanbaatar, National University of Mongolia. 6. Battsetseg, M., 2011. Changes in the Kharaa River water regime. In Climate Change in Cool Climate: Water Resources and Permafrost. Workshop proceedings. Muren, Khuvsgul. pp.45-51. 7. Boroo Gold Mine, 2013. Report on Groundwater Monitoring 2012. Boroo Gold LLC. 8. Bulgan, T., 2008. Methodologies for chemical analysis in water. Ministry of Nature, Environment and Tourism (MNET), Ulaanbaatar, pp. 166-167. 9. Myagmarjav, B., G. Davaa, R. Oyunbaatar, S.Tumurchudur, 2012. Surface Water Resources Assessment. in Integrated Water Resources Management Plan Development. Ulaanbaatar. Volume 1. pp. 9-98. 10. Central Laboratory for Environment and Meteorology, 2013. The Kharaa River Water Hydro-chemical Data Analysis. (Unpublished report prepared for this study by Erdenebayar Y.) 11. Dorjgotov, D., 2003. Soils of Mongolia. Ulaanbaatar. pp 24. 12. Dulmaa, A., 1999. Fish and Fisheries in Mongolia. In T. Petr (ed.) Fish and Fisheries at Higher Altitudes: Asia. 385, Rome. 13. UNIDO, 2013. Hot-Spot and TEST methodologies. Available on: http://www.unido.org/what-we-do/environment/ 14. Hudelmer, D., 2006. Land Cover Change in Mongolia. Ulaanbaatar. (unpublished technical report) 15. Hunt, R.J., and I.H.Christiansen, 2000. Dissolved Oxygen: Information Kit. ACRC Sugar Technical Publication. 16. Institute of Meteorology, Hydrology and Environment, 2013. The Kharaa River Water Hydrobiological Data Analysis. (Unpublished report prepared for this study by Tumertsooj D.) The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 72 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" 17. Jadambaa, N.,2000. Groundwater Quality Overview. Ulaanbaatar. (unpublished technical report) 18. Jadambaa, N.,2012. Groundwater Assessment of Mongolia. Technical report. Ulaanbaatar. 19. Ministry of Environment, Nature and Tourism (MNET), 2011. Research report on waste management in Darkhan city, Ulaanbaatar, Mongolia. 20. MoMo, 2009. Integrated Water Resources Management for Central Asia–MoMo” Final report. 21. Myagmarjav, B., and G. Davaa (eds),1999. Surface Water Resources of Mongolia. Ulaanbaatar. 22. National Atlas, 2009. Institute of Geography (Editor: Dorjgotov D.) Ulaanbaatar. 23. National Standard Agency (NSA),1998. National Standard for Water Quality of the Aquatic Environment: General Requirements. MNS 4586-98. Ulaanbaatar. 24. National Standard Agency (NSA), 2010. Mongolian National Standard on Water Quality: Permissible Levels for Groundwater Pollutants MNS 6148:2010. Ulaanbaatar 25. National Standard Agency (NSA), 2011.Mongolian National Standard for Discharge of Treated Wastewater into the Environment MNS 4943-2011. Ulaanbaatar 26. NSO, 2010. Population and housing inventory. Ulaanbaatar. 27. NSO, 2010. Statistics 2011. Ulaanbaatar 28. Vidon, P., C. Allan, D. Burns, T. P. Duval, N. Gurwick, S. Inamdar, R. Lowrance, J. Okay, D. Scott, and S. Sebestyen, 2010. Hot spots and hot moments in riparian zones: potential for improved water quality management, in Journal of the American Water Resources Association. Vol.46, No.2, pp 278-298. The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. 73 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Annex 1. Mongolian National Standard for Water Quality of the Aquatic Environment: General Requirements. MNS 4586-98. Ulaanbaatar. (in Mongolian) 2. Mongolian National Standard on Water Quality: Permissible Levels for Groundwater Pollutants MNS 6148:2010 (in Mongolian). 3. Mongolian National Standard for Discharge of Treated Wastewater into the Environment MNS 4943-2011. Ulaanbaatar. (in Mongolian) The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 74 project. Water Quality of the Kharaa River Basin, Mongolia: UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" Data analyses 1. The Kharaa River Water Hydro-biological Data Analysis for the period 2005-2010 A data analysis report prepared based on data provided by the Institute of Meteorology, Hydrology and Environment of Mongolia. The report was prepared in the framework of this study by Tumertsooj D. (in Mongolian language) 2. The Kharaa River Water Hydro-chemical Data Analysis for the period 1986-2011 A data analysis report prepared based on data provided by the Central Laboratory for Environment and Meteorology of Mongolia. The report was prepared in the framework of this study by Erdenebayar Y. (in Mongolian language) The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the Pollution threats and hotspots assessment project. 75 UNDP-GEF project "Integrated Natural Resource Management in the Baikal Basin Transboundary Ecosystem" The intellectual property rights belong to UNOPS and UNDP, the information should not be used by a third party before consulting with the 76 project. Water Quality of the Kharaa River Basin, Mongolia: