Torrötning på Tekniska verken?
Transcription
Torrötning på Tekniska verken?
Increased biogas production, pasteurization and reduced methane emissions by dry digestion of dewatered sludge 2014-03-25 Erik Nordell Development Engineer Tekniska verken i Linköping AB (public) Tekniska verken i Linköping AB • Owns and operates 3 full-scale biogas plants • Linköping biogas - co-digestion • Norrköping biogas - co-digestion • Nykvarnsverket WWTP (Located in Linköping) - sludge digestion • Total annual bio-methane production of these plants are 130 GWh, whereas 15% of the production derived from the WWTP Nykvarnsverket WWTP: Schematic sketch 7 200 m3/d Biogas to upgrading unit (viechle fuel) 7 200 m3/d Mesophilioc wet digestion (38°C) 300 t/d TS = 6% 20 days (V = 6000 m3) Dewatering 300 t/d TS = 3% Slamlager Recirculation of reject water for removal of nitrogen 300 t/d TS = 3% 270 t/d TS <1% 28 t/d TS = 32% Open ”composting” for 6 months before beeing used on agriculture land Background • 42% of all biogas produced in Sweden (2012) was from WWTPs (660 GWh) • Primary- and bio-sludge are the “substrates” at the WWTP digestion, typically with 50-60% degradation yields due to short retention time and persistent substances • Emissions from the storage of sludge are crucial for the whole biogas business, a higher degradation yield is equal to lower emissions • How can we increase the biogas production from sludge? Methane yield – BMP tests Net production from primary/bio-sludge Methane production (Nml CH4/gVS) 300 250 200 20% on VS basis 150 100 Eq. 10% on w/w Production from digested sludge 50 0 5 10 Time (days) 15 20 “How can we increase the biogas production from sludge?” • Well, increase the retention time by building a postdigestion unit • However, the post-digestion unit need to be relatively large to collect as much as possible of the biogas formed in the post-digester • At Nykvarn WWTP 3,000-6,000 m3 • Heavy investment cost Digester Post-digester Nykvarnsverket WWTP: Schematic sketch 7 200 m3/d Biogas to upgrading unit (vehicle fuel) 7 200 m3/d Same amount of TS/VS but only 10% of the w/w Mesophilic wet digestion (38°C) 300 t/d TS = 6% 20 days (V = 6000 m3) Dewatering 300 t/d TS = 3% Buffer Recirculation of reject water for removal of nitrogen 300 t/d TS = 3% 270 t/d TS <1% 28 t/d TS = 32% Open ”composting” for 6 months before being used on agriculture land Dry-digestion of dewatered sludge? • Digester volume may be decreased with 90%, but the retention time for the sludge can be the same • E.g. instead of 6,000 m3, the digester volume can be 600 m3 if the dewatered sludge are used for post-digestion • Dry-digestion (TS > 20%) technique differ from the normal wet-digestion (typically 2-6% TS) | mass-transfer is different, mixing etc. • A 2nd setup of BMP tests were performed, at 20°C and 38°C to simulate “optimal” conditions in the current storage as well as the maximal potential at mesophilic temperature BMP-test on dewatered sludge from Nykvarnsverket WWTP Biogas production (m3/y) 20 grader Reaktorstorlek 1 000 180 000 900 160 000 800 140 000 700 120 000 600 100 000 500 80 000 400 60 000 300 40 000 200 20 000 100 - 0 5 10 15 20 Time (days) 25 30 35 Reactor size - plugflow (m3) 38 grader 200 000 Dry-digestion of dewatered sludge? • Pasteurization may be applied by using a thermophilic temperature (52-55 C) to meet the further demand for the government (“Fosforremissen”) = combo effect! • Plug-flow reactor (= non mixed reactor) may be used to guarantee that the sludge are pasteurized Substrate Day 1 Digestate Day 1+HRT Radial mixing only How do we proceed form here? • Swedish Energy Authority (Energimyndigheten) has granted financial support to the full-scale investment with 6 mSEK • This spring, a pilot-scale plug-flow reactor will be used to evaluate and confirm the pasteurization effect as well as effect on the viscosity of the final sludge Future implementation at Nykvarnsverket WWTP 7 200 m3/d Biogas to upgrading unit (vehicle fuel) 7 200 m3/d Mesophilic wet digestion (38°C) 300 t/d TS = 6% 20 days (V = 6000 m3) 550 m3/d (+7,5%) Dewatering 300 t/d TS = 3% Buffert Recirculation of reject water for removal of nitrogen 300 t/d TS = 3% 270 t/d TS <1% 28 t/d TS = 32% Dry-digestion (55°C) 36 days (V = 1 000 m3) Simultaneously pasteurization To farming land Less emissions! Idé Conclusion/summary • By implementing a dry-digestion step to post-digest the dewatered sludge, the biogas production can be increased with 8% • Methane slip from storage will decrease significantly • Thermophilic temperature will simultaneously make the post-digestion unit to a pasteurization step • Pilot-scale experiment this spring! Questions or comments? Contact information Erik Nordell Tekniska verken i Linköping AB Dept. R&D Biogas [email protected] +46(0)13-30 85 42