Binchotan: The future battery
Transcription
Binchotan: The future battery
Original Research Binchotan: The future battery Haruno Murakami, Kentaro Asai, Tatsuhiko Watanabe, Naoko Oyobe, Mio Oe, Yuya Hiramatu Jishukan Senior High School, Toyohashi, Japan. E-mail: [email protected] DOI: 10.4103/0974-6102.107616 ABSTRACT This group of students aimed to develop a more efficient type of binchotan battery. They did this by setting up several batteries and changing one of the electrolytic solution, the electrode material or the material of the conducting wire. They plotted graphs of voltage against time as each variance discharged. The higher the voltage and the longer it endured, the better the material. They found the binchotan battery works best using sodium sulphate as the electrolytic solution, platinum wire, and binchotan wrapped in visking tubes. Introduction Experiment Based on past research by seniors, this project aims to develop a more efficient binchotan (traditional oak wood charcoal) battery.[1] When a direct current (DC) is passed through the electrodes, electrons flow through the electrolytic solution from the anode to the cathode. As they pass through water molecules, the water molecules are electrolyzed to form hydrogen and oxygen through the following reactions: The basic experimental set up was solid binchotan, wrapped in visking tubes, was used as electrodes, aqueous sodium sulphate was used as the electrolyte, and copper was used for the conducting wire [Figure 1]. Charging time for the setup was three minutes under fixed conditions. Effectiveness was determined by plotting voltage against time as the battery was subsequently discharged, where a higher voltage for a longer duration meant that the battery was more effective. The experiments varied composition of electrolytic fluid, electrode material, and conducting wire material to find the optimal combination. i) Varying Electrolytic solution: For this setup, electrolyte solution was varied from sodium sulphate, trisodium phosphate, and phosphoric acid. ii) Varying Electrode: 2H2O + 2 e- → H2 + 2OH 2H2O → 4H+ + 4e- + O2 (O’Leary, 2000)[2] This is how a binchotan battery works. Current flows through the wires connected to the terminals to complete the circuit for the reaction to proceed. Young Scientists Journal | 2013 | Issue 13 25 Figure 1: A schematic diagram of a Binchotan battery Figure 2: A graph of potential difference against time as the battery discharges with different electrolytic fluids Graphite as an electrode was compared to carbon sticks. iii) Varying Conducting Wire: Copper wire was compared against stainless steel wire, enamel wire, and platinum wire. Results and Discussion In experiment i, sodium sulphate and disodium phosphate showed good results [Figure 2]. In experiment ii, binchotan was shown to be better than graphite sticks [Figure 3]. During these experiments, it is worthwhile to note that after many charges, the conducting wire began to corrode. Hence, we compared some materials in the experiment iii for conducting wire. As a result, platinum showed the best efficiency [Figure 4]. Figure 3: A graph of potential difference against time as the battery discharges with different electrodes Figure 4: A graph of potential difference against time as the battery discharges with different conducting wire Conclusion The binchotan battery works best using sodium sulphate as the electrolytic solution, platinum wire, and binchotan wrapped in visking tubes. However, platinum wire is expensive, so a low-cost conducting wire like copper would be more desirable than platinum. References 1. Based on a research on fuel cells in Jishukan High School in 1997. 2. O’Leary, D. (2000). Electrolysis of Aqueous Solutions. Retrieved from University College Cork: http://www.ucc.ie/academic/chem/ dolchem/html/dict/electrol.html. [Last accessed on 2012 Feb 2] About the Authors Yuya Hiramatsu wants to be a doctor and helps injured and sick people. Mio Oe and Naoko Oyobe want to be pharmacologists and hope to make new and useful medicines. Tatsuhiko Watanabe and Kentaro Asai want to be scientists. Tatsuhiko likes the idea of discovering something new, whereas Kentaro wants to devote himself to improvements in modern science. Haruno Murakami hopes to be an engineer. She wants to develop new materials that are useful and ecofriendly. 26 Young Scientists Journal | 2013 | Issue 13