SUChE 2015--program book-22 - The 8th Sino
Transcription
SUChE 2015--program book-22 - The 8th Sino
SUChE SHANGHAI 2015 Http:// suce.ecust.edu.cn The 8th Sino-US Joint Conference of Chemical Engineering October 12-16 • 2015 • SHANGHAI • CHINA Program Book NEW ERA of CHEMICAL ENGINEERING EAST CHINA UNIVERSITY of SCIENCE AND TECHNOLOGY Program Book Editors of the Program book: Prof. Yi-Fan Han Prof. Donghui Long CONTENTS The 8th Sino-US Joint Conference of Chemical Engineering Program 02 Chairmen’s Message 05 Conference Co-Chairs 07 About the conference 08 About ECUST 09 Registration & Meals 10 Information about the Conference 12 Conference at a Glance 13 Campus Map 14 Plenary Lectures and Discussions 23 Space for Symposium 24 List of Symposium 25 Parallel Symposium Schedule Table 27 Parallel Symposium Descriptions 135 Poster Sessions Page 1 Chairmen’s Message Welcome to the 8th Sino-US Joint Conference of Chemical Engineering ON behalf of the organizing committee, we are pleased to welcome you to the 8th Sino-US Joint Conference of Chemical Engineering (SUChE2015). SUChE2015 was hosted by East China University of Science and Technology during October 12–16, 2015 in Shanghai, China. The conference was also sponsored by the following organizations: The Chemical Industry and Engineering Society of China, American Institute of Chemical Engineers, Chinese Academy of sciences, Chinese Academy of Engineering, and National Natural Science Foundation of China. There are undeniable challenges in areas such as energy, resources and the environment. The Sino-US Joint Chemical Engineering Conference will act as a platform for scientists, engineers, and technologists from both China and the United States to communicate the latest developments and share their knowledge in the field of chemical engineering. The theme of the 8th conference is “New Era of Chemical Engineering”, emphasizing not only the role of chemical engineers in the development of clean and sustainable processes, but also exploring the frontiers for developing fundamentals needed to tackle these challenges. The conference will foster new and substantial collaborations between scientists and engineers from both academic institutions and industrial companies. The Sino-US Joint Conference of Chemical Engineering started in 1982, and since then they have been held in Beijing. This is the first time the conference is being held in Shanghai. With all the exciting developments happening, this event promises to be a sensational gathering for all participants. The Conference Organizing Committee is grateful to all those who have contributed to its organization, its scientific program and the sessions. It also would like to thank ExxonMobil, National Institute of Low Carbon and Clean Energy (NICE), National Science Foundation of USA, UOP Co. for their financial support. We would also like to extend a warm welcome to all our colleagues in the industry who share our interest in developing and improving Academic-Industry partnership. We hope that you will participate in the stimulating scientific sessions as well as enjoying the special, unique charm of Shanghai. On behalf of the Conference Dr. Xuhong Qian Dr. Norman Li East China University of Science and NL Chemical Technology, Inc., The United Technology, Shanghai, China States of America Member of Chinese Academy of Engineering Member of US National Academy of Engineering Page 3 New Era of Chemical Engineering Organizer Sponsors Special Sponsors Page 4 New Era of Chemical Engineering Conference Co-Chairs Prof. Kechang Xie Prof. Jinghai Li Dr. Xianghong Cao Prof. Xuhong Qian Dr. Norman Li Vice President of Chinese Academy of Engineering, Member of Chinese Academy of Engineering Vice President of Chinese Academy of Sciences, Member of Chinese Academy of Sciences Sinopec Group, China; Member of Chinese Academy of Engineering Prof. of East China University of Science and Technology, Member of Chinese Academy of Engineering President of NL Chemical Technology, Inc., USA; Member, US National Academy of Engineering Conference Secretaries Prof. Shan-Tung Tu, Prof. Zhong Xin (Deputy) Local Organizing Conference Prof. Yi-Fan Han (China), Dr. Teh Chung Ho (US) Scientific Advisory Committee From China (Listed alphabetically) Mr. Xianghong Cao (曹湘洪), Member of Chinese Academy of Engineering, China Petrochemical Corporation Prof. Bingzhen Chen (陈丙珍), Member of Chinese Academy of Engineering, Tsinghua University Prof. Jiayong Chen (陈家镛), Member of Chinese Academy of Sciences, Institute of Process Engineering, CAS Prof. Junwu Chen (陈俊武), Member of Chinese Academy of Sciences, Luoyang Petrochemical Corp., China Petrochemical Corporation Prof. XueDuan (段雪), Member of Chinese Academy of Sciences, Beijing University of Chemical Technology Prof. WeiyangFei (费维扬), Member of Chinese Academy of Sciences, Tsinghua University Dr. Mingyuan He (何鸣元), Member of Chinese Academy of Sciences, Research Institute of Petroleum Processing, China Petrochemical Corporation Prof. Ying Hu (胡英), Member of Chinese Academy of Sciences, ECUST Prof. Hongzhong Li (李洪钟), Member of Chinese Academy of Sciences, Institute of Process Engineering, CAS Prof. He Tian (田禾) Member of Chinese Academy of Sciences, ECUST Prof. Jinghai Li (李静海), Member of Chinese Academy of Sciences, Institute of Process Engineering, CAS Prof. Enze Min (闵恩泽), Member of Chinese Academy of Sciences, Research Institute of Petroleum Processing, China Petrochemical Corporation Page 5 Scientific Advisory Committee Prof. Pingkai Ouyang (欧阳平凯), Member of Chinese Academy of Engineering, Nanjing University of Technology Prof. Jingkang Wang (王静康), Member of Chinese Academy of Engineering, Tianjin University Prof. KechangXie (谢克昌), Member of Chinese Academy of Engineering, Taiyuan University of Technology Prof. Nanping Xu (徐南平), Member of Chinese Academy of Engineering, Nanjing University of Technology Prof. Guocong Yu (余国琮), Member of Chinese Academy of Sciences, Tianjin University Prof. Qingtang Yuan (袁晴棠), Member of Chinese Academy of Engineering, China Petrochemical Corporation Prof. Xuhong Qian (钱旭红), Member of Chinese Academy of Engineering, ECUST Prof. Quan Yuan (袁权), Member of Chinese Academy of Sciences, Dalian Institute of Chemical Physics, CAS Prof. Weikang Yuan (袁渭康), Member of Chinese Academy of Engineering, ECUST Prof. Yi Zhang (张懿), Member of Chinese Academy of Engineering, Institute of Process Engineering, CAS Prof. Tao Zhang (张涛), Member of Chinese Academy of Sciences, Dalian Institute of Chemical Physics, CAS Prof. Wei Huang (黄维), Member of Chinese Academy of Sciences, Nanjing University of Technology From US Dr. Monty Alger, Member of National Academy of Engineering of USA, Myriant Corporation Prof. Mark A. Barteau, Member of National Academy of Engineering of USA, University of Michigan Prof. Dibakar Bhattacharyya, University of Kentucky Dr. Maria K. Burka, National Science Foundation Prof. Chau-Chyun Chen, Member of National Academy of Engineering of USA, Texas Tech. University Prof. Steven M. Cramer, Rensselaer Polytechnic Institute Prof. L. S. Fan, Member of National Academy of Engineering of USA, The Ohio State University Dr. Teh C. Ho, Hydrocarbon Conversion Technologies Prof. W. S. Winston Ho, Member of National Academy of Engineering of USA, The Ohio State University Prof. William J. Koros, Member of National Academy of Engineering of USA, Georgia Institute of Technology Prof. James L. Lee, The Ohio State University Dr. Norman N. Li, Member of National Academy of Engineering of USA, NL Chemical Technology Inc. Prof. G. Glenn Lipscomb, University of Toledo Prof. Kamalesh K. Sirkar, New Jersey Institute of Technology Dr. James A. Trainham, Member of National Academy of Engineering of USA, RTI International Prof. James Wei, Member of National Academy of Engineering of USA, Princeton University Prof. Ralph T. Yang, Member of National Academy of Engineering of USA, University of Michigan Dr. Scott Y. Zhang, Honeywell Inc. Prof. Andrew L. Zydney, Pennsylvania State University Page 6 About the Conference About the conference The Sino-US Joint Chemical Engineering Conference will act as a platform for scientists, engineers, and technologists from both China and the United States to communicate the latest developments and share their knowledge in the field of chemical engineering. The theme of the 8th conference is “New Era of Chemical Engineering”. The conference will foster new and substantial collaborations between scientists and engineers from both academic institutions and industrial companies. List of Symposia S1—Advanced Technology for Air Separation and Purification S2—Bioengineering and Biotechnology S3—Catalysis and Reaction Engineering S4—Energy Energy S5—Food and Pharmaceutical Technologies S6—Green Technology S7—Management Science for Research and Development ---How to make R&D effective and efficient S8—Materials and Nano Technology S9—Membrane Technology for Water Purification S10—Particle and Fluidization Technology S11—Petrochemicals and Fine Chemicals S12—Process Development and Optimization S13—Thermodynamics and Transport Phenomena S14—Separation Technology S15— Forum of Chemical Engineering Department Deans and Chairs Page 7 About ECUST About ECUST East China University of Science and Technology (ECUST), originally named East China Institute of Chemical Technology, was founded in 1952. ECUST is a key research university in China featuring Chemical Sciences & Engineering. ECUST rank among the top 500 universities in the world, according to the Ranking List of Universities by ARWU, THE and QS. East China University of Science and Technology has a top quality teaching and R&D staff represented by nationally renowned educators as well as very competitive scientific research teams based in many state-level key laboratories and engineering and technological research centers. In December 2013, the Chemical Engineering and Technology major was accredited by ABET (6+3), which is the first ABET accreditation in China. ECUST is comprised of more than 1.7 million square meters on 3 campuses. There are more than 16,300 full time undergraduates, 8,500 graduate students studying at ECUST. The number of faculty and staff members has reached 3,700 among whom there are about 1,000 professors and associate professors. Page 8 Registration & Meals Registration Site All participants are kindly asked to confirm and pay for their registration fee and pick up their conference materials at the registration desk. The registration desk will be located: The lobby of Yifu Building at 09:00-20:00, Oct. 12 The lobby of Yifu Building at 08:00-18:00, Oct. 13-15 M104 M105 Registration Desk Yifu Building M103 Conference meals All registered participants will receive meal tickets lunch and dinner for the three and half days (Oct. 13th to 16th ) during the conference. Each ticket for the conference meal is valid only for the lunch or the dinner as indicated on the ticket. The meal tickets will not be refundable. The place for the conference meals is in Youyi Restaurant and for banquet is in Pullman Hotel. Page 9 Information About the Conference Shuttle Service Shuttles will provide service from official hotels to and from the ECUST. Hotels include the Pullman Shanghai South and Grand Skylight Hotel (GSH). Date Leaving at Hotel (PSS) Leaving at Hotel (GSH) Leaving at ECUST Oct. 12 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40, 17:30 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40, 17:30 9:00, 10:00, 11:00, 12:00, 13:00, 14:00, 15:00, 16:00, 17:00, 20:00 Oct. 13 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40, 21:00(for GSH and ECUST) 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40 9:00, 10:00, 11:00, 12:00, 13:00, 14:00, 15:00, 16:00, 17:30(for Pullman Shanghai South only) Oct .1 4 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40, 17:30 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40, 17:30 9:00, 10:00, 11:00, 12:00, 13:00, 14:00, 15:00, 16:00, 17:00, 18:30(for Huangpu River Night Cruise only) Oct. 15 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 13:40, 14:40, 15:40, 16:40 9:00, 10:00, 11:00, 12:00, 13:00, 14:00, 15:00, 16:00, 17:00, 19:00 Oct .1 6 7:40, 8:40, 9:40, 10:10, 11:40, 12:40, 7:40, 8:40, 9:40, 10:10, 11:40, 12:40 9:00, 10:00, 11:00, 12:00, 13:00 (for Jewish Refugees Museum visit and hotels), 15:30 (from museum to hotels and Pudong Int’l Airport) Please contact Dr. Jie Wang ([email protected] or 13917682730) if you need any assistance in transportation! WiFi Network You may access free WiFi network in the meeting space area. SSID: SUChE2015 Encryption Key: ecust2015 Page 10 About Tour 上海黃浦江夜遊 Shanghai Huangpu River Night Cruise Wednesday, Oct.14 2015, 18:30-21:00 The Huangpu River is the mother river of Shanghai. Nanpu Bridge, Yangpu Bridge and Oriental Pearl TV Tower compose of a huge picture scroll. The Bund is the cultural section of Shanghai that best represents the blending of ancient and modern influences. This renowned waterfront district is the city's most famous landmark. Local people honor the Huangpu River as Mother River, and as you view the lights and spectacle from the deck of your evening cruise, you will understand why. 上海犹太难民纪念馆 Shanghai Jewish Refugees Museum Friday, Oct.16 2015, 13:00-16:00 Located on Changyang Road in the Hongkou District, the Shanghai Jewish Refugees Museum was built in memory of the time during the Second World War when Jewish refugees sought sanctuary from massacre. It is housed in the former Ohel Moshe Synagogue where the Jewish refugees gathered for religious activities. The museum holds many scrolls and other cultural relics. Page 11 Conference at a Glance Date Monday Oct.12, 2015 Tuesday Oct.13, 2015 Wednesday Oct.14, 2015 Thursday Oct.15 2015 Friday Oct.16 2015 Page 12 Time Events 9:00 - 18:00 Conference Registration (Yifu Building) 18:00-20:00 Welcome reception (Youyi Restaurant) 8:15-8:45 Opening ceremony 8:45-12:10 Plenary lectures 12:10-13:30 Lunch (Youyi Restaurant) 13:30-17:00 Parallel symposiums 18:00-21:00 Banquet (Pullman Hotel) 8:30-12:00 Parallel symposiums 12:00-13:30 Lunch (Youyi Restaurant) 13:30-17:00 Parallel symposiums 17:00-18:30 Dinner (Youyi Restaurant) 18:30-21:00 Huangpu River Night Cruise 8:30-12:00 Parallel symposiums, Poster 12:00-13:30 Lunch (Youyi Restaurant) 13:30-17:00 Parallel symposiums, Poster 17:00-19:00 Dinner (Youyi Restaurant) 8:30-10:00 Discussion on Challenges and Opportunities of Chemical Industry 10:15- 11:45 Discussions on Future Education of Chemical Engineering 11:45-12:15 Conference Closing Ceremony including the Best Poster Paper Awards 12:15-13:00 Lunch (Youyi Restaurant) 13:00-16:00 A Visit to the Shanghai Jewish Refugees Museum Campus Map Heping Building No. 16 Building Main Gate East Gate Heping Building Youyi Restaurant Yifu Building Page 13 Plenary Lectures and Discussions Plenary lectures and Plenary discussion will be held at the Hall of Yifu Building (M105). Plenary lecture 8:459:30 Tuesday Oct.13, 2015 Plenary lecture 1: Progress, Challenge and Perspective of Chemical Engineering Education in China Prof. Xuhong Qian (ECUST, Member of Chinese Academy of Engineering) 9:3010:15 Plenary lecture 2: Efficiency, Integration and Molecular Management – The Role of Innovation Dave Martindale (Vice President, UOP LLC) 10:4011:25 Plenary lecture 3: China's Oil Refining and Petrochemical Industry: Looking Forward to 2030 11:2512:10 Plenary lecture 4: Development of Technologies for Clean and Low Carbon Energy Xianghong Cao (Sinopec, Member of Chinese Academy of Sciences) Chang Wei (President, National Institute of Clean and Low Carbon Energy) Plenary discussion 8:3010:00 Friday Oct.16, 2015 1. Discussion on Challenges and Opportunities of Chemical Industry Dr. Dingyi Hong, Dr. Xiaodong Hu, Mr. Guanglian Pang Mr. Dave Martindale, Dr. Bing Zhang, Dr. Yi Jiang 10:2011:50 2. Discussions on Future Education of Chemical Engineering Speakers:Prof. Guohua Chen, Prof. Daming Wang, Prof. Shan-Tung Tu Prof. Arvind Varma, Prof. Dan Luss, Prof. James Wei Page 14 Plenary lecture speakers Xuhong Qian Member of Chinese Academy of Engineering Xuhong QIAN Ph.D., FRSC Professor, Bioorg. Chem. Engi. (Pesticide & Dyes) Member, Chinese Academy of Engineering Former President of ECUST He was born in Baoying county, Jiangsu province in 1962. 1/2014-, Member, Advisory Editorial Board, J. Agric. Food Chem., USA; 12/2012-, Honorary Doctor of Science, Queen’s University , Belfast, UK; 6/2012-, Editor-in-Chief, Chinese Chemical Letters; 12/2011-, Member, Chinese Academy of Engineering; 7/2011-, Honorary Professor, Bath University , UK. 3/2009-, Fellow, The Royal Society of Chemistry, UK; 5/2008-7/2014, Member, Advisory Commission for Chemistry, National Science Foundation of China; 5/2008-10/2014, Ambassador Scientist, Alexander von Humboldt Foundation, Germany; 3/2007-12/2008, President, Asian Pacific Confederation of Chemical Engineering; 2007-, Vice President, Chemical Industry and Engineering Society of China; 7/2004-3/2015, President, East China University of Science and Technology (ECUST), Shanghai; 2003-2014, Scientist-in-Chief, National Basic Research Key Project (973), The Ministry of Science and Technology; 9/2000-6/2004. CheungKong Chair Professor, in Dalian University of Technology. 2000. Research Grant for Outstanding Young Scientist, National Natural Science Foundation of China; 4/1996-10/2000. Vice President, ECUST, Shanghai; 1999. Distinguished 10 Persons in Science and Technology of Shanghai; 9/1995-3/1996. Assistant President, ECUST, Shanghai. 8/1994-9/2000. Professor; 8/1992-7/1994. Associate Professor; 8/1988-8/1992. Lecturer, East China University of Science and Technology (ECUST), Shanghai; 9/1990-1/1992. Alexander von Humboldt Postdoctoral Fellow, Wurzburg University, West Germany; 8/1989-8/1990. Research Associate, Lamar University, Texas, USA; 6/1988. Ph. D.; 4/1985. Master.; 7/1982. Bachelor, East China Institute of Chemical Technology, Shanghai (Presently, East China University of Science and Technology). Progress, Challenge and Perspective of Chemical Engineering Education in China Xuhong Qian East China University of Science and Technology The history of Chinese chemical engineering education (CEE) is reviewed; in particular, we analyzed the reason why the naissance of modern engineering science didn’t occur even though the outstanding chemical production practice was achieved in ancient China. As followed, the recent progresses of CEE in China are outlined including the development of East China University of Science and Technology, and we show, from several aspects, that the Chinese chemical engineering is catching up with the World including United States. Despite of this great success, we are facing new global and domestic challenges, of which some are from the development bottleneck of modern chemical engineering discipline and some from the Chinese national conditions. These challengers together with the opportunities are discussed. Finally, we outlook the CCE in new era, and hope make our own contribution to the World. We suggest that multi-scale total engineering education system, composed of self-contained knowledge hierarchy ranging from quantum chemistry to Newton dynamics, continuous fluid dynamics and finally to chemical process design, is necessitated in order to bring up qualified chemical engineers for the upcoming era. Page 15 Plenary lecture speakers Xianghong Cao Member of Chinese Academy of Engineering Cao Xianghong, male, was born in June 1945, in Jiangyin, Jiangsu Province. He worked for Sinopec Beijing Yanshan company more than 30 years, engaged in technical development, production and technical management. Mr. Cao is a professor-level senior engineer and an expert in petrochemical engineering field. He is now a senior member at Sinopec Science and Technology Committee, vice president of Chinese Petroleum Society, vice president of China Energy Research Society, chairman of National Petroleum Products and Lubricants Standardization Technical Committee, and committee member of the Expert Committee of National Energy Administration. After 2000, he served successively as general manager, director and senior vice president, and chief engineer in Sinopec Corp., in charge of technology development and informatization. Since the year of 2008 he left the leadership position but remained as a senior advisor of Sinopec. He has served as president of the chemical industry and engineering society of china, director of Division of Chemical, Metallurgical and Materials Engineering in Chinese Academy of Engineering Mr. Cao was elected as member of Chinese Academy of Engineering in 1999 and elected as foreign member of the National Academy of Engineering, USA, in February 2009. He is a member of the 11th and 12th CPPCC National Committee. China's Oil Refining and Petrochemical Industry: Looking Forward to 2030 Cao Xiang Hong Sinopec, 22 Chaoyangmen North Street,Chaoyang District, Beijing, 100728 The report summarizes the current situation of China's oil refining and petrochemical industry, China has become the major country of oil refining and petrochemical industry, but big and not strong; analysis the challenges that China's oil refining and petrochemical industry will face by 2030, pointed out that diesel, gasoline and oil consumption will have experience peak levels, petrochemical product consumption growth will also slow down, the lack of market competitiveness of raw material factors, resource import dependence continues to rise, challenging task in environment management and so on. For 2030, China's oil refining and petrochemical industry should strengthen industrial foundation; second, develop high-end products;third, adhere to the green low-carbon strategy;fourth,Encourage Science and Technological Innovation;fifth,Integration of information technology;sixth, Strengthen international cooperation, to achieve the industry target from big to strong. Page 16 Plenary lecture speakers Dave Martindale Vice President and General Manager Engineering, Services and Equipment UOP, A Honeywell Company Dave Martindale is Vice President and General Manager of UOP LLC’s Engineering, Services and Equipment group. Dave is responsible for over 1500 technical personnel in 20 offices around the world. His group provides engineering services, equipment design and project management, commissioning support and technical services to UOP’s global customer base. Dave began his career with UOP in 1979. Through the years, he has held positions in R&D and Sales and management positions in Business, Engineering, and R&D. In 2010, Dave was named the Sr. Business Leader for PT&E Hydroprocessing. In 2012, Dave became the Sr. Director of R&D Development for all UOP technologies. He was named the Vice President of Engineering, Services and Equipment in early 2015. Dave has a Bachelor of Science degree in Chemical Engineering and an MBA from the Loyola University of Chicago. Efficiency, Integration and Molecular Management -- The Role of Innovation Dave Martindale, Vice President (Speaker) and Frank Xin Zhu, Corporate Fellow UOP LLC, A Honeywell Company The demand in emerging regions for refinery and petrochemicals products such as higher quality transport fuels, fabrics and plastics continues to grow rapidly. The main challenges to meet this increased demand are value creation and energy utilization. These can be enabled by innovations in molecular management, refinery and petrochemical integration and energy efficiency. This presentation will discuss these innovations including some recently commercialized examples. Page 17 Plenary lecture speakers Chang Wei President, National Institute of Clean and Low Carbon Energy Dr. Chang Wei is President and CEO of the National Institute of Cleanand-low Carbon Energy (NICE). Prior to his current role, Dr. Wei was an executive at General Electric company where he worked for almost 20 years, most recently he was the General Manager responsible for the global water R&D at GE Global Research in the US. NICE is managed by the Shenhua Group, one of the global fortune 500 companies. At NICE, Dr. Wei leads about 300 scientists conducting advanced research in energy areas including coal conversion and processes; coal-based functional materials; water technologies and processes; distributed power and hydrogen energies. Dr. Wei holds a PhD degree in Chemistry with 27 issued US patents and 30+ publications in referred journals. Development of Technologies for Clean and Low Carbon Energy Dr. Chang Wei President, National Institute of Clean and Low Carbon Energy, Beijing, China Formerly, General Manager, GE Global Research in USA and GE Greater China One of the major energy sources is coal and the clean coal applications are critical to the sustainable growth of China. This presentation outlines key technologies in clean coal field including coal refining, coal conversion, ultra-low emission combustion and carbon capture and storage technologies. In addition, this talk will discuss hydrogen energy and its applications, such as hydrogen production, hydrogen transport and storage and downstream hydrogen applications. Different sources of hydrogen, venues of transporting hydrogen, and types of hydrogen applications as well as related economics will also be presented. The major challenges that the energy industry is facing and the potential pathways going forward will be highlighted and discussed Page 18 Plenary discussion speakers Dr. Dingyi Hong Prof. Dr. Hong Dingyi, born in 1946, is the Standing Board Member and Senior Counselor of The Chemical Industry and Engineering Society of China (CIESC). Hong graduated from department of chemical engineering, Beijing Institute of Technology in 1969 and got doctor degree of chemistry from University of Hamburg in 1991.His former positions were: President, Research Institution, Sinopec Yanshan CompanyVice President, PetroChina Daqing Petrochemical Company Director, Science and Technologies Department, Sinopec Group Director, Technology Advisory Committee, Sinopec Group Secretary General, CIESC .Hong is also the Member of Review Committee, China Engineering Education Accreditation Association; Vice Director of Petroleum Processing, Chinese Petroleum Society; Deputy Editor-in-chief of Chemical Industry and Engineering Progress; Editor-in-chief of China Synthetic Resin and Plastics and Petroleum Knowledge. Dr. X.D. Hu currently is the China Managing Director of Albemarle Corporation, a listed company in New York Stock Exchange. Dr. Hu obtained his BS from South China University of Technology, MS in Chemical Engineering from State University of New York at Buffalo, and his Ph.D. from University of Delaware. Over the years, Dr. Hu has been working in catalysis science, new materials, green chemistry, as well as new energy field; and he is holding more than twenty US and PCT patents. In 2003, the team led by Dr. Hu was bestowed the US Presidential Green Chemistry Challenge Award. In 2011, Dr. Hu was granted the Person of ‘Eleventh Five-Year’ Chemical Industry Award, by Gu Xiulian, Vice Chairman of PRC National People’s Congress, at Beijing National Convention Center. In 2013, he was awarded as ‘Entrepreneur with Outstanding Contribution’, in the program of “China Petroleum and Chemical Industry • Corporate Citizenship Model Chart”. Dr. Xiaodong Hu Dr. Hu served as a Visiting Professor for the MOE Green Chemistry Key Laboratory in Tianjin University, and for South China University of Technology. Mr. Guanglian Pang, born on 22 Sep., 1967. International Marketing Specialist, Senior Economist. Mr. Pang has a master’s degree from Peking University since 1991. Secretary General of International Cooperation Committee, Director of International Affairs, China Petroleum and Chemical Industry Federation Deputy Director General, China National Chemical Foreign Economic Cooperation Centre. Mr. Guanglian Pang Mr. Pang has won Science Award from Peking University and some honorary titles have been awarded to him by CMC, Genertec and SASAC. He published such books as Chinese-English Foreign Economic Contracts, Dictionary of English Stylistics, etc and so many professional articles such as On Fund Management, Saudi Petrochemical Industry, Survey of Iranian Petroleum & Chemical Industry Development, Low Carbon Strategy and Environmental Responsibility of Multinational Oil & Chemical Corporations in China, Outlook of China Gas Industry, 8 Principal Basic Tasks for China’s Shale Gas Industry. He also led the task forces such as REACH and the Impact on China Chemical Industry. Page 19 Plenary discussion speakers Dave Martindale Dave Martindale is Vice President and General Manager of UOP LLC’s Engineering, Services and Equipment group. Dave is responsible for over 1500 technical personnel in 20 offices around the world. His group provides engineering services, equipment design and project management, commissioning support and technical services to UOP’s global customer base. Dave began his career with UOP in 1979. Through the years, he has held positions in R&D and Sales and management positions in Business, Engineering, and R&D. In 2010, Dave was named the Sr. Business Leader for PT&E Hydroprocessing. In 2012, Dave became the Sr. Director of R&D Development for all UOP technologies. He was named the Vice President of Engineering, Services and Equipment in early 2015. Dave has a Bachelor of Science degree in Chemical Engineering and an MBA from the Loyola University of Chicago. Director, Strategic Innovation & Collaboration, GE China Technology Center Dr. Bing Zhang has been China Technology Growth Leader of GE China Technology Center since March 1, 2011. He responsible to drive In China For China (ICFC) technology and product initiative across all businesses. The program invested more than 250 million USD and resulted in 70+ new products aiming at local market needs. Since 2014, Dr. Zhang has taken on additional responsivity as the director for Strategic Innovation&Collaboration, to facilitate growth through collaborations with government and external institutions and companies in strategic technology areas. The center is one of GE’s five global research centers, covering a diverse range of industries and technologies including Energy, Water, Oil & Gas, Healthcare, Transportation, Aviation, Lighting, and Industrial Solutions. Dr. Bing ZHANG Dr. Yi Jiang Page 20 Dr. Yi Jiang, Business Director, Corning Incorporated (USA), is responsible for general management of Corning Advanced-Flow Reactor (AFR) business globally, and also for Emerging Business Development (EBD) in Asia. Formerly, the Manager of Global Reactor & Application Engineering at Corning European Technology Center in France; the Project Manager & Research Manager at Corning Corporate Research in USA. Before joining Corning Incorporated, Yi has worked in chemical & petrochemical industries (Sinopec, DuPont, and ConocoPhillips) as senior process & research engineers for industrial novel reactor designs and process development. Yi earned his PhD in chemical engineering from Washington University in St. Louis (USA); holds more than 10 patents, 30+ publications in top ranking chemical engineering journals. Yi has served as chairs/co-chairs for novel reactor technical sessions at AIChE Annual Meetings, Asia Pacific Chemical Reactor Engineering Conferences etc. Yi delivered track records in revenue growth and profitability for Corning new business in emerging markets, has received “2013 Technology Innovation Award” and “2014 Outstanding Entrepreneur Award” from China Petroleum and Chemical Industry Federation . Plenary discussion speakers Arvind Varma is the R. Games Slayter Distinguished Professor and Head, School of Chemical Engineering at Purdue University. His research interests are in chemical and catalytic reaction engineering, and new energy sources. Dr. Arvind Varma has served as the R. Games Slayter Distinguished Professor and Head, School of Chemical Engineering at Purdue University since January 2004 – he was named Jay and Cynthia Ihlenfeld Head in 2012. Prior to joining Purdue, he was the Arthur J. Schmitt Professor of Chemical Engineering and Director of the Center for Molecularly Engineered Materials at the University of Notre Dame. Prof. Arvind Varma Dan Luss is the Cullen Professor in the Department of Chemical & Biomolecular Engineering at the University of Houston. Dr. Luss is the co-developer, director and lecturer in a continuous education course on Applications of Heterogeneous Catalysis given by now to over 2000 participants in the US and 600 in Europe. He is the editor of the book series, Reviews in Chemical Engineering and the journal editor of Catalysis Reviews, Science and Engineering. Dr. Luss has won the Wilhelm Award and Founders Award of the AIChE, Research Award by the Alexander von Humboldt Foundation, and the Amundson Award. He is a Fellow of the AIChE and a member of the National Academy of Engineering. Prof. Dan Luss James Wei began his career as a research scientist for Mobil Oil in 1955. Since then, he held academic positions as Colburn Professor at the University of Delaware, Head and Lewis Professor at MIT’s chemical engineering department, and Dean of Princeton's School of Engineering & Applied Science. As an expert on the environmental impact of the chemical industry, he has participated in many governmental panels, such as the National Research Council. Dr. Wei is the author of eight books and many papers. He is a former president of the AIChE and a member of the US National Academy of Engineering. Prof. James Wei Page 21 Plenary discussion speakers Professor in mechanical and chemical Engineering, East China University of Science and Technoogy. He received Ph.D degree from Nanjing Tech University in 1988. He has been engaged in the research of thermal effect on materials, structures and processes, and development of micro chemo-mechanical systems. He is an author of more than 300 papers and received a number of distinguished national and international awards. He had been a vice president of Nanjing Tech University and East China University of Science and Technology for many years. He is now an honorary professor of the University of Nottingham and has been the honorary President of Chinese Pressure Vessel Institution (since 2010) and The honorary president of Chinese Materials Institution (since 2015), Chairman of China Structural Integrity Consortium, Chairman of Asian Oceanic Regional Committee of International Council for Pressure Vessel Technology. Prof. Shan-Tung Tu Professor and Head, Department of Chemical and Biomolecular Engineering, Director, Centre for Green Products and Processing Technologies, Fok Ying Tung Graduate School Co-Director, Joint Centre of HK-BJ UST, Fok Ying Tung Graduate School, The Hong Kong University of Science and Technology. Prof. Chen is the editor of Separation and Purification Technology, editorial board member of International Journal of Drying Technology, Chinese Journal of Chemical Engineering, International Journal of Food Engineering, International Journal of Environment and Waste Management, Modern Chemical Industry; IAC member of The 8th world congress of chemical engineers and the 13th AsiaPacific Confederation Conference of Chemical Engineering; SC Member of the 2nd International Symposium on Green Chemical Products and Process Engineering. Prof. Guohua Chen Prof. Wang currently is the Professor and Chairman of Department of Chemical Engineering in National Taiwan University. He obtained his B.S. in Chemical Engineering from National Taiwan University and Ph.D. in Chemical Engineering from Pennsylvania State University. Prof. Wang has been working in membrane separation technology, molecular simulation and tissue engineering. In 2005, he was bestowed Outstanding Teaching Award of the NTU. He is editorial board of Journal of Applied Membrane Science and Technology, Chinese Institute of Chemical Engineers and Journal of Chemical Engineering of Japan, Scientific Committee Member of Aseanian Membrane Society, Scientific Committee Member of Aseanian Membrane Society. Prof. Daming Wang Page 22 Space for Symposium M105 M103 (M105) M203 Page 23 List of Symposium No. Symposia Session Room 1 Advanced Technology for Air Separation and Purification 3 C201 2 Bioengineering and Biotechnology 5 C104 3 Catalysis and Reaction Engineering 4 C204 4 Energy 4 M105 5 Food and Pharmaceutical Technologies 5 C103 6 Green Technology 5 M1004 7 Management Science for Research and Development---How to make R&D effective and efficient 2 M806 8 Materials and Nano Technology 5 C208 9 Membrane Technology for Water Purification 4 C202 10 Particle and Fluidization Technology 3 M203 11 Petrochemicals and Fine Chemicals 3 M104 12 Process Development and Optimization 3 M103 13 Thermodynamics and Transport Phenomena 5 C209 14 Separation Technology 5 M106, No16 Building 15 Forum of Chemical Engineering Department Deans and Chairs 1 M103 Note: M806 and M1006 are also located in Yifu Building, on the 8th floor and 10th floor, respectively. For example, the air separation/purification symposium is assigned S1. Page 24 Parallel Symposium Schedule Table Tuesday Oct.13 Afternoon C201 Yifu Building No.16 Building Thursday Oct.15 Morning Afternoon Morning 1-A 1-B 1-C Afternoon C104 2-A 2-B 2-C 2-D C204 3-A 3-B 3-C 3-D M105 4-A 4-B 4-C 4-D C103 5-A 5-B 5-C 5-D 5-E C208 8-A 8-B 8-C 8-D 8-E C202 9-A 9-B 9-C 9-D M201 10-A 10-B 10-C M104 11-A 11-B 11-C M101 12-A 12-B 12-C 15 C209 13-A 13-B 13-C 13-D 13-E M106 14-A 14-B 14-C 14-D 14-E 7-A 7-B 6-B 6-C 6-D 6-E M806 Yifu Building Wednesday Oct.14 M1004 6-A 2-E For example, Room C201 was allocated for the 3 sessions (1-A, 1-B, 1-C) of the air separation/purification symposium on 10/14 (am & pm) and 10/15 (am). Page 25 Keynote & Invited Speakers The 8th Sino-US ChE conference will comprise 3.5 days of presentations; nearly 300 oral presentations and over 550 abstracts. This handbook only publishes some feature abstracts. For more detailed information, please see our electronic version of the proceedings. Page 26 Symposium 1- Advanced Technology for Air Separation and Purification ( C201) Symposium 1- Advanced Technology for Air Separation and Purification Chairs: Zhong Li, [email protected]; Huizhou Liu, [email protected] John Billingham, [email protected]; Norberto Lemcoff, [email protected] Featured Speakers Jerry Y. S. Lin Wednesday Oct.14, 10:20-11:00 AM C201, Yifu Building Dr. Jerry Y.S. Lin is a Regents‘ Professor at the Arizona State University in Tempe. He also serves as editor of Journal of Membrane Science. Dr. Lin was a professor of chemical engineering and co-director of the NSF Center for Membrane Applied Science and Technology at University of Cincinnati prior to joining ASU in January, 2005. Dr. Lin received B.S. (1982) from Zhejiang University in China, and M.S. (1985) and Ph.D (1988) from Worcester Polytechnic Institute in the U.S., all in chemical engineering. In research, Dr. Lin has made significant contributions to the advancement of inorganic membrane science and high temperature gas separation technologies. As of January, 2015 he has published over 255 refereed papers in chemical engineering and materials science SCI journals, 10 book chapters and 50 conference proceedings papers; he also holds 8 patents; his papers have received over 8400 SCI citations (with H-index over 51) . Perovksite Structured Metal Oxide Sorbents with Oxygen Vacancy OrderDisorder Transition for High Temperature Air Separation Oxygen sorption on perovskite-structured metal oxides offers an effective solution to air separation at high temperatures. However, the main challenges in developing this new high temperature adsorption separation technology are large heat of adsorption and slow desorption kinetic. This talk will present a method to minimize the heat effects and enhance desorption kinetics by taking advantage of an endothermic process of oxygen vacancy order-disorder phase transition accompanying the oxygen sorption process on some perovskite-structured metal oxide sorbents. The paper will report oxygen sorption isotherms, phase diagram, exothermic heat of oxygen sorption, and endothermic heat of order-disorder phase transition for a perovskite sorbent with composition of La0.1Sr0.9Co0.9Fe0.1O3−δ. The conditions for zero apparent heat of sorption are determined. The strategy for heat effect minimization is demonstrated with the results of TGA/DSC measurements at different operating conditions. Air separation by a fixed-bed packed with the perovskite-type oxide sorbent will be presented to demonstrate the enhancement in the oxygen adsorption and desorption rates. Page 27 Page 1 Symposium 1- Advanced Technology for Air Separation and Purification ( C201) Heqing JIANG Wednesday Oct.14, 8:30-9:15 AM C201, Yifu Building Prof. Dr. Heqing JIANG is the Leader of Membrane Separation & Catalysis Group, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Science (QIBEBT, CAS). After his postdoctoral stay with Prof. Schueth at the Max-Planck-Institut für Kohlenforschung in Mülheim, he joined QIBEBT as a full professor in 2013. Dr. Jiang is the recipient of Thousand Talents Program for Distinguished Young Scholars. His main research interest focuses on the functional materials with nanostructures and their application in separation and catalysis. So far, Dr. Jiang has published more than 30 papers on a number of scientific journals such as Angew. Chem. Int. Ed., Chem. Commun., J. Membr. Sci., etc. Oxygen transport membranes for air separation under harsh conditions The oxyfuel technology using ceramic membranes with mixed oxygen ion and electronic conductivity for oxygen production represents a promising technique for CO2 capture, and is considered as one of the most advanced technologies for clean power production. The operation environment of oxygen transport membrane (OTM) in oxyfuel process is relatively harsh, and the membrane is exposed to a recirculated sweep gas stream to pick up the permeated oxygen, which contains highly concentrated CO2. The stability of the membrane against CO2 corrosion is essential to guarantee long-term operation. In addition, OTM is attracting increasing interests as the reactor for partial oxidation of methane to syngas due to the simplicity in process design, safety in operation, and outstanding performance in oxygen separation. To choose appropriate OTM with high oxygen permeability and thermochemical stability is very important when constructing such kind of membrane reactors. In this talk, we will discuss the stability of cobalt-containing perovskites and ceria-based membranes for air separation under CO2 or reducing atmosphere. Chu Zheng Thursday Oct.15 , 8:30-9:10 AM C201, Yifu Building Chu Zheng obtained PhD Degree from East China University of Science and Technology in 2012. He is appointed as Deputy Chief Engineer of Nanjing Chemical Industry Group, Director of R&D Dept, and concurrently President of Research Institute of Nanjing Chemical Industry Group, Sinopec. He is also deputy president of CCU and CO2 Mineralization Utilization Institute of Sinopec &Sichuan University. Professional Field: Technology development and management of Gas purification, CO2 Capture and Utilization, Catalysis, Oilfield chemicals and Fine Chemicals. Obtained more than 10 times of Provincial & Ministerial Grades Award for Science and Technology Progress. Published more than 10 professional papers, and be granted nearly 20 patents. He is successively awarded as “Outstanding Contribution to Sinopec Experts”, “State Council Expert for Special Allowance” and Senior Export of Sinopec. CCUS Technology Development in SINOPEC The paper summarizes SINOPEC’s research findings on various types of CCUS technology, and analyzes their overall status of R&D&D (research and development and demonstration), technology feature, challenging difficulty, development potential, application performance and promising prospect. SINOPEC has comprehensively integrated with whole CCUS value chain, including carbon capture, utilization and EOR. In the aspect of CO2 capture, SINOPEC has series of proprietary CO2 capture technologies and recently developed numerous novel technologies. Meanwhile, SINOPEC has implemented CO2 utilization technology featured as chemical utilization (methanol), mineralization utilization (solid waste phosphogypsum) and biological utilization (microalgae oil). CO2 capture and injection into oil reservoirs for EOR is a practical and economical way for reducing CO2 emissions and enhancing oil recovery. SINOPEC has been planning for constructing four large gas flooding industrial demonstration projects to carry out CO2 EOR and storage, including Shengli, Zhongyuan, Huadong and Dongbei. Page 28 Symposium 1- Advanced Technology for Air Separation and Purification ( C201) Wei Tang Wednesday Oct.14, 11:00-11:40 AM C201, Yifu Building General Manager of Beijing Peking University Pioneer Technology Co., Ltd. Associate Professor of College of Chemistry and Molecular Engineering of Peking University. Major participant of the Project “Development of Highly efficient adsorbent for air separation and large scale VPSA-O2 equipment”, which won the first prize for Science and Technology Progress by the Ministry of Education in 2006. Major participant of the Project “Using highly dispersed CuCl/zeolite adsorbent for CO separation”, which won the Second Prize for National Technology Invention in 2007 Separation of CO from blast furnace gas by VPSA using adsorbent PU-1 In China, steel plants are emitting 2×1010 m3/year blast furnace gas (BFG) containing 25% CO, which might be used as fuel or to synthesize methane, acetic acid, DMF, DMC, glycol, TDI etc.. However, 50% N2 in BFG makes it difficult for cryogenic separation, since the boiling points of CO and N2 are too close. To solve that problem, a highly efficient CuCl/Zeoilte adsorbent named PU-1 has been developed, which has high CO adsorption capacity and high CO/N2 selectivity. By using PU-1 in VPSA process, over 40 large scale equipments have been built in China to separate CO from syngas, calcium carbide tail gas etc., with CO purity >99% and recovery >85%. As for the separation of CO from BFG, the first 67000 Nm3/h plant was built in China in 2013. Without pretreatment of 25% CO2 in BFG, the plant produces 20000 Nm3/h CO with purity 65~75% and recovery >77%, which has been used as the fuel for steel rolling heating furnace, replacing 4×107 Nm3 natural gas per year. Further removing CO2 in BFG, purification to >99% CO could be done to meet the requirement of chemical synthesis. Qingyuan Yang Wednesday Oct.14, 9:15-10:00 AM C201, Yifu Building Qingyuan Yang was born in China in 1976. He received his Ph.D. degree (2005) in Chemical Engineering at Beijing University of Chemical Technology, then, he joined the group of professor Chongli Zhong. He worked as a postdoctoral research fellow at Université Montpellier 2 in France from 2010-2011. He currently is a professor in Chemical Engineering at Beijing University of Chemical Technology. His main research interest focuses on employing computational techniques to model gas adsorption, diffusion and separation in nanostructured materials including metal-organic frameworks and covalent-organic frameworks. Computational study of structure-property relationships of MOFs and COFs for gas separation Currently, the associated research on MOFs and COFs has been rapidly developed into one of the important areas in chemistry, materials science, and multiple branches of engineering. The remarkable feature of the two types of porous materials allows them to serve as a uniquely ideal platform for various specific applications including gas separation. Considering the structural complexity and diversity of MOFs and COFs, molecular modeling provides a powerful tool to give deep insight into the phenomena studied at the molecular level compared to experimental exploration. On the other hand, structure−property relationships are crucial for enabling a theoretically rapid screening of existing MOFs and COFs as well as for guiding the design/synthesis of novel adsorbents with desirable structural characteristics. Thus, with the aid of a multiscale computation, some new concepts and research methods have been developed for better understanding the structure-property relationships of MOFs and COFs for targeted gas separation, and some quantitative models have been further derived. These models could be used to rationalize and predict the performance of a large series of MOFs and COFs as well as guide the design of advanced materials with outstanding performance for industrial gas separation. Page 29 Symposium 1- Advanced Technology for Air Separation and Purification ( C201) Krista S. Walton Wednesday Oct.14, 15:20-16:00 PM C201, Yifu Building Krista Walton was the Tim and Sharon Taylor Assistant Professor of Chemical Engineering at Kansas State University from 2006-2009 and then joined the faculty of the Georgia Institute of Technology in the School of Chemical & Biomolecular Engineering in August 2009. She serves as Director in the AIChE Separations Division and Secretary/Treasurer of the International Adsorption Society. Metal-Organic Frameworks for Removal of Ammonia from Air Metal-organic frameworks (MOFs) are permanently porous coordination polymers that have recently emerged as an important new class of porous materials with the potential to make an immediate impact in adsorption separation technologies. MOFs are synthesized by a self-assembly process in which metal or metal-oxide vertices are connected by rigid or semi-rigid organic molecules. The rational synthesis approach opens up the possibility for new advances in the development of new and improved adsorbents for air purification and the removal of toxic industrial chemicals.1 MOFs have shown the potential to be designed for adsorbate-specific interactions. However, the density of active sites is often low, and the commercial use of MOFs is still limited by issues with water stability2 and synthesis scale-up. This presentation will discuss our recent progress in this area and will demonstrate the applicability of MOFs in ammonia removal from air. Page 30 Symposium 1- Advanced Technology for Air Separation and Purification ( C201) Wednesday Oct.14 (C201) Chair : John Billingham Title Morning Name Affiliation S1-K1 Computational study of structure-property Qingyua relationships of MOFs and COFs for gas n Yang separation (A0150) Beijing University of Chemical Technology 9:10-9:40 S1- I1 Recent advances in oxygen production by Christian VPSA (A0104) Voss Linde AG, Engineering Division 9:40-10:10 S1- I2 8:30-9:10 Progress on removal NOx and VOCs by environmental catalysis (A0404) 10:1010:20 10:2011:00 11:0011:40 Junhua Li Tsinghua University Jerry Lin Arizona State University Tang Wei Beijing Peking University Pioneer Technology Co. Ltd Name Affiliation Coffee break S1-K2 Perovksite Structured Metal Oxide Sorbents with Oxygen Vacancy OrderDisorder Transition for High Temperature Air Separation (A0079) Separation of CO from blast furnace gas by VPSA using adsorbent PU-1 S1-K3 11:4013:30 Lunch (Youyi Restaurant) Chair : Norberto Lemcoff Title Afternoon 13:3014:10 S1-K4 Oxygen transport membranes for air separation under harsh conditions (A0143) Heqing Jiang Qingdao Institute of Bioenergy and Bioprocess Technology, CAS 14:1014:40 S1-I3 Innovative Process Design for Large Scale Air Separation (A0125) Stephen Cook Air Products PLC UK 14:4015:10 S1-I4 Core-shell oxide catalysts for VOCs combustion Shen Zhao Tsinghua University Page 31 Symposium 1- Advanced Technology for Air Separation and Purification ( 201) 15:10-15:20 15:20-16:00 16:00-16:30 16:30-17:00 Coffee break S1-K5 S1-I5 S1-I6 Metal-Organic Frameworks for Removal of Krista Georgia Institute Ammonia from Air (A0155) Walton of Technology Synergy Action Mechanism of Water Vapor and Surface Chemistry of Adsorbents for Enhancing CO2/N2/CH4 Sepration (A0279) Jing Xiao South China University of Technology Hydrogen separation through mixed proton-electron conducting membrane (A0207) Yanying Wei Institute of Physical chemistry and Electrochemi stry, Leibniz University of Hannover Thursday Oct.15 (C201) Chair : John Billingham Morning Title Name Affiliation Nanjing 8:30-9:10 S1-K6 9:10-9:40 S1- I7 9:40-10:10 S1-I8 Chu Zheng Air purification in industrial and commercial Norberto environments (A0146) Lemcoff CFD study of mixing performance in Quan Sulzer Chemtech redistribution systems for packed columns (A0306) Yang Ltd Note: S ~ Symposium K~ Keynote I~ Invited talk Page 32 Petrochemica l Research Institute Co. Ltd., China CCUS Technology Development in SINOPEC (A0331) Rensselaer Polytechnic Institute Symposium 2- Bioengineering and Biotechnology (C104) Symposium 2- Bioengineering and Biotechnology Chairs: Jianhe Xu, [email protected]; Yan Sun, [email protected] Shijie Liu, [email protected]; Steven Peretti, [email protected] Featured Speakers Percival Zhang Tuesday Oct.13, 13:30-14:10 PM C104, Yifu Building Percival Zhang is a professor in department of biological systems engineering at Virginia Tech. He received his M.S. degree (1996) in biochemical engineering at East China University of Science and Technology and PhD in chemical engineering and biochemistry from Dartmouth College. He worked as a postdoctoral research associate at Dartmouth College from 2004-2005. He His main research interest focuses on watershed science & engineering and biomolecular engineering. He was deputy editor-in-chief in Energy Science and Engineering in 2012. He serves as academic editor in PLoS One. Biomanufacturing 4.0: in vitro Synthetic Enzymatic Biosystems The largest production challenge of biocommodities (e.g., biofuels, renewable chemicals, and even food) from carbohydrates, other energy sources (e.g., solar energy and methane) or other carbon sources (e.g., CO2 and coal) is economics, satisfying three manufacturing criteria: high product yield, fast productivity and easy product separation. Living natural or engineered cells have their inherent constraints, such as selfduplication, bioenergetics, cell membrane, and so on, resulting in their limited success in high-energy efficiency biotransformation, especially in the energy area. In vitro synthetic biosystems (IVSB) via the in vitro assembly of numerous standardized and exchangeable enzymes or their complexes and/or (biomimetic) cofactors can implement complicated biological reactions that microbes cannot do . Guanghui Ma Thursday Oct.15, 8:30-9:10 AM C104, Yifu Building Ph.D., Doctoral Supervisor, Winner of the National Science Fund for Distinguished Young Scholars, Member of “One Hundred Person Project of The Chinese Academy of Sciences”, Director of National Key Laboratory of Biochemical Engineering, Director of National Engineering Research Center for Biotechnology. Her main research field focuses on bioformulation and biomaterial engineering. She has published more than 200 peer-reviewed journal papers, 7 English and 4 Chinese scientific books, 96 patents (44 granted) and 4 PCT patents. Recently, She has been awarded National Award for Technological Invention 2nd Prize (2009), Asian Young Women Researcher Awards 1st Prize in Engineering and Technology (2009), and YABEC Award (2012). Utilizing Microsphere Material Technology to Promote Development of Biochemical Engineering Microsphere materials have played great role on development of Biochemical Engineering and related industries in history. Microcapsule technique promoted the birth of long-acting formulation of protein/peptide drugs. Therefore, it can be expected the invention of new microsphere materials will lead to development of biochemical engineering. In fact, in above chemical engineering application, the size and morphology of microsphere materials should be controlled and optimized respectively according to their applications. However, there is few method to prepare uniform microsphere for biocompatible polymer system such like polysaccharide, polylactide, and so on. As a result, the effect of size on application results could not be studied systematically and precisely. Page 33 Symposium 2- Bioengineering and Biotechnology (C104) Yu-Chen Hu Wednesday Oct.14, 8:30-9:10 AM C104 Classroom, Yifu Building Dr. Yu-Chen Hu currently is a professor in department of chemical engineering, National Tsing Hua University, Hsinchu, Taiwan. Dr. Hu’s main research interests include vaccine development, gene therapy and tissue engineering. Dr. Hu has won the Asia Research Award (Society of Chemical Engineers, Japan), Outstanding Research Award (Ministry of Science and Technology, 2006, 2014), Wu Ta-You Memorial Award (NSC), Outstanding Academia-Industry Research Award and Outstanding Young Investigator Award in Taiwan. Gene Therapy Meets Cell Therapy: Applications in Regenerative Medicine Delayed union/non-union resulting from bone fractures or serious trauma remains a challenging problem for orthopaedic surgeons. Conversely, cartilage defect or degeneration due to trauma or joint diseases can lead to debilitating pain and physical impairment. These problems have inspired the development of tissue engineering, which combines cells, biomaterials and biological signals, to stimulate cartilage/bone regeneration. Over the past decade, gene therapy has converged with cartilage and bone engineering, by which an increasing number of therapeutic genes are explored to stimulate cartilage and bone repair. These genes can be administered to cells via in vivo or ex vivo approaches using either viral or nonviral vectors. This presentation will focus on the use of viral vectors for genetic engineering of mesenchymal stem cells for cartilage/bone regeneration. In particular, emphasis is placed on the applications of baculovirus, an emerging nonpathogenic gene delivery vector, for the repair of cartilage and bone. Jian-Jiang Zhong Wednesday Oct.14, 10:30-11:10 AM C104 Classroom, Yifu Building Prof. Jian-Jiang Zhong graduated from Petro-Chemical Engineering course of ECICT (Now: East China University of Science & Technology) in 1986, and obtained his Ph.D. degree in Fermentation Technology/Biotechnology from Osaka University, Japan in 1993. He was awarded the Cheung Kong Scholar Professorship by the Ministry of Education of China in 1999 and the National Science Fund for Distinguished Young Scholars by NSFC in 2002. He is a Distinguished Professor of Shanghai Jiao Tong Univ., and on the executive board of Asian Federation of Biotechnology (AFOB). Dr. Zhong is Editor-in-Chief of two SCI-journals - Process Biochemistry and Biotechnology and Applied Biochemistry. Professor Zhong's major research interests include molecular biochemical engineering, advanced fermentation technology, and synthetic biology. Bioproduction process intensification by innovative engineering studies on bioreactor and cellular metabolism Bioproduction process has "green" and some unique features which attract great interest for industrial application as a powerful biomanufacturing platform. Reduction of production cost, which depends on the enhancement of bioprocessing efficiency, is a critical issue to commercial success. Bioproduction process intensification, as a key to solving the bottleneck, was here achieved by innovative engineering studies on bioreactor and cellular metabolism. A typical example to be illustrated is production of ganoderic acids by Ganoderma lucidum, a traditional Chinese medicinal mushroom, which have significant anti-tumor and antimetastasis activities. Their further (pre-)clinic evaluations are severely hampered by lack of sufficient amount of the pure compounds. To overcome the problem of target compound supply, advanced bioprocess technology and smart bioseparation protocol are very important and urgently required. Our strategies for enhancing the production and recovery of the secondary metabolites from fermentation of the mushroom mycelia include bioreactor innovation, two-stage cultivation strategy, signal transduction engineering of calcium/calcineurin signaling system, metabolic engineering, novel chemical conversion and simultaneous extraction/hydrolysis, etc. This presentation will show how the titer and productivity of fermentation production of ganoderic acid by G. lucidum was greatly improved by innovative engineering studies. Page 34 Symposium 2- Bioengineering and Biotechnology (C104) Zheng Liu Tuesday Oct.13, 15:30-16:10 PM C104 Classroom, Yifu Building Prof. Zheng Liu is a Yangtze River Scholarship Professor of biochemical engineering at department of chemical engineering, Tsinghua University. Prof. Liu obtained his bachelor's, master's and doctoral degrees in chemical engineering from Tsinghua University in 1987, 1989 and 1993, respectively. He worked as a UNESCO Research Fellow at Tokyo Institute of Technology, Japan, during 1993 to 1994. Prof. Liu’ research focuses on chemical and biomolecular engineering, with special interests in simulation and control of protein conformational transition in vitro; design and synthesis nanostructured enzyme catalysts for chemical synthesis; and bioremediation of contaminated soil. He has supervised more than 40 graduate students, published 180 peer-reviewed journal papers, and 12 patents. Harnessing Nanostructures for Enhanced Biocatalysis This presentation will summarize our recent progress in constructing robust and active biocatalysts through modifying enzymes by various nanomaterials. In addition to the enhanced activity, we will show how nanostructures are applied for an enhanced catalysis through either substrate channeling or active uptake of substrate. The newly developed methods including aqueous synthesis of multi-enzyme embedded MOFs and Con A mediated multi-enzyme catalyst will be described. A multi-scaled molecular dynamics simulation of CO2 transport into the active site of carbonic anhydrase will also be presented in the context of fabricating a carbonic anhydrase based catalysts for enhanced CO2 capture and transformation. He Huang Wednesday Oct.14, 15:30-16:10 PM C104 Classroom, Yifu Building Dr. He Huang was born in 1974. He obtained PhD degree in chemical engineering at Purdue University (USA) in 2002 and established laboratory of industrial catalysis and microbial metabolic engineering at Nanjing University of Technology in 2004. His main research interests focus on engineering technology platform for microbial metabolism of bio based chemicals and industrial catalytic technology platform for bio based chemicals. So far, Dr. Huang has published more than 90 papers on a number of scientific journals such as Biotechnol. Adv. Carbon., etc. He is reviewers of several journals such as Bioresour. Technol., Process Biochem., Catal. Commun., etc. Bioproduction of nutritional chemicals in China With the increase of economic level and the improvement of the health concerns, people are increasingly concerned about the nutrition, safety and function of the food. Nutritional chemicals are now the trend of fine chemical industry. Nutritional supplements could be produced by enzymatically or through microbial fermentation. In the present report, the historic developments and technological achievements in nutritional chemicals production in the past several years are reviewed. The species, characteristics, market of nutritional chemicals were firstly introduced. Subsequently, recent studies of the bio-based nutritional chemical production are summarized. In this part, we will focus on several typical products, such as polyunsaturated fatty acids, vitamin K2, functional sugar, and so on. Furthermore, progress in the industrial production of several nutritional chemicals is discussed. Finally, guidelines for future studies of nutritional chemical production are proposed in light of the current progress, challenges, and trends in the field. Page 35 Symposium 2- Bioengineering and Biotechnology (C104) Shijie Liu Wednesday Oct.14, 13:30-14:10 PM C104 Classroom, Yifu Building Prof. Shijie Liu currently worked in SUNY ESF, he earned his PhD degree in Chemical Engineering from University of Alberta, Edmonton (1992). His research interests mainly focus on bioenergy, biomaterials, sustainability bioengineering, chemical kinetics, mass transfer, fluid particle systems process optimization, fiber properties, applied mathematics. Ligand-Binding Isotherm and Catalysis of Polymorphic Enzymes While most enzymes are single-sited for binding key ligands (or substrate) for which Michaelis-Menten equation is adequate, there exist multiple binding-site enzymes. Multiple binding sites can appear either for simple enzymes or for conformal complex structure of enzyme molecules. The multi-site behavior of enzymes (or enzyme complexes) leads to the concepts of coorperativity, allostery or allosteric enzymes. Substrate binding isotherm and catalytic rate expressions have been derived for multi-site enzymes without differentiating the different structural confirmations. The simple kinetic expressions can explain some of the simple allosteric interactions. Still, there are enzymes present as dynamic mixtures of multiple oligomer forms, or polymorphs. A polymorph or system of multiple oligomeric enzymes can be summarily described quantitatively with cooperative substrate binding and catalytic reaction theory. Page 36 Symposium 2- Bioengineering and Biotechnology (C104) Tuesday Oct.13 (C104) Chairs : Prof. Liu, Shijie, SUNY ESF Afternoon Title Name Affiliation 13:3014:10 S2-K1 Biomanufacturing 4.0: in vitro Synthetic Enzymatic Biosystems (B0420) Percival Zhang Virginia Institute of Technology S2- I1 Engineering energy metabolism based on synthetic cofactor (B0090) Zongbao Zhao Dalian Inst Chem Phys, CAS S2- I2 A novel biochemical route for fuels and chemicals production from cellulosic biomass (B0377) Zhiliang (Julia) Fan University of California , Davis Zheng Liu Tsinghua University 14:1014:35 14:3515:00 15:0015:30 Coffee break Chairs : Prof. Yuan Qi-Peng, Beijing Univ Chem Technol 15:3016:10 16:1016:35 16:3517:00 S2-K2 S2-I3 Harnessing Nanostructures for Enhanced Biocatalysis (B0094) Novel biocompatible materials and their applications in biomedical engineering Lei Zhang (B0285) S2-I4 Enzymatic Modification of Collogen Proteins (B0190) Daidi Fan Tianjin University Northwest University Page 37 Symposium 2- Bioengineering and Biotechnology (C104) Wednesday Oct.14 (C104) Chairs : Prof. Zhang, Lei, Tianjin University Morning 8:30-9:10 9:10-9:35 9:35-10:00 Title S2-K3 S2- I5 S2-I6 Name Gene Therapy Meets Cell Therapy: Applications in Regenerative Medicine Yu-Chen Hu (B0432) Build competitiveness of industrial biotechnology (B0594) Jibin Sun Scale-up and Optimization of the Animal Wensong Cell Culture Processes and Bioreactors for Tan Biologicals Production (B0400) 10:00-10:30 Affiliation Tsing Hua University Tianjin Inst Ind Biotechnol, CAS ECUST Coffee break Chairs : Prof. Zhang, Percival West Virginia 10:30-11:10 11:10-11:35 S2-K4 Bioproduction process intensification by innovative engineering studies on bioreactor and cellular metabolism (B0165) Jianjiang Zhong Shanghai Jiaotong University S2-I7 Production of courmarines and muconic acid by metabolic-engineered E. coli (B0337) Qipeng Yuan Beijing Univ Chem Technol Metabolic engineering of Saccharamyces cerevisiae for production of fumaric acid Liming Liu 11:35-12:00 S2-I8 12:00-13:30 Page 38 (B0322) Lunch (Youyi Restaurant) Jiangnan University Symposium 2- Bioengineering and Biotechnology (C104) Chairs : Prof. Zhao, Zong-Bao, Dalian Inst Chem Phys, CAS Afternoon 13:3014:10 14:1014:35 Title S2-K5 Name Ligand-Binding Isotherm and Catalysis Shijie Liu of Polymorphic Enzymes (B0296) Affiliation SUNY ESF S2-I9 Engineering bacterial biocatalysts for Christopher ESF, Syracuse the production of biodegradable Nomura plastics (B0463) S2-I10 Enhancement of Fatty Alcohols Production with E. coli Modified with Tandem Repeats Assisted Genome Editing Method (B0124) Jianmin Xing Institute of Process Engineering, CAS S2-K6 Bioproduction of nutritional chemicals in China (B0205) He Huang Nanjing University of Technology 16:1016:35 S2-I11 Microalga Neochloris Oleoabundans Cultivation for Biodiesel Feedstock (B0419) Zisheng (Jason) Zhang U Ottawa 16:3517:00 S2-I12 Cellulosic ethanol production using Jerusalem Artichoke stalks: strain development and process integration Xinqing Zhao Shanghai Jiaotong Univ Name Affiliation Guanghui Ma Institute of Process Engineering, CAS 14:3515:00 15:00- Coffee break 15:30 Chairs : Prof. Lin, Dong-Qiang, Zhejiang University 15:3016:10 Thursday Oct.15 (104) Chair: Prof. Liu, Prof. Christopher Nomura Morning Title 8:30-9:10 Utilizing Microsphere Material Technology to Promote Development of Biochemical Engineering (B0508) S2-K7 Page 39 Symposium 2- Bioengineering and Biotechnology (C104) 9:10-9:35 9:3510:00 S2-I13 Rational design of mixed-mode Dongqiang chromatography for antibody purification Lin (B0149) Zhejiang University Xiao Zhang Washington State University S2-I15 Engineering clostridia for biofuels and chemicals production from renewable biomass (B0385) Shangtian Yang The Ohio State University S2-I16 Dry milling biorefinery processing of lignocellulose biomass for production of biofuels and biochemicals (B0095) Jie Bao ECUST S2-I17 High-throughput droplet microfluidic screening for improving protein secretion of cell factories Yunpeng Bai ECUST S2-I14 Biomaterial from renewable lignocellulosic biomass (B0367) 10:0010:30 Coffee break Chairs: Prof. Sun, Yan, Tianjin Univ 10:3010:55 10:5511:20 11:2011:45 12:0013:30 Lunch (Youyi Restaurant) Chairs : Prof. Zheng Liu (Tsinghua Univ)/Prof. Liu, Shijie, SUNY ESF 13:3015:00 Free discussion: New opportunities and challenges of industrial biotechnology Note: S ~ Symposium; K~ Keynote lecture; I~ Invited talk Note: Chairs will announce at the beginning of the symposium that there would be a free discussion session (2E) on Thursday afternoon. Page 40 Symposium 3- Catalysis and Reaction Engineering (C204) Symposium 3- Catalysis and Reaction Engineering Chairs: Guanzhong Lu, [email protected]; Xiaojun Bao, [email protected] Maria Burka, [email protected]; Ted Oyama, [email protected] Featured Speakers Bruce C. Gates Wednesday Oct.14, 8:30-9:15 AM C201, Yifu Building Bruce Gates began his career as a researcher at Chevron. He then joined the chemical engineering department at Delaware University. He was one of the founders of the Center of Catalytic Science and Technology at Delaware. He coauthored the widely-used text book “Chemistry of Catalytic Processes.” In 1992, Dr. Gates joined the University of California Davis. His research interests are: catalysis, nanomaterials, surface chemistry, organometallic surface chemistry, new catalytic materials, reaction kinetics and engineering. He made seminal contributions to hydroprocessing, a vital petroleum refining process. He received many awards from the AIChE, ACS, and North American Catalysis Society. He is a member of US Academy of Engineering. Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science Advances in synthesis and characterization of essentially molecular metal complexes and clusters on supports are making a reality of catalyst design. We summarize work unraveling effects of the design variables of these siteisolated catalysts: the metal, metal nuclearity, support, and other ligands on the metal. Successful syntheses provide structurally simple, uniform species bonded to crystalline porous supports chosen for their relatively high degrees of uniformity: zeolites, MOFs, and MgO. The catalyst syntheses involve reactions of organometallic precursors (e.g., Ir(C2H4)2(acac) (acac is acetylacetonate) with OH groups of the support surfaces—to give structures such as Ir(C2H4)2, with the Ir atom bonded to two oxygen atoms of the support. The methods of characterization of the supported species include IR, EXAFS, XANES, and NMR spectroscopies, atomic-resolution electron, and computations at the level of density functional theory. Tao Zhang Tuesday Oct.13, 15:20-16:00 PM C204 Classroom, Yifu Building Dr. Tao Zhang is currently a Professor & Director General of the Chinese Academy of Sciences from State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS. He was elected as member of Chinese Academy of Science. His research expertise and interests are in the area of catalytic decomposition technology of aerospace nontoxic propellants, environmental catalysis, new catalytic materials, etc. So far, there are more than 260 SCI papers and 100 patents to be published. He is the editorial broad of Applied Catalysis, Environmental and ChemPhyChem. Catalytic conversion of biomass to fuels and chemicals: opportunities and challenges Lignocellulose is the most abundant biomass. The huge and diversified resources and non-edible nature of lignocellulose make it an ideal feedstock alternative to fossil for the sustainable production of fuels and chemicals in a renewable way. Catalysis is intensively involved in the biorefinery of lignocellulose, as it has been doing in the oil/coal refinery process. However, the stubborn and recalcitrant structure of lignocellulose, the high O/C ratio in its composition, and the difficulty in separation of cellulose, hemicellulose and lignin in natural raw materials present significant challenges in the biorefinery process. In this presentation, I will first give a summary of the recent advances in the catalytic conversion of biomass to fuels and chemicals, and then put focus on the development of new catalytic processes in my own group, and finally provide an outlook on the opportunities and challenges. Page 41 Symposium 3- Catalysis and Reaction Engineering (C204) James Wei Wednesday Oct.14, 8:30-9:10 AM C204 Classroom, Yifu Building Diffusion Regimes of Molecules in One-dimensional Zeolite Channels The diffusion of noble gas molecules (Ne, Ar, Kr) in one-dimensional zeolite channels (VET, AFI, VFI) is simulated by molecular dynamics. The diffusion regimes include: Knudsen Diffusion where molecule-wall collisions dominate, Gaseous Diffusion where molecule-molecule collisions dominate, and Configurational Diffusion where molecule and wall are in constant contact. The principal parameters in the determination of diffusivity regimes are: the diameter ratio (dc/dm) of the channel to the molecule, and the volume density (NVm/Vc) which is the ratio of the volume of N molecules to volume of channel. For a molecule in a channel, we define the mean stop path (MSP) as the average distance between collisions, which may be with another molecule or with the wall; it depends on both the mean free path and the channel diameter. Dan Luss Wednesday Oct.14, 13:30-14:10 PM C204 Classroom, Yifu Building Impact of cycling and catalyst configuration on reduction of NOx emission from diesel engines The reduction of NOx gases emitted by diesel passenger cars is usually accomplished by a Lean NOx Trap (LNT) also referred to as NOx Storage and Reduction (NSR) technology. This process consists of periodic cycling between a lean feed (NOx + excess O2,), leading to storage of the NOx storage on the LNT catalyst (Pt/BaO/CeO2/Al2O3) and a rich feed (mixture of CO, H2 and hydrocarbons) that reduces the stored NOx to N2 . The NOx conversion by the LNT is typically unsatisfactory (< 80%) at exhaust temperatures lower than 200 oC, and higher than 400 oC. Toyota researchers developed a Di-Air (Diesel NOx aftertreatment by Adsorbed Intermediate Reductants) process in which a high frequency injection of hydrocarbon expands the operating temperature window of the LNT. Page 42 Symposium 3- Catalysis and Reaction Engineering (C204) Xiaojun Bao Wednesday Oct.14, 15:20-16:00 PM C204 Classroom, Yifu Building Dr. Xiaojun Bao was born in April, 1963. He is currently a professor of the faculty of Chemical Science and Engineering in China University of Petroleum (Beijing) as well as director of The Key Laboratory of Catalysis, China National Petroleum Co. Dr. Xiaojun Bao’s main research interests include synthesis of mesoporous materials, catalyst development for upgrading petroleum products, catalyst and reactor development for synthesis gas making via partial oxidation. Dr. Xiaojun Bao has been editorial members of Chinese Journal of Chemical Engineering, Chinese Journal of Fuel Chemistry, Petroleum Science. So far, there are more than 20 SCI papers and four monographs to be published. Development and Application of A Fluid Catalytic Cracking Gasoline Hydro-Upgrading Process GARDES More than 90% of sulfur-containing compounds and about 90% of olefins in typical refinery gasoline pools come from fluid catalytic cracking (FCC) gasoline, thus the sulfur and olefin reduction of this stream is crucial for producing clean gasoline. It has been widely recognized that hydrotreating is the most important technique for producing clean transportation fuels in industrial practice, but the existing techniques can hardly accomplish the objectives of both deep hydrodesulfurization (HDS) and olefin reduction of FCC gasoline with acceptable loss in gasoline research octane number (RON). To solve this problem, we developed a novel process, GARDES, by coupling high-efficient HDS and directed olefin conversion. Michael P. Harold Thursday Oct.15, 8:30-9:10 AM C204 Classroom, Yifu Building Michael P. Harold is Dow Chair Professor and Chairman of the Department of Chemical Engineering at the University of Houston. In the 1990’s, he was a research manager of the Chemical Process Fundamentals Group in the Central Research Department of DuPont. In this role Mike led programs to develop breakthrough technologies for the manufacture of key industrial polymers and their corresponding chemical intermediates, and synthetic melt-spun fibers. Mike’s expertise and research interests are in the area of chemical reaction engineering, with specific focus on reaction-separation devices, inorganic membrane synthesis and applications, and catalytic and biocatalytic materials. He is the editor of the AIChE J. Reaction and Transport Coupling in Multi-Functional Catalysts for Selective Oxidation of Ammonia to N2 The reduction of NOx from lean burn engine exhaust involves structured catalytic reactors wherein storage, transport and reaction are coupled to achieve emission targets over a wide range of temperatures and space velocities. The lean selective catalytic reduction (SCR) of NOx requires the supply of the reductant NH3, a fraction of which may escape unconverted from the SCR reactor. For this reason an “Ammonia Slip Catalyst” (ASC) is positioned downstream of the SCR catalyst with the purpose of eliminating the slipped ammonia by catalytic oxidation to N2. The most active ammonia oxidation catalyst is Pt but the N2 selectivity is only high near the light-off temperature (~200-250 oC). At higher temperature NO and NO2 are the major oxidation products. The ASC combines an ammonia oxidation catalytic function containing Pt with a NOx reduction function containing Fe- or Cu-exchanged zeolite to convert NH3 with high selectivity to N2. In this talk we describe the performance features of the ASC reactors comprising catalyst architectures that combine multiple active layers and/or zones containing the NH3 oxidation and NOx reduction functions. We show how focused experiments complemented by modeling can not only lead to deeper insight but also to “optimal” structures and operating strategies. Page 43 Symposium 3- Catalysis and Reaction Engineering (C204) Suojiang Zhang Thursday Oct.15, 10:20-11:00 AM C204 Classroom, Yifu Building Suojiang Zhang is Professor & Director General of Institute of Process Engineering (IPE), Chinese Academy of Sciences (CAS). Since 2001, he started to work in IPE as the "Hundred Talents". He won “National Science Fund for Distinguished Young Scientists” in 2006 and “973 Chief Scientist” in 2008. Prof. Zhang mainly engages in ionic liquids and green process engineering, including molecular design, large-scale preparation, clean processes and system integration. He has published more than 180 SCI papers in academic journals, and authored or edited four monographs, and filed for more than 40 patents. He served as the editor in chief of Process Engineering Journal (China), and Editorial Board Members of Journal of Industrial & Engineering Chemistry Research, Journal Greenhouse Gases: Science and Technology, Science China Chemistry and etc. Ionic Liquid Catalytic Reaction for Green Process Engineering As a green medium, ionic liquids (ILs) have been widely used in catalytic reaction, organic synthesis, separation process and other fields due to their unique properties and great potentials in industry applications. We focused on the investigation of ILs from fundamental studies to practical applications. On the molecular level, we found that H-bond in ILs showed the covalent feature based on the molecular dynamic simulation and experimental characteristic, which has been defined as a new concept of Z-bond. It was also found that Z-bond made a great contribution to the catalytic reaction. We revealed the synergistic catalytic effect of cations and anions, and developed series of homogeneous and supported functionalized IL catalysts with high catalytic activity. Based on the fundamental research on Z-bond, the novel green processes were established. Page 44 Symposium 3- Catalysis and Reaction Engineering (C204) Tuesday Oct.13 (C204) Chair : Tao Zhang/Ted Oyama Afternoon Title 13:3014:10 S3-K1 14:1014:40 S3- I1 14:4015:10 S3- I2 Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science (C0406) Development of Earth Abundant Membrane Reactors for Energy Efficient Chemical Processing (C0380) Theoretical studies of rare earth CeO2 catalysis (C0545) 15:1015:20 Name Bruce Gates Colin A Wolden Xueqing Gong Affiliation University of California, Davis Colorado School of Mines ECUST Coffee break 15:2016:00 S3-K2 16:0016:30 S3-I3 16:3017:00 S3-I4 Dalian Catalytic conversion of biomass to fuels Institute of and chemicals: opportunities and Tao Zhang Chemical challenges Physics, CAS ExxonMobil Bifunctional Zeolite-Metal Catalyzed JoséG. Research and Paraffin Hydroisomerization: Santiesteba Engineering Implications for Production of High n Company Performance Distillate and Lubricants Annandale (C0365) The Kinetics and mechanism of Ted University of hydrodeoxygenation of a model biomass Oyama Tokyo/Virgin compound on nickel phosphide (C0049) ia Tech Wednesday Oct.14 (C204) Chair : Chunming Xu/ Ted Oyama Morning 8:30-9:10 9:10-9:40 9:40-10:10 Title Name Affiliation S3-K3 Diffusion Regimes of Molecules in Onedimensional Zeolite Channels (C0378) James Wei Princeton S3- I5 Electrocatalytic Dehydrogenation of 2propanol in EHP reactor Xuemei Wu Dalian Univerisity of Technology S3-I6 Selective oxidation of glycerol to dihydroxyacetone catalyzed by Pt-Bi supported on N-doped carbon nanotubes (C0185) Hao Yu South China University of Technology Page 45 Symposium 3- Catalysis and Reaction Engineering(C204) 10:1010:20 10:2011:00 11:0011:30 11:3012:00 Coffee break Chunming Xu China University of Petroleum Goetz Veser University of Pittsburgh Andrew Gellman Carnegie Mellon University Name Affiliation Dan Luss University of Houston Boping Liu ECUST Dalin Li Fuzhou University S3-K6 Development and Application of A Fluid Catalytic Cracking Gasoline HydroUpgrading Process GARDES (C0414) Xiaojun Bao China University of Petroleum, Beijing S3-I11 Integrated Multi-functional Catalyst Devices for Vehicle Emission Control (A0268) Wei Li GM S3-I12 Quantitative Kinetics and the Structural Mechanism for Ni-Co Dry Reforming Catalysts (C0065) Haiyan Zhao University of Idaho S3-K4 S3-I7 S3-I8 12:0013:30 Composite Ionic liquid alkylation(CILA) process produces high-quality gasoline Bimetallic Oxygen Carriers for Chemical Looping Conversion of Methane (C0248) Alloy Catalysis across Alloy Composition Space: AuxCuyPd1-x-y (C0055) Lunch (Youyi Restaurant) Chair : Xiaojun Bao/Maria Burka Afternoon Title 13:3014:10 S3-K5 14:1014:40 S3-I9 14:4015:10 S3-I10 15:1015:20 15:2016:00 16:0016:30 16:3017:00 Page 46 Impact of cycling and catalyst configuration on reduction of NOx emission from diesel engines (C0175) One Pot Synthesis of Bimodal Molecular Weight Polyethylene Using Cr/V Bimetallic Catalysts Controlled synthesis and catalytic property of Ni-based alloy catalysts for steam reforming of tar (C0246) Coffee break Symposium 3- Catalysis and Reaction Engineering (C204) Thursday Oct.15 (C204) Chair : Suojiang Zhang/ Ted Oyama Morning Title Name Affiliation 8:30-9:10 S3-K7 Reaction and Transport Coupling in Multi-Functional Catalysts for Selective Oxidation of Ammonia to N2 (C0325) Michael Harold University of Houston S3-I13 From fundamentals to industrial practice: ordered-structure carrier materials in hydortreating catalyst for ultra-clean fuel production (C0309) Yandan Wang China University of Petroleum, Beijing S3-I14 Bimetallic structure considerations in the catalytic production of aromatic amines (C0374) Michael Wong Rice University 9:10-9:40 9:40-10:10 10:1010:20 Coffee break 10:2011:00 S3-K8 Ionic Liquid Catalytic Reaction for Green Process Engineering (C0265) Suojiang Zhang Institute of Process Engineering, CAS 11:0011:30 S3-I15 Catalytic Consequences of LayeredZeolite Precursor Delamination (C0081) Alexander Katz UC Berkeley Raffaella Ocone Heriot-Watt University 11:3012:00 12:0013:30 Complex Reactions in a FCC Riser S3-I16 Reactor (C0184) Lunch (Youyi Restaurant) Note: S ~ Symposium K~ Keynote I~ Invited talk Page 47 Symposium 4- Energy (M105) Symposium 4- Energy Chairs: Zhongmin Liu, [email protected]; FuchenWang, [email protected] Mike Klein, [email protected]; Joseph Smith, [email protected] Featured Speakers Arvind Varma Tuesday, Oct.13, 13:30-14:10 PM M105, Yifu Building Selected Topics Related to Energy and Chemicals In the presentation, some selected research programs to produce energy carriers and valuable chemicals from new or renewable sources, currently being conducted in my group, will be discussed. These include (i) hydrogen generation for vehicle applications, (ii) catalytic upgrading of bio-oils, (iii) utilization of glycerol, a biodiesel waste product, for its purification and production of valuable chemicals, and (iv) oxidative coupling of methane [6]. Xinbin Ma Tuesday, Oct.13, 15:20-16:00 PM M105, Yifu Building Xinbin Ma is the Dean of School of Chemical Engineering and Technology, Tianjin University. His research interests are in C1 chemical engineering, and green chemistry and technology. An Alternative Synthetic Route for Ethylene Glycol/Ethanol Production: Fundamental Research and Industrial Applications Ethylene glycol (EG) and ethanol (EtOH) are important chemicals or fuel additives used in a variety of consumer and industrial applications. We described an alternative approach for the synthesis of EG/EtOH derived from syngas based on an integrated technology consisting of the coupling of CO with methanol to form dimethyl oxalate (DMO) and subsequent hydrogenation. For the key issues of copper-based catalysts faced in the hydrogenation reaction, such as indeterminate active sites, unstable active species and the internal diffusion limit in scale-up, new strategies were presented not only for design of a highly efficient and stable catalyst, but also for highly chemo-selective synthesis of EtOH and EG. …… Page 48 Symposium 4- Energy (M105) Jinsen Gao Wednesday, Oct.14, 10:20-11:00 AM M105, Yifu Building Jinsen Gao is the dean of Chemical Engineering College in CUPB and director of the State Key Laboratory of Heavy Oil Processing. His research interests are in heavy oil processing technology, clean fuel oil production and computational chemical engineering. An Upgrading Process of Viscous Heavy Oil by Fluid Thermo-Cata-Contacting Conversion Pretreating inferior residues to provide feedstock with trace metals and a few asphaltenes for downstream processes is important for refineries to process heavier crude oils. Toward this end, the upgrading of Liaohe vacuum residue over special catalysts designed for decarbonization and demetalization, which is called fluid thermal conversion (FTC), was investigated in a technical pilot scale riser apparatus. The experimental results demonstrate that moderate cracking severity is favorable for obtaining the maximum distillate (C5~500 oC) yield. Under the favorable conditions, the yield of total liquid product was 79.63 wt%, and coke yield was 15.59 wt%, which took up 87% CCR value of the feedstock, while the gas yield was 2.11 wt%. In addition, most of the contaminants, such as above 97% asphaltenes and metals were removed. Then, the properties of liquid products were analyzed in detail. The RON of gasoline is high up to 94, whereas that is generally only about 60 for coker gasoline. The basic nitrogen compounds in heavy cycle oil was 824 μg•g-1, only about 1/3 that of coker gas oil. To understand secondary processing performance of heavy liquid products, fluid catalytic cracking (FCC) of heavy cycle oil and FTC of slurry were conducted. The results reveals that heavy cycle oil has better FCC ability than coker gas oil, whereas FTC ability of slurry is considerably below that of Liaohe vacuum residue. Jingguang Chen Wednesday, Oct.14, 13:30-14:10 PM M105, Yifu Building Jingguang Chen is the Thayer Lindsley Professor of Chemical Engineering in the Department of Chemical Engineering at Columbia University. Previously, he was a senior researcher at Exxon’s Corporate Research Laboratories. His research interests are in understanding and developing metal carbides and bimetallic alloys as catalysts and electrocatalysts through combined theoretical and experimental approaches over model surfaces and supported catalysts. He is an expert in using in situ synchrotron techniques for investigating structural and electronic properties of catalysts. CO2 Conversion to Methanol and Syngas Rising atmospheric concentration of CO2 is forecasted to have potentially disastrous effects on the global climate changes and ocean acidification. A catalytic process that utilizes CO2 as a feedstock to make methanol, carbon monoxide, or methane is potentially more desirable than sequestration. In the current talk we will describe our recent results of CO2 conversion through heterogeneous catalysis, using approaches involving parallel efforts in density functional theory (DFT) calculations, surface science experiments on model systems, synthesis and evaluation of supported catalysts, and in-situ characterization of catalysts under reaction conditions. We will compare three examples for the catalytic conversion of CO2, to methanol over Cu-based oxides, to methane over bimetallic alloys, and to CO over metal carbides. We will discuss general trends, challenges and opportunities for the catalytic conversion of CO2. Page 49 Symposium 4- Energy (M105) Yong Yang Wednesday, Oct.14, 15:20-16:00 PM M105, Yifu Building Yong Yang is the Director of research and development center of Synfuels China Co., Ltd. His research interests is in the catalytic chemistry of coal-toliquids Fischer–Tropsch synthesis process development: from laboratory to commercial scale Milestone advances using Synfuels China’s Fischer–Trospch (F–T) synthesis technology have been made towards commercialization of Fischer-Trospch synthesis technology in China. A four million ton/a coal-toliquids (CTL) plant is under construction in Ningxia province following the successful technology demonstration at 4000 bbl/d scale in Inner Mongolia. The CTL process development by Synfuels China started from solid fundamental studies with more than twenty years experience accumulation in catalysis and kinetic studies, which led to the demonstration of Synfuels China’s medium temperature FT (MTFT) synthesis process. Density Functional Theory (DFT) together with the sophisticated catalyst property characterization tools has been routinely applied during catalyst development. Fundamental R&D efforts integrating all aspects of chemical engineering have greatly been enhanced by combining the fundamental tools covering the F–T synthesis mechanism, reaction engineering, and process optimization. Joseph Smith Thursday Oct.15, 8:30-9:10 AM M105, Yifu Building Joseph D. Smith currently holds the Laufer Endowed Energy Chair at Missouri University of Science and Technology (formally Missouri Rolla) where he also serves as Director of the Energy Research and Development Center, positions to which he brings over 25 years of diversified experience in academia and industry. Dr. Smith has served as an expert witness for Flare Performance and Hydrocarbon Processing. He has significant experience in the fossil energy industry, including application of multi-physics CFD based models for coal combustion, biomass gasification, and industrial furance optimization. Resilient Energy through Hybridization in Microgrid Applications In the future, the electric grid must be more resilient and adaptable to local catastrophes including fires, severe storms, and heat waves. Microgrids represent a way to improve energy resilience because they would allow smaller regions (neighborhoods, towns, cites) to disconnect from the national electric grid and become islands of stable, independent power to support critical infrastructure including hospitals, airports, food distribution, communication centers, etc. The work reported here describes efforts to develop resilient energy through hybridization in Microgrid applications. These efforts are focused on incorporating clean, low-carbon energy resources together with efficient energy storage and local on-site energy management systems. These microgrids will help meet carbon reduction goals as we explore concept that integrate various technologies into the larger grid, including electric vehicles. The focus of our work has been to assess the viability of a microgrid to manage renewable energy together with conventional energy resources to meet electric power demand while minimizing adverse grid impacts. Our work examines the use of microgrid controller/energy management systems coupled with renewable energy resources (i.e., solar, wind, geothermal, hydro, biomass) in a hybridized energy system. Our work examines the economic impact replicating deployment of renewable-based microgrids for commercial, industrial, and mixed-use applications. …… Page 50 Symposium 4- Energy (M105) Tuesday, Oct.13 (M105) Chair : Zhongmin Liu Afternoon 13:30-14:10 S4-K1 14:10-14:40 S4-I1 14:40-15:10 S4-I2 Title Name Affiliation Selected Topics Related to Energy and Chemicals (D0506) Arvind Varma Prudue University Dalian Recent researches on coal pyrolysis in DUT Haoquan University of (D0583) Hu Technoloy North Carolina Tailored Transition Metal Oxides for Light Fanxing State Paraffin Conversion (D0053) Li University 15:10-15:20 Coffee break 15:20-16:00 S4-K2 An Alternative Synthetic Route for Ethylene Glycol/Ethanol Production: Fundamental Research and Industrial Applications (D0566) 16:00-16:30 S4-I3 High Energy Density Chemistries for Redox Flow Batteries (D0203) 16:30-17:00 S4-I4 17:00-17:30 S4-I5 Recent Progress in Heavy Oil Hydroconversion (D0379) Xinbin Ma Tianjin University Levi University of Thompson Michigan Min Chang Ultra-deep Reactive Adsorption Desulfurization of FCC Gasoline over Ca- Hao Ling Doped Ni/ZnO-Al2O3-SiO2 Adsorbents Alpha Management Consulting Services ECUST Wednesday, Oct.14 (M105) Chair : Michael Klein; Xinbin Ma Morning Title Name Affiliation Xinjin Zhao ExxonMobil 8:30-9:10 S4-K3 The Outlook for Energy: A View to 2040 (D0195) 9:10-9:40 S4- I6 Molecular Characterization and Modeling Shu Wang AspenTech, Inc. for Crude Oil and Reactors (D0066) S4-I7 Chemical Looping Gasification with University of Catalytic Oxygen Carrier for Hydrogen- Kunlei Liu Kentucky Rich Syngas Production (D0409) 9:40-10:10 10:10-10:20 Coffee break Page 51 Symposium 4- Energy (M105) 10:20-11:00 S4-K4 11:00-11:30 S4-I8 11:30-12:00 S4-I9 12:00-13:30 An Upgrading Process of Viscous Heavy China Oil by Fluid Thermo-Cata-Contacting Jinsen Gao University of Conversion (D0399) Petroleum Evaluation of CO2 capture from flue gas by two successive VPSA units in an existing Ping Li coal power plant (D410) Beyond Carbon Neutral (D0327) ECUST Mark Barteau University of Michigan Energy Institute Name Affiliation Lunch (Youyi Restaurant) Chair : Joseph Smith; Jinsen Gao Afternoon Title CO2 Conversion to Methanol and Syngas Jingguang Chen (D0375) Columbia University 13:30-14:10 S4-K5 14:10-14:40 S4-I10 Research and application of SE gasification Xiaolei technology of pulverized coal (D0525) Guo 14:40-15:10 S4-I11 RD&D Activities of SNG Production from Zhongshan Dalian Institute Yuan Syngas Methanation at DICP of Chem Phy 15:10-15:20 15:20-16:00 16:00-16:30 Coffee break S4-K6 S4-I12 Fischer–Tropsch synthesis process development: from laboratory to commercial scale (D0590) Synfuels China Yong YangTechnology Co., Ltd Software Tools for Molecular-Level Kinetic Michael Modeling in Thermochemical Klein Conversions(D0166) 16:30-17:00 S4-I13 Co-feeding of biomass liquids with fossil feedstocks to FCC unit for production of Siauw Ng renewable transportation fuels (D384) 17:00-17:30 S4-I14 Hydrogen production from biomass using an integrated process (D0442) Page 52 ECUST Suping Zhang University of Delaware Canmet ENERGY, Natural Resources Canada ECUST Symposium 4- Energy (M105) Thursday Oct.15 (M105) Chair : Michael Klein; Fuchen Wang Morning Title 8:30-9:10 S4-K7 Resilient Energy through Hybridization in Microgrid Applications (D0396) 9:10-9:40 S4-I15 Understanding the influences on coal ash slag viscosity at gasification condition (D0453) 9:40-10:10 S4-I16 10:10-10:20 S4-I17 10:50-11:20 S4-I18 11:50-13:30 Affiliation Missouri Joseph University of Smith Science and Technology Institute of Jin Bai Coal Chemistry, CAS Soil-based Microbial Fuel Cell for Indore Institute Mukund Electricity generation using Shewanella and of Science & Mishra Geobacter bacteria present in soil (D0580) Technology Coffee break 10:20-10:50 11:20-11:50 Name S4-I19 FCC co-processing of oil sands bitumen and shale oil (D0401) Canmet ENERGY Yi Zhang Devon, Natural Resources Canada Molecular-Level Modeling on the Linzhou Composition, Conversion and Separation of Zhang Heavy Petroleum (D0495) Biomass Conversion to Hydrogen with Suppressed COx formation via Alkaline Ah-Hyung Thermal Treatment and integrated Carbon Park Capture (D0593) China University of Petroleum Columbia University Lunch (Youyi Restaurant) Note: S ~ Symposium K~ Keynote I~ Invited talk Page 53 Symposium 5- Food and Pharmaceutical Technologies (C103) Symposium 5- Food and Pharmaceutical Technologies Chairs: Yingjin Yuan, [email protected]; Bangce Ye, [email protected] Daniel Hsieh, [email protected]; Shang Tian Yang, [email protected] Featured Speakers San Kiang Tuesday Oct.13 , 13:30-14:10 PM C103; Yifu Building Dr. San Kiang work as an Director Process R/D for Bristol-Myers Squibb Company. Bristol-Myers Squibb Company (BMS) is a global biopharmaceutical company. The Company is engaged in the discovery, development, licensing, manufacturing, marketing, distribution and sale of biopharmaceutical products on a global basis. The role of particle engineering in designing pharmaceutical particles and pharmaceutical composite material (PCM) In solid dosage processes, the Active Pharmaceutical Ingredient (API) is generally blended with excipients via wet or dry granulation. In some cases, direct blending is also possible. The size and shape of the API particle can be modified in a way so that the formulation process and the drug product performance can be optimized. Some common particle engineering approaches will be reviewed. A relatively new area of particle engineering is to study how certain commonly used excipients can be combined with API in more deliberate and controlled manner. This approach leads to the design of pharmaceutical composite material (PCM). In the field of material science, there are many examples of composite materials. Two well-known composite materials in everyday use are Concrete (stones and cement), and fiber reinforced polymer. The composite approach combines two or more material in a specific way in order to produce a material with different physical or chemical properties. PCM can be designed to solve some of the common issues related to solid dosage production such as material flow, stability, release profile, bioavailability, content uniformity and taste. Ren Xiang Tan Tuesday Oct.13, 15:20-16:00 PM C103, Yifu Building Ren Xiang Tan is a professor in State Key Laboratory of Pharmaceutical Biotechnology, Nanjing University. His research focuses upon natural products, including the discovery methods, structural analysis, functional identification and biosynthetic pathway in novel molecules from plants and microbes. Published more than 300 papers in a broad range of journals such as Nat. Commun., Proc. Natl. Acad. Sci. USA, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nat. Prod. Rep., Chem. Rev., et. al. Mycosynthetic generation of new bioactive molecules The impact of natural products on drug discovery pipelines keep kindling the interest in structurally unpredictable low-molecular-weight biomolecules as an unforeseeable source of pharmaceutical leads. But scientists are being more or less frustrated by re-isolations of described compounds from new organism collections since countless natural products have been characterized since Serturner’s isolation of morphine in 1806. To overcome this frustration and the limitation in the organism-based affordability and chemical space expansion of minor new natural products, chemical synthesis has been performed to produce complex molecules and natural product-like compounds with privileged scaffolds found in nature. To add more skills to the existing arsenal of searching for new bioactive molecules, this talk will present the mycosynthetic generation of unnatural hybrid molecules with biological function by taking the advantage of evolutionally acquired fungal bioassembly lines. The key points and advantages of the mycosynthetic approaches will be mentioned for enabling fungi to produce more novel alkaloids and polyketides as well as the alkaloid-polyketide hybrid molecules. …… Page 54 Symposium 5- Food and Pharmaceutical Technologies (C103) Zhixian Gao Wednesday Oct.14 , 8:30-9:10 AM C103; Yifu Building Dr. Zhixian Gao works as the Director of Hygiene Monitoring Center of PLA. Dr. Gao’s research focus on Bionsensing and Food safety detection. Development of rapid detection technology and equipment for drinking water and food safety With increasing requirements of drinking water safety under special conditions(such as more affairs activities 、more emergencies 、more natural disasters、more international affairs,and so on ), How to insure safety for drinking water and food ?we developed rapid screening ,monitoring technologies and risk monitoring technological system of typical harmful factors in drinking water and food safety,established the preparation technologies for molecularly imprinted polymers ,and then developed nanoparticle molecular imprinted materials for small molecular chemical pollutant and macromolecular SE toxin. High specific antibodys of typical pesticide and veterinary drug were prepared with selection of antibodies by ribosome display library. MIPs-chemiluminescence sensor and MIP-SPR immunosensor used for the detection small molecular chemical contaminant were fabricatied.we have established high-throughput 3-D agrose immunochip technology for the multiple detection of mycotoxins and suspension array technology for the detection of a variety of chemical contaminates and some pathogenic bacteria.A series of rapid detection kits , strips based on cadmium telluride quantum dots and photonic crystal and it’s portable mini-sized detectors were developed for drinking water and food safety. Y. Martin Lo Wednesday Oct.14, 10:20-11:00 AM C103, Yifu Building Dr. Y. Martin Lo is the CEO & President of Biointellipro LLC. He serves as the first Ambassador for the International Union of Food Science and Technology (IUFoST) and received from White House the US Presidential Volunteer Service Award in 2012. As a FDA-recognized Process Authority, Dr. Lo reviews and certifies scheduled process for food companies to meet FDA/USDA regulations on high risk acidified and low-acid canned foods. His area of expertise are food Sciences, food processing safety, and biochemical engineering Food safety and agriculture challenges and call for actions Food safety has become an emerging issue globally, especially with interwoven food supply chain that not only increases challenges but also adversely impacts human health. There is a dire need to establish a sound and effective mechanism to reduce and minimize food safety hazards. While movements toward risk-based management are evident in recent years, voids remain when it comes to foster environmentally benign, sustainable agriculture. Additional to the guiding principles, this talk intends to address the practices and challenges when assessing food safety risks on a global level, as well as how to integrate various tools from a broad spectrum in order to attain safe and quality foods for the ever-increasing global population. Page 55 Symposium 5- Food and Pharmaceutical Technologies (C103) Daijie Chen Wednesday Oct.14 , 13:30-14:10 PM C103; Yifu Building Dr. Daijie Chen, Microbial Biochemical Pharmaceuticals (Shanghai Institute of Pharmaceutical Industry.), Professor and doctoral tutor, vice dean of pharmacy school, Shanghai Jiaotong University. Four stage anaerobic technology Two sets of 20T four stages anaerobic reactor system were established and were used to treat sewage from spiramycin and etimicin production respectively. The results showed that the COD degration rate reached 90% and 95% which were much more higher than those in one stage anaerobic reactor system. Some other parameters such as antibiotics degration rate, the time course of pH and activated sludge were also investigated. After more than 6 months tests, we concluded that antibiotic production sewage could be treated using such multistage-anaerobic technology more effectively to substitute one stage anaerobic reactor system commonly used nowadays. In addition, the anaerobic degradation behaviors of spiramycin I by sludge were investigated. Structural determination was then performed by nuclear magnetic resonance and MS/MS spectra, and data indicated that hydroxylation and hydrolysis were main reactions during the anaerobic digestion of spiramycin I. P-1 is the intermediate of hydroxylation, and P-2 is the intermediate of hydrolysis. P-3 is the final product of the both reaction. This study revealed a hydroxylation and hydrolysis mechanism of macrolide in anaerobic digestion. Jing Wu Wednesday Oct.14, 15:20-16:00 PM C103; Yifu Building Dr. Jing Wu is a professor in Wuxi Medical School of Jiangnan University. Her research interests are in Peptide drug molecular pharmacology and Replication mechanism of DNA polymerase mismatch and cell damage Study on the Preparation of Cyclodextrin Cyclodextrins (CDs) are unique natural materials, which can bind hydrophobic molecules within their internal cavities and carry them into aqueous solution. These advantageous properties have led to their widespread use in many industrial fields. Cyclodextrin glycosyltransferases (EC 2.4.1.19, CGTases) could catalyze the conversion of starch or starch derivatives into mixtures of -, -, and -cyclodextrins. Starch is composed of D-glucose units linked together by -1,4-glucosidic linkages and -1,6-glucosidic linkages. Due to CGTases’ incapability of hydrolyzing -1,6-glucosidic linkages, only a part of starch could be used to be transformed into CDs. In order to improve the yield of starch conversion, a new synchronous bioconversion process was applied, in which both the isoamylase and CGTase (- or - CGTase) were used simultaneously. The yield of α- and γ-cyclodextrin was turned out to be 79.8% and 72.5% (w/w), respectively. Symposium 5- Food and Pharmaceutical Technologies (C103) Y-H Percival Zhang Thursday Oct.15, 8:30-9:10 AM C103, Yifu Building Percival Zhang is a professor in department of biological systems engineering at Virginia Tech. He received his M.S. degree (1996) in biochemical engineering at East China University of Science and Technology and PhD in chemical engineering and biochemistry from Dartmouth College. He worked as a postdoctoral research associate at Dartmouth College from 2004-2005. He His main research interest focuses on watershed science & engineering and biomolecular engineering. He was deputy editor-in-chief in Energy Science and Engineering in 2012. He serves as academic editor in PLoS One. Out-of-the-box Solutions: Making Synthetic Starch and Zero-Calorie Sweetener from Nonfood Biomass The global food system is experiencing profound changes as a result of anthropegenic pressures. Increasing population to 9 billion and food consumption per capita means that the global food demand could increase by 70% by 2050. Food security is placing unprecedented demands on agriculture and natural resources, such as water, land, fertilizers, and fossil fuels. The World Health Organization (WHO) and Food and Agricultural Organization (FAO) recommend population nutrient intake goals for preventing diet-related chronic diseases in terms of caloric uptake: total carbohydrate (55-75%), total fat (15-30%), and protein (1015%), where free sugars (i.e., monosaccharides and disaccharides) in the diet accounts for less than 10% of carbohydrate intake. A properly balanced diet is important to lower health risks, such as obesity, type 2 diabetes, cardiovascular diseases, hypertension, cancer and so on. …… Changsheng Zhang Thursday Oct.15, 10:20-11:00 PM C103, Yifu Building Dr. Changsheng Zhang works as a professor in South China Sea Institute of Oceanology, China. His research focus on discovery, biosynthesis and metabolic engineering of marine microbial natural products Biosynthesis and Metabolic Engineering of Pharmaceutically Relevant Polycyclic Natural Products from Marine-derived Actinomycetes Marine-derived actinomycetes are emerging as the most important new sources for discoverying novel natural product possessing excellent bioactivities with pharmaceutical significance. Our findings demonstrate that marine-deirved actinomycetes are rich in taxonomical diversity and are prolific in producing bioactive compounds, as exemplified by bisindole alkaloids with unprecedented spiro-rings, and several polycyclic natural products with diverse bioactivities. Biosynthetic studies revealed different mechanisms to form polycyclic rings. Xiamycin A is an indolosesquiterpene isolated from a marine-derived Streptomyces sp. SCSIO 02999. Genetic and biochemical experiments demonstrated that a cascade of oxidative cyclization reactions were involved in the formation of the pentacyclic ring in xiamycin A. In contrast, a reductive cyclization strategy was unveiled for the biosynthesis of ikarugamycin, a polycyclic tetramate macrolactam. The biochemical mechanism to form an inner five-membered ring, catalyzed by the NAD(P)H-dehydrogenase IkaC, was unveiled by labelling studies using stereospecifically deuterated NADPH cofactor and/or deuterium oxide,mechanistcally analogous to a [1 + 6] Michael addition reaction. Intriguingly, spontaneous cyclizations occured during the biosynthesis of polycyclic macrolactams heronamides, which also featuring double bond migrations in the side chain. We also reported the production of structure variants of polycyclic naturla products via metabolic engineering. Symposium 5- Food and Pharmaceutical Technologies (C103) Canping Pan Thursday Oct.15, 13:30-14:10 AM C103, Yifu Building Canping Pan is a Professor at China Agricultural University. His interested topic are Pesticide residue, MRM analytical methods, food safety, pollutants, environment, MRLs, GAP, dietary risk assessment, QSPR, Codex CLXs, CCMAS, CCPR, and JMPR Progress on Pesticide Residue Analytical Methodology and International Risk Management Pesticide/veterinary residue analysis is advancing very rapidly, which is required by monitoring market samples in many countries for both domestic and international trading, regulatory enforcement, risk assessment of dietary intakes, organic food verification, environmental research and so on. At the same time, analytical methods for pesticide/veterinary determination are facing challenges with various demands, for ins. rapid screening, on-site detection. For most methods, the key procedures of pesticide/veterinary residue analysis are: cleanup of sample extracts in order to avoiding interferences from complicated matrices, increasing powerful resolution and determination ability of analyzers. Maximum Residue Limits (MRLs) are set by risk assessment bodies based on scientific reviews on residue data of field trial (or monitoring) and toxicological findings of pesticides. MRLs differ among countries for some crop/pesticide combinations, due to reasons such as: different GAP use patterns, residue data variations as of climate, geographic zone or crop species; also there are other factors such as risk analysis differentiations of: dietary data of national population, risk assessment model or policy, trade considerations etc. The speaker will concentrate on the introduction and comparison of crop grouping system for MRL setting used now in China and other countries/organizations, and on the representative crops for residue data evaluations. Experimental data of field trials on Leaf vegetables and Brassicas may give some examples for representative crop selection/extrapolation. Minor crop problems of herbs, mushrooms, and bean sprouts products in China will also be addressed and discussed. Page 56 Symposium 5- Food and Pharmaceutical Technologies (C103) Tuesday Oct.13 (C103) Chair :Shangtian Yang Afternoon 13:30-14:10 14:10-14:40 14:40-15:10 Title S5-K1 S5- I1 S5- I2 15:10-15:20 Affiliation The role of particle engineering in Bristol Myers designing pharmaceutical particles and San Kiang Squibb pharmaceutical composite material (E0179) The Secondary Drying and the Fate of Organic Solvents for Spray Dried Dispersion Drug Product (E0215) Daniel Hsieh Selective DDRs Inhibitors as Novel Therapeutic Agents for Human Cancers and Ke Ding Pulmonary Fibrosis (E0105) Bristol-Myers Squibb Company Guangzhou Institute of Biomedicine and Health, CAS Coffee break Mycosynthetic generation of new bioactive Renxiang molecules (E0100) Tan 15:20-16:00 S5-K2 16:00-16:30 S5-I3 A material sparing predictive approach employing dry coating for enabling continuous tablet manufacturing (E0182) S5-I4 Interrogation of Streptomyces avermitilis for efficient production of avermectins (E0099) 16:30-17:00 Name Rajesh Dave Lixin Zhang Nanjing University New Jersey Institute of Technology Institute of Microbiology , CAS Wednesday Oct.14 (C103) Chair : Daniel Hsieh Morning 8:30-9:10 9:10-9:40 Title S5-K3 S5- I5 Name Development of rapid detection technology Zhixian and equipment for drinking water and food Gao safety (E0564) Affiliation Tianjin Institute of Health and Environment Medicine Anthocyanins can exert preventive effect China against the diverse acrylamide toxicity Fang Chen Agricultural (E0115) University Page 57 Symposium 5- Food and Pharmaceutical Technologies (C103) 9:40-10:10 S5-I6 10:10-10:20 Low-cost Microfluidic Devices for Food Peng Zuo Safety Detection (E0111) ECUST Coffee break S5-K4 Biointellipro Food safety and agriculture challenges and Y. Martin LLC University call for actions (E0139) Lo of Maryland 11:00-11:30 S5-I7 Research and application of aroma blending Zuobing and control release (E0137) Xiao 11:30-12:00 S5-I8 10:20-11:00 Discovery of Cycloxaprid as cisNeonicotinoids (E0148) Shanghai Institute of Technology Zhong Li ECUST Title Name Affiliation S5-K5 Four stage anaerobic technology (E0112) Daijie Chen Shanghai Institute of Pharmaceutical Industry 14:10-14:40 S5-I9 Design of a pH responsive “Smart” biopolymer-blend hydrogel for encapsulation and controlled release of anthocyanins (E0321) 14:40-15:10 S5-I10 Imidazolium-based ionic liquids: Novel reaction media for the chemical synthesis of peptides (E0324) 12:00-13:30 Lunch (Youyi Restaurant) Chair :Yingjin Yuan Afternoon 13:30-14:10 15:10-15:20 Ming Chen University of Bonn Jing Wu Jiangnan University Coffee break 15:20-16:00 S5-K6 16:00-16:30 S5-I11 Page 58 Gonul The Ohio State Kaletunc University Study on the Preparation of Cyclodextrin (E0096) Technology trends in process development WuXi AppTec and manufacturing in biopharmaceutical Yuan Wen Biopharmaceuti industry (E0162) cals Symposium 5- Food and Pharmaceutical Technologies (C103) Thursday Oct.15 (C103) Chair :Bang-Ce Ye Morning 8:30-9:10 9:10-9:40 9:40-10:10 Title Name Affiliation S5-K7 Out-of-the-box Solutions: Making Y-H Synthetic Starch and Zero-Calorie Percival Sweetener from Nonfood Biomass (E0138) Zhang Virginia Tech S5-I12 Intelligent Microbial Heat Regulating Engine for Improving the Thermotolerance and Efficiency of Biotransformation (E0097) Chun Li Beijing Institute of Technology S5-I13 Anti-solvent Crystallization of Erythromycin Ethylsuccinate in the Presence of a Liquid-Liquid Phase Separation (E0297) Xiang Li Tianjin University Chang sheng Zhang South China Sea Institute of Oceanology 10:10-10:20 Coffee break 10:20-11:00 S5-K8 Biosynthesis and Metabolic Engineering of Pharmaceutically Relevant Polycyclic Natural Products from Marine-derived Actinomycetes (E0098) 11:00-11:30 S5-I14 Tailor-designed biocatalyst towards bioproducts Dongzhi Wei ECUST S5-I15 Rational Engineering of Bacteria and Yeast for Overproduction of Isoprenoids (E0101) Kang Zhou National University of Singapore Name Affiliation 11:30-12:00 12:00-13:30 Lunch (Youyi Restaurant) Chair :Chun Li Afternoon Title 13:30-14:10 S5-K9 Progress on Pesticide Residue Analytical Methodology and International Risk Management (E0147) 14:10-14:50 S5-K10 Research progress in the development and Xichang quallity evaluation of freshwater fish Wang emulsions College of Canping Science, China Pan Agricultural University Shanghai Ocean University Page 59 Symposium 5- Food and Pharmaceutical Technologies (C103) 15:00-15:30 15:30-16:00 16:00-16:30 S5-I16 3D fluorescent cell-based high-throughput Shangtian The Ohio State screening (HTS) for cytotoxicity assay and Yang University drug discovery (E0356) S5-I17 Qingdao Institute of Bioenergy and Zhijie Sun Bioprocess Technology, CAS S5-I18 Synergistic benefits of Chinese luzhouflavor-liquor solid state ferme- ntation process (CLSSF) on hydrothermal pretreatment of rice husks (E0358) DNA-stabilized nanozyme and its application on colorimetric assay (E0603) Note: S ~ Symposium K~ Keynote I~ Invited talk Page 60 Wei Li Tianjin University Symposium 6- Green Technology (M1004, Yifu Building) Symposium 6- Green Technology Chairs: Xuhong Guo, [email protected]; Biaohua Chen, [email protected] Winston Ho, [email protected]; Giulio C. Sarti, [email protected]. Featured Speakers Yushan Yan Wednesday Oct.14, 8:30-9:10 AM M1004, Yifu Building Yushan Yan is the Distinguished Engineering Professor in the Department of Chemical and Biomolecular Engineering and the Associate Dean for Research and Entrepreneurship for the College of Engineering at the University of Delaware. He received his B.S. in Chemical Physics from the University of Science and Technology of China in 1988, and Ph.D. in Chemical Engineering from the California Institute of Technology in 1997. He studied heterogeneous catalysis at the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences from 1988 to 1992. He worked for AlliedSignal Inc. as Senior Staff Engineer and Project Leader for two years (1996-1998) before beginning his academic career at the University of California Riverside. Toward a distributed renewable electrochemmical energy and mobility system: Polymer electrolytes and electrocatalysis One of the grand challenges facing humanity today is the development of an alternative energy system that is safe, clean, and sustainable and where combustion of fossil fuels no longer dominates. A distributed renewable electrochemical energy and mobility system (DREEMS) could meet this challenge. At the foundation of this new energy system are a number of electrochemical devices including fuel cells, electrolyzers, and flow batteries. For all these devices polymer electrolytes and electrocatalysis play a critical role in controlling their performance and cost, and thus their commercial viability. In this presentation, I will focus on our recent work on hydroxide exchange membrane fuel cells which can work with non-precious metal catalysts and inexpensive polymer electrolytes, and thus can be economically viable. More specifically I will show how we have discovered a super-stable organic cation, why hydrogen oxidation reactions are slower in base than in acid, and what we have developed as the most active nonprecious metal hydrogen oxidation reaction catalysts. Page 61 Symposium 6- Green Technology (M1004, Yifu Building) Benjamin Chu Wednesday Oct.14, 13:30-14:10 PM M1004, Yifu Building Benjamin Chu is a Distinguished Professor at the State University of New York in Stony Brook, New York; his research interests are in Physical Chemistry, Polymer Physics and Materials Science & Engineering.. He is one of the founders of Liquidity Corporation in California and is an Honorary Member of the Society of Polymer Science, Japan. Application of Green Technology to Fibrous Separation Membranes for Water Purification The ultra-thin cellulose nanofibers have been isolated by using a variety of methods. Among them, the combined TEMPO oxidation/mechanical treatment has been a very successful way to fabricate nanofibers with cross-sections of a few nanometers and a high degree of crystallinity. Non-woven nanofibrous scaffolds have unique properties, including interconnected pores, a very large surface-to-volume ratio, and a high capacity for surface modifications. The hierarchical fibrous structure with fibers of different crosssections, together with the use of directed water channels in the barrier layer and surface functionalization, permits us to fabricate high throughput separation media. In this presentation, we discuss the fabrication and characterization of those nanofibers and their applications to micro-, ultra-, and nano-filtration. Kamalesh Sirkar Thursday Oct.15, 8:30-9:10 AM M1004, Yifu Building amalesh K. Sirkar, PhD, is a Distinguished Professor of Chemical Engineering K and the Foundation Professor in Membrane Separations at New Jersey Institute of Technology (NJIT). He is an internationally renowned expert in membrane separation technologies. He is the inventor of the commercialized membranebased solvent extraction technology for which Hoechst Celanese received Honorable Mention in the 1991 Kirkpatrick Award. He has pioneered among others the notion of microporous membranes as membrane contactors of two immiscible fluid phases as well as the contained liquid membrane. Sirkar was a professor of Chemical Engineering at IIT, Kanpur as well as at Stevens Institute of Technology. Polyamidoamine-facilitated Poly (ethylene glycol)/Ionic Liquid based Pressure Swing Membrane Absorption Process for CO2 Removal from Shifted Syngas A novel cyclic 5-valve pressure swing membrane absorption (PSMAB) process is being developed for CO2 removal from lower-temperature shifted syngas at ~ 100oC in hollow-fiber membrane contactors using ionic liquid (IL) absorbent, 1-butyl-3-methyl-imidazolium dicyanamide ([bmim][DCA]). Separation performance is considerably enhanced by adding nonvolatile polyamidoamine (PAMAM) dendrimer Generation 0 to the IL at higher temperatures for a 40% CO2, 60% He (surrogate for H2) feed. Absorption performance in the cyclic process depends on selective sorption and other absorbent properties especially viscosity and hollow-fiber membrane contactor module design employing microporous hydrophobized polyether ether ketone (PEEK) hollow fiber-based membranes. Equilibrium CO2 solubility and CO2-He selectivity for IL, [bmim][DCA], has been compared with those for poly(ethylene glycol) (PEG) 400 which yields improved equilibrium CO2-He selectivity and CO2 absorption with/without 20 wt% PAMAM dendrimer over the temperature range 50-100oC. The PSMAB process separation performance has been explored using PEG 400-based absorbent in two hollow-fiber membrane contactor modules with improved designs in series at temperatures up to 100oC and feed-gas pressures up to 1724 kPag (250 psig). Page 62 Symposium 6- Green Technology (M1004, Yifu Building) Zhigang Lei Thursday Oct.15, 9:50-10:30 AM M1004, Yifu Building Lei Zhigang is now a Professor in State Key Laboratory of Chemical Resource Engineering (BUCT, China). His current research interests include process intensification in chemical engineering and its molecular thermodynamics. He has contributed to more than 40 papers (indexed by SCI) as the first author or corresponding author in international journals such as Chemical Reviews, AIChE J., and Chemical Engineering Science. He has received one National Science and Technology Progress Award (second rank), two ministry-level Science and Technology Progress Awards and one ministry-level Natural Science Award (first rank). Structured Catalysts and Reactors: A Green Chemical Technology Structured catalysts and reactors have been becoming significant green chemical technologies in gassolid and gas-liquid-solid reactions due to the unique advantages they offer such as controlling hydrodynamics, transport phenomena and reaction kinetics, so that energy efficiency would be improved and generation of hazardous substances would be reduced or eliminated. In this work, for gas-solid reaction with structured catalysts, we focus on selective catalytic reduction (SCR) for NO (nitrogen oxide) removal, and try to identify the relationship between the internals of SCR system and mixing performance for controlling ammonia (NH3) slip (<5 ppm). On the other hand, for gas-liquid-solid reaction with structured catalysts, the transfer and reaction performances for the alkylation of benzene with propylene to produce cumene over monolith catalysts as well as structured catalytic packings were investigated by means of the combination of experiments and computational fluid dynamics (CFDs) . Sumith Wickramasinghe Thursday Oct.15, 13:30-14:10 PM M1004, Yifu Building Wickramasinghe joined the Department of Chemical Engineering at the University of Arkansas in 2011 where he holds the Ross E Martin Chair in Emerging Technologies and leads the Membrane, Science, Engineering and Technology Center (MAST). Prof Wickramasinghe has published over 100 peer reviewed journal articles, several book chapters and is co-editor of a book on responsive membrane and materials. He is active in AIChE and was the Meeting Program Chair of the 2014 Annual Meeting in San Francisco. He has also served on the Board of Directors of the North American Membrane Society. Catalytic Membranes for Production of Biofuels and Chemicals Catalytically active membranes may be used to catalyze a reaction and separate the product in one step leading to significant process intensification. Here we focus on biomass hydrolysis and dehydration for production of biofuels and chemical intermediates. Ceramic membranes have been functionalized by growing poly(styrene sulfonic acid) (PSSA) chains as well as polymeric ionic liquid (PIL) chains from the surface of ceramic membranes. A UV initiator based on a benzoin ether derivative and 2-bromobutyryl bromide (ATRP initiator) were immobilized on the ceramic membrane surface. Next ATRP of sodium 4styrenesulfonate was conducted followed by UV initiated free radical polymerization of 1-vinylimidazole(VI). The density of the PSSA and PIL chains was varied by varying the incubation times of the two different initiators. Modified membranes were characterized using X-ray Photoelectron Spectroscopy, Infrared Spectroscopy and Scanning Electron Microscopy.A membrane reactor was designed and tested using feed streams consisting of cellulose and hemicellulose and glucose in water and water/ionic liquid, acetonitrile/ionic liquid, dimethylacetamide/ionic liquid, -valerolactrone/ionic liquid mixtures. Reduced sugars as well as chemical intermediates such as hydroxymethylfurfural, furfural and levulinic acid were collected in the permeate. We have tuned the membrane pore structure in order to maximize recovery of the desired products in the permeate. Our results indicate the feasibility of designing a catalytic membrane reactor for production of biofuels and chemicals. Page 63 Symposium 6- Green Technology (M1004, Yifu Building) Weihong Zhu Thursday Oct.15, 14:50-15:30 PM M1004, Yifu Building Prof. Weihong Zhu is a professor of East China University of Science & Technology (ECUST), and a deputy director in 2006. He has published over 150 SCI papers in international journals. He has received several awards, such as Oriental Scholar (2009) and NSFC for Distinguished Young Scholars (2013). His current research interests are focused on functional chromophores, including fluorescent sensors, photochromism, and metal free solar cell sensitizers. Insight into D−A−π−A featured sensitizers: a reliable route to highly efficient and stable dye-sensitized solar cells The practical application of DSSCs requires further improvements in the power conversion efficiency and long term stability. Recently, we have systematically studied a novel concept of D−A−π−A model for the molecular engineering of organic photosensitizers. We highlights recent advance in the D−A−π−A based photosensitizers, specifically focusing on the mechanism of efficiency and stability enhancements. Also we take insight into the additional acceptor as well as the trade-off of long wavelength response. The basic principles are involved in the molecular engineering of efficient D−A−π−A sensitizers, providing a clear road map how to rationally extend the response wavelength, enhance molecular extinction coefficients, and step by step optimize photovoltaic efficiency. Page 64 Symposium 6- Green Technology (M1004, Yifu Building) Tuesday Oct.13 (M1004, Yifu Building) Chair : Winston S. Ho Afternoon 13:3014:10 S6Keynote 1 S6- 14:1014:40 Invited talk 1 14:4015:10 S6- I2 Title Name Affiliation Can we predict gas solubility and permeability in glassy polymeric membranes? (F0033) Giulio Sarti University of Bologna Advances in Developing Iptycenecontaining Polymer Membranes for Gas Separation (F0227) Ruilan Guo University of Notre Dame Olefin/Paraffin Separations by Membranes: An Industrial Perspective (F0326) 15:1015:20 15:2016:00 16:0016:30 Xiaotong (Tony) Wei SABIC Coffee break S6-K2 Design and synthesis of synergic multimetallic nanocatalysts towards highly active and stable catalysts for oxidation and hydrogenation reactions (C0455) S6-I3 Recent Development of Thin-sheet Molecular Sieve Membranes for Air Dehumification and Conditioning (F0510) Binghui Chen Wei Liu Xiamen University Pacific Northwest National Lab Wednesday Oct.14 (M1004, Yifu Building) Chair : Xuhong Guo, Giulio C. Sarti Morning Title 8:30-9:10 S6-K3 9:10-9:40 S6-I4 9:40-10:10 10:1010:20 S6-I5 Toward a distributed renewable electrochemmical energy and mobility system: Polymer electrolytes and electrocatalysis (F0153) Designing polymer-matrix nanocomposite membranes for specific applications in water treatment and reuse (F0236) Recovery and separation of Europium and Yttrium ions by using supported liquid membrane with strip dispersion (F0354) Coffee break Name Affiliation Yushan Yan University of Delaware Newark Baolin Deng University of Missouri Da-Ming Wang National Taiwan University Page 65 Symposium 6- Green Technology (M1004, Yifu Building) Wednesday Oct.14 (M1004, Yifu Building) Chair : Xuhong Guo, Giulio C. Sarti Morning Title 10:20- S6- 11:00 K4 11:0011:30 S6-I6 Name Affiliation Effective removal of nitrogen-containing waste gases from chemical industry by the zeolite catalysts Runduo Zhang Beijing University of Chemical Technology Graphene Oxide Membranes for Fouling Control in Pressure Retarded Osmosis (F0241) Baoxia Mi University of California 11:30- Lunch (Youyi Restaurant) 13:30 Chair : Biaohua Chen, Wei Liu Title Name Affiliation S6K5 Application of Green Technology to Fibrous Separation Membranes for Water Purification (F0035) Benjamin Chu Stony Brook University S6-I7 Impregnated Membranes for Water Purification by Forward Osmosis (F0228) Haiqing Lin SUNY at Buffalo Afternoon 13:3014:10 14:1014:40 14:40- Coffee break 14:50 14:5015:30 15:3016:00 Page 66 S6K6 The oxidative removal of typical volatile organic compounds over porous catalysts Hongxing Dai Beijing University of Technology S6-I8 Controlled assembly of polymers in water: towards soft nanoparticles for potential applications in biology and environment Junyou Wang Wageningen University Symposium 6- Green Technology (M1004, Yifu Building) Thursday Oct.15 (M1004, Yifu Building) Chair : Haiqing Lin Morning Title 8:30-9:10 S6-K7 9:10-9:40 S6-I9 Polyamidoamine-facilitated Poly (ethylene glycol)/Ionic Liquid based Pressure Swing Kamalesh Membrane Absorption Process for CO2 Sirkar Removal from Shifted Syngas (F0295) Robust CO2 separation membrane composed of double network gel Hideto containing amino acid ionic liquid Matsuyama (A0333) 9:40-9:50 9:50- 11:00 Affiliation New Jersey Institute of Technology Kobe University Coffee break S6-K8 10:30 10:30- Name S6-I10 Structured Catalysts and Reactors: A Green Chemical Technology (F0498) Zhigang Lei Bimodal Comb Block Polyolefins by Serial Reactors Andy Tsou (C0102) 11:00- Beijing University of Chemical Technology ExxonMobil Chemical Company Lunch (Youyi Restaurant) 13:30 Chair : Xiaotong (Tony) Wei Afternoon Title Name Affiliation 13:30S6-K9 Catalytic Membranes for Production of Biofuels and Chemicals (F0252) Sumith Wickramasinghe University of Arkansas S6-I11 Osmotic Membrane Bioreactors for Water Reclamation and Energy Recovery Chuyang Y. Tang The University of Hong Kong Insight into D−A−π−A featured sensitizers: a reliable route to highly efficient and S6-K10 stable dye-sensitized solar cells Weihong Zhu ECUST Graphene oxide composite membranes for pervaporation Wei Song Hung Chung Yuan University 14:10 14:1014:40 14:40- Coffee break 14:50 14:5015:30 15:3016:00 S6-I12 Note: S ~ Symposium K~ Keynote I~ Invited talk Page 67 Symposium 7- Management Science for Research and Development (M806, Yifu Building) Symposium 7- Management Science for Research and Development --------How to make R&D effective and efficient Chairs: Jane Li, [email protected]; Zaiku Xie, [email protected]; Tieju Ma, [email protected] Featured Speakers Willibrord A. Groten Wednesday Oct.14, 13:30-14:30 PM M806, Yifu Building Dr. Will Groten is currently Vice President of Research & Development for CB&I, the world’s most complete energy infrastructure company. Additionally, he holds titles of Managing Director of CDTech and President of Chemical Research & Licensing LLC, now wholly owned subsidiaries of the Technology group of CB&I since 2011. In his current capacity he oversees R&D, technology evaluations, intellectual property and the fabrication of proprietary CDTech products, for CB&I. In prior roles, Dr. Groten held numerous R&D roles leading to the development of new process technologies for CDTech including that of Director of Technology. He also served for several years with Criterion Catalysts & Technologies, L.P as VP Process Technology & Projects for Criterion, overseeing their clean fuels technology programs. Dr. Groten earned a Bachelor of Science & Engineering in Fuels and Materials Engineering at the Royal Military College of Canada in 1982 and served in the Canadian Armed Forces as an officer and Search & Rescue pilot. He retired from military service with the rank of Captain in 1987 and went on to earn his PhD from Queen’s University, Kingston, Ontario in the field of catalysis and reaction engineering. He is author or co-author on a dozen papers and named inventor on two dozen patents. Over the course of his engineering career, he has been involved in the successful development and launch of more than 20 new, innovative process technologies into the refining and petrochemical industry. Innovation and culture in the engineering firm It is fitting that the subject of this symposium be now included in the Sino-US Chemical Engineering Conference. Innovation, although an often overused buzz word, is central to economic growth and wellbeing of society in general. For businesses, it is an essential ingredient in a sustainable business model. The fundamental driver of the process of innovation is, of course, the associated human factor. Thus, managing the process of innovation in the field of Chemical Engineering will necessarily require both “art” and “science”. The innovation process does not occur in a void but rather occurs in a particular context. Broadly speaking, this can include the internal organization of a company, its culture, and the external world environment, which typically includes a marketplace populated by competitors all aimed to deliver their innovative technology solutions to solve and address a customer’s problems and needs. Using CB&I’s history of innovation in the chemical process industry, a generic framework of the innovation process will be presented, capturing specific experiences, and address a few of the unique challenges found along the way. This presentation is meant to be thought provoking and set the stage for a successful first R&D Management Science Symposium. Page 68 Page 1 Symposium 7- Management Science for Research and Development (M806, Yifu Building) Medhat Tannous Wednesday Oct.14, 8:30-9:15 AM M806, Yifu Building Dr. Medhat Tannous is currently Sr. Director for Regional R&D. He is responsible for strategic development and direction of UOP regional R&D programs, including: providing technology support to the UOP regional General Managers and developing strategic and operational plans for regional R&D customer engagements. He also provides oversight to regional labs in India and Saudi Arabia. Prior to that, Medhat was R&D Director for the Middle East where he established collaborative development projects and activities with key customers and Universities in the area. Medhat joined UOP in 1985. In the past 30 years, he held different technical and managerial positions in R&D, Manufacturing Technology and Catalyst business. Medhat has a Ph.D. in Chemical Engineering and an MBA. He is also a Honeywell certified Six Sigma Master Black Belt and Six Sigma Lean expert. Medhat is the author of 4 patents and several publications. Enhancing the effectiveness of R&D The goal of every R&D department is to develop new technologies to support business growth. For over one hundred years, UOP has been providing the oil, gas and petrochemicals industries with groundbreaking technical innovations resulting from its pioneering research work in catalysis, separations and process design. The key factors for a successful R&D operation are acquiring and retaining talents, providing researchers with the tools and capabilities that are necessary to perform cutting edge science, and aligning research programs with business objectives that are based on customer needs, market trends, regulations and competitive analysis. Needless to mention that having the best talents, resources and capabilities alone will not enhance the effectiveness of R&D unless disciplined, integrated and cross functional work processes are strictly deployed. Among such work processes are strategic planning, technology road mapping, voice of the customer, portfolio management, open innovation and technology delivery process. Such work processes, enabled with the six sigma methodology and tools are key to an efficient and effective R&D operation designed to enhance the growth of the business and maximize the return on R&D investment. Examples of such work processes and tools will also be described. Page 69 Page 1 Symposium 7- Management Science for Research and Development (M806, Yifu Building) Special lecture Wednesday Oct.14, 11:00-12:00 AM M806, Yifu Building Sergei Ikovenko, Dr.-Eng., Ph.D., P.E., Dr. Sergei Ikovenko is one of leading consultants in innovation technology of design. He is the President of the International TRIZ Association and is an adjunct professor at Massachusetts Institute of Technology (Cambridge, USA). He has conducted more than 900 courses on innovation and TRIZ (Theory for Inventive Problem Solving) topics for Fortune 500 companies worldwide. Dr. Ikovenko was the primary instructor on TRIZ at Procter & Gamble,Mitsubishi Research Institute, Samsung, Intel, Siemens, General Electric Global Research, Hyundai Motor Company, and other companies. Dr.Ikovenko holds two doctorate degrees –in Industrial Engineering and in Environmental Engineering and Sciences, and a Master degree in Patent Law. He is the author of more than 100 publications, and 104 patents in various engineering fields. Innovative Technology of Design – TRIZ Sergei Ikovenko International TRIZ Association and Massachusetts Institute of Technology, Cambridge, MA, USA, 02139 [email protected] TRIZ (a Russian acronym for Theory for Inventive Problem Solving) is a powerful suite of tools and methodologies for improving existing products (such as by reducing cost, improving functionality, or both) and for developing new generation products. In the conventional wisdom, innovation is an inefficient and ineffective process. Limited resources, psychological inertia, limited breadth of technical knowledge, information overload, tendency to compromise, inability to objectively forecast the technological future and, finally, choosing the wrong problem to solve have all been cited as reasons that prevent innovation. Because of these so called "innovation killers", most innovations are incremental at best and are aimed at improving already existing products. TRIZ bypasses typical innovation killers by using: Analytical tools that identify the right problems Objective and statistically proven Trends of Evolution for Engineering Systems Problem-solving tools that solve engineering problems without compromise, often leading to breakthrough solutions The power of TRIZ lies in its ability to make innovation a predictable, and, therefore, risk-averse process by applying a scientific and methodological framework to solving engineering problems. Importantly, TRIZ is not a substitute for intelligence. Rather, it can be viewed as a multiplication constant to intelligence that serves as a stimulator, an optimizer, and a filter to make the innovation process significantly more productive, efficient, and effective. Page 70 Symposium 7- Management Science for Research and Development (M806, Yifu Building) Wednesday Oct.14 (M806, Yifu Building) Chair : Jane Li Morning Title 08:30- S7-K1 09:30 09:30S7- I1 10:10 Name Affiliation Enhancing the Effectiveness of Medhat R&D TANNOUS Honeywell/U Accelerating Innovation with integrated Six sigma implementation Selena CHU Asia Pacific R&D, Dow Chemical Yongwei SUN National Institute of low carbon and Clean Energy OP Coffee break 10:00-10:20 Chair : Jane Li 10:20-11:00 S7- I2 S711:00-12:00 Special Accelerating Innovation for Chemical Engineering R&D projects by Design for Six Sigma Innovative Technology of Design – Seigei TRIZ IKOVENKO Lecture 12:00-13:30 International TRIZ Association and Massachusetts Institute of Technology Lunch (Youyi Restaurant) Chair : Zaiku Xie Afternoon 13:3014:30 14:3015:10 15:10-15:20 S7-K2 S7-I3 Title Name Affiliation The Science (and Art) of Innovation at CB&I Willibrord GROTEN CB&I Some thoughts for improving the efficiency of an industrial research Xiangchen institute and their application FANG results Fushun Research Institute of Petroleum and Petrochemica ls, SINOPEC Coffee break Page 71 Symposium 7- Management Science for Research and Development (M806, Yifu Building) Chair : Tieju Ma 15:20-16:00 S7-I4 Mission and exploration of Research Center of Meso-science (COM) in R&D of process engineering Ning YANG Institute of Process Engineering, CAS Yi JIANG Corning, NY Best Practice in Implementing Safety Measures in Fine & 16:00-16:40 S7-I5 Specialty Chemical Manufacturing 16:40-17:20 S7-I6 R & D program strategy and Bing decision ZHANG Note: S ~ Symposium K~ Keynote I~ Invited talk. GE China Technology Center Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Symposium 8- Materials and Nano Technology Symposium 8- Materials and Nano Technology Chairs: Chunzhong Li, [email protected]; Jieshan Qiu, [email protected] James Lee, [email protected]; Liming Dai, [email protected] Featured Speakers Dongyuan Zhao Wednesday Oct.14, 8:30-9:10 AM C208, Yifu Building Dr. Dongyuan Zhao was born in Northeastern of China, he received B.S. (1984), M.S. (1987) and PhD (1990) from Jilin University. He was a post-doctoral fellow in the Weizmann Institute of Science (1993– 94), University of Houston (1995–96), University of California at Santa Barbara (1996–98). Now he is a Professor (Cheung Kong and HaoQing Professorship) in the Department of Chemistry at Fudan University, Currently, he is a fragmental professor in Department of Chemical Engineering, Monash University. He was a member of Chinese Academy of Sciences and The World Academy of Science (TWAS), Council Member of IZA, President of International Mesostructured Materials Association (IMMA). He has received many prizes from China and international awards such as CRN Rao Award from India Chemical Research Society (2013); Muetterties Memory Award (2012); The Ho Leung Ho Lee Award (2009), TWAS Prize (2008); IMMS Award (2008); DuPond Award (2005). He is now appointed as senior Editor of ACS Central Science. He was Editor-inChief of Journal of Materials Chemistry, and co-editor of Journal of Colloid and Interface Science before. He published more than 550 peer-review papers, 40 patents and is listed as one of highly cited researchers in ISI (Total citation ~ 50,000, h index 105). His research interests mainly include designed synthesis, assembly, structure and application of ordered mesoporous materials. http://www.mesogroup.fudan.edu.cn Interfacial Assembly and Engineering of Ordered Functional Mesoporous Materials for Applications With recent progresses made in modern nanoscience and nanotechnology, ordered mesoporous materials have been one of the hottest research topics in scientific community spanned chemistry, materials science, physics and biology. The construction of mesoporous materials is mainly concerned with building monodispersed mesosized (2-50 nm) pore voids and arranging them in a long-range ordered array. Generally, two kinds of templates are used to produce the mesopores: supramolecular aggregates such as surfactant micelle arrays, and rigid preformed solids such as ordered mesoporous silica, carbon, and colloidal crystals. Noticeably, besides the templates, the interface also plays a central role in the synthetic process, because it provides a rich and crucial space for the assembly and construction of mesostructures. Generally, two kinds of interfaces involve in the synthetic system. The first one is at between surfactant templates and guest species, which has been extensively investigated. Another important interface is the two-phase (solid, liquid and gas) one, including liquid-solid, gasliquid, liquid-liquid, gas-solid, and solid-solid interface, which has been well developed for the synthesis of ordered mesoporous materials. Compared with the one phase synthesis referring to homogeneous nucleation and growth, the introduction of a two-phase interface in the system can change the growth behaviors of mesoporous materials and lead to the formation of molding or multifunctional mesoporous materials. Page 72 Page 1 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Zhonglin Wang Tuesday Oct.13, 13:30-14:10 PM C208, Yifu Building Dr. Zhong Lin (ZL) Wang is the Hightower Chair in Materials Science and Engineering, Regents'Professor, College of Engineering Distinguished Professor and Director, Center for Nanostructure Characterization, at Georgia Tech. Dr. Wang has made original and innovative contributions to the synthesis, discovery, characterization and understanding of fundamental physical properties of oxide nanobelts and nanowires, as well as applications of nanowires in energy sciences, electronics,optoelectronics and biological science. He invented and pioneered the in-situ technique for measuring the mechanical and electrical properties of a single nanotube/nanowire inside a transmission electron microscope. Dr. Wang is a pioneer and world leader in nanoscience and nanotechnology for his outstanding creativity and productivity. Dr. Wang was elected as a foreign member of the Chinese Academy of Sciences in 2009, member of European Academy of Sciences in 2002, fellow of American Physical Society in 2005, fellow of AAAS in 2006, fellow of Materials Research Society in 2008, fellow of Microscopy Society of America in 2010. He is an honorable professor of over 10 universities in China and Europe. He received 1999 Burton Medal from Microscopy Society of America, 2001 S.T. Li prize for Outstanding Contribution in Nanoscience and Nanotechnology, the 2000 and 2005 Georgia Tech Outstanding Faculty Research Author Awards, Sigma Xi 2005 sustain research awards, Sigma Xi 1998 and 2002 best paper awards, and the 2009 Purdy Award from American Ceramic Society. His breakthrough researches in the last 15 years have been featured by over 50 media world wide including CNN, BBC, FOX News, New York Times, Washington Post, NPR radio, Time Magazine, National Geography Magazine, Discovery Magazine, New Scientists, and Scientific America. Nanogenerators for self-powered systems and piezotronics for smart devices Developing wireless nanodevices and nanosystems is of critical importance for sensing, medical science, environmental/infrastructure monitoring, defense technology and even personal electronics. It is highly desirable for wireless devices to be self-powered without using battery. Nanogenerators (NGs) have been developed based on piezoelectric, trioboelectric and pyroelectric effects, aiming at building self-sufficient power sources for mico/nano-systems. The output of the nanogenerators now is high enough to drive a wireless sensor system and charge a battery for a cell phone, and they are becoming a vital technology for sustainable, independent and maintenance free operation of micro/nano-systems and mobile/portable electronics. An energy conversion efficiency of 55% and an output power density of 500 W/m2 have been demonstrated. This technology is now not only capable of driving portable electronics, but also has the potential for harvesting wind and ocean wave energy for large-scale power application. This talk will focus on the updated progress in NGs. Page 73 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Stuart Cooper Wednesday Oct.14, 9:40-10:10 AM C208, Yifu Building Stuart Cooper currently is a professor of department of chemical and biomolecular engineering from Ohio State University, he earned his PhD degree at Princeton University (1967). Prof. Stuart Cooper won AIChE Founders Award for Outstanding Contributions to the Field of Chemical Engineering (2014) and Chemistry of Thermoplastic Elastomers Award from American Chemical Society‘s Rubber Division (2013),and National Academy of Engineering (2011). His main research interests focus on polymer science and engineering, properties of polyurethanes and Ionomers, polyurethane biomaterials, blood-material interactions and tissue engineering. Polyurethanes and Ionomers: High Performance Elastomers and Plastics Self Reinforced with Nanoscale Structure Elastomeric (AB)n-type segmented copolymers are systems which exhibit properties similar to crosslinked rubbers, but are thermoplastic and may therefore be processed by conventional molding and extrusion techniques. At use temperature, one component is viscous or rubbery (soft segment), while the second block is glassy or semi-crystalline in nature (hard segment). Typically, polyurethane segmented elastomers exhibit phase separation on the scale of nanometers with the hard segment domains acting as physical crosslinks and/or filler particles for the flexible soft segment matrix. Ionomers are copolymers where a low concentration ionic monomer is polymerized within a hydrophobic backbone. In the solid state the ionic species aggregate into nanoscale reinforcing domains which impart unique physical properties to these materials Changsheng Liu Tuesday Oct.13, 15:20-16:00 PM C208, Yifu Building Dr. Changsheng Liu is currently vice president of East China University of Science and Technology and a director of Engineering Research Center of Biomedical Materials under Ministry of Education. Dr Liu has devoted for decades into the fundamental and application research of biological materials and has obtained a series of outstanding achievements in the field of bone regeneration. He won an international Fellow of Biomaterials Science and Engineering (2012). Dr Liu has a Ph.D. in Chemical Engineering in East China University of Science and Technology in 1996. He has visited University of Pennsylvania, Philadelphia, USA as a visiting professor from March to Sept, 2005. He has successfully applied 50 invention patents (including 2 international PCT Patent and 3 USA Patent) and published more than 170 SCI articles. He won the Second-prize of National Award for Natural Science (China) in 2014 (the first rank) and the Second-prize of National Award for Science and Technology Progress (China) in 2003 (the first rank), the Firstprize of Award for Natural Science (Shanghai) in 2013 (the first rank). . Bioinspired 2D/3D architecture-mediated cell response and tissue regeneration Critical size bone defects raise great demands for efficient bone substitutes. Development of advanced bone substitutes with excellent osteogenic capability that can support damaged tissue, induce osteogenic differentiation and re-establish original geometry and function of the impaired tissue is highly desired. Insitu guided tissue regeneration based on the functional materials and growth factor represents a new strategy and is being rapidly developed nowadays. For this promising strategy, the key is to explore 2D/3Dmediated cell response and tissue formation. Here, we show some interesting results about the 2D interface/surface-induced protein adsorption and cell response, and 3D hierarchical architecture and bone regeneration. Combining experiment and molecular dynamic simulations, we found that the 2D nanostructured HAPs could modulate the way of adsorption of rhBMP-2, and thus the recognition of BMPRIA and the bioactivity of rhBMP-2. Compared with 2D CPC surface, 5MCPC could strongly enhance the attachment, morphology, focal adhesion formation, actin filaments assembly and osteogenic differentiation of BMSCs. With 3D Macro-micro-meso bioactive glass and PHBHHx/SMC scaffolds, we investigated the effects of the surface morphology, porous structure, etc on the cell response, mass transfer and bone regeneration in details. The results obtained in this study might provide new thoughts on the design and development of future orthopedic biomaterials. Page 74 Page 1 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Liming Dai Wednesday Oct.14, 13:30-14:10 PM C208, Yifu Building Liming Dai is currently a professor of CWRU in the Department of Macromolecular Science and Engineering. He is also director of Case4Carbon. He received a PhD from the Australian National University in 1991. He was a postdoctoral fellow at the University of Cambridge,a visiting fellow at the University of Illinois, and spent 10 years with CSIRO in Australia. He was a professor at the University of Akron and at the University of Dayton. His research interests mainly focus on the synthesis, chemical modification, and device fabrication of conjugated polymers and carbon nanomaterials for energy and bio-related applications. Carbon-based metal-free electrocatalysts for energy conversion and storage As a building block for carbon materials of all other dimensionalities (e.g., 0D buckyball, 1D nanotube, 3D graphite) , the two-dimensional (2D) single atomic carbon sheet of graphene has emerged as an attractive candidate for energy applications due to its unique structure and properties. Recently, a new class of graphitic carbon nanomaterials has been discovered as metal-free electrocatalysts to replace commercially available noble metal (e.g., Pt, Ru) electrocatalysts for energy conversion and storage. For instance, we have demonstrated that nitrogen-doped graphene (N-graphene) could actively electrocatalyze ORR via a fourelectron process free from the CO-poisoning effect with a higher electrocatalytic activity and better longterm durability than that of commercially available Pt/C electrocatalysts. On the basis of these experimental observations and quantum mechanics calculations, we have attributed the observed ORR electrocatalytic activities of the graphene-based catalysts to the electron-accepting ability of the chemically-bonded nitrogen atoms. The N-doping induced charge-transfer could create a net positive charge (via intramolecular charge-transfer) on adjacent carbon atoms in the nanocarbon structures to effectively change the O2 adsorption mode and to readily attract electrons from the anode, facilitating the oxygen reduction reaction (ORR) on the metal-free cathode in fuel cells. Shuhong Yu Wednesday Oct.14, 15:20-16:00 PM C208, Yifu Building Prof. Shu-Hong Yu is the Cheung Kong Chair Professor of Chemistry in the Department of Chemistry at the University of Science and Technology of China (USTC), P.R. China. He serves as the Director of the Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale and the Deputy Dean of the Suzhou Advanced Study Institute, USTC. He was elected as a Fellow of the Royal Society of Chemistry in 2013 and now serves as a General Secretary and a Council member of the International Solvothermal Hydrothermal Association (ISHA) since 2010. His research interests include bio-inspired synthesis of nanostructures, self-assembly of nanoscale building blocks, nanocomposites, their related properties and applications. He has authored or co-authored 390 refereed journal publications, and 17 invited book chapters. Macroscopic Nanoparticle Assemblies: Integration, Functionalization and Applications The huge diversity of hierarchical micro-/nano- rigid structures existing in biological systems is increasingly becoming a source of inspiration of materials scientists and engineers to create next generation advanced functional materials. Recently, accompanied with the development of nanotechnology, some biologically hierarchical rigid structures have been duplicated and mimicked in artificial materials through hierarchical organization of micro-/nanosized building blocks. Although the properties of nanomaterials are frequently superior to those of their bulk counterparts, translating the unique characteristics of individual nanoscale components into macroscopic functional devices still remains a challenge. In this lecture, we discuss how to assemble nanoscale building blocks into ordered assemblies as well as their functionalities, and how to integrate them with already existing macroscopic structures and realize their functionalization. A family of nanowire or nanoplate assemblies in form of thin films or 3D integrated structures can be generated, demonstrating that it is possible to access a variety of high quality hybrid materials with tunable mechanical property and other multifunctionalities. These assembled structures show enormous application potential in diverse fields such as electronics, elastomeric conductors, electrocatalysis, and super adsorbents. Page 75 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Bogeng Li Thursday Oct.15, 8:30-9:10 AM C208, Yifu Building Dr. BoGeng Li currently is a Professor from Department of Polymer Science and Engineering, Zhejiang University. His research interests include polymer reaction engineering and synthesis of polymer materials. He has published more than 200 papers in international journals, presented more than 10 invited talks in international conferences, and holds more than 30 Chinese patents. Now he is the Chief Scientist of the “973 Program (National Basic Research Program of China)” project “Preparation and Processing of High Performance Thermal Plastic Elastomers”. He is presently Qiushi Chair Professor and Dean of Engineering of the ZJU, and Associate Editor of Ind. & Eng. Chem. Res., an ACS journal. Controlled Manufacturing of Polymers with Complex Chain Microstructure Precise control over chain microstructure in a large-scale industrial production of polymer is an exciting emerging research area and it is driven by the practical demands not only for superior physical properties and special functionalities of the polymer materials, but also for value addition to polymerization processes and raw materials. Constrained by the conventional mechanisms, the current industrial practices can only control average chain properties such as average molecular weight, average copolymer composition, tacticity, etc. Based on the CLRP and LCP mechanisms and polymerization kinetics, we have derived process models for the semi-batch CLRP and LCP copolymerization, and used the models to design computer-programmed comonomer feeding policies for production of polymers with targeted chain microstructures. Using this methodology, copolymers with various chain microstructures, including uniform, random, linear, inverse linear, gradient, hyperbolic, di-block and triblock copolymers and polymers having complex topologies such as V-shape gradient, hyper-branched, crosslinked, and multi-armed star polymers were experimentally synthesized. Weishen Yang Thursday Oct.15, 10:20-11:00 AM C208, Yifu Building Dr. Weishen Yang is Professor of the State Key Laboratory of Catalysis at Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China. He received his PhD from the Chinese Academy of Sciences in 1990. He has a background in catalysis, inorganic membranes (H2 permeable membrane, O2 permeable membrane, and zeolite membrane) and fuel cells (Solid Oxide Fuel Cell). Prof. Yang has published ~260 referred journal papers (SCI citations > 7000;H-index 43), 4 book chapters and 20 patents on material synthesis with strong emphasis on the rational design and molecular-level engineering of functional nano-materials for applications in catalysis, separation and fuel cells. Molecular sieving nanosheets of metal-organic framework as building blocks for H2/CO2 separation Separation of H2 from CO2 with membranes is an energy-efficient and environmentally friendly alternative to cryogenic and absorptive or adsorptive gas separation processes. To obtain high membrane separation performance, i.e., to fast screen molecules with high resolution, ultrathin membranes possessing regular pores with precise size is long-cherished. Molecular sieving nanosheets (MSNs) are the ideal building blocks to put this kind of membranes into reality. We prepare 1-nm-thick MSNs with large lateral area and high crystallinity from layered metal-organic framework precursor and report their use in fabricating highly selective and ultrapermeable molecular sieving membranes. Unlike previous membranes performance reported to date, we found an unusual proportional relationship between H2 permeance and H2 selectivity for the MSNs membranes, and we achieved a simultaneous increase in both permeance and selectivity by suppressing lamellar stacking of the MSNs so as to avoid pore blockage of the MSNs. Page 76 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Guangsheng Luo Thursday Oct.15, 13:30-14:10 PM C208, Yifu Building Dr. Guangsheng LUO is a professor of chemical engineering at Tsinghua University. He is currently the Director of the State Key Lab of Chemical Engineering. His research interests revolve around micro-structured chemical systems, separation science and technology, mass transfer phenomena, and controllable preparation of functional Materials. He is the co-author of more than 300 peer reviewed papers and more than 70 invention patents in China. He received his BSc. Degree in applied chemistry in 1988 and his Ph.D. in chemical engineering in 1993 at Tsinghua University. He worked at Caen University as a Postdoctoral Research fellow from 1995 to 1996, and as a visiting scientist from 2001 to 2002 at Massachusetts Institute of Technology. He is the recipient of several awards. He obtained the “National Outstanding Young Scientist Award” from the National Natural Science Foundation of China in 2005 and he was appointed as a Chungkung Professor by the Ministry of Education of China in 2009. Preparation of microcapsules and nanoparticles with microflows Microflow engineering and technology have high promising prospects for the development of controllable preparation processes for materials, because they could have safety, fast mixing, and high mass and heat transfer rate. More than ten years ago we began to develop micro-structured chemical systems for developing controllable processes for material preparation. Multiphase microflows including gas-liquid, liquid-liquid, gas-liquid-liquid, liquid-liquid-liquid, gas-liquid-solid systems have been realized. Uniform bubbles and droplets could be generated with microdevices. Controllable preparation of nanoparticle and microcapsule in microstructured chemical systems have been tested. The results show that the microstructured systems are very controllable. The particle size and the morphologies of the prepared materials can be well controlled. In this presentation, we will show some cases for the development of controllable processes for material preparation with microstructured systems. Changjun Liu Thursday Oct.15, 15:20-16:00 PM C208 Classroom, Yifu Building Dr. Chang-jun Liu is a Chang Jiang Distinguished Professor in Tianjin University and Fellow of the Royal Society of Chemistry. He is now in charge of the Program of Clean Utilization of Fossil Fuels of Tianjin Co-Innovation Center of Chemical Science and Engineering (COIC_CSE). His research interests include catalysis, energy material and plasma science. He served as the 2010 Program Chair of Fuel Chemistry Division (now Energy and Fuels Division) of the American Chemical Society and Vice Chair of Committee on Plasma Science & Technology of Chinese Society of Theoretical and Applied Mechanics. He was guest editors of ACS Symposium Series, Catalysis Today, Green Chemistry, ChemCatChem and Energy & Environmental Science. He was the Advisory Board Member of Energy & Environmental Science. Nano and nanostructured materials created by room temperature electron reduction Electron is the greenest reducing agent for the reduction of noble metal ions to prepare nanoparticles or nanostructured materials. Two methods have been developed with electron as reducing agent: electron beam irradiation and room temperature electron reduction with glow discharge or radio frequency discharge as the resource of electrons. In this presentation, we attempt to summarize the current status of electron reduction with those non-hydrogen discharges as electron resource. Future development has been addressed too. The room temperature electron reduction via discharges is excellent for size and structure control with fast nucleation and slow crystal growth. It is a simple, easy, cheap and energy efficient way to reduce metal ions. It is also excellent to load noble metal particles into channels of ordered porous materials, like SBA-15, with no need of complex chemical modification. The room temperature operation makes it very useful for the preparation of noble metal catalysts supported on thermal sensitive substrates like peptide, porous organic materials, conducting polymers, ultrahigh surface area carbon, peptides and proteins. Page 77 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Youqing Shen Tuesday Oct.13, 14:10-14:40 PM C208, Yifu Building Prof. Youqing Shen is a chair professor in department of chemical and biological engineering from Zhejiang University. Shen’s main research interests include polymer reaction engineering, biomaterials, bionano engineering and nanomedicines, gene and drug delivery. Shen has won the National Outstanding Dissertation Award (1999) and National Distinguished Young Investigator (2008). He is also a director of center for bionano engineering and a adjunct professor in Soft Materials Laboratory (SML) and Department of Chemical & Petroleum Engineering at University of Wyoming. Cancer Drug Delivery: A CAPIR Cascade and Nanocarrier Design The cancer drug delivery process is a cascade of five steps consisting of circulation in blood, accumulation and penetration into the tumor, cellular internalization and intracellular drug release, or the CAPIR cascade. Thus, the most challenging aspect of cancer nanomedicine design is the integration and synchronization of all functions required to accomplish the CAPIR cascade into one system, particularly, many of which are in opposite in different CAPIR steps. Here, we present a nanocarrier likened to a “ cluster bomb” capable of releasing small pH-sensitive drug-carrying nanoparticles (bomblets). This cluster bomb-like nanocarrier synchronizes pegylation-to depegylation, large-to-small size, and neutral-to-positive charge transitions essential for accomplishing the CAPIR cascade, enabling the carried drug to reach cells deep in the tumor, significantly enhancing its in vivo antitumor efficacy. Zhongyi Jiang Tuesday Oct.13, 14:40-15:10 PM C208, Yifu Building Prof. Zhongyi Jiang is a professor at School of Chemical Engineering and Technology of Tianjin University. He obtained a Ph.D. degree from Tianjin University in 1994. He was a visiting scholar of University of Minnesota with prof. Edward Cussler in 1997 and California Institute of Technology with prof. David Tirrell in 2009. He is the winner of National Science Fund for Distinguished Young Scholars in China. His research interest includes biomimetic and bioinspired membranes and membrane processes, biocatalysis, photocatalysis. Till now, he has coauthored over 330 SCI papers, and the total citation times is over 6000 and the h-index is 41. Tunable nanochannels along graphene oxide nanosheets to achieve high-performance proton exchange membrane Simultaneous manipulation of topological and chemical structures to induce ionic nanochannel formation within solid electrolytes is a crucial but challenging task for the rational design of high-performance electrochemical devices including proton exchange membrane fuel cell. Herein, we present a novel generic approach for the construction of tunable ion-conducting nanochannels via direct assembly of graphene oxide (GO)/poly(phosphonic acid) core-shell nanosheets prepared by surface-initiated precipitation polymerization. Using this simple and rapid approach to engineer GO/polymer nanosheets at the molecularlevel, ordered and continuous nanochannels with interconnected hydrogen-bonded networks having a favorable water environment can be created. Page 78 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Guangzhao Mao Tuesday Oct.13, 16:00-16:30 PM C208, Yifu Building Professor Guangzhao Mao is currently a professor of chemical engineering and materials science of Wayne State University (WSU), an adjunct professor of biomedical engineering, the director of the multidisciplinary research incubator program in nanotechnology and nanomedicine. Her research group is developing a wide range of nanomaterials including molecular nanowires for electrochemical sensing, gold nanoparticle carriers for targeted drug delivery in spinal cord injury and cancer therapies, and bioreducible polymer coatings for localized and sustained gene delivery. Bioreducible Layer-by-layer Films for Sequential Gene Delivery Layer-by-layer (LbL) films containing nucleic acids are promising biomaterials for localized gene delivery applications including DNA vaccine delivery and tissue regeneration. Gene delivery applications require that LbL films degrade and release film contents in physiological conditions. Our research focuses on the synthesis and engineering of bioreducible poly(amido amine)s containing the disulfide bond as gene delivery vectors. This talk describes a method to achieve sequential DNA release from LbL films containing strategically placed bioreducible and nonbioreducible polycations. In order to control DNA release sequence, the LbL film assembly and disassembly were studied by in situ atomic force microscopy, fluorescence spectroscopy, and dynamic light scattering. We found that the LbL film containing alternating layers of poly(amido amine) and DNA underwent fast degradation in reducing solution with micrometer particles released from the surface. This bulk degradation behavior was changed into a sequential DNA release pattern with nanometer products by periodic insertion of a nonbioreducible polycation poly(ethylenimine). The insertion also resulted in improved transfection of human embryonic kidney 293 cells. We will present results that directly link the LbL film structure with DNA release dynamics and cell transfection efficiency. Our work demonstrates a simple method for the designing of LbL films for sequential and sustained DNA release for gene delivery applications. Liangyin Chu Tuesday Oct.13, 16:30-17:00 PM C208, Yifu Building Dr. Liang-Yin Chu is a dean of School of Chemical Engineering in Sichuan University and Distinguished Professor of " Yangtze River scholar “. He is Honorary Professor of School of Chemical Engineering in University of Birmingham, also fellow of the Royal Society of Chemistry. He won National Science Fund for Distinguished Young winner before. His current research interests include: Membrane materials and technology, Smart controlled-release and targeting drug delivery systems, Microfluidics, Mass transfer and Separations, and Biomaterials. Drop microfluidics: A versatile and promising approach to fabricate functional granular materials Functional granular materials with typical sizes of 1~1000 µm have received considerable attention for many applications. Generally, the overall functions of these microparticles strongly rely on both of their structures and the properties of their component materials. Thus, the combination of unique structures with functional materials provides an important route for developing advanced functional granular materials. In this presentation, we highlight the recent effort for microfluidic fabrication of granular materials with welldesigned functions for potential biomedical applications, along with the development of microfluidic techniques for producing the versatile emulsion templates. The phase-separated multiple emulsions allows utilization of a variety of functional materials to generate compartment microparticles including hollow, coreshell, multicore/shell and hole-shell structures for controlled encapsulation/release, selective capture, and confined bioreaction. We envision that the versatility of microfluidics for microparticle synthesis could open new frontiers and provide promising and exciting opportunities for fabricating brand-new functional microparticles with broad implications for myriad fields. Page 79 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Zidong Wei Wednesday Oct.14 .15 9:10-9:40 C208 Classroom, Yifu Building Prof. Zidong Wei currently is the dean of school of chemical engineering at Chongqing University. Prof. Wei’ is a supervisor of PhD, person selected for New Century Talents Project, who has been awarded the Cheung Kong Scholar Professorship by the Ministry of Education (MOE) and enjoys the special allowance of the State Department. Prof. Wei’s main research interests include electrochemical reaction engineering, molecular Catalysis and materials chemistry of new energy. Palladium, a most possible alternative for Platinum used in fuel Palladium, iridium, ruthenium and silver based catalysts have been widely investigated as alternatives to Pt in fuel cell applications. Among them, Pd has received considerable attention in comparison with other metal catalysts because of its relatively high activity for the oxygen reduction reaction (ORR), stability, abundance, and low cost. Our latest research shows that the electronic structure of Pd is tuned to be close to that of Pt when Pd is supported on an exfoliated two dimensional oxide nanoplatelet (montmorillonite, MMT). 10 Further investigation revealed that a thin PdOx layer with Pd–O–MMT junctions, formed at the particle/support interface, alters the electronic structure of Pd and diminishes the bonding strength of the adsorbed O, and thus, leading to an enhanced ORR activity and stability.11 In addition, our study on a reduced polyoxometalate (rPOM) supported Pd nanoparticle catalyst show that the ORR activity of Pd is superior to that of the commercial Pt/C catalyst in alkaline medium due to the assist catalytic effect and the electron delocalization effect of the rPOM support. Jieshan Qiu Wednesday Oct.14, 9:40-10:10 AM C208 Classroom, Yifu Building Jieshan Qiu is CheungKong Distinguished Professor, Director of Liaoning Key Lab for Energy Materials & Chemical Engineering, Director of Center for Nano Materials and Science, Co-Director of the PSU-DUT Joint Center for Energy Research, Executive Director of the Institute for Energy Science and Technology; Dean for Research and International Collaboration, Faculty of Chemical, Environmental & Biological Science and Technology, Dalian University of Technology (DUT), China. His research interests have been focused on the development of new methodologies for synthesis of functional carbon materials, and their uses in catalysis, energy conversion/storage and environment protection. . Preparation and Functionalization of Graphene Materials for Water treatment The low-cost preparation and functionalization of graphene materials with tuned structure and properties have drawn much attention, and remain a big challenge up to now. With an aim of developing techniques for making functional materials based on graphene for water treatment, and energy storage & conversion, we have made efforts to explore the potential of producing graphene from coal, and the simple yet effective new approaches to functionalized graphene via chemical and physical ways. In this talk, I will report on the preparation of graphene from coal, the reduction of graphene oxides (GO) by microwave and dielectric barrier discharge techniques, the synthesis of graphene aerogels with unique structure and properties via self-assembly schemes by tuning the GO with chemicals containing NH2 groups, and the applications of graphene aerogels in oil/water separation. I also will report a new strategy for high performance membrane capacitive deionization (MCDI) by designing a novel graphene-based cationselective coating material over film-like electrospun carbon fibers. The composites function to minimize the co-ion expulsion effect that is not uncommon for traditional CDI process,leading to an enhanced electrosorption capacity and an improved charge efficiency. This may open up a new avenue for highperformance, energy-efficient and cost-effective MCDI, and for wide applications of functional graphenebased materials.. Page 80 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Tongwen Xu Wednesday Oct.14, 11:00-11:30 AM C208, Yifu Building Tongwen Xu is a professor of The University of Science and Technology of China. He received his Ph.D degree of Chemical Engineering in 1995 from Tianjin University, China and Post-Ph.D of Polymer Science in 1997 from Nankai University, China. His research interests cover membranes and the related process with a focus on ion exchange membrane as well as the controlled release. Advanced Ion Exchange Membrane for Enhanced Ion Transportation via Molecular Design The depletion of conventional energy sources and the pollution of the environment have put great pressure on the human beings. Seeking for alternative energy and methods to diminish environmental pollution is currently the most urgent task. In this context, ion exchange membrane research has attracted intensive research interests over the past decades. Ion exchange membranes are composed of a polymeric backbone and fixed groups (either anionic or cationic), which are utilized for the transportation of counter-ions. Over the years, researcher of the membrane community have continued to design series of anion exchange membranes and cation exchange membranes. Our work also falls into this category. Since 1997, we have designed several types of ion exchange membranes. We have employed atomic transfer radical polymerization, polyacylation, Suzuki-Miyaura coupling, Menshutkin reaction etc. to precisely control the membrane morphology, mechanical properties, topology, ion transportation properties and so on. In this meeting, we will introduce our most recent work on advanced ion exchange membrane for enhanced ion transportation based on molecular design. Yifan Han Wednesday Oct.14, 11:30-12:00 AM C208, Yifu Building Dr. Yi-Fan Han is a professor of East China University of Science and Technology. Currently, he is also the head of School of Chemical Engineering and Energy in Zhengzhou University (adjunct). Yi-Fan Han received his master degree in chemistry from the ECUST in 1994. After obtaining his Ph.D from the ECUST in 1997 under the supervision of Prof. Ren Wang, he worked as a postdoctoral fellow with Prof. JingFa Deng at the department of chemistry of Fudan university (Shanghai) and with Prof. R. J. Behm at Catalysis and Surface Chemistry department of ULM university (Germany) and Prof. D. W. Goodman and Prof. J.H. Lunsford at the chemistry department of Texas A&M University (USA). From 2004.11 until 2009.9, he was a senior research fellow of Institute of Chemical and Engineering Sciences (A*STAR, Singapore). . New Strategies to Characterize Dynamic Structure of Functional Materials: Advances in Operando Techniques The structure of functional materials is usually significantly affected by the environmental media during working processes. For instance, the surface structure for catalysts, absorbers and sensors are likely changed more or less by the interaction with molecules around or adsorbed on the surfaces. The establishment of the structure-performance relationship is of paramount importance for the rational design and controllable synthesis of those functional materials. Up to date, Operando/in situ spectroscopy, as cutting-techniques, are developed for this aim. More recent advances in this field and a case study will be introduced. Page 81 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Yong Wang Wednesday Oct.14, 14:10-14:40 PM C208, Yifu Building Prof. Yong Wang earned his PhD from Institute of Chemistry, the Chinese Academy of Sciences in 2005, and worked as Research Scientist at Procter&Gamble and as Humboldt Fellow at the Max Planck Institute of Microstructure Physics from 2006 to 2009. He is currently Professor at the College of Chemical Engineering and also at the State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University. He is leading a group of about 20 members focused on homoporous membranes (HOMEs, membranes having homogenous pore sizes and pore geometries). He serves as Co-chair of the Organizing Committee of the 10th International Congress on Membranes and Membrane Processes (ICOM2014), and Member of the Editorial Board of Technology of Water Treatment. Prof. Wang has (co)authored ~100 peer-reviewed papers and 17 patents. Ordered nanoporous polymers by selective swelling of amphiphilic block copolymers Nanoporous materials are finding extensive applications in a diversity of fields ranging from membrane separation to drug delivery to optoelectronics. In these applications pore geometries and size uniformity play important roles in dictating the performances of the materials; therefore, it is highly demanding for efficient and affordable strategies to produce materials with well-defined porosities. In this lecture, we will talk about our recent works on highly ordered nanoporous polymeric materials derived from block copolymers (BCPs). When exposed to selective solvents preferential only to the more polar blocks of BCPs, (e. g. the P2VP block in polystyrene-block-poly (2-vinyl pyridine), PS-b-P2VP), P2VP domains will be swollen selectively by ethanol and mesopores form upon ethanol removal, while the major, nonpolar PS block holds the infrastructure of the BCP material mainly unchanged because PS chains are in the glassy state during the swelling treatment. The sizes of pores in the BCP layer can be tuned either by changing swelling conditions, e. g. time and temperature, or by using BCPs with different molecular weights. Interestingly, due to the immigration of the polyelectrolyte-natured blocks onto the pore wall, the resulting porous materials possess an intrinsically active surface with enhanced hydrophilicity, fouling resistance, and even a stimuli-response function. Hao Jiang Wednesday Oct.14, 14:40-15:10 PM C208, Yifu Building Dr. Hao Jiang is currently a Full Professor in the School of Materials Science and Engineering, East China University of Science and Technology (ECUST). He obtained his Ph.D. degree at the ECUST in 2009. He joined Temasek Laboratories, Nanyang Technological University (NTU) in Singapore, as a research scientist in 2009-2011. He was awarded the Professor of Special Appointment (East Scholar) at Shanghai Institutions of Higher Learning in 2012, the New Century Excellent Talents in University of Ministry of Education of China in 2013. In 2015, he became the winner of the National Science Fund for Excellent Young Scholars. Hao mainly focuses on the controlled preparation of new energy electrode materials by means of chemical engineering principles and methods for applications in supercapacitors and lithiumion batteries (LIBs). As the first or corresponding author, Hao published above 30 SCI papers in recent 5 years, including Energy Environ. Sci., Adv. Mater., etc. Controlled synthesis of hierarchical nanostructured electrode materials for energy storage applications In this topic, we mainly focus on the design and synthesis of novel hierarchical nanostructures electrode materials by confined reaction. Firstly, the heterostructures have been fabricated via the spray-assisted combustion. For example, SnO2 nanorod@TiO2 hybrids are obtained by a modified flame spray pyrolysis approach, showing high power conversion efficiency. Secondly, the interlayer nanocomposites have been prepared by the intercalation assembly methods in the channel in two-dimensional layers. Typically, we designed a new two-dimensional hybrid nanosheet superstructure consisting of the layer-by-layer interoverlapped single-layer MoS2 and mesoporous carbon (m-C) nanosheets by the confined reaction in the MoS2 interlamilation. The hybrids created rich atomic interface for lithium ion storage. Thirdly, the host-guest composites of mesoporous materials with semiconductor and conductive polymer have been constructed by the confined reaction in the mesopores. The relationship between material structure and application performance is also developed. Our studies are expected to provide new materials for energy storage applications. Page 82 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Luyi Sun Wednesday Oct.14, 16:00-16:30 PM C208, Yifu Building Dr. Sun received his B.S. degree in Chemical Engineering from South China University of Technology and his Ph.D. degree in Chemistry from the University of Alabama. After that, he worked as an Assistant Research Engineer at Texas A&M University. Dr. Sun was a Senior Research Engineer at TOTAL Petrochemicals USA, Inc. from 20062009, and an Assistant Professor at Texas State University from 2009-2013. He joined University of Connecticut in Fall 2013. High Performance Multi-functional Nanocoatings Biomimetic organic/inorganic hybrid nanocoatings with a nacre-like microstructure were prepared via a facile coassembly process. The formed nanocoatings typically possess a very low thickness of less than one micron, and their thickness can be easily controlled. Slightly different from conventional polymer nanocomposites, such nanocoatings contain a high concentration of nanosheets, which can be well aligned along the substrate surface. Moreover, the nanosheets and polymer matrix can be chemically cocrosslinked. As a result, the nanocoatings exhibit exceptional mechanical properties (high stiffness and strength), barrier properties (to both oxygen and water vapor), and flame retardancy, but meanwhile they are highly transparent (the coated substrates can typically maintain more than 85% of their original transmittance to visible light). The nanocoatings can be applied to various substrates (such as various polymers, glass, metals, wood) and regular or irregular surfaces. Because of their excellent performance and high versatility, such nanocoatings are expected to find practical daily applications such as food packaging, etc. Clemens Burda Wednesday Oct.14, 16:30-17:00 PM C208, Yifu Building Dr. Clemens Burda is the director of the Center for Chemical Dynamics and Nanomaterials Research in the Chemistry Department, Case Western Reserve University. Since 2001 he is appointed as a faculty in Physical Chemistry specializing on Nanoscience and Nanotechnology. His interests revolve around optically active or activatable nanomaterials for energy conversion, environmental studies, and health applications. This applies in areas such as photovoltaics, photocatalysis, photobiology andbiomedicine, including bioimaging, therapy and tissue targeting for drug delivery Perovskites as Energy Materials: Synthesis and Femtosecond Laser Spectroscopy Studies Perovskite films were prepared using solution deposition at different annealing temperatures and annealing times. The crystal structure, phases and grain size were investigated with XRD, XPS and SEM/EDX. The prepared films show a typical orientation of tetragonal perovskite phase and a gradual transition at room temperature from the yellow intermediate phase to the black perovskite phase. Films with high purity were obtained by sintering at 100 °C. In addition, the intermediate phase could be transformed to the perovskite phase upon Photoirradiation. These CH3NH3PbI3 perovskite were deposited as layered films on substrates with and without a titania support structure and studied using femtosecond time-resolved transient absorption (fs-TA) spectroscopy in the visible light range (450-800 nm). The electron relaxation dynamics from the photoexcited perovskite layers to the neighboring film structures could be directly monitored via the transient bleaching dynamics of the perovskite at ~750 nm and thus systematically studied as a function of the layer-by-layer architecture. We could also spectrally distinguish transient bleaching at ~750 nm from laser induced fluorescence that occurs red-shifted at ~780 nm. Carrier trapping is found to be enhanced on mesoporous titania due to the possibility of grain boundaries within perovskite and PbI2 nanocrystals at the TiO2 interface. As a result of device and material degradation, PbI2 nanocrystals can be conveniently verified in the fs-TA spectra as transient bleach signal at ~510 nm. Page 83 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Xiangping Zhang Thursday Oct.15, 9:10-9:40 AM C208 Classroom, Yifu Building Prof. Xiangping Zhang received her Ph.D. degree in 2002 from Dalian University of Technology. She has been a professor of Institute of Process Engineering (IPE), CAS since 2008.Her current research focuses on the green process system integration, properties and thermodynamic models of ionic liquids, industrial applications of ionic liquids and cleaner processes. She has published about 132 papers in peer-reviewed journals, and obtained 15 issued Chinese invention patents and 1 issued PCT patent. She was awarded the National Award for Natural Sciences, the Nomination Award of the 4th Top Ten Outstanding Women in CAS in 2012. She was the Winner of the National Science Fund for Distinguished Young Scientists in 2014. Ionic liquid-based material for gas separation Gas separation was regarded as an important operation to remove harmful and toxic gas emissions to resolve the environmental problems, and also separate impurities from gas mixtures to improve the gas product quality. As emerged promising alternatives, ionic liquid-based materials have great potentials to be applied in gas purification and separation. In order to develop a new gas separation process, the fundamentals research has been conducted focusing on the structure-property relationship of ILs, the simulation and characterization of gas absorption mechanism, the molecular design of IL structure, the new thermodynamic model for predicating physicochemical properties of ILs, and the transfer properties and fluid dynamic models of gas-ionic liquids system. Changchun Zeng Thursday Oct.15, 9:40-10:10 PM C208 Classroom, Yifu Building Dr. Changchun Zeng is currently an Associate Professor of Industrial and Manufacturing Engineering of FAMU-FSU College of Engineering, and a principle investigator of High-Performance Materials Institute of Florida State University. Dr. Zeng’s main research interests are porous polymeric materials, polymer composites and nanocomposites, and synthesis and processing of materials using supercritical fluids. Prior to join FSU, he was a Senior Research Engineer at Hexcel Corporation, one of the world leaders in carbon fiber and aerospace composite materials. Dr. Zeng received his PhD in Chemical Engineering from The Ohio State University, and MS (Chemical Engineering) and BS (Polymer Engineering) degrees from Zhejiang University. Porous Polymers as Smart Materials Novel functional materials such as nanostructured materials and smart materials have the potential to fundamentally change the way materials are used. Comparing to conventional materials they are of lighterweight and significantly higher performance, and may offer functionalities that do not exist today. Manufacturing these materials in an efficient, environmentally benign process is also of paramount importance for sustainability. Widely used in many applications, porous polymeric materials have been intensely investigated. In this paper we discuss our effort in exploring porous polymers as smart materials for sensing, energy harvesting, and biomedical applications. We illustrate the utilization of environmentally benign supercritical carbon dioxide enabled process to fabricate several types of porous polymer based smart materials and their property enhancement by nanomaterials. Examples will be given to highlight how fundamental understanding in chemical engineering and thermodynamics, materials science and engineering, and design principles work together to create these materials. Their performance characteristics and applications will also be discussed. Page 85 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Kewen Tang Thursday Oct.15 , 11:00-11:30 C208 Classroom, Yifu Building Kewen Tang, who is professor, post-doctor, doctoral supervisor, winner of Education Ministry's program for New Century Excellent Talents in University, winner of Outstanding Youth Fund of Hunan province, leading scholars in higher education of Hunan province, and director of key laboratory on catalysis and separation in fine petrochemical engineering of Hunan province, mainly engages in the research area of chiral separation, reaction kinetics, simulation and optimization of chemical process. He presided 5 National Natural Science Foundation Projects. More than 120 academic papers is published by him in international journals including AIChE Journal, Chemical Engineering Science, Industrial & Engineering Chemistry Research and so on. He is one of the Most Cited Authors of Chemical Engineering Science in 2011. One of the paper is the Top cited AIChE Journal Paper in 2014. Experimental and Model Studies on Continuous Separation of 2-Phenylpropionic Acid Enantiomers by Enantioselective Liquid–Liquid Extraction in Centrifugal Contactor Separators Multistage enantioselective liquid-liquid extraction (ELLE) of 2-phenylpropionic (2-PPA) enantiomers using hydroxypropyl-β-cyclodextrin (HP-β-CD) as extractant was studied experimentally in a counter-current cascade of centrifugal contactor separators (CCSs). Performance of the process was evaluated by purity (enantiomeric excess, ee) and yield (Y). A multistage equilibrium model was established on the basis of single-stage model for chiral extraction of 2-PPA enantiomers and the law of mass conservation. A series of experiments on the extract phase/washing phase ratio (W/O ratio), extractant concentration, the pH value of aqueous phase and the number of stages was conducted to verify the multistage equilibrium model. It was found that model predictions were in good agreement with the experimental results. The model was applied to predict and optimize the symmetrical separation of 2-PPA enantiomers. The optimal conditions for symmetric separation involves a W/O ratio of 0.6, pH of 2.5 and HP-β-CD concentration of 0.1 mol/L at temperature of 278 K, where eeeq (equal enantiomeric excess) can reach up to 37% and Yeq (equal yield) to 69%. By simulation and optimization, the minimum number of stages was evaluated at 98 and 106 for eeeq > 95% and eeeq > 97%. Shuangfeng Yin Thursday Oct.15, 11:30-12:00 AM C208, Yifu Building Dr. Shuang-Feng Yin is currently Professor and Deputy Director of College of Chemistry and Chemical Engineering, Hunan University, Hunan Province, P.R. China. He went to study in Beijing University of Chemical Technology and received B.Sc. degree in 1996. Then he moved to Research Institute of Petroleum Processing and got his Master Degree in 1999. He furthered his study in Tsinghua University and received Ph.D. in 2003. He had postdoctoral research in HK with Professor Au from 2002 t0 2004. From 2004 to present, he worked as lecturer and later full professor (2006) in the college of chemistry and chemical engineering, Hunan University. From 2004 to 2006, he visited Japan as a JSPS fellow. Prof. Yin’s main research interest includes industrial catalysis, CO2 capture and use, new energy, and novel materials. He has 42 patents and over 130 research papers on international journals such as JACS, Angew Chem. AIChE J. Bismuth-containing nano-photocatalysts: controlled synthesis and applications Through the construction of novel structures, exposure of active facets, and/or fabrication of heterojunctions, we developed bismuth-containing materials that show excellent visible-light-induced activity.2-6 (1) Flower-like BiOX (X= Cl, Br, I, CO3) with high exposure of (110) faces can be easily synthesized at room temperature. (2) Composites with BiOI/Bi2O2CO3, g-C3N4/Bi2O2CO3, and g-C3N4/Bi2O3 p-n heterjunctions can efficiently facilitate the dye-sensitizing and charge-carriers separation processes. (3) Cu2O-BiVO4 composites can synergistically remove dyes and Cr(VI) from water. The composites can be synthesized by a two-step solvothermal method. (4) Hollow and branched Bi2O3-Bi2S3 heterostructures can be generated by an environment-friendly “etching and re-growth” method, and the method can be applied to synthesize other Bi2S3-sensitized photocatalysts. The as-fabricated materials display high photocurrent response as well as high activity towards dye degradation under visible light. Most recently, by unifying Bi2WO6 microflowers with g-C3N4-Bi2MoO6 as well as other bismuth-containing composites, we prepared photocatalysts that exhibit high activity towards the selective oxidation of organics. Page 84 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Zongwu Bai Thursday Oct.15, 14:10-14:40 PM C208, Yifu Building Dr. Zongwu Bai is a Senior Research Scientist in Materials & Manufacturing Directorate, Wright-Patterson Air Force Base and University of Dayton Research Institute, University of Dayton. His research interests revolve around Design and synthesis of functional polymers, and Nanoparticle and nanocomposite synthesis. Nanocomposites and Nanotechnology in Proton Exchange Membranes Materials All polymeric electrolyte fuel cells have typically been operated in a temperature range between approximately 50 and 90oC. The temperatures above the polymer glass transition temperature (~110oC for Nafion) can cause polymer chain rearrangements, which can lead to structural changes in the membrane and lower the membrane stability, performance, and lifetime. Polymeric membranes able to operate above 120oC could benefit from both enhanced carbon monoxide (CO) tolerance and improved heat removal. The addition of nanofunctions into a polymeric membranes to form a nanocomposites can alter and improve polymer properties such as glass transition temperature, elastic modulus, tensile strength, solvent permeability, hydrophilicity, water uptake and proton conductivity while enabling the polymeric membranes to maintain its suitability for operation in the fuel cells. Highly sulfonated polyarylenethioethersulfones (SPTES) polymers were successfully synthesized. To improve the high temperature performance of the SPTES membranes in the fuel cell application, the nanoparticles, such as ZrP or Clay, sulfonated poly(p-phenylene benzobisimidazole) (SPBI) were introduced into the SPTES membranes to form nanocomposite membranes. The interesting feature of the nanoparticles is that it can retain water at high temperature, and it was found that the swelling of the nanocomposite membranes was reduced due to the reduced water uptake of the nanocomposite membrane. The morphology changes of the nanocomposite membranes were examined by a combination of techniques such as X-ray diffraction (WAXD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to confirm the dispersion of SPBI and nanoparticles as well as nanophase separation. The membrane electrode assembly (MEA) performance of the nanocomposite membranes was preliminary studied for H2/O2 fuel cells applications Page 86 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Yingwei Li Thursday Oct.15, 14:40-15:10 PM C208 Classroom, Yifu Building Dr. Yingwei Li is currently the deputy dean of School of Chemistry and Chemical Engineering at the South China University of Technology. He received his B.S. degree in 1998 and Ph.D. in 2003 from Tsinghua University. Following postdoctoral work at the University of Calgary (Canada) and the University of Michigan (Ann Arbor) from 2003 to 2007, he joined the South China University of Technology as a full professor. His research interest focuses on design and synthesis of new metal-organic framework (MOF) materials for heterogeneous catalysis and gas adsorption /separation. In the past 10 years, he has published more than 60 papers on MOFs in the peer reviewed journals. Metal-organic frameworks encapsulated metal nanoparticles for heterogeneous catalysis In this talk, we focus on two aspects of MOFs’ catalysis applications: the use of MOF materials as scaffold for the incorporation of metal nanoparticles, and the preparation of metal/carbon materials from thermolysis of MOFs.We employed stable MOFs as support for highly dispersed metal. The metal-doped MOFs are shown to be highly efficient for a variety of chemical conversions. In order to encapsulate metal NPs within MOFs, we have developed a novel synthesis strategy through ligand design prior to MOF assembly, achieving uniformly distributed metal NPs inside the cavities of MOFs. On the other hand, taking advantage of their ordered structures and relatively low thermal stability, MOFs could be utilized for the preparation of new metal oxides or carbon nanomaterials by thermal decomposition. Here we show that Co nanoparticles embedded in nitrogen-doped carbon prepared from MOFs thermonlysis could catalyze a variety of organic transformations, such as aerobic oxidation of alcohols to esters, low-temperature CO oxidation, and oxidative amidation of aldehydes. Ling Zhang Thursday Oct.15, 16:00-16:30 PM C208 Classroom, Yifu Building Dr. Zhang Ling has a Ph.D. in Materials Processing Engineering graduated from Sichuan University. She is currently a Professor in East China University of Science and Technology and also a member of Key Laboratory for Ultrafine Materials of the Ministry of Education. Her research focuses on surface modification of nanoparticles, the design and synthesis of new reinforcement with specific structure, and their application in polymer composites. In the past 10 years, she presided over a number of national and provincial projects. She has published more than 50 journal articles and is the inventor/co-inventor of 21 Chinese patents. Highly conductive and flexible polymer composites based on carbon nanotube/graphene network Here, the carbon nanotubes and graphene were prepared into 3D carbon aerogel (CA) structures by using organic sol-gel method. Meanwhile, we also creatively designed a new stretchable conductive material that integrates 3D CNTs/reduced graphene oxide (rGO) network with a porous PDMS (p-PDMS) elastomer (pPCG). This reciprocal architecture not only alleviates the aggregation of carbon nanofillers but also significantly improves the conductivity of pPCG under large strains. The simulation of the mechanical properties of the p-PDMS model demonstrates that an extremely large applied strain can be accommodated through local rotations and bending of cell walls. Thus, after a slight decrease, the conductivity of pPCG can continue to remain constant even as the strain increases to 50%. In general, this architecture of pPCG with a combination of a porous polymer substrate and 3D carbon nanofiller network possesses considerable potential for numerous applications in next-generation stretchable electronics. Page 87 Symposium 8- Materials andand Nanoand Technology (C208) Symposium 11Petrochemicals Fine Chemicals Symposium 11- Petrochemicals Fine Chemicals (M104) Chunzhong Li Symposium Chair Dr. Chunzhong Li received B.S. (1989), M.S. (1992) and PhD (1997) from East China University of Science and Technology (ECUST). He became a full professor of school of materials science and engineering in 1998, and now he is the director of Key Laboratory for Ultrafine Materials of the Ministry of Education at ECUST. He was elected as a Fellow of the Royal Society of Chemistry in 2015, became the Cheung Kong Distinguished Professor in 2014, the winner of the National Science Fund for Distinguished Young Scholars in 2009. As the first accomplished person, he has achieved the second-class prize of the National Science and Technology Progress Award in 2009, the first Class Prize for Shanghai Natural Science Award in 2014, the first class prize for the science and technology progress award of the Ministry of Education of China in 2010, and the first class prize of the Science and Technology Progress Award of Shanghai City in 2009, 2006 and 2004 respectively. He published more than 350 peerreview papers (Total citation ~ 8,400, H index 46), and more than 90 invention patents in China. His research interests mainly include designed synthesis of functional nanomaterials based on the principle and methods of chemical engineering, the synthesis and processing polymer based nanocomposites, and the engineering properties and process scale-up for nanomaterials. Page 88 Symposium 8- Materials and Nano Technology (C208) Tuesday Oct.13 (C208) Chair : Changsheng Liu, Stuart Cooper Afternoon 13:30-14:10 14:10-14:40 14:40-15:10 Title S8-K1 Name Nanogenerators for self-powered systems Zhong Lin and piezotronics for smart devices Wang Affiliation Georgia Institute of Technology S8- I1 Cancer Drug Delivery: A CAPIR Cascade and Nanocarrier Design (H0093) Youqing Shen Zhejiang University S8- I2 Tunable nanochannels along graphene oxide nanosheets to achieve highperformance proton exchange membrane (H0413) Zhongyi Jiang Tianjin University 15:10-15:20 Coffee break East China Changsheng University of Liu Science and Technology 15:20-16:00 S8-K2 Bioinspired 2D/3D architecturemediated cell response and tissue regeneration 16:00-16:30 S8-I3 Bioreducible Layer-by-layer Films for Sequential Gene Delivery (H0251) Guangzhao Mao Wayne State University S8-I4 Drop microfluidics: A versatile and promising approach to fabricate functional granular materials (H0218) Liangyin Chu Sichuan University 16:30-17:00 Page 89 Symposium 8- Materials and Nano Technology (C208) Wednesday Oct.14 (C208) Chair : Liming Dai, Shuhong Yu Morning Title Name Interfacial Assembly and Engineering of Dongyuan Ordered Functional Mesoporous Materials Zhao for Applications (H0490) Affiliation Fudan University 8:30-9:10 S8-K3 9:10-9:40 S8-I5 Palladium, a most possible alternative for Platinum used in fuel cells (C0163) Zidong Wei Chongqing Univ. S8-I6 Preparation and Functionalization of Graphene Materials for Water treatment (H0376) Jieshan Qiu Dalian University of Technology Stuart Cooper Ohio State University 9:40-10:10 10:10-10:20 10:20-11:00 11:00-11:30 11:30-12:00 Coffee break S8-K4 Polyurethanes and Ionomers: High Performance Elastomers and Plastics Self Reinforced with Nanoscale Structure (H0201) S8-I7 Advanced Ion Exchange Membrane for Enhanced Ion Transportation via Molecular Design (H0220) Tongwen Xu Univ. of Science and Technology of China S8-I8 New Strategies to Characterize Dynamic Structure of Functional Materials: Advances in Operando Techniques (H0435) Yifan Han ECUST Title Name Affiliation Carbon-based metal-free electrocatalysts for energy conversion and storage (H0439) Liming Dai Case Western University 12:00-13:30 Lunch (Youyi Restaurant) Chair : Weishen Yang, Guangzhao Mao Afternoon 13:30-14:10 S8-K5 14:10-14:40 S8- I10 14:40-15:10 S8-I10 15:10-15:20 Page 90 Ordered nanoporous polymers by selective Yong swelling of amphiphilic block copolymers Wang (H0488) Controlled synthesis of hierarchical nanostructured electrode materials for Hao Jiang energy storage applications (D0526) Coffee break Nanjing Tech University ECUST Symposium 8- Materials and Nano Technology (C208) Shuhong Yu Univ. of Science and Technology of China Luyi Sun University of Connecticut Perovskites as Energy Materials: Synthesis Clemens and Femtosecond Laser Spectroscopy Burda Studies (H0357) Case Western Reserve University 15:20-16:00 S8-K6 Macroscopic Nanoparticle Assemblies: Integration, Functionalization and Applications (H0407) 16:00-16:30 S8-I11 High Performance Multi-functional Nanocoatings (H0027) 16:30-17:00 S8-I12 Thursday Oct.15 (C208) Chair : Jieshan Qiu, Clemens Burda Morning Title Name Affiliation S8-K7 Controlled Manufacturing of Polymers with Complex Chain Microstructure Bogeng Li Zhejiang University 9:10-9:40 S8-I13 Ionic liquid-based on material for gas separation (H0492) Xiangping Zhang Institute of Process Engineering 9:40-10:10 S8-I14 Porous Polymers as Smart Materials (H0271) Changchun Florida State Zeng University 8:30-9:10 10:10-10:20 10:20-11:00 Coffee break S8-K8 11:00-11:30 S8-I15 11:30-12:00 S8-I16 12:00-13:30 Molecular sieving nanosheets of metalorganic framework as building blocks for H2/CO2 separation (H0276) Weishen Yang Experimental and Model Studies on Continuous Separation of 2Kewen Phenylpropionic Acid Enantiomers by Tang Enantioselective Liquid–Liquid Extraction in Centrifugal Contactor Separators Bismuth-containing nano-photocatalysts: Shuangfeng controlled synthesis and applications Yin (H0403) Dalian Institute of Chemical Physics, CAS Hunan Institute of Science and Technology Hunan University Lunch (Youyi Restaurant) Page 91 Symposium 8- Materials and Nano Technology Chair : Bogeng Li, Guangsheng Luo Afternoon 13:30-14:10 14:10-14:40 14:40-15:10 Title Affiliation S8-K9 Preparation of microcapsules and Guangsheng nanoparticles with microflows (H0103) Luo S8-I17 Nanocomposites and Nanotechnology in Proton Exchange Membranes Materials (H0353) Zongwu Bai AFRL/RXC C-UDRI S8-I18 Metal-organic frameworks encapsulated metal nanoparticles for heterogeneous catalysis (H0535) Yingwei Li South China University of Technology Changjun Liu Tianjin University Ling Zhang ECUST 15:10-15:20 Tsinghua University Coffee break 15:20-16:00 S8-K10 16:00-16:30 S8-I19 Nano and nanostructured materials created by room temperature electron reduction (H0170) Highly conductive and flexible polymer composites based on carbon nanotube/graphene network Note: S ~ Symposium; K~ Keynote; I~ Invited talk Page 92 Name Symposium 9- Membrane Technology for Water Purification (C202) Symposium 9- Membrane Technology for Water Purification Chairs: Zhenliang Xu, [email protected]; Weihong Xing, [email protected] Ranil Wickramasinghe, [email protected]; Xianghong Qian, [email protected] Featured Speakers Tongwen Xu Tuesday Oct.13, 13:30-14:10 PM C202 Classroom, Yifu Building Tongwen Xu is a professor of The University of Science and Technology of China. He received his Bachelor’s degree in 1989 and Master’s degree in 1992 from Hefei University of Technology, China. Till now, he supervised more than 100 graduate students and published more than 300 papers in peer-reviewed international journals with over 4500 citations and H-index 40. He applied 62 invention patents (32 License). He was selected as Fellow of Royal Society of Chemistry in 2013 and as Changjiang Scholars Program Chair Professor in 2014. . Ion exchange membrane-based separation technologies Ion exchange membranes are of the corresponding resins in membrane shape. Electro-membranes and related processes have attracted more and more attention and have found numerous applications in resource recycling, energy conversion, and environmental protection. These vital technologies are developing as a new platform in industrial ecosystems because they can realize some novel separation and production to achieve the maximal utilization of resources and pollution prevention. The economical and environmental benefits of electro-membranes technologies are flexibly coupled with many other technologies to achieve a synergistic technological intensification. In this Keynote report, the recent developments of the most commonly used ion exchange membrane-based separation technologies such as diffusion dialysis (DD), conventional electrodialysis (CED) and bipolar membranes electrodialysis (BMED) will be presented with following sub-titles. Zhenliang Xu Tuesday Oct.13, 15:20-16:00 PM C202 Classroom, Yifu Building Dr. Zhen-Liang Xu is a professor of State Key Laboratory of Chemical Engineering and National Engineering Research Center of Ultrafine Powder at East China University of Science and Technology (ECUST) of China. He applied 42 invention patents (15 Licenses). Prof. Xu was selected as “Project Coordinator of Ministry of Science and Technology of China in 2012 and as the expert of China Membrane Industry Association in 2009. Prof. Xu are serving as the editors and editorial boards of 7 Chinese journals and edited five Chinese books including “New Progresses and Engineering Applications of Membrane Technologies (2013)”. His research interests cover asymmetric and composite membranes, Functional membrane materials. Novel Fluoropolyamide NF Membranes and Separation Properties A novel composite nanofiltration (NF) membrane was prepared by interfacial polymerization of 2,2’bis(1-hydroxyl-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4’-methylenedianiline (BHTTM) and trimesoyl chloride (TMC) on polyethersulfone (PES) supporting membrane. Different preparation conditions and NF membrane performances were discussed. The membrane structures of composite NF membranes were characterized by attenuated total reflectance infrared (ATR-IR), scanning electron microscope (SEM) and atomic force microscopy (AFM). The results showed that the NF membrane prepared under the optimum condition exhibited Na2SO4 rejection of 85.3% and the water flux of 10.1 l.m-2.h-1. The NF membrane was treated by 5000 ppm chlorine solution for 1 h. The salt rejection and water flux of the treated membrane reached to 94.5% and 94.8 l.m-2.h-1. The rejection of two NF membranes for inorganic electrolyte solutions decreased in the order of Na2SO4, MgSO4, MgCl2, NaCl, which were typical characteristics of negatively charged membranes. Page 93 Symposium 9- Membrane Technology for Water Purification (C202) Enrico Drioli Wednesday Oct.14, 8:30-9:10 AM C202 Classroom, Yifu Building Professor Enrico Drioli has been working in Membrane Science and Membrane Engineering for many years. He is a Full Professor at the Department of Chemical Engineering and Materials at the University of Calabria, where he founded the Institute of Membrane Technology of the Italian Research Council in 1993. He is also the author of more 530 scientific papers, 18 patents in the field of Membrane Science and Technology, and 10 scientific books . . Membrane engineering for water purification and reuse in mining industry High water stress, increasing energy consumptions and mineral depletion are all already critical issues. Process engineering is one of the disciplines more involved in the technological innovations necessary to face these strongly inter-connected problems. As a matter of fact, water is also needed for energy generation (e.g. as cooling component); energy is also needed in desalination and for raw material production (especially in mining where large amount of energy and water are necessary). Membrane technology can represent a problem-solver with inter-correlated solutions. In the last years membranes operations have been already assigned a key role in water reclamation schemes that are aimed at higher water quality reuse applications (i.e., reverse osmosis is considered one of the most promising technologies for desalting salty waters). Moreover, the traditional membrane separation operations (e.g., MF, UF, NF, RO), widely used in many different applications, are today combined with new membrane systems such as MD, MCr, PRO, RED. At present, redesign of important industrial production cycles by combining various membrane operations suitable for separation and conversion units, and thus realizing highly integrated membrane processes, is an attractive opportunity because of the synergistic effects that can be attained. In this work, integrated membrane-based desalination have been considered for the extraction of fresh water and metals of interest from seawater and high concentrated brine streams of the desalination plants. Wanqin Jin Wednesday Oct.14, 10:20-11:00 AM C202 Classroom, Yifu Building Dr. Wanqin Jin is a professor of Chemical Engineering at Nanjing Tech University (former name: Nanjing University of Technology), the Deputy-director of the State Key laboratory of Materials-oriented Chemical Engineering and the Chief-scientist of the National Basic Research Program of China (973 Program). He has published over 200 SCI tracked journal publications with over 5800 citations, and edited 5 books and had 32 authorized patents. He presented over 30 plenary, keynote lectures and invited speeches in international conferences, and was chair of the 10th International Congress on Membrane and membrane Processes (ICOM2014). Molecular Separation Membranes Derived from Graphene Oxide nanosheets A facile silane-graft modification approach proposed by our group was demonstrated to be an efficient way to improve the quality of the GO film formed on the porous ceramic substrate. Based on this, we further demonstrated a scalable fabrication of GO membranes on ceramic hollow fiber substrate and showed good PV dehydrotion of aqueous organic solution. The as-prepared membrane exhibited excellent water permeation for dimethyl carbonate/water mixtures. In addition, we also proposed a novel type of membrane with fast and selective gas-transport channels of GO laminates enabled by polymer-GO hydrogen bonding.[4] Featuring molecular-sieving interlayer spaces and straight diffusion pathways, the assembled graphene oxide laminates endow the gas separation membranes with excellent CO2 permeation performance and extraordinary operational stability which is believed to be attractive for implementation in practical CO2 capture. Recently, we demonstrated a novel bio-inspired strategy that utilizes the synergistic effect of a hydrophilic polymer and GO laminates to realize fast water-transport channels for constructing high-efficiency membrane. Because GO nanosheets can be easily mass-produced by chemical oxidization and ultrasonic exfoliation from inexpensive raw graphite, it is expected that GO-based material is promising for membrane based process, including PV dehydration and gas separation Page 94 Symposium 9- Membrane Technology for Water Purification (C202) Ingo Pinnau Wednesday Oct.14, 13:30-14:10 PM C202 Classroom, Yifu Building Ingo Pinnau is Director of Advanced Membrane and Porous Materials Research Center and named Professor of Chemical and Biological Engineering, Physical Science and Engineering. His research interests are in membrane processes for separation of gases and liquids-natural gas treatment, CO2 sequestration, hydrogen recovery, olefin/paraffin separation, and water purification. His research focuses on: Synthesis of high-performance polymers; Development of high-performance membranes for gas and liquid separations; Hybrid organic/inorganic membranes; Nanostructured microporous polymer membranes. Elucidation of the microstructure of interfacially polymerized reverse osmosis membranes Today, the most commonly used commercial membranes for brackish and seawater desalination are based on thin-film polyamide composite membranes formed by interfacial polymerization of multifunctional aromatic or cycloaliphatic diamines and acid chlorides. The resulting thin films are typically 200 to 2000 Å thick with various topologies ranging from smooth and continuous to highly heterogeneous, ridge and valley structures. Optimized RO membranes exhibit salt rejection of 99+%, indicating that the highly water permeable, salt rejecting polyamide layer is essentially defect-free. It has been postulated that transport across the polyamide layer occurs by a solution/diffusion mechanism similar to that well accepted in gas permeation processes. In this work, we investigated the microstructure of RO membranes by means of water transport studies (RO and FO mode), gas permeation experiments as well as tomography, TEM and FESEM studies. Our results confirm that the water flux of RO membranes can be optimized by incorporation of various porous and non-porous nanofillers, such as POSS and ZIF-8, without loss in salt rejection. Kamalesh K. Sirkar Wednesday Oct.14, 15:20-16:00 PM C202 Classroom, Yifu Building Kamalesh K. Sirkar is a Distinguished Professor of Chemical Engineering at New Jersey Institute of Technology (NJIT) in Newark, New Jersey, USA. He is also the Foundation Professor of Membrane Separations and Director of the NJIT Center for Membrane Technologies. He is internationally recognized as an expert in membrane separation technologies. Experimental and Modeling Studies in Membrane Distillation We have studied direct contact membrane distillation (DCMD) using porous polypropylene hollow fiber membranes (HFMs) having a highly porous plasma polymerized fluorosiloxane coating on the outside surface. These fibers are arranged in a rectangular module with hot brine in cross-flow. When such a module is fed with hot de-oiled produced water (Chevron), we can recover as much 80% of the water by DCMD without scaling damage on the membranes. Since this water is hot, no heat source is needed. Although the feed had many constituents, the permeate produced was highly purified; conventional treatment for this produced water involved 7-8 steps. Steam assisted gravity drainage (SAGD) process of producing oil from Canadian oil-shale yields a produced water at 2-4 atm and 130-150oC+. We have studied successfully a DCMD process to recover water using flat and HFMs of polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVDF) from simulated SAGD-produced water at high temperatures. To evaluate the influence of membrane properties on DCMD, many commercially-available microporous hydrophobic flat membranes of PVDF and PTFE (varying pore size and thickness) were studied over a range of hot brine temperatures. Membrane properties, e.g., the maximum pore size and tortuosity, were experimentally determined for use in modeling Knudsen and the transition regimes. The heat transfer coefficients in the membrane cell and membrane surface temperatures were determined from experimental data via Wilson plots. Page 95 Symposium 9- Membrane Technology for Water Purification (C202) W.S. Winston Ho Thursday Oct.15, 8:30-9:10 AM C202 Classroom, Yifu Building W.S. Winston Ho is Distinguished Professor of Department of Chemical & Biomolecular Engineering and Department of Materials Science and Engineering, the Ohio State University. He experts in molecularly based separations including definition of approaches, design of practical systems, scale-up and commercialization. Specialized in membranes and separations including polymer and liquid membranes, fuelcell fuel processing and membranes, separations with chemical reaction, supported liquid membranes, reverse osmosis, gas treating, pervaporation, and facilitated transport. New Fouling-Resistant High-Flux Membranes for Seawater Desalination We have synthesized high flux membranes by incorporating a hydrophilic additive in the aqueous amine solution during interfacial polymerization, resulting in increasing water flux significantly through an additional pathway for water transport while maintaining high salt rejection via charge repulsion. For seawater desalination using synthetic 3.28 wt% NaCl solution at 800 psi (5.52 MPa) and 25oC, the membrane synthesized with the hydrophilic additive showed a very high flux of 1.81 m3/m2/day (44.4 gallons/ft2/day (gfd)) and a salt rejection of 99.41%. This flux was 83.5% higher than the membrane synthesized without the hydrophilic additive. The high-flux membrane was further tested using seawater from Port Hueneme, CA and exhibited a very good and stable desalination performance for 30 days. FTIR confirmed the good membrane stability. The membrane synthesized with hydrophilic additive showed significantly improved fouling resistance using sodium alginate as the model foulant. With 25 ppm sodium alginate in the synthetic feed solution, the water flux reduction of the membrane synthesized with the hydrophilic additive was 11.0% compared to 18.2% for the membrane synthesized without the additive. Analysis of the fouling resistance using the resistance-in-series model indicated that the values of the ratio of the mass transfer resistance due to the foulant for the membrane synthesized with the additive to that for the membrane without the additive were 0.30 and 0.29 for 25 ppm and 50 ppm sodium alginate in the feed solutions, respectively. Analysis using atomic force microscopy showed a smoother membrane surface for the membrane incorporated with the hydrophilic additive. Page 96 Symposium 9- Membrane Technology for Water Purification (C202) Tuesday Oct.13 (C202) Chair : Ranil Wickramasingle, Zhenliang Xu Afternoon 13:30-14:10 14:10-14:40 14:40-15:10 Title Name Affiliation S9-K1 University of Ion exchange membrane-based separation Tongwen Science and technologies (I0221) Xu Technology of China S9-I1 Design of Multiwalled Carbon Nanotubes Functionalization for Optimizing Dispersion in Mixed-Matrix Membranes for Advanced Separations (I0286) S9- I2 15:10-15:20 Elena Tocci ITM-CNR Institute of Affinity membranes for dynamic Chuanfang Process adsorption of heavy and precious metals Yang Engineering, CAS Coffee break S9-K2 Novel Fluoropolyamide NF Membranes and Separation Properties (I0130) ZhenLiang Xu ECUST 16:00-16:30 S9-I3 Coupling Magnetic Pickering Emulsions with Membranes for Fouling-Free Oil/Water Separations (I0031) David Jassby University of California 16:30-17:00 S9-I4 15:20-16:00 Blend Polymer Membranes with Filtration Bao-Ku and Absorption Property (I0223) ZHU Zhejiang University Wednesday Oct.14 (C202) Chair : Ranil Wickramasingle, Zhenliang Xu Morning Title Name Affiliation 8:30-9:10 Membrane engineering for water purification and reuse in mining industry Enrico Drioli King Abdulaziz University Research on novel membranes and processes designed for membrane Xiaolong Tianjin Polytechnic 9:10-9:40 S9-K3 S9- I5 distillation purpose Lv University Page 97 Symposium 9- Membrane Technology for Water Purification (C202) 9:40-10:10 S9-I6 10:10-10:20 Enhanced membrane antifouling and separation performance by manipulating phase separation and surface segregation behaviors through incorporating versatile modifier (I0418) Zhongyi Jiang Tianjin University Wanqin Jin Nanjing Tech University Coffee break 10:20-11:00 S9-K4 Molecular Separation Membranes Derived from Graphene Oxide Nanosheets (I0466) 11:00-11:30 S9-I7 Adsorptive Membranes for Ammonia Removal Xianghong University of Qian Arkansas Development of high efficient MEAbased solvents for CO2 capture (I0467) Beijing Weidong University of Zhang Chemical Technology 11:30-12:00 S9-I8 12:00-13:30 Lunch (Youyi Restaurant) Chair : Xinhong Qian and Weihong Xing Afternoon 13:30-14:10 Title S9-K5 Elucidation of the microstructure of interfacially polymerized reverse osmosis membranes (I0393) Name Affiliation Ingo Pinnau King Abdullah University of Science and Technology The University of Hong Kong Baolin Deng Universityof Missouri Kamalesh Sirkar New Jersey Institute of Technology 14:10-14:40 S9-I9 Doppler optical coherence tomography: a Chuyang novel method to characterize fluid Tang dynamics and membrane fouling for a spacer-filled membrane system 14:40-15:10 S9-I10 Antibacterial TFC membranes enabled by chemically-bound metal nanoparticles 15:10-15:20 Coffee break 15:20-16:00 S9-K6 Experimental and Modeling Studies in Membrane Distillation (I0225) 16:00-16:30 S9-I11 Effect of membrane structure on membranes performance during membrane distillation (I0254) 16:30-17:00 S9-I12 Treatment of pharmaceutical wastewater for reuse by coupled membrane-aerated biofilm reactor (MABR) system (I0364) Page 98 Sumith University of Wickram Arkansas asinghe Baoan Li Tianjin University Symposium 9- Membrane Technology for Water Purification (C202) Wednesday Oct.15 (C202) Chair : Ranil Wickramasingle, Weihong Xing Morning Title Name 8:30-9:10 S9-K7 New Fouling-Resistant High-Flux Membranes for Seawater Desalination (I0216) Winston Ho S9-I13 Surface Engineering of Electrospun Polymeric Nanofibers For Membrane Distillation(I0362) Yunxia Hu S9-I14 Unique Transport Phenomena in Graphene Oxide Membranes for Water Purification Baoxia Mi 9:10-9:40 9:40-10:10 Affiliation The Ohio State University Yantai Institute of Coastal Zone Research, ChineseAcad emy of Sciences University of California, Berkeley Note: S ~ Symposium K~ Keynote; I~ Invited talk Page 99 Symposium 10- Particle and Fluidization Technology (M203) Symposium 10- Particle and Fluidization Technology Chairs: Fei Wei, [email protected] Qingshan Zhu, [email protected] Marc-Olivier Coppens, [email protected]; Alissa Park, [email protected] Featured Speakers Liang-Shih Fan Tuesday Oct.13, 13:30-14:10 PM M203 Classroom, Yifu Building Prof. L.-S. Fan is the Distinguished University Professor and C.J. Easton Professor in the Department of Chemical and Biomolecular Engineering at The Ohio State University. Prof. Fan also serves as the Director of the Clean Energy Research Laboratory at The Ohio State University. Prof. Fan is widely recognized for the development of clean energy technologies such as the removal of SOX/ NOX, As and Se using super-reactivity limestone sorbents, CO2 separation from flue gases using high reactivity metal oxides, chemical looping combustion of coal, enhanced H2 production with in-situ CO2 capture, and CO2 mineral sequestration using Mgbearing minerals. He is an elected member of the U.S. National Academy of Engineering and an Academician of the Academia Sinica, and a foreign member of the Australian Academy of Technological Sciences and Engineering, the Chinese Academy of Engineering, and the Mexican Academy of Sciences. Chemical Looping Processes: Role of Fluidization and Particle Science The concept of chemical looping reactions has been applied to processes used in chemical industries. Fundamental and applied research on chemical looping reactions in energy systems has been extensively carried out. Fossil fuel chemical looping applications started with the steam-iron process using syngas from coal as feedstock in the 1900s through the 1940s and were demonstrated at a pilot scale with the carbon dioxide acceptor process in the 1960s and 1970s. There are presently no chemical looping processes using carbonaceous fuels in commercial operation. However, with CO2 emission from fossil fuel usage that is now of great concern, interest is high in chemical looping technology applications for CO2 capture. Chemical looping technology is a manifestation of the interplay among all the key elements of particle science and technology including particle synthesis, reactivity and mechanical properties, flow stability and contact mechanics, gas-solid reaction engineering and fluidization. This presentation will describe the fundamental and applied aspects of modern chemical looping technology that utilizes fossil and other carbonaceous feedstock. Specifically, it will discuss the characteristics of fluidized bed and moving bed and their impact on the metal oxide conversion in the reducer operation the key operation of the chemical looping processes. The energy conversion efficiency and economics of the Coal-Direct Chemical Looping Process and Syngas Chemical Looping Process being developed at Ohio State University based on the moving bed configuration will also be elaborated. Page 100 Symposium 10- Particle and Fluidization Technology (M203) Wei Wang Tuesday Oct.13, 14:10-14:50 PM M203 Classroom, Yifu Building Dr. Wei Wang is Professor of Institute of Process Engineering (IPE), Chinese Academy of Sciences. has been working on multiscale modeling, computational fluid dynamics (CFD) for multiphase flow and computerized tomography (CT) techniques for multiphase flow systems. his method has been applied successfully for troubleshooting/design in industrial processes of e.g. fluid catalytic cracking, coal gasification and combustion, polyethylene polymerization, kaolinite clay calcination and so on. Speeding Up Reactive Modeling of Fluidized Bed Reactor by Combining CRE and Multiscale CFD The methanol to olefins (MTO) process, which is a promising alternative to produce light olefins from coal resources, has been successfully commercialized in China by DICP. The design of MTO reactor borrows ideas from the reaction-regeneration configuration of the modern fluid catalytic cracking (FCC) process, but the fluidized bed for MTO reactions operates in the regime of bubbling or turbulent fluidization. The coke content of catalyst is found to greatly affect the MTO reaction rate, but its conversion rate is slow and normally takes hours prior to reaching desired level of content (about 6%~7%). The mean residence time of solid catalysts is hence in orders of minutes or hours. Time-dependent computational fluid dynamics (CFD) simulation of such a long process poses a big challenge to reactive multiphase flow modeling. To speed up it, we try to combine the classic chemical reaction engineering (CRE) model with CFD. For example, the continuous stirred tank reactor (CSTR) model is used to estimate the steady state distribution of coke content, which is then set as the initial distribution for CFD simulation to shorten the time to reach steady state of MTO reactors. Comparison with experimental data shows good agreement and also great speed up ratio compared to pure CFD simulation. Mao Ye Wednesday Oct.14, 9:10-9:40 AM M203 Classroom, Yifu Building Mao Ye is professor of chemical engineering at the Dalian Institute of Chemical Physics (DICP), CAS. His research interests include methanol to olefins and fluid catalytic cracking process, fluidized bed reactor, and multiphase flow modeling and measurement techniques. He was the recipient of the Newton Advanced Fellowship by Royal Society, UK in 2015. . Improve bubble size estimation by pressure fluctuation analysis in gas-fluidized beds Pressure fluctuation signals captured at a single point in the gas-fluidized bed is composed by global fast compression waves and local bubble-passage induced slow pressure waves. Based on the Davidson and Harrison bubble model, the local bubble-passage induced slow wave has the amplitude proportional to the size of bubbles, and can only be detected when the bubbles move close to the pressure measurement points. In principle, if the local pressure wave can be separated from the global one, the information of bubble size can be inferred accordingly. Van der Schaaf et al. proposed an interesting frequency decoupling method to estimate bubble size in fluidized beds according to the different propagation velocity of the two types of pressure waves. As the pressure signal in the windbox only contain the global pressure waves while the in-bed pressure signals are a combination of the global pressure waves and the local bubble induced ones, a coherence analysis between on the pressure series simultaneously detected in the bed and in the windbox can be used to measure bubble size. This frequency decoupling method has now been widely used in bubble size estimation. However, this method seemingly can only give a qualitative prediction of the bubble size. No studies have been carried out so far to analyze the systematic deviation of bubble size estimated from pressure fluctuation signals. In this study, we used an ECT system together with the synchronized pressure sensors to study the inherent reasons for the deviation in bubble size measurement. Page 101 Symposium 10- Particle and Fluidization Technology (M203) Ah-Hyung Alissa Park Wednesday Oct.14, 8:30-9:10 AM M203 Classroom, Yifu Building Professor Park is Lenfest Junior Professor in Applied Climate Science, the Earth Institute, Columbia University. She is currently leading a worldwide multidisciplinary NSF Research Coordination Network devoted to CCUS. Her current research interests are include: Carbon Capture, Utilization and Storage (CCUS); Novel Nano-scale Hybrid Materials for energy and environmental technologies; Synthesis of hydrogen and liquid fuels from biomass and municipal solid wastes; Clean fossil energy conversion systems; Electrostatic charging phenomena in multiphase flows and electrostatic tomography; Particle technology and Fluidization. Enhanced Water-Gas Shift Reaction in the Presence of a Mg(OH)2 Slurry in a High Pressure Aqueous System This study investigated the integration of slurry phase Mg(OH)2 carbonation with the water gas shift reaction (WGSR) at temperatures up to 215 oC with a 0.5 wt% platinum on alumina catalyst. The removal of CO2 by the carbonation reaction enhanced hydrogen yield of the WGSR as the equilibrium of the gas phase reaction was shifted towards products. Aqueous Mg(OH)2 carbonation has been shown to occur readily, and various metastable and stable magnesium carbonates are formed depending on the reaction conditions (primarily driven by temperature). This study revealed that the H2 yield was enhanced in the presence of Mg(OH)2 slurry, and more interestingly the unexpected conversion of CO to aqueous formate ion was observed, which did limit the overall production of H2. The presence of the basic aqueous phase within the reactor promoted a side reaction between CO and hydroxide ions. The formate can persist in solution or decompose to yield H2 depending on the solution conditions. The solid and liquid components of the reacting slurry were carefully analyzed for carbonate and formate in order to investigate the reaction mechanisms. Page 102 Symposium 10- Particle and Fluidization Technology (M203) Tuesday Oct.13 (M203) Chair : Alissa Park and Qingshan Zhu Afternoon Title Name 13:30-14:10 S10-K1 Chemical Looping Processes: Role of Fluidization and Particle Science (J0160) Liang-Shih Fan 14:10-14:50 S10- K2 Speeding Up Reactive Modeling of Fluidized Bed Reactor by Combining CRE and Multiscale CFD (J0083) 14:50-15:20 S10- I1 15:20-15:30 15:30-16:00 16:00-16:30 16:30-17:00 S10-I2 S10-I3 S10-I4 DEM Validation via System-SizeIndependent Measurements (J0323) Coffee break Regular Bubble Pattern Formation in Pulsed Fluidized Beds – From Exciting Phenomenon to Fingerprint for Simulation Method Validation (J0194) A Novel Two-stage Fluidized Reduction Process for Enhanced Synthesis of Fe Nanoparticles (J0452) 3D Full-loop Simulation of Hydrodynamics in a M-type Circulating Fluidized Bed Boiler (J0082) Affiliation The Ohio State University Institute of Process Wei Wang Engineering, CAS Christine University Hrenya of Colorado MarcOlivier Coppens University College London Institute of Process Jun Li Engineering, CAS Institute of Process Nan Zhang Engineering, CAS Wednesday Oct.14 (M203) Chair : Marc-Olivier Coppens and Fei Wei Morning 8:30-9:10 S10-K3 Title Enhanced Water-Gas Shift Reaction in the Presence of a Mg(OH)2 slurry in a High Pressure Aqueous System (J0386) 9:10-9:50 S10-K4 Improve bubble size estimation by pressure fluctuation analysis in gasfluidized beds (J0387) 9:50-10:20 S10-I5 Fluidized bed direct reduction for the Panzhihua titano magnetite (J0106) Name Affiliation Ah-Hyung Park Columbia University Mao Ye Qingshan Zhu Dalian Institute of Chemical Physics, CAS Institute of Process Engineering, CAS Page 103 Symposium 10- Particle and Fluidization Technology (M203) 10:20-10:30 10:30-11:00 11:00-11:30 11:30-12:00 Coffee break S10-I6 Thinking Small with Fluidization Scale Up (J0291) Raymond Cocco Particulate Solid Research, Inc. (PSRI) S10-I7 Micro fluidized bed applied in catalytic tests of selective oxidative dehydrogenation of isopentene to isoprene (J0312) Qi Wang Tsinghua University S10-I8 Multifluid Modeling of Low-rank Coal Pyrolysis in a Downer Reactor (J0038) 12:00-13:30 Institute of Process Zhan Shu Engineering, CAS Lunch (Youyi Restaurant) Wednesday Oct.14 (M203) Chair : Raymond Cocco and Wei Wang Afternoon Title 13:30-14:10 S10-K5 14:10-14:40 S10- I9 14:40-15:10 S10- I10 15:10-15:20 Page 104 Affiliation China University Development and Commercialization of a Mengxi Liu of Gas-solid Airlift Loop Reactor Petroleum (Beijing) Institute of Modeling the Hydrodynamics of Process Cocurrent Gas-solid Downward Flow Xinhua Liu Based on Energy-minimization MultiEngineering, scale (EMMS) Theory (J0040) CAS Institute of Dynamic Multi-scale Simulation of GasProcess solid Flows Using Spatially Coupled Two- Xizhong fluid Model and Discrete Particle Method Chen Engineering, (J0037) CAS Coffee break Particle Self-assembly for 3D Structured Coatings (J0189) Functional Uniform Microparticles Tailored by a Novel Spray Drying 15:50-16:20 S10-I12 Technology (J0235) Note: S ~ Symposium K~ Keynote I~ Invited talk 15:20-15:50 Name S10-I11 James Gilchrist Lehigh University Duo Wu Soochow University Symposium 11- Petrochemicals and Fine Chemicals (M104) Symposium 11- Petrochemicals and Fine Chemicals Chairs: Jinsen Gao, [email protected]; Xiaojun Peng, [email protected] Bipin Vora, [email protected]; Jim Johnson, [email protected] Featured Speakers Yi Xiao Tuesday Oct.13, 15:20-16:00 PM M104, Yifu Building Prof. Dr. Yi Xiao graduated from Tianjin University Fine Chemical Engineering, and he received his Ph.D. degree (2003) in Fine Chemicals at Dalian University of Technology Department of Applied Chemistry, then, he joined the Japan's National Institute of Industrial Science and Technology as a Postdoctoral(2003-2004). He currently is a professor in Fine Chemical Engineering at Dalian University of Technology. His main research interest focuses fluorescent sensors and organic semiconductor. Development and applications of long wavelength BODIPY fluorescent dyes BODIPY is one of the famous families of fluorescent dyes. BODIPY dyes take advantages of high fluorescence quantum yields and high photostability over many other fluorescent dyes. Hence, BODIPYs are popular in various fields. Especially, they are important fluorophores to develop molecular probes or sensors extensively applied in life sciences. Recently years, BODIPYs have also found new applications such as donor materials in thin-film solar cells. The limitation of most BODIPYs is the relatively short wavelength excitation/emission, which is likely interfered by biological background fluorescence and is also not favorable to match the solar light spectrum. Our group have rationally developed a series of long wavelength (from red to NIR) BODIPY with tunable photophysical properties. And we apply them in different ways, e.g. laser dyes, fluorescent probes, solar cells etc. In this presentation, I would like to report these works. Zhenghong Luo Wednesday Oct.14, 15:20-16:00 PM M104, Yifu Building Prof. Dr. Zhenghong Luo currently worked in department of Chemical Engineering at Shanghai Jiao Tong University. His research interests focus on multi-phase flow reaction engineering, polymerization reaction engineering, functional polymer chemistry and chemical engineering, chemical process simulation and optimization. Effect of Copolymer Composition on pH-Responsive Surface Wettability: Identifying the Best Copolymer for Efficient Water/Oil Separation Used polymer as case, this study aimed to fabricate reversible pH-responsive polymeric surfaces for controllable wettability and to identify the best copolymer for water/oil separation from the chemical product engineering viewpoint. To attain this aim, three block copolymers with different PAA segment lengths were synthesized for the first time through Cu(0)-mediated reversible-deactivation radical polymerization and hydrolysis reaction. pH-induced controllable surface wettability was achieved by spincoating the resulting block copolymers onto silicon wafers. Results showed that the pH-responsive wetting behavior was introduced by incorporating the PAA block, and that the responsiveness of as-fabricated surfaces was greatly influenced by PAA content. All three evolutions of water contact angle with pH shared a similar inflection point at pH 5.25. Furthermore, a simple solution-casting technique was developed to functionalize the stain steel meshes (SSMs) by using the as-prepared block copolymers to separate layered water/oil mixtures. Page 105 Page 1 Symposium 11- Petrochemicals and Fine Chemicals (M104) Jennifer Holmgren Wednesday Oct.14, 8:30-9:10 AM M104, Yifu Building Dr. Jennifer Holmgren is the Chief Executive Officer of LanzaTech. Jennifer has over 20 years of experience in the energy sector including a proven track record in the development and commercialization of fuels and chemicals technologies. Prior to joining LanzaTech, she was Vice President and General Manager of the Renewable Energy and Chemicals business unit at UOP LLC, a Honeywell Company. In that role, she led UOP’s renewable business from its inception through to the achievement of significant revenues from the commercialization of multiple novel biofuels technologies. Carbon Recycling to Produce Valuable Commodities LanzaTech offers an innovative biosynthesis approach and has developed and scaled a complete process platform to allow the continuous biological production of fuels and an array of chemical intermediates from gases at scale. Exceptional feedstock flexibility and metabolic diversity make LanzaTech’s gas fermenting microbe unique. The ability to utilize gases relies on a unique redox chemistry and energy conservation mechanisms that are not possible in standard hosts as E. coli or yeast. In order to maximize the value that can be added to the array of gas resources that the LanzaTech process can use as an input, the company has developed a robust genetic toolbox to allow the carbon and energy consumed by its proprietary gas fermenting microbe to be channeled into a spectrum of valuable chemicals. This has allowed LanzaTech to develop chassis strains with optimized production and multiple proprietary strains for synthesis of non-natural products via novel routes. LanzaTech has demonstrated synthesis of over 25 new products from gas fermentation, including fuels ethanol or platform chemicals as 2,3-Butanediol (2,3-BDO), a four-carbon alcohol that can be catalytically converted to bio butadiene. Zhichang Liu Wednesday Oct.14, 10:20-11:00 AM M104, Yifu Building Zhichang Liu is a professor in Chemical Engineering of China University of Petroleum, Beijing. He received PhD degree from Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences (1999). Winner of the Outstanding Young Scientists Fund. His main research interests focus on ionic liquid catalyst and compound ionic liquid. New alkylation process-Composite Ionic Liquid Alkylation(CILA) Chloroaluminate ionic liquids (ILs) [1] were discovered as potential alternatives for the traditional isobutane alkylation catalysts (HF and H2SO4). A composite ionic liquid (CIL) developed by China University of Petroleum[2] shows good catalytic performance for isobutane alkylation.The first commercial 100 kt/a CILA plant was succesfully started-up in 2013 in Shandong by Deyan Chemical Co., Ltd.. Thus far, the plant has been running stably over two years. This plant includes four sections, namely feed treatment, staged reactors, reactor refrigeration and product treatment. In addition, this plant also has CIL handling facilities to enable solids removal and CIL regeneration. The typical composition of C4 feed during this time is listed in Table 1. The result showed that: the olefin conversion was 100%; the alkylate yield was 80% of feed; the average RON of alkylate was 96.8; the catalyst consumption per ton alkylate was 5 kg; the energy consumption per ton alkylate was 150 kgEO. Table 2 shows the typical mass balance of the plant. It shows that the CILA plant has safety and environmental benefits compared with HF and H2SO4 alkylation processes. Page 106 Symposium 1Advanced Technology for Air Separation Symposium 11- Petrochemicals and and FinePurification Chemicals( C201) (M104) Tuesday Oct.13 (M104) Chair : Jinsen Gao, Bipin Vora Afternoon S1113:30-14:10 14:10-14:40 14:40-15:10 K1 S11I1 S11I2 Title Name Affiliation Advances in Petrochemical Technology (K0334) James Johnson UOP LLC Xiang Ma ECUST Liang Zhao China University of Petroleum (Beijing) Yi Xiao Dalian University of Technology Stimuli-Responsive Functional Supramolecular Polymers in Aqueous Solution (K0459) K-edge XANES and DFT studies of mechanism of reactive adsorption desulfurization of thiophene on Ni/ZnO (K0543) 15:10-15:20 15:20-16:00 16:00-16:30 16:30-17:00 Coffee break S11K2 S11I3 S11I4 Development and applications of long wavelength BODIPY fluorescent dyes (K0282) Development of Biodegradable Anionic Detergent (K0381) New Process Technologies for Conversion of Acetic Acid to Ethanol or Acrylic Acid (K0382) Retired Bipin V. Vora UOP/Honeyw ell Fellow Ralph Gillespie Celanese Corporation Title Name Affiliation Carbon Recycling to Produce Valuable Commodities (K0449) Jennifer Holmgren LanzaTech Inc. Wednesday Oct.14 (M104) Chair : Xiaojun Peng, Jim Johnson Morning 8:30-9:10 9:10-9:40 9:40-10:10 10:10-10:20 S11K3 S11I5 S11I6 Hindered diffusion of sulfur-containing compounds in residue fractions through membranes and catalyst (K0572) Zhentao Chen Construction of Functional MoleculesPlasmonic Nanoparticle for Colorimetric Recognition (H0445) Jianjun Du China University of Petroleum (Beijing) Dalian University of Technology Coffee break Page 107 Symposium 11- Petrochemicals and Fine Chemicals (M104) 10:20-11:00 11:00-11:30 S11-K4 S11-I7 China New alkylation process-Composite Ionic Zhichang University of Liquid Alkylation(CILA) (K0499) Liu Petroleum Design of interconnected ion conductive Xuemei channels for fuel cells Wu Dalian University of Technology 11:30-12:00 S11-I8 12:00-13:30 Separating Olefins from Sulfur in FCC Gasoline Mid-Cut (K0390) Zhepeng Liu GTC (Beijing) Technology Inc. Name Affiliation Lunch (Youyi Restaurant) Chair : Xiaojun Peng, Jim Johnson Afternoon Title Preparations and applications of Ni2P- 13:30-14:10 S11-K5 based catalytic materials for hydrogen China Chen University of guang Liu Petroleum evolution (K0530) 14:10-14:40 S11-I9 14:40-14:50 (East China) Fluoresecein-based sensors for metal ions Xiaoqiang Nanjing Tech and biological rargets Chen Coffee break Effect of Copolymer Composition on pH- 14:50-15:30 S11-K6 Responsive Surface Wettability: Zheng Identifying the Best Copolymer for hong Luo Efficient Water/Oil Separation 15:30-16:00 University S11-I10 High Throughput Testing of Naphtha Reforming Catalysts (K0383) Alfred Haas Shanghai Jiao Tong University hte GmbH China 16:00-16:30 S11-I11 A hybrid absorption-adsorption method for separating gas mixtures Pei Liu University of Petroleum (Beijing) Note: S ~ Symposium K~ Keynote I~ Invited talk Page 108 Symposium 12- Process Development and Optimization (M103) Symposium 12- Process Development and Optimization Chairs: Feng Qian, [email protected]; Guangsheng Luo, [email protected] Joe Qin, [email protected]; Michael Baldea, [email protected] Featured Speakers Frank Zhu Tuesday Oct.13, 13:30-14:10 PM M103, Yifu Building Dr. Frank Zhu, a leading expert in industrial process design, modeling, and energy optimization, is a Senior Fellow of UOP. During his tenure at UOP, he has helped several major refinery companies achieve significant energy savings by applying energy management systems, led designs of several most efficient refinery plants, implemented energy optimization into UOP engineering process, and led R&D projects achieving major breakthroughs. His latest book "Energy and Process Optimization for the Process Industries" is jointly published by Wiley and AIChE in 2014. Molecular Modeling Creates News Ways for Process Design and Operation Optimization The capability of obtaining molecular information and molecular models provides a new platform for developing new catalysts and novel process designs as well as optimizing existing assets for refining and petrochemical processes. The theory of molecular management and applications will be introduced with practical examples. Yu Qian Tuesday Oct.13, 15:20-16:00 PM M103, Yifu Building Dr. Yu Qian is Chair Professor of Chemical Engineering at South China University of Technology, the Director of the Center for Process Systems Engineering. His research interests are modeling and Integration of process and operation, Life cycle analysis and sustainability study of the chemical/energy processes. Dr. Qian received his BSc, MSc, PhD degrees from Tsinghua University in Beijing. After his post-doctoral research experience in the Norwegian Institute of Technology in 1989-1991, he became a Research Associate Fellow at the University of British Columbia in Vancouver, Canada. In 1994 he was appointed as a full professor at South China University of Technology, where he served as the Dean of the School of Chemical Engineering during 2002-2012. Dr. Qian has been the Deputy Director of the Chinese Institute of Computer Aided Process Engineering since 2005. Coal based processes development and integration for better resource utilization and less environmental impacts In this presentation, Multi-dimensional technical-economical-environmental-social models are built for quantitative sustainability and life cycle assessment of alternative coal processes from feedstock, to production, market, and recycling; to rationalize the decision-making on resource allocation and process design; and finally, to raise efficiency and minimize environmental impacts of existing and potential alternative coal based processes. A number of coal gasification syngas derived energy and chemical product chains are taken as benchmark cases in this work. With integration and optimization of the mass and energy network, coal based processes with higher CO2 capture rate and higher CO2 purity for commercial use could improve environmental and economic performance a lot. Page 109 Symposium 12- Process Development and Optimization (M103) Xigang Yuan Wednesday Oct.14, 10:20-11:00 AM M103, Yifu Building Xigang Yuan is Professor of Chemical Engineering and Director of Chemical Engineering Research Center at Tianjin University. He is director of the Distillation Laboratory of the State Kay Laboratory of Chemical Engineering at Tianjin Universty. He is a member of the Council of the Chemical Industry and Engineering Society of China, the Fellow of the IChemE (Institution of Chemical Engineers UK), member of the Fluid Separation Working Party of the European Federation of Chemical Engineering, member of the Process Systems Engineering Committee of the Systems Engineering Society of China, and member of editorial board of Chiness Journal of Chemical Engineering. Professor Yuan’s research interests are in the areas of mass transfer in chemical processes, separation engineering, process systems engineering and computational mass transfer and fluid dynamics for chemical engineering. Computational mass transfer approach to chemical process simulation In the present presentation, two kinds of theoretical models, namely: isotropic model and anisotropic model, for convective mass transfer in multiphase turbulent flow systems are summarized. In the isotropic model, a two-equation model is proposed based on the Boussinesq hypothesis to calculate the turbulent diffusivity. While in the anisotropic model, a Reynolds mass flux model is derived, and the assumption of an isotropic turbulent diffusivity introduced by the Boussinesq postulation can be eliminated. Then, computational mass transfer approach is developed based on the theoretical models. The proposed approach is finally validated by simulating chemical processes including distillation and fluidized bed reaction. The advantages of the proposed method in avoiding empirical parameters utilization, like in some traditional methods, and some other features are discussed. Yongrong Yang Wednesday Oct.14, 13:30-14:10 PM M103, Yifu Building Professor Yang Yongrong was born in 1962 who now works as the research fellow in UNILAB, Zhejiang University, executive chief editor of Chemical Reaction Engineering and Technology journal. The main research field concerns multiphase flow reaction engineering, polymerization engineering and process system engineering. Professor Yang has completed successfully 863 Programs and projects from National Natural science foundation. In the recent five years, Professor Yang has published more than fifty SCI papers and been authorized more than forty patents. The Industrial Application of Condensation Mode in Gas Phase Polyethylene Process project was awarded second prize of Nation Award for Science and Technology Progress and Process Package for a 300 Thousand Tons LLDPE per year by Gas Phase Process was awarded the first prize of Science and Technology Progress Award of SINOPEC Page 110 Symposium 12- Process Development and Optimization (M103) Joe Qin Wednesday Oct.14, 8:30-9:10 AM M103, Yifu Building Dr. S. Joe Qin is Vice President of the Chinese University of Hong Kong, Shenzhen, and is on leave from the position of Fluor Professor of Process Engineering at the Viterbi School of Engineering of the University of Southern California. Dr. Qin is a Fellow of IEEE and Fellow of the International Federation of Automatic Control (IFAC). He is a recipient of the National Science Foundation CAREER Award, the 2011 Northrop Grumman Best Teaching award at Viterbi School of Engineering, the DuPont Young Professor Award, Halliburton/Brown & Root Young Faculty Excellence Award, NSF-China Outstanding Young Investigator Award, Chang Jiang Professor of Tsinghua University, Thousand Talent Professor of the Northeastern University of China, and an IFAC Best Paper Prize for the model predictive control survey paper published in Control Engineering Practice. Big Data Process Analytics In normally-operated engineering systems where processes, units, and equipment are designed with specific purposes, mechanistic models and first-principles are dependable. However, for the operation of emerging or abnormal situations that are not anticipated in the design, operation data become indispensable assets for the decision-making in safe and efficient operations. In this talk we offer a perspective on the essence of process data analytics, how data have been effectively used in process operations and control, and new perspectives on how process systems operations might evolve to a paradigm of data-enhanced operations and control. The discussed perspectives include i) mining of time series data for event discovery, decision-making, and causality analysis; ii) exploring the power of new machine learning techniques that have enjoyed tremendous development in nearly two decades; and iii) anticipating a system architecture shift towards a data-friendly information system. Xiao Feng Wednesday Oct.14, 14:10-14:50 PM M103, Yifu Building Xiao Feng is a professor of Chemical Engineering at Xi’an Jiaotong University, China. Her research interests lie in process integration and include energy, water and hydrogen system integration, by graphical method and mathematical programming. Prof. Feng is an author on over 200 archival publications and two books and the Vice-Chair of the Thermodynamics and Engineering Application Committee, China Energy Research Society, Standing Director of Chinese Chemical Education Society, and Director of Process System Engineering Society, Chinese System Engineering Society. Optimization of recirculating cooling water systems with coupling cooler and pump networks Re-use of cooling water between different coolers has been proved to be an effective way to reduce flowrate of cooling water. However, the coolers with series configurations require a higher pressure head of the corresponding branch pipe, which may result in more pump power needed. On the other hand, the pumps for transporting cooling water from a cooling tower to each cooler traditionally are installed in the header line of the feed pipe, constituting main pump network. The pressure head of the main pumps must be large enough to satisfy heat loads and pressure heads of all coolers. The pressure drop of parallel branch pipes must be balanced by turning down the opening of valves for some coolers, which causes energy penalty of pumps. In order to minimize power consumption, a novel methodology is proposed to simultaneously consider pump arrangement in the pump network and cooling water reuse exploration in the cooler network. The total annualized cost of cooling water systems is taken as the objective function. A superstructure of cooling water systems is developed to consider the interactions between the performance of pumps and the design of cooler network. Page 111 Symposium 12- Process Development and Optimization (M103) Tuesday Oct.13 (M103) Chair : Feng Qian, Joe Qin Afternoon Title Name 13:3014:10 S12-K1 Molecular Modeling Creates News Ways for Process Design and Operation Optimization (L0266) Frank Zhu 14:1014:40 S12-I1 Integrated Control System Harmonic to Batch Process Natures Furong Gao Affiliation UOP LLC, A Honeywell Company Hong Kong University of Science and Technology 14:4015:10 Liquid-liquid microflow for fast chemical reaction processes (L0515) Yangcheng Lu Tsinghua University Yu Qian South China University of Technology Xi Chen Zhejiang University Zhen Liu LIST AG Switzerland Title Name Affiliation S12-K3 Big Data Process Analytics Joe Qin USC S12-I5 Total site water-using system design for industrial parks (L0555) Jian Du Dalian University of An integrated model for industrial catalytic ethylene polymerization reactors (L0591) Zhou Tian S12-I2 15:1015:20 Coffee break 15:2016:00 S12-K2 16:0016:30 S12-I3 16:3017:00 S12-I4 Coal based process development and integration for better resource utilization and less environmental impacts (L0482) Large Scale Simulation and Optimization of a Polymerization Process with Embedded Molecular Weight Distributions (L0534) Efficient Processing in the concentrated Phase (L0088) Wednesday Oct.14 (M103) Chair : Guangsheng Luo, Michael Baldea Morning 8:30-9:10 9:10-9:40 9:40-10:10 10:1010:20 Page 112 S12-I6 Coffee break Technology ECUST Symposium 12- Process Development and Optimization (M103) 10:20-11:00 11:00-11:30 11:30-12:00 S12-K4 Computational Mass Transfer Approach to Chemical Process Simulation (L0521) S12-I7 Pseudo-transient Methods for EquationOriented Flowsheet Simulation and Optimization (L0157) Michael Baldea S12-I8 Modeling the oxidation kinetics of hydrocarbon in liquid phase based on reaction mechanism (L0462) Ling Zhao ECUST Title Name Affiliation S12-K5 Progress on olefin polymerization process technology in China Yongrong Yang Zhejiang University S12-K6 Optimization of recirculating cooling water systems with coupling cooler and pump networks Xiao Feng Xi'an Jiaotong University S12-I9 Advanced Design Optimization of Combustion Equipment for BioEnergy Systems Using Sculptor® with CFD Tools (L0395) Joseph Smith Missouri University of Science and Technology S12-I10 Optimization and control technology for maximizing high added-value product of ethylene plants Wenli Du ECUST 12:00-13:30 Xigang Yuan Tianjin University The University of Texas at Austin Lunch (Youyi Restaurant) Chair : Ling Zhao, Michael Baldea Afternoon 13:30-14:10 14:10-14:50 Coffee break 14:50-15:00 15:00-15:30 15:30-16:00 Note: S ~ Symposium K~ Keynote I~ Invited talk Page 113 Symposium 13-Thermodynamics and Transport Phenomena (C209) Symposium 13-Thermodynamics and Transport Phenomena Chairmen: Honglai Liu, [email protected]; Xiaohua Lu, [email protected] Glenn Lipscomb, [email protected] David Rumschitzki, [email protected] Randall Snurr Tuesday Oct.13, 8:30-9:10 AM C209, Yifu Building Randy Snurr is the John G. Searle Professor of Chemical and Biological Engineering at Northwestern University. He holds BSE and PhD degrees in chemical engineering from the University of Pennsylvania and the University of California, Berkeley, respectively. From 1994-95, he performed post-doctoral research at the University of Leipzig in Germany supported by a fellowship from the Alexander von Humboldt Foundation. Other honors include a CAREER award from the National Science Foundation, the Leibniz professorship at the University of Leipzig in 2009, and the 2011 Institute Award for Excellence in Industrial Gases Technology from the American Institute of Chemical Engineers. Molecular Modeling, Screening, and Design of Metal-organic Frameworks for Gas Storage and Separation Applications Metal-organic frameworks (MOFs) are an interesting class of nanoporous materials synthesized in a “building-block” approach from inorganic nodes and organic linkers. Some of the most intensively studied applications are related to solving energy and environmental problems, including hydrogen and natural gas storage for cleaner vehicles, capture of CO2 from power plant exhaust, and energy efficient separations. Because of the predictability of MOF synthetic routes and the nearly infinite number of possible structures, molecular modeling is an attractive tool for screening new MOFs before they are synthesized. Modeling can also provide insight into the molecular-level details that lead to observed macroscopic properties. This talk will illustrate how molecular modeling and high-throughput computational screening can be used to discover, develop, and ultimately design new MOFs for desired gas adsorption applications. Shiang-Tai Lin Tuesday Oct.13, 15:20-16:00 AM C209, Yifu Building • Lin is a full professor at the Department of Chemical Engineering, National Shiang-Tai Taiwan University. Dr. Lin’s research focuses on the determination of thermophysical properties of materials from the combined use of statistical mechanical theory and modern computational chemistry. Specific examples include the phase equilibria of fluids, the equilibrium and kinetic properties of gas hydrates, the efficiency of polymer photovoltaic. His research works have been published in over 90 peer-reviewed journals. Dr. Lin’s research team was the recipient of the Best Poster APJ award in the APCChE2010, and the champion of the 5th Industrial Fluid Property Simulation Challenge in 2008. From First Principles to Fluid Phase Equilibria The knowledge of thermodynamic properties of fluids is critical for the design, development, and optimization of relevant chemical processes. However, the collection of such data via experimental approaches can be very time-consuming or even impractical in some areas, such as drug discovery where properties of thousands to millions of chemicals are investigated. Recent advances in the quantum physical and quantum chemical theories open up possibilities to obtain these important properties without resorting to any experimental measurement. However, there are challenges remain such as the need for overwhelming computational resources for industrial problems and the insufficient chemical accuracy for phase equilibrium predictions. In this talk, we present approximate methods for fluid property predictions that utilize results from quantum chemical solvation calculations. The method we have developed is general and can be used to determine all aspects of properties of a chemical or a mixture of chemicals under almost any conditions. Page 114 Symposium 13-Thermodynamics and Transport Phenomena(C209) Jianguo Wang Tuesday Oct.13, 16:00-16:30 AM C209, Yifu Building • Jianguo Wang is the leader of Molecular Catalysis and Computational Prof. nanoMaterials Group , Zhejiang University of Technology. He received his B.Sc, M.Sc and Ph.D degree in Central South University, Nanjing University of Technology and Tianjin University, respectively. From 2004 to 2008, he worked as postdoctoral researcher at University of Aarhus, Denmark and Princeton University, USA. In 2008, Dr. Wang jointed Zhejiang University of Technology as Qianjiang Professor of Zhejiang Province. Reaction and Diffusion on Supported Metal Nanocatalysts Supported noble metal catalysts have played an important role in the conversion of energy and resources. During the recent years, we have systematically investigated: (1) The diffusion and reaction on hydrophobic carbon and hydrophilic TiO2 supported noble metal catalysts by means of density functional theory calculations and molecular dynamics simulations. Size effect has been regularly utilized to tune the catalytic activity and selectivity of metal nanoparticles(NPs). At present, it is still a computational challenge to directly simulate the catalytic properties over different sizes of metal nanoparticles. Therefore, a simple method to describe the relationship between the noble metal particle size and catalytic properties is developed. (2) The preparation of different size Pd catalysts s on carbon and TiO2 by the controlling the interaction between metal and support. (3) The application of Pd/C nanocatalysts on halogenated nitrobenzene selective hydrogenation, CO2 reduction. Chunshang Li Wednesday Oct.14, 8:30-9:10 AM C209, Yifu Building Professor of Institute of Process Engineering (IPE), Chinese Academy of Sciences (CAS). Structure-Property Relationship in Ionic Liquids A systematic property database are established by us and near 4000 ILs are contained. The new thermodynamic models based on the ionic fragment contribution-corresponding states (FCCS) are developed to predict the physicochemical properties of ILs and phase equilibrium of IL-containing mixtures. The contribution values of io、nic fragment can be expected to be estimated by quantum chemistry (QC) method. In structural investigation, the non-covalent interactions are the underlying aspect in determining the properties of ILs. Based on the QC calculation, it is found that the hydrogen bond is very critical to pairing, packing and assembly, although the electrostatic force was stronger ions. The properties such as melting point, viscosity and enthalpy are correlated with the hydrogen bond forces. The force fields of new ILs were developed and the properties of density, viscosity, conductivity and so on were predicted by molecular dynamic (MD) simulation. It is found that the nano-clusters in some ILs induce the charge redistribution and the aggregation of polar-heads. The clusters are changeable dynamically and show rodlike and vesicle structures with the different concentrations. Page 115 Symposium 13-Thermodynamics and Transport Phenomena(C209) Doraiswami Ramkrishna Thursday Oct.15, 15:20-16:00 PM C209, Yifu Building Doraiswami Ramkrishna, Harry Creighton Peffer Distinguished Professor of Chemical Engineering at Purde University since 1994, obtained his B (Chem) Eng. Degree from University of Mumbai in 1960, and his PhD in Chemical Engineering from the University of Minnesota in 1965. Following his PhD, he was an Assistant Professor for two years at Minnesota before returning to the India Institue of Technology Kanpur where he served on the faculty for nearly seven years. He returned to the United States in 1974 as a Visiting Associate Professor in 1974, thereafter as a visiting professor at Minnesota in 1975 before joining Purdue University as a Professor of Chemical Engineering in 1976. Professor Ramkrishna's research group is motivated by ideas in the application of mathematics to solving problems in chemical and biochemical reaction engineering, biotechnology and biomedical engineering. Population balance modeling: A ubiquitous tool for engineering analysis Although the earliest use of population balances dates back to the days of Boltzmann, its status as a ubiquitous modeling tool in engineering has come about only in relatively recent times. In particular, while its importance began with conventional areas such as in modeling the behavior of commonly occurring dispersed phase systems, its role in enabling extension to many modern exotic applications has been spectacular. It is the purpose of this talk to expound the basic tenets of population balances with examples drawn from traditional and current areas of application towards their further exploration. Dapeng Cao Wednesday Oct.14, 13:30-14:10 PM C209, Yifu Building Dapeng Cao is a Professor and Director of the Division of Molecular and Materials Simulation, State Key Laboratory of Organic-Inorganic Composites at Beijing University of Chemical Technology (BUCT). He received his Ph D from BUCT in 2002, and was a research scientist at NanoMaterials Technology Pte Ltd in Singapore (2002-2003) and a postdoctoral researcher at the University of California at Riverside (2003-2005). His research interests are focused on the designed synthesis and applications of functional materials, including porous luminescent polymers and energy conversion and storage materials related to fuel cells supercapacitors and solar cells. Currently, he is the Editorial Board Members of 《Scientific Reports》, 《ISRN Chemical Engineering》 and 《American of Macromolecular Science》. He has published more than two hundred articles in journals such as 《J. Am. Chem. Soc.》, 《Angew. Chem. Int. Ed.》, 《Adv. Mater.》, 《Energy Environ. Sci.》. Multiscale Simulation Designed Synthesis of Nanostructured Porous Materials in Chemical Engineering It has become increasingly clear that hydrogen as a viable energy carrier may play an important role in future energy plans. However, development of reasonably safe and reversible hydrogen storage materials for transportation is still a great challenge. In this work, we present the scheme of designing novel materials and address the multiscale simulation method, in which the first-principles calculation is performed to calculate the interaction energy between adsorbate and adsorbent, and then the interaction is input to grand canonical Monte Carlo (GCMC) simulation for evaluation of hydrogen storage capacities.12 By using the multiscale simulation method proposed, a series of novel materials are designed. These materials include new carbon allotrope - diamondyne, silicon nanotube (SiNT), silicon Li12Si60H60 fullerene, Li-doped covalent organic frameworks (COFs), Porous aromatic Frameworks (PAFs). Furthermore, hydrogen storage capacities of these materials are also investigated. In addition, we also proposed a targeted synthesis method to fabricate the nitrogen-doped graphene analogue materials for oxygen reduce reaction (ORR), in which we used the well-defined 2D covalent organic polymers as targeted template and then carbonized the targeted materials for in situ synthesis of nitrogen-doped porous carbons. These synthesized porous carbons are excellent metal-free electrocatalysts for ORR. Page 116 Symposium 13-Thermodynamics and Transport Phenomena(C209) Shuangliang Zhao Wednesday Oct.14, 15:20-16:00 PM C209, Yifu Building Shuangliang Zhao received his Ph.D. degree from Ecole Normale Superieure de Lyon, France in 2007, and after postdoctoral periods in Ecole Normale Superieure, Paris (2008-2009) and University of California at Riverside (20102011), he joined the Department of Chemical Engineering in East China University of Science and Technology as an associated professor. His research area mainly focuses on molecular modeling and equilibrium/non-equilibrium statistical mechanics theory. Unified Framework of Multi-scale Density Functional Theories and Its Recent Applications Most chemical engineering processes involve complex multi-phase fluid systems, and their evolution depends on the mechanism by which the inhomogeneous subsystems exchange information at different length-scales. Whereas numerous theoretical methods with specific description accuracies have been developed for investigating physicochemical properties of various fluid systems, a unified theory that enables the investigation of mesoscale problems is still needed. In this talk, we present a unified framework of multi-scale density functional theories (DFTs). In addition, the combinations of those DFTs with each other and with other conventional theories and simulation approaches are also discussed. Finally, general discussions on the up-to-date progress of DFTs and the expectations on their further extensions are given. Jian Zhou Wednesday Oct.14, 10:20-11:00 AM C209, Yifu Building Prof. Dr. Jian ZHOU is the leader of nano-bio interface engineering group at the department of chemical engineering, South China University of Technology. He received his Ph.D. degree (1998) of Chemical Engineering at Nanjing University of Chemical Technology. Then, he had his postdoc research at Beijing University of Chemical Technology, University of Washington and University of Utah during 19982005. He was appointed as a full professor in Chemical Engineering at South China University of Technology since 2006. His research interest is multiscale simulation of complex chemical and biological systems, including protein adsorption, smart materials, adsorption and diffusion of confined fluids, self-assembling of soft matters etc. Multiscale Simulations of Protein Adsorption Protein adsorption plays an important role not only in a wide range of basic biological processes but also in many applications such as protein chromatography, drug delivery on solid substrates, biosensors, biofuel cells and biomaterials. For these processes and applications, one key issue is the orientation of adsorbed proteins on surfaces. Another key issue that determines the activity of adsorbed proteins is their conformation (i.e., how the conformation of the adsorbed protein resembles that of its native state). In this talk, the protein orientation and conformation on charged surfaces are investigated by a hierarchical approach, i.e., studied by colloidal, coarse-grained and all-atom models. It is found that the electric dipole and hydrophobic dipole of adsorbed proteins play important roles in determining the protein orientation on charged and hydrophobic surfaces. Page 117 Symposium 13-Thermodynamics and Transport Phenomena(C209) Yudan Zhu Thursday Oct.15, 11:00-11:30 AM C209, Yifu Building Yudan Zhu was born in China in 1982. She received her Ph.D. degree (2010) in Chemical Engineering at Nanjing Tech University (Used name: Nanjing University of Technology), then, she joined the group of professor Xiaohua LU. She currently is an associate professor in Chemical Engineering at Nanjing Tech University . Her main research interest focuses on nanoconfined fluid molecule behaviors using molecular simulation for nanoporous material applications. She is the project leader of two National Natural Science Foundations of P.R. China (Youth Program and General Program ) Molecular simulations on nanoconfined fluid molecule behaviors for nanoporous material applications Nanoporous materials (e.g. membranes and catalysts) applications have been increasingly applied in energy and environmental fields. Material performance is largely dependent on structure. Most applications of nanostructured materials involve fluids. The properties of bulk fluids are independent of their microstructure; hence, classical phase equilibrium and transfer mechanism based on the continuum model can be applied. However, a decrease in the molecule number of fluids confined within the nanostructure enhances the influence of material interfacial properties on fluid molecule behaviors. Thus, the properties of nanoconfined fluids are different from those of bulk fluids. The behaviors and microstructures of nanoconfined fluids are closely related, which make the continuum model frequently invalid at the nanoscale. To establish the structure–property relationship of nanoporous materials, not only the structures of materials themselves, but also the microstructures of nanoconfined fluids are required to be explored. Our group carried on a series molecular simulation studies of nanoconfined fluid molecules behavior for many years to understand what indeed we can learn from molecular simulations of nanoconfined fluid molecule behaviors and how these understandings could promote the nanoporous material applications. Theodore Tsotsis Thursday Oct.15, 8:30-9:10 AM C209, Yifu Building Theodore Tsotsis is Professor of Chemical Engineeringis and Holder of Robert E. Vivian Chair in Energy Resources. He is expert in high temperature reactions, with applications to landfill remediation and other environmental issues.He is also Consultant to ALCOA, UNOCAL and U.S. Department of Energy and Holds several patents on reaction engineering methods. Microporous Inorganic Membranes for Conventional and Reactive Separations Microporous inorganic membranes are attracting today substantial research interest due to their potential for finding widespread use in a number of high-temperature conventional and reactive separation applications of interest in the Energy field. In our group the emphasis has been on carbon molecular sieve and SiC membranes. The preparation and characterization of these materials presents significant technical challenges. Issues of membrane preparation, reproducibility, and robustness to the proposed application environments remain of significant importance. In this talk, we will describe the techniques that we utilize for the preparation and characterization of such microporous membranes. They involve a variety of surface analytical techniques, TGA, and various chromatographic and mass spectrometric techniques useful for characterizing the membrane structure, and its surface and bulk chemical composition. They are coupled to transport and sorption experimental investigations, and molecular simulations of such processes. Combining all these techniques helps to provide unique insight into the key factors that determine membrane properties and performance. The use of these membranes in important reactive separations will be also discussed. Page 118 Symposium 13-Thermodynamics and Transport Phenomena(C209) Tuesday Oct.13 Chair : Honglai Liu Afterno Title Name Affiliation S13-K1 Molecular Modeling, Screening, and Design of Metal-organic Frameworks for Gas Storage and Separation Applications Randall Snurr Northwester n University, USA S13- I1 Thermodynamic and Transport Properties of Porous Materials for Carbon Dioxide Separation Shuguang Deng New Mexico State University S13- I2 High-throughput Screening of Fluid Adsorption in Metal-organic Frameworks by Using a Classical Density Functional Theory Yu Liu East China University of Science and Technology S13-K2 From First Principles to Fluid Phase Equilibria Shiang-Tai Lin National Taiwan University S13-K3 Reaction and Diffusion on Supported Metal Nanocatalysts Jianguo Wang Zhejiang University of Technology S13-I3 A Novel Multiscale Strategy for Prediction of Phase Behaviors through Distribution of Molecular Conformations on 13:3014:10 14:1014:40 14:4015:10 15:10Coffee break 15:20 Chair : Glenn Lipscomb 15:2016:00 16:0016:40 16:40- 17:10 Li Yang Wuhan Institute of Technology Page 119 Symposium 13-Thermodynamics and Transport Phenomena(C209) Wednesday Oct.14 Chair : David Rumschitzki Morning 8:30-9:10 9:10-9:40 9:40-10:10 Title S13-K4 S13-I4 S13-I5 Structure-property Relationships and Physicochemistry of Ionic Liquids Investigation of Lower Critical Solution Temperature Transition of Poly Nvinylcaprolactam (PVCL) Monte Carlo Simulations of Phase Equilibria and Structural Properties of Thiophene/[Bmim][PF6]/CO2 Name Affiliation Chunshang Li Institute of Process Engineering, Chinese Academy Science Xianghong University of Qian Arkansas Yongping Zeng Yangzhou University Doraiswami Purdue Ramkrishna University 10:10Coffee break 10:20 Population Balance Modeling. A 10:2011:00 S13-K5 Ubiquitous Tool for Engineering Analysis Anomalous Structures and Vibrational 11:0011:30 S13-I6 Spectra of Ethylammonium Nitrate Ionic Jiangxi Zhen Yang Liquids in 1-nm Hydrophobic Normal University Nanochannel 11:3012:00 S13-I7 DFT Study of Molecules Adsorption and Reaction on Grapheme 12:0013:30 Page 120 Lunch (Youyi Restaurant) Yingchun Liu Zhejiang University Symposium 13-Thermodynamics and Transport Phenomena(C209) Chair : Randall Snurr Afternoo Title Name Affiliation n Beijing Multiscale Simulation Designed 13:3014:10 S13-K6 Synthesis of Nanostructured Porous University Dapeng Cao Materials in Chemical Engineering of Chemical Technology Equilibrium and Dynamic Properties of 14:1014:40 Thermodynamically Small Clusters: S13- I8 Views at Both Atomistic and Colloidal University of David Ford Massachuse tts Amherst Scales Blood Pressure-driven Trans-artery Wall 14:4015:10 S13-I9 Water Flow and Early Atherosclerosis: The Role of A Membrane Protein David Rumschitzki City College of New York 15:10Coffee break 15:20 Chair : Jianguo Wang Unified Framework of Multi-scale 15:2016:00 S13-K7 Density Functional Theories and Its Recent Applications East China Shuangliang University of Science Zhao and Technology The Interaction Between Nanoparticles 16:0016:30 S13-I10 Drug Delivery Review on Modified Poisson- 16:3017:00 and Membranes: From Cytotoxicity to S13-I11 Boltzmann (MPB) and Its Recent Applications Xianren Zhang Manman Ma Beijing University of Chemical Technology Shanghai Jiaotong University Page 121 Symposium 13-Thermodynamics and Transport Phenomena(C209) Thursday Oct.15 Chair : Guangjin Chen Morning Title Thermodynamics of Deformation and 8:30-9:10 S13-K8 Phase Transformations in Nanoporous Adsorbents 9:10-9:40 S13-I12 Poroviscoelasticity in protein hydrogels S13-I13 Large-scale molecular dynamics simulation and online measurement of thermal conductivity of bulk silicon and silicon nanowires 9:4010:10 Name Affiliation Alexander Rutgers Neimark University Ruben Mercade Prieto Soochow University Chaofeng Hou Institute of Process Engineering, CAS 10:10Coffee break 10:20 Chair : Alexander Neimark 10:2011:00 S13-K9 S13-K10 Fluid Molecule Behaviors for Effective Gas Separation Using S13-I14 Membranes Based on Metal-organic Frameworks 12:0013:30 Page 122 Lunch (Youyi Restaurant) South China University of Technolog y Nanjing Yudan Zhu Nanoporous Material Applications 11:3012:00 Jian Zhou Molecular Simulations on Nanoconfined 11:0011:30 Multiscale Simulations of Protein Adsorption Technology University Dahuan Liu Beijing University of Chemical Technology Symposium 13-Thermodynamics and Transport Phenomena(C209) Chair : Dapeng Cao Afternoon Title Name Affiliation China 13:3014:10 S13-K11 Natural Gas Hydrate and Carbon Guangjin Univerisity Dioxide Chen of Petroleum, Beijing 14:1014:40 S13-I15 CO2 Capture on Amine-Functionalized Polymer Hollow Fiber Sorbents in Rapid Temperature Swing Adsorption Fateme Rezaei Modeling and Simulation of CO2 Chunyan Capture from Biogas using aqueous Ma Missouri University of Science and Technology Nanjing 14:4015:10 S13-I16 Technology University 15:10Coffee break 15:20 Chair : Shuguang Deng 15:2016:00 S13-K12 16:0016:30 S13-I17 Microporous Inorganic Membranes for Theodore Conventional and Reactive Separations Tsotsis Dynamics Study of Methane Dissociation on Ni (111) Surface Prediction of Liquid-Liquid Equilibrium 16:3017:00 for Ternary Solutions Based on the S13-I18 COSMO-SAC and the Ising Lattice Xiangjian Shen University of Southern California Institute of Chemical Physics of Dalian East China YongUniversity of Ming WEI Science and Technology Model Note: S ~ Symposium K~ Keynote I~ Invited talk Page 123 Symposium 14- Separation Technology (M106, No. 16 Building) Symposium 14- Separation Technology Chairs: Suojiang Zhang, [email protected]; Hualin Wang, [email protected]; Kamalesh K. Sirkar, [email protected]; Ralph Yang, [email protected]. Featured Speakers William Koros Tuesday Oct.13, 13:30-14:10 PM M106, No. 16 Building William J. Koros is the GRA Eminent Scholar in Membranes and the Roberto C. Goizueta Chair for Excellence in Chemical Engineering at Georgia Institute of Technology. Professor Koros received his Bachelor's degree in Chemical Engineering from The University of Texas in 1969 and worked in the Engineering Department of the E. I. DuPont Company for the next four years. He entered graduate school in 1973 and upon completion of his studies in 1977 joined the faculty of the Chemical Engineering Department at the North Carolina State University as an Assistant Professor. Diffusion Entropic Activation Factors: Maxwell’s Demons at Work Chemical Engineering separation research has a long history with connections to the thermodynamic and transport phenomena pioneers in our discipline. Advanced materials have become increasingly important as vehicles explore separation options, with increasing attention being paid to energy efficiency and process carbon footprints. Gas separations are highly energy-intensive processes when based upon a traditional phase-change paradigm such as distillation or sorption processes. Membranes avoid this paradigm by integrating molecularly selective partitioning and diffusive discrimination between components into a single device. This integrative ability can change the separations landscape by offering a full order of magnitude lower energy-intensity compared to phase-change separation approaches. The selective partitioning feature is understandable in terms of well-known thermodynamic factors. On the other hand, engineering diffusion selectivity usually relies upon tuning relative diffusion activation energies of permeating species within the membrane. Unfortunately, higher relative diffusion activation energies between similar penetrants are correlated with higher absolute diffusion activation energies for both components. This correlation creates a natural tradeoff in which dramatically lower permeabilities are typically seen for highly selective membranes. A new approach, tuning the diffusion activation entropy associated with size-similar penetrants can avoid major productivity losses if done properly. Page 124 Symposium 14- Separation Technology (M106, No. 16 Building) Jerry Lin Wednesday Oct.14, 10:20-11:00 PM M106, No. 16 Building Dr. Jerry Y.S. Lin is a Regents‘ Professor at the Arizona State University in Tempe. He also serves as editor of Journal of Membrane Science. Dr. Lin was a professor of chemical engineering and co-director of the NSF Center for Membrane Applied Science and Technology at University of Cincinnati prior to joining ASU in January, 2005. Dr. Lin received B.S. (1982) from Zhejiang University in China, and M.S. (1985) and Ph.D (1988) from Worcester Polytechnic Institute in the U.S., all in chemical engineering. In research, Dr. Lin has made significant contributions to the advancement of inorganic membrane science and high temperature gas separation technologies. As of January, 2015 he has published over 255 refereed papers in chemical engineering and materials science SCI journals, 10 book chapters and 50 conference proceedings papers; he also holds 8 patents; his papers have received over 8400 SCI citations (with H-index over 51) . Carbon Dioxide Permeation Properties of Samarium-Doped-Ceria Carbonatedual-phase membranes High temperature CO2 perm-selective membranes can be used in a number of important separation and reaction processes for hydrogen production or carbon capture. Oxygen ionic conducting metal oxide and molten carbonate dual-phase membranes are the only membranes perm-selective to CO2 at high temperatures with selectivity as high as 3000. This talk will discuss high temperature CO2 permeation properties of samarium doped ceria (SDC)-carbonate dual-phase membranes. Hermetic SDC-carbonate membranes were prepared by infiltrating porous SDC ceramic support with Li/K/Na molten carbonate. CO2 permeation/separation data for the SDC-carbonate membranes were then obtained with either atmospheric or high pressure feed of CO2:N2 mixture or simulated syngas with composition of 50% CO, 35% CO2, 10% H2, and 5% N2. The SDC-carbonate membranes exhibit CO2 permeation flux in the range of 0.2-0.8 mL(STP).cm-2.min-1 in 700-950oC with measured CO2 to N2 separation factor above 1000. CO2 permeation data through the SDC-carbonate membranes at different upstream and downstream CO2 partial pressures were obtained. Page 126 Symposium 14- Separation Technology (M106, No. 16 Building) Xiangchen Fang Tuesday Oct.13, 15:20-16:00 PM M106, No. 16 Building Dr. Xiangchen Fang received his phD degree on Chemical Engineering from East China University of Science and Technology in 2005. He is now work as the director in Fushun petroleum research institute, SINOPEC and part-time professor of school of chemical engineering in ECUST. His research interest focus on the catalysis process and system fabrication on petroleum refinery, especially the hydrogenation reforming, hydrogenation treatment and hydrogenation pyrolysis. He was listed as the co-author of over 30 research paper and inventor of over 120 invention patent. He was also the owner of various academic and industrial honor, including He Leung He Lee Foundation Award, National Technical Invention Award, CAS Outstanding contribution award, Sinopec Outstanding contribution award, Science Talent in Liaoning Province etc. Several points on gas-liquid-solid separation for ebullated bed resid hydrocracking Resid hydrocracking has been attract more and more attention by the refining industry for this decades, and one of the best approach is the ebullated bed resid hydrocracking (EBRH). STRONG ebullated bed resid hydrocracking uses a new type of ebullated bed reactor, and a 50,000Tons/Year demonstration unit has been putting on operation now. The crucial technology of STRONG is the gas-liquid-solid separation efficiently in the reactor. Several points on gasliquid-solid separation for the resid hydrocracking reactor has to be specially mentioned: 1. the mass transfer in the system is very important, especially the gas-liquid mass transfer and liquid diffusion in catalyst particle pores. In order to overcome the mass transfer difficulties, increase the gas hold-up ratio, decrease the gas bubble size and catalyst particle size are preferred, but the problem of gas-liquid-solid separation will be enlarged quickly. 2. controlling the system flow pattern is another important point, how to meet the needs for fully back mixing flow while does not causing large size vortex flow, how to avoid the gas bubble quickly coalescence to become large bubbles, how to maintain the three phase distributed in the reactor an even as possible, and so on. 3. the resid hydrocracking is a sensitive process for the reactor system coking block up, especially in the phase separation system. The three phase separator of STONG ebullated bed resid hydrocracking has solved the above problem satisfactorily, and will described in this paper in detail. Weiqiao Deng Wednesday Oct.14, 10:20-11:00AM M106, No16. Building Dr. Weiqiao Deng is the group leader of 1109 at Dalian Institute of Chemical Physics. He has published more than 80 publications including Nature Comm. J. Am. Chem. Soc., Angew. Chemie. Int. Ed., Energy Env. Sci., Nano Lett., Phys. Rev. Lett. etc with citations more than 2000 times. Deng’s research is about materials simulation and design, which includes the multi-scaled computational simulation to screen and design novel materials with desired properties and synthesis of the designed materials accordingly. Conjugated microporous polymer for water purification Resid Oils, organic solvents, dyes, and heavy metal ions are primary pollutants in water resources. Currently, no sorbent material can effectively remove these types of pollutants simultaneously. Here we report a perfluorous conjugated microporous polymer with superhydrophobicity and a large surface area, which exhibits outstanding adsorption capacities, kinetics, and recyclability for a wide range of organic solvents, oils, dyes, and heavy metal ions. The adsorption capacities of this polymer, 1376.7 mg g-1 for Congo red, 808.2 mg g-1 for Pb(II) and 303.2 mg g-1 for As(V), are higher than the adsorption capacities of any previously described porous materials. Our theoretical calculation reveals that the superior properties of this polymer are due to fluorination and triple bonds within the polymer. A benchmark experiment indicates that this polymer can efficiently remove these pollutants simultaneously. Application of this polymer may lead to the development of next-generation reusable and portable water purification appliances. Symposium 14- Separation Technology (M106, No. 16 Building) ) Xuefeng Zhu Tuesday Oct.15, 15:20-16:00 PM M106, No. 16 Building Dr. Xuefeng Zhu got his Bachelor degree from the chemistry college of the Beijing Normal University in 2001 and PhD from the Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences in 2007. He went to the Jerry Lin group in Arizona State University and carried out a project from DOE on zeolite membrane for hydrogen separation (2008). After that he came back to DICP and then was appointed as an associate professor (2009) and full professor (2014) of the State Key Laboratory of Catalysis (SKLC). He has published more than 50 scientific papers, contributed to 2 book chapters and holds more than 10 patents. Mixed oxygen ionic-electronic conducting perovkite membrane reactors for H2 separation Mixed oxygen ionic-electronic conducting membrane was used as catalytic membrane reactor for hydrogen separation to acquire high-purity hydrogen from steam and low-purity hydrogen. One side of the membrane is exposed to steam atmosphere where water splits into hydrogen and oxygen ions at high temperature, and the other side of the membrane is swept by low-purity hydrogen to react with the oxygen ions permeated from the opposite side. Theoretically, hydrogen of 100 % purity can be obtained from steam side after cooling and drying. With 80% H2/He balance as feeding gas, the hydrogen separation rate of a 0.5-mm-thick BaCe0.05Fe0.95O3-δ membrane increased from 2.0 to 9.6 mL cm-2 min-1 as the operation temperature was raised from 700 to 900 °C, which were two orders higher than those of the mixed protonic-electronic conducting membranes at the same conditions. Winston Ho Thursday Oct.15, 8:30-9:10 AM M106, No. 16 Building Winston Ho is Distinguished Professor of Eng, Chemical & Biomolecular Eng in the Ohio State University. He was elected member of Academia Sinica, the highest form of academic recognition in the Republic of China in Taiwan, 2015. New Scale-up Membranes for CO2 Capture and Separation This presentation covers new scale-up carbon dioxide-selective membranes for (1) hydrogen purification for fuel cells and (2) carbon capture from flue gas. We have synthesized carbon dioxideselective membranes by incorporating amino groups into polymer networks. The membranes have shown high carbon dioxide permeability and selectivity vs. hydrogen, carbon monoxide and nitrogen. The membranes were scaled up to fabricate 14-inch wide membranes by using a continuous roll-to-roll machine equipped with a thin-film-coating assembly. Aided by a material balance equation, three variables, including the coating knife gap setting, substrate rolling speed, and coating solution concentration, were identified as the critical factors to control the membrane selective layer thickness. For the CO2 separation from a synthesis gas stream containing CO2 and H2S, i.e., pre-combustion CO2 capture in IGCC (integrated gasification combined cycle) technology or hydrogen purification for fuel cells, the thicker amine-containing membranes with around 15 ± 2 microns of selective layer thicknesses were fabricated by using a gap setting of 17 mils, a rolling speed of 0.5 ft/min (set by the drying capacity of the drier, i.e., its length), and an amine coating solution of 18 wt% solid concentration. For the post-combustion CO2 capture from flue gas, the same thin-film-coating assembly machine was used to fabricate thinner amine containing membranes with < 250 ± 20 nm of selective layer thicknesses by using various rolling speeds and amine-containing solution concentrations at a fixed gap setting of 0.45 mils. Page 127 Symposium 14- Separation Technology (M106, No. 16 Building) ) Wednesday Oct.14 , 10:20-11:00 AM Junhua Li M106, No. 16 Building Dr. Junhua Li received his Ph.D. degree major in Nuclear Fuel Cycle and Material from China Institute of Atomic Energy in July 2001. After a post-doctral period in School of Environment, Tsinghua University from 2002-2003, he was selected as the Associate professor of School of Environment in Tsinghua University. He was prompted to full professor from 2007 and become an excellent talent on Environmental Science of NSF China in 2013. He has once been a visiting professor at University of Michigan and University of Sydney, respectively. His research interests including Environmental Catalysis and Adsorbent Materials and Air Pollution Chemistry and Control Technology. He was listed as the co-author of over 50 peered reviewed research paper, most of which were published on high-ranking reseach journals, including Environ. Sci. Technol., Appl. Catal. B: Environ. and J. Phy. Chem. etc. Progress on removal NOx and VOCs by environmental catalysis In this work, a series of MnO2 with various structures were prepared, and their catalytic activities were evaluated for reduction of NOx and oxidation of VOCs. The preparation method affects the structure of Mn-based catalyst, and the dispersion of active sites depends on concentration of the precursor solution, and the final procedure of drying. Tunneled alpha-MnO2 had much higher catalytic activity than other MnO2 under the same reaction conditions. Experiment results revealed that the surface area was not the main factor to affect the NH3-SCR activities over the MnO2 nanorods and that the activities were structure sensitive. The crystal structure and surface properties of alpha-MnO2 are more suitable to the adsorption of NH3 and activation of NH3 and NOx, which accounts for the higher catalytic activity of the alpha-MnO2 nanorods. 1D-MnO2, 2D-MnO2 and 3D-MnO2 with different structures were successfully synthesized. The decrease order of the activity of ethanol oxidation on different MnO2 catalysts is 3D-MnO2 > 2D-MnO2 > 1D-MnO2, which is consistent with the sequences of some factors such as surface areas, Mn4+ cations species, surface active oxygen species and reducibility. 3D-MnO2 has the best catalytic property of ethanol oxidation due to the special 3D pore channel structure, larger specific surface area, better low-temperature reducibility, more abundant active surface oxygen species and sufficient active Mn4+ cationic species. Daming Wang Thursday Oct.15, 13:30-14:10 PM M106, No. 16 Building Daming Wang is the Professor and Chairman of Department of Chemical Engineering in National Taiwan University. He obtained his B.S. in Chemical Engineering from National Taiwan University and Ph.D. in Chemical Engineering from Pennsylvania State University.Prof. Wang has been working in membrane separation technology, molecular simulation and tissue engineering. In 2005, he was bestowed Outstanding Teaching Award of the NTU. He is editorial board of Journal of Applied Membrane Science and Technology, Chinese Institute of Chemical Engineers and Journal of Chemical Engineering of Japan, Scientific Committee Member of Aseanian Membrane Society, Scientific Committee Member of Aseanian Membrane Society. Formation of pores in polymeric membranes --a thermodynamically or kinetically controlled process It is well known that the thermodynamic stability of casting solution plays an important role in phase separation and the formation of membrane pores. However, phase separation may need time to occur, which makes kinetics also important. For example, phase separation via the mechanism of nucleation and growth may not occur if there is not enough time for the nuclei to form; similarly, a polymer solution with a composition in the crystallization region (can crystallize thermodynamically) may not crystallize if not enough time is given for the crystalline nuclei to occur. Therefore, kinetic factors influencing the time given for the nuclei to occur and the rate of nuclei forming can also play important roles in the formation of membrane pores. We will show how the mass transport during membrane formation and the entanglement of polymer chains are important kinetic factors in controlling membrane morphology. Insight into these kinetic factors is important in understanding the formation of membrane pores. Page 128 Symposium 14- Separation Technology (M106, No. 16 Building) Tuesday Oct.13 (M106, No. 16 Building) Chair : Suojiang ZHANG Afternoon Title Name Affiliation 13:30- S14-K1 Diffusion Entropic Activation Factors: Maxwell’s Demons at Work William Koros Georgia Institute of Technology S14- I1 Ionic Liquid Solvent Design for Extraction Processes Based on Molecular Group Descriptor and Multiscale Simulations Zhiwen Qi East China University of Science and Technology S14- I2 Lattice Boltzmann simulation of mixing process inside micro-droplet Yi Cheng 14:10 14:1014:40 14:4015:10 15:10- Tsinghua University Coffee break 15:20 15:2016:00 S14-K2 Several points on gas-liquid-solid separation for ebullated bed resid hydrocracking S14-I3 Mixed-linker zeolitic imidazolate framework (ZIF) materials and scalable membrane processing on polymeric hollow fibers S14-I4 Responsive Hydrophobic Interaction Membrane Chromatography 16:0016:30 16:3017:00 Xiang chen Fang Fushun Research Institute of Petroleum and Petrochemical s, SINOPEC Nair Georgia Institute of Technology Xiang hong Qian University of Arkansas Sankar Wednesday Oct.14 (M106, No. 16 Building) Chair :Ralph T. YANG Morning Title Name Affiliation 8:30-9:10 S14-K3 Carbon dioxide permeation properties of samarium-doped-ceria carbonate dualphase membranes Jerry Lin Arizona State University S14-I5 Density Functional Theory Study on the Electrophoresis Separation of Charged Particles Yangxin Yu Tsing Hua University 9:10-9:40 Page 129 Symposium 14- Separation Technology (M203) 9:40-10:10 Xiaohua Ma King Abdullah University of Science and Technology S14-K4 Conjugated microporous polymer for water purification Weiqiao Deng Dalian Institute of Chemical Physics S14-I7 Optimization of staged configurations for membrane-based CO2 capture Glenn Lipscomb University of Research and Applications of Baosteel's BSSF Process for Molten Steelmaking Slag Treatment Yongli Xiao Baosteel Research Institute S14-I6 Novel Microporous Polyimide Membrane Derived from a Spirobifluorene-Based Dianhydride for Gas Separation Applications 10:10Coffee break 10:20 10:20- 11:00 11:0011:30 11:30- S14-I8 12:00 12:00- Toledo Lunch (Youyi Restaurant) 13:30 Chair : Hualin WANG Afternoon Title Name Affiliation 13:30S14-K5 Ionic liquid-based materials as electrolytes Shimo Chen Institute of Process Engineering S14- I9 Treating Poultry Processing Wastewaters by Ultrafiltration Sumith Wickrama singhe University of Arkansas S14-I10 Preparation of PVA composite catalytic membrane and the intensification of esterification reaction Weidong Zhang Beijing University of Chemical Technology 14:10 14:1014:40 14:4015:10 15:10- Coffee break 15:20 15:2016:00 16:0016:30 16:3017:00 Page 130 S14-K6 Mixed oxygen ionic-electronic conducting perovkite membrane reactors for H2 separation S14-I11 A Rotating Carbon Nanotube Membrane Filter for Water Desalination S14-I12 Continuous Production of Polymer Coated Drug Crystals, Particles and Nanoparticles by Cooling and Antisolvent Crystallization Dalian Xuefeng Institute of Zhu Chemical Physics University of Shaofan Li CaliforniaBerkeley Kamalesh Sirkar New Jersey Institute of Technology Symposium 14- Separation Technology (M106, No. 16 Building) Thursday Oct.15 (M106, No. 16 Building) Chair : Kamalesh K. SIRKAR Morning 8:30-9:10 9:10-9:40 9:40-10:10 Title Name S14-K7 Progress on removal NOx and VOCs by environmental catalysis Junhua Li S14-I13 High-performance multilayer composite membranes with polydopamine as a versatile molecular bridge for CO2 separation Zhi Wang S14-I14 Novel Liquid-like Nanoparticle Organic Hybrid Materials (NOHMs) for Carbon Capture and Conversion Ah-Hyung (Alissa) Park 10:10- 11:00 11:0011:30 11:3012:00 Tsing Hua University Tianjin University Columbia University Coffee break 10:20 10:20- Affiliation New Scale-up Membranes for CO2 Winston Capture and Separation Ho S14-I15 Nanoengineered Coalescence Separation of Water-in-oil and Oil-in-water Emulsions Chuan fang Yang S14-I16 The micromixing performance of a micro-impinging stream mixer and its extraction applications S14-K8 12:00- Lixiong Wen The Ohio State University Institute of Process Engineering Beijing University of Chemical Technology Lunch (Youyi Restaurant) 13:30 Chair :Suojiang ZHANG Afternoon 13:30- Title S14-K9 14:10 14:1014:40 14:4015:10 S14-I17 S14-I18 Formation of pores in polymeric membranes --a thermodynamically or kinetically controlled process Elevated pervaporation performance of polysiloxane membrane using metal organic framework CuBTC Numerical simulation of mechanical property of plant cell during ultrahigh pressure extraction process Name Affiliation Daming Wang National Taiwan University Zhongyi Jiang Jun Xi Tianjin University Sichuan University Page 131 Symposium 14- Separation Technology (M106, No. 16 Building) 15:10- Coffee break 15:20 15:20- S14-I19 Dynamic interactions of small molecules with KCNQ2 channels Huaiyu Yang S14-I20 Simulation research on the thermally coupled reactive distillation in the biodiesel production Lanyi Sun 15:50 15:5016:20 Note: S ~ Symposium K~ Keynote I~ Invited talk Page 132 Shanghai Institue of Materia Medica China University of Petroleum Symposium 15- Forum of Chemical Engineering Department Deans and Chairs (M103) Symposium 15- Forum of Chemical Engineering Department Deans and Chairs Chairs: Shan-Tung Tu, [email protected]; Bogeng Li, [email protected] Linda Broadbelt, [email protected]; William Koros, [email protected] Featured Speakers Mark Barteau Thursday Oct.15, 8:30-9:10 AM M103, Yifu Building Mark Barteau is the Director of Energy Institute; DTE Energy Professor of Advanced Energy Research; and the Professor of Chemical Engineering. His researches are mainly about Design of catalysts and nanomaterials to improve efficiency and sustainability of chemicals and fuels production and strategies for utilization of renewable resources. Lessons from a (half) career in academic leadership It is almost a truism that junior faculty are often thrown into the classroom with little formal preparation in teaching. It is also the case that those taking on positions of academic leadership at the department chair and similar levels receive little preparation for their new responsibilities. The author has served in a variety of academic leadership positions, from center and institute director, to department chair, to university central administration, and will share experiences and thoughts about the lessons learned along the way. Wenjun Wang Thursday Oct.15, 10:20-11:00 AM M103, Yifu Building Wenjun Wang is the Professor of Department of Chemical and biochemical Engineering in Zhejiang University, 2010.12-present. And a Visiting Professor of Department of Chemical Engineering in McMaster University, 2010.11-present. His research areas includes functional fine polymer product engineering, olefin polymerization and functionalization and polymeric materials and interface engineering. Globalization Initiatives in Chemical Engineering Education at Zhejiang University Adapting to the rapid globalization of post-secondary education is a great challenge for engineering programs in China, but the removal of boundaries separating educational institutions also provides significant opportunities. Increasing international collaborations and the global flow of research talent allows institutions to enhance their exposure and influence, and recalibrate both their undergraduate and graduate engineering education. Zhejiang University (ZJU) is strongly committed to maintaining its reputation as a top tier chemical engineering program both nationally and internationally. To achieve this objective, ZJU has enacted several outreach approaches to facilitate interactions with some of the best engineering institutions, educators, and researchers in the world. In this presentation, an update on these efforts is provided. This will include a review of our most promising initiatives such as (1) design of programs facilitating formation of long-term collaborations with internationally recognized institutions; (2) participation in major international meetings and conferences through presentations and the hosting of receptions; (3) arrangement of lectures, special courses, and long-term visits from international scholars; and (4) development of summer research exchange programs, which facilitates the placements of ZJU students at various universities around the world and supports the visit of international students. Page 133 Symposium 15- Forum of Chemical Engineering Department Deans and Chairs (M103) Thursday Oct.15 (M103) Chair : Shan-Tung Tu, Bogeng Li, Linda Broadbelt, William Koros Morning Title Name Affiliation S15-K1 Lessons from a (half) career in academic leadership Mark Barteau University of Michigan Energy Institute 9:10-9:40 S15- I1 Reform and Practice of Chinese Higher Education in Chemical Engineering (O0394) Xuhong Guo ECUST 9:40-10:10 S15- I2 The evolving role of assessment in chemical engineering education (O0313) Glenn Lipscomb University of Toledo Wen-Jun Wang Zhejiang University MarcOlivier Coppens University College London Department of Chemical Engineering 8:30-9:10 10:10Coffee break 10:20 10:2011:00 11:0011:30 S15-K2 S15-I3 Globalization Initiatives in Chemical Engineering Education at Zhejiang University (O0470) A World of Opportunities for Chemical Engineering (O0193) 12:0013:30 Lunch (Youyi Restaurant) Note: S ~ Symposium K~ Keynote I~ Invited talk Page 134 Posters The size for the poster should not be bigger than 900 mm (W) x1200 mm (L). Poster boards will be numbered. Presenters should attach their posters to the board number corresponding to the number assigned to their posters in the final program. The Best Student Poster Awards will be given to the winners at the 8th Sino-US ChE conference. Poster Presentation, Wednesday Oct.14, 2015 S1--Air S2--Bio P001 P006 Electrochemical NO2 Sensor based on Gd1xCaxAlO3-δ using NiO sensing electrode (A0256) Synergistic Effect of Epigallocatechin-3-Gallate and Polymeric Nanoparticle in Inhibition and Detoxification of Amyloid β-Protein Fibrillation (B0043) Dongmei Wang, Yuanyuan Ding, Chufan Zhang, Xu Zhang, Fulan Zhong, Yihong Xiao (Fuzhou University) Hongchen Liu, Xiaoyan Dong, Yan Sun (Tianjin University) P002 P007 Study on the Oxidation of Formaldehyde over various dimensional Co-based Catalysts (A0465) Enhanced Inhibition Effect of Acidulated Serum Albumin on Zn2+-Mediated Amyloid β-Protein Fibrillogenesis and Cytotoxicity (B0051) Bingyang Bai, Zichen Li (Chinese Research Academy of Environmental Sciences) Baolong Xie, Xiaoyan Dong, Yongjian Wang, Yan Sun (Tianjin University) P003 P008 Experimental study on Combination of Wood fiber with Catalyst for Improving Capacity of Nonthermal Plasma Treating Automobile Exhaust (A0578) Tailored Cell Morphology of Polylactide Foams by Controlling Its Crystallization during Foaming (B0070) Wenli Zhu (Hubei University of Arts and Science) Xiurong Guo, Yinghui Wang, Danfeng Du (Northeast Forestry University ) S2--Bio P004 P009 Fast aggregation kinetics of amyloid β-protein in the presence of zinc ions (B0041) High-yield Synthesis of Stain Precursor with a New Aldehyde-Tolerant Aldolase (B0091) Jingjing Guo, Linling Yu, Yan Sun, Xiaoyan Dong (Tianjin University) Xuecheng Jiao, Huilei Yu, Jianhe Xu (East China University of Science and Technology) P005 P010 Hematoxylin Inhibits Amyloid β-Protein Aggregation and Cytotoxicity (B0042) Switching a thermostable lactonase into an efficient phosphotriesterase by simple double mutations (B0107) Yilong Tu, Fufeng Liu, Yan Sun, Xiaoyan Dong (Tianjin University ) Xiao-Jing Luo, Jiahai Zhou, Jian Zhao, Xu-Dong Kong, Qi Chen, Jian-He Xu (East China University of Science and Technology) Page 135 Poster Presentation, Wednesday Oct.14, 2015 S2--Bio S2--Bio P011 P016 (B0117) Modeling isotopic fractions of intercellular metabolic pools in isotope experiments with isotopomer decomposition units (B0208) Weilu Lin, Mingzhi Huang, Yingping Zhuang, Siliang Zhang (East China University of Science Technology) P012 P017 Highly efficient and enantioselective biosynthesis of (R)-2-chloro-1-(2,4dichlorophenyl)ethanol with a reductase SsCR from Scheffersomyces stipites CBS 6045 (B0123) Modular optimization of multi-gene pathways for fumarate production (B0209) Xiulai Chen, Liming Liu (Jiangnan University) Yuepeng Shang, Huilei Yu, Jianhe Xu (East China University of Science and Technology) P013 P018 Cold Plasma at Atmospheric Pressure as A Novel Approach to Regulate Cell Membrane Permeability for Formation of ATP and NADH in Saccharomyces cerevisiae (B0168) Non-sterilized production of ethanol or L-Lactic Acid from waste substrate by Metabolic Directing of Thermoanaerobacterium (B0219) Xiaoyu Dong (Dalian University) Shuang Li , Muzi Zhu , Xiaofeng Yang (South China University of Technology) P014 P019 pH optimization of oil recovery bacteria strain (B0169) DNA assembler method for construction of omega-6 arachidonic acid producing strain of Yarrowia lipolytica (B0259) Chunyan Chen , Sihua Long (Southwest Petroleum University) Huhu Liu, Catherine Madzak, Xiao-Jun Ji, He Huang (Nanjing Tech University) P015 P020 Semi-rational design the enantioselectivity of lipase aided by molecular docking (B0196) Comparison of the Behavior of High-silica Zeolite and ZIF-8 for 1-Butanol Adsorption and Separations from ABE Model Solution (B0262) Hongjiang Wang, Bin Yang, Xiulai Chen, Liming Liu (Jiangnan University) Page 136 Chunping Gao, Qi Shi, Jinxiang Dong (Taiyuan University of Technology) Poster Presentation, Wednesday Oct.14, 2015 S2--Bio S2--Bio P021 P026 A de novo NADPH generation pathway for improving xylitol production in Escherichia coli (B0283) On structural identifiability analysis of the cascaded linear dynamic systems in transient isotope experiments (B0443) Buli Su, Mianbin Wu, Jianping Lin (Zhejiang University) Weilu Lin, Mingzhi Huang, Yingping Zhuang, Siliang Zhang (East China University of Science Technology) P022 P027 Foaming simulation in ethanol fermentation of high solids lignocellulose feedstock (B0308) Performance of different strains of Clostridium thermocellum and Clostridium thermosaccharolyticum in production of Hydrogen and VFA (B0460) Weiliang Hou, Jian Zhang, Jie Bao (East China University of Science and Technology) Md. Saiful Islam, Chen Zhang, Chunzhao Liu (Institute of Process Engineering, Chinese Academy of Sciences) P023 P028 Biocompatible hydrogels support in vitro cell survival (B0335) Vanillic acid treatment enhances Trametes versicolor laccase production (B0480) Jing Yang, Yingnan Zhu, Lei Zhang (Tianjin University) Kefeng Wang, Chunzhao Liu (Institute of Process Engineering, Chinese Academy of Sciences) P024 P029 Inhibitory effects of ammonia on methanogen mcrA transcripts in anaerobic digester sludge (B0423) Performance of different strains of Clostridium thermocellum and Clostridium thermosaccharolyticum in production of Hydrogen and VFA (B0500) Chen Zhang, Quan Yuan, Yahai Lu (China Agricultural University) Chunzhao Liu (Institute of Process Engineering, Chinese Academy of Sciences) P025 P030 Effect of two different vectors on expression and purification of CotA laccase (B0440) Cellulosic ethanol production using Trichoderma reesei mutant with enhanced cellulase activity and integrated cellulase production, saccharification and ethanol fermentation (B0560) Nadia A. Samak, Chunzhao Liu (Institute of Process Engineering, Chinese Academy of Sciences) Yonghao Li, Cheng Cheng, Liang Xiong, Xinqing Zhao, Fengwu Bai (Dalian University of Technology) Page 137 Poster Presentation, Wednesday Oct.14, 2015 S2--Bio S3--Cat P031 P036 Enhanced stress tolerance of Saccharomyces cerevisiae by overexpression of genes involved in amino acid metabolism (B0561) Water vs. Ethanol: Effects of impregnation solvent on Ni/SBA-15 catalyst for CO methanation reaction (C0026) Mingming Zhang, Keyu Zhang, Qingqing Wan, Xinqing Zhao, Fengwu Bai (Dalian University of Technology) Miao Tao, Zhong Xin (East China University of Science and Technology) P032 P037 Separated hydrolysis and ethanol production from Jerusalem artichoke stalk (JAS) with high solid loading (B0581) Kinetic study on hydrogen evolution from decalin over Pt catalysts supported on carbon nanofibers with different microstructures (C0029) Liang Xiong, Ruiqi Tang, Yonghao Li, Xinqing Zhao, Fengwu (Dalian University of Technology) Yongxiao Tuo, Xing Li, Hao Jiang, Xuezhi Duan, Xinhai Yu, Ping Li (East China University of Science and Technology) P033 P038 Moderate high fermentation temperature improves xylose consumption of recombinant Saccharomyces cerevisiae (B0584) Simultaneous catalytic conversion of H2S and CO2 into valuable products (C0030) Liang Xiong, Xinshui Yu, Cheng Cheng, Xinqing Zhao, Fengwu Bai (Dalian University of Technology) Hui Su , Yuyang Li, Ping Li, Xuezhi Duan, Zhizhi Zhang, Xiangchen Fang (East China University of Science and Technology) P034 P039 Construction of efficient recombinant Saccharomyces cerevisiae strain for simultaneous saccharification and cellulosic ethanol production from Jerusalem artichoke stalk (B0585) Platform of on-site oxidants generation (C0047) Zijun Xia, Yida Xu, Xing Zhang, Lei Cao (GE Global Research) Cheng Cheng, Liang Xiong, Xinqing Zhao, Fengwu Bai(Dalian University of Technology) P035 S3--Cat Effect of MoO3 on catalytic performance and stability of the SBA-16 supported Ni-catalyst for CO methanation (C0025) Zhicheng Bian, Zhong Xin (East China University of Science and Technology) Page 138 P040 Reasearch on Reactive Distillation of Aldol Comdensation of Acetaldehyade (C0068) Yanhui Wu, Xiangbin Kong, Zelei Liang, Gaosheng Wu (Tongji University) Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S3--Cat P041 P046 Steam reforming of dimethyl ether over a novel anodized γ-Al2O3/Al monolith supported Cubased bi-functional catalyst (C0077) Rational design the enantioselectivity of lipase aided by molecular docking and Molecular Dynamics (C0196) Feiyue Fan, Qi Zhang, Xing Wang, Zibin Zhu (East China University of Science and Technology) Hongjiang Wang (Jiangnan University) P042 P047 Bimodal Comb Block Polyolefins by Serial Reactors (C0102) Controllable Synthesis of Silica Hollow Microspheres with Size-tunable Penetrating Macroporous Shells and their Application in NBR Hydrogenation (C0206) Andy Tsou (ExxonMobil Chemical Company) Pei Yuan, Jian Wang (China University of Petroleum(Beijing)) P043 P048 Selective Hydrogenation of Succinic Acid by Regenerable Atomically Dispersed Pd on zirconia (C0127) New insights into the function of potassium carbonate species and the superiority of base metals to noble metals in the polytitanate nanobelt supported LNT catalysts (C0234) Chi Zhang, Lifang Chen, Zhiwen Qi (East China University of Science Technology) Yuxia Zhang, Ming Meng (Tianjin University) P044 P049 Direct production of high octane gasoline by LCO Hydrocracking (C0156) Catalytic Cracking Performance of Daliya VGO and Penglai VGO (C0239) Chong Peng, Xiangchen Fang, Ronghui Zeng, Zhenmin Cheng (East China University of Science and Technology) Xin Zhao, Qingxiang You, Haiyan Liu, Rui Zhang, Xianghai Meng (China University of Petroleum (Beijing)) P045 P050 Identifying active sites of CoNC/CNT from pyrolysis of molecularly defined complexes for oxidative esterification and hydrogenation reactions (C0186) Co-Mo sulfur resistant shift catalyst supported on Mg-Al mixed oxide derived from layered double hydroxides (C0243) Tianyuan Cheng, Hao Yu, Feng Peng, Hongjuan Wang, Bingsen Zhang, Dangsheng Su (South China University of Technology) Jinxing Mi, Yanning Cao, Dalin Li, Lilong Jiang (Fuzhou University) Page 139 Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S3--Cat P051 P056 Cobalt-aluminum mixed oxides prepared from layered double hydroxides for benzene total oxidation (C0244) Acid modification of natural bauxite mineral and its application in slurry-bed hydrocracking process (C0264) Yuanyuan Ding, Dongmei Wang, Dalin Li, Yihong Xiao (Fuzhou University) Pengli Niu, Yuanyuan Yue, Lilong Jiang, Xiaojun Bao (Fuzhou University) P052 P057 Layered double hydroxides as precursors of Cu catalysts for water-gas shift reaction (C0245) Discovery, engineering and application of acid phosphatases for ascorbic acid-2-phosphate preparation (C0267) Yunbing Cai, Dalin Li, Chongqi Chen, Lilong Jiang (Fuzhou University) Wei Song, Hui Liu, Ruidong Chen, Xiulai Chen, Jia Liu, Liming Liu (Jiangnan University) P053 P058 Synthesis of sheet-like γ-FeOOH and Its Removal of Carbonyl Sulfide Property at Low Temperature (C0247) Cyclohexene as hydrogen carrier to promote the biomimetic catalytic oxidation of aliphatic C-H bond in the presence of molecular oxygen (C0269) Zhongjie Du, Xuebin Lin, Yan Lin, Ronghai Huang, Yanning Cao, Lilong Jiang (Fuzhou University) Jun Jiang , Xiantai Zhou , hongbing Ji (Sun Yat-sen University) P054 P059 Optimization of Modified Hollow Titanium Silicalite HTS in Cyclohexane Selective Oxidation (C0257) Mesoporous Silica Supported Ionic Liquids Catalyst for the Alkylation between Benzene with 1-Dodecene (C0270) Houjie Song, Meiqin Zheng, Shujuan Guo, Qingming Huang, Min Lin, Xiaohui Chen (Fuzhou University) Yibo He, Qinghua Zhang, Xiaoli Zhan, Dang-Guo Cheng, Fengqiu Chen (Zhejiang University) P055 P060 Pervaporation Enhanced Esterification of Propionic Acid and its kinetics (C0258) Highly Efficient Aerobic Oxidation of Tetralin to α-Tetralone over Cr2O3-CeO2/Al2O3 Catalysts (C0281) Shasha Na, Wenying Zhang, Weixing Li , Weihong Xing (Nanjing Tech University) Page 140 Lixin Xu, Guangyuan Chen, Jian Zhang, Bing Hong, Chao Wan (Anhui University of Technology) Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S3--Cat P061 P066 A study of H2 release from dodecahydro-Nethylcarbazole over a supported Pd catalyst (C0287) Isobornyl Acetate Synthesis Kinetics (C0314) Yingshu Wang, Chao Li, Naru Huang, Suying Zhao (Fuzhou University) Chao Wan , Yue An , Dang-guo Cheng , Fengqiu Chen , Lixin Xu (Anhui University of Technology) P062 P067 Bimetallic PtSb Nanocatalyst for Selective Oxidation of Glycerol with Oxygen in a Basefree Aqueous Solution (C0298) Synthesis of SAPO-11 and application in the isomerization of n-heptane (C0341) Hua Dong, Jiaqi Lei, Xuezhi Duan, Gang Qian, Xinggui Zhou (East China University of Science and Technology) Dongliang Jin, Kake Zhu (East China University of Science and Technology) P063 P068 Kinetics of the Catalytic Polymerization of Cottonseed Oil Acid (C0301) The Creation of Sulfur Vacancies for the Hydrodesulfurization over 2H-MoS2 M-edge and S-edge: A DFT Study (C0343) Suying Zhao, Fuqiang Li, Yanyi Shen , Dan Wu (Fuzhou University) Peng Zheng , Liang Zhao , Kebin Chi , Aijun Duan , Zhen Zhao (China University of Petroleum(Beijing)) P064 P069 Identification of the kinetic parameters and autocatalytic behavior in esterification via isoperibolic reaction calorimetry (C0304) Oxidative dehydrogenation of light alkanes over mesoporous Cr-Ce-Al composite oxide using N2O as an oxidant (C0345) Zichao Guo, Lin Hao, Hongyuan Wei (Tianjin University ) Suresh Kumar Megarajan, Jingting Lu, Wenyuan Liang, Yan Zhang, Heqing Jiang (Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences) P065 P070 Photocatalytic activity of Methyl orange and Congo red using Ba0.2Sr0.8Co0.5Fe0.5O3-δ (C0311) Study on the microscopic mechanism of microwave and effects on the dissolution of Potassium Feldspar at low temperature (C0346) Hongyan Meng , Jun Qiao , Zhengquan Shi, Xianghong Huang (Zhejiang Shuren University) Jingxing Zhao, Jianhai Zhao, Jiao Meng, Huanhuan Shi (Tianjin Chengjian University) Page 141 Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S3--Cat P071 P076 Hydrogenation of coal tar model compounds catalyzed by Ni2P/SBA-15 and MoNiWP/Al2O3 (C0355) Immobilization of laccase on amine-functioned Fe3O4 nanoparticles via metal affinity adsorption or covalent binding (C0436) Shuai Ma, Mengxiang Fang, Zhenzhen Liu, Qinhui Wang, Zhongyang Luo (Zhejiang University) Tingting Xia, Chen Guo, Jianhua Hu, Chunzhao Liu (Institute of Process Engineering, Chinese Academy of Sciences) P072 P077 Biomass derived p-xylene by selective aromatization (C0388) Selective oxidation of furfural in a bi-phasic system with homogeneous acid catalyst (C0448) Gangli Zhu, Huanling Song, Feng Zhao, Chungu Xia (Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences) Xiaodan Li, Tiefeng Wang (Tsinghua University) P073 P078 Study on preparation of Ru-based catalysts with bioreduction method and their application in liquid phase hydrogenation (C0389) Characterization and catalytic performances of Pd-CeO2/C catalysts for caprolactam hydrogenation purification (C0451) Yangqiang Huang, Youwei, Cheng Lijun Wang, Xi Li (Zhejiang University) Chunyan Tu, Li Xie, Shibiao Cheng (Research Institute of Petroleum Processing, SINOPEC) P074 P079 Facile fabrication of porous magnetic polymer microspheres via inverse replication for efficient enzyme immobilization (C0422) Effect of HZSM-5 crystal size and mesoporosity on catalytic conversion of methanol and ethanol into propylene (C0456) Pingping Han , Zhongyi Jiang , Jiafu Shi , Hong Wu (Tianjin University) Ali A. Rownaghi, Xin Li, Amit Kant, Yingxin He, Harshul V. Thakkar (Missouri University of Science and Technology) P075 P080 Understanding NH3-SCR kinetics over Cu-SSZ-13 catalysts prepared by different methods (C0434) Reaction mechanism of cyclodehydration of sugar alcohols over a layered niobium molybdate solid acid (C0477) Tao Zhang, Feng Qiu, Wenkang Su, Junhua Li (Tsinghua University) Page 142 Atsushi Takagaki, S. Ted Oyama (The University of Tokyo) Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S3--Cat P081 P086 Molecular modeling of water adsorption in MFI zeolites (C0485) Hierarchical Zeolite Y: Influence of the acid wash on the structural and acidic characteristics of the hierarchical zeolites (C0539) Xiongfei Zhang (Tianjin University) Wenlin Li, Zhijian Da, Yibin Luo, Jinyu Zheng(Research Institute of Petroleum Processing, SINOPEC) P082 P087 Hydrogen peroxide decomposition in aqueous suspensions of nano-magnetite (C0507) Ketonization of acetic acid over Ce-Ti mixed oxide catalysts: Effect of redox and basicity properties (C0554) Na Wang, Xin Cai, Xiaodong Chen, ShengPeng Sun (Soochow University) Feipeng Lu, BinBo Jiang , Zuwei Liao, Jingdai Wang, Yongrong Yang (Zhejiang University) P083 P088 Novel Core-Sheath Copper Catalysts with tunble Surface Cu(0)/Cu(I) active species and Confinement Effect for CO2 Hydrogenation (C0509) Pelletization process of spherical Pb-Mn composite oxide supports (C0557) Jie Zhou, Yue Hu, Xiaojun Yang (Wuhan Institute of Technology) Jing Li, Bohan Jin, Kui Ma, Siyang Tang, Changjun Liu, Hairong Yue, Bin Liang (Sichuan University) P084 P089 Synthesis of ethyl acetate in a reactive-distillation unit (C0514) Synthesis of 7-hydroxy-4-methylcoumarin via the Pechmann reaction with PVP-supported phosphotungstic acid catalyst (C0568) Bencheng Wu, Jianhua Zhu, Jiayue Wang (China University of Petroleum(Beijing)) Sifang Li, Xiaoxia Qi, Binbin Huang (Xiamen University) P085 P090 Quantitative Kinetics and the Structural Mechanism for Ni-Co Dry Reforming Catalysts (C0527) Modeling and kinetics study of bisphenol A (BPA) degradation over a FeOCl/SiO2 Fentonlike catalyst (C0577) Haiyan Zhao, Mohsen Shakouri, Karena Chapman, Peter Chupas, Hui Wang(University of Idaho) XueJing Yang, Ximeng Xu, Xinchao Xu, Jing Xu, Hualin Wang, Raphael Semiat, Yi-Fan Han (East China University of Science and Technology) Page 143 Poster Presentation, Wednesday Oct.14, 2015 S3--Cat S4--Ene P091 P096 Heteropolytungstate-ionic liquid supported on the surface of silica coated magnetite nanoparticles: An efficient and reusable catalyst for esterification (C0582) Coal Polygeneration Systems for Efficiency and Environment Benefits (D0057) Junli Xue (GE Global Research Center , Shanghai) Honglei Lian, Jingyi Yang, Jian Gao, Mingzhu Ding (Zhengzhou University) P092 P097 Intensification the C4 alkylation process by Ionic Liquids (C0586) Meso-scale computational fluid dynamics in energy and process industry (D0086) Tao Zhang, Fei Zhou, Yuan Zhang, Shengwei Tang (Sichuan University) Ning Yang, Jinghai Li (Institute of Process Engineering, Chinese Academy of Sciences) P093 P098 Oxidative desulfurization of dibenzothiophene using H3PMo12O40 immobilized onto ionic liquidmodified SiO2 (C0588) Retrofitting Industrial Heat Exchanger Network Based on Simple Pinch Analysis (D0087) Bao-Hong Li (Dalian Nationalities University) Jian Zhang , Yanjuan Wang , Haiyan Wang , Huipeng Li , Hao Ling , Hongla Liu , Bing Wang (Liaoning Shihua University) P094 P099 Effect of the acidity of metal modified Y zeolites on adsorptive desulfurization (C0596) Kinetic study of catalytic pyrolysis of nheptane (D0204) Yanfei Lu (Tianjin University) Guili Liu, Shaopeng Guo, Rui Zhang, Haiyan Liu, Zhichang Liu, Xianghai Meng (China University of Petroleum(Beijing) P095 P100 Electrocatalytic Dehydrogenation of 2-propanol in EHP reactor (C0613) Copper–free ZnGaO complex oxide catalysts with low CO selectivity and high catalytic stability for dimethyl ether steam reforming to produce H2 (D0233) Shiqi Huang , Xuemei Wu , Lin Ma , Shishui Liu , Gaohong He (Dalian University of Technology) Zhou Shuang, MengMing (Tianjin University) Page 144 Poster Presentation, Wednesday Oct.14, 2015 S4--Ene S4--Ene P101 P106 Efficiency, Integration and Molecular Management – The Role of Innovation (D0249) Controlled synthesis of hierarchical nanostructured electrode materials for energy storage applications (D0526) Dave Martindale, Xin Zhu (UOP LLC, A Honeywell Company) Hao Jiang , Chunzhong Li (East China University of Science and Technology) P102 P107 Crystallization kinetics of ice slurry formation (D0359) Reactivity of 1-hexene over the sulfided CoMo catalyst for hydrodesulfurization (D0532) Xi Liu, Xuelai Li, Ping Yao, Zhiqiang Wu(Fuzhou University) Chunyan Tu, Mingfeng Li, Yang Chu, Huifeng Li, Feng Liu, Hong Nie, Dadong Li (Research Institute of Petroleum Processing, SINOPEC) P103 P108 Bioconversion of syngas to ethanol: cultivation system and impact factors (D0402) Characterization of basic heteroatom compounds in coal liquefaction residue (D0536) Huijuan Xu, Cuiyi Liang, Jingliang Xu, Qiang Hua, Zhenhong Yuan, Ying Guo, Yu Zhang (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences) Li Peng, Fangui Xia, Zhouguo Li (Zhengzhou University) P104 P109 Effects of sodium nitrite on structure and thermal properties of LiNO3-NaNO3-KNO3 molten salt (D0475) Esterification of methanol with oleic acid using double SO3H-functionalized ionic liquid as recoverable catalyst (D0556) Xinmei Yang, Ze Sun, Xingfu Song, Jianguo Yu (East China University of Science and Technology) Jian Gao , Honglei Lian, Yadong Zhao , Wenqi Liu , Bo Meng , Jie Zhang (Zhengzhou University) P105 P110 Density Functional Theory Study on the Thermodynamics and Mechanism of Carbon Dioxide Capture by CaO and CaO Regeneration (D0476) Soil- based Microbial Fuel Cell for Electricity generation using Shewanella and Geobacter bacteria present in soil (D0580) Haiou Ni, Wei Du, Ze Sun, Guimin Lu, Jianguo Yu (East China University of Science and Technology) Mukund Mishra (Indore Institute of Science & Technology) Page 145 Poster Presentation, Wednesday Oct.14, 2015 S4--Ene S5--Foo P111 P116 Adsorption of Heterocyclic Sulfur and Nitrogen Compounds in Liquid Hydrocarbons on Activated Carbons Modified by Oxidation: Capacity, Selectivity and Mechanism (D0595) Synthesis and characteristics of Acid-Alkali modified Al2O3/PVDF hybrid membrane (E0542) Na Li , Xiaoliang Ma , Xiao Feng , Xiao Dong Chen (Soochow University) Qi He, Kaijun Xiao (South China University of Technology) P112 P117 RD&D Activities of SNG Production from Syngas Methanation at DICP (D0599) The study on L-lactic acid production by Rhizopus oryzae from lignocellulosic waste (E0547) Zhongshan Yuan , Sheng Wang , Defu Li , Tianjun Sun , Hongjiu Su , Deyi Li , Shudong Wang (Dalian Institute of Chemical Physics, Chinese Academy of Sciences) Li Zhang, Jian Gao (Yancheng Institute of Technology) P113 Nanofibre - based imidazolium-functionalized polysulfone composite anion exchange membrane for fuel cell (D0612) Xue Gong (Dalian University of Technology) S6--Gre P114 P119 Novel route for preparation of imidazoliumfunctionalized polysulfone anion exchange membranes for direct methanol alkaline fuel cells (D0614) Heterogeneous catalysis process for precious metal recovery and premier organosilicon product manufacturing (F0045) He Bai (Momentive Performance Materials Inc.) Tiantian Li (Dalian University of Technology) S5--Foo P115 P120 Critical dissolution and gelation conditions from whey protein aggregates in alkali (E0263) Noval acrylamide-free flocculant and its application for sludge dewatering (F0059) Lei Zhao, Xiao Dong Chen, Ruben Mercadé-Prieto (Soochow University) Lianghua Lu, Zhida Pan, Nan Hao and Wenqing Peng (Global Research Center of General Electric) Page 146 Poster Presentation, Wednesday Oct.14, 2015 S6--Gre S6--Gre P121 P126 Study of asymmetric splitting of AlCl3 in amideAlCl3 based ionic liquid analogues (F0177) CO2 Capture from Flue Gas by PSA: Bench Scale Demonstration of a Novel Structured Adsorbent (F0430) Pengcheng Hu, Xianghai Meng, Rui Zhang, Haiyan Liu, Zhichang Liu (China University of Petroleum(Beijing)) Armin D. Ebner, MD Atikur Rahman, Nima Mohammadi, Marjorie A. Nicholson, Charles E. (University of South Carolina) P122 P127 Production of hydrogen peroxide on mixedmetal oxide/carbon nitride composite catalyst driven by solar Light (F0192) Design and Control of Supercritical CO2 Blown Polymer Foaming Process (F0446) Kecheng Pan, Ruirui Wang, Xu Xiang (Beijing University of Chemical Technology) Ling Zhao, Tao Liu (East China University of Science and Technology) P123 P128 Graphene oxide composite membranes for pervaporation (F0340) Fractional pyrolysis of pretreated algae from water blooms (F0501) Wei-Song Hung, Chien-Chieh Hu, Juin-Yih Lai (Chung Yuan University) Linling Li, Rui Zhang, Xiaoyan Lv, Dongmei Tong, Changwei Hu (Sichuan University) P124 P129 Green production of cumene from liquid-phase isopropylation of benzene over nano-beta zeolite in a submerged membrane reactor(F0392) Microwave-enhanced Pyrolysis of Natural Algae from Water Blooms (F0502) Yang Zou , Hong Jiang , Weihong Xing , Huanxin Gao , Rizhi Chen (Nanjing Tech University) Rui Zhang, Linling Li, Dongmei Tong, Changwei Hu (Sichuan University) P125 P130 Solar photocatalytic degradation of Acidic Black 10B over (Sr0.5Ca0.5)Fe2O4-ZnO composites (F0428) Fractional Pyrolysis of Pubescens at Low Temperature Stage (F0503) Jun Qiao, Hongyan Meng, Xianghong Huang (Zhejiang Shuren University) Xiaoyan Lv, Linling Li, Dongmei Tong, Changwei Hu (Sichuan University) Page 147 Poster Presentation, Wednesday Oct.14, 2015 S6--Gre S8--Mat P131 P136 Monophenols production in H2Otetrahydronfuran directly from corncob residue catalyzed by alkali (F0504) NiPdPt nanoclusters decorated on graphene as a catalyst for ethanol electrooxidation (H0188) Jingwen Ma, Yang Li (Tianjin University) Zhicheng Jiang, Jianmei Li, Ting He, Jian Yi, Changwei Hu (Sichuan University) P132 P137 Study on Kinetics of Poly(3hydroxybutyrate)(PHB) Hydrolysis Using Acidic Functionalized Ionic Liquid as Catalyst (F0513) A solvent evaporation route towards fabrication of nanosized SAPO-34 molecular sieve (H0319) Xiuyan Song, Fusheng Liu, Shitao Yu (Qingdao University of Science and Technology) Jingwei Zheng, Kake Zhu, Xinggui Zhou and Weikang Yuan (East China University of Science and Technology) P133 P138 Quantitative analysis of OH radicals formed on the surface of TiO2 photocatalysts in aqueous solution by fluorescence probe method (F0559) Synthesis and characterization of Beta-FDU-12 and Its applications in the catalysts for FCC gasoline hydrodesulfurization (H0347) Jie Zhang, Nosaka Yoshio (Zhengzhou University) Jiayue Wang , Peng Du , Peng Zheng , Kebin Chi , Aijun Duan , Zhen Zhao (China University of Petroleum(Beijing)) S7—R&D P134 P139 Innovation and culture in the engineering firm (G0600) Covalent organic polymers (COPs) for energy conversion (H0398) Will Groten (CB&I) Zhonghua Xiang (Beijing University of Chemical Technology) S8—Mat P135 P140 Carbide bonded graphene network and applications (H0167) Nanoplatform for low toxicity and high efficacy: integration of hidden targeting ligand, tumor responsiveness, and synergistic therapy (H0405) L. James Lee, Wenyi Huang, Jianfeng Yu, Paul Garman (The Ohio State University ) Page 148 Faquan Yu, Yanan Xue, Bo Yu, Ning Cai, Sihui Long, Xiaogang Luo (Wuhan Institute of Technology) Poster Presentation, Wednesday Oct.14, 2015 S8--Mat S8--Mat P141 P146 Fabrication of novel hybrid membranes based on acid-base pairs for enhanced proton conductivity (H0421) Fabrication of Gold Nanoparticles with Functional Molecules for Colorimetric Recognition (H0445) Yongheng Yin , Tao Xu , Zhongyi Jiang , Hong Wu (Tianjin University) Jianjun Du, Jiangli Fan, Xiaojun Peng (Dalian University of Technology) P142 P147 In situ fabrication of Ag3PO4/TiO2 nanotube heterojunctions with enhanced visible-light photocatalytic activity (H0424) Crystallization Behaviors of Polypropylene under the Action of a Novel Aromatic Amide Nucleating Agent (H0454) Zhenwei Tong , Dong Yang , Yuanyuan Sun , Zhongyi Jiang (Tianjin University) Yue-Fei Zhang, Huichen, Lihua Guo, Xin Yang, Bao Liu (Changsha University of Science and Technology) P143 P148 Fabrication of Three-dimensional Porous SrTiO3 Microspheres with Improved Visible-Light Photocatalytic Performance for Cr (VI) (H0425) Controlled additive-free hydrothermal synthesis and characterization of uniform and monodisperse hydroxyapatite nanobelts (H0493) Dong Yang , Yuanyuan Sun , Zhenwei Tong , Zhongyi Jiang (Tianjin University) Liang An, Wang Li, Yong Xu, Yang Cheng, Guanghui Wang (Wuhan University of Science and Technology) P144 P149 Graphitic carbon nitride nanosheets/poly(ether ether ketone) nanocomposite membrane for fuel cells application (H0427) Corrosion resistant properties of polybenzoxazine/TiO2 Hybrid films (H0516) Mingyue Gang , Guangwei He , Zhen Li , Hong Wu , Zhongyi Jiang (Tianjin University) Yan Liu, Xin Lu, Changlu Zhou, Zhong Xin (East China University of Science and Technology) S9--Wat P145 P150 Assembly and Processing of Functional Porous Microspheres via Micro-Fluidic Jet Spray Drying (H0441) Highly hydrophilic fouling resistant PVDF ultrafiltration membranes with TiO2 nanoparticles both on membrane surface and in membrane matrix (I0067) Zhangxiong Wu , Winston Duo Wu , Cordelia Selomulya , Dongyuan Zhao , Xiaodong Chen (Soochow University) Hassan Younas, Jiahui Shao,Qiaochu Han, Yuhan Ling, Yiliang He (Shanghai Jiao Tong University) Page 149 Poster Presentation, Wednesday Oct.14, 2015 S9--Wat S9--Wat P151 P156 Produced water treatment by Direct Contact Membrane Distillation (DCMD) (I0071) Fabrication and characterization of forward ossimos (FO) composite membranes of cellulose triacetate (CTA)-magnetic nanoparticles (MNPs) (I0133) Hui Lei, Xianguo Yu, Hai Yang, Su lv, Andrew Shapiro (GE Global Research, Shanghai) Ping-Yun Zhang, Zhenliang Xu, Xiangyu Chi, Xuejiao Guo, Tao Wang (East China University of Science and Technology) P152 P157 Fouling Analysis of RO membrane (I0074) Superhydrophobic modification of PVDF-SiO2 electrospun nanofiber membranes for vacuum membrane distillation (I0134) Yun Peng, Hua Li, Bo Yan, Su Lv (Global Research Center of General Electric, Shanghai) Zheqin Dong, Xiaohua Ma, Zhenliang Xu (East China University of Science and Technology) P153 P158 Preparation of ordered porous microfiltration membranes on ice substrates by breath figure method (I0118) Coalescence separation of oil/water emulsions with roughened non-woven filter mat (I0136) Hailin Cong, Bing Yu, Jilei Wang, Zejing Li (Qingdao University) Hu Dan, Li Xiaoyu, Li Lei, Yang Chuanfang (Institute of Process Engineering, Chinese Academy of Sciences) P154 P159 Preparation and modification of porous stainless steel hollow fibers by adding nanoparticles (I0131) Preparation and characterization of selfassembled nanostructure on the PVC ultrafiltration membrane (I0151) Ming Wang, Qifeng Zhong, Xiaohua Ma, Zhenliang Xu (East China University of Science and Technology) Liang Cheng, Zhenliang Xu, Hanyang Zan, Jiazhou Zhu (East China University of Science and Technology) P155 P160 A chlorine-tolerant nanofiltration membrane prepared by the mixed diamine monomers of PIP and BHTTM (I0132) The effect of the manifold on the energy consumption and flow distribution of the hollow fiber membrane module-A CFD study (I0226) Yongjian Tang, Zhenliang Xu, Shuangmei Xue, Yongmin Wei, Hu Yang (East China University of Science and Technology) Page 150 Liwei Zhuang, Hanfei Guo, Gance Dai (East China University of Science and Technology) Poster Presentation, Wednesday Oct.14, 2015 S9--Wat S9--Wat P161 P166 Development of nanofiltration hollow fiber membranes for industrial water treatment (I0288) Porous PES nanofibers loading PFSA catalyst and its application in esterification (I0444) Shipeng Sun, Taishung Chung (Nanjing Tech University) Xiaohua Ma, Siwen Gu, Zhenliang Xu (East China University of Science and Technology) P162 P167 Water flow through the graphene nanochannels: A viewpoint from non-equilibrium molecular dynamics simulations (I0305) Atomic layer deposition enabled advanced membranes (I0489) Yong Wang (Nanjing Tech University) Mingjie Wei, Yong Wang (Nanjing Tech University) P163 P168 Surface engineering of electrospun polymeric nanofibers for membrane distillation (I0362) Ultrathin graphene oxide nanosheet membranes assembled using the pressureassisted filtration method for removing natural organic matter (I0548) Haoyuan Zhou, Xiaochan An, Zhongyun Liu, Yunxia Hu (Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences) Shengji Xia, Muzi Ni, Nana Li, Yu Zhao ( Tongji University) P164 P169 Manipulating the multifunctionalities of polydopamine to prepare high-flux antibiofouling composite nanofiltration membranes (I0426) Conjugated microporous polymers for metal ions removal (I0579) Ruixia Yang (Dalian Institute of Chemical Physics) Runnan Zhang, Zhongyi Jiang, Yanlei Su (Tianjin University) P165 P170 Composite CNTs-Polyaniline electro-conductive membranes (I0438) Highly stable graphene oxide membranes prepared on polydopamine functionalized supports for seawater desalination (I0592) Wenyan Duan, Avner Ronen, Sharon Walker, David Jassby (University of California) Kai Xu, Bo Feng, Aisheng Huang (Ningbo Institute of Material Technology and Engineering ) Page 151 Poster Presentation, Wednesday Oct.14, 2015 S9--Wat S10--Par P171 P176 Influence of low molecular weight alcohol with single hydroxyl on performance of PVDF ultrafiltration membrane (I0609) Speeding Up Reactive Modeling of Fluidized Bed Reactor by Combining CRE and Multiscale CFD (J0083) Feng Bai , Yan Dai, Gaohong He (Dalian University of Technology) Wei Wang, Bona Lu, Hao Luo, Hua Li, Mao Ye, Zhongmin Liu, Jinghai Li (Institute of Process Engineering, Chinese Academy of Sciences) P172 P177 Improved antifouling properties of poly(ether sulfone) membrane: effect of the sequence structures of amphiphilic modifiers (I0610) Comparison of Bubbles Hydrodynamics in GasSolid Bubbling Bed Obtained from TFM and DEM Simulation (J0121) Guangfa Zhang, Qinghua Zhang, Xiaoli Zhan, Fengqiu Chen (Zhejiang University) Xingying Lan, Yingya Wu, Jinsen Gao (China University of Petroleum(Beijing)) S10--Par P173 P178 An Experimental Analysis of Pressure Drop Fluctuations of Cyclone Separator in the FCCU (J0173) Xiaoman Li, Zhigang Wei, Guogang Sun , Chaoyu Yan, Yaodong Wei (China University of Petroleum(Beijing)) P179 Functional Uniform Microparticles Tailored by a Novel Spray Drying Technology (J0235) Winston Duo Wu, Zhangxiong Wu, Jie Xiao, Nan Fu, Xiao Dong Chen (Soochow University) P180 Direct Liapunov Method for Predicting Maldistribution of Gas-solid Flow through Parallel Lines (J0273) Chenxi Zhang, Fei Wei , Weizhong Qian, Zhao Jia , Qi Wang (Tsinghua University) Page 152 Poster Presentation, Wednesday Oct.14, 2015 S10--Par S10--Par P181 P186 Pyrolysis of long flame coal under steam atmosphere in a fluidized-bed reactor (J0280) Enhancing CO2 absorption into MEA solution by nanoparticles (J0332) Airong Li, Daohong Wu (Southwest Petroleum University) Wei Yu, Tao Wang, Hui He, Mengxiang Fang (Zhejiang University) P182 P187 Study on Discharging Characteristics of the Cyclone Dipleg-Trickle Valve System in the FCC Unit (J0284) Hydromechanical simulation of bubbling fluidized bed based on modified EMMS model (J0417) Zhigang Wei, Xiaoman Li, Xiaoyang Cao, Chaoyu Yan, Yaodong Wei (China University of Petroleum(Beijing)) Bolun Yang (Xi'an Jiaotong University) P183 P188 Gas-solids contacting efficiency in the high density circulating fluidized bed reactors (J0290) Oxygen Carrier Particle Design and Development for Chemical Looping Processes (J0491) Chengxiu Wang, Jinsen Gao, Jesse Zhu (China University of Petroleum(Beijing)) Liang Zeng, Jinlong Gong (Tianjin University) P184 P189 Origin, propagation and attenuation of pressure waves in a circulating fluidized bed standpipe (J0299) Numerical simulations of porous particles settling using lattice Boltzmann method (J0496) Jun Xu, Siqing Zhong, Zhinan Yu (Shanghai Research Institute of Petrochemical Technology) Cheng-Gong Li, Mao Ye, Jibin Zhou, Zhongmin Liu (Dalian Institute of Chemical Physics) P190 Spray-drying route to uniform and large mesoporous titania microspheres for heavy metal ions removal (J0497) Xingmin Gao, Zhangxiong Wu, Xiaodong Chen, Winston Duo Wu (Soochow University) Page 153 Poster Presentation, Wednesday Oct.14, 2015 S10--Par S11--Pet P191 P196 Hydromechanical simulation of bubbling fluidized bed based on modified EMMS model (J0511) Effect of Copolymer Composition on pHResponsive Surface Wettability: Identifying the Best Copolymer for Efficient Water/Oil Separation (K0601) Jiageng Li , Bolun Yang (Xi’an Jiaotong University) S11--Pet Yin-Ning Zhou, Jin-Jin Li, Zheng-Hong Luo (Shanghai Jiao Tong University) P192 P197 Catalytic Cracking of Vacuum Gas Oil and Vacuum Residue Deasphalted Oil from Huizhou Refinery (K0302) Improving Fluorescence Bio-imaging with Cyanine and Fluorescein Dyes (K0605) Mengyao Wang, Tianhua Ren, Jiawen Zhou, Rui Zhang, Haiyan Liu, Xianghai Meng(China University of Petroleum(Beijing)) (Dalian University of Technology) P193 P198 Reaction behavior of inferior residue in a carbon-rejection process(K0351) Development of cyclic pressure swing operating process for hydrogen production by sorptionenhanced ethanol steam reforming (L0046) Nan Jin , Gang Wang , Hongliang Wang , Jinsen Gao , Chunming Xu (China University of Petroleum(Beijing)) Fengling Song , Xiaoqing Xiong, Xiaojun Peng Yi-Jiang Wu, Ping Li, Jian-Guo Yu , Alírio E. Rodrigues (East China University of Science and Technology) S12--Pro P194 P199 Fluorescent Probes for Cancer Cells (K0429) Optimal thermodynamic feed conditions for sharp separation distillation column with double feeds (L0060) Xiaojun Peng (Dalian University of Technology) Xuegang Liu, Bingjian Zhang, Changchun He, Qinglin Chen(Sun Yat-Sen University) P195 P200 Low temperature catalytic naphthalene hydrogenation to naphthalene over highlyloaded NiMo, NiW and NiMoW catalysts (K0598) Simulation and optimization of salt-production from desalination brine (L0063) Chenguang Liu, Huan Liu, Changlong Yin(China University of Petroleum(East China)) Page 154 Lian-Ying Wu , Teng Sun(Ocean University of China) Poster Presentation, Wednesday Oct.14, 2015 S12--Pro S12--Pro P201 P206 Extractive distillation of hydrocarbons with sulfolane and n-formylmorpholine mixture based on modeling and simulation (L0064) Dr.(L0411) You Li, Xingang Li, Hong Li, Yonghong Li, Wentao Zhou (Tianjin University) Qin Wang, Bingjian Zhang, Changchun He, Qinglin Chen (Sun Yat-sen University) P202 P207 Analysis of capacity expansion and retrofit for crude distillation unit based on statistical model (L0069) Solid state fermentation of untreated and steam-explode corn stalk for laccase production from Trametes versicolor (L0458) Kan Wang, Bingjian Zhang, Qinglin Chen(Sun Yat-sen University) Abiodun E. Adekunle , Chen Zhang , Chun-Zhao Liu(Institute of Process Engineering, Chinese Academy of Sciences) P203 P208 A model for mixed heavy crude refinery and multi-plant planning (L0076) Modeling multistage crystallization fouling of heat exchangers: How do crystal structures affect heat transfer (L0478) Xiaoqiao Huang, Yangdong Hu, Lijuan Song, Yuzhen Zhang, Yongsheng Duan (China University of Petroleum) Jie Xiao, Jian Han, Xiao Dong Chen Rodrigues (Soochow University) P204 P209 Process simulations of CO2 desorption in the novel direct steam stripping process with different solvents(L0350) Optimum target for double feeds preheating of the stabilizer in absorption-stabilization units (L0479) He Hui, Fang Mengxiang, Wang Tao, Yu Wei Xuegang Liu , Junjie Chen , Bingjian Zhang , Qinglin Chen (Sun Yat-Sen University) (Zhejiang University) P205 P210 Progress on olefin polymerization process technology in China (L0408) CO2 mineralization using natural K-feldspar and industrial waste: the role of mechanical activation on the process intensification (L0519) Yongrong Yang, Jingdai Wang, Musango Lungu, Can Zi, Haotong Wang (Zhejiang University) Wenjie Shangguan, Hairong Yue, Jimin Song, Longpo Ye, Zhixi Gan, Siyang Tang, Chanjun Liu, Chun Li, Bin Liang, Heping Xie(Sichuan University) Page 155 Poster Presentation, Wednesday Oct.14, 2015 S12--Pro S13--The P211 P216 Microwave-assisted preparation of the crystal seeds for producing easily phase-transformed anatase to Rutile (L0541) Molecular dynamics simulation of nanoparticles modified viscoelastic fracturing fluids (M0278) Yaowen Zhang, Siyang Tang, Shaoyun Yuan, Hairong Yue, Changjun Liu, Chun Li, Bin Liang(Sichuan University) Yaqian Ning, Tao Wang, Fei Xue, Zhongyang Luo (Zhejiang University) P212 CO2 Mineralization, Soluble potash salts extraction, And sulfur recovery via Coupling Carbothermal Reduction of Phosphogypsum with Thermal Activation of Potash Feldspar (L0562) Zhixi Gan, Hairong Yue, Longpo Ye, Wenjie Shanguan , Siyang Tang, Changjun Liu, Chun Li, Bin Liang, Heping Xie(Sichuan University) P217 Quantum chemistry calculations for the quaternary-ammonium-based CO2 sorbent (M0320) Kun Ge, Kexian Chen, Tao Wang, Mengxiang Fang (Zhejiang University) S13--The P213 P218 Large-scale molecular dynamics simulation and online measurement of thermal conductivity of bulk silicon and silicon nanowires (M0061) Separation of Li+ and Mg2+ in nanopores: a molecular dynamics study (M0484) Chaofeng Hou, Guoxian Gao, Ji Xu, Wei Ge, Jinghai Li (Institute of Process Engineering, Chinese Academy of Sciences) Yang Ruan, Yudan Zhu, Xiaohua Lu, Yumeng Zhang, Linghong Lu (Nanjing Tech University) P214 P219 Metastable zone determination and crystal growth of K2SO4 in the concentrated alkali solution (M0072) Fast phase diagram predictions of ternary aqueous saline solutions: a density functional approach (M0533) Mengjie Luo, Chenglin Liu, Jin Xue, Ping Li, Jianguo Yu (East China University of Science and Technology) Jie Zhang, Chongzhi Qiao, Shuangliang Zhao, Xingfu Song (East China University of Science and Technology) P215 P220 Thermophysical and Electrochemical Properties of Ionic Liquids with Azolide Anions (M0180) The molecular dynamics simulations of friction of confined liquid (M0563) Joan Brennecke (University of Notre Dame) Wei Chen (Computer Network Information Center, Chinese Academy of Sciences) Page 156 Poster Presentation, Wednesday Oct.14, 2015 S13--The S14--Sep P221 P226 Numerical study on heat transfer of shear thinning flow in twisted noncircular ducts (M0570) Selective extraction of lithium from brine with ionic liquid systems (N0120) Jingjing Chen, Ruiping Han, Shaopeng Zhang, Changsong Wang, Xiaohua Lu (Nanjing Tech University) Chenglong Shi, Jinhe Sun, Yan Jing, Yongzhong Jia (Qinghai Institute of Salt Lakes, Chinese Academy of Sciences) S14--Sep P222 P227 Selective adsorption of thiophenic compounds from fuel over TiO2/SiO2 under UV-irradiation (N0050) Experiment on the continuous separation of gas mixtures via hydrate formation and dissolution in the presence of hydrate promoter (N0154) Guang Miao, Feiyan Ye, Luoming Wu, Zhong Li, Jing Xiao (South China University of Technology) Yang Luo, Aixian Liu, Xuqiang Guo, Qiang Sun, Lanying Yang (China University of Petroleum(Beijing)) P223 P228 Preparation of Hybrid adsorbents with SelfImmobilizing Mycelia and Magnetic Nanoparticles (N0052) Recent advances in pressure swing adsorption technology (N0159) Qilei Zhang, Dongqiang Lin, Shanjing Yao (Zhejiang University) James A. Ritter, A. D. Ebner (University of South Carolina) P224 P229 Membrane Chemical Exchange (MCEx) for lithium isotope separation (N0054) Control of extractive distillation with heat integration for separating benzene/cyclohexane mixtures (N0172) Jianfeng Song, Dingfeng Kong, Ran Zhang, Lixin Xing, Baolong Zhao, Zhouwei Wang, Xuemei Li, Tao He (Shanghai Advanced Research Institute, Chinese Academy of Sciences) Lumin Li, Yanan Tian, Lanyi Sun, Jian Zhai, Yuliang Liu (China University of Petroleum(East China)) P225 P230 Studies on preparation and absorption/desorption behaviors of Fe-doped Li4SiO4 sorbent for CO2 capture at medium temperatures (N0075) The hydrodynamics and mass transfer during centrifugal molecular distillation: simulations and experiments (N0183) Jiang Yu, Xigang Yuan, Aiwu Zeng (Tianjin University) Sai Zhang, Qi Zhang, Chen Shen, Dong Peng, Zibin Zhu (East China University of Science and Technology) Page 157 Poster Presentation, Wednesday Oct.14, 2015 S14--Sep S14--Sep P231 P236 Phase equilibria and phase diagrams for the aqueous ternary system (NaCl+Na2SO4+H2O) at different temperatures (N0187) Design, optimization and control of energysaving dividing-wall column for separating azeotropes (N0277) Haijiao Lu, Jingkang Wang, Hongxun Hao, Ying Bao (Tianjin University) Ming Xia, Litao Jia, Bo Hou, Debao Li (Institute of Coal Chemistry, Chinese Academy of Sciences) P232 P237 Relating performance of thin-film composite gas separation membranes to support layer formation and structure (N0197) Thin-film composite organic solvent nanofiltration membranes: from flat-sheet to hollow fibers (N0289) Mengqi Shi, Zhi Wang, Jixiao Wang, Shichang Wang (Tianjin University) Shi-Peng Sun, Tai-Shung Chung (Nanjing Tech University) P233 P238 Practical gas separation polymer membranes in the organic fluorine industry (N0200) Experimental study on mass transfer of CO2 in mixed solvents using a wetted-wall column (N0303) Xuehua Ruan, Yan Dai, Gaohong He, Xiaoming Yan, Baojun Li (Dalian University of Technology) Fei Liu, Xuping Zhou, Tao Wang, Mengxiang Fang (Zhejiang University) P234 P239 Membrane properity analysis and optimize for hydrogen purification (N0202) Novel bio-crosslinking Schiff base adsorbent for silver ions rapid removal: synthesis, characterization, and adsorption property and mechanism (N0307) Jiayou Xu, Zhi Wang, Chenxin Zhang, Song Zhao, Zhihua Qiao, Panyuan Li, Jixiao Wang, Shichang Wang (Tianjin University ) Qiangfeng Yin (East China University of Science and Technology) P235 P240 [Bmim][FeCl4] for the extractive separation of aromatic and aliphatic hydrocarbons (N0224) Separation of low boiling gas mixture by a hybrid absorption-adsorption method (N0310) Hao Tong , Linyang Qiu , Rui Zhang , Haiyan Liu , Xianghai Meng (China University of Petroleum(Beijing)) Bei Liu, Huang Liu, Yong Pan, Changyu Sun, Guangjin Chen (China University of Petroleum(Beijing)) Page 158 Poster Presentation, Wednesday Oct.14, 2015 S14--Sep S14--Sep P241 P246 Synthesis of energy efficient separation processes using distillation (N0330) Investigation of fine particle packing structure by introducing a wide-ranged and adjustable interparticle force (N0370) Gautham Madenoor Ramapriya, Zheyu Jian, Rakesh Agrawal, Mohit Tawarmalani (Purdue University) Fushen Yang, Ning Li, Le Du, Weidong Zhang (Beijing University of Chemical Technology) P242 P247 Structure-controllable adsorbents for CO2 air capture in moisture swing process (N0352) The application of PTFE hollow fiber membrane in alcohol amine absorber desorption process (N0371) Jun Liu, Tao Wang, Chenglong Hou, Mengxiang Fang, Zhongyang Luo (Zhejiang University) Tianran Yu, Xianhang Jin, Ye Yang, Xinyang Du, Le Du, Yuhai Guo, Weidong Zhang (Beijing University of Chemical Technology) P243 P248 Dispersion of adsorption active sites by using confined space (N0363) Preparation and modification of PPhTMS ethanol-permselective pervaporation separation membrane (N0372) Lin-Bing Sun, Xiao-Qin Liu (Nanjing Tech University) Junna Zhang, Wei Jia, Zhongqi Cao, Le Du, Weidong Zhang (Beijing University of Chemical Technology) P244 P249 Preparation of a high-flux pervaporation PDMDES membrane to separate dilute alcohol/water (N0368) Efficient carbon capture by constructing CO2philic surface on integrally skinned asymmetric membranes via surface segregation (N0415) Wei Jia, Chunjie Xia, Yanping Yu, Zhongqi Cao, Le Du, Weidong Zhang (Beijing University of Chemical Technology) Shaofei Wang, Zhizhang Tian, Hong Wu, Zhongyi Jiang (Tianjin University) P245 P250 Development of MEA-based solvents for CO2 capture (N0369) Synthesis of NaY zeolite membrane for pervaporation separation of alcohol/water mixtures (N0416) Xianhang Jin, Le Du, Weiwei Tu, Jinming Xing, Ye Yang, Weidong Zhang (Beijing University of Chemical Technology) Fei Zhang, Longnv Xu, Xiangshu Chen (Jiangxi Normal University) Page 159 Poster Presentation, Wednesday Oct.14, 2015 S14--Sep S14--Sep P251 P256 NaKA zeolite adsorbents with high CO2-N2 selectivity for CO2 capture (N0437) Continuous de-emulsification of Kerosene/Water Emulsions with a Threedimensional Spiral Asymmetric Plate-type Microchannel (N0587) Bo Yang , Yan Liu , Ming Li (Tongji University) Zhi-Kun Yao, Da Ruan, Xiao Chen, Zhi-Gang Zhao (Southwest University for Nationalities) P252 P257 Research and application of steel slag separation technology (N0487) Imidazole functionalized graphene oxide / PEBAX mixed matrix membrane for CO2 capture (N0608) Yongli Xiao, Yongqian Li, Yin Liu, Youping Zhang (Baosteel Research Institute) Yan Dai, Zhijun Yan, Miao Yu, Feng Bai, Hao Li, Gaohong Heg (Dalian University of Technology) P253 P258 Modeling and simulation of CO2 capture from biogas using aqueous (N0531) Sodium 1,2,4-1H-Triazole incorporated mixed matrix membrane for CO2 separation (N0611) Chunyan Ma (Nanjing Tech University) Miao Yu, Yan Dai, Kai Yang, Hao Li, Gaohong He (Dalian University of Technology) P254 Novel extraction methods: High intensity pulsed electric field extraction and ultrahigh pressure extraction (N0571) Lang He, Liang-gong Yan, Jun Xi (Sichuan University) P255 Numerical simulation of mechanical property of plant cell during ultrahigh pressure extraction process (N0576) Lianggong Yan, Lang He, Jun Xi (Sichuan University) Page 160 Poster Presentation Sup P259 Design of hierarchical zeolite Y catalysts by sequential dealumination- desilication (K0540) Da Zhijian , Li Wenlin , Luo Yibin , Zheng Jinyu (Research Institute of Petroleum Processing, SINOPEC) P260 Study on the crystallite orientation of clustered AlOOH nano-sheets(H0044) Yuming Sun, Ping Li(East China University of Science and Technology) P261 Exploring the mechanisms underlying the formation of core-shell particles by spray drying of homogenous droplets (E0212) Nan Fu(Soochow University) P262 Effect of microstructure on the swelling and dissolution of protein hydrogels(M0260) Ruben Mercade Prieto, Hui Li , XiaoDong Chen (Soochow University) P263 Introduction of a second promoter to NiMobased catalysts: Preparation, characterization, and hydrodesulfurization activity(K0529) Chenguang Liu, Changlong Yin , Huan Liu (China University ofPetroleum (East China)) P264 Synthesis of cobalt nitrides and their catalytic performance for NO dissociation(H0574) Meng Bo , Gao Jian (Zhengzhou University) Organizer Sponsors Special Sponsors The 8th Sino-US Joint Conference of Chemical Engineering October 12-16 • 2015 • SHANGHAI • CHINA