SAFETY DATA SHEET Tetrapotassium pyrophosphate Table of

Transcription

SAFETY DATA SHEET
Tetrapotassium pyrophosphate
Date of issue: xxx
Table of Contents
1. Identification of the substance/mixture and of the company/undertaking ......................2
2. Hazards identification...................................................................................................3
3. Composition / information on ingredients .....................................................................4
4. First aid measures .......................................................................................................4
5. Fire fighting measures .................................................................................................5
6. Accidental release measures .......................................................................................5
7. Handling and storage ...................................................................................................5
8. Exposure controls / personal protection .......................................................................6
9. Physical and chemical properties .................................................................................8
10. Stability and reactivity ................................................................................................9
11. Toxicological information .........................................................................................10
12. Ecological information ..............................................................................................10
13. Disposal considerations ...........................................................................................12
14. Transport information ...............................................................................................12
15. Regulatory information .............................................................................................13
16. Other information .....................................................................................................13
Annex: summary of relevant exposure scenarios ...........................................................15
ES1: Manufacture of TKPP ............................................................................................15
ES2: Mixing TKPP into final products.............................................................................19
ES3: Use as raw material and process aid in chemical synthesis ..................................29
ES4: Use of TKPP and products containing TKPP for treatment and finishing of
metals ..............................................................................................................35
ES5: Leather and textiles manufacturing and treatment with products containing
TKPP ...............................................................................................................45
ES6: Use of TKPP and products containing TKPP for water and wastewater
treatment..........................................................................................................51
ES7: Industrial and professional use of washing and cleaning products containing
TKPP ...............................................................................................................61
ES8: Application in oil well and other drilling fluid applications, liquefying and
conditioning earths, mud, clays ........................................................................72
ES9: Use of TKPP and products and materials containing TKPP in ceramic
manufacture and construction and building work ..............................................78
ES10: Professional and consumer use of TKPP and products containing TKPP in
fertiliser products..............................................................................................88
ES11: Consumer use of detergents ...............................................................................93
ES12: Consumer use of cosmetics, toothpaste and other products containing TKPP ....95
NOTICE : Important information
Please note that this generic exposure scenario is by no means intended to be mandatory, prescriptive or
exhaustive. The content of this document is intended for guidance only and whilst the information on uses
covered is provided in utmost good faith and has been based on the best information currently available, is to
be relied upon at the user’s own risk. Ultimately, it is for each company to assess the appropriateness and
Revision date: X
Version: XX
NB. Please read the NOTICE on the front page
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completeness of the information on a case-by case basis and decide what elements they wish to adopt or to
add. In particular, the preparation and content of the e-SDS is the legal responsibility of each company for its
own products placed on the market, and the user should verify, complete, correct or adapt this generic
document appropriately.
No representations or warranties are made with regards to its completeness or accuracy, in particular
regarding the list of uses that are covered, and no liability will be accepted by [the consortium members] for
damages of any nature whatsoever resulting from the use of or reliance on the information.
The consortium members acknowledge that any activities carried out under REACH have to be carried out in
full compliance with EU competition law, in particular but not limited to Articles 101 and 102 of the Treaty on
the Functioning of the European Union (TFEU) as well as any applicable national laws.
SECTION 1. Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier:
EINECS Number: 230-785-7
CAS Number: 7320-34-5
REACH Registration number: [to be filled in by company]
Other identifiers: TKPP
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Industrial / professional uses:
- Manufacture of TKPP (exposure scenario 1)
- Mixing TKPP into final products (exposure scenario 2)
- Use as raw material and process aid in chemical synthesis and as a laboratory agent (exposure
scenario 3)
- Use of TKPP and products containing TKPP for treatment and finishing of metals (exposure scenario
4)
- Leather and textiles manufacturing and treatment with products containing TKPP (exposure scenario
5)
- Use of TKPP and products containing TKPP for water and wastewater treatment (exposure scenario
6)
- Industrial and professional use of washing and cleaning products containing TKPP (exposure
scenario 7)
- Application in oil well and other drilling fluid applications, liquefying and conditioning earths, mud,
clays (exposure scenario 8)
- Professional use of TKPP and products and materials containing TKPP in ceramic manufacture and
construction and building work (exposure scenario 9)
- Professional use of TKPP and products containing TKPP in fertiliser products (exposure scenario 10)
Consumer uses:
- Use of TKPP and products and materials containing TKPP in ceramic manufacture and construction
and building work (exposure scenario 9)
- Consumer use of TKPP and products containing TKPP in fertiliser products (exposure scenario 10)
- Consumer use of detergents (exposure scenario 11)
- Consumer use of cosmetics, toothpaste and other products containing TKPP (exposure scenario 12)
- Use in food, animal feeds, medical and pharmaceutical products containing TKPP (listed for supply
chain information, exempted from REACH, NO EXPOSURE SCENARIO)
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No known uses advised against.
1.3 Details of the supplier of the safety data sheet:
[Insert relevant details including contact name, address, phone number, email here]
1.4 Emergency telephone number:
[Insert suitable emergency number and hours of operation]
SECTION 2. Hazards identification
2.1 Classification of the substance
2.1.1 According to Regulation (EC) No.
1272/2008 (EU CLP):
2.1.2 According to Directive 67/548/EC
(DSD):
Eye Irritation 2, H319:Causes serious eye
irritation
Xi; R36 Irritant; Irritating to eyes
2.2 Label elements
2.2.1 According to Regulation (EC) No. 1272/2008 (EU CLP):
Name: Tetrapotassium pyrophosphate
Index Number: Not applicable
CAS Number: 7320-34-5
Signal word: Warning
Hazard Statements:
H319: Causes serious eye irritation.
Precautionary Statements:
Prevention:
P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P337+P313: If eye irritation persists: Get medical advice/attention.
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NOTE: Information in Section 2.2 MUST be consistent with the information provided on the supplier’s
labels.
2.3 Other hazards
The material is not considered to be PBT or vPvB.
SECTION 3. Composition / information on ingredients
3.1 Substance:
Name
EC Number
CAS Number
Tetrapotassium
pyrophosphate
230-785-7
7320-34-5
Typical
concentration
>90%
[Taken from
SIP - specific
company to
update where
necessary]
Concentration
Range
[to be provided
by company]
Registration Number (if available): [specific to each registrant – insert number here]
EC name: tetrapotassium pyrophosphate
Identification of hazardous impurities (where applicable):
All impurities > 1% are other inorganic phosphates or other related inorganic substances, similar to the
Registered substance, and which do not significantly affect its toxicological and ecotoxicological properties
All hazardous impurities are < 0.1%
NOTE: The above information on impurities is company specific therefore suppliers to update where
necessary and in line with the data that is provided in their joint registration dossier Section 1.2.
SECTION 4. First aid measures
4.1 Description of first aid measures
Inhalation
In case of exposure by inhalation, provide fresh air.
Ingestion
Rinse out mouth and then drink plenty of water (approx. 500 ml). In case of symptoms consult
doctor.
Skin Contact
In case of contact with skin, rinse with plenty of water and soap.
Eye Contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Tetrapotassium pyrophosphate causes irritation. No delayed effects are noted.
4.3 Indication of any immediate medical attention and special treatment needed
No specific information available.
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SECTION 5. Fire fighting measures
5.1 Extinguishing media
Suitable extinguishing media:
Tetrapotassium pyrophosphate is not flammable. Use fire fighting measures that suit the environment; CO2,
extinguishing powder or water jet. Fight larger fires with foam.
Inappropriate extinguishing media:
Not applicable.
5.2 Special hazards arising from the substance or mixture
None.
5.3 Advice for fire-fighters
In cases where dust particles of tetrapotassium pyrophosphate may be present respiratory ventilation is
recommended. Wear appropriate eye protection. See Section 8.2.
SECTION 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with eyes. Use personal protection equipment.
6.2 Environmental precautions
Do not allow concentrated solutions to enter drainage system, surface or ground water.
6.3 Methods and material for containment and cleaning up
Shovel up material and recycle if possible. Dispose of contaminated material according to the waste disposal
recommendations.
6.4 Reference to other sections
Refer to Section 8 for suitable PPE.
Refer to Section 13 for disposal considerations.
SECTION 7. Handling and storage
7.1 Precautions for safe handling
Technical measures: sufficient ventilation and local suction is required in accordance with the details in the
annex to the SDS.
Do not eat, smoke or drink.
7.2 Conditions for safe storage, including any incompatibilities
Tetrapotassium pyrophosphate is to be transported and stored in cool, dry conditions and in the original
packaging. This product is hygroscopic.
Do not store with acids. Do not use light alloy containers.
7.3 Specific end use(s)
See annex for details of end uses covered in the exposure scenarios and CSR. The exposure scenarios
detailed in the annex represent a worst case for exposure to humans and the environment.
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SECTION 8. Exposure controls / personal protection
8.1 Control parameters
3
3
Workplace exposure limits: General dust exposure limit: 10 mg/m (inhalable fraction), 3 mg/m (alveolic
fraction). German TRGS 900 (2006).
[please check occupational limits for the country you supply to and insert limit here if available]
DNELS (worker):
Exposure route
Inhalation
Exposure pattern
Acute systemic effects
Long term systemic
Dermal
Long term systemic
DNEL (workers)
As no acute toxicity hazard has identified, there is
no requirement to derive acute DNELs. Therefore
only long term DNELs have been derived.
3
44.08 mg/m
As the substance to be registered is an inorganic
solid, absorption through the skin is not an
appropriate route of exposure. Dermal exposure will
not result in systemic toxicity and therefore it is not
considered to be appropriate to calculate a dermal
DNEL.
No DNELs can be derived for local effects as no dose-response relationship can be identified in any of the
studies available.
DNELs (general population):
Exposure route
Inhalation
Exposure pattern
Long term systemic
Oral
Long term systemic
Dermal
Revision date: X
DNEL (general population)
3
10.87 mg/m
Consumer uses of inorganic phosphates (sodium
and potassium pyrophosphates) do not contribute
to the oral intake of phosphates. Oral intake is
predominately via food and water in the form of
food additives or similar or from natural sources. It
is therefore considered appropriate to use the
Maximum tolerable daily intake (MTDI) value of 70
mg/kg bw /day of phosphorus as calculated by the
Joint FAO/WHO Expert Committee on Food
Additives (JEFCA) as any toxicity effects noted via
the oral route are not attributable to the cation but
are as a result of high doses of phosphates.
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Long term systemic
As the substance to be registered is an inorganic
solid, absorption through the skin is not an
appropriate route of exposure. Dermal exposure will
not result in systemic toxicity and therefore it is not
considered to be appropriate to calculate a dermal
DNEL.
No DNEL can be derived for local effects as no dose-response relationship can be identified in any of the
studies available.
PNECs:
Compartment
PNEC aqua
(freshwater)
PNEC aqua
(marine water)
PNEC aqua
(intermittent
releases)
PNEC STP
PNEC sediment
(freshwater)
PNEC sediment
(marine water)
PNEC soil
Revision date: X
PNEC
Remarks
No long-term toxicity studies are available and therefore the
PNEC is based on the lowest value from the short-term
0.05 mg/L
studies (100 mg/L), the assessment factor used takes the use
of short-term data and read-across data into account. (AF =
2000)
No reliable studies are available on marine species. The
PNEC is therefore based on the short-term studies conducted
0.005 mg/L
on freshwater species. The assessment factor used takes the
use of short-term data in freshwater species and read-across
data into account. (AF = 20000)
The PNEC is based on the lowest value from the short-term
0.5 mg/L
studies (100 mg/L), the assessment factor used takes the use
of read-across data into account. (AF = 200)
The PNEC is based on the NOEC from the ASRI study. The
assessment factor used takes the use of read-across data into
50 mg/L
account and uses the assessment factor appropriate for use of
a NOEC value. (AF = 20)
No data is available for freshwater sediments. Na+, K+, Mg2+, Ca2+ and
PO43- ions are ubiquitous in the environment and are found naturally in soil,
water and sediment. All are assimilated by species residing in the sediment,
water or soil and are essential for maintaining a good chemical balance. It is
therefore unlikely that inorganic phosphates of this nature would be toxic to
sediment organisms and hence toxicity studies are scientifically unjustified.
No data is available for marine sediments. Na+, K+, Mg2+, Ca2+ and PO43ions are ubiquitous in the environment and are found naturally in soil, water
and sediment. All are assimilated by species residing in the sediment, water
or soil and are essential for maintaining a good chemical balance. It is
therefore unlikely that inorganic phosphates of this nature would be toxic to
sediment organisms and hence toxicity studies are scientifically unjustified.
No data is available for soil macroorganisms. Na+, K+, Mg2+, Ca2+ and
PO43- ions are ubiquitous in the environment and are found naturally in soil,
water and sediment. All are assimilated by species residing in the sediment,
water or soil and are essential for maintaining a good chemical balance.
Furthermore inorganic phosphate fertilizers (containing Na+, K+, Mg2+, Ca2+
and PO4- ions) are often added to soils to improve soil quality. Given the
extensive use of inorganic phosphates as soil fertilizers and the natural
occurrence of the ions in the environment it is unlikely that inorganic
phosphates of this nature would have a detrimental effect on soil
macroorganisms and plants and hence toxicity studies are scientifically
unjustified.
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PNEC oral
Date of issue: xxx
Inorganic phosphates are not considered to pose a risk of secondary
poisoning as they are unlikely to bioaccumulate due to the fact that they are
not lipophillic and will therefore not accumulate in fatty tissues. It not
considered necessary to derive a PNEC to take into account the risk of
secondary poisoning and no further testing is considered necessary.
8.2 Exposure controls
Appropriate engineering controls: Ensure work area is well ventilated or exhausted (where appropriate and in
line with the exposure scenarios). Provide eye wash station.
Respiratory protection: See annex for details of processes requiring respiratory protection. In case of
insufficient ventilation, wear suitable respiratory device such as EN141 or EN405, Type A or Dust mask
according to DIN EN 140 or 149 (FFP1 or FFP2).
Skin protection: Laboratory coat or overalls and plastic or rubber boots. Store protective clothing separately.
Eye protection: Tightly sealed chemical safety goggles (compliant with EN 166:2001)
Hand protection: Wear protective gloves: In case of spray contact at least protection index 2
recommended, according to more than 30 min. penetration time (EN 374). Layer thickness of gloves
at least: 0.4 mm In case of prolonged and intensive contact protection index 6 recommended,
according to more than 480 min. penetration time (EN 374). Layer thickness of gloves at least: 0.7
mm
Material of gloves: Butyl rubber, BR. Fluorocarbon rubber (Viton). Nitrile rubber, NBR. Natural
rubber, NR. Chloroprene rubber, CR. Neoprene gloves
Environmental controls: Refer to Sections 6, 7, 12 and 13 of the SDS.
SECTION 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Property
Value
Method
Appearance; including colour and
physical state
Odour
Odour threshold
pH
Solid, white granules
Observed
Odourless
Not available
pH 10.7 – 10.9
Observed
Melting point/freezing point
>300°C
In accordance with Annex XI, Section
1.2. of Regulation (EC) No. 1907/2006
(REACH) a weight of evidence
approach has been used to fulfil the
endpoint ‘Melting Point’.
Initial boiling point and boiling range
Not determined
Flash point
Not determined
According to Regulation No. 1907/2006, a
study for boiling point is not required for
solids which melt above 300°C
According to Regulation No. 1907/2006, the
flash point does not need to be assessed
for inorganic chemicals.
Evaporation rate
Not available
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As measured in the water solubility study
(EU Method A.6)
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Flammability (Solid, gas)
Not flammable
Upper/lower flammability or explosive
limits
Vapour pressure
Not applicable
Vapour density (Air = 1)
Relative density
Solubility(ies)
Not applicable
2.61 at 21.0°C
Date of issue: xxx
Not determined
Not determined
Auto-ignition temperature
No auto-ignition
anticipated
Not applicable
Not determined
Explosive properties
Oxidising properties
According to Regulation No. 1907/2006, a
study for the vapour pressure need not be
conducted if the melting point is above
300°C.
EU Method A.3.
EU Method A.6
Water: 67.2 to
69.9 % w/w at 20.0 A temperature range 10 to 30°C had no
significant influence on the observed
± 0.5°C
solubility of the test material. No effect of
(very soluble)
Partition coefficient: N-octanol/water
Decomposition temperature
Viscosity
Based on prediction and use based
observations
Not considered to be
explosive
No oxidising
properties
pH was noted.
According to Regulation No. 1907/2006, the
partition coefficient n-octanol/water does
not need to be assessed for inorganic
chemicals.
Based on prediction
Testing not technically possible: According
to the relevant OECD guideline (OECD
114) a study cannot be conducted on a
substance that is a solid at room
temperature.
Prediction – in accordance with EU Method
A14
Prediction – in accordance with EU Method
A17
9.2 Other information
Testing has been performed on tetrapotassium pyrophosphate, in accordance with Annex X of REACH.
SECTION 10. Stability and reactivity
10.1 Reactivity
Non-reactive under recommended storage and handling conditions.
10.2 Chemical stability
Stable under recommended storage and handling conditions.
10.3 Possibility of hazardous reactions
May react with strong acids.
10.4 Conditions to avoid
None identified.
10.5 Incompatible materials
Strong acids.
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10.6 Hazardous decomposition products
None identified.
SECTION 11. Toxicological information
11.1 Information on toxicological effects
Toxicological endpoint
Value (including
relevance to CLP
criteria)
Method
Acute toxicity
LD50 = >2000 mg/kg
bw/day. Not classified.
In accordance with Annex XI, Section 1.2.
of Regulation (EC) No. 1907/2006
(REACH) a weight of evidence approach
has been used to fulfil the endpoint ‘Acute
Oral Toxicity’
LD50 = 2000 mg/kg bw/day
Rabbit, equivalent to OECD 402 Klimisch
reliability 1
LC50 = > 1.1 mg/L
Rat, EPA OPP 81-3, OECD 403, EU
Method B.2. . Klimisch reliability 1.
Rabbit, equivalent to OECD 404. Klimisch
reliability 2
Rabbit, equivalent to OECD 405. Klimisch
reliability 2
Mouse, OECD 429, EU Method B.42.
Klimisch reliability 2 – read across from
analogous substance.
No data to suggest substance is a
respiratory sensitiser.
Tetrapotassium pyrophosphate is not
expected to produce germ cell genotoxic
damage.
Not required for REACH. No data to
suggest likelihood of carcinogenicity.
Oral
Dermal
Inhalation
Skin corrosion/irritation
Serious eye/damage/irritation
Respiratory or skin sensitisation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT-single exposure – all
routes
STOT-Repeated exposure - all
routes
Aspiration hazard
Not irritating to skin
Irritating to eyes –
category 2.
Non- sensitiser
Not considered to be
mutagenic.
Not considered to be a
carcinogen.
Not considered to be a
reproductive toxicant
No STOT SE observed
via the oral, dermal or
inhalation route
Not considered to induce
specific organ toxicity after
repeated exposure via oral
route.
NOAEL: 500 mg/kg
bw/day
No aspiration hazard
identified
OECD Guideline 408 (Repeated Dose 90Day Oral Toxicity in Rodents), Klimisch
reliability 2 (read-across from analogous
substance).
Not applicable.
The substance has been assessed with regards to the data requirements of Annex X of REACH.
SECTION 12. Ecological information
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12.1 Toxicity
Toxicological endpoint
Acute fish toxicity
Value (including
relevance to CLP
criteria)
96 hr LC50 = > 100 mg/L
96 hr NOEC = 100 mg/L
Species, Method
Rainbow trout, OECD 203, EU Method C.1.
Conducted on analogous substance,
reliability 2.
Daphnia magna, OECD 202, EU Method
Acute Daphnia toxicity
48 hr EC50 = > 100 mg/L
48 hr NOEC = >100 mg/L
C.2.
reliability 2.
72 hr EC50 = > 100 mg/L
72 hr NOEC = >100 mg/L
Algal growth inhibition
Desmodesmus subspicatus (algae), OECD
201, EU Method C.3.
Basis for effect: growth
rate
reliability 2.
Activated sludge of a predominantly
domestic sewage, OECD 209, EU Method
Activated Sludge Respiration
3 hr EC50 = > 1000 mg/L
C.11, EPA OPPTS 850.6800.
3 hr NOEC = 1000 mg/L
reliability 2.
The substance has been assessed with regards to the data requirements of Annex X of REACH
12.2 Persistence and degradability
Tetrapotassium pyrophosphate is an inorganic substance, biodegradation studies are not applicable. No
further testing is deemed to be necessary.
12.3 Bioaccumulative potential
Tetrapotassium pyrophosphate hydrolyses to orthophosphate and sodium ions in aqueous and biological
systems. The degradation products of tetrapotassium pyrophosphate are essential nutrients (food elements)
for plants, and stimulate the growth of water plants (macrophytes) and/or algae (phytoplankton) and are
ubiquitous in the environment.
The potential for bioaccumulation is therefore considered to be minimal.
12.4 Mobility in soil
No data available:
A batch equilibrium study according to OECD Guideline 106 was deemed to be not applicable to
Tetrapotassium pyrophosphate for the following reasons:
Firstly, analysis of the test material may not be possible due to interference from the soil extracts that may
leach into the aqueous media during the test. This would prevent quantification of the test material.
In addition, the mobility of the test item would be dependent on the anion exchange capacity of the soils as
the main component of the test material is an anion. This absorption relationship would not be anticipated to
correlate with the organic carbon content of the soils and is considered to be beyond the scope of the OECD
106 method.
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12.5 Results of PBT and vPvB assessment
According to the Guidance on Information Requirements and Chemical Safety Assessment, Chapter R.11:
PBT Assessment, the PBT and vPvB criteria of Annex XIII to the regulation do not apply to inorganic
substances. Therefore tetrapotassium pyrophosphate is not considered to require any further assessment of
PBT properties.
12.6 Other adverse effects
No sediment or terrestrial toxicity data exists. Substance is not considered to be hazardous to
sediment dwelling or terrestrial organisms. According to the criteria of the European classification
and labelling system, the substance does not require classification as hazardous for the
environment
SECTION 13. Disposal considerations
13.1 Waste treatment methods
Disposal recommendations are made based on the material as supplied. Disposal must be in accordance with
current applicable laws and regulations.
Disposal of substance: Dispose of in accordance with national and local regulations for special waste via an
appropriately licensed waste contractor. Do not discharge to drains or STP.
Disposal of packaging: Empty containers and clean out appropriately before reuse or disposal. Packaging
may be recycled if thoroughly cleaned. Packaging that cannot be cleaned should be disposed of according to
national and local regulations for special waste via an appropriately licensed waste contractor.
Regulatory disposal information:
European waste codes: Waste producers need to assess the process used when generating the waste and its
contaminants in order to assign the most appropriate waste disposal code(s).
Recommended code: European waste catalogue 16 03 03 inorganic wastes containing dangerous substances
SECTION 14. Transport information
Transport classifications (ADR/RID/IMDG/IATA) are not defined in the REACH Registration Dossier for the
substance. The information provided here is therefore not derived from this Dossier and is based on other
information available to the Consortium Members. The Transport classifications (ADR/RID/IMDG/IATA)
provided here are indicative and based on the data in the REACH dossier for the pure substance only and
may not be applicable for solutions or other preparations. Please seek advice from your Dangerous Good
Safety Advisor.
According to information available: UN transport classification: Not Classified (for pure substance as solid and
solution in water
14.1 UN number
LAND (ADR/RID)
Revision date: X
SEA (IMDG)
Version: XX
AIR (IATA)
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14.2 UN proper
shipping name
14.3 Transport
hazard class(es)
Labels
14.4 Packing
group
14.5
Environmental
hazards
14.6 Special
precautions for
user
14.7 Transport in
bulk according to
Annex II of
MARPOL 73/78
and the IBC code
Other Information:
SECTION 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture.
[COMPANY TO INCLUDE ANY INFORMATION RELEVANT TO THE COUNTRY OF PRODUCT AND/OR
SUPPLY]
This safety data sheet is compliant with Regulation (EC) No 1907/2006 (REACH) (including the amendment,
Regulation (EU) No 453/2010 and Regulation (EC) No. 1272/2008 (EU CLP).
15.2 Chemical Safety Assessment.
A Chemical Safety Assessment is available for tetrapotassium pyrophosphate.
SECTION 16. Other information
This SDS supersedes the SDS dated [TO BE COMPLETED BY COMPANY SUPPLYING SDS]
The following amendments have been made:
- SDS has been fully revised and re-written in accordance with Regulation (EU) No 453/2010 and
Regulation (EC) No. 1272/2008 (EU CLP).
- Any further amendments to be detailed by supplier of SDS
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Sources of Key data used:
- Registration dossier submitted to ECHA in accordance with Regulation (EC) No. 1907/2006 and therefore a
full reference list can be found in the corresponding CSR.
Abbreviations and acronyms used:
AF =
Assessment factor
DNEL =
Derived no effect level
EC50 =
Median effect concentration
LC50 =
Median lethal concentration
LD50 =
Median lethal dose
LEV =
Local Exhaust Ventilation
NOAEL =
No observed adverse effect level
NOEC =
No observed effect concentration
PBT
Persistent bioaccumulative toxic
PEC =
Predicted effect level
PNEC =
Predicted no effect level
PRE =
Personal Respiratory Equipment
OEL =
Occupational Exposure Limit
SDS =
Safety data sheet
STOT–SE = Specific target organ toxicity – single exposure
STOT–RE = Specific target organ toxicity – repeated exposure
STP =
Sewage treatment plant
vPvB =
Very persistent very bioaccumulative
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Annex: summary of relevant exposure scenarios
Annex: summary of relevant exposure scenarios ...........................................................15
ES1: Manufacture of TKPP ............................................................................................15
ES2: Mixing TKPP into final products.............................................................................19
ES3: Use as raw material, process aid and laboratory agent in chemical synthesis .......29
ES4: Use of TKPP and products containing TKPP for treatment and finishing of
metals ..............................................................................................................35
ES5: Leather and textiles manufacturing and treatment with products containing
TKPP ...............................................................................................................45
ES6: Use of TKPP and products containing TKPP for water and wastewater
treatment..........................................................................................................51
ES7: Industrial and professional use of washing and cleaning products containing
TKPP ...............................................................................................................61
ES8: Application in oil well and other drilling fluid applications, liquefying and
conditioning earths, mud, clays ........................................................................72
ES9: Professional and consumer use of TKPP and products and materials
containing TKPP in ceramic manufacture and construction and building
work .................................................................................................................78
ES10: Professional and consumer use of TKPP and products containing TKPP in
fertiliser products..............................................................................................88
ES11: Consumer use of detergents ...............................................................................93
ES12: Consumer use of cosmetics, toothpaste and other products containing TKPP ....95
ES1: Manufacture of TKPP
1. Short title of exposure scenario 1
Manufacture of TKPP
2. Description of activities and processes covered in the exposure scenario
Sector of use
(SU)
Product
category (PC)
Process
category
(PROC)
Article
category (AC)
Environmental
release
category
Revision date: X
SU 3: Industrial uses: uses of substances as such or in preparations at industrial sites
SU 8: Manufacture of bulk, large scale chemicals (including petroleum products).
SU 9: Manufacture of fine chemicals.
Not applicable
PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to
vessels/large containers at dedicated facilities.
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line,
including weighing).
PROC 26: Handling of solid inorganic substances at ambient temperature.
Not applicable
ERC 1: Manufacture of substances
Version: XX
Page 15/97
SAFETY DATA SHEET
Date of issue: xxx
(ERC)
3. Operational conditions
3. 1 Operational conditions related with frequency and quantities of use
Duration of
exposure at
workplace:
24 hours/day (3 working shifts of 8 hours/shift)
Frequency of
exposure at
workplace:
365 days/year for each worker
Annual
amount used
per site:
The daily and annual amount/emission per site is not considered to be the main
determinant for environmental exposure.
3.2 Operational conditions related with substance/ product
Physical state
Solid / Liquid
Concentration
of substance
in mixture
In the first-tier assessment of exposure, A concentration of 100% w/w was used to assess
exposure to the solid substance. The concentration of TKPP in solutions was assumed to
be > 25%.
3.3 Other relevant operational conditions
Processes may be operated on 365 days a year for 24 hours a day divided into three working shifts. A
single worker may be exposed on 220 days per year. No information about frequency and duration of the
various tasks is available. In the first-tier assessment of exposure a frequency of once a day and an
exposure duration of 8 hours was considered.
4. Risk Management Measures
4.1 RMMs related to workers
Organisational
measures
The employer must ensure that the required PPE is available and used according to
instructions (provide training if necessary). PPE are required when breaching the system
or handling the pure substance and concentrated solutions.
Eye wash stations should be available in case of accidental contact.
Technical
measures
Respiratory
protection
Hand
protection
Revision date: X

Transport over pipes, technical barrel filling/emptying of barrel with automatic systems
(suction pumps etc.) (Good practice)
 Use of pliers, grip arms with long handles with manual use “to avoid direct contact and
exposure by splashes (no working over one’s head)” (Good practice)
 Store in cool, dry, clean, well ventilate areas. (Good practice).
 Local exhaust / general ventilation should be present when solids are handled to
reduce the likelihood of inhalation exposure to dusts.
 Workers wear appropriate personal protective equipment, such as gloves, breathing
masks and safety glasses when breaching the system or else being in contact with the
undiluted substance.
Respiratory protection: Respiratory protection is required when workers are exposure to
dusts, if LEV with a suitable efficiency (see table below) is not available. Exposure to dusts
from the handling of solid materials should be reduced by the use of local exhaust
ventilation (efficiency of at least 90%). Some processes occurring outdoors may require
respiratory protection.
If local exhaust ventilation is not available then it will be necessary to use personal
respiratory protection that is compliant with EN141 or EN 405.
Hand protection is recommended: impervious chemical resistant protective gloves.
Material: Material of gloves: Butyl rubber, BR. Fluorocarbon rubber (Viton). Nitrile rubber,
NBR. Natural rubber, NR. Chloroprene rubber, CR. Neoprene gloves.
Version: XX
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SAFETY DATA SHEET
Eye protection
Date of issue: xxx
Workers handling concentrated TKPP solutions or pure, solid substances are obliged to
wear chemical resistant safety goggles. Goggles or face protection shield should be
consistent with EN 166 or equivalent.
Skin and body
protection
Wearing of suitable protective clothing and rubber boots is recommended.
Hygiene
measures
Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at end of
work. Keep work clothes separate.
4.2 RMMs related to the environment
Organisational
measures
Emissions to the environment must meet the requirements of Council Directive 96/61/EC
and National Regulations concerning phosphate in industrial wastewater.
Abatement
measures
related with
wastewater
The efficiency of the process is maximised in such a way that minimal emission of
phosphates into the wastewater will occur. In addition, phosphate can be precipitated from
the wastewater by addition of metal ions.
Abatement
measures
waste air and
solid waste
Emissions of particles into the air of workplaces or the atmosphere can be significantly
reduced by the use of cyclones, gas scrubbers or bag filters. Solid and liquid waste has to
be incinerated or appropriately disposed of as chemical waste.
4.3 Waste related measures
Type of waste
Liquid waste, solid residues.
Disposal
technique
The release of phosphates to wastewater is highly regulated.The residue of the containers
or the used container itself should be disposed in accordance with local requirements. See
Section 13 of the SDS for more information.
Fraction
released to
environment
during waste
treatment
Not determined.
5. Prediction of exposure and comparison of predicted exposure with DNELs (Risk Characterisation)
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
Workers
(inhalation)
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
3
10 mg/m
Revision date: X
ECETOC TRA (2010).
MEASE(EBRC, Eurometaux, 2010): Used to assess exposure to inorganic solutions and
handling of solid inorganics (PROC 26).
The manufacture and processing of TKPP will not notably contribute to the oral intake of
phosphates.
It is also considered that workplace exposure limits for dust are applicable to this
substance in the countries in which the substance is manufactured and used. Therefore,
the exposure estimates will also be compared against a relevant general dust limit for an
inhalable fraction of 10 mg/m3 as described by the occupational exposure limits detailed in
the Technical Rules for Hazardous Materials – TRGS 900, January 2006 (Germany).This
applies to both industrial and professional use as although the two settings are not directly
comparable, it may be prudent to assess both the DNEL and the industrial against the
same values both for consistency and for worker safety.
A comparison of both the DNEL and a dust limit will ensure that downstream users have
enough information on the required RMMs to ensure safe use in line with regional or
national limits.
A number of industrial activities associated with the manufacture and processing of TKPP
may result in inhalation exposure of workers to the substance. The risk characterisation
ratios for these activities are given in the table below. Workers handling concentrated
Version: XX
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SAFETY DATA SHEET
Date of issue: xxx
TKPP solutions or pure, solid substances are obliged to wear chemical resistant safety
goggles. The use of appropriate gloves and working suits is recommended. It is concluded
that conditions can be defined under which the potential health risks from the manufacture
and processing of TKPP are adequately controlled.
Exposure scenario: Risk characterisation of manufacturing and processing of TKPP
Activity type: Industrial
Location: Indoors
LEV
Duration
(hours)
1
No
>4
2
No
>4
8b
No
>4
9
No
>4
1
No
>4
2
No
>4
8b
No
>4
9
No
>4
26
No
>4
1
No
>4
2
No
>4
8b
No
>4
9
No
>4
26
No
>4
1
No
>4
2
No
>4
No
>4
95%
>4
No
>4
90%
>4
No
>4
75%
>4
8b
9
26
Workers
Revision date: X
Airborne
TKPP
RCR
PRE
Conclusion
conc.
(DNEL)
3
(mg/m )
Activities performed with TKPP solutions
Risk
0.001
No
> 25
2.269E-05 Controlled
Risk
0.001
No
> 25
2.269E-05 Controlled
Risk
0.01
No
> 25
0.0002269 Controlled
Risk
0.01
No
> 25
Activities performed with solids of low dustiness
Risk
0.01
No
100
Risk
0.01
No
100
Risk
0.10
No
100
Risk
0.10
No
100
Risk
1.50
Controlled
No
100
0.034029
Activities performed with solids of medium dustiness
Risk
0.01
No
100
Risk
0.50
Controlled
No
100
0.011343
Risk
5.00
No
100
Risk
5.00
No
100
Risk
4.00
No
100
Activities performed with solids of high dustiness
Risk
0.01
No
100
Risk
1.00
Controlled
No
100
0.022686
Risk
25.00
No
100
Risk
No
100
1.25
Risk
20.00
No
100
Risk
No
100
2.00
Risk
10.00
No
100
Risk
No
100
2.50
Process
Category
Weight
fraction
(%)
RCR
(OEL)
0.0001
0.0001
0.001
0.001
0.001
0.001
0.01
0.01
0.15
0.001
0.05
0.5
0.5
0.4
0.001
0.1
2.5
0.125
2
0.2
1
0.25
Conclusion
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
Risk
Controlled
RMMs
required
Risk
Controlled
RMMs
required
Risk
Controlled
RMMs
required
Risk
Controlled
No systemic toxicity effects are expected due to the inorganic nature of the substance
Version: XX
Page 18/97
SAFETY DATA SHEET
Date of issue: xxx
(dermal)
however local effects may occur but these effects will not be dose-dependent but will
depend on the concentration of the substance present in the mixture/solution used in a
specific application.
Indirect
exposure via
the
environment
No indirect exposure of humans via the environment is expected for TKPP, as the
substance can be effectively removed from the wastewater. Thus, no assessment of
indirect exposure of humans via the environment is performed.
Consumer
exposure
No direct consumer exposure is anticipated with the manufacture and processing of TKPP.
It is concluded that the manufacture and processing of TKPP is of no risk for the general
public.
5.2. Environmental exposure (qualitative assessment)
Environmental
release
The production of TKPP can potentially result in aquatic emissions and locally increase the
3phosphate (PO4 ) concentration. Phosphates reaching surface water increase the
phosphorus content in the water body which may cause eutrophication and water quality
deterioration.
Waste water
treatment
plants
(WWTP)
Phosphorus should be removed from industrial wastewater before it is released to the
environment. This can be done by chemical treatment (by precipitation with the help of
aluminium or iron addition) or biological treatments. A high degree of removal can be
reliably achieved by the available phosphorus removal techniques. Site-specific conditions
such as flow rate of the receiving surface water body and phosphorus concentration in the
receiving surface water body should be taken into account when implementing an
appropriate wastewater treatment. Council Directive 96/61/EC concerning integrated
pollution prevention and control and national regulations concerning phosphates in
industrial wastewater have to be followed to minimise the risk of eutrophication due to
phosphate releases.
Aquatic
pelagic
compartment
No direct acute or long-term adverse effects on aqueous or terrestrial organisms are
anticipated with orthophosphates in the environment.
Sediments
No direct acute or long-term adverse effects on aqueous or sediment organisms are
Soil and
groundwater
No direct acute or long-term adverse effects on terrestrial organisms are anticipated with
orthophosphates in the environment.
Atmospheric
compartment
The manufacture of TKPP is not considered to pose a risk to the atmospheric
compartment.
Secondary
poisoning
Bioaccumulation in organisms is not relevant for inorganic phosphates.
ES2: Mixing TKPP into final products
Mixing TKPP into final products
Sector of use
(SU)
SU 3: Industrial uses
SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
SU 13: Manufacture of other non-metallic mineral products, e.g. plasters, cement
SU 11: Manufacture of rubber products
SU 14: Manufacture of basic metals, including alloys
Product
category (PC)
PC 1: Adhesives, sealants
PC 0: Other: Food and feed product
PC 3: Air care products
Revision date: X
Version: XX
Page 19/97
SAFETY DATA SHEET
Date of issue: xxx
PC 7: Base metals and alloys
PC 8: Biocidal products (e.g. disinfectants, pest control)
PC 9a: Coatings and paints, thinners, paint removes
PC 9b: Fillers, putties, plasters, modelling clay
PC 9c: Finger paints
PC 12: Fertilisers
PC 14: Metal surface treatment products, including galvanic and electroplating products
PC 15: Non-metal-surface treatment products
PC 16: Heat transfer fluids
PC 17: Hydraulic fluids
PC 18: Ink and toners
PC 20: Products such as ph-regulators, flocculants, precipitants, neutralisation agents
PC 21: Laboratory chemicals
PC 23: Leather tanning, dye, finishing, impregnation and care products
PC 24: Lubricants, greases, release products
PC 26: Paper and board dye, finishing and impregnation products: including bleaches and
other processing aids
PC 27: Plant protection products
PC 29: Pharmaceuticals
PC 32: Polymer preparations and compounds
PC 34: Textile dyes, finishing and impregnating products; including bleaches and other
processing aids
PC 35: Washing and cleaning products (including solvent based products)
PC 36: Water softeners
PC 37: Water treatment chemicals
PC 39: Cosmetics, personal care products
Process
category
(PROC)
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure
arises
PROC 5: Mixing or blending in batch processes for formulation of preparations and articles
(multistage and/or significant contact)
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to
vessels/large containers at non-dedicated facilities
vessels/large containers at dedicated facilities
including weighing)
PROC 14: Production of preparations or articles by tabletting, compression, extrusion,
pelletisation
PROC 15: Use as laboratory reagent
PROC 21: Low energy manipulation of substances bound in materials and/or articles
PROC 22: Potentially closed processing operations with minerals/metals at elevated
temperature. Industrial setting
PROC 23: Open processing and transfer operations with minerals/metals at elevated
temperature
PROC 24: High (mechanical) energy work-up of substances bound in materials and/or
articles
PROC 26: Handling of solid inorganic substances at ambient temperature
Article
category (AC)
Environmental
release
category
(ERC)
Not applicable
Revision date: X
ERC 2: Formulation of preparations
ERC 3: Formulation in materials
ERC 4: Industrial use of processing aids in processes and products, not becoming part of
articles
ERC 5: Industrial use resulting in inclusion into or onto a matrix
Version: XX
Page 20/97
SAFETY DATA SHEET
Date of issue: xxx
ERC 6a: Industrial use resulting in manufacture of another substance (use of
intermediates)
ERC 6b: Industrial use of reactive processing aids
ERC 6d: Industrial use of process regulators for polymerisation processes in production of
resins, rubbers, polymers
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8b: Wide dispersive indoor use of reactive substances in open systems
Duration of
exposure at
workplace:
No information about frequency and duration of the various tasks is available. In the firsttier assessment of exposure a frequency of once a day and an exposure duration of 8
hours was considered. A single worker may be exposed on 220 days a year.
Frequency of
exposure at
workplace:
Annual
amount used
per site:
Physical state
Solid / Liquid
Concentration
of substance
in mixture
No information about the concentration of the substance in solutions or in solids is
available. In the first-tier assessment of exposure a concentration of 100% w/w was used
to assess exposure to the solid raw material and a concentration of >25% w/w was used to
assess exposure to the aqueous solutions.
No information about frequency and duration of the various tasks is available. In the first-tier assessment of
exposure a frequency of once a day and an exposure duration of 8 hours was considered. A single worker
may be exposed on 220 days a year. No information about the concentration of the substance in solutions
or in solids is available. No information about the concentration of the substance in solutions or in solids is
available. In the first-tier assessment of exposure a concentration of 100% w/w was used to assess
exposure to the solid raw material and a concentration of >25% w/w was used to assess exposure to the
aqueous solutions.
Organisational
measures
instructions (provide training if necessary). PPE are required when breaching the system
or handling the pure substance and concentrated solutions.
Technical
measures
Respiratory
Revision date: X

 Local exhaust / general ventilation should be present when solids are handled to
 Workers wear appropriate personal protective equipment, such as gloves, breathing
dusts, if LEV with a suitable efficiency (see table below) is not available. Exposure to dusts
Version: XX
Page 21/97
SAFETY DATA SHEET
protection
Date of issue: xxx
from the handling of solid materials should be reduced by the use of local exhaust
ventilation (efficiency of at least 90%). Some processes occurring outdoors may require
respiratory protection.
respiratory protection that is compliant with EN141 or EN 405.
Hand
protection
Eye protection
Skin and body
protection
Hygiene
measures
Organisational
measures
Abatement
measures
related with
wastewater
Abatement
measures
waste air and
solid waste
Type of waste
Liquid waste, solid residues.
Disposal
technique
The release of phosphates to wastewater is highly regulated. The residue of the containers
Not determined.
Fraction
released to
environment
during waste
treatment
5. Prediction of exposure and comparison of predicted exposure with DNELs (Risk
Characterisation)
5.1. Human exposure
Exposure
estimation
tool(s)
ECETOC TRA (2010).
Workers (oral)
The use of TKPP in the mixing of final products will not notably contribute to the oral intake
of phosphates.
Workers
(inhalation)
DNEL:
Revision date: X
substance in the countries in which the substance is manufactured and used. Therefore,
the exposure estimates will also be compared against a relevant general dust limit for an
Version: XX
Page 22/97
SAFETY DATA SHEET
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
3
10 mg/m
Date of issue: xxx
inhalable fraction of 10 mg/m3 as described by the occupational exposure limits detailed in
the Technical Rules for Hazardous Materials – TRGS 900, January 2006 (Germany).This
national limits.
A number of industrial activities associated with the the mixing of TKPP into final products
may result in inhalation exposure of workers to the substance. The risk characterisation
ratios for these activities are given in the table below. Workers handling concentrated
TKPP solutions or pure, solid substances are obliged to wear chemical resistant safety
goggles. The use of appropriate gloves and working suits is recommended. It is concluded
that conditions can be defined under which the potential health risks from the manufacture
and processing of TKPP are adequately controlled.
Exposure scenario: Risk characterisation for the mixing of TKPP into final products.
Location: Indoors (In) and outdoors (Out)
No
>4
Out*
30%
>4
In
No
>4
Out*
30%
>4
In
No
>4
Out*
30%
>4
In
No
>4
Out*
30%
>4
In
No
>4
In
90%
>4
In
No
>4
Out*
30%
>4
Out*
30%
>4
In
No
>4
Out*
In
30%
No
>4
>4
Version: XX
Conclusion
In
RCR
(OEL)
>4
Conclusion
Revision date: X
30%
RCR
(DNEL)
8b
9
Out*
Airborne
TKPP conc.
(mg/m3)
7
>4
Weight
fraction (%)
5
No
PRE
4
Time
3
LEV (%
efficiency)
2
Indoors/
Outdoors
Process
Category
1
In
Risk
2.27E0.001
controlled
No
> 25
05
Risk
1.59Econtrolled
No
> 25
0.0007 05
Risk
2.27E0.001
controlled
No
> 25
05
Risk
1.59Econtrolled
No
> 25
0.0007 05
Risk
0.01
controlled
No
> 25
0.0002
Risk
controlled
No
> 25
0.007
0.0002
Risk
0.05
controlled
No
> 25
0.001
Risk
controlled
No
> 25
0.035
0.0008
Risk
0.05
controlled
No
> 25
0.001
Risk
controlled
No
> 25
0.035
0.0008
Risk
20.00
controlled
No
> 25
0.454
Risk
controlled
No
> 25
2.00
0.045
Risk
controlled
75% > 25
5.00
0.113
Risk
controlled
No
> 25
14.00
0.318
Risk
controlled
75% > 25
3.50
0.079
Risk
0.01
controlled
No
> 25
0.0002
Risk
controlled
No
> 25
0.007
0.0002
0.01
Risk
No
> 25
0.0002
0.0001
0.00007
0.0001
0.00007
0.001
0.0007
0.005
0.004
0.005
0.004
2
0.2
0.5
1.4
0.35
0.001
0.0007
0.001
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
Page 23/97
SAFETY DATA SHEET
14
15
1
2
Out*
30%
In
No
Out*
30%
In
No
Out*
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
3
4
5
7
8b
9
14
15
21
22a
pt<mp Low
Fugacity
22b
pt ≈ mp
- Med
Fugacity
Revision date: X
Date of issue: xxx
controlled
Risk
controlled
>4
No
> 25
0.007
0.0002
Risk
0.01
controlled
>4
No
> 25
0.0002
Risk
controlled
>4
No
> 25
0.007
0.0002
Risk
0.01
controlled
>4
No
> 25
0.0002
Risk
controlled
>4
No
> 25
0.007
0.0002
Risk
0.01
controlled
>4
No
100
0.0002
Risk
controlled
>4
No
100
0.007
0.0002
Risk
0.01
controlled
>4
No
100
0.0002
Risk
controlled
>4
No
100
0.007
0.0002
Risk
0.10
controlled
>4
No
100
0.0023
Risk
controlled
>4
No
100
0.07
0.0016
Risk
0.50
controlled
>4
No
100
0.0113
Risk
controlled
>4
No
100
0.35
0.0079
Risk
0.50
controlled
>4
No
100
0.0113
Risk
controlled
>4
No
100
0.35
0.0079
Risk
1.00
controlled
>4
No
100
0.0227
Risk
controlled
>4
No
100
0.70
0.0159
Risk
0.10
controlled
>4
No
100
0.0023
Risk
controlled
>4
No
100
0.07
0.0016
Risk
0.10
controlled
>4
No
100
0.0023
Risk
controlled
>4
No
100
0.07
0.0016
Risk
0.10
controlled
>4
No
100
0.0023
Risk
controlled
>4
No
100
0.07
0.0016
Risk
0.10
controlled
>4
No
100
0.0023
Risk
controlled
>4
No
100
0.07
0.0016
Risk
1.00
controlled
>4
No
100
0.0227
Risk
controlled
>4
No
100
0.70
0.0159
Risk
1.00
controlled
>4
No
100
0.0227
Risk
controlled
>4
No
100
0.70
0.0159
Risk
3.00
controlled
>4
No
100
0.0681
Risk
controlled
>4
No
100
2.10
0.0476
Version: XX
0.0007
0.001
0.0007
0.001
0.0007
0.001
0.0007
0.001
0.0007
0.01
0.007
0.05
0.035
0.05
0.035
0.1
0.07
0.01
0.007
0.01
0.007
0.01
0.007
0.01
0.007
0.1
0.07
0.1
0.07
0.3
0.21
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 24/97
SAFETY DATA SHEET
Date of issue: xxx
Risk
controlled
Risk
controlled
>4
No
100
1.00
0.0227
Risk
controlled
>4
No
100
7.00
0.1588
Risk
1.00
controlled
>4
No
100
0.0227
Risk
controlled
>4
No
100
0.70
0.0159
Risk
3.00
controlled
>4
No
100
0.0681
Risk
controlled
>4
No
100
2.10
0.0476
Risk
10.00
controlled
>4
No
100
0.2269
Risk
controlled
>4
No
100
1.00
0.0227
Risk
controlled
>4
No
100
7.00
0.1588
Risk
1.00
controlled
>4
No
100
0.0227
Risk
controlled
>4
No
100
0.70
0.0159
Risk
3.00
controlled
>4
No
100
0.0681
Risk
controlled
>4
No
100
2.10
0.0476
Risk
10.00
controlled
>4
No
100
0.2269
Risk
controlled
>4
No
100
2.00
0.0454
Risk
controlled
>4
No
100
7.00
0.1588
Risk
1.50
controlled
>4
No
100
0.0340
Risk
controlled
>4
No
100
1.05
0.0238
Risk
0.01
>4
No
100
0.0002
controlled
Risk
>4
No
100
0.007
0.0002
controlled
No
In
90%
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
In
90%
Out
30%
24a
Low
Fugacity
In
No
Out
30%
24b
Med
Fugacity
In
No
Out
30%
In
No
In
80%
Out
30%
In
No
Out*
30%
In
No
Out
30%
In
No
>4
No
100
0.50
0.011
Out
30%
>4
No
100
0.35
0.008
In
No
>4
No
100
1.00
0.023
Out
30%
>4
No
100
0.70
0.016
In
No
>4
No
100
5.00
0.113
Out
30%
>4
No
100
3.50
0.079
In
No
>4
No
100
5.00
0.113
Out
30%
>4
No
100
3.50
0.079
In
No
>4
No
100
20.00
0.454
In
95%
>4
No
100
1.00
0.023
Out
Out
30%
30%
>4
>4
No
90%
100
100
14.00
1.40
0.318
0.032
22c
pt > mp
- High
Fugacity
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
24c
High
Fugacity
26
1
2
3
4
>4
No
100
10.00
In
0.2269
5
7
Revision date: X
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
1
0.1
0.7
0.1
0.07
0.3
0.21
1
0.1
0.7
0.1
0.07
0.3
0.21
1
0.2
0.7
0.15
0.105
0.001
0.0007
0.05
0.035
0.1
0.07
0.5
0.35
0.5
0.35
2
0.1
1.4
0.14
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
Page 25/97
SAFETY DATA SHEET
Date of issue: xxx
In
No
>4
No
100
5.00
0.113
Out
30%
>4
No
100
3.50
0.079
In
No
>4
No
100
5.00
0.113
Out
30%
>4
No
100
3.50
0.079
In
No
>4
No
100
1.00
0.023
Out
30%
>4
No
100
0.70
0.016
In
No
>4
No
100
0.50
0.011
Out
30%
>4
No
100
0.35
0.008
In
No
>4
No
100
3.00
0.068
21
Out
30%
>4
No
100
2.10
0.048
22a
pt<mp Low
Fugacity
In
No
>4
No
100
1.00
0.023
Out
30%
>4
No
100
0.07
0.002
22b
pt ≈ mp
- Med
Fugacity
In
No
>4
No
100
3.00
0.068
Out
30%
>4
No
100
2.10
0.048
In
No
>4
No
100
10.00
0.227
In
90%
>4
No
100
1.00
0.023
Out
30%
>4
No
100
7.00
0.159
In
No
>4
No
100
1.00
0.023
Out
30%
>4
No
100
0.70
0.016
In
No
>4
No
100
3.00
0.068
Out
30%
>4
In
No
In
90%
Out
30%
24a
Low
Fugacity
In
No
Out
30%
24b
Med
Fugacity
In
No
Out
30%
In
No
In
80%
Out
30%
In
No
Out*
No
In
No
8b
9
14
15
22c
pt ≈ mp
– High
Fugacity
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
24c
High
Fugacity
26
1
Revision date: X
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
10.00
>4
No
100
0.227
controlled
Risk
>4
No
100
1.00
0.023
controlled
Risk
>4
No
100
7.00
0.159
controlled
Risk
1.00
>4
No
100
0.023
controlled
Risk
>4
No
100
0.70
0.016
controlled
Risk
3.00
>4
No
100
0.068
controlled
Risk
>4
No
100
2.10
0.048
controlled
Risk
10.00
>4
No
100
0.227
controlled
Risk
>4
No
100
2.00
0.045
controlled
Risk
>4
No
100
7.00
0.159
controlled
Risk
4.00
>4
No
100
0.091
controlled
Risk
>4
No
100
2.80
0.064
controlled
Risk
0.01
>4
No
100
0.0002
controlled
No
100
Version: XX
2.10
0.048
0.5
0.35
0.5
0.35
0.1
0.07
0.05
0.035
0.3
0.21
0.1
0.007
0.3
0.21
1
0.1
0.7
0.1
0.07
0.3
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
0.28
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
0.001
Risk
controlled
0.21
1
0.1
0.7
0.1
0.07
0.3
0.21
1
0.2
0.7
0.4
Page 26/97
SAFETY DATA SHEET
2
3
4
5
7
8b
9
14
15
21
22a
pt<mp Low
Fugacity
Revision date: X
Date of issue: xxx
Out
30%
>4
No
100
0.007
0.0002
In
No
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
0.70
0.0159
In
No
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
0.70
0.0159
In
No
>4
No
100
25.00
0.5672
In
90%
>4
No
100
2.50
0.0567
Out
30%
>4
No
100
17.50
0.3970
Out
30%
>4
90%
100
1.75
0.0397
In
No
>4
No
100
25.00
0.5672
In
90%
>4
No
100
2.50
0.0567
Out
30%
>4
No
100
17.50
0.3970
Out
30%
>4
90%
100
1.75
0.0397
In
No
>4
No
100
100.00
2.2686
In
95%
>4
No
100
5.00
0.1134
Out
30%
>4
No
100
70.00
1.5880
Out
30%
>4
90%
100
7.00
0.1588
In
No
>4
No
100
25.00
0.5672
In
95%
>4
No
100
1.25
0.0284
Out
30%
>4
No
100
17.50
0.3970
Out
30%
>4
90%
100
1.75
0.0397
In
No
>4
No
100
20.00
0.4537
In
90%
>4
No
100
2.00
0.0454
Out
30%
>4
No
100
14.00
0.3176
Out
30%
>4
90%
100
1.40
0.0318
In
No
>4
No
100
10.00
0.2269
In
90%
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
7.00
0.1588
In
4 to 8
100
5
0.1134
Out
4 to 8
100
0.5
0.0113
In
No
>4
No
100
10.00
0.2269
In
90%
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
7.00
0.1588
In
No
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
0.70
0.0159
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
0.0007
0.1
0.07
0.1
0.07
2.5
0.25
1.75
0.175
2.5
0.25
1.75
0.175
10
0.5
7
0.7
2.5
0.125
1.75
0.175
2
0.2
1.4
0.14
1
0.1
0.7
0.5
0.05
1
0.1
0.7
0.1
0.07
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 27/97
SAFETY DATA SHEET
22b
pt ≈ mp
- Med
Fugacity
Out
Date of issue: xxx
No
>4
No
100
3.00
0.0681
30%
>4
No
100
2.10
0.0476
In
No
>4
No
100
10.00
0.2269
In
90%
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
7.00
0.1588
In
No
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
0.70
0.0159
In
No
>4
No
100
3.00
0.0681
Out
30%
>4
No
100
2.10
0.0476
In
No
>4
No
100
10.00
0.2269
In
90%
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
7.00
0.1588
24a
Low
Fugacity
In
No
>4
No
100
1.00
0.0227
Out
30%
>4
No
100
0.70
0.0159
24b
Med
Fugacity
In
No
>4
No
100
3.00
0.0681
Out
30%
>4
No
100
2.10
0.0476
22c
pt > mp
- High
Fugacity
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
24c
High
Fugacity
26
In
No
>4
No
100
10.00
0.2269
In
80%
>4
No
100
2.00
0.0454
Out
30%
>4
No
100
7.00
0.1588
In
No
>4
No
100
10.00
0.2269
In
75%
>4
No
100
2.50
0.0567
Out*
30%
>4
No
100
7.00
0.1588
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
0.3
0.21
1
0.1
0.7
0.1
0.07
0.3
0.21
1
0.1
0.7
0.1
0.07
0.3
0.21
1
0.2
0.7
1
0.25
0.7
*Outdoor exposure of industrial workers assumed to be reduced by 30% to give
consistency with ECETOC calculations for solids.
Workers
(dermal)
Indirect
exposure via
the
environment
Consumer
exposure
No direct consumer exposure is anticipated with the mixing of TKPP into final products. It
is concluded that the mixing of TKPP into final products is of no risk for the general public.
Environmental
release
Revision date: X
The use of TKPP can potentially result in aquatic emissions and locally increase the
deterioration.
Version: XX
Page 28/97
SAFETY DATA SHEET
Date of issue: xxx
Waste water
treatment
plants
(WWTP)
phosphate releases.
Aquatic
pelagic
compartment
Sediments
Soil and
groundwater
Atmospheric
compartment
The formulation of TKPP is not considered to pose a risk to the atmospheric compartment.
Secondary
poisoning
ES3: Use as raw material, process aid and laboratory agent in
chemical synthesis
Use as raw material in chemical industry (synthesis), reactive processing aid and laboratory agent
Sector of use
(SU)
Product
category (PC)
Process
category
(PROC)
Revision date: X
SU 8: Manufacture of bulk, large scale chemicals (including petroleum products)
SU 9: Manufacture of fine chemicals
SU 12: Manufacture of plastics products, including compounding and conversion
PC 19: Intermediate
PC 21: Laboratory chemicals
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
including weighing)
pelletisation
PROC 15: Use as laboratory reagent
PROC 19: Hand-mixing with intimate contact and only PPE available.
Version: XX
Page 29/97
SAFETY DATA SHEET
Date of issue: xxx
Article
category (AC)
Environmental
release
category
(ERC)
Not applicable
articles
ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates)
ERC 6d: Industrial use of process regulators for polymerisation processes in production of
resins, rubbers, polymers
ERC 8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix
Duration of
exposure at
workplace:
Frequency of
exposure at
workplace:
Annual
amount used
per site:
TKPP may be used in chemical synthesis on 365 days a year for 24 hours a day divided
into three working shifts. A single worker may be exposed on 220 days a year. No
information about frequency and duration of the various tasks is available. In the first-tier
assessment of exposure a frequency of once a day and an exposure duration of 8 hours
will be considered.
Physical state
Solid / Liquid
Concentration
of substance
in mixture
A concentration of 100% w/w was used to assess exposure to the solid substance. The
concentration of TKPP in solutions was set to > 25% w/w.
Not applicable.
Organisational
measures
instructions (provide training if necessary). PPE are required when breaching the system or
handling the pure substance and concentrated solutions.
Technical
measures





Revision date: X
Use of pliers, grip arms with long handles with manual use “to avoid direct contact and
Store in cool, dry, clean, well ventilate areas. (Good practice).
Local exhaust / general ventilation should be present when solids are handled to
Workers wear appropriate personal protective equipment, such as gloves, breathing
Version: XX
Page 30/97
SAFETY DATA SHEET
Date of issue: xxx
Respiratory
protection
Hand
protection
Eye protection
dusts, if LEV with an efficiency of ≥90% is not available. Exposure to dusts from the
handling of solid materials should be reduced by the use of local exhaust ventilation
(efficiency of at least 90%, please see below for specific requirements).
NOTE. For certain processes an efficiency of ≥95% is assumed. Please see below
exposure summary for details.
respiratory protection that is compliant with EN141 or EN 405 and has a sufficient
efficiency.
Hand protection is recommended: impervious chemical resistant protective gloves. Material:
Material of gloves: Butyl rubber, BR. Fluorocarbon rubber (Viton). Nitrile rubber, NBR.
Natural rubber, NR. Chloroprene rubber, CR. Neoprene gloves.
Skin and body
protection
Hygiene
measures
Organisational
measures
Abatement
measures
related with
wastewater
Abatement
measures
waste air and
solid waste
Type of waste
Liquid waste, solid residues, packaging materials.
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
ECETOC TRA (2010).
Workers (oral)
The use of TKPP in chemical synthesis will not notably contribute to the oral intake of
phosphates.
Revision date: X
Version: XX
Page 31/97
SAFETY DATA SHEET
Date of issue: xxx
It is also considered that workplace exposure limits for dust are applicable to this substance
in the countries in which the substance is manufactured and used. Therefore, the exposure
estimates will also be compared against a relevant general dust limit for an inhalable
fraction of 10 mg/m3 as described by the occupational exposure limits detailed in the
Technical Rules for Hazardous Materials – TRGS 900, January 2006 (Germany).This
national limits.
A number of industrial activities associated with the mixing of TKPP into final products may
result in inhalation exposure of workers to the substance. The risk characterisation ratios for
these activities are given in the table below. Workers handling concentrated TKPP solutions
or pure, solid substances are obliged to wear chemical resistant safety goggles. The use of
appropriate gloves and working suits is recommended. It is concluded that conditions can
be defined under which the potential health risks from the use of TKPP in chemical
synthesis are adequately controlled.
Workers
(inhalation)
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
10 mg/m3
Revision date: X
Exposure scenario: Risk characterisation for use of TKPP as a raw material in chemical
synthesis, as a process aid or as a laboratory reagent
Location: Indoors
Airborne
Weight TKPP
fraction conc.
RCR
PRE (%)
(mg/m3) (DNEL)
Conclusion
Process
Category
LEV
Duration
(hours)
1
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
2
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
3
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
4
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
5
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
No
>4
No
> 25
20.00
0.45372
Risk controlled
2
90%
>4
No
> 25
2.00
0.04537
Risk controlled
0.2
7
No
>4
75%
> 25
5.00
0.11343
Risk controlled
0.5
8b
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
9
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
14
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
15
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
19
No
>4
0.05
No
> 25
0.00113 Risk controlled
0.005
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Version: XX
RCR
(OEL)
Conclusion
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 32/97
SAFETY DATA SHEET
Date of issue: xxx
3
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
4
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
5
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
7
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
9
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
14
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
15
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
19
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
26
No
>4
1.50
Risk controlled
No
100
0.0340
0.15
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
3
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
4
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
5
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
20.00
0.4537
Risk controlled
2
7
95%
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
15
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
19
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
26
No
>4
4.00
Risk controlled
No
100
0.0907
0.4
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
3
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
7
No
>4
No
100
100.00
2.2686
Risk controlled
10
9
14
4
Revision date: X
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 33/97
SAFETY DATA SHEET
8b
9
Date of issue: xxx
95%
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
95%
>4
No
100
1.25
0.0284
Risk controlled
0.125
No
>4
No
100
20.00
0.4537
Risk controlled
2
90%
>4
No
100
2.00
0.0454
Risk controlled
0.2
No
>4
No
100
10.00
0.2269
Risk controlled
1
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
No
>4
No
100
5
0.1134
Risk controlled
0.5
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
10.00
0.2269
Risk controlled
1
75%
>4
No
100
2.50
0.0567
Risk controlled
0.25
14
15
19
26
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Workers
(dermal)
specific application. Workers are recommended to wear the appropriate PPE.
Indirect
exposure via
the
environment
Consumer
exposure
No direct consumer exposure is anticipated with the use of TKPP as a raw material and
process aid in chemical synthesis. It is concluded that the use of TKPP as a raw material
and process aid in chemical synthesis is of no risk for the general public.
Environmental
release
deterioration.
Waste water
treatment
plants
(WWTP)
phosphate releases.
Aquatic
pelagic
compartment
Sediments
Revision date: X
Version: XX
Page 34/97
SAFETY DATA SHEET
Date of issue: xxx
Soil and
groundwater
Atmospheric
compartment
The use of TKPP as a raw material and process aid in chemical synthesis is not considered
to pose a risk to the atmospheric compartment.
Secondary
poisoning
ES4: Use of TKPP and products containing TKPP for treatment
and finishing of metals
Use of TKPP and products containing TKPP for treatment and finishing of metals
Sector of use
(SU)
Product
category
(PC)
PC 14: Metal surface treatment products, including galvanic and electroplating products
PC 25: Metal working fluids
PC 33: Semiconductors
Process
category
(PROC)
PROC 6: Calendaring operations
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large
containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large
containers at dedicated facilities
including weighing)
PROC 10: Roller application or brushing
PROC 11: Non industrial spraying
PROC 12: Use of blowing agents in manufacture of foam
PROC 13: Treatment of articles by dipping and pouring
PROC 17: Lubrication at high energy conditions and in partly open process
articles
Article
category
(AC)
Not applicable
Revision date: X
SU 14: Manufacture of basic metals, including alloys
SU 15: Manufacture of fabricated metal products, except machinery and equipment
SU 16: Manufacture of computer, electronic and optical products, electrical equipment
SU 17: General manufacturing, e.g. machinery, equipment, vehicles, other transport
equipment
SU 22: Professional uses
Version: XX
Page 35/97
SAFETY DATA SHEET
Environment
al release
category
(ERC)
Date of issue: xxx
articles
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
ERC 8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix
ERC 8e: Wide dispersive outdoor use of reactive substances in open systems
Duration of
exposure at
workplace:
No information about frequency and duration of the various tasks is available. In the first-tier
assessment of exposure a frequency of once a day and an exposure duration of 8 hours will
be considered.
Frequency of
exposure at
workplace:
Annual
amount used
per site:
The daily and annual amount/emission per site is not considered to be the main determinant
for environmental exposure.
Physical
state
Solid / Liquid
Concentratio
n of
substance in
mixture
In the first-tier assessment of exposure the concentration of TKPP in solid form is set to
100% w/w; the concentration in the delivered solution is > 25% w/w.
Not applicable.
Organisationa
l measures
Technical
measures





Revision date: X
Use of pliers, grip arms with long handles with manual use “to avoid direct contact and
Local exhaust / general ventilation should be present when solids are handled to reduce
the likelihood of inhalation exposure to dusts.
Breathing masks and local exhaust ventilation are present during industrial or nonindustrial spraying of solutions onto metal surfaces.
Version: XX
Page 36/97
SAFETY DATA SHEET
Respiratory
protection
Date of issue: xxx
NOTE. For certain processes an efficiency of ≥95% is assumed. Please see below exposure
summary for details
It is assumed that professional locations may not have sufficient local exhaust ventilation,
therefore , If local exhaust ventilation is not available then it will be necessary to use
personal respiratory protection that is compliant with EN141 or EN 405 and has a sufficient
efficiency (see table below for assumed APF and/or efficiency values).
Hand
protection
Eye
protection
consistent with EN 166 or equivalent. Eye protection is also recommended when workers
are using metal parts treated with TKPP.
Skin and
body
protection
Hygiene
measures
Organisationa
l measures
Abatement
measures
related with
wastewater
Abatement
measures
waste air and
solid waste
Type of waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
Workers
Revision date: X
ECETOC TRA (2010).
The use of TKPP in metal treatment and finishing will not notably contribute to the oral
Version: XX
Page 37/97
SAFETY DATA SHEET
(oral)
Date of issue: xxx
intake of phosphates.
estimates will also be compared against a relevant general dust limit for an inhalable fraction
of 10 mg/m3 as described by the occupational exposure limits detailed in the Technical
Rules for Hazardous Materials – TRGS 900, January 2006 (Germany).This applies to both
industrial and professional use as although the two settings are not directly comparable, it
may be prudent to assess both the DNEL and the industrial against the same values both
for consistency and for worker safety.
national limits.
INDUSTRIAL USERS:
Various industrial activities associated with metal treatment and finishing may result in
inhalation exposure of workers to TKPP. The risk characterisation ratios for these activities
are given in the table below. Workers handling concentrated TKPP solutions or pure, solid
substances are obliged to wear chemical resistant safety goggles. The use of appropriate
gloves and working suits is recommended. It is concluded that conditions can be defined
under which the potential health risks from the use of TKPP in metal treatment and finishing
are adequately controlled.
Workers
(inhalation)
Table 1.
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
Exposure scenario: Risk characterisation for the industrial use of TKPP and products
containing TKPP in metal treatment and finishing
Location: Indoors
General dust
exposure
limit: 10
mg/m3
Process
Category
LEV
Duratio
n
(hours)
1
No
>4
No
> 25
0.001
0.0000
2
2
No
>4
No
> 25
0.001
4
No
>4
No
> 25
5
No
No
90
%
7 -Industrial
spraying
8b Transfer of
chemicals
from/to
vessels/
large
containers
at
dedicated
facilities
9 -Transfer
of
chemicals
Revision date: X
Airborn
e TKPP
Weight conc.
PR
fractio
(mg/m3
RCR
E
n (%)
)
(DNEL)
Conclusion
>4
>4
No
No
> 25
> 25
> 25
RCR
(OEL)
Conclusio
n
Risk controlled
0.000
1
0.0000
2
Risk controlled
0.000
1
0.05
0.0011
3
Risk controlled
0.005
0.05
0.0011
3
Risk controlled
0.005
20.00
0.4537
2
Risk controlled
2
2.00
0.0453
7
Risk controlled
0.2
Risk controlled
0.5
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
>4
No
No
>4
75
%
> 25
5.00
0.1134
3
No
>4
No
> 25
0.01
0.0002
3
Risk controlled
0.001
Risk
controlled
No
>4
No
> 25
0.01
0.0002
3
Risk controlled
0.001
Risk
controlled
Version: XX
Page 38/97
SAFETY DATA SHEET
into small
containers
(dedicated
filling line)
10 – Roller
application
or brushing
12 – Use of
blowing
agents in
manufactur
e of foam
13 –
Treatment
of articles
by dipping
and pouring
17 –
Lubrication
at high
energy
conditions
and in
partly open
process
19 – Hand
mixing with
intimate
contact and
only PPE
available
Revision date: X
Date of issue: xxx
No
>4
No
> 25
0.05
0.0011
3
Risk controlled
0.005
Risk
controlled
No
>4
No
> 25
< 0.001
0.0000
2
Risk controlled
0.000
1
Risk
controlled
No
>4
No
> 25
0.01
0.0002
3
Risk controlled
0.001
Risk
controlled
No
>4
No
> 25
0.10
0.0022
7
Risk controlled
0.01
Risk
controlled
No
>4
0.005
Risk
controlled
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
4
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
5
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
6
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
7
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
9
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
10
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
13
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
17
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
19
24a
Low
Fugacity
24b
Med
Fugacity
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Risk
controlled
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
24c
High
Fugacity
No
80
%
>4
No
100
10.00
0.2269
Risk controlled
1
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
4
5
No
No
>4
>4
No
No
100
100
5.00
5.00
0.1134
0.1134
Risk controlled
Risk controlled
0.5
0.5
>4
0.0011
0.05
Risk controlled
No
> 25
3
No
100
2.00
0.0454
Risk controlled
Version: XX
0.2
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
Page 39/97
SAFETY DATA SHEET
Date of issue: xxx
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
95
%
>4
No
100
20.00
0.4537
Risk controlled
2
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
9
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
10
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
13
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
>4
No
100
20.00
0.4537
Risk controlled
2
17
No
95
%
>4
No
100
1.00
0.0227
Risk controlled
0.1
19
24a
Low
Fugacity
24b
Med
Fugacity
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Risk
controlled
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
24c
High
Fugacity
No
80
%
>4
No
100
10.00
0.2269
Risk controlled
1
1
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
>4
No
100
25.00
0.5672
Risk controlled
2.5
4
No
90
%
>4
No
100
2.50
0.0567
Risk controlled
0.25
>4
No
100
25.00
0.5672
Risk controlled
2.5
>4
>4
No
No
100
100
2.50
25.00
0.0567
0.5672
Risk controlled
Risk controlled
0.25
2.5
6
No
90
%
No
90
%
>4
No
100
2.50
0.0567
0.25
>4
No
100
100.00
2.2686
7
No
95
%
Risk controlled
RMMs
required
>4
No
100
5.00
0.1134
Risk controlled
0.5
>4
No
100
25.00
0.5672
Risk controlled
2.5
8b
No
95
%
>4
No
100
1.25
0.0284
Risk controlled
0.125
>4
No
100
20.00
0.4537
Risk controlled
2
9
No
90
%
>4
No
100
2.00
0.0454
Risk controlled
0.2
No
90
%
>4
No
100
10.00
0.2269
Risk controlled
1
>4
No
100
1.00
0.0227
Risk controlled
0.1
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
95
%
No
>4
No
100
50.00
1.1343
Risk controlled
5
>4
>4
No
No
100
100
2.50
25.00
0.0567
0.5672
Risk controlled
Risk controlled
0.25
2.5
6
7
5
10
13
17
19
Revision date: X
>4
No
100
2.00
0.0454
Risk controlled
Version: XX
0.2
10
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
Page 40/97
SAFETY DATA SHEET
24a
Low
Fugacity
24b
Med
Fugacity
24c
High
Fugacity
Date of issue: xxx
90
%
>4
No
100
2.50
0.0567
Risk controlled
0.25
required
Risk
controlled
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Risk
controlled
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
No
80
%
>4
No
100
10.00
0.2269
Risk controlled
1
>4
No
100
2.00
0.0454
Risk controlled
0.2
Risk
controlled
RMMs
required
Risk
controlled
*Outdoor exposure of industrial workers assumed to be reduced by 30% to give consistency
with ECETOC calculations for solids.
PROFESSIONAL USERS:
Various professional activities associated with metal treatment and finishing may result in
inhalation exposure to TKPP of workers. The risk characterisation ratios for these activities
under which the potential health risks from the use of TKPP in professional metal treatment
and finishing are adequately controlled.
Table 2.
Exposure scenario: Risk characterisation for the professional use of TKPP and products
containing TKPP in metal treatment and finishing
Location: Indoors (Ind / Outdoors (Out)
Activity type: Professional
No
>4
Out
30%
>4
In
No
>4
Out
30%
>4
In
No
>4
Out
30%
>4
In
No
>4
In
80%
>4
Version: XX
Conclusion
In
RCR
(OEL)
>4
Conclusion
30%
RCR
(DNEL)
Out
Airborne
TKPP conc.
(mg/m3)
Revision date: X
>4
Weight
fraction (%)
11
No
PRE
10
Duration
(hours)
8a
LEV
5
Location
Process
Category
4
In
Risk
No
> 25 0.10
0.0023 controlled
Risk
No
> 25 0.071
0.0016 controlled
Risk
No
> 25 0.10
0.0023 controlled
Risk
No
> 25 0.071
0.0016 controlled
Risk
No
> 25 0.05
0.0011 controlled
Risk
No
> 25 0.036
0.0008 controlled
Risk
No
> 25 0.05
0.0011 controlled
Risk
No
> 25 0.036
0.0008 controlled
Risk
No
> 25 20.00
0.4537 controlled
Risk
No
> 25 4.00
0.0907 controlled
0.01
Risk controlled
0.0071
Risk controlled
0.01
Risk controlled
0.0071
Risk controlled
0.005
Risk controlled
0.0036
Risk controlled
0.005
Risk controlled
0.0036
Risk controlled
2
RMMs required
0.4
Risk controlled
Page 41/97
SAFETY DATA SHEET
Out
30%
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
5
Out
30%
6
In
No
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
5
Out
30%
6
In
No
In
No
Out
30%
In
No
Out
30%
In
No
In
80%
In
No
13
19
4
8a
10
11
13
19
4
8a
10
11
Revision date: X
Date of issue: xxx
Risk
controlled
Risk
>4
75% > 25 3.56
0.0808 controlled
Risk
>4
No
> 25 0.05
0.0011 controlled
Risk
>4
No
> 25 0.036
0.0008 controlled
Risk
>4
No
> 25 0.05
0.0011 controlled
Risk
>4
No
> 25 0.05
0.0011 controlled
Risk
1.00
>4
No
100
0.0227 controlled
Risk
>4
No
100
0.70
0.0159 controlled
Risk
1.00
>4
No
100
0.0227 controlled
Risk
>4
No
100
0.70
0.0159 controlled
Risk
>4
No
100
0.1
0.0023 controlled
Risk
0.50
>4
No
100
0.0113 controlled
Risk
>4
No
100
0.35
0.0079 controlled
Risk
0.50
>4
No
100
0.0113 controlled
Risk
>4
No
100
0.35
0.0079 controlled
Risk
1.00
>4
No
100
0.0227 controlled
Risk
>4
No
100
0.70
0.0159 controlled
Risk
0.50
>4
No
100
0.0113 controlled
Risk
>4
No
100
0.35
0.0079 controlled
Risk
0.50
>4
No
100
0.0113 controlled
Risk
>4
No
100
0.35
0.0079 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
Risk
>4
No
100
5.00
0.1134 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
Risk
20.00
>4
No
100
0.4537 controlled
Risk
>4
No
100
4.00
0.0907 controlled
Risk
>4
90% 100
2.00
0.0454 controlled
>4
No
> 25
Version: XX
14.25
0.3233
1.425
Risk controlled
0.356
Risk controlled
0.005
Risk controlled
0.0036
Risk controlled
0.005
Risk controlled
0.005
Risk controlled
0.1
Risk controlled
0.07
Risk controlled
0.1
Risk controlled
0.07
Risk controlled
0.01
Risk controlled
0.05
Risk controlled
0.035
Risk controlled
0.05
Risk controlled
0.035
Risk controlled
0.1
Risk controlled
0.07
Risk controlled
0.05
Risk controlled
0.035
Risk controlled
0.05
Risk controlled
0.035
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
0.5
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
2
RMMs required
0.4
Risk controlled
0.2
Risk controlled
Page 42/97
SAFETY DATA SHEET
13
19
4
5
8a
10
11
Revision date: X
Out
30%
Out
30%
In
No
Out
30%
In
No
Out
30%
In
No
In
80%
In
80%
In
No
Out
30%
Out
30%
In
No
In
80%
In
80%
In
No
Out
30%
Out
30%
In
No
In
80%
In
80%
In
No
Out
30%
Out
30%
In
No
In
80%
In
No
Out
30%
In
No
In
80%
In
80%
In
No
In
No
In
80%
Out
30%
Out
30%
Date of issue: xxx
Risk
controlled
Risk
>4
90% 100
1.40
0.0318 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
Risk
5.00
>4
No
100
0.1134 controlled
Risk
>4
No
100
3.50
0.0794 controlled
RMMs
50.00
>4
No
100
1.1343 required
Risk
>4
No
100
10.00
0.2269 controlled
Risk
1 to 4
No
100
6.00
0.1361 controlled
Risk
>4
90% 100
5.00
0.1134 controlled
Risk
>4
No
100
35.00
0.7940 controlled
Risk
>4
90% 100
3.50
0.0794 controlled
RMMs
50.00
>4
No
100
1.1343 required
Risk
>4
No
100
10.00
0.2269 controlled
Risk
1 to 4
No
100
6.00
0.1361 controlled
Risk
>4
90% 100
5.00
0.1134 controlled
Risk
>4
No
100
35.00
0.7940 controlled
Risk
>4
90% 100
3.50
0.0794 controlled
RMMs
50.00
>4
No
100
1.1343 required
Risk
>4
No
100
10.00
0.2269 controlled
Risk
1 to 4
No
100
6.00
0.1361 controlled
Risk
>4
90% 100
5.00
0.1134 controlled
Risk
>4
No
100
35.00
0.7940 controlled
Risk
>4
90% 100
3.50
0.0794 controlled
Risk
10.00
>4
No
100
0.2269 controlled
Risk
>4
No
100
2.00
0.0454 controlled
Risk
>4
90% 100
1.00
0.0227 controlled
Risk
>4
No
100
7.00
0.1588 controlled
RMMs
200.00 4.5372 required
>4
No
100
Risk
>4
No
100
40.00
0.9074 controlled
Risk
0.25 to 1 No
100
8.00
0.1815 controlled
Risk
>4
90% 100
20.00
0.4537 controlled
Risk
0.25 to 1 90% 100
4.00
0.0907 controlled
Risk
>4
90% 100
4.00
0.0907 controlled
RMMs
>4
No
100
140.00 3.1760 required
Risk
>4
95% 100
7.00
0.1588 controlled
>4
No
100
Version: XX
14.00
0.3176
1.4
RMMs required
0.14
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
0.5
Risk controlled
0.35
Risk controlled
5
RMMs required
1
RMMs required
0.6
Risk controlled
0.5
Risk controlled
3.5
Risk controlled
0.35
Risk controlled
5
RMMs required
1
RMMs required
0.6
Risk controlled
0.5
Risk controlled
3.5
Risk controlled
0.35
Risk controlled
5
RMMs required
1
RMMs required
0.6
Risk controlled
0.5
Risk controlled
3.5
RMMs required
0.35
Risk controlled
1
RMMs required
0.2
Risk controlled
0.1
Risk controlled
0.7
Risk controlled
20
RMMs required
4
RMMs required
0.8
Risk controlled
2
RMMs required
0.4
Risk controlled
0.4
Risk controlled
14
RMMs required
0.7
Risk controlled
Page 43/97
SAFETY DATA SHEET
13
19
Date of issue: xxx
In
No
>4
No
100
5.00
0.1134
Out
30%
>4
No
100
3.50
0.0794
In
No
>4
No
100
50.00
1.1343
In
80%
>4
No
100
10.00
0.2269
In
80%
1 to 4
No
100
3.00
0.0681
In
No
>4
90%
100
5.00
0.1134
Out
30%
>4
No
100
35.00
0.7940
Out
30%
>4
90%
100
3.50
0.0794
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
0.5
Risk controlled
0.35
Risk controlled
5
RMMs required
1
RMMs required
0.3
Risk controlled
0.5
Risk controlled
3.5
RMMs required
0.35
Risk controlled
Workers
(dermal)
Indirect
exposure via
the
environment
substance can be effectively removed from the wastewater. Thus, no assessment of indirect
exposure of humans via the environment is performed.
Consumer
exposure
No direct consumer exposure is anticipated with the use of TKPP in metal treatment and
finishing. It is concluded that the use of TKPP in metal treatment and finishing is of no risk
for the general public.
Environmenta
l release
deterioration.
Waste water
treatment
plants
(WWTP)
aluminium or iron addition) or biological treatments. A high degree of removal can be reliably
achieved by the available phosphorus removal techniques. Site-specific conditions such as
flow rate of the receiving surface water body and phosphorus concentration in the receiving
surface water body should be taken into account when implementing an appropriate
wastewater treatment. Council Directive 96/61/EC concerning integrated pollution
prevention and control and national regulations concerning phosphates in industrial
wastewater have to be followed to minimise the risk of eutrophication due to phosphate
releases.
Aquatic
pelagic
compartment
Sediments
Soil and
groundwater
Atmospheric
compartment
The use of TKPP and products containing TKPP for the treatment of metals is not
considered to pose a risk to the atmospheric compartment.
Secondary
poisoning
Revision date: X
Version: XX
Page 44/97
SAFETY DATA SHEET
Date of issue: xxx
ES5: Leather and textiles manufacturing and treatment with
products containing TKPP
Leather and textiles manufacturing and treatment with products containing TKPP
Sector of use
(SU)
Product
category (PC)
Process
category
(PROC)
Article
category (AC)
Environmental
release
category
(ERC)
SU 5: Manufacture of textiles, leather, fur
PC 23: Leather tanning, dye, finishing and impregnation and care products
PC 34: Textile dyes, finishing and impregnating products; including bleaches and other
processing aids
including weighing)
Not applicable
articles
ERC 11a: Wide dispersive indoor use of long-life articles and materials with low release
Duration of
exposure at
workplace:
assessment of exposure a frequency of once a day and an exposure duration of 8 hours
was considered. A single worker may be exposed on 220 days per year.
Frequency of
exposure at
workplace:
Annual
amount used
per site:
Physical state
Revision date: X
Solid / Liquid
Version: XX
Page 45/97
SAFETY DATA SHEET
Concentration
of substance
in mixture
Date of issue: xxx
No information about the concentration of the substance in solid products and dilute
solutions is available. In the first-tier assessment of exposure the concentration of TKPP in
the solid preparations will be set to 100% w/w. The concentration in the undiluted solution is
set to > 25 % w/w.
Not applicable.
Organisational
measures
Technical
measures
Respiratory
protection

 Local exhaust ventilation may be present.
 Workers wear appropriate personal protection equipment, such as gloves, working suits
and safety glasses, when handling the TKPP in solid form or as solutions.
exposure summary for details
Hand
protection
Eye protection
Skin and body
protection
Hygiene
measures
Organisational
measures
Abatement
measures
related with
wastewater
Revision date: X
Version: XX
Page 46/97
SAFETY DATA SHEET
Abatement
measures
waste air and
solid waste
Date of issue: xxx
Type of waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
Workers
(inhalation)
ECETOC TRA (2010).
The use of TKPP in manufacturing and treatment of leather and textiles will not notably
contribute to the oral intake of phosphates.
comparable, it may be prudent to assess both the DNEL and the industrial against the same
values both for consistency and for worker safety.
national limits.
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
Various industrial activities associated with manufacturing and treatment of leather and
textiles may result in inhalation exposure of workers to TKPP. The risk characterisation
ratios for these activities are given in the table below. Workers handling concentrated TKPP
solutions or pure, solid substances are obliged to wear chemical resistant safety goggles.
The use of appropriate gloves and working suits is recommended. It is concluded that
conditions can be defined under which the potential health risks from the use of TKPP in
leather and textiles manufacture and treatment are adequately controlled.
General dust
exposure limit:
10 mg/m3
Exposure scenario: Risk characterisation for the industrial use of TKPP in leather and
textile manufacturing and treatment
Location: Indoors
Revision date: X
Airborne
Weight TKPP
fraction conc.
RCR
PRE (%)
(mg/m3) (DNEL)
Conclusion
Process
Category
LEV
Duration
(hours)
2
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
3
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
4
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Version: XX
RCR
(OEL)
Conclusion
Risk
controlled
Risk
controlled
Risk
controlled
Page 47/97
SAFETY DATA SHEET
Date of issue: xxx
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
No
>4
No
> 25
20.00
0.45372
Risk controlled
2
90%
>4
No
> 25
2.00
0.04537
Risk controlled
0.2
7
No
>4
75%
> 25
5.00
0.11343
Risk controlled
0.5
8b
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
9
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
10
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
13
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
19
No
>4
0.05
No
> 25
0.005
2
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
3
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
4
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
5
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
6
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
7
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
9
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
10
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
13
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
19
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
26
No
>4
1.50
RMMs required
No
100
0.0340
0.15
2
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
3
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
4
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
5
6
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
20.00
0.4537
Risk controlled
2
95%
>4
No
100
1.00
0.0227
Risk controlled
0.1
8b
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
9
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
10
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
13
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
19
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
26
No
>4
4.00
No
100
0.0907
Risk controlled
0.4
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
2
No
>4
0.1
Risk
controlled
7
Revision date: X
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
No
5
No
100
1.00
Version: XX
0.0227
Risk controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 48/97
SAFETY DATA SHEET
Date of issue: xxx
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
100.00
2.2686
RMMs required
10
95%
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
95%
>4
No
100
1.25
0.0284
Risk controlled
0.125
No
>4
No
100
20.00
0.4537
Risk controlled
2
90%
>4
No
100
2.00
0.0454
Risk controlled
0.2
No
>4
No
100
10.00
0.2269
Risk controlled
1
10
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
13
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
No
>4
No
100
10.00
0.2269
Risk controlled
1
75%
>4
No
100
2.50
0.0567
Risk controlled
0.25
3
4
5
6
7
8b
9
19
26
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Workers
(dermal)
Indirect
exposure via
the
environment
substance can be effectively removed from the wastewater. Thus, no assessment of indirect
exposure of humans via the environment is performed.
Consumer
exposure
No direct consumer exposure is anticipated with leather and textile manufacture and
treatment. It is concluded that the use of TKPP in leather and textile manufacture and
treatment is of no risk for the general public.
Environmental
release
deterioration.
Waste water
treatment
plants
Revision date: X
Version: XX
Page 49/97
SAFETY DATA SHEET
Date of issue: xxx
(WWTP)
pollution prevention and control and national regulations concerning phosphates in industrial
wastewater have to be followed to minimise the risk of eutrophication due to phosphate
releases.
Aquatic
pelagic
compartment
Sediments
Soil and
groundwater
Atmospheric
compartment
The use of TKPP and products containing TKPP for the manufacture and treatment of
leather and textiles is not considered to pose a risk to the atmospheric compartment.
Secondary
poisoning
Revision date: X
Version: XX
Page 50/97
SAFETY DATA SHEET
Date of issue: xxx
ES6: Use of TKPP and products containing TKPP for water and
wastewater treatment
Use of TKPP and products containing TKPP for water and wastewater treatment
Sector of use
(SU)
Product
category (PC)
Process
category
(PROC)
Article
category (AC)
Environmental
release
category
(ERC)
SU 22: Professional uses.
SU 23: Electricity, steam, gas water supply and sewage treatment
PC 16: Heat transfer fluids
PC 37: Water treatment chemicals
PROC 8a: Transfer of chemicals from/to vessels/ large containers at non dedicated facilities
including weighing)
PROC 11: Non-industrial spraying
pelletisation
PROC 22: Potentially closed processing operations with minerals/metals at elevated
temperature. Industrial setting.
Not applicable
ERC 3: Formulation in materialsERC 4: Industrial use of processing aids in processes and
products, not becoming part of articles
ERC 7: Industrial use of substances in closed systems
ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: wide dispersive outdoor use of substances in closed systems
ERC 11a: Wide dispersive indoor use of long-life articles and materials with low release
Revision date: X
Version: XX
Page 51/97
SAFETY DATA SHEET
Duration of
exposure at
workplace:
Frequency of
exposure at
workplace:
Annual
amount used
per site:
Date of issue: xxx
The conditions of exposure can be characterised on the basis of an AISE exposure
scenario developed for the treatment of drinking water (AISE 2009a). Accordingly, the
transfer of concentrated solutions occurs once a day for 10 minutes and treatment in the
closed process occurs once a day for 8 hours.
Physical state
Solid / Liquid
Concentration
of substance
in mixture
No information about the concentration of the substance in solid form or in dilute solutions is
available. In the first-tier assessment of exposure the concentration of TKPP in solids will be
set to 100% w/w and the concentration in the working solution to > 25% w/w, respectively.
Not applicable.
Organisational
measures
Technical
measures
Respiratory
protection

 Local exhaust ventilation may be present.
 Workers wear appropriate personal protection equipment, such as gloves, working suits
(efficiency of at least 90%, please see below for specific requirements). If outdoors PRE
may be required.
Hand
protection
Eye protection
Skin and body
Revision date: X
Version: XX
Page 52/97
SAFETY DATA SHEET
Date of issue: xxx
protection
Hygiene
measures
Organisational
measures
Abatement
measures
related with
wastewater
Abatement
measures
waste air and
solid waste
Type of waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
Workers
(inhalation)
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
10 mg/m3
Revision date: X
ECETOC TRA (2010).
The substance should be used in the drinking water treatment in such a way that the final
concentration of phosphate in drinking should not exceed the maximum admissible
concentration of 5 mg/L given in the Council Directive 80/778/EEC relating to the quality of
water intended for human consumption.
national limits.
INDUSTRIAL USERS:
Various industrial activities associated with the treatment of industrial waters and
wastewater may result in inhalation exposure of workers to TKPP. The risk characterisation
Version: XX
Page 53/97
SAFETY DATA SHEET
Date of issue: xxx
conditions can be defined under which the potential health risks from the use of TKPP in
treatment of industrial waters and wastewater are adequately controlled.
Table 1.
Exposure scenario: Risk characterisation for the industrial use of TKPP in water treatment
Location: Indoors (In) / Outdoors (Out)
Conclusion
RCR
(OEL)
Conclusion
RCR
(DNEL)
Airborne
TKPP conc.
(mg/m3)
Weight
fraction (%)
PRE
Duration
(hours)
LEV
Location
Process
Category
In
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
Out*
30%
>4
No
> 25
0.0007
0.00002
Risk controlled
0.00007
In
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
Out*
30%
>4
No
> 25
0.0007
0.00002
Risk controlled
0.00007
In
No
>4
No
> 25
20.00
0.45372
Risk controlled
2
In
90%
>4
No
> 25
2.00
0.04537
Risk controlled
0.2
In
No
>4
75%
> 25
5.00
0.11343
Risk controlled
0.5
Out*
30%
>4
No
> 25
14.00
0.31760
Risk controlled
1.4
Out*
30%
>4
75%
> 25
3.50
0.07940
Risk controlled
0.35
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Out*
30%
>4
No
> 25 0.035
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
2
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
6
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
1
2
7
8b
9
14
19
1
7
Revision date: X
Version: XX
0.0035
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 54/97
SAFETY DATA SHEET
8b
9
14
19
22a
pt<mp Low
Fugacity
22b
pt ≈ mp
- Med
Fugacity
22c
pt > mp
- High
Fugacity
26
Date of issue: xxx
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
1.50
0.0340
Risk controlled
0.15
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Out*
30%
>4
No
100
1.05
0.0238
Risk controlled
0.105
Risk
controlled
1
2
6
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
95%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
7
8b
9
14
Revision date: X
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 55/97
SAFETY DATA SHEET
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
19
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
22a
pt<mp Low
Fugacity
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
22b
pt ≈ mp
- Med
Fugacity
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
4.00
0.0907
Risk controlled
0.4
Out*
No
>4
No
100
2.80
0.0635
Risk controlled
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
In
No
>4
No
100
100.00
2.2686
RMMs required
10
In
95%
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
70.00
1.5880
RMMs required
7
Out
30%
>4
90%
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
95%
>4
No
100
1.25
0.0284
Risk controlled
0.125
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
90%
>4
No
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
4 to 8
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
4 to 8
No
100
2.50
0.0567
Risk controlled
0.25
22c
pt ≈ mp
– High
Fugacity
26
1
2
6
7
8b
9
14
19
Revision date: X
Date of issue: xxx
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
0.28
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Page 56/97
SAFETY DATA SHEET
22a
pt<mp Low
Fugacity
22b
pt ≈ mp
- Med
Fugacity
22c
pt > mp
- High
Fugacity
26
Date of issue: xxx
Out
30%
>4
No
100
17.5
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
75%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out*
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
* Outdoor exposure of industrial workers assumed to be reduced by 30% to give
consistency with ECETOC calculations for solids
PROFESSIONAL USERS:
Various professional activities associated with the treatment of industrial waters and
wastewater may result in inhalation exposure of workers to TKPP. The risk characterisation
conditions can be defined under which the potential health risks from the use of TKPP in the
professional treatment of industrial waters and wastewater are adequately controlled.
Table 2.
Exposure scenario: Risk characterisation for the professional use of TKPP in water
treatment
Weight
fraction (%)
Airborne
TKPP conc.
(mg/m3)
RCR
(DNEL)
Conclusion
RCR
(OEL)
No
> 25
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
> 25
0.071
0.0016
Risk controlled
0.0071
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
8b
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
9
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Version: XX
Conclusion
PRE
Revision date: X
Duration
(hours)
>4
8a
LEV
No
5
Location
Process
Category
In
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 57/97
SAFETY DATA SHEET
11
19
5
8a
8b
9
11
19
5
8a
8b
9
11
Revision date: X
Date of issue: xxx
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
20.00
0.4537
Risk controlled
2
In
80%
>4
No
> 25
4.00
0.0907
Risk controlled
0.4
Out
30%
>4
No
> 25
14.25
0.3233
Risk controlled
1.425
Out
30%
>4
75%
> 25
3.56
0.0808
Risk controlled
0.356
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25 0.05
0.005
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Version: XX
0.035
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Page 58/97
SAFETY DATA SHEET
19
5
8a
8b
9
10
11
Revision date: X
Date of issue: xxx
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
>4
No
100
2.00
0.0454
Risk controlled
0.2
In
No
>4
90%
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
200.00
4.5372
RMMs required
20
In
80%
>4
No
100
40.00
0.9074
Risk controlled
4
In
80%
0.25 to 1
No
100
8.00
0.1815
Risk controlled
0.8
In
No
>4
90%
100
20.00
0.4537
Risk controlled
2
Version: XX
0.35
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
RMMs
required
Page 59/97
SAFETY DATA SHEET
19
Date of issue: xxx
In
No
0.25 to 1
90%
100
4.00
0.0907
Risk controlled
0.4
In
80%
>4
90%
100
4.00
0.0907
Risk controlled
0.4
Out
30%
>4
No
100
140.00
3.1760
RMMs required
14
Out
30%
>4
95%
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
3.00
0.0681
Risk controlled
0.3
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Workers
(dermal)
Indirect
exposure via
the
environment
Consumer
exposure
No direct consumer exposure is anticipated with the use of TKPP in water and wastewater
treatment. The substance should be used in the drinking water treatment in such a way that
the final concentration of phosphate in drinking should not exceed the maximum admissible
concentration of 5 mg/L given in the Council Directive 80/778/EEC relating to the quality of
water intended for human consumption. It is concluded that the use of TKPP in water and
wastewater treatment is of no risk for the general public.
Environmental
release
deterioration.
Waste water
treatment
plants
(WWTP)
phosphate releases.
Aquatic
pelagic
compartment
Sediments
Soil and
Revision date: X
Version: XX
Page 60/97
SAFETY DATA SHEET
Date of issue: xxx
groundwater
Atmospheric
compartment
The use of TKPP in wastewater treatment is not considered to pose a risk to the
atmospheric compartment.
Secondary
poisoning
ES7: Industrial and professional use of washing and cleaning
Industrial and professional use of washing and cleaning products containing TKPP
Sector of use
(SU)
Product
category (PC)
Process
category
(PROC)
Article
category (AC)
Environmental
release
category
(ERC)
Revision date: X
SU 0: Other: industrial washing and cleaning applications
SU 5: Manufacture of textiles, leather, fur
SU 20: Health services
SU 22: Professional uses
PC 3: Air care products
PC 8: Biocidal products
PC 31: Polishes and wax blends
PC 35: Washing and cleaning products
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure
arises
PROC 5: Mixing or blending in batch processes (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to
vessels/large containers at non-dedicated facilities
PROC 9: Transfer of substance or preparation into small containers (dedicated filling
line, including weighing)
PROC 12: Use of blow agents for foam production
Not applicable
ERC 4: Industrial use of processing aids in processes and products, not becoming part
of articles
ERC 6a: Industrial use resulting in manufacture of another substance (use of
intermediates)
Version: XX
Page 61/97
SAFETY DATA SHEET
Date of issue: xxx
Duration of
exposure at
workplace:
Frequency of
exposure at
workplace:
Annual amount
used per site:
The industrial and professional use of cleaners is characterised on the basis of an AISE
exposure scenario developed in the context of REACH (AISE 2009a) for the use of such
products. Accordingly, the transfer of undiluted cleaners may occur once a day for 10
minutes and the industrial or professional use of diluted solutions may occur once a day
for 8 hours. A single worker may be exposed on 220 days per year.
Physical state
Solid / Liquid
Concentration
of substance in
mixture
No information about the concentration of the substance in cleaners or in dilute solutions
is available. In the first-tier assessment of exposure the concentration of TKPP solid
cleaning products was > 10% w/w and the concentration in the liquid products and
working solutions was set to > 25% as a worst-case.
Not applicable.
Organisational
measures
instructions (provide training if necessary). PPE are required when breaching the
system or handling the pure substance and concentrated solutions.
Technical
measures






Respiratory
protection
Revision date: X
Transport over pipes, technical barrel filling/emptying of barrel with automatic
systems (suction pumps etc.) (Good practice)
Use of pliers, grip arms with long handles with manual use “to avoid direct contact
and exposure by splashes (no working over one’s head)” (Good practice)
Local exhaust ventilation may be present.
Workers wear appropriate personal protection equipment, such as gloves, working
suits and safety glasses, when handling the TKPP in solid form or as solutions.
Breathing masks are used during manual high-pressure spraying of solutions onto
surfaces. Professional users may wear gloves and safety glasses during transfer of
cleaning products and cleaning activities.
(efficiency of at least 90%, please see below for specific requirements). If outdoors
PRE may be required.
It is assumed that professional locations may not have sufficient local exhaust
ventilation, therefore , If local exhaust ventilation is not available then it will be
necessary to use personal respiratory protection that is compliant with EN141 or EN
405 and has a sufficient efficiency (see table below for assumed APF and/or efficiency
Version: XX
Page 62/97
SAFETY DATA SHEET
Date of issue: xxx
values).
Hand protection
Material: Material of gloves: Butyl rubber, BR. Fluorocarbon rubber (Viton). Nitrile
rubber, NBR. Natural rubber, NR. Chloroprene rubber, CR. Neoprene gloves.
Eye protection
Skin and body
protection
Hygiene
measures
Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at end
of work. Keep work clothes separate.
Organisational
measures
Emissions to the environment must meet the requirements of Council Directive
96/61/EC and National Regulations concerning phosphate in industrial wastewater.
Abatement
measures
related with
wastewater
phosphates into the wastewater will occur. In addition, phosphate can be precipitated
from the wastewater by addition of metal ions.
Abatement
measures waste
air and solid
waste
reduced by the use of cyclones, gas scrubbers or bag filters. Solid and liquid waste has
to be incinerated or appropriately disposed of as chemical waste.
Type of waste
Disposal
technique
The release of phosphates to wastewater is highly regulated. The residue of the
containers or the used container itself should be disposed in accordance with local
requirements. See Section 13 of the SDS for more information.
Not determined.
Fraction
released to
environment
during waste
treatment
Characterisation)
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
ECETOC TRA (2010).
MEASE(EBRC, Eurometaux, 2010): Used to assess exposure to inorganic solutions
and handling of solid inorganics (PROC 26).
The use of TKPP in industrial and professional washing and cleaning will not notably
contribute to the oral intake of phosphates.
Workers
(inhalation)
substance in the countries in which the substance is manufactured and used.
Therefore, the exposure estimates will also be compared against a relevant general
dust limit for an inhalable fraction of 10 mg/m3 as described by the occupational
exposure limits detailed in the Technical Rules for Hazardous Materials – TRGS 900,
January 2006 (Germany).This applies to both industrial and professional use as
although the two settings are not directly comparable, it may be prudent to assess both
the DNEL and the industrial against the same values both for consistency and for
worker safety.
DNEL: Worker,
long-term,
systemic,
inhalation:
3
44.08 mg/m
Revision date: X
Version: XX
Page 63/97
SAFETY DATA SHEET
General dust
exposure limit:
10 mg/m3
Date of issue: xxx
A comparison of both the DNEL and a dust limit will ensure that downstream users
have enough information on the required RMMs to ensure safe use in line with regional
or national limits.
INDUSTRIAL USERS:
Various industrial activities associated with industrial cleaning and washing may result
in inhalation exposure of workers to TKPP. The risk characterisation ratios for these
activities are given in the table below. Workers handling concentrated TKPP solutions
or pure, solid substances are obliged to wear chemical resistant safety goggles. The
use of appropriate gloves and working suits is recommended. It is concluded that
conditions can be defined under which the potential health risks from the use of TKPP
in industrial cleaning and washing are adequately controlled.
Table 1.
Exposure scenario: Risk characterisation for the industrial use of TKPP in cleaning
applications
Conclusion
RCR
(OEL)
Conclusion
RCR
(DNEL)
Airborne
TKPP conc.
(mg/m3)
Weight
fraction (%)
PRE
Duration
(hours)
LEV
Location
Process
Category
In
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
Out*
30%
>4
No
> 25
0.0007
0.00002
Risk controlled
0.00007
In
No
>4
No
> 25
0.001
0.00002
Risk controlled
0.0001
Out*
30%
>4
No
> 25
0.0007
0.00002
Risk controlled
0.00007
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Out*
30%
>4
No
> 25
0.035
0.00079
Risk controlled
0.0035
In
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Out*
30%
>4
No
> 25
0.035
0.00079
Risk controlled
0.0035
In
No
>4
No
> 25
20.00
0.45372
Risk controlled
2
In
90%
>4
No
> 25
2.00
0.04537
Risk controlled
0.2
In
No
>4
75%
> 25
5.00
0.11343
Risk controlled
0.5
Out*
30%
>4
No
> 25
14.00
0.31760
Risk controlled
1.4
Out*
30%
>4
75%
> 25
3.50
0.07940
Risk controlled
0.35
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
8b
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
9
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
1
2
3
4
5
7
Revision date: X
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 64/97
SAFETY DATA SHEET
10
12
13
19
1
2
3
4
5
7
8b
9
10
13
19
Revision date: X
Date of issue: xxx
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Out*
30%
>4
No
> 25
0.00079
Risk controlled
0.0035
In
No
>4
No
> 25
0.035
<
0.001
<0.00002
Risk controlled
<0.0001
<0.00002
Risk controlled
<0.0001
Out*
30%
>4
No
> 25
<
0.001
In
No
>4
No
> 25
0.01
0.00023
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.00016
Risk controlled
0.0007
In
No
>4
No
> 25
0.05
0.00113
Risk controlled
0.005
Out*
30%
>4
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
Risk controlled
No
> 25 0.035
0.00079
0.035
Risk controlled
No
100
0.35
0.0079
Version: XX
0.0035
0.035
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 65/97
SAFETY DATA SHEET
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
95%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
In
No
>4
No
100
0.01
0.0002
Risk controlled
0.001
Out
30%
>4
No
100
0.007
0.0002
Risk controlled
0.0007
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
3
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
4
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
1
2
3
4
5
7
8b
9
10
13
19
1
2
Revision date: X
Date of issue: xxx
Risk controlled
No
100
3.50
0.0794
Version: XX
0.35
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Page 66/97
SAFETY DATA SHEET
5
7
8b
9
10
13
19
Date of issue: xxx
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
100.00
2.2686
In
95%
>4
No
100
5.00
0.1134
Out
30%
>4
No
100
70.00
1.5880
Out
30%
>4
90%
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
95%
>4
No
100
1.25
0.0284
Risk controlled
0.125
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
90%
>4
No
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
90%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
4 to 8
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
4 to 8
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.5
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
10
Risk controlled
0.5
7
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
PROFESSIONAL USERS:
Various professional activities associated with professional cleaning and washing may
result in inhalation exposure of workers to TKPP. The risk characterisation ratios for
these activities are given in the table below. Workers handling concentrated TKPP
solutions or pure, solid substances are obliged to wear chemical resistant safety
Revision date: X
Version: XX
Page 67/97
SAFETY DATA SHEET
Date of issue: xxx
goggles. The use of appropriate gloves and working suits is recommended. It is
concluded that conditions can be defined under which the potential health risks from
the use of TKPP in professional cleaning and washing are adequately controlled.
PROFESSIONAL USERS:
Table 2.
Exposure scenario: Risk characterisation for the professional use of TKPP in cleaning
applications
Conclusion
RCR
(OEL)
Conclusion
RCR
(DNEL)
Airborne
TKPP conc.
(mg/m3)
Weight
fraction (%)
PRE
Duration
(hours)
LEV
Location
Process
Category
In
No
>4
No
> 25
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
> 25
0.071
0.0016
Risk controlled
0.0071
In
No
>4
No
> 25
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
> 25
0.071
0.0016
Risk controlled
0.0071
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
20.00
0.4537
Risk controlled
2
In
Out
80%
30%
>4
>4
No
No
> 25
> 25
4.00
14.25
0.0907
0.3233
Risk controlled
Risk controlled
0.4
1.425
Out
30%
>4
75%
> 25
3.56
0.0808
Risk controlled
0.356
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25 0.05
0.005
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
4
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
5
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
4
5
8a
9
10
11
13
19
Revision date: X
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 68/97
SAFETY DATA SHEET
8a
9
10
11
13
19
26
4
5
8a
9
10
11
13
Revision date: X
Date of issue: xxx
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
4 to 8
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
4 to 8
No
100
2.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
In
30%
No
>4
>4
No
No
100
100
3.50
5.00
0.0794
Risk controlled
0.35
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
0.1134
0.0794
Risk controlled
Risk controlled
0.5
0.35
In
No
>4
No
100
5.00
Out
30%
>4
No
100
3.50
Version: XX
0.214
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
Page 69/97
SAFETY DATA SHEET
Date of issue: xxx
In
No
>4
No
100
5.00
Out
30%
>4
No
100
3.50
In
No
4 to 8
No
100
8.00
Out
30%
4 to 8
No
100
5.70
19
26
0.1134
Risk controlled
0.5
0.0794
Risk controlled
0.35
0.1815
Risk controlled
0.8
4
5
8a
9
10
11
Revision date: X
0.57
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
>4
No
100
2.00
0.0454
Risk controlled
0.2
In
No
>4
90%
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
200.00
4.5372
RMMs required
20
In
80%
>4
No
100
40.00
0.9074
Risk controlled
4
Version: XX
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Page 70/97
SAFETY DATA SHEET
13
19
26
Date of issue: xxx
In
80%
0.25 to 1
No
100
8.00
0.1815
Risk controlled
0.8
In
No
>4
90%
100
20.00
0.4537
Risk controlled
2
In
No
0.25 to 1
90%
100
4.00
0.0907
Risk controlled
0.4
In
80%
>4
90%
100
4.00
0.0907
Risk controlled
0.4
Out
30%
>4
No
100
140.00
3.1760
RMMs required
14
Out
30%
>4
95%
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
3.00
0.0681
Risk controlled
0.3
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
4 to 8
No
100
20.00
0.4537
Risk controlled
2
In
80%
4 to 8
No
100
4.00
0.0907
Risk controlled
0.4
In
No
4 to 8
75%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
4 to 8
No
100
14.25
0.3233
Risk controlled
1.425
Out
30%
4 to 8
75%
100
3.56
0.0808
Risk controlled
0.356
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Workers
(dermal)
Indirect
exposure via
the environment
Consumer
exposure
No direct consumer exposure is anticipated with the industrial and professional use of
washing and cleaning products. It is concluded that the use of TKPP in industrial and
professional use of washing and cleaning products is of no risk for the general public.
Environmental
release
phosphorus content in the water body which may cause eutrophication and water
quality deterioration.
Waste water
treatment plants
(WWTP)
reliably achieved by the available phosphorus removal techniques. Site-specific
conditions such as flow rate of the receiving surface water body and phosphorus
concentration in the receiving surface water body should be taken into account when
implementing an appropriate wastewater treatment. Council Directive 96/61/EC
Revision date: X
Version: XX
Page 71/97
SAFETY DATA SHEET
Date of issue: xxx
concerning integrated pollution prevention and control and national regulations
concerning phosphates in industrial wastewater have to be followed to minimise the risk
of eutrophication due to phosphate releases.
Aquatic pelagic
compartment
Sediments
Soil and
groundwater
No direct acute or long-term adverse effects on terrestrial organisms are anticipated
with orthophosphates in the environment.
Atmospheric
compartment
The use of TKPP in washing and cleaning products is not considered to pose a risk to
the atmospheric compartment.
Secondary
poisoning
ES8: Application in oil well and other drilling fluid applications,
liquefying and conditioning earths, mud, clays
Application in oil well and other drilling fluid applications, liquefying and conditioning earths, mud, clays
Sector of use
(SU)
SU 2a: Mining (without offshore industries)
SU 2b: Offshore industries
Product
category (PC)
PC 17: Hydraulic fluids
Process
category
(PROC)
including weighing)
PROC 18: Greasing at high energy conditions
Not applicable
Article
category (AC)
Environmental
release
category
(ERC)
articles
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Revision date: X
Version: XX
Page 72/97
SAFETY DATA SHEET
Date of issue: xxx
Duration of
exposure at
workplace:
Frequency of
exposure at
workplace:
Annual
amount used
per site:
Drilling may be operated on 365 days a year for 24 hours a day. A single worker may be
exposed on 220 days per year. No information about frequency and duration of the various
tasks is available. In the first-tier assessment of exposure a frequency of once a day and an
exposure duration of 8 hours was considered.
Physical state
Solid / Liquid
Concentration
of substance
in mixture
No information about the concentration of the substance in solid products and dilute
solutions is available. In the first-tier assessment of exposure the concentration of TKPP in
the solid preparations was 100% w/w and the concentration in the working solution was >
25%.
Not applicable.
Organisational
measures
Technical
measures
Respiratory
protection
Hand
protection
Eye protection
Skin and body
protection
Revision date: X



Personal respiratory equipment may be available.
Workers wear appropriate personal protection equipment, such as gloves, working suits
may be required.
Version: XX
Page 73/97
SAFETY DATA SHEET
Hygiene
measures
Date of issue: xxx
Organisational
measures
Abatement
measures
related with
wastewater
Phosphate can be precipitated from the wastewater by addition of metal ions.
Abatement
measures
waste air and
solid waste
Solid and liquid waste has to be incinerated or appropriately disposed of as chemical waste.
Type of waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
Workers
(inhalation)
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
10 mg/m3
ECETOC TRA (2010).
The activities associated with the drilling fluid applications will not result in oral exposure of
workers to TKPP.
national limits.
Various industrial activities associated with the drilling fluid applications may result in
inhalation exposure of workers to TKPP. The risk characterisation ratios for these activities
under which the potential health risks from the use of TKPP in drilling fluid applications are
adequately controlled.
Exposure scenario: Risk characterisation for the industrial use of TKPP in drilling
applications
Revision date: X
Version: XX
Page 74/97
SAFETY DATA SHEET
Date of issue: xxx
Conclusion
RCR
(OEL)
Conclusion
RCR
(DNEL)
Airborne
TKPP conc.
(mg/m3)
Weight
fraction (%)
PRE
Duration
(hours)
LEV
Location
Process
Category
3
4
5
8b
9
13
18
In
No
>4
No
> 25
0.01
0.01
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.007
Risk controlled
0.0007
In
No
>4
No
> 25
0.05
0.05
Risk controlled
0.005
Out*
30%
>4
No
> 25
0.035
0.035
Risk controlled
0.0035
In
No
>4
No
> 25
0.05
0.05
Risk controlled
0.005
Out*
30%
>4
No
> 25
0.035
0.035
Risk controlled
0.0035
In
No
>4
No
> 25
0.01
0.01
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.007
Risk controlled
0.0007
In
No
>4
No
> 25
0.01
0.01
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.007
Risk controlled
0.0007
In
No
>4
No
> 25
0.01
0.01
Risk controlled
0.001
Out*
30%
>4
No
> 25
0.007
0.007
Risk controlled
0.0007
In
No
>4
No
> 25
0.10
0.10
Risk controlled
0.01
Out*
30%
>4
No
> 25
0.07
0.07
Risk controlled
0.007
In
No
>4
No
> 25
0.05
0.05
Risk controlled
0.005
0.035
Risk controlled
0.0035
19
Out*
30% > 4 No
> 25 0.035
3
4
5
8b
9
Revision date: X
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
Version: XX
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 75/97
SAFETY DATA SHEET
13
18
19
26
3
4
5
8b
Date of issue: xxx
In
No
>4
No
100
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
100
0.07
0.0016
Risk controlled
0.007
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.50
0.0340
Risk controlled
0.15
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Out*
30% > 4 No
100
1.05
0.105
Risk
controlled
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
95%
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.5
0.0794
Risk controlled
0.35
In
No
>4
No
100
4.00
0.0907
Risk controlled
0.4
Out*
No
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
9
13
18
19
26
3
Revision date: X
> 4 No
100
2.80
Version: XX
0.28
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 76/97
SAFETY DATA SHEET
4-
5
8b
9
13
18
19
26
Date of issue: xxx
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
95%
>4
No
100
1.25
0.0284
Risk controlled
0.125
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
90%
>4
No
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
RMMs required
0.35
In
No
>4
No
100
50.00
1.1343
In
95%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
25.00
0.5672
Risk controlled
2.5
In
90%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out
30%
>4
No
100
17.50
0.3970
Risk controlled
1.75
Out
30%
>4
90%
100
1.75
0.0397
Risk controlled
0.175
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
75%
>4
No
100
2.50
0.0567
Risk controlled
0.25
Out*
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
5
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
*Outdoor exposure of industrial workers assumed to be reduced by 30% to give consistency
with ECETOC calculations for solids.
Workers
Revision date: X
Version: XX
Page 77/97
SAFETY DATA SHEET
Date of issue: xxx
(dermal)
Indirect
exposure via
the
environment
Consumer
exposure
No direct consumer exposure is anticipated with the use of TKPP in drilling fluid
applications. It is concluded that the use of TKPP in drilling fluid applications is of no risk for
the general public.
Environmental
release
TKPP is listed in the OSPAR list of substances/preparations used and discharged offshore
which are considered to pose little or no risk to the environment (PLONOR). Further,
national regulations are available to regulate the waste management from offshore and
mining industry.
deterioration.
Waste water
treatment
plants
(WWTP)
phosphate releases.
Aquatic
pelagic
compartment
Sediments
Soil and
groundwater
Atmospheric
compartment
The use of TKPP in drilling applications is not considered to pose a risk to the atmospheric
compartment.
Secondary
poisoning
ES9: Professional and consumer use of TKPP and products and
materials containing TKPP in ceramic manufacture and
construction and building work
Use of TKPP and products and materials containing TKPP in ceramic manufacture and construction and
building work
Revision date: X
Version: XX
Page 78/97
SAFETY DATA SHEET
Date of issue: xxx
Sector of use
(SU)
SU 19: Building and construction work
SU 21: Consumer uses: private households
SU 22:Professional uses
Product
PC 0: Other: construction materials
category (PC) PC 1: Adhesives, sealants
PC 9a: Coatings and paints, thinners, paint removers
PC 9b: Fillers, putties, plasters, modelling clay
PC 18: Ink and toners
PC 30: Photo-chemicals
PC 31: Polishes and wax blends
Process
category
PROC 5: Mixing or blending in batch processes (multistage and/or significant contact)
(PROC)
PROC 8a: Transfer of chemicals from/to vessels/ large containers at non dedicated
facilities
including weighing)
PROC 23: Open processing and transfer of minerals at elevated temperature
articles
Article
AC 0: Other: Constructional articles and building material for indoor use: wall construction
category (AC) material ceramic, metal, plastic and wood construction material, insulating material
Environmental ERC 8a: Wide dispersive indoor use of processing aids in open systems
release
category
ERC 8c: Wide dispersive indoor use of resulting in inclusion into or onto a matrix
(ERC)
ERC 10a: Wide dispersive outdoor use of long-life articles and materials with low release
Duration of
exposure at
workplace:
Frequency of
exposure at
workplace:
Revision date: X
No information about frequency and duration of the various tasks is available. In the firsttier assessment of exposure a frequency of once a day and an exposure duration of 8
hours was considered. A single worker may be exposed on 220 days per year. No
information about the concentration of the substance in dilute and concentrated solutions or
in solids is available.
The CEPE has developed exposure scenarios for consumer use of coatings in the context
of the REACH regulation (CEPE 2009). These scenarios indicate a maximum duration of
use ranging from 4 to 8 hours. No use frequency is given in the CEPE scenarios. The
frequency of paint use by consumers is between 1 to 3 times a year depending on the type
of paint used; the amount of paint used per application ranges from approximately 1 to 1.3
kg (RIVM 2007b). No information about the concentration of TKPP in paints for consumer
use is given. In the first-tier assessment of exposure the concentration of the substance in
paints is set to 10 %. Paints containing TKPP are used by consumers in various ways. The
ready-to-use preparations can be purchased in retail shops. Hand mixing of other
components into the paint before use may occur. The paint mixture has to be transferred
from the transport, storage or mixing vessels to smaller containers or the spray systems.
Paints are brushed onto surfaces or sprayed using medium to high pressure systems in
private indoor or outdoor settings. Spray painting is performed manually in open processes.
Painted surfaces are air-dried. Extensive manual cleaning of the equipment after use may
be necessary.
Version: XX
Page 79/97
SAFETY DATA SHEET
Annual
amount used
per site:
Date of issue: xxx
Physical state
Solid / Liquid
Concentration
of substance
in mixture
In the first-tier assessment of exposure worst-case assumptrion were made with regards to
the composition of materials containing TKPP. The concentration of TKPP in undiluted
liquid mixtures was > 25 % w/w. The concentration of solid TKPP delivered to professional
and private users was 100% w/w and the concentration in cements, plasters and other solid
products for consumer use was 10% w/w. The amounts of products and materials used per
event may vary considerably ranging from a few grams to several hundred kilograms of
material per event.
The CEPE has developed exposure scenarios for consumer use of coatings in the context
of the REACH regulation (CEPE 2009). These scenarios indicate a maximum duration of
use ranging from 4 to 8 hours. No use frequency is given in the CEPE scenarios. The
frequency of paint use by consumers is between 1 to 3 times a year depending on the type
of paint used; the amount of paint used per application ranges from approximately 1 to 1.3
kg (RIVM 2007b). No information about the concentration of TKPP in paints for consumer
use is given. In the first-tier assessment of exposure the concentration of the substance in
paints is set to 10 %. Paints containing TKPP are used by consumers in various ways. The
ready-to-use preparations can be purchased in retail shops. Hand mixing of other
components into the paint before use may occur. The paint mixture has to be transferred
from the transport, storage or mixing vessels to smaller containers or the spray systems.
Paints are brushed onto surfaces or sprayed using medium to high pressure systems in
private indoor or outdoor settings. Spray painting is performed manually in open processes.
Painted surfaces are air-dried. Extensive manual cleaning of the equipment after use may
be necessary.
Not applicable.
Organisational
measures
Technical
measures



Respiratory
protection
Revision date: X
Professionals wear appropriate personal protection equipment, such as goggles,
gloves and working suits, when handling solutions or materials, cements and plasters
containing TKPP
Breathing masks may be used during transfer and mixing of solid preparations to
reduce the inhalation of dusts.
may be required.
Version: XX
Page 80/97
SAFETY DATA SHEET
Hand
protection
Eye protection
Date of issue: xxx
Skin and body
protection
Hygiene
measures
4.2 RMMs related to consumers
It is assumed that consumers will not wear PPE. However, eye protection and hand protection is
recommended.
Organisational
measures
Abatement
measures
related with
wastewater
Phosphate can be precipitated from the wastewater by addition of metal ions.
Abatement
measures
waste air and
solid waste
Solid and liquid waste has to be incinerated or appropriately disposed of as chemical
waste.
Type of waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
tool(s)
Workers (oral)
Workers: ECETOC TRA (2010). MEASE(EBRC, Eurometaux, 2010): Used to assess
exposure to inorganic solutions and handling of solid inorganics (PROC 26).
Consumers: ConsExpo (RIVM 2006)
The use of TKPP in products and materials in construction and building work will not
notably contribute to the oral intake of phosphates.
Workers
Revision date: X
Version: XX
Page 81/97
SAFETY DATA SHEET
(inhalation)
DNEL:
Worker, longterm,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure limit:
10 mg/m3
Date of issue: xxx
national limits.
Various professional activities associated with the use of products and materials containing
TKPP in construction and building work may result in inhalation exposure of workers to
TKPP. The risk characterisation ratios for these activities are given in the table below.
wear chemical resistant safety goggles. The use of appropriate gloves and working suits is
recommended. It is concluded that conditions can be defined under which the potential
health risks from the use of products and materials containing TKPP in construction and
building work are adequately controlled.
Exposure scenario: Risk characterisation for the professional use of TKPP in products
and materials in the construction and building industries.
Conclusion
RCR
(OEL)
Conclusion
RCR
(DNEL)
Airborne
TKPP conc.
(mg/m3)
Weight
fraction (%)
PRE
Duration
(hours)
LEV
Location
Process
Category
In
No
>4
No
> 25
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
> 25
0.071
0.0016
Risk controlled
0.0071
In
No
>4
No
> 25
0.10
0.0023
Risk controlled
0.01
Out
30%
>4
No
> 25
0.071
0.0016
Risk controlled
0.0071
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
0.05
0.0011
Risk controlled
0.005
Out
30%
>4
No
> 25
0.036
0.0008
Risk controlled
0.0036
In
No
>4
No
> 25
20.00
0.4537
Risk controlled
2
In
80%
>4
No
> 25
4.00
0.0907
Risk controlled
0.4
Out
30%
>4
No
> 25
14.25
0.3233
Risk controlled
1.425
11
Ou
30%
>4
75%
> 25
3.56
0.0808
Risk controlled
0.356
In
Out
No
30%
>4
>4
No
No
> 25
> 25
0.05
13
0.0011
0.0008
Risk controlled
Risk controlled
0.005
0.0036
4
5
8a
9
10
Revision date: X
Version: XX
0.036
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
Page 82/97
SAFETY DATA SHEET
Risk controlled
0.005
No
> 25 0.05
0.005
No
>4
Out
30%
>4
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
0.70
0.0159
Risk controlled
0.07
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
0.50
0.0113
Risk controlled
0.05
Out
30%
>4
No
100
0.35
0.0079
Risk controlled
0.035
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
24a
Low
Fugacity
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
24b
Med
Fugacity
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
4
5
8a
9
10
11
13
19
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
No
> 25
0.05
In
19
Revision date: X
Date of issue: xxx
Version: XX
0.0011
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Page 83/97
SAFETY DATA SHEET
24c
High
Fugacity
26
4
5
8a
9
10
11
13
19
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
Revision date: X
Date of issue: xxx
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
75%
>4
No
100
5.00
0.1134
Risk controlled
0.5
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Ou
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
Version: XX
0.214
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Page 84/97
SAFETY DATA SHEET
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
24a
Low
Fugacity
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
24b
Med
Fugacity
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
75%
>4
No
100
5.00
0.1134
Risk controlled
0.5
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
8.00
0.1815
Risk controlled
0.8
Out
30%
>4
No
100
5.70
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
RMMs required
5
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
6.00
0.1361
Risk controlled
0.6
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
8a
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
9
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
24c
High
Fugacity
26
4
5
Revision date: X
Date of issue: xxx
Version: XX
0.57
5
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Page 85/97
SAFETY DATA SHEET
10
11
13
19
23a
pt<mp Low
Fugacity
23b
pt ≈ mp
- Med
Fugacity
23c
pt > mp
- High
Fugacity
24a
Revision date: X
Date of issue: xxx
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
>4
No
100
2.00
0.0454
Risk controlled
0.2
In
No
>4
90%
100
1.00
0.0227
Risk controlled
0.1
Out
30%
>4
No
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
200.00
4.5372
In
80%
>4
No
100
40.00
0.9074
Risk controlled
4
In
80%
0.25 to 1
No
100
8.00
0.1815
Risk controlled
0.8
In
No
>4
90%
100
20.00
0.4537
Risk controlled
2
In
No
0.25 to 1
90%
100
4.00
0.0907
Risk controlled
0.4
In
80%
>4
90%
100
4.00
0.0907
Risk controlled
0.4
Out
30%
>4
No
100
140.00
3.1760
Out
30%
>4
95%
100
7.00
0.1588
Risk controlled
0.7
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
50.00
1.1343
In
80%
>4
No
100
10.00
0.2269
Risk controlled
1
In
80%
1 to 4
No
100
3.00
0.0681
Risk controlled
0.3
In
No
>4
90%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
35.00
0.7940
Risk controlled
3.5
Out
30%
>4
90%
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
3.00
0.0681
Risk controlled
0.3
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
In
30%
No
>4
>4
90%
No
100
100
1.40
3.00
0.0318
0.0681
Risk controlled
Risk controlled
0.14
0.3
Version: XX
20
14
5
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
Page 86/97
SAFETY DATA SHEET
Date of issue: xxx
Low
Fugacity
24b
Med
Fugacity
24c
High
Fugacity
26
Out
30%
>4
No
100
2.10
0.0476
Risk controlled
0.21
In
No
>4
No
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
3.50
0.0794
Risk controlled
0.35
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
75%
>4
No
100
5.00
0.1134
Risk controlled
0.5
In
No
>4
90%
100
2.00
0.0454
Risk controlled
0.2
Out
30%
>4
No
100
14.00
0.3176
Risk controlled
1.4
Out
30%
>4
90%
100
1.40
0.0318
Risk controlled
0.14
In
No
>4
No
100
20.00
0.4537
Risk controlled
2
In
80%
>4
No
100
4.00
0.0907
Risk controlled
0.4
In
No
>4
75%
100
5.00
0.1134
Risk controlled
0.5
Out
30%
>4
No
100
14.25
0.3233
Risk controlled
1.425
Out
30%
>4
75%
100
3.56
0.0808
Risk controlled
0.356
controlled
Risk
controlled
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
RMMs
required
Risk
controlled
Risk
controlled
RMMs
required
Risk
controlled
* Outdoor exposure of industrial workers assumed to be reduced by 30% to give
consistency with ECETOC calculations for solids
Workers
(dermal)
Indirect
exposure via
the
environment
Consumer
exposure
Private users of products and materials used for construction and building work and
containing TKPP and users of paints containing TKPP may be exposed to the substance
by inhalation. The risk characterisation ratios obtained for different types of paints applied
by rolling, brushing or spraying are given in the tables below. It is concluded that the
conditions of consumer use of products and materials containing TKPP for private
construction and building work are such that the potential human health risks are
DNEL:
General
Population,
long-term,
systemic,
inhalation:
10.87 mg/m3
Revision date: X
Risk characterisation for consumer use of powdery building materials and paints
Parameter
High-solid
WaterSolventWall
Spray paint
(unit)
based
based
0.00019
1.82E-05
0.000112
4.73E-05
0.521
Mean
concentration
of a day of
exposure
(mg/m3)
1.75E-05
1.67E-06
1.03E-05
4.35E-06
0.048
RCR inhalation
Risk
Risk
Risk
Risk
Risk
adequately
adequately
adequately
adequately
adequately
Conclusion
controlled
controlled
controlled
controlled
controlled
Version: XX
Pneumatic
spraying
0.0117
1.08E-03
Risk
adequately
controlled
Page 87/97
SAFETY DATA SHEET
Date of issue: xxx
Environmental
release
deterioration.
Waste water
treatment
plants
(WWTP)
phosphate releases.
Aquatic
pelagic
compartment
Sediments
Soil and
groundwater
Atmospheric
compartment
The use of TKPP and products and materials containing TKPP is not considered to pose a
risk to the atmospheric compartment.
Secondary
poisoning
ES10: Professional and consumer use of TKPP and products
containing TKPP in fertiliser products
Professional and consumer use of TKPP and products containing TKPP in fertiliser products
Sector of
use (SU)
Product
category
(PC)
Process
category
(PROC)
SU 1: Agriculture, forestry, fishery
SU 22: Professional Uses
PC 12: Fertilizers
PROC 8a: Transfer of chemicals from/to vessels/ large containers at non dedicated facilities
including weighing)
Revision date: X
Version: XX
Page 88/97
SAFETY DATA SHEET
Article
category
(AC)
Environment
al release
category
(ERC)
Date of issue: xxx
Not applicable
ERC 8c: Wide dispersive indoor use of resulting in inclusion into or onto a matrix
ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix
Duration of
exposure at
workplace:
assessment of exposure a frequency of once a day and an exposure duration of 8 hours was
considered. A single worker may be exposed on 220 days per year.
Frequency of
exposure at
workplace:
Annual
amount used
per site:
Physical
state
Solid / Liquid
Concentratio
n of
substance in
mixture
No information about the concentration of TKPP in liquid or solid fertilisers is available and a
concentration of 100% w/w for the undiluted product and > 25% w/w for the diluted product
was considered in the first-tier exposure assessment and worst-case.
Not applicable.
Organisation
al measures
Technical
measures




Respiratory
protection
Local exhaust ventilation may be present.
Professionals wear appropriate personal protection equipment, such as goggles, gloves
and working suits, when handling solutions or materials, cements and plasters
containing TKPP
Breathing masks may be used during transfer and mixing of solid preparations to reduce
the inhalation of dusts.
dusts, if LEV with an efficiency of ≥90% is not available. Exposure to dusts from the handling
of solid materials should be reduced by the use of local exhaust ventilation (efficiency of at
least 90%, please see below for specific requirements). If outdoors PRE may be required.
NOTE. For certain processes an efficiency of ≥95% is assumed. Please see below exposure
summary for details
Revision date: X
Version: XX
Page 89/97
SAFETY DATA SHEET
Hand
protection
Eye
protection
Date of issue: xxx
Skin and
body
protection
Hygiene
measures
It is assumed that consumers will not wear PPE. However, eye protection and hand protection is
recommended.
Organisation
al measures
Not applicable
Abatement
measures
related with
wastewater
Phosphates are generally retained on soil particles and except in exceptional circumstances
will not leach through soils to ground or surface water as soluble ions. Loss to surface waters
is thus usually related to surface run-off or erosion of soil particles, which carry attached
phosphates. To avoid such effects, the following recommendations (Lory, 1999) should be
followed:






Abatement
measures
waste air and
solid waste
Apply phosphorus sources below the surface.
Surface-apply phosphorus sources during periods of the year when runoff is unlikely.
Surface-apply phosphorus sources only on fields with a low potential for runoff.
Do not surface-apply phosphorus sources to frozen or snow-covered soils.
Maintain buffer strips around water resources where no phosphorus is applied.
Add alum or similar treatment to manure to reduce the availability of phosphorus.
Solid and liquid waste has to be incinerated or appropriately disposed of as chemical waste.
Type of
waste
Disposal
technique
Not determined.
Fraction
released to
environment
during waste
treatment
5.1. Human exposure
Exposure
estimation
Workers, TIER 1: ECETOC TRA (2010), MEASE(EBRC, Eurometaux, 2010): Used to
assess exposure to inorganic solutions and handling of solid inorganics (PROC 26). [Results
Revision date: X
Version: XX
Page 90/97
SAFETY DATA SHEET
tool(s)
Workers
(oral)
Date of issue: xxx
not summarised].
Workers, TIER 2: UK POEM
Consumers: UK POEM and German model
No oral exposure to TKPP is anticipated with the use of TKPP in fertilisers.
estimates will also be compared against a relevant general dust limit for an inhalable fraction
of 10 mg/m3 as described by the occupational exposure limits detailed in the Technical
Rules for Hazardous Materials – TRGS 900, January 2006 (Germany).This applies to both
industrial and professional use as although the two settings are not directly comparable, it
may be prudent to assess both the DNEL and the industrial against the same values both for
consistency and for worker safety.
enough information on the required RMMs to ensure safe use in line with regional or national
limits.
Various professional activities associated with the use of fertilisers may result in inhalation
exposure of workers to TKPP. The risk characterisation ratios for these activities are given in
the table below. Workers handling concentrated TKPP solutions or pure, solid substances
are obliged to wear chemical resistant safety goggles. The use of appropriate gloves and
working suits is recommended. It is concluded that conditions can be defined under which
the potential health risks from the professional use of fertilisers containing TKPP are
Workers
(inhalation)
DNEL:
Worker,
long-term,
systemic,
inhalation:
3
44.08 mg/m
General dust
exposure
limit: 10
mg/m3
Hand-held
Tractorsprayer (15
TractorTractormounted/
L tank):
mounted/
mounted/
trailed
hydraulic
trailed boom trailed boom broadcast
nozzles.
sprayer:
sprayer:
air-assisted Outdoor,
hydraulic
rotary
sprayer: 500 low level
nozzles
atomisers
L/ha
target
Mixing and loading
Solid, granular fertiliser
Long-term
exposure
concentratio
n of a.s.
1.08
RCR
inhalation
0.108
Risk
Conclusion controlled
Long-term
exposure
concentratio
n of a.s.
6.3
RCR
inhalation
0.63
Risk
Long-term
exposure
concentratio
n of a.s.
with PRE,
90%
efficacy
0.63
RCR
inhalation
with PRE,
90%
efficacy
0.063
Risk
0.03
Hand-held
rotary
atomiser
equipment
(2.5 L tank).
Outdoor,
low level
target
Hand-held
rotary
atomiser
equipment
(2.5 L tank).
Outdoor,
high level
target
Unit
0.04
0.04
mg/m
3
1.08
0.32
0.108
Risk
controlled
0.032
0.003
Risk
Risk
controlled
controlled
Solid, powdery fertiliser
0.004
Risk
controlled
0.004
Risk
controlled
6.3
1.89
0.61
0.92
0.92
0.63
Risk
controlled
0.189
Risk
controlled
0.061
Risk
controlled
0.092
Risk
controlled
0.092
Risk
controlled
-
mg/m
3
-
0.63
0.063
Risk
controlled
Spray Application
Revision date: X
Version: XX
Page 91/97
SAFETY DATA SHEET
Long-term
exposure
concentratio
n of a.s.
0.06
inhalation
RCR
0.006
Risk
Date of issue: xxx
mg/m
3
0.03
0.3
0.12
0.06
0.06
0.003
Risk
controlled
0.03
Risk
controlled
0.012
Risk
controlled
0.006
Risk
controlled
0.006
Risk
controlled
-
Workers
(dermal)
however local effects may occur but these effects will not be dose-dependent but will depend
on the concentration of the substance present in the mixture/solution used in a specific
application.
Indirect
exposure via
the
environment
No indirect exposure of humans via the environment is expected for TKPP, as the substance
can be effectively removed from the wastewater. Thus, no assessment of indirect exposure
of humans via the environment is performed.
Consumer
exposure
Private users of fertilisers containing TKPP may be exposed to the substance by inhalation.
The risk characterisation ratios obtained for different types of fertiliser applied are given in
the table below. It is concluded that the conditions of consumer use of fertilisers containing
TKPP are such that the potential human health risks are adequately controlled.
DNEL:
General
Population,
long-term,
systemic,
inhalation:
10.87 mg/m3
Private spraying of liquid fertilisers with
home garden sprayer, 5 L-tank, low-level
target
Mixing and loading
Solid, granular fertiliser
0.00015
1.38E-05
Risk adequately controlled
Solid, powdery fertiliser
0.004
3.68E-04
Spray Application
0.004
3.68E-04
Long-term concentration of a.s.
RCR inhalation
Conclusion
RCR inhalation
Conclusion
RCR inhalation
Conclusion
Unit
mg/m3
-
mg/m3
-
mg/m3
-
Environment
al release
deterioration.
Waste water
treatment
plants
(WWTP)
aluminium or iron addition) or biological treatments. A high degree of removal can be reliably
achieved by the available phosphorus removal techniques. Site-specific conditions such as
flow rate of the receiving surface water body and phosphorus concentration in the receiving
surface water body should be taken into account when implementing an appropriate
wastewater treatment. Council Directive 96/61/EC concerning integrated pollution prevention
and control and national regulations concerning phosphates in industrial wastewater have to
be followed to minimise the risk of eutrophication due to phosphate releases.
Aquatic
pelagic
compartment
Revision date: X
Version: XX
Page 92/97
SAFETY DATA SHEET
Sediments
Date of issue: xxx
Soil and
groundwater
Atmospheric
compartment
The use of TKPP in fertilisers is not considered to pose a risk to the atmospheric
compartment.
Secondary
poisoning
ES11: Consumer use of detergents
Consumer use of detergents
Sector of use (SU)
Product category (PC)
PC 35: Washing and cleaning products (including solvent based products)
Process category
(PROC)
Article category (AC)
Not applicable
Not applicable
Environmental release
category (ERC)
Duration of exposure
at workplace:
Frequency of exposure
at workplace:
Annual amount used
per site:
Generic exposure scenarios for the consumer use of detergents were described
(AISE 2009b). The ConsExpo tool contains representative exposure scenarios
for a number of cleaning products (RIVM 2006).
Physical state
Solid / Liquid
Concentration of
substance in mixture
Generic exposure scenarios for the consumer use of detergents were described
(AISE 2009b). The ConsExpo tool contains representative exposure scenarios
for a number of cleaning products (RIVM 2006).
Not applicable.
Revision date: X
Version: XX
Page 93/97
SAFETY DATA SHEET
Date of issue: xxx
Organisational measures
Not applicable
Technical measures
Respiratory protection
Consumer products should be intrinsically safe. Risk management
measures relating to the use of TKPP in detergents should be conveyed
on the package and no further consideration is required for the purpose of
characterising the risk from this application.
Not applicable
Hand protection
Not applicable
Eye protection
Not applicable
Skin and body protection
Not applicable
Hygiene measures
Not applicable
Not applicable
Abatement measures related
with wastewater
Detergents and cleaning products containing TKPP will finally be released
to the sewage. Council directive 91/271/EEC concerning urban waste
water requires phosphate removal from sewage, wherever receiving
waters are potentially susceptible to eutrophication, in agglomerations
>10,000 person equivalents. This requirement is confirmed by the EU
Water Framework Directive 2000/60, which also further requires
phosphate removal in smaller agglomerations where this is necessary to
achieve water quality standards.
Abatement measures waste
air and solid waste
Not applicable.
Type of waste
Disposal technique
The release of phosphates to wastewater is highly regulated. The residue
of the containers or the used container itself should be disposed in
accordance with local requirements. See Section 13 of the SDS for more
information.
Not determined.
Fraction released to
environment during waste
treatment
Characterisation)
5.1. Human exposure
Exposure estimation tool(s)
ConsExpo (RIVM 2006)
Workers (all routes)
No worker exposure is anticipated with the consumer use of detergents.
Indirect exposure via the
environment
No indirect exposure of humans via the environment is expected for
TKPP, as the substance can be effectively removed from the wastewater.
Thus, no assessment of indirect exposure of humans via the environment
is performed.
Consumer exposure
Private users of detergents containing TKPP may be exposed to the
substance by inhalation. The risk characterisation ratios obtained for
different types of detergents and cleaners applied by rolling, brushing or
Revision date: X
Version: XX
Page 94/97
SAFETY DATA SHEET
DNEL: General Population,
long-term, systemic,
inhalation: 10.87 mg/m3
Date of issue: xxx
spraying are given in the table below. It is concluded that the conditions of
consumer use of detergents containing TKPP are such that the potential
human health risks are adequately controlled.
Detergent:
loading
Detergent:
use
Mean concentration
of a day of
exposure (mg/m3)
Inhalation RCR
4.67 x 10-9
Not
applicable
4.3E-10
Conclusion
Risk
adequately
controlled
Not
applicable
Risk
adequately
controlled
Liquid
cleaner:
mixing and
loading
3.04 x 10-9
Liquid
cleaner:
spraying
2.8E-10
1.06E-06
Risk
adequately
controlled
Risk
adequately
controlled
1.15 x 10-5
Environmental release
Waste water treatment plants
(WWTP)
The use of TKPP can potentially result in aquatic emissions and locally
3increase the phosphate (PO4 ) concentration. Phosphates reaching
surface water increase the phosphorus content in the water body which
may cause eutrophication and water quality deterioration.
Phosphorus should be removed from industrial wastewater before it is
released to the environment. This can be done by chemical treatment (by
precipitation with the help of aluminium or iron addition) or biological
treatments. A high degree of removal can be reliably achieved by the
available phosphorus removal techniques. Site-specific conditions such as
flow rate of the receiving surface water body and phosphorus
concentration in the receiving surface water body should be taken into
account when implementing an appropriate wastewater treatment. Council
Directive 96/61/EC concerning integrated pollution prevention and control
and national regulations concerning phosphates in industrial wastewater
have to be followed to minimise the risk of eutrophication due to
phosphate releases.
Aquatic pelagic compartment
No direct acute or long-term adverse effects on aqueous or terrestrial
organisms are anticipated with orthophosphates in the environment.
Sediments
No direct acute or long-term adverse effects on aqueous or sediment
organisms are anticipated with orthophosphates in the environment.
No direct acute or long-term adverse effects on terrestrial organisms are
The use of TKPP in detergents is not considered to pose a risk to the
atmospheric compartment.
Soil and groundwater
Atmospheric compartment
Secondary poisoning
ES12: Consumer use of cosmetics, toothpaste and other
Consumer use of cosmetics, toothpaste and other products containing TKPP
Sector of use (SU)
Revision date: X
SU 21: Consumer uses: private households.
Version: XX
Page 95/97
SAFETY DATA SHEET
Date of issue: xxx
Product category (PC)
PC 28: Perfumes, fragrances
PC 39: Cosmetics, personal care products
Process category
(PROC)
Article category (AC)
Not applicable.
Not applicable
Environmental release ERC 8a: Wide dispersive indoor use of processing aids in indoor systems.
category (ERC)
ERC 8b: wide dispersive indoor use of reactive substances in open systems.
The human exposure to TKPP from use of toothpaste is to be assessed under the Cosmetics Directive
and is not investigated under the REACH regulation. Therefore operational conditions are not relevant for
this scenario.
General advise
Consumer products should be intrinsically safe. The human exposure to
TKPP from use of toothpaste and other dental care products is to be
assessed under the EU Cosmetics Directive and is not investigated under
the REACH regulation. Risk management measures relating to the use of
TSP in dental care products should be conveyed on the package and no
further consideration is required.
Not applicable
Abatement measures related
with wastewater
Wastewater is treated via chemical/biological municipal wastewater
treatment plants.
Abatement measures waste
air and solid waste
Not applicable.
Type of waste
Disposal technique
Fraction released to
environment during waste
treatment
After brushing teeth the mouth is flushed with water and the greatest
portion of the toothpaste is disposed of via the sewer system. Sewage will
be treated in municipal wastewater treatment plants. Minor amounts of
products remain in the packages and will be disposed of via the regular
household waste. Household waste may be deposited in a landfill.
Not applicable.
Characterisation)
5.1. Human exposure
Exposure estimation tool(s)
Not applicable.
Consumer exposure
Consumer exposure to TKPP from the use of toothpaste is not assessed
under REACH. The potential risk for consumers from the use of cosmetics
and personal care products falls under the EU Cosmetics Directive.
Worker exposure
No occupational exposure to TKPP is expected from the use of
toothpaste.
Revision date: X
Version: XX
Page 96/97
SAFETY DATA SHEET
Indirect exposure via the
environment
Date of issue: xxx
No indirect exposure of humans via the environment is expected for
TKPP, as the substance can be effectively removed from the wastewater.
Thus, no assessment of indirect exposure of humans via the environment
is performed.
3-
The use of TKPP can potentially result in aquatic emissions and locally increase the phosphate (PO4 )
concentration. Phosphates reaching surface water increase the phosphorus content in the water body
which may cause eutrophication and water quality deterioration. Phosphorus should be removed from
industrial wastewater before it is released to the environment. This can be done by chemical treatment (by
precipitation with the help of aluminium or iron addition) or biological treatments. A high degree of removal
can be reliably achieved by the available phosphorus removal techniques. Site-specific conditions such as
flow rate of the receiving surface water body and phosphorus concentration in the receiving surface water
body should be taken into account when implementing an appropriate wastewater treatment. Council
Directive 96/61/EC concerning integrated pollution prevention and control and national regulations
concerning phosphates in industrial wastewater have to be followed to minimise the risk of eutrophication
due to phosphate releases. No direct acute or long-term adverse effects on aqueous or terrestrial
organisms are anticipated with orthophosphates in the environment. Bioaccumulation in organisms is not
relevant for inorganic phosphates.
Revision date: X
Version: XX
Page 97/97

SAFETY DATA SHEET Tetrapotassium pyrophosphate Table of

Transcription

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