Feds probe Jacksonville, FL process blast
Transcription
Feds probe Jacksonville, FL process blast
Feds probe Jacksonville, FL process blast RUNAWAY By ANTON RIECHER P.O. BOX 9161, COLLEGE STATION, TX 77842 PRSRT STD US POSTAGE PAID Permit #204 Bollingbrook, IL Nov-Dec09a.pmd PLUS: • IFW posts program for February conference • Delaware refinery fire blamed on corrosion • Federal court orders fire fighting foam recall Volume 24, No. 6 November-December 2009 1 11/3/2009, 9:39 AM 2 INDUSTRIAL FIRE WORLD Nov-Dec09a.pmd 2 11/3/2009, 9:40 AM IFW CONTENTS DEPARTMENTS 6: COVER STORY RUNA WAY RUNAW 4: Dave’s Notes By David White We must look to the past and have a “what if” future perspective as we report on potential disasters. COVER SHOT: Jacksonville Fire & Rescue Department firefighters mount a foam attack on the blazing aftermath of a reactor explosion involving six tons of gasoline additive in December 2007. Federal investigators blamed the explosion on a cooling system failure. Photo by Mark Treglio 8: Incident Log 30: Industry News Federal investigators blame failure to recognize the runaway reaction hazard in making a specific gasoline additive as a root cause of the T2 Laboratories explosion and fire in Jacksonville, FL, in December 2007. 13: Attack Strategy An injured survivor using his cell phone to plead for help forced responders at T2 to act instantly. 18: History of Violence Federal investigators cite four runaway reactor accidents similar to T2 in the last 11 years. 5: Point of Penetration 3M offers new fire barrier duct wrap to meet ASTM E 2336 standard. 26: Means of Protection Personal protective equipment traces its origins back as far as humanity’s will to survive. 20: Rust Never Sleeps Fire officials blame a May 2009 fire at a New Jersey-Delaware refinery on pipe failure due to corrosion. 21: 2010 IFW Conference Program Baton Rouge conference in February covers diverse topics from spill response & emerging fuels to EMS. 28: Fire Fighting Encounters International Fog’s First Attack piercing fog nozzle tested to deliver carbon dioxide extinguisher. 30: U.S. Foam Recall Ordered Product mislabeled with UL identifier assigned to competing foam maker. Technical Consultant Louis N. Molino, Sr. Hazmat Contributor John S. Townsend, Ph.D. EMS Contributor Bill Kerney Risk Contributor John A. Frank Publisher David White Editor Anton Riecher Marketing Manager Lynn White Associate Editor Kendra Graf Bookkeeper Cyndie Norman NOVEMBER-DECEMBER 2009 Volume 24 Number 6 31: Focus on Hazmat By John S. Townsend To be functional, a contingency plan must be fleshed out with at least ten essential elements. 34: Risk Assessment By John Frank Safety concerns are driving more chiefs to consider defensive rather than offensive fire operations. 35: EMS Corner By Bill Kerney Lathering your hands to the tune of “Happy Birthday” is one way to battle the outbreak of H1N1. 36: Industrial Service Directory 38: Spotlight Ads INDUSTRIAL FIRE WORLD® SINCE 1985 (ISSN 0749-890X) P.O. Box 9161/540 Graham Rd. College Station, TX 77842/45 (979)690-7559 FAX (979)690-7562 E-MAIL [email protected] WEB SITE www.fireworld.com Industrial Fire World, Nov.-Dec. 2009, Volume 24, No. 6. Industrial Fire World (ISSN 0749-890X) is published bimonthly by Industrial Fire World, Inc., P.O. Box 9161, College Station, Texas 77842. (979) 690-7559. Fax: (979) 6907562. E-mail: [email protected]. All rights reserved under International Convention. Copyright © 2009 by Industrial Fire World Inc., all rights reserved. Industrial Fire World is a registered trademark of David White Investments, Inc., College Station, Texas. The design and content are fully protected by copyright and must not be reproduced in any manner without written permission of the publisher. Bulk rate postage paid at Fulton, MO, and additional mailing offices. Subscription rates: USA, one year $29.95, two years $49.95, and three years $59.95; Canada and foreign, add $20 per year postage. Single copies $6. Back issues available at $6 a copy plus postage. Payment must accompany orders for single copies. All inquiries regarding subscription problems, change of address and payments, call (979) 690-7559. Please allow six to eight weeks for your first subscription copy to be shipped. Please state both old and new addresses when requesting an address change and notify us at least six weeks in advance. (If possible enclose subscription address label.) Industrial Fire World is edited exclusively to be of value for people in the industrial fire protection field. Subscriptions are reserved to those engaged in the area of industrial fire protection and related fields or service and supply companies’ personnel. Address advertising requests to Marketing Director, Industrial Fire World, P.O. Box 9161, College Station, Texas 77842. (979) 690-7559. Advertising rates and requirements available on request. Editorial Information: Industrial Fire World welcomes correspondence dealing with industrial fire and safety issues, products, training and other information that will advance the quality and effectiveness of industrial fire and safety management. We will consider for publication all submitted manuscripts and photographs. All material will be treated with care, although we cannot be responsible for loss or damage. Submissions should be accompanied by a stamped, self-addressed envelope. (Any payment for use of material will be made only upon publication.) Industrial Fire World assumes no responsibility for the return of unsolicited manuscripts or photographs. Industrial Fire World reserves the right to refuse any editorial or advertising material submitted for publication. Information and recommendations contained in this publication have been compiled from sources that are believed to be reliable and representative of the best current opinion on various topics. No warranty, guarantee, or representation is made by Industrial Fire World as to the absolute validity of sufficiency of information contained within the publication. Industrial Fire World assumes no responsibility for statements made by contributors. Advertising in Industrial Fire World does not imply approval nor endorsement by Industrial Fire World. Printed in the USA. CPC publication number 40801529. Postmaster: Send address changes to Industrial Fire World, P.O. Box 9161, College Station, Texas 77842. For subscription inquiries call: (979) 690-7559. NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 3 11/3/2009, 9:40 AM 3 DAVE’S NOTES The more things change ... By DAVID WHITE O n October 23, an explosion with the force of a 2.9 magnitude earthquake and the resulting fire destroyed 11 tanks at a 40-tank petroleum storage facility near San Juan, Puerto Rico. Over the next two days flames spread through at least six more tanks containing jet fuel, bunker fuel and gasoline in one of the largest fires ever in the U.S. Caribbean island territory. No deaths were reported but at least two people were hurt. Strangely enough, the date also marked the 20th anniversary of Pasadena Chemical Complex explosion and fire near Houston, TX (See “Wrong Pasadena,” SeptemberOctober 2009). The initial blast registered 3.5 on the Richter scale. The conflagration took 10 hours to bring under control. Some 23 workers were killed and 314 were injured. Rather than blowing up a fuel storage terminal in Puerto Rico, I would rather have celebrated the Pasadena anniversary quietly. Maybe not as quietly as the Houston news media though. A quick survey of the for newspapers web sites in Houston and Pasadena, together with the web sites for all the major Houston television stations, revealed not one mention commemorating the worst industrial disaster in U.S. history in the past 60 years. Granted, the U.S. has a lot on its plate right now — health care reform, the economy, swine flu, Iraq, Afghanistan and wayward airline pilots who can not find Minneapolis. Industrial Fire World is entering its 25th year of service to our namesake. What have we learned over the years? We must look to the past and have a “what if” future perspective as we report on potential disasters. A few examples: • Whiting, IN - 1955: An explosion in an oil refinery hydroformer triggered an eight day fire that spread through 67 storage tanks. We learned that one tank boilover can destroy a total refinery. • Sunray, TX - 1956: A little known refinery disaster that still ranks only three places behind 9/11 in the record for firefighters killed. You must address impinging fire on a pressure vessel in the vapor space and the dangers of pumping out liquids during the fire. • Philadelphia, PA - 1975: A refinery fire that killed eight. The incident commander must have the big picture of what is going on in a fire and monitor the liquid levels in the dike because overflowing dikes put flammable liquid under personnel outside the dike. Also, a covered floating roof tank can boil over as much as two weeks after the initial fire. For the 50th anniversary of the Sunray incident, the refinery joined with the community to hold a dinner honoring the relatives of the survivors. A special display case for memorabilia related to the disaster was dedicated the refinery’s new fire station. In contrast, unfortunately, the Pasadena anniversary, passed without a glimmer of interest from the hometown press. Tiny Sunray, population 1,950, seems to have a longer memory as a community than Pasadena, population 146,518. We would have written the articles about Whiting, Sunray and Pasadena regardless. As poet and philosopher George Santayana said, “Those who cannot remember the past are condemned to repeat it.” Sure, the technology and procedures change. And, yes, we also work to keep you updated on the latest developments. But, more important, the mind set that leads to industrial catastrophe past and present too often remains the same. Some moment of carelessness or, worse, incompetence, begins a cascade of events that in the end gets someone killed. A decision based on false economy, such as delaying fire training, results in the loss of the entire facility. I hope your focus in 2010 will be to learn from the expertise of your peers who have “battled the dragon” and from those developing strategies and technology to meet today’s emerging issues by joining us for the 25th Industrial Fire World conference C in Baton Rouge. www.fireworld.com 4 INDUSTRIAL FIRE WORLD Nov-Dec09a.pmd 4 11/3/2009, 9:40 AM 3M introduces new fire barrier duct wrap Point of Penetration By ANTON RIECHER IFW Editor T o meet the most stringent standard being enforced nationally for grease duct fire protection, 3M Company introduced a lighter and less dense fire barrier duct wrap in September to compete with traditional fire protection such as gypsum wallboard shafts and other bulky wrap systems. Jenny Hicks, marketing manager for Fire Protection Products with 3M Building and Commercial Services Division, said that 3M Fire Barrier Duct Wrap 615+ was developed specifically to meet the new ASTM E 2336 test standards referenced in the 2009 Edition of the International Mechanical Code. “UL 1978 was the original test standard for grease duct protection that was referenced in the building code,” Hicks said. “However, part of the country was using a more rigorious test standard known as ASTM E 2336.” Testing agencies responsible for the model building codes adopted by more jurisdictions opted to move to the tougher ASTM E 2336 test standard. As a result, 3M replaced its previous fire barrier duct wrap designated 15A with the new 3M Fire Barrier Duct Wrap 615+ product. The new standard requires that grease duct enclosure systems resist combustion when exposed to 1,382 degrees F. Fire Barrier Duct Wrap 615+ is a lightweight, thin-profile insulation product that provides up to two hours of fire protection for grease and air ventilation ducts by resisting maximum temperature of up to 2,192 degrees F. 3M Fire Barrier Duct Wrap 615+ installed around duct creates a fire-resistive barrier that maintains the duct integrity and helps prevent fire from rapidly spreading throughout a building. ASTM E 2336 requires two layers of fire protection material are necessary around grease ducts in jurisdiction that have adopted the 2009 IMC or the 2008 edition of NFPA 96. “There are different ways to protect a grease duct,” Hicks said. “You can use a gypsum rock wall around the grease duct or you can use a prefabricated duct which provides another layer of metal around the duct with additional insulation inside.” The advantage of using duct wrap instead is zero clearance, Hicks said. “A gypsum wall is combustible,” she said. “If you chose to protect a grease duct with it you have to have 18 inches of clearance between them. If there are space constrains a zero clearance product such as 3M Fire Barrier Duct Wrap 615+ is very important.” The new 3M product weighs only six pound per cubic foot, about two pcf lighter than previous wraps on the market. However, depending on insulation alone presents problems. Fire Barrier Duct Wrap 615+ is only part of an overall 3M system of duct wraps and sealants designed to better protect industrial facilities. “When a grease duct crosses a fire rated wall or floor, the situation becomes more complicated,” Hicks said. “We call that a point of through penetration.” Using special chalks in conjunction with the duct wrap prevents fire from passing through the point of penetration, she said. “We like to talk about the value of our whole system, not just protecting the duct but protecting the points of through penetration that ducts create,” Hicks said. C For further reference, the website is www.3m.com/firestop. NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 5 11/3/2009, 9:40 AM 5 Above, the explosion is captured by an infrared camera more than four miles away. The cooling towers to the right of the blast are at a nearby power station. On December 19, 2007, a process reactor containing six tons of gasoline additive blew apart in Jacksonville, FL, killing four employees and injuring 28 people. A federal report attributes the disaster to a failure in the reactor’s cooling system. It also blames failure to recognize the runaway reaction hazard associated with the product being manufactured. 6 RUNAWAY By ANTON RIECHER IFW Editor A loud jet engine-like sound drew startled attention from businesses neighboring the T2 Laboratories chemical plant one afternoon in December 2007. Eyewitnesses reported high pressure venting from the top of a 2,450-gallon batch reactor designed to produce a specialized gasoline additive. Within moments, the reactor violently ruptured with a force equivalent to 1,420 pound of TNT. “The incident at T2 Laboratories included one of the most powerful explosions that the CSB (U.S. Chemical Safety and Hazard Investigation Board) INDUSTRIAL FIRE WORLD Nov-Dec09a.pmd 6 11/3/2009, 9:40 AM At left, the T2 Laboratories facilities are consumed by flames after a December 2007 explosion. At right, a four-inch diameter agitator shaft from the exploded reactor imbedded in a sidewalk 350 feet away. Below, Jacksonville Fire and Rescue Department Capt. Kurt Wilson, left, confers with Lt. Todd Smith during the fire. Wilson and Smith are the leading hazmat instructors with the department. At bottom, a 2,000 pound portion of the three-inch thick reactor that damaged a building 400 feet from the explosion. Photo Courtesy of Steve Gerbert Photo Courtesy of Steve Gerbert Photo Courtesy of Steve Gerbert Photo Courtesy of Steve Gerbert The company might have has ever investigated, a blast • Firefighters search hot zone for blast survivor, Page 13 that was felt 15 miles away in • Feds cite four reactor runaways similar to T2, Page 18 survived if management recognized the runaway reaction downtown Jacksonville (FL),” hazard associated with their product, said system was available. said CSB chairman John Bresland. Ordinarily, the CSB made specific safety CSB lead investigator Robert Hall. Four T2 workers, including a company “Had they understood this they might co-owner were killed in the blast. Four recommendations regarding the process other T2 employees and 28 workers at under investigation. Instead, this report have chosen to design and operate their made wide ranging recommendations to process differently,” he said. nearby businesses were also injured. The blast damaged other businesses better educate chemical engineers with within one quarter mile of the facility. Four regard to chemical reactive hazard damaged buildings were subsequently awareness, Bresland said. condemned. Debris landed up to one mile “We would have made different away. recommendations had the company still A report issued by the CSB in September been in operation,” he said. “But the 2009 blamed the disaster on a runaway company was basically destroyed by the exothermic reaction following a breakdown explosion. There wouldn’t be any point in in the reactor’s cooling system. No making recommendations to the emergency backup to the primary cooling company.” NOVEMBER-DECEMBER 2009 7 Nov-Dec09a.pmd 7 11/3/2009, 9:40 AM Sept. Incident Log Underlined items denote fatalities Sept. 1 – Florence, AL: A machine that makes landscaping mats caught fire at a factory. Sept. 1 – Joshua, TX: A fire near a gas well site destroyed expensive support equipment. Sept. 1 – Macomb, IL: Firefighters dealt with leaking anhydrous ammonia that forced the evacuation of several homes and businesses. Sept. 1 – Malgobeck, Ingushetia: A trunk gas pipeline exploded. Sept. 1 – Nahariya, Israel: Toxic gas leaking from a factory forced police to close nearby roads. Sept. 1 – North Sea, Denmark: An oil platform shutdown when cracks were found in an underwater oil storage tank. Sept. 1 – Quezon City, Phillippines: Fire destroyed a factory which produced plywood. Sept. 1 – Priest River, ID: Chlorine gas leaking from a water treatment plant forced the evacuation of the downtown area. Sept. 1 – Ringwood, Australia: An explosion rocked a recycling plant, injuring a worker. Sept. 2 – Cibolo, TX: A worker welding was injured in an explosion and fire that heavily damaged a warehouse. Sept. 2 – Coosa, GA: A worker at a timber processing plant suffered sulfuric acid burns. Sept. 2 – East Providence, RI: An equipment fire broke out at a metals recycling plant. Sept. 2 – Flaxweiler, Luxemburg: Fire erupted in a biogas plant. Sept. 2 – Great Falls, MT: A fire at an oil refinery triggered by a hydrogen explosion was quickly extinguished. Sept. 2 – Haridwar, India: Fire spread through an electronics plant. Sept. 2 – Jinlan, China: 18 people died and 10 were injured in an explosion involving a lacquer-curing agent being unloaded from a truck. Sept. 2 – Mangalore, India: Several fires broke out in an electrical substation supplying an effluent treatment plant at an oil refinery. Sept. 2 – Nampa, ID: A small fire broke out at a meat packing plant. Sept. 2 – Pointe-a-Pierre, Trinidad & Tobago: A breakdown in a sulfur recover unit at an oil refinery led to an evacuation. Sept. 2 – Prawes, Thailand: A paint factory worker was injured in a fire. 8 8 Photo Courtesy of Steve Gerbert Billowing flames dwarf the woods adjoining the T2 Laboratories site. METALATION Prior to 2004, T2 Laboratories, Inc., a small privately-owned corporation, concentrated primarily on blending solvents used in the printing industry. Other than issues of inherent flammability, these solvents remained non-reactive when blended into solution as needed. Manufacturing methylcyclopentadienyl manganese tricarbonyl (MCMT), an organomanganese compound used as an octane-increasing gasoline additive, was T2’s sole reactive chemical process, Hall said. The additive was marketed under the brand name Ecotane. “It was much more hazardous than the other processes they were performing at this site,” he said. Before 2001, T2 blended premanufactured MCMT to specified concentrations for a third-party distributor. That year, T2 moved from a downtown warehouse to a site in a north Jacksonville industrial area where construction began on an MCMT process line. “The seeds were planted the first day they operated,” Hall said. “That ultimately led to the explosion.” Although both of T2’s owners – a chemical engineer and a chemist – had prior chemical industry experience, neither had previously worked with reactive chemical processes. “The owners who developed the process did not fundamentally understand the hazard of the material they were dealing with,” Hall said. “They did not understand the runaway reaction potential that existed.” Utilizing a patent dating back to the 1950s, the owners developed a three-step process for making MCMT within a single process reactor. After running more than 100 test batches in a one-liter glass reactor, T2 moved to the north Jacksonville site. “My guess is that the laboratory testing was more involved with improving the process, making sure they were getting a good quality material and good yields,” Hall said. T2 hired consulting engineers to assist in the process design, control system engineering and project management. Due to limited funding, T2 purchased and refurbished used equipment, including a 12-foot high, seven-foot diameter reactor originally built in 1962. Modifications to the reactor reduced the maximum allowable working pressure from 1,200 psig (pounds per square inch) to 600 psig. A four-inch vent pipe connecting to a rupture disk provided INDUSTRIAL FIRE WORLD INDUSTRIAL FIRE WORLD Nov-Dec09a.pmd 8 11/3/2009, 9:40 AM overpressure protection for the reactor. T2 employees told the CSB that the rupture disk was set at 400 psig. “Had they done thermal hazard evaluation testing, which is very specific to the task, they could have properly designed the reactor relief system,” Hall said. Three of the first 10 full scale MCMT batches using the revamped reactor resulted in unexpected exothermic reactions, all during metalation, the first step in the process. In each instance the batch recipe was slightly different. T2 did not repeat batch recipes to isolate the problem. Instead, they changed recipes in each of the first 10 batches, the CSB report stated. “Records we reviewed show that in some early production batches there were excursions that took the temperature higher than the normal operating temperature,” Hall said. “In each case the plant was able to get the reaction back under control, primarily through cooling. In the first 10 batches there were three of these events.” T2 announced successful commercial Incident Log (Continued) Sept. 2 – Ste-Therese, QC: Nearby residents were evacuated when chemicals leaked at a building materials plant. Sept. 2 – Tampa, FL: Lightning that struck nearby injured a worker operating a 130foot crane at a lime rock quarry. Sept. 2 – West Point, GA: About 200 workers at a new auto plant were moved after a city fire official raised a safety issue. Sept. 3 – Chantenay District, France: Fire broke out inside a grain silo. Sept. 3 – Clairton, PA: A contract employee doing maintenance in the gas cleaning area of a steel plant coke works died in an explosion. Diagram Courtesy of CSB Sept. 3 – Claypool, IN: An equipment fire broke out at a plant that processes soybean and biodiesel products. operation to its stakeholders in 2004 after Batch 11. “They had these near misses but the response was not to investigate the hazard further, just begin making another batch,” Hall said. With Batch 42 in July 2005, T2 increased Sept. 3 – Dhaka, Bangladesh: An ammonia leak at a cold storage plant made 13 workers ill. Sept. 3 – New Bedford, MA: Fire threatened to spread throughout a printing plant. Sept. 3 – Rio Claro, Brazil: A fire in a storage tank at an ethanol plant killed a worker. NOVEMBER-DECEMBER 2009 9 NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 9 11/3/2009, 9:40 AM 9 Incident Log (Continued) Sept. 3 – Shan-dong Province, China: An explosion in a chemical plant killed at least 18 workers and injured 10 more. Sept. 3 – Uzice, Serbia: 4 explosions ripped through a munitions plant, killing 6 workers. Sept. 3 – Warsaw, IN: An explosion severely burned a worker at a plant making orthopaedic surgical products. Sept. 4 – Canton, PA: The second fire in 3 months broke out at a recycling plant. Sept. 4 – Greymouth, New Zealand: A subcontractor welding atop a storage tank at a bitumen plant died in an explosion. Sept. 4 – Hebbagodi, India: 2 workers died when a vessel exploded at a chemical plant. Sept. 4 – Marifu, Japan: A lightning strike knocked out power to an oil refinery, forcing a two-day shutdown. Sept. 4 – Markdale, ON: Welding work was being done when fire broke out that destroyed an ice cream plant. Sept. 5 – Ampang district, Malaysia: Fire spread through seven factories at an industrial park, including an aluminum manufacturing plant and a recycling center. Sept. 5 – Bergkamen, Germany: A tank of alkyl aluminium exploded at a pharmaceutical plant. Sept. 5 – Fehring, Austria: More than 50 gallons of diluted hydrochloric acid leaked from a storage tank at a printed circuit manufacturer. Sept. 5 – Karachi, Pakistan: 4 firefighters suffered burns battling a fire at a towel factory. Sept. 5 – Middleboro, KY: An ammonia spill at a meat processing plant polluted a downtown canal, killing fish. Sept. 5 – Newman, GA: Fire destroyed a plant making molded flexible products. Sept. 5 – Philadelphia, PA: A food processing plant was evacuated when xylene fumes spread through the building. Sept. 5 – Vanderbijlpark, South Africa: A steel plant worker died in an explosion. Sept. 6 – Allentown, PA: A plant making industrial valves was damaged by a fire that destroyed 2 nearby buildings. Sept. 6 – Aston, PA: A foul odor emanating from a chemical plant forced the evacuation of an adjoining business. Sept. 6 – Johor Baharu, Malaysia: Fire destroyed a plastics manufacturing plant. Sept. 6 – Manheim Twp., PA: Spilled molten metal spread fire through an aluminum plant. 10 10 Nov-Dec09a.pmd Photo Courtesy of Mark Treglio Firefighters move through the wreckage at T2 following their foam attack. the batch size from four to six tons. No records exist of additional chemical or process analysis conducted as part of the recipe change. A greater volume of reactants increased the energy that the reaction could produce, likely altering the cooling and pressure relief requirements, the CSB report stated. Hall compared the management situation to the loss of the Space Shuttle Challenger in January 1986. “It’s a reoccurring theme in accident investigation,” he said. “In the Challenger accident you had the failure of the O-ring that led to the explosion of the shuttle. They had prior failures of the O-ring but normalized it. There wasn’t an explosion, so they did the same thing again.” At T2, because operators were able to cope with these unexpected temperatures with applied cooling, the company normalized the situation, continuing to do the same thing rather than mounting an investigation into what was happening, Hall said. At 7:30 a.m. on December 19, 2007, production of T2’s 175th batch of MCMT began. The process required both heating and cooling. Hot oil circulated through three-inch piping installed around the inside of the reactor. For cooling, water injected into a jacket covering the lower three quarters of the reactors was allowed to boil, the steam venting through an open pipe connected to the top of the jacket. The capacity of the cooling system exceeded that of the hot oil system by a margin of 10-to-1. Each MCMT production step required the process operator to add raw materials and adjust heating, cooling and pressure using a computerized process control system. In the metalation reaction, the process operator fed a mixture of methylcyclopentadiene (MCPD) dimmer and diethylene glycol dimethyl ether (diglyme) into the reactor. An outside operator then hand-loaded blocks of sodium metal through a six-inch gate valve on top of the reactor. At about 11 a.m., the process operator began heating the mixture, setting the reactor pressure control at 50 psig (3.45 bar) and hot oil temperature control at 360 degrees Fahrenheit. The melted sodium reacted with the MCPD to form sodium methylcyclopentadine, hydrogen gas and heat. The hydrogen gas vented to the atmosphere through a pressure control valve and one-inch vent line. Once the mixture temperature reached 210 degrees, the process operator started the agitator. The mixing and higher temperature both increased the metalation reaction rate. At 300 degrees, the operator turned off the hot oil system as specified by established procedure. Heat generated by the metalation reaction continued to raise the mixture temperature. Once the process reached 360 degrees, the operator initiated the control system cooling program, which intermittently INDUSTRIAL FIRE WORLD INDUSTRIAL FIRE WORLD 10 11/3/2009, 9:40 AM Incident Log (Continued) Sept. 6 – Pu’unene, Hawaii: A fire at a cement plant caused massive damage. Sept. 6 – Richmond, RI: Fire in a mulch pile created thick smoke at a sand and gravel plant. Sept. 7 – Catoosa, OK: Flames at a filter plant warehouse sent three firefighters to the hospital for heat-related injuries. Sept. 7 – Dayton, OH: A hopper railcar caught fire at an agricultural processing plant. Sept. 7 – Mexico City, Mexico: Fire spread through paper stored at a printing plant. Sept. 7 – Tuttlingen, Germany: A factory fire threatened to spread to a nearby supermarket and gas station. Photo Courtesy of Steve Gerbert Flames at T2 Laboratories threatened tankers and tube trailers parked on site. injected water into the jacket. Investigators suspect that a single point failure in the cooling system left the operator powerless to control the increasing heat. No emergency source of cooling existed. “Had they recognized the hazard up front and designed a cooling system that was more robust and had more redundancy, that could have prevented the accident,” Hall said. At 1:23 p.m., the process operator asked an outside operator to contact the owners, who were off site. Within minutes, the owners returned. The owner/chemical engineer reported to the control room to assist while the owner/chemist searched for the plant mechanic. An outside operator en route to the control room to investigate multiple process alarms was met halfway by the owner/chemical engineer who said he thought there would be a fire. The owner/ chemical engineer motioned employees away from the reactor before returning to the control room. At 1:33 p.m., the reactor’s relief system could no longer control the rapidly increasing temperature and pressure. The three-inch thick reactor ruptured, its contents exploding. Flames also spread through the other flammable processes and storage at the facility. “It was just a matter of time with the various batches that one got far enough out on the parameter to cause an explosion,” Hall said. ANALYSIS CSB investigators determined that insufficient cooling was the only credible cause for this incident, ruling out cross contamination, wrong concentration of raw materials, local concentration of chemical within the reactor and application of excessive heat. “We likely had a cooling system failure,” Hall said. “They were unable to apply sufficient cooling, leading to the result we had.” Witness statements confirm that the process operator reported a cooling problem shortly before the explosion. The cooling system lacked design redundancy, making it susceptible to single point failures. Employees indicated that T2 did not perform preventive maintenance on the cooling system, replacing components only after failure. On at least one prior occasion, the reactor cooling drain valve failed during operations and required repair. Formation of mineral scale inside the jacket could have interfered with heat removal. Also, loose scale could have blocked the inlet/drain pipe, causing it to stick open. CSB conducted laboratory tests based on the T2 chemical recipe using a small sample size to minimize potential hazards. Two exothermic reactions were observed. The first reaction occurred at about 350 degrees as desired. A second more energetic reaction occurred when the Sept. 7 – Xigu District, China: More than 100 people became sick from fumes leaking from a chemical plant processing waste oil. Sept. 8 – Bolton, UK: Responders battled an arson fire at a plastics manufacturing plant. Sept. 8 – Brockport, NY: A steel tank being moved at a former plant site ruptured, spilling 100 gallons of an unknown liquid. Sept. 8 – Broomfield, CO: Responders allowed a fire in an unstable stack of trees at a recycling center to burn itself out. Sept. 8 – Calgary, AB: 2 workers using extinguishers put out a fire in a commercial oven at a furniture factory. Sept. 8 – Doral, FL: High levels of carbon monoxide generated by forklifts made 8 warehouse workers ill. Sept. 8 – Frodsham, UK: More than 50 gallons of sodium silicate spilled from a truck, closing a major roadway for hours. Sept. 8 – Goor, Netherlands: At least 8 workers were affected by ammonia leaking from a tank being disassembled at a plant that processes butchery waste. Sept. 8 – Huntington, WV: More than 50,000 pounds of aniline spilled while being unloaded at a pigments plant, injuring a worker. Sept. 8 – Karratha, Australia: A worker at an LNG plant was seriously injured while unloading pipe from a vessel. Sept. 8 – Lake City, FL: A tractor-trailer carrying hazardous materials overturned and caught fire. Sept. 8 – Larymna, Greece: A metals plant worker splattered with molten ore in late August died from his injuries. Sept. 8 – Manchester, UK: Fire swept through inventory at a plastics factory. NOVEMBER-DECEMBER 2009 NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 11 11/3/2009, 9:40 AM 11 11 Incident Log (Continued) Sept. 8 – Melbourne, Australia: Fire destroyed a carpet factory. Sept. 8 – Shriopshire, UK: Fire broke out at a tire recycling plant. Sept. 8 – Wuxi City, China: More than 300 workers at a pipe manufacturing plant were overcome by food poisoning. Sept. 9 – Baton Rouge, LA: A leaking flange caused a small fire at an oil refinery. Sept. 9 – Bolton, UK: 2 vehicles parked in an industrial park were set ablaze by vandals. Sept. 9 – Canal Fulton, OH: An orthopedic surgeon helped rescue a meat processing plant worker who caught his arm in a grinder. Sept. 9 – Caramut, Australia: Molten sulfur spilled into a creek when a truck overturned. Sept. 9 – Cedar Rapids, IA: Sprinklers suppressed a fire at a manufacturing plant when an electrical transformer exploded. Sept. 9 – Chiba, Japan: An oil leak at a refinery led to a fire in the crude distillation unit. Sept. 9 – Colusa County, CA: Fire ignited in a rice dryer at an agricultural processing plant. Sept. 9 – Dummerston, VT: The sprinkler system in a paper plant warehouse held a fire in check until responders could arrive. Sept. 9 – Houthalen, Belgium: Nitric acid vapor was released from a ventilation shaft at a recording plant. Sept. 9 – Lake Park, IA: Fire destroyed a warehouse at an animal feed processing plant. Sept. 9 – Menomonee Falls, WI: A machine designed to wash parts caught fire and burned at a motorcycle manufacturing plant. Sept. 9 – Norit, TX: Welding work at a carbon manufacturing plant triggered a fire. Sept. 9 – Oldbury, UK: Flames spread through a historic brewery. Sept. 9 – Topsham, ME: Lack of water hindered firefighters battling a metal recycling plant fire. Sept. 9 – Wem, UK: Heavy equipment was used to separate waste material burning at an industrial park. Sept. 9 – West Heidelberg, Australia: Nearly a ton of glass panes fell in a domino effect, crushing a glass plant worker to death. Sept. 9 – Zaporizhia District, Ukraine: 3 people were injured in a fire that spread through a car plant. 12 12 Nov-Dec09a.pmd temperature exceeded 390 degrees. Pressure from that second reaction overwhelmed the reactor’s pressure relief system designed for normal operating conditions. The CSB report stated that it was unlikely the T2 owners were aware that reaction would occur. “In a perfect world, T2 would have done sophisticated testing that we did after the accident,” Bresland said. “Then, based on that, T2 would have designed the process in such a way that, for example, there would have been a backup cooling system,” Bresland said. The pressure and temperature rise during the second exothermic reactions was about 32,000 psig per minute (2,206 bar per minute) and 2340 degrees per minute. This was sufficient to burst the test cells. It is unlikely that an overpressure relief device of any size set at 400 psig could have prevented the reactor failure during the second exothermic reaction, the CSB report stated. Had T2 set its four-inch reactor rupture disk at 75 psig, rather than the 400 psig used, the runaway reaction likely would have been relieved during the first exothermic reaction, precluding the second. “Had they done thermal hazard evaluation testing, which is very specific testing to the task, they could have properly designed the relief system to better protect the reactor,” Hall said. All three steps of the MCMT process involved toxicity, flammability or reactivity hazards. A literature search by CSB found little published information on the production of MCMT other than the patents and no published information specific to its reactivity hazards. That lack of process hazard information made laboratory testing especially important, the report stated. Initial testing done by T2 did not observe extreme exothermic behavior. Test temperatures never exceeded 380 degrees. However, the one-liter laboratory reactor did not accurately indicate the amount of cooling needed in the full-scale T2 reactor. “The thermal hazard evaluation testing that CSB performed is a specialized group of tests that is done by a very small number of companies across the U.S.,” Hall said. “These tests look at the heat produced and the reaction rate. We have used these tests in a number of cases to replicate chemistry that occurred in similar types of runaway reaction accidents.” The owner/chemical engineer held a bachelor’s degree in chemical engineering and was active in his university’s engineering curriculum advisory board. However, most baccalaureate chemical engineering curricula in the U.S. do not specifically address reactive hazard recognition or management, a survey by Texas A&M University’s Mary Kay O’Connor Process Safety Center revealed. Of the universities surveyed by the center, only 11 percent required process safety education in the core baccalaureate curriculum. An additional 13 percent offered an elective process safety course. RECOMMENDATIONS The CSB recommended that the American Institute of Chemical Engineers and the Accreditation Board for Engineering and Technology, Inc., work together to add reactive hazard awareness to baccalaureate chemical engineering curricula requirements. It also recommended that the AIChE inform all student members about its Process Safety Certificate Program, encouraging participation. A report on reactive hazard management issued by the CSB in 2002 documented 167 serious reactive incidents in the U.S. between January 1980 and June 2001 that resulted in 108 deaths and hundreds of injuries. At least 35 percent of those incidents were due to runaway reactions similar to the one at T2. Many of those incidents were at small manufacturing sites similar to T2, the report stated. Four previous runaway reaction incidents investigated by the CSB since 1998 resulted in 10 deaths and more than 200 injuries. Only one other company in the U.S. manufactures MCMT, Bresland said. That company, a market leader in fuel and lubricant additive research, development and manufacturing, was the originator of the MCMT patent. “We don’t know what their process is like but they have not had an incident so we assume they are doing things the right C way,” he said. INDUSTRIAL FIRE WORLD INDUSTRIAL FIRE WORLD 12 11/3/2009, 9:40 AM Incident Log RUNAWAY (Continued) Attack Strategy Sept. 10 – Buffalo, NY: 7,000 gallons of jet fuel spilled from an overturned tanker truck onto one of the busiest roads in the region. Sept. 10 – Capitol Heights, MD: Hazardous materials were involved in an explosion and fire at a commercial warehouse. Firefighters search hot zone for injured T2 survivor By ANTON RIECHER IFW Editor A voice pleading on a cell phone forced firefighters to risk entering the blazing T2 Laboratories complex soon after a reactor processing six tons of gasoline additive blew apart, said hazardous materials responder Kurt Wilson. “He said he was trapped by the fire,” Wilson said. “We had people trying to find him but they couldn’t.” Only one option remained — mount a quick attack with foam, not to extinguish the fire but to open a window through the flames to locate the badly injured worker, said Wilson, a captain with the Jacksonville (FL) Fire and Rescue Department’s hazardous materials team. Debris from the December 2007 reactive chemical explosion at T2 Laboratories landed up to a mile away, a U.S. Chemical Safety Board report stated. Businesses within a quarter mile radius were badly damaged, including four buildings that were ultimately condemned. Sept. 10 – Carlyss, LA: Nearly 100 barrels of crude oil leaked from an underground storage line. Four T2 personnel died. Four other T2 employees and 28 workers at nearby businesses were also injured. Responders arriving at a disaster scene such as T2 usually depend on personnel on site to gain a quick grasp of the hazards involved, Wilson said. “When we arrived 100 percent of the workers were killed, trapped or en route to the hospital,” he said. Sept. 10 – Lavera, France: Four chemical plant workers were overcome by a leak of dichlorethane. Sept. 10 – Logan County, WV: Flames engulfed a five-story coal preparation plant. Sept. 10 – Madison, WI: 30 tons of cardboard burned in a recycling plant fire. Sept. 10 – Mount Airy, NC: Fire spread through the ductwork of a textile plant. Sept. 10 – Sharjah, UAE: 8 warehouses stocked with petrochemicals burned in an industrial district. COME TOGETHER Covering 840 square miles, Jacksonville is the largest city in land and water area in the contiguous United States. The Jacksonville Fire & Rescue Department (JFRD) is the country’s 14th largest fire department. A staff of 1,200 firefighters and emergency medical personnel protects a population of 850,000. Jacksonville, a major transportation hub, is home to a wide variety of industries. “Jacksonville is an industrial city,” Wilson said. “There is no way to keep up with every process in use.” The St. Johns River that splits the city also divides the JFRD into two battalions. Sept. 10 – South Gate, CA: A fire erupted in an asphalt tank being dismantled at a roofing company. Sept. 10 – Springs, South Africa: An explosion at a zinc refinery killed 3 contractors and injured 12 others. Sept. 10 – St. Austell, UK: Fire broke out in a bin at a chemical plant. Sept. 11 – Barrancabermeja, Colombia: Fire broke out at an oil refinery. Sept. 11 – Gainsborough, UK: Fire broke out in a storage silo at a plastics recycling plant. Sept. 11 – Jiyaguda, India: 2 people were injured in a fire that gutted a plastic recycling plant. Firefighters apply alcohol-resistant foam against the burning solvents at T2. Sept. 11 – Kingston, Jamaica: Nearly 300 tons of sulfuric acid spilled into the sea near Kingston Harbor produced an immediate fish kill. Sept. 11 – Melksham, UK: A fuel spill at a tire factory threatened to pollute the Avon River. Sept. 11 – Norwich, UK: 11 emergency workers were treated after a factory fire. Sept. 11 – Pudong, China: A worker died from inhaling toxic fumes after an explosion and fire in a waste oil pit at an oil refinery. Photo Courtesy of Steve Gerbert Sept. 12 – Jasper County, IL: Workers quickly brought a fire at a power plant under control. Sept. 12 – Jefferson County, OH: A faulty valve in the emissions control system at a power plant allowed ammonia vapor to leak. NOVEMBER-DECEMBER 2009 NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 13 11/3/2009, 9:40 AM 13 13 Incident Log (Continued) Sept. 12 – New Delhi, India: Flames destroyed a multi-story candle plant. Sept. 12 – Rio Grande City, TX: A 16-inch gas pipeline ruptured but crews were able to stop the supply and repair the line without igniting it. Sept. 12 – Studley, UK: Fire spread through 10 portable cabins at a factory site. Sept. 13 – Barton, AL: An opossium short circuited an electrical substation at a railcar plant. Exhaust from emergency generators then caught the roof of the building on fire. Sept. 13 – Bindlacher Berg, Germany: A massive fire broke out in rubber granules stored at a factory. Sept. 13 – Bucharest, Romania: Fire spread through a combined tire and chemical plant. Sept. 13 – Calgary, ON: An ammonia leak broke out at a chicken processing plant. Sept. 13 – Jaipur, India: 3 people died and 3 were injured in an explosion at a metal recycling factory. Sept. 13 – Robinson, IL: A small plane clipped a power line, leading to a shut down at an oil refinery. Sept. 13 – Talara, Peru: An explosion and fire in the heat exchanger area of an oil refinery burned three workers. Sept. 13 – Zhejiang, China: 3 people died and 17 were injured after exposure to hazardous waste at a chemical plant. Sept. 14 – Calgary, AB: An ammonia leak at a poultry plant shut down operations. Sept. 14 – Cambridge, OH: Hydrogen sulfide gas leaking from a gas well killed 1 worker and injured 4. Sept. 14 – Kilburn, Australia: An arrest for arson was made after fire spread through plastic bottles stored at a recycling plant. Sept. 14 – Votanikos, Greece: Fire gutted an ice cream factory. Sept. 15 – Cedar Rapids, IA: A cutting torch was in use when fire broke out on the roof of an electronics plant. Sept. 15 – Hunslet, UK: Butylacrylate was discovered leaking from a railroad tanker parked at an industrial facility. Sept. 16 – Aschau, Germany: An explosion rocked a chemical plant. Sept. 16 – Bilecik, Turkey: More than 60 tons of oil leaked from a pipeline damaged by an explosion. Sept. 16 – Clarines, Venezuela: Chlorine gas that leaked from a wrecked tanker truck killed 9 people and injured 326. Sept. 16 – Morrinsville, New Zealand: Responders sprayed water on a leaking container of liquid argon, causing it to ice over. 14 14 Nov-Dec09a.pmd Battalion 1 is east and south of the river while Battalion 2 is northwest. Nine district chiefs administer the city’s 53 districts, each with its own station and engine. JFRD also has 12 ladder trucks and more than 30 ambulances, referred to as rescues. Each battalion also has its own hazardous materials team, Wilson said. The Jacksonville Fire & Rescue Department is home to the nation’s first fire department-operated Hazardous Materials Response Team, established in 1977. Station 21, located on Jacksonville’s south side, serves Battalion 1, while Station 7, located in northwest Jacksonville, serves Battalion 2. “On the small stuff like gasoline spills at car accidents we operate separately,” he said. “On the big stuff, we come together. T2 obviously qualified for that.” On the afternoon of December 19, T2 Laboratories and JFRD Station 7 personnel found themselves working with radically different recipes. At T2 Laboratories, workers closely monitored a batch of specialty gasoline additive processing in a 12-foot high reactor vessel. Since January 2004, the refurbished batch reactor had been used 174 times to make the same additive. Meanwhile, on the fifth floor of Wolfson Children’s Hospital, the Station 7 hazmat team prepared to serve ice cream to the patients and staff in the cancer ward. Organized by a retired firefighter, the quarterly ice cream social had been a tradition for the hazmat responders for nearly four years. At 1:33 p.m., the reactor vessel at T2 exploded. Light from the blast was so intense that it blanked out video captured by an infrared surveillance camera four miles away for nearly 12 seconds. Then a slow, steady mushroom cloud was seen rising on a column of smoke that soon dwarfed the 640-foot tall cooling towers of a nearby power plant. Neither the sound nor concussion reached the children’s hospital 15 miles away. A rush of confused traffic on the hazmat team’s radios was the first indication of trouble. First reports linked the explosion to a transformer at the power plant. Another report involved an airplane crashing into the cooling towers. Finally, an off duty district chief nearby responded to the scene, tracing the blast back to T2. “He told the dispatcher, ‘This is going to a second alarm real quickly,’” Wilson said. “He said, ‘I’m at a chemical plant with multiple BLEVEs (boiling liquid expanding vapor explosion). I’ve got people injured.” He also asked for a hazmat response. Since T2 is in Batallion 2, Station 7 caught the call. The hazmat team, including Lt. Todd Smith and Lt. Chris Woods, made hasty apologies at the hospital and headed for their emergency vehicles. “We were downtown and T2 Laboratories is on the northside,” Woods said. “It was probably a 15 to 20 minute response easily.” Station 7 arrived at T2 to find the fiveacre facility divided into three main bodies of fire, he said. No water was being applied out of concern for the water reactive nature of chemicals known to be on site. Reactors used to blend solvents were venting to the atmosphere. However, the reactor that was the source of the blast was now scattered over a one mile radius. Two large steel support columns traveled about 1,000 feet in opposite directions. A 2,000-pound section of the three-inch thick reactor head damaged a building 400 feet away. The four-inch diameter agitator shaft from the reactor imbedded itself in a sidewalk 350 feet from the reactor. Pressure fires were apparent throughout the facility. BLEVEs involving trapped product continued to take place. “We had a couple of tractor trailers on fire,” Woods said. “We had a stack of conex shipping containers with fire and smoke coming from them. We had flame impingement on two MC-306 tankers. We also had a tube trailer on fire with the pressure release device going off.” Private vehicles in the parking lot were also burning. Smoke from the fire carried an extremely acrid odor, Woods said. Hazmat responders broke out air monitoring equipment and weather stations to track wind direction. Firefighters donned full bunker gear complete with self-contained breathing apparatus. EPCRA No one was sure what various chemicals INDUSTRIAL FIRE WORLD INDUSTRIAL FIRE WORLD 14 11/3/2009, 9:40 AM Incident Log (Continued) Sept. 18 – Trostberg, Germany: Nitric acid leaked from a ruptured pipe at a chemical plant with firefighters using a water curtain to control the fumes. Sept. 19 – Cam Ranh, Vietnam: 3 workers at a fish sauce factory died of suffocation when they entered a fermenting vat. Sept. 19 – Waharoa, New Zealand: Sludge from a cheese factory leaked into a nearby river. Sept. 20 – Leverkusen, Germany: Hydrofluoric acid leaked from containers stored at a chemical facility. Sept. 21 – Joinville, Brazil: A furnace explosion rocked a foundry. Photo Courtesy of Steve Gerbert Damage to a trailer parked at a trucking company operating adajacent to T2. were involved, the hazmat responders said. Under the Emergency Planning and Community Right-to-Know Act (EPCRA) annual reporting from facilities storing or processing substances listed as extremely hazardous was required. These facilities must submit annual reports, known as Tier II reports, to the State Emergency Response Commission (SERC) and local emergency planning committees (LEPCs), listing the substances and quantities on site. Other than the gasoline additive involved in the blast, T2 Laboratories, Inc., a small privately-owned corporation, concentrated primarily on blending solvents used in the printing industry. Other than issues of inherent flammability, these solvents remained non-reactive when blended into solution as needed. Manufacturing methylcyclopentadienyl manganese tricarbonyl (MCMT, also known as MMT), an organomanganese compound used as an octane-increasing gasoline additive, was T2’s sole reactive chemical process. Of the chemicals on site at T2, only MCMT was listed as an extremely hazardous substance under EPCRA. “We pulled up T2’s web page and all we got was MSDSs of what went into their end product,” Wilson said. “It was like looking at a bunch of LEGOs and trying to figure out what it looked like when it was put together.” A U.S. Chemical Safety and Hazard Investigation Board report issued in September 2009 stated that T2 had not yet filed its annual Tier II report for the 2007 reporting year. T2 failed to list MCMT on its previous Tier II reports, despite producing thousands of pounds per batch and storing thousands more pounds prior to shipment off site. The incomplete report failed to warn responders that MCMT is toxic by ingestion, inhalation and skin absorption. Smith said that only one of the workers at T2 was in any shape to be interviewed by responders after the blast. He talked while being treated in the back of an ambulance. “He kept saying the name of the product was MMT,” Smith said. “He never told the full name. So we used Google to search for MMT.” The NIOSH pocket guide revealed that MMT was a Class IIIB combustible liquid with a flash point at or above 200 degrees Fahrenheit. Also stored in large amounts on site was water reactive sodium used to manufacture MCMT. Based on the chemicals that T2 reported storing, JFRD conducted hazardous materials response drills for emergencies involving sodium metal since it required specialized fire fighting strategies. “We keyed on these 50 pound bricks of sodium more because of the Tier II reporting,” Wilson said. “There were tons of this stuff packed in 55-gallon drums with mineral oil. We were looking at that more Sept. 21 – Oravasaari, Finland: Hydrogen peroxide spilled from an overturned cargo vehicle. Sept. 22 – Ringwood, Australia: A dust explosion rocked a metal recycling plant for the second time in a month. Sept. 23 – Atyrau, Kazakhstan: A fire in an oil refinery workshop killed a worker and injured 2 others. Sept. 23 – Gonfreville-l’Orcher, France: An explosion in a polyethylene unit rocked a chemical plant. Sept. 23 – Hillsville, VA: A battery explosion injured a worker at a carpet weaving plant. Sept. 23 – Korba, India: A chimney under construction at a thermal power plant collapsed, killing 14 workers. Sept. 23 – Osceola County, FL: Lack of water hindered firefighters battling a fire that destroyed a biodiesel plant. Sept. 23 – Saint John, NL: A paper mill fire involving molten sulfur forced workers to evacuate. Sept. 23 – Voronezh, Russia: An explosion at a pyrotechnic warehouse killed a worker and injured 25. Sept. 24 – Aichi, Japan: A desulfurization unit caught fire at an oil refinery. Sept. 24 – Dabrowa Chelminska, Poland: More than 30 workers were overcome by toxic fumes at a fish processing plant. Sept. 24 – Memphis, TN: A pressure valve on a 9,000 gallon tank of liquid oxygen ruptured at a chemical plant, spewing flammable gas. Sept. 24 – Richmond, CA: A gasoil hydrotreater unit caught fire at a 245,271 barrel-per-day oil refinery. Sept. 24 – Skikda, Algeria: Fire broke out in a central air conditioning unit at an oil refinery. NOVEMBER-DECEMBER 2009 NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 15 11/3/2009, 9:40 AM 15 15 Incident Log (Continued) Sept. 25 – Barrackpore, Trinidad & Tobago: A lightning strike caused an explosion at a crude oil facility. Sept. 25 – Wilmington, CA: A fire at an oil refinery lasted several hours. Sept. 26 – Hohenbrunn, Germany: A leaking drum of thionyl chloride at a chemical plant reacted with water, causing sulfur dioxide and hydrogen chloride fumes. Sept. 26 – Temagami, ON: A major Canadian natural gas pipeline ruptured, forcing a shut down. Sept. 27 – Franklin, NH: A brief fire broke out when material under a smelting pot ignited at a valve foundry. Sept. 27 – Hidd, Bahrain: A welder died from burns when multiple gas cylinders exploded at a shipbuilding yard. Sept. 27 – Lewiston, ID: A small explosion involving a shell rocked a munitions plant. Sept. 28 – Albany, GA: 700 gallons of hazmat tainted oil leaked from transformers being scrapped. Sept. 28 – Burnaugh, KY: 7 workers were injured in an explosion at a metallurgical plant. Sept. 28 – Mansfield, LA: A contract worker at a paper mill died when he fell into a tank of heated water. Sept. 28 – Preston, MN: A fire at a bio-fuel plant caused minor damage. Sept. 28 – Rio de Galinhas, Portugal: Three people cleaning a wine vat died from toxic fumes. Sept. 28 – St. Louis, MO: Fire broke out at an airplane parts manufacturing plant. Sept. 29 – Apaxtla, Mexico: An equipment explosion at a hydroelectric plant killed a worker. Five others were overcome by carbon monoxide fumes. Sept. 29 – Berto Cirio, Brazil: An explosion in a sawdust storage bin rocked a local plant. Sept. 29 – Garden City, GA: An explosion injured 2 workers cutting up a steel tank at a recycling plant. Sept. 29 – South Bend, IN: Dust was blamed for a fire that involved welding equipment at a steel tubing plant. Sept. 29 – Tilton, IL: A truck driver hauling anhydrous trimethylamine was overcome by fumes when he stopped to inspect his vehicle for a suspected leak. Sept. 29 – Winfred, SD: Fire broke out at a wax plant, injuring a worker. Sept. 30 – Baghdad, Iraq: 2 people died in an explosion and fire at an oil refinery.C 16 16 Nov-Dec09a.pmd than the end product.” Large quantities of solvents were also stored on site. While the main end product at T2 remained a mystery, many JFRD responders were far too familiar with the location. Under previous ownership, the chemical manufacturing facility was the site of a chemical explosion and fire in June 1998 that forced an area evacuation. “The stuff they made back then was ten times worse,” Wilson said. “They were making pesticides. The owner met the first arriving engine at the gate and said, ‘Don’t enter — it’s not worth your life.’ He said, ‘Whatever it’s going to do, let it do.’” Firefighters took the owner’s advice and let the fire burn itself out. It soon became clear that a full hazmat response would be necessary, bringing Station 21 to the scene as well, Wilson said. FULL RESPONSE AT T2 “When we got there the incident commander had basically declared the fenced area of the property a hot zone,” he said. “They basically handed it over to us – ‘Here’s what we’ve got, so handle it.’” A better reconnaissance was needed. Smith led a small group through the gates and into the flames. Hose lines protected the responders from the fire. Fortunately, the nearly windless day allowed the smoke to rise straight up, aiding visibility. Woods armed himself with a 30-pound extinguisher filled with Purple K. Another responder sketched out the location of tanks and buildings, in particular noting the markings on the tanks. The firefighters made a clockwise circuit of the property, walking in a semi-crouch. Around them, the explosions continued. Fifty-five gallon drums of chemical would suddenly launch themselves high into the sky. Of primary concern was the injured survivor using his cell phone to communicate with responders from somewhere in the heart of the fire. He had been one of three outside operators ordered away from the overpressurized reactor moments before the explosion. “He said he was next to the office surrounded by fire,” Wilson said. “We were thinking he had to be trapped where all this fire was coming from.” After about 10 minutes, the reconnaissance team backed out. Firefighters now had a better concept of the complex and the chemicals involved. However, the injured operator was still missing. Firefighters formulated a rescue plan. Using a quick foam attack, firefighters hoped to open a path into the burning facility long enough to reach the injured worker. Jacksonville hazmat units are equipped with 240 gpm foam nozzles and eductors, Smith said. Alcohol-resistant foam was used because of the polar solvents involved. To back up the JFRD supply, a crash truck from the U.S. Naval Air Station Mayport Fire Department was dispatched. The Jacksonville International Airport Fire Department responded as well. “Initially, we drove the fire back to the reactor site,” Woods said. “We got the exposures under control first. We had two foam lines established and used water and foam to protect the MC-306 trailers. Once those were under control, we went up the center of the yard, turned around and came back down the middle to get to the core of what was burning.” Aside from the 2½-inch hose lines, the firefighters used Purple K extinguishers to handle various pressure fires from damaged flanges and ruptured gas lines. Runoff from the hose lines mostly drained into a large retention pond. “When water got into a conex box containing sodium, the pop always got your attention,” Woods said. “Those 55gallon drums of dry sodium bounced off the inside of the containers.” Responders finally located the injured operator but nowhere near where he was thought to be, Wilson said. “He was blown about 200 feet away from the reactor out into the woods,” he said. “Because he was losing blood he went into shock. Although the fire was advancing on him, he was not near the office as he thought.” The operator lost both legs due to the explosion. Two fellow operators moving away from the reactor were killed, cut in half by the blast. A company co-owner and a process engineer died in the control room about 50 feet from the reactor. A plant mechanic also suffered injuries INDUSTRIAL FIRE WORLD INDUSTRIAL FIRE WORLD 16 11/3/2009, 9:40 AM AFTERMATH Three hours after the blast a company representative was finally located who could address the specific material. “The wife of one of the co-owners was Christmas shopping and showed up because she heard there had been a chemical plant explosion on the north side,” Wilson said. “She was also one of the plant’s chemical engineers. We started getting some answers.” SWS First Response, an environmental services company, contracted to take charge of remediation the following day. JFRD turned responsibility for the site over to the Jacksonville Sheriff’s Office, which conducted an investigation to determine the possibility of foul play. “We maintained an incident command presence for the next five days,” Wilson said. “Our big chore was to get the investigators and evidence technicians trained and suited up in Level A.” After the T2 explosion and fire, JFRD decided to convert its entire stock of fire fighting foam to an alcohol resistant brand, he said. The only exception was an 8,000 gallon foam tanker containing AFFF. Wilson often addresses the T2 accident when asked to speak to process safety engineering committees and other industrial safety organizations. “I ask everybody to give me a worst case scenario,” he said. “Somebody will say, ‘Well, this tank could blow up.’ That’s not worse case, I tell them. Keep going. If somebody says, ‘Everybody is dead, trapped or gone and there is nobody on scene to give me any information,’ that’s a worse case scenario.” The solution Wilson proposes is for management to compile all Tier II When water got into a conex box reports, MSDSs containing sodium, the pop always got and a site safety your attention. Those 55-gallon drums plan to be bounced off the inside of the containers. downloaded onto a thumb drive. JFRD Hazmat Team Lt. Chris Woods That drive is then placed in a rapid entry or KNOX-BOX accessible to the fire can’t tell me what is in this particular atmospheric tank or what is in those conex department. “Most places have ordinances stating boxes over there,” Wilson said. “I had two that if your business is behind a locked tube trailers burning with no idea of the gate you have to install a KNOX-BOX to product inside. It turned out to be carbon which the fire department has a key,” monoxide, which can still be toxic.” Today, T2 Laboratories exists only as a Wilson said. “Most fire departments now have laptops available on their vehicles.” web site that has never been taken down. No proprietary information need be The remaining owner who survived a heart included. The information on the drive can attack after the blast died only weeks be password protected so that it is only before the final CSB report was issued. “It’s kind of a sad story,” Wilson said. available to the fire department, he said. It “All the workers at T2 said they were can also be regularly updated. C “The problem with CHEMTREC is they treated like family.” Photo Courtesy of Steve Gerbert in the explosion. A shipping container shielded T2’s other co-owner from the blast, but he suffered a non-fatal heart attack during the incident. With the dead and injured accounted for, the operation at T2 turned into a fire fight, Wilson said. In about 45 minutes, firefighters knocked down the bulk of the fire. As a final precaution, foam was injected into the boilers to extinguish internal fires. “Fortunately, the fire went out quickly,” Wilson said. “After that, it became a much more manageable hazmat event.” Above, aerial view of T2 Laboratories and neighboring businesses indicating the range of injury and damage. At left, firefighters search for survivors in the wreckage of T2 Laboratories. NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 17 11/3/2009, 9:40 AM 17 I n today’s economic environment, a company’s attempt to fast-track production from scaled down test models or to increase production without completely accounting for potential hazards can lead to costly, sometimes deadly results. A report issued by the U.S. Chemical Safety and Hazard Investigation Board (CSB) on the December 2007 explosion and fire at T2 Laboratories, Inc., cites four similar runaway reaction incidents investigated by the CSB since 1998 resulting in 10 deaths and more than 200 injuries. Paterson, NJ – April 8, 1998 An explosion and fire at a chemical plant in Paterson, NJ, occurred during the production of a dye used to tint petroleum fuel products. The explosion and fire were the consequence of a runaway reaction, which overpressurized a 2,000-gallon chemical vessel and released flammable material that ignited. Nine employees were injured. The incident caused the hospitalization of two employees, the release of chemicals into the community and damage to the plant. The investigation team determined that the product reaction accelerated beyond the heat-removal capability of the reactor. The resulting high temperature led to a secondary runaway decomposition reaction causing an explosion, which blew the hatch off the reactor and allowed the release of the reactor contents. The initial runaway reaction was most likely caused by excessive reactor heating and delayed use of the cooling water system. The reactor’s cooling system could not control the exothermic reaction and had no emergency shutdown or quenching function. The CSB investigation found that the company had not adequately evaluated or controlled the hazards of the dye production process. Neither a preliminary assessment conducted in 1990 nor a subsequent hazard analysis five years later considered the possibility of a runaway chemical reaction—one of the most common reactive hazards. As a result, the reactor 18 Nov-Dec09a.pmd was not provided with sufficient cooling capacity or adequate emergency shutdown or venting systems. The company’s analyses never considered possible scenarios—such as excessive heat input or inadequate cooling—that could trigger a runaway reaction. Allentown, PA – February 19, 1999 A process vessel containing several hundred pounds of hydroxylamine exploded at a production facility near Allentown, PA. Employees were producing the facility’s first full-sized batch of hydroxylamine (HA). After the distillation process of an HA and potassium sulfate solution was stopped, the HA in the process tank and associated piping explosively decomposed, most likely due to high concentration and temperature. The explosion killed four employees and a manager of an adjacent business. Two employees survived the blast with moderate-to-serious injuries. Four people in nearby buildings were injured. The explosion also caused significant damage to other buildings in the light industrial use business complex where the facility was located and shattered windows in several nearby homes. The company developed the HA production process through laboratoryscale experimentation in 1997, then constructed a 10-gallon pilot plant. In July 1998, the company set up a full production facility in a multi-tenant building. The production parameters that the company designed for the reaction involved a high concentration of HA, which could result in exothermic decomposition forming explosive crystals. Despite available MSDS, information regarding the fire and explosion hazards of such high concentrations was not consulted. The CSB found that the company had not systematically evaluated the reactive hazards of the process during INDUSTRIAL FIRE WORLD 18 11/3/2009, 9:40 AM production development phases, determined the magnitude of the hazard, nor identified control measures. An adequate reactive chemical hazard evaluation and process hazard analysis (PHA) would have helped the company quantify, evaluate, and mitigate the hazards of HA production. Such analyses might have even caused management to question whether its planned process presented substantial or unacceptable risks to employees and to the community. recipe in the full production batch. A comprehensive process design and hazard review of the scale-up was not performed, and the company did not appreciate the significant difference in heat removal capacity of the 4,000-gallon reactor compared to the 30-gallon reactor. The CSB concluded that this incident could have been avoided had the company thoroughly investigated the hazards of the process and properly designed the emergency vent system to contain a potential release of the toxic vapor. added all of the additional monomer needed into the initial charge to the reactor. This more than doubled the rate of energy release in the reactor, exceeding the cooling capacity of the reactor condenser and causing a runaway reaction. The reactor pressure increased rapidly. Solvent vapors vented from the reactor’s manway, forming a flammable cloud inside the building. The vapors found an ignition source and exploded. The CSB investigation found that although the company combined monomers and reaction initiators in the presence of flammable solvent to produce polymer products, it failed to identify the hazards associated with this type of chemistry. Additionally, process safety information was poorly documented, product recipes were changed without systematic review and automatic safeguards to prevent or mitigate the effects of runaway reaction were not in place. When performing reactive chemistry, companies must be aware of the hazards involved and take action to minimize potential consequences of all identified hazards. These examples illustrate the terrible dangers when this is not done. C Dalton, GA – April 12, 2004 A runaway reaction over-pressurized a Morganton, NC – January 31, 2006 chemical reactor at a chemical A runaway chemical reaction and manufacturing plant, releasing toxic allyl subsequent vapor cloud explosion and alcohol vapor into the community. The fires killed one worker, injured 14 (two resulting toxic cloud sent 154 people to a seriously), damaged structures in the local hospital, forced the evacuation of nearby community, and destroyed an nearby residents, and killed vegetation and industrial facility in Morganton, NC. This aquatic life near the plant. facility manufactured a variety of powder The plant was producing its first batch coating and paint additives by of triallyl cyanurate (TAC) in a batch polymerizing acrylic monomers in a 1,500reactor as part of a tolling arrangement with gallon reactor. a third-party company. The CSB The company had received an order for investigation found that the company had slightly more of an additive than the normal not thoroughly researched the reactive size recipe would produce. Plant managers hazards of the process before scaling up scaled up the recipe to produce the from laboratory tests to full production. required larger amount of polymer and Although literature on the hazards of TAC manufacturing was readily available, the company’s literature search focused on patent restrictions rather than the reactive chemistry hazards of the process. Although the company had tested the reaction at the bench scale, these tests were designed to maximize yield and minimize production cost and did not indicate that the process included an additional highly exothermic decomposition reaction which would require additional cooling. The company tested three batches in a 30gallon reactor but then Photo Courtesy of Mark Treglio used a different batch A burning reactor for blending solvents vents to the atmosphere after the T2 Labs explosion. NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 19 11/3/2009, 9:40 AM 19 F Photo courtesy of Claymont (DE) Fire Company Firefighters push into the blazing Marcus Hook refinery. Pipe failure cited in refinery fire 25th IFW Emergency Responder Conference & Exposition Safety & Security Track Who: Safety, security and HSSE managers Rescue Courses: • Fall Protection • Annual Confined Space What to Expect: • Incidents Leading to Change • CFATS • Review of NFPA Security Standards • How National Crime Affects Industry Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com 20 Nov-Dec09a.pmd ire officials blame a May 2009 fire that destroyed part of Sunoco’s Marcus Hook refinery on a rusty 10-inch pipe that ruptured and caused a catastrophic natural gas leak. Separate investigations by the company and the Delaware State Fire Marshal determined that pipe failure caused the fire in the refinery’s ethylene unit. “The Delaware State Fire Marshal’s investigation indicates – and our own internal investigation agrees – that a pipe failure resulted in the release of combustible ethylene unit feed gas, which caught fire,” said Thomas Golembeski, Sunoco’s spokesperson. The pipe failure was caused by external corrosion on the bottom of the pipe, Golembeski said. The evidence shows that localized corrosion stemmed from moisture trapped between the pipe and a loose steel sleeve on which the pipe rested. The corrosion, which occurred over many years, was limited to the space between the sleeve and the pipe. The rest of the pipe showed no indication of corrosion. “Extensive metallurgical testing and analysis of the damaged section of pipe confirms corrosion as the cause of the failure,” Golembeski said. As a result of these findings, Sunoco has voluntarily begun taking the following corrective actions: • Sharing the lessons learned across all of Sunoco’s refineries and chemical plants. • Launched a short-term effort at all facilities to examine piping systems and identify locations of possible concern so they can be addressed immediately. • Begun a process to revise standard inspection practices to make them even more thorough and rigorous. New inspection practices will go beyond the industry standard that Sunoco currently follows. • Implementing a special emphasis program for high-risk systems to be sure similar structures with similar conditions do not exist at any Sunoco facilities. • Initiated a third party review of the revised mechanical integrity and inspection practices to identify other areas for improvement. “Sunoco has long been an active member of community organizations in Claymont, Marcus Hook and Linwood,” Golembeski said. “We work hard to maintain positive and productive relationships with our neighbors, local elected officials, and the community of emergency first responders.” Sunoco participated in a local emergency planning committee devoted to improving communication and cooperation among agencies responding to events straddling the PennsylvaniaDelaware border. Together with other area companies, Sunoco sponsored a new emergency packet for New Castle County residents that contains evacuation routes and procedures. In October 1946, seven Marcus Hook refinery workers died and nearby 200 were injured when fire swept through a recently opened aviation gasoline cracking plant. Nine explosion rocked the facility as firefighters labored to control the blaze. Sunoco announced in July 2009 that it will permanently close the ethylene complex, citing low market demand for ethylene, C ethylene oxide and cyclohexane. INDUSTRIAL FIRE WORLD 20 11/3/2009, 9:40 AM Register Now at www.fireworld.com NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 21 11/3/2009, 9:40 AM 21 2010 Conference & Expo • February 22 - 26 • Baton Rouge, LA WORKSHOP TRACTS KEY MONDAY 8:00-5:00 Industrial Medical Services Annual Confined Space Rescue Course (Part I) LNG Symposium Fall Protection Rescue Course Marine Fire Fighting Preparing the Next Generation Ferrara Dinner & Tour 6:00-8:00 Safety & Security Spill Response & Emerging Fuels Twenty-five years ago, Industrial Fire World held its first conference to bring together the outstanding leaders in our field and share hard-won knowledge gained from first-hand experience. In recent years, IFW has shifted its focus to accredited training and certification in keeping with new requirements placed on industry. This year in Baton Rouge, IFW focuses again on passing leadership skills to a new generation of classroom trained responders moving into positions previously held by firefighters who tested their skills against the real thing at its angriest time and again. Bring your key leaders to participate in the workshop tract that addresses their area of responsibility. TUESDAY 7:30-9:00 Breakfast 8:00-11:30 General Session 11:00-6:00 Exhibits Open 11:30-1:00 Lunch in Exhibit Hall David White 1:00-2:00 Industrial Medical Services Challenges & Differences LNG Events 2:00-3:00 Industrial Burns from Head to Toe Sandia Lab 3:00-4:00 Ongoing Training 4:00-5:00 5:00-6:00 22 Nov-Dec09a.pmd Marine Fire Fighting for Land-based Firefighters Decision Making & Situation Awareness Changes in Safety & Security Real Hazmat Incidents Panel: The Future of Industrial Brigades CFATS Importance of Available Resources Gasoline Terminals Under CFATS Clearing Environmental Impact The Magic of LNG Reception INDUSTRIAL FIRE WORLD 22 11/3/2009, 9:40 AM WEDNESDAY 7:30-9:00 Breakfast in Exhibit Hall 7:30-3:30 Exhibits Open 8:00-9:00 What’s New in Emergency Medical Response 9:00-10:00 Medical Emergencies 10:00-11:00 Securing & 11:00-12:00 Using Med. EMS Panel: Ownership & Legal Aspects Panel: Fire Fighting Aspects UK Fire Rescue Service’s Changing Roles Impact on Ind. Complying to Changing Codes & Standards Marine Fire Fighting for Land-Based Firefighters 1:00-2:00 2:00-3:00 Biodiesel Lunch (Staggered) in Exhibit Hall Immobilization Helicopter AwareLanding ness Rescue Course 3:00-4:00 Panel: Implications of Buncefield (1:00-2:30) Panel: Fire Fighting Tug Aspects OPA 90 Roundtable Discussion: The Role of Chief (2:30-5:00) Roundtable START Triage 4:00-5:00 5:30-8:00 Ethanol & Methanol (9:30-11:00) Knowing the Players: Available Resources Maintaining Fire Protection in Tough Economic Times Around the World 11:30-1:00 Real Hazmat Incident (8:00-9:30) How National Crime Affects Industry Security Technology & Emergency Mangement Fuels Emerging onto Highways Cost Effective, Total Protective Concepts Demonstrations & Southland Fire Sponsored Dinner at LSU FETI THURSDAY 8:00-Noon Maritime Rescue on USS Kidd Noon-5:00 Annual Confined Space Rescue Course (Part II) Make Hotel Reservations Before January 21, 2010 for Industrial Fire World’s $109 Room Rate www.crowneplaza.com 1-877-270-1393 NOVEMBER-DECEMBER NOVEMBER-DECEMBER 2009 2009 Nov-Dec09a.pmd 23 11/3/2009, 9:40 AM 23 23 2010 Conference & Expo Registration Form Date: /// // / Complete and Fax to 979.690.7562 or Register On-Line at www.fireworld.com Month Day Year Exhibitor Exhibitor Speaker Speaker General Admission: $$300 Before Nov. 30 $$400 After Nov. 30 $$200 Each for Group of 5 or More Last Name Company Business Title Mailing Address City State Zip - PH# FX# Email Address Which Workshop Do You Plan To Attend? Attendee Attendee First Name Select payment option: Pay at Conference Check-in Cash or Check (Enclosed) P.O. # Credit Card # Expiration Date PIN Name on Credit Card Industrial Medical Services LNG Symposium Marine Fire Fighting Preparing the Next Generation Safety & Security Spill Response & Emerging Fuels Mail to: INDUSTRIAL FIRE WORLD 540 Graham Road P.O. Box 9161 College Station, Texas 77845/77842 or Fax to: FX#: 979.690.7562 or Register at: www.fireworld.com Billing address is the same as mailing address Zip - Billing Address City State Nov-Dec09a.pmd 25 NOVEMBER-DECEMBER 2009 11/3/2009, 9:41 AM 25 Modern personal protective gear traces its origins back as far as humanity’s will to survive P Means of Protection By Ben Mauti and Leslie Mitchell MSA 26 Nov-Dec09a.pmd rotective helmets have been used for millennia. About 24 BC, Roman emperor Augustus established a municipal fire fighting company that employed a hand-to-hand bucket delivery system. Lacking personal protective gear, early firefighters battled flames from the perimeter. Firefighting protective gear in the United States, worn as far back as the colonial era, was at best rudimentary until about 1730 when the first firefighting “stovepipe” helmet appeared courtesy of NYPD firefighter Jacobus Turck. 1825 produced Italian scientist Giovanni Aldini’s heat protection mask. Goggles were worn to complement London Fire Brigade Superintendent James Braidwood’s 1863 SCBA, an invention comprised of a lined sac, rubber hoses, bellows, and mouthpiece. As primitive as such gear seems today, it’s unlikely that we’d be where we are without building upon its foundation. Leather, Aluminum, Kevlar, and…FOAM? Firefighting helmets of the familiar leather variety have been around for about 170 years. Mass production of fire helmets swayed temporarily to aluminum shells until their heat and electrical conduction properties became obvious. Leather returned as the manufacturing mainstay for its water resistance and ability to offset the blow of falling objects. Leather helmets remained the standard until the 1970s with incorporation of moldable heat- and impact-resistant synthetics and composites such as fiberglass, polyaralyte, and Kevlar. The National Fire Protection Association (NFPA), an international nonprofit group established in 1896 dedicated to developing fire hazard consensus codes and standards, issued the Standard on Structural Fire Fighter’s Helmets in 1979. This standard resulted in design consideration of impact force and acceleration, heat, flame, and electrical current resistance, and other factors. In Europe, CGF Gallet, a French manufacturer of firefighting and military protective headgear, launched the original F1 Helmet in 1985. This design in its fifth generation is still widely used today by firefighters in 80 countries. Gallet’s F2 Wildlands Helmet became available in 1987 for wild fire and technical rescue applications and is popular in Europe, Asia, and South America. Henry T. Gratacap began production of leather fire helmets in 1836. In 1869 Cairns & Brother Inc. bought Gratacap’s factory, and by 1955 produced helmets made of leather, aluminum, and plastics. Plastic composites of the day used phenolic impregnated INDUSTRIAL FIRE WORLD 26 11/3/2009, 9:41 AM fabric and polyester impregnated fiberglass. The flint flex helmet also appeared during this era, a more fracture-resistant and moldable plastic. Cairns & Brother was the first manufacturer to incorporate full thermal/impact caps within fire helmet shells. Foam impact caps were initially designed for impact energy absorption but were found to effectively absorb thermal energy as well. Fire helmets with integral impact caps are significantly cooler for users to wear than are those without. An additional benefit of certain impact cap designs is the ability to disengage from the helmet shell should a firefighter become lodged within a tight space by a helmet brim. The helmet shell is left behind while the user escapes with impact cap intact. An additional unexpected benefit can be derived from the fire helmet eagle ornament. The brass eagle was created about 1825 and became a fire helmet tradition. Eagles serve both ornamental figures and lettered front identification pieces. Some eagle styles are manufactured as solid pieces, while others crush easily and absorb some impact energy, protecting the user and helping to lessen firefighter head and neck injuries. Firefighter eye protection; a quick history More innovation and history can be documented on this subject than most might think. It’s a given that firefighters protect their precious eyesight while on the job. Did anyone think otherwise? Yes, as it turns out. Protective eyewear for firefighters received minimal attention until firefighter Lester Bourke sustained a facial injury in the early 1960s. Lester Bourke, firefighter with FDNY Engine Company 231 in Brooklyn and part-time inventor, sustained a severe blow to his forehead while working the hose line. Although he recovered from his injury, the accident raised his awareness as to firefighters’ eye injury vulnerability. Lester initially tried army goggles as eye shields only to experience constant fogging. Subsequent tinkering and experimentation using spare parts, notably fire engine speedometer cables and clock springs, allowed him to create lenses that could move up and down on the fire helmet. It took time, but within a few years his invention was complete. Cairns and Brother began selling his Bourke Safety Eye Shields in 1966; Lester Bourke received a patent in 1968. This flip-down style eye shield’s appearance, initially resisted by firefighters, became a tradition through the years, only to be surpassed by new and innovated technology made possible through modern materials, design, and manufacturing. Firefighters’ eye protection design must consist of an impact/ heat resistance balance. All externally-mounted eye shields worn with fire helmets share the same drawbacks: their lenses are subject to dirt, grit, and other flying debris, as well as damage from heat, sparks, and liquids. Firefighting faceshields and goggles, also externally-mounted, are subject to the same although faceshields offer tint and material options (generally plastics) not offered with older model eye shields. Goggles provide a close, tight fit with flexibility as well as anti-fog properties. Time passed and firefighting gear took the high-tech route through incorporation of lightweight, heat-resistant synthetic materials. Moldable compounds such as polycarbonate and polyaralyte allow for production of smaller, lower-profile components. A truly retractable visor became a reality for Gallet. This internally-mounted faceshield preserves a goggle’s close fit and a traditional faceshield’s tint options and anti-fog properties. Retract-ability offers between-use protection from abrasive debris, dirt and mud, heat and sparks. By nature, it’s unlikely that integrated visors are lost or left behind. It’s only in recent years that integrated, retractable visors are available across the pond in North America following polyaralyte faceshields in 1983 and non-corroding faceshield hardware in 1984. Most visor choices are NFPA-compliant and meet ANSI Z87.1+. Locking hard detent mechanisms offer easy adjustability and eliminate slippage; optically-correct lenses eliminate peripheral distortion. Most firefighters in the U.S. prefer traditionally-shaped helmets with wide brims and custom fronts, constructed of leather or synthetic materials. An added benefit that became quickly apparent in the United States is firefighters’ ability to clearly read retractable visor users’ helmet identification fronts, as those fronts are not blocked by goggles or faceshields resting in the “up” position. We’ve thankfully come a long way in a relatively short time period due to human ingenuity and resourcefulness and no doubt will continue to do so. Regulations, codes, and standards help to guide protective firefighting gear innovation to offset and minimize the risks of this hazardous but crucial occupation. C NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 27 11/3/2009, 9:41 AM 27 Photos by Anton Riecher International Fog CEO Eugene Ivy uses a First Attack nozzle to extinguish a helicopter prop with carbon dioxide. International Fog demonstrates First Attack nozzle using CO2 Fire Fighting I Encounters of the 28 Nov-Dec09a.pmd INDUSTRIAL FIRE WORLD 28 3rd Kind By ANTON RIECHER IFW Editor nternational Fog Inc.’s First Attack piercing fog nozzle proved effective in applying three chief fire fighting elements — water, foam and carbon dioxide — in special demonstrations conducted in October at Louisiana State University’s Fire and Emergency Training Institute (LSU FETI). Shell Oil is considering the use of the First Attack nozzle on off-shore platforms in the Gulf of Mexico, said Eugene Ivy, president of IFI. “Shell would like to put one if not two of the First Attack nozzles on their big wheeled unit CO2 extinguishers for fighting helicopter fires,” Ivy said. Beginning in late September, use of the First Attack nozzle became part of Shell personnel training at FETI prior to assignment to offshore platforms. “Once we get the LSU instructors trained, all the Shell people coming through will learn to apply First Attack to aircraft rescue fire fighting,” Ivy said. Designed to give firefighters immediate access into a structure, Ivy initially designed a nozzle with a stainless steel piercing tip that also creates a pattern of fine water droplets. This system 11/3/2009, 9:41 AM At left, Eugene Ivy discusses First Attack’s advantages. creates a stream that looks like a mist or fog, which absorbs and extinguishes the fire in a decreased amount of time when compared to other systems. “Over several conversations, Shell indicated that they were interested in the nozzle if it could handle CO2,” Ivy said. “Honestly, I had to tell them I never had to use anything but water and foam for any type fire we’ve been up against. But I said I would put it on my priority list to find out.” Steve Summers, an aviation logistics consultant for Shell, attended the demonstrations at FETI. While piercing nozzles that use CO2 are relatively common in Europe where Shell is based, finding them in the United States is much harder, Summers said. Because FETI handles all helicopter landing officer training for Shell off-shore platforms, training FETI instructors on use of the First Attack nozzle is important, Summers said. “We figured that whatever they train with here would be the optimum thing to use off shore,” he said. At FETI, Ivy demonstrated the First Attack on an industrial training prop using water and foam. The demonstration then moved to FETI’s helicopter training prop using CO2 under pressure. Chris Lacombe with Burner Fire Control said the demonstration was impressive, quickly extinguishing the fire. “Eugene is working on a system to restrict the amount of CO2 flowing through the nozzle to make it easier to handle under pressure,” Lacombe said. Preliminary testing on the First Attack was conducted at the IFI facility in Portland, OR. Ivy then made use of a full sized livefire helicopter “prop” at the Washington State Fire Training Academy near North Bend, WA. A flow test using the First Attack nozzle and a 100 pound CO2 cylinder proved successful in Washington, Ivy said. “The short version is that it worked extremely well,” Ivy said. “We got 50 seconds of useful CO2 time out of the cylinder.” The fire itself was extinguished in only a few seconds. According to Ivy, each helicopter pad on an off shore platform comes with at least four fire fighting stations surrounding it. Each wheeled unit on the Shell platform would come equipped with one or two First Attack nozzles. Gene Caskey, chief of aircraft rescue and fire fighting at the At right, First Attack creates a pattern of fine droplets. Shreveport, LA, Regional Airport, also attended the FETI demonstration. Caskey said he had worked closely with Ivy in the past to adapt First Attack technology to his department. “We needed a nozzle built with Ivy’s patented rotator assembly for a piercing nozzle to fit on the end of a Snozzle,” Caskey said. “We were looking for better conversion to steam through the use a finer water droplett pattern. I designed the nozzle, sent the plans to Eugene and he built it. Right now we are the only ones using it this way.” For a video report on International Fog’s testing at FETI, visit C http://www.youtube.com/watch?v=F2CNGvxCthQ. 25th IFW Emergency Responder Conference & Exposition Marine Fire Fighting Track Who: Industrial and municipal firefighters, ship captains, crew members & port authority What to Expect: • Marine Fire Fighting for Land-Based Firefighters (sponsored by MERE) • Off-Shore Marine Fire Fighting (sponsored by LSU FETI) • OPA 90 • Maritime Rescue on USS Kidd (sponsored by Roco Rescue) Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 29 11/3/2009, 9:41 AM 29 INDUSTRY NEWS U.S. Foam recall ordered by federal court Judge grants injunction to Chemguard based on misuse of UL identifier A federal district judge granted an injunction in favor of Chemguard, Inc. of Mansfield, TX, against a Longview, TX-based foam manufacturer, ordering a recall of fire fighting foam using an Underwriters Laboratories’ control number assigned to Chemguard. United States District Court Judge Reid O’Connor of the Northern District of Texas entered the order in September granting Chemguard’s request for an injunction with respect to U.S. Foam Technologies’ (USF) use of Chemguard’s UL identifier. The Court directed U.S. Foam to issue a general recall to all customers “specifically identifying what product(s) may have been mislabeled as Chemguard product(s), directing them to avoid using mislabeled product, and to return that product to USF.” U.S. Foam must also place a notice in an industry wide publication to inform customers as to how those products can be identified and provide instructions on the return of the product. Roger Bower, president of Chemguard, said that the company is pleased with the court’s action and looks forward to “the correction of this problem with product on which firefighters across the country rely upon.” In issuing his ruling, Judge Connor noted that “many 25th IFW Emergency Responder Conference & Exposition Preparing the Next Generation Track Who: Current and future industrial and municipal fire chiefs and emergency response managers What to Expect: • Maintaining Fire Protection in Tough Economic Times • Panel Discussion • Complying to Changing Codes & Standards • Knowing the Players: Available Resources • Managing Leadership Change • Panel: Implications of Buncefield • Roundtable Discussion Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com 30 Nov-Dec09a.pmd consumers require [UL certification] as part of their bid specifications.” Connor noted that Chemguard learned on May 14, 2009, that U.S. Foam was selling fire fighting foam using Chemguard’s UL identifier. He observed that “both Chemguard and USF agree this was improper.” He also noted that Chemguard purchased UL and military specification foam from USF and “According to Chemguard, USF’s military specification foam did not perform as required by military specifications. . . . Other foam Chemguard purchased from USF revealed, according to Chemguard tests, that it did not perform according to UL or other relevant standards.” In issuing his ruling, Judge Connor stated: “USF admits it has falsely designated USF products with Chemguard’s labels.” After considering U.S. Foam’s arguments, the Court concluded: “The Court is persuaded that USF’s use of Chemguard labels have either actually deceived and confused potential customers, and a presumption exists that it has done so. Therefore, Chemguard has established a likelihood of success on the merits of its substantive claim based on USF’s false use of Chemguard’s labels.” The recall does not pertain to Chemguard-labeled products.C Nevada fire academy consults on new training center in India W ith ongoing consulting assistance from the University of Nevada, Reno Fire Science Academy (FSA)Worldwide, the Institute of Fire Safety and Disaster Management Studies (IFSDMS) in Gujarat, India, has broken ground on its new training facility, expected to provide professional instruction in fire fighting and disaster management for emergency responders in India and the region. “The Fire Science Academy has assisted by sharing our knowledge and experience in the conceptual design and operation of an exceptional training facility that, in the case of IFSDMS, can serve the needs of India’s communities,” said Mitchell Baclawski, assistant director of FSA’s worldwide division. “We began a consultation partnership with IFSDMS in 2008 and have worked to promote the Indian institute’s development of a handson emergency response training facility, which is designed to be as comprehensive as our own academy in Nevada.” Construction began in March 2009. Buildings for administration, education and hostel accommodations have been completed. Full-scale training props, key to the realistic handson training that will be offered at the facility, are also due to be built this year. A rescue tower prop and smoke chamber prop are under construction, and remaining training structures will be built after the end of India’s monsoon season. C INDUSTRIAL FIRE WORLD 30 11/3/2009, 9:41 AM Feds release 2008 PA oleum overflow report T he Chemical Safety Board (CSB) released a final report in October on the uncontrolled oleum release from Petrolia, PA, chemical plant which forced the evacuation of three surrounding towns in October 2008. CSB encouraged companies that handle hazardous chemicals to follow proper managementof-change procedures, monitor deviations from written operating procedures, and implement appropriate safeguards to mitigate human errors. The accident that took place on Saturday, October 11, 2008, forced over two thousand residents of Petrolia, Bruin, and Fairview, to evacuate or to shelter-in-place for approximately eight hours. Oleum, also known as fuming sulfuric acid, was released when a tank transfer operation was left unattended during weekend operations and an oleum storage tank overflowed. The oleum formed a toxic sulfur trioxide gas, which mixed with moisture in the air to form a dense, corrosive, sulfuric acid cloud that threatened the neighboring towns. CSB Chairman John Bresland said, “The managers of companies that handle highly hazardous substances, such as oleum, need to exercise special care that appropriate process safeguards are in place. In this accident, the CSB found that for many years, operators had been using an auxiliary pump power supply that lacked safety interlocks to prevent tank overfilling.” Located approximately 50 miles northeast of Pittsburgh, the facility produces resorcinol, a chemical used for making tires and other products. The CSB report noted that three operators were involved in bulk liquid loading and unloading work from Monday to Friday. However, to maintain operations on a continuous, seven-day-per-week schedule, an operator would regularly perform work on weekends, transferring oleum from pressure vessels to storage tanks used to supply the resorcinol manufacturing process. The CSB investigation determined that the normal power supply for the three oleum transfer pumps was equipped with a safety interlock, which would automatically shut off the flow of oleum when the receiving tank was full, preventing a dangerous overflow. However, the oleum storage building also had an auxiliary or “emergency” power supply that had been installed in the late 1970s. It was originally intended as a temporary way to keep the pumps functioning during interruptions of the normal power supply but eventually the emergency power supply became a permanent fixture. Facility management never installed interlocks for the emergency power and written operating procedures did not address how or when the emergency power supply should be used. C NOVEMBER-DECEMBER 2009 Nov-Dec09a.pmd 31 11/3/2009, 9:41 AM 31 FOCUS ON HAZMAT Putting meat on the bones E ver since the dawn of civilization, man has been confronted with the certainty that, at some unpredictable time and place, some sort of unexpected catastrophic event will overtake him. Once this certainty was conceptualized the next step was to consider what action was to be taken if ... thus emergency planning was born. A contingency plan is like a skeleton: to be a functional organism it must be equipped with muscle, skin, organ systems and a network of nerves. Otherwise it is just a pile of bones that hang uselessly in a dark closet. To be functional, there must be meat on the bones. The “meat” on the bones of any emergency contingency plan must consist of at least ten essential elements: — Definition of objective: What sort of emergency are we planning for? Severe weather? Fire? Flood? Process failure? Power outage? Transportation emergency? Terrorism or industrial sabotage? We need to define it and plan for as many different scenarios as possible. — Evaluation: What will be the likely consequences of an incident of this type? What would be the “worst case” scenario? — Determination of required resources: What will we need to deal with this situation? Are these resources available? If so, 25th IFW Emergency Responder Conference & Exposition Spill Response & Emerging Fuels Track Who: Industrial and municipal hazmat teams What to Expect: • Real hazmat incidents • Importance of Available Resources • Cleanup: Environmental impact • Ethanol & Methanol • Fuel Technology: CNG, LPG, LNG, Hydrogen, Electric & Hybrid Vehicles • Fire Fighting Technologies for Emerging Fuels Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com 32 Nov-Dec09a.pmd By DR. JOHN S. TOWNSEND where are they located? If not, what shall we do to obtain them? Who is responsible for obtaining additional supplies and resources? — Staffing: Who will be in charge of the response effort? Where will these people assemble? Will there be someone tasked in advance to start up the fire water pumps or activate the standby power plant? — Communications: How will the alarm be propagated and who is responsible for doing it? Will the notification be confined to the plant proper or will nearby communities need to be alerted? Will it be necessary to evacuate nearby residents? How will this be accomplished and by whom? — Off site assistance: Who will be responsible for notifying mutual aid groups and, if needed, civilian fire departments, medical facilities and local law enforcement? Who will conduct an evacuation if one becomes necessary? — Financial responsibility: Will there be someone with the authority to write checks or issue purchase orders immediately for urgently required materials such as foam concentrate and where will these materials be obtained? — Liaison with local government: in the event that an evacuation is called for, who is responsible for notifying local authorities and securing their cooperation? — Record keeping: Who is responsible for keeping a log of events as well as the financial obligations incurred while responding to the incident? The log especially is most important as it will document the actions of the company, the government and third parties when, months, or even years, after the event, litigation occurs, as it will almost certainly do. — Safety: Who will be responsible for the safety of the responders and for implementing the protocols for emergency medical treatment? There may be more elements than these but this list covers the salient points. In actuality, a complete Emergency Response Protocol (ERP) will consist of a master plan and a number of incident specific sub-plans. Thus the XYZ facility will have a master emergency plan that will outline the chain of command, set out the basics of the plant’s response organization and protocols. A series of subplans will account for fire, severe weather, power outage, off-site transportation incident or other scenarios. When an incident occurs, the master plan will be activated along with appropriate sub-plan(s). These sub-plans will be facility specific; for example the severe weather sub-plan for a plant located in northern Michigan would likely pertain to a winter storm. They will also be product or process specific. The response protocol appropriate for chlorine, for example, will be vastly different from one designed for gasoline or sulfuric acid. The best place to find the proper “fit” for a plan INDUSTRIAL FIRE WORLD 32 11/3/2009, 9:41 AM is within the group that will have to ultimately activate and deploy in the event of an incident. In the case of manufacturers, who would be expected to know more about a product and the ways to safely handle it than the people who actually make it? To be functional, an ERP must be constantly updated. There is a saying among emergency planners that any plan will be out of date ten minutes after the last page comes out of the copier. In a large organization, this is not entirely fallacious. People change positions, employees come and go, e-mail addresses, telephone numbers and radio call-signs change frequently, and in a very large installation, such changes may occur on a daily basis. No ERP, no matter how elaborate, has ever saved a life or prevented an injury or averted a single incidence of property damage. Plans do not protect anything; they only empower people to do so. A plan is nothing more or less than a theoretical framework for organizing response capabilities and resources a specific problem. To be effective, any plan must be known to those who are affected by it and these parties must take ownership in the plan. Far too many ERP’s are created, bound in blue leather with gold lettering and promptly filed away in some remote archive to be forgotten. Any job description that involves participation in an emergency response protocol, either in the private sector or within government, should have this participation spelled out in detail and it should be one of the first things that a newly hired employee receives as part of his initial orientation; the new-hire should know exactly what would be expected of him/her in the event of an emergency. As soon as the new employee comes aboard the ERP should be updated to show his/her new position, name, contact number(s) and his responsibility within the emergency response organization. To facilitate this, particularly in a large plant site, it is quite convenient to have the ERP on a computer attached to a Local Area Network (LAN). Changes, additions or deletions can be made from a central location (the personnel office, for instance, or the emergency response manager’s headquarters) and show up on all computers within the network. An alternate method is to have a notice sent out by e-mail and occasionally to have the whole plan reviewed and re-distributed on computer disks. Such notices and disks should carry some sort of receipt to acknowledge that they have actually been received by those for whom they were intended — thus ensuring that those persons can be held accountable for the information contained in the notices. Whatever method is employed the ERP must be kept current. Nothing can “throw a wrench in the works” quicker than to place an urgent call to the fire chief only to hear that, “he retired last week,” “He is on vacation” or “That telephone number has been changed.” Anything and everything that happens in and around a facility affects the ERP; if the fuel delivery truck is down for repairs, the fire chief needs to know it now, not when he is pumping full bore at a four-alarm barn burner and his fuel gauges are approaching “empty.” ERPs and ERP Updates are like fire bells; they do nothing if there is nobody around to heed them and to act accordingly. Those affected by an ERP must understand its purpose and their part in it. Those involved or affected by an ERP must understand that an emergency is just that, an emergency, and “business as usual” goes out the window. Administrators, be they local government, or corporate, must be familiar with the ERP and instruct their employees that when “the big bell rings” they are authorized to immediately do whatever is necessary or requested. We can sort out the details and address the finger-pointing later. It has often been said that frequently activated ERPs are the most effective. People in Tornado Alley know very well what it means when the sirens start sounding so they act accordingly. They know the emergency is real; it is not a game or a drill that can be ignored. Indeed, ignoring an alarm as “just a drill” has been the means by which an incident has escalated into a full blown disaster on more than one occasion. People who experience emergencies understand the need for preparedness. The obvious way to foster understanding and appreciation for the importance of ERP is to have frequent drills, simulations and exercises. Most of these will involve only a segment of the entire emergency response community. Announced drills involve the entire emergency response organization simulations. These are, or at least should be, about as close to the “real thing” as it is possible to get without causing undue interruption of normal activities. The best possible scenario for simulations is one for which the probability is high in the particular venue. Such simulations should occur on an unannounced basis just as real emergencies do. The alarm should be sounded and the ERP actuated. The objective here is to see what actually happens when the bell rings. Do the people know what to do and will they do it without hesitation? In order to determine this, the simulation should be scheduled with as few people actually aware of it as possible. It should not be scheduled to occur at the most opportune or convenient time; real emergencies never do. Is the boss out of town or the fire chief at a seminar? Fine, let us see how our back up plan works. If we need to make adjustments or modifications, now is the time to find out about it. Is it raining or snowing? We can see how well our response team functions in adverse weather. Finally, do not neglect the assessment phase of the simulation. There will be errors and miscalculations to be sure. Determining what these are is the reason for running the simulation in the first place. The critique session(s) should be thorough, perhaps held the day after the simulation when everyone has had a chance for rest. It should be all inclusive and not be rushed. C NOVEMBER-DECEMBER 2009 33 Far too many ERP’s are created, bound in blue leather with gold lettering and promptly filed away in some remote archive to be forgotten. Nov-Dec09a.pmd 33 11/3/2009, 9:41 AM RISK ASSESSMENT Intervene or leave it alone By JOHN FRANK, P.E., CFPS/XL GAPS A t recent loss prevention meetings in both the United States and the United Kingdom the issue of public fire department (brigade) intervention at industrial properties was raised. There is growing awareness that a public fire department may not perform offensive1 operations at industrial properties if everyone has made it out of the building and has been accounted for. There have been numerous reports of chief officers who stated something to the effect of “if everyone is out, we are not going in” meaning they will assume a defensive2 posture. This is driven by safety concerns, a new emphasis on fire service risk management, and actual firefighter injuries and fatalities. While there are certainly circumstances where the risk to firefighters is too great to conduct offensive operations, when properly designed and functioning fire protection systems are installed, the incident commander may decide that offensive operations to save property could be undertaken. National Fire Protection Association (NFPA) 1500 Standard on Fire Department Occupational Safety and Health Program States in A.8.3.2: “When considering risk management, fire departments should 25th IFW Emergency Responder Conference & Exposition LNG Symposium Track Who: Industrial, municipal, private, public and governmental management and personnel working in or near LNG facilities. What to Expect: Tuesday, February 23, The Magic of LNG by Peter Micciche (Open to the Public Based on Availability) Wednesday, February 24 Panel discussion addressing ownership, legalities and fire fighting Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com 34 Nov-Dec09a.pmd consider the following Rules of Engagement after evaluating the survival profile of any victims in the involved compartment: (1) We will risk our lives a lot, in a calculated manner, to save SAVABLE LIVES. (2) We will risk our lives a LITTLE, in a calculated manner, to save SAVABLE property. (3) We WILL NOT risk our lives at all for a building or lives that are already lost.” From my perspective, the first and third items are relatively obvious. It is the second item that seems to generate the most discussion as to what is savable. A primary purpose of this series of articles, since inception, has been to help facility managers and fire departments to analyze their risks during thorough prefire planning. The basic message to facility operators is to make every effort to invite the fire department to conduct a technical pre-plan. This way they will know what to expect and whether or not the situations they will likely face involve savable property (as in a fire well controlled by sprinklers) or if the building will likely be lost — which might be the case where sprinkler systems are not properly engineered for the hazards present. The key is that this should be a technical tour, not a “gee whiz” tour where the fire service marvels at the process but is given little understanding of the technical design of the fire protection systems. It may be necessary to engage a fire protection engineer to help explain the technical basis for the fire protection design and what to expect for various scenarios. Likewise, the fire department should make every effort to conduct these tours and to ask facility operators to host them. In future articles, we will outline expectations for various occupancies and situations. Emphasis will be placed on what actions various NFPA standards anticipate that the fire department will take. Recent loss experience indicates that sometimes there is a disconnect between what the fire protection designers expect the fire department to do and what they are actually able or willing to do. It is essential that these gaps be closed before the incident occurs. Feel free to contact this author at [email protected] or at (404) 431-2673. C 1 Per NFPA 1500 3.3.69.4 Offensive Operations. Actions generally performed in the interior of involved structures that involve a direct attack on a fire to directly control and extinguish the fire. 2 Per NFPA 1500 3.3.69.1 Defensive Operations. Actions that are intended to control a fire by limiting its spread to a defined area, avoiding the commitment of personnel and equipment to dangerous areas. John Frank, P.E., CFPS is with XL GAPS, a leading loss prevention services provider and a member of the XL Capital group. “XL Insurance” is the global brand used by member insurers of the XL Capital Ltd (NYSE: XL) group of companies. More information about XL Insurance and its products is available at www.xlinsurance.com. INDUSTRIAL FIRE WORLD 34 11/3/2009, 9:41 AM EMS Corner Avoid being KOd by H1N1 By WILLIAM R. KERNEY, MA, EMTP (Ret.)/College of Southern Nevada andemics being what they are, often prone to panic type standard germicidal thinking and behavior, it is little surprise that swine flu cleaners (or 1:10 has been given so much attention. In the early outbreaks sodium hypochlorite of the virus, it was not uncommon to see people in Mexico’s solution if allowed) will major cities wearing protective masks. They even closed many of suffice, but special the ports of call on both coasts causing the cruise industry to attention must be paid cancel many cruises with Mexican destinations. In June of this to the common contact year the World Health Organization (WHO) declared it officially surface areas. It is also to ‘pandemic’ with the virus having spread to more than 70 countries. encouraged There had also been cases reported in every one of the 50 United frequently wash hands States. Then it seemed to back-off. There were fewer cases and in warm water and soap deaths reported, the panic seemed to abate, the ports were re- and avoid touching opened and hygiene campaigns seemed to take center stage. your mouth, nose and Now the flu season has arrived and a renewed interest has emerged eyes. In the absence of by the agencies responsible for the tracking, reporting and soap and water, “waterless” hand preventing of this very kind of outbreak. H1N1 (Figure 1) The CDC (Centers for Disease Control and Prevention) has sanitizers may be only issued routine guidelines up until this point but states they substituted. These are alcohol based, gel in style products that expect the cases of swine flu, now categorized as novel influenza should be used freely, fully wetting the hands and rubbed until A or H1N1, to rise with regular flu during the flu season. Cases in dry. They are inexpensive for a large size container. Invest in one the United States are ongoing with some having increased and use it. Continued on Page 37 intensity. H1N1 is transmitted just like normal flu through droplet infectivity (sneezes and coughs) but is also transmitted via surface (door handles, stair railings) contamination. Apparently studies have shown that the H1N1 (fig. 1) can live on surfaces two-to25th IFW Emergency Responder Conference eight hours after being deposited. In light of this, it is even more & Exposition important than ever to make sure shared work spaces are Industrial Medical Services Track decontaminated frequently. This includes counter surfaces, Who: Nurses, Paramedics, EMTs keyboards, telephones, and other common use shared items. What to Expect: Flu symptoms are numerous and people should be aware of • Industrial Emergency Medical Services – classic signs before they occur.: fever, cough, sore throat, runny Challenges & Differences or stuffy nose, body aches, headache, chills, fatigue and, • Caring for Fire Victims: Burns & Breathing sometimes, diarrhea and vomiting. Emergencies It is important to note that not everyone with flu will have a • Medical Emergencies fever and not all of the signs and symptoms may be present. The • Ongoing Training for Your Emergency Response Team other issue that has arisen and is truly problematic for all the • What’s New in CPR, First Aid & Emergency human resource directors is the recommendation for all employees Medical Response who present illness of this type be sent home (or remain at home) • Securing & Using Medical Services Around for a week’s (seven day recommendation) convalescence and to the World remain at home for at least 24 hours past their last incidence of • START Triage: Black Tagging Friends & fever and without the use of any fever-reducing medications. Coworkers The CDC also does not recommend that persons seek medical • Helicopter Landing care unless absolutely necessary. Here is where the problem arises • Awareness Rescue Course (sponsored by for HR as many of these persons will not have doctors’ notes to Roco Rescue) Group rate – Send 5 people for $1,000 present for their time off work. It is also not recommended that (a $2,000 value) they be required to have one as this creates an undue and, according to the CDC, an unnecessary burden on the medical Register at community. www.fireworld.com Decontamination follows routine procedures and the use of NOVEMBER-DECEMBER 2009 35 P Nov-Dec09a.pmd 35 11/3/2009, 9:41 AM INDUSTRIAL SERVICE DIRECTORY CAFS FIRE FIGHTER TOOL CO. 5150 Franz Road Katy, TX 77493 281/391-0588 • Fax 281/391-1593 COMPRESSED BREATHING AIR TESTING ISO 9001: 2008 Certified Meeting NFPA, CGA & OSHA Standards www.dyneusa.com (800) 632-2304 Email: [email protected] CONSULTING/TRAINING EMERGENCY SERVICES TRAINING 600 Marina Drive Beaumont, TX 77701 409/833-BEST • Fax 409/833-2376 FIRE & SAFETY SPECIALISTS INC. P.O. Box 9161 College Station, TX 77842 979/690-7559 • Fax 979/690-7562 HAINES FIRE & RISK CONSULTING 609/294-3368 • www.hainesfire-risk.com Fire Protection Consulting, Water Supplies, Emergency Planning, Testing, Fire Investigation INDUSTRIAL FIRE TRAINING CONSULTANTS P.O. Box 17947 • Nashville, TN 37217-0947 615/793-5400 • [email protected] www.iftcfire.com LSU FIRE & EMERGENCY CONSULTANTS 6868 Nicholson Drive Baton Rouge, LA 70820 800/256-3473 • Fax 225/765-2416 http://feti.lsu.edu • [email protected] WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 FIRE APPARATUS SUTPHEN CORPORATION P.O. Box 0158 Amlin, OH 43002 800/848-5860 E-ONE 1601 SW 37th Ave. Ocala, FL 34474 352/237-1122 • www.e-one.com Ferrara Fire Apparatus, Inc. Holden, Louisiana Toll Free 800/443-9006 www.ferrarafire.com 36 36 ISDp36.pmd ISO 9001: 2008 Certified Meeting NFPA and IMO Standards www.dyneusa.com (800) 632-2304 Email: [email protected] HARD SUCTION HOSE FIRE APPARATUS HARDWARE HARRINGTON, INC. 2630 West 21st St. Erie, PA 16506 • 800/553-0078 814/838-3957 • Fax 814/838-7339 TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” FIRE FIGHTING & HAZARD CONTROL WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 FOAM TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” HAZMAT EMERGENCY RESPONSE EQUIPMENT SKEDCO, INC. 10505 SW Manhasset Drive Tualatin, OR 97062 503/691-7909 • Fax 503/691-7973 www.skedco.com HOSE/HOSE COUPLINGS WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 HOTELS WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 FOAM EQUIPMENT FOAMPRO-HYPRO 375 Fifth Ave. N.W. New Brighton, MN 55112 651/766-6300 • 800/533-9511 • Fax 651/766-6614 EDUCATION & TRAINING LAMAR INSTITUTE OF TECHNOLOGY 855 E. Lavaca, Beaumont, TX 77710 OSH, Fire & Homeland Security Training 409/880-8321 or 800/950-6989 • www.lit.edu FIRE APPARATUS FOAM TESTING TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 www.fireworld.com 2355 IH-10 South — Beaumont, TX 77705 409/842-3600 • Fax 409/842-0023 e-mail: [email protected] HOLIDAY INN BEAUMONT PLAZA 3950 I-10 S & Walden Rd. Beaumont, TX 77705 409/842-5995 • Fax 409/842-7878 INCENTIVES/AWARDS/GIFTS 180 Franklin St. Framingham, MA 01702 www.firecatalog.com • 1-800-729-1482 Gifts, badges, & accessories for firefighters INDUSTRIAL INDUSTRIAL FIRE FIRE WORLD WORLD 36 11/4/2009, 9:36 AM LDH EQUIPMENT HARRINGTON, INC 2630 West 21st St. Erie, PA 16506 800/553-0078 814/838-3957 • Fax 814/838-7339 TURNOUT GEAR SAFETY GEAR GLOVE GUARD Phone: 888-660-6133 Fax: 281-426-6135 Email: [email protected] TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” MONITORS TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 NOZZLES TASK FORCE TIPS, INC. Valparaiso, IN 46383 • 800/348-2686 [email protected] • www.tft.com “An American Owned Company.” WILLIAMS FIRE & HAZARD CONTROL P.O. Box 1359 Mauriceville, TX 77626 409/727-2347 • Fax 409/745-3021 RESCUE EQUIPMENT- CONFINED SPACE SKEDCO, INC. 10505 SW Manhasset Drive P.O. Box 3390 Tualatin, OR 97062 800/770-7533 • Fax 503/639-4538 www.skedco.com www.fireworld.com 2010 IFW Conference February 22-26 Baton Rouge, LA Nov-Dec09a.pmd 37 103 S. Main St. Quakertown, PA 18951-1119 215/536-2991 • Fax 215/538-2164 [email protected] • www.quakersafety.com H1N1 Continued from Page 35 So, what about total protection via a vaccination program? Well, that is here but there is not enough of the virus vaccine to completely go around yet. Target groups will be the first to receive the initial dosages. It takes time, not only to manufacture, but to isolate, develop and of course, clinically test any new vaccine. Are you in a target group? Health care workers and emergency workers are at the top of the list because of the vast exposure to the patient population. The young and elderly come next and pregnant mothers and those who care for dependant children (child care workers) are also slated to receive the vaccine. So have your agency check with the local health district, and see what the current information about the vaccine is, get your people inoculated and get the protection necessary. Visit vaccine sources at http://www.cdc.gov/h1n1flu/ vaccination/statecontacts.htm. This is a full state reference for contact points for the vaccine. Your agency may even become a provider for the vaccine as this may help with its dissemination to the general public. Use good public relations tools. You can never have too many of those. In the mean time, wash your hands. That has always been the forte for health care workers and now is not the time to back off. Lather soapy water for the time it takes to sing “Happy Birthday.” Rinse and dry with paper towels or air dry. Remember to use a paper towel to open the bathroom door. C Company dumped pesticide wastes into public sewers T he president of a pesticide company based in St. Joseph, Mo., was sentenced in September in federal court in Kansas City, Mo., for violations of the Clean Water Act and hazardous waste storage laws related to the company’s pesticide production, the Justice Department announced. He was sentenced to serve six months in prison, six months of home confinement and was ordered to pay a $100,000 fine for having disposed of pesticide waste water down the sewers of the city of St. Joseph. Sentencing for the company was delayed by the court. The company executive pleaded guilty on Jan. 27, 2009, to a felony violation of the Clean Water Act for disposing of the pesticide waste. The company pleaded guilty on the same day to the same violation of the Clean Water Act as well as a felony violation of the hazardous waste storage laws. The company maintained warehouses at various locations in St. Joseph where it stored wastes from its operations for years without notifying the proper regulatory agencies. Many of the stored wastes were considered hazardous based upon their ingredients or their characteristics. In addition, employees under the company president’s supervision disposed of waste waters from the production of pesticides down floor drains and into the city of St. Joseph’s sewers for several years without permit. C NOVEMBER-DECEMBER 2009 37 11/3/2009, 9:41 AM SPOTLIGHT ADS March 2-4: Hazardous Materials On-Scene IC March 9-12: Entry Level Industrial Firefighter March 16-19: Advanced Exterior Industrial Firefighter Mar. 29-April 1 : Incident Command Emergency Response Visit http://www.fireworld.com/training/training_cal.php for the 2009-2010 FSA training calendar. Feds issues record $87 million penalty T 25th IFW Emergency Responder Conference & Exposition Rescue Courses Track Sponsored by Roco Rescue • Maritime Rescue on USS Kidd (Thursday, February 25) • Fall Protection Rescue Course (Monday, February 22) • Annual Confined Space Rescue Course (Monday, February 22 & Thursday, February 25) • Basic Awareness Rescue Course (Wednesday, February 24) Group rate – Send 5 people for $1,000 (a $2,000 value) Register at www.fireworld.com Nov-Dec09a.pmd 38 he U.S. Department of Labor’s Occupational Safety and Health Administration (OSHA) announced in October it is issuing $87,430,000 in proposed penalties to one of the world’s largest energy companies for failure to correct potential hazards faced by employees. The fine is the largest in OSHA’s history. The prior largest total penalty, $21 million, was issued in 2005, also against the same company. Safety violations at a Texas City, TX, refinery resulted in a massive explosion — with 15 deaths and 170 people injured – in March of 2005. The company entered into a settlement agreement with OSHA in September of that year, under which the company agreed to corrective actions to eliminate potential hazards similar to those that caused the 2005 tragedy. The latest announcement comes at the conclusion of a six-month inspection by OSHA, designed to evaluate the extent to which the company has complied with its obligations under the 2005 agreement and OSHA standards. When the company signed the OSHA settlement from the March 2005 explosion, it agreed to take comprehensive action to protect employees, said Secretary of Labor Hilda L. Solis. Instead of living up to that commitment, the company has allowed hundreds of potential hazards to continue unabated,” “Fifteen people lost their lives as a result of the 2005 tragedy, and 170 others were injured. An $87 million fine won’t restore those lives, but we can’t let this happen again. Workplace safety is more than a slogan. It’s the law. The U.S. Department of Labor will not tolerate the preventable exposure of workers to hazardous conditions.” For noncompliance with the terms of the settlement agreement, the Texas City Refinery has been issued 270 “notifications of failure to abate” with fines totaling $56.7 million. Each notification represents a penalty of $7,000 times 30 days, the period that the conditions have remained unabated. OSHA also identified 439 new willful violations for failures to follow industry-accepted controls on the pressure relief safety systems and other process safety management violations with C penalties totaling $30.7 million. 11/3/2009, 9:41 AM Nov-Dec09a.pmd 39 11/3/2009, 9:41 AM Nov-Dec09a.pmd 40 11/3/2009, 9:41 AM