Sequence stratigraphy, hydrostratigraphy, and mineralizing fluid
Transcription
Sequence stratigraphy, hydrostratigraphy, and mineralizing fluid
Sequence stratigraphy, hydrostratigraphy, and mineralizing fluid flow in the Proterozoic Manitou Falls Formation, eastern Athabasca Basin, Saskatchewan E.E. Hiatt1 and T.K. Kyser2 Hiatt, E.E. and Kyser, T.K., 2005: Sequence stratigraphy, hydrostratigraphy, and mineralizing fluid flow in the Proterozoic Manitou Falls Formation, eastern Athabasca Basin, Saskatchewan; in EXTECH IV: Geology and Uranium EXploration TECHnology of the Proterozoic Athabasca Basin, Saskatchewan and Alberta, (ed.) C.W. Jefferson and G. Delaney; Geological Survey of Canada, Bulletin 588 (also Saskatchewan Geological Society, Special Publication 17; Geological Association of Canada, Mineral Deposits Division, Special Publication 4). Abstract: The Manitou Falls Formation, deposited during the early evolution of the eastern Athabasca Basin, is composed of flat-lying, unmetamorphosed sandstone and conglomerate that change stratigraphically upward from polymictic pebble conglomerate to medium-grained quartz arenite. This succession has been subdivided into lithofacies that are diachronous by nature. Variations in lithofacies and paleoenvironment are useful for lithostratigraphic correlation, but do not allow resolution of chronostratigraphic horizons. Drill cores along two transects were studied, thickness of fluvial fining-upward successions were recorded, and these were plotted stratigraphically. Thickness of fining-upward intervals is used as a proxy for accommodation. These show systematic changes from times of low accommodation marked by coarse-grained intervals followed by gradual shifts to greater accommodation and finer-grained intervals. A hydrostratigraphic model for the eastern Athabasca Basin is presented based on integration of sedimentology, sequence stratigraphy, and diagenesis. The two basal sequences contain aquifers that onlap basement rock units eastward and focused burial brines. 1 2 Department of Geology, University of Wisconsin, Oshkosh, Wisconsin, 54901 U.S.A. Department of Geological Sciences and Geological Engineering, Queen’s University, Kingston, Ontario K7L 3N6 1 GSC Bulletin 588 INTRODUCTION The Athabasca Basin (Fig. 1) of northern Saskatchewan hosts the world’s largest known high-grade unconformity-type uranium deposits and has been the subject of many studies (Kyser et al., 2000 and references therein). These include pioneering studies of basinwide lithostratigraphy by Ramaekers (1990), and those concerning mineralogical and geochemical characteristics of rocks within, and away from, uranium mineralization (Hoeve and Quirt, 1984; Wilson and Kyser, 1987; Kotzer and Kyser, 1992, 1995; Fayek and Kyser, 1997; Holk et al., 2003). Broad-based regional studies that have considered the evolution of the Athabasca Basin are rare, and stratigraphic relationships have not been documented in detail until this bulletin (e.g. Ramaekers et al., 2005). The interconnected role that sedimentology, stratigraphy, and diagenesis played in controlling mineralizing fluid flow has never been adequately documented. The recognition that sedimentological and stratigraphic variation, even in a thick, coarse-clastic sediment-filled continental basin, can cause major differences in the subsequent hydraulic properties of the resulting rock (e.g. Hiatt et al., 2003) suggests that the linkages between sedimentology, stratigraphy, and diagenesis in the Athabasca Basin need to be addressed. There are many difficulties inherent in the investigation of Proterozoic sedimentary successions; primary among these are the absence of fossils to guide paleoenvironmental interpretation, the dominance of braided fluvial systems in terrestrial settings, and the paucity of exposures. In the Phanerozoic, fossils provide the basis for both paleoenvironmental interpretation and regional correlation. Correlation in Proterozoic sedimentary rocks, on the other hand, must rely totally on physical and/or chemical characteristics. The dominance of braided fluvial systems also makes lithological correlation difficult because without land plants to bind floodplain sediments, very little mud is deposited, resulting in extensive, thick, amalgamated sand and gravel-dominated, sheet-like deposits (e.g. Schumm, 1968). These factors contributed to the difficulties in understanding regional and even local stratigraphic variation in clastic sediment-filled Proterozoic terrestrial basins, like the Athabasca Basin. Rivers flowing into the Athabasca Basin were sourced in the Trans-Hudson Orogeny to the east and deposited most of the gravel to medium-grained sand that comprises the Manitou Falls Formation (Fig. 2). The Manitou Falls Formation, which is the focus of this study, records the early dynamic history of the eastern Athabasca Basin. Notwithstanding the new lithostratigraphic nomenclature introduced by Ramaekers et al. (2005), this paper is based on and utilizes the lithofacies of Ramaekers (1990). The ability to predict and project stratigraphic relationships is essential for understanding sedimentary basin-hosted, unconformity-type uranium mineralization in the Athabasca Basin because fluid flow related to mineralization is controlled by stratigraphic relationships (Holk et al., 2003). Figure 1. Map showing the study area, general geology, and location (inset) of the Proterozoic Athabasca Basin, Canada. The locations of some major unconformity-type uranium deposits are shown by black dots. Athabasca Basin formations are: FP = Fair Point, S = Smart, RD = Read (hereafter referred to as MFa), MF = Manitou Falls (members b (u = upper, l = lower), r, w, c and d), LZ = Lazenby Lake, W = Wolverine Point, LL = Locker Lake, O = Otherside, D = Douglas, C = Carswell). Modified from Ramaekers and Catuneanu (2004) and Ramaekers et al. (2005). 2 E.E. Hiatt and T.K. Kyser Figure 2. Stratigraphic subdivision, position of major unconformities and hiatuses (grey), sedimentary environmental interpretations, sediment source areas, and estimated relative base-level change for the subbasins of the Athabasca Basin (modified from Ramaekers, 1990; Ramaekers et al., 2005; this study). The relative base-level curve depicts major changes in basin dynamics, such as tectonic uplift, subsidence, and eustasy. The dashed line represents the point at which base-level fall could allow a marine transgression into the basin (based on data from this study for the Manitou Falls Formation and Ramaekers (1990) for the entire Athabasca Group). This suggests that stratigraphy played a role in determining the hydrostratigraphy of the basin and thus in the mineralization process. Existing lithofacies correlation is useful for regional correlation (up to tens of kilometres), but lithofacies are a product of paleoenvironmental changes, which are diachronous. For the most part, the lithofacies represent variations in energy of the river systems. Such changes can occur both at local and regional scales and have no chronostratigraphic significance. To achieve a better understanding of the hydrology of the basin, the present authors developed a sequence stratigraphic model for the Manitou Falls Formation to provide a spatial and temporal framework in which to understand its hydrostratigraphic evolution. The goal of this work is to identify and correlate time-equivalent stratigraphic units and internal bounding surfaces that controlled hydrological flow regimes (cf. Miall, 2000). Mineralization processes in sedimentary basins are often related to regional movement of chemically active fluids (e.g. Garven and Freeze, 1984; Kotzer and Kyser, 1995; Fayek and Kyser, 1997; Lee, 1997; Renac et al., 2002). Direct geochemical evidence for these processes is recorded in the coarsegrained conglomerate and sandstone units of the Manitou Falls Formation where significant fluid (brine) flow in the deep burial setting has occurred (e.g. Kotzer and Kyser, 1995; Fayek and Kyser, 1997; Renac et al., 2002; Holk et al., 2003). Isotopic, chemical, microthermometric, and petrological data indicate that the Athabasca Basin has had a protracted fluid history unlike that documented for any Phanerozoic sedimentary basin (Kyser et al., 2000). Therefore, understanding fluid movement throughout the basin is of primary importance for mineral exploration (e.g. Garven and Freeze, 1984; Bethke, 1986; Fayek and Kyser, 1997; Kyser et al., 2000). Understanding sedimentary basin hydrodynamic systems has long been a goal of petroleum geologists and has allowed evolution of hydrological systems to be tracked through critical intervals during which fluid migration occurred in burial settings (e.g. Tyler and Finley, 1991; Harrison and Tempel, 1993; Galloway and Hobday, 1996; Selley, 1998). These concepts, however, have not been widely applied to sediment-hosted mineral systems. The purposes of this paper are: 1) to present a stratigraphic model for the Mantiou Falls Formation that may facilitate correlation of intraformational sequences, and 2) to test whether there are sedimentological and stratigraphic controls over diagenesis, and if so, 3) to present an integrated sequence stratigraphic and hydrostratigraphic model for the eastern Athabasca Basin. GEOLOGICAL SETTING The Athabasca Basin began as a series of northeastsouthwest-oriented subbasins (Fig. 3A) at 1750–1700 Ma (Ramaekers, 1980; Armstrong and Ramaekers, 1985; Kotzer and Kyser, 1992, 1995; Ramaekers and Catuneanu, 2004). These early subbasins were controlled by major northeastsouthwest faults associated with the Hudsonian Orogeny and rooted in underlying Paleoproterozoic metasedimentary rocks and Archean gneiss units (Ramaekers, 1990). The 1–2 km thick Athabasca Group (Fig. 2, 3) makes up the sedimentary basin fill, and consists of flat-lying, quartz-rich 3 GSC Bulletin 588 The Athabasca Group sedimentary rocks and the basement complex are cut by a series of northwest- and east-trending mafic dykes that were emplaced along fractures reactivated during tectonic activity between 1350 Ma and 900 Ma, postdating the Athabasca Group deposition (Ey et al., 1991). The dykes are believed to be related to the Mackenzie dyke complex (Cumming and Kristic, 1992) and are the only preserved evidence of igneous activity throughout the evolution of the basin. Temperature estimates derived from fluid inclusions indicate that the Manitou Falls Formation was buried to about 5 km depth during the peak diagenesis (Pagel et al., 1980). Uranium mineralization occurred at 1700–1600 Ma with remobilization events at ca. 900 Ma and earlier than 400 Ma (Kyser et al., 2000). Relation between tectonism and formation of the Athabasca Basin The Athabasca Basin is an intracratonic basin with no direct evidence of rift-related igneous activity. Cumming and Kristic (1992) reported U-Pb ages of 1700–1650 Ma for fluorapatite from the Athabasca Basin that they interpreted as a minimum age of deposition in the basin. The basin probably formed at ca. 1750 Ma based on timing of rapid uplift in the region of the Trans-Hudson Orogen that was likely a major source of sediment that comprises most of the Manitou Falls Formation (Kyser et al., 2000; Ramaekers and Catuneanu, 2004). Multiple fluid events, involving isotopically and chemically distinct fluids that migrated laterally for considerable distances and along fault zones, produced a paragenetically identifiable assemblage of clay, silicate, and oxide minerals in the basin and basement rocks (Kyser et al., 2000). Isotopic, chemical, microthermometric, and petrological data indicate that the major sandstone aquifers in the Athabasca Basin, which were most pronounced in the coarse-grained basal units, have been affected by widespread lateral flow of diagenetic fluids over distances of hundreds of kilometres (Kyser et al., 2000). These fluids appear to have been present in the basinal conglomerate and sandstone units at temperatures in excess of 200oC for a minimum of 600 Ma (Kyser et al., 2000). Circulation of these warm brines and their reactions with minerals in basin-filling clastic rocks occurred in response to tectonic events, such as those associated with intrusion of the Mackenzie dykes and the break-up of Rodinia (Kyser et al., 2000). Fluid migration paths followed stratigraphic units above unconformities (Holk et al., 2003). The stratigraphic pathways, however, were modified by crossformational fluid flow near active fault zones (Kyser et al., 2000). Figure 3. A) Locations of subbasins, major faults, and diabase dykes (Mackenzie dykes) in the Athabasca Basin. B) Cross-section of the basin showing the basic stratigraphic units. Modified from Ramaekers (1981). sandstone and conglomerate interpreted to have been deposited in major river systems and near-shore to shallow-shelf marine environments (Ramaekers and Dunn, 1977; Ramaekers, 1990), recently reinterpreted as mostly fluvial (Ramaekers and Catuneanu, 2004; Ramaekers et al., 2005). Crystalline basement rocks underlying the Athabasca Group are mantled by a well developed paleoregolith that extends to a depth of several metres where it has not been removed by erosion (Hoeve and Sibbald, 1978). The faults cutting the Athabasca Group are major crustal lineaments that have remained intermittently active to recent times (Hoeve and Quirt, 1984). The Paleoproterozoic metasedimentary rocks and Archean gneiss that comprise the basement are components of the Wollaston Domain of the Trans-Hudson Orogen (Lewry and Sibbald, 1979, 1980; MacDonald, 1985). Paleoproterozoic metasedimentary rocks that unconformably overlie the Archean granitoid gneiss units consist mostly of quartz, plagioclase, biotite, cordierite, garnet, and tourmaline, with several anatectic and graphitic layers (Ey et al., 1991; Marlatt et al., 1992). Quartzite units are locally developed and are generally separated by intervals of garnet-cordierite gneiss (Marlatt et al., 1992). 4 E.E. Hiatt and T.K. Kyser Sedimentology and stratigraphy The basal sequence of the late Paleoproterozoic to Mesoproterozoic Athabasca Group (Fair Point and Manitou Falls formations) consists of quartz-rich conglomerate and sandstone (Fig. 2) with paleocurrent indicators suggesting a predominately east to west transport direction (Ramaekers, 1990; Ramaekers and Catuneanu, 2004). Most framework grains in the Manitou Falls Formation are quartz, with very minor muscovite, up to 15% lithic clasts (quartzite, gneiss, schist, and sandstone), and rare heavy minerals, such as zircon and apatite. The absence of preserved feldspar and rarity of other minerals further suggests relatively long transport, intense weathering, and/or diagenetic alteration of remaining feldspar during burial diagenesis. The sandstone units of the Manitou Falls Formation are overlain by a succession of less permeable marine sandstone, phosphatic siltstone, and phosphatic mudstone (the Lazenby Lake and Wolverine Point formations, respectively), which are in turn overlain first by sandstone (Locker Lake and Otherside formations), then by shale (Douglas Formation), and finally by stromatolitic dolomite (Carswell Formation; Fig. 2). Lithofacies subdivision of the Manitou Falls Formation Ramaekers (1979) defined the Manitou Falls Formation and informally subdivided it into members, based on lithofacies characteristics (Ramaekers, 1980). This lithofacies classification has proven useful in the eastern Athabasca Basin where correlation between closely spaced exploration drill cores is needed; however, it is difficult to apply beyond the eastern portion of the Athabasca Basin (Cree subbasin; Fig. 4A; Ramaekers et al. (2005)). A brief summary of the informal lithofacies subdivisions is given below. The newly defined Read Formation (Ramaekers et al., 2005) (MFa) lithofacies is composed of conglomerate, sandstone, and minor sandy mudstone. It is thickest in the east-central part of the basin, but it is absent throughout much of the northeastern, northern, and western portions of the basin (Fig. 4B; Ramaekers (1990)). The rapid thinning of MFa to the north, east, and west suggests that, unlike the overlying Manitou Falls Formation, MFa was sourced from the south and may have been the result of tectonic uplift during the initial stages of basin evolution. Ramaekers (1990) interpreted this unit as having been bounded by unconformities, and deposited in marine and fluvial environments. Ramaekers and Catuneanu (2004) and Ramaekers et al. (2005), however, interpreted all of the Manitou Falls Formation as having been deposited in fluvial and possibly large lake depositional systems. The Manitou Falls Formation unit B (MFb; Fig. 4C) lithofacies is defined as sandstone interbedded with clast-supported conglomerate beds that are greater than or equal to 2 cm thick (Ramaekers, 1980). Ramaekers (1990, p. 15) noted that the clast-supported conglomerate beds are best preserved in drill core because their lack of matrix and paucity of cement makes them friable and easily eroded in outcrop. From these characteristics Ramaekers (1990) deduced that the MFb lithofacies may have been much more widespread than is suggested by preserved outcrops. In much of the study area (and in much of the Cree subbasin; Fig. 4C) MFb directly overlies the basal unconformity with metamorphic basement. The Manitou Falls Formation unit C (MFc; Fig. 4D) lithofacies is defined as those units of the Manitou Falls Formation with less than 1% mud intraclasts and that contain conglomerate layers that are less than 2 cm thick (Ramaekers, 1980). The contact between MFc and the underlying MFb is gradational and conformable (Ramaekers, 1990). In the central and western portion of the Athabasca Basin, MFc appears to directly overlie paleohighs on the basal unconformity underlying Manitou Falls Formation (Ramaekers, 1990). The Manitou Falls Formation unit D (MFd; Fig. 4E) lithofacies is composed of sandstone units that are generally well sorted and make up beds with greater than 1% of mud intraclasts (Ramaekers, 1990). The contact with the underlying MFc lithofacies is gradational and conformable, but MFd is overlain disconformably both by the Lazenby Lake Formation in the south and west, and by the Wolverine Point Formation in the north (Ramaekers et al., 2005). The MFb, MFc, and MFd lithofacies are all interpreted to represent braided fluvial depositional systems with energy levels generally decreasing through time. Ramaekers (1990, p. 20), however, discovered a stratigraphic interval in the MFd lithofacies (west-central Athabasca Basin; NTS map area 74 F) that he interpreted as a possible marine shoreline facies in the upper Manitou Falls Formation, although Ramaekers and Catuneanu (2004) and Ramaekers et al. (2005) interpreted the entire Manitou Falls Formation as representing fluvial and possibly lacustrine deposition. METHOD AND RESULTS Six drill cores from two strategic locations in the eastern Athabasca Basin were examined, described, and logged in detail. Samples were collected from each major stratigraphic unit, and 80 of these were analyzed petrographically in this study (Fig. 5). Outcrop exposures are generally poor in the eastern Athabasca Basin and provide only fragmentary stratigraphic information due to their limited thickness. Exploration drill cores provide extensive continuous stratigraphic records (e.g. more than 830 m of continuous core in RL-51; Fig. 5; 6A, see colour folio). At each location a core was chosen proximal to known mineralization and others were chosen distal to mineralization as a means to test whether stratigraphy affected fluid flow and diagenesis. Lithological data collected for each drill core included mean grain size, maximum clast size, sorting, sedimentary structures, and framework grain composition. Sedimentary structures are generalized on the lithological columns, and stratigraphic changes in mean grain size are represented by the width of the column profile (Fig. 6A, B). Abrupt changes in grain size and facies associations, and lithofacies defined by Ramaekers (1980), noted above, were recorded and are also represented graphically in Figures 6A and B. 5 GSC Bulletin 588 Figure 4. Maps of the Athabasca Basin showing: A) the position of subbasins, and B)–F) isopach thicknesses of lithostratigraphic units defined by Ramaekers (1980). Modified from Ramaekers (1990). 6 E.E. Hiatt and T.K. Kyser Figure 5. Map of the study area showing the McArthur River and Cigar Lake uranium deposits and drill-core transects used in the stratigraphic analysis in this study. Base map modified from Ramaekers et al. (2005). Lithofacies in the Manitou Falls Formation unit A, B, C, and D are represented by MFa, MFb, MFc, and MFd, respectively. Facies associations Five major lithofacies associations were identified in the Manitou Falls Formation (Fig. 6A, B). Facies association 1 (alluvial fan association) consists of matrix-supported polymictic lithic conglo}erate with matrix- and clast-suoported fabrics, pebbly lithic wacke, and moderately sorted lithic arenite. The pebbly to cobbly conglomerate and sandstone are medium grey to tan, and contain abundant metamorphic quartzite, gneiss, and schist clasts that locally make up more than 15% of the rock. Trough crossbedding, scour surfaces, mudcracks, and asymmetrical ripple crosslaminae are present. Many matrix-supported conglomerate units have angular clasts, suggesting mass wasting and deposition by debris flows associated with alluvial fans. Other units in this coarse-grained, mud-rich, heterolithic lithofacies suggests rapid deposition in high-energy, proximal braided river systems where seasonal rainfall resulted in rapid deposition of both coarse- and fine-grained sediment, fine-grained sediments were exposed, mudcracks formed, and were periodically ripped up in high-energy stream-flow events. Lithofacies association 2 (proximal braided stream association) is composed of clast-supported lithic to quartzose conglomerate that in most places grades stratigraphically upward into very coarse- to coarse-grained, moderately to well sorted, sublithic to quartz arenite. Lithic clasts (primarily fragments of gneiss and schist, but including some sandstone clasts) rest directly on major erosional surfaces, suggesting that episodes of downcutting and stream rejuvenation punctuated this association. Beds fine upward stratigraphically and are commonly pebbly at the base, but grade upward into coarse-grained sandstone; trough crossbedding is abundant. This lithofacies is interpreted to represent high-energy, proximal, in-channel deposition of braided stream gravel and sand bars (cf. Miall, 1996). Lithofacies association 3 (distal braided stream association) is composed of thin granule to pebble beds that generally overlie scour surfaces and grade upward into coarse- to medium-grained, moderately to well sorted quartz arenite. This association is interpreted to represent moderate- to low-energy conditions in distal braided stream systems where much of the sand was transported in large sand bars, subaqueous dunes and sand waves, and by sheet flow on submerged braidplains (cf. Miall, 1996). Lithofacies association 4 (estuarine–braid delta association) is marked by well sorted, well rounded, generally medium-grained quartz arenite with thin, well rounded, quartz granule laminae. Abundant mud intraclasts are concentrated on bedding surfaces. Current ripple marks and ripple crosslaminae are pervasive throughout this association. Minor, thin mud laminae form mud drapes over ripple marks. This association is interpreted to represent distal braided stream, estuarine, and braid delta deposition (cf. McCormick and Grotzinger, 1993). Lithofacies association 5 (upper shoreface association) is composed of medium-grained, well sorted quartz arenite with small-scale trough crossbedding, heavy mineral bands, and pervasive early quartz cementation. This lithofacies is only found in the lower sequence in core MAC-224. An unconformity separates this interval from the overlying Manitou Falls Formation. This lithofacies is interpreted to represent an upper shoreface setting in either a marine or lacustrine paleoenvironment. 7 GSC Bulletin 588 Fining-upward cycle thickness and stratigraphic correlation Abrupt changes from finer to coarser grain size are commonly accompanied by the appearance of lithic clasts (primarily metamorphic rock fragments). Such changes may be followed by a gradual shift to finer grain sizes, and changes in clast composition from polycrystalline to monocrystalline quartz. These variations, along with changes in grain size and position of erosional surfaces, were measured and plotted stratigraphically for each drill core in both transects (Fig. 7A, B, see colour folio). The data used in the stratigraphic plots were smoothed by calculating a running average (window size of two) to compensate for possible errors in measurement of fining-upward cycle thickness. These fining-upward packages largely represent deposition of dunes and bars in fluvial channels. Major rapid changes in fining-upward package thickness were used to correlate changes in accommodation (Fig. 7A, B). Correlation along each of the transects suggests topographic relief was important early in the depositional history of the Manitou Falls Formation. The authors estimate that there was 85 m of relief over 15 km distance, or 6 m vertical change per kilometre in the McArthur River transect, and 30 m relief over 1500 m, or 20 m vertical change per kilometre in the Cigar Lake transect. Petrography and diagenesis Diagenesis varies with lithofacies and stratigraphy due to such factors as: the variable amount of mud matrix present, original clast composition, sorting, and grain size. Quartz cement is a major diagenetic component in the Manitou Falls Formation. Quartz cement is virtually absent in units that are clay-rich, such as the matrix-supported conglomerate of the alluvial fan lithofacies association (Fig. 8A). Quartz cement becomes important where interstitial clay is less abundant, such as in the grain-supported conglomerate units that characterize the proximal braided fluvial associations (Fig. 8B, C). Early quartz cement and paleosol horizons characterize the well sorted lithofacies of the basal sequence in core MAC-224 (Fig. 8D, E). The paleosol interpretation is based on primary textures such as mechanically infiltrated mud-filled vugs with internal horizontal laminations. The early cement phase filled pore space and prevented significant pressure solution. In well sorted, interstitial clay-poor lithofacies, pressure-solution–generated silica drives precipitation of typical burial quartz cement (Fig. 9A, B). Most stratigrapic units that did not experience early cementation commonly experienced intense pressure solution creating sutured grain-to-grain boundaries (Fig. 9C, D). Where matrix clay was present, chemical compaction coupled with clay diagenesis commonly resulted in removal of earlier formed quartz cement through replacement (Fig. 9E, F). A detailed paragenesis for the Manitou Falls Formation across the entire basin was developed by Kotzer and Kyser (1992, 1995), refined by Fayek and Kyser (1997), and is here updated in Figure 10. Early diagenetic events include precipitation of pore-filling quartz cement in the MFa (Qa), precipitation of pressure-solution–derived quartz cement (Q1), chemical compaction, precipitation of authigenic 8 phosphate (crandalite), and crystallization of hematite on dust rims of detrital grains. Overall, the hydraulic conductivity of the Manitou Falls Formation remained relatively high where quartz cementation was either inhibited or earlierformed cement was replaced by clay minerals. These units preferentially would have allowed fluid movement, and thus were important for basin hydrology during burial diagenesis. DISCUSSION The coarse clastic rocks that make up the Manitou Falls Formation represent deposition in a continental basin initially marked by alluvial fans, braided rivers, and possible shallow-marine environments (Ramaekers, 1990). Ramaekers and Catuneanu (2004), however, interpret the marine environments as possible lake to eolian environments. The Proterozoic age of this succession and the absence of interbedded volcanic rocks that can be traced regionally make paleoenvironmental determination and correlation difficult both because of the absence of fossils, and because without land plants to trap and bind fine-grained alluvial plain sediments, braided streams would have dominated the landscape in which mud was rarely deposited and preserved (e.g. Schumm, 1968). Without lithological or paleontological markers, a new approach is needed to provide intraformational correlation and a means to understand the basic foundation for diagenesis, and the resulting hydrostratigraphy of the eastern Athabasca Basin. The sequence stratigraphic model offers a possible means to build such a stratigraphic framework, but outcrop extent and quality of Proterozoic rocks are generally not sufficient to allow lateral tracing of surfaces, the detection of erosional truncation, or the recognition of incised valleys and sequence boundaries. Therefore, any new approach to understanding the stratigraphy of Proterozoic continental deposits must include a means to recognize changes in basin dynamics (uplift, subsidence, eustasy) within generally monotonous lithofacies from limited outcrop exposures and drill core. This requires an understanding of the relationship between lithofacies, paleoenvironments, and their chronostratigraphic significance. Lithofacies and paleoenvironments in the Manitou Falls Formation To clarify the relationship between lithofacies and stratigraphic changes due to basin-scale processes the authors identified and recorded Ramaekers (1980) lithofacies and recognized five broad lithofacies associations based on interpreted paleoenvironments (Fig. 6A, B). Ramaekers (1980) subdivided the Manitou Falls Formation into the MFa, MFb, MFc, and MFd lithofacies based on simple criteria that make field classification easy, however, these subdivisions are based on factors that were largely controlled by variations in paleoenvironmental conditions (primarily changes in fluvial flow-energy levels). It is important to recognize the relationships between lithofacies, paleoenvironments, and their diachronous nature. E.E. Hiatt and T.K. Kyser The MFa lithofacies is heterolithic and contains facies marked by angular pebbles and cobbles with a matrixsupported texture overlain by matrix-rich sandstone units containing mudchips and mudcracks (Fig. 6A, B) that suggest an alluvial fan setting. In one location (MAC-224; Fig. 5, 6A) MFa is marked by paleosol horizons and an interval of well sorted quartz arenite with small-scale crossbeds. A) The MFa in the westernmost core in this study (RL-51; Fig. 5, 6A) is marked by a thick interval of coarse sandstone and moderately to well sorted quartzose clast-supported conglomerate units that represent high-energy, proximal, braided stream deposition. E) dq dq MC dq dq Qa dq 5 µm 2 mm B) dq MC Figure 8. A) Photomicrograph in planepolarized light showing angular quartz grains (dq) supported by a clay-rich mud matrix (MC) that, along with lack of interbedding or fabric suggests that this unit of MFa was deposited in a debris flow. B) Photomicrograph in plane-polarized light showing quartz-pebble conglomerate with angular to well rounded sand and gravel grains (dq) with a poorly sorted, clast-supported texture characteristic of the proximal braided fluvial facies association. Quartz cement (Qa) appears to predate significant grain-to-grain compaction and, although it effectively blocks pore throats, the moderate amount of mud matrix (MC) present inhibited cementation. C) Same field of view as in Figure 8B, but in cross-polarized light using the mica plate (1/4 wavelength) to highlight subtle differences in birefringence. D) Photomicrograph in plane-polarized light that shows a well sorted, well rounded, mediumgrained quartz arenite from MFa lithofacies in which detrital quartz grains (dq) are completely surrounded by hematite inclusion-rich quartz cement (Qa). The cement predates significant compaction as indicated by the minor degree to which grains have experienced pressure solution. E) Same field of view as in Figure 8D, but in cross-polarized light with the mica plate inserted. Qa dq 1 mm C) dq MC Qa dq 1 mm D) dq dq dq Qa 5 µm 9 GSC Bulletin 588 A) B) dq dq PS PS Q1 dq 250 µm Q1 dq 250 µm D) C) MC dq dq dq dq sb sb sb sb 500 µm 500 µm E) F) dq dq Q1 Dk 50 µm dq Q1 50 µm Dk dq Figure 9. A) Photomicrograph in plane-polarized light of a well sorted quartz arenite from MFd lithofacies in which well rounded detrital grains (dq) have undergone pressure solution (PS) as indicated by the abundance of convex-concave grain-to-grain contacts. Silica derived from pressure solution is reprecipitated in remaining pores as blocky quartz cement (Q1) indicating that this cement phase is contemporaneous with or postdates chemical compaction. B) Same field of view as in Figure 9A, but in cross-polarized light. C) Photomicrograph in plane-polarized light of a moderately sorted quartz arenite that has undergone significant pressure solution as indicated by the well developed solution boundaries (sb) at grain contacts. Quartz cementation may have been inhibited in this unit by the presence of a small amount of clay (MC), perhaps carried by groundwater into the pores. D) Same field of view as in Figure 9C, but in cross-polarized light and with the mica plate inserted. E) Photomicrograph in plane-polarized light showing detrital quartz grains (dq), burial quartz cement (Q1) and dickite clay (Dk). Dickite replaced the earlier-formed quartz cement as indicated by the dickite-filled caries in the cement. F) Same field of view as in Figure 9E, in cross-polarized light. 10 E.E. Hiatt and T.K. Kyser Mineral Precompaction qartz overgrowth Stage E Hydrothermal alteration Late meteoric Temp (°C) events <70 Qa Quartz overgrowth Q1 Chemical compaction Cm Hematite (A-mag.) H1 Crandallite P1 Chlorite basement C1, C2 Illite + dickite diagenetic I1, K1 Hematite (B-mag.) H2 150– 170 Fluid Low-latitude meteroricwater Pore-fluids (10–25 wt % NaCl) Basement fluids (reducing) Quartz+dravite alteration halo Q2,T1 Uranium U1,U2 Fluorapatite A2 X1 Xenotime Cu-Ni-As-sulphides S1 Rutile R1 Hematite (C-mag.) H3 Dravite fractures T2 Kaolinite pervasive K2 Pyrite fractures S2 Uranium fractures U3 Siderite vugs S Kaolinite fractures K3 U1 U2 180– 240 <50 1.7 1.4 1.0 Mid-latitude basinal brine (oxidizing; 30– 33 wt % NaCl) High-latitude meteroric waters (<5 wt % NaCl) 0.4 Age (Ga) Figure 10. Paragenesis of minerals in the Athabasca Basin as a function of time. E = early, near surface (< 2 km burial) stage of diagenesis. Major diagenetic events that established the hydrostratigraphy of the basin, as well as the primary uranium mineralization events are highlighted by shade-filled boxes. The H1 hematite phase (A-mag.) occurs throughout the Athabasca Basin and has been interpreted as a paleomagnetic direction that occurred at 1600–1750 Ma (Kotzer and Kyser, 1992). H2 hematite is coincident with peak diagenesis and a paleomagnetic age (B-mag.) of 1450–1600 Ma (Kotzer and Kyser, 1992). The H3 hematite (C-mag.) is coincident with recrystallization of uraninite (U2) and is association with final stages of the Grenville Orogeny and onset of Rodinia break up at ca. 900–1000 Ma (Kotzer and Kyser, 1992; Kyser et al., 2000). Modified from Kyser et al. (2000). The MFb lithofacies corresponds exclusively to our high-energy, proximal, braided stream association (Fig. 6A, B) and is marked by coarse-grained, clast-supported, quartz-rich conglomerate and moderately to well sorted quartz arenite that contain abundant trough crossbedding. This initial interval of coarse sediment is overlain by a variably developed, finer, sandy interval that probably represents subsidence in the basin and a decrease in overall stream energy. As noted by Ramaekers (1990) the contact between MFb and overlying MFc is gradational. The fact that MFc reaches a maximum thickness over an interpreted paleohigh (Fig. 4D), and comparison of MFb and MFc isopach maps (Fig. 4C, D) suggest that the change from MFb to MFc simply represents a decrease in energy level in the fluvial systems. This paleoenvironmental change would have been diachronous across the region. The change from MFc to the overlying MFd lithofacies is also gradational (Ramaekers, 1990) and represents another diachronous paleoenvironmental change. The MFd lithofacies is marked by thicker beds of well sorted, generally medium-grained quartz arenite with abundant current ripple marks, mudstone intraclasts, and thin granule laminae on scour surfaces (Fig. 6A, B). The presence of mud drapes, exceptional textural and compositional maturity of the sand, and stratigraphic relationships suggest that MFd represents either a distal portion of a large braided stream, or an estuary and possible braid delta setting. McCormick and Grotzinger 11 GSC Bulletin 588 (1993) defined a braid delta facies association as one where a sand-dominated braided stream enters a marine shelf setting, and is subsequently modified by marine processes. In their study of a Proterozoic braid delta system, McCormick and Grotzinger (1993) noted that abundant mud rip-up clasts are characteristic of the braid delta platform and braid deltaplain environments. Abundant rip-up clasts however, could be associated with flash floods with minor reworking and rapid burial — conditions that based on the thickness of the MFd must have persisted for an extended time interval. It is unlikely that these conditions were maintained over the extended time required to accumulate the hundreds of metres of sediment on a braidplain. This set of characteristics and the greater thickness of the MFd in the Cree subbasin (Fig. 4E) are consistent with aggradation and progradation of deltaic sand; this interpretation is further supported by the presence of a lithofacies that suggests a possible marine incursion noted by Ramaekers (1990, p. 20) in the upper MFd in the west-central part of the basin. Paleoestuaries and deltaic settings, however, can be very difficult to distinguish from alluvial, lacustrine, and marine environments in strata that predate the advent of macrofossils (McCormick and Grotzinger, 1993). These regional-scale stratigraphic relationships show that the lithofacies nomenclature developed by Ramaekers (1980, 1990) reflects variation in energy levels in the paleoenvironments, and has little chronostratigraphic significance. Paleotopography and subbasins The presence of an alluvial fan facies association that thins basinward (cores RL-51 and RL-86; Fig. 6A) and the concentration of MFa deposition in the east-central portion of the basin (Fig. 4B) suggest that significant relief existed early during deposition of the Manitou Falls Formation. Overall geometries of the Fair Point Formation and the MFa lithofacies along with the subbasins (Fig. 3, 4) recognized by Ramaekers (1981) suggest a tectonically active early stage in the development of the Athabasca Basin. These early, coarse-grained basal units probably mark a period when subdivision of the overall Athabasca Basin was at its greatest with alluvial fans adjacent to paleohighs, and high-energy braided streams flowing in the deeper parts of the subbasins mostly from the Ahenakew drainage area of Ramaekers and Catuneanu (2004). Subsidence and possible development of the Dufferin paleohigh during Manitou Falls Formation deposition is suggested by absence of MFb lithofacies beyond the western part of the Cree subbasin (Fig. 4C). Proterozoic continental depositional systems and stratigraphic correlation. The controls over stratal architecture in continental basins are primarily: subsidence, tectonic uplift, climate, and eustasy (Shanley and McCabe, 1994). Prior to the rise of land plants (before the Silurian) climate would have had a much simpler effect on sedimentary systems without the complexities inherent in vegetated landscapes. Overbank deposition of muddy facies would have been rare due to the absence of terrestrial macrophytes (Schumm, 1968; Cotter, 1978; Long, 12 1978) and the resulting increased effectiveness of wind in the removal of fine-grained sediments as loess (Dalrymple et al., 1985). Therefore, without terrestrial vegetation all Proterozoic rivers are widely believed to have been braided due of the lack of mud-rich cohesive overbank sediments to stabilize the stream banks (Schumm, 1968). Without overbank mud-rich facies, fluvial channel deposits would have been stacked one on another causing extensive channel amalgamation. The result is what, at least initially, appears to be monotonous thick successions of conglomerate and sandstone without any stratigraphic marker beds, such as shale beds that are regional in extent (e.g. Christie-Blick et al., 1988; McCormick and Grotzinger, 1993; Eriksson et al., 1998). Changes in grain size have been used to recognize sequence boundaries in Proterozoic fluvial deposits (e.g. Christie-Blick et al., 1988), but given the dynamic nature of the Manitou Falls Formation, changes in grain size are insufficient to permit recognition of sequence boundaries, and a multivariate approach is needed. The present authors developed a semiquantitative method for regional correlation that reflects significant regional changes in basin dynamics by carefully recording the thickness of fluvial fining-upward successions, location of erosional surfaces, and changes in framework grain composition within the Manitou Falls Formation and plotting these data along with lithology, lithofacies, and paleoenvironmental interpretations for each drill core (Fig. 7A, B). Fluvial fining-upward succession thickness is interpreted as a proxy for channel depth, and thus, accommodation (i.e. the space available for sediment accumulation or sedimentation capacity; e.g. Vail et al. (1977); Posamentier et al. (1988); Van Wagoner et al. (1990). Such space is created by base-level (i.e. sea- or lake-level) rise, decreased sediment supply, and/or tectonic subsidence (e.g. Shanley and McCabe, 1994). Changes in climate, however, can also affect accommodation by either increasing or decreasing sediment supply. In continental settings climate change can modify the shape and/or position of the fluvial equilibrium profile (e.g. Schumm, 1968; Shanley and McCabe, 1994). Lowering this profile can cause streams to downcut and deposit coarsegrained sediments, whereas a climate change that causes the equilibrium profile to rise rapidly can produce the same end result as a base-level rise. It is the change in accommodation through time that determines the nature of the stratigraphic succession. These concepts can be applied to stratigraphic successions even when the mechanism responsible for the change is not known (Emery and Myers, 1996). There is an inverse relationship between grain size and channel thickness — coarse-grained beds represent times of low accommodation, sediment bypassing (mud and medium- to fine-grained sand mostly), and stream-channel amalgamation (e.g. Wright and Marriott, 1993; Shanley and McCabe, 1994). Finer-grained beds (medium- to coarse-grained sand mostly) represent times of relatively high accommodation, sediment deposition, and a low degree of channel amalgamation (e.g. Wright and Marriott, 1993; Shanley and McCabe, 1994). E.E. Hiatt and T.K. Kyser These principles can be used in isolated sections, such as drill cores, and have potential as a regional correlation tool (provided the accommodation changes responsible for the changing degree of channel amalgamation are regional in extent). This technique appears to work on the kilometre scale and the linkage between fluvial fining-upward packages and accommodation provided the basis for correlating sections along the two transects included in this study (Fig. 5, 7A, B). The limited data set included in this study may apply to the immediate region, but may not be represent of the entire basin. These correlations are based largely on major changes in fining-upward succession thickness over intervals, major erosional surfaces, and where possible, changes in clast composition. This technique, however, may not be applicable to stratigraphic changes within stratigraphic sections on a fine scale because of the potential variable sizes of individual rivers and the randomness of channel erosion and amalgamation. In addition to variation within the fluvial depositional system, alluvial fan deposition would have produced individual beds that were very different in character and with very irregular patterns of cycle bundling relative to braided streams. This may explain why the patterns in fining-upward cycle thickness are more subtle in the Cigar Lake transect (Fig. 7B) relative to that of the McArthur River (Fig. 7A), and why the cycle bundling in sequence 1 and the lower portion of sequence 2 is difficult to cor elate from core to core. Furthfsmore, this technique may not work in all circumstances, at least when the available stratigraphic database is limited, and where absence of coarse channel-base deposits (i.e. very uniform sediment textures) might lead to missing amalgamation surfaces and an underestimate of the degree of amalgamation. Conversely, stratigraphic change within deposits created by individual flood events might be misinterpreted as amalgamation surfaces, causing an overestimate of the degree of amalgamation. Sequence stratigraphy Based on these stratigraphic relationships, a sequence stratigraphic model was developed for the Manitou Falls Formation in which three depositional sequences are identified (Fig. 7A, B). Sequence 1 is bounded below by the basal unconformity developed on older crystalline basement rocks, and by an unconformity above that marks a major change in depositional environment and paleoclimate. This basal sequence in the eastern Athabasca Basin is composed dominantly of the MFa lithofacies. It contains paleosol horizons and records alluvial fan and braided stream depositional environments (Fig. 7A). Sequence 1 thickens to the southwest in the study area because it is composed mostly of sediments shed directly off paleohighs rimming the eastern edge of the basin. High-energy braided fluvial deposits of MFa and MFb, and to a lesser degree, distal braided fluvial deposits of MFc dominate sequence 2 (Fig. 7A) and mark a period of basin subsidence and rapid filling. Gradually, channel depth and accommodation increased, as inferred from thicker finingupward stratigraphic successions. Sequence 2 is terminated by an unconformity marked by a sudden decrease in fluvial fining-upward succession thickness suggesting a rapid drop in base level that would have caused downcutting and channel amalgamation (Fig. 7A, B). The base-level fall that led to the boundary between sequence 2 and sequence 3 caused a rapid, regional-scale accommodation drop; active river systems downcut, channels would have become highly amalgamated, and finer-grained sediment bypassed the study area (was flushed through in suspension) and was deposited to the west. Sequence 3 is marked by a period of relatively low base level as suggested by coarser grained sediments of the MFc lithofacies and thin fining-upward cycles, followed by a major increase in accommodation reflected in the finer grained sediments and thick, fining-upward cycles of the MFd lithofacies. The sequence boundary that caps sequence 3 was not captured in these drill cores in this study area. The next reported sequence boundary is the contact between the Manitou Falls Formation and the overlying units (Lazenby Lake and Wolverine Point formations; Ramaekers and Catuneanu (2004)), and may correspond to the top of sequence 3 of this study. Stratigraphic controls on diagenesis In Proterozoic continental deposits diagenetic processes differed from those of the Phanerozoic because of the paucity of muddy facies. In these matrix-poor rocks compaction (both mechanical and chemical) and cementation play a more important role in determining porosity and permeability than do depositional processes relative to similar Phanerozoic ones (Hiatt et al., 2003). Depositional aquitards (impermeable mud-rich facies) in these continental settings are virtually absent and the role of quartz cementation becomes more important in establishing initial basin hydrology (Hiatt et al., 2003). Because quartz cement preferentially formed in quartz-rich, clay-poor, well sorted lithofacies, the porosity and permeability relationships during the critical interval of peak diagenesis (Fig. 10) in the burial setting in the Manitou Falls Formation were opposite to those predicted on the basis of lithofacies characteristics. There is a predictable succession of facies within each of the Manitou Falls Formation sequences (Fig. 7A, B). The lower part of each sequence consists of the coarsest sediment and thinnest fining-upward cycles, and the smallest amount of quartz cement (Fig. 7A, B). These deposits commonly contain an interstitial clay component that is interpreted to have formed either by depositional processes, the infiltration of mud, sometimes associated with soil-forming processes, because water tables were commonly low and variable during lowstands, and/or by the diagenetic alteration of detrital aluminosilicate grains, such as feldspar. This clay inhibited later quartz cementation during burial diagenesis (Fig. 8A, B, C). Basal units in each sequence are overlain by finer grained, quartz-rich, clay-poor facies composed of much more compositionally and texturally mature sediments. The absence of clay and excellent initial hydrological properties permitted preferential development of quartz cementation in these more quartz-rich facies (Fig. 8D, E, 9A, B). 13 GSC Bulletin 588 Quartz cementation Grain-to-grain spatial relationships give a first-order indication of relative timing of quartz cementation with respect to burial-driven compaction (e.g. Pittman, 1979). In stratigraphic units that experienced early quartz cementation, grain-to-grain relationships show few signs of compaction before emplacement of cement. The earliest such quartz cement in the Athabasca Basin is a blocky cement phase that is found only in the well sorted lithofacies in sequence 1 (Fig. 8D, E). Based on isotopic analysis, Hiatt et al. (in press) determined that this cement phase formed at temperatures that correspond to burial depths of less than 1 km. This cement phase appears to have formed before the onset of pressure solution, and therefore required an external source of dissolved silica. Its close association with a paleosol horizon (Fig. 6A) suggests intense weathering may have provided the silica. Where some matrix clay was present, quartz cementation was patchy, but because it preferentially formed at grain contacts it effectively lowered the permeability of the rock (Fig. 8B, C). The next stage of cementation occurred during burial compaction with silica derived through compaction-driven, grain-to-grain pressure solution. This burial-cement phase precipitated in open pores adjacent to pressure-solution points (Fig. 9A, B). Quartz cement with this morphology is common in sandstone in general and is well developed in clay-free units of lithofacies associations 3 and 4, and to a lesser extent lithofacies association 2. Pressure solution can also occur with little cement precipitation and, in the absence of clay matrix, can result in ‘welded’, interlocking grain fabrics (Fig. 9C, D). Where clay was present, compaction, along with replacement reactions, often resulted in dissolution of earlier-formed quartz cement (Fig. 9E, F). Although this matrix clay occludes porosity to varying degrees, some permeability remains and such units can allow fluid movement in the burial realm (cf. Hiatt et al., 2003). Athabasca Basin hydrostratigraphy Changes in sedimentary environments are ultimately driven by basin-scale processes that control the internal fabric and lateral and vertical extents of rock types that fill sedimentary basins (e.g. Hiatt, 2000). Depositional environments not only determine internal aquifer properties, but on a basin scale (tens to hundreds of kilometres) their geometries are one of the major factors that determine the degree of aquifer compartmentalization. The sequence stratigraphic model for the Manitou Falls Formation presented above provides a means of understanding the degree of aquifer heterogeneity and compartmentalization in the eastern portion of the basin. Figure 11 summarizes the possible relationships between sequences, lithofacies, and geometries of the fluvial basinfilling succession. During times of lowered base level, fluvial channels incise into pre-existing sequences, show a high degree of amalgamation, and are typically very coarse grained. These conditions characterize the porous and permeable lower portions of the MFa, MFb, and to a lesser extent, the MFc lithofacies. The juxtaposition of a major aquifer over 14 the paleoweathering surface on the basal unconformity may have channellized flow along the unconformity, and established a flow system that delivered basinal fluids to sites of mineralization. Indeed, Holk et al. (2003) showed that fluids associated with uranium mineralization moved preferentially along the basal unconformity in both transects included in this study. Based on lithological and diagenetic characteristics, the lower portion of the upper sequence should have been favorable for fluid flow also; although due to limited stratigraphic thickness and greater textural and compositional maturity, this aquifer would have played a lesser role than that of the underlying sequences. The overlying clay-rich Wolverine Point Formation would have been a regional aquitard; it shows little evidence of diagenetic alteration relative to the underlying Manitou Falls Formation, suggesting that it was indeed a barrier to fluid flow (Sibbald and Quirt, 1987). The authors developed a hydrostratigraphic model based on the integration of sedimentology, diagenesis, and the sequence stratigraphic model presented above (Fig. 12). This hydrostratigraphic subdivision shows that aquifers thin and onlap onto the basal unconformity in the eastern portion of the basin. This geometry would have focused diagenetic fluid flow toward the underlying basement in the eastern portion of the basin (Fig. 12) and could have established a flow system that delivered basinal fluids to sites favorable for mineralization (rocks in the underlying basement that contain graphite, amphibole, etc. drive reduction reactions). Possible mechanisms driving fluid movement include: thermal convection, tectonic uplift and/or subsidence, and compaction-driven expulsion of pore fluid (e.g. Raffensperger, 1997; Einsele, 2000). It may be impossible to identify the exact mechanism(s) controlling fluid flow in the Athabasca Basin. The choice of mechanism has profound implications for basin evaluation and exploration strategy. For example, if compartmentalization produced by the development of diagenetic aquitards directed or focused fluid flow, as proposed here, then aquifer intersections with paleotopographic highs become important targets. If on the other hand, the thermal convection model is adopted, then uranium mineralization is predicted to occur throughout the basin where these convection cells intersect reducing rock types (graphitic schist units are the most common in the Athabasca Basin) in the underlying basement rocks (Raffensperger, 1997). This model, however, requires that the flow of convection cells was uninterrupted in a sedimentary succession that is greater than 2 km thick (Raffensperger, 1997). Subtle differences between sequences in the Athabasca Basin, coupled with stratigraphic control over later diagenesis, led to the development of distinct diagenetic pathways for fluid flow (Fig. 12). As a result, permeabilities would not have been uniform stratigraphically at the time when the uranium mineralizing fluids were flowing in the basin. Thus, it is unlikely that the thermal convection mechanism could operate given the complexity of the hydrostratigraphy. Furthermore, chemostratigraphic analysis of lead isotopes in the Athabasca Basin shows that fluids associated with uranium mineralization flowed laterally along the main aquifer SB-1 SB-2 SB-3 SB-4 Dufferin Paleohigh Virgin River Domain Mudjatik Domain Cree subbasin Wollastin Domain Virgin River Domain Cree subbasin Mudjatik Domain MFc Wollaston Mineralization MFd Figure 12. Interpreted hydrostratigraphy of the Athabasca Basin. Aquifers represent stratigraphic units that could have conducted burial brines associated with uranium mineralization along the eastern portion of the basin. Aquitards represent stratigraphic intervals that were preferentially cemented with quartz prior to major mineralization events, and intermediate aquifers were units that would have allowed a small amount of fluid movement, but were not major conduits for mineralizing fluids. Lithofacies in the Manitou Falls Formation unit A, B, C, and D are represented by MFa, MFb, MFc, and MFd, respectively. Mirror subbasin Western Craton MFa Lazenby Lake Fm Wolverine Point Fm MFb MFc Mineralisation MFb Figure 11. Generalized east-west cross-section of the eastern Athabasca Basin showing interrelationships between lithofacies, lithostratigraphy, and sequence boundaries (SB-1, SB-2, and SB-3). Lithofacies in the Manitou Falls Formation unit A, B, C, and D are represented by MFa, MFb, MFc, and MFd, respectively. Note that the MFb, MFc, and MFd lithofacies are diachronous and interfinger stratigraphically. Mirror subbasin Western Craton MFa MFc MFd Lazenby Lake Fm 500 m Wolverine Point Fm SB-1 & SB-2 SB-3 SB-4 500 m Crossbedding Pebbles Current ripple marks Wave ripple marks Heavy minerals Mud rip-up clasts E.E. Hiatt and T.K. Kyser 15 GSC Bulletin 588 unit identified in this study (Holk et al. (2003); Fig. 12), and not vertically, as would have been the case if thermal convection had occurred. CONCLUSIONS Understanding paleohydrological systems during basin evolution requires integration of sedimentology, stratigraphy, diagenesis, and geology of basin-filling successions. The semiquantitative method to arrive at a sequence stratigraphic model presented here utilizes fluvial fining-upward succession thickness in the Manitou Falls Formation as a proxy for changes in channel thickness, and thus accommodation. The authors’ data from the eastern Athabasca Basin may not be completely representative of the entire basin, but the results may provide a possible tool for correlation with chronostratigraphic significance in the absence of alternate stratigraphic markers. It allows the recognition of stratigraphic sequences in the Athabasca Basin and should be applicable to other Proterozoic (and younger) fluvial deposits where changes in accommodation are caused by changes in basin dynamics. These results confirm theoretical models wherein the influence of changing accommodation affects the stratigraphic architecture of fluvial deposits; this technique should be further tested regionally in the Athabasca Basin and in other younger basins where independent means exist to generate a sequence-stratigraphic subdivision. There is a systematic relationship between diagenesis and stratigraphy in the Manitou Falls Formation. During periods of low accommodation, fluvial channels were highly amalgamated, experienced downcutting, and most finer grained sediment was bypassed to distal settings. These intervals are marked by variable amounts of clay due to depositional and diagenetic processes, subsequently experienced little quartz cementation, and thus, were highly permeable during mineralization-related burial diagenesis. During periods of high accommodation, fluvial channel amalgamation was at a minimum, channels were large, and migrated across the braidplains, and extensive medium-grained, texturally and compositionally mature sandstone units were deposited. These clay-poor units experienced extensive quartz cementation, and thus became diagenetic aquitards at the time of mineralization. This relationship is important where the stratigraphic sequences onlap to the east onto paleotopographic highs. Burial brines, possibly driven by tectonic tilting of the basin toward the east, moved laterally within aquifer units that are concentrated, but not limited to, the lower sequences. This lateral flow was a direct result of the hydrostratigraphy of the Athabasca Basin; it lends support for hydrostratigraphic focusing of basinal fluids into zones where diagenetic aquifers onlap basement rock types. These factors should be taken into account in development of exploration strategies. 16 ACKNOWLEDGMENTS The authors would like to thank the staff at Cameco Corporation, including Dave Thomas, Vlad Sopuck, Scott McHardy, and Ken Wysluk for providing logistical, technical, and geological assistance and advice. Thanks to Paul Ramaekers and Grant Young for thoughtful reviews that improved the final version of this manuscript. The authors also thank colleagues at Queen’s University including Bob Dalrymple for discussions that led to the development of the stratigraphic model, and Paul Polito and Kyle Durocher for helping further the authors’ understanding of basin analysis. This project was funded by a Natural Science and Engineering Research Council of Canada (NSERC) operating grant and an NSERC–Cameco Corporation Collaborative Research and Development grant to T.K. Kyser. REFERENCES Armstrong, R.L. and Ramaekers, P. 1985: Sr isotopic study of Helikian sediment and diabase dikes in the Athabasca Basin, northern Saskatchewan; Canadian Journal of Earth Sciences, v. 22, p. 399–407. Bethke, C.M. 1986: Hydrologic constraints on the genesis of the Upper Mississippi Valley mineral district from Illinois Basin brines; Economic Geology, v. 81, p. 233–248. Christie-Blick, N., Grotzinger, J.P., and von der Borch, C.C. 1988: Sequence stratigraphy in Proterozoic successions; Geology, v. 16, p. 100–104. 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Wilson, M.R. and Kyser, T.K. 1987: Stable isotope geochemistry of alteration associated with the Key Lake uranium deposit; Economic Geology, v. 82, p. 1450–1557. Wright, V.P. and Marriott, S.B. 1993: The sequence stratigraphy of fluvial depositional systems: the role of floodplain sediment storage; Sedimentary Geology, v. 86, p. 203–210. Depth (m) 800 700 600 500 400 300 200 100 0 A) MFa MFb MFc MFd Gneiss F M C G P Cb RL-51 Proximal braided stream Alluvial fan 1 500 400 300 200 100 0 MFa MFb MFc MFd F M C G P Cb Quartzite 2.5 km Depth (m) Depth (m) 600 500 400 300 200 100 0 MFa? MFa MFb MFc MFd Paleosol F M C G P Cb Gneiss MAC-224 Figure 6. A) Lithological logs for the drill cores in the McArthur River transect: RL-51, RL-86, and MAC-224 (Fig. 5). B) Lithological logs for drill cores near the Cigar Lake deposit: CL-182, CL-185, and CL-229 (Fig. 5). Lithofacies associations and sedimentary structures are shown on the logs. The position of each right edge of the log shows the mean grain size: F = fine-grained sand, M = medium-grained sand, C = coarse-grained sand, G = granules, P = pebbles, Cb = cobbles. Lithofacies in the Manitou Falls Formation unit A, B, C, and D are represented by MFa, MFb, MFc, and MFd, respectively. Mudcracks Mud rip-up clasts Heavy minerals Wave ripple marks Current ripple marks Pebbles Crossbedding Distal braided stream Estuarine–braid delta Upper shoreface–marine Interpretation 5 4 3 2 Lithofacies Key: 15 km RL-86 From: Article by E.E. Hiatt and T.K. Kyser 19 20 Depth (m) MFa MFb MFc MFd Metapelite 1.5 km F M C G P Cb Figure 6. (cont.) 600 500 400 300 200 100 0 B) CL-182 500 400 300 200 100 0 MFa MFb MFc MFd 0.5 km F M C G P Cb Metapelite CL-185 500 400 300 200 100 0 MFa MFb MFc MFd F M C G P Cb Schist CL-229 Proximal braided stream Alluvial fan 1 Mudcracks Mud rip-up clasts Heavy minerals Wave ripple marks Current ripple marks Pebbles Crossbedding Distal braided stream Estuarine–braid delta Upper shoreface–marine Interpretation 5 4 3 2 Lithofacies Key: From: Article by E.E. Hiatt and T.K. Kyser Depth (m) Depth (m) Depth (m) 800 700 600 500 400 300 200 100 0 A) MFa MFb MFc MFd F M C G P Cb Gneiss RL-51 0 20 15 km 500 400 300 200 100 0 MFa MFb MFc MFd 0 10 20 Apparent accommodation (thickness in metres) F M C G P Cb Quartzite RL-86 SB-1 Sequence 1 SB-2 Sequence 2 2.5 km SB-3 Sequence 3 600 500 400 300 200 100 0 MFa? MFa MFb MFc MFd 0 10 20 Apparent accommodation (thickness in metres) Paleosol F M C G P Cb Gneiss MAC-224 Figure 7. A) Correlation diagram for the McArthur transect drill cores, RL-51, RL-86, and MAC-224 (Fig. 5). B) Correlation diagram for the Cigar Lake transect drill cores CL-182, CL-185, and CL-229 (Fig. 5). Lithofacies associations and sedimentary structures are shown on the logs. The position of each right edge of the log shows the mean grain size: F = fine-grained sand, M = medium-grained sand, C = coarse-grained sand, G = granules, P = pebbles, Cb = cobbles. Lithofacies in the Manitou Falls Formation unit A, B, C, and D are represented by MFa, MFb, MFc, and MFd, respectively. For each diagram, the bar graph to the right of each lithological log is the thickness of a single depositional cycle in its correct stratigraphic position. Depositional cycles are dominantly expressed as fining-upward successions caused by fluvial processes and represent apparent accommodation. The shaded areas around the thickness data highlight major trends in accommodation. Dashed lines represent interpreted correlations of fining-upward cycle bundles. Sequence boundaries (SB-1, SB-2, and SB-3) were identified based on sedimentological characteristics and major stratigraphic changes in accommodation. 10 Apparent accommodation (thickness in metres) From: Article by E.E. Hiatt and T.K. Kyser 21 22 MFa MFb MFc MFd 0 5 10 Apparent accommodation (thickness in metres) F M C G P Cb Metapelite Figure 7. (cont.) 600 500 400 300 200 100 0 B) CL-182 SB-1 & SB-2 Sequence 2 SB-3 Sequence 3 1.5 km 500 400 300 200 100 0 MFa MFb MFc MFd 0 5 10 Apparent accommodation (thickness in metres) F M C G P Cb Metapelite CL-185 0.5 km 500 400 300 200 100 0 MFa MFb MFc MFd 0 5 10 Apparent accommodation (thickness in metres) F M C G P Cb Schist CL-229 From: Article by E.E. Hiatt and T.K. Kyser Depth (m)